Document 447ZzpxobpRDpggQgX9q6Yxya
CAS Number 25268-77-3
3M Company
A R 2 2 6 0s& & 1
N-VMoeltuhnytlarpyerUfsleuoarnodocEtxapnoessuurlefoInnafmoirdmoatetihoynl Parcorfyillaete
L
CHEMICAL IDENTIFICATION
Chemical Name: `CAS Number:
N-Methyl perfluorooctanesulfonamidoethyl acrylate (MeFOSEA) 25268-77-3
In. COMPANY IDENTIFICATION
Company Name: 3M
Site Location:
10746 Innovation Road Cottage Grove, MN 55016
1400 State Docks Road Decatur, AL 35601
`Technical Contact: Phone: `Address:
W.A. Weppner 651/733-6374 3M Center, Building 236-1B-10 St. Paul, MN 55144
IL ON-SITE ACTIVITIES
CAS #
Mfg. (1997)
Imported
25268-77-3*
< IMM Ibs.
0
Estimate the amountof subject chemical distributed off-site: <1%
*Submitted in 1998 TSCA TUR.
CAS Number 25268-77-3
3M Company
2
Narrative Description and.
low Schematic:
3M Company utilizes a process known as Simons Electro-Chemical Fluorination (ECF) to synthesize ohrygdarnoogfelnuofrliunoerimdeo,leacnuldesa.n elIencttrhiics cpurrorceensts,isorpgaasnsiecdfteherdosutgohcktshearseolduitsipoenr,sceaduisninlgiqtuhied,hayndhryodgreonusatoms obny tthhiesmporloecceuslsehatovebethreepslaamceedcwairtbhonflsukoerliente.al aTrhreanpgreemdeonmtinaasntthecofmepedosnteonctksuosfedt,hebuptrowdiutchtasllcorfeattheed hskyedlreotgoenncaantoamlssoroecplcaucreadnbdysfilgunoirfiincea.ntHaomwoeuvnetrs,offcralgemaevnetda,tibornanacnhdedreaanrdracnygcelimcensttorfutcthuerescamrabyonbe formed. The degreeoffluorination of the organic feedstock is also dependent upon the specific cthaerbloenngcthhaoifn tliemnegtthheofprtohecefsesedisstrounc.k aIntdisppaorsasmiebtleertsoofsytnhteheEsiCzFe pfrulolcyesfslusourcinhaatsedeloerctpreircfallucourroroerngtanaincd `flmuoolreicnueleastowmhse.reUaslilnogftthheesheypderrofglueonroaotrogmasnoifctmhoelehcyudlreoscaasrbboansifcebeudisltdoicnkghbalvoeckbse,eunnrieqpuleaccehdembiystries can be created by further reactions with functionalized hydrocarbon molecules.
3prMocehsass.prAodbuasciecdbsuuillfdoinnyglbblaoscekdofflusourcohcphreomdiuccatlss caonmdmtehrecihiaglhleystfoprroovduecrt4i0onyevaorlsuumseinfglutohreoEchCeFmical
3M manufactures is perfluorooctanesulfony! is 1-octanesulfonyl fluoride.
fluoride
(POSF).
The
starting
feedstock
for
this
reaction
(Reaction 1)
Reaction 1 CeHUSOF + 17HF 1-Octanesulfony fluoride
Energy
eeECeF
CiFiiSOF + 17H,
Perfluorooctanesulfonyl fluoride:
Tmihxetuerleecotfrobcihpermoidcuacltsflaunodriwnaastitoenofpuronckenssoywineldasndabvoaurtia3bl5e%c-o4m0p%ossittriaoignhtcocmhpariins(endoromfatlh)e PfOolSlFo,wianng:d a
1) higher and lower straight-chain homologs, i.., n-CnFan. SOF, e.g., CaF SOSF, CrF15SO5F, `CoF15SO2F which comprise about 7%ofthe process output
2)
branchied-chain, output
perfluoroalkylsulfonyl
fluorides
with
various
chain
lengths,
about
18-20%ofthe
3)
straight-chain, branched, and about 20-25%ofthe output
cyclic
(non-functional)
perfluoroalkanes
and
ethers,
which
comprise
4) "htyadrrso"g(ehni,ghwhmioclheccuolmaprriwesiegahbtouftluo1r0o-c1h5e%moicfatlhbeyopurtopduutc.ts) and other byproducts, including molecular
Bpreocdauucseeodfbysltihgehteldeicftferroecnhceemsicianlprfloucoersisnactoinodnitpirooncse,srsavwarmiaetsersioamlse,whaantd efqruoimpmloetn-tt,o-tlhoteamnidxtfurroem planttroa-tphlearnta.mTihxeopfriosdoumcetrtshaatndrehsuolmtoslforgoumese.lecTthreocchoemmmiecralcifalluiozreindatPiOonSFis dtehruisnveodtparopduurcetcshaermeiacamlixbtuutre ofapproximately 70% linear POSF derivatives and 30% branched POSF derived impurities.
