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wWlIS gC eoOnNsShIN y FFIINNAALL RREEPPOORRTT RWRooggeerr G. G. Perkins, Perkins, PhO PhD TT83Mouox1xi1iccdooilnloogggyy22SS0e-er2rvv6iic0ce2ess SBtu.ildPianugl, 2W2N0-2E$5-01244-1000 St. Paul, MN 55144-1000 HHAWII NNuummbbeerr:: 0011110044119388 SSaammpplele:: TT--55229988 Study Title: Study Title: PPrriim Smtaaurrdyyy EEoyyfee 1II-rr5rr2iti9at8taitoiinno/nRC/aCobobrrrirotosssiioonn Study(OoEfCDT-G5u2i9d8eliinneRs)abbits (OECD Guidelines) SSiiggnneedd:: Nore S WN SStteevveenn MM. . GGllaazzaa Study Director Study Director Acute Toxicology Acute Toxicology Ne. Ae 0 ASA Daattee Phone 608-241-4471 22778877..00000011 Fax 608-Z4 ~-7227 I EEx2;;h7i8i81b7~iitt ) W_UNO1241251 3M MN01241251 WWIIS SC COONNSSIIN N + ESE HHWW]I NNuummbebre:r" 0011110044119988 SSaammppllee:- TT1--55229088 Acute Tosicoloay Acute Toxicoloqy Steven 1. Glaza Steven M. Glaza SSStetuucddtyyionDDiirSreeucpctetoorrvrisor Section Supervisor SSSttteeuvvdeeynnCo8R.o. rdSSioonrraeetnnossoronn Study Coordinator PGParatotruripicciiLaaeadPpeaarddgghhaimm Group Leader SRShehaparoreernnt CL1.o. orHHdooivwneearrtyyor Report Coordinator RS PPaaggee 22 Ke peRsoEL KEY PERSONNEL sborstory Animal Veterinarian Laboratory Animal Veterinarian Cindy 3, Cary, ow Cindy J. Cary, DVM DDiipplloommaattee,, AACCLLAAMM contents CONTENTS key personnel 2 Key Personnel Bettie g Objective Sa aterian 3 Test Material Toit Site 3 Test System Peaesiees : Procedures Summary of Results : Summary of Results BiEeersion S Discussion Soterences 5 References Raw Data Appendix IH Raw Data Appendix PPaagqee 2 3 3 3 4 6 9 9 10 22778877..00000022 Uniled Kingdom S_uNor241252 3M MN01241252 WISSoNS IN Wl Nanbers 01108158 HWI Number: 01104198 SSaammpplele:' TT--55229988 Page 3 onsecrive OBJECTIVE Tne objective of this study as to assess the relative level of rritation/ The objective of this study was to assess the relative level of irritation/ Coreen arsctloriToeutdna single exposure of a test material Fa ne ere corrosion produced following a single exposure of a test material to one eye Tone ee of albino rabbits,z TEST TERIAL TEST MATERIAL sent fication Identification The test satel vas fdentified as T6258 wd described 35 an office The test material was identified as T-5298 and described as an off-white Tots liquid. bursty and stp iny Purity and Stability Sponsor assures responsibility for purity and stability determinations Sponsor assumes responsibility for purity and stability determinations reins wnaar' Seat condi rons) (including under test conditions). Storage ang setention Storaqe and Retention Tne test materia) was stored st roon temperaturs, Any unused material will be The test material was stored at room temperature. Any unused material will be ddiissccaarrddeedd aaccccoorrddiinngg ttoo HHaazzlleettoonn W Wiissccoonnssiinn ((HHWWII)) SSttaannddaarrdd OOppeerraattiinngg PPrroocceedduurree ((SsoOpP)).. Safety pescautions Safety Precautions Norsal handling procedures were used according to WHI SOP. Normal handling procedures were used according to HWI SOP. Tact mim Test Animal Test swsren TEgT SYSTEM AAdduulltt aallbbiinnoo rraabbbbiittss,, HHrraa::((NNZIWW))SSPPFF,, wweerree pprrooccuurreedd,, m maaiinnttaaiinneedd iinnddiivviidduuaallllyy iinn Sireun botsin Saobs In' sessersture' ans humiaiey Control 6d. quireers, provided screen-bottom cages in temperature- and humidity-controlled quarters, provided $5653 So water 29 113itom and 5 Seasored mous) of Nigh Fiber Rabbit Chie access to water ad libitum and a measured amount of High Fiber Rabbit Cho~#~ TSSEE, Porina mills, Toco and Revd: for anace ination period of St Teast #5326, Purina Mills, Inc., and held for an acclimation period of at least Tay An huSbanary' and hosing at MHL Comply with standards outiinec in 7 days. Animal husbandry and housing at HWI comply with standards outlined in tthhee ""GGuuiiddee ffoorr tthhee CCaarree aanndd UUssee ooff LLaabboorraattoorryy AAnniimmaallss"".