Document 3Q8mqOZxxe58kK8QmrVjLDp6O
Tenneco Polymrs
A Tenneco Company
MATERIAL SAFETY DATA
number
168
(Approved by U.S. Department ot Labor as "essentially similar" to FORM OSHA-20)
SECTION I IDENTIFICATION OF PRODUCT
MANUFACTURER'S NAME
TENNECO POLYMERS, INC., RESEARCH AND DEVELOPMENT
EMERGENCY TELEPHONE NO.
609-386-9200
ADDRESS
P.0. BOX 129, RIVER ROAD, FLEMINGTON, NEW JERSEY 03822__________________
trade name and synonyms
1684, 1688, 1689, 1755-1 , 1755-5, 1776-2,
TENNECO PVC COMPOUND, RECORD 1809, 1815-2, 1820-6
CHEMICAL NAME AND SYNONYMS
VINYL CHLORIDE - VINYL ACETATE COPOLYMER
/'ucuirif auii v
CHL0R0HYDR0CAR80N COPOLYMER
MOLECULAR FORMULA
(CH2CHC1) X 4CH?CHOCOCH34v
MOL. WT.
SECTION 11 COMPONENT
HAZARDOUS COMPONENTS OF MIXTURES
THRESHOLD
A LIMIT
VALUE
(UNITS)
COMPONENT
Carbon Black Lead Compounds
(0.1-1%) - 3.5 mg/m3 (0 -2%) - 0.2 mg/m3
THRESHOLD
A LIMIT
VALUE
. (UNITS)
SECTION III
APPEARANCE ano ODOR Black pellets, practically odorless
BOILING POINT (OEGREES FAHRENHEIT)
Not applicable
VAPOR PRESSURE (MM. OF MERCURY)
Not applicable
VAPOR OESnT (AIR s II
Not applicable
solubility in water
Negligible
PHYSICAL DATA
(degreesFahrenheit)
Not applicable
Softens about 130-150F
SPECIFIC GRAVITY (WATER 1)
1.35 - 1.39
PERCENT VOLATILE (BY WEIGHT)
Essentially non-volatile
EVAPORATION RATE (Butylacetate i)
Not applicable
SECTION IV FIRE AND EXPLOSION HAZARD DATA
FLASH POINT (SPECIFY METHOD! IQI11 tl OH abOUt 735F
(DEGREESFAHRENHEIT!
- ^-..,2 , ' " ," ,
,
______________ for PVC (ASTM D-1929)
FLAMMABLE LIMITS (PERCENT BY VOLUME!
FIRE EXTINGUISHING MEDIA
Water spray, carbon dioxide or dry chemical
LOWER
UPPER
Not applicable_________
SPECIAL FIRE-FIGHTING PROCEDURES
Water spray or fog may be helpful in reducing flame intensity and absorbing
irritating funes. Shut off current in electrical equipment or wiring.
N L HAunusual fire ano explosion hazards lists ignition temperature of 608F for PVC-plasticizer dust cloud and minimum concentration of 0.035 oz./cu. ft. Fire conditions produce hydrogen chloride, requiring protective equipment.
!U ni *nv kffttf. XC#pt tftt! rl t ftCCUffte to t*# feMt Of T*fif*C0 Pofvmn krwvl*0iM Of
TEN 2856
SECTION V HEALTH HAZARD DATA
JHRESMOLD LIMIT VALUE
See Section II
EFFECTS on OVEREXPOSURE
None expected in normal handling. (Processing at high temperatures produces irritating to eyes and respiratory tract, requiring local exhaust).
fumes
EMERGENCY AND FIRST AID PROCEDURES
Ordinary measures of personal hygiene. (See Section IX). (In case of exposure in hot processing move to fresh air, flush eyes with water).
SECTION VI REACTIVITY DATA
stability
unstable
STABLE
Normalconditions to avoid processing temperature, about 350F causes slow darkening and decomposition. Higher X heat increases rate and evolution of HC1.
INCOMPATIBILITY (Mattritl, to ,*onll
None in ordinary use. Soluble in certain ketones and organic solvents.
hazardous DECOMPOSITION PRODUCTS
Thermal decomposition produces HC1, and CO and C02 (above 570F).
HAZARDOUS POLYMERIZATION
MAY OCCUR WILL NOT OCCUR
conditions to AVOIO
X None in ordinary use.