CAS Number 25268-77-3
3M Company
3
pDeurrfilnugorpormoedtuhctainoen,,hbayvperobdeuecntvseanntdedwatosttehepraotdmuocstpshearree fionrtmheed.pasTt,hebuvtopllatainlseawraestbeeipnrgodiumcptlse,mseunctheads
tboeecnapltaunrdefialnldeddienstarhoayztahredsoeurselweaasstees lbayndtfhilelrmianlthoexipdaastt,iobnutovaerre tahllecnuerxrtenftelwy ybeeairnsg. iTnchienetraartsehdavate.an
filnu-ohroiunsaeteodrweixttehrhnyaldrhoagzeanrdaotuosmwsassttiel pirnecsienenrta,tcora.n bTeherebcyypcrloeddubctasc,kminatnoyothfewEhCiFchpraorceesisnocormaprleetely
ptarretaitamlelyntdseygsrtaedmesd.inThsteabtirleiaztamtieonntpsrloucdegsesaesssaocnidadtiesdcwhiatrhgetdhetoEcCoFntprorlolceeds,sihna-shobueseen, ewiatshteerwlaatnedfrilled
or land-incorporated 1998.
in
the
past,
but
all
ofthis
treatment
sludge
is
being
landfilled
off-site
since
early
sPyOntShEesiissoiftssueblafstcaonmcmeesrcuisaeldlyinvmiaabnlye portohdeurct3,Mbuftluisorporcihmeamriiclaylapnroidmupcotrst.anTthientmearjmoerdiitayteisinustehde to produce functionally derivatized fluorochemicals and high molecular weight polymeric products. UmonlieqcuuelechuesmiinsgtrcioensvcenatniboenaclrehaytderdobcyardbeornivraetaicztiinognsP.OPSOFStFhriosurgehacttheedswuliftohnymletfhlyuloroirdeetmhoyiletaymoifntehteo pMreoFduOcSeAeiathnedrENX-mFeOtShAylisoirsNo-laettehdyltopebrefluusoerdooasctiannteesrumlefdoinaatemsidteo (beMereFaOctSeAd toor fEoIrFmOSoAt)h.er mSaotemreioalfst.he `cTahrebomnaajtoerittoyoffotrhmeeiMtheerFON-SmAetahnydloErFNO-eStAhylispneortfliusoorloaotcedtaannedssuulbfsoenqaumeindtolyetrheaancotle.d Twhitehseeatrheyltehnee principal building blocks of the 3M product lines.
(CAS Number 25268-77-3
3M Company
4
`The following block flow diagram describes the process discussed above.
BLOCK FLOW DIAGRAM
(OctaneEsluelcftornoy-!Cfhleumoirciadle +FlHuoFri+naetlieocntrCicealllsenergy)
Perfluorooctane|sulfonyl (flPuOorSiFd)e
CommiReanctosrs]
Perfluorooctane sulfonic acid (PSOF)
Surfactants
commeVracriiaoluiszed Pionvtgeirimneidinateds Amphoteri)c (FsiurrefFacitgahnttisng
Foams)
N-peetrhfyllu(oarnodocmteatnhe-yl) sulfonamide |
Neeptehrfyllu(oarnodocmteatnhe-yl) sulfonamido ethanol
AdditioRneaalctSoercsondary
PhEsotseprshaatned (APcarpyelrat&e/Ppaoclkyamgeirnsg)
AcArdyilpaattee paodldyumcetsrs (UCraertpheatnaenpdoTleyxmteirlse
Protection)
commVearrciioaulsized ainndtesrumrefdaicattanetss
CAS IV.
Number SITE
R2E5L26E8A-7S7E-3AND
TRANSFER
3M Company INFORMATION
FOR
TRI
CHEMICALS
s
Not applicable.
