Document 4JB9xKyw75n9EZ7XVjrpN9LDx

'p QC Laboratories' Analytical Report PETER TYRRELL UNITED HATER CITY OF ORANGE CHESTNUT STREET PLANT AT 632 BEACH STREET ORANGE, NJ 07050 Account No: C00927, UNITED HATER CITY OF ORANGE Project No: C009Z7, UNITED HATER CITY OF ORANGE Sample Nunber L2604751-1 Sample Description CHESTNUT ST Received Temp: 36 F Iced (Y/N): Y Parameter PFOA Method Sample Number L2604751-2 Sample Description ORANGE PARK Received Temp: 36 F Iced (Y/N): Y Parameter PFOA Method Sample Number Sample Description L2604751-3 GIST PLACE Regarding: PETER TYRRELL UNITED HATER CITY OF ORANGE CHESTNUT STREET PLANT AT 632 BEACH STREET ORANGE, NJ 07050 P.O. No: PHSID No: 0717001 Samp. Date/Time/Temp 04/02/08 08:30am NA F Inv. No: 963474 Sampled by Customer Sampled MCL Result ATTACHED RLs Test Date,Time Samp. Date/Time/Temp 04/02/08 07:45am NA F Sampled by Customer Sampled MCL Result ATTACHED RLs Test Date.Time Samp. Date/Time/Temp 04/02/08 08:05am NA F Sampled by Customer Sampled - A result of "I" indicates the concentration of the analyte tested was either not detected or below the RLs. - Definitions: ND=not detected; NEG=negative; Postpositive; COL=colonies; RLs=laboratory reporting limits; L/A=lab accident; TNTC=too numerous to count; NL=No Permit Limits. - A result marked with "DRY" indicates that the result was calculated and reported on a dry weight basis. - All analysis, except field tests are conducted in Southampton, PA unless otherwise identified. - The test"pH lab"is analyzed upon receipt at the laboratory, the result will not be suitable for regulatory purposes. - Actual times of analysis for parameters reported <24 hours are available upon request. All testing is conducted within the required holding time unless otherwise noted. - qc NELAP ID's:PA 09-00131,NO PA166.FL E87954.NY 11223.CT PH-0768,DE PA-018,KY 9 0 2 2 8 , 2 0 6 , EPA PA00018.Bioassay:PA 09-03574,NJ 3A034,FL E87953 KS E10373 SC 89020001 - QC STATE lD's:Wind Gap.NJ PA001.PA 48-01334;E RUTHERFORD NJ02015;Vineland NJ06005; Reading PA 06-03543. - MCL= is the recommended EPA "Maximum Contaminant Level" for a parameter. PLs=customer specific permit limits. legulatory authorities are assessing substantial fines for testing omissions. Please track your sample collections and results m a weekly, monthly, or quarterly basis to ensure compliance. Q C 's internet program 'LIVE ACCESS' will provide you with eal-tiroe access to collection dates and results. Please contact Customer Service for further information on acquiring LIVE ACCESS. 'age 1 of Z Serial Number: 955501 Thom as J. Hines, President 1205 Industriai Bvd., P.O. Box 514,Southampton, PA 18966-0514 Phone: 215-355-3900 Fax: 215-355-7231 www.gclaboratories.com DEP2-SDWB-000158 QC Laboratories Analytical Report Account No: C00927, UNITED HATER CITY OF ORANGE Project No: C009Z7. UNITED HATER CITY OF ORANGE Received Temp: 36 F Iced (Y/N): Y Parameter PFOA Method P.0. No: PWSID No: 0717001 Inv. No: 963474 MCL Result ATTACHED RLs Test Date,Time - A result of "ND" indicates the concentration of the analyte tested was either not detected or below the RLs. - Definitions: ND=not detected: NEG=negative; Postpositive; COL=colonies; RLs=laboratory reporting limits; L/A=lab accident; TNTC=too numerous to count; NL=No Permit Limits. - A result marked