SECTION VII SPILL OR LEAK PROCEDURES
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED
Sweep up and remove to disposal container.
WASTE DISPOSAL METHOD
Bury in an approved landfill.
SECTION VIII SPECIAL PROTECTION INFORMATION
RESPIRATORY PROTECJION (Sovcity iypl
None required in ordinary handling. See Section IX.
ventilation
LOCAL .EXHAUST
For hot processing.
MECHANICAL <Gnr,l| ,
For ordinary handlino.
$enLt0 stack or scrubber. tfenEilate enclosed spaces.
PROTECTIVE GLOVES
EYE PROTECTION
Cotton gloves for hot processing.
Safety glasses.
Noneother protective eouipment required for ordinary handling. For hot processing
exhaust, safety glasses and gloves are recommended.
local
SECTION IX SPECIAL PRECAUTIONS
precautions to be taken in handung and storing OSHA Standard 1910.93q(. 1017) on vi ny 1 ch 1 o ri de 1 i mi ts
exposure to lppm (8 hrs av.) and requires monitoring and other precautions in storage
handling and use of polyvinyl chloride, including labeling "Contains Vinyl Chloride -
Vinyl Chloride is a Cancer-Suspect Agent", excepting "fabricated products" not subject
to ""mass melting", as defined. New, Tow monomer content PVC compounds simplify
operation below the OSHA 0.5ppm action level and compliance, assuning normal conditions
and ventilation in a.processor's work area. Further developments on resins and
regulations are pending.____________________
_____________________________________
r f\*fe
1
TEN 2857
LTENNECOJ Tenneco Polymers
A Tenneco Company
MATERIAL SAFETY DATA
NUMBER
200
(Approved by US. Department ot Labor as "essentially similar" to FORM OSHA -20)
SECTION I IDENTIFICATION OF PRODUCT
MANUFACTURER'S NAME
TENNECO POLYMERS, INC., RESEARCH & DEVELOPMENT
aOORESS
RIVER ROAD, P.0. BOX 129, FLEMINGT0N, NEW JERSEY 08822
TRADE NAME AND SYNONYMS
TENNECO PVC COMPOUND, RIGID 3780, 3782
CHEMICAL NAME ANO SYNONYMS
poly(vinyl chloride) compound
CHEMICAL FAMILY
CHL0R0HYDR0CARB0N POLYMER
MOLECULAR FORMULA
(CH?CHCl)n
EMERGENCY TELEPHONE NO.
609-386-9200
mol wt
SECTION II HAZARDOUS COMPONENTS OF MIXTURES
COMPONENT
Tin Organic Compound
threshold
% LIMIT
value
(UNITS)
(0-3%) - 0.1 mg/m^
COMPONENT
Acrylic Resin
(0-2%) - 10 mg/m3 (ACGIH)
THRESHOLD /. LIMIT
VALUE
(UNITS)
SECTION III PHYSICAL DATA
APPEARANCE ANO OOOR White or colored pellets. practically odorless.
BOILING POINT (DEGREES FAHRENHEIT!
Not applicable
VAPOR PRESSURE (MM. OF MERCURY)
Not applicable
VAPOR desity
(AIR * 1|
~
Not applicable
solubility in water
Negligible
MELTING point (DEGREES FAHRENHEIT!
., ^
. .,
Not applicable
Softens about 160 - 180F
SPECIFIC GRAVITY (WATER m 1)
1.32 - 1.42
PERCENT VOLATILE (BY WEIGHT!
Essentially non-volatile
EVAPORATION RATE (BITTYLACFTATE * 11
Not applicable
SECTION IV FIRE AND EXPLOSION HAZARD DATA
PLASH POINT (SPECIFY METHOD) I n n l'1O n
about 735F auto-(DEGREES FAHpENtHfilT)
. 'i-
flammable limits
(PERCENT BY VOLUME)
ignition about 850F (ASTM D-1929)
LOWER
Not applicable
UPPER
FIRE EXTINGUISHING MEDIA
Water spray, carbon dioxide or dry chemical
SPECIAL FIRE-FIGHTING PROCEDURES
Water spray or fog may be helpful in reducing flame intensity and absorbing
irritating fumes. Shut off current in electrical equipment or wiring.
unusual fire and ExPLosioN hazards NFPA lists ignition temperature of 752F for layer and 1220F
for PVC dust cloud. Produces combustible gases above 570F. Fire conditions produce hydrogen chloride, requiring protective equipment.
