Document 3jmdZM9LXmO97OaBE7EVq5a6
Vista Chemical Company
900 Threadneedle Houston, Texas 77079 (713) 588-3000
P.O. Box 19029 Houston, Texas 77224
Fax (713) 588-3236
June 20, 1990
TGG: JCL ERT mim- AJO, XF:_________
Mr. Mike McCluskey Chemron P. 0. Box 2799 Paso Robles, CA 93446
Dear Mike:
As we discussed, I've enclosed information regarding the SARA 313
definition of glycol ethers.
The attached letter was an EPA
response to questions asked by the counsel for the soap and
detergent association. Please call me at 713-588-3445 if you have
further questions.
Sincerely,
Thomas G. Grumbles, C.I.H. Manager, Environmental Affairs
dlj
Attachment
VVV 000013205
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY
WASHINGTON. D.C. 20460
Mr. Alan S. Ward Baker and Hostetler Washington square
Suite lioo
1050 Connecticut Avenue Washington, DC 20036
JUN 1 6 1389
price or PEBTlCIDE* AND Toxic SUBSTANCES
Dear Mr, Wards
This letter is in response to your recent inquiry regarding a clarification of the glycol ether category under section 313 of
the Emergency Planning and Community Right-to-Know Act of 1986 with respect to alkyl ethoxylates, alkyl phenol ethoxylates and alkyl ethoxy sulfates.
There appear two he two separate issues stated in your
letter. The first is to clarify the glycol ether category under
section 313 to determine whether certain chemicals are subject to
annual release reporting. The second requests that a _
modification to the category be made.
\
The general structure for glycol ethers, as defined under section 313 is as follows:
R-(OCH2CH2)n-OR'
Where n = 1,2, or 3 R = an alkyl or aryl group R* R, H or groups which, when removed,
ethers with the following structure:
yield
glycol
R-(OCH2CH2)n-OH ^polymers^are excluded from this category.
The substances which you are referring to have the following general structural components with regard to the above structure:
R * C8.j. alkyl or alkyl phenyl; R' H, or S03H? n usually averages greater than 3.
VVV 000013206
Both t.hft. H and R' groupg ^vr-:h*e components satisfy the definition of glycol ethers as dancribed under section ah. - However, the degree of ethoxylation (or the value of n) is greater than three* It is widely recognized that these materials have a range associated with the degree of ethoxylation such that for an average value of n, the there may be substantial quantities of chemicals where the value of n is both higher and lower than the average. For section 313 reporting purposes, these substances are considered mixtures. In any mixture, a facility should, to the best of their ability, determine if any section 313 chemicals are contained in that mixture and consider only the fraction or reportable chemicals in determining reporting thresholds and calculating releases. In other words, facilities which manufacture, process, or otherwise use the ethoxylate mixture described above should consider the fraction of the chemicals where ,Tn" is equal to three or less for reporting and release threshold determinations. This fraction of the mixture meets the definition of a glycol ether as described.
As we have discussed, modifications to list of reportable chemicals under section 313 can only take place through Agency rulemaking procedures. This requires proposing a rule in the Federal Register, receiving public comment, and then publishing a final rule. To date, the list of chemicals under section 313 has been modified by petitions to add or delete chemicals to the list and through an Agency initiated proposal to add chemicals to the list.
We would be happy to meet with you to discuss the options
for requesting a modification to the glycol ether category under section 313. As you know, Bob Israel of my staff is the section 313 Petitions Coordinator. You should contact him to pursue this matter further.
sincerely,
cc: Charles Elkins Bob Israel
S'VwWB. M 9 99 l* M V* .
Deputy Director Economics and Technology Division
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