Document 44dR9x6rJNqo4vNywZ4a4oMOV
SILVERMAN-HUSAIN--NITROGEN OXIDE-ARC WELDING
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oxides which are in the highest state, presumably in the form of nitric acid mist, and possibly carried on small submicron iron particles as nitrates. Nitrogen trioxide, NOs or -hexoxide, N206, can exist, but little is known about them.11
It is possible that nitric acid can be formed in an electric arc in the presence of water vapor; hence it is not improbable that this is formed from welding gases.
3 O
Oz
Chart 4.--Total oxides, nitric oxide, nitrogen dioxide, nitrogen trioxide and total fume con
centrations during and after arc welding with coated electrodes. Recirculation of cabinet' air
from 60 to 180 minutes.
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11. Since its absorption spectrum has been obtained, NOs is more nearly a substantiated com pound than a hypothetical intermediate (Johnston, H. S., and Yost, D. M.: The Kinetics of the Rapid Gas Reaction Between Ozone and Nitrogen Dioxide, J. Chem. Phys. 17^386, 1949).