~. IIff vvaarriiaattiioonnss ffrroomm he prescribes environmental cond] ions xisic, hey vere documented and the prescribed environmental conditions existed, they were documented and ConsTiered Uo have no effect on the study outcobe. ho contaminants were considered to have no effect on the study outcome. No contaminants were Scpacted 0 have Seen present in the F464 of nacer Which would have Jmeerfered expected to have been present in the feed or water which would have interfered SER Fretted The vERuTTS of ene shia with or affected the results of the study. 22778877..00000033 awmorzatas 3M MN01241253 2 WisEeONSILN HNI NNuummbbeerr:: 0011110044113988 SSa~mmpplele:: 1T--5522988 PPaaggee 4 wTTewwrooemmacalhleeoseaannndd atoonneeranffedemommaalleeandaaccmccalliiimmnaattateeiddnedaanndiimmuaralilsns,g, wwteheieigghhsitinnuggdyffrrioonmmt2h2e,,5500s22anettooma22n,,5n59e94r4 gga,s, wFtfooeersrret tthhmceeehtoesaareccinccallliiammt aaatdrtaiimonoidnnnoimsppteerrarianiootdddi.o.mnaiTTunhshteaeiningaaenndisim moaddaliulsusr'ni'ngeefyyleeuthssoerwewseserctrueeedinyeexxaadinymmeiinntheepeddrocooseannmduetthrheeemsa.ddnaanyyeOrnbbleaeyfsfoorree wtttheehorossesteemiaadanentiniemmtraiaialflssil edwwaidittbm hhy innnaooinsitmssraaiiglgtninonnuoofmfbueoosrcicnuuglalaanrdsrocdiinoinurjjmuruerrysyflpuoooonrrrdeiiisnrrrgcrieitatienaattrioidoytnneagwwpereorreeceduususeerded.s. . AAOnniinmmlyaallss were identified by animal number and corresponding ear tag. Justiiffiiccaattiioonn for for SSppeecciieess SSeelleeccttiioonn HH biaissstetdoorriuiccpaoalnlllyyi,,ts tthhleeargNNeeewworZZbeeiaatllaannaddndWWhnhioitnteepigaarllbebniintnoeod rraaibrbbibsii.tt iiss tthhee aanniimmaall ooff cchhooiiccee based upon its large orbit and nonpigmented iris. PPRROOCCEEDDUURREESS PPrreeppaarra'attiioonn of of TTeesstt MMaateterriiaall wTTahhsee dtteeetssett rmmmiaanteeterdiriaatlol wbwaeass 6.aa8dd.mmininiisstteerreedd as as rreecceeiivveedd.. was determined to be 6.8. TThhee ppHH ooff tthhee tteesstt m maateterriiaall Ireatnent Treatment vEEaeaccrhhterrdaabbblbioitwterrreecc1ee1idivveeoddf 00t.h.11e nmrLiLghootff etthyheee, uunwndiditihlluuttteehdde tlteeesfsttt mm eayateetersrieiaarlvl inppgllaaccaeseddthiinenttoounttthhreeeated cpecorvoneetnvrrtetorenlod.tl. lloowsTTshheeer oufulippdpmpeaetrorefraainnthaddle lloraowinwgdeehrrttl1hi1eeddnysser, wweelwererieeathseggdeteh.nnettllyyTlehehhfteelelddyeeyesttooggosfeeettrhhvteehinrerg rffoaoabrsrbitIIhtessseecurcoeonnnmtddraeianttoetoedd Unflushed. prevent loss unflushed. of material and then released. The eyes of the rabbits remained RReeaassoonn ffoorr RRoouuttee ooff AAddmmininisisttrraattiioonn HH Oirsiastitozoreir.ci'caallllyy, tthhee ooccuullaarr rroouuttee iiss tthhee rroouuttee ooff cchhooiiccee bbaasseedd oonn tthhee mmeetthhoodd ooff Draize,- OObbsseerrvvaattiioonnss TT9h5hee hottrurereasa,tteeddandeeyyeeDssayswweer7ree aoondbbssee1r4rvveeaddfteffororr toorcecauutllmaaerrntii.rrrriitatattioionn