Document 4QnddqYGkXyBzRV3JJoYmQ7e

PAGE 1 MATERIAL SAFETY DATA SHEET CIBA-GEIGY CORPORATION ADDITIVES DIVISION SEVEN SKYLINE DRIVE HAWTHORNE, NEW YORK 10532 (91A) 347-4700 EMERGENCY PHONE NUMBER. (800) 888-8372 SECTION I-IDENTITY INFORMATION IDENTITY (TRADENAME). CHIMASSORB 944 FL FAMILY/CHEMICAL NAME. P0LY((6-((l,l,3,3-TETRAMETHYLBUTYL)AMIN0)-S-TRIAZINE-2,4DIYL)((2,2,6,6-TETRAMETHYL-4-PIPERIDYL)IMIN0)HEXAMETHYLENE U2,2,6,6-TETRAMETHYL-4-PIPERIDYL)lMINO)) PRODUCT TYPE. HINDERED AMINE LIGHT STABILIZER IMPORTANT. PLEASE NOTE. REVISION 11 - SECTIONS II, VI REVISED. XXXXXXXXXXXXXXXXXXXXXXXXXXXXXX X THIS MATERIAL WILL NOT BE SOLD FOR USE IN PRODUCTS X X FOR WHICH PROLONGED CONTACT WITH MUCOUS MEMBRANES OR X X ABRADED SKIN, OR IMPLANTATION WITHIN THE HUMAN BODY, IS X X SPECIFICALLY INTENDED. BECAUSE OF THEWIDE RANGE OF X X SUCH POTENTIAL USES, CIBA-GEIGY CORPORATION IS NOT ABLE X X TO RECOMMEND THIS MATERIAL AS SAFE ANDEFFECTIVE FOR X X SUCH USES AND ASSUMES NO LIABILITY FOR ANY SUCH USES. X xxxxxxxxxxxxxxxxxxxxxxxxxxxxxx HAZARD STATEMENT . xxxxxxxxxxxxxxxxxxxxxxxxxxxxxx X THIS MATERIAL SAFETY DATA SHEET (MSDS) HAS BEEN X X PREPARED IN COMPLIANCE WITH THE FEDERAL OSHA HAZARD X X COMMUNICATION STANDARD 29 CFR 1910.1200. X X THIS PRODUCT IS CONSIDERED TO BE A HAZARDOUS X X CHEMICAL UNDER THAT STANDARD. X XXXXXXXXXXXXXXXXXXXXXXXXXXXXXX SECTION II-HAZARDOUS INGREDIENTS SPECIFIC CHEMICAL NAME. CHIMASSORB 944 FL Do ^6397 COA/p rDFNT.TO(. PAGE 2 POLYt(6-<(1,1,3,3-TETRAMETHYLBUTYL)AMIN0)-S-TRIAZINE-2,9DIYL)((2,2,6,6-TETRAMETHYL-9-PIPERIDYL)IMINO)HEXAMETHYLENE ((2,2,6,6-TETRAMETHYL-9-PIPERIDYL)IMINO)) CAS t. 70629-18-9 COMMON NAMEi CHIMASSORB 999 FL EXPOSURE LIMITSi OSHA PEL * NONE ESTABLISHED ACGIH TLV< NONE ESTABLISHED CARCINOGENICITYi THIS CHEMICAL HAS NOT BEEN REVIEWED FOR CARCINOGENICITY BY NTP, IARC, OR OSHA. SECTION III-PHYSICAL DATA APPEARANCE. WHITE TO OFF-WHITE GRANULES. ODOR. NO DISCERNABLE ODOR. BOILING POINT. NOT APPLICABLE. MELTING POINT. 100 - 135C DECOMPOSITION TEMPERATURE. NOT DETERMINED. EVAPORATION RATE. NOT APPLICABLE. PERCENT VOLATILE. < 0.5%. VAPOR DENSITY. NOT APPLICABLE. VAPOR PRESSURE. AT 20C, <7.5 X 10(-9) (MM HG) SOLUBILITY IN WATER. AT 20C, INSOLUBLE PH. 8.5 AT 100 G/L WATER SPECIFIC GRAVITY. 1.01 (H20 = 1) SECTION IV-FIRE AND EXPLOSION HAZARD DATA FLASH POINT. 320F (ASTM D-93) FLAMMABLE LIMITS IN AIR-LOWER. NOT DETERMINED. FLAMMABLE LIMITS IN AIR-UPPER. NOT DETERMINED. NFPA CODE. HI FI RO EXTINGUISHING MEDIA. CARBON DIOXIDE, FOAM, DRY CHEMICAL, WATER SPRAY. FIRE FIGHTING PROCEDURES-SPECIAL. USE SELF-CONTAINED BREATHING APPARATUS. CHIMASSORB 999 FL DO 086398 CONFIDENTIAL PAGE 3 UNUSUAL FIRE AND EXPLOSION HAZARDS> THE PRODUCT CAN FORM AN EXPLOSIVE DUST/AIR MIXTURE. AVOID DUST FORMATION AND CONTROL IGNITION SOURCES; EMPLOY GROUND ING, VENTING AND EXPLOSION