Document 3QMp86aXpL94xndZEyD6jLKjJ

tt PLAINTIFFS EXHIBIT CAM-86 COL 00477 McCRONE 0001 Juna g l, 1976 Dr. itua Stovart ifcCroiw A ssociate g&BO Boutb MleMgAn Avenue Chicago, a 6063.6 Dear XA, Thio la to oorifira a oopvarsatloa 1 ,hed. w ith Getto (brieger oonoering fu tu re TBM*flAHD datityaka- f ` ta lo fo r eolg&te^EalmaliY Con*nty. To Bare t in * I aafce `dene i f 1, otar bukpp' could send a a t t f le d ire c tly to your la b whioh you would not utalytte u n til we b&d a otanoe to aoreeit an id e n tic a l eatapl* lu tu r laboratory by xrray d ifirn o tio n end' O p tical .niApoaeofflirt I f thfc 'm aterial were found MtoeBtos-ftrea 1by ue we would tfeief&t .you tine O.X* to gp eaaMtde 1 dot} we would oak j^ .to '& M w r d I t , R d * would awrt.Mm alase an now ' tie to tra v e l ta rn aaoattway to .ra ia a g e ; dae in d icated -tSere aspe' no. spt*lena w its tfciff aw B W at aa fa r aa ffe&ene Aatotfiabee l * concerned. beaC o araaiw u fo r uaj and I cew taly $gri*te your w liiingneea to work in tfcla way. B itte e iy ,. JPSile oat G. R. orieger J , . Bfc&o COL 00478 McCK / De c e iv e d COLGATE-PALMOLIVE COM PANY A Dtlaturt Caftralim , RESEARCH AND DEVELOPMENT DEPARTMENT POf Rivtf Raad Pif tutaway, New Jteny 08854 June 22, 1976 M?. Geno K. Grleger MoCrona A ssociates 2620 South Michigan Avenue Chicago, XL 60616 Sear Gena, This Is to confirm our felephcne conversation of yesterday concerning ta lc lo t m atter 6-13 -1*4 fo r oar Jefferso n v ille p la n t. Please run TBM-BAED analysis fo r asbestos on th is sanale, X irf.ii. telephone you a Purchase Order n a tte r to cover coats, Tours tru ly , JPSsls J . P, Blufeo "CMb,} COL 00479 McCRONE 0003 '-'Smtifmtit:ptterliJ,UtffaxMnttaa0imnitnigon-.' 6 3 5 7 3 1? COLGATE-PALMOLIVE COMPANY . A PKtA W A III 6 6 ft^K A W M IW.HODMN STREET, JERSEY CITY, H.S. 073 ATTCNJ8S, 'E.W4BF"_ pure SUP TO jeiffiFcFryT m-j*waoa :[ ' MoCrone Associates ......... .... i ' a fe o South Michigan A v e n u e c"agODj rI.llIianno iSstew60a6r1t6 4 i/(J ^ M niYCH RD. P19CATA7TAY. N J 0BM ORA NO a r * b e l t l l Y C IT Y . tf.J . 07902 R H C trV IK O f T A T I ON !J # r F U R9 ON V* L i. f t W O U H A A T '90 RRCEIVINO S TA T IO N K A N IA 9 C IT Y . K A N . 001 *9 WSCDUHT TERMS 2/10 N/30 . mo 1/ io m o NrtCtsh T w ft SHIPPINGTERIB J npos Ptitlnitim 2 o3 FOHIRIppla*PI. v\(PnrftiyiBHIKm BtW 3 PO'BHltpplntPU(Cclhd) City > - jtANTfWUY SECMt 7/26/TO . ,. . |FTAOB*OVED12A/T3*1C/A7NN6OT BBfcfitTNOTirY ~ 710 C A R LTO N * T , ^ B C * K *L E Y , CA U fF* U 7 IO 00 A W .' ,, NEW Y O R K. N .Y . T9022 ` if* ' ATTN: Rtciivlfle Clark 0 AW AUTHOBIZgO TO 7UB)HI THC AfrH C lgl LUTCD KEftgQH IK AC&QftPAlEf WITHT-HE T2WH0 AHOCOHOmOWS Oft f HE FACE AMD,BACK 0F 7HI9 OBOE*. QUANTITY AMD UNIT SYMBOL NUMBER ' . ' f_ .' PH1CR ' 1 J . " th is - u u ro h a a e o rA e ? is s u e d t o c o v e r t h e fo llo w in g a n a ly s is : (a s re lix 8 4 ) r * t . . . . ^ . ' . v '> "' F : -l.- _ !C D a n s m i5 * i o i i E le c tr o r t, K ia i^ B tip p y .. a n i^ a f lt p t ? * A re a ' 11 ' ; ; r' 1 H le e tr o n 'D if f ija a t io n J ta a ly e ie o n 7 ^ c 's a m i)le s (im iS flB D A 5 . . ' '4 3 0 0 . e a c h S . - - r a y a a iO y a ia 1 .........' . ^ ifa a h . . . . v- V : *:' . , v .' ^ . ' } V .j . . # * " ' *r -. h . .. . ' 3' _' m. . . ' ' f. . * t ...i .. .'s . .. . 4C r > .1 A - > * & X g ? h jp 7 ~ ' : -L ^ & ' ; ' .t . . ". . . : :> . *,- . . " " . Vic NO OR TO P R O T E C T A L L M&TAL PARTS AGAINST CORROSION BV SUITABLE P R O T E C T IV E SEALING. ................... _ .. i-: .i*- .- T"V .'Tv ft n n .i* jrfrT^OF"*'. n it*'?! s ie r s iNYtJrCW * l s t o W - rr M .M M ofIkwr. ^ ... , - ...... ARKPACKAonWii pvfchoKOnbr w n k M i l w nnrrcM bfttm l R^naty.: -- . --------. - i n t s f a U M a <*rM . Hmf/* t>B%n e *in v f 1 ^ * mBHminr'IIta-e ^ > V ^ fc ra f. PAYMBff W U HOT I I MADE AGAINST PRO PDMIA INVOICE. ' . _ HRY6 DNIOAMND m m m i * m h e tu n y h a * by ritpUntoBi 30143SM300 u l f * a * * V: ' vBuBt .<"9 ** *7 JTOSSS ^ W * m E ^ 3 3 B 5 : COL 00480 McCRONE 0004 Invoice no. 10175 10245 10287 10363 Colgate- Palmolive Company MA 6259 ` Pate 31 Mar 76 19 Apr 76 22 Apr 76 14 May 76 Amount 2>000 900,00 600 1 ,0 0 0 tovoioe 10246, 19 Apr 76 1,800 Waltet1 C. MeGrone A ssociates, Inc. COL 00481 McCRONE 0005 recew edam %W Auguert 3, 1976 Mes* Bfany Waeererraa tt>Qr<9M Awoeiat* 2820 Honth iftafeigon Avenue Chicago, t 60l6 E * U r fitu a g r, TM t6 c<*to* pq talephotte camrFefctioii of th la <3nte tfiish rnspeql; to $MAQ- BWtyai of to lo twQwi fro# Cttlgwtg-PalMollvs. % sfjiardfl BteJVth e&aiag. i&b xusab? a paraba eaat nuafcers w tfh JiflMi-. l$& e * me i-Wwi m Jt .f. JtattehtM* or4er ttgqb 6J3737 1 ruarfoor y&oh trUl cover future roquait fe lis iUboifcfcsd lot, tiurftr *&-&ft tw idtlab ws & net tfwpeit tjtfOyt&i. tf -etMP tant ny CtocNptMi'M m ur requast # ro t covsrwi by parafa eAav njjfcjw? fflaHM*'i*fc nt latea* 1 haltera tbatr tbie WJ p te aj*t*u bMS' ynu ' . P&l o c i t t r . a . s r e ig e r J-* Pt Slio COL 00482 McCRONE 0006 COLGATE-PALMOLIVE COMPANY A Dtimwrt Gtrpmtita RESEARCH AND DEVELOPMENT DEPARTMENT 909 R h tr Raid - Plstattwtty, Nttv Jtrtty QiSii August 6, 1976 1fr. Gene OrelgSBr fcCrono A ssociates 830 South Michigan Avenue Chicago, IC 80616 ` . Bear Gene, Enclosed is a ta lc sample coded 0-H fc asbestos analysis by TBJt-SAED, Charges far th is swupiLe should be mdde to Purchase Order #535737. Ihanls: you. ' . JFS:ls J . F. Siwko C H IM COL 00483 COLGATE-PALMOLIVE COMPANY A Ddaitftr* Gr$vttm RESEARCH AND DEVELOPMENT DEPARTMENT 909 Rivtr Read * Piecatamy, New Jtrsty 0U54 m August 11, 1976 i t - Gene Qreiger MbCrone A ssociates i 2820 South Michigan Avenue Chicago, IL 60616 , - Dear Gene, ' This Is to confirm our telephone conversation of August 10 requesting tevu SABI analysis of ta lc lo t 8-6-7. Please charge our blanket purchase order number to th is work. Thanks. JPSils J . P. Slmfco COL 00484 McCRONE 0008 w aiter c. mecrone associates, inc. CONSULTING: ULTRAMICROANALYSIS - MICROSCOPY < SMALL PARTICLE PROBLEMS SOUO-STATE CHEMISTRY SI August 1976 Dr. Joseph Stake, J r. Colgate-Palmolive Company R&D Department - 90 River Road Eiecataway, New Jersey 08854 ' . ' ' . . D ear D r. Stako: . '. Using transmission: electron mloroscopy and selected area electron diffraction, we have analyzed -the sample of tale designated as 8-6-7. We found this talc to be free of asbestiform m inerals, both amphlboles and serpentines. This is an excellent quality talc, that is very platy and with a high percentage offine plates. . Thank you for consulting McCrone Associates. If there are any further questions concerning this report or the data contained therein, please feel free to contact me. . Very truly yours, GRQife ref: 5500 Senior Research Physicist ZBIO SOUTH MICHIGAN AVENUE . CHICAGO, ILLINOIS 50618 . 3tI/U 2-71Q 0 > CABLE: GHEMICRONE COL 00485 McCRONE 0009 w aiter a m ccrone associates, inc, CONSULTING! ULTRAMICROANALYSIS MICROSCOPY > SMALL PARTICLE PROBLEMS SOLID-STATE CHEMISTRY 31 August 1076 Dr. Joseph Simko FOoIgate-FalmoIive Company #R&D Department I JJ009 River Road 'i^gPlseataway, New Jersey 08854 ,r D r. Slmkot sing transm ission electron micros copy and selected area electron .diffraction, we have examined a Bample designated by Code O-H. ^ T M s Bample was completely tree from asbesttfonn m aterials, both fjam phibole and serpentine. The m aterial was platy and showed a moderate If level of fine particles, hi general, therefore, it was an excellent sample of talc. - If thfere should be any questions regarding these results, please feel free to contact us. Very truly yours, Q ^ ^ . Q U j y ' GdpeB. Grieger ^ U Senior Research Physicist GRG:fe ref: 6600 vi 650 SOUTH MICHIGAN AVENUE CHICAGO ILLINOIS 6061$ 312/942-7100 - CAULE? CHEMJCRONE COL 00486 McCRONE 0010 w aiter a mecrone associates, inc, CONSULTING! ULTHAMICROANALYSIS - MICROSCOPY SMALL PARTICLE PROBLEMS SOLID-STATE CHEMISTRY 31 August 1976 Dr. Joseph Blmhn, J r. Colgate-Palmolive Company 009 River Road U s cutaway, New Jersey 08864 - Dear D r, Simla); .. ' Using transmission electron microscopy and selected area electron diffraction, I have analyzed a sample of talc designated as 8-10-12. In this sample we found no amphiboles and no serpentines. We found this sample to be free of all asbestifom m inerals. The sample consisted of a large portion of fines approximately 18-25% moat of which were pltrfy. Thers was a small portion, 5-7%, which was not platy and just general irreg u lar particles which were also thin enough to be transparent to the electron beam. The difference here was that they were not thin sheets with well defined crystalline edges. There was also somewhat less than one percent of talc fibers and shards. . This m aterial seems to be quitegood in general and hotter than the average that we have seen. As I mentioned previously, there was slightly less fines than in Sample 8-6-7 which we analyzed previouslyI Thank you for consulting MoCrone Associates and if you should have any questions concerning these results please contact us. Very truly yours, GBGrfe ref; 5800 ZSSQSOUTH MICHIGAN AVENUE . CHICAGO. ILLINOIS 80616 . 313AM2-71D0 >CABLE: CHEMK5RQNE . COL 00487 McCRONE 0011 w aller a m ucrone associates, inc. COL 00488 M?McCRONE 0012 COL 00489 McCRONE 0013 i w aiter c. m ucrone associates, ine. CONSULTINO: ULTRAMICROANALYSIB MICROSCOPY - SMALL PARTICLE PROBLEMS SOLID-STATE CHEMISTRY 15 September 1976 Dr. Joseph P. Simko, J r. Colgate-Palmolive Company 909 River Road Pisoataway, New Jersey 08854 ' . Dear D r. Slmfco: . Using transmission, electron nrioECfloopy and selected area electron diffraetloni we have analyzed a sample of talo designated as 8-28-89 We found no asbesttfom minerals in this talo. We did, however, find a few extremely fine tale ribbons and particles of rolled talc, of which we teak eleotron photomicrographs, and they axe included with this report. Again we foundthat there was a fairly subetantlal portion of this talo which was fine In nature, less than 5 pm In general The talo constitutes an excellent cosmetic quality talo and is extremely platy. If there are any further questions concerning this report or the data contained therein, please contact me. Yours sincerely, GeaeR. Qrieger Senior Research Physicist GRGife enclosures ref: 6500 0620 SOOTH MICHIGAN AVENUE . CHICAGO, ILLINOIS 03616.312/842-7100 . CABLE: OHEMIDRONE COL 00490 McCRONE 0014 A - 'r w aiter a me crone associates, Inc, COL 00491 McCRONE 0015 COL 00492 McCRQNE 0016 w aiter c, me crone associates, ine. CONSULTING: ULTRAMICROANALYSIS * MICHOSCOPY SMALL PARTICLE PROBLEMS SOLID-STATE CHEMISTRY 5 October 1976 Dr. J. P . Stoke, J r . Colgate-Palmolive Company B&D Department 909 River Road Piscataway, New Jersey 08854 Dear D r. Bimbo: Using transm ission electron mioroeoopy and selected area electron diffraction, we bave analysed two samples of talc. These M o b were designated as 9-8-9 and 9-9-10. These two samples were extremely sim ilar in. that both showed a high percentage of fines, some rolled talc and fine tale ribbons. ' In Sample 9-8-9 we found one approximately 1 p m long which appeared morphologically to be sim ilar to chrysotlle. However, the SA.ED pattern positively eliminated this as a possibility. to Sample 9-9-10 we also found one partitole Which, although sim ilar In size to dbiysotlle, was different morphologically and gave no diffraction pattern. Both samples were platy and with the exception of the two fibers mentioned (one from each sample) there was nothing which remotely resembled chrysotlle o r amphihole. If there are any further questions concerning this report or the data contained therein, please contact me. Very truly yours GKG:e enclosures ref: 5600 * C* Gene R. Gxieger Senior Research Physicist isso s o u t h Mic h ig a n a v e n u e . c iiic a q q . I l l in o is s w . a i2 /B -7 io o . c a b l e : c h e m id r o n e COL 00493 McCRONE 0017 COL 00494 McCRONE 0018 y * * l* * i^tjftfrfilMiiJili'nruiiuripiiii'i f lin c n rfi-WlMWi, *>-*** ** , COL 00495 McCRONE 0019 w aiter c. me crone associates, inc. COL 00496 McCRONE 0020 t . A w aiter c. m ^erone associates, inc. CONSULTING; ULTRAMICROANALYSIB MICROSCOPY SMALL PARTICLE PROBLEMS SOLID-STATE CHEMISTRY 28 October 1976 . Dr. J. P. Simko, J r. ` Colgate-Palmolive Company 909 River Road PiBoataway, New Jersey 08854 . ' Dear Dr. Simko: Using transm ission eleotronmicroscopy and selected area electron diffraction, we have analysed a sample of talc designated as Dot 10-7-8* "Wefound Hus talc to be completely free from ashestiform m inerals. ` There were, however, some talc ribbons and some shards. The particles seem to be generally eqiftaxlal and not as platy as some of toe talc which we have analyzed. This talc generally seemed to be less plaiy than most cosmetic talcs which we have analyzed, and there w ere not as many ftneB in fids m aterial as we have found in some previous samples. ' Thank you for consulting MoCrone Associates, If there are any farther gnestians concerning this report Dr toe data contained herein, please contact me. Yours sincerely, <3RG:fe enei* ref: S500 820 SO T K MICHIGAN AVENUE >CHICAGO. ILLINOIS 60818 312/W 2-7100 CAGLE! CHEMICRONE COL 00497 McCRONE 0021 w aller a me crone associates, inc. COL 00498 McCRONE 0022 ' ' w aiter c. m ucrone associates, ina COL 00499 McCRONE 0023 waiter c, micron associates, ina COL 00500 McCRONE 0024 W alter c. m ucrone associates, inc. ' COL 00501 McCRONE 0025 w aiter c, me crone associates, Inc, COL 00502 ,McCRONE 0026 r MA 6500 *& ' 10-7-8 (5O,G00X) w aiter a m ucrone associates ine. COL 00503 McCRONE 0027 COLGATE-PALMOLIVE COMPANY ADtlmxm Ctrfaatim RESEARCH AND DEVELOPMENT DEPARTMENT 909 Rivir Rea# PiscstAv/ay, Nrtv Jtrsty 0H34 Ncnremfoer 1, 1976 Mr, Gene Qridge? MiCrone A ssociates 2820 South Michigan Avenue Chicago, IL 60616 Dear Gena, Enclosed are th ree ta lc samples fo r EBM-SAED analysis fo r aobestiform m inerals, Please do sample 1*915 f i r s t and as soon as possible. The other two are im portant hut of lower p rio rity . TWO are fin ish ed product ta lc s , both d iffe re n t, and one is a raw m aterial ae follows h9L5 Finished Product 68-130 ' " " Hag Raw m aterial ta lc I w ill phone purchase orders. Only 1*915 may go on our blanket purchase order. Many thanks. S in c e re ly , J . P. Simko, J r . dP8:la Enclosure -42)111*-* COL 00504 McCRONE 0028 -Up w aiter a me crone associates, inc. CONSULTING: ULTRAMICR0ANALYS1S MICROSCOPY SMALL PARTICLE PROBLEMS SOLID-STATE CHEMISTRY 18 November 1976 Dr. J.P Slmko, J r. ` Colgate Palmolive 909 River Road Pieoataway, New Jersey 08864 ' Dear Dr. SLmkot Using transm ission electron miorosoopy and selected area electron diffraction we have analyzed a sample of talc designated as 10- 20 21. We found this m aterial to he free of asbesttform m inerals; the only non - talo that we found was some sodium oblorlde crystals. The transm ission eleotron micrographs and selected area diffraction patterns of these salt crystals are Included with this report. ` Thank you for consulting MoOrcne Associates, Sf there are any further questions concerning this report or the data contained therein, please feel free to contact me. Very truly yours, ` GRGtjd Ref. MA 5500 i i i t\ 1810 SO UTH MICHIGAN AVENUE . CHICAGO. ILLINOIS 6001 . 