Document 3QvD50ob2mZmgLpxm3870m7mx
FORM N0.45A 201 - It
PPG INDUSTRIES
CHEMICAL DIVISION LAKE CHARLES, LOUISIANA
LABORATORY PRODUCT REPORT
TRICHLOR SHIPMENTS
1968
Avg.
Type t15(Dual Purpose Gn dej
Color
apha
6,
Specific Gravity 20/50 C
1.464
Distillation Range
C
Low
Water Content
High Cloud Point
C
Non.-Volatile Acio Acceptance
* ft as NaOH
86.5 3?.5 (-10
.0002 0.11
JAN
6
(-10 .0002
FES
6
--
-
Too" .0002
--
MAR
APR
66
--
----
---
jm.
(-10 ..0002
---
MAY JUNE JULY
(5 5 5
*
** . w
(-10 (-10 (-10 .0006 .0002 .0001
AUG
SEP
OCT
5 (5 6
--
_
(-10 .0002
am_ -
-
(-10 (-10 .0008 .0003
NOV
DEC
1969
Avg.
5 65
-- *-
_
(-10 .0002
--
---
(-10 TTo~
.0002 .0003
--
*
------------- -----
So Li
nUnlonUcuou
-------------- m________________ i
i
m
c ONFIDI NTIAL
ut------- 80 1
sject 1th Ju
to Prc dicia J
tecti Dist]
re Ord ict C
_________ 311 rfr
So. 91 -1145
-----------1---------- .
A w
FORM N0.45A 201-12
PERCHLOR SHIPMENTS
TYPE 207
Color
APHA
Specific Gravity ZO/20 C Distillation Range
C
Low
Water Content
High Cloud Point
C
Non-Volatile
GM-100 ml
PH Acid Acceptance
% as NaOH
Copper Corrosion
Acidity Ml of 0.01 N NaOH
Flask MG/30 CM*
Soxhlet MG/30 CM2 Condenser mg/30 CMZ
Chlorioes
ppm
1968 Avg.
1.623"'
-- To (,0001 8.4 -
i l 4 4 "0.05""
JAN
8
-- (0
8.2
*-
-- -
PPG INDUSTRIES
CHEMICAL DIVISION LAKE CHARLES, LOUISIANA laboratory product report
FEB
MAR
APR
MAY
JUNE JULY
78
_ (0
8.2
-- (0 _ 8.3 -
---
-----
87 --
-- (0 -- 8.3
-- -- -
-- -- To 8.3 -
-- -- -
87 mm
(0 (0
8.4
8.2 -
* ----*
AUG
SEP
OCT
NOV
8 89 --
8
(0 -- 8.2 --
(0 7.6
(0
8.5 -
----- -_-
(0
(Mi
-- -
DEC
1969 Avg.
6 _a_______
(0 -
8.4 -
-- -- -- --
_ (0 8.2 -
--* -- --
TYPE 208
Color
apha .
8
88
8
7 "7
87
Specific Gravity 20/20 C
1.624 1.624
1.624 1.624 1.624 1.624 1.624 1.624
Distillation Range Low
C
High
Water Content Cloud Point
C
Non-volatile
Wt.S^
PH
120.8 120.8
121.5 121.3 (0 10 .0003 roooi
6.8 "77U"
120.6 120.6 120.7 121.1
121.3 121.3 121.3 121.8
(o To
To
(0
121.0
121.7 (0
123-2. 121.9 (0
.0001 (.0003,(.0001 (.0003 (.0001 .0002
6.8'
6.9
6.6
6.7
6.7
Copper Corrosion
Acidity ML of 0.01 N NaOH Flask mg/30 CM*
Soxhlet MG/30 CM2 Condenser MG/30 CM2 Chlorides
ppm
2 (1
5 6 0.06
2 TT
~2------------- OA,
1----------
1 ~J----------- TI
55
5
6
7 (0.06
5 0.12
5 0.12
6 (.06
1 1 6
5 0.18
21 (1 1 64
54 0.11 ~ (.06
7
(0 6.8 -- _
78
1.624 1.624
9 1.624
88 1.624 1 *624-
121.1 121,8 (0 .0001 6.7
121.2 121.8 (0 .0004 6.7
121.2 121.2
121.9 122.0
To
r "To
121.0 121.6
(0
(.0001 (.0001 .0001
6.9
6.7
6.6
t (1
5 6
.06
1 (1 6
6 .08
J________ _2________ _J_______
(1
6
A
,n6
1 _n______
5
0 T06~
_______ 6
0.08
SLJV '3069
COT FTTTOtr I At*: Sub j SCt td ' TTO'tT :U L i vu 0 L (t (J 1
IB-if 141 ti Jud i cial 1 nrsTtrT ;L Luu
FORM NO.45A 201 -13
PERCHLOR SHIPMENTS
TYPE 203
Color
apha
Specific Gravity
20/20 C
Distillation Hinge
Low
C
Water Content Non-volatile
High
Cloud Point
C
GM- too ML
PH Acid Acceptance
% as NaOH
Copper Corrosion Acidity ML of 0.01 N NaOH Flask mg/30 CM2 Sgxhlet MG/30 CM2
Condenser MG/30 CM2
Chlorides
PPM
1968
Avg.
8
120.8 121.2 (0 .0002 8.6
-- -
JAN
7
_
(0
8.5 -
PPG INDUSTRIES
CHEMICAL DIVISION LAKE CHARLES, LOUISIANA
LABORATORY PRODUCT REPORT
FEB MAR
APR MAY
JUNE JULY
87 _
7
to -- 8.5
(0
8.6
-- --- --- -----
(0
mm
8.6
_ --
m w.
