Document 3NxbOJo1YJ4rnYEvg4XKdBpnJ

www.axysanalytical.com >)][( A X Y S Axys Analytical Services Ltd 2045 Mills Road West SIDN EY, BRITISH COLUMBIA, CANADA V8L 5X2 T E L 250-655-5800 FAX 250-655-5811 www.axysanalytical.com AXYS Client No.: Client Address: 4731 Weston Solutions Inc. 1400 Weston Way West Chester, PA, US, 19380 The AXYS contact for these data is Candice Navaroli. Page 1 of 307 www.axysanalytical.com PERFLUORINATED ORGANIC ANALYSIS AQUEOUS SAMPLES PROJECT NAME: Fall 2012 Tennessee River Sampling Contract: 4731 Data Package Identification: DPWG42492 Analysis WG42273 & WG42428 17 January 2013 Page 2 of 307 www.axysanalytical.com Weston Solutions Inc. AQUEOUS SAMPLES PERFLUORINATED ORGANIC ANALYSIS AXYS METHOD: MLA-06Q PROJECT NAME: Fall 2012 Tennessee River Sampling 4731: L18989-1 t o -14 NARRATIVE 17 January 2013 This narrative describes the analysis of fourteen aqueous samples for the determination of perfluorinated organic compounds using high performance liquid chromatography/tandem mass spectrometry (HPLC/MS-MS), SAMPLE RECEIPT AND STORAGE The samples were received on the 14th of December 2012. Upon receipt, the temperature for the samples ranged from 2.1 to 4.7 C marginally exceeding the required sample storage conditions of 0 to 4C for some samples. This variance from method criteria was deemed to not be of sufficient magnitude to affect data quality. Details of sample conditions on receipt are provided on the sample receiving records included with this data package. The samples were stored at 4C prior to extraction and analysis. SAMPLE PREPARATION AND ANALYSIS The extraction and analysis procedures were followed as outlined with AXYS Method MLA-060: Analytical Procedure fo r the Analysis o f Perfluorinated Organic Compounds in Aqueous Samples by LC-MS/MS. A method summary (MSU-060) of the method is included with this data package. The client and associated QC samples (consisting of a laboratory procedural blank, a lab-generated reference sample referred to as an Ongoing Precision and Recovery (OPR) sample and a duplicate sample) were analysed collectively under two batches as WG42273 and WG42428. The composition of these analysis batches are shown on the correlation table, and also on the batch list heading of the extraction workup sheets provided with the data package. For each sample, an accurately weighed subsample of approximately 0.5 L was spiked with labeled quantification standards (surrogates), extracted and then cleaned up using SPE cartridges. The cleaned extract for each sample was spiked with labeled recovery (internal) standards, and instrumentally analysed using liquid chromatography/mass spectrometry (LC-MS/MS). CALCULATIONS Target analyte concentrations were determined by isotope dilution quantification procedures, comparing the area of the quantification of the target analyte to that of the labeled quantification standard (surrogate) and correcting for response factors. Linear regression equations were determined from a multi-point calibration series with 1/X weighting fit. Labeled analyte recovery was determined by using average response factors determined from the initial multipoint calibration and were used as general data quality indicators. Recovery values of the recovery (injection) standard were estimated by external standard quantification and used as indicators of the extent of signal suppression or enhancement. Sample specific detection limits (SDL) were determined from the analysis data by converting the area equivalent to 3x the chromatographic noise to a concentration in the same manner that peak areas are converted to concentrations. Formulae used for the conversion of the raw chromatogram data to concentration are provided in the method summary document, MSU-060. REPORTING CONVENTIONS For internal tracking, AXYS assigned Weston Solutions inc. contract number 4731. AXYS logged the samples under unique laboratory identifiers L18989-X; where X is a numeral. All data reports provided reference both the Axys ID and the client sample identifier. To assist in locating data, a table correlating Axys IDs with the client Page 3 of 307 www.axysanalytical.com sample numbers is included with this data package. The report forms were generated using Laboratory Information Management Software (LIMS). Any additional work performed after the initial instrumental analysis of the sample extract is indicated by a suffix added to the AXYS ID. The notation used to identify samples reported from extra work data or that were used as the duplicate of a client sample for this data package includes: R = repeat analysis using a fresh aliquot of sample (A) = the parent sample for a duplicate pair The following data qualifier flags were used in this data package: B = analyte found in sample and associated blank U = identifies a compound that was not detected The reporting limit (RL) was defined as the concentration equivalent to the lowest calibration standard analyzed in the initial calibration (CSO), corrected for sample size, or the sample specific detection limits, whichever was greater. Sample analyte concentrations are reported in units of nanograms per litre (ng/L). Results are reported to three significant figures. The analysis results for each sample are provided on Analysis Report forms 1A and 2. QA/QC NOTES The laboratory procedural blank, OPR, and duplicate samples were prepared alongside the client samples, and were subjected to the same analytical procedures. The results were evaluated through comparison to the batch QC samples. Sample analyte concentrations are not blank corrected and should be evaluated with consideration of the laboratory procedural blank results. By virtue of the isotope dilution standard quantification procedures, data are recovery corrected for possible losses during extraction and clean-up. 9 The Signal/Noise (S/N) ratios were measured as `0' for some compounds In the QC samples and sample data. This has been determined to be a limitation of the software and does not affect the data 9 All linearity, calibration verification, OPR and labelled compound recovery specifications were met with the following exception: WG42273 The target analyte PFHpA was detected in the laboratory procedural blank (AXYS ID: WG42273-101) at a concentration (1.48 ng/L) above the reporting limit (RL) of 1.00 ng/L. Subsequently, the results reported for this compound for the sample and duplicate sample (AXYS IDs: L18989-11 and WG42273-103) have been flagged with a `B' on the report forms. The detection of this compound in the laboratory procedural blank sample should be considered when reviewing the results for these two samples. WG42428 No issues to report ANALYTICAL DISCUSSION WG42273 ' As indicated above, the target analyte PFHpA was detected in the laboratory blank sample (AXYS ID: WG42273101) above the reporting limit. For most of the client samples, the same compound was detected at similar concentrations. Accordingly, where possible, the back-up portion of the client samples was used to repeat the analysis with the results reported from the second (repeat) analysis batch (WG42428), as indicated by that addition of the suffix `R' to the AXYS ID. For the DAL-SW-T606-DUPA-121204 and duplicate samples (AXYS IDs: L18989- Page 4 of 307 www.axysanalytical.com 11 and WG42273-103), no back-up portion was available to repeat the analysis. Subsequently, the results for these samples were reported from the initial analysis batch (WG42273). WG42428 No analytical difficulties were encountered for this analysis. DATA PACKAGE This data package is assigned a unique identifier, DPWG42492, shown on the front page. The following documents are included in the data package: Method summary Sample Correlation Table Sample Receiving Documentation Laboratory extraction Worksheets Sample data reports (in order of Axys Sample ID) Laboratory QC data reports a Instrumental QC data reports Laboratory QC and sample raw data Instrumental QC raw data Accreditation Scope 1 certify that this data package is in compliance with the terms and conditions of the contract, both technically and for completeness, except for the conditions detailed above. In addition, I certify that to the best of my knowledge and belief the data as reported are true and accurate. The following signature authorizes on behalf of Axys Analytical Services Ltd the release of the data contained in this data package. Signed: Andrew Porat, Data Validation Chemist Date Signed m Page 5 of 307 www.axysanalytical.com AXYS Analytical Services Ltd. Method Summary Analytical Procedure for the Analysis of Perfluorinated Organic Compounds in Aqueous Samples by LC-MS/MS by AXYS Method MLA-060 Rev. 10 Ver. 03 Method MLA-060 describes the analysis of perfluorinated organic compounds (PFC) in aqueous samples. Typical quantification limits are in the range of 1 - 2 ng/L for a 0.5 L sample size. ANALYTES OF INTEREST Perfluorobutanoate (PFBA) Perfluoropentanoate (PFPeA) Perfluorohexanoate (PFHxA) Perfluoroheptanoate (PFHpA) Perfluorooctanoate (PFOA) Perfluorononanoate (PFNA) Perfluorodecanoate (PFDA) Perfluoroundecanoate (PFUnA) Perfluorododecanoate (PFDoA) Perfluorobutanesulfonate (PFBS) Perfluorohexanesulfonate (PFHxS) Perfluorooctanesulfonate (PFOS) Perfluorooctane sulfonamide (PFOSA) 1 EXTRACTION AND CLEANUP Sample size may be up to 1000 mL. Samples are stored in HDPE (high density polyethylene) containers. Samples are filtered, adjusted to pH 6.5, spiked with surrogate standards and extracted by solid phase extraction (SPE) using weak anion exchange cartridges. Wash and elution procedures are chosen to meet various analysis requirements. The eluates are spiked with recovery standards and analyzed by LC-MS/MS. Calibration solutions are processed through SPE in the same way as the samples. QUALITY ASSURANCE / QUALITY CONTROL All samples are analyzed in batches. The composition of a batch is detailed on a batch sheet. Each batch has the following composition: Batch Size - Each batch consists of test samples and additional QC samples. Blanks - Blanks are analyzed with a minimum frequency of 5% of client samples. Duplicates - With each analysis batch containing greater than six (6) test samples, or as required by contract, a duplicate sample is analyzed, provided there is sufficient sample. Matrix Spike/Matrix Spike Duplicate analyzed upon client request. OPR (Spiked Reference Sample) - OPRs are analyzed with a minimum frequency of 5% of client samples. MSU-060 Rev 06, 06-Sep-2012 Summary of AXYS Method MLA-060 Rev. 10 Ver. 03 Page 1 of 6 Page 6 of 307 www.axysanalytical.com QC Specification: Procedural Blank Levels and OPR Recoveries Analyte Perfluorobutanoate Perfluoropentanoate Perfluorohexanoate Perfluoroheptanoate Perfluorooctanoate Perfluorononanoate Perfluorodecanoate Perfluoroundecanoate Perfluorododecanoate (PFBA) (PFPeA) (PFHxA) (PFHpA) (PFOA) (PFNA) (PFDA) (PFUnA) (PFDoA) Procedural Blank Level ng/sample 2 <0.25 <0.25 <0.25 <0.25 <0.25 <0.25 <0.25 <0.25 <0.25 OPR Recovery Range (% )1 80 - 120 1 80 - 120 1 80 - 120 1 80 - 120 1 80 - 120 1 80 - 120 1 80 - 120 1 80 - 120 1 80 - 120 1 Perfluorobutanesulfonate Perfluorohexanesulfonate Perfluorooctanesulfonate (PFBS) (PFHxS) (PFOS) <0.25 <0.25 <0.25 70 - 130 70 - 130 70 - 130 Perfluorooctane sulfonamide (PFOSA) <0.25 70 - 130 1 Marginal exceedance allowance - recovery for 2 compounds may be 75-125% and for one compound 70-130%. 2 Reporting limits (based on the lowest calibration standard and routine final extract volume of 4 mL) may exceed the stated blank criteria. QC Specification: Surrogate Standard Recoveries (Calibration Solutions and Samples) Surrogate Standard 13C4-Heptafluorobutyric acid (13C4-PFBA) 13C2-Perfluorocaproic acid (13C2-PFHxA) 13C2- Perfluorooctanoic acid (13C2-PFOA) 13C5-Heptadecafluorononanoic acid (13C5-PFNA) 13C2- Perfluorodecanoic acid (13C2-PFDA) 13C2-Perfluoro-n-(1,2)dodecanoic acid (13C2-PFDoA) 18O2-Perfluorohexanesulfonate (18O2-PFHxS) 13C4-Perfluorooctanesulfonate (13C4-PFOS) 13C8-Perfluoro-1-octanesulfonamide (13C8-PFOSA) 1 Lower recoveries may be accepted based on application and professional judgment 2 The recovery range for 13C8-PFOSA is a guideline Recovery Range 1 2 0 - 150% 40 - 150% 4 0 - 150% 4 0 - 150% 4 0 - 150% 40 - 150% 40 - 150% 4 0 - 150% 40 - 150% 2 Page 7 of 307 www.axysanalytical.com QC Specification Table: Other Parameters QC Parameter Specification Instrument Sensitivity Daily, S:N > 3:1 for all analytes for lowest calibration standard. Initial Calibration (native compounds) Run initially, and as required to maintain calibration verification and instrument sensitivity. (1/x) weighted quadratic, exclude origin. Calculated conc. 75-125 % of actual (lowest cal may be 70-130%), R2 > 0.990. Surrogate recoveries must fall within the same limits as for the samples in the table above. Continuing Calibration Verification (native compounds) Run every 20 samples or more frequently, quantify against I-CAL. Calculated conc. 70-130% actual for a maximum of three compounds with the remainder 80-120 % of actual. Surrogate recoveries must fall within the same limits as for the samples in the table above. Instrumental Carryover and Every Initial Calibration, Cal/Ver, or SPM: < 0.3 % carryover and area Instrument Background response of analytes in instrument blank < 800. Duplicate Samples or MS/MSD If conc. > 5 times R.L., RPD < 40% If conc. < 5 times R.L., difference between pairs < R.L. m Page 8 of 307 www.axysanalytical.com ANALYSIS BY LC-MS/MS Analysis of sample extracts for perfluorinated organics by HPLC-MS/MS is performed on a high performance liquid chromatograph coupled to a triple quadrupole mass spectrometer. The mass spectrometer is run at unit mass resolution in the Multiple Reaction Monitoring (MRM) mode. Instrument specifications: Instrument LC Column Ionization Acquisition Injection Volume Waters 2690 or Waters 2795 HPLC, Micromass Quattro Ultima MS/MS Waters Xtera C18MS Reverse Phase C18, 10.0 cm, 2.1 mm i.d., 3.5 pm particle size (or equivalent) Negative Ion Electrospray MRM mode, unit resolution 15 pL LC-MS/MS Operating Conditions: LC Gradient Program General LC Conditions Time (min) 0.0 1.0 5.0 8.5 Flow m ixture1 15% eluent A 85% eluent B 15% eluent A 85% eluent B 70% eluent A 30% eluent B 100% eluent A LC Flow Rate Program 0.15 mL/min 0.15 mL/min 0.20 mL/min 0.20 mL/min G ra d ie n t Curve 1 1 4 4 Column Temp (C) 40 Max Pressure (bar) 300 MS Conditions Source Temp (C) Desolvation Temp (C) 120 300 11 100% eluent A 11.3 - 14.5 15% eluent A 85% eluent B 0.20 mL/min 0.20 mL/min 4 Capillary Voltage 2 Gases 2.75 ~70L/hr cone ~300L/hr desolvation 1 Eluent A = 90% CH3CN (aqueous) Eluent B = 13 mM ammonium acetate in 0.1% acetic acid (aqueous) Initial calibration of the LC-MS/MS instrument is performed by the analysis of six or more calib ration solutions. A mid-level calibration standard is analyzed to verify the initial calibration after every 20th sample (including QC samples) injected at a minimum. All calibration solutions go through the same SPE extraction/cleanup procedures as the samples. Page 9 of 307 www.axysanalytical.com ANALYTE IDENTIFICATION Positive identification of target PFC, surrogate standard and recovery standards require: > 3:1 S:N for parent ion to daughter ion transition. Compound retention time must fall within 0.4 minutes of the predicted retention times from the daily Calibration Verification. Natives with labelled surrogate standards must elute within 0.1 minutes of the associated labelled surrogates. QUANTIFICATION AND DATA REPORTING PROCEDURES Target compounds are quantified using the internal standard method, comparing the area of the quantification ion to that of the 13C-labelled standard and correcting for response factors. Quadratic calibration equations are determined from a multi-point calibration series with 1/X weighing fit as described by the following general equation: Y= a + bX + cX2 (general quadratic equation) where Y = (area target/area surr) x weight surr X = weight target a,b,c are empirical constants Concentrations in samples are determined as: - b Sample Conc = ------- b2 - ( 4c a - ( area of t arg et \\ x weight sur area o f sur 2c x sample size The recovery of the surrogate standard is calculated (by internal standard quantification against the recovery standard using an average RRF) and monitored as an indication of overall data quality. Final target concentrations are recovery corrected by this method of quantification. Sample Specific Detection Limits (SDL) are determined .by converting the area equivalent of 3.0 times the estimated chromatographic noise height to a concentration in the same manner that target peak responses are converted to final concentrations. The SDL accounts for any effect of matrix on the detection system and for recovery achieved through the analytical work-up. Results are reported to the greater of the SDL or the concentration equivalent to the lowest calibration standard analyzed. MSU-060 Rev 06, 06-Sep-2012 Summary of AXYS Method MLA-060 Rev. 10 Ver. 03 Page 5 of 6 Page 10 of 307 www.axysanalytical.com Analytes, Ions and Quantification References Target Analyte Typical Retention Time (minutes) Target Analytes Perfluorobutanoate (PFBA) Perfluoropentanoate (PFPeA) Perfluorohexanoate (PFHxA) Perfluoroheptanoate (PFHpA) 5.0 5.8 6.2 6.6 Perfluorooctanoate (PFOA) 7.0 Perfluorononanoate (PFNA) Perfluorodecanoate (PFDA) Perfluoroundecanoate (PFUnA) Perfluorododecanoate (PFDoA) 7.4 7.9 8.5 9.0 Perfluorobutanesulfonate (PFBS) 6.3 Perfluorohexanesulfonate (PFHxS) 7.2 Perfluorooctane sulfonate (PFOS) Perfluorooctane sulfonamide (PFOSA) 2 Surrogate Standard 13C4-Heptafluorobutyric acid (13C4-PFBA) 13C2-Perfluorocaproic acid (13C2-PFHxA) 13C2-Perfluorooctanoic acid (13C2-PFOA) 13C5-Heptadecafluorononanoic acid (13Ca-PFNA) 13C2-Perfluorodecanoic acid (13C2-PFDA) 13C2-Perfluorododecanoic acid (13C2-PFDoA) 18O2-Perfluorohexanesulfonate (18O2-PFHxS) 8.2 9.9 5.0 6.2 7.0 7.4 7.9 9.0 7.2 13C4-Perfluorooctanesulfonate (13C4-PFOS) 13C8-Perfluorooctane sulfonamide (13C8-PFOSA) Recovery Standard 13C2-2H-Perfluoro-2-decenoic acid (13C2PFOUEA) 13C4-Perfluorooctanoic acid (13C4-PFOA) 8.2 9.9 7.3 6.9 Parent Daughter Ion Mass Ion Mass Q u a n tifie d Against <GO LL CL1 o CO 213 169 263 219 13C2 -PFHxA 313 269 13C2-PFHxA 363 319 13C2-PFHxA 413 369 (169)1 13C2-PFOA 463 419 13C5-PFNA << QQ LL LL CL1 CL1 CM CM OO CO CO 513 469 563 519 613 569 13C2 -PFDoA 299 80 (99)1 1 8 O2 -PFHxS 80 399 (99/119)1 18O2-PFHxS cn cn OO LL LL CL1 CL1 oo CO CO 499 80 (99)1 498 78 217 172 13C2-PFOUEA 315 270 13C2-PFOUEA 415 370 13C4-PFOA 468 423 13C2-PFOUEA 515 470 13C2-PFOUEA 615 570 13C2-PFOUEA 84 403 13C2-PFOUEA (103)1 80 503 13C2-PFOUEA (99)1 506 78 13C2-PFOUEA 459 394 417 372 - 1 Alternate transition within brackets, may be used if necessary to avoid interference. 2 13C 8-P F O S A may be used as an alternate surrogate for P F O S A if deem ed necessary to improve data quality. Page 11 of 307 www.axysanalytical.com Weston Solutions Inc. CORRELATION TABLE PERFLUORINATED ORGANIC ANALYSIS Lab Name: AXYS Analytical Services Ltd. Project Name:Fall 2012 Tennessee River Sampling Data Package Identification: DPWG42492 Project Manager: Candice Navaroli Contract No: 4731 AXYS Method: MLA-060 Program: Aqueous Samples Client Sample No. Lab Sample ID LAB BLANK OPR W G 42273-101 W G 42273-102 DAL-SW -T606-DUPA-121204 L18989-11 W G42428-103 DUPLICATE LAB BLANK OPR W G 42428-101 W G 42428-102 DAL-SW -R02L3-DUPA-121116 DAL-SW -R15L1-DUPA-121117 DAL-SW -R10L3-DUPA-121119 DAL-SW -R05L1-1-121119 DAL-SW -RO6L2-DUPA-121120 DAL-SW -T101-DUPA-121203 DAL-SW -T202-DUPA-121203 DAL-SW -T303-DUPA-121203 DAL-SW -T404-DUPA-121203 DAL-SW -T505-DUPA-121204 DAL-SW -T707-DUPA-121204 DAL-SW -T808-DUPA-121205 DAL-SW -T909-DUPA-121205 L18989-1 L18989-2 L18989-3 L18989-4 L18989-5 L18989-6 L18989-7 L18989-8 L18989-9 L18989-10 L18989-12 L18989-13 L18989-14 Page 12 of 307 www.axysanalytical.com >I0 AXYS Axys Analytical Services Ltd 2045 Mills Road W est TEL: (250) 655-5800 Sidney, British C olum bia, C anada V 8L 5X2 FAX: (250) 655- 5811 REPORT TO: Company Address P iP .U f ) - T A ^ INVOICE TO: ^ Compar * Addres 8 CHAIN OF CUSTODY i, r 1. AXYS CLIENT #: 4 T S ANALYSIS REQUESTED \A > K k i H O /) A J e Z h n . w m / J & a Contact V p fA ^ v r ju /Z j fZ o a d > .H fa , 3 S 7 O S V o J rZ Phone 5 O FAX E-mail ^ Project Name/Number: 555 *A o \W > <?54 1 iJ e S f |W " > T 5 Conta ct Phon e FA x E-itielil A k to 2 /0 Sampler's Name: V ova* ^0 / 5 ^ ^ 7d / z> 4 0 / '' /& * \|x u_ Client Sample Identification Matrix Sampling Date S ig n a tu r e :'^ ^ H '1 Sampling Container Preservative Time Type/No. Y /N AXYS Lab ID Lab use only Au-Sv j - R tS V t- k P A & i . J , b v P`V )LtW<i 1L-SW ' & "i t - b v iA *4?A -iZ jn*& VJ w vo W vo 'bi/ituii. t| ( j j a >ij L ,1/t 'l)lv .\* iW T rS " m oo iy .a r' a* I N/ 'W 1 Y "T V Y ~3 -S > ___________ J I Z . ______________ Relinq qature) Date nquished by (Signature) Remarks / Type Of Preservative Date Time W oo Time Received by (Signature) ......... . Date I H ' h & v Received by (Signature) Time ! 0 s s Date_________________________I ime__________ Tbuse c m r e ^ o l h oJ> v J lli. 0A courier fe te Waybill No. Temp C Custody Seal # Seal Intact Sample Tags Sample Receipt Y/ N Y /N Cooler m Page 13 of 307 www.axysanalytical.com A axys Axys Analytical Services Ltd 2045 Mills Road W est TEL: (250) 655-5800 Sidney, B ritish C olum bia, C a na da V 8 L 5X 2 FAX: (250) 655- 5811 CHAIN OF CUSTODY AXYS CLIENT#: REPORT TO: Company A" oss ADE M F iv .U o f l f e , INVOICE TO: % Compariy \ Addre; 3S IHo0 W p a -Id a i/Jtu ^ ANALYSIS REQUESTED 4 * ^ E k d 5 , 1 A/. Con,* c, Phone FAX E-mail X X d S6> ~f4~s>o'z>_______ P o o /o s 9^ Conta ct Phor e FAx E-miill (^ ^ iu rit s Yftw /t* 9ol ^ # 7 - %>( 3 * / o l Project Name/Number: Sampler's Name: ?. J c . To Signature: sA <o Client Sample Identification Matrix Sampling Date Sampling Time Container Type/No. Preservative Y /N AXYS Lab ID Lab use only P A L S v> iT -|e > \- y Ca - U n * T >A v.'S u-T .cx- t>vp a - ix i-m >Au-JvJ 'T o S -B v P A -trx x ^ A c -d w -T H o ^ - tx ip A - 1x n a PA- * S v 4 -rA "fti"*b P A - iz.)26 P a v -w - T<*ofo - V j PA" f ilT TJAl- s^ - t ^ o v W A " ru x o T>a c - S w -T -b ^ P A -R P - PAt_-S\J "T ^C I^- DupA -I2I20 w <*[*/** 2- S ' H o I i_ V .ID ___ s _____ Iz N lz o lX II-fo o n -.a a - 1 2 F i t 'l l I f . to / o '-t o N / ___ s j k ____ i z - n r > - t J * Y L \ % % 9 ' U * - I'D "V I -IX -1 3 V/ ~ /4 V/ ignature) nquished by (signature) lahl l lDate Time L__ Date Time Remarks / Type Of Preservative Courier Date H " h e d - IT ._____Time / O ' L > S Received by (Signature) fe d E * Date copy cS well : Time 3 fzsolk Temp C Custody Seal # Seal Intact Sample Tags Waybill No. Sample Receipt Cooler Y /N Y /N m Page 14 of 307 www.axysanalytical.com Expanded Service International A ir Waybill Express Not all services and options are available to all destinations. 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U R S A Routing x V H a n d lin g U nits r r , \ "k \j \ I I V ' ' f f Total Volume t l\\N T A ' 1/ ReceivedAt-- . ^__ : 1[___IRb9-StopSifF2j__j0n-Cal! Stop EFmedpE.x#K/ j A f; j / { " (! : ' AEmudpi.t# __ 3j JDrop Box 4 0 S . i,&mi" s0 H -" nRt_ . Del. Courier V<' Fr,`"hl f* Other k itf------------- Non-Negotiable International Air Waybill 1994-2002 Federal Express Corporation FormsAttached:.... . ' -- U I'U S E D -- Total. ----U" 10 Required Signature !: .UJ e .?, .h.i,s A 5 ; y V,,avbil.1c o n s titu ie s y o u r a g r e e m e n t to th e C o n d itio n s o f C o n tra c t on th e b a c k of th is A ir W ay b ill. C ertain international tre atie s, includ ing th e W a rs a w Convention, m ay apply to this shipm ent and limit ou r lia b llity fo r/ ta g e , lo ss, or delay, a s d e scrib ed In the Conditions of C o n tra c t Sender's Signature J jf i/ / / ( / { ,/ if / A .J 7 j c ' ' Date Executed j/yl / lrJ < Received above shipment In good order and condition. We agree to pay all charges, including Customs duties and taxesasapplicable,andweagreetotheConditionsofContractasstatedonthereversesideoftheRecipient'sCopy. P '5 0 FedEx Tracking Number 3SS S14 7n03 UI 1i L11i IQH II PRPRea1vIr9Nt-9#TD14Ea5-Dt27e06IN208/320U2F.Se.dAE.x DMSb m Page 15 of 3(1)7 www.axysanalytical.com Waybill : Date Shipped: AXYS Client & Contract # Project Number: Login Number: Received By: KSTADLER Axys Sample IP's: L - \ Matrix Type: 5x water AXYS Analytical Services Ltd SAMPLE RECEIVING RECORD (*fes)/No 12-DEC-12 4731-Weston Solutions Waybill#: 835521847903 Date /Time Received: 14-DEC-12 09:15 Receipt No: WB14214 \ `C Log in by: Signature: T V 1 A U I A z i a / / V x > Condition of Shipping Container: j w V C \ i l A r ~ ` Temperature upon Receipt: 4.7 Celcius shipped with wet ice, ice melted, no temp blank Thermometer ID: 3266 Custody Seals: Shipping Containers Yes l(fio) Samples Yes (N o ) Intact Yes/No Intact Yes /No Seal Numbers Y es /N o Seal Numbers Yes /No Chain of Custody or Documents: Sample ID's Collection Location Date & Time Collection Collector's Name Tracking Report /Packing List: Y es(N o , Sample Tag Numbers YesMo^ Sample Type @/No" Preservative Added Yes//No> Preservation Requested Yes/i Sample Tags Sample Labels Sample Labels Cross Referenced to COC Sample Tags Cross Referenced to Sample Labels Sample Tags Cross Referenced to COC Yesf/^o) (feslNo (Y e s ) No Yes /No Yes /No Information Agrees Information Agrees Information Agrees Comments: h>A I - s v u - g.oSnUi - k u p a u I : i IQ L'ftl.-SW-R'ORU- O- JZLiiq__ (^Yes)No Yes /No Yes /No X Cu ( M v e w H % ( l w \ p \ e I 0 0 q C V - "\V\ f t S ' - 'tX V n - R s O S L l ' " 1 - \ ? V r A ] Action Taken: m Page 16 of 307 www.axysanalytical.com AXYS Analytical Services Ltd SAMPLE RECEIVING RECORD Waybill : DateShipped: AXYS Client & Contract # Project Number: Login Number: (^YepNo 12-DEC-12 4731-Weston Solutions W aybill#: 8355218477903 Date/Time Received: 14-DEC-12 10:55 Receipt No: WB14215 Received By: KSTADLER Axys Sample IP's: ^ Matrix Type: 9 water ~ lo Log In by: \ A \ r T L - M T ' | L ^ - t _______________________________________ Signature:T E 5 3 A A z v 2 v x . Condition of Shipping Container: | Temperature upon Receipt: 2.1 Celcius shipped with wet ice, melted, temp blank present Thermometer ID: 3265 Custody Seals: Shipping Containers Yes j/No) Samples Yes M o ) Intact Yes /No Intact Yes /No Seal Numbers Yes /No Seal Numbers Yes /No Chain of Custody or Documents: Sample ID's Collection Location Date & Time Collection Collector's Name Qfe'/No (fes /No Y e s^jo ) (YS)/No (Ye|)/No Tracking Report/Packing List: Sample Tag Numbers Sample Type Preservative Added Preservation Requested Sample Tags Sample Labels Sample Labels Cross Referenced to COC Sample Tags Cross Referenced to Sample Labels Sample Tags Cross Referenced to COC Yes(/No) (fes)/No (Yep/No Yes /No Yes /No Information Agrees Information Agrees Information Agrees <Ygf/Np Yes /No Yes /No Comments: op.Y' 1 Pilio^fAioAd-CfYdivai\PrWxCie-r;(rt`er\ fslioiVyHM { Yn\fv^ P.H. CDC i no*-1^-4 j(A Action Taken: r\ ~ t <~>r\rvn Page 17 of 307 www.axysanalytical.com ftJ J Ia y ik AXYS AXYS Analytical Services Ltd. Login Chain of Custody Report (In01) Dec. 17, 2012 10:05 AM Login Number: L18989 Account: 4731 Weston Solutions Project: Axys ID versus Client Sample Identification L18989-1 DAL-SW-R02L3-DUPA-121116 16-NOV-12 13:20 ' Storage: WIC2, 2A EDataDeliv D.Package Aqueous Aqueous ANY L18989-2 PFC EDD PFOS DATA PKG FC060 FC060.PS SAMPLE RECEIPT DAL-SW-R15L1-DUPA-121117 17-NOV-12 12:25 Storage: WIC2, 2A EDataDeliv D.Package Aqueous Aqueous ANY L18989-3 PFC EDD PFOS DATA PKG FC060 FC060.PS SAMPLE RECEIPT DAL-SW-R10L3-DUPA-121119 19-NOV-12 11:00 Storage: WIC2, 2A EDataDeliv D.Package Aqueous Aqueous ANY L18989-4 PFC EDD PFOS DATA PKG FC060 FC060.PS SAMPLE RECEIPT DAL-SW-R05L1-1-121119 19-NOV-12 16:25 Storage: W1C2, 2A EDataDeliv D.Package Aqueous Aqueous ANY PFC EDD PFOS DATA PKG FC060 FC060.PS SAMPLE RECEIPT /<7- Page: 1 of 4 Received 14-DEC-12 Due PR 1 1 L plastic 14-DEC-12 USD USD USD USD USD 1 1 L plastic 14-DEC-12 USD USD USD USD USD 1 1 L plastic 14-DEC-12 USD USD USD USD USD 1 1 L plastic USD USD USD USD USD Page 18 of 307 www.axysanalytical.com I( AXYS AXYS Analytical Services Ltd. Login Chain of Custody Report (In01) Dec, 17,2012 10:05 AM Login Number: L18989 Account: 4731 Weston Solutions Project: Axys ID versus Client Sample Identification L18989-5 DAL-SW-R06L2-DUPA-121120 20-NOV-12 16:30 Storage: WIC2, 2A EDataDeliv D.Package Aqueous Aqueous ANY L18989-6 PFC EDD PFOS DATA PKG FC060 FC060.PS SAMPLE RECEIPT DAL-SW-T101 -DUPA-121203 03-DEC-12 08:40 Storage: WIC2, 2A EDataDeliv D.Package Aqueous Aqueous ANY L18989-7 PFC EDD PFOS DATA PKG FC060 FC060.PS SAMPLE RECEIPT DAL-SW-T202-D UPA-121203 03-DEC-12 09:10 Storage: WIC2, 2A EDataDeliv D. Package Aqueous Aqueous ANY L18989-8 PFC EDD PFOS DATA PKG FC060 FC060.PS SAMPLE RECEIPT DAL-SW-T303-DUPA-121203 03-DEC-12 11:50 Storage: WIC2, 2A EDataDeliv D.Package Aqueous Aqueous ANY PFC EDD PFOS DATA PKG FC060 FC060.PS SAMPLE RECEIPT Page: 2 of 4 Received 14-DEC-12 Due PR 1 1 L plastic 14-DEC-12 USD USD USD USD USD 1 1 L plastic 14-DEC-12 USD USD USD USD USD 1 1 L plastic 14-DEC-12 USD USD USD USD USD 1 1 L plastic USD USD USD USD USD Page 19 of 307 www.axysanalytical.com AXYS AXYS Analytical Services Ltd. Login Chain of Custody Report (In01) Dec. 17,2012 10:05 AM Login Number: L18989 Account: 4731 Weston Solutions Project: Axys ID versus Client Sample Identification L18989-9 DAL-SW-T404-DUPA-121203 03-DEC-12 14:50 Storage: WIC2, 2A EDataDeliv D.Package Aqueous Aqueous ANY L18989-10 PFC EDD PFOS DATA PKG FC060 FC060.PS SAMPLE RECEIPT DAL-SW-T505-D UPA-121204 04-DEC-12 11:22 Storage: WIC2, 2A EDataDeliv D.Package Aqueous Aqueous ANY L18989-11 PFC EDD PFOS DATA PKG FC060 FC060.PS SAMPLE RECEIPT DAL-SW-T606-DUPA-121204 04-DEC-12 12:55 Storage: WIC2, 2A EDataDeliv D.Package Aqueous Aqueous ANY L18989-12 PFC EDD PFOS DATA PKG FC060 FC060.PS SAMPLE RECEIPT DAL-SW-T77-DUPA-121204 04-DEC-12 15:10 Storage: WIC2, 2A EDataDeliv D. Package Aqueous Aqueous ANY PFC EDD PFOS DATA PKG FC060 FC060.PS SAMPLE RECEIPT Page: 3 of 4 Received 14-DEC-12 Due PR 1 1 L plastic 14-DEC-12 USD USD USD USD USD ' 1 1 L plastic 14-DEC-12 USD USD USD USD USD 1 1 L plastic 14-DEC-12 USD USD USD USD USD 1 1 L plastic USD USD USD USD USD Page 20 of 307 www.axysanalytical.com AXYS AXYS Analytical Services Ltd. Login Chain o f Custody Report (In01) Dec. 17,2012 10:05 AM Login Number: L18989 Account: 4731 Weston Solutions Project: Axys ID versus Client Sample Identification L18989-13 DAL-SW-T808-DUPA-121205 05-DEC-12 10:10 Storage: WIC2, 2A EDataDeliv D.Package Aqueous Aqueous ANY L18989-14 PFC EDD PFOS DATA PKG FC060 FC060.PS SAMPLE RECEIPT DAL-SW-T909-DUPA-121205 05-DEC-12 12:45 Storage: WIC2, 2A EDataDeliv D.Package Aqueous Aqueous ANY PFC EDD PFOS DATA PKG FC060 FC060.PS SAMPLE RECEIPT Page: 4 of 4 Received 14-DEC-12 Due PR 1 1 L plastic 14-DEC-12 USD USD USD USD USD 1 1 L plastic USD USD USD USD USD Page 21 of 307 www.axysanalytical.com Candice Navaroli From: Young, Charles T. [Charles.Young@WestonSolutions.com] Sent: Friday, December 14, 2012 12:56 PM FILING To: Candice Navaroli; Smith, Martin; McLoughlin, Rachel; Kesari, Jai Subject: RE: Shipment of Tennessee River SW samples for Thursday 12/12/2o12 arrival atAXYS Candice: Thanks for calling these to our attention. The last string is a date code of the form YYMMDD so the bottle ID (with the character in red denoting day of the week in your listing below) has the full sample ID for your login and reporting purposes. Please make the appropriate additions on the chain of custody (COC) form for these samples by inserting the final character from each of the sample bottles For the last sample, please correct the entry on the COC to match that recorded on the sample bottle by a single strike through DURA and replacing with the number 1. Thanks, Charlie Charles T. Young Technical Director Weston Solutions, Inc. 1400 Weston Way (5-2) West Chester, PA 19380 (010) 701-3787 cell (610) 952-1093 fax (610) 701-3401 char! es ,young@westo nsolution s .com From: Candice Navaroli [ mailto:cnavaroll@axys.com] Sent: Friday, December 14, 2012 3:25 PM To: Smith, Martin; McLoughlin, Rachel; Kesari, Jai Cc: Young, Charles T. Subject: RE: Shipment of Tennessee River SW samples for Thursday 12/12/2ol2 arrival at AXYS Hi Jai and Charles, . There are a couple of sample label discrepancies that we need to have resolved before we can move forward with the logging in of your samples. There are several samples where the sample label on the bottle does not match the client ID listed on the chain of custody form. Please advise as to which one we should use. Sample Bottle ID Chain o f Custody ID DAL-SW-T101 -DUPA-12120 3 DAL-SW-T202-DUPA-12120 3 DAL-SW-T303-DUPA-12120 3 DAL-SW-T404-DUPA-12120 3 DAL-SW-T505-D UPA-12120 4 DAL-SW-T606-DUPA-12120 4 DAL-SW-T707-D UPA-12120 4 DAL-SW-T808-DUPA-12120 5 DAL-SW-T909-DUPA-12120 5 DAL-SW-R05L1--121119 DAL-SW-T101-DUPA-12120 DAL-SW-T202-D UPA-12120 DAL-SW-T303-DUPA-12120 DAL-SW-T404-D UPA-12120 DAL-SW-T505-DUPA-12120 DAL-SW-T606-D UPA-12120 DAL-S W-T707-DUPA-12120 DAL-SW-T808-DUPA-12120 DAL-SW-T909-DUPA-12120 DAL-SW-R05L1 -DUPA-121119 Regards, Candice Candice Navaroli (B.Sc.) 17/12/2012 Page 22 of 307 www.axysanalytical.com Project Manager Tel.: 250-655-5800 Direct: 250-655-5839 Toll free: 1-888-373-0881 Ext.5839 Fax: 250-655-5811 Email: cnavaroli@axys.com Axys Analytical Services Ltd. 2045 Mills Road Sidney, BC. Canada, V8L 5X2 17/12/2012 Page 23 of 307 www.axysanalytical.com BATCH LIST PART ONE BATCH ID: W G42273 Method ID: MLA-060 R10.03 M ethod ID: M ethod ID: Analyst: Start Date: 18-Dec-12 Batch List Author: SDHESI Checked By: . Project Manager: Glassware Type: !Devin, Candice Regular Glassware Treatment: Regular Rotovap Type: N/A Comments: Sample size - 5G0mL AXYS Analytical Services Ltd Duplicate required for 4731. Choose largest available sample. Matrix: Sampie size: Moistures required? Lipids required? Extraction Solvent: FMS Program: Save FMS discards? Biohazard Type: Aqueous, EFFLUENT final 500 mL NO :NO iSRE N/A N/A . Human Biohazard Tor 4501 previous WG's associated with samples: W G42264 PS Spiking: Samples, Batch Surrogate, Recovery Spiking details Contract # Sample 4501 L18992-1 4501 L18992-2 4731 L18989-1 4731 L1899 2 ....... 