8127*48-7100 CABLE: CHEUICRONE COL 00505 McCRONE 0029 w aiter c, me crone associates, ine, COL 00506 I McCRONE 0030 ' * w alter c. mecrone associate^ ine, * ...............................r f COL 00507 % MeCRONE 0031 t J. w a ite r a me crone associates, inc. COL 00508 McCRONE 0032 4 V+f*+***" ft I w aiter c, m e crone associates, in a COL 00509 ..McCRONE 0033 -I w aiter c. me crone associates, inc, COL 00510 McCRONE 0034 w aiter c. me crone associates, fnc. CONSULTING: ULTfiAMICflOANALYSiS MICROBOOPY - SMALL PARTICLE PROBLEMS - SOLID-STATE CHEMISTRY 18 November 1976 Dr. J.Po Slrako, Jr. Colgate Palmolive 909 Ktver Road Plseataway, New Jersey 08854 ' Dear Dr. Simian Using transmission electron microscopy and selected area electron diffraction we have analysed a sample of talc designated as 10-20 21. We found this material to be free of aabesttform minerals; the only non - talc that we found was some Bodlnm chloride orystals. The transmission electron micrographs and selected area diffraction patterns of these salt orystalB are inoluded with this report. Thank you for consulting MeCrone Associates. If there are any further questions concerning this report or the data contained therein, please feel free to contact me. Very truly yours, GRGtjd ' Ref. MA 5500 Gene R, Grieger Senior Research Physicist / 020 SOUTH MICHIGAN AVENUE CHICAGO, ILLINOIS 0061B 312/i2*71W . CABLE! CHEMtCRONE COL 00511 McCRONE 0035 n rw w aiter a me crone associates, ine, I A i CONSULTING: ULTRAMICROANALYSIS ' MICROSCOPY SMALL PARTICLE PROBLEMS > SOLID-STATE CHEMISTRY 18 November 1976 Dr. JoP. Simko Colgate Palmolive 900 River Road Piaeataway, New Jersey 08854 - ' Dear Dr. Simkoi . truing transmission eleotron mlorosoopy and selected area diffraction we have examined a sample of tale designated as 4915. In this talc we found one fiber of tremollte approximately 2 micrometers by 1/2 micrometer. Using selected area diffraction and gone analysis to give the angles between spots we positively Identified this as tremollte. We examined a further preparation from this sample and found no other tremollte. This particular fiber would not represent more than a flaw parts per million, less that 8 parts pBr million of asbestlform minerals and certainly may well just be Stray contamination. Thank you for consulting MoCrone. Associates, If there.are any further questions concerning this report or the data contained therein please fe'el free to contact me. ' i , Very truly yours, GRG:jcL Ref. MA 5500 * Gene B. Grieger - Senior Research Physicist . .* ` 2820 SOUTH MICHIGAN AVENUE CHICAGO, ILLINOIS 6 0 6 1 6 .31/842.T100 . CABLE: CHEMICRONE COL 00512 McCRONE 0036 * w aiter a me crone associates, inc, CONSULTING: ULTRAMICflOANALYSlS MICROSCOPY * SMALL PARTICLE PROBLEMS SOLID-STATE CHEMISTRY 18 November 1976 S r. JoPo Simko ' Colgate Palmolive 909 Elver Road Plseataway, New Jersey 08864 ' Dear Dr. Sfmkoi Using transmission electron microscopy and selected area diffractIon we have examined a sample of talc designated as 4916. In this talc we found one fiber of tremollte approximately 2 micrometers by 1 /2 micrometer. Using selected area diffraction and zone analysis to give the angles between spots we positively Identified this as tremollte. We examined a further preparation from this sample and found no other tremollte. This particular fiber would not represent more than a few parts per million, less than 6 t parts per million of asbestiform minerals and oertalzdy may well Just be stray contamination. . Thank you few consulting McCrone Associates, if there are any further questions concerning this report or the data contained therein please feel free to contact me. . Very truly yours. GRGjjd Ref, HA 5600 2820SOUTH MICHIGAN AVENUE . CHICAGO, ILLINOIS S0B16.810/842-7100 . CABLE: CHEMCRONE COL 00513 McCRONE 0037 COL 00514 * McCRONE 0038 :r' waiter c, me crone associates, inc. COL 00515 McCRONE 0039 i!Jin .W'. ./ ORiGINAL PURCHASE ORDER fJsqw this ftim iff ma prpx on in* voitws, itficki*x ilttfm* -- G3 6 1 5 5 W wm , COLGATE-PALMOLIVE COMPA1 & 1 06116 f ) A l BILL T O J* ABKLAWAAXCOftFOAATlOH [/ **^^3 :._105.HUDSD^I S T R E E T , JERSEY C /T O 4 J L 7 3 0 2 AT NTIONj .L__L - x ~ L J... - L J -------------- -- ------ j McOrooe Associates 1 j_ 2820 South M ichigan Avenu I Chic.ago, m in o is 6o6l6 Jfgjyj, ` sa HI YEA RD. f ia c a t a w a y . n .j . o im m O G RAND ST. J E R S E Y C I T Y . N . J . 6 7 8 Z R E C E IV IN G S TA T IO N JeFFERSON Vl LUE. IN D IA N A *7180 R E C E IV IN G S T A T IO N K AN SAS C IT Y . K A N . 66IQB DISCOUNT TERMS 12/10 N/30 1k/o ll/jio H/30 SHIPPING TERM5 1 n POD Dastlnatlon 1 SjFOSiWpptasPI. (ProPa'ri B!ll)Sx Btlmr WANTEDBY ASA? I f above d ate cannot ez met n o t if y 3 ]fR04SF*AKH*tt?AMVEE. fc. M,,, 3 NEW Y O R K . N .Y . 10(1*2 J NbI C n h Trad 3 FOB Shippin{ P t (C alhdl City_______________________ ATTW: RecsWInj Clerk 1 YOUME AUTHORIZED TO FURRIiHTHt ARTICLE LISTED HEREOR IH ACCORDANCE WITHTHE TERMS AND CONDITIONS OK YKE FACE AND HACK OFTHIS ORDER. QUANTITYANDUNIT SYMBOLNUMBER PRICE , II.......... Transmission ^ eo tro n IflcroBcftRr and Selected Area Electron . . ,_. D iffraction Analysis of two Talc *Ftamples lab elle'd as follows: ___ *........... .............. 68-130 _______ _____ '................................................. - j ._. ....___Mag ................ ........... ..................... .. .............: ................... ..... ...... . t ,........... This i s a one time request: _____ _____ __ i.................... .. - -........ " " ................... MOTE: /Samples sent under separate covet to . , ........ Mr. Gene Grieger of MoCrone on 11/1/76 1 ' ( TA X 'EX EM PT 7 $ l V E N D O R T O P R O T E C T A L L M E T A L P A R TS A G A IN ST CCRRC 5N B Y S U IT A B L E P R O T E C T IV E S E A L IN G . ' 3EllEltS INVOICESum Indaif. wfbwtad TrsmperlaHon i l v g ^ m il fasiuppotliU by prtpatd freigit bill Copy of original btO of lading. mark PACKAGES wRh purdun. onbr nimbnv qmtbN nYMb.Hr ttnl.ntt m i tpanSly. Aitepta of Hilt otdw Isle bp Jm iryJ a e*rtiSpafWn fhof voll how n e d and agmid to Um ta rn a id m o i sa Ib* back h W . PAYMENT Yiltt NOT IE MADE AGAINST HO rORMA INVOICE. . RESERVE UNIQAMW m m w H h i* h rJa m fatub by Hhabwflrm. MtldlMMO .OUVB C0M P M Y 4 ' m JERSEY SALES TAX MUST BE'BILLED UNW&S EJfEKPi'ffiD Bi J t v viiA'xfJ.CJYTE COL 00516 McCRONE 0040 w aiter c. mecrone associates, iric; ' ! ' Tr CONSULTING; ULTRAMJOROANALYSIS MICROSCOPY- SMALL PARTICLE PROBLEMS SOLID-STATE CHEMISTRY 2 December 1976 Dr Joseph P. Simko, J r. Colgate-Palmolive Company 909 River Road Piscaiaway, New Jersey 08864 ' ' ' Dear Dr. Simko: -' i Using transmission electron microscopy and. selected area electron diffraction, we have examined two samples of talo which were shipped to ns as special lots. These talos were designated as MAG 11-1-76 and 88-100, dated 11/1/76. ; j The first set of these two talcs, MAG 11/1/76, was an excellent example of talc. It was extremely platy, had an excellent particle size distribution and no asbesttform minerals. We did, however, find some slight traces of bodium chloride in this material, but that was the only extraneous material which we oould find in fids sample. The second sample, 68-130 dated 11/1/76, showed some rolled talo, talo ribbons, talc fibers and an extremely high percentage of fines, but other- wise was extremely platy and again did not show any asbestiform minerals, nor was there any platy antigorite. This did not look as good a sample of talo as the MAG 11-1-76 sample in that it had a lot of fiberB, even though they were talo. ' = ! . - f j . Thank yon for consulting MoOrone Associates. If there are any furfiier questions concerning this report or file data contained herein, please feel free to contact ua. Tours sincerely, GRG;fe ref: 6500 - P.O. 686166 GenB R. Grieger Senior Researoh Physicist I S SOUTH MICHIGAN AVENUE CHICAGO. ILLINOIS 60818.312/842.7100 . CABLE; OHEMICHONE COL 00517 McCRONE 0041 COL 00518 McCRONE 0042 -- y* * COL 00519 McCRONE 0043 COLGATE-PALMOLIVE COMPANY A ThUn&tn RESEARCH AND DEVELOPMENT DEPARTMENT 909 R itir Read * Piseataway, Nttv Jtrtty 0SSJ4 Becenber Yj 3-976 Gone Grieger IfcSrcne Associates S8eO South MLchigen Avenue Chicago, E. 60616 _ ` Beer Gene, Enclosed is a ta lc ewnple labeled ABE. Please do T0M and SAKE on i t . Charge to our blanket purchase order. Thanhs. JPflils Enclosure J . P . Sinkt COL 00520 McCRONE 0044 w aiter c. mccrone associates, Inc, CONSULTING: ULTRAMICROANALYSIS < MICROSCOPY SM AU . PARTICLE PROBLEMS SOLID-STATE CHEMISTRY 3 January 1977 j i Dr. Joseph P. FHmkn, J r, Colgate-Palmolive Company ' 909 Silver Road Plsoataway, New Jersey 08854 Dear Dr. Simla); Using transmission electron, microscopy and selected area electron diffraction, we have analysed a sample of talc Identified as talc ABE and dated 12/6/76. We found this talc to he com pletely free of ashestlform minerals. We did, however, find that it had a few fine tala ribbons and some tale fibers. We also found this to he fairly low to moderate in fines and not as platy as the sample designated as MAG which we previously analysed. Thank you for consulting McCxonAssociates and if there axe any further questions concerning this report o r the data contained herein, please feel free to contact me. ` Very truly yours, Gene R, Grleger Senior Research Physicist GRGtfe enol. reft 5500 2 0 SOUTH MICHIGAN AVENUE - CHICAGO. ILLINOIS H 6tS 312/W2-710Q CABLE: CKEMIC80NE COL 00521 McCRONE 0045 w aiter c. m ucrone associates, in e COL 00522 McCRONE 0046  Walter c. m ccrone associates, Inc. CONSULTING: ULTRAMICROANALYSIS MICROSCOPY SMALL PARTICLE PROBLEMS SOLID-STATE CHEMISTRY 17 January 1977 Dr. Joseph P. Slmko Colgate-Palmolive , 909 BLver Hoad PiBcataway, New Jersey 08894 . Dear Dr. Slmko* . Using transmission electron microscopy and selected area electron diffraction we have analyzed your latest sample of tala designated as Lot 1-5-9. The date on this sample was erroneously given as l-S-76 .and should be 1-5-77. In this talo we found no Indication of asbejsfciform minerale. This talc is extremely platy, and In general better than the average tala which we have seen from this supplier. Beoause of its platlness we find some fine talo ribbons and floe rolled tala fibers which appear Inevitabile on grinding such platy material, Thank you for consulting MoCrone Associates. If there are any further questions concerning this report or the data contained therein, please feel free to contact me. ' -. Vary truly yours, GRGiJd . Kef. MA 5500 GeneR, Grleger Senior Research Physicist saao s o u t h M ic h ig a n a v e n u e . c h iq a g q , I l l in o is b o b ib . 3 i i/ e 4 e - 7 i o o . c a b l e .- c He m ic r o n e i ._i COL 00523 McCRONE 0047 w aiter c. m ccrone associates, Inc. OONSULTINQ; ULTRAMICROANALYSIS MICROSCOPY SHALL PARTICLE PROBLEMS SOUO-BTATE CHEMISTRY 21 January 1977 M r. J. P. SJmko, Jr. Colgate-Palmolive Company 909 River Road Plscataway, New Jersey 08854 ' Dear Mr. S im fc o : - We have completed our determination of fee asbestos content of fee talc samples which you submitted to us {Talc ABE), using the techniques of x-ray diffraotton and light microscopy. The results are given in fee attached sheet and fee x-ray diffraotton pattern. If there should be any questions concerning these results please contact us. Tours sinoeraly, Ralph J. Hinoh, Jr. Research Chemist RJH.-fe attach. ref* 6600 - V. 2 m SOUTH MICHIGANAVENUE * CHICAGO, ILLINOIS 60S16*16/612-71W CABLE ChEMICITONE COL 00524 McCRONE 0048 Pate g I ? j LQT? Client C a i & 'f 'a ~ P a l tu. e>11V e _________ MA Project, j T ^ O . ' Sample D escription T ol} g, X-RAY DIFFRACTION . Serpentine Content 7? o y i'G . d & Amphibole Content y i OY\.& / b T ^ c / es/ Commente ! P r ^ S ^ / i a t n / a H t / ' / e t ____________ ^ o l - S t O - ^ . __________________ LIGHT MICROSCOPY Serpentine Content Amphibole Content. wowC. gW dt A Commente____U t ^ o A o lo v d rg . A - U lf f , o -tjp U - IA O , . wetter . m'ccrone associates, Inc COL 00525 McCRONE 0049 9ZS00100 COL 00527 McCRONE 0051 COL 00528 COL 00529 McCRONE 0053 Q COL 00530 McCRQNE 0054 COL 00531 McCRONE 0055 sstmMS&m, ^ S IV E D F lB o s m COLGATE-PALMOLIVE COMPANY A "Dtimvm Cofwtf RESEARCH AND DEVELOPMENT DEPARTMENT 9Q9 R istr R tad Phtttavwy, Ntw Jirsty 0SS4 l'ehruary 1, 1977 Mr. Gana S ie g e r McCrone Aueoalntes 2820 South Michigan Avenue dbioago, IL 60616 Dear Gene, Enclosed i s a saiqple of ta la labeled 4156. Please do EEM-SAED analysis fear asbestos minerals. Change to our open purchase. order number. Thanks. 1 i i ! JPBtls Enclosure <T. P. Simfco I COL 00532 McCRONE 0056 w aiter a me crone associates ina CONSULTING: ULTRAMICROANALYEIS * MICROSCOPY SMALL PARTICLE PROBLEMS ' SOLID-STATE CHEMISTRY 10 February 1977 Dr, Joseph F, Shako Colgate Palmolive Company 909 Blver Hoad . Fisoataway, New Jersey 08854 ' Dear Dr. -Slmfcbt Using transmission electron mlorosoopy and aeleoted area electron diffraction we have analysed a talc designated as lot 1-.21-22 from the 1677 series. We found no aefoeBtlform minerals In this talc and the tadc was not extremely plaiy. What plates there were, were rather thick. We did find some shards, some sodium chloride, and a moderate . to high level of fine s. Thank you for consulting MoCrone Aeacolatea. If there are any farther questions concerning this report, please contact me. Very truly yours, GBGjjd Bef, MA 5500 ' ' GeneH. Grleger . Senior Besearch Scientist ' 2320SOUTH MICHIGAN AVENUE . CHICAGO, ILLINOIS 30S1B . 312/342-7100 .CABLE: CHBVltGHONE COL 00533 McCRONE 0057 jp -e - w alter a mecrone associates, Inc. CONSULTING: ULTFAMICROANALYSlS MICROSCOPY * SMALL PARTICLE PROBLEMS SOLID-STATE CHEMISTRY U February 1977 Dr. Joseph P. Simko, Jr.Colgate-Palmolive Company 909 River Road Fiscataway, New Jersey 08864 . Dear Dr, Stmkoi ' Using transmission electron microscopy and selected area eleoton difEraotion* we have analyzed a sample of talc designated by the number 4165. In this talc we found no asbesttform minerals. The plates which we found were rather thick and tire material was not very platy. There were some shards and moderate to high fines. We did find three fibers in this sample. Two of these were organio and did not diffract. The third was quite obviously not ohrysotlie but did give a weak ring pattern consisting of one ring whioh could not be positively identified, ' Thank you for consulting McCrone Associates and if yon should have any questions concerning these results, please oontact us, ,, Sincerely, GRG:fe. refi SS00 ZttO SOUTH MICHIGAN AVENUE >CHICAGO, ILLINOIS 6 0 8 1 6 .31S/B4S-7100 CABLE- QHEMICRONE COL 00534 McCRONE 0058 COL 00535 McCRONE 0059 COL 00536 McCRONE 0060 w aiter c, mo crone associates; in a COL 00537 McCRONE 0061 COL 00538 McCRONE 0062 .............. ................ . A V' w aiter c. me crone associates, inc. CONSULTING: ULTRAMICROANALYSIS MICROSCOPY SMALL PARTICLE PROBLEMS SOLID-STATE CHEMISTRY 12 August 1977 D r. Joseph P. Stmko Colgate-PainolIve Company 909 Elver Road Piscataway, New Jersey 08864 Dear Dr. Slmfeoi Using transmission electron microscopy and selected area electron diffraction, we have analyzed a sample of talc designated as Lot 7-24-26 from die 1077 series. Morphologically, this wan a poor qualify talc in. that it seemed to have a lot of fibrous material in it. However, nano of this fibrous material was an ashestiform mineral, bat was talo fibers, rolled talc, talc shards and talo ribbons. The percentage of fines present were moderate to high with some plafy talo, but mostly small equjaxial parttoles in the 2 to a range. ' Thank you for consulting McCrone Associates and if you should have any further questions concerning these results, please oontaot us. Very truly yours GeneR. Grioger Senior Research Physicist GRGife enol. reft 6600 2620SOUTH MICHIGAN AVENUE CHICAGO, ILLINOIS 60S16 . S1Z/B42-7100 CABLE: CKEMICRONE COL 00539 McCRONE 0063 COL 00540 McCRONE 0064 4 COL 00541 McCRONE 0065 r m w aiter c. mecrone associates, inc. m CONSULTING: ULTRAMIOROANALYSIB MICROSCOPY < SMALL PARTICLE PROBLEMS SOLID-STATE OHEMISTRY 8 March 1977 D r. Joseph P. Simko, J r. Colgate-Palmolive Company 609 Stiver Hoad Plscat&way, New Jersey 08864 . Dear Dr. Simko: . Uaihg transmission electron microscopy and selected area electron diffraction, we have analysed a sample of talc designated as Lot 2-10-11 of the 1677 series. In this sample we fonnd moderate ' fines, somewhat ihioker plates and also a fine inorganio m aterial which was too widely dispersed to allow for electron dtttraction. identification of, but is believed to be NaCl. ,We did not find any . - asbestifoxm m inerals in this sample. - Thank you for consulting McCrone Associates. If there a re any further questions concerning this report please fe d free to contact me. Very truly yours, ` Gene R. Grieger Senior Research Physicist ' GRGtfe ref: 5600 2820 SOUTH MlQHIGAN AVENUE,. CHICAGO, ILLINOIS 00618 3l2 /S -7 10 0 , CABLE: OHEMKRONE COL 00542 McCRONE 0066 w aiter a m ccrone associates, ine. CONSULTING; ULTRAM ICR0ANALY6IB MICROSCOPY SHALL PARTICLE PROBLEMS SOLID-STATE CHEMISTRY 10 March 1077 D r. Joseph P, Shnko, J r. Colgate-Palmolive Company 909 Blver Road H a cataway New Jersey 08854 Dear Dr. Slmko: . Using transmis eden electron microscopy and selected,area electron diffraction.) we have analyzed a sample designated as Lot no. 2-22-28 from &e 1077 series, in this talo we found no asbeatlform minerals The tale seemed to have moderate to high levels of fines and the plates were a little hit on file thick side. We also fonnd a few ribbons and shards, but,-.'from their diffraction pattern, these were undoubtedly talo. If there should be any further questions please feel free to contact me. ` Very truly yours, GRG:fe ref: 6500 * Gene B. Grieger Senior Research Physicist .; i ' 020s o u t h M ic h ig a n a y e n u e c h io a e , il u n o is e i e - s i / m -t io t . b l e c h e m ic r o n e COL 00543 McCRONE 0067 I * * - " TO w aiter a m ccrone associates, inc, CONSULTING: ULTRAM1CROANALY6IS MICROSCOPY SMALL PARTICLE PROBLEMS - SOLID-STATE CHEMISTRY IS April 1977 D r, Joseph P. Simko, J r. Colgate-Palmolive Company 909 River Road Plscataway, Mew Jersey 08854 Dear Dr. Simko: Using transm ission electron microscopy and selected area electron diffraction, we have analyzed a sample of talc designated as Lot , S-31-4-1, and found no asbestiform minerals In this sample. Although the talc did Include a high percentage of fines and same shards, It was extremely platy but did not show large thin plates. Instead, small alm ost round equaadal particles were the predominant talc form present. If there are any farther questions oonoernlng tide report or the data contained herein,' please contact me. . Very truly yours, Gene R. Grieger Senior Research Physicist GRGfe ref: 6500 5520 SOUTH MICHIGAN AVENUE . CHICAGO, ILLINOIS G061B E15/B12-7100 CABLE: OHEMIORONE COL 00544 McCRONE 0068 w aiter c. m ucrone associates, inc. /- * CONSULTING: ULTflAMICROANALYSIS MICROSCOPY SMALL PARTICLE PROBLEMS * SOLID-STATE CHEMISTRY 12 Jhly 1977 Dr. Joseph Simko Colgate-Palmolive 809 Hiver Hoad Pisoatuway, New Jersey 08864 . Dear Dr. Slmko: Using transmission electron microscopy and selected area electron diffraction we have analyzed a sample of talc designated as M O N 8, 040> dated 6/18/77. lia tins sample we find no aebesttform m inerals. The particles gen erally seem to be equbdal with moderate fines. Some of the m aterial ` is platy and there Is a fine fiber whloh may be organic in nature. This fiber Is very sim ilar to a ribbon. This Is not bacterial debris. Thank you for consulting MoCroneAssociates and If there are any further questions concerning this report, or the data contained therein, pleaae feel free to oontact me. . Very truly yours, GRG:jd R6f. MA 6500 Gene R. Grioger Senior Research Physicist 9820 SOUTH MICHIGAN AVENUE . CHICAGO. ILLINOIS 6081B 312/845-7100 . CAGLE: CHEM10RONE COL 00545 McCRONE 0069 w aiter c, me crone associates, inc, CONSULTING; ULTRAMlCROANALYSIS MICROSCOPY SMALL PARTICLE PROBLEMS SOLID-STATE CHEMISTRY IS October 1977 Dr. Joseph P. Simko, J r. Colgate-Palmolive Company 909 River Road Piscataway, New Jersey 0B854 . Dear Dr. Simkoj I Using transmission electron microsoopy and selected area electron diffraction, we have analyzed a sample of talc designated as Lot 9-21-02 from the 1977 series. We did not find any ashesflfonn m inerals in this sample. We did find however, that there were moderate fines with some of the talc platy end a rather high percentage of sodium chloride in tbie sample. This same sample was also analyzed by x-ray diffraction and in it we again found no asbestiform minerals. We did find, however, that ` there was present chlorite and some alpha silicon dioxide (quartz). Thanh you for consulting McCrome Associates and If you should have any questions oonierning fids analysis, please contact me. Sincerely, Gene R. Grieger Senior Research Physicist .GRGsfe reft 5500 2820 SOUTH MICHIGAN AVENUE CHICAGO, ILLINOIS 60516.312/542-7100 . CABLE: CHEMICRONE COL 00546 McCRONE 0070 ' Date_ Q - h n k * t v 1077 Client4 & fjaf - .Pa/H Ok U ________ _M A Project -S's'ta Sample Description M r fi. JZ b . h elm (Mj A P b -1 . - a f Q -2./-21.. X-BAY DIFFRACTION Serpentine Centent-w p ^ jd ttc & t# Amphibole Content y , ) , j Comments_ P r 'g . ,ry> v/-2-- e . /a jii`Y-tt IJQBT MICROSCOPY Serpentine Content Amphibole Content Comments_______ waiter a mucrone associate^ ina COL 00547 McCRONE 0071 COL 00548 COLGATE-PALMOLIVE COMPANY A D lbtm i CwfmtUh RESEARCH AND DEVELOPMENT DEPARTMENT 9Q9 River RotttI Piieataieay, New Jersey 0SI54 <ioi / j i s - '/ t / 'i * November T, 1977 Mr, Gene Grleger HcCrone A ssociates 2820 Bouth Michigan Arenue Chicago, XL 606x6 L ear Gene: I'm enclosing two camples of ta lo for o p tical microscope examination. We^re not certain about the composition fo r th e following reasons: (a ) w e bos a p o s s ib le w eak a a p h lb o le l in e by je-ray a t 20 n 10.'55 a n d l i n e s a t 29 10V35 a n d 10/ 75 l a s a m p l e 1615. b u t n o n e o f t h e s e i n t h e F r e n c h T a l c . tb`) dispersion stalp in g shows proper colors from trem ollte in both cases bub th e morphology I s n 't rig h t. We vant' to know more about what these m a te ria list might be. Charge our open purchase order number fo r th is work. S in c e re ly 1 . - ' JF S :ls Enclosure J . F. Simko, J r 1 <1B107- COL 00549 McCRONE 0073 waiter c. mecrone associates, inc. ' CONSULTING; ULTFtAMICnOANALYSIS . MIOROSCOPY SMALL PARTICLE PROBLEMS . SOLID-STATE CHEMISTHY 15 November 1977 D r. Joseph P . Simko Colgate-Palmolive R & D Department 909 River Road Piscaiaway* New Jersey 09854 - Dear Dr, SLrnko: I have completed -the analysis of your sample bearing the designation: MTRTalo-Code M-0670-2, Lot No.-10-86-77, 10-87-77, presMpmeht sample, forl'the determination of file asbBsUform m aterial oontent. H tls specimen was found to consist, prim arily, of platy tala ranging from sm all to moderately large (>10 pm) sizes. Tale shards, talo ribbons, infrequent uneven fibrous aspect nonasbestlfom sioate,m aterial and occasional chunfey inorganic particles are to be noted in fids sample. This electron microscopical examination did not reveal the presence of asbesfifoxm m aterial in the sample. Thanh yon for consulting us once again. If any questions should arise concerning this analysis* please do not hesitate to oontaot me directly. Sincerely, BJSijd Ref. MA 5500 . Richard J . Stamps Research Chemist 2820 SOUTH MICHIGAN AVENUE CHICAGO, ILLINOIS 80616 312/8+2-7100 . CABLE: OHEMICRCNE COL 00550 McCRONE 0074 waiter g mucrone associates, inc. - CONSULTINO: ULTflAMlCROANALYSIS . MICROSCOPY SMALL PAHUCLE PROBLEMS SOLID-STATE CHEMISTRY 16 November 1977 D r. J . P. Shako, J r . Colgate-Palmolive Company 909 River Road . Placataway, Mew Jersey 08854 .. ' ' Dear Dr. Slmko: ' .. Tide letter confirma the telephoned results of our microscopical examination of your two samples, French. Talo - Lot 5654-11/3 and Tale 1615-Lab #4811-11/3. .. /. :Jo a had noted in your letter of November'7 .that both pamples contain , .: s partidles which show the right microscopical dispersion staining oolors " ' , fo r trem olite but die wring morphology. We have Identified these ' . partidles as apatite. . . ; -, .. , . *' '\ ' I v t .t . ...We also found small amount of trem olite in Talc 1615 but none in ' -. - ' . the French, talc. TMs is consistent with your XRD results. The other . ' m inerals identified are noted on the nolosed laboratory report sheets. . ,' If you have any questions please le t me know. ' . " With beet wishes, '' . ' . ' -Sincerely, .L B M s fe ' end. ref: 6500 J Lucy B. MoCrohe Senior Research Scientist - '' e s SOUTH MICHIGAN AVENUE. CHICAGO, ILLINOIS 6061B. S1/44-71Q 0 CABLE: CHEMIRONE COL 00551 McCRONE 0075 . Date 9 N o v s tib tf t<?77 Citent COLGATE-PALM0UV qH P /W Y MA Project 5 5 0 0 Sample DescgtptLon TA } JjOT SS54- l / _____________ x -ray d iffr a c tio n Serpentine content . .. I _______ ' AmpHbole content_________________ Cotnmente________________ ___________ _______________________ . ' ' I. I ' . .... . LIGHT MTCROSCOPY ' ' Serpentine Content M iti, d ti, . Amphibole Content s U&h. c h u h d Commenta p k -k . j r q a s J j *a c . U td a o h th A jl ju , H t- ____ y tu . mm/ 1 0 & /& . U ^ ie tf&OM, LU T d c. )& ($,_______ ' ____________ ____ y ? / j f c Q h tH t. watter - mccrone assoctatea inc. COL 00552 McCRONE 0076 Date 9 A fo vm & se J 9 7 7 Client: Q pL & A Tg- 7 >A L M 0i.itfg` QoM PAW _________ _MA Prefect $ 5 0 0 Sample Description 7Jl& IfaW ] $ $ & [/, tt/s _____________ ______ X-BAY DIFFRACTION Serpentine Content__ ______________ Amphibole Content Cotaments 1 ______________ LIGHT MICROSCOPY Serpentine Content hiiftf i i t e i u L Amphibole Content ir tm ilh M d td Comments A g p u M f a a a d .. U f& U w d . tu tltJ c f ^ A tj te d /tU te s& M & u H k - S a c f f i L u u ffiJ c ! 4 l . 'fats faf O W , 4 n k oajl a M L jim fz d * J d s ito r iL . t^ e a . h (A & 4 * t waiter c, mccrone associates, ina McCRONE 0077 COL 00553 r4 waiter ame crone associates, inc. CONSULTING: ULTRAMICROANALYGIS MICROSCOPY . SMALL PARTICLE PROBLEMS SOUO-STATHCHEMISTRV 5 January 1978 Hr, Joseph P. Simko, J r. Colgate-Palmolive Company 909 River Hoad Pis cutaway, N ew J e r s e y 08854 . . Dear D r. Simkos . Using transmission electron microscopy and selected area electron diffraction, we have analyzed a sample of pre-shipment talo designated as Lot 11-27-28 of the 1977 series. In this sample we found no asbesttfoxm m inerals. ha this sample we found moderate levels of fines and the sample again indicated predominantly equiaxial partiles which, were not extremely platy with, some indication of shards. Some sodium chloride was also present. The sample, however, did not exhibit any fibers that we could detect. . Thank you for consulting McCrone Associates and if you should have ' any further questions concerning M s analysis please contact me. Sincerely, Gene R. Grieger Senior Research Physicist GRG:fe reft 5500 asso SOUTH MICHIGAN AVENUE CHICAGO, ILLINOIS 80616.312/642-7100 . CABLE: CHEMICRONE COL 00554 McCRONE 0078 waiter a mecrone associates, ine. CONSULTING: ULTRAMICRQANALVSIS MICROSCOPI SMALL PARTICLE PROBLEMS SOLID-STATE 0HEM1STHT 25 January 1978 Dr. J. P. Strato, J r. Colgate-Palmolive Company 909 River Hoad Piscataway, New Jersey 08854 . Dear Dr. Simko: I have finished the transmission electron microscopical examination of your sample, designated as lo t 1-5-6, for asbesttform m aterial content. . This sample was found to contain platy m aterial ranging from the submicrometer size ranges ip plates In excess of 20 pm. U tile m aterial of any other morphological type was found to be present. No asbesttform m aterial was detected. Representative electron micrographs of the sample are appended. Thank you for consulting us once again. If any questions should arise concerning the analyses we are performing for you, please do not hesitate to call. RJSsfe enol. reft 5500 Richard J . Shimps Research. Chemist B820 SOUTH MICHIGAN AVENUE > CHICAGO. ILLINOIS GOfilB <312/842.7100 . CABLE: CHEMICRONE COL 00555 McCRONE 0079 w aiter c. mccron associates, ine. COL 00556 McCRONE 0080  p ' _- e* w aiter c, m ucrone associates, ino. CONSULTING: ULTflAMJCROANALYSIS MtCROBCOP/ SMALL PARTIOLE PROBLEMS * SOD-STATH CHEMISTRY 23 February 1978 D r. Joseph P. Simio, Jr. Colgate-Palmolive Company 909 River Road Fiscataway, New Jersey 08864 *" Dear D r. Shnkot I have completed my transmission electron microscopical examination of your sample, designated Lot 2-6-7, for asbesttform m aterial, The sample contains m aterial ranging from the submicrometer size ranges to partiles In excess of 25 pm. Although the predominant m aterial Is basically platy it occurs mainly In chunky m asses. No asbesttform m aterial is found to be present although fibrous aspeot inorganic partiles are common and range In morphological types from shards to an apparent fiber bundle. ' Repnesentative electron micrographs showing the sample m aterial, typical fibers and electron diffraction patterns are appended for your further inform ation. Thank you for consulting ns once again. If any questions should arise concerning this data, please do not hesitate to call. BJStfe enol. reft 5500 Richard'J. Skimps Research Chemist 2820 SOUTH MICHIGAN AVENUE . CHICAGO. ILLINOIS G0?16.312/042-7100 . CABLE; CHEMICRONE COL 00557 McCRONE 0081 <1I; I 2-25-10 2-6-7 32,000X Diffraction pattern of 2-26-11 * . waiter c. mucrone associates, ine. COL 00558 McCRONE 0082 2-85-11 2-6-7 20,00GX fiber w aiter c. roccrone associates, ine. COL 00559 McCRONE 0083 ' i. waiter c. mecrone qssodates, inc. M M CONSULTING: ULTRAM1CH0ANALY5IS MICROSCOPY SMALL PARTICLE PROBLEMS SOLIO-STATE CHEMISTRY 7 A p ril 1978 D r. Joseph P. Slmko, Jr. Colgate-Palmolive Company 909 R iver Road Pleoataway, New Jersey 08864 D ear D r. Slmkot -- . Using transmission electron microscopy and selected area electron diffraction, we have analyzed a sample of talc, designated as 3-16-17, - for asbefltiform m inerals. ... We did not find any asbestiform m inerals In this talc and it appeared to be quite typical of the previous tale which we have examined for you in that only some of the talc was platy and there were moderate fines. Thank you for consulting McCrone Associates and if yon should have any farther questions concerning this report, please feel free to call me. ' Yours sincerely, ' GRGtfe re f: 5500 - Gene R. Grieger Senior Research Physicist 2810 SOUTH MICHIGAN AVENUE .CHICAGO, ILLINOIS 8W1B >312/842.7100 . CABLE: CHEMICRONE COL 00560 McCRONE 0084 f-y .ITALIEN, TALQ AGENCIB8 SodcUHTnalccroobS (GNroarftihteIVttaljlr)Chiton* Societ Anonimi. Tko Enrico Tran tt C, Leghorn, Itafy u . a , JMiartoco 9 Nipote Torino . Cabu Audmm "MATBUOAR" A.9.C.conouno CHARLES MATHIEU, ine. F.O, BOX AM . 