Document 3ejb3pjb66R6bJ1qZvjXaaMrE

HARRIS mac tsodom; wqong prcoucts UNIBRAZE SUBSIDIARY Of iW, HARRIS CO. INC. MATERIAL SAFETY DATA SHEET SOLDERS SECTION 1 - MATERIAL IDENTIFICATION Manufacturers Name ! W. HaffiS CO., lllC.___________ A(Jdress 10930 Deerfield Road Ad(Jress Cincinnati, Ohio 45242 Distributor Name (If Applicable) Emergency Tiphnn (513j 891-2000 msds Date November 1985 The following table lists the trade name and composition of products covered by this Material Safety Data Sheet. See section 2 and especially section 6 for important health hazard data. Trade Name Stay Brite Stay Brite #8 Alsolder 500 95/5 50/50 60/40 40/60 63/37 30/70 Wire Composition wt% Sn Pb Sb *9 Cd Zn 96 4 95 5 83 17 95 5 50 50 60 40 40 60 63 37 30 70 Acid Core Rosin Core Core Composition for Flux Cored Solders Element WL (% of core WL) Zinc Chloride 70 Activated Rosin 100 WL (% of total solder WL) 1-3 1-3 SECTION 2 - HAZARDOUS MATERIALS Settle' wire 'S a nonhazardous solid at ambient temperature. Hazards (as defined by CSIIA 2S2T. 12'C.I^C' r,r. roci-H krr\ryy nonor^faH Hi iripin C rMor*nf* Qo***>r*s 1 | * -- j - *........................... = / II,>1 Juu ^t.wliuli o 101 liliui HiailUM Oil pUlclllldi lulllfc HataivJ ICSUitllly IfOtll use 01 tfie prOdUCt. DO A 061510 C0NFTDENTTA1 SECTION 3 - PHYSICAL DATA Wire, grey to silver in color. Solder may be solid or contain an inner core of flux. SECTION 4 - FIRE AND EXPLOSION DATA Nonflammable. Open flame and sparks can ignite combustibles, See ANSI/ASC Z49.1-1983 Section 6. SECTION 5 - HEALTH HAZARD DATA Exposure - Section 1 lists nominal composition of solders. Section 6 lists exposure limits for hazardous de composition products which might be present in fume generated during soldering. Actual exposure should be determined by monitoring the fume in the operator's breathing zone. Primary Route of Exposure - Inhalation of fume. Possible lead dust ingestion from smoking or eating after handling lead bearing solders. Pre-Existing Medical Conditions - Individuals with impaired pulmonary functions or illness may have symptoms exacerbated by fume irritants. Possible Effects of Exposure - Ingestion of lead dust or inhalation of lead oxide fume is one of the main hazards. Over exposure can produce symptoms such as headache, nausea, dizziness, body aches, and anemia. Symptoms are similar to other illnesses and require medical verification. Lead accumulates in the body and small amounts can build up over a period of time to toxic levels. Short term exposure to cadmium fume causes irritation of the nose and throat. Chest pain, cough, fever or shortness of breath may develop after several hours. Severe over exposure can cause pulmonary edema. Prolonged inhalation exposure may cause lung or kidney damage. Cadmium compounds should be considered suspected carcinogens based on some animal tests and recent epidemiological studies. Tin and antimony fume may cause metal fume fever, characterized by fever, body ache, chills. Fumes from acid and rosin core can irritate nose, throat. Zinc chloride in acid core solder may irritate the skin Emergency First Aid - Remove from dust or fume exposure. If breathing has stopped perform ar^nai resp' a io v Summon medical aid immediately. flux fume should be considered in evaluation of hazards. A 063531 confidfntiai SECTION 6 - REACTIVITY DATA Solid Wire Soldering fumes cannot be classified simply. The composition and quantity are dependent upon the metal being soldered, the process, procedures, and filler metals used. Other conditions which also influence the composition and quantity of the fumes and gases to which workers may be exposed include: coatings on the metal being soldered (such as paint, plating, or galvanizing), the number of operators and the volume of the work area, the quality and amount of ventilation, the position of the