Document 3VGYdVm6ZG0zDOnjYRy9aogx
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Date Printed: 03-25-1996 Page 1
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1 -PRODUCT IDENTIFICATION
PRODUCT NAME: COMMON SYNONYMS: CHEMICAL FAMILY: FORMULA: FORMULA WT.: CAS NO.: NIOSH/RTECS NO. : PRODUCT USE:
ACETONE DIMETHYL KETONE; 2 -PROPANONE; KETONES
(CH3)2CO
58.08 67-64-1 AL3150000 LABORATORY REAGENT
DIMETHYL KETAL
CHEMTREC # (800) 424-9300 LA-MAR-KA, INC.
10272 SOUTH PERDUE STREET BATON ROUGE, LA. 70814
EFFECTIVE: 09/06/89 REVISION #05
ISSUED: 04/13/90 REVIEWED 1-1-95
PRECAUTIONARY LABELING
LA-MAR-KA LABELING SYSTEM HEALTH
1 SLIGHT
FLAMMABILITY
3 SEVERE (FLAMMABLE)
REACTIVITY
2 MODERATE
CONTACT
1 SLIGHT
LABORATORY PROTECTIVE EQUIPMENT
GOGGLES; LAB COAT; VENT HOOD; PROPER GLOVES; CLASS B EXTINGUISHER
U.S. PRECAUTIONARY LABELING
DANGER
CAUSES IRRITATION. EXTREMELY FLAMMABLE. HARMFUL IF SWALLOWED OR INHALED.
KEEP AWAY FROM HEAT, SPARKS, FLAME. AVOID CONTACT WITH EYES, SKIN, CLOTHING. AVOID BREATHING VAPOR. KEEP IN TIGHTLY CLOSED CONTAINER. USE WITH ADEQUATE VENTILATION. WASH THOROUGHLY AFTER HANDLING. IN CASE OF FIRE, USE ALCOHOL FOAM, DRY CHEMICAL, CARBON DIOXIDE - WATER MAY BE INEFFECTIVE. IN CASE OF SPILL, SOAK UP WITH SAND OR EARTH. FLUSH SPILL AREA WITH WATER.
INTERNATIONAL LABELING
HIGHLY FLAMMABLE.
PRECAUTIONARY LABELING (CONTINUED)
KEEP CONTAINER IN A WELL-VENTILATED PLACE. KEEP AWAY FROM SOURCES OF IGNITION - NO SMOKING. DO NOT BREATHE VAPOUR. TAKE PRECAUTIONARY MEASURES AGAINST
STATIC DISCHARGES.
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LA-MAR-KA MSDS for ACETONE
Date Printed: 03-25-1996 Page 2
1 -PRODUCT IDENTIFICATION (continued)
LA-MAR-KA STORAGE COLOR CODE: RED (FLAMMABLE)
2 -COMPONENTS
COMPONENT ACETONE
CAS NO. 67-64-1
WEIGHT % 90-100
OSHA/PEL 750 PPM
ACGIH/TLV 750 PPM
3 -PHYSICAL DATA
BOILING POINT: 56 C (132 F) (AT 760 MM HG)
VAPOR PRESSURE (MMHG): 181 (20 C)
MELTING POINT: -95 C (-139 F) (AT 760 MM HG)
VAPOR DENSITY (AIR=1): 2.0
SPECIFIC GRAVITY: 0.79 (H20=l)
EVAPORATION RATE: 14.4 (BUTYL ACETATE = 1)
. ^UBILITY(H20): COMPLETE (100%)
% VOLATILES BY VOLUME: 100 (21 C)
PH: N/A
ODOR THRESHOLD (P.P.M.): 100
PHYSICAL STATE: LIQUID
COEFFICIENT WATER/OIL DISTRIBUTION: N/A
APPEARANCE Sc ODOR: CLEAR, COLORLESS LIQUID. SWEET ODOR.
4 -FIRE AND EXPLOSION HAZARD DATA
FLASH POINT (CLOSED CUP): -17 C (0 F)
NFPA 704M RATING: 1-3-0
AUTOIGNITION TEMPERATURE: 464 C (869 F)
FLAMMABLE LIMITS: UPPER -13.0 %
LOWER - 2.6 %
FIRE EXTINGUISHING MEDIA USE ALCOHOL FOAM, DRY CHEMICAL OR CARBON DIOXIDE. (WATER MAY BE
INEFFECTIVE.)