V. SITE RELEASE AND TRANSFER INFORMATION FOR NON-TRI CHEMICALS a`nWhdilceomanpaoluyntidcsa,l smoetdhaotadsavhaaivlaebliempfrorovtehdsorveeporrttiimse,molsatrlgey voarfaiabqiulailtiytasttiivleenxaitsutrse.forAcletrhtoauinghmaltirmiicteesd emnogniinteoerriinnggdcaatlacuelxaitsitosn,sm.osEtngeimniesesriionngacnadlcwulaasttieoness,tihmoawteevsearr,ehbaavseedliumpitoantipornoscweisstmhordeseplescatntdo ifnltueorrmoecdhieamtiecasltesp.because fluorochemical losses were not always included in the analysis ofeach
aTrheedaifcfciucrulatcytoofmtehaseuermeisdsuieotnosqduaitcaksluybcmhiatntgeidnvgarpireoscdesusectoondsievteiroanls,favcetnortsi.ngBpartecsshuprreoscaenssd sdiyfsftiecmulsty cinomispooluatnidnsg pcraoucseesstehsemtottoabkeehmaevaesudirfefmeernetntsl.y fAdrdoimticoonnavlelnyt,iothnealuncioqmupeouchnadrsa,ctearnidstpihcysosifctahlecsheemical data properties are not available for all intermediate reaction steps in the past
A. ONSITE AIR RELEASES
FAuLgiLtiPveLeAmNisTsSio-ns may occur from vacuum charging from drums, sampling from reactors, hdarnudmlmeidnignoafmporlotdeuncto/rinstoelrimdesdaitaet;e,vafploarkisnagrmeopnroomdeurc,eddrfyrionmgmoopletreatniomnatse.riMaalt.eriIandlussmtraiyalbe chyogmipeonuenmdosnihtaovreinbgeehnasdebteeecntecdonasdufcutgietdivfeoresmiosmseiocnosmdpuoruinndgsi.ndSuostmreialmihnyogrieanmeoeuxnptososufrtehese testing.
Decatur,AL
Emission estimates are based upon existing process models and engineering calculations. qFuuagnittiifvieede.missions may have occurred during some handling steps but have not been
Fugitive - (non-point) Stack (point)
AEsntniumaalteRdelTeoatsaels [I
Not quantified.
AEcsctiumraatceydo%f Estimate (options)
r#edlaeaysseiyoecacrusrs
AEsntniumaalteRdelTeoatsaels ~~ AEcsctiumraatceydo%f (bs) (1997) Estimate options
<1
r#edlaeyasseiyoecacrusrs
CAS Number 25268-77-3
3M Company
6
CottageGrove
Fugitive emissions quantified.
may
have
occurred
during
some
handling
steps
but
have
not
been
Fugitive (non-point) Stack (point) Comments:
Estimated Total Estimated % Annual Releases ~~ Accuracy of (Ibs) (1997) Estimate (options)
No data available. No data available.
#daysiyears release occurs
CAS Number 25268-77-3
3M Company
7
B. WATER RELEASES FROM SITE
Decatur, AL
`This compound was not partofanalyte lst in wastewater studies.
Water releases:
Estimated Total ~~ Estimated%
Annual Releases (bs) (1997)
Accuracy of Estimate options)
No data available.
Number of days/year release occurs:
Receiving Water Name:
NPDES Number:
Comments:
Cottage Grove, MN
Engineering wastewater.
calculations
are
used
to
estimate
the
amountofmaterial
discharged
to
Estimated Total Annual Releases (Ibs) (1997)
Water releases:
0
Number of days/year release occurs:
Receiving Water Name:
NPDES Number:
Comments:
Estimated % Accuracy of Estimate options)
203
CAS Number 25268-77-3 C. ON-SITE LAND RELEASES
3M Company
8
Decatur, AL
t`TrhaenslpaonrdtetdretaotamnenotffosfitDeelcaantdSuirlls,laufdtgeer wpaasssidnigsctohnrtoiunguhedaitnhciacrkleyne1r99a8n.d
Sludge is now a sludge press.
An
uismepdoufonrdbmaecnkt-uwpasopuesraetdioinn. 1997 as partofthe wastewater treatment operation but is now only
Estimated Total Annual Releases
~~
Estimated % Accuracy of
(Ibs) (1997) Estimate (options)
Landfill Land Treatment/Land Amendment Surface Impoundments Underground Injection Other (specify):
0 Not quantified/No longer used Not quantified/No longer used.
0
Comments:
Cottage Grove, MN
Sludge from the Cottage Grove facility is sent to an off-site industrial landfill
:
Estimated Total Estimated % Annual Releases Accuracy of
(bs) (1997) Estimate (options)
Landfill
0
Land Treatment/Land Amendment
0
Surface Impoundments
0
OUtnhdeerrg(srpoeucnifdy)I:njection
0
Comments:
CAS Number 25268-77-3
3M Company
9
D. OFF-SITE TRANSFERS
Decatur,AL
Process wastewaters to the POTW.
are
managed
in
an
on-site
wastewater
treatment
facility
and
are
not
sent
DI. Transfer to Publicly Owned Treatment Works (POTW) Number of days/year the release occurs:
Annual Transfer (1b): 0
Estimated % Accuracyof Transfer Estimate (optional) (%):
POTW Name: Street Address: City: State: NPDES Number:
Country: Zip Code:
Comments:
205
CAS Number 25268-77:3
3M Company
10
Cottage Grove, MN
Process wastewaters to the POTW.