RELIEF PROVISIONS IN ACCORD WITH ACCEPTED ENGINEERING PRACTICES IN PROCESS OPERATIONS CAP ABLE OF GENERATING DUST AND/OR STATIC ELECTRICITY. SECTION V-REACTIVITY DATA STABILITYi STABLE. INCOMPATIBILITY NONE KNOHN. HAZARDOUS DECOMPOSITION PRODUCTSi THERMAL DECOMPOSITION AND BURNING MAY PRODUCE CARBON MONOXIDE, CARBON DIOXIDE AND NITROGEN OXIDES. HAZARDOUS POLYMERIZATION: WILL NOT OCCUR. SECTION VI-HEALTH HAZARD DATA PRIMARY ROUTES OF EXPOSURE: DERMAL, INGESTION, AND INHALATION. ORAL LD50: (RATS) 9900 MG/KG SKIN IRRITATION: (RABBITS) NOT AN IRRITANT. EYE IRRITATION: (RABBITS) NOT AN IRRITANT. SENSITIZATION: (GUINEA PIGS) NO SENSITIZATION OBSERVED. INHALATION LC50: (RATS) >1.1 MG/L AIR FOR A 1-HOUR EXPOSURE; 1.1 MG/L AIR WAS THE HIGHEST AEROSOL CONCENTRATION OBTAINABLE UNDER THE CONDITIONS OF THE EXPERIMENT. (FOR AN ANALOGOUS PRODUCT) (RATS) A 4-HOUR EXPOSURE TO THE DECOMPOSTION PRODUCTS PRODUCED BY HEATING THE PRODUCT TO 300C ELICITED NO MORTALITIES WITH ONLY TRANSIENT SYMPTOMS NOTED IN THE ANIMALS. (FOR AN ANALOGOUS PRODUCT) MUTAGENICITY: AMES TEST: NEGATIVE NUCLEUS ANOMALY TEST (CHINESE HAMSTER): NO EVIDENCE OF MUTAGEN IC EFFECTS. SISTER CHROMATID EXCHANGE STUDIES ON SOMATIC CELLS: NO MUTAGENIC ACTIVITY. SUBCHRONIC STUDIES: FEEDING STUDIES WERE CONDUCTED USING THE RAT OR DOG FOR PERIODS UP TO 6-MONTHS AT DIETARY LEVELS UP TO 10,000 PPM. TOXICITY PRIMARILY INVOLVING THE LIVER AND MESENTERIC LYMPH NODE WERE EVIDENT IN BOTH SPECIES AT THE HIGHER DOSAGES. SPLEEN AND BLOOD CHANGES WERE ALSO SEEN. THE RAT NOEL WAS IN THE 5-7 MG/KG/DAY RANGE (100 PPM) WITH THE DOG NOEL BEING 19 MG/KG/DAY (600 PPM). A 2-GENERATION REPRODUCTION RANGE-FINDING STUDY IN THE RAT CHIMASSORB 944 FL DO 086399 CONFIDENTIAL PAGE 4 USING SIMILAR DIETARY LEVELS FOUND EFFECTS ON PUP WEIGHT AND DEVELOPMENT WITH A NOEL OF 33 MG/KG/DAY (500 PPM). A PHARMACOKINETIC STUDY IN THE RAT WAS CONDUCTED USING A SINGLE ORAL DOSE OF 15 OR 200 MG/KG. THE CHEMICAL WAS ABSORBED AND DISTRIBUTED INTO THE LIVER, SPLEEN AND KIDNEY WITH A PLASMA HALF-LIFE OF 28-HOURS. METABOLISM OCCURRED WITH FECAL EXCRETION ACCOUNTING FOR 69 - 76JS OF THE INITIAL DOSE WITHIN 24-HOURS AND 95 - 1002 BY 168-HOURS. OVEREXPOSURE EFFECTS DUST MAY BE HARMFUL IF INHALED AND IRRITATE THE RESPIRATORY TRACT. MAY CAUSE SKIN AND EYE IRRITATION AFTER REPEATED EXPO SURE. ANIMAL STUDIES INDICATE A POTENTIAL FOR LIVER, SPLEEN, LYMPH NODE AND BLOOD EFFECTS AS WELL AS A SLOWING OF INFANT DEVELOPMENT. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE! ASTHMA, CHRONIC RESPIRATORY DISEASE, SKIN CONDITIONS; LIVER DISEASE OR JAUNDICE. EMERGENCY AND FIRST AID PROCEDURES-EYESt FLUSH EYES WITH WATER FOR AT LEAST 15 MINUTES. GET MEDICAL ATTENTION. EMERGENCY AND FIRST AID PROCEDURES-SKINi IMMEDIATELY WASH WITH MILD SOAP AND WATER. IF IRRITATION SUBSEQUENTLY RESULTS, CONSULT A PHYSICIAN. EMERGENCY AND FIRST AID PROCEDURES-INGESTIONi IF CONSCIOUS, GIVE LARGE QUANTITIES OF WATER. GET MEDICAL ATTENTION. EMERGENCY AND FIRST AID PROCEDURES-INHALATIONi IF INHALED, REMOVE TO FRESH AIR. IF BREATHING IS DIFFICULT, GIVE OXYGEN. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION, (PREFERABLY MOUTH-TO-MOUTH). GET MEDICAL ATTENTION. EMERGENCY AND FIRST AID PROCEDURES-OTHER: WASH CONTAMINATED CLOTHING PRIOR TO REUSE. SECTION VII-SPILL OR LEAK PROCEDURES SPILL PROCEDURES! PREWET MATERIAL WITH WATER TO AVOID DUST FORMATION. SWEEP OR VACUUM AND PLACE INTO CLOSABLE CONTAINER FOR DISPOSAL. WEAR PROTECTIVE EQUIPMENT SPECIFIED BELOW. TOXIC TO FISH. WASTE DISPOSAL METHODSi INCINERATE IN A CHEMICAL INCINERATOR EQUIPPED WITH AN AFTER BURNER AND SCRUBBER. FOLLOW ALL FEDERAL, STATE AND LOCAL REGULATIONS. EFFLUENT DATA-BODi NOT BIODEGRADABLE IN THE MODIFIED STURM TEST, WITH 0 - IX IN 28 DAYS SEWAGE BACTERIAL TOXICITYi INHIBITORY CONCENTRATION ON RESPIRATION OF AEROBIC WASTE WATER BACTERIA: IC20, IC50, IC80 >100 PPM FISH TOXICITYi RAINBOW TROUT, LC50 96 H: 0.35 PPM BLUEGILL, LC50 96 H: 0.59 PPM CHIMASSORB 944 FL DO 086400 CONFIDENTIAL PAGE 5 INVERTEBRATE TOXICITYi DAPHNIA MAGNA, EC50 (24 HOURS)< 55 PPM ________________________ SECTION VIII-SPECIAL PROTECTION INFORMATION VENTILATIONi LOCAL EXHAUST REQUIRED. PROTECTIVE GLOVES. WEAR IMPERVIOUS GLOVES AS A STANDARD HANDLING PROCEDURE. EYE PROTECTION. IN CASES WHERE THERE IS LIKELIHOOD OF EYE CONTACT, WEAR CHEMICAL GOGGLES. RESPIRATORY PROTECTION. USE NIOSH APPROVED RESPIRATOR OR DUST MASK, IF REQUIRED. OTHER PROTECTIVE EQUIPMENT. WEAR COVERALLS. SECTION IX-SPECIAL PRECAUTIONS HMIS CODE. HEALTH . 2* FIRE . 1 REACTIVITY . 0 HANDLING PRECAUTIONS. AVOID SWALLOWING. AVOID INHALING DUST. AVOID EYE CONTACT AND REPEATED OR PROLONGED SKIN CONTACT. DO NOT USE OR HANDLE IN SUCH A MANNER AS TO GENERATE SIGNIFICANT AIRBORNE DUST. USE ONLY WITH ADEQUATE VENTILATION. FOR INDUSTRIAL USE ONLY. SHIPPING AND STORING PRECAUTIONS. KEEP CONTAINER TIGHTLY CLOSED WHEN NOT IN USE AND DURING TRANSPORT. PERSONAL HYGIENE. WASH THOROUGHLY AFTER HANDLING AND BEFORE EATING, DRINKING, OR USING TOBACCO PRODUCTS. SECTION X- REGULATORY INFORMATION DOT PROPER SHIPPING NAME. NOT REGULATED AS A HAZARDOUS MATERIAL BY THE U.S. DEPT. OF TRANSPORTATION (DOT) 49 CFR 172.101 HAZARDOUS MATERIALS TABLE. DOT CLASS. NONE. DOT NUMBER. NONE. RCRA STATUS. NOT A HAZARDOUS WASTE UNDER RCRA (40 CFR 261). SARA/TITLE III - EHS LIST. THIS PRODUCT DOES NOT CONTAIN AN 'EXTREMELY HAZARDOUS SUB STANCE' (EHS) FOR EMERGENCY PLANNING UNDER SEC. 301-303 (40 CFR 300 AND 355) AND FOR EMERGENCY RELEASE NOTIFICATION UNDER SEC. 304. SARA/TITLE III - CERCLA LIST. CHIMASSORB 944 FL DO 086401 CONFIDENTIAL PAGE 6 THIS PRODUCT IS (OR CONTAINS) A 'CERCLA' LISTED HAZARDOUS