18-22 BANK STREET SUMMIT, NEWJERSEY 07901 . EEPR0SBNTA3TVEINUSA. 07 TOEEIGNMDTBE - May 17, 1978 . (201) 277-0610 , 1 Mr* Ian M. Stew art ' W alter C. McCrone A ssoo., in o .' 2820 S . M ichigan Avenue Chicago, I l l i n o i s 60816 Sear Mr. Stew art t Confirming our telephone conversation o f th e oth er day we are w ritin g to r eg u est th a t, e ffe c tiv e im m ediately, you perform on ta lo samples s e n t to you th e follow in g t e s t s to determ ine th e absence o f fib ro u s, asbestos p a r tic le si (1) x-ray defra ctio n (2) o p tic a l microBoopy (3) TEK - SED ' These sam ples w i l l he forwarded to you from e ith e r our. p la n t in A lpin e, Alabama or South P la in fie ld , Mew Jersey and marked fo r C olgate P alm olive Company. The t e s t r e s u lts should be forwarded to us a t P.O. Box AM, Summit, New Jersey 07901. P lea se send th e report in d u p licate. As you remember, you have been perform ing th e teem t e s t s fo r C olgate P alm olive company and they have now asked us to perform the whole t e s t procedure and c e r tify th e variou s lo t s to them. T herefore, p le a s e use t h is la tt e r aw a blan ket ord er, au th o risin g you to perform th e te s ts above so th a t we may c e r tif y th e absence o f ash estiform m inerals to C olgate Palm olive Company, Thank you fo r your cooperation w ith th e above. Very tr u ly yours, CHARLES MATHIEU, INC. I DRFteb Hot ^ u o n a ld xR. F e rry -- f*r do**inowradbytu n ittt. AII.uoW** riEContract,abjectteCM&tfenbtytmdourcentral. Ptfctt era in ti ujujti citrini miff nut end cwtenu raptleriem. COL 00561 McCRONE 0085 watter c mocrone associates, Inc. CONSULTING: ULTRAMJCftOANALYBIS MjCROSCOFV SMALL PAHT1CLE PROBLEMS SOLID-STATE CHEMISTRY 2 Jura 1978 Mr, Donald R. Ferry Charles Mathieu, Inc. . P. 0 , Box&i . ' 18-22 Bank S tre e t. ' Summit, New Jersey 07901 ~ Dear Mr. Ferry: - ' We have completed cur exonmation of your ta lc sample identified as: Talc KMPS, M-6670-9, lo t 5-2-3 using th e CIEA J4-1 method supplemented by transm ission electron microscopy w ith selected area electron d iffrac tio n . N either method Indicated the presence of asbestiform m inerals present. The J4-1 resu lts are presented on the attached summary sheet. The electrcti m icrosropical examination showed the . ta lc to be present as equl-axed grains rath er than as extremely thin p la te s. There was l i t t l e or no indication of fibrous or rolled ta lc present. -Thank you fa r consulting MsCrone A ssociates and i f you , should have ary questions concerning these re s u lts, please contact us. Very tru ly yours, GRG:fe end. re f: 5500 ce: J . p. Siateo, J r . Colgate-Palmolive Go. R. Gcieger a Researach P h y sicist 2820 SOUTH MlCHIQ AN AVENUE . OHICAQO, ILLINOIS 60S1B aie/B 4I-7100 . CABLE: CHEMICRON COL 00562 McCRONE 0086 Date . . S - ' S 0 - 7 S . ______ CUant C o ~ I t ^ ____________ MA Proje.ot ^ ? g Sample Description ~T>Jc- g I>fP,S . 7^ - ? ^ L n ' t S~- 2 .-3 __ X-RAY DIFFRACTION Serpentine Content __ Amphibole Content ' Comments *'P m t .. ,, ^ ^>g j A f iaief y J . '" I' ^ ia r M f l gx?- ^ ' L ---------------- . LIGHT MICROSCOPY Serpentine Content Amphibole Content Comments_______ waiter c, mccrone associates, Inc, COL 00563 McCRONE 0087 COL 00564 McCRONE 0088 . li' / 2- m^ 7 f ' COLGATE-PALMOLIVE COMPANY A DtUinut QtfeoJba RESEARCH AND DEVELOPMENT DEPARTMENT 909 River Read * iiscelatvtjr, Niw Jersey 0>S54 September 26, 1978 Ian Stewart lie Creme A sso c ia te s 2820 South Miohig an Avenue C hicago, IL 60616 Dear Ia n , As d is c u s s e d , I h i r e enclo sed two m illip o re f i l t e r B c o n ta in in g p a r t i c u l a t e m a tte r w hich we w ant i d e n t i f i e d . ,,The samples were o b tain ed by f i l t e r i n g a liq u id product follow ed by washing w ith w ater. Photomicrographs of each are a ls o en clo sed . Colee a re 10033 and 60007, p le a s e give p r i o r i t y to 10033. S p e c if ic a lly i n sam ple 10033 we a re in te r e s te d in id e n tif y in g th e b lack -ap p earin g p a r t i c l e s . By l i g h t m icroscope th e se appear to be h e ld In a y e llo w ish mass o f m a te r ia l whose i d e n t i t y i s a ls o unknown. In fo rm atio n concerning th e y e llo w ish mass i s d esired b u t i s secondary to th e b la c k . I suspect th e b lack m a te ria l Is amorphous oarbon. I f so th e surfaoe la y e rs w ill be contam inated w ith a .v a r ie ty o f o rg an ic and in o rg a n ic components. I have had SEM w ith Energy d is p e rs iv e x -ra y run. w ith th e follow ing r e s u lts ! . ( l y l 11 B la c k P a r t ic le s o o h ta ln : A l . Htt. C a . S i . S . C l. K . Ha A second p o s s ib ility fo r the source of the black contaminant is a dye used in th e p ro d u ct. T his i s an o rg an ic c o n ta in in g C, H, 0 , S and Ha. Sample 6QQD7 h as b la c k p a r t i c l e s to g e th e r w ith what ap p ears t o u s a c r y s ta llin e s u b sta n c e . In t h i s case we a re I n te r e s te d In th e id e n t i t y o f th e c r y s t a l l i n e phase. Ehe m illip o r a i s 0.22 micron. GB. ' A purchase order w ill follow under separate cover. I f I can be of any help please call. S in c e re ly , J P S :ls Enclosures / J . p . Simko COL 00565 McCRONE 0089 COL 00566 McCRONE 0090 COL 00567 f.-t) COL 00568 McCRONE 0092 iTM w aiter c me crone associates, ine, A ' CONSULTING: ULIRAMICROANALYSIS - MICROSCOPY SMALL PARTICLE PROBLEMS ' SOLID-STATE CHEMISTRY 17 October 1978 Dr. J . P. Snko Colgate-Palmolive Ocnotpany B&D Department 909 River Road Piscataway, HewJersey 08854 Dear lit. Sinko- This le tte r w ill confirm and summarize the re su lts we obtained on the p a rtic le s from the f ilte r s you sent us on 26 September and id en tified as 10033 and 60007. Your "le tte r indicated th a t the black p article s cn f i l t e r 10033 were o f highest p rio rity and you were p articu larly in terested in determining whether these black p a rtic le s were amorphous carbon. During the analyses we were in frequent contact and I sh a ll therefore Ju st b rie fly stmmarize our conclusions here. Sample 10033. Blade -particles are a m ixture o f etnorpbous carbon and graphite. Cbnclusian is based m electron mLeroprobe analysis of black p a rtic le s which shows approximately 807 C and x-ray d iffrac tio n th ich shows a mixture of 3 phases, one amorphous, one graphite and the th ird unidentified. Yellowish mass. This m aterial is very inhomogeneous and contains approximately 37. S i, 12% C, 35% Ou, 4% Fe, 3% Al, 2% P and 2% Ha. Based on x-ray d iffractio n th is phase probably contains about 50% CaF and 20% CuOOj. The CaF shows, however, an inversion o f the re la tiv e In te n sitie s o f the 3.15 and 1.93 lin es and very broad d iffu se lin es in d icativ e of smal l p a rtic le size. . . ' Sample 60007. Yellowish mass. C onsist o f many fin e p a rtic le s, electron probe shows 207. S i, 8% C, 107 Ca, 12% Re, 0.8% K, 12% Al and 0.8% P. Electron probe data suggested possibly a clay but x-ray data again indicates CaF predominant. I I 1 II 2B20 SOUTH MICHIGAN AVENUE CHICAGO, ILLINOIS 60610 * 31 '64&710Q a CABLE: CHEMCHONE COL 00569 McCRONE 0093 Dr. J . P. Sinico Page two At th is point you indicated th a t you did not wish any further work performed on these samples. We sh all discard your samples in two weeks unless we hear otherwise from you. ' Yours sincerely, Ian M. Stewart Manager, Electron Optica Group IMS:fe ref: 5500 COL 00570 McCRONE 0094 . L . ,, '.j iJ L L ' ** V lig it, COL 00571 McCRONE 0095 COL 00572 McCRONE 0096 POSITION OF PARTICLE QH PLATE Sompio No. o O n n z ~ h . 2 - COL 00573 McCRONE 0097 POSITION OF PARTICLE ON PLATE Sample No. COL 00574 McCRONE 0098 POSITION OF PARTfCLE ON PLATE, Sofflpte No. " p o n - - y - COL 00575 McCRONE 0099 -S S W : (/> S ) o tf- . -y h g l ' i.=l0' j -- ^4 s< COL 00576 ?Y cO tii O ft- . o ' Ds McCRONE 0100 MICROPROBE DATA S H E ET Date Q C T 4 1978 Company a/^at^ .fJ- rt. . - "f*f'<"S~ in o - W A No. COL 00577 A ff d. (ifeut sum t v*w\ 3 * if * ; 7* ^ eOW -j^ y i* 'f)A - -- - * -- t*" toi'^- 'S & Zo (J) occ ( ^ ; j *j y -10. o^j T^ui>v -4Wv-~ V O 0 $ } COL 00578 McCRONE 0102 I0>^7 EEDS-II gjfHA ftt S p 8 CL K CA FE PST> CPS* 43? HEK`61 ET= 833 fflT5 8 1K 28 EU/CH * 88,08 88-18 KEU =80.08 O 775 I 18.22 f COL 00579 McCRONE 0103 46 1320 COL 00580 McCRONE 0104 1i I . FHD'fiL SI P Cft FE : PST: W T - I . i HEM<Ai T- 39S IK EEBS-II CPS= 526 HDT'19 29 EU/CH 80.00 80-10 m E80.00 O 362 1= 18.22 t i COL 00581 McCRONE 0105 COL 00582 McCRONE 0106 ID'- FHD`SI CA M T * U * 1085 MEM'A ET 1875 512 EEBS-I CPS> 1 ijOT'- 8 8 EV/CH 88.88 88-18 KEV =38.68 0 1888 I 18.22 * COL 00583 M c C R O N E 0107 r - ozei 91? McCRONE 0108 I t& Z HO* _ PST'LT 1083 H'ftt ET= 5l 1868 EEBS-II CPS> 7G BT- ? 0 Etf/CH 06.00 08-10 KEU E*00.00 C 1088 l~ 10.22 # COL 00585 McCRONE 0109  s? I Il si 3 COL 00586 McCRONE 0110 0-5 EEDS-II AL SI P CA FE PST*-CKT= IK CPS: 624 i MEH'Al ET= 35S m -iz IK 26 ai/CH .es 03- i e KHU 10.22 "68.86 C- 318 3- # :l \ COL 00587 McCRONE 0111 COL 00588 McCRONE 0112 COL 00589 McCRONE 0113 COL 00590 McCRONE 0114 w aiter a m ocrone associates, inc. CONSULTING: ULTRAMlcROANALYSIS MICROSCOPY - SMALL PARTICLE PROBLEMS SOLID-STATE CHEMISTRY 22 November 1978 -Me. D. R. Rexry Charles Mathieu, Inc. P.O, Box m 18-22 Bank S treet . Summit, Neff Jersey 07901 ' ' Dear Mr. Ferry; Using transmission electron microscopy and selected area electron d iffraction, we have'analysed a sample of ta lc designated as "Lot 11-2-3, 1978 Series". We found no asbestiform trvfn^l h in this- sample o f ta lc and the platy ta lc and ta lc fines, were both moderately distributed s ta tis tic a lly . There were a few shards in th is ta lc which are quite typical. We also analyzed the aanple using x-ray d iffractio n and in th is we found no serpentines and no smphlboles. We did however, find some chlorites and some alpba-Si02 Thank you fox consulting tfcCrcme A ssociates and i f there are any fu rth er questions concerning tills rep o rt or the data contained herein, please fe e l free to contact me. Very tru ly yours, GRG:jd Ref. m 5500 cc: Dr. Joseph F. Simko, Jr, Gene R, Grieger Senior Research Physicist 2820 SOUTH MICHIGAN AVENUE CHICAGO, ILLINOIS 60610 312, 842-7100 . CABLE: CHEMiCRONE COL 00591 McCRONE 0115 Date f i -- 7 -- 7 % __________ C lient, C k t ^ y g^si /^ .-fA e .i.t-_______ MA Project g 'S 'b -a Sample Description M T tL T a .te. r M X-KAY DIFFRACTION ' Serpentine; Detected______ ___________ Not D etected______ Amphibole; Detected Not Detected Other Phasea Present; Chlorite I S ______ g-SlOy ______ Dolom ite,_____ ____ C alcite_________ M agnesite________ M ica, O ther:________ ;_______________________________________________________ Comments; LIGHT MICROSCOPY Chrysotile ______ Trem oliterAotinolite _ Nonfibrous Serpentine O thers:__________ __ Comments: ' .% __ total % g-StOo % ___________ _% fibrous waiter c. mccrone associates, inc. COL 00592 McCRONE 0116 COL 00593 McCRONE 0117 6 w aiter a mecrone associates, inc. CONSULTING; ULTRAMICRQANALYSIS MICROSCOPY SMALL PARTICLE PROBLEMS SOLID-STATE CHEMISTRY 22 January 1979 Mr, D. R. Retry Charles Mathieu, Inc, P, 0. Box AM 18-22 Bank Street SumrLt, Mew Jersey 07901 Dear Mr. Ferryi Using transmission electron microscopy End selected area electron d iffractio n , we have analysed a sanple of ta lc designated as Lot #12-19-20 of the 1978 series. We found th is talc to be completely free of asbestos minerals, both annbiboles and serpentines. We found th is ta lc bo be s lig h tly p la tte r than the previous talcs 'sfoleh we have examined and I t was an excellent quality talc. We algo examined th is m aterial using x-ray d iffra c tio n . Hie re s u lts o f cur x-ray d iffractio n analysis in d icates th a t we could not d etect say amphlbole or serpentine nrW ral* in th is ta lc using x-ray d iffractio n techniques. We did, however, find slig h t traces o f c h lo rite and alpha-SiO?. We could d etect no other minerals in th is ta lc , the x-ray d iffrac tio n data are included with th is re p o rt. We thank, you for consulting MiCrone Associates and i f you have any questions concerning th is report or the data contained herein, p lease c a ll me. Yours sincerely, Qene R. Grieger Senior Research Physicist GRGife hariTi Dr. J. P. Sinko - Colgate-Palmolive 2 K 0 SOUTH MICHIGAN AVENUE < CHICAGO..ILLINOIS 606 16.312/842-7100 CABLE: CHEMICRONE COL 00594 McCRONE 0118 r^ Date } - Z ~ 7 ? _________ Client C k f f l v / e 9__ )w ^ . MA Project i T O o Sample Description T ,J c L * i - A /o . J I - l T - n-<i X-BAY DIFFRACTION Serpentine; Detected______________ Not Deteoted ______ Amphibole; Detected______________ Not Deteoted ______ Other Phases Present; Chlorite a-Si02 Dolomite________ Caloite________ Magnesite_______ r Mica___ O th e r:______________________________________ ,_________ Comments; LIGHT MICROSCOPY Chrysotlle ___________ ' % Tremoltte-Actinollte_____ _______ total % Nonflbrons Serpentine__________________ O thers:______________________________ a -Si02 ___________ __ % ____________ % fibrous Comments; walterc, m<=crone associates, inc. McCRONE 0119 COL 00595 V Date 2 4 - 7 9 Citent ( 'In /^ > a .7 g - 'fa - + tn /u e>______ __ MA Project >5"X&ci Sample Description 'Z.lflIPs ; ^ - 6 2 7 7 ^ a t ' R X l S P O ______ X-RAY DIFFRACTION Serpentine; Detected______________ Not Detected_____ ________ Amphibole; Detected______________ , Not Detected ^ ______ Other Phases Present; Chlorite ,,. _ q-StOp C+yprmi) Dolomite alette *---' Magnesite Mica _____ O th e r;_____________________________ Comments: LIGHT MICROSCOPY Chrysottle ,_____ Tremoltte-Actinoltte _ Nonfibrous-Serpentine Others;,___ ,_______ Comments; % _total % q-St02 _____________ % ___________ % fibrous waiter c. mucrone associates, ine. COL 00597 McCRONE 0121 COL 00598 McCRONE 0122 COLGATE-PALMOLIVE COM PANY A D ilm tr t C trfiM th * RESEARCH AND DEVELOPMENT DEPARTMENT ^ > 909 Riiitr Rtitd Piscataway, Ni-w Jerny OftJi [SalV>D hftS f February 2, 1979 Hr. Ian Stewart MeCrone Associates 2820 South Michigan Avenue Chicago, IL 60616 . hear Ian, Enclosed are two sauries coded 600X6. and 100l6. for microprobe and aicrodiffraction studies. These are. residues trapped cm 0.22 micron mlUipore f i l t e r discs and are sim ilar to sample 10033 I sent you September 2.6, We want the sam information on these as on 10033 (reported in your l e t t e r dated 10/17/78). We are concerned i f any toxic elements are p resent, what are the black specks, and what other crystals are present . I would guess the two samples are sim ilar and might d iffe r in the proportions present. A purchase order has been sent .under separate cover. JFSils Enclosure ca P. A. Mingar J. P, Hauscbild |. C *1 3 7 -3 COL 00599 McCRONE 0123 jL J.lC /,f -z/,&< /.k }. t T /til /V O fo sv S fo /o c_izU ~ ebf.) / j 9Z-- /a<3 -37 ~ / 'L' h / ^ " V <=> COL 00600 McCRONE 0124 ,, L ._ ITT - --I ---- J.