are
managed
inanon-site
wastewater
treatment
facility
and
are
not
sent
DI. Transfer to Publicly Owned Treatment Works (POTW)
Number of dayslyear the release occurs:
Annual Transfer (Ib): 0
Estimated % Accuracy of Transfer Estimate (optional) (%):
POTW Name: Street Address: City: State: NPDES Number:
Country: Zip Code:
Comments:
CAS Number 25268-77-3
3M Company
D2. TRANSFERS TO OTHER OFF-SITE LOCATIONS
2
sGpeenceifriaclrWepaosrttiengInafnodrmoafftsiiotne:tTrhanesrfeeriss clainmnitoetdbienfreoardmialtyiovnerbifyieCd.ARSatnhuemrbwearsftoerscaorme pcolausnsidfied bflyuhoarolcohgeemniccoanltecnatte,gorreigeusl.atWohryerwaeswtaesctoedseasr,epthryascikceadl bpryopCeArtSiensuamnbdern,ont-hsepeacmiofuincts have been included.
Decatur, AL
Awasrteevsieiwnodfipcaltaenstthraetc7or0d%s riesgdairsdpionsgedwatshtreoudgihspionscailnelroactaitoinonast fvoarriDoeucsatofufr-sfiltueolroicdaet-icoonnstaainnding
approximately 30% is landfilledat a hazardous waste predominant disposal method for these materials.
landfill.
Incineration
is
now the
Incineration:
Estimated Total Estimated %
Aunual Releases ~~ Accuracy of
(Ibs)
Estimate (options)
No specific CAS number data available.
Wastewater Treatment
0
(Excluding POTW)
Underground Injection
0
Hazardous Waste (RCRA Subtitle C) landfill
No specific CAS number data available.
Other Landfill
No specific CAS number data available.
Recycle or Recovery
Unknown or Other
Comments
CAS Number 25268-77-3
3M Company
2
Cottage Grove facility ilizes incineration for all their drummed wastes.
Cottage Grove, MN
Incineration: `Wastewater Treatment (Excluding POTW)
Estimated Total Annual Releases (ibs.)
130 0
Estimated % Accuracy of Estimate (options
Underground Injection
0
Hazardous Waste (RCRA Subtitle C) landfill
0
Other Landfill
0
Recycle or Recovery
0
Unknown or Other
0
Comments:
CAS Number 25268-77-3
3M Company
5
VI. ON-SITE WORKPLACE EXPOSURE
3M Company, Specialty Materials Manufacturing Division, Cordova, IL, `mTahginsiitnufdoer,maftrieoqnuewniclyl,asasnidstdEurPaAtioinnocfhpaortaecntetriiazlinegxptohseurneu.mbWehreonf wporrokveirdsinpgotmeonntiitaolrlyinegxpdaotsae,deansnudrtehe that data is linked with worker activities described in question 2. 1. eEascthiomfattehetheexpnousmubreerdoufrawtoiroknertsimpeost.enItifaalwloyrekxeprosies dinrvooultviendeliyntmootrhee stuhbajnecotnechaectmiivciatyl,feonrter
otontlayl hnius/mhbeerrmoinstthteyptiacballeaschtoiuviltdyeiqnutahletthaeblteo.talDonnu'mtbceoruonftwaowrokrekresrpmotoernetitahllayneoxnpcoes.edT.he
HoursDay
Days/Year
<10
10-100 100250
250
Le [TT
LeTo
LL TTT]
2. sDaemspclriinbge,trheemroovuatlionfefwioltrekrecraakcet,ivaintidesdrtouwmhmiicnhgtohfe lwioqruikdesr,smiannuqfueascttiuorne1aanraerteixcploe,seedtc:. For
these activities, or aerosol, etc.)
describe the physical state of the subject chemical and, if in a mixture, the chemical's concentration:
(liquid,
gas,
particulate,
c`Tohnececnhtermaitciaoln)(t2h5a2t6i8s-c7h7a-r3g)eids farnoimngfriebdeirednrtuimnsthientfooarmproocafesnsovne-sdsuesltiwnhge,rseoliitd,iswcaoxnysufmleakdei(n8a0% reaction leaving less than 1% residual in the final product.
