Document 44mr65J66yyKprJyb1Xvd0b51

MATERIAL SAFETY DATA SHEET ************************** The C.P. Hall Company 7300 S. Central Avenue, Chicago, IL 60638 Emergency Telephone No: 312/767-4605 ______________SECTION I____________ Chemical Name: n-hexyl,n-octyl, n-decyl trimellitate Chemical Family: Ester Formula: Indefinite Product Name: HMIS Number: Goggles SECTION II - HAZARDOUS INGREDIENTS None SECTION III ~ PHYSICAL DATA Boiling Point (F): N/A Specific Gravity: Vapor Pressure: Negligible (H20=1 at 25/25C) Vapor Density: N/A % Volatile by Vol: Solubility in Water: Negligible Evaporation Rate: (Water = 1) Appearance & Odor: Clear liquid; mild odor 0.97 Nil Nil SECTION IV - FIRE AND EXPLOSION HAZARD DATA Flash Point (Method used): COC 535F Extinguishing Media: C02, Dry Chemical, Water Fog Flammability Limits: Not available Special Fire Fighting Procedures: Wear MESA/NIQSH approved selfcontained breathing apparatus (Sch. 13). Use water spray to cool fire-exposed containers. Unusual Fire and Explosion Hazards: Water may cause frothing. SECTION V ~ HEALTH HAZARD DATA Threshold Limit Value: Not determined by the ACGIH. Effects of Overexposure: Excessive fumes have disagreeable effect. In industry hazard rating considered low as skin irritation, toxicity from ingestion or inhalation. Emergency & First Aid Procedures: In case of skin contact, remove ex cess oil with cloth or absorbent paper, then wash with soapy water. In case of eye contact, remove excess oil with cloth or absorbent paper then wash with water. If excessive inhalation, remove to fresh air. Consult physician for discomfort. 1 CDOONF0T8D780N2T9T Al Product Name: PLASTHALL Linear Trimellitate SECTION VI ~ REACTIVITY DATA Stability Unstable: Stable: X Jncompatibility Conditions to Avoid: (Materials to Avoid): N/A Hazardous Decomposition Products: Carbon monoxide, carbon dioxide, organic acids. Hazardous Polymerization May Occur: Conditions to Avoid: Will Not Occur: X SECTION VII - SPILL OR LEAK PROCEDURES Steps To Be Taken In Case Material Is Released or Spilled: If material is hot or comes in contact with hot objects, fumes may result. Avoid excessive breathing of fumes. Remove sources of ignition. Dousing spilled oil with water may be an initial necessary safety step. Waste Disposal Method: Recover or collect major portion of oily plasti cizer if possible with vacuum hose or other methods. Emulsify residual oil with water/detergent and further collect on solid absorbents. Follow with normal housekeeping methods. If spilled product not resuable, burn as fuel or waste. SECTION VIII- SPECIAL PROTECTION INFORMATION Respiratory Protection (Specify Type): Use only for protection from excessive fumes or emergencies-not to supplant ventilation. Ventilation Local Exhaust: Additional near mills, extruders, etc. to control fumes. Mechanical (General): Special: Other: Protective Gloves: Oil resistant Eye Protection: Splash goggles Other Protective Equipment: Eliminate ignition (ANSI Z87.1, 1968) sources SECTION IX - SPECIAL PRECAUTIONS Precautions To Be Taken In Handling And Storing: No special handling precautions are necessary; product has good stability in proper storage. Other Precautions: None Revision Date: 5/85 JTH _ 00 087030 C0NFTDFNTTA1 2 MATERIAL SAFETY DATA SHEET ,\ EFFECTIVE DATE: NOVEMBER, 1985 l. J DO NOT DUPLICATE THIS FORM. REQUEST ORIGINAL. ~J Union Carbide Corpori'lon urges the euilomer receiving thlt Material Safety Oata Sheet Is study II carefully is become irire el huortft. il >ny. ol the product Involved, to the Interest ot snlehr fou mould (t| nntity your employees, agents, end contractors ol the Information or. this sheet, (2) turnish a copy to each ol your customers lor the product, and (3) request your customers to inform their