4731 I 18S8S-3 4731 L18989-4 4731 L16959-5 4731 L18989-6 4731 L18989-7 4731 L18989-8 4731 L18989-9 Wt Contract it Sample 500 mL 500 m l 500 m l 500 r:L 500 ~ l. 600 m l 500 .rL 500 mL 500 mL 500 mL 500 mL 4731 4731 4731 4731 4731 118989-10 L18989-11 L18989-12 L18989-13 118989-14 500 mL 500 mL 500 mL 500 mL 500 mL . |w t Product FC060 Before Extraction: Samples required: Surrogate L169S2-1. 2. L 6S6S-1. 2. 3. 4, S, 5, 7, 8. & 10. I t , 12. 13, 14. WG42273-1QI. 102. 103, 104 iS r ii- ) Z* Z O u L F C O Z 3 A -S U S /f5 i r After Extraction: Cleanup Surrogate WA ; Recovery 't 50uL FC 009A -R E C /6/ t | W' F.V. Z 4000 uL U-vial Instructions and Comments: P P R O P S N A P W / MS/MSD: 105 u L FC039A-AUT; not same as SPM AUT; second SAR is MS/MSD PVCD A u th e n ti c . FSA-004 Rev 16, 16-Feb-2010 m Page 1^80^24 of 307 www.axysanalytical.com b a tc h lis t par t tw o BATCH ID: WG42273 Type and QC Samples Weight Analysis QC I required for: Authentic spiking: AXYS Analytical Services Ltd QC samples, Authentic Spiktng and Comments Comments: Type and Analysis QC QC Samples Weight required for: Authentic spiking: Comments: WG42273-101 BLANK 5G0M L C A N A D IA N S P R IN G S W A T E R O R 1 L FO R 1 L SAM PLES) WG42273-12 SPM 5Q0M L C A N A D IA N S P R IN G S W A T E R (O R 1 L FO R 1 L SAM =_CS: 1160uL FC039B-AU T/ & jL WG42273-103 ( F O R 4731 ) 500M L DUP O F L I 0389- W G 42273-104 SAR 1 6 0u LFC 0 3 9 B -A U T/ FSA-004 Rev 16, 16-Feb-2010 Page 2Page 25 of 307 www.axysanalytical.com AXYS Analytical Services Ltd Sample Labeling Information: Batch ID: WG42273 Method: MLA-060 R10.03 Date: I S i n _ Analyst: Sample ID Sample Type and Description Original Labelling Contract #: 4731 L18989-1 L18989-2 L18989-3 L18989-4 L18989-5 L18989-6 L18989-7 L18989-8 L18989-9 L18989-10 L18989-11 L18989-12 L18989-13 L18989-14 C A iM r- c-nt-Dur LOi A k D k L -S k )^ .O ic V T > k l> A - 0 -4 Ik LA tX siX ' Co k o r W s ^ X^CfUick u J iX k X A l - S k i - e i s ^ i - T x iX X - H U i t - 2) cvr A" i j \ exV Q. (- l& c^r-- f & A u r l ' c f s / t 4_ c v i'i'U 10L X - 'i> U ? A -\2 ll H l)< X r ~VT C.V W i-C . '(2- le t , /-- D o U > u r lefi.5 I k A. 14a L - S k i ^ O C X 1 " O - 17- 11 I k t ) o r Vtc^- U 'W i-Sv\y. t ) A 7 . ~ 1 > L U ~ ^ C x r o i- - l - 12.1U \ r _ i n c r (>.') I 'o f V i i . `v i ' l ' U T ) A L .- S U } L X 1-2. 11A d ff lU o r f.mto o r k s S t)w v u , W W <4f 4 k T > A L 7 S U jk " T 'lo l ' 4 A c, r tto to u -r le s *> ( A fk A ? w V-7 <u j W W . . 1 lA A L - S U i^ T A o z . 121A o A C o in i j f WLS [ 7& t^ j\ X W L A c tr - 4 a CO \ Ct 4- -_ ` fc -L o w - c o /.o t a le s s (.>4 Ma VL* ptfx.r T sCa j W X c riX o ix -r l C o lo u r l e s S i ^ v i X A t l o , 7>^r k ' V<? tk>e=nrt- Cc a o ' f U e tj r le s s 'piX C t'T c-t' 1. V $L~ l 'CtJ. 4 ^ w r^L . O -lCitf" C o ( jr U $ 3 i A- O 'fJ 'X rpwP V i Cci 1^ 4 c ^ T>AJ - S k i - 'T 3 o 3 - 12-12,0 3 T )A L " S k J " " r4 o M "-T X 7kA - la to - o s llA L ^ k J - T T S k ^ lD U X A " V k iA D k t> A i^ S u ) - r k ) t - h u lk A - la ix o 4 T i A l - S k i " T ^ D A - ' b u 4 > A '- n J A o k fVa.o, J-- C n l o o f U s s "par V >x; U Vo C G o x .r C b k o r W s i.k r;i cL io ; k X , 1 U s A. i / s f k . T W L - S u ; " T fio $ V - > > 0 k A - la iA O S ' m a -S k i -D u P A -a ia n S " '-w V ttv U W . 1' 1 LIMS label correct as per client n FWO-305 Rev 07, 1B-Dec-2012 Reviewed by_ date C Page o f_____ Page 26 of307 www.axysanalytical.com AXYS Analytical Services Ltd Sample Labeling Information: Batch ID: WG42273 Method: MLA-060 R1.3 Date: Analyst: -- Sample ID Sample Type and Description Original Labelling WG42273-103 (DUP) C-DLutcp<jr ColouafJt-f.S--11tf) 8^--/! J- i iO^r-LIWDA\i\Lf-iLStj Contract #: NONE i^ z.o4 FWO-305 Rev 07, 18-Dec-2012 Reviewed by_ date LIMS label correct as per client n Page. ILL o f ____ m Page 27 of 307 www.axysanalytical.com AXYS Analytical Services Ltd Sample Labeling Inform ation: Batch ID: W G 4 2 2 7 3 __________ Date: (PTDgcrA- M e th o d : MLA-G6G R 10.03 Analyst: Sample ID Sample Type and Description Original Labelling Contract #:_____ NONE WG42273-11 (BLANK) WG42273-102 (SPM) WG42273-104 (SAR) P roodt ns, \ lWccn p " CJ~P-c*s~ G o/oc^rUfeS , H cA fh x A C Jp j^ r C o lo u r iesS , i>Vcfv i X > A u c fD ^ c i.le /A t k i^ ^ 4 ir W o v e r - g /" 0-Vv-^i J-tv<v--v. :J U PAsk -- P -A i-i A a^ f irl. AJ . lA &> 3b i / 3*- / FWO-3Q5 Rev 07, t8-Dec-2012 ehReviewed by. date *7 -- LIMS label correct as per client n Page 28 of 307 www.axysanalytical.com AXYS Analytical Services Ltd Upfront 10Ox dilution Particulate Y/N Sam ple W t #2 : Batch ID: WG42273 Analyst Date: ( " y Method: MLA-060 R10.03 Sample ID Container + Sam ple Sample w t (g) {Compositing SLA-084 Container Container Container + Sam ple 7 - Bal ance #: 3 ' oLj ) Sam ple w t ___ Sam ple w t ___ CSubsample required (SLA-084 (g) ) Bottle + Empty Total Remaining cap + bottle sam ple sample sam ple Sam ple W t. (g) L18989-1 L18989-2 L18989-3 L18989-4 L18989-5 L18989-6 L18989-7 L18989-8 L18989-9 L18989-10 118989-11 L18989-12 L18989-13 L18989-14 L18992-1 L18992-2 WG42273-101 (BLANK) W G 42273-102 (SPM) Extraction Information: visible particulate: Stirring: Solvent used: DCM Start Date: Shakinq: time: Solvent used: DCM Date: time: Particulate {soxhiet extraction): Solvent: Start Date: time: no visible particulate: v o lu m e : end Date: # of shakes: vo lu m e : end Date: fr. U* fo Z O .1 2 3 ( 7 3 ? J S lM S io o Q .S S io H .i a 1 6 3 7 1 4 3 6 . tf 1 4 6 .8 3 3 7 .3 8 '7 .0 8 .3 ? S o i) 7 7 l o i e , s -4, 12-17. ^ -+0" 3748 o z s u a 4 1 1 7 1 0 3 3 . ft, 5 7 6 .08 11377 n -H H W 3 3 i ZLtL .0^4 7 3 3 io z I T - I f r / r . / x 0 ^Jo 0 .SAO ^$Dc> ^ < o c> ''-'S X O /^Scx? CiSin&0Mt.i ~So >1 S O 'L5 `D O x/<7>0 A'5 ^ > ------ y T i- b tT r /S '.4 S ' y y4 7 3 3 3 7 fC /3 1 y T > 6 .$ 7 S o t. t o W -1 1 4 M .U O y y y y $ 2 1 .7 3 b 2 z> .3 o y y y s n -.fi $0 8 . 0 4 V y y S -Z 4.08 y y 4 n .p i S o l. L z ki S o {.l3 kj mL Analyst: time: vo lu m e: mL Analyst: mL Analyst: time: FWO-307 Rev 08, 26-Jul-2011 Reviewed bv dale Page 2 * 4 of Page 29 of 307 Upfront 10Ox dilution I Particulate Y/N www.axysanalytical.com AXYS Analytical Services Ltd Sample W t #2 : Batch ID: WG42273 Method: m l a -060 R 10 .03 Sample ID Container + Sam ple Analyst Date: ' Sample w t (g) (Compositing SLA-084 Container + Sample Container Container t-Y7- Balance #: 2 > i o L\ , ) Sam ple w t ___ Sam ple w t ___ iSubsample required [SLA-084 (g) Bottle + cap + E m pty bottle Total sam ple Remaining sample sam ple Sam ple W t. (g) WG42273-103 (DUP) WG42273-104 (SAR) 7 .^ . Il ----- .- --- c - ---- Extraction Information: visible particulate: S tirrin g : Solvent used: PCM Start D ate:______________ time: __ Shaking: Solvent used: PCM D ate:_____________ time: _ P articulate (soxhlet extraction): Solvent:___ Start Date: time: FWO-37 Rev 08, 26-Jui-2011 no visible particulate: volume: end Date: # of shakes: mL Analyst: time: volume: volume: end Date: Cri--Reviewed by date mL Analyst: time: _ml_ Analyst: ~,_ofPage. ____m_ Page 30-of 307 www.axysanalytical.com AXYS Analytical Services Ltd S p ikin g Sheet: Batch ID: WG42273____________ Method: MLA-060 R10.03 / SLA-017 Witness name/ initials: J & ' m k Q Sam ple ID L18989-1 L18989-2 L18989-3 L18989-4 L18989-5 L18989-6 L18989-7 L18989-8 L18989-9 L18989-10 L18989-11 L18989-12 L18989-13 L18989-14 L18992-1 L18992-2 WG42273-101 (BLANK) WG42273-102 (SPM) Before extraction , Surr. ID: P C O Q S A - S & M Date: l o E c Q 1 Voi.: QO mL Svrinqe#: 571 IQ Ampoule: 5t Analyst: fcT7>C_- Before extraction Surr. ID: Date: Voi.: uL Svrinqe#: Ampoule: Analyst: Time IQ I5 iai IQ 1C fQ R ID lF [Q H ' fQ R I2 !$ 31% 131% is fo iq i& iR ia jq m c\ ia a o 29-0 Witness it/J Jew S tb A .\L H U ja J6M J6H j CM It M JcM Je m Jl h JC M j M JfjA iC M Sr M JcH Time Witness Cleanup Std. Surr.: Date: Voi.: uL Svrinqe#: Amooule: Start time: Fin. time: Analyst: Cleanup Std. Surr.: Date: Voi.: uL Svrinae#: Amooule: Start time: Fin. time: Analyst: Recovery S u it .: rCooA A -&-A Date: !&"!> c l z . Vol.: T o uL F.V.: M o t ? o uL Svrinqe#: S1) Amooule: n r- Start time: l< T t o Fin. time: sr2-< ~ Recovery Surr.: Date: Vol.: F.V.: Svrinqe#: Ampoule: Start time: Fin. time: uL uL Analyst: J J ^ Analyst: y / y y y y y y y y y y y y y Sample ID Authentic Std: Date: i f O E c P Voi.: I, Svrinqe#: 2 1 Ampoule#: H Analvst: ( f O Time uL Witness Authentic Std: Date: Voi.: Svrinqe#: Ampoule#: Analvst: Time uL Witness Authentic Std: Date Voi. : Syringe# Ampoule# Analvst: Time ML Witness W 6 U 1 3 ^ 3 - loQiSPM) -10*4 /5A R ) ia i5 m JcH Jew FWO-310 Rev 08, 16-Feb-2010 Reviewed by _ ^ i d a te /C b g c i'Z m P a a e ~ S ^ oi F ig 3fT3D7 www.axysanalytical.com AXYS Analytical Services Ltd S p ik in g Sheet: Batch ID: WG42273_____________ M ethod: MLA-060 R 10.03 / SLA-017 W itness nam e/ initials: __ J a m ie k cJ u ) f f / T L aa, Sam ple ID Before extraction Before extraction Surr. ID: PCG3 ^A - f42yk! Surr. ID: Date: li'O t R 1 Date: Vol.: 34T uL Voi.: uL Syringe#: S! f2 Svrinqe#: Ampoule: Y Ampoule: Analvst: - Analvst: Cleanup Std. Surr.: Date: Voi.: uL Svrinqe#: Ampoule: Start time: Fin. time: Cleanup Std. Surr.: Date: Voi.: uL Svrinqe#: Ampoule: Start time: Fin. time: WG42273-103 (DUP) WG42273-104 (SAR) Time IQ Q I1A A ^ Witness J fM If M Time Witness Analyst: Analyst: Recovery Surr. A -P e e /n i Date: lT>Cl2- ' VoL: -V--> uL F.V.: 4 co uL Svrinqe#: "SilM Ampoule: l-bi. Start time: (S '!* Fin. time: i5 v C Analyst: FTW / y Recovery Surr.: Date: Voi.: F.V.: Svrinqe#: Ampoule: Start time: Fin. time: Analvst: uL uL Sample ID Authentic Std: Date: VoL: Svrinqe#: Ampoule#: Analvst: Time . uL Witness Authentic Std: Date Voi. Syringe# Ampoule# Analyst: Time ML Witness Authentic Std: Date Voi. Syringe# Ampoule# Analvst: Time ml Witness FWO-310 Rev 08. 16-Feb-2010 Reviewed bv efhuiPtt- n , da ter^? """ ' o Page ; ui Page 32 of307 www.axysanalytical.com AXYS Analytical Services Ltd LC M ethods W o rksh e e t Workgroup: WG42273_____ Method: MLA-060 R10.03 Sample Preparation and Extraction: Analyst: & Date: Fraction: Reagent 50% formic acid 0.05 M KOH in MeOH 3% acetic acid 0.3% (NHjOH)/ 99% MeOH Reagent water ty p e :.............. Carbon (50 mg } acetonitrile (CH>CN) Formic acid cone, NHsOH cone. EDTA 0.14M Na2H P 04 buffer pH 2 HCI cone. ammonium acetate buffer 1 M, pH 5.0 ammonium acetate buffer 1 M, pH 6.5 ammonium acetate buffer 1 M, pH 4.0 Phosphate buffer 1 M, pH 6.0 ' enzyme ftqJucoronidase/suifatase enzyme ft- gtucoronidase 5% NHjOH in water HpO type 5% borate buffer pH 9 0.012 g/mL FMOC-Cf Acidified water with HCi ipH ) 3:1 MtBE:MeOH Sodium acetate buffer 0.5M, pH 4 10% acetate buffer pH 4 EDC.HCI 140mM KOH in 80:20 MeOH: Water MeOH Lot# Voi. ml Time Voi. Time ml Voi. Tim e mL Sonication Analyst: ate: Time: #times: Shake/ tipper Analyst: Date: Time: #times: Derivatization Anaiyst: Date: Start time: End time: Miiiipore: Analyst; Date: I B i> c C\~z. Time: II Sto Filtration: Anaiyst: Date: Time: Extract pH check/adjust c1 -P H ( b . S ' - ' f . Date; / & D f c C ) 2 Time: f Z _Q Q Anaiyst: <S7S i__ 2. pH Date: Time: Analyst: 3. pH Date: Time: Analyst: incubation: Analyst: Date: Start time: M anifold # r? >2 . P 2 A n a ly s t Sample ID Date: r 3 t it r ^ i 2 Position L 18989-1 1/ \ L18989-2 I L18989-3 L18989-4 L18989-5 V3 j 8 <( L18989-6 L18989-7 L18989-8 L18989-9 118989-10 L18989-11 ^c > / 1 X. ( o f f L18989-12 / L18989-13 L18989-14 \ L18992-1 L18992-2 T iO \J '^ WG42273-101 (BLANK) \ i f z 3 4 4 Stiller units WG42273-102 (SPM) WG42273-103 (DUP) WG42273-104 (SAR) i i? ^ V .......... End time: FWO-333 Rev 04, 26-Oct-2011 Reviewed by: 6 / O c - Date: tr /0L_ mPaqe of J L Page 33 of 307 www.axysanalytical.com AXYS Analytical Services Ltd LC Methods Cleanup Worksheet W orkgroup: W G42273 Method: m l a -060 r i o .Q3 SPE P re-E lution/ C onditionir>g: Date: f 1 2_ Analyst: <T>c. SP E type: ur A-X Lot#: Reagent Lot Voi. Tim e # mL 0.1 M Formic add 0.3% NH4OH/ 99% MeOH 1: MeOH 2: MeOH Reagent water type: Acidified water H ,0 Type (with HCI) pH DCM I'S-z. . s ~ O 3 0 r 12. Z - f 2:30:68 Formic acid: Acetonitrile:MtBE 2% NH4OH in water H20 T y p e Wash: / Load Sam ple: J Reagent Reagent water type: C S 50% 0,1 M Formic acid/ 50% MeOH 0.1 M Formic add 0.3% basic (NH4OH)/ 99% CS water 20% MeOH/ 80% 0,1 M Formic acid Lot VoL Time # mL $43 '^ )5 L iS z e Acidified water HjOType (with HCI) dH 0.1 M HCI/ 5% MeOH Elution: Reagent MeOH 0.3% NH,,OH/ 99% MeOH Carbon (optional) 1:1 Acetone:MeOH 2 % Formic acid in MeOH Lot # Acetonitrile (CH3CN) Hexane 2:30:68 Formic add: Acetonitrile: MtBE DCM Hexane 1 : Acetonitrile (CH3CN) 2: Acetonitrile (CH3CN) 0.1 M H C I/5% MeOH MtBE 10:20:70 NH4OH: MeOH: MtBE Acetonitrile (CH3CN) 5% MeOH/ 95% water H20 Type 2% NH4OH in water. H ,0 Tvoe Hexane MtBE DCM 10:20:70 NH4OH: MeOH:MtBE 1:1 DCM;MeOH 3:1 MtBE: MeOH Ethyl acetate 9:1 MtBE: MeOH Fraction: -- --- Analyst: d l) Voi. Time ml 4 is 'S ? Reconstitute fo r pviai: Date: A n a ly s t: / / / // / Reagent 0.1% Formic acid buffer Lot Voi. # rpL / / Tim e 1: MeOH 2: MeOH / // / / 3: MeOH /./ 0.3% NH4O H /99% / MeOH / / 70:30 MeOH: wafr H O T vo e // / 1:1 MeOH: 0./% acetate buffer / 1 : 1 CHjCH' Ammonsurfr acetate, Acetic acid buffer 1:1 0,1% Acetic acid in CH3dN:W ater HjO "fype 1:1 tf.2% Acetic acid in o(-|3CN:Water H2P Type Ragent water type: 0.5M Sodium Acetate Buffer pH 4 1:1 Acetonitrile: Acetone 5% Acetonitrile in water H20 Type MeOH 1: 1 Acetonitrile: Acetone 2 % Formic acid in MtBE MeOH= M ethanol; MIBE= M ethyl-l-butyi ether; DCM= D ichlorom elhane; M eCN = C H 3CN= Acetonitrile; NH4OH= Am m onium hydroxide (30% aqueous unless otherwise spec.); CS= C anadian Springs FWO-334 Rev 03, 18-Sep-2012 Reviewed by; Date; / >T - Page 34 of 307 www.axysanalytical.com Notes: Batch ID: WG42273 AXYS Analytical Services Ltd Method: m l a -060 R 10.03 Date: Analyst Fraction Notes: Reviewed by 50^-- ________ date_ FWO-314 Rev 04, 13-May-2008 Page Page~35of 307 www.axysanalytical.com BATCH LIST PART ONE BATCH ID; W G42428 M ethod ID: M LA -060 R 10.03 M ethod ID: Comments: Sam ple size - 500rnL M ethod ID: A nalyst: .............. Start Date: 14-Jan-13 Batch List Author: ............. SDH ESI......................... Checked By: .......................... - i r ....... Project Manaqer: Candice Glassware Type: Regular Glassware Treatment: Regular Rotovap Type: N/A A X Y S Analytical Services Ltd Matrix: Sample size: Moistures required? Lipids required? Extraction Solvent: FMS Program: Save PMS discards? Aqueous 500 mL NO NO ;SPE N/A N/A Biohazard Type: None previous WG's associated w ith sam ples: WG42264_PS, WG42273JDRIG Contract # Sample Wt Contract # Sample 4731 LI 8389-1 R 500 m l 4731 L18989-2 R 500 mL 4731 L 18989-3 R 500 mL 4731 L18989-4 R 500 mL .....4731 ...... L18989-5 R 500 mL 4731 L18989-6 R 500 mL 4731 L18989-7 R 500 mL 4731 L18989-8 R 500 mL 4731 L18989-9 R 500 mL 4731 L18989-10 R 500 mL 4731 L18989-12 R 500 mL 4731 L18989-13 R 500 m l 4731 L18989-14 R 500 m l Wt www.axysanalytical.com BATCH UST PART ' 'WO BATCH ID: WG42428 Type and QC Samples Weight Analysis QC required for: Authentic spiking: AXYS Analytical Services Ltd QC samples, Authentic Spiking and Comments Comments: Type and Analysis QC QC Samples Weight required for: Authentic spiking: Comments: WG4242S-101 IBLANK 500M l CANADIAN SPRINGS WATER (OR 1 L FOR 1 L SAMPLES) WG42428-12 SPM 5GML CANADIAN SPRINGS WATER (OR 1 L FOR 1 L SAMPLES) 'l60uLFC 039S -A U T /bl^ W G 4 24 28-103 SAR ' 160L FC038B-AUT/ 0 l* FSA-004 Rev 16, 16-Feb-201G Page 2p a e 3 7 of 307 www.axysanalytical.com Sample Labeling Inform ation: Batch ID: W G 42428 Method: MLA-060 R10.03 AXYS Analytical Services Ltd _____ Date: M ~ J f r ,K .M 3 Analyst: ZLciO Sample ID Sample Type and Description Original Labelling Contract #:_____ 4731 L18989-1 R L18989-2 R L18989-3 R L18989-4 R L18989-5 R L18989-6 R L18989-7 R L18989-8 R L18989-9 R L18989-10 R L18989-12 R L18989-13 R L18989-14 R WG42428-101 (BLANK) WG42428-102 (SPM) WG42428-103 (SAR) clPa/ (oicsl& 5 lk/1 vjj rV .i A iYtrn1\rL/li1S.-F r ' D A -L-S W - R o a L Y - D ^ P /A - Q 1 1 1 6 c k o v . slto/rf udlfAtJ &uy W / V;AL~-SA~Q J5L - W P A - f t H l ^ >rdl pacH ooiai-* d e a r (AcA-P/r-* liaokJ u/y m - 5 k J - Q.\ o L 3 ~ DOPA - I Z i U q f h e pA cA tik> ciear isOr\Q&} ttjJ "io c par'P/'.JrN ZW rAo/Uy? Ib liil y} m i - .TIaJ " 2 0 A L 3 - V U P A - I Z / I Z O kiiVb parlV .bldfe dOfi-j (Aofboo A kjj D 4 L - 5 W - T l o l - V v Pa - 1 X 1 7 - 0 3 Dlt p&r-fi ( A C$'V d m / rAof\$&) ik iM kj/ D A L - 51 a ) - r i o i - QOPA ~ a i z o l A nl. naA-icddXx^ e lite /' fA n A b d i>cri M 0 A 0 - 5 b J ~ r Z o 3 - DO P A - { 2 1 2 0 ? 'i A- pctrH Jafer\& / (A o fl M iw? JW iv2 1 W --5 W -T HoH- V uP A -1212P 3 -TiAp. nar'kcjAcJJ' & H (A o f\m o ^(yt iiA e - p a r k t,blcL&. M ' J W - W - VoPA -IZiZOH d o o r rc J /U ^vU wJ -ia a , fA'ic-i/lrXsL d -ea r c j o f o*Q r>oe\J) D A L-5LJ - T A 0 Z - 9 0 P A - V fik 'D u j - V O P A - 1212-0 5 4 W payfiiA ft tlOj&r Co\o< Qjy) t\lx'A \AjT D A L 'C L j- T - do P A - 12120 5 A'ifVP, D a ^ lk c la X i c o j y s cA o( \,paVf h o \jiA .....l e l a m m :.... r ............ r i.OS cA fi-A yt i W i J i^ sxk C a riQ fU o / kp n n A A WgAq s P ci'A .k ^ 3 b 5 Cojr\ a r il 5pn r\^o Vjak&r B a A o k ik - 1>b 5 s . A e, FWO-305 Rev 07, ie-Dec-2012 Reviewed trcM d, ,, H - m y - u LIMS label correct as per client 10/ Page 38 of 307 Upfront tOOx dilution Particulate Y/N www.axysanalytical.com AXYS Analytical Services Ltd S am ple Wt #2 : Batch ID: WG42428 Analyst Date: H Method: m la-060 r io .03 Sample ID Container + Sample Sample w t (g) (Compositing SLA-084 Container Container Container + Sample Balance #: ^ ) Sample w t__ Sample w t__ Cubsam ple required SLA-084 (g) ) Bottle + cap + sample Empty bottle Total Remaining sample sample Sample Wt. (g) L18989-1 R L18989-2 R L18989-3 R L18989-4 R L18989-5 R L18989-6 R L18989-7 R L18989-8 R L18989-9 R L18989-10 R L18989-12 R L18989-13 R L18989-14 R WG42428-101 (BLANK) W G 42428-102 (SPM) W G42428-103 (SAR) 1033.16 4 qg.IV 534.64 ^\c\ 4 5 a .o a 591.04- 413. aa m a i 413.61 lois.qa s i s . w . w 1 0 0 1 ^ 5i.3g 515.3$ 46 1. 0 5 " 4 3 3 . 3 5 143. ta m .S r m ? 6 !S| \i T . M 4 ^ . 4 5 l a s i . ^ 4 4 4 . 4 0 446.44- i 1 & .0 ? ^56. 430.30 10S 33 10 6 v a . ia 1331.65 3 . 1 1 5 40 .44 ---- D a 0 0 0 6) 0 0 0 a 0 0 -- --- ---- y Vi uir 1/ i XV 8 Xr r V i y y r KJ N .-- . Extraction Information: visible particulate: Stirrina: Solvent used: DCM Start Date: Shaking: time: Solvent used: DCM Date: time: Particulate (soxhlet extraction): Solvent: Start Date: time: FWO-307 Rev 08, 26-Jui-2011 no visible particulate: v o lu m e : end Date: # of shakes: mL Analyst: time: vo lu m e: vo lu m e : end Date: mL Analyst: time: Reviewed bv 5TC date I U - o ATJ- 6 mL Analyst: Pago a ( Page 39 of 307 www.axysanalytical.com S p ikin g Sheet: Batch ID: WG42428 SLA-017 Sam ple ID Before extraction S um ID: Date: U ^la ^vU l Voi.: x o uL S v rin q e # : Am poule: tv Anaivs: 1 C M L18989-1 R L18989-2 R L18989-3 R L18989-4 R L18989-5 R L18989-6 R L18989-7 R L18989-8 R L18989-9 R L18989-10 R L18989-12 R L18989-13 R LI 8989-14 R WG42428-101 (BLANK) WG42428-102 (SPM) WG42428-103 (SAR) Tim e fo * > f o~AOr \D '- t >4io-M 'R 1O: l 2 10-2 V r- l sO', j o - -4- ! 0-4-1 1o #a | io '-W IG'-Ml W itness V -ftt ki+ tx y-f*. a -f*'-it*. "Ma. 'fs* vj-ftX 4 -fa 44. 4 fix AXYS Analytical Services Ltd te th o d : m LA-060 R 1 0 . 0 3 W itness nam e/ initials: OP 6 f '\ Before extraction S u m ID: Date: V o i.: uL S v rin q e # : Am poule: Anaivst: Cleanup Std. Surr.: Date: Voi.: uL Svrinqe#: Ampoule: Start time: Fin. time: Cleanup Std. Surr.: Date: Voi.: uL Svrinqe#: Ampoule: Start time: Fin. time: Tim e W itness A n a ly s t: A n a ly s t: Recovery Recovery S urr.: rC O o ik -g iC J f 1Surr.: Date: M -J flU -M Date: Voi.: ^ o uL Vol.: F.V.: iA o c UL F.V.: Syrinqe#: J /V S v rin q e # : A m p o u le : 14 Am poule: Start time: N : 1*> Start time: Fin. time: 14 F in. time: uL uL Anaivst: M M y A n a iv s t: y if y y y v"' y y y y' y Sample ID yj(x, -- foT. Authentic Std :f r .o \t -AuT/M . Date 4-J o w l Voi. f i? & Syringe# s i mL Ampoule# Analyst: j z y i Tim e W itness . Li % gQ LM -3. 4-fa. Authentic Std:_ Date: Voi.: Syringe#: _ Ampoule#:^ ______ Analyst: Tim e ml W itness Authentic Std: Date Vo! Syringe#: Ampoule#: ______Analyst: Tim e FW0-31G Rev 08, 16-Feb-2010 Reviewed by_4 C M date 1 M - J . ml W itness mPage ? f Page 40 of 307 www.axysanalytical.com LC M ethods W o rksheet Workgroup: WG42428 Sam ple Preparation and Extraction: Analyst: ZT6M Reagent Lot# VoL Tim e mL 50% formic acid 0.05 M KOH in MeOH 3% acetic acid 0.3% (NHjOH)/ 99% MeOH Reagent water type: C . S . Carbon (50 mg } acetonitrile (CH3CN) Formic acid cone. NHiOH cone. EDTA 0.14 M Na,HPO< buffer pH 2 HCI cone. ammonium acetate buffer 1 M. pH 5.0 ammonium acetate buffer 1 M, pH 6.5 ammonium acetate buffer 1 M, pH 4.0 Phosphate buffer 1 M, pH 6.0 enzyme ftqiucoronidase/sulfalase enzyme ft- giucoronidase 5% NHaOH in water H?G type 5% borate buffer pH 9 0.012 g/mL FMOC-CI Acidified water with HCi (pH ) 3:1 MtBE:MeOH Sodium acetate buffer 0.5M, pH 4 10% acetate buffer pH 4 EDC.HCI 14QmM KOH in 80:20 MeOH: Water MeOH Voi. Tim e mL AXYS Analytical Services Ltd Method: MLA-060 R10.03 Fraction: Date: Voi. Tim e mL S o n ic a tio n A n a ly s t: Date: Time: #tim es: E xtract pH ch e ck/a d ju st 1-PH .SloT Manifold # PS, PK 'Analyst 7c m . Date: f M - j /r p - G S a m p le ID Position ate: f t Tim e: 0 q L18989-1 R L18989-2 R f li I IS A nalyst: "JZ/A 2. pH _L_18_9_89_-3_R_________\IL H L18989-4 R |) ^ ^ l 3 Shake/ tipper A nalyst: D a te : Time: #tim es: D e riv a tiz a tio n A n a ly s t: ate: Start time: End time: D a te : Tim e: A n a ly s t: 3. pH Date: Tim e: A n a ly s t: L18989-5 R L18989-6 R L18989-7 R 1a 11 j \c L18989-8 R l L18989-9 R iGo L18989-10 R fi L18989-12 R rz. L18989-13 R L I8989-14 R PQ J <3 ] (4 /WG42428-101 (B LA N K ) (5 WG42428-102 (SPM) V ' WG42428-103 (SAR) # filte r units Millipore: A nalyst: Date: | U Time: Filtration: A n a ly s t: a te : Tim e: incubation: A n a ly s t: D a te : S tart lim e: End time: FWO-333 Rev 04, 26-Oct-2011 R . by: ________________ D ,le: M ' M - # Pw o. L _ $ ) ][( $ Page 41 of 307 www.axysanalytical.com AXYS Analytical Services Ltd LC Methods Cleanup Worksheet W orkgroup: WG42428______ Method: m l a -06 0 r io .Q3 SPE Pre-Elution/ Conditioning: Date: M - , sAAm 3 A na lyst: Sc M SPEtvoe: 150mA W/fti Lot#: 0 iV 3 _______________ Reagent Lot Vol. Tim e 0.1 M Formic acid # mL 5 IN? 0.3% NHaOH/ 99% MeOH 1: MeOH m 6 IMS' 2: MeOH Reagent water type: Acidified water H',0 Type (with HCi) pH DCM 2:30:68 Formic acid: AcetonitrilerMtBE 2% NH4OH in water H ,0 Type Wash: , Load Sam ple: v ' Reagent Reagent water type: C. 5 50% 0.1 M Formic acid/ 50% MeOH 0.1 M Formic add 0.3% basic (NH4OH)/ 99% CS water 20% MeOH/ 80% 0.1 M Formic acid Lot # IS S V ol. Time mL 9 5 W -00 Acidified water H2OTvpe (with HCt) pH 0.1 M HCl/ 5% MeOH Elution: Reagent MeOH 0.3% NH4OH/ 99% MeOH Carbon (optional) 1:1 Acetone:MeOH 2 % Formic acid in MeOH Lot # Acetonitrile (CH3CN) Hexane 2:30:68 Formic acid; Acetonitrile: MtBE DCM Hexane 1: Acetonitrile (CH3CN) 2: Acetonitrile (CHjCN) 0.1 M HCi/ 5% MeOH MtBE 10:20:70 NH4OH: MeOH: MtBE Acetonitrile (CH3CN) 5%MeOH/ 95% water H30 Type 2% NH4OH in water, H20 Type Hexane MtBE DCM 10:20:70 NH4OH: MeOH;MtBE 1:1 DCM:MeOH 3:1 MtBE: MeOH Ethyl acetate 9:1 MtBE: MeOH F ra c tio n :________ Analyst: JC M Reconstitute for pvial: Date: Analyst: V ol. Time mL H Reagent 0.1% Formic acid buffer 1: MeOH 2: MeOH 3: MeOH 0.3% NH3OH/ 99% MeOH 70:30 MeOH: water H O Tvoe Lot Vol. # mL 1:1 MeOH: 0.1% acetate buffer 1:1 CH3CN: Ammonium acetate, Acetic acid buffer 1:1 0.1% Acetic acid in CH3CN:Water H20 Type 1:1 0.2% Acetic acid in CH3CN:Water H20 Type Reagent water type: Tim e 0.5M Sodium Acetate Buffer pH 4 1:1 Acetonitrile: Acetone 5% Acetonitrile in water H20 Type MeOH 1:1 Acetonitrile; Acetone 2 % Formic acid in MtBE MeOH= Methanol; M t8E = Methyi-t-butyi ether; DCM= Dichloram ethane; MeCN= C H 3CN= Acetonitrile: NH4OH= Am m onium hydroxide (30% aqueous unless otherwise spec.); CS= Canadian Springs FWO-334 Rev 03. 18-Sep-2012 JLM Reviewed b y :__________ Date: Page 42 of 307 www.axysanalytical.com Notes: Batch ID: W G 4 2 4 2 8 AXYS Analytical Services Ltd Method: MLA-060 R10.03 Date: Analyst Fraction Notes: JdM . Reviewed b y __________ M e JV-JAM-t3 FWO-314 Rev 04, 13-May-2008 Page Page 43 of 307 www.axysanalytical.com A X Y S M ETH O D M LA -060 R ev 10 Form 1A PE R FLU O R IN A TED O R G A N IC S A N A LYS IS REPO RT A XYS A N A LYTIC A L SERVICES 2045 MILLS RD., SIDNEY, B.C., CANADA V8L 5X2 TEL (250) 655-5800 FAX (250) 655-5811 Project No. C o ntract No.: 4731 Lab S am ple I.D.: C LIEN T SAM PLE NO. DAL-SW -R02L3-DUPA-121116 Sam ple C ollection: 16-Nov-2012 13:20 FALL 2012 TENNESSEE RIVER SAMPLING L18989-1 R M atrix : AQUEOUS Sam ple Size: 0.525 L Sam ple Receipt Date: 14-Dec-2012 Initial C alibration Date: 10-Jan-2013 Extraction Date: 14-Jan-2013 Instru m en t ID: LC MS/MS A nalysis Date: 15-Jan-2013 Tim e: 01:38:17 C olum n ID: C18MS Extract V olum e (uL): 4000 Sam ple Data Filenam e: FC3G _015 S: 23 Injection V olum e (uL): 15 B lank Data Filenam e: FC3G_015 S: 22 D ilution Factor: N/A Cal. Ver. Data Filenam e: FC3G_015 S: 16 C oncentration Units: ng/L This page is part of a total report that contains information necessary for accreditation compliance. Results are compliant with NELAP accreditation described in the total report. Sample results relate only to the sample tested. COMPOUND LAB FLAG 1 CONC. FOUND REPO RTING LIM IT (RL)2 R E T E N T IO N TIM E PFBA PFPeA PFHxA PFHpA PFOA PFNA PFDA PFUnA PFDoA PFBS PFHxS PFOS PFOSA 8.82 0.952 (L) 2.22 0.952 (L) 3.83 0.952 (L) 4.64 0.952 (L) 9.14 0.952 (L) U 0.952 (L) U 0.952 (L) U 0.952 (L) U 0.952 (L) 2.70 1.90 (L) U 1.90 (L) 7.59 1.90 (L) U 0.952 (L) 5:12 5:57 6:21 6:44 7:06 6:27 8:10 (1) Where applicable, custom lab flags have been used on this report; U = not detected at RL. (2) Reporting Limit (Code): S = sample detection limit; M = method detection limit; L = lowest calibration level equivalent; Q = contract defined limit. These data are validated and reported as accurate and in accord with AXYS Analytical Services Ltd. ISO17025 compliant quality assurance processes. Signed:____________ A ndrew P o r a t ____________ For Axys Internal Use Only [ XSL Template: FC-Form1A.xsl; Created: 16-Jan-2013 14:49:00; Application: XMLTransformer-1.13.28; ReportFilename: PFC_FC_LC_PFOA_L 18989-1_Form1 A_FC3G_015S23_SJ1552186.html; Workgroup: W G42428;DesignID: 1980 ] Page 44 of 307 Page 1 of 1 (WG42428 - PFC_FC_LC_PFOA_L18989-1_Form1A_FC3G_015S23_SJ1552186.html) www.axysanalytical.com A X Y S M ETH O D M LA -060 R ev 10 Form 2 PE R FLU O R IN A TED O R G A N IC S A N A LYS IS REPO RT A XYS A N A LYTIC A L SERVICES 2045 MILLS RD., SIDNEY, B.C., CANADA V8L 5X2 TEL (250) 655-5800 FAX (250) 655-5811 Project No. C o ntract No.: 4731 Lab S am ple I.D.: C LIEN T SAM PLE NO. DAL-SW -R02L3-DUPA-121116 Sam ple C ollection: 16-Nov-2012 13:20 FALL 2012 TENNESSEE RIVER SAMPLING L18989-1 R M atrix : AQUEOUS Sam ple Size: 0.525 L Sam ple Receipt Date: 14-Dec-2012 Initial C alibration Date: 10-Jan-2013 Extraction Date: 14-Jan-2013 Instru m en t ID: LC MS/MS A nalysis Date: 15-Jan-2013 Tim e: 01:38:17 C olum n ID: C18MS Extract V olum e (uL): 4000 Sam ple Data Filenam e: FC3G _015 S: 23 Injection V olum e (uL): 15 B lan k Data Filenam e: FC3G_015 S: 22 D ilution Factor: N/A Cal. Ver. Data Filenam e: FC3G_015 S: 16 C oncentration Units: ng absolute This page is part of a total report that contains information necessary for accreditation compliance. Results are compliant with NELAP accreditation described in the total report. Sample results relate only to the sample tested. LABELED COMPOUND LAB FLAG 1 S P IK E CONC. CONC. FOUND R(%) 2 R E T E N T IO N TIM E 1 3 C 4 -P F B A 1 3 C 2 -P F H x A 13C2-PFO A 1 3 C 5 -P F N A 1 3 C 2 -P F D A 1 3 C 2 -P F D o A 1 3 C 4-P F O S 18 O 2-P F H x S 12.0 12.0 36.0 12.0 12.0 12.0 18.0 18.0 8.29 9.46 33.1 12.1 10.8 10.6 17.4 18.5 69.1 78.8 92.1 101 90.2 88.6 96.9 103 5:11 6:20 7:06 7:29 8:03 9:11 8:21 7:20 (1) Where applicable, custom lab flags have been used on this report. (2) R(%) = percent recovery. These data are validated and reported as accurate and in accord with AXYS Analytical Services Ltd. ISO17025 compliant quality assurance processes. Signed:____________ A ndrew P o r a t ____________ For Axys Internal Use Only [ XSL Template: FC-Form2.xsl; Created: 16-Jan-2013 14:49:00; Application: XMLTransformer-1.13.28; ReportFilename: PFC_FC_LC_PFOA_L18989-1_Form2_FC3G_015S23_SJ1552186.html; Workgroup: WG42428; Design ID: 1980 ] Page 45 of 307 Page 1 of 1 (WG42428 - PFC_FC_LC_PFOA_L18989-1_Form2_FC3G_015S23_SJ1552186.html) www.axysanalytical.com A X Y S M ETH O D M LA -060 R ev 10 Form 1A PE R FLU O R IN A TED O R G A N IC S A N A LYS IS REPO RT A XYS A N A LYTIC A L SERVICES 2045 MILLS RD., SIDNEY, B.C., CANADA V8L 5X2 TEL (250) 655-5800 FAX (250) 655-5811 Project No. C o ntract No.: 4731 Lab S am ple I.D.: C LIEN T SAM PLE NO. D A L-SW -R 15L1 -D U PA-121117 Sam ple C ollection: 17-Nov-2012 12:25 FALL 2012 TENNESSEE RIVER SAMPLING L18989-2 R M atrix : AQUEOUS Sam ple Size: 0.454 L Sam ple Receipt Date: 14-Dec-2012 Initial C alibration Date: 10-Jan-2013 Extraction Date: 14-Jan-2013 Instru m en t ID: LC MS/MS A nalysis Date: 15-Jan-2013 Tim e: 01:55:18 C olum n ID: C18MS Extract V olum e (uL): 4000 Sam ple Data Filenam e: FC3G_015 S: 24 Injection V olum e (uL): 15 B lank Data Filenam e: FC3G_015 S: 22 D ilution Factor: N/A Cal. Ver. Data Filenam e: FC3G_015 S: 16 C oncentration Units: ng/L This page is part of a total report that contains information necessary for accreditation compliance. Results are compliant with NELAP accreditation described in the total report. Sample results relate only to the sample tested. COMPOUND LAB FLAG 1 CONC. FOUND REPO RTING LIM IT (RL)2 R E T E N T IO N TIM E PFBA PFPeA PFHxA PFHpA PFOA PFNA PFDA PFUnA PFDoA PFBS PFHxS PFOS PFOSA 10.4 1.10 (L) 2.93 1.10 (L) 4.21 1.10 (L) 3.88 1.10 (L) 10.6 1.10 (L) U 1.10 (L) U 1.10 (L) U 1.10 (L) U 1.10 (L) 20.9 2.20 (L) U 2.20 (L) 22.0 2.20 (L) U 1.10 (L) 5:12 5:56 6:21 6:44 7:06 6:27 8:17 (1) Where applicable, custom lab flags have been used on this report; U = not detected at RL. (2) Reporting Limit (Code): S = sample detection