This information it fomlthod wltnoof warranty, rtprttontaifon, Inducamant Of licont# of any kind, axcapt tnat it it accufaia to fh# boat of Tonnoco Polymar* Lnowiadot or
TEN 2858
SECTION V HEALTH HAZARD DATA
THRESHOLD LIMIT value
See Section II
fc*CTS OB OVEREXPOSURE
None expected in normal handling. (Processing at high temperatures produces irritating to eyes and respiratory tract, requiring local exhaust).
fumes
EMERGENCY AND FIRST AJO PROCEDURES
Ordinary measures of personal hygiene. (See Section IX). (In case of exposure in hot proce-sing, move to fresh air, flush eyes with water).
SECTION VI REACTIVITY DATA
STABILITY
UNSTABLE
stable
conditions to avoid Normal processing temperature, about 350F, causes slow darkening and decomposition. Higher X heat increases rate and evolution of HC1.
INCOMPATIBILITY (Mtranaii to avoid!
None in ordinary use. Soluble in certain ketones and organic solvents.
HAZARDOUS DECOMPOSITION PRODUCTS
Thermal decomposition proc uces HC1, and CO and CO? (above 570F).
HAZARDOUS POLYMERIZATION
MAY OCCUR WILL NOT OCCUR
CONDITIONS to avoid
X None in ordinary use.
SECTION VII SPILL OR LEAK PROCEDURES
TEPS TO BE TAKEN IN CASE MATERIAL IS RELEASEO OR SPILLED
Sweep up and remove to disposal container.
WASTE DISPOSAL METHOO
Bury in an approved landfill.
SECTION VIII SPECIAL PROTECTION INFORMATION
RESPIRATORY PROTECTION <S;*city typal.
None required in ordinary handling . See Section IX.
U^CAL EXHAUST
For not Drocessina. TWSfolW handling.
PRCTdt1tvdnL^f&ves for hot processing.
\ZerrLto stack or scrubber.
tfen?ilate enclosed spaces.
EYE PROTECTION _ , .
,
Safety glasses.
.
other protective equipment None required for ordinary handling. For hot processing local exhaust, safety olasses and oloves are recommended.
SECTION IX SPECIAL PRECAUTIONS
)SHAPRECAUTIONS TO BE TAKEN IN HANDLING ANO STORING Standard 1910.l0l7(.93q) on vinyl chloride limits exposure to lppm (8 hr av.) and requires monitoring and other precautions in storage, [handling and use of polyvinyl chloride, including labeling "Contains Vinyl Chloride Vinyl Chloride is a Cancer-Suspect Agent", excepting "fabricated products" not subject to T'mass melting" as defined. New, low monomer content PVC compounds simplify operation ielow the OSHA O.Sppm action level and compliance, assuming normal conditions and ventilation in a processor's work area. Further developments on resins and regulations are pending._____________________________________
DATE 3/12/84
NAME ANO TITLE D. GOODMAN, PRODUCT REGULATIONS
200SHEET NUMBER
TEN 2859
[TtMfcqJ Tenneco Polymers A Tenneco Company
MATERIAL SAFETY DATA
NUMBER
T90
(Approved by U.S. Department ot Labor as "essentially similar" to FORM OSHA-20)
SECTION 1 IDENTIFICATION OF PRODUCT
MANUFACTURER S NAME
TENNECO POLYMERS, INC., RESEARCH & DEVELOPMENT
EMERGENCY TELEPHONE NO.
609-386-9200
address
RIVER ROAD, P.0. BOX 129, FLEMINGTON, NEW JERSEY 08822
taaoe name and synonyms
TENNECO PVC COMPOUND, RIGID 3773, 3774, 3775
CHEMICAL NAME AND SYNONYMS
POLY(VINYL CHLORIDE) COMPOUND
rucuim cauii y
CHL0R0HYDR0CARB0N POLYMER
molecular formula
(CH2CHCl)n
MOL WT.