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4 -FIRE AND EXPLOSION HAZARD DATA (continued)
SPECIAL FIRE-FIGHTING PROCEDURES FIREFIGHTERS SHOULD WEAR PROPER PROTECTIVE EQUIPMENT AND SELF-CONTAINED BREATHING APPARATUS WITH FULL FACEPIECE OPERATED IN POSITIVE PRESSURE MODE. MOVE CONTAINERS FROM FIRE AREA IF IT CAN BE DONE WITHOUT RISK. USE WATER TO KEEP FIRE-EXPOSED CONTAINERS COOL.
UNUSUAL FIRE & EXPLOSION HAZARDS VAPORS MAY FLOW ALONG SURFACES TO DISTANT IGNITION SOURCES AND FLASH BACK. CLOSED CONTAINERS EXPOSED TO HEAT MAY EXPLODE. CONTACT WITH STRONG OXIDIZERS MAY CAUSE FIRE.
TOXIC GASES PRODUCED CARBON MONOXIDE, CARBON DIOXIDE
EXPLOSION DATA-SENSITIVITY TO MECHANICAL IMPACT NONE IDENTIFIED.
EXPLOSION DATA-SENSITIVITY TO STATIC DISCHARGE NONE IDENTIFIED.
-HEALTH HAZARD DATA
THRESHOLD LIMIT VALUE (TLV/TWA): 1780 MG/M3 (750 PPM)
SHORT-TERM EXPOSURE LIMIT (STEL): 2375 MG/M3 (1000 PPM)
PERMISSIBLE EXPOSURE LIMIT (PEL): 1800 MG/M3 (750 PPM)
TOXICITY OF COMPONENTS
ORAL RAT LD50 FOR ACETONE
ORAL MOUSE LD50 FOR ACETONE
INTRAPERITONEAL MOUSE LD50 FOR ACETONE
SKIN RABBIT LD50 FOR ACETONE
CARCINOGENICITY: NTP: NO
IARC: NO
Z LIST: NO
OSHA REG:
9750
3Q00
1297 20 NO
MG/KG
MG/KG
MG/KG G/KG
CARCINOGENICITY NONE IDENTIFIED.
REPRODUCTIVE EFFECTS NONE IDENTIFIED.
EFFECTS OF OVEREXPOSURE
INHALATION:
IRRITATION OF NOSE AND THROAT, HEADACHE, NAUSEA, VOMITING, DIZZINESS, NARCOSIS, RESPIRATORY FAILURE, LOW BLOOD PRESSURE, CENTRAL NERVOUS SYSTEM DEPRESSION, COMA
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5 -HEALTH HAZARD DATA (continued)
SKIN CONTACT:
IRRITATION, PROLONGED CONTACT MAY CAUSE DERMATITIS
EYE CONTACT:
SEVERE IRRITATION, MAY CAUSE TEMPORARY CORNEAL DAMAGE
SKIN ABSORPTION: MAY OCCUR
INGESTION:
HEADACHE, NAUSEA, VOMITING, DIZZINESS, GASTROINTESTINAL IRRITATION, CENTRAL NERVOUS SYSTEM DEPRESSION, UNCONSCIOUSNESS
CHRONIC EFFECTS: KIDNEY DAMAGE, LIVER DAMAGE
TARGET ORGANS RESPIRATORY SYSTEM, LUNGS, EYES, SKIN, CENTRAL NERVOUS SYSTEM
MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE CHRONIC RESPIRATORY DISEASE, SKIN DISORDERS, EYE DISORDERS
PRIMARY ROUTES OF ENTRY INHALATION, INGESTION, EYE CONTACT, SKIN CONTACT
URGENCY AND FIRST AID PROCEDURES
INGESTION:
CALL A PHYSICIAN. IF SWALLOWED, IF CONSCIOUS, GIVE LARGE AMOUNTS OF WATER. INDUCE VOMITING.
INHALATION:
IF INHALED, REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE
ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN.
SKIN CONTACT: IN CASE OF CONTACT, FLUSH SKIN WITH WATER.