limit; M = method detection limit; L = lowest calibration level equivalent; Q = contract defined limit. These data are validated and reported as accurate and in accord with AXYS Analytical Services Ltd. ISO17025 compliant quality assurance processes. Signed:____________ A ndrew P o r a t ____________ For Axys Internal Use Only [ XSL Template: FC-Form1A.xsl; Created: 16-Jan-2013 14:49:00; Application: XMLTransformer-1.13.28; ReportFilename: PFC_FC_LC_PFOA_L18989-2_Form1A_FC3G_015S24_SJ1552187.html; Workgroup: W G42428;DesignID: 1980 ] Page 46 of 307 Page 1 of 1 (WG42428 -PFC_FC_LC_PFOA_L18989-2_Form1A_FC3G_015S24_SJ1552187.html) www.axysanalytical.com A X Y S M ETH O D M LA -060 R ev 10 Form 2 PE R FLU O R IN A TED O R G A N IC S A N A LYS IS REPO RT A XYS A N A LYTIC A L SERVICES 2045 MILLS RD., SIDNEY, B.C., CANADA V8L 5X2 TEL (250) 655-5800 FAX (250) 655-5811 Project No. C o ntract No.: 4731 Lab S am ple I.D.: C LIEN T SAM PLE NO. D A L-SW -R 15L1 -D U PA-121117 Sam ple C ollection: 17-Nov-2012 12:25 FALL 2012 TENNESSEE RIVER SAMPLING L18989-2 R M atrix : AQUEOUS Sam ple Size: 0.454 L Sam ple Receipt Date: 14-Dec-2012 Initial C alibration Date: 10-Jan-2013 Extraction Date: 14-Jan-2013 Instru m en t ID: LC MS/MS A nalysis Date: 15-Jan-2013 Tim e: 01:55:18 C olum n ID: C18MS Extract V olum e (uL): 4000 Sam ple Data Filenam e: FC3G_015 S: 24 Injection V olum e (uL): 15 B lan k Data Filenam e: FC3G_015 S: 22 D ilution Factor: N/A Cal. Ver. Data Filenam e: FC3G_015 S: 16 C oncentration Units: ng absolute This page is part of a total report that contains information necessary for accreditation compliance. Results are compliant with NELAP accreditation described in the total report. Sample results relate only to the sample tested. LABELED COMPOUND LAB FLAG 1 S P IK E CONC. CONC. FOUND R(%) 2 R E T E N T IO N TIM E 1 3 C 4 -P F B A 1 3 C 2 -P F H x A 13C2-PFO A 1 3 C 5 -P F N A 1 3 C 2 -P F D A 1 3 C 2 -P F D o A 1 3 C 4-P F O S 18 O 2-P F H x S 12.0 12.0 36.0 12.0 12.0 12.0 18.0 18.0 9.68 9.56 35.0 13.2 12.0 12.0 17.6 19.4 80.7 79.7 97.2 110 99.8 100 97.8 108 5:12 6:21 7:06 7:29 7:59 9:11 8:21 7:20 (1) Where applicable, custom lab flags have been used on this report. (2) R(%) = percent recovery. These data are validated and reported as accurate and in accord with AXYS Analytical Services Ltd. ISO17025 compliant quality assurance processes. Signed:____________ A ndrew P o r a t ____________ For Axys Internal Use Only [ XSL Template: FC-Form2.xsl; Created: 16-Jan-2013 14:49:00; Application: XMLTransformer-1.13.28; ReportFilename: PFC_FC_LC_PFOA_L18989-2_Form2_FC3G_015S24_SJ1552187.html; Workgroup: WG42428; Design ID: 1980 ] Page 47 of 307 Page 1 of 1 (WG42428 - PFC_FC_LC_PFOA_L18989-2_Form2_FC3G_015S24_SJ1552187.html) www.axysanalytical.com A X Y S M ETH O D M LA -060 R ev 10 Form 1A PE R FLU O R IN A TED O R G A N IC S A N A LYS IS REPO RT A XYS A N A LYTIC A L SERVICES 2045 MILLS RD., SIDNEY, B.C., CANADA V8L 5X2 TEL (250) 655-5800 FAX (250) 655-5811 Project No. C o ntract No.: 4731 Lab S am ple I.D.: C LIEN T SAM PLE NO. DAL-SW -R10L3-DUPA-121119 Sam ple C ollection: 19-Nov-2012 11:00 FALL 2012 TENNESSEE RIVER SAMPLING L18989-3 R M atrix : AQUEOUS Sam ple Size: 0.465 L Sam ple Receipt Date: 14-Dec-2012 Initial C alibration Date: 10-Jan-2013 Extraction Date: 14-Jan-2013 Instru m en t ID: LC MS/MS A nalysis Date: 15-Jan-2013 T im e: 02:12:11 C olum n ID: C18MS Extract V olum e (uL): 4000 Sam ple Data Filenam e: FC3G _015 S: 25 Injection V olum e (uL): 15 B lank Data Filenam e: FC3G_015 S: 22 D ilution Factor: N/A Cal. Ver. Data Filenam e: FC3G_015 S: 16 C oncentration Units: ng/L This page is part of a total report that contains information necessary for accreditation compliance. Results are compliant with NELAP accreditation described in the total report. Sample results relate only to the sample tested. COMPOUND LAB FLAG 1 CONC. FOUND REPO RTING LIM IT (RL)2 R E T E N T IO N TIM E PFBA PFPeA PFHxA PFHpA PFOA PFNA PFDA PFUnA PFDoA PFBS PFHxS PFOS PFOSA 6.79 1.08 (L) 1.67 1.08 (L) 1.64 1.08 (L) 1.24 1.08 (L) 2.56 1.08 (L) U 1.08 (L) U 1.08 (L) U 1.08 (L) U 1.08 (L) U 2.15 (L) U 2.15 (L) 5.48 2.15 (L) U 1.08 (L) 5:15 5:57 6:21 6:41 7:06 8:10 (1) Where applicable, custom lab flags have been used on this report; U = not detected at RL. (2) Reporting Limit (Code): S = sample detection limit; M = method detection limit; L = lowest calibration level equivalent; Q = contract defined limit. These data are validated and reported as accurate and in accord with AXYS Analytical Services Ltd. ISO17025 compliant quality assurance processes. Signed:____________ A ndrew P o r a t ____________ For Axys Internal Use Only [ XSL Template: FC-Form1A.xsl; Created: 16-Jan-2013 14:49:00; Application: XMLTransformer-1.13.28; ReportFilename: PFC_FC_LC_PFOA_L 18989-3_Form1 A_FC3G_015S25_SJ1552188.html; Workgroup: W G42428;DesignID: 1980 ] Page 48 of 307 Page 1 of 1 (WG42428 - PFC_FC_LC_PFOA_L18989-3_Form1A_FC3G_015S25_SJ1552188.html) www.axysanalytical.com A X Y S M ETH O D M LA -060 R ev 10 Form 2 PE R FLU O R IN A TED O R G A N IC S A N A LYS IS REPO RT A XYS A N A LYTIC A L SERVICES 2045 MILLS RD., SIDNEY, B.C., CANADA V8L 5X2 TEL (250) 655-5800 FAX (250) 655-5811 Project No. C o ntract No.: 4731 Lab S am ple I.D.: C LIEN T SAM PLE NO. DAL-SW -R10L3-DUPA-121119 Sam ple C ollection: 19-Nov-2012 11:00 FALL 2012 TENNESSEE RIVER SAMPLING L18989-3 R M atrix : AQUEOUS Sam ple Size: 0.465 L Sam ple Receipt Date: 14-Dec-2012 Initial C alibration Date: 10-Jan-2013 Extraction Date: 14-Jan-2013 Instru m en t ID: LC MS/MS A nalysis Date: 15-Jan-2013 T im e: 02:12:11 C olum n ID: C18MS Extract V olum e (uL): 4000 Sam ple Data Filenam e: FC3G _015 S: 25 Injection V olum e (uL): 15 B lan k Data Filenam e: FC3G_015 S: 22 D ilution Factor: N/A Cal. Ver. Data Filenam e: FC3G_015 S: 16 C oncentration Units: ng absolute This page is part of a total report that contains information necessary for accreditation compliance. Results are compliant with NELAP accreditation described in the total report. Sample results relate only to the sample tested. LABELED COMPOUND LAB FLAG 1 S P IK E CONC. CONC. FOUND R(%) 2 R E T E N T IO N TIM E 1 3 C 4 -P F B A 1 3 C 2 -P F H x A 13C2-PFO A 1 3 C 5 -P F N A 1 3 C 2 -P F D A 1 3 C 2 -P F D o A 1 3 C 4-P F O S 18 O 2-P F H x S 12.0 12.0 36.0 12.0 12.0 12.0 18.0 18.0 8.67 9.47 32.8 11.7 10.1 10.4 17.3 17.0 72.3 78.9 91.2 97.9 84.5 86.6 96.3 94.4 5:12 6:21 7:06 7:29 8:03 9:11 8:21 7:20 (1) Where applicable, custom lab flags have been used on this report. (2) R(%) = percent recovery. These data are validated and reported as accurate and in accord with AXYS Analytical Services Ltd. ISO17025 compliant quality assurance processes. Signed:____________ A ndrew P o r a t ____________ For Axys Internal Use Only [ XSL Template: FC-Form2.xsl; Created: 16-Jan-2013 14:49:00; Application: XMLTransformer-1.13.28; ReportFilename: PFC_FC_LC_PFOA_L18989-3_Form2_FC3G_015S25_SJ1552188.html; Workgroup: WG42428; Design ID: 1980 ] Page 49 of 307 Page 1 of 1 (WG42428 - PFC_FC_LC_PFOA_L18989-3_Form2_FC3G_015S25_SJ1552188.html) www.axysanalytical.com A X Y S M ETH O D M LA -060 R ev 10 Form 1A PE R FLU O R IN A TED O R G A N IC S A N A LYS IS REPO RT A XYS A N A LYTIC A L SERVICES 2045 MILLS RD., SIDNEY, B.C., CANADA V8L 5X2 TEL (250) 655-5800 FAX (250) 655-5811 Project No. C o ntract No.: 4731 Lab S am ple I.D.: C LIEN T SAM PLE NO. DAL-SW -R05L1-1-121119 Sam ple C ollection: 19-Nov-2012 16:25 FALL 2012 TENNESSEE RIVER SAMPLING L18989-4 R M atrix : AQUEOUS Sam ple Size: 0.443 L Sam ple Receipt Date: 14-Dec-2012 Initial C alibration Date: 10-Jan-2013 Extraction Date: 14-Jan-2013 Instru m en t ID: LC MS/MS A nalysis Date: 15-Jan-2013 Tim e: 02:29:12 C olum n ID: C18MS Extract V olum e (uL): 4000 Sam ple Data Filenam e: FC3G _015 S: 26 Injection V olum e (uL): 15 B lank Data Filenam e: FC3G_015 S: 22 D ilution Factor: N/A Cal. Ver. Data Filenam e: FC3G_015 S: 16 C oncentration Units: ng/L This page is part of a total report that contains information necessary for accreditation compliance. Results are compliant with NELAP accreditation described in the total report. Sample results relate only to the sample tested. COMPOUND LAB FLAG 1 CONC. FOUND REPO RTING LIM IT (RL)2 R E T E N T IO N TIM E PFBA PFPeA PFHxA PFHpA PFOA PFNA PFDA PFUnA PFDoA PFBS PFHxS PFOS PFOSA 75.5 1.13 (L) 17.0 1.13 (L) 66.1 1.13 (L) 64.7 1.13 (L) 210 1.13 (L) 2.01 1.13 (L) U 1.13 (L) U 1.13 (L) U 1.13 (L) 166 2.26 (L) 35.5 2.26 (L) 388 2.26 (L) 20.3 1.13 (L) 5:12 5:57 6:21 6:41 7:06 7:29 6:29 7:20 8:17 9:59 (1) Where applicable, custom lab flags have been used on this report; U = not detected at RL. (2) Reporting Limit (Code): S = sample detection limit; M = method detection limit; L = lowest calibration level equivalent; Q = contract defined limit. These data are validated and reported as accurate and in accord with AXYS Analytical Services Ltd. ISO17025 compliant quality assurance processes. Signed:____________ A ndrew P o r a t ____________ For Axys Internal Use Only [ XSL Template: FC-Form1A.xsl; Created: 16-Jan-2013 14:49:00; Application: XMLTransformer-1.13.28; ReportFilename: PFC_FC_LC_PFOA_L18989-4_Form1A_FC3G_015S26_SJ1552189.html; Workgroup: W G42428;DesignID: 1980 ] Page 50 of 307 Page 1 of 1 (WG42428 -PFC_FC_LC_PFOA_L18989-4_Form1A_FC3G_015S26_SJ1552189.html) www.axysanalytical.com A X Y S M ETH O D M LA -060 R ev 10 Form 2 PE R FLU O R IN A TED O R G A N IC S A N A LYS IS REPO RT A XYS A N A LYTIC A L SERVICES 2045 MILLS RD., SIDNEY, B.C., CANADA V8L 5X2 TEL (250) 655-5800 FAX (250) 655-5811 Project No. C o ntract No.: 4731 Lab S am ple I.D.: C LIEN T SAM PLE NO. DAL-SW -R05L1-1-121119 Sam ple C ollection: 19-Nov-2012 16:25 FALL 2012 TENNESSEE RIVER SAMPLING L18989-4 R M atrix : AQUEOUS Sam ple Size: 0.443 L Sam ple Receipt Date: 14-Dec-2012 Initial C alibration Date: 10-Jan-2013 Extraction Date: 14-Jan-2013 Instru m en t ID: LC MS/MS A nalysis Date: 15-Jan-2013 Tim e: 02:29:12 C olum n ID: C18MS Extract V olum e (uL): 4000 Sam ple Data Filenam e: FC3G _015 S: 26 Injection V olum e (uL): 15 B lan k Data Filenam e: FC3G_015 S: 22 D ilution Factor: N/A Cal. Ver. Data Filenam e: FC3G_015 S: 16 C oncentration Units: ng absolute This page is part of a total report that contains information necessary for accreditation compliance. Results are compliant with NELAP accreditation described in the total report. Sample results relate only to the sample tested. LABELED COMPOUND LAB FLAG 1 S P IK E CONC. CONC. FOUND R(%) 2 R E T E N T IO N TIM E 1 3 C 4 -P F B A 1 3 C 2 -P F H x A 13C2-PFO A 1 3 C 5 -P F N A 1 3 C 2 -P F D A 1 3 C 2 -P F D o A 1 3 C 4-P F O S 18 O 2-P F H x S 12.0 12.0 36.0 12.0 12.0 12.0 18.0 18.0 9.67 9.05 32.1 12.0 11.1 11.3 18.4 20.3 80.6 75.4 89.1 99.9 92.8 94.1 102 113 5:11 6:21 7:06 7:29 7:59 9:11 8:17 7:20 (1) Where applicable, custom lab flags have been used on this report. (2) R(%) = percent recovery. These data are validated and reported as accurate and in accord with AXYS Analytical Services Ltd. ISO17025 compliant quality assurance processes. Signed:____________ A ndrew P o r a t ____________ For Axys Internal Use Only [ XSL Template: FC-Form2.xsl; Created: 16-Jan-2013 14:49:00; Application: XMLTransformer-1.13.28; ReportFilename: PFC_FC_LC_PFOA_L18989-4_Form2_FC3G_015S26_SJ1552189.html; Workgroup: WG42428; Design ID: 1980 ] Page 51 of 307 Page 1 of 1 (WG42428 - PFC_FC_LC_PFOA_L18989-4_Form2_FC3G_015S26_SJ1552189.html) www.axysanalytical.com A X Y S M ETH O D M LA -060 R ev 10 Form 1A PE R FLU O R IN A TED O R G A N IC S A N A LYS IS REPO RT A XYS A N A LYTIC A L SERVICES 2045 MILLS RD., SIDNEY, B.C., CANADA V8L 5X2 TEL (250) 655-5800 FAX (250) 655-5811 Project No. C o ntract No.: 4731 Lab S am ple I.D.: C LIEN T SAM PLE NO. DAL-SW -RO6L2-DUPA-121120 Sam ple C ollection: 20-Nov-2012 16:30 FALL 2012 TENNESSEE RIVER SAMPLING L18989-5 R M atrix : AQUEOUS Sam ple Size: 0.413 L Sam ple Receipt Date: 14-Dec-2012 Initial C alibration Date: 10-Jan-2013 Extraction Date: 14-Jan-2013 Instru m en t ID: LC MS/MS A nalysis Date: 15-Jan-2013 Tim e: 02:46:05 C olum n ID: C18MS Extract V olum e (uL): 4000 Sam ple Data Filenam e: FC3G _015 S: 27 Injection V olum e (uL): 15 B lank Data Filenam e: FC3G_015 S: 22 D ilution Factor: N/A Cal. Ver. Data Filenam e: FC3G_015 S: 16 C oncentration Units: ng/L This page is part of a total report that contains information necessary for accreditation compliance. Results are compliant with NELAP accreditation described in the total report. Sample results relate only to the sample tested. COMPOUND LAB FLAG 1 CONC. FOUND REPO RTING LIM IT (RL)2 R E T E N T IO N TIM E PFBA PFPeA PFHxA PFHpA PFOA PFNA PFDA PFUnA PFDoA PFBS PFHxS PFOS PFOSA 6.18 1.21 (L) 3.81 1.21 (L) 1.62 1.21 (L) U 1.21 (L) 2.75 1.21 (L) U 1.21 (L) U 1.21 (L) U 1.21 (L) U 1.21 (L) 2.69 2.42 (L) U 2.42 (L) 7.66 2.42 (L) U 1.21 (L) 5:14 5:55 6:21 7:06 6:29 8:14 (1) Where applicable, custom lab flags have been used on this report; U = not detected at RL. (2) Reporting Limit (Code): S = sample detection limit; M = method detection limit; L = lowest calibration level equivalent; Q = contract defined limit. These data are validated and reported as accurate and in accord with AXYS Analytical Services Ltd. ISO17025 compliant quality assurance processes. Signed:____________ A ndrew P o r a t ____________ For Axys Internal Use Only [ XSL Template: FC-Form1A.xsl; Created: 16-Jan-2013 14:49:00; Application: XMLTransformer-1.13.28; ReportFilename: PFC_FC_LC_PFOA_L18989-5_Form1A_FC3G_015S27_SJ1552190.html; Workgroup: WG42428; Design ID: 1980 ] Page 52 of 307 Page 1 of 1 (WG42428 - PFC_FC_LC_PFOA_L18989-5_Form1A_FC3G_015S27_SJ1552190.html) www.axysanalytical.com A X Y S M ETH O D M LA -060 R ev 10 Form 2 PE R FLU O R IN A TED O R G A N IC S A N A LYS IS REPO RT A XYS A N A LYTIC A L SERVICES 2045 MILLS RD., SIDNEY, B.C., CANADA V8L 5X2 TEL (250) 655-5800 FAX (250) 655-5811 Project No. C o ntract No.: 4731 Lab S am ple I.D.: C LIEN T SAM PLE NO. DAL-SW -RO6L2-DUPA-121120 Sam ple C ollection: 20-Nov-2012 16:30 FALL 2012 TENNESSEE RIVER SAMPLING L18989-5 R M atrix : AQUEOUS Sam ple Size: 0.413 L Sam ple Receipt Date: 14-Dec-2012 Initial C alibration Date: 10-Jan-2013 Extraction Date: 14-Jan-2013 Instru m en t ID: LC MS/MS A nalysis Date: 15-Jan-2013 Tim e: 02:46:05 C olum n ID: C18MS Extract V olum e (uL): 4000 Sam ple Data Filenam e: FC3G _015 S: 27 Injection V olum e (uL): 15 B lan k Data Filenam e: FC3G_015 S: 22 D ilution Factor: N/A Cal. Ver. Data Filenam e: FC3G_015 S: 16 C oncentration Units: ng absolute This page is part of a total report that contains information necessary for accreditation compliance. Results are compliant with NELAP accreditation described in the total report. Sample results relate only to the sample tested. LABELED COMPOUND LAB FLAG 1 S P IK E CONC. CONC. FOUND R(%) 2 R E T E N T IO N TIM E 1 3 C 4 -P F B A 1 3 C 2 -P F H x A 13C2-PFO A 1 3 C 5 -P F N A 1 3 C 2 -P F D A 1 3 C 2 -P F D o A 1 3 C 4-P F O S 18 O 2-P F H x S 12.0 12.0 36.0 12.0 12.0 12.0 18.0 18.0 9.84 9.98 32.9 12.2 11.1 9.90 17.7 19.1 82.0 83.1 91.3 102 92.4 82.5 98.1 106 5:11 6:20 7:06 7:29 7:59 9:11 8:17 7:17 (1) Where applicable, custom lab flags have been used on this report. (2) R(%) = percent recovery. These data are validated and reported as accurate and in accord with AXYS Analytical Services Ltd. ISO17025 compliant quality assurance processes. Signed:____________ A ndrew P o r a t ____________ For Axys Internal Use Only [ XSL Template: FC-Form2.xsl; Created: 16-Jan-2013 14:49:00; Application: XMLTransformer-1.13.28; ReportFilename: PFC_FC_LC_PFOA_L18989-5_Form2_FC3G_015S27_SJ1552190.html; Workgroup: WG42428; Design ID: 1980 ] Page 53 of 307 Page 1 of 1 (WG42428 - PFC_FC_LC_PFOA_L18989-5_Form2_FC3G_015S27_SJ1552190.html) www.axysanalytical.com A X Y S M ETH O D M LA -060 R ev 10 Form 1A PE R FLU O R IN A TED O R G A N IC S A N A LYS IS REPO RT A XYS A N A LYTIC A L SERVICES 2045 MILLS RD., SIDNEY, B.C., CANADA V8L 5X2 TEL (250) 655-5800 FAX (250) 655-5811 Project No. C o ntract No.: 4731 Lab S am ple I.D.: C LIEN T SAM PLE NO. DAL-SW -T101-DUPA-121203 Sam ple C ollection: 03-D ec-2012 08:40 FALL 2012 TENNESSEE RIVER SAMPLING L18989-6 R M atrix : AQUEOUS Sam ple Size: 0.497 L Sam ple Receipt Date: 14-Dec-2012 Initial C alibration Date: 10-Jan-2013 Extraction Date: 14-Jan-2013 Instru m en t ID: LC MS/MS A nalysis Date: 15-Jan-2013 Tim e: 03:03:06 C olum n ID: C18MS Extract V olum e (uL): 4000 Sam ple Data Filenam e: FC3G _015 S: 28 Injection V olum e (uL): 15 B lank Data Filenam e: FC3G_015 S: 22 D ilution Factor: N/A Cal. Ver. Data Filenam e: FC3G_015 S: 16 C oncentration Units: ng/L This page is part of a total report that contains information necessary for accreditation compliance. Results are compliant with NELAP accreditation described in the total report. Sample results relate only to the sample tested. COMPOUND LAB FLAG 1 CONC. FOUND REPO RTING LIM IT (RL)2 R E T E N T IO N TIM E PFBA PFPeA PFHxA PFHpA PFOA PFNA PFDA PFUnA PFDoA PFBS PFHxS PFOS PFOSA 5.42 1.01 (L) 1.51 1.01 (L) 1.69 1.01 (L) 1.16 1.01 (L) 2.54 1.01 (L) U 1.01 (L) U 1.01 (L) U 1.01 (L) U 1.01 (L) U 2.01 (L) U 2.01 (L) 5.26 2.01 (L) U 1.01 (L) 5:11 5:57 6:21 6:41 7:06 8:17 (1) Where applicable, custom lab flags have been used on this report; U = not detected at RL. (2) Reporting Limit (Code): S = sample detection limit; M = method detection limit; L = lowest calibration level equivalent; Q = contract defined limit. These data are validated and reported as accurate and in accord with AXYS Analytical Services Ltd. ISO17025 compliant quality assurance processes. Signed:____________ A ndrew P o r a t ____________ For Axys Internal Use Only [ XSL Template: FC-Form1A.xsl; Created: 16-Jan-2013 14:49:00; Application: XMLTransformer-1.13.28; ReportFilename: PFC_FC_LC_PFOA_L 18989-6_Form1 A_FC3G_015S28_SJ1552191.html; Workgroup: W G42428;DesignID: 1980 ] Page 54 of 307 Page 1 of 1 (WG42428 -PFC_FC_LC_PFOA_L18989-6_Form1A_FC3G_015S28_SJ1552191.html) www.axysanalytical.com A X Y S M ETH O D M LA -060 R ev 10 Form 2 PE R FLU O R IN A TED O R G A N IC S A N A LYS IS REPO RT A XYS A N A LYTIC A L SERVICES 2045 MILLS RD., SIDNEY, B.C., CANADA V8L 5X2 TEL (250) 655-5800 FAX (250) 655-5811 Project No. C o ntract No.: 4731 Lab S am ple I.D.: C LIEN T SAM PLE NO. DAL-SW -T101-DUPA-121203 Sam ple C ollection: 03-D ec-2012 08:40 FALL 2012 TENNESSEE RIVER SAMPLING L18989-6 R M atrix : AQUEOUS Sam ple Size: 0.497 L Sam ple Receipt Date: 14-Dec-2012 Initial C alibration Date: 10-Jan-2013 Extraction Date: 14-Jan-2013 Instru m en t ID: LC MS/MS A nalysis Date: 15-Jan-2013 Tim e: 03:03:06 C olum n ID: C18MS Extract V olum e (uL): 4000 Sam ple Data Filenam e: FC3G _015 S: 28 Injection V olum e (uL): 15 B lan k Data Filenam e: FC3G_015 S: 22 D ilution Factor: N/A Cal. Ver. Data Filenam e: FC3G_015 S: 16 C oncentration Units: ng absolute This page is part of a total report that contains information necessary for accreditation compliance. Results are compliant with NELAP accreditation described in the total report. Sample results relate only to the sample tested. LABELED COMPOUND LAB FLAG 1 S P IK E CONC. CONC. FOUND R(%) 2 R E T E N T IO N TIM E 1 3 C 4 -P F B A 1 3 C 2 -P F H x A 13C2-PFO A 1 3 C 5 -P F N A 1 3 C 2 -P F D A 1 3 C 2 -P F D o A 1 3 C 4-P F O S 18 O 2-P F H x S 12.0 12.0 36.0 12.0 12.0 12.0 18.0 18.0 9.18 9.42 33.4 12.8 11.3 10.0 17.9 17.7 76.5 78.5 92.7 106 94.3 83.5 99.2 98.1 5:09 6:21 7:06 7:29 7:59 9:09 8:17 7:17 (1) Where applicable, custom lab flags have been used on this report. (2) R(%) = percent recovery. These data are validated and reported as accurate and in accord with AXYS Analytical Services Ltd. ISO17025 compliant quality assurance processes. Signed:____________ A ndrew P o r a t ____________ For Axys Internal Use Only [ XSL Template: FC-Form2.xsl; Created: 16-Jan-2013 14:49:00; Application: XMLTransformer-1.13.28; ReportFilename: PFC_FC_LC_PFOA_L18989-6_Form2_FC3G_015S28_SJ1552191.html; Workgroup: WG42428; Design ID: 1980 ] Page 55 of 307 Page 1 of 1 (WG42428 - PFC_FC_LC_PFOA_L18989-6_Form2_FC3G_015S28_SJ1552191.html) www.axysanalytical.com A X Y S M ETH O D M LA -060 R ev 10 Form 1A PE R FLU O R IN A TED O R G A N IC S A N A LYS IS REPO RT A XYS A N A LYTIC A L SERVICES 2045 MILLS RD., SIDNEY, B.C., CANADA V8L 5X2 TEL (250) 655-5800 FAX (250) 655-5811 Project No. C o ntract No.: 4731 Lab S am ple I.D.: C LIEN T SAM PLE NO. DAL-SW -T202-DUPA-121203 Sam ple C ollection: 03-D ec-2012 09:10 FALL 2012 TENNESSEE RIVER SAMPLING L18989-7 R M atrix : AQUEOUS Sam ple Size: 0.492 L Sam ple Receipt Date: 14-Dec-2012 Initial C alibration Date: 10-Jan-2013 Extraction Date: 14-Jan-2013 Instru m en t ID: LC MS/MS A nalysis Date: 15-Jan-2013 Tim e: 03:19:59 C olum n ID: C18MS Extract V olum e (uL): 4000 Sam ple Data Filenam e: FC3G _015 S: 29 Injection V olum e (uL): 15 B lank Data Filenam e: FC3G_015 S: 22 D ilution Factor: N/A Cal. Ver. Data Filenam e: FC3G_015 S: 16 C oncentration Units: ng/L This page is part of a total report that contains information necessary for accreditation compliance. Results are compliant with NELAP accreditation described in the total report. Sample results relate only to the sample tested. COMPOUND LAB FLAG 1 CONC. FOUND REPO RTING LIM IT (RL)2 R E T E N T IO N TIM E PFBA PFPeA PFHxA PFHpA PFOA PFNA PFDA PFUnA PFDoA PFBS PFHxS PFOS PFOSA 8.61 1.02 (L) 3.08 1.02 (L) 4.93 1.02 (L) 6.01 1.02 (L) 10.5 1.02 (L) U 1.02 (L) U 1.02 (L) U 1.02 (L) U 1.02 (L) 3.83 2.03 (L) U 2.03 (L) 8.44 2.03 (L) U 1.02 (L) 5:14 5:58 6:22 6:44 7:06 6:31 8:17 (1) Where applicable, custom lab flags have been used on this report; U = not detected at RL. (2) Reporting Limit (Code): S = sample detection limit; M = method detection limit; L = lowest calibration level equivalent; Q = contract defined limit. These data are validated and reported as accurate and in accord with AXYS Analytical Services Ltd. ISO17025 compliant quality assurance processes. Signed:____________ A ndrew P o r a t ____________ For Axys Internal Use Only [ XSL Template: FC-Form1A.xsl; Created: 16-Jan-2013 14:49:00; Application: XMLTransformer-1.13.28; ReportFilename: PFC_FC_LC_PFOA_L18989-7_Form1A_FC3G_015S29_SJ1552192.html; Workgroup: WG42428; Design ID: 1980 ] Page 56 of 307 Page 1 of 1 (WG42428 -PFC_FC_LC_PFOA_L18989-7_Form1A_FC3G_015S29_SJ1552192.html) www.axysanalytical.com A X Y S M ETH O D M LA -060 R ev 10 Form 2 PE R FLU O R IN A TED O R G A N IC S A N A LYS IS REPO RT A XYS A N A LYTIC A L SERVICES 2045 MILLS RD., SIDNEY, B.C., CANADA V8L 5X2 TEL (250) 655-5800 FAX (250) 655-5811 Project No. C o ntract No.: 4731 Lab S am ple I.D.: C LIEN T SAM PLE NO. DAL-SW -T202-DUPA-121203 Sam ple C ollection: 03-D ec-2012 09:10 FALL 2012 TENNESSEE RIVER SAMPLING L18989-7 R M atrix : AQUEOUS Sam ple Size: 0.492 L Sam ple Receipt Date: 14-Dec-2012 Initial C alibration Date: 10-Jan-2013 Extraction Date: 14-Jan-2013 Instru m en t ID: LC MS/MS A nalysis Date: 15-Jan-2013 Tim e: 03:19:59 C olum n ID: C18MS Extract V olum e (uL): 4000 Sam ple Data Filenam e: FC3G _015 S: 29 Injection V olum e (uL): 15 B lan k Data Filenam e: FC3G_015 S: 22 D ilution Factor: N/A Cal. Ver. Data Filenam e: FC3G_015 S: 16 C oncentration Units: ng absolute This page is part of a total report that contains information necessary for accreditation compliance. Results are compliant with NELAP accreditation described in the total report. Sample results relate only to the sample tested. LABELED COMPOUND LAB FLAG 1 S P IK E CONC. CONC. FOUND R(%) 2 R E T E N T IO N TIM E 1 3 C 4 -P F B A 1 3 C 2 -P F H x A 13C2-PFO A 1 3 C 5 -P F N A 1 3 C 2 -P F D A 1 3 C 2 -P F D o A 1 3 C 4-P F O S 18 O 2-P F H x S 12.0 12.0 36.0 12.0 12.0 12.0 18.0 18.0 8.25 9.03 30.9 11.9 10.4 9.36 16.5 16.1 68.7 75.3 86.0 99.1 87.0 78.0 91.7 89.5 5:11 6:21 7:06 7:29 7:59 9:09 8:21 7:20 (1) Where applicable, custom lab flags have been used on this report. (2) R(%) = percent recovery. These data are validated and reported as accurate and in accord with AXYS Analytical Services Ltd. ISO17025 compliant quality assurance processes. Signed:____________ A ndrew P o r a t ____________ For Axys Internal Use Only [ XSL Template: FC-Form2.xsl; Created: 16-Jan-2013 14:49:00; Application: XMLTransformer-1.13.28; ReportFilename: PFC_FC_LC_PFOA_L18989-7_Form2_FC3G_015S29_SJ1552192.html; Workgroup: WG42428; Design ID: 1980 ] Page 57 of 307 Page 1 of 1 (WG42428 - PFC_FC_LC_PFOA_L18989-7_Form2_FC3G_015S29_SJ1552192.html) www.axysanalytical.com A X Y S M ETH O D M LA -060 R ev 10 Form 1A PE R FLU O R IN A TED O R G A N IC S A N A LYS IS REPO RT A XYS A N A LYTIC A L SERVICES 2045 MILLS RD., SIDNEY, B.C., CANADA V8L 5X2 TEL (250) 655-5800 FAX (250) 655-5811 Project No. C o ntract No.: 4731 Lab S am ple I.D.: C LIEN T SAM PLE NO. DAL-SW -T303-DUPA-121203 Sam ple C ollection: 03-D ec-2012 11:50 FALL 2012 TENNESSEE RIVER SAMPLING L18989-8 R M atrix : AQUEOUS Sam ple Size: 0.483 L Sam ple Receipt Date: 14-Dec-2012 Initial C alibration Date: 10-Jan-2013 Extraction Date: 14-Jan-2013 Instru m en t ID: LC MS/MS A nalysis Date: 15-Jan-2013 Tim e: 03:37:00 C olum n ID: C18MS Extract V olum e (uL): 4000 Sam ple Data Filenam e: FC3G _015 S: 30 Injection V olum e (uL): 15 B lank Data Filenam e: FC3G_015 S: 22 D ilution Factor: N/A Cal. Ver. Data Filenam e: FC3G_015 S: 16 C oncentration Units: ng/L This page is part of a total report that contains information necessary for accreditation compliance. Results are compliant with NELAP accreditation described in the total report. Sample results relate only to the sample tested. COMPOUND LAB FLAG 1 CONC. FOUND REPO RTING LIM IT (RL)2 R E T E N T IO N TIM E PFBA PFPeA PFHxA PFHpA PFOA PFNA PFDA PFUnA PFDoA PFBS PFHxS PFOS PFOSA 5.91 1.04 (L) 1.87 1.04 (L) 1.67 1.04 (L) 1.15 1.04 (L) 3.07 1.04 (L) U 1.04 (L) U 1.04 (L) U 1.04 (L) U 1.04 (L) U 2.07 (L) U 2.07 (L) 6.68 2.07 (L) U 1.04 (L) 5:14 5:55 6:21 6:44 7:06 8:14 (1) Where applicable, custom lab flags have been used on this report; U = not detected at RL. (2) Reporting Limit (Code): S = sample detection limit; M = method detection limit; L = lowest calibration level equivalent; Q = contract defined limit. These data are validated and reported as accurate and in accord with AXYS Analytical Services Ltd. ISO17025 compliant quality assurance processes. Signed:____________ A ndrew P o r a t ____________ For Axys Internal Use Only [ XSL Template: FC-Form1A.xsl; Created: 16-Jan-2013 14:49:00; Application: XMLTransformer-1.13.28; ReportFilename: PFC_FC_LC_PFOA_L18989-8_Form1A_FC3G_015S30_SJ1552193.html; Workgroup: W G42428;DesignID: 1980 ] Page 58 of 307 Page 1 of 1 (WG42428 - PFC_FC_LC_PFOA_L18989-8_Form1A_FC3G_015S30_SJ1552193.html) www.axysanalytical.com A X Y S M ETH O D M LA -060 R ev 10 Form 2 PE R FLU O R IN A TED O R G A N IC S A N A LYS IS REPO RT A XYS A N A LYTIC A L SERVICES 2045 MILLS RD., SIDNEY, B.C., CANADA V8L 5X2 TEL (250) 655-5800 FAX (250) 655-5811 Project No. C o ntract No.: 4731 Lab S am ple I.D.: C LIEN T SAM PLE NO. DAL-SW -T303-DUPA-121203 Sam ple C ollection: 03-D ec-2012 11:50 FALL 2012 TENNESSEE RIVER SAMPLING L18989-8 R M atrix : AQUEOUS Sam ple Size: 0.483 L Sam ple Receipt Date: 14-Dec-2012 Initial C alibration Date: 10-Jan-2013 Extraction Date: 14-Jan-2013 Instru m en t ID: LC MS/MS A nalysis Date: 15-Jan-2013 Tim e: 03:37:00 C olum n ID: C18MS Extract V olum e (uL): 4000 Sam ple Data Filenam e: FC 3G _015 S: 30 Injection V olum e (uL): 15 B lan k Data Filenam e: FC3G_015 S: 22 D ilution Factor: N/A Cal. Ver. Data Filenam e: FC3G_015 S: 16 C oncentration Units: ng absolute This page is part of a total report that contains information necessary for accreditation compliance. Results are compliant with NELAP accreditation described in the total report. Sample results relate only to the sample tested. LABELED COMPOUND LAB FLAG 1 S P IK E CONC. CONC. FOUND R(%) 2 R E T E N T IO N TIM E 1 3 C 4 -P F B A 1 3 C 2 -P F H x A 13C2-PFO A 1 3 C 5 -P F N A 1 3 C 2 -P F D A 1 3 C 2 -P F D o A 1 3 C 4-P F O S 18 O 2-P F H x S 12.0 12.0 36.0 12.0 12.0 12.0 18.0 18.0 8.99 9.77 33.2 12.6 10.7 10.4 18.0 18.3 74.9 81.4 92.3 105 89.1 87.0 100 102 5:12 6:21 7:06 7:29 7:59 9:11 8:21 7:20 (1) Where applicable, custom lab flags have been used on this report. (2) R(%) = percent recovery. These data are validated and reported as accurate and in accord with AXYS Analytical Services Ltd. ISO17025 compliant quality assurance processes. Signed:____________ A ndrew P o r a t ____________ For Axys Internal Use Only [ XSL Template: FC-Form2.xsl; Created: 16-Jan-2013 14:49:00; Application: XMLTransformer-1.13.28; ReportFilename: PFC_FC_LC_PFOA_L18989-8_Form2_FC3G_015S30_SJ1552193.html; Workgroup: WG42428; Design ID: 1980 ] Page 59 of 307 Page 1 of 1 (WG42428 - PFC_FC_LC_PFOA_L18989-8_Form2_FC3G_015S30_SJ1552193.html) www.axysanalytical.com A X Y S M ETH O D M LA -060 R ev 10 Form 1A PE R FLU O R IN A TED O R G A N IC S A N A LYS IS REPO RT A XYS A N A LYTIC A L SERVICES 2045 MILLS RD., SIDNEY, B.C., CANADA V8L 5X2 TEL (250) 655-5800 FAX (250) 655-5811 Project No. C o ntract No.: 4731 Lab S am ple I.D.: C LIEN T SAM PLE NO. DAL-SW -T404-DUPA-121203 Sam ple C ollection: 03-D ec-2012 14:50 FALL 2012 TENNESSEE RIVER SAMPLING L18989-9 R M atrix : AQUEOUS Sam ple Size: 0.422 L Sam ple Receipt Date: 14-Dec-2012 Initial C alibration Date: 10-Jan-2013 Extraction Date: 14-Jan-2013 Instru m en t ID: LC MS/MS A nalysis Date: 15-Jan-2013 T im e: 03:54:01 C olum n ID: C18MS Extract V olum e (uL): 4000 Sam ple Data Filenam e: F C 3 G _ 0 1 5 S: 31 Injection V olum e (uL): 15 B lank Data Filenam e: FC3G_015 S: 22 D ilution Factor: N/A Cal. Ver. Data Filenam e: FC3G_015 S: 16 C oncentration Units: ng/L This page is part of a total report that contains information necessary for accreditation compliance. Results are compliant with NELAP accreditation described in the total report. Sample results relate only to the sample tested. COMPOUND LAB FLAG 1 CONC. FOUND REPO RTING LIM IT (RL)2 R E T E N T IO N TIM E PFBA PFPeA PFHxA PFHpA PFOA PFNA PFDA PFUnA PFDoA PFBS PFHxS PFOS PFOSA 6.09 1.18 (L) 1.21 1.18 (L) 1.58 1.18 (L) 1.28 1.18 (L) 2.53 1.18 (L) U 1.18 (L) U 1.18 (L) U 1.18 (L) U 1.18 (L) U 2.37 (L) U 2.37 (L) 6.30 2.37 (L) U 1.18 (L) 5:11 5:57 6:20 6:41 7:06 8:14 (1) Where applicable, custom lab flags have been used on this report; U = not detected at RL. (2) Reporting Limit (Code): S = sample detection limit; M = method detection limit; L = lowest calibration level equivalent; Q = contract defined limit. These data are validated and reported as accurate and in accord with AXYS Analytical Services Ltd. ISO17025 compliant quality assurance processes. Signed:____________ A ndrew P o r a t ____________ For Axys Internal Use Only [ XSL Template: FC-Form1A.xsl; Created: 16-Jan-2013 14:49:00; Application: XMLTransformer-1.13.28; ReportFilename: PFC_FC_LC_PFOA_L 18989-9_Form1 A_FC3G_015S31_SJ1552194.html; Workgroup: W G42428;DesignID: 1980 ] Page 60 of 307 Page 1 of 1 (WG42428 -PFC_FC_LC_PFOA_L18989-9_Form1A_FC3G_015S31_SJ1552194.html) www.axysanalytical.com A X Y S M ETH O D M LA -060 R ev 10 Form 2 PE R FLU O R IN A TED O R G A N IC S A N A LYS IS REPO RT A XYS A N A LYTIC A L SERVICES 2045 MILLS RD., SIDNEY, B.C., CANADA V8L 5X2 TEL (250) 655-5800 FAX (250) 655-5811 Project No. C o ntract No.: 4731 Lab S am ple I.D.: C LIEN T SAM PLE NO. DAL-SW -T404-DUPA-121203 Sam ple C ollection: 03-D ec-2012 14:50 FALL 2012 TENNESSEE RIVER SAMPLING L18989-9 R M atrix : AQUEOUS Sam ple Size: 0.422 L Sam ple Receipt Date: 14-Dec-2012 Initial C alibration Date: 10-Jan-2013 Extraction Date: 14-Jan-2013 Instru m en t ID: LC MS/MS A nalysis Date: 15-Jan-2013 T im e: 03:54:01 C olum n ID: C18MS Extract V olum e (uL): 4000 Sam ple Data Filenam e: F C 3 G _ 0 1 5 S: 31 Injection V olum e (uL): 15 B lan k Data Filenam e: FC3G_015 S: 22 D ilution Factor: N/A Cal. Ver. Data Filenam e: FC3G_015 S: 16 C oncentration Units: ng absolute This page is part of a total report that contains information necessary for accreditation compliance. Results are compliant with NELAP accreditation described in the total report. Sample results relate only to the sample tested. LABELED COMPOUND LAB FLAG 1 S P IK E CONC. CONC. FOUND R(%) 2 R E T E N T IO N TIM E 1 3 C 4 -P F B A 1 3 C 2 -P F H x A 13C2-PFO A 1 3 C 5 -P F N A 1 3 C 2 -P F D A 1 3 C 2 -P F D o A 1 3 C 4-P F O S 18 O 2-P F H x S 12.0 12.0 36.0 12.0 12.0 12.0 18.0 18.0 