employees and customers as well. I. IDENTIFICATION PRODUCT NAME: TRIETHANOLAMINE, COMMERCIAL CHEMICAL NAME: Triethanolamine mixture CHEMICAL FAMILY: Alkanolamines FORMULA: Not applicable MOLECULAR WEIGHT: Not applicable SYNONYMS: Not applicable CAS # Not applicable CAS NAME Not applicable (mixture) BOILING POINT, 760 mm Hg II. PHYSICAL DATA Decomposes >250C (>482F) FREEZING POINT ~16C <~6lF) SPECIFIC GRAVITY (H20 = 1) 1.126 at 20/20C VAPOR PRESSURE at 20C. <0.01 mm Hg VAPOR DENSITY (air = 1) ~4.8 SOLUBILITY IN WATER, % by wt. at 20C 100 APPEARANCE AND ODOR Water-white liquid; characteristic odor. EVAPORATION RATE <0.01 (Butyl Acetate = 1) III. INGREDIENTS MATERIAL Triethanolamine % TLV 85 None established HAZARD See Section V Diethanolamine 15 3ppm, ACGIH See Section V FLASH POINT IV. FIRE AND EXPLOSION HAZARD DATA 382F, Fensky-Martens closed cup ASTM D 93 375F, Cleveland open cup ASTM D 92 FLAMMABLE LIMITS LOWER Not determined IN AIR, % by volume UPPER Not determined EXTINGUISHING MEDIA Apply alcohol-type or all-purpose-type foams by manufacturers recommended techniques for large fires. Use C02 or dry chemical media for small fires. SPECIAL FIRE FIGHTING Do not direct a solid stream of water or foam into hot, PROCEDURES burning pools; this may cause frothing and increase fire intensity. Use protective clothing, eye protection, and self-contained breathing apparatus. Use remote spray monitors or fight fire from behind shields. Oxides of nitrogen can be evolved during a fire. N US UAL FIRE AND EXPLOSION HAZARDS None DO 087031 CONFIDENTIAL EMERGENCY PHONE NUMBER * l-fcOO-UCOHELP This number Is available cktys, nights, weekends, and holidays. .J UNION CARBIDE CORPORATION INDUSTRIAL CHEMICALS DIVISION 39 OLD RIDGF GURY ROAD, DANBURY. CT 06317-0001 Triethanolamine, Commercial V, HEALTH HAZARD DATA [ADVERSE HEALTH EFFECTS WHICH MAY OCCUR FROM OVEREXPOSURE.] '.V AND SOURCE: See Section III EFFECTS OF AN ACUTE OVEREXPOSURE ` SWALLOWING May cause chemical burns of the mouth, throat, esophagus, and stomach. Signs and symptoms will include pain or discomfort in the mouth, chest, and abdomen, nausea, vomiting, diarrhea, dizziness, drowsiness, faintness, weakness, collapse, and coma. SKIN ABSORPTION No evidence of adverse effects from available information. INHALATION Vapors may be irritating and cause coughing and discomfort in the nose, throat, and chest. Prolonged exposure may cause local injury to the respiratory tract. SKIN CONTACT Brief contact may cause irritation, seen as local redness. Prolonged contact, as with clothing wetted with the material, may cause more severe irritation. EYE CONTACT May cause severe irritation, seen as marked excess redness and swelling of the conjunctiva. EFFECTS OF REPEATED OVEREXPOSURE Hay possibly cause kidney and liver damage. 1 HER EFFECTS OF OVEREXPOSURE Secondary and tertiary amines may react with nitrites to form nitrosamines. Some nitrosamines have been shown to be carcinogenic in laboratory animals. Inhalation may aggravate asthma and inflammatory or fibrotic pulmonary disease. Because of its irritating properties, this material may aggravate an existing dermatitis. EMERGENCY AND FIRST AID PROCEDURES: SWALLOWING Give at least two glasses of milk or water, unless the patient is unconscious. Do not induce vomiting. Call a physician. SKIN Remove contaminated clothing and wash skin with soap and water. Wash clothing before reuse. INHALATION Remove to fresh air. EYES Immediately flush eyes with plenty of water for at least 15 minutes. Seek medical attention promptly, preferably an ophthalmologist. (continued) DO 08703? CONFIDENTIAL Triethanolamine, Commercial V. HEALTH HAZARD DATA Continued NOTES TO PHYSICIAN The hazards of this material are mainly due to its severe irritant