--* -.
mm
m
_
mm
_
----
-- _--
AUG
SEP
OCT
NOV
DEC
1969 Avg .
--*
* _--
---- -- m, a*
_-
-
m--
tm
-
---
7
to
8.6
-
TYPE 209
Color Specific Grayity
apha
20/20 C
Distillation Range
Low
C
Water Content
Hi gh Cloud Point
C
Non-Volatile PH
Gm-IOO ML
Acid Acceptancr
% as NaOH
Copper Corrosion Acidity ml of 0..0I N NaOH
Flask MG/30 CM2 Sokhlet MG/30 CM2
Condenser MG/30 CM2 Tui not nrs
PPM
8
-
-
to
-
8.6
-
-
-
SL 13070
--* --
--- --- -----
------
~7--------------
7
-
-
3.7
(0
6.8
-
--
-
--T ---- -- *-- -- - --
w
8-
-
W
to
6.8
-
-
-
-- -- --
-
_
9 ---
---
-- -- (0
--
-- -- -- -
-
-
mm
-
-- -- -- --- ---
-8
--
-
--
-* ---
_
.(0 .
5.8
-
-
-
A w
FORM NO.45A202- 13 .
HEAVIES STILL BOTTOMS
TplCHLOROETHYLENE 1 .1,2TRICHLOROETHANE Pfrchloroe thylene U-Tetrachloroethane S-Tetrachloroethane Pentachloroethane
Hexachloroethane
% % % % * %
%
Heavy Unknowns
*
FeClij Non-Volatile
ppm
*
PPG INDUSTRIES
1968
Avg.
(o.oi (0.01 21.57 2.26 37.27 33.09 1.74
CHEMICAL DIVISION LAKE CHARLES, LOUISIANA laboratory operations report
JAN FEB MAR APR MAY JUNE JULY AUG
0 (0.01
12.89 2.29 48.11 30.16 1.00
00 (0.01 (0.01 12.42 T^OB 1.99 2.10 55.09 56.90
23.79 22.77 0.69 0.62
0
(0.01 17.88 1.68 49.24 23.55 0.71
0 (0.01 (0.01 (0.01
12.86 11.25 1.59 2.36
54.24 48.02 25.06 28.43
~075r~ 0.87
(0.01 (0.01 18.43 1.89
43.67 27.23 0.86
6
(0.01 15.63 1 .R3 1.1 .56 29.29 1-23
SEP
0 (0.01 14.11 1.97 46.13 25.78 1.25
OCT NOV DEC
(0.01 0
0
(0.01 (0.01 0
13-34 19.37 20.38
1 -Q7 1.71 1.45
46.84 38.64 37.44 24.44 20.44 24.12
1.35 1.80 1.39
1.08 1.29 1.33 1.26 1.40 T7L2' 1.66 1.65 2.33 2.22 3.06 3.92 3.02
66
"(T2
-
-
*-,
'-- -
-
-
0.28 (0.01 - - -
----
---
-
-- --
1969
Avg. (o.oi (0.01 15.05 1.90 47.16 25.42 1.02
2.02
--. --
HEAVIES STILL REFLUX
(PER STILL FEED)
Trichloroethylene
R
1,1.2 Tr1CHLOROETHANE
%
Perchloroethylene
%
U-Tetrachloroethane
*
S-Tcthachloroethane
%
-- -- -
---
---
-- -
-
--
-
--
-- --
DRIED UNSTAB. PERCHLOR
Trichloroethylene
*0
---
--
1.1.2 Thichloroethane
% (0.01 - -- - ..
Perchloroethylene
* 99.73 - -- -
--
U-Tetrachloroethane
* 0.02
-
---
--
--
---
- *
-
--
--
--
-*
-* --*
-
---
-
-- --
-- --
-- --
--
- .
MR
---
-
-- --
--
-
-
--
-
* * *
------- --
HjO
PH
N I * a Test
Oxides
PPM " ' ' ppm
-
6.6
NEG.
-- OqiL Unn1 OnU7/ i1
m__
________
___________________
--
6.7
NEG.
6.7 6.6
NEG. NEG.
i
6*6
NEG.
----
6.7 TJ>
NEG. NEG.
--
6.7 NEG.
--
570-----
6.8
NEG. mr NEG.
6.7 NEG.
W
< ONFID1 :ntial J Si bject to Pr< teoti fe Ord ar ot J 4th Ji aicia. Dist :ict C 3urt
Wo- 93 -1145
:
-
675" neg;
t
-
NEG.
FORM N0.45A 202-14
PERCHLOR STABILIZATION
1968
avg.
TYPE 208
WT. %
Perchloroethylene 1 .j-Dichlorobromoethylene 1 .2-Dichlorobromoethylene 1,1,2-TR1CHLOROETHANE
UtTETRACHLOROETHANE EPE Unknown. Total
99 a 88
(O.Ql
fo.m
(0.01
0.05
0.04
--
JAN
FEB
PPG INDUSTRIES
CHEMICAL DIVISION LAKE CHARLES, LOUISIANA
LABORATORY OPERATIONS REPORT
MAR APR MAY JUNE JULY
AUG
99.86 99.88 99.87
(0.01 (o.oi (o.ol
0.02 0.01 0.01
(0.01 0.01 (0.01
0.05 0.04 0.05 0.04 0.04 0.04
-
99.86
(0.01
0.02
(0.01
0.05 0.04
99.89
(0.01
0.01
(0.01
0.05 0.04
99.86 fntm n.ni
(nrm
0.07 n.ru
99.85 (0.01 0.02 (0.01 0.06 0.04
--
99.89 (0.01 0.01 (0.01
0.04 0.04
-
19^9 SEP OCT NOV DEC Avg.
99.88 (0.01 0.01
(0.01
0.05 0.04
99.88 99.88
(0.0t (o.ot o.ot 0.01 Colot (o.ot
0.06 0.05 0.04 1.04
99.84 (0.01 0-01
(o.ot
0.05 0.05
99.87 (0.01 0.01
(0.01 0.05 0.04
--
TYPE 207
Perchloroethylene
WT
1,t-DlCHLOROBROMOETHYLENE t . 2-Dl CHLOROBROMOETHYLENE t.,.1 .2-.TRICHL0R0ETHANE U-sTETRACHLO roe thane EPE Unknown. Total
%
99.80
0
0 (0.01
0.05 0.05
-
.