8.56 9.47 35.5 12.0 10.1 9.58 16.7 16.6 71.3 78.9 98.7 100 84.1 79.8 93.0 92.1 5:11 6:20 7:06 7:29 7:59 9:09 8:17 7:17 (1) Where applicable, custom lab flags have been used on this report. (2) R(%) = percent recovery. These data are validated and reported as accurate and in accord with AXYS Analytical Services Ltd. ISO17025 compliant quality assurance processes. Signed:____________ A ndrew P o r a t ____________ For Axys Internal Use Only [ XSL Template: FC-Form2.xsl; Created: 16-Jan-2013 14:49:00; Application: XMLTransformer-1.13.28; ReportFilename: PFC_FC_LC_PFOA_L18989-9_Form2_FC3G_015S31_SJ1552194.html; Workgroup: WG42428; Design ID: 1980 ] Page 61 of 307 Page 1 of 1 (WG42428 - PFC_FC_LC_PFOA_L18989-9_Form2_FC3G_015S31_SJ1552194.html) www.axysanalytical.com A X Y S M ETH O D M LA -060 R ev 10 Form 1A PE R FLU O R IN A TED O R G A N IC S A N A LYS IS REPO RT A XYS A N A LYTIC A L SERVICES 2045 MILLS RD., SIDNEY, B.C., CANADA V8L 5X2 TEL (250) 655-5800 FAX (250) 655-5811 Project No. C o ntract No.: 4731 Lab S am ple I.D.: C LIEN T SAM PLE NO. D AL-SW -T505-DUPA-121204 Sam ple C ollection: 04-D ec-2012 11:22 FALL 2012 TENNESSEE RIVER SAMPLING L18989-10 R M atrix : AQUEOUS Sam ple Size: 0.449 L Sam ple Receipt Date: 14-Dec-2012 Initial C alibration Date: 10-Jan-2013 Extraction Date: 14-Jan-2013 Instru m en t ID: LC MS/MS A nalysis Date: 15-Jan-2013 Tim e: 04:10:54 C olum n ID: C18MS Extract V olum e (uL): 4000 Sam ple Data Filenam e: FC3G _015 S: 32 Injection V olum e (uL): 15 B lank Data Filenam e: FC3G_015 S: 22 D ilution Factor: N/A Cal. Ver. Data Filenam e: FC3G_015 S: 16 C oncentration Units: ng/L This page is part of a total report that contains information necessary for accreditation compliance. Results are compliant with NELAP accreditation described in the total report. Sample results relate only to the sample tested. COMPOUND LAB FLAG 1 CONC. FOUND REPO RTING LIM IT (RL)2 R E T E N T IO N TIM E PFBA PFPeA PFHxA PFHpA PFOA PFNA PFDA PFUnA PFDoA PFBS PFHxS PFOS PFOSA 6.14 1.11 (L) U 1.11 (L) 1.56 1.11 (L) 1.29 1.11 (L) 2.65 1.11 (L) U 1.11 (L) U 1.11 (L) U 1.11 (L) U 1.11 (L) U 2.23 (L) U 2.23 (L) 5.10 2.23 (L) U 1.11 (L) 5:16 6:22 6:44 7:06 8:07 (1) Where applicable, custom lab flags have been used on this report; U = not detected at RL. (2) Reporting Limit (Code): S = sample detection limit; M = method detection limit; L = lowest calibration level equivalent; Q = contract defined limit. These data are validated and reported as accurate and in accord with AXYS Analytical Services Ltd. ISO17025 compliant quality assurance processes. Signed:____________ A ndrew P o r a t ____________ For Axys Internal Use Only [ XSL Template: FC-Form1A.xsl; Created: 16-Jan-2013 14:49:00; Application: XMLTransformer-1.13.28; ReportFilename: PFC_FC_LC_PFOA_L18989-10_Form1A_FC3G_015S32_SJ1552195.html; Workgroup: WG42428; Design ID: 1980 ] Page 62 of 307 Page 1 of 1 (WG42428 - PFC_FC_LC_PFOA_L18989-10_Form1A_FC3G_015S32_SJ1552195.html) www.axysanalytical.com A X Y S M ETH O D M LA -060 R ev 10 Form 2 PE R FLU O R IN A TED O R G A N IC S A N A LYS IS REPO RT A XYS A N A LYTIC A L SERVICES 2045 MILLS RD., SIDNEY, B.C., CANADA V8L 5X2 TEL (250) 655-5800 FAX (250) 655-5811 Project No. C o ntract No.: 4731 Lab S am ple I.D.: C LIEN T SAM PLE NO. D AL-SW -T505-DUPA-121204 Sam ple C ollection: 04-D ec-2012 11:22 FALL 2012 TENNESSEE RIVER SAMPLING L18989-10 R M atrix : AQUEOUS Sam ple Size: 0.449 L Sam ple Receipt Date: 14-Dec-2012 Initial C alibration Date: 10-Jan-2013 Extraction Date: 14-Jan-2013 Instru m en t ID: LC MS/MS A nalysis Date: 15-Jan-2013 Tim e: 04:10:54 C olum n ID: C18MS Extract V olum e (uL): 4000 Sam ple Data Filenam e: FC3G _015 S: 32 Injection V olum e (uL): 15 B lan k Data Filenam e: FC3G_015 S: 22 D ilution Factor: N/A Cal. Ver. Data Filenam e: FC3G_015 S: 16 C oncentration Units: ng absolute This page is part of a total report that contains information necessary for accreditation compliance. Results are compliant with NELAP accreditation described in the total report. Sample results relate only to the sample tested. LABELED COMPOUND LAB FLAG 1 S P IK E CONC. CONC. FOUND R(%) 2 R E T E N T IO N TIM E 1 3 C 4 -P F B A 1 3 C 2 -P F H x A 13C2-PFO A 1 3 C 5 -P F N A 1 3 C 2 -P F D A 1 3 C 2 -P F D o A 1 3 C 4-P F O S 18 O 2-P F H x S 12.0 12.0 36.0 12.0 12.0 12.0 18.0 18.0 8.86 10.0 34.3 12.2 10.5 10.4 16.2 17.6 73.9 83.4 95.3 101 87.2 86.6 90.1 97.7 5:15 6:22 7:09 7:29 7:59 9:07 8:17 7:20 (1) Where applicable, custom lab flags have been used on this report. (2) R(%) = percent recovery. These data are validated and reported as accurate and in accord with AXYS Analytical Services Ltd. ISO17025 compliant quality assurance processes. Signed:____________ A ndrew P o r a t ____________ For Axys Internal Use Only [ XSL Template: FC-Form2.xsl; Created: 16-Jan-2013 14:49:00; Application: XMLTransformer-1.13.28; ReportFilename: PFC_FC_LC_PFOA_L18989-10_Form2_FC3G_015S32_SJ1552195.html; Workgroup: WG42428; Design ID: 1980 ] Page 63 of 307 Page 1 of 1 (WG42428 - PFC_FC_LC_PFOA_L18989-10_Form2_FC3G_015S32_SJ1552195.html) www.axysanalytical.com A X Y S M ETH O D M LA -060 R ev 10 Form 1A PE R FLU O R IN A TED O R G A N IC S A N A LYS IS REPO RT A XYS A N A LYTIC A L SERVICES 2045 MILLS RD., SIDNEY, B.C., CANADA V8L 5X2 TEL (250) 655-5800 FAX (250) 655-5811 Project No. C o ntract No.: 4731 Lab S am ple I.D.: C LIEN T SAM PLE NO. D AL-SW -T606-DUPA-121204 Sam ple C ollection: 04-D ec-2012 12:55 FALL 2012 TENNESSEE RIVER SAMPLING L18989-11 (A) M atrix : AQUEOUS Sam ple Size: 0.498 L Sam ple Receipt Date: 14-Dec-2012 Initial C alibration Date: 13-Dec-2012 Extraction Date: 18-Dec-2012 Instru m en t ID: LC MS/MS A nalysis Date: 18-Dec-2012 Tim e: 23:49:24 C olum n ID: C18MS Extract V olum e (uL): 4000 Sam ple Data Filenam e: F C 2 G _ 4 5 5 S: 21 Injection V olum e (uL): 15 B lank Data Filenam e: FC2G_455 S: 10 D ilution Factor: N/A Cal. Ver. Data Filenam e: FC2G_455 S: 4 C oncentration Units: ng/L This page is part of a total report that contains information necessary for accreditation compliance. Results are compliant with NELAP accreditation described in the total report. Sample results relate only to the sample tested. COMPOUND LAB FLAG 1 CONC. FOUND REPO RTING LIM IT (RL)2 R E T E N T IO N TIM E PFBA PFPeA PFHxA PFHpA PFOA PFNA PFDA PFUnA PFDoA PFBS PFHxS PFOS PFOSA 6.01 1.00 (L) 1.59 1.00 (L) 2.09 1.00 (L) B 2.11 1.00 (L) 3.62 1.00 (L) U 1.00 (L) U 1.00 (L) U 1.00 (L) U 1.00 (L) 2.14 2.01 (L) U 2.01 (L) 7.45 2.01 (L) U 1.00 (L) 5:09 5:59 6:21 6:42 7:04 6:30 8:03 (1) Where applicable, custom lab flags have been used on this report; U = not detected at RL; B = analyte found in sample and the associated blank. (2) Reporting Limit (Code): S = sample detection limit; M = method detection limit; L = lowest calibration level equivalent; Q = contract defined limit. These data are validated and reported as accurate and in accord with AXYS Analytical Services Ltd. ISO17025 compliant quality assurance processes. Signed:____________ A ndrew P o r a t ____________ For Axys Internal Use Only [ XSL Template: FC-Form1A.xsl; Created: 16-Jan-2013 15:20:40; Application: XMLTransformer-1.13.28; ReportFilename: PFC_FC_LC_PFOA_L18989-11_Form1A_FC2G_455S21_SJ1549333.html; Workgroup: WG42273; Design ID: 1980 ] Page 64 of 307 Page 1 of 1 (WG42273 -PFC_FC_LC_PFOA_L18989-11_Form1A_FC2G_455S21_SJ1549333.html) www.axysanalytical.com A X Y S M ETH O D M LA -060 R ev 10 Form 2 PE R FLU O R IN A TED O R G A N IC S A N A LYS IS REPO RT A XYS A N A LYTIC A L SERVICES 2045 MILLS RD., SIDNEY, B.C., CANADA V8L 5X2 TEL (250) 655-5800 FAX (250) 655-5811 Project No. C o ntract No.: 4731 Lab S am ple I.D.: C LIEN T SAM PLE NO. D AL-SW -T606-DUPA-121204 Sam ple C ollection: 04-D ec-2012 12:55 FALL 2012 TENNESSEE RIVER SAMPLING L18989-11 (A) M atrix : AQUEOUS Sam ple Size: 0.498 L Sam ple Receipt Date: 14-Dec-2012 Initial C alibration Date: 13-Dec-2012 Extraction Date: 18-Dec-2012 Instru m en t ID: LC MS/MS A nalysis Date: 18-Dec-2012 Tim e: 23:49:24 C olum n ID: C18MS Extract V olum e (uL): 4000 Sam ple Data Filenam e: F C 2 G _ 4 5 5 S: 21 Injection V olum e (uL): 15 B lan k Data Filenam e: FC2G_455 S: 10 D ilution Factor: N/A Cal. Ver. Data Filenam e: FC2G_455 S: 4 C oncentration Units: ng absolute This page is part of a total report that contains information necessary for accreditation compliance. Results are compliant with NELAP accreditation described in the total report. Sample results relate only to the sample tested. LABELED COMPOUND LAB FLAG 1 S P IK E CONC. CONC. FOUND R(%) 2 R E T E N T IO N TIM E 1 3 C 4 -P F B A 1 3 C 2 -P F H x A 13C2-PFO A 1 3 C 5 -P F N A 1 3 C 2 -P F D A 1 3 C 2 -P F D o A 1 3 C 4-P F O S 18 O 2-P F H x S 12.0 12.0 36.0 12.0 12.0 12.0 18.0 18.0 8.35 8.01 31.1 11.0 9.95 9.40 15.8 15.6 69.6 66.8 86.5 91.8 82.9 78.3 87.9 86.7 5:08 6:21 7:06 7:28 7:56 9:02 8:14 7:18 (1) Where applicable, custom lab flags have been used on this report. (2) R(%) = percent recovery. These data are validated and reported as accurate and in accord with AXYS Analytical Services Ltd. ISO17025 compliant quality assurance processes. Signed:____________ A ndrew P o r a t ____________ For Axys Internal Use Only [ XSL Template: FC-Form2.xsl; Created: 16-Jan-2013 15:20:40; Application: XMLTransformer-1.13.28; ReportFilename: PFC_FC_LC_PFOA_L18989-11_Form2_FC2G_455S21_SJ1549333.html; Workgroup: WG42273; Design ID: 1980 ] Page 65 of 307 Page 1 of 1 (WG42273 -PFC_FC_LC_PFOA_L18989-11_Form2_FC2G_455S21_SJ1549333.html) www.axysanalytical.com A X Y S M ETH O D M LA -060 R ev 10 Form 1A PE R FLU O R IN A TED O R G A N IC S A N A LYS IS REPO RT A XYS A N A LYTIC A L SERVICES 2045 MILLS RD., SIDNEY, B.C., CANADA V8L 5X2 TEL (250) 655-5800 FAX (250) 655-5811 C o ntract No.: 4731 Project No. Lab S am ple I.D.: C LIEN T SAM PLE NO. D AL-SW -T606-DUPA-121204 (D u p lic a te ) Sam ple C ollection: 04-D ec-2012 12:55 FALL 2012 TENNESSEE RIVER SAMPLING WG42273-103 (DUP L18989-11) M atrix : AQUEOUS Sam ple Size: 0.498 L Sam ple Receipt Date: 14-Dec-2012 Initial C alibration Date: 13-Dec-2012 Extraction Date: 18-Dec-2012 Instru m en t ID: LC MS/MS A nalysis Date: 19-Dec-2012 Tim e: 00:07:06 C olum n ID: C18MS Extract V olum e (uL): 4000 Sam ple Data Filenam e: FC2G _455 S: 22 Injection V olum e (uL): 15 B lank Data Filenam e: FC2G_455 S: 10 D ilution Factor: N/A Cal. Ver. Data Filenam e: FC2G_455 S: 4 C oncentration Units: ng/L This page is part of a total report that contains information necessary for accreditation compliance. Results are compliant with NELAP accreditation described in the total report. Sample results relate only to the sample tested. COMPOUND LAB FLAG 1 CONC. FOUND REPO RTING LIM IT (RL)2 R E T E N T IO N TIM E PFBA PFPeA PFHxA PFHpA PFOA PFNA PFDA PFUnA PFDoA PFBS PFHxS PFOS PFOSA 5.71 1.00 (L) 1.98 1.00 (L) 2.24 1.00 (L) B 1.88 1.00 (L) 3.77 1.00 (L) U 1.00 (L) U 1.00 (L) U 1.00 (L) U 1.00 (L) U 2.01 (L) U 2.01 (L) 8.62 2.01 (L) U 1.00 (L) 5:08 5:57 6:20 6:42 7:04 8:00 (1) Where applicable, custom lab flags have been used on this report; U = not detected at RL; B = analyte found in sample and the associated blank. (2) Reporting Limit (Code): S = sample detection limit; M = method detection limit; L = lowest calibration level equivalent; Q = contract defined limit. These data are validated and reported as accurate and in accord with AXYS Analytical Services Ltd. ISO17025 compliant quality assurance processes. Signed:____________ A ndrew P o r a t ____________ For Axys Internal Use Only [ XSL Template: FC-Form1A.xsl; Created: 16-Jan-2013 15:20:40; Application: XMLTransformer-1.13.28; ReportFilename: PFC_FC_LC_PFOA_WG42273-103_Form1A_FC2G_455S22_SJ1549334.html; Workgroup: WG42273; Design ID: 1980 ] PPaaggee 66 of 307 Page 1 of 1 (WG42273 -PFC_FC_LC_PFOA_WG42273-103_Form1A_FC2G_455S22_SJ1549334.html) www.axysanalytical.com A X Y S M ETH O D M LA -060 R ev 10 Form 2 PE R FLU O R IN A TED O R G A N IC S A N A LYS IS REPO RT A XYS A N A LYTIC A L SERVICES 2045 MILLS RD., SIDNEY, B.C., CANADA V8L 5X2 TEL (250) 655-5800 FAX (250) 655-5811 C o ntract No.: 4731 Project No. Lab S am ple I.D.: C LIEN T SAM PLE NO. D AL-SW -T606-DUPA-121204 (D u p lic a te ) Sam ple C ollection: 04-D ec-2012 12:55 FALL 2012 TENNESSEE RIVER SAMPLING WG42273-103 (DUP L18989-11) M atrix : AQUEOUS Sam ple Size: 0.498 L Sam ple Receipt Date: 14-Dec-2012 Initial C alibration Date: 13-Dec-2012 Extraction Date: 18-Dec-2012 Instru m en t ID: LC MS/MS A nalysis Date: 19-Dec-2012 Tim e: 00:07:06 C olum n ID: C18MS Extract V olum e (uL): 4000 Sam ple Data Filenam e: FC2G _455 S: 22 Injection V olum e (uL): 15 Blank Data Filenam e: FC2G_455 S: 10 D ilution Factor: N/A Cal. Ver. Data Filenam e: FC2G_455 S: 4 C oncentration Units: ng absolute This page is part of a total report that contains information necessary for accreditation compliance. Results are compliant with NELAP accreditation described in the total report. Sample results relate only to the sample tested. LABELED COMPOUND LAB FLAG1 S P IK E CONC. CONC. FOUND R(%) 2 R E T E N T IO N TIM E 1 3 C 4 -P F B A 1 3 C 2 -P F H x A 13C2-PFO A 1 3 C 5 -P F N A 1 3 C 2 -P F D A 1 3 C 2 -P F D o A 1 3 C 4-P F O S 18 O 2-P F H x S 12.0 12.0 36.0 12.0 12.0 12.0 18.0 18.0 8.67 8.70 34.1 12.2 11.3 11.0 16.1 16.9 72.3 72.5 94.7 102 94.2 91.5 89.2 94.1 5:09 6:20 7:04 7:28 7:56 9:02 8:10 7:15 (1) Where applicable, custom lab flags have been used on this report. (2) R(%) = percent recovery. These data are validated and reported as accurate and in accord with AXYS Analytical Services Ltd. ISO17025 compliant quality assurance processes. Signed:____________ A ndrew P o r a t ____________ For Axys Internal Use Only [ XSL Template: FC-Form2.xsl; Created: 16-Jan-2013 15:20:40; Application: XMLTransformer-1.13.28; ReportFilename: PFC_FC_LC_PFOA_WG42273-103_Form2_FC2G_455S22_SJ1549334.html; Workgroup: WG42273; Design ID: 1980 ] Page 67 of 307 Page 1 of 1 (WG42273 -PFC_FC_LC_PFOA_WG42273-103_Form2_FC2G_455S22_SJ1549334.html) www.axysanalytical.com A X Y S M ETH O D M LA -060 R ev 10 PE R FLU O R IN A TED O R G A N IC S A N A LYSIS REPO R T RELATIVE PE RCENT DIFFERENCE A XYS A N A LYTIC A L SERVICES 2045 MILLS RD., SIDNEY, B.C., CANADA V8L 5X2 TEL (250) 655-5800 FAX (250) 655-5811 Project No. C ontract No.: 4731 C lient ID: D A L -S W -T 606-D U P A -12 1 204 C oncentration Units: FALL 2012 TENNESSEE RIVER SAMPLING ng/L COMPOUND PFBA PFPeA PFHxA PFHpA PFOA PFNA PFDA PFUnA PFDoA PFBS PFHxS PFOS PFOSA L18989-11 (A) LAB FLAG 1 CONC. FOUND 6.01 1.59 2.09 2.11 3.62 U U U U 2.14 U 7.45 U W G42273-103 LAB FLAG 1 CONC. FOUND 5.71 1.98 2.24 1.88 3.77 U U U U U U 8.62 U MEAN 5.86 1.79 2.17 1.99 3.70 R E L A T IV E PERCENT DIFFER ENCE 5.11 21.9 6.48 11.4 4.12 8.03 14.7 (1) Where applicable, custom lab flags have been used on this report; U = not detected at RL. These data are validated and reported as accurate and in accord with AXYS Analytical Services Ltd. ISO17025 compliant quality assurance processes. Signed:____________ A ndrew P o r a t ____________ These pages are part of a larger report that may contain information necessary for full data evaluation. Results reported relate only to the sample tested. For Axys Internal Use Only [ XSL Template: RPD.xsl; Created: 16-Jan-2013 15:20:57; Application: XMLTransformer-1.13.28; ReportFilename: RPD_FC_LC_PFOA-RPD_WG42273-103_L18989-11_.html; Workgroup: WG42273; Design ID: 1980 ] Page 1 of 1 (WG42273 - RPD_FC_LC_PFOA-RPD_WG42273-103_L18989-11_.html) Page 68 of 307 www.axysanalytical.com A X Y S M ETH O D M LA -060 R ev 10 Form 1A PE R FLU O R IN A TED O R G A N IC S A N A LYS IS REPO RT A XYS A N A LYTIC A L SERVICES 2045 MILLS RD., SIDNEY, B.C., CANADA V8L 5X2 TEL (250) 655-5800 FAX (250) 655-5811 Project No. C o ntract No.: 4731 Lab S am ple I.D.: C LIEN T SAM PLE NO. D AL-SW -T707-DUPA-121204 Sam ple C ollection: 04-D ec-2012 15:10 FALL 2012 TENNESSEE RIVER SAMPLING L18989-12 R M atrix : AQUEOUS Sam ple Size: 0.458 L Sam ple Receipt Date: 14-Dec-2012 Initial C alibration Date: 10-Jan-2013 Extraction Date: 14-Jan-2013 Instru m en t ID: LC MS/MS A nalysis Date: 15-Jan-2013 Tim e: 04:27:55 C olum n ID: C18MS Extract V olum e (uL): 4000 Sam ple Data Filenam e: FC3G _015 S: 33 Injection V olum e (uL): 15 B lank Data Filenam e: FC3G_015 S: 22 D ilution Factor: N/A Cal. Ver. Data Filenam e: FC3G_015 S: 16 C oncentration Units: ng/L This page is part of a total report that contains information necessary for accreditation compliance. Results are compliant with NELAP accreditation described in the total report. Sample results relate only to the sample tested. COMPOUND LAB FLAG 1 CONC. FOUND REPO RTING LIM IT (RL)2 R E T E N T IO N TIM E PFBA PFPeA PFHxA PFHpA PFOA PFNA PFDA PFUnA PFDoA PFBS PFHxS PFOS PFOSA 9.21 1.09 (L) 3.68 1.09 (L) 4.65 1.09 (L) 3.93 1.09 (L) 9.73 1.09 (L) U 1.09 (L) U 1.09 (L) U 1.09 (L) U 1.09 (L) 15.0 2.18 (L) U 2.18 (L) 17.3 2.18 (L) U 1.09 (L) 5:12 5:57 6:21 6:44 7:06 6:29 8:17 (1) Where applicable, custom lab flags have been used on this report; U = not detected at RL. (2) Reporting Limit (Code): S = sample detection limit; M = method detection limit; L = lowest calibration level equivalent; Q = contract defined limit. These data are validated and reported as accurate and in accord with AXYS Analytical Services Ltd. ISO17025 compliant quality assurance processes. Signed:____________ A ndrew P o r a t ____________ For Axys Internal Use Only [ XSL Template: FC-Form1A.xsl; Created: 16-Jan-2013 14:49:00; Application: XMLTransformer-1.13.28; ReportFilename: PFC_FC_LC_PFOA_L18989-12_Form1A_FC3G_015S33_SJ1552196.html; Workgroup: WG42428; Design ID: 1980 ] Page 69 of 307 Page 1 of 1 (WG42428 - PFC_FC_LC_PFOA_L18989-12_Form1A_FC3G_015S33_SJ1552196.html) www.axysanalytical.com A X Y S M ETH O D M LA -060 R ev 10 Form 2 PE R FLU O R IN A TED O R G A N IC S A N A LYS IS REPO RT A XYS A N A LYTIC A L SERVICES 2045 MILLS RD., SIDNEY, B.C., CANADA V8L 5X2 TEL (250) 655-5800 FAX (250) 655-5811 Project No. C o ntract No.: 4731 Lab S am ple I.D.: C LIEN T SAM PLE NO. D AL-SW -T707-DUPA-121204 Sam ple C ollection: 04-D ec-2012 15:10 FALL 2012 TENNESSEE RIVER SAMPLING L18989-12 R M atrix : AQUEOUS Sam ple Size: 0.458 L Sam ple Receipt Date: 14-Dec-2012 Initial C alibration Date: 10-Jan-2013 Extraction Date: 14-Jan-2013 Instru m en t ID: LC MS/MS A nalysis Date: 15-Jan-2013 Tim e: 04:27:55 C olum n ID: C18MS Extract V olum e (uL): 4000 Sam ple Data Filenam e: FC3G _015 S: 33 Injection V olum e (uL): 15 B lan k Data Filenam e: FC3G_015 S: 22 D ilution Factor: N/A Cal. Ver. Data Filenam e: FC3G_015 S: 16 C oncentration Units: ng absolute This page is part of a total report that contains information necessary for accreditation compliance. Results are compliant with NELAP accreditation described in the total report. Sample results relate only to the sample tested. LABELED COMPOUND LAB FLAG 1 S P IK E CONC. CONC. FOUND R(%) 2 R E T E N T IO N TIM E 1 3 C 4 -P F B A 1 3 C 2 -P F H x A 13C2-PFO A 1 3 C 5 -P F N A 1 3 C 2 -P F D A 1 3 C 2 -P F D o A 1 3 C 4-P F O S 18 O 2-P F H x S 12.0 12.0 36.0 12.0 12.0 12.0 18.0 18.0 9.26 9.68 35.1 13.0 11.3 11.3 17.7 20.0 77.1 80.6 97.5 109 94.2 94.0 98.3 111 5:12 6:21 7:06 7:29 7:59 9:11 8:21 7:20 (1) Where applicable, custom lab flags have been used on this report. (2) R(%) = percent recovery. These data are validated and reported as accurate and in accord with AXYS Analytical Services Ltd. ISO17025 compliant quality assurance processes. Signed:____________ A ndrew P o r a t ____________ For Axys Internal Use Only [ XSL Template: FC-Form2.xsl; Created: 16-Jan-2013 14:49:00; Application: XMLTransformer-1.13.28; ReportFilename: PFC_FC_LC_PFOA_L18989-12_Form2_FC3G_015S33_SJ1552196.html; Workgroup: WG42428; Design ID: 1980 ] Page 70 of 307 Page 1 of 1 (WG42428 - PFC_FC_LC_PFOA_L18989-12_Form2_FC3G_015S33_SJ1552196.html) www.axysanalytical.com A X Y S M ETH O D M LA -060 R ev 10 Form 1A PE R FLU O R IN A TED O R G A N IC S A N A LYS IS REPO RT A XYS A N A LYTIC A L SERVICES 2045 MILLS RD., SIDNEY, B.C., CANADA V8L 5X2 TEL (250) 655-5800 FAX (250) 655-5811 Project No. C o ntract No.: 4731 Lab S am ple I.D.: C LIEN T SAM PLE NO. DAL-SW -T808-DUPA-121205 Sam ple C ollection: 05-D ec-2012 10:10 FALL 2012 TENNESSEE RIVER SAMPLING L18989-13 R M atrix : AQUEOUS Sam ple Size: 0.477 L Sam ple Receipt Date: 14-Dec-2012 Initial C alibration Date: 10-Jan-2013 Extraction Date: 14-Jan-2013 Instru m en t ID: LC MS/MS A nalysis Date: 15-Jan-2013 Tim e: 04:44:56 C olum n ID: C18MS Extract V olum e (uL): 4000 Sam ple Data Filenam e: FC3G_015 S: 34 Injection V olum e (uL): 15 B lank Data Filenam e: FC3G_015 S: 22 D ilution Factor: N/A Cal. Ver. Data Filenam e: FC3G_015 S: 16 C oncentration Units: ng/L This page is part of a total report that contains information necessary for accreditation compliance. Results are compliant with NELAP accreditation described in the total report. Sample results relate only to the sample tested. COMPOUND LAB FLAG 1 CONC. FOUND REPO RTING LIM IT (RL)2 R E T E N T IO N TIM E PFBA PFPeA PFHxA PFHpA PFOA PFNA PFDA PFUnA PFDoA PFBS PFHxS PFOS PFOSA 8.89 1.05 (L) 2.59 1.05 (L) 3.61 1.05 (L) 3.11 1.05 (L) 7.56 1.05 (L) U 1.05 (L) U 1.05 (L) U 1.05 (L) U 1.05 (L) 11.4 2.10 (L) U 2.10 (L) 12.8 2.10 (L) U 1.05 (L) 5:12 5:57 6:20 6:41 7:03 6:29 8:10 (1) Where applicable, custom lab flags have been used on this report; U = not detected at RL. (2) Reporting Limit (Code): S = sample detection limit; M = method detection limit; L = lowest calibration level equivalent; Q = contract defined limit. These data are validated and reported as accurate and in accord with AXYS Analytical Services Ltd. ISO17025 compliant quality assurance processes. Signed:____________ A ndrew P o r a t ____________ For Axys Internal Use Only [ XSL Template: FC-Form1A.xsl; Created: 16-Jan-2013 14:49:00; Application: XMLTransformer-1.13.28; ReportFilename: PFC_FC_LC_PFOA_L18989-13_Form1A_FC3G_015S34_SJ1552197.html; Workgroup: WG42428; Design ID: 1980 ] Page 71 of 307 Page 1 of 1 (WG42428 -PFC_FC_LC_PFOA_L18989-13_Form1A_FC3G_015S34_SJ1552197.html) www.axysanalytical.com A X Y S M ETH O D M LA -060 R ev 10 Form 2 PE R FLU O R IN A TED O R G A N IC S A N A LYS IS REPO RT A XYS A N A LYTIC A L SERVICES 2045 MILLS RD., SIDNEY, B.C., CANADA V8L 5X2 TEL (250) 655-5800 FAX (250) 655-5811 Project No. C o ntract No.: 4731 Lab S am ple I.D.: C LIEN T SAM PLE NO. DAL-SW -T808-DUPA-121205 Sam ple C ollection: 05-D ec-2012 10:10 FALL 2012 TENNESSEE RIVER SAMPLING L18989-13 R M atrix : AQUEOUS Sam ple Size: 0.477 L Sam ple Receipt Date: 14-Dec-2012 Initial C alibration Date: 10-Jan-2013 Extraction Date: 14-Jan-2013 Instru m en t ID: LC MS/MS A nalysis Date: 15-Jan-2013 Tim e: 04:44:56 C olum n ID: C18MS Extract V olum e (uL): 4000 Sam ple Data Filenam e: FC3G_015 S: 34 Injection V olum e (uL): 15 B lan k Data Filenam e: FC3G_015 S: 22 D ilution Factor: N/A Cal. Ver. Data Filenam e: FC3G_015 S: 16 C oncentration Units: ng absolute This page is part of a total report that contains information necessary for accreditation compliance. Results are compliant with NELAP accreditation described in the total report. Sample results relate only to the sample tested. LABELED COMPOUND LAB FLAG 1 S P IK E CONC. CONC. FOUND R(%) 2 R E T E N T IO N TIM E 1 3 C 4 -P F B A 1 3 C 2 -P F H x A 13C2-PFO A 1 3 C 5 -P F N A 1 3 C 2 -P F D A 1 3 C 2 -P F D o A 1 3 C 4-P F O S 18 O 2-P F H x S 12.0 12.0 36.0 12.0 12.0 12.0 18.0 18.0 7.90 8.98 34.0 12.0 10.8 9.52 17.4 17.6 65.9 74.9 94.5 99.8 89.8 79.4 96.6 97.7 5:11 6:18 7:06 7:28 7:59 9:07 8:17 7:17 (1) Where applicable, custom lab flags have been used on this report. (2) R(%) = percent recovery. These data are validated and reported as accurate and in accord with AXYS Analytical Services Ltd. ISO17025 compliant quality assurance processes. Signed:____________ A ndrew P o r a t ____________ For Axys Internal Use Only [ XSL Template: FC-Form2.xsl; Created: 16-Jan-2013 14:49:00; Application: XMLTransformer-1.13.28; ReportFilename: PFC_FC_LC_PFOA_L18989-13_Form2_FC3G_015S34_SJ1552197.html; Workgroup: WG42428; Design ID: 1980 ] Page 72 of 307 Page 1 of 1 (WG42428 - PFC_FC_LC_PFOA_L18989-13_Form2_FC3G_015S34_SJ1552197.html) www.axysanalytical.com A X Y S M ETH O D M LA -060 R ev 10 Form 1A PE R FLU O R IN A TED O R G A N IC S A N A LYS IS REPO RT A XYS A N A LYTIC A L SERVICES 2045 MILLS RD., SIDNEY, B.C., CANADA V8L 5X2 TEL (250) 655-5800 FAX (250) 655-5811 Project No. C o ntract No.: 4731 Lab S am ple I.D.: C LIEN T SAM PLE NO. DAL-SW -T909-DUPA-121205 Sam ple C ollection: 05-D ec-2012 12:45 FALL 2012 TENNESSEE RIVER SAMPLING L18989-14 R M atrix : AQUEOUS Sam ple Size: 0.430 L Sam ple Receipt Date: 14-Dec-2012 Initial C alibration Date: 10-Jan-2013 Extraction Date: 14-Jan-2013 Instru m en t ID: LC MS/MS A nalysis Date: 15-Jan-2013 Tim e: 05:01:49 C olum n ID: C18MS Extract V olum e (uL): 4000 Sam ple Data Filenam e: FC3G _015 S: 35 Injection V olum e (uL): 15 B lank Data Filenam e: FC3G_015 S: 22 D ilution Factor: N/A Cal. Ver. Data Filenam e: FC3G_015 S: 16 C oncentration Units: ng/L This page is part of a total report that contains information necessary for accreditation compliance. Results are compliant with NELAP accreditation described in the total report. Sample results relate only to the sample tested. COMPOUND LAB FLAG 1 CONC. FOUND REPO RTING LIM IT (RL)2 R E T E N T IO N TIM E PFBA PFPeA PFHxA PFHpA PFOA PFNA PFDA PFUnA PFDoA PFBS PFHxS PFOS PFOSA 8.91 1.16 (L) 2.72 1.16 (L) 5.42 1.16 (L) 3.73 1.16 (L) 9.60 1.16 (L) U 1.16 (L) U 1.16 (L) U 1.16 (L) U 1.16 (L) 12.6 2.32 (L) U 2.32 (L) 17.7 2.32 (L) U 1.16 (L) 5:12 5:57 6:22 6:44 7:06 6:29 8:10 (1) Where applicable, custom lab flags have been used on this report; U = not detected at RL. (2) Reporting Limit (Code): S = sample detection limit; M = method detection limit; L = lowest calibration level equivalent; Q = contract defined limit. These data are validated and reported as accurate and in accord with AXYS Analytical Services Ltd. ISO17025 compliant quality assurance processes. Signed:____________ A ndrew P o r a t ____________ For Axys Internal Use Only [ XSL Template: FC-Form1A.xsl; Created: 16-Jan-2013 14:49:00; Application: XMLTransformer-1.13.28; ReportFilename: PFC_FC_LC_PFOA_L18989-14_Form1A_FC3G_015S35_SJ1552198.html; Workgroup: WG42428; Design ID: 1980 ] Page 73 of 307 Page 1 of 1 (WG42428 - PFC_FC_LC_PFOA_L18989-14_Form1A_FC3G_015S35_SJ1552198.html) www.axysanalytical.com A X Y S M ETH O D M LA -060 R ev 10 Form 2 PE R FLU O R IN A TED O R G A N IC S A N A LYS IS REPO RT A XYS A N A LYTIC A L SERVICES 2045 MILLS RD., SIDNEY, B.C., CANADA V8L 5X2 TEL (250) 655-5800 FAX (250) 655-5811 Project No. C o ntract No.: 4731 Lab S am ple I.D.: C LIEN T SAM PLE NO. DAL-SW -T909-DUPA-121205 Sam ple C ollection: 05-D ec-2012 12:45 FALL 2012 TENNESSEE RIVER SAMPLING L18989-14 R M atrix : AQUEOUS Sam ple Size: 0.430 L Sam ple Receipt Date: 14-Dec-2012 Initial C alibration Date: 10-Jan-2013 Extraction Date: 14-Jan-2013 Instru m en t ID: LC MS/MS A nalysis Date: 15-Jan-2013 Tim e: 05:01:49 C olum n ID: C18MS Extract V olum e (uL): 4000 Sam ple Data Filenam e: FC3G _015 S: 35 Injection V olum e (uL): 15 B lan k Data Filenam e: FC3G_015 S: 22 D ilution Factor: N/A Cal. Ver. Data Filenam e: FC3G_015 S: 16 C oncentration Units: ng absolute This page is part of a total report that contains information necessary for accreditation compliance. Results are compliant with NELAP accreditation described in the total report. Sample results relate only to the sample tested. LABELED COMPOUND LAB FLAG 1 S P IK E CONC. CONC. FOUND R(%) 2 R E T E N T IO N TIM E 1 3 C 4 -P F B A 1 3 C 2 -P F H x A 13C2-PFO A 1 3 C 5 -P F N A 1 3 C 2 -P F D A 1 3 C 2 -P F D o A 1 3 C 4-P F O S 18 O 2-P F H x S 12.0 12.0 36.0 12.0 12.0 12.0 18.0 18.0 9.25 9.37 36.2 12.9 10.0 10.1 17.1 17.2 77.1 78.1 101 107 83.6 83.9 95.0 95.8 5:12 6:22 7:06 7:28 7:56 9:02 8:14 7:17 (1) Where applicable, custom lab flags have been used on this report. (2) R(%) = percent recovery. These data are validated and reported as accurate and in accord with AXYS Analytical Services Ltd. ISO17025 compliant quality assurance processes. Signed:____________ A ndrew P o r a t ____________ For Axys Internal Use Only [ XSL Template: FC-Form2.xsl; Created: 16-Jan-2013 14:49:00; Application: XMLTransformer-1.13.28; ReportFilename: PFC_FC_LC_PFOA_L18989-14_Form2_FC3G_015S35_SJ1552198.html; Workgroup: WG42428; Design ID: 1980 ] Page 74 of 307 Page 1 of 1 (WG42428 - PFC_FC_LC_PFOA_L18989-14_Form2_FC3G_015S35_SJ1552198.html) www.axysanalytical.com A X Y S M ETH O D M LA -060 R ev 10 Form 1A PE R FLU O R IN A TED O R G A N IC S A N A LYS IS REPO RT A XYS A N A LYTIC A L SERVICES 2045 MILLS RD., SIDNEY, B.C., CANADA V8L 5X2 TEL (250) 655-5800 FAX (250) 655-5811 C o ntract No.: 4731 Project No. Lab S am ple I.D.: C LIEN T SAM PLE NO. Lab Blank Sam ple C ollection: N/A N/A WG42273-101 M atrix : AQUEOUS Sam ple Size: 0.500 L Sam ple Receipt Date: N/A Initial C alibration Date: 13-Dec-2012 Extraction Date: 18-Dec-2012 Instru m en t ID: LC MS/MS A nalysis Date: 18-Dec-2012 Tim e: 20:35:06 C olum n ID: C18MS Extract V olum e (uL): 4000 Sam ple Data Filenam e: F C 2 G _ 4 5 5 S: 10 Injection V olum e (uL): 15 B lan k Data Filenam e: FC2G_455 S: 10 D ilution Factor: N/A Cal. Ver. Data Filenam e: FC2G_455 S: 4 C oncentration Units: ng/L This page is part of a total report that contains information necessary for accreditation compliance. Results are compliant with NELAP accreditation described in the total report. Sample results relate only to the sample tested. COMPOUND LAB FLAG 1 CONC. FOUND REPO RTING LIM IT (RL)2 R E T E N T IO N TIM E PFBA PFPeA PFHxA PFHpA PFOA PFNA PFDA PFUnA PFDoA PFBS PFHxS PFOS PFOSA U 1.00 (L) U 1.00 (L) U 1.00 (L) B 1.48 1.00 (L) U 1.00 (L) U 1.00 (L) U 1.00 (L) U 1.00 (L) U 1.00 (L) U 2.00 (L) U 2.00 (L) U 2.00 (L) U 1.00 (L) 6:45 (1) Where applicable, custom lab flags have been used on this report; U = not detected at RL; B = analyte found in the blank. (2) Reporting Limit (Code): S = sample detection limit; M = method detection limit; L = lowest calibration level equivalent; Q = contract defined limit. These data are validated and reported as accurate and in accord with AXYS Analytical Services Ltd. ISO17025 compliant quality assurance processes. Signed:____________ A ndrew P o r a t ____________ For Axys Internal Use Only [ XSL Template: FC-Form1A.xsl; Created: 16-Jan-2013 15:20:40; Application: XMLTransformer-1.13.28; ReportFilename: PFC_FC_LC_PFOA_WG42273-101_Form1A_FC2G_455S10_SJ1549320.html; Workgroup: WG42273; Design ID: 1980 ] PPaaggee 75 of 307 Page 1 of 1 (WG42273 -PFC_FC_LC_PFOA_WG42273-101_Form1A_FC2G_455S10_SJ1549320.html) www.axysanalytical.com AXYS METHOD MLA-060 Rev 10 Form 2 PE R FLU O R IN A TED O R G A N IC S A N A LYS IS REPO R T A XYS A N A LYTIC A L SERVICES 2045 MILLS RD., SIDNEY, B.C., CANADA V8L 5X2 TEL (250) 655-5800 FAX (250) 655-5811 C o ntract No.: 4731 Project No. Lab S am ple I.D.: CLIENT SAMPLE NO. Lab Blank Sam ple C ollection: N/A N/A WG42273-101 M atrix : AQUEOUS Sam ple Size: 0.500 L Sam ple Receipt Date: N/A Initial C alibration Date: 13-Dec-2012 Extraction Date: 18-Dec-2012 Instru m en t ID: LC MS/MS A nalysis Date: 18-Dec-2012 Tim e: 20:35:06 C olum n ID: C18MS Extract V olum e (uL): 4000 Sam ple Data Filenam e: F C 2 G _ 4 5 5 S: 10 Injection V olum e (uL): 15 B lank Data Filenam e: FC2G _455 S: 10 D ilution Factor: N/A Cal. Ver. Data Filenam e: FC2G _455 S: 4 C oncentration Units: ng absolute This page is part of a total report that contains information necessary for accreditation compliance. Results are compliant with NELAP accreditation described in the total report. Sample results relate only to the sample tested. LABELED COMPOUND LAB FLAG 1 S P IK E CONC. CONC. FOUND R(%) 2 R E T E N T IO N TIM E 1 3 C 4 -P F B A 1 3 C 2 -P F H x A 13C2-PFO A 1 3 C 5 -P F N A 1 3 C 2 -P F D A 1 3 C 2 -P F D o A 1 3 C 4-P F O S 18 O 2-P F H x S 12.0 12.0 36.0 12.0 12.0 12.0 18.0 18.0 10.1 11.3 34.0 10.5 9.72 12.3 15.5 15.9 84.4 94.4 94.3 87.4 81.0 103 86.1 88.4 5:11 6:21 7:06 7:28 8:00 9:02 8:14 7:18 (1) Where applicable, custom lab flags have been used on this report. (2) R(%) = percent recovery. These data are validated and reported as accurate and in accord with AXYS Analytical Services Ltd. ISO17025 compliant quality assurance processes. Signed:____________ A ndrew P o r a t ____________ For