SECTION II COMPONENT
HAZARDOUS COMPONENTS OF MIXTURES
THRESHOLD V. limit
VALUE
(UNITS)
COMPONENT
Tin Organic Compound (0-3%) - 0.1 mg/m3
THRESHOLD % LIMIT
VALUE
(UNITS)
SECTION III PHYSICAL DATA
APPEARANCE ANO ODOR
White or colored pellets, practically odorless.
BOILING POINT (DEGREES FAHRENHEIT)
Not applicable
VAPOR PRESSURE (MM. OF MERCURY)
Not applicable
(mDeElGtRinEgESpFoAinHtRENHEIT)
NntL a0D^D1li'cLaflUblIeC
Softens about 160 - 180F
SPECIFIC GRAVITY (water m i)
O37TT7O3, O37TT7C5 3774
11.4A4A - 1t .4A8n
1.40 - 1.44
vapor desitt
(AIR * 1)
Not applicable
PERCENT VOLATILE (BY WEIGHT)
-
Essentially non-volatile
Solubility in water
Negligible
EVAPORATION RATE (BUTYLACETATE * i)
Not applicable
SECTION IV FIRE AND EXPLOSION HAZARD DATA
(fOlEafsPhpo^in5t(srpeacifotmuethtod)85ig0*nFitio(AnSTMabDou-1t92793)5__F__a__u_t_o
flammable limits
(PERCENT BY VOLUME)
LOWER
Not applicable
UPPER
FIRE EXTINGUISHING MEDIA
Water spray, carbon dioxide or dry chemical.
SPECIAL FIRE-FIGHTING PROCEDURES
Water spray or fog may be helpful in reducing flame intensity and absorbing irritating fumes. Shut off current in electrical equipment or wiring.
NFPAunusualfireandexplosionhazaros lists ignition temperature of 752 F for layer" and 1220F
for PVC dust cloud. Produces combustible gases above 570F. Fire conditions produce hydrogen chloride, requiring protective equipment.
TEN 2860
SECTION V HEALTH HAZARD DATA
resmold limit value
ee Section II
EFFECTS OR OVEREXPOSURE
None expected in normal handling. (Processing at high temperatures produces irritating to eyes and respiratory tract, requiring local exhaust).
funes
EMERGENCY AND FIRST AJO PROCEDURES
Ordinary measures of personal hygiene. (See Section IX). (In case of exposure in hot processing, move to fresh air, flush eyes with water)
SECTION VI REACTIVITY DATA
stability
unstable
STABLE
INCOM PATIBILITY (Malarial, to trend.
None in ordinary use.
conditions to avoid Normal processing temperature, about 350 F, causes slow darkening and decomposition. Higher X heat increases rate and evolution of HC1.
Soluble in certain ketones and organic solvents.
HAZARDOUS DECOMPOSITION PRODUCTS
Thermal decomposition produces HC1, and CO and CO2 (above 570"F).
HAZARDOUS
polymerization
MAY OCCUR WILL NOT OCCUR
CONDITIONS TO AVOID
X None in ordinary use.
,
^ SECTION VII SPILL OR LEAK PROCEDURES
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED
Sweep up and remove to disposal container.
WASTE DISPOSAL METHOD
Bury in an approved landfill.
SECTION VIII SPECIAL PROTECTION INFORMATION
RESPIRATORY PROTECTION (Spaeify lytl
None required in ordinary handling.
LFOoCArL EnXHoAtUSTprocessing.
See Section IX. Ver$ALto stack or scrubber.
FocrAorcfffiary/ handling.
\/eTnlRilate enclosed spaces.
PROTECTIVE GLOVES
EYE PROTECTION
Cotton gloves for hot processing.
Safety glasses.
Noneother protective equipment required tor ordinary handling, tor hot
exhaust, safety glasses and gloves are recormended.
processing
local
SECTION IX SPECIAL PRECAUTIONS
OS HA Standardprecautions to be taken in handung and storing 1910.1017(. 93q) on vinyl chloride limits exposure to lppm (8 hr av.) and requires monitoring and other precautions in storage, handling and use of polyvinyl chloride, including labeling "Contains Vinyl Chloride Vinyl Chloride is a Cancer-Suspect Agent", excepting "fabricated products" not subject to "mass melting", as defined. New, Tow monomer content PVC compounds simplify operation be]ow the OSHA O.Sppm action level and compliance, assuming normal conditions and ventilation in a.processor s work area. Further developments on resins and regulations are pending.
TEN 2861