CAS Number 25268-77-3
3M Company
1
3. Psraomvpildienginmdeutsthroidalahnydgieexnpeosmuorneitsocreinanrgidoamtao,niitfoarveadil,abe.lge.,,wdietshcraibberitehfedsepseccriifpictiwoonrokfetrhe ancottiviintcilesudpeearnfyorpmeerdsobnyalthiedeinntdiifviierdsuasluschmoansitaowroerdk.erF'osrnparmiveaocyr scoocnisaildesreactuirointsy,upmlebaeserdwoith any data submitted to EPA. `mTohneirteoirsinnog dcahteamifcoarlt-hsipsecspiefciicfipcermsaotnearliailndautstthriisalfahciylgiitye.neFmoornimtoosrtinargedaasotafotrhearfeaac/isliotuyr,creecent qhuyagliietnaetipveroagsrsaesmsimnednitcoatfepsotaelntoiwaelxepxopsousruerepottoentthiiaslmtaotetrhiiaslmautnedreiral3.M's ongoing industrial
Esuapcphor3tMedpblaynatctohraptoprraotdeucinedsussturlifaolnhatyegdiefnleuogrroocuph.emi3cMal'sshiansduasntriinadluhstyrgiiaelnheypgireongirsatmonfsoctuasfefsanodn is atnads/k-obraqsueadnteixtpaotisvuerley.asQsueaslsimteatnitvaenadssceosntsrmoeln.tsExarpeospuerrefsoramreedidbeyntainfiiendduasntdriaaslsheysgsieedniqsuta.litatively Qfulaunotriotcahteimviecaalssseasnsdm/eonrtssoiunrccleuodre atraesak-sbaamspeldipnegr.soTnhael sreasmuplltsionfg ftohre caesrsteaisns,mesnpetcsifsiucpport decisions oben eusxepdosounreancoinnttroelr.im Ebnagsiisneoerrwinhgencoenftfreocltsiavreeepnrgeifneererreidn,gbcuotnptreorlsoinsanloptrfoetaescitbilvee. equipment may 4. Briefly describe the engineering controls used to minimize exposure to this chemical: No additional engineering controls are used.
S.
Briefly list the personal protective exposure of this chemical:
equipment
your
workers
regularly
wear
to
prevent
During charging employees wear safety glasses and hard hats, and gloves.
Comments: desired.)
(This section is available to clarify the responses given.
Attach additional pages if
CAS Number 25268-77-3
3M Company
15
3M Company, Specialty Materials Manufacturing Division, Cottage Grove, MN
``Tmhaigsniitnufdoer,maftrieoqnuewniclyl,asasnidstdEurPaAtioinnocfhpaortaectnetriiazlinegxptohseunreu.mbWerhoefn wporrokveirdsinpgotmeonntiitaollryinegxdpaotsae,deansnudrtehe that data is linked with worker activities described in question 2
1. eEascthiomafttehteheexnpuomsubreerdoufrawtoiroknertsimpeost.eInftiaalwloyrekxeprosiesdinrvooultviendeliyntmootrhee stuhbajnecotnechaecmtiivciatly,feonrter otontlayl hniusm/hbeerrmoinstthteyptiacballe aschtoiuviltdyeiqnutahletthaeblteo.taDlonnu'mtbceorunotfwaowrokrekresrpmotoernetitahllayneoxnpcoes.edT.he
Days/Year
Hours/Day
<10
10-100 100-250
250
es[TT
[ae | TT
L=1 [TT]
2. Dseasmcprliibneg,trheemroovuatilnoefwfoirltkerercaakcet,ivaitnidesdtrouwmhmiicnhgthoef wlioqrukidesr,smiannquufeascttiuorne1aanrearetxicploes,eedt:c. For othreaseeroacstoilv,iteitecs.,) daensdc,riifbeintahempihxytsuircea,ltshteatceheomfitchael'ssubcjoencctencthreamtiicoanl: (liquid, gas, particulate,
`maVianctueunmancchaer(gcihnagnfgrionmg
drums, flange,
sampling from reactor, hose, pipe, valve, filter,
drumming ofproduct/intermediate, pump or sight glass); materials may
be
`hmaonldtleendmaitnearimaoll;taepnporroxsiomliadtestcaotencoerndtirsatsioolnverdainngeosrgfarnoimc <so1l%venttos8;0v%a.pors are produced from
CAS Number 25268-77-3
3M Company
16
3. Psraomvpildienginmdeutsthroidalahnydgieexnpeosmuorneitsocreinanrgidoamtao,niiftoarveaidl,ab.lge.,,wdietshcraibbreitehfedsepseccriifpitciwoonorfktehre nacottiviintcilesudpeearnfyorpmeerdsobnyalthiedeinntdiifvieirdsuasluschmoansitaowroerdk.erF'osrnparmiveaocry csoocnisaildesreactuirointsy,npulmeabseerdwoith any data submitted to EPA.
