Document 4Kpn74XmGmnONeaDMy6Gpggx

Substance: I Vinyl chloride. OSIIA SAMPLING DATA SHEET //7a ' Standard: 29 CER 1910.93g, permanent standard of October 4. 1974 1* Limits of exposure: a. 8 hour time weighted average (TWA) b 15 minute ceiling average c. 15 minute ceiling for those electing not to wear respirators 1 ppm ' 5 ppm ' 25 ppm 2. Action level: 8 hour TWA Sampling Equipment: 0.5. ppm A calibrated personal sampling pump whose flow rate at 50 ml/mln is accurate within + 5% and activated coconut shell tubes containing two sections of 20/40 mesh activated charcoal separated by a 2-mm portion of urethane foam. Qualifications: Samples shall be collected only by or under the direction or Compliance Safety and Health Officers (CSllOs) who are Industrial Hygienists. Sampling Rate: * 50 ml/min`for all samples . Sample Size: 1 TWA samples: a. 5 liter maximum at concentrations below 200 ppm; maximum duration 100 min. b. 2 liter maximum at concentrations above 200 ppm; maximum duration 40 minutes. NOTE: In some cases it may be necessary to estimate the vinyl chloride concentration with a portable direct reading Instrument to determine the proper volume of air to sample. * #* ******* f ' M " ,tt ` t ** * . . -J* * * ' ... . UCC 092840 2. Celling average samples; 750 milliliters; 15 min. duration There should be no variation from 15 minutes unless the variation is justifiable. Sampling Procedure; \ (1) Employee exposures are determined by collecting air samples from a worker's breathing zone using personal samplers. (2) TWA 8-hour average exposures are determined by collecting a series of consecutive personal air samples that completely cover the duration of exposure in the 8-hours. (3) Fifteen minute ceiling average exposures are determined by collecting full 15 minute period personal air samples. (4) Which employee exposures to measure may be determined by screening the concentration of vinyl chloride in the workplace area with' a direct reading instrument. (5) Immediately before sampling, both ends of two charcoal tubes are broken so as to provide openings at least one-half the internal diameter of the tubes. .' (6) The first charcoal tube is positioned in the tube holder with the smaller backup section of charcoal being positioned nearest the pump. The second charcoal tube serves as a breakthrough indicator and is connected with a small, i.e 0.5 inch, piece Y~<of Tygon tubing to the outlet of the plastic charcoal tube ' "holder with the smaller section of charcoal being positioned nearest the pump and connected to the main sample line leading to the pump. Both tubes must be in a vertical position during sampling to avoid channeling and subsequent premature breakthroug , of vinyl chloride. (7) Air being sampled must not be passed through any hose or tubing before entering the first charcoal tube. ,. (8) Set the flow rate at approximately 50 ml/min and record the initial counter number. Sample for an appropriate amount of time and record the final counter number. The sample volume is obtained by multiplying the number of counter strokes times the cc/stroke factor. Record the date, location, temperature, pressure and the tube number. f` MV -v't-**;- UCC 092841 -3 j (9) Immediately after sample collection separate the Sample tube froi the backup tube and cap the tubes with the supplied plastic caps. Put a sample seal on each tube and label the tubes with matching numbers. Designate the sample tube by the letter "S" and the backup tube by the letters "BU". For example, the tubes used to collect the first sample of the day would be labeled 1-S and 1-Bl (10) .' Include one blank charcoal tube with every 20 samples (or one wit each lot of samples if less than 20 samples are taken), Handle t blank in the same fashion as the others with the exception that r sample is collected on it. The ends are broken and the tube is immediately capped and prepared for shipping. Label the tube as blank. The backup tubes are not to be considered as blanks. Analytical Procedure: .* Vinyl chloride is desorbed from activated coconut shell charcoal with carbon disulfide and analyzed using a gas chromatograph with a flame ionization detector,. The primary charcoal tube., is analyzed as the sample (both front and back, sections together) and the backup charcoal tube is analyzed as the breakthrough indicator. Minimum to be Reported: 0.25 ppm * * NOTE: Lesser concentrations will be reported as less than 0.25 ppm, except where none is detected it will be reported as "none detected", * * . i Special Considerations; . (1) Do not ship bulk samples of polyvinyl chloride or copolymers ... of vinyl chloride to the laboratory for VC analysis. Our . procedure deals with airborne VC. (2) Where two or more compounds are known or suspected to be present in the air, transmit this information, including their suspected identities, with the sample to the laboratory. (3) The sampling places a heavy load on the sampling pump due to the high resistance of-two charcoal tubes in series. Therefore, do not operate the pumps more than 8 hours continuously without fully recharging the battery. ****, r** * *'* ** V' 'I#*- > ' ucc 092842 (4) The presence of high humidity or water mist causes a reduction in breakthrough volume. However, this has been taken into accou and as long as the specified maximum sample size is not exceeded no breakthrough should occur. , \ (5) The desorption efficiency of charcoal can vary from batch to batch. Therefore, all the tubes used 'to collect a set of sample should contain charcoal from the same batch. Record the charcoa. lot number'on the sample seal. (6) The increased pressure drop of two tubes in series will cause the cc/stroke factor to change. Also this cc/stroke factor, at this high pressure drop, will vary slightly with flov; rate. Therefore, for this special sampling situation, the pumps must be calibrated at a flow rate in the vicinity of 50 ml/min with two charcoal tubes in line ahead of the pump and a corresponding cc/stroke factor determined. When sampling for vinyl chloride use only the flow control setting that correspond? to the flow rate in the vicinity of 50 ml/min as determined from this calibration. Shipping Instructions r Ship samples in a mailing tube. Mark it "RUSH" and send it '"AIR MAIL." The CSHO should make every effort to forward the samples to the laboratory by the morning following the day the samples are collected. It is imperative that the laboratory receive the samples soon enough to complete the analyses within 96 hours after sample collection. Fre-planning is necessary. \jcc 092843