.-
- 99.77 "0- ------------- -
- 0.02 - 0.01
- 0.04 - 0.04
- ---
-
99.80 99.80
00 00 (0.01 (0.01
0.04 0.06 0.04 0.04
---
99.78 99.80 00 0 13 (0.01 (0.01 0.06 0.06"
0.05 0.04
-
-
99.80 0 -
0- (0.01 - 0.06 - 0.04 -
-- -
99.80 0
0
(o.ot 0.0$ 0.04
-
nSiL
fOt 4lou/z
______ 9_____ :
w
cc iNFTnn ITTAr.f
Slifc iect
o P ro
14Of
th .7nr i t: i a 1
r*T i "j a Orrc
i P r i t- P Cr\ II*P
h o. 1 i i 4 S
A W
FORM N0.45A 202--I5
ppG INDUSTRIES
CHEMICAL DIVISION LAKE CHARLES, LOUISIANA
LABORATORY OPERATIONS REPORT
TRICHLOR STABILIZATION
TYPE 115
BLM
THF
Carbon Tetrachloride ADH
NPL TRICHLOROETHYLENE
PERCHtOROETHYLENE 1.1.2-TRICHLOROETHANE GDL Unioentifieo. Total
WT.%
1968 Avg.
(o.m 0.03 (0.01 99.50 (0.01 (0.01
0.05 (o.ol
JAN
-- 0 0.02 (0.01 99.55 --U~~ 0.01 -- (0.01
FEB
_ -
MAR
-- _ -- -
APR MAY
(n.m 0.02 0.01 99.57 (0.01 0.01
(0.01
--
-- .. -- -
JUNE JULY AUG SEP OCT
(0.01 0 0.03 0.Q3 (0.01 (0.01 98.62 99.48
(0.01 (0.01
(0.01 0.01
O 0.04
99.45 0
_
_
(0.01
Dr 03 (0.01 99.57 (0.01 Q.Q1.
(0.01 (0.01 (0.01 (0.01
-- -
--
NOV
OEC
1969 Avg .
mm
(QmSL. (Q.Q1- 0.02 0.Q2- (0.01 (0.01 - 99.48 99*3.6
(0.01 (0.01 - 0-01 0.01 ----- -- (0.01 (0.01
TYPE l'C22:
BLM THF Carbon Tetrachlorioe
ADH NPL Thichloroethvlche
PERCHtOROETHYLENE lv V,2-Trichloroethane GDL Unidentified. Total
WT. %
---
---
(0.01 _(o;oi
0.03 0.15
0.03 0.14
99.47 (0.01
(0.01 O'. 06
99. 49 (0.01
(0.01 0.07
(0.01 (0.01
-----
(0.01 (0.01 0.03 0.03 0.1 4 0.14 99. SO 99.69 (0.01 (0.01 0.01 0.01 0.06 0.07 (0.01 (0.01
-- --
-- ---
(0.01 (0.01 (0.01 (0.01
0.03 0.03 0.03 0.Q3
0.14 0.13 0.14 0.14
99.48 99.5! QQ.I.A 99.44 (0.01 (0.01 (6.01 (0.01
o.w0.02 0.01
(o.m
0.07 (0.01
n.m 0.01 0.071 0.07 (otoi (0.01
--
--
---
--
(0.01 (O.OL ToToT
0.03 0.03 0.03
0W".XI4nr
0.15 99.45
0.15 99.46
(0.01 (0.01 (0.01
TOTE 0.01 0.02
0.06 0.06 0.07
(0.01 (0.01 (0.01
*--
--
--
0.01 (0.01 (O.Oi
0.03 0.03 0.03
0.15 0.15 Q-l-4__
99.4J 99.46, 99.47-
(0.0 (0.01 (O^Ql_
Q.0L (0.01 0.Q1
0.06 -0.06- -O.Og -
AQ.Qj (0.Q1- (0.01
SI
w<--
n 1 3n7O
u 1 OU / 0
_____ _ji__________ ______
C( MFTDE? TIAL:
fitiTi jpefc t 0 Pro! ectiv : Orde r nF 14 fch Juc icial Distr Let Co art
______1 fc_____
F 0. 91 1145
FORM NO.45A 202-16
1963
TRICHLOR STABILIZATION Avg.
JAN
TYPE 1 10E
WT.. %
BLM THE Carbon Tetrachloride ADH NPL Trichloroethylene Perchloroethylene t.1,2-Trichloroethane GDL Unidentified,! Total
---
--
fo.oi 0.01 0.05 0.06 0.26 0.34 99.30 98.90 (0.01 (0.01 0.01 0.01 0.13 0.06 (0.01 (0.01
