Document 3QxwGrRkx4wea8yng6myenXp6

OxyChem Vinyl Chloride (Monomer) ox-yCUtM VJCM *AST>5 W. iq - 1990 DANGER! EXTREMELY FLAMMABLE. LIQUID CONTACT CAN CAUSE BURNS TO EYES AND SKIN. HIGH CONCENTRATIONS MAY CAUSE CENTRAL NERVOUS SYSTEM DEPRES SION AND KIDNEY/LIVER DAMAGE. CANCER HAZARD, CAN CAUSE CANCER. RISK OF CANCER DEPENDS ON DURATION AND LEVEL OF EXPOSURE. Keep away from heat, sparks and flame. Use only with adequate ventilation. Keep containers closed when not in use. Avoid contact with liquid and vapor. Bond and ground containers and equipment. Do not cut, drill, grind or weld on or near containers. Vapors can travel to ignition sources and flash back. Wear goggles, chemical resistant gloves, and protective clothing. Use NIOSH approved respirator as required to prevent overexposure. Use explosion-proof ventilation. Avoid contact with heat, oxidiizing agents, polymerization catalysts, copper, aluminum, alkali metals. IN CASE OF CONTACT: FIRST AID: FOR EYES: If direct liquid contact occurs, IMMEDIATELY flush eyes with a directed stream of water for at least 15 minutes. Forcibly hold eyelids apart to ensure complete irrigation of all eye and lid tissue. GET IMMEDIATE MEDICAL ATTENTION. FOR SKIN: If direct liquid contact occurs, flush with water. If frostbite or burn occurs, do not rub area. GET MEDICAL ATTENTION IMMEDIATELY. IF INHALED: Remove to fresh air. If breathing has stopped, give mouth-to-mouth resuscitation. If breathing is difficult, have trained person administer oxygen. GET IMMEDIATE MEDICAL ATTENTION. IF SWALLOWED: NA. PT.70 LABEL 0S9M919Z OCC 5844 o IN CASE OF: SPILL OR LEAK: Extremely flammable. Eliminate all ignition sources. Isolate area and deny entry to unprotected personnel. Stay upwind and disperse any vapor cloud with water spray. Releases to air, land or water exceeding 1 pound must be reported to National Response Center 1-800-424-8802. FIRE: Clear area of all unprotected personnel. Wear full protective equipment. Cool fire exposed containers with water. Use water fog, foam, dry chemical or C02. Stop source ol leak if possible. DISPOSAL: Submit to an approved chemical disposal service for disposal in accordance with government regulations. INFORMATION REQUIRED BY FEDERAL, STATE, OR LOCAL REGULATIONS: This product contains: CAS# Name 108990 1,3-Butadiene 75014 Ethene, chloro- HMIS RATING SYSTEM: FOR INDUSTRIAL USE ONLY HEALTH 3' FLAMMABILITY 4 REACTIVITY 2 24 Hour Emergency Phone: (716) 278-7021 Chemtrec EMERGENCY TELEPHONE NUMBER 1-800-424-9300 OXY. Occidental Chemical Corporation Electrochemicals & Specialty Products Group Dallas, Texas 75380 214-404-3800 OCC 5845 OCCIDENTAL CHEMICAL MATERIAL SAFETY DATA SHEET MSDS NUMBER MbDG C'ATE PRODUCT NAME M9 192 05-23-89 VINYL CHLORIDE (MONOMER) 24 HOUR EMERGENCY PHONE. (716) 278-7021 I. PRODUCT IDENTIFICATION ~~ HMIS HAZARD RATINGS ~ HEALTH HAZARD 3* FIRE HAZARD 4 REACTIVITY 2 Based on the National Paint & Coatings Association hM[S rating system SARA/TITLE III HAZARD CATEGORIES (See Section X) Immediate (ACUTE) Health, Delayed (Chronic) Health, Fire Hazard. YES YES YES Reactive Hazard: YES Sudden Release of Pressure. YES MANUFACTURER'S. NAME AND ADDRESS Occidenta1 Chemica1 Corporation Customer Service. Occidental Tower, P O Box 809Q5Q. Dallas, Texas 75380 Telephone ( 1-800-752-5 15 1) CHEMICAL NAME: Ethylene. Chloro- CAS NUMBER: 75-01-4 SYNONYMS/COMMON NAMES: VCM. Ethene. Chloro: Monoch1oroethy1ene. Ch1oroethene CHEMICAL FORMULA C2C1H3 DOT PROPER SHIPPING NAME. Vinyl Chloride DOT HAZARD CLASS. Flammable Gas DOT I D