mTohneirteoirsinnog dcahteamifcoarlt-hsipsecspiefciicfipcermsaotnearliailndautsttrhiisalfahcyigliitey.neFmoornimtoosrtinargedaasotfatohrearfeaac/isliotuyr,creecent hquyagliietnaetipveroagsrsaemssimnednitcoatfepsotaelntoiwaelxepxopsousruerepottoentthiiaslmtaotetrhiisalmautnedreiral3M's ongoing industrial sEuapcphor3tMedpblayanctotrhaptorpraotdeucinedsussturlifaolnhaytegdiefnleuogrrooucph.emi3cMa'lsshiansduastnriianlduhstyrgiiaelnheygpireongirstamonfsotcaufsfesanodn is atansdk/-obraqsueadnteixtaptoisvuelrye.asQsueaslsimteatnitvaenadssceonstsrmoel.ntsEaxrpeospuerrefsoramreedidbeyntainfiienddausntdriaaslsheysgsieedniqsuta.litatively fQulaunotriotcahteimviecaalssseasnsdm/eonrtssoiunrccleudoer taracsak-sbaamspeldinpge.rsoTnhael sreasmuplltsionfgtfhoer caesrsteasins,mesnptecsifsiucpport decisions boen uesxepdosounreancoinnttreorli.mEbnagsiisneoerrwinhgencoenftfreocltsivaereenprgeifneererreidn,gbcuotntpreorlsoinsanloptrfoetaescitbilvee. equipment may 4. Briefly describe the engineering controls used to minimize exposure to this chemical: Mcoantteariinaelrss.areVatrcaunsufmercrheadrugsiinngg ocflomsaetedrpiiaplisnfgr(owmhderreumpsosissiablset)afndraormdrperaaccttoicre.vesPsoeslisttioonoatbhleer local dexrhuamumsitngv.entiGleanteiroanlhrooodosmaraiersiptruoavtideedsatfosrigdniilfuitciaonnot fpoaiinrtbsoorunrecmeastseruicahlsa.s at drum bungs when
5. Berxipeofsluyrleisotfththeispecrhseomniaclalp:rotective equipment your workers regularly wear to prevent
pParrotciecsuslaotpeeprraetfiilntgers,taorndpaarrdtsicluilstattehefirletserpiinrga)t,orgl(oe.vge.,bsyupepllaisetdomaeirr, (ocr.gg.a,nniceovparpeonre coarrtnriitrdiglee)w, ith gcohgegmliecsalwiptrohteorctwiivtehcoluotthfuilnlgf(ac.cge.,shi2e-lpdicdceepePnVdCinrgaionnsutiyt)p,eoefyerepsrpoitreacttoironus(ee.dg).,tochbeemiucsaeld bspylatshhe employee when the task involves exposure to a particular fluorochemical material.
Comments: desired.)
(This section is available to clarify the responses given.
Attach additional pages if
CAS Number 25268-77-3
3M Company
"
3M Company. Specialty Materials Manufacturing Division, Decatur, AL
`Tmhaigsniitnufdoer,maftrieoqnuewniclyl,aassnidstdEurPaAtioinnocfhpaortaecntetriiazlinegxptohseurneu.mbWehreonf wporrokveirdsinpgotmeonntiitaolrlyinegxpdaotsae,deansnudrtehe that data is linked with worker activities described in question 2.
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Days/Year
Hours/Day
<10
10-100
100250
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[os[TTT
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= [TTT
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may be handled in a concentration ranges
molten orsolid up to 85%.
state;
vapors
are
produced
from
molten
material;
material
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CAS Number 25268-77-3
3M Company
1s
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are not included validated.
with
this
submission.
Priorto
1999,
these
samples
were
considered
to
be
semi-
wSuirtfhamceetshiynlparlocdouhcotliownasanwdipademdiniinsstirdaetaio1n0acremasxw1e0reemsasmqpulaerde winit1h99a8n.alyAsigslbasysLfCib-eMrSf.ilteRrewseutlttesd `iTnhdiiscraetseudlttheed pirneismepnrcoeovefmtehnetsse tmoatHearziaarlsdoCnomflmouonriscaantdieoqnupirpamcetinctess,urpfearcseosnailn hpryogdiuecnteieomnpahraesaiss., personal protective equipment emphasis, and several engineering and administrative changes.