FES
PPG INDUSTRIES
CHEMICAL DIVISION LAKE CHARLES, LOUISIANA
LABORATORY OPERATIONS REPORT
MAR
APR MAY JUNE JULY
AUG
SEP
OCT
--
_
---
- (0.01
- 0.06
- 0.27 - 9^03
-- "0------- --
T5V01
- 0.14 --
- ~o:oi --
--
0.01 0.02
0.06 0.06 0.25 0.30 99.10 99.02 (0.01 0 0.02 0.15 0.12 (0.01 (0.01
HO
O
n.m 0:05
0.28 99.09 (0.01 0.01 0.18 (0.01
-
-
0.01 0.07 0.28 98.99 0 0.01
-
*-
0.01 (0.01
0.05 0.07 0.28 0.29 99.00 98.88 0 (0.01 0.01 0.02 - 0.20
(0.01 (0.O1
NOV
DEC
1969 Avg.
wm
0,01
0.06
0.28 98.96 0 0.01 0.09 (0.01
(0,07 6.07 _ 0.31. 98.98 0
(o.or
0
(0.01 0.06 0.29 99.00 (0.01 0.01
0.13 (0.01
TYPE 113
BLM THF Carbon Tetrachloride
ADH NPL TR1CHLOROETHYLENE Perchloroethylene 1.1.2-Trichloroethane GDL Unidentified. Total
WT. %
-
-
(0.01
0
(0.01
$9.97
(0.01 (0.01 0
(0.01
---
--
(0.01 ~U---------
0 0 99.99 0 (O.OT 0 (0.01
0 0 99.98 (0.01 0.01 0 (0.01
--
--
-- -- -- * -- --
(0.01
0
99.98 0
0.01 0
(0.01
--
--
-
--
-- -
-
X-OJJT
TJ
T3
99.98 (0 ."01"
(0.01 n ?n,m
--
0 0 0 99.99 0 (0.01 0 0
--
- --
(0.01TJ---------------- WJT
0v----------------
0
0 O (0.01 99.98 90.93 99-93
0 0.01 0 (0.01
0O
0.01 (0.01 00 (0.01 (0.01
-
-
(0.01
T5
0
9fo9..o9^i
0.01 0 (O.Of
-
-
(0.01
0
0
99. qq n 0.07
0
(n.m
-
-
(0.01
0
(0.01
99.93 fn m (o.oi
6
(0.07
___ SL OijVJ/h A
Subi
COtf 2ct td
->
i-iTT-Ml1
TAiL: ft i ve
i str i<
Order :t tou
rt
Yf
Ut t!
Jlldj
w*
r* 1 -- 1 1 4 5
' ___________
________
_
DRIED UNSTAB. TR1CHLOR
1968 Ave
Carbon Tetrachloride
% (o.oi
Trichloroethylene -
% 99.99
1.1.2 Trichloroethane______ %_ rto.oi
Perchloroethylene
% 0.00
JAN
--
-
--
PPG INDUSTRIES
CHEMICAL DIVISION LAKE CHARLES, LOUISIANA
LABORATORY OPERATIONS REPORT
FEB MAR
-- --
mm -
APR
-
--
MAY
-- -- *
JUNE JULY
-- -- -- _
AUG
-
-
-
SEP
-
--
OCT
--
NOV DEC
-- --
1969
Avg
--
-
H20 pH NaI Test . Oxides
ppm _
-
--
- -
- - - - -- - -
6.2 6.9 7.0 6.9
6.9 7.0
6.9 7.0 6.3 773 7.0 7.0 679
6.9
ppm NEG. NEG. NEG. Msg. NEG. NEG. NEG. NEG. ttect; NEG. NEG. NEG. NEC'. NEG.
r
- SL 01375 1---------------------------------------------------------------- -------------------------
----------------------1
'
*
a
.
CUTTF TTENTl rcr*
Sub je it to 'rotec :ive t refer oi I4th Jiidic Lai Oi strict Cf'ouri
No. 91-11 IS
* i-
*
-
FORM N0.45A 210.1
PPG INDUSTRIES
. . .. -
1e,,'T'nENT"',:=
SL 013076
'
chemical DivisionUke CHARLES, LOUISIANA
.. ; ; ;Judicial
; ' : Da
PERCHLOPETHYLENE-TRICHLORETHYLENE DEPARTMENT OPERATIONS REPORT
Co"
GENERAL DEPARTMENT
Ji'ircmlob (Stab. Production T/D
S-HIPifENTS T/D INVtNTURT IONS
I^ICHtdR (MAd. ) PhoOUC II ON T/D
Shipments T/D Inventory Tons
1968
AVG.
JAN
FE3 MAR
APR MAY
110.6 96.2 91.9 87.3 94.1 95.1 103.7 lO/i * A 63.6 51.7 195.8 45.4 2331.7 3A7R.1 *466.2 5579.7 2519.4 *063.1 97.6 121;$' 132.3 113.6 135.3 125.8
102.5 95.9 160.1 40.9 225.9 87.7 2631.9 2883.E 2074.3 4946.1 2229.3 J413.0
Unstab. Pehcklor Production T/D
EDC
T/T
110.9 101. O' 91.0 87.9 O.665 "0.611 0.641 0.652
CL2 T/T - 0.411
Thi-Eth.Bot. T/T
0.369 3.330
-
0.383 -
NH, Lbs./T 8.1
11.1 IT.X 1275
Clo From HC1 T/f 0.156 0.106 07146 0.095
Unstab. Trichlor Production T/D 97.6 ' 122.6 133.6 132.1
EOC
t/T
Cl 2
T/T
Tri-Etk.Bot T/T
0.839 0.256 -
0.771 0.809 0.823 0.233 0.209 0.241 --
NH,
Lbs./T 6.4
2.2 3.3 2.2
Cl2 From HC1 T/' 0.097 0.-067 0.092 0.060
Unstab. Product O2
T/T 0.268 757258 0.260 0.254
N2 T/T 0.215 0.052 0.060 C.089
2.?2 2.55Catalyst Lbs./T *
1.53 2.20
400# Stm,(actual) Lbs./T 2950 3453 ~WI2~ 3877
KV.H/T
68.3 65.2 62.7 67.1
`Miofl- Still Bottoms
T/T 0.051 0.022 0.U78 0.089
Uustab. Product Cl* Yield C YlELO
% *
36.2 738.7 84.9 738'. y
85.7 8/|r9` 84.7 82.5
95.8 0.634 0*457
--
1075 0.000 136.4 6.800 16.289
--
2.1 0.000
0.214 0.086 1.51 5125
63.3 0.076 37.8 36.4
94.6
o776o
0.477
-
9-5
0.000
124.2 0.793 0.285
2.5 0.000 0.212 0.097 2.87 3671 64.8 0.067 84.6 82.1
MAN HOURS/T STAB. PRODUCT
Production
Maintenance
eoSalahi
To TAL
Contract Mwi Hps* Ihcluopo
MAN HOURS/T SHIPPEO
Bulk
Drum
Salar ie^^P
O.41.3 0.355 0.467 0.236 0.168 0.133 1.048 0.724 OaQ52 0.054
0.056 0.048 0.668 0.655 0.019 0.008
0.361 ,0.353 0.77Q 0.372
0.134 0.129 0.774 0.854
0.334 0.441
0.126
0.901
0.138 0.000 0.000
0.391
0.509
0.130 1.030 0.000
0.045 0.301
0.QQ8
I
0.081 0.019 0.046
0.497 0.277 flko5
0.012 0.003 (TO08
JUNE JULY AUG SEP OCT NOV DEC 1969
Avg.