----- -J j -U:qia el--|--& .^^A jk ji 2L --L' r.l Ia...}.. : 1 ! 'i \-- * - - * -- - + j --.L ^ ,-;, ...j.. I 'M-jwaJi pjjr&fijb-s-- :__;-- SbaLji<L_j ' 1 1 ' : ' 1 laljin j '' 1I ! : COL 00601 McCRONE 0125 __ nlasiJ __________ Q .Q W h a V MICROPROBE DATA SHEET Date Company ______ MA No. MICROSCOPIC OBSERVATIONS Sam ple or P artic le No S x 3 H S' 6 1 Size' Shape i Color(T) S \ iM *13 i -- - ft] ELECTRON MIC ROPRO BE DATA, % COMPOSITION Ag A) A - 3 3.-fe_ l- Ba t i . . ' } Ca l - A . A - . S 6 . 3 ' I - A O Cl . - l Cr 6.A,r6,3 a .D t-s I - A . 3 - 1 - n SMf SOSO A -4 1 -i y- i /-A AK 3 6 . SO Cu t - - 6 .A -0 .S Fe 1- f - # a. A - a . s t - A K 0. A -. S Mg l - A Mn 1 - d Mo Ni 0.6-1 O.A-.S IS -A O A - H - __ 1 6 - 1 3 l-A So - /o* A -4 P t - - .J-fi.f / /- A >-A Pb S l-A Si 3 . 1 . - ) A l - A - A Ti Zrt a -4 A-4 * 4 - 7 __ o . A - a . S t - J L . Jf-r .A-0.5 A A -0.6 C 4 0 - 0 ,0 s / i - t f a 1 0 - 9 6 A - 4 F n .<. n .d. n * <L- i- Na 0 7 0 -16 A & -36 n , < L . _d. *4-7 i -!A 4- 3- S *V . ** if*. frfejikjL 4.. 3 . 0 ia.it .y S . A __ l - S A 4 . 1 A t.5 A l . a fa ld te . C. S o s , 4 1 o . / \ M A "L i. i t l . n iO S i.1 3 9 1 .a 1 3 . I * A 3 A .4A . 1 S - I tttyte. 0 J , X ii,3 _ _ J.A __ho._ A l . . S . i-- S 3 . i l o . 4 - - L U __ Comments\ tJE', jA*lq ) --------- ------------------------ .--ti --1 tl ( L => n a l d *J tr_ 4 e J > U .____ _________________________________________________________ COL 00602 McCRONE 0126 S3 I 3* I t i I COL 00603 McCRONE 0127 o k - s: "tpv jX tftn. S^tooyw / JU C . I 3^- ^ Qh H 2 ^ . j- M H S". |^ h & *v*k . 6 ityAhd'" 7 %0f~ Z ^ \M y h ' ? O^V. *1 lOjp- *JyyJv^ lO lo^ih / Vj ) O) 3-W t ^w h'w to r . . . T" luYfalrti lO O ^03 3 Je <*s`ta , .fy & V b . 3 'gloujsv nprt._s J fewumfsi, toat-<y*+ jitJlow^ * Tnot r Fl^oKwjaref Uo C&ock ^ 3 * $ ] L .** i o ^ r ;p $g> H*. J wisK 'IWS COL 00604 McCRONE 0128 waiter c. mecrone associates, inc. CONSULTING: ULTRAMICR0ANALY6IB MICROSCOPY SMALL PARTICLE PROBLEMS ' SOLID-STATE CHEMISTRY 9 February 1979 Mr. Donald Ferry Charles Mathieu, Inc. ` P.O. Box AM Summit, MewJersey 07901 Dear Me. Ferryi Using x -ray diffraction- and transm ission electron ndcroacopy w ith selected area electron d iffra c tio n , we have analyzed a sacple of ta lc designated as Mbnltal 100, Lot 881800. Both techniques show th is ta lc to be completely free from aebestiform m inerals. E lectron microscopy showed th is ta lc is extronely p la ty . Because of i t s platin ess there were some ro lled ta lc shards, but th is we normally find w ith p laty ta lc . The re s u lts o f our x-ray analysis also indicated th a t no anphiboles and serpentines were p resen t. We did find seme chlorides and traces of alpha-SiO^, dolom ite, calc-ite and m agnesite, The re su lts of th at in v estig atio n are included with th is report. Kxank you for consulting McCrone A ssociates and i f there are any fu rth e r questions concerning th is report or the data contained herein , please fe e l free to contact roe. Very tru ly yours, Gene R. Grieger Senior Research H y sic istx GBG:fe end. r e f : S500 cc: Joseph Shdco - Colgate-Palmolive Go. M O SOUTH MICHIGAN AVENUE . CHICAGO- ILLINOIS 6061B. B 1 M 2-710I). CABLE: OHMIORONE COL 00605 McCRONE 0129 waiter c, mecrone associates, inc, CONSULTING: ULTRAMICR0ANALY6IP ' MICROSCOPY * SMALL PARTICLE PROBLEMS. SOLID-STATE CHEMISTRY 9 February 1979 Me. Donald Ferry Charles Mathieu, Inc, P.0. Boot ' Smndt, Mew Jersey 07901 Dear Me. Ferry: Using x-ray d iffrac tio n and transm ission electron microscopywith selected area electrcn d iffractio n , we have analyzed a satp le o f ta lc designated as M arital 100, Lot 981800. Both techniques show th is ta lc to be completely free from asbeatifor minera ls. Electron microscopy shewed th is ta lc is extremely p laty . Because o f i t s p latin ess there were some ro lled ta lc shards, but th is we normally fin d w ith p laty ta lc . The re su lts o f our x-ray analysis also indicated th a t no amphlholes and serpentines were presen t. We did find acme chlorides and traces of alpha-SiOp, dolom ite, c a lc ite and magnesite* The re su lts of that in v estig atio n are included with th is report. Thank you fo r consulting tfcCrone A ssociates and i f there are any fu rth er questions concerning th is report or the data contained herein, please fe e l free to contact me. ' Very tru ly yours, Gene R. G rieger Senior Research F hyslcistr GBG:e end. r e f : 5500 cc; Joseph Sinico - Colgate-Palmolive Co. 2B2D SOUTH MICHIGAN AVENUE , CHICAGO. ILLINOIS E M 16 al2/<Z-71O 0 . CAGLE: CHEM CRONE COL 00606 McCRONE 0130 Date_____ Client__ a \ '/ a .im a /tU g . ___ MA Project J T J ig o Sample Description g j H IP S f J .n f~ % Xt& DO______ *y X-HAY DIPPBACTIOW Serpentine i Detected Not Deteoted____ ^ Amphlholei Deteoted_______________ Not Deteoted ^ Other Phases Present! Chlorite t-SiOo Dolomite Calotte 1-- Magnesite * ^ ~ Mica O th e r:_____________________________________________________ Comments: -L-I-G1. HT MICROSCO--PY Ghrysotlle ' ____ ' . % Treraolite-ActlnoUte_______ total % Nonflbrous Serpentine__________________ O th e rs :______________________________ a-SIO2- Commente: , % fibrous waiter c, m<=crone associates, inc. COL 00607 -McCRONE 0131 COL 00608 McCRONE 0132 < Vi^v'.VWJJnwvwmetti TO w n tr& A c , m cC#&*JS flSSVCn ,2 -fa <Kt7# # )s /? ;j/jJ / ) / y C./J* ^ Speed Letter. From c m-5A:, M k. xf,, * (^i ?<5* ?/- afe Q^n"ic Subject > 0 ^c> M8B0e fSjTii^TA 'l J*< .tS* /S S W 'V / t f -F s n A s /T J K . T J Z C f a A y<s*A /C'*T*W if'V s s s T /js r F /^ & ? /? S # & r? l& # y n fa A C e i j /W F - P L w i-s'i/e C e , /* . /? $ /*#?*#-. j & h A u /a A A ^ T& S C & n A lf i W u 'fi ; 1 # 7/? A A & V $ T T*> ** A ( o A p 7? OC S /M p G # ] Reply D ateJ^.S lg n ed 1 -KilTOi) WfeonJones.wmniwnw MiwrnftitwttMiiM Date..___ -__ Signed.---------------------- ----------- ------------ - Retain white copy, return pink copy <?* COL 00609 McCRONE 0134 4T waiter,c mecrone associates, inc, CONSULTING: ULTHAMICROAHAL.Y0IS >MICROSCOPY SMALL PARTICLE PROBLEMS SOLID-STATE CHEMISTRY 4 May 1979 Mr. Donald F erry Charles M athieu, Inc. P.0. Box M Summit;, Mew J e rs e y 07901 . Dear Mr. F erry i Using transm ission e le c tro n microscopy and se le c te d area e lectro n d i f f r a c t i o n , we have analyzed a sample of t a l c d e sig n a te d as Monotel 6040, lo t #492400. - Wa found t h i s t a l c to he p la ty and of e x c e lle n t q u a lity . There were no atibeetifoxm m inerals contained in th is t a l c , n e ith e r auphlboles nor serpentines. .. Thank you f o r c o n su ltin g MeCrone A sso ciates and i f you have any q u e stio n s reg ard in g th is r e p o rt p le a s e f e e l f r e e to c o n tact me. .' Sincerely, Gene R. Griegex ' Senior Research ph y sicist GRGsfe re f: 3500 ' c c : J . F . Simko - G olgate 2320SOUTHMICHIGANAVENUE. CHICAGO, ILLINOIS30318 312/842-7100. CABLE: CHEM1CRONE COL 00610 McCRONE 0135 ' Date < ? - Z - 7 9 Client C . ft'h x .'h k i & u - ___________________ MA Project S 'S ~ O c > Sample Descripti/m _ T a ^ c ..- 6*C>4xo -h i/- o f 4 9 1 4 Q Q x- r ay diffraction Serpentine; Detected_______________ Not Detected _ Arnphtbolei Detected_______________ Not Detected_ Other Phages Present; , Chlorite _______ a-SiOg Dolomite \ S * Calette ^ Magnesite --- Other:____________________________ ____________________ ;___ Mtoa Comments;_________________________________________ ,,______________ LIGHT MICROSCOPY ', Chryeottle _____,_____ ' . ' % q-siO o ________ % Tremoltte-Acttnoltte ; total % ______ % fibrous Nonfibroue Serpentine *______________________________ _ Others; ,, ______ _____ " _______ ___________ ______ _____ ' Comments; ___________________________________ ___________ Waltere, rrv=crone associates, Inc. COL 00611 McCRONE 0136 COL 00612 McCRONE 0137 t- WJU.T7$ A C Speed Letter, /<tev<3. Frora________C ./V # T tfS # A ________ 2J-24 X ^ T ti M X, __________ f / W ^ J 7 T f L l . h f / d " ________ . _________ / f c / - ? Subject_____ -- --.-------------- ___ _____________________________ s ! WfettUKK hem a e ; # cjs& / r A L > /* a/ . t . 'r /o ^ 'TM -fy A y a \ . K f e w , u s S t e V S i T .k A m i , >F r f r r f r / * * 0 M st? s* > JZ * A }i.f ____ ______ C # lJ jX } 'm ` h tf C&, y n)tuft l*& vjvjLdd '% $> $ tf/to ? // * & * * {& '& H 4 >_______________ __ REPLY D ate j T - 2 - " - 7 / S i g n e d ^ , Yvwy-T^ --Vo J^A ^A wl -IkIKW - . i & I C T J ...................................................... .. ..................................................................................................................................... ,........... ................................... ............ Date Signed Wilson Join com pan? ssmssuw&ir" recipient--retainwhite copy, return pinkcopy COL 00613 McCRONE 0138 COL 00614 McCRONE 0139 / . If w aiter c. mecrone associates, Inc, CONSULTING; ULTRAMlCRCANALYSIS MICROSCOPY SMALL PARTICLE PROBLEMS S 0U 0-8TA TE CHEMISTRY 9 May 1979 Mr. Donald F e rry Charles H athieu, Inc. 18-22 Bank S tr e e t P .0 . Box AM Summit, Hew J e rs e y 07901 Dear Mr. F e rry : Using x-ray d iffra c tio n and transm ission e le c tro n microscopy w ith selected, a re a e le c tro n d if f r a c tio n , we have analyzed a 8ample o f Mondial 6040 t a l c designated as Lot #590300. - We found t h i s t a l c to he com pletely f r e e from a sb e e tifo rm m in e ra ls both amphlbole and serp en tin e. There w ere, however, a few ta lc shards in th is sample b u t the bulk of the te le is predom inantly p la ty . If you should have any questions concerning th is a n a ly sis, please contact me. S in c e re ly , Gene R. G rieger Senior Research P h y sicist GRGife r e f ; 5500 cc> Josep h Sirako - C olgate . . . i j ' 2320 SO UTH MICHIGAN AVENUE > CHICAGO, ILLINOIS 60B16.312/342*710 0 . CABLE: CHEMIDRONE COL 00615 McCRONE 0140 Date 7 ? ___________ Client C , l u f MA Project _ S ^C O o Sample Description i^otV.-ha.f 6 o f a T j < ; f y - <57-77 / n f - S '^ o ^ o a X-RAY DIFFRACTION Serpentine: Detected______ Amphlbole: Detected__________ Other Phases Present: Chlorite Dolomite________ Calotte_____ O ther:___ ___________ __________ _ Not Detected______ is '' _ Not Detected______ i / ^ g-SlOo \ s ^ Magnesite t X Mloa Comments:_____________ _______________;______________________ ___ __ Jr* LIGHT MICROSCOPY . Chrysottle ' _______ a-SiOa _____________ % Tremolite-ActLnoltte ______ _ total % ,___________ % fibrous Nonflbrcue Serpentine________________ ;____________________________ _ O thers:____________________ _ _ _ _____________________ '__________ Comments: Waltere, mccrone associates, Inc. COL 00616 McCRONE 0141 } //? ' Dear Ms. Paleni^k,7: Attached please find the l e t te r from Dr. J . P. S1mko whteh-was to accompany th e 4 samples he sent you yesterday. ' ' There was a s lig h t mfx-up and the l e t te r was l e f t behind. Sorry for the Inconvenience, Maryanne Bechtold Secretary to Dr. Simko COL 00617 McCRONE 0142 \ COLGATE-PALMOLIVE COM PANY A M mwv aBijmCir jiND DSTBZOPMNT EP^STMENT 909 R W Rani Ptitatmany, 2fw /<rJO- OiSii August 18, 1983 Ms. Deborah Palenik . McCrane Associates 2820 South Michigan Ave. Chicago, IL 0615 Dear Ns. Palenikt Enclosed are 4 samples of Talc for analysis fo r Asbestos by T5N-SAED. Lot Nos; a re : 12873, 12877, 13080 and 13081. Lot 12873 has Been previously analyzed by your laboratory But we want to check i t again. I understand cost per analysis w ill be approximately $350. I am having a purchase order sent under separate cover. Sincerely, v~- <K P. Simkq, J r . Sr. Section Head Analytical Department JPS:meB cct W. Schubert J . H. Callahan COL 00618 McCRONE 0143 O o r oo On i--1 vO | Or*. 3 . ? . Sinifcg, Jr, ; COLGATE - PALMOLJVE COMPANY i rn V a r Xmi - Um Jm o - MtSf J] CB|M 1 s II i McCRONE 0144 jv' T'U, /J: {- BUOGSWIV'SBJ) Ms, Deborah Palenik McCrne A ssentes 2820 South Michigan Ave. Chioagoj IL 60616 Re c e iv e d aus 2 z fise \ o' Tr * J-f PROJECT TITLE;_____ SPONSOR; 3LQ 4& ADDRESS;____________ ^ iLV U t / b i UO A ESCA COLGATE-PALMOLIVE COMPANY 909 Elver Road ` Piscataway, New Jersey 08B54 ' ' ( o fifr ') PROJECT NO.. HA 5500 , DATE RECEIVED'; 7 3t*76 P.O . NO. ;___________ COMMITMENTS. $ Contact; ^ tr h nk t>, v rr- Telephone No. (201) 463 1212 COL 00620 McCRONE 0145 w aiter c. m^crone associates, inc, CONSULTING; ULTRAMICfiOANALYSfS MICROSCOPY * SMALL PARTICLE PROBLEMS SOLID-STATE CHEMISTRY 27 October 1983 Dr. J . P. Simko, J r . Colgete-Palraaliva Company RSD Department 909 River Road Piseataway, Hew Jersey 08854 . Dear Dr. Simko: This l e t t e r concerns the asbestos analysis of three ta lc samples labelled 12873, 13080 and 13081. Sample 12877 was found broken when the sample box was opened and could not be analysed. The Banrples were analyzed by transmission electron microscopy. Chryeotile asbestos was detected in a l l three samples. The examination was not done quantitatively so no amount o f asbestos can be determined. Thank you fo r consulting McCrone Associates. I f you have any questions please do not h esitate to c a ll. Sincerely, Deborah P. Palenik Mgr., Electron O ptics Group DFF:fe Ref: 5500 2620 SO U T H MICHIGAN AVENUE CHICAGO. ILLINOIS 00616 SIB/M2-71 CO CABLE CHEMIQRONE COL 00621 McCRONE 0146 / ^ r th ? /> -s-p -- - sL~* ?* f > 3 'J j* * # * ? " c ist/V * 2 & w 4 ts 2 _^ d h c c ^ i / S o r o c W 7 y 3 ? V , S ^ y U c / W )} S iJ t-d j a s s 4 r C ? J * 4 ' ^ r & ' ~ ~ 77ul t * C & ^< Z j J s U o o z ^ ^ h s c*~ts*< ? U>^-J ^P A /L A -s , ~~~7*%4s t-* * ^-# * * -0>t4fc>>i6^^2P^W ^7 a C -^ rz^ u _ ^ f- Cf s c ^ S^ s b^ ^ M ^r /L oe * M . ^ d k - '^ v Z f /^Lgsc i & ^L Z ~ * $ . /j^ts^ ^L 2^ COL 00622 McCRONE 0147 COLGATE-PALMOLIVE COM PANY .' - . A Vd/ntm Cvftmtfui . RESEARCH AND DEVELOPMENT DEPARTMENT ' . 909 R i v t r S i . P tttu ta w a y , N rw J tr s ty 0 88f 4 . . . . ' / '" * October 3a *' 1983 Ms. Deborah Palenifc. McCrone Associates 2820 outh. Michigan Aye. . Chicago, ,IL- 6CL616 ' Dear Ms'; pal entk, -. s- . ' . ^nclos^d.'ts'\a sin g le t a lc sample Lot Ncr. S09Q63 fo r a n a ly s is . by.. Tt^-SAED.'for'asbestos. Please expedite, t h i s rtqrlt, A'.^urc'basa .Pr.ijer^Nq.: ts '-being se n t separately. ... . \. Many, thanks.'. Sincerely, Dr. d. ,p. stmkfl,' dr-. P$|;ne&, . ' J . *. ' * ,cc:' P. .-A. Munger' . ' . V!. -S.bhubert ' C."Schwarz, E -l-5 '.' - ' f. ' * iI ' <1 , !i COL 00623 McCRONE 0148 COlGATE-PAlMOLm COMPANY ILL* T O : , ` k ec ev eo && 'fOS-me -&tfsoo'c?O&&&ti& 8g&'Stu$ itothiea^! AiMVf^&hUte C34.Ppg!t, 33ilnp>l^ 6f>& ? y a y> ? 3 g fn_aS_CRAIVTKAVHIARyD,fH|J* W 4 r a g aIj S ^ c it V . M .J* 07a AfKcFeFerKtfRlHlOQMSVTAlHT.IgO-N IN B IA H A 47130 * C * lV tm S S T A T IO N _ KANSAS C IT Y . KAN* M IO DISCOUNT TERMS 1 D 2/to N/30 2 1/10 N/30 SHIWING TERMS 1 n FOB 2 2 f OB ShapingP t . WAITEDBY FLesuse Push ||W HARKAVE. ___ [ h r w Y o r k . w . r . lo o a a 3 0 , NM6 S m Btiew I F A B O V E D A T E C A N N O T SE M E T N T IF Y 4 3 5 ^ N/30 B 6 O NET CASH 3 O FOB Shipping PuiCoUeot) City Mrtohit* *R. Pit.' Cod* ATTO: R*cttWn{ Clark YOU A M 'A V rk B U g O TO FW H rSH TH t A m a c * LISTO HPI0W IH ACCOMAHCC B IR frT W m u * . A m COHOmOFfl.OH.THE FA C TA BACK O f TM lf OflPCB, QUAHTIfV AHO UNIT SYMBOL Ump . *.JI.'