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on be
exposure control. used on an interim
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equipment
may
CAS Number 25268-77-3
3M Company
19
Air Sampling Data for 25268-77-3
ClassiJofbication nSuammpbleer ~~Con(cmegnitrma3t)ion
eres Tolals >
Chemical Operator
9920-080080 00.0162
Buiding3 92-061 027
94.031 <0.01
94-032" <001
94-034" <001
94.037" <0.01
94.038" <0.01
94-030" <0.008
94-041" <001
94.046" <001
94.050 <001
94.075 <0.006
94.078 <0.008
95-006" 0012
95.007" 0.007
95.014* 027
95.040" 0.46
95.041" 0.019
COhpeemriatcoarl os024 028
Flaker 97-091" 01s
TeamLeader 62-060 0.06
Building3 92-061
027
94.036" <0003
94.047" <002
94.051" <0.005
94.054" <0.005
94-056" 0.005
96.069 016
Team Leader 9988-.408918""
0.05 0.049
Flaker
Mi(mngiimmu3)m _<0003
M(amxgi/mm3u)m 046 -
GeoMmeeatnric 0025
GSetoamnedtarridc Devi4a6tion
*Thevalueforthis sample is oneofseveral fluorochemical analytes collected on the sample. Samples are all personal breathing zone samples taken over the duration of a specific task.
CAS Number 25268-77-3
3M Company
2
4. Briefly describe the engineering controls used to minimize exposure to this chemical:
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5.
Briefly list the personal of this chemical:
protective
equipment
your
workers
regularly
wear
to
prevent
exposure
Specific personal protective equipment is indicated on written operating procedures used by process operators.
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Hand protection: (Scorpio) or nitrile
All tasks industrial
identified gloves.
as
having
potential
for
hand
contact
require
neoprene
Body protection: Exposure worn for some low exposure
significant tasks use one or two-piece potential tasks such as sampling.
PVC
suits.
Aprons
may
be
Fchoeomtipcraolterecstiisotna:nt Tbaoostkss.identified as posing a significant foot exposure potential require.
Comments: desired.)
(This
section
is
available
to
clarify
the
responses
given.
Attach
additional
pages
if
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The fluorochemical hazard communication program was improved upon in 1998. This has resulted in improved exposure avoidance behaviors among production employees and better use ofwith personal protective equipment requirements.
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frNeoqnu-epnrtoldyu.ction equipment surfaces such as f2loo]rs, d1oorknobs and stair rails are cleaned
CAS Number 25268-77-3
3M Company
2
VIL. CHEMICAL END USES
A. END USE AS AN INTERMEDIATE CONSUMED TO MAKE OTHER CHEMICALS
AL OnSite Use as a Intermediate:
Intermediate consumed in the productionofseveral polymeric products which are used as protective treatments for circuit boards, nonwovens, apparel and leather.
Product chemical class or product chemical (Include CAS number if appropriate)
%oftotal volume of subject chemical manufactured
or imported
1 Fluoroaliphatic Acrylates
90-95%
2. Fluorochemical Acrylates CAS 92265-81-1
38%
A2. Off-Site Use as an Intermediate
Product chemical class or product chemical (Include CAS numberif appropriate) 1. Notapplicable.
As reported in Part III, p.2 % of total
`volumeof subject chemical manufactured
or imported As reported in Part III, p.2
CAS
Number
B.
2E5N26D8-U7S7E-3S OTHER THAN
AS
A3MCOCNomSpUaMnyED
INTERMEDIATE
z
Use Number 1 of 8 `DmeasncurfiapcttiuorneopfolCyhmeemrisctahlatEanrde sUosled:toTihnidsusCtrAiSalnuusemrbsetroibseusmieldlaasppalniiendtaesrmperdoitaetcetitvoe, repellent treatments for apparel substrates. These substrates will be made into apparel products to be used by consumers and commercial industry. This CAS number itselfwill be present in these products at low levels as a residual
Percentof total manufactured or imported Volume going to this use: 1-2
Check all physical formsofthe chemical during this use:
If used in a mixture check appropriate box to indicate weight fraction. Average values are acceptable: _ <a%
X_ 1-30% (0.12%)
TT 3060% 60-90%
-- >o0%
__ Aerosol "Dry Powder
Pellets or large crystals Water or solvent ~wet solid __ Gasorvapor
_X_ Liquid solution
Other (Explain)
Use Number 2 of 8 Description of Chemical End Use: This CAS number is used as an intermediate to `manufacture polymers that are sold to industrial users to be mill applied as protective, irnedpuesltlreyn.t tTrheiastmCenAtSs fnourmcbaerpriettsiengl.fwiTlhlebcearppreetsienngtwiinllthbeeseupsreoddbucytcsoantsluomwerlsevaenlds acsomarmeesricdiuaall.