93.6 85.3 84.0 90.2 86.5 92.2 91.4 92.2 135.5 80.9 61.1 30.5 102.3 150.9 117.4 95.6 2804*3 2938.2 3646.1 5A38-1 4948.3 3185.1 2379.C 3803.0 120.1 101.8 97.9 138.5 117.9 127.0 113.4 120.5
99.1 97.1 146.1 158.5 98.4 135.9 114.8 121.7 4188.8 2693.5 1493.0 2097.6 1799.0 1755.c 2801.5
92.4 87.4 84.2
O.660 0.654 nTA4?
0.301 0.403 0.501
--
10.1
1.177 L19.5 0.833
778----- 10.8 0.061 0.009 10376" 96.3 0.829 0.798
0.190 0.255 0.311
---
-
92.0 0.687 0.496
<--
14.0 0.000 119.9 0.867 0.313
89.5 90.2 92.2 0.645 0.659 0.619 0.502 0.500 0.434
- ---
11.9 14.9 14.6 0.000 0.000 0.010 121 .9 t30.6 115.0 0.814" '0.797 0.782 0;317 07302 0.274
-
91.5 0.655 0.429
11.8 07050
409t?
0.810 0.268
-
2.6 579-- 475-- 2.6 2-4
1.8 3.0
2.8
0.107 0.038 0.006 n.nno 0.000 0.000 0.006 0.031
0.248 0.1230 0.225' 0.238 0.239 0.248 0.258 0.240
0.099 0.207 0.063 0.066 0.069 0.099 0.147 0.095
1756 1.70 3.80 4.41 3.98
2.02 2.44
2.46
mr~ 3727 3963 3274.9 3290.0 3096.3 3620.4 3517
'7475' 78.4 82.0 77.8 72.2 70.4 70.3 70.7
07091 0.056 0.107 0.079 0.103. 0.124 O.llo 0.084
33.7 8675 81.9 31.2 32.1
81.4. 67.3
84.6
3176 64.5 83.1 30.0 32.6 80.5 85.3 "8375"
0.387 0.254 0.139
0.780
0.000
0;414 0.822
0.156
1.392 0.000
0.467 1.027 0.158 1.652 0.000
0.403
0.393 0.139 0.935 0.000
0.394 0.470 0.147 1.011 _ 0.000
0.344 0.418
0.199 0.336 0.120 0.137 0.663 Q.891 0.009 0.007
4
0.385 0.445 0.137 0.967 0.017
0.035 0.047 0.027 1-OAl 0.055 0.681 07366" 0.638 0.571 0.676
0.005 0.007 0.006 0.012 0.010
0.026 0.012 0.63 Q 0.# 0,006 0.008
0.042
0.549 0.008
FORM
45A 210.?
MATERIAL BALANCE
CARBON - TONS
Total Carbon in Feed Carbon in Unstab. Product Process Loss by Difference
PPG .. .JUSTRIES CHEMICAL DIVISION LAKE CHARLES, LOUISIANA PERCHLORETHYLENE.tr ICHLORETHYLENE DEPARTMENT OPERATIONS REPORT
1968 JAN FEB MAR APR MAY JUNE JULY AUG SEP OCT . AVG.
NOV
OEC 1969 avg.
1217.C 1291.1 1242.8 1385.8 1347.7 1374.6 L294.9 1159.1 1112.3 1321.2 1321.6 1376.5 1249.5 1289.8
1083.8 1118.3 1052.8 11A3.6 1164.5 1128.4 L056.7 183.2 hi. 2.8 190.0 212.2 163.2 246.2 238.2
07*1-2 179.9
924.1
166-2
2160547.1.1 229.4
1106.0 1065.3 157577 26At*; 184.2 213 a
Accountable Process Losses Blowdown Reactor Miscellaneous Sub Total
Unaccountable Process Losses
Carbon Loading Loss
Total Carbon Losses
2G.k 143.0 20.0
183.3 0.0
19.1 103.7 20.0
142.8
0.0
16.3
153.7 20.0
tL90.0
4.9 23.6 20
17.3 16.9 204.9 146.3 20.0 20.0 242.2 133.2 "075 0..0
W.8 " 13.1
19.7 206.5 20.0 246.2 075
-5.0
[571 lL4.0
200.1 14$.9
257)
20.0
238.2 179.9
"075 0.0
1.9 3.5
189.8 166.4 21178 237.4 196.3. 241.2 240a 160.4
17.4 18:4 150.6 225.7 20.0 20.0
166.2 264.1 0.0 075
21.9 L87.5 20.0
229.4 3.0
48.1 -0.5 11.6
236.3 263.6 241.0
19.6
226.Q
20-0
268.5 0.0 L
24.1 18.6
140.0 17575"
20.0 1070
184.2 213.I
073
"070
19.2 4;i HI
287.7 188.3 224.2
CHLORINE-TONS
Total Chlorine in Feed Chlorine in Unstab. Product Process Loss by Difference
Accountable Process Losses Blowdown Reactor Mlscellaneous Sub Total
Unaccountable Process Losses
Chlorine Loading Loss
Total Chlorine Loss
_ SL 013077
6148.9 6489.8 6073.3 5301.3 5754.8 5206.8 847.6 735.0 866.5
6706.7 6573.1 6646.2
5647.6 5772.0 5624.4
1059.1 801.1
1021.8
6302.7 558570" 5676.6 5492.2 >611.0 5273.0 4916.1 4650.8 5271.8 5430.7
1029.7 769.9 1025.fi 122n. j, liso.3
6738.3 6102.4 6341.5 5485.9 5329.2 5363.6 1252.4 773.2 977.9
123.1 624.4 100.0 847.6 0.0
35.2
106.2 528.8 100.0 735.0 0.0
133.6
90.2
576.3 100.0 366.5 3.0
*
L0$.5
95.8 93.8 863.3 607.3 100.0 100.0 1059.1 301.1
070" 0.0
69.4
109.2 10O.3 ~777F 96.6 L02.1 L21.4.