.J* . -.WI 'i.T* ,B4 PRICE ea. Talo Sample fo r analysis fo r asbestos ; cost .'' approx, $3JR -. | ` i Hete* Thib Is a one time request* T#-. 4S,amples sent upder separate oover ` .v w sl1-:; : `>~%\'.t, ' ` 't'o'lrfa.`"Bebrh `Falenifc at" MeCirone A ssociates. ' - v ....... .. TAX EXEMPT y V E MOOR TO PR O TE C T A L L M E TA L F ART fi AGAINST CORROSION BY SU ITA B LE F R O T E C T fV E SEALING. SELLERSINVOICES lhat lodwli tnrtherbid Iramportalfar o i ^ ntttf bfl tupprtrltd-hy pnpott frt^Hl Wl tiff CvC0U1GuAiUTOB ""FrAAUuHuQ/UZIrY4B WAriflWja copy f rigfaid WIJ trf lodino. J" ` MARX PACXA0E5 wlfir parch* ord*r nutabar* syaibd mnnbwr arcanti ad ^vsittllY* Accaplcn of this d o t Ti la bo rftonr a cvrtlAcdHoH that you haw Toad aid a g n td 1 th* term no constiti on thi book horoof. PAYMENT Wilt NOT IE MADE AGAINST PRO FORMA INYOtCE. M m UNIOAPINO twee d tfaa far h - w COL 00624 *. v t i2.w*.uvL.,`; `fc r .v- McCRONE 0149 McCRONE 0150 O O o ao \ to O <J3DnOO*M3&^C f COL 00626 McCRONE 0151 / tw w a ite r c. m ^crone associates, inc, CONSULTING: ULTHAMICROANALYSIS MICROSCOPY SMALL PARTICLE PROBLEMS SOLID-STATE CHEMISTRY 16 November 1983 Dr. J . P. Slmko, J r . Colgate-Palmolive Ccnpany Research & Development Department 909 River Road . KLscataway, New Jersey 0885*1 Dear Dr. Simko: Phis rep o rt sunmarlzes the asbestos analysis o f one ta lo sample labelled Lot #309063 which was sent to us under P.0. #633715. 3he sample was examined by transm ission electron microscopy and no asbestos was detected. Hris technique has a detection lim it of o .ljt by weight. . . Shank you fo r consulting McCrone A ssociates. I f you have any questions., please do not h esitate to c a ll. S in c e re ly , Deborah F. Palenik Manager, E lectron Optics Group DPP:cb Ref: 5500 2820 SOUTH MICHIGAN AVENUE . CHICAGO. ILLINOIS GCB1S 312/842-71 DO . CABLE CHEMICRONE COL 00627 McCRONE 0152 ^ s ~ o .a ~ ~ ~n4f`s " / ti 5 & w p i? . tJJ--iXxs> j^ /l^ x in O v O ^ y i* J U ^ C ^ jU f . ~ ( A m tr a sr* 4 $ Js r j j , J b c -^s \-- & / - / J % & <& S . d * fe* = , C & & <Zs . jfy " s j ? (-C fr a s L AA'*Z>C / ^ fi" eU^ ' 1 2^ 'S k COL 00628 McCRONE 0153 *. f .^ s^ ja V . * -- p t0 if* O ; i iii i COL 00629 McCRONE 0154 COLGATE-PALMOLIVE COM PANY A D ttm n ri C c rfu tth tt RESEARCH AND DEVELOPMENT DEPARTMENT 909 R ip if Re/td Piscatavjay, Net# Jtrsty 08854 RECEIVED NOV2 1 ST* November IB, Dr. Ian, Stewart McCrone Associatea 2820 South Michigan Averne Chicago, XL 60616 .' ' Dear lam Enclosed are three samples of' ta lc I would lik e analyzed far ehrysotile and tram olite using IBM and SAED, Sareples are labeled A, F and $. Charges fo r th is work should carry our purchase order No. 63276B. JPS) l a P, Sirtko, l r . Research Associate C 1J7-J COL 00630 McCRONE 0155 COL 00631 - it * ! / f t n K -X McCRONE 0156 ihf i '' '"1'I*I *` ; , : . - ( , t\>m* ` ' ORIGINAL PURCHASE ORDER ,5 Sanh4ewPtrbefiitxmouns tier safest, psckirtt ta p i atm p e s te n t. <532760 COLGATE-PALMOLIVE COMPANY A OKLAWARXCR^6RATIOH < r , w_ IOS HUDSON S T R E E T . JERSEY C IT Y . H .J. 07302 ATTNHONl I MoCrone A ssodate 'I 220 South Michigan Avenue Chicago, m in o is 6o6l6 / 7 z < /& SHIP TO I Q a o n e s N fi s t . JERSEY C IT Y . NmJ. D790* 1idSlIa r I| *i&<*BCrAivteArih*rtd, .N J . 88B4 1 iO RAND ST. J C R IB V C fT T , N.J* TAOS w 1 RECEIVING STATION J JE F FEASON V ILLE * TNOrANA 47150 , RKAENC--SKAIVS--INC--OI-T Y^S T AKTaINO*Nnot DISCOUNT TERMS ' SHIPPING TERMS WANTEDBT I I R kV l K T ? C A L t r . ,471 O 1 n S / 1 0 111/30 2 HN/SO 1/10 N/3D 1 riroD pIottlnallcn 2MPOB !Shipping PI. f fft-*.Po/S B lic o * B elar ASAP ' I P A B O VE' D A T E CANNOT BE MET N O T jH T I I n e h P$ o R k* n' t . lo oa a Q . .. -, I " .Net Cash 3 LU FOB flIpptnEPI. (C otisai Clly _________ I ATTN: RKMini Ciarli wf WHI AftC AUTHORIZED TO rwiHUH THE ARTICLES LISJED HEREON IH ACCORDANCE WITH THE TERMS ARP tOHtUTlOH* OHTHE RACE AHO IACE OF THIS ORDER. u a n t it y and u n it SYMBOL NUMBER P R IC E Tranim iBBion E le c tro n MiftODOORy- aiid e le c tr o n d i f f r a c t i o n a n a ly sis o f th re e ta lc samples fo r e h ry a o tlle and tr a s o l i t e ' '' ' ' '. ~ ' 7. __ HOTE T h is i s a jifiji one tim e orddn f o r a s p e c i f i c jo{j address as. above ' Attention Br. I , Stewart ' _________________ t a x exem pt Y E N O O R 'T O P R O T E C T A L L M E T A L P A R T S A G A IN S T C O R R O S IO N B Y S U IT A B L E P R O T E C T IV E S E A U W C . MtapyBaf^J^NjpVTfOVrIfCMSRamtft Indnh otrtorfMd frumportoHe^i chat, morvtb',a,.wHpp*ort.ad ,,pwp*# IWihl MB<* c0 MnAtRaKrbMloCbKoAdiOMESBTMUMl IapbvbrdCUnhiaMIoriiWwTthyitwheirM, jmytnnbaodtuaenndb*arrr,*e*odnTlioH*b,oelfdrqaciira>ndjr.I TM ^ TAX wist M * h* * d m e s s * = BTA TM sm sm ssm COL 00632 McCRONE 0157 i PROJECT COST HEconn PROJECT TITLE:_______ 3 talc samples________ _________ ______ _ PIOJECT NO: MA 4428 SPONSOR:________ COLGATE-PALMOLIVE COMPANY_____________ DATE RECEIVED: 12 2 74 ADDRESS:,_____ _________ 909 River R e a d ______________________P.O. NO.: 632768_______ Pisoataway, New Jersey 08854 COMMITMENTS^ $ Contact: _______ J. Witruk_______________ SUMMARY OF PROBLEM: Telephone No. (201) 463 1212 Lab Notebook References: No. pp. Initials No. pp. Initials No. pp. Initials Photomioroffraphic record no. Sample disposal: retornad filed (where) discarded , . Individual---timSe. I * * en* i*via*tUatsx\*nv*O. \ Date Name Hours Charas - , DIRECT COSTS Travel Date ' Traveler Destination {` Instrument time 1 Date . SEM TEM XRD EMP IMP ESCA Hoars Charge Outside Servioes Date' Photo Photo Materials Supplies Company Charge Summary Cost Individuis $ Instrument Travel . !Outside Other Cost Total Charne 8 UA lor DilUHg Project Ldr ____ Group Ldr ____ PROJECT LEADER IMS ________________ TOTAL CHARGE $ _ ROUGH DRAFT ___________________ ;_________ . BILLED TO CLIENT $ REPORT RECEIVED __________________________ INVOICE NO, (S)_____ COL 00633 McCRONE 0158 tea ef tale McCRONE 0159 O O r oo o LO ) B r, i , P, Start Paga fcwo 4o tt tal ntne. Banlieu P and 8 chmrad no lu p J M i bat did showlargar jp3atH f tal tbao Swnpl*A, Moli aajBfe ? also lfrir&igbtgli aj&MmtBof affante nnatamlnatton, Ttumkyen ter comroltio*M odo ewttJateiT U tterr* are anjr 3n#rtte<u neernlijf tela pori e* tite tela <nntU*i h*x*tn, plse IMI ftee te ita** me. '' VJr trfliy junta, $Btkn anleaorea t*iM445 #*bp* Iteeeajrch Pbysfolet COL 00635 McCRONE 0160 COL 00636 McCRONE 0161 MEMO FROM GENE GRIEGER SA&b f yifi/C 0-& L MEMO FROM GENEGRIEGER (& 4 L * 4 -$ u j -Z, 5 AE& J ~ J W m w jL*. COL 00638 WicCRONE 0163 W a lte r G. tcC rone A s s o c ia te s , Inc. gampieA-2 SAE T -ro m V H Ft COL 00639 McCRONE 0164 W a lte r C, M cCrcm e A s s o c ia te s , Ine. . Sample , not 1 (euKX) COL 00640 . McCRONE 0165 COL 00641 McCRONE 0166 ^OGOCOO DJ I COL 00642 ,McCRONE0167 .* COLGATE-PALMOLIVE COMPANY A Ddevun C tr^tntlm research an d developm ent d epartm ent 909 Riper Redd * TLtvtaway, Nets Jersey 00S54 ' ' ' ' January 28, 197^ 1. Ian Stewart . IfcCrone A ssociates 2820 South Michigan Avenue Chicago, I llin o is 60616 -, ' Dear Da?. Stewart: .' ` Enclosed ere th ree s a b le s o f ta lc which we want analysed fo r cbxysotile and tromaLlte. I hove discussed these, with you by telephone and I want transmission electron microBcoy andeleotron d iffra c tio n `wwlysiB done. Charges fear th is work should carry our purchase order Ifo. 63A953. I f I can be of any assistance please contact me: ( 2 d ) 1^3-1212 ext* 379* Sincerely, - . .1 _ J . P. Siwfco, Tr, Hesearch Associate PB:#: *I P. S. Dr. Schneiber of our company has not received promised lite r a tu r e . .611374 COL 00643 McCRONE 0168 P R O J E C T COST R E C O RD PROJECT TITLE;______ Talo analysis____________________ __ PROJECT NO. :MAS805 SPONSOR: _______ COLGATE-PALMOLIVE COMPANY________ DATE RECEIVED; 1 30 74 ADDRESS: ________________ R&DDepartment .____________ ___ p .o . NO.: 614953_______ _____________________ 909 River Road_____________ COMMITMENTE*$ 2-300/ssn ' Contact: Piseataway, New Jersey 08864 . J . P . Simko, Jr.___________ ^ Telephone No. (201) 463 1213 XS79 SUMMARY OF PROBLEM: . Lab Notebook References: No. pp. Initials No. PP- Initials No. PP- __ Initials____ Pho tconicrographio record no. _________ Sample disposal: returned '* led (Where) discarded. " DIRECT COSTS Individuiil time f.fixmoeluosnlvine of oper. at. below) Travei Date Name Hours Charge 'Date ' Traveler Destination t- Distrarnent time Date SEM TEM XRD EMP IMP ' ESCA ' Hours Gharge Outside Services Date Photo Photo Materials Supplies Company HCharge Summary Cost! . Individuals 1_____ Instrument Travel Outside Other Cost Total L nn VA AUX UiUUi Project L dr____ Group Ldr _ _ _ PROJECT LEADER IMS ROUGH DRAFT ________ REPORT RECEIVED __ ,__ TOTAL CHARGE $ 1 0 BILLED TO CLIENT $ I P * INVOICE NO. (9) COL 00644 McCRONE 0169 )^6 tjU u o 5 February 1874 " f Mr. J. P Slmko, <fir, C tlggJ^dm olfr Couspsay H id DH aputnant 8QFUVwr HOad Fiwrtttawiy, i j 088M . Dear Mr. Bimboi We haya fleiehad pot muJyri e f your ewaplag daalgiwtadl 016. Caabmira Bouquet, wmJK, C. Hagai, . . In eena of tba sample did * detect tr*jU isj h a w s* , bryajdU waa dateatad i* id aftbamu wa; tf oto**, a dettata vital* prenant bab bava da iwdrap.^iaagitfwi>ft <o t)u ao niobi naba flytjiil* di8;$oo6*|ttfi:* 0*01 to** Oifc oh*f~ otta, Costater i& % 6 , :ta$U '~ 0*0001 t* O.01&. la M i i i l tlt* itiiulfll-'liiM i a Mah lavt BaitoSiiBt* ' ttitaphotemijBwgrttaft^^^ wttbiWB revert. H uait yott for cooaulUpg MoCronc A itatati Il yot bara aby quarto plastea do ta t b u ta i* to ta l* Yo*r**bj*ly, Kataswres Bonn H ot 8M u b ip itd taf**yp Hdaaaah Tedhalptioi COL 00645 McCRONE 0170 1 ___* J & i .0 -- ^ ----- z iJ k 2 /-^ ~ ^ iy a S ^ COL 00646 McCRONE 0171 McCRONE 0172 Cashmere Bouquet Diffraction pattern of previously shown eh iysotile fibers COL 00648 McCRONE 0173 W alter C. McCrone Associates, Inc. COL 00649 , McCRONE 0174 W alter C. McCrone Associates, Inc. COL 00650 McCRONE 0175 "WMF;SC Waiter C. McCrone Associates, inc. COL 00651 rV> McCRONE 0176 Waiter C. McCrone Associates, inc. COL 00652 McCRONE 0177 W aiter C. McCrone Associates, Inc. COL 00653 McCRONE 0178 Walter C. McCrone Associates, Inc. COL 00654 McCRONE 0179 . ITA L IA N TALQ AGEN CES. '* * * * * ^ 8 /^ S cctett /aotm ^ m ^ O T to a 9 O. G. A . BzM nem V Nipote Cuts Amwan `MATBUOAR," JU S.,CODSVMS CHARLES MATHIEU, lu Smpttriism P.O. BOX AM . 18*82 BANK STREET SUMMIT, NEW JERSEY 07901 REPRESENTATIVE IN TIRA. OF FOREIGN MINES Ra ^ 'A. ni (01) 277-OfilO . >t(r~ Jan u ary 10, 1979 Mr. Gene R. G rie g e r Senior Research P h y sicist W alter C. M ccrm e A s s o c ia te s , I n c , 2820 South M ichigan Avenue C hicago, XL 60616 D ear Mr, G rie g e r: Confirming o u r telephone conversation o f today, enclosed p lease fin d a sample o f t a l c marked "M onital 100, h o t 861800" which is a new so u rce f o r th e C o lg ate P alm o liv e Company, t h e i r s p e c if ic a tio n No. M-6277. P le a s e t e s t t h i s sam ple w ith th e u s u a l CTFA J 4 -1 m ethod and r e p o r t th e r e s u l t s to us and Dr. Simko in th e u s u a l m anner. Thank you f o r your cooperation w ith th e above. Very tr u ly yo u rs, CHARLES MATHIEU, INC. DEFseb o c: Dr. J . P . Slrako fiat jtairfN far icWMia hwtrrfd !>ycarrier. AHewtttteH* mid centra idrfto eondfclon beanti or contrat. Frf m ta rd ta t a t i ttttff rote* find tm m t xtiatton. COL 00655 McCRONE 0180 V w aiter a m ccrone associates, inc, 'A T CONSULTING: ULTRAMICflOANALYSIS MICHOSCOPY SMALL PARTICLE PROS LEMS SOLID-STATE CHEMISTRY 6 Ju ly 1979 Hr. Donald Parry Charles Matthdeu, Inc. P. 0. Box AM . Summit, HJ 07901 . .' Dear Mr. Ferry '1 Using x-ray diffractio n , transmission electron microscopy and selected area electron diffraction, we have analyzed a sample of Colgate ta lc, designated as wonotel $040, Lot 592200. . X-ray d iffractio n did not detect either amphlfcole or serpentine. We did, however, find th at some chlorite, a trace of o~8i0,,, some 'dolo mite, c a lc ite and a trace of magnesite were present in th is talc. The resu lts of our electron microscopic examination confirm th at'th ere are no asbestlform minerals, amphlhole or serpentine, present In th is sample e ith e r. The talc Is platy and has a' well-characterized crystal structure. Thank you fo r consulting HeCrone Associates. . Very truly yours, GRGismg enclosures HA-5500 Gene X. Gxieger Senior Research Physicist 2 0 SOUTH MICHIGAN AVENUE-. CHICAGO, ILLINOIS 6D61B . ai2/&tt-710t> . CABLE: CHEMICROfflS COL 00656 McCRONE 0181 COL 00657 Date S ' - 2 ^ - 7 f Client C MA Project r T o o Sample Description _ _ _ __ M o n i~hg / K-. o 4 o L o t S ^ l.'L -D 'O X-RAY DIPFRACTION Serpentine Detected__________ Amphlbole: Detected__________ Other Phases Present: Chlorite. Dolomite Calcite u*"* Other: ________________________ _ Net Detected _______ _ Not Detected ____ _ _____ a-SiOg Magnesite `^'fvmr^'Mtoa _ _ _ _ Commentsi ____________ ^_____________ ____________________ _______ ---- f . LIGHT MICROSCOPY . Chrysotile ___________ ' , % a -BlOg _ _ _ _ _ _ _ _ _ _ % Tremollte-Aotiuol ite _______ total % _____% fibrous Nonflbrous Serpentine ____________________________ i__________ ______ Others:________________________________ ._______________ Comments: waiter c. mccrone associates, Inc. COL 00658 McCRONE 0183 1? 4 ^' w aiter a m ccrone associates, inc, CONSULTING: ULTRAMICHOANALYSIS MICROSCOPY < SMALL PARTICLE PROBLEMS SOLID-STATE CHEMISTRY 6 Ju ly 1979 Mr. Donald F erry CharleB M atth ieu , In c . . P . 0 . Box .AH Summit, HJ 07901 . '. Dear Mr. Ferrys ` Using x -ray d iffra c tio n , transm ission electron, microscopy and se le c te d axe e le c tro n d iffra c tio n , ve have analysed a sample of C olgate ta lc , designated as monotal 6040, l o t 592200. ' Z -ra y d i f f r a c t i o n did n o t d e te c t e i t h e r am phibole o r s e rp e n tin e . Ve d id , how ever, f in d th a t some c h l o r i t e , 'a t r a c e o f cs-010. , some d o lo - m ite, c a lc ite and a tra c e of m agnesite were p resen t in th is ta lc . Hie r e s u lts of our e le c tro n m icroscopic exam ination confirm th a t th e re a re no a sb e stifo rm m in e ra ls, amphibole o r se rp e n tin e , p re se n t in. th i s sample e i t h e r . The't a l c i s p la ty and h s s a w e ll-c h a ra c te ris e d c r y s ta l stru ctu re. Thanh you f o r c o n s u ltin g MeCrone A s s o c ia te s . ' . Very tr u ly yours, GRGismg enclosures MA-5500 - Gene S . G rieger Senior Research Physicist '- ` ! . ] i I 2820 SOUTH MICHIGAN AVENUE . CHICAGO. ILLINOIS BD618.312784 -7100 . CABLE! CHEM1CRONE COL 00659 McCRONE 0184 ' tifi Tp . j t A l& r ^ c - / 7#~ / jS &<%~o /- > f T '/o yr? <**-*v- ex--* J ^ t --' J f* ^ . t C uf f - d w ^ L c P ^ ^ w * / O -pCrCK^M ^^Q ^ ^ ( ! lm4 4 4 TkDv' -- e ^ * / -w-gu-o A l~ *. 1? / ^ '^ n ''? ^ ^ - ,,4,j O yj& *air ' U c~ & e U--3 r M ^ i ^ - 4~ L , /'^ T P f*-?