with "DRY" indicates that the result was calculated and reported on a dry weight basis. - All analysis, except field tests are conducted in Southampton, PA unless otherwise identified. - The tesf'pH Iab"is analyzed upon receipt at the laboratory, the result will not be suitable for regulatory purposes. - Actual times of analysis for parameters reported <24 hours are available upon request. All testing is conducted within the required holding time unless otherwise noted. - QC NELAP ID'srPA 09-00131,NJ PA166,FL E87954.NY 11223,CT PH-0768,DE PA-018,KY 90228,Ml 206.EPA PA00018.Bioassay:PA 09-03574.NJ 3A034 FL E87953 KS E10373 SC 89020001 - QC STATE ID's-Wind Gap.NJ PA001.PA 48-01334;E RUTHERFORD NJ02D15;Vineland NJ06005; Reading PA 06-03543. - MCL= is the recommended EPA "Maximum Contaminant Level" for a parameter. PLs=customer specific permit limits. legulatory authorities are assessing substantial fines for testing emissions. Please track your sample collections and results in a weekly, monthly, or quarterly basis to ensure compliance. QC's internet program 'LIVE ACCESS' will provide you with eal-time access to collection dates and results. Please contact Customer Service for further information on acquiring LIVE ACCESS. 'age 2 of 2 Serial Number: 955501 Thom as J. Hines, President DEP2-SDWB-000159 TestA m erica THE LEADER IN ENVIRONMENTAL TESTING ANALYTICAL REPORT PFOA/PFOS Analysis L o t#: D8D040262 Nicki Sm ith Q C Laboratories, Inc. 1205 Industrial Highw ay Southam pton, PA 18966 TestA m erica Laboratories, Inc. Project M anager A pril 17,200 8 4955Yarrow Street Arvada, CO 80002 te l 303.736.0100 fax 303.431.7171 www.te$tam ericaincxom Table Of Contents Standard Deliverables Report Contents Standard Deliverables The Cover Letter and the Report Coverpage are considered integral parts ofthis Standard Deliverablepackage. This report is incomplete unless a llpages indicated in this Table o fContents are included. Table of Contents Case Narrative Executive Summary - Detection Highlights Methods Summary Method/Analyst Summary Lot Sample Summary Analytical Results QC Data Association Summary Chain-of-Custody TotoaflPNaugmesber TestAmerica l DEP2-SDWB-000161 Case Narrative D8D040262 TestAmerica Denver utilizes USEPA approved methods in all analytical work. The samples presented in this report were analyzed for the parameters listed on the methods summary page in accordance with the methods indicated. Dilution factors and footnotes are provided on each datasheet to assist in the interpretation of the results. The results relate only to the samples in this report and meet all requirements of NELAC. All data have been reviewed for compliance with the laboratory QA/QC plan and have found to be compliant with laboratory protocols with any exceptions noted below. Please note that Non-Detect (N D ) results have been evaluated down to the Method Detection Limit (M DL) and should be considered ND a t the MDL. Unless otherwise noted, results for solids have been dry weight corrected. This report shall not be reproduced except in full, without the written approval of the laboratory. Sam ple A rrival and R eceipt The following report contains the analytical results for three samples received 4/4/08, according to documented sample acceptance procedures. The samples were