Document 3eZ6bO9wXJakB2NowRxN9pk23
Fluorotelomer and ECF Products : Different Chemistry
Fluorotelomers (Telomerization)
CF2=CF2
I
(TFE)
F(CF2)nl
Perfluoroalkyl Iodide
n = 6,8,10,12, even
F(CF2)nCH2CH2l Fluorotelomer Iodide
----- F (C F 2) nC H 2C H 2S 0 3X : F T S u lfo n a te
AFFF Surfactant Products F(CF2)nCH2CH2OH
| Fluorotelomer Alcohol
ECF (Electrochemical Fluorination)
H(CH2)nSH
'r
F(CF2)nS 0 2F
F(CF2)nS 0 3X
PFOS n = 8; PFHXS n = 6 ' r PFBS n = 4
F(CF2)nS 0 2N(R)CH2CH20H
Perfluoroalkyl sulfonamido ethanol
ir
Sales Products
Sales Products
Even number, straight chains, No Branching Polymers n> 8 ; Surfactants n=6 primarily
ECF produced materials have up to 30% branched isomers at the fluorinated chain end and contain odd and even carbon chain lengths
US00005803