EYE CONTACT: IN CASE OF EYE CONTACT, IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES.
NOTES TO PHYSICIAN TREATMENT FOR ACCIDENTAL INGESTION OF A SMALL AMOUNT OF ACETONE IS UNNECESSARY. IF A LARGE AMOUNT HAS BEEN INGESTED, ADMINISTER AN AQUEOUS CHARCOAL SLURRY.
SARA/TITLE III HAZARD CATEGORIES AND LISTS
ACUTE: YES CHRONIC: YES FLAMMABILITY: YES PRESSURE: NO REACTIVITY: NO
EXTREMELY HAZARDOUS SUBSTANCE: NO
CERCLA HAZARDOUS SUBSTANCE:
YES
SARA 313 TOXIC CHEMICALS:
YES
GENERIC CLASS:
CONTAINS ACETONE (RQ = 5000 LBS) CONTAINS ACETONE C07
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5 -HEALTH HAZARD DATA (continued)
TSCA INVENTORY:
YES
6 -REACTIVITY DATA
STABILITY: STABLE
HAZARDOUS POLYMERIZATION: WILL NOT OCCUR
CONDITIONS TO AVOID:
HEAT, FLAME, OTHER SOURCES OF IGNITION
INCOMPATIBLES:
STRONG OXIDIZING AGENTS, STRONG BASES, HALOGEN ACIDS AND HALOGEN COMPOUNDS, CAUSTICS, AMINES AND AMMONIA, CHLORINE AND CHLORINE COMPOUNDS, STRONG ACIDS, ESP. SULFURIC, NITRIC, HYDROCHLORIC
DECOMPOSITION PRODUCTS: CARBON MONOXIDE, CARBON DIOXIDE
7 -SPILL & DISPOSAL PROCEDURES
r-^EPS TO BE TAKEN IN THE EVENT OF A SPILL OR DISCHARGE WEAR SUITABLE PROTECTIVE CLOTHING. SHUT OFF IGNITION SOURCES; NO FLARES, SMOKING, OR FLAMES IN AREA. STOP LEAK IF YOU CAN DO SO WITHOUT RISK. USE WATER SPRAY TO REDUCE VAPORS. TAKE UP WITH SAND OR OTHER NON-COMBUSTIBLE ABSORBENT MATERIAL AND PLACE INTO CONTAINER FOR LATER DISPOSAL. FLUSH AREA WITH WATER.
DISPOSAL PROCEDURE DISPOSE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE, AND LOCAL
ENVIRONMENTAL REGULATIONS.
EPA HAZARDOUS WASTE NUMBER:
U002 (TOXIC WASTE)
8 -INDUSTRIAL PROTECTIVE EQUIPMENT
VENTILATION:
USE GENERAL OR LOCAL EXHAUST VENTILATION TO MEET TLV REQUIREMENTS.
RESPIRATORY
PROTECTION:
RESPIRATORY PROTECTION REQUIRED IF AIRBORNE CONCENTRATION EXCEEDS TLV. AT CONCENTRATIONS UP TO 5000 PPM, A CHEMICAL CARTRIDGE RESPIRATOR WITH ORGANIC VAPOR CARTRIDGE IS RECOMMENDED. ABOVE THIS LEVEL, A
SELF-CONTAINED BREATHING APPARATUS IS RECOMMENDED.
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LA-MAR-KA MSDS for ACETONE ---------------------------------------j. '--------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------+
(
8 -INDUSTRIAL PROTECTIVE EQUIPMENT (continued)
EYE/SKIN PROTECTION:
SAFETY GOGGLES, BUTYL RUBBER GLOVES ARE RECOMMENDED.
9 -STORAGE AND HANDLING PRECAUTIONS
LA-MAR-KA STORAGE COLOR CODE: RED (FLAMMABLE)
STORAGE REQUIREMENTS KEEP CONTAINER TIGHTLY CLOSED. STORE IN A COOL, DRY, WELL-VENTILATED, FLAMMABLE LIQUID STORAGE AREA. ISOLATE FROM INCOMPATIBLE MATERIALS.
SPECIAL PRECAUTIONS BOND AND GROUND CONTAINERS WHEN TRANSFERRING LIQUID.