received in good condition at a temperature o f 2.3C . No anomalies were encountered during sample receipt S ta n d a rd s Analytical standards w ere prepared using the add form o f the compound perfluorooctanoic acid (PFOA). PFOS is a commercial prepared and certified solution. Perfluoro-n-[1,2,3,4-taC 4]octanoic add was introduced at the extraction step and was used as an internal standard for quantitation of PFOA. Perfluoro-1-I1,2,3,4-13C4]octanatesulfonate was introduced at the extraction step and was used as an internal standard for quantitation of PFOS. Sample Extraction and Analysis The sample presented in this report was analyzed for the target analyte by TestAmerica Denver's SO P DEN-LC-0012A. For water samples a 250 mL aliquot of each sample is acidified with 1 mL o f 6N H Q solution and it is extracted using solid phase extraction technique with methanol conditioned C18 cartridges. Each sample is spiked with the internal standard, prior to extraction. After the sample is passed through the cartridge, the analytes are eluted with 4 mL of methanol. The final volume is brought to 5 mL using methanol and the extract is analyzed by LC/MS/MS. M ethod Q C Sam ples The Method Blank is processed reagent water spiked with surrogate and prepared with each batch of 20 samples o f the same matrix. The method blank was non-detect at the reporting limit. Each batch is prepared with a Laboratory Control Sample (LCS). The recoveries of two concentration levels of Laboratory Control Samples were within control limits. TestAmerica DEP2-SDWB-000162 Analytical Comments The Standard Operating Procedure (S O P ) was altered slightly for these samples in the sample prep and LC conditions. The alterations are listed below. Sample Prep Differences: The samples were propped following the normal procedure for SO P DEN-LC-0012, Revision 4 up until section 10.1.3.10. These samples were not acidified and a W aters Oasis W ax column was used instead of a Phenomenex Strata X column. The samples were rinsed 2 times with 6 mL of formic acid solution instead o f HPLC grade water, which differs from section 10.1.3.19. The formic acid solution is propped by diluting 2.225 mL of 88% formic acid to 100 mL with water. Section 10.1.3.20 was altered by adding 4 mL of 1% ammonium hydroxide in methanol to each cartridge instead o f 4 mL o f methanol. No other anomalies were observed. TestAmerica EXECUTIVE SUMMARY - Detection HighHgfats D8D040262 PARAMETER L2604751-1 04/02/08 08:30 001 PFOA PFOS L2604751-2 04/02/08 07:45 002 PFOA PFOS L2604751-3 04/02/08 08:05 003 PFOA PFOS RESULT REPORTING LIMIT UNITS ANALYTICAL METHOD 0.030 0.010 0.0082 J 0.010 ug/L ug/L DEN -LC-0012 DEN -LC-0012 0.066 0.010 0.0085 J 0.010 ug/L ug/L DEN -LC-0012 DEN -LC-0012 0.071 0.016 0.010 0.010 ug/L ug/L DEN -LC-0012 DEN -LC-0012 TestAmerica DEP2-SDWB-000164 METHODS SUMMARY D8D040262 ANALYTICAL PARAMETER_________________________________________ METHOD______ LC/MS/MS, PFOA DEN -LC-0012 References: DEN Severn Trent Laboratores, Denver, Facility Standard Operating Procedure. PREPARATION METHOD_____ TestAmerica DEP2-SDWB-000165 METHOD / ANALYST SUMMARY D8D040262 ANALYTICAL MBTHOD________________________ ANALYST_______________________ DEN -LC-0012 Jaqueline Bonnett References: DEN Severn Trent Laboratores, Denver, Facility