^ S / /^ . COL 00660 McCRONE 0185 w aiter c, mecrone associates, inc, CONSULTING: ULTRAMICROANALYSIS MICROSCOPY SMALL PARTICLE PROBLEMS 30UD-STATE CHEMISTRY 6 September 1979 Hr, D. R. Perry ` Charles Mathleu, Inc, r. 0. Box AH Summit, Hew Jersey 07901 Dear Mr. Perrys ' We have completed our analysis of ta lc Monital #6040 lo t 791000 received 1 August, and find I t free from asbeslform minerals. The ta lc was examined f ir s t by x-ray diffraction, which showed neither serpentines nor amphlboles present. An examination was then performed by electron microscopy combined with selected area electron d iffractio n . This examination showed l i t t l e evidence of fibrous m aterials present. High aspect ratio p articles observed In thlB ta lc were Identified by electron d iffractio n aa ribbons or sbards of ta lc. The majority of the ta lc consisted of good, platy talc. ' As usual, 'If you have any questions on th is work, please feel free to call me. Tours sincerely, lan M. Stewart Manager, Electron Optics Group IMS; f e Ref: 5500 cct Dr, J, Slmko - Colgate SCO SOUTH MICHIGAN AVENUE CHIGAGO. ILLINOIS 0 0 6 1 6 .3 1 2 /6 4 2 -7 1 0 0 . CABLE: CHEM1CRONE COL 00661 McCRONE 0186 s wi - ti 3 "! ' fI 9I COL 00662 McCRONE 0187 Client C Sample Description T & /c , Date 7 9 il* . C. .MA Project < S^T O o +a / <S,o 4 - o . / - 7 7 / O O d X-HAY DIFFRACTION Serpentine: Detected__________ Amphibole: Detected_____ Other Phases Present! Chlorite, Dolomite \r Calotte_____ O th e r:____________ ___ Not Detected _ Not Defected _ _____ a~St02 _ Magnesite Mica Comments: LIGHT MICROSCOPY Chrysotile Tremolite-Aotlnollte _ , - \ v: i. Nonflbrous Serpentine '_ Others: ____ " Comments: _% total % -a-SlOg. ___ % fibrous waiter a incerane associates, h a COL 00663 McCRONE 0188 To WAU35R C MCCHCNE ASSOC. IN 820 s o u m MICHIGAN AVE Chicago, h l . 60S16 Speed Letter. -\o' From_ CSFRUS IHDU3TRIAL MIMBRAIS [C L ^ e rrt 651 KEOTCHBN ROAD SOTOS PIiAIBITEEtD, H ,J. O?080 Subject -MPttoteload.Ti7jC rikt*raia G en tlem en * M168AQE -- Honital- TalajL A. i-nadfc-tq E n c lo s e d i s a sa m p le o f M eu cb le a d S a le H-6277 ( S o m it e l C a lc ) f o r y o u r r o u tin e is T e s t ig a t ie a fo r a s b e s to s m in e r a ls f o r C o lg a te-P a lm o - _________l i r e C o . P le a s e p r e form y o u r u s u a l w ork on t h i s sa m p le a n d fo rw a rd th e r e s u l t s to ub w ith a co p y t o J , S im p oo. BEPUf Date lO rrlS -7 9 : 1' Signed "-- V -Nhtrou nMuttPCiifl WUeonJnet Date Signed RETAIN WHITE COPY, RETURN PINK COPY *76 COL 00664 McCRONE 0189 Bate Client C v /p v c s I v y d u s i t i a J A?i*lier<i / g MA. Project Sample Description TZlI c- fit- >7.7 7 / 0 9 f S o d _______ X-BAY DIFFRACTION Serpentine: Detected Amphibole: ' Detected . Other Pbass Present: Chlorite Dolomite Calcite t-'" Other! ` Not Detected Not Detected ^ * CE--SiOo Magnesite Mica Commenta! LIGHT MICROSCOPY . Chryeotile ' ' ' . % a-S io 2 _ _ _______ % Trem oltte-Actlnoltte________ total % ' ' ' % fibrous Nonfibrous Serpentine________ |________ ____________________________ O thers:______________________________________________ '_______ _ ___ Comments; walterc. mccrone associates, ine. COL 00665 McCRONE 0190 >1 waiter c. mccrone associatesene. COL 00666 McCRONE 0191 COL 00667 McCRONE 0192 A sso o m ....? U ,... S h H f ..... - - ..........................^ ......... . \ I le , . . m : .... , ^ J X c $ ^ J \ O S f'& lk y & tfl, L & & ... , : i & - x y \/jU ~ & . & - ...jfc J & r . ..L Z ^ Q j . ....... i^ . iZ d n Z 2 k L i d / m A J iJ M . ..... _ i \ 4 4 ^ A ^ l ..........A..-.<T; i : : ^ _______ * : * 7 j > ; ....................../ r ^ .jS**r^(frfymyL-'Ls . / v ^ - 'I j E s u & V...& L , _ . J j t f L ( l A ^ i / U ^ ^ i X ^ ........ COL 00668 McCRONE 0193 COL 00669 McCRONE 0194 A w aiter a m ucrone associates, ine, C 0N 6U LTW 6; ULTRAMICROANALYSIS MICROSCOPY * SMALL PARTICLE PROBLEMS * SOLID-STATE CHEMISTRY 12 November 1979 Mr. John P. S h lff . Cyprus in d u s tr ia l M inersis ` 651 Metucheu Rood South P l a i n f i e l d , New J e rs e y 07080 . Dear Mr. S h lf f : We have com pleted o u r a n a ly s is of th e sample of t a l c la b e le d "Mono blend T a lc M-6277 (M onital T a lc ) Lot 109 1300". No a s b a s tlfo rm - m inerals were detected using x-ray d iffra c tio n and transm ission e le c tr o n m icroscopy. The t a l c showed ty p ic a l blocky anJ p la ty p a r t i c l e s and t a l c rib b o n s. The rlbbone were d i f f e r e n t i a t e d from a e b a stlfo rm m in e ra ls by s e le c te d a re a e le c tro n d i f f r a c t i o n . A IBM ' photom icrograph tak en a t 2,2,500X i s en clo sed . Thank you f o r c o n s u ltin g McCrone A sso c ia te s and I f you have any . questions concerning th is work, p lease contact us. Tours sin cerely . ' R ichard M. R i l l s , J r . Research H icroscopiot SMEtfe End. . R e f : 5500 - ce: D r. Joe Slmko, J r . - C o lg ate-P alm o liv e Co. 2820 SOUTH MICHIGAN AVENUE . CHICAGO, ILLINOIS 6 0B 1 6 .3 12 /S 2M 1 W . CABLE; CHEMICRONB COL 00670 McCRONE 0195 ' Spe@d Let&er, ' tfa ltc r foCrono A esociates Ino_________ Fmm Proras In d o strial H ierais Co. _____ 2828 South. Michigan. Are.______________ ____ 651 Metnchen Boad___________ C h icag o 1 1 1 . 6 0 6 0 7 __________________________ * c S o a th P ia ia f la ld . tr .J . 07080 si.hj.r,* Tat Sor Asbestos gibara_____________________________________________ _ IkUlVM MESSAGE 1 - Sample M onoblend Code h6277 Lot # 1291IOO i-L* V"\ Please nm yoar re g a la r te a t fo r sebastos jib a ra ani taloaed am p ie. Please send a a d d itio n a l copy o f y o u r re p o rt to J . S ia to . C olgate Palm olive C o.. Research Center \ -Nfciirvu 8S S - r" . - f . Date Signad RETAINWHITECOPY, RETURNPNKCOPY * .a' a'V -- *. . . F . . " S . ' 1. V " v i -- t -. . h? ." j I* '?- V COL 00671 ft McCRONE 0196 w aiter a m ccrone associates, ine, CONSULTING: ULTRAMICROANALYSIS MICROSCOPY SMALL PARTICLE PROBLEMS SOLID-STATE CHEMISTRY & Jan u ary 1980 Hr. J . P. S tif f Cyprus I n d u s t r i a l M inerals Company 651 M atuchen B,oad . South P l a i n f i e l d , Hew J e rs e y 07080 Dear Mr. S t i f f : . We .have com pleted our a s b e s to s a n a ly s is of t a l c sample Monoblend Code M6277 l o t #1291100. The x - r a y d i f f r a c t i o n a n a ly s is showed no d e te c ta b le a s b e s tifo rm m in e ra ls . The BUI a n a ly s is lik e w ise showed no d e te c ta b le a sb e stifo rm m in e ra ls. The sample was a ty p ic a l t a l c and co n tain ed a few fib ro u s ribbons. Please c o n ta c t us i f you bave any questions concerning th e work. Thank you f o r c o n s u ltin g McCrone A sso c ia te s. S in c e re ly KMEfjr Ref. Mi 5500 E n c lo su res c c : J . Simko R ichard M. E l l i s Research M icroscopist SO SO UTH MICHIGAN AVENUE . CHICAGO, ILLINOIS 90*16.312/842.7100 . CABLE: CHEMlCHDNE COL 00672 McCRONE 0197 Date Client C f) PctS-tY vt& U vtL . C o Sample Description fW o U ,& k \e * ,.d /Z .-/9 -7 ? MA Project .rT O fO L c f " ^ 7 G u n n X-RAY DIFFRACTION Serpentine Detected _________ Not Detected Amphibole Detected_______________Not Detected Other Phases Present Chlorite _______ a-SiOg Dolomite x S ' Calotte ^ Magnesite i/^ O thers_____________________ ________ _______ M ica_____ Comments:_____ .__________________ _______________________ LIGHT MICROSCOPY C h ry so ttle ' Tremollte-Actinollte _ Nonfibrous Serpentine _ Others: Comments: ;__ '% ____ total % a * .S i0 2 ________________ % `_______ ' % fibrous V waiter c. m^crone associates, inc, COL 00673 McCRONE 0198 'j r ' r r r c r f f r i c c c f { f f f r( C l >' C l 'C l C C l C (. . L COL 00674 McCRONE 0199 - "fl# 5U V / M u TEW w M U * 3 0 0 - . m u t . & k j ~ ^ l t M J U ^ . ^ J . X M ^ a ^ z* J / J f A A M A J L J c2 a M ^ . . M A A ^ ' tk - i u J b l ^ j ^ / Y A ^ / f W X A ^ i '_.L__ m s Q .__ ^ L - . C A P U L S ^ .^ .M ^ L .___ .2 m ,,.CL.....v l ^ - COL 00675 McCRONE 0200 Cyprus Industrial Minerals Com pany 651 Metuchsn Road South Plainfield. N J. 07080 Telephone (201) 754-4880 TWX710-987-0528 August 28, 1980 W a lte r C. M ucrone A s s o c ia te s , In c . 2820 South Michigan-,Avenue C hicago, 11 60618 G entlem en: Enclosed i s a sample of monoblend t a l c fp r your ro u tin e in v e s tig a tio n o f a s b e s tifo m u m in e ra ls f o r C o lg a te P a lm o liv e Oo. P le a s e p erfo rm your usual work on th is sample ana forward th e re p o rt to u s. Clot No. 802509) yours tru ly , CYPRUS INDUSTRIAL, MINERALS JP S /o r CYPRUS COL 00676 McCRONE 0201 waiter c. mecrone associates Inc. CONSULTING: ULTflAMICflOANALYSIS MICROSCOPY SMALL PARTICLE PROBLEMS SOLID-STATE CHEMISTRY 8 September 1980 fi Mr. J . P . S t i f f . Cyprus I n d u s t r i a l M inerals Company 651 M etuchen Road South P l a i n f i e l d , Hew Je rse y 07080 . Dear Mr. S tif f .' He have com pleted our asb esto s a n a ly s is o f a ta lc sample la b e le d Lot #601809. The sam ple was examined w ith the tra n sm issio n e le c tro n m icroscope. The sam ple contained no d e te c ta b le asb e stifo rm m in e ra ls. Thank you fo r consu lting. McCrone A sso c ia te s, i f you should have ' any q u e stio n s concerning th is a n a ly s is p lease c o n tact us. . Sincerely, R ichard M. E l l i s , J r . Research M icroscopist 5MB:fe Ref: 5500 ' cc: J . F . Simfco, J r . 1Sega SOUTH MICHIGAN AVENUE . CHICAGO, ILLINOIS SQS B . 312/B42-7100 . CABLE: CHSMlCnoNE COL 00677 McCRONE 0202 waiter c. mecrone associates, h a CONSULTING: ULTRAMICROANALYSIS . MICROSCOPY - SMALL PARTICLE PROBLEMS SOLID-STATE CHEMISTRY 1 9 'September 1980 - Mr, J . P . S t i f f Cyprus I n d u s t r i a l M in erals Cong?any 651 Ketuohen Road ' South P l a i n f i e l d , New J e r s e y ' 07080- : Q ear Mr. S tif f - X have com pleted' my a s b e s to s ' a n a ly s is o n ' a t a l c sa m p le-lab eled . L ot #802509. ' Hie sample was examined w ith th e tran sm issio n e le c tro n ' m icroscope and se le c te d a re a e le c tro n d if f r a c tio n . The. sample con tain ed no d e te c ta b le asbestifprm m inerals. ' - . Thanh, you f o r c o n s u ltin g MoCrcne h sso c ih te s * 'P le a s e c o n ta c t me i f you have any q u e stio n s. S in c e re ly , RMEigb R ef: 5500 c o j J . p* 81mko, (Jr. Richard.M , E llis , J r . Besaarch Jticroscopist - t SMO SOUTH MICHIGAN AVENUE . CHICAGO. ILLINOIS 6061 318 ^ 2 -7 10 0 . OABLEl OHEMICRONE COL 00678 McCRONE 0203 Cyprus Industrial Minerals Company 861 Metuohen Road South PlainRaki, N.J, oroso Tatephone <201) 754-4680 TWX 71O-097-BS2B January 13, 1981 W alter C \ McCrone A sso c ia te s, Inc. 2820 South Michigan Avenue Chicago, i l l , 60616 "S' Gentlinen; Enclosed i s a sample o f monohlend t a lc for your routine in v e stig a tio n o f asb estlform m inerals fo r Colgate Palm olive Co. Please perform your usual work on t h is sample and forward th e report, to u s. LOT# 110865 ' . yours truly, CYPRUS INDUSTRIAL MINERALS CO, REITH B. LEHMAN CYPRUS COL 00679 McCRONE 0204 16 March 1981 Mx. Lou Mrino Cyprus In d u stria l. M inerals 555 South Flower S tre e t L ob AcgelsB, C a lifo rn ia 90071 X, Dear Mr. Hurino: 1 have completed my asb esto s a n a ly sis o f a sample of Cyprus Konoblend T alc Lot #110865, submitted w ith K. Lehman's l e t t e r of 13 January 1981: The sample was analysed w ith th e tra n sm issio n e le c tro n microscope <TEM) and e le c tro n d if f r a c tio n . The sample contained c h ry s o tile asb esto s a t a le v e l le s s than O .li by w eight. The c h ry s o tile was id e n tifie d by i t s e le c tro n d iffra c tio n p a tte rn . Thank you fo r c o n su ltin g McCrone A sso c ia te s. P le a se co n tact us i f yon have any q u e stio n s. Sincerely, R ichard M. S l l i s , J r . Research Microscopit i Ref: 5500 cc: Vem A lltu s - Cyprus I n d u s tr ia l, MJ 2B20 SOUTH MlOHIOAN AVENUE CHICAGO, ILLINOIS 80BIB S1/W 2.710H CABLE; OHEMICHONe COL 00680 McCRONE 0205 A a /l ( M h > L A , * & {-. k j j k A s M $0 COL 00681 McCRONE 0206 RECEIVED A0 9 3 1381. Cyprus Industrial Minerals Company Talc Division 555 South Flower Street Los Angelos, Californie 90071 Telephone (213) 49-37O TWX (910) 321-5753 July 30, 1931 Mr. Richard M. E l l i s , Jr. Research M icroscopist Walter C. McCron'e A sso cia tes, Inc. 2820 South Michigan Avenue Chicago, I llin o is 60616 Dear Mr, E l l i s : In response to your January 1681 le t t e r addressed to Mr. Lou Murino, we would lik e to rec e iv e th e d iffr a c tio n p attern of the c h r y so tile a sb estos fib e r s which you observed in the Monoblend sample. P lea se send the d iffr a c tio n pattern to me a t: Cyprus In d u stria l Minerals Company 2485 M ilita ry Avenue W. Los Angeles, CA 90064 Thank you fo r your a ssista n c e . MIE into T echnical Services Manager CYPRUS COL 00682 McCRONE 0207 KfTl waiter a mecrone associates, inc. ' A A ' CONSULTING: ULTRAMICROANAtYSIS . MICROSCOPY SMALL PARTICLE PROBLEMS SOLID-STATE CHEMISTRY 26 August 1981 M& M oral M. K azazian Cyprus I n d u s t r i a l M in erals Company Talc D iv isio n ' 555 South Flower S tre e t Dos A n g e le s, C a lif o r n ia 90071 ' ' Dear K azaiian: I n re sp o n se to your l e t t e r of 30 Ju ly 1981, X have en clo sed the d i f f r a c t i o n p a tte r n o f th e monoblend t a l c sam ple #110865. The d iffra c tio n pattern is of a chrysotile single fib er taken at 200 kV. The sample contained a very sm all amount of c h ry s o tile and may have been a contam inant. The v ery sm all s i r e o f the s in g le f i b e r s (<*" 340 a d ia m e te r) nske i t d i f f i c u l t o r impos s i b l e t o g e t a d i f f r a c tio n p a tte r n u sin g le s s th a n 200 ItV. You - bad m entioned th a t you were ueing'low W . I f e e l th a t th is could, be the problem with seeing tbe p a tte rn . . P le a se c o n ta c t he i f you have any q u estio n s: Sincerely, Diehard K. E l l i s , J r . Research H ieroseopist HME:fe E n el. Ee: 5500 i m SOUTH M ICHIGAN AV EN U E. CHICAGO. ILLINOIS iOSIB . 312/842-7100 CABLE: CHEMICRONE COL 00683 McCRONE 0208 COL 00684 V T T T T T T r^n i COL 00685 McCRONE 0210 COL 00686 8288dS S QY3WS ii i ii i COL 00687 McCRONE 0212 ORIGINAL PURCHASE ORDER JERSEY CITY, N.J, ' PURCHASE ORDER NO. iquiLTo (Afe FURCHA9BORDBRNDo TYPEFSrix PERCtNT RCHH4. CHAR. DATE D T TENpORNUMBERn 4-\z - 1 i 1--1--1r-r. 1--1 14J - i L" ti ti \1a( t 11 M 'ti X1 *- XL j In) I..I - 1ISJ irwrlU - CODE1 CODE2HIP TOCODE9 eoe4 DCILOLDETCl COODlPECOUSHPTECTERRMATE TlntuifdI <2S0H1IP1-T5*7- i< :ir "103 n o - IOTI 44- 4j TOT" 4 t - a i COLGATE-PALMOLIVE COMPANY A DELAWARB CORPORATION 0 PARK AVENUE, NEW YORK, HtY* tM32 l .j . st (W T (U 1H> <i i 'lu I I M I,T1E.m1.ETIjJT I loiI , OTTiff J U HBBT?: 5% TM [1 S M I B X I T , X B J t J f M l V I T T . NoJ o 073Q2 7 GRAND STo X lif t J I W B T C IT Y . N .J. 0702 74 GRAND ST* X t * * JE R B ET C IT T f N.J. o n t lt REEHE IT . X M il XJ E R I E T C IT T * NoJ. |SB GRAMO T . 20 J B V H T fi|T Y < H/. * y j ^ - t g y [vtC y% ng s ^ ' d ^ H , BILL TO ' ' ' TORJC ETo X 3 ? fD _ J E R S ftT C I T T i NoJo 0 7*0 1 Z S ( z . ' M ich\'.^A + s A M C Jm C,A*<|Aj 4 (h C 1 Q t&-)ANhETuW&.nTUrOMHCREHINOiOTlHOWA,TLl.CSTTOoAMlTtIMiONKr .BOX 401 J K R IC T C IT Y . H .J . TIOS O u n ilO lN d . PRR X I M I ao X ar. x*-J o anoJ E R tE T C lT T . NhTo 0 7 J *R *E T C IT Y , U .J, 0702 DllCOUHT TERMS JHIPPH5 TERMS ATm WANTED BY " " TCsurnsrAwpWTiT.