Axys Internal Use Only [ XSL Template: FC-Form2.xsl; Created: 16-Jan-2013 15:20:40; Application: XMLTransformer-1.13.28; ReportFilename: PFC_FC_LC_PFOA_WG42273-101_Form2_FC2G_455S10_SJ1549320.html; Workgroup: WG42273; Design ID: 1980 ] Page 76 of 307 Page 1 of 1 (WG42273 - PFC_FC_LC_PFOA_WG42273-101_Form2_FC2G_455S10_SJ1549320.html) www.axysanalytical.com A X Y S M ETH O D M LA -060 R ev 10 Form 1A PE R FLU O R IN A TED O R G A N IC S A N A LYS IS REPO RT A XYS A N A LYTIC A L SERVICES 2045 MILLS RD., SIDNEY, B.C., CANADA V8L 5X2 TEL (250) 655-5800 FAX (250) 655-5811 C o ntract No.: 4731 Project No. Lab S am ple I.D.: C LIEN T SAM PLE NO. Lab Blank Sam ple C ollection: N/A N/A WG42428-101 M atrix : AQUEOUS Sam ple Size: 0.500 L Sam ple Receipt Date: N/A Initial C alibration Date: 10-Jan-2013 Extraction Date: 14-Jan-2013 Instru m en t ID: LC MS/MS A nalysis Date: 15-Jan-2013 Tim e: 01:21:16 C olum n ID: C18MS Extract V olum e (uL): 4000 Sam ple Data Filenam e: FC3G _015 S: 22 Injection V olum e (uL): 15 B lan k Data Filenam e: FC3G_015 S: 22 D ilution Factor: N/A Cal. Ver. Data Filenam e: FC3G_015 S: 16 C oncentration Units: ng/L This page is part of a total report that contains information necessary for accreditation compliance. Results are compliant with NELAP accreditation described in the total report. Sample results relate only to the sample tested. COMPOUND LAB FLAG 1 CONC. FOUND REPO RTING LIM IT (RL)2 R E T E N T IO N TIM E PFBA PFPeA PFHxA PFHpA PFOA PFNA PFDA PFUnA PFDoA PFBS PFHxS PFOS PFOSA U U U U U U U U U U U U U 1.00 (L) 1.00 (L) 1.00 (L) 1.00 (L) 1.00 (L) 1.00 (L) 1.00 (L) 1.00 (L) 1.00 (L) 2.00 (L) 2.00 (L) 2.00 (L) 1.00 (L) (1) Where applicable, custom lab flags have been used on this report; U = not detected at RL. (2) Reporting Limit (Code): S = sample detection limit; M = method detection limit; L = lowest calibration level equivalent; Q = contract defined limit. These data are validated and reported as accurate and in accord with AXYS Analytical Services Ltd. ISO17025 compliant quality assurance processes. Signed:____________ A ndrew P o r a t ____________ For Axys Internal Use Only [ XSL Template: FC-Form1A.xsl; Created: 16-Jan-2013 14:49:00; Application: XMLTransformer-1.13.28; ReportFilename: PFC_FC_LC_PFOA_WG42428-101_Form1A_FC3G_015S22_SJ1552184.html; Workgroup: WG42428; Design ID: 1980 ] PPaaggee 77 of 307 Page 1 of 1 (WG42428 -PFC_FC_LC_PFOA_WG42428-101_Form1A_FC3G_015S22_SJ1552184.html) www.axysanalytical.com AXYS METHOD MLA-060 Rev 10 Form 2 PE R FLU O R IN A TED O R G A N IC S A N A LYS IS REPO R T A XYS A N A LYTIC A L SERVICES 2045 MILLS RD., SIDNEY, B.C., CANADA V8L 5X2 TEL (250) 655-5800 FAX (250) 655-5811 C o ntract No.: 4731 Project No. Lab S am ple I.D.: CLIENT SAMPLE NO. Lab Blank Sam ple C ollection: N/A N/A WG42428-101 M atrix : AQUEOUS Sam ple Size: 0.500 L Sam ple Receipt Date: N/A Initial C alibration Date: 10-Jan-2013 Extraction Date: 14-Jan-2013 Instru m en t ID: LC MS/MS A nalysis Date: 15-Jan-2013 Tim e: 01:21:16 C olum n ID: C18MS Extract V olum e (uL): 4000 Sam ple Data Filenam e: FC 3G _015 S: 22 Injection V olum e (uL): 15 B lank Data Filenam e: FC3G _015 S: 22 D ilution Factor: N/A Cal. Ver. Data Filenam e: FC3G _015 S: 16 C oncentration Units: ng absolute This page is part of a total report that contains information necessary for accreditation compliance. Results are compliant with NELAP accreditation described in the total report. Sample results relate only to the sample tested. LABELED COMPOUND LAB FLAG 1 S P IK E CONC. CONC. FOUND R(%) 2 R E T E N T IO N TIM E 1 3 C 4 -P F B A 1 3 C 2 -P F H x A 13C2-PFO A 1 3 C 5 -P F N A 1 3 C 2 -P F D A 1 3 C 2 -P F D o A 1 3 C 4-P F O S 18 O 2-P F H x S 12.0 12.0 36.0 12.0 12.0 12.0 18.0 18.0 12.7 13.3 31.5 13.1 10.9 12.4 19.5 20.9 106 110 87.5 109 90.5 103 108 116 5:12 6:21 7:06 7:29 7:59 9:11 8:21 7:20 (1) Where applicable, custom lab flags have been used on this report. (2) R(%) = percent recovery. These data are validated and reported as accurate and in accord with AXYS Analytical Services Ltd. ISO17025 compliant quality assurance processes. Signed:____________ A ndrew P o r a t ____________ For Axys Internal Use Only [ XSL Template: FC-Form2.xsl; Created: 16-Jan-2013 14:49:00; Application: XMLTransformer-1.13.28; ReportFilename: PFC_FC_LC_PFOA_WG42428-101_Form2_FC3G_015S22_SJ1552184.html; Workgroup: WG42428; Design ID: 1980 ] Page 78 of 307 Page 1 of 1 (WG42428 - PFC_FC_LC_PFOA_WG42428-101_Form2_FC3G_015S22_SJ1552184.html) www.axysanalytical.com A X Y S M ETH O D M LA -060 R ev 10 Form 8A PERFLUO RINATED O RG ANICS O NG O ING PRECISIO N AND R EC O VERY (OPR) A XYS A N A LYTIC A L SERVICES 2045 MILLS RD., SIDNEY, B.C., CANADA V8L 5X2 TEL (250) 655-5800 FAX (250) 655-5811 C o ntract No.: 4731 Lab S am ple I.D.: W G 42273-102 M atrix : AQUEOUS Initial C alibration Date: 13-Dec-2012 Extraction Date: 18-Dec-2012 Instru m en t ID: LC MS/MS A nalysis Date: 18-Dec-2012 Tim e: 19:42:48 C olum n ID: C18MS Extract V olum e (uL): 4000 O P R D ata Filenam e: FC2G_455 S: 7 Injection V olum e (uL): 15 B lank Data Filenam e: FC2G _455 S: 10 D ilution Factor: N/A Cal. Ver. Data Filenam e: FC2G _455 S: 4 A L L C O N C E N T R A T IO N S R E P O R TE D O N TH IS FO R M A R E C O N C E N T R A T IO N S IN E X TR A C T , B A S E D O N A 1 m L E X T R A C T V O L U M E . COMPOUND LAB FLAG 1 SPIKE CONC. (ng/m L) CONC. FOUND (n g /m L ) % RECOVERY R E T E N T IO N TIM E PFBA PFPeA PFHxA PFHpA PFOA PFNA PFDA PFUnA PFDoA PFBS PFHxS PFOS PFOSA 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 40.0 40.0 40.0 20.0 19.0 17.7 20.0 19.0 19.5 19.8 22.8 20.9 20.2 43.3 40.1 38.8 22.5 95.0 88.7 100 95.2 97.4 99.0 114 105 101 108 100 97.0 112 5:06 5:57 6:20 6:42 7:06 7:28 7:56 8:30 9:04 6:27 7:18 8:14 9:54 (1) Where applicable, custom lab flags have been used on this report. These data are validated and reported as accurate and in accord with AXYS Analytical Services Ltd. ISO17025 compliant quality assurance processes. Signed:____________ A ndrew P o r a t ____________ These pages are part of a larger report that may contain information necessary for full data evaluation. Results reported relate only to the sample tested. For Axys Internal Use Only [ XSL Template: FC-Form8A.xsl; Created: 16-Jan-2013 15:20:40; Application: XMLTransformer-1.13.28; ReportFilename: PFC_FC_LC_PFOA_WG42273-102_Form8A_SJ1549315.html; Workgroup: WG42273; Design ID: 1980 ] Page 1 of 1 (WG42273 - PFC_FC_LC_PFOA_WG42273-102_Form8A_SJ1549315.html) Page 79 of 307 www.axysanalytical.com AXYS METHOD MLA-060 Rev 10 Form 8B PERFLUORINATED ORGANICS ONGOING PRECISION AND RECOVERY (OPR) A XYS A N A LYTIC A L SERVICES 2045 MILLS RD., SIDNEY, B.C., CANADA V8L 5X2 TEL (250) 655-5800 FAX (250) 655-5811 C ontract No.: 4731 Lab S am ple I.D.: W G 42273-102 M atrix : AQUEOUS Initial C alibration Date: 13-Dec-2012 Extraction Date: 18-Dec-2012 Instru m en t ID: LC MS/MS A nalysis Date: 18-Dec-2012 Tim e: 19:42:48 C olum n ID: C18MS Extract V olum e (uL): 4000 O P R D ata Filenam e: FC2G_455 S: 7 Injection V olum e (uL): 15 B lank Data Filenam e: FC2G _455 S: 10 D ilution Factor: N/A Cal. Ver. Data Filenam e: FC2G _455 S: 4 A L L C O N C E N T R A T IO N S R E P O R TE D O N TH IS FO R M A R E C O N C E N T R A T IO N S IN E X TR A C T , B A S E D O N A 1 m L E X T R A C T V O L U M E LABELED COMPOUND LAB FLAG1 SPIKE C O N C . (ng/m L) CONC. FOUND (ng/m L) % RECOVERY RETENTIO N TIM E 1 3 C 4 -P F B A 1 3 C 2 -P F H x A 13C2-PFO A 1 3 C 5 -P F N A 1 3 C 2 -P F D A 1 3 C 2 -P F D o A 1 3 C 4-P F O S 18 O 2-P F H x S 12.0 12.0 36.0 12.0 12.0 12.0 18.0 18.0 10.6 11.4 33.3 11.4 9.64 11.7 16.6 17.7 88.0 94.7 92.5 94.6 80.3 97.9 92.3 98.5 5:06 6:20 7:06 7:28 7:56 9:04 8:14 7:18 (1) Where applicable, custom lab flags have been used on this report. These data are validated and reported as accurate and in accord with AXYS Analytical Services Ltd. ISO17025 compliant quality assurance processes. Signed:____________ A ndrew P o r a t ____________ These pages are part of a larger report that may contain information necessary for full data evaluation. Results reported relate only to the sample tested. For Axys Internal Use Only [ XSL Template: FC-Form8B.xsl; Created: 16-Jan-2013 15:20:40; Application: XMLTransformer-1.13.28; ReportFilename: PFC_FC_LC_PFOA_WG42273-102_Form8B_SJ1549315.html; Workgroup: WG42273; Design ID: 1980 ] Page 1 of 1 (WG42273 - PFC_FC_LC_PFOA_WG42273-102_Form8B_SJ1549315.html) Page 80 of 307 www.axysanalytical.com A X Y S M ETH O D M LA -060 R ev 10 Form 8A PERFLUO RINATED O RG ANICS O NG O ING PRECISIO N AND R EC O VERY (OPR) A XYS A N A LYTIC A L SERVICES 2045 MILLS RD., SIDNEY, B.C., CANADA V8L 5X2 TEL (250) 655-5800 FAX (250) 655-5811 C o ntract No.: 4731 Lab S am ple I.D.: W G 42428-102 M atrix : AQUEOUS Initial C alibration Date: 10-Jan-2013 Extraction Date: 14-Jan-2013 Instru m en t ID: LC MS/MS A nalysis Date: 15-Jan-2013 T im e: 00:30:21 C olum n ID: C18MS Extract V olum e (uL): 4000 O P R D ata Filenam e: F C 3 G _ 0 1 5 S: 19 Injection V olum e (uL): 15 B lank Data Filenam e: FC3G _015 S: 22 D ilution Factor: N/A Cal. Ver. Data Filenam e: FC3G 015 S: 16 A L L C O N C E N T R A T IO N S R E P O R TE D O N TH IS FO R M A R E C O N C E N T R A T IO N S IN E X TR A C T , B A S E D O N A 1 m L E X T R A C T V O L U M E . COMPOUND LAB FLAG 1 SPIKE CONC. (ng/m L) CONC. FOUND (n g /m L ) % RECOVERY R E T E N T IO N TIM E PFBA PFPeA PFHxA PFHpA PFOA PFNA PFDA PFUnA PFDoA PFBS PFHxS PFOS PFOSA 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 40.0 40.0 40.0 20.0 19.2 19.2 22.3 21.1 23.7 21.8 22.3 23.1 22.5 44.4 43.1 46.8 23.7 96.2 96.0 111 106 119 109 112 115 113 111 108 117 119 5:11 5:56 6:20 6:44 7:06 7:29 7:59 8:35 9:11 6:29 7:20 8:21 9:59 (1) Where applicable, custom lab flags have been used on this report. These data are validated and reported as accurate and in accord with AXYS Analytical Services Ltd. ISO17025 compliant quality assurance processes. Signed:____________ A ndrew P o r a t ____________ These pages are part of a larger report that may contain information necessary for full data evaluation. Results reported relate only to the sample tested. For Axys Internal Use Only [ XSL Template: FC-Form8A.xsl; Created: 16-Jan-2013 14:49:00; Application: XMLTransformer-1.13.28; ReportFilename: PFC_FC_LC_PFOA_WG42428-102_Form8A_SJ1552180.html; Workgroup: WG42428; Design ID: 1980 ] Page 1 of 1 (WG42428 - PFC_FC_LC_PFOA_WG42428-102_Form8A_SJ1552180.html) Page 81 of 307 www.axysanalytical.com AXYS METHOD MLA-060 Rev 10 Form 8B PERFLUORINATED ORGANICS ONGOING PRECISION AND RECOVERY (OPR) A XYS A N A LYTIC A L SERVICES 2045 MILLS RD., SIDNEY, B.C., CANADA V8L 5X2 TEL (250) 655-5800 FAX (250) 655-5811 C ontract No.: 4731 Lab S am ple I.D.: W G 42428-102 M atrix : AQUEOUS Initial C alibration Date: 10-Jan-2013 Extraction Date: 14-Jan-2013 Instru m en t ID: LC MS/MS A nalysis Date: 15-Jan-2013 T im e: 00:30:21 C olum n ID: C18MS Extract V olum e (uL): 4000 O P R D ata Filenam e: F C 3 G _ 0 1 5 S: 19 Injection V olum e (uL): 15 B lank Data Filenam e: FC3G_015 S: 22 D ilution Factor: N/A Cal. Ver. Data Filenam e: FC3G 015 S: 16 A L L C O N C E N T R A T IO N S R E P O R TE D O N TH IS FO R M A R E C O N C E N T R A T IO N S IN E X TR A C T , B A S E D O N A 1 m L E X T R A C T V O L U M E LABELED COMPOUND LAB FLAG1 SPIKE C O N C . (ng/m L) CONC. FOUND (ng/m L) % RECOVERY RETENTIO N TIM E 1 3 C 4 -P F B A 1 3 C 2 -P F H x A 13C2-PFO A 1 3 C 5 -P F N A 1 3 C 2 -P F D A 1 3 C 2 -P F D o A 1 3 C 4-P F O S 18 O 2-P F H x S 12.0 12.0 36.0 12.0 12.0 12.0 18.0 18.0 12.3 11.8 30.1 11.6 10.1 11.7 16.6 19.1 102 98.7 83.6 96.3 84.0 97.3 92.2 106 5:12 6:20 7:06 7:29 7:59 9:11 8:21 7:20 (1) Where applicable, custom lab flags have been used on this report. These data are validated and reported as accurate and in accord with AXYS Analytical Services Ltd. ISO17025 compliant quality assurance processes. Signed:____________ Andr ew P o r a t ____________ These pages are part of a larger report that may contain information necessary for full data evaluation. Results reported relate only to the sample tested. For Axys Internal Use Only [ XSL Template: FC-Form8B.xsl; Created: 16-Jan-2013 14:49:00; Application: XMLTransformer-1.13.28; ReportFilename: PFC_FC_LC_PFOA_WG42428-102_Form8B_SJ1552180.html; Workgroup: WG42428; Design ID: 1980 ] Page 1 of 1 (WG42428 - PFC_FC_LC_PFOA_WG42428-102_Form8B_SJ1552180.html) Page 82 of 307 www.axysanalytical.com _______________________ p fc - f% . Sam ple List Report M assLynx4.1 SCN627 Sample List: G:\MassIynx\lnst_G\_Master.PRO\SampleDB\FC2G_445.SPL Last Modified: Thursday, December 13, 2012 11:30:57 Pacific Standard Time Printed: Thursday, December 13, 2012 14:52:46 Pacific Standard Time Page 1 of 1 Page Position (1,1) File Name Sample ID File Text Bottle Signln SignOut Inj VoL 1 FC2G 445S001 MeOH,, 2 FC2G 445S002 MeOH,, 3 FC2G 445S003 FC-LIN-42221W500-A,, 4 FC2G 445S004 FC-Li N-42221W500-A,, 5 FC2G 445S005 FC-L1N-42221W500-B,, 6 FC2G 445S006 FC-LIN-42221W5Q0-C,, 7 FC2G 445S007 FC-LiN-42221 W500-D,, 8 FC2G 445S008 FC-LIN-42221W500-E,, 9 FC2G 445S009 FC-LIN-42221W50Q-F,, 10 FC2G 445S010 FC-LIN-42221 W500-G,, 11 FC2G 445S011 FC-LIN-42221 W500-H,, 12 FC2G 445S012 MeOH,, 13 FC2G 445S013 MeOH,, 14 FC2G 445S014 FC-42221W500-SAR2,, 15 FC2G 445S015 FC-42221W500-SAR,, 16 FC2G 445S016 FC-LIN-42221W500-D,, 17 FC2G 445S017 FC-LIN-42221W500-D,, 18 FC2G 445S018 WG42214-103,,SAR 19 FC2G 445S019 WG42214-102,,SPM 20 FC2G 445S020 MeOH,, 21 FC2G 445S021 MeOH,, 22 FC2G 445S022 WG42214-101,,BLK 23 FC2G 445S023 L18938-1 ,, 24 FC2G 445S024 L18938-2,, 25 FC2G 445S025 L18938-3,, 26 FC2G 445S026 L18955-1,, 27 FC2G 445S027 L18955-2,, 28 FC2G 445S028 L18955-3,, 29 FC2G 445S029 L18955-4,, 30 FC2G 445S030 L18955-5,, 31 FC2G 445S031 L18955-6,, 32 FC2G 445S032 L18955-7,, - 33 FC2G 445S033 L18970-1,, 34 FC2G 445S034 L18970-2,, 35 FC2G 445S035 L18970-3,, 36 FC2G 445S036 L18970-4,, 37 FC2G 445S037 FC-LIN-42221W500-D,, 38 FC2G 445S038 FC-LIN-42221W500-D,, 39 FC2G 445S039 MeOH,, 40 FC2G 445S040 MeOH,, 1,,15uL 1,,15uL 1,,15uL 1,,15uL 1,,15uL . 1,,15uL 1,, 15u L 1,,15uL 1,,15uL 1,,15uL ' 1,,15uL 1,,15uL 1,,15uL 1,,15uL 1,,15uL 1,,15uL 1,,15uL 1,WG42214,15/4000uL 1,WG42214,15/4000uL 1,,15uL 1,,15uL 1.WG42214,15/4000uL 1,WG42214,15/4000uL 1,WG42214,15/4000uL 1,WG42214,15/4000uL 1,WG42214,15/4000uL 1.WG42214,15/4000uL 1,WG42214,15/4000uL 1,WG42214,15/4000uL 1,WG42214,15/4000uL 1,WG42214,15/4000uL 1,WG42214,15/4000uL 1,WG42214,15/4000uL 1,WG42214,15/4000uL 1,WG42214,15/4000uL 1,WG42214,15/4000uL 1,,15uL 1,,15uL 1,,15uL 1,,15uL 1:8,A 1:8,A 1:1,A 1:1,A 1:1,B 1:1,C 1:1,D 1:1,E 1:1,F 1:2,A 1:2,B 1:8,A 1:8,A 1:2,C 1:2,D 1:1,D 1:1,D 1:2,E 1:2,F 1:8,A 1:8,A 1:6,E 1:6,F 1:7,A 1:7,B 1:7,0 1:7,D 1:7,E 1:7,F 1:8,B 1:8, C 1:8,D 1:8,E 1:8,F 1:4,E 1:4,F 1:1,D 1:1,D 1:8,A 1:8,A -- -- - - -- -- -- --- -- -- -- -- - -- -- - " -- -" -~ - -" - - -- - i f ' ---fTi1. - -4_ 4- -j -T - -T- - -77 - -- ir- ----- ' - -1 4 4 4 4 4 - - 7j i j j M -q \- - \ - - -4 - v - -- / / -V 15,0 15,0 15.0 15.0 - 15.0 15,0 15.0 Al 15.0 15.0 15.0 15.0 15.0 15.0 15.0 15.0 15.0 15.0 15.0 15.0 15.0 15.0 15.0 15.0 15.0 15.0 15.0 15.0 15.0 15.0 15.0 15.0 15.0 15.0 15.0 15.0 15.0 15.0 15` 15.0 15.0 Page 83 of 307 www.axysanalytical.com AXYS METHOD MLA-060 Rev 10 Form 3A PERFLUORINATED ORGANICS INITIAL CALIBRATION PERCENT RECOVERIES AXYS ANA LYTIC A L SERVICES 2045 MILLS RD., SIDNEY, B.C., CANADA V8L 5X2 TEL (250) 655-5800 FAX (250) 655-5811 Initial C alibration Date: 13-Dec-2012 CS0 D ata Filenam e: CS1 D ata Filenam e: FC2G_445 S: 4 FC2G_445 S: 5 In stru m en t ID: LC MS/MS CS2 D ata Filenam e: FC2G_445 S: 6 LC C o lum n ID: C18MS CS3 D ata Filenam e: FC2G_445 S: 7 CS4 D ata Filenam e: FC2G_445 S: 8 CS5 D ata Filenam e: FC2G_445 S: 9 CS6 D ata Filenam e: FC2G_445 S: 10 CS7 D ata Filenam e: FC2G_445 S: 11 CS8 D ata Filenam e: N/A COMPOUND PFBA PFPeA PFHxA PFHpA PFOA PFNA PFDA PFUnA PFDoA PFBS PFHxS PFOS PFOSA LAB FLAG1 CS0 113 122 111 120 113 114 85.2 106 92.6 103 102 111 123 CS1 110 102 103 96.3 94.3 90.9 110 104 107 104 117 104 107 CS2 90.2 87.5 90.4 90.0 94.1 96.6 97.9 95.4 96.2 87.8 84.2 88.6 79.5 PER C EN T R EC O V ER Y (%) CS3 CS4 CS5 88.3 90.1 94.8 90.4 95.8 95.3 104 91.6 102 96.2 89.7 92.5 91.3 99.5 95.3 98.3 99.9 104 103 101 97.7 100 111 105 102 96.0 96.1 102 104 106 99.6 101 107 111 104 103 105 103 104 CS6 103 101 98.5 97.6 99.4 99.1 94.9 94.4 96.8 95.6 96.6 98.1 99.6 CS7 99.6 99.8 100 100 100 100 101 101 102 101 100 100 CS8 (1) Where applicable, custom lab flags have been used on this report. These data are validated and reported as accurate and in accord with AXYS Analytical Services Ltd. ISO17025 compliant quality assurance processes. Signed:____________ Andr ew P o r a t ____________ For Axys Internal Use Only [ XSL Template: FC-Form3A.xsl; Created: 16-Jan-2013 15:20:40; Application: XMLTransformer-1.13.28; ReportFilename: PFOA_FC_LC_13-Dec-2012_FC2G__Form3A_GS48529.html; Workgroup: WG42273; Design ID: 1980 ] Page 1 of 1 (WG42273 - PFOA_FC_LC_13-Dec-2012_FC2G__Form3A_GS48529.html) Page 84 of 307 www.axysanalytical.com AXYS METHOD MLA-060 Rev 10 Form 3B PERFLUORINATED ORGANICS INITIAL CALIBRATION PERCENT RECOVERIES AXYS ANA LYTIC A L SERVICES 2045 MILLS RD., SIDNEY, B.C., CANADA V8L 5X2 TEL (250) 655-5800 FAX (250) 655-5811 Initial C alibration Date: 13-Dec-2012 CS0 D ata Filenam e: CS1 D ata Filenam e: FC2G_445 S: 4 FC2G_445 S: 5 In stru m en t ID: LC MS/MS CS2 D ata Filenam e: FC2G_445 S: 6 LC C o lum n ID: C18MS CS3 D ata Filenam e: FC2G_445 S: 7 CS4 D ata Filenam e: FC2G_445 S: 8 CS5 D ata Filenam e: FC2G_445 S: 9 CS6 D ata Filenam e: FC2G_445 S: 10 CS7 D ata Filenam e: FC2G_445 S: 11 CS8 D ata Filenam e: N/A LABELED COMPOUND 1 3 C 4 -P F B A 1 3 C 2 -P F H x A 13C2-PFO A 1 3 C 5 -P F N A 1 3 C 2 -P F D A 1 3 C 2 -P F D o A 1 3 C 4-P F O S 1 8 O 2-P F H xS LAB FLAG1 CS0 101 107 94.6 98.9 94.3 84.4 98.5 105 CS1 98.8 109 98.1 116 97.9 86.4 112 104 CS2 PER C EN T REC O VER IES (%) CS3 CS4 CS5 CS6 98.3 100 103 104 100 102 99.4 104 92.8 95.2 94.6 95.2 101 104 102 98.9 99.3 102 101 97.0 87.9 89.0 102 92.3 111 88.9 88.5 104 111 137 103 99.3 110 96.9 101 110 110 105 97.1 94.8 CS7 93.8 90.9 110 86.3 125 79.6 73.9 CS8 (1) Where applicable, custom lab flags have been used on this report. These data are validated and reported as accurate and in accord with AXYS Analytical Services Ltd. ISO17025 compliant quality assurance processes. Signed:____________ Andr ew P o r a t ____________ For Axys Internal Use Only [ XSL Template: FC-Form3B.xsl; Created: 16-Jan-2013 15:20:40; Application: XMLTransformer-1.13.28; ReportFilename: PFOA_FC_LC_13-Dec-2012_FC2G__Form3B_GS48529.html; Workgroup: WG42273; Design ID: 1980 ] Page 1 of 1 (WG42273 - PFOA_FC_LC_13-Dec-2012_FC2G__Form3B_GS48529.html) Page 85 of 307 www.axysanalytical.com A X Y S M E T H O D M L A -0 6 0 R e v 10 Form 3C P E R FLU O R IN A TED O R G A N IC S IN ITIA L C A LIB R A TIO N R ETEN TIO N TIM ES AXYS A N A LYTIC A L SERVICES 2045 MILLS RD., SIDNEY, B.C., CANADA V8L 5X2 TEL (250) 655-5800 FAX (250) 655-5811 Initial C alibration Date: 13-Dec-2012 CS0 D ata Filenam e: CS1 D ata Filenam e: FC2G_445 S: 4 FC2G_445 S: 5 Instrum ent ID: LC MS/MS CS2 D ata Filenam e: FC2G_445 S: 6 LC C olum n ID: C18MS CS3 D ata Filenam e: FC2G_445 S: 7 C S4 D ata Filenam e: FC2G_445 S: 8 CS5 D ata Filenam e: FC2G_445 S: 9 C S6 D ata Filenam e: FC2G_445 S: 10 CS7 D ata Filenam e: FC2G_445 S: 11 CS8 D ata Filenam e: N/A COMPOUND PFBA PFPeA PFHxA PFHpA PFOA PFNA PFDA PFUnA PFDoA PFBS PFHxS PFOS PFOSA LAB FLAG1 CS0 5:08 5:58 6:23 6:45 7:06 7:29 8:00 8:30 9:06 6:29 7:18 8:14 9:54 CS1 CS2 5:10 5:58 6:21 6:45 7:06 7:28 7:56 8:30 9:06 6:28 7:18 8:14 9:52 5:09 5:59 6:23 6:45 7:06 7:29 8:00 8:32 9:07 6:29 7:18 8:17 9:54 RETEN TIO N TIM ES CS3 CS4 CS5 5:11 5:59 6:23 6:45 7:06 7:29 8:00 8:32 9:06 6:29 7:18 8:14 9:54 5:06 5:58 6:21 6:45 7:06 7:29 8:00 8:32 9:07 6:28 7:18 8:14 9:56 5:09 5:59 6:21 6:45 7:06 7:29 8:00 8:30 9:06 6:29 7:18 8:14 9:54 CS6 5:06 5:57 6:19 6:42 7:04 7:28 7:56 8:30 9:06 6:27 7:18 8:14 9:54 CS7 5:12 5:59 6:21 6:45 7:06 7:29 8:00 8:33 9:07 6:28 7:18 8:14 CS8 MEAN RT 5:09 5:58 6:22 6:45 7:06 7:29 7:59 8:31 9:06 6:28 7:18 8:14 9:54 (1) Where applicable, custom lab flags have been used on this report. These data are validated and reported as accurate and in accord with AXYS Analytical Services Ltd. ISO17025 compliant quality assurance processes. Signed:____________ Andr ew P o r a t ____________ For Axys Internal Use Only [ XSL Template: FC-Form3C.xsl; Created: 16-Jan-2013 15:20:40; Application: XMLTransformer-1.13.28; ReportFilename: PFOA_FC_LC_13-Dec-2012_FC2G__Form3C_GS48529.html; Workgroup: WG42273; Design ID: 1980 ] Page 1 of 1 (WG42273 - PFOA_FC_LC_13-Dec-2012_FC2G__Form3C_GS48529.html) Page 86 of 307 www.axysanalytical.com A X Y S M E T H O D M L A -0 6 0 R e v 10 Form 3D P E R FLU O R IN A TED O R G A N IC S IN ITIA L C A LIB R A TIO N R ETEN TIO N TIM ES AXYS A N A LYTIC A L SERVICES 2045 MILLS RD., SIDNEY, B.C., CANADA V8L 5X2 TEL (250) 655-5800 FAX (250) 655-5811 Initial C alibration Date: 13-Dec-2012 CS0 D ata Filenam e: CS1 D ata Filenam e: FC2G_445 S: 4 FC2G_445 S: 5 Instrum ent ID: LC MS/MS CS2 D ata Filenam e: FC2G_445 S: 6 LC C olum n ID: C18MS CS3 D ata Filenam e: FC2G_445 S: 7 C S4 D ata Filenam e: FC2G_445 S: 8 CS5 D ata Filenam e: FC2G_445 S: 9 CS6 D ata Filenam e: FC2G_445 S: 10 CS7 D ata Filenam e: FC2G_445 S: 11 CS8 D ata Filenam e: N/A LABELED COMPOUND 1 3 C 4 -P F B A 1 3 C 2 -P F H x A 1 3 C 2 -P F O A 1 3 C 5 -P F N A 1 3 C 2 -P F D A 1 3 C 2 -P F D o A 13C4-PFO S 18 O 2-P F H x S LAB FLAG1 CS0 CS1 CS2 RETEN TIO N TIM ES CS3 CS4 CS5 CS6 CS7 CS8 MEAN RT 5:08 6:23 7:06 7:28 8:00 9:06 8:14 7:18 5:09 6:21 7:06 7:28 7:56 9:06 8:14 7:18 5:09 6:21 7:06 7:29 8:00 9:07 8:17 7:18 5:11 6:21 7:06 7:29 8:00 9:06 8:14 7:18 5:08 6:21 7:06 7:28 8:00 9:07 8:14 7:18 5:09 6:21 7:06 7:29 8:00 9:04 8:14 7:18 5:04 6:19 7:04 7:28 7:56 9:06 8:14 7:18 5:10 6:21 7:06 7:29 8:00 8:17 7:18 5:09 6:21 7:06 7:29 7:59 9:06 8:15 7:18 (1) Where applicable, custom lab flags have been used on this report. These data are validated and reported as accurate and in accord with AXYS Analytical Services Ltd. ISO17025 compliant quality assurance processes. Signed:____________ Andr ew P o r a t ____________ For Axys Internal Use Only [ XSL Template: FC-Form3D.xsl; Created: 16-Jan-2013 15:20:40; Application: XMLTransformer-1.13.28; ReportFilename: PFOA_FC_LC_13-Dec-2012_FC2G__Form3D_GS48529.html; Workgroup: WG42273; Design ID: 1980 ] Page 1 of 1 (WG42273 - PFOA_FC_LC_13-Dec-2012_FC2G__Form3D_GS48529.html) Page 87 of 307 www.axysanalytical.com _______ # 7 3 /____________ p f C - __________ _________ Sample List Report MassLynx 4.1 SCN627 Sample List: G:\Masslynx\lnst_G\_Master.PRO\SampleDB\FC2G_455.SPL Last Modified: Tuesday, December 18, 2012 16:01:48 Pacific Standard Time Printed: Tuesday, December 18, 2012 16:07:45 Pacific Standard Time Page 1 of 1 Page Position (1,1) File Name Sample ID File Text Bottle Signln Signut Inj VoL 1 FC2G 455S001 MeOH,, 1,,15uL ' 1:8,A 2 FC2G 455S002 MeOH,, 1,,15uL 1:8,A 3 FC2G 455S0Q3 FC-LIN-42221W500-A,, 1,,15uL 1:1,A 4 FC2G 455SQ04 FC-LIN-42221W500-D,, 1,,15uL 1:1,D 5 FC2G 455S005 FC-liN-42221 W500-D,, 1,,15uL 1:1,D 6 FC2G 455S006 WG42273-104,,SAR 1,WG42273,15/4000uL 3:2,B 7 FC2G 455S007 WG42273-102,,SPM 1,WG42273,15/4000uL 3:2,C 8 FC2G 455S008 MeOH,, 1,,15uL . 1:8,A 9 FC2G 455S009 MeOH,, 1,,15uL - 1:8,A 10 FC2G 455S010 WG42273-101,,BLK 1,WG42273,15/4000uL 3:2,D 11 FC2G 455S011 L18989-1,, 1,WG42273,15/4000uL 3:2,E 12 FC2G 455S012 L18989-2,, 1,WG42273,15/4000uL 3:2,F 13 FC2G 455S013 L18989-3,, 1,WG42273,15/4000uL 3:3,A 14 FC2G 455S014 L18989-4,, 1,WG42273,15/4000uL 3:3,B 15 FC2G 455S015 L18989-5,, 1,WG42273,15/4000uL 3:3,C 16 FC2G 455S016 L18989-6,, 1,WG42273,15/4000uL 3:3,D 17 FC2G 455S017 L18989-7,, 1.WG42273,15/4000uL 3:3,E 18 FC2G 455S018 L18989-8,, 1,WG42273,15/4000uL 3:3,F 19 FC2G 455S019 L18989-9,, 1,WG42273,15/4000uL 3:4,A 20 FC2G 455S020 L18989-10,, 1,WG42273,15/4000uL 3:4,B 21 FC2G 455S021 L18989-11,, 1,WG42273,15/4000uL 3:4,C 22 FC2G 455S022 WG42273-103,,DUP 1,WG42273,15/4000uL 3:4,D 23 FC2G 455S023 L18989-12,, 1,WG42273,15/4000uL 3:4,E 24 FC2G 455S024 L18989-13,, T,WG42273,15/4000uL 3:4,F 25 FC2G 455S025 L18989-14,, 1,WG42273,15/4000uL 3:5,A 26 FC2G 455S026 L18992-1,, 1,WG42273,15/4000ul 3:5,B 27 FC2G 455S027 L18992-2,, 1,WG42273,15/4000uL 3:5,C 28 FC2G 455S028 FC-LIN-42221W500-D,, 1,,T5.uL 1:1,D 29 FC2G 455S029 FC-LIN-42221W500-D,, 1,,15uL 1:1,D 30 FC2G 455S30 MeOH,, 1,,15uL 1:8,A 31 FC2G 455S031 MeOH,, 1,,15u'L 1:8,A lm f f J-_ 1L 1Ti1r - fff -... --h - --- - - -- 7 - /L -- -- - - - -- - - - - -- -- - -- --. - y 15.0 15.0 15.0 -1 15.0 15.0 15.0 15.0 15.0 15.0 15.0 15.0 15.0 15.0 15.0 15.0 15.0 15.0 15.0 15.0 15.0 15.0 15.0 15.0 15.0 15.0 15.0 15.0 15.0 15.0_ 15.0 15.0 Page 88 of 307 www.axysanalytical.com AXYS METHOD MLA-060 Rev 10 Form 4A PERFLUORINATED ORGANICS CALIBRATION VERIFICATION A XYS A N A LYTIC A L SERVICES 2045 MILLS RD., SIDNEY, B.C., CANADA V8L 5X2 TEL (250) 655-5800 FAX (250) 655-5811 Initial C alibration Date: 13-Dec-2012 V E R Data Filenam e: FC2G_455 S: 4 Instru m en t ID: LC MS/MS A nalysis Date: 18 -D e c -2 0 1 2 LC C o lum n ID: C18MS A n alysis Tim e: 18:49:50 COMPOUND PFBA PFPeA PFHxA PFHpA PFOA PFNA PFDA PFUnA PFDoA PFBS PFHxS PFOS PFOSA LAB FLAG1 R ETEN TIO N TIM E 5:11 5:58 6:21 6:42 7:06 7:28 7:56 8:30 9:04 6:27 7:15 8:14 9:54 EXPECTED CONC. (ng) 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 40.0 40.0 40.0 20.0 C O N C .FO U N D (ng) 17.4 16.6 19.0 18.1 18.8 19.8 20.9 17.6 20.5 40.7 39.5 39.1 18.1 R EC O VERY (%) 87.0 82.9 95.0 90.3 93.8 99.0 105 88.2 103 102 98.6 97.7 90.3 (1) Where applicable, custom lab flags have been used on this report. These data are validated and reported as accurate and in accord with AXYS Analytical Services Ltd. ISO17025 compliant quality assurance processes. Signed:____________ L e a n n e H e n l e y ____________ For Axys Internal Use Only [ XSL Template: FC-Form4A.xsl; Created: 16-Jan-2013 15:20:40; Application: XMLTransformer-1.13.28; Report Filename: PFOA_FC_LC_FC2G_455S4__Form4A_SJ1549312.html; Workgroup: WG42273; Design ID: 1980 ] Page 1 of 1 (WG42273 - PFOA_FC_LC_FC2G_455S4__Form4A_SJ1549312.html) Page 89 of 307 www.axysanalytical.com AXYS METHOD MLA-060 Rev 10 Form 4B PERFLUORINATED ORGANICS CALIBRATION VERIFICATION A XYS A N A LYTIC A L SERVICES 2045 MILLS RD., SIDNEY, B.C., CANADA V8L 5X2 TEL (250) 655-5800 FAX (250) 655-5811 Initial C alibration Date: 13-Dec-2012 V E R Data Filenam e: FC2G_455 S: 4 Instru m en t ID: LC MS/MS A nalysis Date: 18 -D e c -2 0 1 2 LC C o lum n ID: C18MS A n alysis Tim e: 18:49:50 LABELED COMPOUND 1 3 C 4 -P F B A 1 3 C 2 -P F H x A 13C2-PFO A 1 3 C 5 -P F N A 1 3 C 2 -P F D A 1 3 C 2 -P F D o A 1 3 C 4-P F O S 18 O 2-P F H x S LAB FLAG 1 RETEN TIO N TIM E 5:11 6:20 7:06 7:28 7:56 9:04 8:14 7:18 EXPECTED CONC. (ng) 12.0 12.0 36.0 12.0 12.0 12.0 18.0 18.0 C O N C .FO U N D (ng) 12.4 12.9 34.5 12.8 11.9 10.7 18.4 20.0 R E C O V ER Y (%) 104 108 96.0 107 99.3 88.9 102 111 (1) Where applicable, custom lab flags have been used on this report. These data are validated and reported as accurate and in accord with AXYS Analytical Services Ltd. ISO17025 compliant quality assurance processes. Signed:____________ L e a n n e H e n l e y ____________ For Axys Internal Use Only [ XSL Template: FC-Form4B.xsl; Created: 16-Jan-2013 15:20:40; Application: XMLTransformer-1.13.28; ReportFilename: PFOA_FC_LC_FC2G_455S4__Form4B_SJ1549312.html; Workgroup: WG42273; Design ID: 1980 ] Page 1 of 1 (WG42273 - PFOA_FC_LC_FC2G_455S4__Form4B_SJ1549312.html) Page 90 of 307 www.axysanalytical.com AXYS METHOD MLA-060 Rev 10 Form 4A PERFLUORINATED ORGANICS CALIBRATION VERIFICATION A XYS A N A LYTIC A L SERVICES 2045 MILLS RD., SIDNEY, B.C., CANADA V8L 5X2 TEL (250) 655-5800 FAX (250) 655-5811 Initial C alibration Date: 13-Dec-2012 V E R Data Filenam e: FC2G_455 S: 28 Instru m en t ID: LC MS/MS A nalysis Date: 19 -D e c -2 0 1 2 LC C o lum n ID: C18MS A n alysis Tim e: 01:53:10 COMPOUND PFBA PFPeA PFHxA PFHpA PFOA PFNA PFDA PFUnA PFDoA PFBS PFHxS PFOS PFOSA LAB FLAG1 R ETEN TIO N TIM E 5:10 5:59 6:23 6:45 7:06 7:29 7:56 8:28 9:02 6:28 7:18 8:14 9:54 EXPECTED CONC. (ng) 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 40.0 40.0 40.0 20.0 C O N C .FO U N D (ng) 18.0 17.4 19.0 19.4 18.5 19.3 22.1 19.3 20.4 38.4 35.3 38.3 17.7 R EC O VERY (%) 90.1 86.8 95.0 97.0 92.5 96.7 110 96.7 102 96.0 88.4 95.8 88.6 (1) Where applicable, custom lab flags have been used on this report. These data are validated and reported as accurate and in accord with AXYS Analytical Services Ltd. ISO17025 compliant quality assurance processes. Signed:____________ L e a n n e H e n l e y ____________ For Axys Internal Use Only [ XSL Template: FC-Form4A.xsl; Created: 16-Jan-2013 15:20:40; Application: XMLTransformer-1.13.28; ReportFilename: PFOA_FC_LC_FC2G_455S28_Form4A_SJ1549340.html; Workgroup: WG42273; Design ID: 1980 ] Page 1 of 1 (WG42273 - PFOA_FC_LC_FC2G_455S28__Form4A_SJ1549340.html) Page 91 of 307 www.axysanalytical.com AXYS METHOD MLA-060 Rev 10 Form 4B PERFLUORINATED ORGANICS CALIBRATION VERIFICATION A XYS A N A LYTIC A L SERVICES 2045 MILLS RD., SIDNEY, B.C., CANADA V8L 5X2 TEL (250) 655-5800 FAX (250) 655-5811 Initial C alibration Date: 13-Dec-2012 V E R Data Filenam e: FC2G_455 S: 28 Instru m en t ID: LC MS/MS A nalysis Date: 19 -D e c -2 0 1 2 LC C o lum n ID: C18MS A n alysis Tim e: 01:53:10 LABELED COMPOUND 1 3 C 4 -P F B A 1 3 C 2 -P F H x A 13C2-PFO A 1 3 C 5 -P F N A 1 3 C 2 -P F D A 1 3 C 2 -P F D o A 1 3 C 4-P F O S 18 O 2-P F H x S LAB FLAG 1 RETEN TIO N TIM E 5:08 6:21 7:06 7:28 7:56 9:02 8:14 7:18 EXPECTED CONC. (ng) 12.0 12.0 36.0 12.0 12.0 12.0 18.0 18.0 C O N C .FO U N D (ng) 11.9 12.0 37.0 12.6 10.6 10.3 18.3 20.7 R E C O V ER Y (%) 99.6 100 103 105 88.1 85.8 101 115 (1) Where applicable, custom lab flags have been used on this report. These data are validated and reported as accurate and in accord with AXYS Analytical Services Ltd. ISO17025 compliant quality assurance processes. Signed:____________ L e a n n e H e n l e y ____________ For Axys Internal Use Only [ XSL Template: FC-Form4B.xsl; Created: 16-Jan-2013 15:20:40; Application: XMLTransformer-1.13.28; Report Filename: PFOA_FC_LC_FC2G_455S28_Form4B_SJ1549340.html; Workgroup: WG42273; Design ID: 1980 ] Page 1 of 1 (WG42273 - PFOA_FC_LC_FC2G_455S28__Form4B_SJ1549340.html) Page 92 of 307 www.axysanalytical.com ________________________ m i P t- O f i t ______________________;_________________________ Sample List Report MassLynx 4.1 SCN627 Sample List: G:\Masslynx\lnst_G\_Master.PRO\SampleDB\FC3G_015.SPL Last Modified: Monday, January 14, 2013 15:51:45 Pacific Standard Time Printed: Monday, January 14, 2013 15:58:34 Pacific Standard Time Page 1 of 1 Page Position (1,1) File Name Sample ID File Text Bottle Signln SignOut Inj VoL 1 FC3G 015S001 MeOH,, 1,,15uL 1:8,A -+ 2 FC3G 015S002 MeOH,, 1,,15uL 1:8,A - 3 FC3G 015S003 FC-L1N-4242QW50Q-A,, 1,,15uL 2:1,A -i- 4 FC3G 015S004 FC-LI N-42420W500-A,, 1,,15uL 5 FC3G 015S005 FC-LIN-42420W500-B,, 1,,15uL 2:1,A 2:1,B - .. 6 FC3G"015S006 FC-Ll N-42420W500-C,, 1,,15uL 2:1,C - - 7 FC3G 015S007 FC-LI N-42420W500-D,, 1,,15uL 2:1, D .- - 8 FC3G 015S008 FC-LI N-42420W500-E,, 1,,15uL 2:1,E - - 9 FC3G 015S009 FC-LI N-42420W5Q0-F,, 1,,15uL 2:1,F - - 10 FC3G 015S010 FC-LI N-42420W500-G,, 1,,15uL 2:2,A - 11 FC3G~015S011 FC-LI N-42420W500-H,, 1,,15uL 2:2,B - - - 12 FC3G 015S012 MeOH,, 1,,15uL 1:8,A - - 13 FC3G 015S013 MeOH,, 1,,15uL 1:8,A - 14 FC3G 015S014 FC-42420W500-SAR2,, 1,,15uL 2:2,C- - 15 FC3G 015S015 FC-42420W500-SAR,, 1,,15uL 2:2,D - 16 FC3G Q15S016 FC-LI N-42420W500-D,, 1,,15uL 2:1, D - - 17 FC3G 015SQ17 FC-LIN-42420W500-D,, 1,,15uL 2:1, D* - 18 FC3G 015S018 WG42428-103,,SAR 1,WG42428,15/4000uL 2:2,E - - - 19 FC3G 015S019 WG42428-102,,SPM 1,WG42428,15/4000uL 2:2,F - - - 20 FC3G 015S020 MeOH,, 1,,15uL 1:8,A - - 21 FC3G 015S021 MeOH,, 1,,15uL 1:8,A - - 22 FC3G 015S022 WG42428-101,,BLK 1,WG42428,15/4000uL 2:3,A ' - - 23 FC3G 015S023 L18989-1 ,R, 1,WG42428,15/4000uL 2:3,B- - - 24 FC3G 015S024 L18989-2,R, 1,WG42428,15/4000uL 2:3,C - - 25 FC3G 015S025 L18989-3,R, 1,WG42428,15/4000uL 2:3,D - - 26 FC3G 015S026 L18989-4,R, 1,WG42428,15/4000uL 2:3,E - - 27 FC3G 015S027 L18989-5,R, 1,WG42428,15/4000uL 2:3,F - - 28 FC3G 015S028 L18989-6,R, 1,WG42428,15/4000uL 2:4,A- - 29 FC3G 015S029 L18989-7, R, 1,WG42428,15/4QQ0uL 2:4,B -- 30 FC3G 015S030 L18989-8.R, 1,WG42428,15/4000uL 2:4,C -- 31 FC3G 015S031 L18989-9, R, 1,WG42428,15/4000uL 2:4,D - 32 FC3G 015S032 L18989-10.R, 1.WG42428,15/4000uL 2:4,E -- 33 FC3G 015S033 L18989-12.R, 1,WG42428,15/4000uL 2:4,F- - 34 FC3G 015S034 L18989-13,R, 1,WG42428,15/4000uL 2:5,A - -- 35 FC3G 015S035 L18989-14,R, 1,WG42428,15/4000uL 2:5,B - 36 FC3G 015S036 FC-LI N-42420W500-D,, 1,,15uL 2:1,D - 37 FC3G 015S037 FC-LI N-42420W500-D,, 1,,15uL 38 FC3G 015S038 MeOH,, 1,,15uL 39 FC3G 015S039 MeOH,, 1,,15uL 21::81,'AD Jt 1:8,A > byj _ , -- ... ... --I 4 4 4 T -|- "T "T 4 4 -"1 --... ... ... -- ... ... ... ... ... ... ... ... ... ... -- -- -- ... ... "t 15.0 15.0 15.0 1i55.