Percent oftotal manufactured or imported volume going to this use: <I *
Check all physical formsofthe chemical during this use:
Ifused in a mixture check appropriate box to indicate weight fraction. Average values are acceptable: _X_ <1%(<5000 ppm) TT 130% TT 3060%
60-90% >90%
Aerosol _ DryPowder
Pellets or large crystals Water or solvent ~ wet solid --_ Gasorvapor X_ Liquid solution Other (Explain)
CAS Number 25268-77-3
3M Company
23
Use Number 3 of 8 Dmeasncurfiapcttuiroen pofolCyhmeemrisctahlatEanredsUosled:toTihnidsusCtrAiSalnuusemrbsetroibseusmeildlaasppalniiendtaesrmperdoitaetcetitvoe, r`ewpoerlklweenatrtroeramtemdenitcsalfogranrmoennwtosvteonbseubusstreadtebsy. cTohmmeesrecsiuablstirnadtuesstrwyi.llTbheismaCdAeSinntuomibnedurstirtisaellf will be present in these products at low levels as 2 residual.
Percentoftotal manufactured or imported volume going to this use: <1 *
cChheemcikcaallldpuhryisnigcatlhifsoursmes: of the
If used in a mixture check appropriate box to indicate weight fraction. Average values are acceptable: X <1% TT o130% -- 3060%
60-90% 90%
__ Aerosol Dry Powder Pellets or large crystals Water or solvent ~ wet solid
--_ Gasorvapor X_ Liquid solution
Other (Explain)
Use Number 4 of 8 Description of Chemical End Use: This CAS number is used as an intermediate to manufacture polymers thatare sold to industrial users to be mill applied as protective, repellent treatments for upholstery. The upholstery will be used by consumers and commercial industry. This CAS numberitselfwill be present in these products at low levels asa residual.
Percentoftotal manufactured or imported volume going to this use: <I +
Check all physical forms of the chemical during this use:
If used in a mixture check appropriate box to indicate Weight fraction. Average values are acceptable: xX <1%
130% 060% 600% A 90%
__ Aerosol Dry Powder Pellets or large crystals Water or solvent ~ wet solid
--_ Gasorvapor X_ Liquid solution
Other (Explain)
CAS Number 25268-77-3
3M Company
2
Use Number 5 of 8 Description of Chemical End Use: This CAS number is used as an intermediate to `manufacture materials that are regulated by the Food and Drug Administration as indirect food additives used to impart grease and oil resistance to paper and paperboard. Paperor paperboard are used in food packaging products such as bags, wrappers, cartons, or trays. This CAS number itself will be present in these products at lowlevelsas a residual.
Percentoftotal manufactured or imported volume going to this use: <1 +
Check all physical formsof the chemical during this use:
Ifused in a mixture check appropriate box to indicate weight fraction. Average values are acceptable: X_ <113%0%(<4000 ppm)
3060% 60-90% so
__ Aerosol Dry Powder Pellets or large crystals Water or solvent - wet solid
X___ LGiaqsuoird vsoalpuotrion Other (Explain)
Use Number 6 of Description of Chemical End Use: This CAS number is used as an intermediate to `manufacture materials that are sold to industrial users to be mill applied as protective treatments for carbonless paper (business forms). This CAS number itselfwill be present in these products at low levels as a residual.
Percent of total manufactured or imported volume going to this use: <I %
Check all physical formsofthe chemical during this use:
Ifused in a mixture check appropriate box to indicate Weight fraction. Average values are acceptable:
aw XX 130% (012%) ZT 3060%
60.90% so so%
Aerosol Dry Powder Pellets or large crystals Water or solvent ~ wet solid __ Gasorvapor X_ Liquid solution Other (Explain)
CAS Number 25268-77-3
3M Company
2s
Use Number 7 of 8 Description of Chemical End Use: This CAS number is used as an intermediate to manufacture materials that are sold to industrial users to be applied as protective treatments for porous surfaces. This CAS numberitselfwill be present in these products at low levels as a residual.
Percentoftotal manufactured or imported volume going to this use: <I +
Check all physical formsofthe chemical during this use:
Ifused in a mixture check appropriate box tvoaliunedsicaarteeawceciegphtatbflrea:ction. Average
an 013600%%012%) 60.90% >o%
__ Aerosol __ DryPowder
Pellets or large crystals Water or solven-t wet solid --_ Gasorvapor X_ Liquid solution Other (Explain)
Use Number 8 of 8 Description of Chemical End Use: This CAS number isusedas an intermediate to manufacture polymers that are incorporated into products for consumer use as protective, repellent treatments for upholstery. This CAS number itself will be present in these products atlow levels as a residual.
Percentoftotal manufactured or imported volume going to this use: <I +
Check all physical formsofthe chemical during this use:
If used in a mixture check appropriate box to indicate Weight fraction. Average values are acceptable: xX <1% TT 130%
3060% 60-90% so% so
__ Aerosol Dry Powder Pellets or large crystals
_ Wateror solvent -- wet solid. --_ Gasorvapor X_ Liquid solution
Other (Explain)