properties on the skin and mucosal surfaces. Carefully gastric lavage is required. There is no specific antidote, and treatment should be directed at the control of symptoms and the clinical condition. VI. REACTIVITY DATA STABILITY UNSTABLE -- STABLE X CONDITIONS None TO AVOID INCOMPATIBILITY (materials to avoid) Strong mineral acids and strong oxidizing agents such as nitric acid, liquid oxygen, ozone. HAZARDOUS COMBUSTION OR Burning can produce nitrogen oxides, carbon monoxide DECOMPOSITION PRODUCTS and/or carbon dioxide. HAZARDOUS POLYMERIZATION May Occur -- Will Not Occur X CONDITIONS None TO AVOID VII. SPILL OR LEAK PROCEDURES STEPS TO BE TAKEN F MATERIAL IS RELEASED OR SPILLED Wear suitable protective equipment; avoid contact with eyes and skin. Small spills should be flushed with large quantities of water. Large spills should be collected for disposal. See Section IX. WASTE DISPOSAL METHOD Incinerate in a furnace where permitted under appropriate Federal, State, and local regulations. Also, See Section IX. VIII. SPECIAL PROTECTION INFORMATION RESPIRATORY PROTECTION (specify type) None expected to be needed. VENTILATION This product should be confined within covered equipment, in which case, general (mechanical) room ventilation is expected to be adequate. PROTECTIVE GLOVES PVC - coated or butyl EYE Monogoggles PROTECTION OTHER PROTECTIVE Eye bath, safety shower, and chemical apron. EQUIPMENT (continued) DO 087033 CONFIDENTIAL Trie.thanolamine, Commercial ~" \X. SPECIAL PRECAUTIONS PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING Do not take internally Avoid breathing vapor Avoid contact with eyes, skin, and clothing Keep container closed Use with adequate ventilation Wash thoroughly after handling FOR INDUSTRY USE ONLY ' OTHER PRECAUTIONS Spills/Disposal - Laboratory tests show that, at very low concentration (about lOppm) this product can be degraded in a biological wastewater treatment system. It may be feasible to flush a small spill to a sanitary sewer with large amounts of water. However, a large spill might be detrimental. If spilled material cannot be collected, it may be possible to neutralize with dilute hydrochloric acid and, then, landfill the neutral salt. The opinions expressed herein are those of qualified experts within Union Carbide Corporation. We believe that the information contained herein is current as of the date of this Material Safety Data Sheet. Since the use of this information and of these opinions and the condi tions of use of the product are not within the control of Union Carbide Corporation, it is the user's obligation to determine the conditions of safe use of the product. F-48006B - ICD 11/85 - 4M PCC - 88205 Copyright 1985 Union Carbide Corporation Printed in U.S.A. 00 087034 CONFJO FNTTA(,, MATERIAL SAFETY DATA SHEET PAGE: 1 DOW CHEMICAL U.S.A. MIDLAND MICHIGAN 48640 EMERGENCY PHONE: 517-636-4400 EFFECTIVE DATE: 27 JUN 80 PRODUCT CODE: 87719 PRODUCT NAME: TRIETHANOLAMINE 85 f MSD: 0269 INGREDIENTS (TYPICAL VALUES-NOT SPECIFICATIONS) :% : TRIETHANOLAMINE DIETHANOLAMINE : 85 : 15 : : SECTION 1 PHYSICAL DATA BOILING POINT: 335-650F, 168-343C: SOL. IN WATER: COMPLETELY MISCIBLE VAP PRESS: 0.1 MMHG @ 20C : SP. GRAVITY: 1.1 25/25C VAP DENSITY (AIR=1): ------- : h VOLATILE BY VOL: 100 APPEARANCE AND ODOR: COLORLESS LIQUID - SLIGHTLY AMMONIACAL ODOR. SECTION 2 FIRE AND EXPLOSION HAZARD DATA FLASH POINT: 365F, 185C : FLAMMABLE LIMITS (STP IN AIR) METHOD USED: TAG OPEN CUP. : LFL: NOT DETER. UFL: NOT DETER. EXTINGUISHING MEDIA: WATER FOG, ALCOHOL FOAM, C02, DRY CHEMICAL. SPECIAL FIRE- FIGHTING EQUIPMENT AND HAZARDS:------- SECTION 3 REACTIVITY DATA STABILITY: ------- INCOMPATIBILITY: OXIDIZERS. HAZARDOUS DECOMPOSITION PRODUCTS: NOX AT DECOMPOSITION TEMPERATURE. HAZARDOUS POLYMERIZATION: WILL NOT OCCUR. SECTION 4 SPILL, LEAK, AND DISPOSAL PROCEDURES ACTION TO TAKE FOR SPILLS (USE APPROPRIATE SAFETY EQUIPMENT): USE ABSORBENT MATERIAL OR SAND. SCOOP UP AND PUT IN A CLEAN DRUM. DISPOSAL METHOD: BURN IN INCINERATOR OR BURY AWAY FROM WATER SUPPLIES. SECTION 5 HEALTH HAZARD DATA INGESTION: LOW SINGLE DOSE ORAL TOXICITY; LD50 (RAT) APPROX. 