Standard Operating Procedure. ANALYST ID_____ 003601 TestAmerica DEP2-SDWB-000166 SAMPLE SUMMARY D8D040262 WO ft SAMPLE# CLIENT SAMPLE ID______________________________________ ____ SAMPLED SAMP DATE TIME K K Q W 001 L2S04751-1 KKQVX 002 L2604751-2 KKQVO 003 L2604751-3 04/02/08 08:30 04/02/08 07:45 04/02/08 08:05 NOTB(S): - The analytical resubs o f ibe samples listed above are presented on die following pages. - AU calculations are performed before rounding to avoid round-offerrors in calculated respite. - Results noted as *ND* were not detected at or above tbe stated lim it. - This report must not be reproduced, except in foil, without die wriiten approval o f the bboratory. - Results fo r die following parameters are o arer reported on a dry weight b ass; color, corrosivity, density, fbdipoint, gnitability. layers, odor, paint filter test. pH , porosity pressure, reactivity, redox potential, specific gravity, spot tests, solids, sohdnhty, temperature, viscosity, and weight. TestAmerica DEP2-SDWB-000167 QC Laboratories CLient Sample ID: L260475I-1 HPLC Lot-Sample #...: D8D040262 -001 Work Order f __ : KKQW2AA Date Sampled__ : 04/02/08 08:30 Date Received..: 04/04/08 Prep Date..... : 04/09/08 Analysis Date..: 04/11/08 Prep Batch # __ : 8100121 Analysis Trine..: 00:42 Dilution Factor: 1 Method... .... : DEN -LC-0012 M PARAMETER PFOA PROS RESULT 0.030 0.0082 J REPORTING LIMIT 0.010 0.010 UNITS ug/L ug/L SURROGATE 13C4 PFOA 13C4 PFOS PERCENT RECOVERY 115 76 RECOVERY LIMITS (50 - 200) (50 - 200) NOTTS(S):_____________ I Estimated tts A . Result is less thaa RL. : WATER TestAmerica 8 DEP2-SDWB-000168 QC Laboratories Client Sanale ID: L2604751-2 HP1.C Lot-Sample # __ Date Sampled__ Prep Date..... Prep Batch # __ Dilution factor D8D040262-002 Work Order i ... : KKQVX2AA 04/02/08 07:45 Date Received..: 04/04/08 04/09/08 Analysis Date..: 04/11/08 8100121 Analysis Tine..: 01: 2 1 1 Method DEN -LC-0012 Matrix PARAMETER PFOA PFOS RESULT 0.066 0.0085 J REPORTING LIMIT 0.010 0.010 UNITS ug/L sg/L SURROGATE 13C4 PF0A 13C4 PFOS PERCENT RECOVERY 110 76 RECOVERY LIMITS (50 - 200) (50 - 200) MOTB(S) ;____________ _ I Estimated result. R an k is less t e n RL. : WATER TestAmerica DEP2-SDWB-000169 QC Laboratories Client Saaple ID: L2604751-3 HPLC Lot-Sanale # __ Date Sampled__ Prep Date_____ Prep Batch 9 -- Dilution Factor D8D040262-003 Work Order 9...: KKQV02AA 04/02/08 08:05 Date Received..: 04/04/08 04/09/08 Analysis Date..: 04/11/08 8100121 Analysis Time..: 01:35 1 Method........ : DEN -LC-0012 Matrix PARAMETER PFOA PFOS RESULT_________ 0.071 0.016 REPORTING LIMIT 0.010 0.010 UNITS ug/L ug/L SURROGATE 13C4 PFOA 13C4 PFOS PERCENT RECOVERY______ 108 64 RECOVERY LIMITS (50 - 200) (50 - 200) WATER TestAmerica 10 DEP2-SDWB-000170 QC DATA ASSOCIATION SUMMARY D8D040262 Sample Preparation and Analysis control Numbers SAMPLE# 001 002 003 MATRIX WATER WATER WATER ANALYTICAL METHOD DEN -LC-0012 DEN -LC-0012 DEN -LC-0012 LEACH BATCH # PREP BATCH # 8100121 8100121 8100121 MS RUN# 8100064 8100064 8100064 TestAmerica 11 DEP2-SDWB-000171 METHOD H U N K REPORT HPLC Client Lot ft...: D8D040262 MB Lot-Saaple ft: R8D090000-121 Analysis Date..: 04/10/08 Dilution Factor: 1 Work. Order ft__ : KKXWT1AA Prep Date..... : 04/09/08 Prep Batch ft...: 8100121 Matrix........ : HATER Analysis Time..: 23:50 PARAMETER PFOA PFOS RESULT ND ND REPORTING LIMIT OMITS 0.010 ug/L 0.010 ug/L METHOD DEN -LC-0012 DEN -LC-0012 SURROGATE 13C4 PFOA 13C4 PFOS PERCENT RECOVERY 101 60 RECOVERY LIMITS (50 - 200) (50 - 200) HOTB(S) :_____________________________________ Calculation are performed before rounding to avoid round-off errors in calculated results. TestAmerica 12 DEP2-SDWB-000172 LABORATORY CONTROL SAMPLE EVALUATION REPORT HPLC Client Lot I -- : D8D040262 Work Order # ___ : KKXWT1AC LCS Lot-Sample#: R8D090000-121 Prep Date..... : 04/09/08 Analysis Date..: 04/11/08 Prep Batch i...: 8100121 Analysis Tine..: 00:03 Dilution Factor: 1 Matrix PARAMETER PFOA PFOS PERCENT RECOVERY 98 93 RECOVERY LIMITS (70 - 130) (39 - 120) METHOD______ DBB -LC-0012 DEN -LC-0012 SURROGATE 13C4 PFOA 13C4 PFOS PERCENT RECOVERY 108 72 RECOVERY LIMITS (50 - 200) (50 - 200) NOTB(S) :________________________ ____________ Calculation: arc performed before rounding to avoid rcmnd-oif errors in calm laird results. Bold prim denotes connot parameters KATER TestAmerica 13 DEP2-SDWB-000173 LABORATORY CONTROL SAMPLE DATA REPORT HPLC Client Lot 9 __ : D8D040262 Work Order 9...: KKXWT1AC LCS Lot-Sample#: R8D090000-121 Prep Date_____ : 04/09/08 Analysis Date-.: 04/11/08 Prep Batch # __ : 8100121 Analysis Time..: 00:03 Dilution Factor; 1 Matrix........ : WATER PARAMETER PFOA PFOS SPIKE AMOUNT 0.200 0.200 MEASURED AMOUNT 0.197 0.186 UNITS ug/L ug/L PERCENT RECOVERY 98 93 METHOD DEN -LC-0012 DEN -LC-0012 SURROGATE 13C4 PFOA 13C4 PFOS PERCENT RECOVERY 108 72 RECOVERY LIMITS (50 - 200) (50 - 200) MOrB(S} :____________________________________ Calculations are perfoimed before rounding to avoid round-off errors in calculated results. Bold print d epot control parameters TestAmerica 14 DEP2-SDWB-000174 LABORATORY CONTROL SMPLB EVALDATIQH REPORT HPLC client Lot # __ : D8D040262 Work Order #.. . LCS Lot-Sample#; R8D090000-121 Prep Date.... 04/09/08 Analysis Date.. Prep Batch # -- : 8100121 Analysis Tine.. Dilution Factor; 1 KKXWT1AD 04/11/08 00; 16 Matrix PARAMETER PFQA PEGS SURROGATE 13C4 PFOA 13C4 PFOS PERCENT RECOVERY 98 98 RECOVERY LIMITS (70 - 330) (39 - 120) PERCENT RECOVERY 115 97 METHOD DEB -LC-0012 DEN -LC-0012 RECOVERY LIMITS (50 - 200) (50 - 200) NOTK(S) :____________________________________ Calculations are performed before rounding to avoid round-off errors m calculated results. Bold prim denotes control parameters WATER TestAmerica 15 DEP2-SDWB-000175 LABORATORY CONTROL SAMPLE DATA REPORT HPLC Client Lot D8D040262 Work Order #... : KKXWT1AD LCS Lot-Sample#: R8D090000-121 Prep Date.... . ; 04/09/08 Analysis Date..: 04/11/08 Prep Batch # __ : 8100121 Analysis Time..: 00:16 Dilution Factor: 1 Matrix........ : WATER PARAMETER PFQA PROS SPIKE AMOUNT 0.0200 0.0200 MEASURED AMOUNT 0.0196 0.0196 UNITS ug/L ug/L PERCENT RECOVERY 98 98 METHOD DEN -DC-0012 DEN -LC-0012 SURROGATE 13C4 PFOA 13C4 PFOS PERCENT RECOVERY 115 97 HOTK(S): _______________________________ Calculations are performed before rounding to avoid round-off errors in results. Bold prim denotes coatto! parameters RECOVERY LIMITS (50 - 200) (50 - 200) TestAmerica 16 DEP2-SDWB-000176 MATRIX SPIKE SAMPLE EVALUATION REPORT HPLC Client Lot #...: D8D040262 Work Order # __ : KKQW1AC -MS MS Lot-Sample #; D8D040262:- o o i KKQW1AD-MSD Date Sampled__ ; 04/02/08 08:30 Date Received..: 04/04/08 Prep Date..