-0r i 15.0 15.0 ) 15.0 15,0 15.0 15.0 15.0 15.0 15.0 15.0 15.0 15.0 15.0 15.0 15.0 15.0 15.0 15.0 15.0 15.0 15.0 15.0 15.0 15.0 15,0 15.0 15.0 15.0 15.0 15.0 15.0 15.0 15.0 15.0 Page 93 of 307 www.axysanalytical.com AXYS METHOD MLA-060 Rev 10 Form 3A PE R FLU O R IN A TED O R G A N IC S INITIAL CALIB R A TIO N PER C EN T REC O VERIES AXYS ANA LYTIC A L SERVICES 2045 MILLS RD., SIDNEY, B.C., CANADA V8L 5X2 TEL (250) 655-5800 FAX (250) 655-5811 Initial C alibration Date: 10-Jan-2013 CS0 D ata Filenam e: CS1 D ata Filenam e: FC3G_015 S: 4 FC3G_015 S: 5 In stru m en t ID: LC MS/MS CS2 D ata Filenam e: FC3G_015 S: 6 LC C o lum n ID: C18MS CS3 D ata Filenam e: FC3G_015 S: 7 CS4 D ata Filenam e: FC3G_015 S: 8 CS5 D ata Filenam e: FC3G_015 S: 9 CS6 D ata Filenam e: FC3G_015 S: 10 CS7 D ata Filenam e: FC3G_015 S: 11 CS8 D ata Filenam e: N/A COMPOUND PFBA PFPeA PFHxA PFHpA PFOA PFNA PFDA PFUnA PFDoA PFBS PFHxS PFOS PFOSA LAB FLAG1 CS0 92.2 109 93.8 91.8 81.1 87.2 86.5 87.9 73.2 82.5 90.4 101 100 CS1 115 109 112 106 113 107 99.7 99.8 110 105 112 104 94.3 CS2 101 91.1 95.9 103 104 103 104 104 107 98.5 89.9 102 110 PER C EN T R EC O V ER Y (%) CS3 CS4 CS5 94.9 93.7 99.3 101 99.1 105 103 102 105 110 106 95.8 108 97.7 95.8 98.8 97.2 103 98.9 107 105 105 106 101 95.9 85.4 95.4 99.1 99.1 102 101 96.8 103 107 105 99.6 103 101 99.6 CS6 104 102 101 99.7 98.4 102 94.3 93.7 94.2 97.9 97.8 101 103 CS7 99.5 99.7 99.8 100 100 99.8 102 101 103 100 100 99.9 99.7 CS8 (1) Where applicable, custom lab flags have been used on this report. These data are validated and reported as accurate and in accord with AXYS Analytical Services Ltd. ISO17025 compliant quality assurance processes. Signed:____________ K r i s t i n a C o l e m a n ____________ For Axys Internal Use Only [ XSL Template: FC-Form3A.xsl; Created: 16-Jan-2013 14:49:00; Application: XMLTransformer-1.13.28; ReportFilename: PFOA_FC_LC_10-Jan-2013_FC3G__Form3A_GS48596.html; Workgroup: WG42428; Design ID: 1980 ] Page 1 of 1 (WG42428 -PFOA_FC_LC_10-Jan-2013_FC3G__Form3A_GS48596.html) Page 94 of 307 www.axysanalytical.com AXYS METHOD MLA-060 Rev 10 Form 3B PE R FLU O R IN A TED O R G A N IC S INITIAL CALIB R A TIO N PER C EN T REC O VERIES AXYS ANA LYTIC A L SERVICES 2045 MILLS RD., SIDNEY, B.C., CANADA V8L 5X2 TEL (250) 655-5800 FAX (250) 655-5811 Initial C alibration Date: 10-Jan-2013 CS0 D ata Filenam e: CS1 D ata Filenam e: FC3G_015 S: 4 FC3G_015 S: 5 In stru m en t ID: LC MS/MS CS2 D ata Filenam e: FC3G_015 S: 6 LC C o lum n ID: C18MS CS3 D ata Filenam e: FC3G_015 S: 7 CS4 D ata Filenam e: FC3G_015 S: 8 CS5 D ata Filenam e: FC3G_015 S: 9 CS6 D ata Filenam e: FC3G_015 S: 10 CS7 D ata Filenam e: FC3G_015 S: 11 CS8 D ata Filenam e: N/A LABELED COMPOUND 1 3 C 4 -P F B A 1 3 C 2 -P F H x A 13C2-PFO A 1 3 C 5 -P F N A 1 3 C 2 -P F D A 1 3 C 2 -P F D o A 1 3 C 4-P F O S 1 8 O 2-P F H xS LAB FLAG1 CS0 109 107 95.9 99.6 78.9 90.5 103 109 CS1 108 111 95.3 106 98.7 85.3 113 108 CS2 PER C EN T REC O VER IES (%) CS3 CS4 CS5 CS6 103 106 99.7 102 92.7 97.6 105 113 102 101 99.8 102 95.9 99.0 106 106 99.2 97.4 99.0 101 94.6 94.7 109 99.4 98.6 96.8 98.2 106 95.2 111 98.6 100 87.2 86.1 106 89.1 107 122 85.5 87.6 CS7 92.6 94.4 106 94.0 137 79.5 77.0 CS8 (1) Where applicable, custom lab flags have been used on this report. These data are validated and reported as accurate and in accord with AXYS Analytical Services Ltd. ISO17025 compliant quality assurance processes. Signed:____________ K r i s t i n a C o l e m a n ____________ For Axys Internal Use Only [ XSL Template: FC-Form3B.xsl; Created: 16-Jan-2013 14:49:00; Application: XMLTransformer-1.13.28; ReportFilename: PFOA_FC_LC_10-Jan-2013_FC3G__Form3B_GS48596.html; Workgroup: WG42428; Design ID: 1980 ] Page 1 of 1 (WG42428 - PFOA_FC_LC_10-Jan-2013_FC3G__Form3B_GS48596.html) Page 95 of 307 www.axysanalytical.com A X Y S M E T H O D M L A -0 6 0 R e v 10 Form 3C P E R FLU O R IN A TED O R G A N IC S IN ITIA L C A LIB R A TIO N R ETEN TIO N TIM ES AXYS A N A LYTIC A L SERVICES 2045 MILLS RD., SIDNEY, B.C., CANADA V8L 5X2 TEL (250) 655-5800 FAX (250) 655-5811 Initial C alibration Date: 10-Jan-2013 CS0 D ata Filenam e: CS1 D ata Filenam e: FC3G_015 S: 4 FC3G_015 S: 5 Instrum ent ID: LC MS/MS CS2 D ata Filenam e: FC3G_015 S: 6 LC C olum n ID: C18MS CS3 D ata Filenam e: FC3G_015 S: 7 C S4 D ata Filenam e: FC3G_015 S: 8 CS5 D ata Filenam e: FC3G_015 S: 9 C S6 D ata Filenam e: FC3G_015 S: 10 CS7 D ata Filenam e: FC3G_015 S: 11 CS8 D ata Filenam e: N/A COMPOUND PFBA PFPeA PFHxA PFHpA PFOA PFNA PFDA PFUnA PFDoA PFBS PFHxS PFOS PFOSA LAB FLAG1 CS0 5:12 5:57 6:22 6:44 7:09 7:33 8:03 8:37 9:15 6:31 7:20 8:24 9:59 CS1 CS2 5:11 5:57 6:21 6:44 7:06 7:33 8:03 8:37 9:15 6:29 7:20 8:24 9:59 5:11 5:58 6:22 6:44 7:09 7:33 8:03 8:37 9:15 6:30 7:20 8:24 9:59 RETEN TIO N TIM ES CS3 CS4 CS5 5:14 5:57 6:21 6:44 7:09 7:33 8:03 8:37 9:13 6:30 7:20 8:24 9:59 5:15 5:58 6:22 6:44 7:09 7:33 8:03 8:37 9:13 6:30 7:20 8:21 9:59 5:14 5:58 6:22 6:44 7:09 7:33 8:03 8:39 9:15 6:30 7:20 8:24 9:59 CS6 5:14 5:57 6:20 6:44 7:06 7:29 8:03 8:37 9:13 6:29 7:20 8:21 9:59 CS7 5:15 5:58 6:21 6:44 7:06 7:29 8:03 8:35 9:11 6:30 7:20 8:21 9:59 CS8 MEAN RT 5:13 5:58 6:21 6:44 7:08 7:32 8:03 8:37 9:14 6:30 7:20 8:23 9:59 (1) Where applicable, custom lab flags have been used on this report. These data are validated and reported as accurate and in accord with AXYS Analytical Services Ltd. ISO17025 compliant quality assurance processes. Signed:____________ K r i s t i n a C o l e m a n ____________ For Axys Internal Use Only [ XSL Template: FC-Form3C.xsl; Created: 16-Jan-2013 14:49:00; Application: XMLTransformer-1.13.28; ReportFilename: PFOA_FC_LC_10-Jan-2013_FC3G__Form3C_GS48596.html; Workgroup: WG42428; Design ID: 1980 ] Page 1 of 1 (WG42428-PFOA_FC_LC_10-Jan-2013_FC3G__Form3C_GS48596.html) Page 96 of 307 www.axysanalytical.com A X Y S M E T H O D M L A -0 6 0 R e v 10 Form 3D P E R FLU O R IN A TED O R G A N IC S IN ITIA L C A LIB R A TIO N R ETEN TIO N TIM ES AXYS A N A LYTIC A L SERVICES 2045 MILLS RD., SIDNEY, B.C., CANADA V8L 5X2 TEL (250) 655-5800 FAX (250) 655-5811 Initial C alibration Date: 10-Jan-2013 CS0 D ata Filenam e: CS1 D ata Filenam e: FC3G_015 S: 4 FC3G_015 S: 5 Instrum ent ID: LC MS/MS CS2 D ata Filenam e: FC3G_015 S: 6 LC C olum n ID: C18MS CS3 D ata Filenam e: FC3G_015 S: 7 C S4 D ata Filenam e: FC3G_015 S: 8 CS5 D ata Filenam e: FC3G_015 S: 9 CS6 D ata Filenam e: FC3G_015 S: 10 CS7 D ata Filenam e: FC3G_015 S: 11 CS8 D ata Filenam e: N/A LABELED COMPOUND 1 3 C 4 -P F B A 1 3 C 2 -P F H x A 1 3 C 2 -P F O A 1 3 C 5 -P F N A 1 3 C 2 -P F D A 1 3 C 2 -P F D o A 13C4-PFO S 18 O 2-P F H x S LAB FLAG1 CS0 CS1 CS2 RETEN TIO N TIM ES CS3 CS4 CS5 CS6 CS7 CS8 MEAN RT 5:12 6:22 7:06 7:33 8:03 9:15 8:24 7:20 5:10 6:21 7:06 7:29 8:03 9:13 8:21 7:20 5:10 6:22 7:09 7:29 8:03 9:15 8:24 7:20 5:14 6:22 7:09 7:33 8:03 9:13 8:21 7:20 5:12 6:21 7:09 7:33 8:03 9:13 8:21 7:20 5:12 6:22 7:09 7:33 8:03 9:15 8:24 7:20 5:11 6:20 7:06 7:29 8:03 9:13 8:21 7:20 5:12 6:21 7:06 7:29 7:59 8:21 7:20 5:12 6:21 7:08 7:31 8:03 9:14 8:22 7:20 (1) Where applicable, custom lab flags have been used on this report. These data are validated and reported as accurate and in accord with AXYS Analytical Services Ltd. ISO17025 compliant quality assurance processes. Signed:____________ K r i s t i n a C o l e m a n ____________ For Axys Internal Use Only [ XSL Template: FC-Form3D.xsl; Created: 16-Jan-2013 14:49:00; Application: XMLTransformer-1.13.28; ReportFilename: PFOA_FC_LC_10-Jan-2013_FC3G__Form3D_GS48596.html; Workgroup: WG42428; Design ID: 1980 ] Page 1 of 1 (WG42428 - PFOA_FC_LC_10-Jan-2013_FC3G__Form3D_GS48596.html) Page 97 of 307 www.axysanalytical.com AXYS METHOD MLA-060 Rev 10 Form 4A PERFLUORINATED ORGANICS CALIBRATION VERIFICATION A XYS A N A LYTIC A L SERVICES 2045 MILLS RD., SIDNEY, B.C., CANADA V8L 5X2 TEL (250) 655-5800 FAX (250) 655-5811 Initial C alibration Date: 10-Jan-2013 V E R Data Filenam e: FC3G _015 S: 16 Instru m en t ID: LC MS/MS A nalysis Date: 14-Jan-2013 LC C o lum n ID: C18MS A n alysis Tim e: 23:39:26 COMPOUND PFBA PFPeA PFHxA PFHpA PFOA PFNA PFDA PFUnA PFDoA PFBS PFHxS PFOS PFOSA LAB FLAG1 R ETEN TIO N TIM E 5:12 5:58 6:21 6:44 7:06 7:29 7:59 8:35 9:11 6:29 7:20 8:21 9:58 EXPECTED CONC. (ng) 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 40.0 40.0 40.0 20.0 C O N C .FO U N D (ng) 19.3 18.5 20.7 20.1 20.6 21.7 21.5 21.1 21.8 44.4 38.7 40.3 18.6 RECOVERY 96.7 92.7 104 101 103 108 108 106 109 111 96.8 101 93.1 (1) Where applicable, custom lab flags have been used on this report. These data are validated and reported as accurate and in accord with AXYS Analytical Services Ltd. ISO17025 compliant quality assurance processes. Signed:____________ L e a n n e H e n l e y ____________ For Axys Internal Use Only [ XSL Template: FC-Form4A.xsl; Created: 16-Jan-2013 14:49:00; Application: XMLTransformer-1.13.28; ReportFilename: PFOA_FC_LC_FC3G_015S16__Form4A_SJ1552177.html; Workgroup: WG42428; Design ID: 1980 ] Page 1 of 1 (WG42428 - PFOA_FC_LC_FC3G_015S16__Form4A_SJ1552177.html) Page 98 of 307 www.axysanalytical.com AXYS METHOD MLA-060 Rev 10 Form 4B PERFLUORINATED ORGANICS CALIBRATION VERIFICATION A XYS A N A LYTIC A L SERVICES 2045 MILLS RD., SIDNEY, B.C., CANADA V8L 5X2 TEL (250) 655-5800 FAX (250) 655-5811 Initial C alibration Date: 10-Jan-2013 V E R Data Filenam e: FC3G _015 S: 16 Instru m en t ID: LC MS/MS A nalysis Date: 14-Jan-2013 LC C o lum n ID: C18MS A n alysis Tim e: 23:39:26 LABELED COMPOUND 1 3 C 4 -P F B A 1 3 C 2 -P F H x A 13C2-PFO A 1 3 C 5 -P F N A 1 3 C 2 -P F D A 1 3 C 2 -P F D o A 1 3 C 4-P F O S 18 O 2-P F H x S LAB FLAG 1 RETEN TIO N TIM E 5:11 6:21 7:06 7:29 7:59 9:11 8:21 7:20 EXPECTED CONC. (ng) 12.0 12.0 36.0 12.0 12.0 12.0 18.0 18.0 C O N C .FO U N D (ng) 12.0 12.3 36.4 12.3 11.1 10.9 18.8 20.1 R E C O V ER Y (%) 100 102 101 102 92.8 90.6 104 112 (1) Where applicable, custom lab flags have been used on this report. These data are validated and reported as accurate and in accord with AXYS Analytical Services Ltd. ISO17025 compliant quality assurance processes. Signed:____________ L e a n n e H e n l e y ____________ For Axys Internal Use Only [ XSL Template: FC-Form4B.xsl; Created: 16-Jan-2013 14:49:00; Application: XMLTransformer-1.13.28; ReportFilename: PFOA_FC_LC_FC3G_015S16__Form4B_SJ1552177.html; Workgroup: WG42428; DesignID: 1980 ] Page 1 of 1 (WG42428 - PFOA_FC_LC_FC3G_015S16__Form4B_SJ1552177.html) Page 99 of 307 www.axysanalytical.com AXYS METHOD MLA-060 Rev 10 Form 4A PERFLUORINATED ORGANICS CALIBRATION VERIFICATION A XYS A N A LYTIC A L SERVICES 2045 MILLS RD., SIDNEY, B.C., CANADA V8L 5X2 TEL (250) 655-5800 FAX (250) 655-5811 Initial C alibration Date: 10-Jan-2013 V E R Data Filenam e: FC3G _015 S: 36 Instru m en t ID: LC MS/MS A nalysis Date: 15-Jan-2013 LC C o lum n ID: C18MS A n alysis Tim e: 05:18:50 COMPOUND PFBA PFPeA PFHxA PFHpA PFOA PFNA PFDA PFUnA PFDoA PFBS PFHxS PFOS PFOSA LAB FLAG1 R ETEN TIO N TIM E 5:14 5:57 6:22 6:44 7:09 7:29 7:59 8:32 9:07 6:29 7:20 8:17 9:58 EXPECTED CONC. (ng) 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 40.0 40.0 40.0 20.0 C O N C .FO U N D (ng) 20.0 17.8 20.0 19.9 19.9 21.0 20.6 20.5 22.4 42.1 42.3 41.7 18.4 RECOVERY 100 88.9 99.8 99.3 99.5 105 103 103 112 105 106 104 92.1 (1) Where applicable, custom lab flags have been used on this report. These data are validated and reported as accurate and in accord with AXYS Analytical Services Ltd. ISO17025 compliant quality assurance processes. Signed:____________ L e a n n e H e n l e y ____________ For Axys Internal Use Only [ XSL Template: FC-Form4A.xsl; Created: 16-Jan-2013 14:49:00; Application: XMLTransformer-1.13.28; ReportFilename: PFOA_FC_LC_FC3G_015S36__Form4A_SJ1552199.html; Workgroup: WG42428; Design ID: 1980 ] Page 1 of 1 (WG42428 - PFOA_FC_LC_FC3G_015S36__Form4A_SJ1552199.html) Page 100 of 307 www.axysanalytical.com AXYS METHOD MLA-060 Rev 10 Form 4B PERFLUORINATED ORGANICS CALIBRATION VERIFICATION A XYS A N A LYTIC A L SERVICES 2045 MILLS RD., SIDNEY, B.C., CANADA V8L 5X2 TEL (250) 655-5800 FAX (250) 655-5811 Initial C alibration Date: 10-Jan-2013 V E R Data Filenam e: FC3G _015 S: 36 Instru m en t ID: LC MS/MS A nalysis Date: 15-Jan-2013 LC C o lum n ID: C18MS A n alysis Tim e: 05:18:50 LABELED COMPOUND 1 3 C 4 -P F B A 1 3 C 2 -P F H x A 13C2-PFO A 1 3 C 5 -P F N A 1 3 C 2 -P F D A 1 3 C 2 -P F D o A 1 3 C 4-P F O S 18 O 2-P F H x S LAB FLAG 1 RETEN TIO N TIM E 5:12 6:22 7:09 7:29 7:59 9:07 8:17 7:20 EXPECTED CONC. (ng) 12.0 12.0 36.0 12.0 12.0 12.0 18.0 18.0 C O N C .FO U N D (ng) 11.7 12.1 35.7 12.2 10.6 10.3 18.0 18.6 R E C O V ER Y (%) 97.2 101 99.3 102 88.3 85.7 99.8 104 (1) Where applicable, custom lab flags have been used on this report. These data are validated and reported as accurate and in accord with AXYS Analytical Services Ltd. ISO17025 compliant quality assurance processes. Signed:____________ L e a n n e H e n l e y ____________ For Axys Internal Use Only [ XSL Template: FC-Form4B.xsl; Created: 16-Jan-2013 14:49:00; Application: XMLTransformer-1.13.28; ReportFilename: PFOA_FC_LC_FC3G_015S36__Form4B_SJ1552199.html; Workgroup: WG42428; DesignID: 1980 ] Page 1 of 1 (WG42428 - PFOA_FC_LC_FC3G_015S36__Form4B_SJ1552199.html) Page 101 of 307 www.axysanalytical.com Quantify Sample Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\lnst_G\PFC.PRO\FC\FC3G_015-B.qld Last Altered: Tuesday, January 15, 2013 14:23:27 Pacific Standard Time Printed: Wednesday, January 16, 2013 11:54:43 Pacific Standard Time ID: L18989-1,R, Name: FC3G_015S023 Description: 1,WG42428,15/4000uL Date: 15-Jan-2013 Time: 01:38:17 PFBA FC3G_015S023 loo- 1 9.c39e3 \ 37.725 => min 5.00 6.00 7.00 PFPeA FC3G 015S023 100- 3 .51e3l 15171 1 %- 5.60 ; ' 6.34 7 V' 0 - ........ .....................- min 5.00 6.00 7.00 PFNA FC3G_015S023 100- 7.49 2.21t;3 . 8717 III %- .6.63 7.00 8.00 PFDA FC3G_015S023 100- 8.05 f 2 02c3 ;; 5255 % ; -.. ! 1059 . ... .,- . 8.00 10.00 12.00 PFHxS-1 FC3GJM5SQ23 7.33 100-- 8 .0 8 e 2 ^| 2372 . %6.71 PFHxS-2 FC3G 015S023 PFHxA FC3G 015S023 100- 1 .0 6 e 4 l 50412 I %5.86 1 \ o " ____ ' ' - / - - I h -.. . 5.00 6.00 7.00 PFUnA FC3G 015S023 PFHxS-3 FC3G 015S023 7.00 8.00 PFHpA FC3G 015S023 100 : % 1.21e4~l 47023 f S| 5.65 r____ v s 0- lh J 5.00 6.00 7.00 . PFDoA FC3G_015S023 100 j 53 ' 9,18 I 3.80e2 12.08 | 1489 j \ %- 0 rr 8.00 10.00 12.00 PFOS-1 FC3G 015S023 PFOA-1 FC3GJJ15S023 ioo-q _ 7.09 . 2.93e4 \ 113445 %~ 07.00 8.00 PFBS-1 FC3G__015S023 100- 6.46 1 56e3 jt 5869 ;; %- 5.25 5.84 : i 5.00 6.00 7.00 PFOS-2 FC3G_015S023 100 8.17 A 1.34e3 2658 8.00 10.00 12.00 PFOA-2 FC3G_015S023 100- _ 7.09 : 7.32e3 \ 26233 %- 7.00 8.00 PFBS-2 FC3G_015S023 100- 6.49 5.80e2 } 2631 %- 7 4.70 5.58 3 : .a . a - /.... 5.00 6.00 7.00 PFOSA F C 3 G 0 15S023 1 0 0 - 7*53 9-7* 10.89 11-87 . I mir 8.00 10.00 12.00 PV by LEH 15-Jan-13, SV by AP 16-Jan-13. NOTE: OPR Conen. & LOD units = ng/mL, Sample and Lab BLK Conen. & LOD units = ng/L. Page 102 of 307 www.axysanalytical.com Quantify Sample Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\lnst__G\PFC.PRO\FC\FC3G_015-B.qld Last Altered: Tuesday, January 15, 2013 14:23:27 Pacific Standard Time Printed: Wednesday, January 16, 2013 11:54:43 Pacific Standard Time ID: L18989-1 ,R, Name: FC3G_015S023 Description: 1,WG42428,15/4000uL Date: 15-Jan-2013 Time: 01:38:17 13C2-PFOA FC3G_015S023 100-1 ~7 n Jf-2.07e5 I #826207 : 7.00 . min 8.00 13C4-PFOA FC3G 015S023 100- f 7,90e4 I t 314694 %- 07.00 .. . min 8.00 13C4-PFOS-1 FC3G 015S023 1 00 - j f 1.15e4 [j 45060 %~ 1 M o - i|S U M....... ....... . , min 8.00 10.00 12.00 13C4-PFOS-2 FC3G 015S023 1 00 - f 9.34e3 | 37285 %fj 0 - n i l , : , , , rn >i1". , min 8.00 10.00 12.00 1802-PFHxS-l FC3G 015S023 1 0 0 - 1.01e4 1 42374 | | %~ 0J / 7.00 8.00 13C4-PFBA FC3G 015S023 100- 5.19 2.2 1 e4 I 88535 %- 4.03 :L~--_ L _ A i 5.00 6.00 7.00 . 13C2-PFHxA FC3G 015S023 100- 6.33 4.99e4 1 232416 :: %- y\ . ^ .<i--,,-Krr.-- rni.n 5.00 6.00 7.00 13C5-PFNA FC3G 015S023 100- 7.49 7.16e4 h 278949 f-\ %-H \ 7.00 8.00 13C2-PFDA FC3G 015S023 100- 8.05 JT 8.09e4 1 287382 %- I 13C2-PFDOA FC3G 015S023 100- 9.18 f 1.24e5 :i 544719 %- . f f n. r p, , mi n 8.00 10.00 12.00 -1 ^ 8.00 10.00 1802-PFHxS-2 FC3G_015S023 100pj 7.33 7.02e3 | 29514 M %- 7.00 V 8.00 13C 2-P FO U E A FC3G 015S023 7.38 2.72e4 ~T\ 104121 I ; ,..ioo %- j \ i\ J........ 7.00 8.00 PV by LEH 15-Jan-13, SV byAP 16-Jan-13. NOTE: OPR Concn. & LOD units = ng/mL, Sample and Lab BLK Concn. & LOD units = ng/L. __ 10 Page 103 of 307 www.axysanalytical.com Quantify Sample Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\lnstJ3\PFC.PRO\FC\FC3G_015-B.qld Last Altered: Tuesday, January 15, 2013 14:23:27 Pacific Standard Time Printed: Wednesday, January 16, 2013 11:54:43 Pacific Standard Time ID: L18989-1 ,R, Name: FC3G_015S023 Description: 1,WG42428,15/4000uL Date: 15-Jan-2013 Time: 01:38:17 # Name 1 PFBA 2 PFPeA 3 PFHxA 4 PFHpA 5 PFOA-1 6 PFOA-2 7 PFNA 8 PFDA 9 PFUnA 10 PFDoA 11 PFBS-1 12 PFBS-2 13 PFHxS-1 14 PFHxS-2 15 PFHxS-3 16 PFOS-1 17 PFOS-2 18 PFOSA 19 13C2-PFOA 20 13C4-PFOA 21 13C4-PFOS-1 22 13C4-PFOS-2 23 1802-PFHxS-1 24 1802-PFHxS-2 25 13C4-PFBA 26 13C2-PFHxA 27 13C5-PFNA 28 13C2-PFDA 29 13C2-PFDoA 30 13C2-PFOUEA IS# Trace RT 25 212.99>168.98 5.21 26 262.98 >2 1 8.... 5.95 26 312.97> 268.98 6.34 26 362.97> 318.98 6.73 19 412.97> 368.98 7.09 19 412.97> 168.80 7.09 27 462.96 >4 1 8.... 7.49 28 512.96 >468.... 8.05 28 562.96 >5 1 8.... 8.73 29 612.95 > 568,... 9.18 23 298.94> 79.96 6.46 24 298.94 > 98.95 6.49 23 398.84 > 79.96 7.33 24 398,84> 98.96 7.29 23 398.84> 118.70 7.38 21 4 9 8 .93> 79.96 8.17 22 498.93> 98.96 8.17 21 498 > 78 20 414.97 > 369.... 7.09 416.97 >3 7 1.9 7.09 30 503 > 79.96 8.35 30 503 > 98.96 8.35 30 402.9>84 7.33 30 402.9>103 7.33 30 216.99>171.98 5.19 30 314,,97>269.98 6.33 30 467.96>422.97 7.49 30 514.96 >469.96 8.05 30 614.95 > 569.... 9.18 458.98 >393.98 7.38 Area 9391 3512 10589 12095 29302 7320 2209 2021 721 380 1564 580 808 267 172 3069 1341 206795 78970 11475 9344 10069 7019 22121 49932 71635 80908 124386 27164 IS Area 22121 49932 49932 49932 206795 206795 71635 80908 80908 124386 10069 7019 10069 7019 10069 11475 9344 11475 78970 27164 27164 27164 27164 27164 27164 27164 27164 27164 ng/L 8.816 2.221 3.826 4.635 9.138 9.613 0.366 2.700 2.082 1.098 1.118 0.961 7.593 4.697 63.137 22.358 33.233 34.061 35.283 33.208 15.793 18.023 22.976 20.627 20.253 18.801 LOD 0.0806 0.2323 0.1745 0.1219 0.1192 0.3180 0,1368 0.2198 1.0415 0.4610 0.7750 0.1197 0.0649 0.0563 0.1072 %Rec S/N 62 20 85 38 124 297 11 15 5 5 28 67 23 135 6 36 44 92.1 97.8 96.9 99.3 102.9 96.8 69.1 78,8 100.5 90.2 88.6 98.7 597 0 747 484 112 237 64 548 1078 1019 648 0 Noise 610 743 591 1236 912 88 759 358 337 322 208 39 104 7 110 203 61 17 1384 0 60 77 380 124 1387 424 259 282 841 0 Height 37725 15171 50412 47023 113445 26233 8717 5255 1564 1489 5869 2631 2372 963 685 7347 2658 826207 314694 45060 37285 42374 29514 88535 232416 278949 287382 544719 104121 IS Height Sample size 88535 0.5250 232416 0.5250 232416 0.5250 232416 0.5250 826207 0.5250 826207 0.5250 278949 0.5250 287382 0.5250 287382 0.5250 544719 0.5250 42374 0.5250 29514 0.5250 42374 0.5250 29514 0.5250 42374 0.5250 45060 0.5250 37285 0.5250 45060 0.5250 314694 0.5250 0.5250 104121 0.5250 104121 0.5250 104121 0.5250 104121 0.5250 104121 0.5250 104121 0.5250 104121 0.5250 104121 0.5250 104121 0.5250 0.5250 Factor2 Detection... 1.0 MM 1.0 MM 1.0 bb 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MMI 1.0 MMl 1.0 MM! 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 MM 1.0 bb 1.0 bb 1.0 bb 1.0 bb PV by LEH 15-Jan-13, SV by AP 16-Jan-13. NOTE: OPR Conen. & LOD units = ng/mL, Sample and Lab BLK Conen. & LOD units = ng/L. Page 104 of 307 www.axysanalytical.com Quantify Sample Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\inst_G\PFC.PRO\FC\FC3G_015-B.qld Last Altered: Tuesday, January 15, 2013 14:23:27 Pacific Standard Time Printed: Wednesday, January 16, 2013 11:54:43 Pacific Standard Time ID: L18989-2,R, Name: FC3G_015S024 Description: 1,WG42428,15/4000uL Date: 15-Jan-2013 Time: 01:55:18 PFBA FC3G_015S024 100 _ 5.21 i 1.12e4 II 51174 %- i 4.03 05.00 6.00 7.00 PFPeA FC3G_015S024 100- 5.93 4.03e3 i 16979 ;; 6.53 4.03 5.41 ' .. .1 0 - Vrrrp-^p-rTTTTrTTjmrj-nTrrr-!-- min 5 .0 0 '6 .0 0 7.00 PFHxA FC3G_015S024 100- 6.34 _ 1.02e4 44450 %- - 4.26 5.69 i 05.00 6.00 7.00 PFNA FC3G 015S024 PFDA FC3G 015S024 100- 7:99 A2.24e3 1 8620 1 % - II f t 8.79 / 10.62 ^ chTTT-rn-rT-^-rv-p-TTTri-rrt-rrr min 8.00 10.00 12.00 PFUnA FC3G 015S024 100- 8.61 I 4.25e2 A 1698 i . 12.17 %-t . y 11.54^ 7\A ' k 10.08 iW 08.00 10.00 12.00 PFHxS-1 FC3G__015S024 100- - 9 7.33 .1 7 e 2 l 3332 ft % 16.63 oA 7.00 8.00 PFHxS-2 FC3G_015S024 100- 7.29 ,f4.48e2 1962 %- 6.86 0- . 7.00 V V7..96 8,00 m jn PFHxS-3 FC3G 015S024 100- 7.29 3 51o2 ; \ 1287 %-- 6.63 / -I ...L 0- 7.00 8.00 PFHpA FC3G_015S024 100- 6.73 8.94e3~| 35269 - %" -11 ^ . A 0 -FF-rF^-rT^; :::;,,M;Mn;;::I min ' 5 .0 0 '6 .0 0 ' 7.00 PFOA-1 FC3G_015S024 7.09 100 T 3.19e4 ' 122202 0 - ............ " 7.00 8.00 PFOA-2 FC3G_015S024 100-i _ 7.09 i 8.22e3 \ 29542 %1 7.00 8.00 PFDoA FC3G 015S024 100,^ 7.53 _ 9.21 1 5.59e2 12.14 1 1671 i. ,1 II %~ 0 - -|""i'"i"r"vv11i i , 1.1 ..11 1n. min 8.00 10.00 12.00 PFBS-1 FC3G 015S024 100" 6.46 8.19e3 1 35644 % a : oJ 5.00 6.00 7.00 PFBS-2 FC3GJ015S024 100: 6.46 3.9 7e3 18704 %- 5.00 PFOS-1 FC3G 015S024 100- 8.29 |~ 7.18e3 /I 17666 %- 0 - Mf#P?rTMrrrr:T7.TrTrrr min 8.00 10.00 12.00 PFOS-2 FC3G 015S024 100- 8.29 f 3.92e3 \\ 11005 %" \ \ ! \ 11.54 -- - . - > 7 min 8.00 10.00 12.00 PFOSA FC3G 015S024 100- 9.96 1.49e2~l 743 i %- 9.24 J i 12.29 o: IW t- -rfA min 8.00 10.00 12,00 PV by LEH 15-Jan-13, SV by AP 16-Jan-13. NOTE: OPR Conen. & LOD units = ng/mL, Sample and Lab BLK Conen. & LOD units = ng/L. Page 105 of 307 www.axysanalytical.com Quantify Sample Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\lnst_G\PFC.PRO\FC\FC3G_015-B.qld Last Altered: Tuesday, January 15, 2013 14:23:27 Pacific Standard Time Printed: Wednesday, January 16, 2013 11:54:43 Pacific Standard Time ID: L18989-2,R, Name: FC3G_015S024 Description: 1,WG42428,15/4000uL Date: 15-Jan-2013 Time: 01:55:18 13C2-PFOA FC3G 015S024 100- 7.09 k 2.25e5 949408 %- 13C4-PFOA FC3G 015S024 100- 7.09 f~ 8.13e4 : \ 335385 7.00 8.00 7.00 8.00 13C4-PFBA FC3G 015S024 100- 5.21 I 2,58e4 1 121982 %M 4.11 l. \ 0- 5.00 6.00 min 7.00 13C2-PFHxA FC3G_015S024 100^ 6.34 5.04e4 244534 %- 0J ., ,, 5.00 6.00 7.00 13C4-PFOS-1 FC3G_015S024 100-i ^ 8.35 I 1.16e4 43554 1 %- 8.00 10.00 12.00 13C5-PFNA FC3G 015S024 100- 7.49 7.85e4 ?\ 335922 ; %-_ 0- / ' 7.00 8.00 1 i 13C4-PFOS-2 FC3G 015S024 8.29 1 00- ip9.53d3 1 36221 %- y i n 0^ 1 Vi 8.00 10.00 12.00 1802-PFHxS-1 FC3G 015S024 7.33 OO- 1.05e4"|| 41120 1 %- 1802 PFHxS-2 FC3G_ 015S024 100 7.29 . 7.R3e3 1130156 / 7.00 __ 8.00 min 0" 7.00 8.00 13C2-PFDA FC3G 015S024 100- 7.99 f 8.94e4 1 330014 %- f1; o: :i -W. 8.00 10.00 min 12.00 13C2-PFDOA FC3G_015S024 r1 0 0 1 9.18 1.41e5 6 612711 %- - min 8.00 10.00 12.00 13C2-PFOUEA FC3G__015S024 100- 7.38 2.71e4 7, 105777 : : 0 7.00 8.00 PV by LEH 15-Jan-13, SV by AP 16-Jan-13. NOTE: OPR Conen. & LOD units = ng/mL, Sample and Lab BLK Conen. & LOD units = ng/L. Page 106 of 307 www.axysanalytical.com Quantify Sample Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\inst_G\PFC.PRO\FC\FC3G_015-B.qld Last Altered: Tuesday, January 15, 2013 14:23:27 Pacific Standard Time Printed: Wednesday, January 16, 2013 11:54:43 Pacific Standard Time ID: L18989-2,R, Name: FC3G_015S024 Description: 1,WG42428,15/4000uL Date: 15-Jan-2013 Time: 01:55:18 # Name 1 PFBA 2 PFPeA 3 PFHxA 4 PFHpA 5 PFGA-1 6 PFOA-2 7 PFNA 8 PFDA 9 PFUnA 10 PFDoA 11 PFBS-1 12 PFBS-2 13 PFHxS-1 14 PFHxS-2 15 PFHxS-3 16 PFOS-1 17 PFOS-2 18 PFOSA 19 13C2-PFOA 20 13C4-PFOA 21 13C4-PFOS-1 22 13C4-PFOS-2 23 1802-PFHxS-1 24 1802-PFHXS-2 25 13C4-PFBA 26 13C2-PFHxA 27 13C5-PFNA 28 13C2-PFDA 29 13C2-PFDOA 30 13C2-PFOUEA IS# Trace RT 25 212.99>168.98 5.21 26 262.98 > 2 1 8 .... 5.93 26 312.97> 268.98 6.34 26 362.97> 318.98 6.73 19 412.97> 368.98 7.09 19 412.97> 168.80 7.09 27 462.96 >4 1 8.... 7.49 28 512.96 >468.... 7.99 28 562.96 > 5 1 8 .... 8.61 29 612.95 >5 6 8.... 9.21 23 298.94> 79.96 6.46 24 298.94 > 98.95 6.46 23 398.84 > 79.96 7.33 24 398.84> 98.96 7.29 23 398.84> 118.70 7.29 21 498.93> 79.96 8.29 . 22 498.93> 98.96 8.29 21 498 > 78 9.96 20 414.97 >3 6 9.... 7.09 416.97 >3 7 1.9 7.09 30 503 > 79.96 8.35 30 503 > 98.96 8.29 30 402.9>84 7.33 30 402.9>103 7.29 30 216.99>171.98 5.21 30 314.97>269.98 6.34 30 467.96>422.97 7.49 30 514.96 >469.96 7.99 30 614.95 > 569.... 9.18 458.98 >393.98 7.38 Area 11163 4028 10221 8937 31931 8223 2098 2236 425 559 8187 3974 917 448 351 7179 3921 149 224822 81315 11560 9534 10526 7629 25804 50396 78491 89362 140512 27128 IS Area 25804 50396 50396 50396 224822 224822 78491 89362 89362 140512 10526 7629 10526 7629 10526 11560 9534 11560 81315 27128 27128 27128 27128 27128 27128 27128 27128 27128 ng/L 10.401 2.933 4.210 3.882 10.596 11.501 0.311 20.869 18.826 1.485 2.111 2.793 22.036 16.692 0.424 77.111 26.630 38.781 40.255 42.725 41.811 21.338 21.070 29.160 26.388 26.501 21.720 LOD 0.1671 0.0315 0.0697 0.1385 0.2329 0.3833 15.6997 0.2002 0.1017 0.0908 0.1044 %Rec 97.2 100.7 97.8 101.5 107.7 105.4 80.7 79.7 110.3 99.8 100.2 98.6 S/N 95 30 85 51 99 70 10 27 4 7 277 386 88 0 19 122 74 44 0 0 483 307 0 0 5 393 944 826 851 0 Noise 538 563 521 691 1241 420 891 316 384 251 129 48 38 0 68 145 149 17 0 0 90 118 0 0 24676 622 356 400 720 0 Height 51174 16979 44450 35269 122202 29542 8732 8620 1698 1671 35644 18704 3332 1962 1287 17666 11005 743 949408 335385 43554 36221 41126 30156 121982 244534 335922 330014 612711 105777 IS Height Sample size 121982 0.4538 244534 0.4538 244534 0.4538 244534 0.4538 949408 0.4538 949408 0.4538 335922 0.4538 330014 330014 0.4538 0.4538 612711 0.4538 41126 30156 0.4538 0.4538 41126 0.4538 30156 0.4538 41126 0.4538 43554 0.4538 36221 0.4538 43554 0.4538 335385 0.4538 0.4538 105777 0.4538 105777 0.4538 105777 0.4538 105777 0.4538 105777 105777 0.4538 0.4538 105777 0.4538 105777 105777 0.4538 0.4538 0.4538 Factor2 Detection... 1.0 MM 1.0 MM 1.0 M M 1.0 bb 1.0 bb 1.0 bb 1.0 MM 1.0 MM I 1.0 bbl 1.0 bbl 1.0 MM 1.0 bb 1.0 M M 1.0 bb 1.0 MM 1.0 MM 1.0 bb 1.0 MM 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 bb PV by LEH 15-Jan-13, SV by AP 16-Jan-13. NOTE: OPR Conen. & LOD units = ng/mL, Sample and Lab BLK Conen. & LOD units = ng/L. Page 107 of 307 www.axysanalytical.com Quantify Sample Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\lnst_G\PFC.PRO\FC\FC3G_015-B.qld Last Altered: Tuesday, January 15, 2013 14:23:27 Pacific Standard Time Printed: Wednesday, January 16, 2013 11:54:43 Pacific Standard Time ID: L18989-3,R, Name: FC3GJJ15S025 Description: 1,WG42428,15/4000uL Date: 15-Jan-2013 Time: 02:12:11 PFBA FC3G 015S025 100 5.24 7.91e3 PFPeA FC3G_015S025 100- 5.95 2.76e3 10979 ` 5.51 [{ 6.47 %" 5.02 '.>.... 'T ... 5.00 6.00 7.00 PFNA FC3G 015S025 5.00 6.00 7.00 PFDA FC3G_015S025 100 8.05 f 1.59e3 6020 %- PFHxA FC3G 015S025 PFUnA FC3G 015S025 PFHxS-1 FC3G 015S025 100- 7.33 4 .0 5 e 2 l, 1597 | | %6.76 / i 0 7.00 7.90 8.00 8.00 10.00 12.00 PFHxS-2 FC3G 015S025 PFHxS-3 FC3G_015S025 100-, 7.33 -1 .0 2 e 2 l 554 M %- 7.00 8.00 PFHpA FC3G 015S025 PFOA-1 FC3G_015S025 100- _ 7.09 :9.37e3 \ 36406 %- PFOA-2 FC3G_015S025 100- 7.09 42.50e3 ; \ 10036 % PFDoA FC3G_015S025 100-, 9.12 fT5.53e2 j 2124 %--7.64 I' 11.25. 12.23 d ' 1I11npv-q-rn1",",": iij. r 8.00 10.00 12.00 PFOS-1 FC3G_015S025 8.17 100- f 2.42e3 I %- it 1 5868 10.6812.05 8.00 10.00 12.00 7.00 8.00 PFBS-1 FC3G015S025 100 6.51 1.24e3~ 4816 %5.75 5.13 , > ' T ---\. 0 . 5.00 6.00 7.00 PFOS-2 FC3G_015S025 100- 8.35 f 1.24e3 3550 %- . 1 1.4 2J1;81 \ . .-.... . -.V-8.00 10.00 12.00 7.00 8.00 PFBS-2 FC3G 015S025 100~ 6.46 5 .1 5 e 2 l 2218 p %- 4.18 5.65 f i | o5.00 6.00 7.00 PFOSA FC3G_015S025 nn 9.96 1003 8.28e11 271 rn" Vo 8.55 8.00 10.00 12.00 PV by LEH 15-Jan-13, SV by AP 16-Jan-13. NOTE: OPR Conen. & LOD units = ng/m l, Sample and Lab BLK Conen. & LOD units = ng/L. Page 108 of 307 www.axysanalytical.com Quantify Sample Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\inst_G\PFC.PRO\FC\FC3G_015-B.qld Last Altered: Tuesday, January 15, 2013 14:23:27 Pacific Standard Time Printed: Wednesday, January 16, 2013 11:54:43 Pacific Standard Time ID: L18989-3,R, Name: FC3G_015S025 Description: 1,WG42428,15/4000uL Date: 15-Jan-2013 Time: 02:12:11 13C2-PFOA FC3G 015S025 100" 7.09 JTZ30e5 fJ915197 %" 13C4-PFOA FC3G 015S025 100m 7.09 8.87e4 t \ 362583 %~ 13C4-PFOS-1 FC3GJ015S025 100-j 8.35 1.32e4 47970 %: 13C4-PFOS-2 FC3G_015S025 100n 8.35 1.05e4 42302 %~ 0- 7.00 - n min 8.00 07.00 8.00 0 8.00 10.00 12.00 8.00 10.00 12.00 13C4-PFBA FC3G 015S025 100^ 5.21 2.68e4 k/ 106913 %: j. 4.03 | I T:\J o: 5.00 6.00 min 7.00 13C2-PFHxA FC3G 015S025 100- 6.34 5.79e4 ; 268128 ' %- ;\ o - ; \ min 5.00 6.00 7.00 13C5-PFNA FC3G 015S025 100- 7.49 8.09e4 h 326335 [ \ %- i ______ 7.00 "fh-r min 8.00 13C2-PFDA FC3G_015S025 100-, 8.05 F 8.79e4 I 307851 %- I! o- 8.00 10.00 12.00 1802-PFHxS-l FC3GJ315S025 100-l l. 7.33 07e4 " J -44341 t \ %- 7.00 8.00 13C2-PFDoA FC3G_015S025 100n 9.18 1.41e5 608451 8.00 10.00 12.00 1802-PFHxS-2 FC3G_015S025 100-- 7.33 8.18e3 A 32319 ! \ %~ 7.00 8.00 13C2-PFOUEA FC3G 015S025 PV by LEH 15-Jan-13, SV by AP 16-Jan-13, NOTE: OPR Conen. & LOD units = ng/mL, Sample and Lab BLK Conen. & LOD units = ng/L. _, 0 Page 109 of 307 www.axysanalytical.com Quantify Sample Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\lnst_G\PFC.PRO\FC\FC3G_015-B.qld Last Altered: Tuesday, January 15, 2013 14:23:27 Pacific Standard Time Printed: Wednesday, January 16, 2013 11:54:43 Pacific Standard Time ID: L18989-3.R, Name: FC3G_015S025 Description: 1,WG42428,15/4000uL Date: 15-Jan-2013 Time: 02:12:11 # Name 1 PFBA 2 PFPeA 3 PFHxA 4 PFHpA 5 PFOA-1 6 PFOA-2 7 PFNA 8 PFDA 9 PFUnA 10 PFDoA 11 PFBS-1 12 PFBS-2 13 PFHxS-1 14 PFHxS-2 15 PFHxS-3 16 PFOS-1 17 PFOS-2 18 PFOSA 19 13C2-PFOA 20 13C4-PFOA 21 13C4-PFOS-1 22 13C4-PFOS-2 23 1802-PFH xS-l 24 1802-PFHxS-2 25 13C4-PFBA 26 13C2-PFHXA 27 13C5-PFNA 28 13C2-PFDA 29 13C2-PFDoA 30 13C2-PFOUEA IS# Trace RT 25 212.99>168.98 5.24 26 262.98 >2 1 8.... 5.95 26 312.97> 268.98 6.34 26 362.97> 318.98 6.68 19 412.97> 368.98 7.09 19 412.97> 168.80 7.09 27 462.96 >4 1 8.... 7.49 28 512.96 >468.... 8.05 28 562.96 >518.... 8.55 29 612.95 > 568.... 9.12 23 298.94> 79.96 6.51 24 298.94 > 98.95 6.46 23 398.84 > 79.96 7.33 24 398.84> 98.96 7.38 23 398.84> 118.70 7.33 21 498.93> 79.96 8.17 22 498.93> 98.96 8.35 21 498 > 78 9.96 20 414.97 >3 6 9.... 7.09 416.97 >3 7 1 .9 7.09 30 503 > 79.96 8.35 30 503 > 98.96 30 402.9>84 8.35 7.33 30 402.S>103 7.33 30 216.99>171.98 5.21 30 314.97>269.98 6.34 30 467.96>422.97 7.49 30 514.96 >469.96 8.05 30 614.95 > 569-.. 9.18 458.98 >393.98 7.38 Area 7907 2758 5446 3646 9373 2497 2019 1591 656 553 1244 515 405 133 102 2420 1237 83 230137 88685 13221 10475 10710 8180 26826 57928 80907 87897 141020 31495 IS Area 26826 57928 57928 57928 230137 230137 80907 87897 87897 141020 10710 8180 10710 8180 10710 13221 10475 13221 88685 31495 31495 31495 31495 31495 31495 31495 31495 31495 ng/L 6.786 1.668 1.639 1.243 2.563 3.084 0.257 1.959 1.631 0.422 0.313 5.484 4.271 0.256 70.666 28.359 37.302 37.197 36.558 37.700 18.656 20.369 25.279 21.829 22.368 24.621 LOD 0.0271 0.1897 0.0597 0.1550 0.1473 0.1577 0.3947 3.2835 0.0514 0.1139 0.0893 0.0522 %Rec 91.2 109.8 96.3 96.0 94.4 97.3 72.3 78.9 97.9 84.5 86.6 114.4 S/N 50 16 48 15 54 50 12 18 5 6 22 50 0 16 12 34 20 9 1400 0 663 294 0 0 17 1418 0 518 834 1414 Noise 643 681 508 874 674 202 741 341 377 337 219 44 0 22 45 174 178 32 654 0 72 144 0 0 6113 189 0 594 729 86 Height 32099 10979 24581 13046 36406 10036 8847 6020 1741 2124 4816 2218 1597 360 554 5868 3550 271 915197 362583 47970 42302 44341 32319 106913 268128 326335 307851 608451 122324 IS Height Sample size 106913 0.4648 268128 0.4648 268128 0.4648 268128 0.4648 915197 0.4648 915197 0.4648 326335 0.4648 307851 0.4648 307851 0.4648 608451 0.4648 44341 0.4648 32319 0.4648 44341 0.4648 32319 0.4648 44341 0.4648 47970 42302 0.4648 0-4648 47970 0.4648 362583 0.4648 0.4648 122324 0.4648 122324 0.4648 122324 0.4648 122324 0.4648 122324 0.4648 122324 0.4648 122324 0-4648 122324 0.4648 122324 0.4648 0.4648 Factor2 Detection... 