NUMBER UN 1086 DOT HAZARDOUS SUBSTANCE. RQ 10# II. HEALTH HAZARD INFORMATION EMERGENCY AND FIRST AID PROCEDURES EYES : If direct 1iquid contact occurs, IMMEDIATELY flush eyes with a directed stream of water for at least 15 minutes. Forcibly hold eye 1 ids apart to ensure complete irrigation of al 1 eye and 1 id tissue. GET IMMEDIATE MEDICAL ATTENTION. SKIN: If direct liauid contact frostbite or burn occurs. ATTENTION IMMEDIATELY. occurs, flush with water. If do not rub area. GET MEDICAL INHALATION; Remove to fresh air. If breathing mouth-to-mou+h resuscitation. If breathing trained person administer oxygen. GET ATTENTION. has stobbed. give is difficult, have IMMEDIATE MEDICAL OCC 5846 -ast'act Sermc* Mwmger szL - OShA 8trm5sioie *oosur# Limit NO 5 No relevant information fogng gr *iQt available CORP * Corograte i*oo$ur u-m.r "'.V -* ACO'H T-we*no*d L.mit /Alga Current NA * Not aoo'icaoie " : Sae C*'0"'C sheets M?CR"Ai\'p erormjrio* 3'esenteo n#rfin Anil ot guaranteed was oreoarod av competent 'ec^nigal oersonnei and s fue md acc.'ate '0 csst 3: -3Vi*edge NO WARRANTY OR GUARANTY ESPRESSO* MPL ED IS MAC REGARDING PERFORMANCE STASiLlTY OR O'HERwrSS Tn.j nrormj- r`9-3tc *0 aa 4'> as to :n* -ijnnf and :dnd.fons a* Ji# *'*r*a ng and itorage 0:t*tr factors m*/ ,m.o.v gtfr gr aodno'Ji 3'*s' --ang* :gns drjt*ons vvn.ie our 'ecnmcai ae'sonnei will 3e naooy to 'esoond to question* 'egardmg safe nanahng *n<j ,,se d'aced*'** iJ` 'r:'N *'9 `n* *ioor's,0,`'11 of '* :us*3mer Mo Suggestions 'or use ire -mended as and nothing s^a-i o ;3^s-r^is 1 -cs --on `o -** rgg ift / .-g patent* o' -oiat* *ed*r*i State or <ocai i*ws occidental c:-em i ca MSD3 NUMBER M9 \ 2 product name v;n L CHLORIDE (MONOMER) II. HEALTH HAZARD INFORMATION (Continued) INGESTION: NA ROUTES OF EXPOSURF INHALATI ON: 3h concentrations may cause central nervous system Georssson an Kidney/' iver damage, as well as affect heart -rv-~ns Pr rnged and repeated exposure may result m changes >n Dl J system and loss of bone from finger tids. SKIN: Direct contact (frostbite). with 1iquid can result in freeze currs EYE CONTACT: Direct contact with 1iquid can result in eye burns. INGESTION: Not a relevant route of exposure. EFFECTS OF OVEREXPOSURE ACUTE: Freeze burns as noted above, early to moderate centr a 1 ner vou s system depression may be evidenced by giddiness, headache. dizziness and nausea, in extreme cases, unconsciousness and death may occur. CHRONIC: Kidney damage may be evidenced by change in urine output, ur're appearance or edema (swelling from fluid retention), ,er damage may oe ev i denced by loss of appet ite. jaund ice i y e l ' o.. ;r Skin co1 or) and sometimes pain in the upper abdomen on the r igr; s i de . TOXICOLOGY DATA-. Acu te Inhalat ion , LC oO = 150.OGG ppm/2 hr 3 lr a t ) Vinyl chloride monomer has been demonstrated to be mutagenic in cultured cell tests, insects and laboratory animals. MEDICAL LIMITATIONS: Aggravated Medical Conditions: Pre-existing eye. skin and respiratory disorders may be aggravated by exposure to this product. Impaired kidney and liver function from pre-existing disorders may be aggravated by exposure to this product. Other Health Effects: uistso a a the Occupational Safety and Health Administration. The Natiora Toxicology Testing Program and the Internationai Agency Fcr Research on Cancer. Long-term exposure to vinyl chloride gas has caused cancer in animals. Some production workers have developed 1i ver cancer when exposed for many years to much highgr concentrations of inyl chloride than encountered P 1 an t s operating today. In addition there are reports that VCM may cause other forms of cancer n addition to 1^ver cancer. OCC 5847 ;ccdent-a_ "-smical mSOS M9 92 product name vinyl chloride <monomer> III. IMPORTANT COMPONENTS material or component CAS NUMBER / NAME `.05990 I ,3-3utadiene Conmon Names : EXPOSURE LIMITS PEL= 1000 ppm . 