812.6 829.4 592.3 828.9 L018.3 ?58.9 100.0 100.0 TOUT? 100.0 LOO.O LOO.O
1021.8 1029*7 769.9 1025.8 L220.4 L180.3
O 0.0
0.0 0.0 3.0
0.0
108.6 133.8 1043.6 539.4 100.0 100.0 1252.4 773.2 0.0 0.0
103.0
774.9 100.0
977.9 0.0
-21.6 8.1
1.4 48.1 -1.4
8270
12.1 TJ072
832.8
^
868.6
972.0
1049.2 ^70.5 1000.2 1037.8 771.3 1073.9 .219.0 vjT.y 1334.4 ?8$.3
-------- M fe-------
uw 1r"iriUnUmJWir --Sub] errfc--be 7T--irt n dual Clul
Ar .
Or Hot-I- rVili rt
--------- tfe . St-r- -bts--
1018.1
FORM N0.45A 210.3
SL 013078
PPG INDUSTRIES
CHEMICAL DIVISION LAKE CHARLES. LOUISIANA
CONFIDENTIAL: Subject to Protective n!r> of 14th Judicial District Court
No. 51-1145
REACTOR NO. 1
On Stream Time Oisch. Press.
Temp. f Vaporizer Liquor Dowtherm Out
Highest Tube
Lowest Tube
Sec. Coho. Disch
Catalyst Charged
Catalyst From Centrifix
Flow GPM
EDC
SCFH
CL2
Air
O,
Vent Analysis C02 Ha
Peh-Tri Ratio Per i Tri in Crude
1968
Avg. Hrs. *8627 psi g 9.2
266 446
20 Lbs. *J.7566 Lbs. *>,7<;66 4.7 6867 1516 10158
JAN
FC8
MAR
APR
MAY
744
672
744
719
689
-280" "275
276
"570
-- "259
123 424
423
427 -
470
---
15 2955 2955
13---------- "13-- 13---------- 29
1923" 2652 2355 9800
1925
2652 2355' 9800
1-1 6352
5.9 8057
6.2 7572
5.7
6.0
7045" 7376
_ ----
11227 11419 16686 9756 8574
JUNE JULY
AUG
SEP
OCT
720
-
--580
744
-
"280
"738
-
"283
716
-
"269
431
433
469
441 -
-- 23
1980 1980 6.9 8755 -
--
"59
25
2475
2005
"2573" 2005
7.0. 6.3
8144 7662
-
-
28> 5300 5300 7.2 7649
-
10991 L0889 10036 10578
745 -
2W 482
42 2000 2000 7.1 7729
10279
NOV
720
276 lt51
DEC
1969 Avg.
731
8682*
--
286____ 225_____
44? 440_____
----
37 2680 2680 6.6
_31_____ Z5l._____
1730 37857*
17,30 ,32852*
6.J
6*3______
7929
6829 --
7591
10360 9861 10388
ft 31.7 % 11.4
1.39 ft 33.96
43.5 36.5
-
27.0 5572
-
1.13 "07917- ~TT.BT-
85.8C 83706 84.84
59.0
0.94 86.40
27.0 1.02 82.78
--
0.87
'-- 1.15
85.39 87.75
1.00 88.97
0.88 82.24
* -
0.77 89.49
-
-
0.92 91.49
- 40.0 - 2713 1.01 6^5
90.56 86.56
REACTOR NO. Cn Stream Time Oisch. Press.
2
Temp, <>f vaporizer Liouor Dowtherm Out Highest tube Lowest Tube Sec. Cono. Oisch.
Catalyst Charged
J Catalyst prom Centrifix
Flow GPM
EDC
SCFH
CL2
Air '5
Hrs. *8515 ~755~ 67?
psig.- 10.4
-
275-------453---------
423-
272 424
_
76 "16-- 14
lbs. *18040 2965 1925
lbs.
*48040 4.7 . 6750
2965 5.0 7933
1925 "771 8880
"
1152
11220
11219 11541
744
719
-
268 267
423 - 426
----
--
7LI,
263 422
15 2672
24 2050
34 2480
2672 "2050" 2480
7.8 8750"
-
7.2
7975
-
7.2 1218
11195 10329 9538
Vent Analysis COj
Ha
PeR'Tri fflRPC
Per i Tri in Crude
* J37f *)T. ft u. n ft ctA kn
60.0 67.5
19.2 27.3
0.99 0.96
34.16 81.63
--
1.10 31.90
-- - >3.0
0.9W.97
84.25 82.18
720 "254 425
-
28
1980 1930 6.7 8570
-
10694
-
0.84
82.74
744 _ 268 432 37 2475 2475 6.8
8095
744
-
"255
446 --
-
3V
3185
3185 6.9 8166
10660 9508
--
1.05
0.96
.34*22. 87.22
702 -
256 459
-
42
1980 1980
6.0 7362
"578
27l
472
-- -- 46
"720
--
"273
488
34
10035 10035 6.4 7715'
--
2680
2680 6.4 7176
-
7.40
8671* --
_228____ 268______
458 --
442______
--
J35______ 30________
.mo. 3615??L
1730.. 3615.7--
.6*2____ 6.7
7088
-
7226____
-
8831 8035
0.80 88.25
* --
0.74
82.90
9469
-
0.87 88.36
9127 10012
- 63.8
23.2
-------0.93
80.29 84.72
"1 V
FORM N0.45A 210-
PPG INDUSTRIES
CHEMICAL D1VISIOH LAKE CHARLES, LOUISIANA PERCHLORETHYLENE-TRICHLORETHYLENE DEPARTMENT OPERATIONS REPORT
REACTOR NO. 5
ON STREAM TIME
DISCH. PRESS. TEMP. OP VAPORIZER LIQUOR
dowthermout HIGHEST TUBE
LOWEST TUBE
SEC. COND. DISCH.
catalyst charged
CATALYST FROM CENTR1FIX
FLOW GPM
EDC
SC FH Cla
AIR 02
AVG. 1968
JAN
HRS. #8629
PS1G
--
744
--
*
-
--
-
lbs.