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 bb 1.0 MM 1.0 MM 1.0 bbl 1.0 MM! 1.0 MMI 1.0 MM 1.0 bb 1.0 MM! 1.0 MM 1.0 MM 1.0 MM 1.0 bb 1.0 MM 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 MM 1.0 bb 1.0 bb 1.0 bb 1.0 ' bb PV by LEH 15-Jan-13, SV by AP 16-Jan-13. NOTE: OPR Conen. & LOD units = ng/mL, Sample and Lab BLK Conen. & LOD units = ng/L. Page 110 of 307 www.axysanalytical.com Quantify Sample Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\lnst_G\PFC.PR0\FC\FC3GJ )1 5-B.qld Last Altered: Tuesday, January 15, 2013 14:23:27 Pacific Standard Time Printed: Wednesday, January 16, 2013 11:54:43 Pacific Standard Time ID: L18989-4,R, Name: FC3G_015S026 Description: 1,WG42428,15/4000uL Date: 15-Jan-2013 Time: 02:29:12 PFBA FC3GJ315S026 loo- i f 7c.54e4 1 297473 M ri V,-.... ... 5.00 6.00 7.00 PFPeA FC3G 015S026 100- 2.08e4 i 92157 o - , ........ 5.00 : 6.00 min 7.00 PFHxA FC3G 015S026 100- 1 .31e5l 549250 %r'\ 0S- .... ............min 5.00 6.00 7.00 PFNA FC3G 015S026 PFDA FC3G 015S026 100- 7.99 f 3;76e3 fl 12635 %- 885 11.3T_ o - 1111111^ i'i i 1111: 11,i min 8.00 10.00 12.00 PFUnA FC3G__015S026 100n 8.58 7.23e2 1 3066 %: 0.4 2 1 1 4 5 1 2 2 9 Li 8.00 10.00 12.00 PFHxS-1 FC3G 015S026 PFHxS-2 FC3GJM5S026 100-- 7.33 6.7)e3 ; 23087 J i %- PFHxS-3 FC3G 015S026 1 7.00 8.00 PFHpA FC3G 015S026 100n 1.31e5 1 487207 %] 1\ 0 - ---m-TTi : mi n 5.00 6.00 7.00 PFOA-1 FC3G 015S026 ioo-q : " 5.28e5 1929210 %- 0J 7.00 8.00 PFOA-2 FC3GJ515S026 1001 7.09 . 1.44e5 : 520304 %J qJ 7.00 8.00 PFDoA FC3G 015S026 100n 9.15 5.50e2 ' I 7.81 1 1830 u %: 'U i Vi ^ o: " 11>i *i i min 8.00 10.00 12.00 PFBS-1 FC3G 015S026 100- 6.47 6.23e4 282535 r- %~ i ` \ ! 0 - -------------------- -- ,-- m in 5.00 6.00 7.00 PFBS-2 FC3G_015S026 100 6.46 3 .2 7 e 4 l 149571 1 %- o5.00 6.00 7.00 PFOS-1 FC3G 015S026 PFOS-2 FC3G_015S026 100- 8.29 I 8.06e4 i 261911 %" PFOSA FC3G_015S026 100n 9.99 9.76e3 37047 %- 08.00 10.00 12.00 8.00 10.00 12.00 PV by LEH 15-Jan-13, SV byAP 16-Jan-13. NOTE: OPR Conen. & LOD units = ng/mL, Sample and Lab BLK Conen. & LOD units = ng/L. Page 111 of 307 www.axysanalytical.com Quantify Sample Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\lnst_G\PFC.PRO\FC\FC3G_015-B.qld Last Altered: Tuesday, January 15, 2013 14:23:27 Pacific Standard Time Printed: Wednesday, January 16, 2013 11:54:43 Pacific Standard Time ID: L18989-4,R, Name: FC3G_015S026 Description: 1,WG42428,15/4000uL Date: 15-Jan-2013 Time: 02:29:12 13C2-PFOA FC3G 015S026 100- 7.09 f2 .0 2 e 5 800235 %- o - t t min 8.00 13C4-PFOA FC3G 015S026 100- 7.09 7.99e4 f t 318382 %- o- I 7.00 ___ ! -m min 8.00 13C4-PFOS-1 FC3G 015S026 100m 8.29 F 1.19e4 U 42833 %- H 0 - min 8.00 10.00 12.00 13C4-PFOS-2 FC3G 015S026 100m 8.29 | 9.00e3 1 32452 %: 1 1 0 - i min 8.00 10.00 12.00 1802-PFHxS-1 FC3G 015S026 7.33 100^ 1.09e4 A 42294 / \ %- 0-^ 7.00 rr min 8.00 I.,> oo 1802-PFHxS-2 FC3G 015S026 7.33 7.71 e3~l 29812 %" 0- J 7.00 8.00 13C4-PFBA FC3G_015S026 100- 5.19 | 2.55e4 S 101806 %- 13C2-PFHxA FC3G_015S026 100n 6.34 4.71e4 '. 207673 13C5-PFNA FC3G_015S026 100- 7.49 7.03e4 291680 13C2-PFDA FC3G_015S026 100- 7.99 r 8.21 e4 I 309631 %" 13C2-PFDoA FC3G_015S026 9.18 I" 1.30e5 ' 558747 13C2-PFOUEA FC3G_015S026 100 7.38 2.68e4 "105369 I : 5.00 6.00 7.00 ... min 5.00 6.00 7.00 7.00 8.00 8.00 10.00 12.00 8.00 10.00 12.00 7.00 8.00 PV by LEH 15-Jan-13, SV by AP 16-Jan-13. NOTE: OPR Conen. & LOD units = ng/mL, Sample and Lab BLK Conen. & LOD units = ng/L. Page 112 of 307 www.axysanalytical.com Quantify Sample Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\lnst_G\PFC.PRO\FC\FC3G_015-B.qld Last Altered: Tuesday, January 15, 2013 14:23:27 Pacific Standard Time Printed: Wednesday, January 16, 2013 11:54:43 Pacific Standard Time ID: L18989-4,R, Name: FC3G_015S026 Description: 1,WG42428,15/4000uL Date: 15-Jan-2013 Time: 02:29:12 # Name 1 PFBA 2 PFPeA 3 PFHxA 4 PFHpA 5 PFOA-1 6 PFOA-2 7 PFN.A 8 PFDA 9 PFUnA 10 PFDoA 11 PFBS-1 12 PFBS-2 13 PFHxS-1 14 PFHxS-2 15 PFHxS-3 16 PFOS-1 17 PFOS-2 18 PFOSA 19 13C2-PFOA 20 13C4-PFOA 21 13C4-PFOS-1 22 13C4-PFOS-2 23 1802-PFHxS-1 24 1802-PFHxS-2 25 13C4-PFBA 26 13C2-PFHxA 27 13C5-PFNA 28 13C2-PFDA 29 13C2-PFDoA 30 13C2-PFOEA IS# Trace RT 25 212.99>168.98 5.21 26 262.98 >218.... 5.95 26 312.97> 268.98 6.34 26 362.97> 318.98 6.68 19 412.97> 368.98 7.09 19 412.97> 168.80 7.09 27 462.96 >418.... 7.49 28 512.96 >468.... 7.99 28 562.96 > 518.... 8.58 29 612.95 >5 6 8.... 9.15 23 298.94> 79.96 6.47 24 298.94 > 98.95 6.46 23 398.84 > 79.96 7.33 24 398.84> 98.96 7.33 23 398.84> 118.70 7.29 21 498.93> 79.96 8.29 22 498.93> 98.96 8.29 21 498 > 78 9.99 20 414.97 > 369.... 7.09 416.97 >371.9 7.09 30 503 > 79.96 8.29 30 503 > 98.96 8.29 30 402.9>84 7.33 30 402.9>103 7.33 30 216.99>171.98 5.19 30 314.97>269.98 6.34 30 467.96>422.97 7.49 30 514.96 >469.96 7.99 30 614.95 >569.... 9.18 458.98 >393.98 7.38 Area 75433 20797 131494 130827 527976 143802 6143 3761 723 550 62254 32705 12365 6701 4412 122132 80650 9756 202327 79861 11925 8998 10879 7713 25472 47122 70268 82085 130386 26812 IS Area 25472 47122 47122 47122 202327 202327 70268 82085 82085 130386 10879 7713 10879 7713 10879 11925 8998 11925 79861 26812 26812 26812 26812 26812 26812 26812 26812 26812 ng/L 75.544 17.018 66.144 64.724 210.014 236.561 2.008 0.168 165.632 162.367 35.453 34.967 42.374 387.878 379.699 20.349 72.348 26.780 41.444 39.359 45.747 43.793 21.821 20.410 27.045 25.112 25.476 21.980 LOD 0.1974 0.0530 0.5982 0.8081 0.1619 0.2850 0.2090 0.1810 0.7392 0.1151 0.0593 0.0561 0.0529 %Rec 89.1 98.9 102.1 96.9 112.6 107.8 80.6 75.4 99.9 92.8 94.1 97.4 S/N 541 176 1049 751 0 0 0 28 10 6 2348 3466 395 0 91 2394 755 1320 0 0 399 519 0 714 90 597 1446 1289 1575 0 Noise 550 525 523 648 0 0 0 456 305 318 120 43 113 0 170 135 347 28 0 0 107 63 0 42 1130 348 202 240 355 0 Height 297473 92157 549250 487207 1929210 520304 21047 12635 3066 1830 282535 149571 44497 23087 15362 322936 261911 37047 800235 318382 42833 32452 42294 29812 101806 207673 291680 309631 558747 105369 IS Height Sample size 101806 0.4432 207673 0.4432 207673 0.4432 207673 0.4432 800235 0.4432 800235 0.4432 291680 0.4432 309631 0.4432 309631 0,4432 558747 0.4432 42294 0.4432 29812 0.4432 42294 0.4432 29812 0.4432 42294 0.4432 42833 0.4432 32452 0.4432 42833 0.4432 318382 0.4432 0.4432 105369 0.4432 105369 0.4432 105369 0.4432 105369 0.4432 105369 0.4432 105369 0.4432 105369 0.4432 105369 0.4432 105369 0.4432 0.4432 Factor2 Detection... 1.0 bb 1.0 MM 1.0 MM 1.0 bb 1.0 MM 1.0 MM 1.0 bb 1.0 MM 1.0 bbl 1.0 MMi 1.0 MM 1.0 MM 1.0 MM 1.0 bb 1.0 bb 1.0 MM 1.0 bb 1.0 MM 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 bb PV by LEH 15-Jan-13, SV by AP 16-Jan-13. NOTE: OPR Conen. & LOD units = ng/mL, Sample and Lab BLK Conen. & LOD units = ng/L. Page 113 of 307 www.axysanalytical.com Quantify Sample Report MassLynx 4.1 SCN627 Dataset: G :\M a s s Iy nx \in s t_G \P F C .P R O \F C \F C 3 G _ 015-B.qld Last Altered: Tuesday, January 15, 2013 14:23:27 Pacific Standard Time Printed: Wednesday, January 16, 2013 11:54:43 Pacific Standard Time ID: L18989-5,R, Name: FC3G_015S027 Description: 1,WG42428,15/4000uL Date: 15-Jan-2013 Time: 02:46:05 PFBA FC3G_015S027 _ 5.23 100 7.42e3 i 27832 %- ; .4.03 \ 5:99 PFPeA FC3G_015S027 1lu0u0- 2.55-922e3-K| 9388 I %- 5.47; 5.28 ; 5.00 6.00 7.00 5.00 6.00 7.00 PFNA FC3G 015S027 PFDA FC3G_015S027 7.99 100_i r2 .2 2 e 3 I 7143 %- M 12.11 PFHxS-1 FC3G_015S027 100- 7.29 I 2.90e2 ill 1114 %" 6.71 7.00 8.00 8.00 10.00 12.00 PFHxS-2 FC3G_015S027 7 29 100^ jk 1,34e2 1 420 %- 6.86 0-^ 7.00 8.00 PFHxA FC3G 015S027 PFHpA FC3G_015S027 100- 6.68 3.83e3 ' 5.54. 12577 '* ri i-i -4.03 .; ' .'. . .. 5.00 6.00 7.00 PFUnA FC3G_015S027 100- 8.61 5.74e2 11.57 1964 ! 12.29 \ \%- . 9Af 5 f\)fA V\ AhA/ v V PFDoA FC3GJ315S027 100- _ 9.15 2.19e2 - 7.75 , 9 7 %- h 26 8.00 10.00 12.00 PFHxS-3 FC3G 015S027 8.00 10.00 12.00 PFOS-1 FC3GJ315S027 8.23 1001 f":2.80e3 l 6581 %- 9.78 11.78 8.00 10.00 12.00 PFOA-1 FC3G_015S027 1001 ' _ 7.09 1 9.21 e3 133913 %- . - PFOA-2 FC3G__015S027 100- 7.09 2.75e3 \ 9536 %~ 7.00 8.00 7.00 8.00 PFBS-1 FC3G_015S027 100n 6.47 _ 1.24e3 5.00 6.00 7.00 PFBS-2 FC3G_015S027 100 6.44 6 .44 4.50e2 14.50e2 1817 fl 1817 %- 1 4.13 5.64 0 A-V _ 5.00 6.00 7.00 PFOS-2 FC3G__015S027 100 _ 8.29 1.27e3 3679 %- : 11.57 J 2 ;11 -- ;-r min 8.00 10.00 12.00 PFOSA FC3GJ)15S027 100- 10.02 1 .7 5 e ll 141 %- 10.23 9.57 11.75 8.00 10.00 12.00 PV by LEH 15-Jan-13, SV by AP 16-Jan-13. NOTE: OPR Conen. & LOD units = ng/mL, Sample and Lab BLK Conen. & LOD units = ng/L. Page 114 of 307 www.axysanalytical.com Quantify Sample Report MassLynx 4.1 SCN627 Dataset G:\Masslynx\Inst_G\PFC.PRO\FC\FC3G_015-B.qld Last Altered: Tuesday, January 15, 2013 14:23:27 Pacific Standard Time Printed: Wednesday, January 16, 2013 11:54:43 Pacific Standard Time ID: L18989-5,R, Name: FC3G_015S027 Description: 1,WG42428,15/4000uL Date: 15-Jan-2013 Time: 02:46:05 oo ooI 1 ! 1 13C2-PFOA FC3G_015S027 ~7n 100- Z35e5 P 946377 j\ 7.00 -n min 13C4-PFOA FC3G 015S027 100^ JT9.05e4 1359917 %- 0- J 7.00 , mjn 8.00 13C4-PFOS-1 FC3G 015S027 100n - %- I 1.28e4 8 48840 1 il 0- . . min 8.00 10.00 12.00 13C4-PFOS-2 FC3G 015S027 ; 1.02e4 : 38856 %' ;; 08.00 10.00 min 12.00 1802-PFHxS-1 FC3G 015S027 100- I*1.15e4 M 42976 0- / 7.00 '. . -T min 8.00 1802-PFHxS-2 FC3G_015S027 100- 7.29 7.70e3 129346 o7.00 8.00 13C4-PFBA FC3G 015S027 5.19 F 2.90e4 \\ 115917 % ! ; 4.03 ! 0 5.00 6.00 n min 7.00 13C2-PFHxA FC3G 015S027 100- 6.33 5.81 e4 254795 l %- _________ : X min 5.00 6.00 7.00 13C5-PFNA FC3G_015S027 7.49 100n 7.99e4 A 321201 ! \ %- o7.00 8.00 13C2-PFDA FC3G_015S027- 100 7.99 | 9.13e4 I 335839 %- 8.00 10.00 12.00 13C2-PFDoA FC3G_015S027 100- 9.18 I- 1.28e5 1 580059 %- ill,! 0-Wr 8.00 10.00 12.00 13C2-PFOUEA FC3G 015S027 PV by LEH 15-Jan-13, SV by AP 16-Jan-13. NOTE: OPR Conen. & LOD units = ng/mL, Sample and Lab BLK Conen. & LOD units = ng/L. Page 115 of 307 www.axysanalytical.com Quantify Sample Report MassLynx 4.1 SCN627 Dataset: G:\MasslynxMnst_G\PFC.PRO\FC\FC3G_015-B.qld Last Altered: Tuesday, January 15, 2013 14:23:27 Pacific Standard Time Printed: Wednesday, January 16, 2013 11:54:43 Pacific Standard Time ID: L18989-5,R, Name: FC3G_015S027 Description: 1,WG42428,15/4000uL Date: 15-Jan-2013 Time: 02:46:05 # Name 1 PFBA 2 PFPeA 3 PFHxA 4 PFHpA 5 PFOA-1 6 PFOA-2 7 PFNA 8 PFDA 9 PFUnA 10 PFDoA 11 PFBS-1 12 PFBS-2 13 PFHxS-1 14 PFHxS-2 15 PFHxS-3 16 PFOS-1 17 PFOS-2 18 PFOSA . 19 13C2-PFOA 20 13C4-PFOA 21 13C4-PFOS-1 22 13C4-PFOS-2 23 1802-PFHxS-1 24 1802-PFHxS-2 25 13C4-PFBA 26 13C2-PFHxA 27 13C5-PFNA 28 13C2-PFDA 29 13C2-PFDoA 30 13C2-PFOUEA IS# Trace RT 25 212.99>168.98 5.23 26 262.98 >218.... 5.92 26 312.97> 268.98 6.34 26 362.97> 318.98 6.68 19 412.97> 368.98 7.09 19 412.97> 168.80 7.09 27 462.96 >418.... 7.49. 28 512.96 >468.... 7.99 28 562.96 > 518.... 8.61 29 612.95 > 568.... 9.15 23 298.94> 79.96 6.47 24 298.94 > 98.95 6.44 23 398.84 > 79.96 7.29 24 398.84> 98.96 7.29 23 398.84> 118.70 21 498.93> 79.96 8.23 22 498.93> 98.96 8.29 21 498 > 78 10.02 20 414.97 > 369.... 7.09 416.97 >3 7 1.9 7.09 30 503 > 79.96 30 503 > 98.96 8.29 8.29 30 402.9>84 7.29 30 402.9>103 7.29 30 216.99>171.98 5.19 30 314.97>269.98 6.33 30 467.96>422,97 7.49 30 514.96 >469.96 7.99 30 614.95 > 569.... 9.18 458.98 >393.98 7.38 Area 7420 2524 5503 3833 9211 2750 2312 2223 574 219 1244 450 290 134 2803 1268 17 235029 90468 12804 10179 11461 7702 28967 58055 79867 91321 127744 29955 IS Area 28967 58055 58055 58055 235029 235029 79867 91321 91321 127744 11461 7702 11461 7702 11461 12804 10179 12804 90468 29955 29955 29955 29955 29955 29955 29955 29955 29955 ng/L 6.583 1.707 1.867 1.478 2.754 3.776 0.409 1.967 1.653 0.524 7.656 5.110 0.158 79.692 32.587 42.786 42.808 46.335 42.042 23.859 24.177 29.554 26.861 23.998 26.379 LOD 0.1613 0.1573 0.1623 0.2527 0.3480 0.6170 0.7047 0.2656 0.1427 0.0853 0.1136 0.1093 0.0477 %Rec S/N 32 18 42 30 90 218 19 30 7 5 23 25 0 0 91.3 112.0 98.1 98.1 106.2 96.4 82.0 83.1 101.6 92.4 82.5 108.8 26 23 6 0 0 509 370 222 179 283 587 1099 686 786 1659 Noise 881 532 529 418 378 44 520 236 278 255 211 74 0 0 40 252 162 25 0 0 96 105 194 164 409 434 292 490 738 69 Height 27832 9388 21956 12577 33913 9536 9959 7143 1964 1197 4881 1817 1114 420 6581 3679 141 946377 359917 48840 38856 42976 29346 115917 254795 321201 335839 580059 113941 IS Height Sample size 115917 0.4126 254795 0.4126 254795 0.4126 254795 0.4126 946377 946377 0.4126 0.4126 321201 0.4126 335839 335839 580059 0.4126 0.4126 0.4126 42976 29346 0.4126 0.4126 42976 29346 0.4126 0.4126 42976 0.4126 48840 38856 0.4126 0.4126 48840 359917 0.4126 0.4126 0.4126 113941 113941 0.4126 0.4126 113941 0.4126 113941 0.4126 113941 113941 113941 0.4126 0.4126 0.4126 113941 113941 0.4126 0.4126 0.4126 Factor2 Detection... 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 bb 1.0 MM 1.0 MM 1.0 MMI 1.0 MMI 1.0 bbl 1.0 MM 1.0 MM 1.0 bbi 1.0 MM 1.0 1.0 bb 1.0 bb 1.0 MM 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 bb PV by LEH 15-Jan-13, SV by AP 16-Jan-13. NOTE: OPR Conen. & LOD units = ng/mL, Sample and Lab BLK Conen. & LOD units = ng/L. _ _. C Page 116 of 307 www.axysanalytical.com Quantify Sample Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\lnst_G\PFC.PRO\FC\FC3G_015-B.qld Last Altered: Tuesday, January 15, 2013 14:23:27 Pacific Standard Time Printed: Wednesday, January 16, 2013 11:54:43 Pacific Standard Time ID: L18989-6,R, Name: FC3G_015S028 Description: 1,WG42428,15/4000uL Date: 15-Jan-2013 Time: 03:03:06 PFBA FC3G_015S028 loo- if" 7.c70e3 |1 27663 I 4.05 5-71 - min 5.00 6.00 7.00 PFPeA FC3G 015S028 100- 2.84e3*|i 11493 j i 5.69 ; \ %" , , \6.51 5.21.... j y . -. . 0- rr min 5.00 6.00 7.00 PFHxA FC3G 015S028 100%- 6.22e3 25945 I \ . 5.62 5.82 05.00 6.00 7.00 PFNA FC3G_015S028 100n 7.49 2.98e3 A 103711 ; : %- 7.00 'l 7.00 8.00 PFDA FC3G_015S028 7 00 100" r2 -1 0 e 3 I 7898 %~ || M 8-70 11.75. 12.35 8.00 10,00 12.00 PFUnA FC3G 015S028 8.55 10 " ^ 3.56e^2 1196 L 1 OTr 8.00 10.00 12.00 PFHxS-1 FC3G 015S028 PFHxS-2 FC3G 015S028 PFHxS-3 FC3G_015S028 100- 7.29 fT6.43e1 / \ 319 %-- 6.90 / i 7.78 7.00 8.00 PFHpA FC3G 015S028 100%~ 3.85e3 13766 549... i\ A' . ` - ...' 0 - .......................... .-I 5.00 6.00 7.00 PFDoA FC3G_015S028 100- 12.29 11.87 i R T V -T ; <h ------ : r 8.00 10.00 12.00 PFOS-1 FC3G__015S028 100- _ 8.29 2.72e3 ` 5838 %- P . 1 0 e 5 11.36 1220 8.00 10.00 12.00 PFOA-1 FC3G 015S028 100- A 1.07e4 : 39726 %- 0 - --------1....... min 7.00 8.00 PFBS-1 FC3GJD15S028 100- 6.51 1.39e3 6346 c. 7 i 5.86 4.63 . ^ : 5.00 6.00 7.00 PFOS-2 FC3G__015S028 100- 8.29 1.70e3 4942 %- Q-- 8.00 11.31 11.99 10.00 12.00 PFOA-2 FC3G_015S028 100-i - %H _ 7.09 : 2.71e3 9793 07.00 8.00 PFBS-2 FC3G_015S028 100- 6.46 _ 2.95e2 1201 I %4.07 5.00 6.00 7.00 PFOSA FC3G_015S028 100- 9.84 _ 3.94e1 I 195 I 8.05 9.15 11.93 lM l J L J U , 8.00 10.00 12.00 PV by LEH 15-Jan-13, SV by AP 16-Jan~13. NOTE: OPR Conen. & LOD units = ng/mL, Sample and Lab BLK Conen. & LOD units = ng/L. Page 117 of 307 www.axysanalytical.com Quantify Sample Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\lnst_G\PFC.PRO\FC\FC3G_015-B.qld Last Altered: Tuesday, January 15, 2013 14:23:27 Pacific Standard Time Printed: Wednesday, January 16, 2013 11:54:43 Pacific Standard Time ID: L18989-6.R, Name: FC3G_015S028 Description: 1,WG42428,15/4000uL Date: 15-Jan-2013 Time: 03:03:06 13C2-PFOA FC3G 015S028 100 J 7.09 f 2.50e5 976616 %-: 13C4-PFOA FC3G 015S028 ioo-q 7.09 J~ 9.46e4 371850 %" i 0" 7.00 8.00 0^ 7.00 8.00 13C4-PFBA FC3GJ515S028 100" 13C2-PFHxA FC3G_015S028 100- 6.34 6.14e4 ;; 279226 h %- 5.00 6.00 7.00 13C4-PFOS-1 FC3G_015S028 100- _ 8.29 1.45e4 56898 %' 13C4-PFOS-2 FC3G__015S028 100- _ 8.29 1.07e4 39210 1802-PFHxS-1 FC3G_015S028 100- 7.29 H"l.19e4 44883 %- 1802 -PFHxS-2 FC3G 015S028 100 _ 7.29 8 .8 5 e 3 M l32703 8:00 10.00 12.00 13C5-PFNA FC3G 015S028 8.00 10.00 12.00 13C2-PFDA FC3G_015S028 7 99 100^ f 1.04e5 I! 372514 *1 Q -- | s,-- 8.00 10.00 12.00 7.00 8.00 13C2-PFDoA FC3GJD15S028 100- 9.15 T 1.45e5 I 654894 : .. 8.00 10.00 12.00 7.00 8.00 13C2-PFOUEA FC3G 015S028 PV by LEH 15-Jan-13, SV byAP 16-Jan-13. NOTE: OPR Conen. & LOD units = ng/mL, Sample and Lab BLK Conen. & LOD units = ng/L. Page 118 of 307 www.axysanalytical.com Quantify Sample Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\lnst_G\PFC.PRO\FC\FC3G_015-B.qld Last Altered: Tuesday, January 15, 2013 14:23:27 Pacific Standard Time Printed: Wednesday, January 16, 2013 11:54:43 Pacific Standard Time ID: L18989-6,R, Name: FC3G_015S028 Description: 1,WG42428,15/4000uL Date: 15-Jan-2013 Time: 03:03:06 # Name 1 PFBA 2 PFPeA 3 PFHxA 4 PFHpA 5 PFOA-1 6 PFOA-2 7 PFNA 8 PFDA 9 PFUnA 10 PFDoA 11 PFBS-1 12 PFBS-2 13 PFHxS-1 14 PFHxS-2 15 PFHxS-3 16 PFOS-1 17 PFOS-2 18 PFOSA 19 13C2-PFOA 20 13C4-PFOA 21 13C4-PFOS-1 22 13C4-PFOS-2 23 1802~PFHxS~1 24 1802-PFHxS-2 25 13C4-PFBA 26 13C2-PFHxA 27 13C5-PFNA 28 13C2-PFDA 29 13C2-PFDoA 30 13C2-PFOUEA IS# Trace RT 25 212.99>168.98 5.19 26 262.98 >218.... 5.95 26 312.97> 268.98 6.34 26 362.97> 318.98 6.68 19 412.97> 368.98 7.09 19 412.97> 168.80 7.09 27 462.96 >418.... 7.49 28 512.96 >468.... 7.99 28 562.96 >518.... 8.55 29 612.95 > 568.... 9.27 23 298.94> 79.96 6.51 24 298.94 > 98.95 6.46 23 398.84 > 79.96 7.33 24 398.84> 98.96 7.29 23 398.84> 118.70 7.29 21 498.93> 79.96 8.29 22 498.93> 98.96 8.29 21 498 > 78 9.84 20 414.97 > 369.... 7.09 416.97 > 371.9 7.09 30 503 > 79.96 8.29 30 503 > 98.96 8.29 30 402.9>84 7.29 30 402.9>103 7.29 30 216.99>171.98 5.15 30 314,97>269.98 6.34 30 467.96>422.97 7.49 30 514.96 >469.96 7.99 30 614.95 > 569.... 9.15 458.98 >393.98 7.38 Area 7699 2840 6216 3854 10682 2709 2976 2099 356 582 1388 295 336 145 64 2715 1699 39 249649 94634 14515 10736 11858 8847 30269 61399 93584 104451 144829 33564 IS Area 30269 61399 61399 61399 249649 249649 93584 104451 104451 144829 11858 8847 11858 8847 11858 14515 10736 14515 94634 33564 33564 33564 33564 33564 33564 33564 33564 33564 ng/L 5.422 1.513 1.686 1.159 2.543 2.883 0.41 G 1.854 0.513 0.398 5.264 5.521 0.161 67.157 28.289 35.923 33.442 35.506 35.769 18.466 18.938 25.649 22.755 20.151 24.529 LOD 0.0676 0.2633 0.0019 0.1191 0.4650 0.2274 0.1527 0.2528 0.6219 0.0876 0.1036 0.0915 0.0590 %Rec 92.7 117.2 99.2 92.4 98.1 98.8 76.5 78.5 106.3 94.3 83.5 122.0 S/N 39 12 34 21 83 233 13 19 3 5 25 8 14 9 10 37 30 12 0 183 485 627 0 410 82 770 784 695 1211 0 Noise 709 941 763 669 480 42 826 419 402 319 254 154 84 52 31 159 166 16 0 2037 117 63 0 80 1301 362 482 536 541 0 Height 27663 11493 25945 13766 39726 9793 10371 7898 1196 1531 6346 1201 1207 478 319 5838 4942 195 976616 371850 56898 39210 44883 32703 106773 279226 378118 372514 654894 128491 IS Height Sample size 106773 0.4972 279226 0.4972 279226 0.4972 279226 0.4972 976616 0.4972 976616 0.4972 378118 0.4972 372514 0.4972 372514 0.4972 654894 0.4972 44883 0,4972 32703 0.4972 44883 0.4972 32703 0.4972 44883 0.4972 56898 0.4972 39210 0.4972 56898 0.4972 371850 0.4972 0.4972 128491 0.4972 128491 0.4972 128491 0.4972 128491 0.4972 128491 0.4972 128491 0.4972 128491 0.4972 128491 0.4972 128491 0.4972 0.4972 Factor2 Detection... 1.0 bb 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 bb 1.0 MM 1.0 MMI 1.0 MMI 1.0 MMI 1.0 MM 1.0 MM 1.0 MMI 1.0 MM 1.0 MMI 1.0 MM 1.0 MM 1.0 MM 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 MM 1.0 bb 1.0 bb 1.0 bb 1.0 bb PV by LEH 15-Jan-13, SV by AP 16-Jan-13. NOTE: OPR Conen. & LOD units = ng/mL, Sample and Lab BLK Conen. & LOD units = ng/L. Page 119 of 307 www.axysanalytical.com Quantify Sample Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\lnst_G\PFC.PRO\FC\FC3G_015-B.qld Last Altered: Tuesday, January 15, 2013 14:23:27 Pacific Standard Time Printed: Wednesday, January 16, 2013 11:54:43 Pacific Standard Time ID: L18989-7,R, Name: FC3G_015S029 Description: 1,WG42428,15/4000uL Date: 15-Jan-2013 Time: 03:19:59 PFBA FC3G 015S029 PFPeA FC3G_015S029 PFNA FC3G 015S029 PFHxS-1 FC3G_015S029 100- 7.33 9.53e2 ?: 4291 ! 6.71 7.00 8.00 5.00 6.00 7.00 PFDA FC3G_015S029 100- 7.99 f 1.91e3 I 6562 ' %- 10-171 1 . 9 0 ^ 20 8.00 10.00 12.00 PFHxS-2 FC3G_015S029 100- _ 7.29 l 4.05e2 !\ 1041 -6.63 7.00 8.00 PFHxA FC3G 015S029 100- 6.36 1.22e4 j 57546 i! %~ 5,82j \ 0- 5.00 6 .0 0 '7 .0 0 PFUnA FC3G_ 015S029 100- _ 8.61 5:32e2 1721 %- tl 12.32 8.00 10.00 12.00 PFHxS-3 FC3G_015S029 100- 7.33 2.08c2 / 961 1 %6.76 7.00 8.00 PFHpA FC3G 015S029 100--| 6.73 1 .4 2 e 4 l 56116 1 %: i i 5.69 L"1 o: -.........::........-....-................. mmii.nn 5.00 6.00 7.00 PFOA-1 FC3G 015S029 100n 7.09 3.00e4 116292 %- uo: -- -.-.-.-.-.-.-.-.-.-.--.-.-.-.-.-.-.-.-.-..--.----t--t- mminin 7.00 8.00 PFOA-2 FC3G 015S029 100-] 7.09 A 8.32e3 f \ 30848 %: u0-J ------------------- -----------, 7.00 8.00 PFDoA FC3G_015S029 1007.53 11.90 11.42 ii , \ /! %'-Vi V, 8.00 10.00 12.00 PFOS-1 FC3GJ515S029 100- 8.29 3.06e3 7032 %- 11.13 . 8.00 10.00 12.00 PFBS-1 FC3G 015S029 100- 6.51 1 .7 0 e 3 l 7855 ii % - ;; 5.645.80J \ 0 - - min 5.00 6.00 7.00 PFBS-2 FC3G_015S029 100 6 47 6.47 5 .3 9 e 2 Pl 5.39e2 2458 ;! 2458 %- 5.115.25" 7.07 o- _ i= 4 . 5.00 6.00 7.00 PFOS-2 FC3G_015S029 100 8.29 ; 1.76k3 i 4714 %- , 1 0 ^ 11.36 1223 0- 8.00 10.00 12.00 PFOSA FC3G 015S029 100- 9.ii i I%~ 8.61 [l I l 11.72 lVj\!\k A a 8.00 J 1o!oO ' 12l00 PV by LEH 15-Jan-13, SV by AP 16-Jan-13. NOTE: OPR Conen. & LOD units = ng/ml, Sample and Lab BLK Conen. & LOD units = ng/L. __ 10 Page 120 of 307 www.axysanalytical.com Quantify Sample Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\lnst_G\PFC.PRO\FC\FC3G_015-B.qld Last Altered: Tuesday, January 15, 2013 14:23:27 Pacific Standard Time Printed: Wednesday, January 16, 2013 11:54:43 Pacific Standard Time ID: L18989-7,R, Name: FC3G_015S029 Description: 1,WG42428,15/4000uL Date: 15-Jan-2013 Time: 03:19:59 13C2-PFOA FC3G_015S029 100- *7 n IT 1.97e5 f '782413 --- i -- 7.00 ---------- min 8.00 13C 4 -P F O A FC3G 015S029 100- A ' 8.07e4 > .310817 %- 0^ ......... r ? " - -- min 7.00 8.00 13C4-PFOS-1 FC3G 015S029 100- '" l.10e4 42623 %~ 1 0 - ,r min 8.00 10.00 12.00 13C4-PFOS-2 FC3G 015S029 100- j8.63e3 ; 34121 %~ : > 0 -------- T - ~ - min 8.00 10.00 12.00 1802-PFHxS-l FC3G 015S029 100- 8.89631 33564 h %_ : 0 - ____ ;. 7.00 \ 8.00 1802-PFHxS-2 FG3G,,015S029 100" 7.33 7.22e3~| 30184 | | %-- - -- 7.00 8.00 13C4-PFBA FC3G_015S029 100- 5.19 i~2.23e4 1 93809 %- i\ ^ 4j L (F min 5.00 6.00 7.00 1302-PFHxA FC3G 015S029 100- 6.34 4.84e4 217636 1 %~ 1 jj|^ tr min 5.00 6.00 7.00 13C5-PFNA FC3G_015S029 100-, 7.49 7.17e4 \ ' 293826 j \ %- o-: 7.00 8.00 13C2-PFDA FC3G_015S029 100- _ 7.99 i 7.92e4 : 292645 %- 8.00 10.00 12.00 13C2-PFDoA FC3G_015S029 100--I 9.15 1.11e5 501386 13C2-PFOUEA FC3G__015S029 100-- 7.38 2.76e4 ~~h 104469 \s\ %- -- : mm 8.00 10.00 12.00 7.00 8.00 PV by LEH 15-Jan-13, SV by AP 16~Jan-13. NOTE: OPR Conen. & LOD units = ng/mL, Sample and Lab BLK Conen. & LOD units = ng/L. Page 121 of 307 www.axysanalytical.com Quantify Sample Report MassLynx 4.1 SCN627 Dataset: G:\MasslynxMnst_G\PFC.PRO\FC\FC3G_015-B.qld Last Altered: Tuesday, January 15, 2013 14:23:27 Pacific Standard Time Printed: Wednesday, January 16, 2013 11:54:43 Pacific Standard Time ID: L18989-7,R, Name: FC3G_015S029 Description: 1,WG42428,15/4000uL Date: 15-Jan-2013 Time: 03:19:59 # Name 1 PFBA 2 PFPeA 3 PFHxA 4 PFHpA 5 PFOA-1 6 PFOA-2 7 PFNA 8 PFDA 9 PFUnA 10 PFDoA 11 PFBS-1 12 PFBS-2 13 PFHxS-1 14 PFHxS-2 15 PFHxS-3 16 PFOS-1 17 PFOS-2 18 PFOSA 19 13C2-PFOA 20 13C4-PFOA 21 13C4-PFOS-1 22 13C4-PFOS-2 23 1802-PFHxS-1 24 1802-PFHxS-2 25 13C4-PFBA 26 13C2-PFHXA 27 13C5-PFNA 28 13C2-PFDA 29 13C2~PFDoA 30 13C2-PFOUEA IS# Trace RT 25 212.99>168.98 5.23 26 262.98 > 218.... 5.97 26 312.97> 268.98 6.36 26 362.97> 318.98 6.73 19 412.97> 368.98 7.09 19 412.97> 168.80 7.09 27 462.96 >4 1 8.... 7.49 28 512.96 >468.... 7.99 28 562.96 > 518.... 8.61 29 612.95 >5 6 8.... 9.18 23 298.94> 79.96 6.51 24 298.94 >98.95 6.47 23 398.84 > 79.96 7.33 24 398.84> 98.96 7.29 23 398.84> 118.70 7.33 21 498.93> 79.96 8.29 22 498 .93> 98.96 8.29 21 498 > 78 20 414.97 > 369.... 7.09 416.97 >3 7 1.9 7.09 30 503 > 79.96 8.35 30 503 >9 8 .9 6 8.29 30 402.9>84 30 402.9>103 7.33 7.33 30 216.99>171.98 5.19 30 314.97>269.98 6.34 30 467.96>422.97 7.49 30 514.96 >469,96 7.99 30 614.95 > 569.... 9,15 458.98 >393.98 7.38 Area 8723 4398 12179 14199 30040 8322 1970 1905 532 284 1704 539 953 405 208 3057 1757 197313 80701 11020 8633 8889 7222 22346 48407 71694 79226 111157 27586 IS Area 22346 48407 48407 48407 197313 197313 71694 79226 79226 111157 8889 7222 8889 7222 8889 11020 8633 11020 80701 27586 27586 27586 27586 27586 27586 27586 27586 27586 ng/L 8.610 3.083 4.926 6.014 10.506 12.273 0.306 3.833 1.941 1.953 1.848 1.626 8.437 7.314 62.838 24.354 33.499 33.030 32.696 35.865 16.745 18.340 24.136 21.200 18.998 20.353 LOD 0.1846 0.1657 0.2019 0.1270 0.1710 0.5264 0.1377 0.1539 0.5530 0.1558 0.0526 0.0578 0.1019 %Rec S/N 44 30 110 46 304 444 18 33 5 2 35 30 136 0 20 32 61 86.0 100.0 91.7 90.4 89.5 98.1 68.7 75.3 99.1 87.0 78.0 100.2 0 0 600 196 710 772 101 419 1490 1074 666 0 Noise 780 525 523 1212 382 69 437 200 353 445 227 82 32 0 47 220 78 16 0 0 71 174 47 39 932 519 197 272 752 0 Height 34477 15975 57546 56116 116292 30848 7914 6562 1721 840 7855 2458 4291 1041 961 7032 4714 782413 310817 42623 34121 33564 30184 93809 217636 293826 292645 501386 104469 IS Height Sample size 93809 217636 0.4925 0.4925 217636 0.4925 217636 782413 0.4925 0.4925 782413 0.4925 293826 0.4925 292645 0.4925 292645 501386 0.4925 0.4925 33564 30184 0.4925 0.4925 33564 30184 0.4925 0.4925 33564 0.4925 42623 0.4925 34121 0.4925 42623 310817 0.4925 0.4925 104469 0.4925 0.4925 104469 0.4925 104469 104469 0.4925 0.4925 104469 104469 0.4925 0.4925 104469 0.4925 104469 0.4925 104469 0.4925 0.4925 Factor2 Detection... 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 bb 1.0 bb 1,0 MM 1.0 MM! 1.0 MM! 1.0 MMI 1.0 MM 1.0 MM 1.0 bb 1.0 bb 1.0 MM 1.0 MM 1.0 MM 1.0 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 MM 1.0 bb 1.0 bb 1.0 bb 1.0 bb PV by LEH 15-Jan-13, SV by AP 16-Jan-13. NOTE: OPR Conen. & LOD units = ng/mL, Sample and Lab BLK Conen. & LOD units = ng/L. Page 122 of 307 www.axysanalytical.com Quantify Sample Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\lnst_G\PFC.PRO\FC\FC3G_015-B.qld Last Altered: Tuesday, January 15, 2013 14:23:27 Pacific Standard Time Printed: Wednesday, January 16, 2013 11:54:43 Pacific Standard Time ID: L18989-8,R, Name: FC3G_015S030 Description: 1,WG42428,15/4000uL Date: 15-Jan-2013 Time: 03:37:00 PFBA FC3G_015S030 100 523 6.62e3 25681 5.00 6.00 7.00 PFPeA FC3G_015S030 100- 5.92 _ 2.93e3 5 92 8918 : ' 2.93e3 %- 5.38 . i . T> 05,00 6.00 7.00 PFNA FC3G 015S030 PFDA FC3GJ315S030 .n n . 7.99 2.21e3 7132 ; : 10.65 12 23 : -r 8.00 10.00 12.00 PFHxS-1 FC3G 015S030 1 0 0 - 7.33 3.06e2 A 1000 / i %6.71 / J 0- l \ F min 8.00 PFHxS-2 FC3GJ315S030 100 7.29;1.08e2;286 ^6.66 A 111 % 0 7.00 8.00 PFHxA FC3G 015S030 PFUnA FC3G_015S030 100-, n 8.61 4.55e2 1 1260 %- 12.23 f, < J\ 0-Ft 3-n-p-.-. -.p -r-.-ri-i-:- r 8.00 10.00 12.00 PFHxS-3 FC3G__015S030 100_7.29;1.25e2;404 7.00 8.00 PFHpA FC3G_015S030 100n 6.73 3.23e3 ' 5.58.. 10476 ; % 4.03 ' 5.00 6.00 7.00 PFDoA FC3G_015S030 100- 12.20 ;7 .5 3 11.45 ' MU,, ,, 11.07.. % . 8.55/, 1u^ V l 8.00 10.00 12.00 PFOS-1 FC3G_015SG30 100- _ 8.23 =2.72e3 i 5933 % \\ 10.801220 !...; j .. _ . " .-...Y/ 8.00 10.00 12.00 PFOA-1 FC3G__015S030 100- 7.09 \ 1.02 e4 i 38004 % 7.00 PFBS-1 FC3G 015S030 PFOS-2 FC3G 015S030 100- 8.29 \ 1.52e3 ;; 4709 %: i! ' ! , 10-56 11.45 8.00 10.00 12.00 PFOA-2 FC3G_015S030 100- 7.09 A 2.43e3 , 9817 %- 7.00 8.00 PFBS-2 FC3G_015S030 100- 6.46 2.64e2~| 1497 I %- 4.13 5.71 ,7.21 5.00 6.00 7.00 PFOSA FC3G_015S030 100-J 9.84 5.06e11 236 I %- 9.18 10.47 11.99 _ - A n . K/rt - ~r~h~7 m i n 8.00 10.00 12.00 PV by LEH 15-Jan-13, SV by AP 16-Jan-13. NOTE: OPR Concn. & LOD units = ng/mL, Sample and Lab BLK Concn. & LOD units = ng/L. Page 123 of 307 www.axysanalytical.com Quantify Sample Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\lnst_G\PFC.PRO\FC\FC3G_015-B.qld Last Altered: Tuesday, January 15, 2013 14:23:27 Pacific Standard Time Printed: Wednesday, January 16, 2013 11:54:43 Pacific Standard Time ID: L18989-8,R, Name: FC3G_015S030 Description: 1,WG42428,15/4000uL Date: 15-Jan-2013 Time: 03:37:00 13C2-PFOA FC3G 015S030 100- 7.09 2.09e5 858383 %- 13C4-PFOA FC3G 015S030 100- 7.09 f 7.9 6e4 M 326778 0J i 7.00 f 8.00 J '^! 7.00 8.00 13C4-PFBA FC3G_015S030 100- 5.21 i f 2.47e4 %- 13C2-PFHxA FC3G 015S030 100- 6.34 5.31e4 [ 240482 M j! %" 13C4-PFOS-1 FC3G 015S030 100- 8.35 i~ 1.22e4 46431 %- 0- ' J min 8.00 10.00 12.00 13C4-PFOS-2 FC3G 015S030 100- 8.29 f 9.95e3 ., 36608 % - ij 0 - ....... min 8.00 10.00 12.00 1802-PFHxS-1 FC3G 015S030 100^ 7.33 1.03e4 li 39962 j %: O-' ____ 7.00 r r r min 8.00 1802-PFHxS-2 FC3G_015S030 100"i . 7.29 I>.42e3 I I 29224 %: 07.00 8.00 13C5-PFNA FC3G 015S030 100- 7.49 7.73e4 319227 %- 13C2-PFDA FC3G_015S030 100-n f 7.99 8.23e4 1 294697 %- 13C2-PFDoA FC3G 015S030 13C2-PFOUEA FC3GJ515S030 100-- 2 7.38 .8 0 e 4 l 1109286 i 1 1 so> o, CoO ( 5.00 6.00 7.00 -- --.............. L -- min 5.00 6.00 7.00 min o~i 7.00 8.00 8.00 10.00 12.00 7.00 8.00 PV by LEH 15-Jan-13, SV byAP 16-Jan-13. NOTE: OPR Conen. & LOD units = ng/mL, Sample and Lab BLK Conen. & LOD units = ng/L. Page 124 of 307 www.axysanalytical.com Quantify Sample Report MassLynx 4.1 SCN627 Dataset G:\Masslynx\lnst_G\PFC.PRO\FC\FC3G_015-B.qld Last Altered: Tuesday, January 15, 2013 14:23:27 Pacific Standard Time Printed: Wednesday, January 16, 2013 11:54:43 Pacific Standard Time ID: L18989-8,R, Name: FC3G_015S030 Description: 1,WG42428,15/4000uL Date: 15-Jan-2013 Time: 03:37:00 # Name 1 PFBA 2 PFPeA 3 PFHxA 4 PFHpA 5 PFOA-1 6 PFOA-2 7 PFNA 8 PFDA 9 PFUnA 10 PFDoA 11 PFBS-1 12 PFBS-2 13 PFHxS-1 14 PFHxS-2 15 PFHxS-3 16 PFOS-1 17 PFOS-2 18 PFOSA 19 13C2-PFOA 20 13C4-PFOA 21 13C4-PFOS-1 22 13C4-PFOS-2 23 1802-PFHxS-1 24 1802-PFHxS-2 25 13C4-PFBA 26 13C2~PFHxA 27 13C5-PFNA 28 13G2-PFDA 29 13C2-PFDoA 30 13C2-PFOUEA IS# Trace RT Area IS Area ng/L 25 212.99>168.98 5.23 6624 24691 5.912 26 262.98 > 218.... 5.92 2926 53115 1.872 26 312.97> 268.98 6.34 5224 53115 1.673 26 362.97> 318.98 6.73 3233 53115 1.153 19 412.97> 368.98 7.09 10220 209046 3.071 19 412.97> 168.80 7.09 2433 209046 3.209 27 462.96 >418.... 7.49 1917 77334 0.243 28 512.96 >4 6 8.... 7.99 2211 82276 28 562.96 >5 1 8.... 8.61 455 82276 29 612.95 > 568.... 9.21 246 125798 23 2 98 .94> 79.96 6.49 1137 10252 . 1.744 24 298.94 > 98.95 6.46 264 7424 0.607 23 398.84 > 79.96 7.33 306 10252 24 398.84> 98.96 7.29 108 7424 0.339 23 398.84> 118.70 7.29 125 10252 0.563 21 498.93> 79.96 8.23 22 498.93> 98.96 8.29 2716 1523 12197 9952 6.678 5.480 21 498 > 78 9.84 51 12197 0.198 20 414.97 > 3 6 9 .... 7.09 209046 79648 68.815 416.97 > 3 7 1 .9 7.09 79648 24.522 30 503 >. 79.96 8.35 12197 27972 37.305 30 503 > 98.96 8.29 9952 27972 38.309 30 402.9>84 7.33 10252 27972 37.939 30 402.9>103 7.29 7424 27972 37.092 30 216.99>171.98 5.21 24691 27972 18.615 30 314.97>269.98 6.34 53115 27972 20.247 30 467.96>422.97 7.49 77334 27972 26.194 30 514.96 >469.96 7.99 82276 27972 22.151 30 614.95 > 5 6 9 .... 9.18 125798 27972 21.631 458.98 >393.98 7.38 27972 21.054 LOD 0.1861 0.7569 0.1190 0.3535 0.1278 0.1886 0.2183 0.3527 0.2239 0.0792 0.0894 0.0913 0.1015 %Rec 92.3 98.6 100.0 102.7 101.7 99.5 74.9 81.4 105.4 89.1 87.0 101.6 S/N 52 14 31 19 124 51 28 26 4 4 26 61 16 1 10 61 52 23 584 576 578 496 0 0 167 314 1048 682 810 622 Noise 494 619 747 554 306 194 322 270 314 194 158 24 63 251 40 97 91 10 1469 568 80 74 0 0 609 765 305 432 692 176 Height 25681 8918 23013 10476 38004 9817 8993 7132 1260 743 4034 1497 1000 286 404 5933 4709 236 858383 326778 46431 36608 39962 29224 101954 240482 319227 294697 560015 109286 IS Height Sample size .101954 0.4827 240482 0.4827 240482 0.4827 240482 0.4827 858383 0.4827 858383 0.4827 319227 0.4827 294697 0.4827 294697 0.4827 560015 0.4827 39962 0.4827 29224 0.4827 39962 0.4827 29224 0.4827 39962 0.4827 46431 0.4827 36608 0.4827 46431 0.4827 326778 0.4827 0.4827 109286 0.4827 109286 0.4827 109286 0.4827 109286 0.4827 109286 0.4827 109286 0.4827 109286 0.4827 109286 0.4827 109286 0.4827 0.4827 Factor2 Detection... 