10 -TRANSPORTATION DATA AND ADDITIONAL INFORMATION
DOMESTIC (D.O.T.)
PROPER SHIPPING NAME: ACETONE
ZARD CLASS:
FLAMMABLE LIQUID
,/NA: UN1090
REPORTABLE QUANTITY: 5000 LBS.
LABELS: FLAMMABLE LIQUID
REGULATORY REFERENCES: 49CFR 172.101; 173.119
INTERNATIONAL (I.M.O.)
PROPER SHIPPING NAME: ACETONE
HAZARD CLASS:
3.1
UN: UN1090
MARINE POLLUTANTS: NO
LABELS: FLAMMABLE LIQUID
REGULATORY REFERENCES: 49CFR 172.102; PART 176;
V
I.M.O. PAGE: 3020 PACKAGING GROUP: II
IMO
AIR (I.C.A.O.)
PROPER SHIPPING NAME: ACETONE
HAZARD CLASS:
3.1
UN: UN1090
LABELS: FLAMMABLE LIQUID
REGULATORY REFERENCES: 49CFR 172.101;
173.6;
PACKAGING GROUP: PART 175; ICAO/IATA
II
U.S. CUSTOMS HARMONIZATION NUMBER: 29141100008
N/A = NOT APPLICABLE OR NOT AVAILABLE N/E = NOT ESTABLISHED
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10 -TRANSPORTATION DATA AND ADDITIONAL INFORMATION (continued)
THE INFORMATION IN THIS MATERIAL SAFETY DATA SHEET MEETS THE REQUIREMENTS OF
THE UNITED STATES OCCUPATIONAL SAFETY AND HEALTH ACT AND REGULATIONS
PROMULGATED THEREUNDER (29 CFR 1910.1200 ET. SEQ.) AND THE CANADIAN WORKPLACE
HAZARDOUS MATERIALS INFORMATION SYSTEM.
THIS DOCUMENT IS INTENDED ONLY AS A
GUIDE TO THE APPROPRIATE PRECAUTIONARY HANDLING OF THE MATERIAL BY A PERSON
TRAINED IN, OR SUPERVISED BY A PERSON TRAINED IN, CHEMICAL HANDLING. THE USER
IS RESPONSIBLE FOR DETERMINING THE PRECAUTIONS AND DANGERS OF THIS CHEMICAL
FOR HIS OR HER PARTICULAR APPLICATION. DEPENDING ON USAGE, PROTECTIVE CLOTHING
INCLUDING EYE AND FACE GUARDS AND RESPIRATORS MUST BE USED TO AVOID CONTACT
WITH MATERIAL OR BREATHING CHEMICAL VAPORS/FUMES.
EXPOSURE TO THIS PRODUCT MAY HAVE SERIOUS ADVERSE HEALTH EFFECTS. THIS
CHEMICAL MAY INTERACT WITH OTHER SUBSTANCES. SINCE THE POTENTIAL USES ARE SO
VARIED, LA-MAR-KA CANNOT WARN OF ALL OF THE POTENTIAL DANGERS OF
USE OR INTERACTION WITH OTHER CHEMICALS OR MATERIALS.
LA-MAR-KA
WARRANTS THAT THE CHEMICAL MEETS THE SPECIFICATIONS SET FORTH ON THE LABEL.
LA-MAR-KA DISCLAIMS ANY OTHER WARRANTIES, EXPRESSED OR IMPLIED, WITH REGARD TO THE PRODUCT SUPPLIED HEREUNDER, ITS MERCHANTABILITY OR ITS FITNESS FOR A PARTICULAR PURPOSE.
mHE USER SHOULD RECOGNIZE THAT THIS PRODUCT CAN CAUSE SEVERE INJURY AND EVEN
\TH, ESPECIALLY IF IMPROPERLY HANDLED OR THE KNOWN DANGERS OF USE ARE NOT
. EDED.
READ ALL PRECAUTIONARY INFORMATION.
AS NEW DOCUMENTED GENERAL
SAFETY INFORMATION BECOMES AVAILABLE, LA-MAR-KA WILL PERIODICALLY REVISE
THIS MATERIAL SAFETY DATA SHEET.
APPROVED BY LA-MAR-KA, INC.
D0 A 060548 CONFIDENTIAl