LBS.
--
-
*36737 2970
*36737 2970
--
~---
-
FEB
i72
--
-- -
1995
TQ'yk
VENT ANALYSIS CO2 HCI
PER* TRI RATI PER + TRI IN CRUDE
% 35.4 62.5 X 18.5 19.1
i .53 1.20 1.03 % 84'.38 84.56 83.66
MAR
APR
MAY
JUNE JULY
702
-
707.
744
--
. -- --
-- --*
- - --
-
-
-
3517 ~5U5CT ~wsr
3517 ~^05tr *405
-
- --
----
- --
720
744
---
--
---
--
--
--
I9BTT 2655
1980 2655
-- --. --
--
--
1.08 83.04
--
--
1.03
82.99
--
-- --
18
--
1.07 "0798" 1.07
82.6? ^T759"~ 82.84
AUG
744
-- * -
1825 182f
-
0.95 84.88
SEP
710
-
I960 1980
-
OCT 672
NOV 720
DEC
AV6. xm,,
13k_____ I5.83JL
286
274
533
23
MB____ 033______ M2________ M3_____
--
--
46 10035 10035
6.2 7430
---
_15______ 37 2690 4500
2690 ,4500
6.8
6.3
8537 7759
-
19_______ 38532* 38532* 6*5 7909
-
9935
--
10678 9904
-
10172
0.91 0.90 85.51 82.33
--
-
0.94
--
0.86
5275 1873 1700
03 Jy
LOT.\
4 S 3 _____
'
- SL 013079
I
0
--
Cnk Hf* trli U 1 ~
liik
F'flUE tnPMmt
Li
tivo-<Qr jlsuxvvkLiulr
fxrtm
TiicLi_P U UU X L
s-bri-e-1 -Cour
ATr-V
01-1 AK
--
---------------------
--
--
FORM l 5A 210-4
SL 013080
PPG It.JUSTRIES CHEMICAL DIVISION LAKE CHARLES, LOUISIANA
Su b irs ,, f <'/>NPjr 0 ENT I
.
,
f ldfk
,
to Pt'rro(tf-'-*
. * c JU(Jicia | .
^1
PERCHLORETHYLENE.- TRICHLORETHYLENE DEPARTMENT OPERATIONS REPORT
' *** ~il4S ' "
,,
'
REACTOR NO. 3
0% Stream Time
Disch. Press.
T ,F emp
Vaporizer Liquor
Dowtherm Out
Highest Tube
Lowest Tube
Sec. Cond. Disch. Catalyst Charged
Catalyst from Centrifix
Flow GPM EDC
SCFH
Cl,
A| R
02
Vent Analysis
C02
HOL
Per-Tri Ratio
1Per
Tri in Crude
1968 AVG.
JAN
FEB
Hrs. *8634
725 '"672"
9.2psig.
--
2$8 --7BT 266 45-- 443 443
-
- ---
22 ~W~ 14
lbs. *40363 5515 1925
lbs. *40363 5515 1925
4.7 5.2 7.9
7314 576/1 8607
143 i -
-
9969 * -
11465
* 36.8 --
54.o
% 10.3
19.1 "| Q ft
%
1.55 _ 1.1*5 1,07 85.30 80.69 ftn, ej.
MAR
724
mm
272 AA9
15 3542 3542 8.5 8563 -- 11500
1.10 79.56
APR MAY
719 744
279 f283 446 442
27 2050 2050 8.1 7522 -
mm
_ 1.01 82.04
-
36 2480 2480 7 #7 7069 --* 11351 1
27.0 1.16 85.22 *.
JUNE JULY
720 -
"2ST" 438
744 -
277 452
-
30 1980' 1950"
7.0
36
2475 2475 6.8
7729 7911 --
11929 10481
- 1-0.86 1.07
82-. 76 85.25
AUG SEP OCT
.738 636" --
745
2B3 555 n72
450 459
445 --
--
-
30 36'
40
2045 5280"' 2000
2045 5250 2000
7.1 6.9 6.6
9162 7500 7U6-'
---
-
1097? 9827 9571
-- -- 1.02 0.97 85.40 84.98
-- w
0.76 85.77
REACTOR NO.
On Stream Time Disch p,,ess.
4
Hrs.
psig
Temp, of
Vaporizer Liquor' Dowtherm Out Highest Tube
*86^0 10.6 264 454
744 672
259 263 455 - 411 -
744 --
265 413 -
719
.-- - 270
: 419 -
1 -' 744
264 405
720 ;1I5
\mm
268" 265 411 410 -
0 -
-
700 745 -
269 286 984' 491 --
Lowest Tube
Sec. Cond. Disch.
Catalyst Charged
lbs.
Catalyst from Centrifix
. lbs.
Flow GPM
EDC
SCFH
Clj
A| R
-
44 *33204 *33204 4.5 7670
--
-
41 3305 .3305 4.6
W&
-
42
1925
1925 6.7 10181
-
40 2652 2652 6.8 8559
.- +
65 . 2050 2305
2050 2305 6.0 7.4 1 8079 '82;66_
---
-
70 76 1980' 0 198tr 0 5.9 A-0 9347 Q3R4
: 2a___________ _________ ____________________ 10767
9613
9931 10287 9357 10043 10164 10491 11
Vent Analysis
C02
HCL
Per-Tri Ratio
JPer i Tri in^^ide
% 38.3
15.0 1 -
-X
--
% 8.7 ~775~ ~6.o 1 --
: - 10.0 : -
1.43
1.14 0.93 10.97 1 l.oi 1.09 0.92 iO.81
% f 84.73 ` 82.68 80.48 1 81-9S ^78 !81.24 184.30
-
6605 6605
-
-
tm
-
64 13510 13510 674 7633
-
10962
-
70
2000 2000 6.2 6754
--
11146
-
0.90 84.63
-
-
0.82 86.29
NOV 720
OEC 730
1969 AVG. 6617*
261 283 274 436 4ta
35 2660 PASO 6.3 7261
9763
mm
41 4500 4500
6.7 6761 -
10445
--
30 36472* 36472'* 7.1 7655 -
10797
-
--
0.95 0.99 87.3* 86.91
54.0
22.0 1.01
83.87
720 "721
278 "253 489 447
-
7344* -- "570
440
-
61 2680 2680 6.0
6953
-
59 4500 4500
6.3 7491
59 43512* '43512* 6.2
8342
1092E 10995 10356.