2200 mg/m3 TLV=10 ppm. 22 mg/m3. A2 Listed On(List Legend Below): 02 09 11 16 18 PERCENT VOL WT T50 14 Ethene, chloro- Common Names; MONOCHLOROETHYLENE VINYL CHLORIDE# VINYL CHLORIDE MONOMER PEL= l QOm, STEL = 5 opm TLV = 5 ppm; (8 hr I TWA ( 15 min) 10 mg/m3, A1 Listed On(List Legend Below): 02 06 08 11 15 16 18 VOL WT NO 39 .i # Chemical name used in the SARA Section 313 List of Toxic Chemicals (40 CFR - Section 372.65) if different from CAS name. See Sect ion I I All components of this product that are required to be on the TSCA Inventory are 1isted on the inventory LIST LEGEND 2 SARA TOXIC CHEM, SECTION 3 13 8 [ARC HUMAN CARCINOGEN, GROUP 1 l l CA PROP 65 - CARCINOGEN 15 NJ WORKPLACE HAZ SUBSTANCE L5'r 6 NTP "KNOWN HUMAN CARCINOGEN 9 [ARC GROUP 2A OR 2B CARCINOGEN 15 PA SPECIAL & ENV HAZ SUSSTANCE 18 NY HAZARDOUS SUBSTANCES IV. FIRE AND EXPLOSION DATA FLASH POINT; -108F (TCC) AUTOIGNITION TEMPERATURE. 882F FLAMMABLE LIMITS IN AIR. % BY VOLUME- UPPER; LOWER: 22.0 4.0 EXTINGUISHING MEDIA: Use water fog. foam, dry chemical or carbon dioxide. SPECIAL FIRE FIGHTING PROCEDURES; Danger! Extremely flammable; Clear fire area of unprotected personnel and isolate. Do not enter confined fire space without full ounker gear (helmet with face shield, bunker coats, gloves and rubber boots). including a positive pressure NIOSH approved self-contained breathing apparatus Cool fire exposed containers with water. Stop source of leak if possible. UNUSUAL FIRE AND EXPLOSION HAZARD: Containers exposed to intense heat from fires should be cooled with water to prevent vapor pressure buildup which could result in container rupture. Container areas exposed to direct flame contact should be cooled with large quantities of water as needed to prevent weakening of container structure. 0CC 5848 ccc: denial. ch=v:;al mSDS number ms '.92 PRODUCT NAME VtNYL CHLORIDE (MONOMER) V. SPECIAL PROTECTION VENTILATION REQUIREMENTS: Use explas ion-proof ventilation as required to control concentrations. ~~ SPECIFIC PERSONAL PROTECTIVE EQUIPMENT RESPIRATORY: Avoid breathing vapor. I exposure may or aoes occupat 1 ona 1 exposure limits t Sec III) use a NI OSH a reso'rater as required to prevent overexposure in aoco. ^ 29 CFR ;9 10. 134. use an atmosphere supplying respirator tai^ or self-contained breathing apparatus). No am pur 1 respirator Has been approved for vinyl chloriae. EYE : Wear chemical goggles if there is likelihood of contact ,v 1 ;n eyes . GLOVES: Wear chemical resistant gloves such as nitrile or viton. OTHER CLOTHING AND EQUIPMENT: Avoid liquid contact with skin and clothing. resistant protective clothing. Emergency shower faci 1 it y shou1d be in close proximity. Wear chemica1 and eye wasn MONITORING EXPOSURF BIOLOGICAL : ND PERSONAL/AREA: USE NI OSH Analytical Method: Number 1007. VI. PHYSICAL DATA BOILING POINT @ 760 mm Hg: 7F MELTING POINT- -245F VAPOR PRESSURE 1.210 mm Hg @ 20C SPECIFIC GRAVITY (H20=t). 0 81 SOLUBILITY IN H2O % BY WT: Slight VAPOR DENSITY (A 1r = 1 ) . 