aatt ]1,, 2244,, 4488,, 7722 aanndd 96 hours, and Days 7 and 14 after treatment. AAitnt rtthheeevea77l22i--nhhogouurpr,,ossaainndbdleDDaaycy-o-77rneaaannldd --i11n4j4urrrye.eaaddiinnIggrssr,,itasstooiddoiiunumnwafflsluuogorrreaesdscecdeeiinnandwwaassscouursseeeddd ttoo aaiidd aainccccoroerrdvdieinnagglinttgoo the Draize technique. possible corneal injury. the Draize technique. Irritation was graded and scored 22778877..00000044 I3MM_MMNNO0T1224411225544 : WW isIS c C oO nN sS tIyN WEAN HHWHTI NNuummbbeerr:: 0011110044119988 SSaammppllee:- 1T--55229988 +CORNING irSvcsComune PPaaggee 55 AAinnniitmneaarllvsaslswweerrteehrwwoeeuiigghghoheuedtd jjtuuhssett sbtbueedffyoo.rree tteesstt mmaatteerriiaall aaddmmiinniissttrraattiioonn aanndd aatt wweeeekkllyy intervals throughout the study. TTeerrnmiinnaattiioonn AdALitsctteaerrrm dmeiidnn.aattiioonn ooff tthhee eexxppeerriimmeennttaall pphhaassee,, 2a1l1l aanniimmaallss wweerree eeuutthhaannaattiizzeedd aanndd discarded. SSttaattiissttiiccaall AAnnaallyysseess NNoo ssttaattiissttiiccaall aannaallyyssiiss wwaass ppeerrffoorrmmeedd.. ocation of Raw Data and Final Report Location of Raw Data and Final Report oTTfhhee HHrrIaa.ww ddaattaa aanndd aa ccooppyy ooff tthhee Ffiinnaall rreeppoorrtt wwiillll bbee rreettaaiinneedd iinn tthhee aarrcchhiivveess of HWI. 22778877..00000055 U nit e d Kin g d o m FIX BOB-2&1-722; I3MM_MMNNO0T1224411225555 e WB W ISIS R ECOONi NSSIINN HHWII NNuummbbeerr:: 0011110044119988 Sample: T-5298 Com src rr PPaaggee SumARY OF RESULTS TSTeeossuttrceAA:nniimmaaRlla::zleAAtllobnbiinnRooeseRRaaarbbcbbhiittssPro--dHSuHUrcMratMa:sA:,(R(YNNZISWOnF)dPeSsPREFEKSUaLlTaSmazoo Mi BSaotuerceR:ninaHlaszleRtecoanivReeds:earch16P/r0o5d/u9cts, Inc., Kalamazoo Date Animals Received: 12/05/90 Start ate (In-1ife): 12/27/50 Start Date (In-life): 12/27/90 enc Date (In-Life)s End Date (In-Life): 01/10/31 01/10/91 AAvveerraaggee PPrriinmaarryy EEyyee IIrrrriittaattiioonn SSccoorreess*t OObbssSeeerrrvviaaettsiioonn AAvvseeorrraaegg.ee 2PI1 eroH4iouourhdr S11c555o..000re 37i4272842 hhoHHHooooauruuurrrrr 805477...713073 [b9D6aa5yr4H?o70ur a411..s373 Day 14 0.0 + TGTsThohhcaeesorreaer.aavvvaeefftrrooiaarroggneeaal}lppperrriittimmhnoaaeedrryydannieieeymyeaaellssiirrGdrriiiivvttiiaaddtteiiedoodnn bbyyssccoottrrhheeee nifssumbttehhere number ottfoottaaallnimeeayyeles iirr(3rr)iittaaatttiiooennach of animals (3) at each observation period. Phone 600-241-4471 22778877..00000066 F~x 808-~41-7~27 S_uNor241255 3M MN0124i256 2 MISES LY = WE SURNAINS HHWKI NNuummbbeerr:: 0011110044119988 SSaammppllee:" TT--55229988 + CORNING snSees Samat PPaaggee 77 amieAuNmnumibmbeaerlr SSeexx FF3355113366"% MM FF3355113377u MM FF3355113333~ FF Tae 3 Table I Comes iris Costectiwe Individual Eye Irritation Scores & Cornea g ~ ~ LIrCeis 2Con.junctivae ~ ~ ~ I Hour 0 0 0 0 yIi 22b 1 1 22: 0 0 0 0 EIid 32b 22 11c 0 0 0 0 1Ii 22b 22 I: TewTSScocootrareel r" 1155 1155 1155 24s 24 Hours Mean 15.0 FF3355113366 MM 0 00 00 FF3355113377 MM o0 0 0 00 FF3355113333 FF 00 0 0 00 2 2 i 1 1 88 22~ i 1 22~ 1100 22b 00 r]c 66 a sours 48 Hours Mean 8.0 Boor o8 FF3355113366 "M 00 F3355113377 "M 00 F35133 F 0 oars Cornea 3 ures of ommetty A - Degree of opacity 00 00 00 00 8 0 fn 0 0 22 1I z2 1I I 0 " onContinciiae Iris GC -Oagree of rida D - Basness Degree of iridal 22: I100 22~ 1100 0 2 Mean 7.3 Con.iunctivae D Redness B - Area of involvement irritation E Chemosis F Discharge R LEEarse "Ce: ( (A x BA x 5)+x + ((CCxB