-H'**.. Z&oi *' EpM *ni mNETCASH a q c O Ui y i h b c: FFOOBBDttlopsstllMollPlt. (FPOiB*-SPkvlpyplnB*lP;IS.mMBkoTiwt clt* -I P A b flV K 6Art fgae ',gt kAHMsTttOoTTa,''BBfil p UU flTT )NOT IFV PATRICK PIETRANTOKIO 201-547-25 Ho c o m m it m k h j __ L C\3i% J __L i_ J_ I 1 i Youe wipwiuw-uo-tixrTuadrirtrM*rtH0.l2O*.i lljf/rdIwI ooInInIaccord_aLnewiththtainoand-cRoEnCdoftlpPaLaAsNuTthCaOfDyE! ATTUI tr/f carrier must CALL24HRS. PRIOR TO DELIVERY. aJnEdRb3aCcTkoCfItTMT-crItw< . Qu a n t it y CONVERSI* COLGATE N U M I** FACTOR VH* [PAH p S l C R f PT I 0 plyPRICE OPI* RtC. til. DO LLAR) FIER ffl(^n}Y e J r r r b j r F b j l . l r & -k y ' l y ~ lrf;d ^ & k a r m H t ' TAii 'F fl'T iL fti J n < L ' i ) ^ 4 ^ rp A L le c b r r } " 'P ~ A < A imt / ov* 4 V J\" gjA*.-? <hi/\ L.J.I 8 1 lo w . FREE FORNI ' l A oPn c " UMBCR,N,,>P 1N<J B O CU M U HT* I t t l T CO NTAIN a n a p p l i c a b l e 81J ^ O N T1 T*p H p A l'o F n eONTUB1 M3 P<2 ! I AT,O H CHAPOES MUST SE packages B , L L W w - v OF O R IG IN AL B U .1 O F L A D IN O . RyP ___ " * o r e e o W to R Tn &f t e Sw f a l i Td ? c iS S 5 U0REC/ iW JF .u"Wc fi-g l e r t if R ic HO., SYMBOL NO. a t io h th at y o u ANO h avu ' * * * * * * IL L h o t BE MADE A B A i H t ? - . a " * 0 m THE SACK rOF. M,lOE - " A 'M T PRO fo r m a IKVO tCE. / \ 0 t . 0 l / \ Ot.TO IL^I.I colgate-palm o u ve c o m p an y - No* VBffd uni*** ilgrm* by otithotlttd COL 00688 McCRONE 0213 ^ PROJECT COST RECORD PROJECT TITLE: CUSTOMER N3.; SPONSOR: ADDRESS: ta lc RCT 1004C 020420 CQLSIUlirpBl rt I ii.Vl ULWi-Aw. ................. _ tf , PROJECT B0.: 12917 BATE RECEIVED: 5 25 8 P .0. NO. TO6M2 COMMTTNENTS;$ Contact : ^ 5 ^ c '^ r (7 7 3 /}p G. Roach o rj t . P etersen fyifrfi K,Qfl<^ n - X > 6 H $ y G tfy Telephone Ko. : SUMMARY OF PROBLEM: Lab Notebook References: No. _ _ _ _ pp. _ _ _ _ M tiala _ No. _ _ _ pp, M tiala __ N o .____ p p ._____ M tiala ^ PhotomicrogTaphic record no. Sample disposai: r e tu rn e d ______ filed {where) ^ _ discarded _ _ _ _ DIRECT COSTS Individual time Date Name (Exclusive of oper. Mme on Inst, below) Hours Charge ^ ...... Travel Date Traveler Charge Summary Destination Cost' Individuals S ! Instrum ent Travel Outside ' Other Instrument time Date SEM TEM 5cr5 & P IM P ESCA EMMA MOLE Hours Charge Date Company Photo ' Photo M aterials Supplies Total Charge . Cost OK for billing Project Ldr Group Ldr tota l charge s 3fl__________ BILLED TO CLIENT $ __________ INVOICE NO. (S) Q tfi* - ' f y o / J S -3& PROJECT leader rme COL 00689 McCRONE 0214 w aiter c, mccrone associates, inc. c o n s u l t in g : u l t h a m ic r o a n a Ly s is m ic r o s c o p y sm a l l p a r t ic l e p r o b l e m s s o l iil s t a t e c h e m is t r y 26 July 1983 $ t G ^ 6 -tefr-ftr Roach C o lg a te -P a lm o liv e Company 300 Park Avenue New Ycojk, New York 10022 ' Dear 44ri Roach: I have completed ny asbestos .analysis o f a ta lc sample. labeled RCT10Q4C, Lot //12873 and submitted tinder purchase order 096142. The sanple was eocamined w ith the transmission electron microscope and belected area electron d iffra c tio n . The sanple was found to contain a vary low le v e l of chryaotile asbestoss probably le ss than 0.1% by weight. Because of tie lew amount, a second sample was prepared mod . eraninecl to preclude the p o ssib ility o f contamination. I t too /vwn-a-tTwl dhryaotile. Tro photanicrographs o f ch ry so tile fibers are enclosed. Shank you fo r consulting McGrone .Associates. Please contact me i f you have any questions regarding th is analysis. Sincerely, Richard M. E llis , J r . Research Microscopiat- RME:e Enel. Ref: 12917 ZffiO SOUTH MICHIGAN AVENUE * CHICAGO, ILLINOIS SQSL6 31W84J-TlQn * CABLE CHEMICROttE COL 00690 McCRONE 0215 b a tte r c . V e r o n e o s s o c fa te s /n c C L 069J CRONE0216 COL 00692 McCRONE 0217 j rc" \ a U 71 ft ^ f .i f w U L - ( s 'T l si/v u ix ^ m ^ d . a ju ^ jJL " J ^ . A fl.& T <x ^ vv- J L a J ^ ^ a ^ J L j u ^ \a s p J L L ^ ^ ^ a i t y g r S : c j ; * A ^ i | . ll/ILvI , ^ ^ /- v 'k -a X j y ^ u & I .J l J 7 \ J r A > _ia M l - z M & lC (H - . ^ j ^ a s A J : _ ^ j-J^ /P L j ^ . 'f P ^ y v A u ^ . V L A fl^ 3 > P i u K i /lA A Av V s jj' (X, / ,s d /V * y -^ s ' L 4 ^ S ^ V : -,,W i; `.;A jV \ J ^ / l l s L A A r J s v^(> J ^ W \ J^ 4 ^ i . ,0 ,fl^ l d fa l/y Y v > V ^ ^.u ,^ ~ / L - ^ r y ^A . ^ M y .A COL 00693 McCRONE 0218 S MEAD a e SP<78 c if ' I 'i Ii :i COL 00694 McCRONE 0219 i ' PROJECT COST [RECORD PROJECT TITLE: ^ snple Laic Soc TEN CUSTOMS?. NO. 0: 20420 SPONSOR: ADDRESS: OCKfiATB-ElMTEJVE CD 909 Rlver" / ^ .-- '-- ------- ----------'Pi\,i.eXf>vfap } J Z 0 p I JPROJECT TOU871 DATE RECEIVED! g& P .0 . KO CG-MIT-IEIxS-.S Contact: f t cc report Co: ** L v. q "TelSpt^ae/ *).878 7666 [cdividunl tirr.e Jte Narr.e Sagole d isp osal: r e Curried discarded consumed . DIRECT C0STS (E xclusive o cper. ' , fcio on i n s t , below) Charge Sumarv H ours______Charge ' Individuals I* Instrument | Travel. l Outside. ] Other j Total t . charge 1$ "' . Inntr.rrenc tir e EMt> iivl UM W i 1lv^ :l 1*T i," " a '* " Date Houra Charge TOTAL GL'JCCS $1 9*0 LAOid:-: ."fl. DPP- v>\tl\ FROJLCT IJvJJEt Cost CSC fo r b i l l i n e Project lender_ Croup leader___ Photo 'ncoriaLs' iiuonUus 1 % _________ 1 COL 00695 McCRONE 0220 * w a ite r c. m ^crone associates, inc; CONSULTING: ULTRAM1DROANALYSI3 MICROSCOPY SMALL PARTICLE PROBLEMS * SOLID-STATE CHEMISTRY 27 A pril' 1984 Dr. J> P. Simkfl, J r . Sr. Section Head, A nalytical Department Colgate-Palmolive Conpany 909 River Hoad Piscatsway, Hew Jersey 08854 Dear Dr. Sinko: This rep o rt concerns th e asbestos analysis by 3EM o f six ta lc camples submitted under your P.O. 634617. C hrysatile asbestos was detected in saoples 0613BK, 2713ES and 1813AX. Kfo asbestos was detected in samples S9073, A122831 and A113031. Since th is technique is not q u an titativ e, no asbestos concentration can be assigned. - Shank you foe consulting McCrone A ssociates. I f you have any questions, please do not h e sita te to c a ll. Sincerely, Deborah P. Palenik Electron M icroscopist DPP:fe Ref: 11871 2820 SOUTH MICHIGAN AVENUE * CHICAGO, ILLINOIS 60618 S12/W 2-7100 CABLE CHEMICRONE COL 00696 ft McCRONE 0221 `= } /$ 0 , o O ~ y / <?'J ?*-'*'7c C sf & C A`*'?'*I ~~At c? S J* 5 (A t^> &L. S C t `J ^ ' SApC ~&A-__, C5" j\ Cuy^ '~ *cS <3 7 S 3 ~ y A O ^ ^ < 3 ^ is 7 ' (3 p ? s i& o S ^ - C - t / ^ - i ^ \j v * S c s - r ^ l^ L -vS ///? /T / * $ * 4 S e S & j& OiS^fJcp c - ir -* - S <Pe~*-*pif C ^ ~3r5f < 5 ~ ^ 2 f3 j 4? / P -^ 3 / 's ? '/ 3 OZ / . A x A ^ j 7^4; ? T--L ^ sr^ t^ p / 6 * ^ ^ L' O S ''^S ^6 - S C^x> ^ ^ ^ u A - ~ & '/s*tf^ '> O a * * <4 J < s ' s /< /? e c ^ , a /r ? c & ^ /-^ < U t - f s* . y sy < Z - *7 s ' <*(/''/ '? & s? $A /J `^f cs sCf l ?/ ,m* , ~4 a S>v c~ 7z ~ r- A/ j , ( ^ ( y/ yA / -c t* 4 ? -*Z a ' S 7 - / tr s x - ( r. 4 c& 4 - s? 4 '--SssA c J /A . r S ;* COL 00697 McCRONE 0222 COLGATE-PALMOLIVE COMrANY Research a n d Development Division WSgiWftoid PBcaawtyNjOBS54 January 24, 1984 Ms. Deborah P a le n ik HcCroue A sso c ia te s 2820 South Michigan. Avenue Chicago, 3X 60616 Dear Ms. P a le n lk s E nclosed a re 6 astaples o f t a l c f o r a n a ly s is f o r a s b e s to s by TEM and SAED. The th r e e coded 0613BK, 18I3AX and 2713EX e r e f in is h e d p ro d u c ts and c o n ta in IX magnesium, c a rb o n a te , IX z in c s t e a r a t e and perfum e as a d d itiv e s . The rem ain in g th re e B09073, A113031 and A122831 a re raw m a te r ia l t a l c w ith no a d d itiv e s .- ' Please analyze these as soon as p o ssib le . - _ A purchase order to cover coats w ill follow . I f there are any questions, my te le p h o n e number i s (201) 878-7666. Thank you. S incerely yours JPSfmeb cc: P. A. Mutiger W. S c h u b e rt D r. J . P, Sioko, J r . S r . S ectio n Mead A n aly tical Department COL 00698 McCRONE 0223 /iL /J7 _ S - $ t> COL 00699 McCRONE 0224 M A y I t R E P R O O U C fiD MMQH Of MXATNM MUI MX jjX jl?-?9V 0Q l M w ifM i) ?tw wndarolthod pvfdiaoor mtMIm Aar H h not raqalrod *o pay (fit Now Ju d y W it and/or Um Tok on ihopyrthtM or ptnA tiM m m ti by Ab CorttWMo I f w> A t I* nlbb portanti y ty irty pvr. twMd wM ba Mad fcr an tntmpf ptrpaM- Sold Nmgltal* ptrrorwl prtptrty wM b vtod for tho following p<Jrpo*t> A ir pda OV. cootuwtion dlradtijr MdmUiglvily la N iw A ad Am&qgptb,, a tho tfr tJ iM n til o r m a n im u iy M I . -- Th* wwnp lwi oh A t alt al m M ttngttli parotnl yroporfy ft bt wad fw A t lova d o M rlb ad mpi pvrpoM i prowMfd In ndwtWlt.il NJA. ^ jflftt m m tilt fyr foffetf of ptlndpul I tMopr m i ^ wngibfo porroad prtporfy and 0 ft Ao ftfeofc wth pryor rotrtdfoa rlM bn/ I, A t vndwolgnod pvrdmmr, horn'rood and wwpHod with A# (rntratriont and nib* ptoMvtgaM P nmol M A t Now Jormy lo b t and Uw Tot A*i with rtiptcl * A t wot of A * Cimnpi Um Corficai*, or I mp M b f tb*f A# mador nomad boron N nor roqttrod fo cofloct A t wit or w * tax on ih* Iran*- (bn or. ironwtdant mvond by A * CirtA toH. Th. vndmifntd Jwrtfo-T boroby *wton (ondtr th* pmnlrtti for porfvry and M m owaariagj that I of Ih informoH*n obown fn Ah CortMtato I* two. __ ________ coum~MoiQuvs comunr 105 ECKIOtT 8 T . , jjesmaaeit oourr, nir. jj,. 0730a (BQUIBSRT hjbchashtg secticst) COL 00700 McCRONE 0225 v.- , termsandconditions . : : ' INVOICES - The Seller's invoice lotothwwith 'the original 81) .of ltd ir* of exprMJ receipts, properly signed by the a irie r, shiUbc ' " mailed qn the day of shipment to 'the Purchaser. ftdMduiil IsvbltM shtD h i Issued for shlpmehlt applying against each purchase order- Monthly statements must be mailed as soon a) possible after the first or each month. WARRANTY --The Seller expressly warrants and agrees that Ifaurehas been compliance with and no violation Ofany trademark rights, . patent r([[lil*,cqpyrbht, of any rule, law or regulation of the federal Government or of any Stale or any of tliclr respective agencies or nollUeal imbdiYMons, in Ute manufacture. produclkm,asle and or etiipmcni or the goods here-under: and the Seller wit) Indemnify anti hold Purdiaser hanntnss from any or alt costs, damages, fines or expenses (including counsel fees and fees of expert witnesses) which may tie incurred by the Purchaser by reason of any claim cr suit arising out of the Infringement of any Irademarit, patenl right or copyright and/or by mason of any citation, claim or suit for damages and/or penalties brought against the Purchaser bused Upon sny Injuries, damogns or violaUoitsreeulllngor daunt'd to havr resulted from any alleged infringement or defect in such gooda or Ingredients or parts thereof,' EQUAL EMPLOYMENT OPPORTUNITY ~ Tile Equal Employment Opportunity Clsuae Section 302 of Executive Order USA6 as amended related to Equal Employment OppOrlunitlrs slid Implementing Rules and Regulations of the farm- buy of Labor; Section SOS of |he lluliabllltalion Act 011973; Srotlon 402 of (lie Vletnxm Era Vetonn's ReBtUultment Amlstsnce Act of 1974;snd ExccaHvr Order I [iM h ittin g to minority buxtnmw enterprises are incorporated herein by apeciftc reformer.. CHANGES In ORDER - This order .cannot be changed, modified or discharged in any manner except by agreement in writing rigned by a duly authorized representative oflhe Purchaser. The Purchaser reserves the fight to (I) make changes in the order (I) esncel ill or any p u t of the order at any time, by notice in writing. The Purchster shall not be responsible for coat incurred by the SeBer In cottneodon widi this order, after the date of receipt of the change or cancelation notice. Uidass the Seiler presents to the Purchaser an Itemtsed statemaot of claim against thePerchaser within twenty (30) day after the receipt o f notice o f such change or cmctSttion. the Seller fiutU be conclusively deemed to have waived an rialmi against the Purchaser with respect thereto. CANCELLATION for SELLER'S DEFAULT - Should the Salter fail (I) to effect delivery on or before the specified delivery date (a) (3) to dotlvet gooda In nD respects conforming with the requirements (3) In the due performance of each and ail of the terms and ' conditions of this order, the Purchstej may cancel this order in whote or in part- Without prejudice to the foregoing, the Seller agrees to report promptly, to tit* Purchaser W act or specified delaysin shipment of the goads covered by fids order. - SPECIFICATIONS. DRAWINGS, etc. - All speculations, drawings, plans, designs, sssnples, or other descriptioh.referred to in this order . (hall be deemed an Integral part of this order as fully si If set out In full herein and ScDer warrants that ail deliveries hereunder shall conform thereto, each delivery being subject to the Inspection and npprovnl of the Purchaser, whether or not any prior payment shall - have been made theraon.by the Purchaser- NONCONFORMING MATERIAL - If Saner dalhen defective materia! or msterlil not conforming to the agreeiKipon specifications, Purchase! may U ) hold such material at S d W s expen pending Instructions as to disposal, (3) return It to Seller nt Seller's expanse, or (3) utilise it In the form received or after up-grading or other operations are performed on ft, or m il it in a different manner or in different proportions with other products than via intended, and Seller will be liable for any diminution In the value to Purchaser of Hi* material snd for any boldenlal or other damages suffered by Purchaser resulting from such defectiveness or nonconformity. No replacement of defective or nonconforming material wtli be mods by Saber unless authorised by Purchaser, PACKING - The Purchaser w il allow no charges for boxing, packaging or anting unless by written agreement. Material must be packed, Shipped and billed in conformity to daieiR atio n requirement pessary to secura minimum freight rates. OUR COUNT - The Purchaser's oount wfit be adapted as final and eonohifive on all Shipments not aeoompanled by a picking ticket. LIABILITY for DAMAGES - Whenever Sallee shall, by virtue hereof, Hive property of the Purchaser In its postceilon. theSeller dull be ' doomed an insurer thereof and riiill be responsible for its a f t return to the Purchaser. ASSIGNMENT - This order shah not be assigned or transferred without prior written consent o f the Purchaser- WAIVER - Purchiscr Shall not be deemed to have waived any of Its fights hereunder unleu such waiver shafi hive been signed by a duly authorized representative or the Purchaser. No such waiver, unless expresdy staled therein, shah be effective as to any delivery nr other tnnsactioc which occurs subsequent to the date o f tbi waiver, nor as to any continuance of a datbult after such data. DELIVERY INSTRUCTIONS SHIPPERS MANIFEST - . . . . . A.SHIPPERE MANI FEST Is provided for each lead and must ' ' cchftipsnj etch'shipment. JERSEY CITY TRUCK DELIVERIES - RESERVE UNLOADING SPACE AND TIME by telephoning 201-647-2910, ' '' ' JEKsEYi'.cfrWRAf^ j - ':... j i i ^ t i l l l d i ^ pj.f ^ ^ A f L 'il^ - o n i^ ^ 'f lB .- ^ r tj _ ^ 'V j' : ;JE^FERSONyilX|:R!L.p^Yeiil^S L .1 ..PriYtl*Wing-qft t^fNIRAIL or^SW.TJMQH.^is OVliO ' ' ' ' i,:R M R A :' .; - ,- .: - .w. . . Kahlas City,r a i u d e u VEr Ies - ; :; ;pfivtie >)diicn.K&f/.SASctTY-squTHEpN.jjaiLROad co.. ' BERKELEY RAl L DELIVER IES - : ` '' 'Private tiding dn SOUTHERN PACIFIC RAI LRdAP: ' '' ? --r. - '' ' . >}. COL 00701 McCRONE 0226