5000 MG/KG (TEA). EYE CONTACT: SEVERE PAIN, MODERATE TO SEVERE IRRITATION. NO CORNEAL INJURY LIKELY. SKIN CONTACT: SINGLE SHORT.EXPOSURE - MILD TO MODERATE IRRITATION. PROLONGED (CONTINUED ON PAGE 2 ) (R) INDICATES A REGISTERED OR TRADEMARK NAME OF THE DOW CHEMICAL COMPANY vi*rri0Hrori The C, P. HALL Company 2500 CHANNEL AVENUE MEMPHIS, TENNESSEE 38113 -- ________________901 -- 948-8663 PR.S, 11 DO 087035 CONFIDENTIAL. f I l MATERIAL SAFETY DATA SHEET PAGE: 3 DOW CHEMICAL U.S.A. MIDLAND MICHIGAN 48640 EMERGENCY PHONE: 517-636-4400 EFFECTIVE DATE: 27 JUN 80 PRODUCT (CONI'D): TRIETHANOLAMINE 85 PRODUCT CODE: 87719 MSD: 0269 SECTION 7 SPECIAL HANDLING INFORMATION (CONTINUED) VENTILATION: (CONTINUED) GUIDE. RESPIRATORY PROTECTION: NIOSH APPROVED RESPIRATORY PROTECTION REQUIRED IN ABSENCE OF PROPER ENVIRONMENTAL CONTROL. FOR EMERGENCIES, A SELF- CONTAINED BREATHING APPARATUS OR A FULL-FACE RESPIRATOR AS APPROVED BY NIOSH IS RECOMMENDED. PROTECTIVE CLOTHING: CLEAN, BODY-COVERING CLOTHING. EYE PROTECTION: CHEMICAL WORKERS GOGGLES. EYE FOUNTAIN AND WASHING FACILITIES NEAR WORK AREA. SECTION 8 SPECIAL PRECAUTIONS AND ADDITIONAL INFORMATION PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE: AVOID SKIN AND EYE CONTACT. AVOID BREATHING VAPORS IF GENERATED. ADDITIONAL INFORMATION: 27 JUN 80 REVISIONS 24 APR 79 -- SECTION 5. LAST PAGE (R) INDICATES A REGISTERED OR TRADEMARK NAME OF THE DOW CHEMICAL COMPANY THE INFORMATION HEREIN IS GIVEN IN GOOD FAITH, BUT NO WARRANTY, EXPRESS OR IMPLIED, IS MADE. DO 087036 CONFIDENT! Al. 13 253B MATERIAL SAFETY DATA SHEET (Approved by U.S. Dspsrtmsnt ol Labor "Essentially Simitar" to Form -1M/-- actuser* name Section I N L Industries, Inc., Pigments and Chemicals Division STREET ADDRESS Post Office Box 420 CITY STATE. AND ZIP CODE Hightstown, New Jersey 08520 EMERGENCY TELEPHONE NO 609-448-3200 EXT. 473 CHEMICAL NAME AND SYNONYMS Tribaslc Lead Sulfate CHEMICAL FAMILY Manager, Quality Control trade name TRIBASE FORMULA PIGMENTS Section II - HAZARDOUS INGREDIENTS PAINTS, PRESERVATIVES. & SOLVENTS % TIV (Uniti) SOLVENTS NPVLA 6-70 % tlv (Unita) CATALYST vr ' V ADDITIVES others HAZARDOUS MIXTURES OF OTHER LIQUIDS. SOLIDS. OR GASES PbO % TLV (Unite) 89 D.5mg/ SOILING POINT l*F ) VAPOR PRESSURE (mm Hg.) VAPOR DENSITY (AIR = I) SOLUBILITY IN WATER APPEARANCE AND ODOR Section III - PHYSICAL DATA N/A N/A N/A SPECIFIC GRAVITY {*,0 = 1) PERCENT VOLATILE BY VOLUME (%) EVAPORATION RATE < =l> Insol. Off-white powder 6.4 N/A N/A Section IV - FIRE AND EXPLOSION HAZARD DATA fla"',"*o"nt `(Lkthoo oft"1 XI I . WISHING media Chemical, N/A Foam, C02> Water, iLAMMABlt LIMITS (fog) N/A ci SPECIAL FIRE FIGHTING PROCEDURES No special fire hazards anticipated DO 087037 CONFIDENTIAL UNUSUAL FIRE AND EXPLOSION HAZARDS None known Reference Section IX S ction V - HEALTH HAZARD DATA THRESHOLO LIMIT VALUE Prolonged excessive absorption of inorganic lead by ingestion or inhalation EfEECTS or OVEREXPOSURE of dust and fume is characterized by abdominal pain (lead colic) metallic taste in moutH, loss of weight, pains in muscles and muscular weakness! The similarity of these symptoms with those or other illnesses require that excessive absorption of lead be verified by medical examination and analysis of biological specimens. CMERGENCV AND FIRST AID PROCEDURES Consult a physician if you have symptoms of illness. Abnormal Ingestion: Call a physician