x85)) ++x ((DD+5 EE F+ )F) )xx22. b - Blanching. = Clear discharge. ~ Injected iris. ~ No pain response after test material instillation. ~ - Excessive pawing at the treated eye after test material instillation. n~te d Kin ~ d o m Fax 608-241-7227 --_---------------- 3M MN01241257 22778877..00000077 : Niscons Ly WISCONSIN - NE 330' SURELY ( '-.SM~,N HHUWTI NNuummbbeerr:: 0011110044113988 SSaammppllee:: TT-55229988 +CORNING iranSc amar PPaaggee 88 AnAtiunsmimbaealrl Number 3F33555111333676 FF333555111333373 F333555111333687 35133 F35137 F35133 F333555111333765 3F355113337 F35133 F333555111333756 F3355113337 F35133 IndividTTuaaabbllleeEy11e ((ICCroornnitttiianntuuieeoddn)) Scores Individual Eye Irritation Scores sex CB oCronrneB eaa L. IIrriiss conjunctiva RD Con.iunctivae E TToottaall score Sex ~ B C ScorR* 7122 HHoouurrss HnM o o 0 o o0 000 222 111 011C 868 fFMF [002 o 0 00 0 [20I 1 0 o 00 6 MMeeaann a4.77 9H9266ouHrousr.s nM " o o0 o00 0 00 222 I11 0I1C 868 MFF 00oo00 0 0 o 02 o0I 0 60 MMeeaann a4.77 fDaayv?7 HuM 0[0I 00 000 11 10 00 000 222 FM F o 00 o00 o0 0 0o 1 o00 0 0 0 2 HMeeaann 11.33 DDaayy114 HHM 000 000 e 0 o00 0o0 0 00 FM F [0o2 0 o 0 0 0 0 0 0 0 o 0 0 Mean Mean 00..00 CCoorrnneeaa AA8 --- DADereeggarreeeeofooffinoovppoaalccviiettnyyent B Area of involvement IrIriiss CC -- DDeeggTrrreereeitaootffioiinrriiddaall irritation -S+a: C( (lAeaxrBA dixsc5)h+ax r+g(e(.CC xB x55))++x ((OD++5 EE F+FF) )) Xx22. c - Clear discharge. CCoonnjjuunnccttiivvaaee 0D -=- cRReheddennneeosssssis EFF -- DCDihiessmccohhsaairrsggee Phone Un~tel Kingdom Fax 608-241-7227 -- 22778877..00000088 wom 3M MN01241258 ~ 2 WISCONSIN WISCONSIN Wee ~05 ~=,~ 8~ HHWWII NNuummbbeer:r' 0011110044119988 SSaammppllee:" TT--55229088 conn con PPaaggee 99 anime) Animal Ter Number F518 F35135 BEY F35137 Fa F35133 NEG - Ho NEG - No TTaabbllee 22 Sodium Fluorescatn Examination Sodium Fluorescein Examination goseryation perios Observation Period Prem ee eT Preinitiation 72 Hour Day 7 nes wows NEG NEG NEG NEE NE one NEG NEG NEG NEE ME ME NEG NEG NEG stain retention. stain retention. Tarn Day 14 nesNEG neNEG NeNEG : orscussion DISCUSSION The test material, T-5298, when evaluated for its primary eye irritation The test material, T-5298, when evaluated for its primary eye irritation potential in rabbit produced ids] invalvenent and moderace conjunctival potential in rabbits, produced iridal involvement and moderate conjunctival Boration." KIT eye Eai returned to a normal appearance by Day 14 after irritation. All eyes had returned to a normal appearance by Day 14 ater treatment treatment. RereRences REFERENCES 1. "Acute ye Irritation Corrosicn, organisation for EconomicConger on "Acute Eye Irritation/Corrosion," Organisation for Economic Cooperation and Developmen3t Gurded nes for Testing of Cremieals. Section 405 and Development's Guidelines for Testing of Chemicals, Section 405 {adapta Hoy 12, 1561) (adopted May 12, 1981). 2. NIH Publication No. 86.23 (revised 1985) NIH Publication No. 86-23 (revised 1985). 3. Dratze, J. H., "Gye Mucosa," In Appraisal of the Safety of Chemicals in Draize, J. H., "Eye Mucosa," In: Appraisal of the Safety of Chemicals in Foods: Orica ind Fasnetres Oeraal Toxicity. Aisociar on of food and Oey Foods, Drugs and Cosmetics - Dermal Toxicity, Association of Food and Drug O Offffiicciiaallss ooff tthhee UU..SS..,, pppp.. 4499--5500 ((11997755)}. --_-- Phone 608-~41-~471 22778877..00000099 Fa~ 608-24t-7227 ww 3M MN01241259