2.15 APPEARANCE AND ODOR. Colorless gas. "sweet" odor pH . ND EVAPORATION RATE (BuAc =1). >1 % VOLATILES BY VOL.. 100% OCC 5849 occidental chemical M S D S number M9 192 PRODUCT NAME JINYL CHLORIDE (MONOMER) VII. REACTIVITY DATA CONDITIONS CONTRIBUTING TO INSTABILITY: Can form shock sensitive peroxides on exposure to air INCOMPATIBILITY: Heat . con t act with oxiOizing agent s. Oxygen. air. sun 1 i gm and other polymerization catalysts. Copper, aluminum, metal 3 L-v;s and alkali met a 1 s such as sod ium and potass ium and then al^o-. 3 HAZARDOUS DECOMPOSITION PRODUCTS: HC1, CO. phosgene on combustion. CONDITIONS CONTRIBUTING TO HAZARDOUS POLYMERIZATION: Heat . contact with oxidizing agen t s. oxygen, air, other polymerizat1 on catalysts. sun 1 igh t and VIII. HANDLING AND STORAGE HANDLING AND STORAGE PRECAUTIONS: Keep 1iquid and vapor away from heat, sparks and f'ame. Surfaces that are sufficiently hot may ignite even 1iquid product in the absence of sparks or f1ame. Ext 1nguish pilot 1 1 gh t 3. cigarettes and turn off other sources of ignition prior to use and until all vapors are gone. Vapors may accumulate and travel to ignition sources distant from the handling site; flash fire can result. Keeo containers closed when not in use Use rzr'' , with adequate ventilation. Containers, even those that have been .emptied. car ccrra r. explosive vapor s. Do not cut , dr ill, burn, we Id or per r orm similar operations on or near containers. -.T t ' C ~=t t 1 3 *5 t y T.^ Ground " '*ed ecu Ipment . eauipmen t accumulate and feats 3cnd and ground transfer IX. ENVIRONMENTAL PROCEDURES STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: Danger1 Extremely flammable. Eliminate all sources of ignition. Isolate hazard area and deny entry to unnecessary or unprotected personnel . Stay uowmd and keep out of low areas. Notify local fire department. Disperse any vapor cloud with a sustained spray of water. Shut off source of leak only if it can Oe done safely. WASTE DISPOSAL METHOD: Under EPA - RCRA (40 CFR 261.21). if vinyl chloride becomes a waste material. it would be a hazardous waste; hazardous waste number U043. Refer to latest EPA or state regulations regaremg proper d1sposa1. EPA - Comprehensive Environmental Response. Compensation and Liability Act. Under EPA-CERCLA "Super-fund" releases to air. land or water which exceed the reportable quantity must be reported to the National Response Center 800~424-8802. RQ = 1 pound. OCC 5850 accidental chemical MSDS NUMBER M9132 PRODUCT NAME VINYL CHLORIDE (MONOMER) X. ADDITIONAL INFORMATION Pursuant to the requirements of the OSHA VCM Standard. 29CPR 19 10, 10 17. certain employees must be afforded approoriate medical surveillance. Pursuant to that standard. signs and 1 aoe1s are also required. OSHA Standard 29CFR 19 10. 1200 requires that information ba provided to employees regarding the hazards of chemicals oy means of a hazard communicat ion program including label mg, mater i a' safety data sheets, training and access to written records. we reauest that you. and it is your legal duty to. make a I I i nformat ion in this Materia 1 Safety Data Sheet available to v;u" emp1oyees. To aid our customers in complying with regulatory requirements. SARA Title III hazard categories for this product are indicated in Section I. If the word "YES" appears next to any category. this product may be reportable by you under the requirements of 40 CFR Part 370. Please consult those regulations for details. This product contains a toxic chemical or the reporting requirements of SECTION 313 SUPERFUND AMENDMENTS AND REAUTHOR IZATI ON ACT PART 372. (See Section I I I.List Legend 02) chemicals subject to of TITLE III of the OF 1986 and 40 CFR State of California Safe Drinking Water and Toxic Enforcement Act Of 1986 (Proposition 65) Warning: This chemical is cause cancer. known to the State of California to XI. PREPARATION INFORMATION For additional Non-Emergency Health, safety, or environmental informatlon teleohone (716> 286-3081. or write to. Occidental Chemical Corporation Product Stewardship Department Suite 400 360 Rainbow Boulevard South Niagara Falls. NY 14302 For Emergencies: 24 HOUR EMERGENCY PHONE: (716) 278-7021 This MSDS replaces MSDS Number M9 192 dated 03/08/88. 