at once. As first aid, induce vomiting, give milk, and magnesium suJLtate. (Bosom salt) . " External: Normal work day accumulations cdh "be effectively cleansed with soap and wat?F.im'~*~Eyesi Use first aid procedure for dust. STASI LI TV UNSTABLE STABLE INCOMPATABILITY (Mat* twit is avoid) HAZARDOUS DECOMPOSITION PRODUCTS Section VI - REACTIVITY DATA CONDITIONS TO AVOIO X Pb, PbO HAZARDOUS POLYMERIZATION MAY OCCUR WILL NOT OCCUR CONDITIONS TQ AVOID X Section VII - SPILL OR LEAK PROCEDURES imnrsr taken in case MATERIAL IS RELEASED OR SPILLEO Sweep carefully, wear gloves, goggles, and respirator r WASTE DISPOSAL METhOO Landfill or smelter. Disposal must be done in accordance with local, state, and Federal regulations. Section VIII - SPECIAL PROTECTION INFORMATION WttPlRATORY PROTECTION (Spteth ITP*> Dust and/or fume respirator (Bureau ocf .M..ines A. pproved) VENTILATION local exhaust Ventilation provided as required by job condition to keep TLV listed in Section II below acceptable limits. _____________________ MECHANICAL (Central) OTHER PROTECTIVE gloves OTHER PROTECTIVE EQUIPMENT Yes EYE PROTECTION Change inwork c.lot,h, es. G_ ogg.les Section IX - SPECIAL PRECAUTIONS AUTIONS TO BE TAKEN IN handling AND STORING Avoid dusting. Personnel must wear prescribed OTHER PRECAUTIONS protective equipment. DO 087038 April 24, 1973 MATERIAL SAFETY DATA SHEET (Approved by U.S. Dspsrlmsnt of Labor "Eaaamlally Similar" to F rm 188*008-4) Mrfl' MANUFACTURER'S NAMi" Section I H L Industries, Inc., Pigments and Chemicals Division shun address Post Office Box 420 ilTY STATI, AMO HR COOI Hightstown, New Jersey 08520 twiAOINCY TELEPHONE NO 609-448-3200 EXT. 473 Chemical name ano synonyms Modified Tribasic Lead Sulfate CmImical family Lead Chemical Manager, Quality Control TRADE NAME TRIBASE AG formula Section II - HAZARDOUS INGREDIENTS PlOMINTf PAINTS, PRESERVATIVES, & SOLVENTS % Tlv (Unite) SOLVENTS NPVLA 6-70 % TLV runiMi CATALYST VfHluU Aoomves others HAZARDOUS MIXTURES OF OTHER LIQUIDS. SOLIDS, OR GASES % TLV (UnlW Pb 73 0.2mg/ Section III - PHYSICAL DATA SOILI NO POINT I'F.I VAPOR PRESSURE (mm H.) VAPOR DENSITY (AlR=1) N/A N/A N/A ' SPECIFIC GRAVITY (HtO = 1 PERCENT VOLATILE BY VOLUME <%) EVAPORATION RATE ( 3.6 N/A N/A SOLUBILITY IN WATER Insol. APPEARANCE AND ODOR Off-white powder OO 087039 ' uONFTDfcNTTAl ____________________________________ I___________________!---------------- Section IV - FIRE AND EXPLOSION HAZARD DATA FLA JINT TBSOTuUST IlAMMABlE LIMITS N/A N/A EXTlNOUISHINO MEDIA ., ,, Chemical, Foam, C02> Water, (fog) on fires involving Tribase AG SPECIAL FlAE FIQHTINO PROCEDURES No special fire hazards anticipated LN . u#l unusual fire and explosion hazaros product will Ignite if it comes directly in contact with a flame sour< Reference Section II Section V - HEALTH HAZARD DATA threshold umit value Prolonged excessive absorption of Inorganic lead by Ingestion or Inhalation IMECTS Of OVEREXPOSURE of dust end fume is characterized by abdominal pain (lead colic) metallic teste in mouth, loss of weight, pains in muscles and muscular weakness. Ihe similarity of these avmptoma with those or other illnesses require that excessive absorption of lead be verified by medical examination and analysis of biological specimens. EMERGENCY AND *IRST AID PROCEDURES Consult a physician if you have symptoms of illness. Abnormal Ingestion: Call a physician at once. As first aid, induce vomiting, give milk, and magnesium sulfate, (.Epsom bait;. EExxtternal: Normal work day accumulations can De effectively cleansed with soap and wafSPT Eyes: Use first aid procedure for dust. STABILITY UNSTABLE STABLE INCOMPATASILITV (Uaurial, io avoid) MAIAROOUS DECOMPOSITION PROOUCTS Section VI - REACTIVITY DATA CONDITIONS TO AVOID X Pk pkQ HA2AR0OU* POLYMERIZATION MAY OCCUR WILL NOT OCCUR CONDITIONS TO AVOID X Section VII - SPILL OR LEAK PROCEDURES 1TW TO If TAKEN IN CASE material IS RELEA5(0 OR SPILLED Sweep carefully, wear gloves, goggles, and respirator. WASTE DISPOSAL METHOO Landfill or smelter. Disposal must be done in accordance with local, state, and Federal regulations. ftlt^lRATOR'* PROJECTION VENTILATION Section VIII - SPECIAL PROTECTION INFORMATION iyp*} Dust and/or fume respira^tor (/rB> ureau oxf xMa .ines A* pprovedbn) local exhaust Ventilation provided as required by job condition to keep TLV listed in Section II below acceptable limits. MECHANICAL /Control) OTHER protective GLOVES OTHER PROTECTIVE EQUIPMENT Yes EVE PROTECTION Proper ventilation in work areas G_ ogg,les Section IX - SPECIAL PRECAUTIONS precautions to be taken in handling and storing Avoid dusting. Personnel must wear prescribed other precautions protective equipment. Product coating melts at 70C. 087040 oonftdfnttai. May 1, 1973 MATERIAL SAFETY DATA SHEET (Approved by U.$. Department of Labor "Essentially Similar" to Porip L8B-00S-4) "SBRii...uTURER'B NAME Ssction l N L Industries, Inc.; Pigments and Chemicals Division STRICT ADDRESS "6itv state. ano zip coot Post OffIce Box 420 Hightstown, New Jersey 08520 MEROENCY TELEPHONE NO 609-448-3200 EXT 473 CHEMICAL NAME AND SYNONYMS Modified Tribasic Lead Sulfate" Manager, Quality Control traoe name TRIBASE XL CHEMICAL FAMILY formula piomcntc Section II - HAZARDOUS INGREDIENTS PAINTS. PRESERVATIVES. & SOLVENTS % UV (Unit*) solvents NPVLA 6-70 % TVv CATALYST VIM ADDITIVES 1 OTHERS HAZARDOUS MIXTURES OF OTHER LIQUIDS, SOLIDS. OR OASES % TLY (Unit*) Pb 74 D. 2mg/T soilinO point i'f.) VAPOR PRESSURE (mm H.) VAPOR DENSITY (AIRsf) SOLUBILITY IN WATER APPEARANCE AND ODOR Section III - PHYSICAL DATA N/A N/A N/A SPECIFIC GRAVITY <HaO=1> PERCENT VOLATILE BY VOLUME (%) E1 VAPORATION RAT=E1) Insol. Off-white powder 4.6 N/A N/A Reference Section II Section V - HEALTH HAZARD DATA THREShOlO limit VALUE Prolonged excessive absorption of Inorgtnic lead by Ingestion or inhalation of IMICTS Of OVEREMROSURE duet and fume Is characterized by abdominal pain (lead colic) metallic taste liouiin, loss or weight, pains In muscles and muscular weakness. The similarity of these AVTOPtoms With those of other Illnesses require thee excessive Absorption nf lead he ^ verified by medical examination and analysis of biological specimens EMERGENCY AND * INST AID RROCEOURES Consult a physician if you have symptoms of Illness, Abnormal Ingestion: Call a physician at once. As first aid, induce vomiting, give milk, "and magnesium suitate, (.iipsoin Salt). External: normal work day accumulations can be effectively cleaned with soap and um-pr. flyey: Use first aid procedure for dust. Section VI - REACTIVITY DATA tasilitv UNSTAKI CONDITIONS TO AVOID $TASL( INCOMRATASILITv fUaututl, la avail) X HAZARDOUS DECOMPOSITION PRODUCTS ____________ ______________________ Pb, PbO HAZARDOUS * LVMERIZATION MAY OCCUR WILL NOT OCCUR CONDITIONS TO AVOID X Section VII * SPILL OR LEAK PROCEDURES ITRT TO SI TAKEN in CASE MatYrialIS RELEASED OR SUllED Sweep carefully, wear gloves, goggles, and respirator warn DISPOSAL METHOD Landfill or smelter. Disposal must be done in accordance with local, state, and Federal regulations. Section VIII - SPECIAL PROTECTION INFORMATION RHRlRATORY PROTECTION (Spaetlt lrpt) Dust and/or fume respirator (Bureau of Mines Approved} VENTILATION local exhaust Ventilation provided as required by lob condition to keep TLV _____________ listed in Section II below acceptable limits. MECHANICAL fCtaanl) OTHER PROTECTIVE CLOVIS OTHER PROTECTIVE EQUIPMENT Yes EYE PROTECTION ., Change In work clothes G_ ogg,les _ Section IX - SPECIAL PRECAUTIONS ^^^SNTT^TrAiStri^rMANOLMsnrN^TOAiNG ______________________Avoid dusting. Personnel must wear prescribed OTNIR PRECAUTIONS protective equipment._____________________ Q07O42 ------------------------------------------------------ CONFIDENTIAL May 1, 1973 MAH IcHBAL SArL l Y DAB A i>Mlb!c i FOR COATINGS. RESINS AND RELATED MATERIALS (Approvod by U S DonjHmpnt nf Lnbof ` ps^nfiaiiy G,fr>i .11 l<* f nrrfl O** HA-20) NPCA ZA*'**' manufacturer'snam^ Haven Che STREET ADDRESS * 5000 Langdon St- Section I city.state.anozipcode Philadelphia, Pa- 19124 EMEJ5GENCYTELEPHONENO 215-533-0900 ' PRODUCT CLASS tradename Es'ter MANUFACTURERS CODE IDENTIFICATION Triallyl Trimellitate TAT ^ Haven 210 ingredient Section II - HAZARDOUS INGREDIENTS PERCENT TIV PPM mfl/m' LEL VAPOR PRESSURE None boiling range 320F (0.1mm) Section III - PHYSICAL DATA 'APOR DENSIT i S3 heavier. lighter, than air .APfV.ATION RATE 'I FASTER I X I SLOWER. THAN ETHER U Nil '--------- ' PF RCE NT VOLAT It T BV VOLUME Nil wriGHT PFR `.All QN 9,5 Section IV - FIRE AND EXPLOSION HAZARD DATA DOT CATEGORY extinguishing media C02, dry chemical, FLASHPOINT water fog 280 F (Tag Closed Cup) LEL Fumesunusual fireand explosion hazards of allylic compounds may be produced- w spe fire riGHTiNG procedures Use se 1 f. - con t a i n ed breathing apparatus to avoid fumes of allylic compounds. DO 087043 CONFIDENTIAL . Section V-HEALTH HAZARD DATA >i-tfic,.MOioriMir value effects of ovehexposure Pulminary edema, corneal burns of eyes* * emergency and hast aid procedures For oral ingestion induce vomiting and hospitalize. For eye contact, ,flush with water, for shin contact, wash with soap & water* section VI - REACTIVITY DATA stability f 1 unstable | X ) staolc cum11.icin., i >avgii, incompatabiutt ,/wji<vMls^vo-o'Base & oxidizing material* haeaboousdecomposition rnoDi-cTs Allylic compounds* uv light exposure, temperature over 200F* ", HAZARDOUS POLYMERIZATION fX I MAY OCCLIII f" j WlI L NO 1 ll"r I l< CONDITIONS TO AVOID UV light exposure, temperatures over 200F* Section VII - SPILL OR LEAK PROCEDURES STEPS TO BE-TAaEN IN CAST M AT LIIc.V. IS HL LT.V.I llllh 111 I I D -Flush away spilled material with large -volumes of water* ~~ WASTE DISPOSAL method j Incinerate in an approved furnace* Section VIII - SPECIAL PROTECTION INFORMATION ] respiratory protection not required at ambient temperatures; at temperatures in'excess of 150F*, air pack should be worn* ventilation Local Exhaust: preferable Mechanical (General): acceptable* protective gloves neoprene rubber," PVC eye protection Safety glasses with side shields*" other protective equipment safety shower, eye bath and apron.*. Section IX - SPECIAL PRECAUTIONS _ Vrec'autionstobetakeninhanoling ANDsiniiiNC, Triallyl Trimellitate is stable to prolonged ~ storage at 80F* or lower* The shelf life is limited if peroxides are added* UV light or temperatures greater than 200F* can cause polymerization* Avoid Ion other precautions,-^ extensive exposure to immersion* Triallyl trimellitate is not a , primary irritant to the skin but certain individuals may show ab reaction to it* " Oo 087044 COMf fOFNTTAl ilcolqc THE SPECIALISTS IK SPECIALTY CHEMICALS \ 3440 FAIRFIELD ROAD / BALTIMORE, MD. 21226 / 301-355-2600 HAZARD RATING: Fir* s EXTREME 3 = HIGH 2 = MODERATE 1 = SLIGHT H**lth 0 = INSIGNIFICANT MATERIAL SAFETY DATA SHEET MATERIAL FORMULA SIPQMER TA1M C18H186 CODE 55-06-08 FREIGHT CLASSIFICATION Chemical NOS CHEMICAL NAME AND SYNONYMS .Triallyl Trimellitate 1^ Ruclivlty Sp*ei*l SUMMARY WEIGHT % TWA/TLV Triallyl Trimellitate Allyl Alcohol Water 98.7 0.01 0.15 Not established APPEARANCE -- ODOR -- PH. VISCOSITY Pale vellcw licruid, mild odor, dH 7 MELTING OR FREEZING POIN'T-POU] BOILING POINT -52.5F Point 160C @ 1mm Ha. SOLUBILITY IN WATER PERCENT