SUBSTANCE FOR EMERGENCY RELEASE NOTIFICATION UNDER SEC. 304 (40 CFR 302). BENZENE, DIMETHYL-. CASRN 1330-20-7; 0.8X SARA/TITLE III - TOXIC CHEMICALS LIST. THIS PRODUCT DOES NOT CONTAIN A TOXIC CHEMICAL FOR ROUTINE ANNUAL 'TOXIC CHEMICAL RELEASE REPORTING' UNDER SEC. 313 (40 CFR 372). TSCA INVENTORY STATUS. CHEMICAL COMPONENTS LISTED ON TSCA INVENTORY. CALIFORNIA PROPOSITION 65> THIS PRODUCT DOES NOT CONTAIN ANY CHEMICALS CURRENTLY ON THE CALIFORNIA LIST OF KNOWN CARCINOGENS AND REPRODUCTIVE TOXINS. MASSACHUSETTS RIGHT-TO-KNON ACT. CONTAINS NO COMPONENTS ON THE MASSACHUSETTS LIST AT A THRESHOLD LEVEL. NEW JERSEY RIGHT-TO-KNOW LABELING INFORMATION. THIS PRODUCT CONTAINS THE FOLLOWING . CHEMICAL NAME . POLY((6-((1,1,3,3-TETRAMETHYLBUTYL)AMINO)-S- TRIAZINE-2,4-DIYL)U2,2,6,6-TETRAMETHYL-4-PI PERIDYL)IMIN0)HEXAMETHYLENE((2,2,6,6-TETRAME THYL-4-PIPERIDYL)IMIN0>> CAS NUMBER . 70624-18-9 XXX PENNSYLVANIA RIGHT-TO-KNOW ACT. THE FOLLOWING IS REQUIRED COMPOSITION INFORMATION. CHEMICAL NAME . 1,6-HEXANEDIAMINE, N,N'-BIS(2,2,6,6-TETRAMET HYL-4-PIPERIDINYL)-, POLYMER WITH 2,4,6-TRIC HLORO-1,3,5-TRIAZINE AND 2,4,4-TRIMETHYL-2-P ENTANAMINE CAS NUMBER . 70624-18-9 COMMON NAME . POLY{(6-((1,1,3,3-TETRAMETHYLBUTYL)AMINO)-S- TRIAZINE-2,4-DIYL)((2,2,6,6-TETRAMETHYL-4-PI PERIDYL)IMIN0)HEXAMETHYLENE((2,2,6,6-TETRAME THYL-4-PIPERIDYL)IMIN0>> COMMENTS . NOT ON PENNSYLVANIA HAZARDOUS SUBSTANCE LIST. XXX ISSUE DATE. 04/03/90 REVISION. 11C FOR FURTHER INFORMATION, PLEASE CONTACT. BRUCE SCHWEMMER THE INFORMATION AND RECOMMENDATIONS CONTAINED HEREIN ARE BASED UPON DATA BELIEVED TO BE CORRECT. HOWEVER, NO GUARANTEE OR WARRANTY OF ANY KIND EXPRESSED OR IMPLIED IS MADE WITH RESPECT TO THE INFORMATION CONTAINED HEREIN. CHIMASSORB 944 FL DO 086402 CONFIDENTIAL CIBA-GEIGY CORPORATION ADDITIVES DIVISION THREE SKYLINE DRIVE HAWTHORNE, NEW YORK 10532 (914) 347-4700 05/17/90 DOW CHEMICAL U. S. A. ATTNi JIM BETHEA BLDG. 2307 LOUISIANA HIGHWAY 1 SOUTH PLAQUEMINE LA 70764 Dear Customer) Material Safety Data Sheets (MSDS) are routinely sent to you with your initial product order. These MSDSs relay identity health and safety* safe handling and regulatory information for our products. During the past few years* several Federal and state right-to-know laws have been enacted. The status of our products with respect to these laws is detailed in Section X of the MSDS, under the heading Regulatory Information. The MSDSs for the following products are enclosed with this letter) CHIMASS0RB 944 FL TINUVIN 328 We urge you to make the information in these MSDSs available to your colleagues and customers* as necessary and appropriate. Your continuing business is sincerely appreciated. ENCL0SURECS) CORDIALLY, CIBA-GEIGY CORPORATION BRUCE SCHWEMMER DIRECTOR, PRODUCT SAFETY AND ECOLOGY ADDITIVES DIVISION DO 086403 CONFTDFNTTAL