---
---
0.99 1.07 6&J1 31M
15.0
7.7 0.97 84.04
FORM NO.45A 210-5
SL 013081
REFR 1 GERATEU bHH\it
Temp. F
Warm (Out) Colo (in!
PPG INDUSTRIES CHEMICAL. DIVISION
of Hfcj,
' LAKE CHARLES, LOUISIANA
PERCHLORETHYLENE-TRICHLORETHYLENE DEPARTMENT OPERATIONS REPORT
c to prot ciai
too. 91-
1968 Avg.
11 6
JAN
4_ 0
FEB
2 -1
MAR
3 5
APR MAY
9 11 44
JUNE
9 3
JULY
16 10
AUG
6 0
SEP OCT NOV
.15 25
22
9 19 "T5
*L'
OEC
23 18
r,
1969 Avg. 12 7
DRYING STILL
Temp. F
Bottom
Top
Bottom Pressure
psig
i?i i-i,?
191 163 1.42
190 161
1.39
187 188 158 157 1.43 0.97
191 161
0.94
15T L~wr 195 186
"157" 162" 160 153
0791 0.97 XIT 1.48
201 173 1.59
197 205 170 174 1.23 1.07
193 163 1.22
PER-TR1
Feed Reflux Bottom Temp. Overhead Temp.
STILL
gpm .
gpm
F F
23. 4 32.4 282
182
24.1 27.2 272'
176
34.3 36.3
279 176
34.4 35.0 32.8 30.4
275 277
173 177
32.8 27.5 274
177
31.4 28.8
~275 178
2ft 21 ,L
272
177
27.8 21, t O
271
177
30.5 23.7 265
171
31.9 26.1
284 191
33.0 34.6 268
184
30.0 33.6 292
191
33.6 28.9 277 179
HEAVIES STILL
Feed Reflux Bottom Temp.
Overhead Temp.
gpm gpm
F F.
11.9
127.6 340
253
10.7 1475 108. ( 115.0 340 340 247 247
14.0 15.lt 17.3 112.0 109.0 95.0
338 336 340
244 "246 247
14.9 83.0
339 247
14.0 12.8 75.0 86.5
333 340 248 248
13.0
94 340 242
12.1
An
340
257
12.4
341 '256'
13.1 in/.
341 268
13.6
qA n ~wr
250
Feeo
PER STILL
Reflux
Recycle
To Wash Column Bottom Temp.
Overhead Temp.
gpm 11.78. ll.Of 30.43 10.40 11.44 30.5
gpm .18.61 15.69 14.16 13.70 16.04 16.0
gpm 1Q.246. 0.304 0.948 1.100 0.889 0.6
gpm 111.61 10.36 9.58
F 280 282
282
9.20 10.83 10.0 282 175 273
F 212___ 237
235 234 227'..... 231
TRI- STILL
Feed Reflux Bottoms Recycle Bottom Temp. Overhead Temp.
gpm 10.98 12.91 gpm 62^ia_ 61.62 gpm 8.25 1572 gpm 1*709 T.936 F 228 22J
F 138 HO
A__________________ w_______________
20.26 20.00 60.92 59.70 15.0 15.0
2.307 2.400
222 "220
130 127'
20.75 18.6 60.27 61.7 15.9 15.2 2.126 --
222...1 222
337"" 134
iWk
'W
9.1 15.8
0.17 9.6
"273
234
8.9 8.3 15.6 14.3 0.2 1.7 9.1 9.0
274 273
235 133
8.5 15.4 1.6
15.4
"267 222
15.2 1.5 .
8.9 283 231
18.2 60.0 14.4 -.
221
130"
H75" 15.1 lO" 19.1
"67.0 67.3 66.2 6l 12.6 12.5 12.6
270-- 2.2 179
` 224 123-- 219 23I
136 U2-- 123 154
--
9.65
14:5 13.6 15.00
2.0 0.5" 0.984'
9.7 10.T 10716" 279 137 277 239 155" 234 "
-
19.4 17.5
55.0 53 14.9 13.2 1.73 1.80
227 231 134 156
16.39 61.14 13.6
2.044 224 135
FORM N0.45A 2IO-6 ;
TRI TOPPING STILL
Bottom Temp. Overhead Temp,
F <>F
PPG IN^''STRIES
'
CHEMk.
(VISION
CAKE CHARIES, LOUISIANA
'
'
PERCHLORETHYLENE-TRICHLORETHYLENE department operations report
1968 Avg.
190 187
JAN
186 182
FEB MAR
188 15S 183 l8l
APR
189 184
MAY
188 184
JUNE JULY
189 189 185 185
AUG
IBS 184
SEP
179
OCT
201 197
NOV
195 190
OEC
202
198
1969
Avg.
190 186
NEUTRALIZATION
Perchlor nh3
FLOW To Stg.
psis spm
9.3 9.55
G
12.6 8.02
9.1 10.6 10.5 10.0 30.7L 10.60 12.43 32.0
10.7
9.4
TL.'Z 10.1
11.1 H7<T
k
13.6 11.5
12.6 10.4
Trichlor
NH3
Flow To Stg.
.
P SI 6 5.3
37S-- 3.9 375--
-- 3.6 ~377
gpm 7.03 9.16 13.03 12.90 13710* 11.9
11.9
*
5.2 5tb-- 3.5 172 10.3 10.2 12.9 13.0
TTTff 14.5 11.5 11.5 6.6 10.36
2.0 3.9
3.8
12.7 11.8 11.91
SL 013082
CO* FTDfi***
--order
Sub" ect
of 141 h
,-prut
.eial )15 v-6 * nt
ti 3*
.r1i'TJl*--
Col rt
*