VOLATILE (BY WT.) VAPOR PRESSURE (MM HG) Not available SPECIFIC GRAVITY (WATER = 1) 45 cps @ 20C VAPOR DENSITY (AIR = 1) >1 EVAPORATION RATE (BV AC = 1) Insoluble 100 1.165 20C 1111. FIRE AND EXPLOSION HAZARD DATA^:^tS^^C.S^-F 1 FLASH POINT 203F (TOC) AUTO IGlTtON TEMPERATURE 447F LOWER EXPLOSION LIMIT Not available UPPER EXPLOSION LIMIT Not available riNGUISHING MEDIA Q FOAM Q ''ALCOHOL" FOAM (3 CO, Q} DRY CHEMICAL Q WATER FOG Q OTHER SPECIAL FIRE FIGHTING PROCEDURES No special procedures UNUSUAL FIRE AND EXPLOSION HAZARDS No unusual hazards IV. HEALTH DATA " "T :V? ' RECOMMENDED HEALTH GUIDE TWA (MAXIMUM TIME WEIGHTED AVERAGE CONCENTRATION FOR AN 8-HOUR WORK PERIOD) Not available for this product. Other lower acrylic esters recommend TOR approximately 50 pcm. EFFECTS OF OVEREXPOSURE Irritation of eyes, nose throat; dermatitis may occur on repeated or prolonged contact. INHALATION Move the exposed person to fresh air at once. If breathing has stopped, perform Ui ft artificial respiration. Keep person warm and resting. Seek medical attention ID s as.soon as possible. 8 EYE AND SKIN CONTACT a < Iirmediately flush eyes with copious amounts of water, occasionally lifting eyelids. h tfi Get medical attention iirmediately. Promptly wash the contaminated skin with soap and water. Remove any contaminated clothing. Get medical attention for persistant > irritation. Clean clothing before reuse. o z UI ingestion (^ii a physician or poison control center. Drink 1 to 2 glasses of water. SC Ui Do not induce vomiting or give anything by mouth to an unconscious person. s Ui DO 087045 OONFrOFNTTAl r STABILITY 0 STABLE Q UNSTABLE CONDITIONS TO AVOID NA HAZARDOUS DECOMPOSITION PRODUCTS 1 Oxides of Carbon and Dartiallv burned carbon Droducts. hazardous polymerization CONDITIONS TO AVOiD pt) MAY OCCUR 0 WILL NOT OCCUR NA INCOMPATABILITY (MATERIALS TO AVOID) 0 WATER [>3 OTHER Caustic, mineral acids may liberate allyl alcohol STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Dike and absorb on sand or other industrial absorbent. Clean up area and ventilate corpletely. Thoroughly wash area to remove any residual product. WASTE DISPOSAL METHODS Incinerate in approved equipment according to local, state and federal regulations. yii. "special protection TYPE VENTILATION , Local exhaust at the point of formulation. RESPIRATORY PROTECTION Organic vapor cartridge with full face respirator. PROTECTIVE GLOVES EYE PROTECTION Rubber Goggles OTHER PROTECTIVE EQUIPMENT Clothing__t_o___p_r_e_ve_n--t rperpoeloantegdedorskin contact. v.' INDOOR yes COMMENTS HEATED no refrigerated 75 F OUTDOOR no Store in cool, dark, dry area. Avoid exposure to U.V. light. STORAGE TEMPERATURE MAX. 75F MIN. 40FE iSofoSacTY LD(.g Oral (rats): 1.8 gAg Acute dermal toxicity (rabbits): Primary Eye Irritation (Draize): >2.0 gAg 1.67 jvvgg BE ^SCELLANEOUS YNFOBMATlbN"^ DO 087046 confidential Refractive Index 1.5229 Distributor* The C. P. HALL Company 2500 CHANNEL AVENUE MEMPHIS, TENNESSEE 38113 901-948-8663 PR-54 NA = NOT APPLICABLE (C) = CEILING VALUE CODE CAS # 2694-54-4 THE INFORMATION CONTAINED HEREIN IS BASED ON DATA CONSIDERED AC CURATE. HOWEVER, NO WARRANTY IS EXPRESSED OR IMPLIED REGARDING If1? OP THESE DATA OR THE RESULTS TO BE OBTAINED FROM THE USE THEREOF. vendor assumes no responsibility for injury to vendee or third E?55.9!i PSOXIMATELY CAUSED BY THE MATERIAL IF REASONABLE SAFETY ?529?Sy.???^Af,E N0T adhered to as stipulated in the data sheet. ADDITIONALLY, VENDOR ASSUMES NO RESPONSIBILITY FOR INJURY TO third persons proximately caused by abnormal use of JflI/5IEI EVEN ,F reasonable safety procedures are followeo. further more, vendee assumes the risk in his use of the material. DATE OF ISSUE 1/86 SUPERSEDES 8/84 pre7%2/*t_ E. Zenler-Safety Director