Document 4az7de89e8LbbYeN8x3eDVrGG

u jTftpft'McilY. ORGA 5C COOLANT DATABOOK TECHNICAL PUBLICATION No. AT-1 JULY, 1958 Compiled 'by: MALCOLM McEWEN MONSANTO CHEMICAL COMPANY Organic Chemicals Division Development Department Lindbergh and Olive Street Road Gt. Louis 24, Missouri 0281685 TOWOLDMONOQ29695 GENERAL PROPERTIES (CHAIN-TYPE POLYPHENYLS) COMPOUND Biphenyl Terphenyl, o* Terphenyl, m* Terphenyl, p- puaterphenyl, o,opueterphenyl, m,m* Pueterphenyl, o,mPueterphenyl, p,p- ' Puatorphonyl, m,p6*-phonyl-m-terphenyl 2''ph#nyl-m-<efphenyl Puinquephenyl, m.m.m* Puinquophenyl, p,p,pPuinquephenyl, p,m,oPuinquephenyl, p,m,pPuinquephenyl, p,m,mPulnquephenyl, o,m,oPuinquephenyl, m.m.oPuinquephenyl, p,p,m2,5'diphonyt*p-terphenyl 2\6'-diphenyl-p-terphertyl 2,3'-diphenyl-p-terpheny1 . Hexaphenyl, o,o,o,oHexaphenyl. p.p.p.p* Hexaphenyl, p,b,o,pHexephenyl, m,m.m.mHexaphenyl, p.p.m.p* 2',3',6' triphenyl-p-terphenyl Heptaphenyt, pHexaphenyl benzene 5"'-biphenyf{p)-p-m-p-quinpheny) Oetaphenyl, m2,2',414\6,6'-hexaphenylbiphenyl Nonaphenyl, m?\3\3",6',6"-hexephenyl-p-queterphonyl Diciphanyl, mUndecipheny), m- Duodcciphcnyl, m* Tredeciphenyt, m- puaHuordeciphenyl, m- puindeciphenyl, mSedoeiphenyl, m- Formula C,,H,, Molecular Weight Melting Point C. 69.050 (2) Boiling Point C. 254.9 (30) Melting Point F. 156 (3) Boil Pom 491 (3 C,,H,, 56.25 {ro> 87.45 (10) 212.7 (10) 33^2_ 364 630 (3 687 (3 725 (3 C,,H,, 86__ 90 318 166 173.7 (3) 420 (3) 471 520 (3) 245 (3) 187 (3| I95_|3J_ 604 (3) 331 (3) 345 880 (2 CH 392 144.5-145.5 (3)| 264-66 (194? 155 (198) t5S.5-l56.5 113-114 |14) 269-70 (9) 277-78 (9) 190-4 (9) 165 (9) 208 (3) 737 |3) 311 312-14 (14)| 235-37 374-61 365 (3) 877 (3) 365 CH CHm CjiHj* C,,H,, CmH CwHai 251-53 (9) 545 449.5 (9) 230-32 (9) 348 (9) 166 (3) 318-19 (9) 184 |3) 202 (3) 223 (3) 245 (3| 270 |3) 292 (3) 321 (3) 484-88 1013 (3) 640-42 (9) 0 0 TOWOLDMON0029696 GENERAL PROPERTIES (ALKYL POLYPHENYLS) COMPOUND Mothylbiphenyl, 2' Methytbipbenyl, 3Mothylbiphenyl, 4Hthylbiphenyl, 2* Ethylbipfcenyl, 3* Formula CaiHu CuHit Dimethylbiphenyl, 2,2* Dlmethylbiphenyl, 2,3'Dtmelhylbiphenyl, 2,4'Dimethylbiphenyl, 3,2'* Dimethylbiphenyl, 3,3'Dimotbvlblphonvl, 3,4'- Dimethylbiphenyl, 2,4* Dlmethylbiphenyl, 2,6Dimethylblphenyl, 3,4* Dimothylbiphenyl, 3.5Pfopcnylbipbenyt, 2- CkHii Ci,Hi* CnHn Propylbiphenyt, 2* Propylbiphenyt, 3* , CnHn liopropylbiphenyl, 2liopropylbiphenyl, 3liopropylbiphenyl, 4liopropylbiphenyl, Mixturo 3 ft 4 n-Butylbiphenyl, 2* Sac-Butylbiphenyl, 2tert-Butylbiphenyl, 2- * Ci,Hu CuHu tetramethylbiphenyl, 2,2',ft,S'tetremefhylblphenyl, 2,2\6,6`Dbethyfbiphenyl, 2,2'Di-ethylbiphenyl, 4,4'liopropylbiphenyl. 