0CC 5851 Ui OCCIDENTAL CHEMICAL MSDS NUMBER. M9 192 PRODUCT NAME. VINYL CHLORIDE (MONOMER) Page 7 -Cg-27-3 WARNING LABEL INFORMATION Occ'dental Chemical Carporation Electrochemica1s & Specialty Products Irving. Texas 75062 In case of CHEMICAL EMERGENCIES - Call (716) 278-7021 (24 hours) CAS Number: 75-01-4 SIGNAL WORD: DANGER STATEMENT OF HAZARDS: EXTREMELY FLAMMABLE LIOUID CONTACT CAN CAUSE BURNS TO EYES AND SKIN HIGH CONCENTRATIONS MAY CAUSE CENTRAL NERVOUS SYSTEM DEPRESSION KIDNEY/LIVER DAMAGE CANCER HAZARD. CAN CAUSE CANCER. RISK OF CANCER DEPENDS ON DURATION AND LEVEL OF EXPOSURE. AND PRECAUTIONARY STATEMENTS: Keep away from heat, sparks and flame Use only with adequate ventilation Keep containers closed when not in use Avoid contact with liquid and vapor Bond and ground containers and equipment Do not cut. drill, grind or weld on or near containers. Vapors can travel to ignition sources and flash back. Wear goggles, chemical resistant gloves, and protective clothing. Use NIOSH approved respirator as required to prevent overexposure. Use explosion-proof ventilation Avoid contact with heat. oxidizing agents. polymerization catalysts, copper, aluminum, alkali metals.. FIRST AID: IN CASE OF CONTACT: FOR EYES: If direct liquid contact occurs. IMMEDIATELY flush eyes with a directed stream of water for at least 15 minutes. Forcibly hold eyelids apart to ensure complete irrigation of all eye and lid tissue. GET IMMEDIATE MEDICAL ATTENTION. FOR SKIN: If direct liquid contact frostbite or burn occurs. ATTENTION IMMEDIATELY. occurs, flush with water. If do not rub area. GET MEDICAL IF INHALED: Remove to fresh air. If breathing mouth-to-mouth resusc1 tation, If breathing trained person administer oxygen. GET ATTENTION. has stopped. give is difficult, have IMMEDIATE MEDICAL IF SWALLOWED: NA OCC 5852 [i n occidental chemical MSOS NUMBER M9192 PRODUCT NAME. VINYL CHLORIDE (MONOMER) WARNING LABEL INFORMATION (Continued) IN CASE OF: SPILL OR LEAK: Extremely Flammable. Eliminate all ignition sources. Isolate area and deny entry to unprotected oersonnel Stay unwind and disperse any vapor cloud with water spray Releases to air, land or water exceeding 1 pound must be to National Response Center 1-800-424-8802 reoorteo FIRE: Clear area of al1 unprotected personnel. Wear full protective equipment. Cool fire exposed containers with water.Use water fog. foam, dry chemical or C02 . Stop source of leak if possible. DISPOSAL; Submit to an approved chemical disposal accordance with government regulations. service for disposal in INFORMATION REQUIRED BY FEDERAL. STATE OR LOCAL REGULATIONS: This product contains: CAS# 106990 NAME 1.3-Butadiene 75014 Ethene, chloro- HMIS RATING SYSTEM: HEALTH 3* FLAMMABILITY 4 FOR INDUSTRIAL USE ONLY LABEL For further information. Request OCC MSDS M9192 REACTIVITY 2 059M9 192 NFPA Fire Hazard Rating: Health 2 F1ammab11ity 4 Reactiv11 y 1 Auto ignition Temperature; 882 F Flammable Limits in Air % by Volume Upper: Lower: Flash Point: (TOC) -108F 22.0 4.0 OCC 5853