operator's head with respect to the fume plume, as well as the presence of contaminants in the atmosphere (such as chlorinated hydrocarbon vapors from cleaning and degreasing activities). A stable material in closed containers at room temperature under normal storage and handling conditions. This material can be considered a weak acid. It can be mildly corrosive to some metals, especially when hot. Zinc chloride flux in acid core solders is incompatible with cyanides, may release HCN gas when mixed with zinc chloride. If combined with sulfides, the liquid flux may release H2S gas. Element Tin (oxide) Lead (as dust & fume) Silver (metal) Silver (soluble compounds) Antimony Cadmium (oxide fume) Zinc (oxide) CAS# 7440-31-5 7439-92-1 7440-22-4 7440-22-4 7440-364) 1306-194) 1314-13-2 PEL mfl/m3^ 2.0 0.05 0.01 0.01 0.5 0.1 0.3 (ceiling limit) 5.0 TLV mg/m3^ 2.0 0.15 0.1 0.01 0.5 0.05 0.3 (ceiling limit) 5.0 (fume) Zinc Chloride (acid core) Activated Rosin (Rosin core) Additional Data for Flux Core 7646-86-7 1.0 No Listing None 1.0 None (1) Permissable exposure limit OSHA 1910 Subpart Z. (2) Threshold limit value American Conference of Government Industrial Hygenists. One recommended way to determine the composition and quantity of fumes and gases to which workers are exposed is to take an air sample in the worker's breathing zone. See ANSI/AWS F1.1, available from the American Welding Society. P.0. Box 351040. Miami, Florida 33135. SECTION 7 SPILL 3R LEAK PROCEDURES t 00 A 061512 CONFIDENTIAL SECTION 8 AND 9 - SPECIAL PROTECTION INFORMATION AND PRECAUTIONS Read and understand the manufacturer's instructions and the precautionary label on the product. See American tional Standard Z49.1, Safety in Welding and Cutting published by the American Welding Society. P.O. Box 351040, miarni, FL 33135 and OSHA Publication 2206 (29CFR1910), U.S. Government Printing Office. Washington. D.C. 20402 for more detail on many of the following. Ventilation Use enough ventilation, local exhaust at the arc (or flame) to keep the fumes and gases below TLV's in the worker's breathing zone and the general area. Train the employee to keep his head out of the fumes. See ANSI/ASC Z49.1 Section 5. Respiratory Protection Use respirable fume respirator or air supplied respirator when soldering in confined space or where local exhaust or ventilation does not keep exposed below TLV. t Eye Protection Wear helmet or use face shield with filter lens of appropriate shade number (see ANSI/ASC Z49.1 -Section 4.2). Provide protection screens and flash goggles, if necessary, to shield others. Protective Clothing Wear head and body protection which help to prevent injury from sparks and flame. See ANSI Z491.1. At a minimum this includes gloves and a protective face shield, and may include arm protectors, aprons, hat, shoulder protection, as well as dark substantial clothing. Other Precautions wash hands thoroughly before smoking or eating after using lead bearing solders. The information and recommendations contained in this publication have been compiled from sources believed to be reliable and to represent the best information on the subject at the time of issue. No warranty, guarantee, or representation is made by Unibraze Corp. or J.W. Harris Co., Inc. as to the absolute correctness or sufficiency of any representation contained in this and other publications; Unibraze Corp. and J.W. Harris Co.. Inc. assume no responsibility in connection therewith; nor can it be assumed that all acceptable safety measures are contained in this (and other publications), or that other or additional measures may not be required under particular or exceptional conditions or circumstances. J. W HARRIS CO . INC. UNIBRAZE CORP 10930 DEERFIELD ROAD 75R? WEST STATE RT 41 CINCINNATI. OHIO *5242 COVlMfVrnN nui/)<<Oifl 513 8C1 "Ore cn j-t-) D0 A 061513 CONFIDFNTTAL