2-methyl-5Amylb'phenyl Hexemrthylbiphenyl Cw.Hu CuH C,,H,, Molecular Weight 168.2 162.3 182.3 182.3 194.3 196.3 196.3 196.3 210.3 210.3 224.3 234.3 . .Iting Point C. 0 (3) 4 |3| 47 13) --6 (3) -27 (3) 34 (31 IS (3) Liq. (3) Uq. (3) Boiling Point C. 2S5 (3) 272 (3) 247 (31 244 (3) 284 (3) 283 (3) 244 (3) 270 (3) 274 (3) 7 (3) 14 13) 121 (3) Liq. (3) Liq. (3) 33 (3) 12 (3) 285 (3) 288 (31 292 3) 244 (3) 243 (3) 282 (3) 274 (31 -- 12 (3) Liq. (3) 40 (3) 24 (3) --54 (18) -13 (3) S (3) 21 13) S3 (3) 47 |3) tl (3) Uq. (3) 0 52 13) 221 (3) 277 (3) 270 (3| 294 (3) 303 (3) 295 (18) 291 (3| 282 (3) 282 (3) 285 (3) 274 (3) 313 (3| 249 (3) 305 320 (3) Melting Point F. 32 40 117 21 -- 17 94 64 Uq. Liq. 45 60 250 Liq. Liq. 91 II II . Liq. 76 --65 8 46 70 127 152 178 L.q. 32 (25) 126 Boil Po J 45 52 5t 51 54 54 50 51 52 54 55 55 50 54 52 42 53 SI 56 57 56 55 54 54 5< 52 5*. 5 5! 6! 0281687 TOWOLDMONOQ29697 GENERAL PROPERTIES IALKYL POLYPHENYLS) COMPOUND Hexylbiphenyl, 2 (?) Herylbiphonyl, 3 (?) DiiiopropvtbiDhony! (mined homers) Di-n-Butylbipheny), 4,4' .. Di-sec-Butylbiphenyl, 4,4'Di-tert-Butylbtph*nyl, 4,4 Di-tert-Amylbiphonyl, 4,4'* Diheicylbiphenyl Trihoxylbiphenyl o-Terphonyl, 6'-methyl o-Torphonyl, 4-vinylO-Terphnnyl, 3',6'-dirnothyl- O-Torphonyl, isopropylo-Terphnnyl, 4-butyl- m-Terphonyl, 5'-methyl- m-Terphenyl, 4-propylm-Terphonyl, Isopropylm-Terphenyl, 4,4",5'-1rImethyl m-Terphenyl, 5,5,,5"-tMmethy!- m-Tcrphonyl, amyl (?) M-Terphenyl, 4-n-oetyl- ni-Terphonvl, 4,4"-dlrnethvl-5'tolyl p-Terphenyl, 2-methyl- p-Terphonyl, 3-methylp-Terphenyl, 4-methyl- - p-Terphenyl, 2,5-dimethylp-Terphenyl, 2',S'-dimethylD-Terphenyl, 4',4"-dimethyl- p-Terphenyl, 2,2'\5,5"-tetremethylp-Terphenyl, diethyl* p-Terphonyl, 4.4'-dlcYrlohexyl* o,o-quaterphenyl, 2,2'"-dimethyl ,-quaterphenyl, 4,4'"-dtmethyl p.p-autrphenyl, 4.4"'-dimothyl 3`-phenyl-p-terphenyl, 2-mothyl 2-phenyl-p-terphonyl, 3',6',-dimethyl p-heiephenyl, 4,4`"'*dimethYl Formula CuHu C*H ChH C,,Hm C*H,, C..H CHi CHii CjiH CdHi, CiHi CuHm CmHji CHm c,,hm * CiiHm C,H,, C*Hn CwH C^H* C*H,, C-.Mm Molecular Weight 238.4 266.4 294.5 322.5 4067 244.3 256.3 250.3 272.4 286.4 244.3 272.4 300.4 342.5 348.5 244.3 25M 286.4 394.6 334.4 370.4 334.4 360.4 Melting Point c. --38 13) --40 (3) -31 (18) 88 (3) Uq. (3) 120 (31 Liq. (3) --30 --23 109 (3) 44 (31 130 (31 44 (3) --8 117,(3) 85 (31 100 1701 (9) 91 (31 189 (3) 207 (3) 159 (3) 183 (3) 249 (3) 112 (3) 280 (9) 13 (3) 113 (9) 334 (31 130 (197) 157 (ICO) 182-83 (9) Boiling Point C. 318 (3) 322 (3) 330 1181 384 (3) -363 (3) 326 (3) 360 (3) 375 436 150="" (3| 193.5*"" 131 l70->*"" (31 161'"" (3) 394 (3) 406 (3) 415 2802" (1931 270!-`"" (91 Melting Point F. --36 --40 --24 137 Llq. 263 Liq. --22 (31 -9 (3) 223 III 266 112 20 (3) 243 149 212 (25) 338-40 197 337 405 319 361 4BI 233 S36 236 236 633 266 315 324-25 Boiling Point F. 604 611 626 723 665 619 630 707 816 13) 3022*m) 455.8*"* 352u.litam 3J^lmxu 741 762 779 (25) 536:0m 889 (9! 0281686 TOWOLDMONOQ29698 MIXTURE COMPOSITION Biphanyl/napHthalana Biphenyl/o-terphanyl 8ipSonyl/m-tarphanyl Biphttvfllp-i^rphenyi m ierpSanyl/o.farphanyl m-tarphenyl/p-tarphenyl o-tarplianyi/p-terphanyl BipStnyl/Santowax R nepSrhalene/O'ferphsnyl Biphanyl/m-terphanyl/naphthalana Blpiienyl/m-tarptanyl/phananthrena Biphanyl/naphthalena/phananthrana 8ipV.eny!/c4erphertyIfnapIithaln* B'p^o.Ryl/o-fo.'p^eAyl/phananfhrena BipSenyWo-tarphanyl/m-tarphanyl Biplienyi/o-t*rpliafiy!/p-tarphanyt o-ierpkny!/m-!arphenyl/naplithalona b.tarpi.*n-/7m-tcrp?;eny!,'pficnantlirena o-tcrpScnyI/m.tcrpkonyl/p-t*rphonyf o-tsrpSeny'/napMValene/plienanlhrana o-terpSenyl/rupMiial'jna/p.ferphenyl Liquid Composition (mot%) 1st 2nd 3rd 57 43 40.5 593 45 55 97.1 2.9 33.7 66.3 95.65 435 98.45 1.55 91.7 8.3 33.7 66.3 ,, 41.0 42.5 42.6 313 31.9 30.9 40.2 51.9 53.2 65.8 53.4 65.8 29.0 30.9 37.0 47.8 48.7 47.5 59.2 24.5 25.2 33.5 24.6 33.5 30.0 26.6 20.4 21.0 19.4 21.6 0.6 23.6 21.6 0.7 22.0 0.7 Vapor Composition (mol%) 1st 2nd 3rd 36.6 63.4 79.1 20.9 20.9 79.1 873 12.7 MJP. OC. 39.5 23 42 67.8 293 85.5 55.75 69 29.2 B.P. C. 234.5 286.5 345.5 263 M.P. F. 103 73.4 108 154 85 185.9 1323 157 85 B.P. F. 454 547 654 505 Raftranea on (17) (1) (10) (17) (10) (10) (20) (17) 38.2 85.4 333 373 71.8 74.1 79.3 15.2 61.7 79.1 143 13.0 1.8 5.3 64.4 9.3 203 213 21.0 3.3 14.9 20.6 79.9 86.8 60.0 9.3 2.4 53.4 7.9 4.6 0.08 81.5 23.4 0.3 5.8 0.04 23.6 253 25.4 10.9 11.9 10.5 22.7 15.3 16.6 28.9 16.9 28.9 250 288 242.5 262 294 297.5 287 279 344 346 275.5 263 75 78 78 51 53 5t 73 59 62 84 62 84 482 550 468 504 561 568 549 534 651 655 528 505 (17) (17) (17) (17) (17) (17) (17) (17) (17) (17) (17) (171 GENERAL PROPERTIES (EUTECTIC MIXTURES) o r a A. TOWOLDMONOQ29699