____: 04/09/08 Analysis Date..: 04/11/08 Prep Batch 8100121 Analysis Time..; 00:55 Dilution Factor: 1 Matrix______ PARAMETER PFQA PFOS PERCENT RECOVERY 95 95 87 89 RECOVERY LIMITS (70 - 130) (70 - 130) (39 - 120) (39 - 120) RPD RPD LIMITS 0.44 (0-20) 1.9 (0-20) METHOD DEN -LC-0012 DEN -LC-0012 DEN -LC-0012 DEN -LC-0012 SURROGATE 13C4 PFOA 13C4 PFOS PERCENT RECOVERY 112 112 81 84 RECOVERY LIMITS (50 - 200) (50 - 200) (50 - 200) (50 - 200) MOTB(S) ;_____________________________________ Calculations are performed before rounding to avoid roundoff error* in ratnilatecl results. Bold print denotes control parameters TestAmerica 17 DEP2-SDWB-000177 MATRIX SPIKE SAMPLE DATA REPORT HPLC Client Lot # ---; D8D040262 Work Order #...: KKQW1AC-MS MS Lot-Sanple #: D8D04 0262-001 KKQW1AD-MSD Date Sampled-- : 04/02/08 08:30 Date Received..: 04/04/08 Prep Date______: 04/09/08 Analysis Date..: 04/11/08 Prep Batch #...: 8100121 Analysis Time..: 00:55 Dilution Factor: 1 Matrix. WATER PARAMETER PFOA PFOS SAMPLE AMOUNT 0.030 0.030 0.0082 0.0082 SPIKE AMT 0.210 0.210 0.210 0.210 MEASRD AMOUNT 0.230 0.229 0.192 0.195 UNITS ug/L ug/L ug/L ug/L PERCNT RECVRY RPD METHOD 95 DEN -LC-0012 95 0.44 DEN -LC-0012 87 DEN -LC-0012 89 1.9 DEN -LC-0012 SURROGATE 13C4 PFOA 13C4 PFOS PERCENT RECOVERY 112 112 81 84 HOTB(S) ;_____________________________________ Calculations are performed before rounding to avoid round-off errors in caknlatrd results. RECOVERY LIMITS (50 - 200) (50 - 200) (50 - 200) (50 - 200) TestAmerica tv> CS)r ~ 7 -7 ' '"' : cn C 18 DEP2-SDWB-000178 DEP2-SDWB-000179 WC K K Io ^ o QC Laboratories' CHAIN OF CUSTODY Page_____ ol_____ S1o2u0t5hIanmdputsotrni,aPl BAlv1d8. 966-0514 PFahxo;nt: 221155--335555--73293010 Bill ta/Rapcrt to: (Hdifferent) CllenVAcct, No. Address Sammifia Bit Addreae: lit difterem) Ctty/State/Zip Phone/Fax Client Contact PROJECT F IE L D ID USLoQ^sr ! -( 0- o ^ f'b c t - 3 P.O. No. QC Contact Collection Date Military Time 0$3Q Yftjf P f NumMr ot Cmamete Matrix Code Ut Total 11 DU :bui -DU M ATRIX C O D E S OW: DRINKING WATER GW: GROUND WATER WW: WASTEWATER SO: SOIL SL: SLUDGE OIL OIL SOL: NON SOIL SOLID Ml: MISCELLANEOUS X: OTHER wmmmmmm PFPSjANALYSIS REQUESTED PfD* Field pH, Temp (C or F), DO, Cl2, 8. Cond. etc. razo> =r. --ur. V Tcr cmr <T\ H cn -no- SAMPLED BY: (Nama/Company) VerOal/tax data d u e:. Hardcopy due:_ Report Format; tBS'taannddaard. Forma Standard + QC NJ Reduced Disk Please eall tor pricing and availability on ruth (< 1 4 -H day) turnaround and on all but standard format. Field Parameters Analyz;ed By: Sip: Oatemma: SAMPLE CUSTODY EXCHANGES MUST BE DOCUMENTED BELOW USE FULL LEGAL SIGNATURE. DATE AND MILITARY TIME (24 HOUR CLOCK. I.E. 8AM IS 0800.4 PM IS 1GOO) RELINQUISHED BY SAMPLER DATE TIME RECEIVED BY DATE TIME DELIVERY MEJMOI5; D O C COURIER Custody Sen Number 1_ .. . ^ M f il u ig H E D e\yn j , i f rW -4 & \i> c C RELINQUISHED BY (J Q // f t/ DATE TIME RELINQUISHED BY DATE TIME I 6 f) ft < u A a w M Y /7 f j 2 R E C B iy /p jL -y / V - a RECEIVED BY ..... . . DATE W y/ i DATE TIME TIME O teO TIME UP8 ' < V e DEX C O M M E N T S '. G OTHER_____ 4 RELINQUISHED BY 5 DATE TIME 4 RECEIVED BY 5 DATE TIME Hazardous: For example to eld completion, see reverse aide. yas / no (S u H u <D 4J (A ID E-r