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 bb 1.0 MM 1.0 MMI 1.0 MMI 1.0 MMI 1.0 MM 1.0 MM 1.0 MMI 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 MM 1.0 bb 1.0 bb 1.0 bb 1.0 bb PV by LEH 15-Jan-13, SV by AP 16-Jan-13. NOTE: OPR Conen. & LOD units = ng/mL, Sample and Lab BLK Conen. & LOD units = ng/L. Page 125 of 307 www.axysanalytical.com Quantify Sample Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\lnst_G\PFC.PRO\FC\FC3G_015-B.qId Last Altered: Tuesday, January 15, 2013 14:23:27 Pacific Standard Time Printed: Wednesday, January 16, 2013 11:54:43 Pacific Standard Time ID: L18989-9,R, Name: FC3G_015S031 Description: 1,WG42428,15/4000uL Date: 15-Jan-2013 Time: 03:54:01 PFBA FC3G 015S031 PFPeA FC3G_015S031 100- 5.95 1.84e3 ij 9847 I 5.43 j [ 6 -42 . 4.07 PFHxA FC3GJ315S031 100" 6.33 4.86e3 19900 : PFNA FC3G 015S031 PFHxS-1 FC3G_015S031 100-- 7.33 2.58e2 _ I 1114 I I % 6 63 7.00 8.00 5.00 6.00 7.00 PFDA FC3G_015S031 -inn 7 -99 1G n r 1.66e3 I 5969 %8.64 11.36 12.14 8.00 10.00 12.00 PFHxS-2 FC3G_015S031 m n 7-29 11)0 f~ 1 .1 5 e2 11 448 %16.63 7.00 l::.n 8.00 5.00 6.00 7.00 PFUnA FC3G_015S031 100- _ 8.58 3.92e2 I 2115 12.02 %- 11.39^ 19.421 \J s \h Jm M M f 0^ 8.00 10.00 12.00 PFHxS-3 FC3G 015S031 7.29 1.10e2 578 :6.63 7.72 8.02 7.00 8.00 PFHpA FC3G_015S031 100- 6.68 3.40e3 A 10828 ; l 5.391 7.;-. . '\ PFOA-1 FC3G_015S031 100- 7.09 \ 8.83e3 \ 34248 %- PFOA-2 FC3G__015S031 100 _ 7.09 , 1.99e3 .* 7345 5.00 6.00 7.00 7.00 8.00 7.00 8.00 PFDoA FC3G_015S031 100 10.86 11-81 9.57), J /I 48.11 m nil 8.00 10.00 12.00 PFBS-1 FC3GJJ15S031 100n 6.53 _ 1.04e3 I 4429 ;l % 5.80 i \ 5 -67 . : 0-^~" - ... min 5.00 6.00 7.00 PFBS-2 FC3GJJ15S031 100- 6.44 3.14e2_|r - 6 44 1490 i !3.14e2 1 1490 f t 6-97 5.775.90 ft f A! : ' T?rWfr11 JJ} 5.00 6.00 7.00 PFOS-1 FC3G_015S031 100n _ 8,23 2.39e3 i 5048 %- o -il 8.00 l l .31/11.90 min 10.00 12.00 PFOS-2 FC3G_015S031 100-. 8.29 f 1.34e3 I 3545 Vo 11.01 11.90 8.00 10.00 12.00 PFOSA FC3GJ315S031 inn 9-81 100~l 2 . 2 3 e ll 137 | 9.81 %- IT2.23e1 | i 137 12.20 .7 .6 4 0- 8.00 MiS 10.681 M ZZJi 10.00 12.00 PV by LEH 15-Jan-13, SV by AP 16-Jan-13. NOTE: OPR Conen. & LOD units = ng/mL, Sample and Lab BLK Conen. & LOD units = ng/L. Page 126 of 307 www.axysanalytical.com Quantify Sample Report MassLynx 4.1 SCN627 Dataset: G:\MasslynxMnst_G\PFC.PRO\FC\FC3G_015-B.qld Last Altered: Tuesday, January 15, 2013 14:23:27 Pacific Standard Time Printed: Wednesday, January 16, 2013 11:54:43 Pacific Standard Time ID: L18989-9,R, Name: FC3G_015S031 Description: 1,WG42428,15/4000uL Date: 15-Jan-2013 Time: 03:54:01 13C2-PFOA FC3G_015S031 100-1 7r JT.2.37e5 943761 i A'A. 7.00 i 8.00 13C4-PFBA FC3G__015S031 100 5.19 2.61e4 113811 13C4-PFOA FC3G 015S031 100~I C 8.4 4 e4 331164 %- 0- J V , t t min 7.00 8.00 ooi 1 13C4-PFOS-1 FC3G 015S031 fl.2 6 e 4 1 48642 %-- li o - min 8.00 10.00 12.00 13C4-PFOS-2 FC3G 015S031 oo J.J 1.01e4 37938 %- ! J 08.00 10.00 min 12.00 1802-PFHxS-l FC3G 015S031 100- A 1.03e4 40930 %~ 0 L-r. 7.00 . , , min 8.00 1802-PFHxS-2 FC3G_015S031 100n 7.29 JT8.44e3 34133 %- 07.00 13C2-PFHxA FC3G 015S031 13C5-PFNA FC3G_015S031 100 7.49 8.18e4 A 329750 j j % 13C2-PFDA FC3G_015S031 100- 7.99 8.63e4 i 323998 %- 13C2-PFDoA FC3G 015S031 13C2-PFOUEA FC3GJ315S031 100-- 7.38 3.11e4 A ,115425/ \ %- 5.00 6.00 7.00 7.00 8,00 -M , 8,00 10.00 12.00 7.00 8.00 PV by LEH 15-Jan-13, SV by AP 16~Jan~13. NOTE: OPR Conen. & LOD units = ng/mL, Sample and Lab BLK Conen. & LOD units = ng/L. Page 127 of 307 www.axysanalytical.com Quantify Sample Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\lnst_G\PFC.PRO\FC\FC3G_015-B.qld Last Altered: Tuesday, January 15, 2013 14:23:27 Pacific Standard Time Printed: Wednesday, January 16, 2013 11:54:43 Pacific Standard Time ID: L18989-9,R, Name: FC3G_015S031 Description: 1,WG42428,15/4000uL Date: 15-Jan-2013 Time: 03:54:01 # Name 1 PFBA 2 PFPeA 3 PFHxA 4 PFHpA 5 PFOA-1 6 PFOA-2 7 PFNA 8 PFDA 9 PFUnA 10 PFDoA 11 PFBS-1 12 PFBS-2 13 PFHxS-1 14 PFHxS-2 15 PFHxS-3 16 PFOS-1 17 PFOS-2 18 PFOSA 19 13C2-PFOA 20 13C4-PFOA 21 13C4-PFOS-1 22 13C4-PFOS-2 23 1802-PFHxS-1 24 1802-PFHXS-2 25 13C4-PFBA 26 13C2-PFHxA 27 13C5-PFNA 28 13C2-PFDA 29 13C2-PFDoA 30 13C2-PFOUEA . IS# Trace RT 25 212.99>168.98 5.19 26 262.98 > 218.... 5.95 26 312.97> 268.98 6.33 26 362.97> 318.98 6.68 19 412.97> 368.98 7.09 19 412.97> 168.80 7.09 27 462.96 > 418.... 7.49 28 512.96 > 468.... 7.99 28 562.96 >5 1 8.... 8.58 29 612.95 > 568.... 9.21 23 298.94> 79.96 6.53 24 298.94 > 98.95 6.44 23 398.84 > 79.96 7.33 24 398.84> 98.96 7.29 23 398.84> 118.70 7.29 21 498 .93> 79.96 8.23 22 498.93> 98.96 8.29 21 498 > 78 9.81 20 414.97 > 369.... 7,09 416.97 >371.9 7.09 30 503 > 79.96 8.29 30 503 > 98.96 8.29 30 402.9>84 7.29 30 402.9>103 7.29 30 216.99>171.98 5.19 30 314.97>269.98 6.33 30 467.96>422.97 7.49 30 514.96 >469.96 7.99 30 614.95 >569.... 9.15 458.98 >393.98 7.38 Area 6366 1844 4862 3400 8826 1988 1767 1660 392 351 1036 314 258 115 110 2387 1343 22 236915 84418 12591 10093 10307 8442 26130 57166 81775 86250 128225 31072 IS Area 26130 57166 57166 57166 236915 236915 81775 86250 86250 128225 10307 8442 10307 8442 10307 12591 10093 12591 84418 31072 31072 31072 31072 31072 31072 31072 31072 31072 ng/L 6.094 1.211 1.580 1.283 2.526 2.536 0.185 1.676 0.760 0.352 0.472 6.297 5.371 0.165 84.103 29.707 39.626 39.979 39.246 43.400 20.270 22.422 28.500 23.893 22.687 26.731 LOD 0.1386 0.0794 0.1347 0.2825 0.3662 0.9936 0.3201 0.1810 0.1105 0.0566 0.1310 0.0122 %Rec 98.7 104.6 93.0 93.8 92.1 101.8 71.3 78.9 100.3 84.1 79.8 112.9 S/N 61 20 46 13 160 77 10 23 9 3 73 16 17 10 13 48 23 14 0 0 438 331 0 143 223 434 840 1281 584 6593 Noise 391 488 428 855 214 95 773 254 231 290 61 95 64 45 45 105 155 10 0 0 111 114 0 239 511 572 393 253 917 18 Height 23712 9847 19900 10828 34248 7345 7941 5969 2115 998 4429 1490 1114 448 578 5048 3545 137 943761 331164 48642 37938 40930 34133 113811 248070 329750 323998 535252 115425 IS Height Sample size 113811 0.4224 248070 0.4224 248070 248070 943761 0.4224 0.4224 0.4224 943761 329750 0.4224 0.4224 323998 0.4224 323998 0.4224 535252 0.4224 40930 0.4224 34133 40930 34133 0.4224 0.4224 0.4224 40930 0.4224 48642 37938 48642 331164 0.4224 0.4224 0.4224 0.4224 115425 115425 0.4224 0.4224 0.4224 115425 115425 0.4224 0.4224 115425 115425 115425 0.4224 0.4224 0.4224 115425 115425 0.4224 0.4224 0.4224 Factor2 Detection... 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 bb 1.0 bb 1.0 MMl 1.0 MMl 1.0 MMl 1.0 MM 1-0 MM 1.0 MMl 1.0 MM 1.0 MM 1.0 MM 1.0 bb 1.0 MM 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 bb PV by LEH 15-Jan-13, SV by AP 16-Jan-13. NOTE: OPR Conen. & LOD units = ng/mL, Sample and Lab BLK Conen. & LOD units = ng/L. Page 128 of 307 www.axysanalytical.com Quantify Sample Report MassLynx 4.1 SCN627 Dataset: G :\M a s s ly n x \In s tJ 3 \P F C P R O \F C \F C 3 G _ 0 1 5-B.qld Last Altered: Tuesday, January 15, 2013 14:23:27 Pacific Standard Time Printed: Wednesday, January 16, 2013 11:54:43 Pacific Standard Time ID: L18989-10.R, Name: FC3G_015S032 Description: 1,WG42428,15/4000uL Date: 15-Jan-2013 Time: 04:10:54 PFBA FC3G 015S032 PFPeA FC3G_015S032 100- 5.99 1.77e3~| 8584 1 % 5.64 Bk 6.53 4.03 A W u PFNA FC3G 015S032 PFHxS-1 FC3G 015S032 5.00 6.00 7.00 PFDA FC3G015S032 100- 7.99 . 1.61 e3 L 4522 %- 04 8.00 10.8312.17 \ \/ a/ 10.00 12.00 PFHxS-2 FC3G 015S032 PFHxA FC3GJ)15S032 100- 6.36 _ 5 .03e3l 23492 1 %- 4.29 5.62 5.00 6.00 7.00 PFUnA FC3G__015S032 100- 8.64 r 2.59e2 I 1194 11.57 H Vu 1 i.j, / V 8.00 10.00 12.00 PFHxS-3 FC3G__015S032 100--1.74.83e32 A 645 M %- 7.00 8.00 PFHpA FC3G 015S032 100- 6.73 3 .6 0 e 3 l 13411 560 %- 4 11 0- ; \ -j \ - v-. rrrrrr min 5.00 6.00 7.00 PFOA-1 FC3GJ015S032 1001 7.09 \ 9.26e3 \ 33791 _ o7.00 8.00 PFDoA FC3G_015S032 100n :7.64 %- 9.12 jj~2.90e2 I 1641 19.99 M/' U / tM w v tjtt min 8.00 10.00 12,00 PFBS-1 FC3G__015S032 100n 6.51 8.27e2~j 4555 %5-49 5.92 I 5.00 6.00 7.00 PFOS-1 FC3GJ015S032 100n 8.11 ) 1.93e3 B 4282 %- - 1 1 `6\ J | 1*63 o 4 ^ir,~77^'Tp:,TTjmTj-TT min. 8.00 10.00 12,00 PFOS-2 FC3G,,015S032 100- 8.29 / 1.03e3 l \ 2493 %- 10.98..11.60 J...... - - - - - 8.00 10.00 12.00 PFOA-2 FC3G_015S032 100- 7.14 2.27e3 7439 %- 7.00 8.00 PFBS-2 FC3G_015S032 4or* 100_i %- 6-46 3.66e2 } 1437 I I , 5.54 646 3.66e2 1437 0^ 5.00 6.00 7.00 PFOSA FC3G 015S032 PV by LEH 15-Jan-13, SV by AP 16-Jan-13. NOTE: OPR Conen. & LOD units = ng/mL, Sample and Lab BLK Conen. & LOD units = ng/L. Page 129 of 307 www.axysanalytical.com Quantify Sample Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\lnst_G\PFC.PRO\FC\FC3G_015-B.qld Last Altered: Tuesday, January 15, 2013 14:23:27 Pacific Standard Time Printed: Wednesday, January 16, 2013 11:54:43 Pacific Standard Time ID: L18989-10,R, Name: FC3G_015S032 Description: 1,WG42428,15/4000uL Date: 15-Jan-2013 Time: 04:10:54 L..ooI 13C2-PFOA FC3G 015S032 7.14 i 2.28e5 864524 %" /\ 0- 7.00 n min 8.00 13C4-PFOA FC3G 015S032 100- 7.09 .' 8.41e4 / \321633 0 - . J . v . ,, . . . . > min 7.00 8.00 13C4-PFOS-1 FC3G_015S032 1 - 8.29 f 1.15e4 44849 i 0- 8.00 - ............. min 10.00 12.00 ooi ! 13C4-PFOS-2 FC3G 015S032 8.29 9.79e3 39133 %- 0" V min 8.00 10.00 12.00 1802-PFHxS-1 FC3G 015S032 100n 7.33 1.03e4~l : 41733 j \ % 0 / 'x - , min 7.00 8.00 1802-PFHxS-2 FC3G 015S032 1 00 - 7.33 7.25e3_l 29186 j f %- 0/ 7.00 8.00 13C4-PFBA FC3GJD15S032 100 5.24 f 2.55e4 ' 102603 13C2-PFHxA FC3G_015S032 100- 6.36 5.70e4 264391 %- 13C5-PFNA FC3GJM5S032 100- 7.49 7.80e4 . 312972 %- 13C2-PFDA FC3G__015S032 100- 7.99 8.44e4 312649 %- 13C2-PFDoA FC3GJJ15S032 100 9.12 1.31e5 566555 13C2-PFOUEA FC3G 015S032 `-- 5.00 6.00 7.00 7.00 8.00 8.00 10.00 12.00 8.00 10.00 12.00 PV by LEH 15-Jan-13, SV by AP 16-Jan-13. NOTE: OPR Conen. & LOD units = ng/mL, Sample and Lab BLK Conen. & LOD units = ng/L. Page 130 of 307 www.axysanalytical.com Quantify Sample Report MassLynx 4,1 SCN627 Dataset: G:\Masslynx\lnst_G\PFC.PRO\FC\FC3G_015-B.qld Last Altered: Tuesday, January 15, 2013 14:23:27 Pacific Standard Time Printed: Wednesday, January 16, 2013 11:54:43 Pacific Standard Time ID: L18989-10,R, Name: FC3G_015S032 Description: 1,WG42428,15/4000uL Date: 15-Jan-2013 Time: 04:10:54 # Name 1 PFBA 2 PFPeA 3 PFHxA 4 PFHpA 5 PFOA-1 6 PFOA-2 7 PFNA 8 PFDA 9 PFUnA 10 PFDoA 11 PFBS-1 12 PFBS-2 13 PFHxS-1 14 PFHxS-2 15 PFHxS-3 16 PFOS-1 17 PFOS-2 18 PFOSA 19 13C2-PFOA 20 13C4-PFOA 21 13C4-PFOS-1 22 13C4-PFOS-2 23 1802-PFHxS-1 24 1802-PFHXS-2 25 13C4-PFBA 26 1302-PFHxA 27 13C5-PFNA 28 13C2-PFDA 29 13C2-PFDoA 30 13C2-PFOUEA IS# Trace RT 25 212.99>168.98 5.26 26 262.98 >2 1 8.... 5.99 26 312.97> 268.98 6.36 26 362.97> 318.98 6.73 19 412.97> 368.98 7.09 19 412.97> 168.80 7.14 27 462.96 >4 1 8.... 7.49 28 512.96 > 468.... 7.99 28 562.96 >518.... 8.64 29 612.95 > 568.... 9.12 23 298 .94> 79.96 6.51 24 298.94 > 98.95 6.46 23 398.84 > 79.96 7.33 24 398.84> 98.96 7.33 23 398.84> 118.70 7.33 21 498.93> 79.96 8.11 22 498.93> 98.96 8.29 21 498 > 78 9.96 20 414.97 > 369.... 7.14 416.97 > 3 7 1 .9 7.09 30 503 > 79.96 8.29 30 503 > 98-96 8.29 30 402.9>84 7.33 30 402.9>103 7.33 30 216.99>171.98 5.24 30 314.97>269.98 6.36 30 467.96>422.97 7.49 30 514.96 >469.96 7.99 30 614.95 > 569.... 9.12 458.98 >393.98 7.38 Area 6630 1775 5029 3600 9264 2266 1580 1613 259 290 827 366 380 161 148 1933 1032 39 227953 84129 11516 9792 10312 7248 25523 57025 78040 84412 131125 29314 IS Area 25523 57025 57025 57025 227953 227953 78040 84412 84412 131125 10312 7248 10312 7248 10312 11516 9792 11516 84129 29314 29314 29314 29314 29314 29314 29314 29314 29314 ng/L 6.144 1.096 1.561 1.292 2.647 2.895 0.137 0.991 1.216 0.672 0.832 5.104 3.889 0.195 76.422 27.862 36.155 38.693 39.171 37.174 19.752 22.313 27.133 23.328 23.145 23.734 LOD 0.3035 0.0538 0.2051 0.1276 0.3897 0.6282 0.0647 0.4844 0.1638 0.0356 0.0656 0.1543 0.0197 %Rec 95.3 104.2 90.1 96.5 97.7 92.7 73.9 83.4 101.5 87.2 86.6 106.5 S/N 45 9 35 25 84 0 18 11 6 3 33 22 45 9 18 26 30 5 0 0 878 316 201 1840 130 502 2432 1047 516 3608 Noise 544 918 669 527 401 0 379 405 194 505 136 66 32 65 35 163 84 57 0 0 51 124 208 16 787 526 129 299 1099 31 Height 24363 8584 23492 13411 33791 7439 6647 4522 1194 1641 4555 1437 1448 556 645 4282 2493 266 864524 321633 44849 39133 41733 29186 102603 264391 312972 312649 566555 110562 IS Height Sam ple size 102603 0.4488 264391 0.4488 264391 0.4488 264391 0.4488 864524 864524 0.4488 0.4488 312972 0.4488 312649 0-4488 312649 0.4488 566555 41733 29186 41733 29186 0.4488 0.4488 0.4488 0.4488 0.4488 41733 0.4488 44849 39133 44849 0.4488 0.4488 0.4488 321633 0.4488 0.4488 110562 0.4488 110562 0.4488 110562 0.4488 110562 110562 0.4488 0.4488 110562 110562 0.4488 0.4488 110562 110562 0.4488 0.4488 0.4488 Factor2 Detection... 1.0 MM 1.0 MM 1.0 bb 1.0 MM 1.0 bb 1.0 bb 1.0 bb 1.0 MMi 1.0 MMI 1.0 MMI 1.0 MM 1.0 MM 1.0 bbl 1.0 MM 1.0 MM 1.0 MM 1-0 MM 1.0 MM 1-0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 MM 1.0 bb 1.0 bb 1.0 bb 1.0 bb PV by LEH 15-Jan-13, SV by AP 16-Jan-13. NOTE: OPR Conen. & LOD units = ng/mL, Sample and Lab BLK Conen. & LOD units = ng/L. _ _. 10 Page 131 of 307 www.axysanalytical.com Quantify Sample Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\lnst_G\PFC.PRO\FC\FC2G_455-B.qld Last Altered: Tuesday, January 08, 2013 12:06:04 Pacific Standard Time Printed: Thursday, January 10, 2013 12:48:05 Pacific Standard Time ID: L18989-11,, Name: FC2G_455S021 Description: 1,WG42273,15/4000uL Date: 18-Dec-2012 Time: 23:49:24 PFBA FC2G 455S021 100^ 5.14 5.28e3 ; 16846 %- 14.03 ; : 5 67 6.60 V/ o J ...................... min 5.00 6.00 7.00 PFPeA FC2G 455S021 100- 5.98 1.60e3 1 7734 1 5.54 M 6.56 %~ CO < 05.00 6.00 7.00 PFNA FC2G 455S021 PFDA FC2G_455S021 7.99 100- {Tl.05e3 2885 %- , 1 10.59 11.66 ' J||Y 0J .|.................... 8.00 10.00 12.00 PFHxS-1 FC2G 455S021 PFHxS-2 FC2G 455S021 PFHxA FC2G__455S021 100-, 6.36 4.08e3 . 18266 %. 5.14 5.98 oJ min 5.00 6.00 7.00 PFHpA FC2G 455S021 100 6.69 3.74e3 A 14307 ;i 5.54. 5.82 ; I ' A \ 4.42 0 5.00 6.00 7.00 PFOA-1 FC2G 455S021 PFUnA FC2G 455S021 100-1 - 7.81 / 11.96 \ . 1 j 11.63 jj j %- i f f 0 10.92. i l l ! \j M /v r 0 rrp-rrTI-lTI-TTl-rTTTTTTTTTT min 8.00 10.00 12.00 PFDoA FC2G 455S021 1007.53 12.11 11.16 % M H 0 min 8.00 10.00 12.00 PFBS-1 FC2G_j455S021 100- 6.51 7 .7 7 e 2 l 3351 i %5.09 5.63 1 y -- 05.00 6.00 7.00 PFHxS-3 FC2G_455S021 100- 7 2 5 PFOS-1 FC2G 455S021 PFOS-2 FC2G,,455S021 100- 8.17 ii 1.11e3 M 2934 i 7.00 . 8.14 8.00 984 10.6812.02 min 08.00 10.00 12.00 PFOA-2 FC2G 455S021 100- 7.06 IT2.53e3 I 9445 %~ 0- / '. 7.00 8.00 PFBS-2 FC2G455S021 100- 6.43 1375 !f3 .4 2 e 2 1 1375 4.51 5.78 am A:4 -- -u 5.00 6.00 7.00 PFOSA FC2G_455S021 9.90 100- 7.33e1 394 %9-45 I 10.56 / .11.m78in 8.00 10.00 12.00 PV by LHE 08-Jan-13, SV by AP 10-Jan-13. NOTE: OPR Conen. & LOD units = ng/mL, Sample and Lab BLK Conen. & LOD units = ng/L. Page 132 of 307 www.axysanalytical.com Quantify Sample Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\lnst_G\PFC.PRO\FC\FC2G_455-B.qld Last Altered: Tuesday, January 08, 2013 12:06:04 Pacific Standard Time Printed: Thursday, January 10, 2013 12:48:05 Pacific Standard Time ID: L18989-11,, Name: FC2G_455S021 Description: 1,WG42273,15/4000uL Date: 18-Dec-2012 Time: 23:49:24 13C2-PFOA FC2G_455S021 100 7.11 ST 1.40c* IS545473 %- 13C4-PFOA FC2G_455S021 100- _ 7.06 I 5.33e4 1216320 %" 8.00 13C4-PFBA FC2G_455S021 . . . 5.13 100 A 1.96e4 ! ; 63771 4.08 y f" . 5.00 6.00 7.00 7.00 8.00 1302-PFHxA FC2G 455S021 13C4-PFOS-1 FC2G 455S021 100 m 8.23 f 8.69e3 - .: 31909 %: 0- v. 13C5-PFNA FC2G 455S021 13C4-PFOS-2 FC2G 455S021 8.23 100n I- 5.96e3 M 21540 %- 1 1 1 o- im , . 8.00 10.00 12.00 13C2-PFDA FC2G_455S021 100- 7.93 f 6.04e4 I 220834 iI ' 0 L- S..: . _ 8.00 10.00 12.00 1802-PFHxS-1 FC2G_455S021 lOOq 7.30 7.44e3 28034 %: ; 7.00 8.00 13C2-PFDoA FC2G_455S021 100n 9.03 r 8.39e4 I 379533 "Zo A om 8.00 10.00 12.00 1802-PFHxS-2 FC2G_455S021 1001 7.25 ,4.93e3 ' 17283 %- ' 7.00 8.00 13C2-PFOUEA FC2G 455S021 PV by LHE 08-Jan-13, SV by AP 10-Jan-13. NOTE: OPR Conen. & LOD units = ng/mL, Sample and Lab BLK Conen. & LOD units = ng/L. Page 133 of 307 www.axysanalytical.com Quantify Sample Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\lnst_G\PFC.PRO\FC\FC2G_455-B.qld Last Altered: Tuesday, January 08, 2013 12:06:04 Pacific Standard Time Printed: Thursday, January 10, 2013 12:48:05 Pacific Standard Time ID: L18989-11,, Name: FC2G_455S021 Description: 1,WG42273,15/4000uL Date: 18-Dec-2012 Time: 23:49:24 # Name 1 PFBA 2 PFPeA 3 PFHxA 4 PFHpA 5 PFOA-1 6 PFOA-2 7 PFNA 8 PFDA 9 PFUnA 10 PFDoA 11 PFBS-1 12 PFBS-2 13 PFHxS-1 14 PFHxS-2 15 PFHxS-3 16 PFOS-1 17 PFOS-2 18 PFOSA 19 13C2-PFOA 20 13C4-PFOA 21 13C4-PFOS-1 22 13C4-PFOS-2 23 1802-PFHxS-1 24 1802-PFHxS-2 25 13C4-PFBA 26 13C2-PFHxA 27 13C5-PFNA 28 13C2-PFDA 29 13C2-PFDoA 30 13C2-PFOUEA IS# Trace RT 25 212.99>168.98 5.14 26 262.98 > 218.... 5.98 26 312.97> 268.98 6.36 26 362.97> 318.98 6.69 19 412.97> 368.98 7.06 19 412.97> 168.80 7.06 27 462.96 >4 1 8.... 7.49 28 512.96 > 468.... 7.99 28 562.96 >518.... 29 612.95 > 568.... 9.09 23 298.94> 79.96 6.51 24 298.94 > 98.95 6.43 23 398.84 > 79.96 7.25 24 398.84> 98.96 7.30 23 398.84> 118.70 21 498.93> 79.96 8.05 22 498.93> 98.96 8.17 21 498 > 78 9.90 20 414.97 > 369.... 7.11 416.97 > 3 7 1.9 7.06 30 503 > 79.96 8.23 30 503 > 98.96 8.23 30 402.9>84 7.30 30 402.9>103 7.25 30 216.99>171.98 5.13 30 314.97>269.98 6.36 30 467.96>422.97 7.46 30 514.96 >469.96 7.93 30 614.95 > 5 6 9 .... 9.03 458.98 >393.98 7.39 Area 5281 1604 4084 3741 7921 2532 1410 1046 257 777 342 317 89 1979 1105 73 140272 53303 8688 5963 7443 4935 19614 40492 55256 60446 83853 22131 IS Area 19614 40492 40492 40492 140272 140272 55256 60446 60446 83853 7443 4935 7443 4935 7443 8688 5963 8688 53303 22131 22131 22131 22131 22131 22131 22131 22131 22131 ng/L 6.01A 1.590 2.095 2.105 3.622 4.678 0.612 2.139 2.812 0.590 1.123 7.446 6.935 0.484 62.456 25.731 31.738 29.407 31.313 29.141 16.763 16.075 22.104 19.973 18.860 22.705 LOD 0.2806 0.5156 0.0466 0.6832 0.0911 0.1380 0.1423 0.9525 0.6038 0.2849 0.4032 0.2043 0.9204 0.0990 0.6355 0.1063 0.1753 0.1940 0.0288 %Rec S/N 39 13 33 10 158 458 14 9 3 21 16 17 18 86.5 106.9 87.9 81.4 86.7 80.7 69.6 66.8 91.8 82.9 78.3 113.1 25 31 11 0 0 444 90 928 0 67 584 0 324 343 2363 Noise 437 583 549 1454 202 21 394 338 294 278 156 87 78 24 60 206 93 37 0 0 72 240 30 0 955 344 0 681 1107 36 Height 16846 7734 18266 14307 31761 9445 5487 2885 810 3351 1375 1315 432 5201 2934 394 545473 216320 31909 21540 28034 17283 63771 200743 238690 220834 379533 85232 IS Height Sample size 63771 0.4983 200743 0.4983 200743 0.4983 200743 545473 0.4983 0.4983 545473 0.4983 238690 0.4983 220834 0.4983 220834 0.4983 379533 0.4983 28034 17283 28034 0.4983 0.4983 0.4983 17283 0.4983 28034 0.4983 31909 0.4983 21540 31909 0.4983 0.4983 216320 0.4983 0.4983 85232 0.4983 85232 85232 0.4983 0.4983 85232 0.4983 85232 85232 0.4983 0.4983 85232 0.4983 85232 85232 0.4983 0.4983 0.4983 Factor2 Detection... 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 bb 1.0 MM 1.0 MM 1.0 MM! 1.0 1.0 MM! 1.0 bb 1.0 bb 1.0 MM 1.0 MM 1.0 1.0 MM 1.0 bb 1.0 MM 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 MM 1.0 bb 1.0 bb 1.0 bb 1.0 bb PV by LHE 08-Jan-13, SV by AP 10-Jan-13. NOTE: OPR Conen. & LOD units = ng/mL, Sample and Lab BLK Conen. & LOD units = ng/L. Page 134 of 307 www.axysanalytical.com Quantify Sample Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\lnst_G\PFC.PRO\FC\FC2G_455-B.qld Last Altered: Tuesday, January 08, 2013 12:06:04 Pacific Standard Time Printed: Thursday, January 10, 2013 12:48:05 Pacific Standard Time ID: WG42273-103,,DUP Name: FC2G_455S022 Description: 1,WG42273,15/4000uL Date: 19-Dec-2012 Time: 00:07:06 PFBA FC2G_455S022 ico- 4 .8c3 e 3 ft 15838 4.08 v 6.04 min 5.00 6.00 7.00 PFPeA FC2G 455S022 100n 2.07e3 10647 % - 5.69 j i 6.47 4.03 i j f ^ 0- ' ' 111....... min 5.00 6.00 7.00 PFHxA FC2G 455S022 100" %-_ 4 .3 7 e 3 l 19377 ;s j; 5-33 5i8o j \ 0~ ... 5.00 6.00 7.00 PFNA FC2G 455S022 PFDA FC2G 455S022 PFUnA FC2G__455S022 100- 12.41 12.14^ . 11-13 7 7/ \7 \M 8.00 10.00 12.00 PFHxS-1 FC2G 455S022 PFHxS-2 FC2G_455S022 100- 7.25 f\ 1.16e2 /436 %- 7.00 8.00 PFHxS-3 FC2G_455S022 100- 7.25 7.46 / :A J 7.00 \7 .7 8 8.00 PFHpA FC2G 455S022 100-, 3.31 e3 h 12705 /; %- 5.37 - - : . 4.79 ' \ 0- .'-V min 5.00 6.00 7.00 PFOA-1 FC2G 455S022 100- 'i 8.31 e3 ; \ 29822 %~ ... j . . . . 0- - 7.00 8.00 PFDoA FC2G_455S022 100- 9.03 3.43e2 1955 11.99 18.05 l I 9.93 IA 7 0-Vr 8.00 10.00 f v\ 2.00 PFBS-1 FC2G_455S022 100- 6-43 ^ 6.43 7.30e2" | " 7.30e2 3007 I 3007 ' 5.83 5.59 ft 5.05. 5.00 6.00 7.00 PFOS-1 FC2G_455S022 100- _ 7.99 I 2.14e3 I 5660 %- \ 1116 12.20 8.00 10.00 12.00 PFOS-2 FC2G_455S022 100- 8.17 9-18e2 i, 2381 % 12.38 : 9.63 10.80 0-" JJ '- A j 8.00 10.00 12.00 PFOA-2 FC2G_455S022 ioo-q 7.06 : 2.34e3 8941 %- 0- 7.00 S.00 PFBS-2 FC2G 455S022 100- 6.47 3.30e2^ 1667 %- 405 5.39 5.00 6.00 7.00 PFOSA FC2G_455S022 100--t 9.93 8.65e1 j' 392 I %9.60 I 11.22 12.02 c 8.00 10.00 12.00 PV by LHE 08-Jan-13, SV by AP 10-Jan-13. NOTE: OPR Conen. & LOD units = ng/mL, Sample and Lab BLK Conen. & LOD units = ng/L. Page 135 of 307 www.axysanalytical.com Quantify Sample Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\lnst_G\PFC.PRO\FC\FC2G_455-B.qld Last Altered: Tuesday, January 08, 2013 12:06:04 Pacific Standard Time Printed: Thursday, January 10, 2013 12:48:05 Pacific Standard Time ID: WG42273-103,,DUP Name: FC2G_455S022 Description: 1,WG42273,15/4000uL Date: 19-Dec-2012 Time: 00:07:06 13C2-PFOA FC2G_455S022 100- *7 A) f 1.41e5 558029 7.00 8-00 13C4-PFOA FC2G 455S022 100-, 1 4.91e4 f 1197609 %- 0- . . 1 7 ..- m -r min 7.00 8.00 13C4-PFOS-1 FC2G 455S022 100- :r 8.17e3 I; 30698 %~ ; ; :i 0- 8.00 10.00 min 12.00 13C4-PFOS-2 FC2G 455S022 100- P7.11e3 1 28131 %- 0- 11 'sJ min 8.00 10.00 12.00 1802-PFHxS-1 FC2G 455S022 100n I"7.49e3 k 31465 %~ 07.00 r-T min 8.00 1802-PFHxS-2 FC2G_455S022 100^ 7.25 5.10e3 I I 21761 %- 07.00 8.00 13C4-PFBA FC2G__455S022 100- 5.14 f 1.89e4 M 66436 %- : 4.14 /-1 ..Iv ... 5.00 6.00 7.00 13C2-PFHxA FC2G 455S022 oo 13C5-PFNA FC2G 455S022 7.46 5.67e4 "A 239422 \ \ %' /V o: 7.00 8.00 min 13C2-PFDA FC2G 455S022 100- \ 7.93 6.36e4 !; 241225 % i ; 0 L i , ______ rrrri-n min 8.00 10.00 12.00 13C2-PFDO FC2G 455S022 100n 9.03 1" 9.08e4 ;; 399904 %- fi \\ ;\ <H .-- j '>sL- mtn 8.00 10.00 12.00 13C2-PFOUEA FC2G 455S022 100- 7.39 2.05e4 ?\ 81878 \ %- j \ V.o- J 7.00 8.00 PV by LHE 08-Jan-13, SV by AP 10-Jan-13. NOTE: OPR Conen. & LOD units = ng/mL, Sample and Lab BLK Conen. & LOD units = ng/L. Page 136 of 307 www.axysanalytical.com Quantify Sample Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\lnst_G\PFC.PRO\FC\FC2G_455-B.qld Last Altered: Tuesday, January 08, 2013 12:06:04 Pacific Standard Time Printed: Thursday, January 10, 2013 12:48:05 Pacific Standard Time ID: WG42273-103,,DUP Name: FC2G_455S022 Description: 1,WG42273,15/4000uL Date: 19-Dec-2012 Time: 00:07:06 # Name 1 PFBA 2 PFPeA 3 PFHxA 4, PFHpA 5 PFOA-1 6 PFOA-2 7 PFNA 8 PFDA 9 PFUnA 10 PFDoA 11 PFBS-1 12 PFBS-2 13 PFHxS-1 14 PFHxS-2 15 PFHxS-3 16 PFOS-1 17 PFOS-2 18 PFOSA 19 13C2-PFOA 20 13C4-PFOA 21 13C4-PFOS-1 22 13C4-PFOS-2 23 1802-PFHXS-1 24 1802-PFHxS-2 25 13C4-PFBA 26 13C2-PFHxA 27 13C5-PFNA 28 13C2-PFDA 29 13C2-PFDoA 30 13C2-PFOUEA IS# Trace RT 25 212.99>168.98 5.13 26 262.98 >218.... 5.95 26 312.97> 268.98 6.34 26 362.97> 318.98 6.69 19 412.97> 368.98 7.06 19 412.97> 168.80 7.06 27 462.96 >418.... 7.46 28 512.96 > 468.... 7.93 28 562.96 > 518.... 29 612.95 > 568.... 9-03 23 298.94> 79.96 6.43 24 298.94 > 98.95 6.47 23 398.84 > 79.96 7.25 24 398.84> 98.96 7.25 23 398.84> 118.70 21 498.93> 79.96 7.99 22 498.93> 98:96 8.17 21 498 > 78 9.93 20 414.97 > 369.... 7.06 416.97 >371.9 7.06 30 503 > 79.96 8.17 30 503 > 98.96 8.17 30 402.9>84 7.25 30 402.9>103 7.25 30 216.99>171.98 5.14 30 314.97>269.98 6.34 30 467.96>422.97 7.46 30 514.96 >469.96 7.93 30 614.95 > 569.... 9.03 458.98 >393.98 7.39 Area 4833 2070 4367 3305 8311 2336 1245 1564 343 730 330 220 116 2142 918 87 141479 49058 8172 7113 7488 5101 18859 40733 56715 63565 90751 20501 IS Area 18859 40733 40733 40733 141479 141479 56715 63565 63565 90751 7488 5101 7488 5101 7488 8172 7113 8172 49058 20501 20501 20501 20501 20501 20501 20501 20501 20501 ng/L 5.714 1.981 2.235 1.879 3.774 4.285 0.529 1.952 2.653 0.188 1.294 8.623 4.582 0.519 68.438 23.680 32.223 37.865 34.002 32.515 17.398 17.455 24.489 22.672 22.032 21.031 LOD 0.6330 0.6435 0.0911 0.5750 0.0621 0.1324 0.1268 0.7651 0.7086 0.4079 0.2903 0.3195 0.7249 0.1399 0.9073 0.1417 0.0796 0.2322 %Rec S/N 20 14 30 12 146 0 12 11 5 17 24 5 9 94.7 98.3 89.2 104.8 94.1 90.0 72.3 72.5 101.7 94.2 91.5 104.8 58 31 10 0 0 313 352 148 745 51 424 0 812 314 0 Noise 794 772 636 1018 204 0 376 429 252 358 178 70 142 50 34 98 77 39 0 0 98 80 213 29 1309 440 0 297 1273 0 Height 15838 10647 19377 12705 29822 8941 4619 4880 1955 3007 1667 741 436 5660 2381 .392 558029 197609 30698 28131 31465 21761 66436 186784 239422 241225 399904 81878 IS Height 66436 186784 186784 186784 558029 558029 239422 241225 241225 399904 31465 21761 31465 21761 31465 30698 28131 . 30698 197609 81878 81878 81878 81878 81878 81878 81878 81878 81878 Sample size 0.4984 0.4984 0.4984 0.4984 0.4984 0.4984 0.4984 0.4984 0.4984 0.4984 0.4984 0.4984 0.4984 0.4984 0.4984 0.4984 0.4984 0.4984 0.4984 0.4984 0.4984 0.4984 0.4984 0.4984 0.4984 0.4984 0.4984 0.4984 0.4984 0.4984 Factor2 Detection... 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MMi 1.0 1.0 MMi 1.0 MM 1.0 bb 1.0 bb 1.0 MM 1.0 1.0 MM 1.0 bb 1.0 MM 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 MM 1.0 bb 1.0 bb 1.0 bb 1.0 bb PV by LHE 08-Jan-13, SV by AP 10-Jan-13. NOTE: OPR Concn. & LOD units = ng/mL, Sample and Lab BLK Concn. & LOD units = ng/L. Page 137 of 307 www.axysanalytical.com Quantify Sample Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\lnst_G\PFC.PRO\FC\FC3G__015-B.qld Last Altered: Tuesday, January 15, 2013 14:23:27 Pacific Standard Time Printed: Wednesday, January 16, 2013 11:54:43 Pacific Standard Time ID: L18989-12,R, Name: FC3G_015S033 Description: 1,WG42428,15/4000uL Date: 15-Jan-2013 Time: 04:27:55 PFBA FC3G 015S033 100 5.21 5.00 6.00 7.00 PFPeA FC3G 015S033 100- 5.95 5.53e3~| 18631 5.69 6.59 4.18 \ . o- -... ' !- -i ..... .......... min 5.00 6.00 7.00 PFHxA FC3G 015S033 100- 6.34 1.23e4 !> 54190 ;; %~ 4.07 0 min 5.00 6.00 7.00 PFHpA FC3G 015S033 100- 6.73 9.97e3 . 36552 '! %- M. o: 5.00 6.00 7.00 PFNA FC3G 015S033 PFDA FC3G_015S033 100- 7.99 f 2.03e3 I 6026 %-64 11.69 tjtt min 8.00 10.00 12.00 PFUnA FC3G_015S033 100 i 8.55 12;23 |\ 9.66 11'7f / ?l| Mm 8.00 10.00 12.00 PFDoA FC3G_015S033 100 F3.9201e82 12.29 i 1337 7.70 110.02 \ . v 8.00 10.00 12.00 PFHxS-1 FC3G 015S033 PFHxS-2 FC3G 015S033 100- 7.29 >4.84e2 \ 1552 %J 6.71 j \7.90 7.00 8.00 PFHxS-3 FC3G 015S033 100- 7.33 3.00e2?: 943 / 6,86/ 7.00 8.00 PFOS-1 FC3G 015S033 100-1 8.29 6.23e3 12196 %- ; 8.00 ' 10:00 ' I 2 I0O PFOA-1 FC3G 015S033 100- 7.09 A 3.06e4 ; 116410 %- PFOA-2 FC3G 015S033 100- 7.09 A 8.89e3 ; l 32775 0: 7.00 -n-r min 8.00 0 : A .. 7.00 8.00 PFBS-1 FC3G__015S033 100- 6.47 6.75e3 30376 %- 0 Vrfrfrf 5.00 6.00 7.00 PFBS-2 FC3G 015S033 100- 6.47 3.61e3~| 16645 | %- 1 m o5.00 6.00 7.00 PFOS-2 FC3G 015S033 PFOSA FC3GJ315S033 mn 10-02 100^ 2.59e2~l 1130 g I %H I I 10.47 -7.53 i t / 1*| fvl . . j y jc. 8.00 10.00 12.00 PV by LEH 15-Jan-13, SV by AP 16-Jan-13. NOTE: OPR Conen. & LOD units = ng/mL, Sample and Lab BLK Conen. & LOD units = ng/L. Page 138 of 307 www.axysanalytical.com Quantify Sample Report MassLynx 4.1 SCN627 Dataset G:\Masslynx\lnst_G\PFC.PRO\FC\FC3G_015-B.qld Last Altered: Tuesday, January 15, 2013 14:23:27 Pacific Standard Time Printed: Wednesday, January 16,2013 11:54:43 Pacific Standard Time ID: L18989-12,R, Name: FC3G_015S033 Description: 1,WG42428,15/4000uL Date: 15-Jan-2013 Time: 04:27:55 13C2-PFOA FC3G__015S033 100" 7.(1 "2.31 e5 926483 13C4-PFOA FC3G 015S033 100- 8.33e4 { 1339141 %-- 13C4-PFOS-1 FC3G 015S033 100- r 1.25e4 | 47066 %" . . min ,J Ik j o- -t"? min 0- IS i. 7.00 8.00 7.00 8.00 8.00 10.00 12.00 13C4-PFBA FC3GJ315S033 100- 5.21 f 2.66e4 1 103488 13C2-PFHxA FC3G_015S033 100- 6.34 5.49e4 l 245900 ji 13C5-PFNA FC3G_015S033 100- 7.49 8.34e4 336754 : \ %- 5.00 6.00 7.00 5.00 6.00 7.00 7.00 8.00 13C4-PFOS-2 FC3G 015S033 1001 r 9.58e3 |j 36142 %- H 8.00 10.00 12.00- 13C2-PFDA FC3G__015S033 100- . 7.99 f 9.09e4 i 331791 %- " **-- -------r 8.00 10.00 12.00 1802-PFHxS-1 FC3G 015S033 100- 1.17e4 ? 46323 i \ /\ 7.00 8.00 13C2-PFDoA FC3G__015S033 100n r 1I.94.21e85 615194 IL.. 8.00 10.00 12.00 1802-PFHxS-2 FC3G 015S033 100- 8.46e3 r 32872 / %-- 7.00 8.00 13C2-PFOUEA FC3G 015S033 PV by LEH 15-Jan-13, SV by AP 16-Jan-13. NOTE: OPR Conen. & LOD units = ng/mL, Sample and Lab BLK Conen. & LOD units = ng/L. Page 139 of 307 www.axysanalytical.com Quantify Sample Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\lnst_G\PFC.PRO\FC\FC3G_015-B.qld Last Altered: Tuesday, January 15, 2013 14:23:27 Pacific Standard Time Printed: Wednesday, January 16, 2013 11:54:43 Pacific Standard Time ID: L18989-12,R, Name: FC3G_015S033 Description: 1,WG42428,15/4000uL Date: 15-Jan-2013 Time: 04:27:55 # Name 1 PFBA 2 PFPeA 3 PFHxA 4 PFHpA 5 PFOA-1 6 PFOA-2 7 PFNA 8 PFDA 9 PFUnA 10 PFDoA 11 PFBS-1 12 PFBS-2 13 PFHxS-1 14 PFHxS-2 15 PFHxS-3 16 PFOS-1 17 PFOS-2 18 PFOSA 19 13C2-PFOA 20 13C4-PFOA 21 13C4-PFOS-1 22 13C4-PFOS-2 23 1802-PFHxS-1 24 1802-PFHxS-2 25 13C4-PFBA 26 13C2-PFHxA 27 13C5-PFNA 28 13C2-PFDA 29 13C2-PFDoA 30 13C2-PFOUEA IS# Trace RT 25 212.99>168.98 5.21 26 262.98 >218.... 5.95 26 312.97> 268.98 6.34 26 362.97> 318.98 6.73 19 412.97> 368.98 7.09 19 412.97> 168.80 7.09 27 462.96 >418.... 7.49 28 512.96 > 468..,. 7.99 28 562.96 >518.... 29 612.95 > 568.... 9.18 23 298.94> 79.96 6.47 24 298.94 > 98.95 6.47 23 398.84 > 79.96 7.33 24 398.84> 98.96 7.29 23 398.84> 118.70 7.33 21 498.93> 79.96 8.29 22 498.93> 98.96 8.29 21 498 > 78 10.02 20 414.97 > 369.... 7.09 416.97 >371.9 7.09 30 503 > 79.96 8.35 30 503 > 98.96 8.29 30 402.9>84 7.33 30 402.9>103 7.33 30 216.99>171.98 5.21 30 314.97>269.98 6.34 30 467.96>422.97 7.49 30 514.96 >469.96 7.99 30 614.95 >569.... 9.18 458.98 >393.98 7.38 Area 10325 5529 12283 9966 30567 8895 2370 2034 320 6751 3607 887 484 300 6234 4240 259 231143 83326 12514 9582 11702 8463 26570 54935 83356 90903 141892 29222 IS Area 26570 54935 54935 54935 231143 231143 83356 90903 90903 141892 11702 8463 11702 8463 11702 12514 9582 12514 83326 29222 29222 29222 29222 29222 29222 29222 29222 29222 ng/L 9.205 3.679 4.646 3.935 9.727 11.998 0.354 14.991 15.122 1.117 2.026 1.979 17.256 17.712 0.606 76.584 27.013 38.579 37.178 43.647 42.623 20.190 21.106 28.457 24.668 24.592 23.160 LOD 0.2189 0.0344 0.2238 0.1713 0.1713 0.4129 0.0538 0.4545 0.3312 0.1535 0.0223 0.1431 0.0801 %Rec S/N 118 27 71 52 651 0 15 21 97.5 103.2 98.3 94.7 111.2 108.6 77.1 80.6 108.7 94.2 94.0 106.2 6 172 253 121 13 33 83 107 28 0 0 674 270 2553 290 189 489 4095 500 1058 0 Noise 345 683 762 707 179 0 569 286 421 226 176 66 20 122 28 146 120 40 0 0 70 134 18 113 548 502 82 663 581 0 Height 40650 18631 54190 36552 116410 32775 8679 6026 1337 30376 16645 2459 1552 943 12196 12803 1130 926483 339141 47066 36142 46323 32872 103488 245900 336754 331791 615194 110229 IS Height Sample size 103488 0.4585 245900 0.4585 245900 0.4585 245900 0.4585 926483 0.4585 926483 0.4585 336754 0.4585 331791 0.4585 331791 0.4585 615194 0.4585 46323 0.4585 32872 0.4585 46323 0.4585 32872 0.4585 46323 0.4585 47066 0.4585 36142 0.4585 47066 0.4585 339141 0.4585 0.4585 110229 0.4585 110229 0.4585 110229 0.4585 110229 0.4585 110229 0.4585 110229 0.4585 110229 0.4585 110229 0.4585 110229 0.4585 0.4585 Factor2 Detection... 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 bb 1.0 MM 1.0 MM 1.0 MMI 1.0 1.0 bbl 1.0 MM 1.0 MM 1.0 bb 1.0 MM 1.0 bb 1,0 MM 1.0 MM 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 MM 1.0 bb 1.0 MM 1.0 bb 1,0 bb 1.0 bb 1.0 bb PV by LEH 15-Jan-13, SV by AP 16-Jan-13. NOTE: OPR Conen. & LOD units = ng/mL, Sample and Lab BLK Conen. & LOD units = ng/L. Page 140 of 307 www.axysanalytical.com Quantify Sample Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\lnst_G\PFC.PRO\FC\FC3G_015-B.qld Last Altered: Tuesday, January 15, 2013 14:23:27 Pacific Standard Time Printed: Wednesday, January 16, 2013 11:54:43 Pacific Standard Time ID: L18989-13,R, Name: FC3G_015S034 Description: 1,WG42428,15/4000uL Date: 15-Jan-2013 Time: 04:44:56 PFBA FC3GJD15S034 100- 5.21 f 8.43e3 | 38045 i fi j`III lViiTrfTrrr^rrn-vrrrir mm 5.00 6.00 7.00 PFPeA FC3G 015S034 100- 5.95 3.61e 3 l I14779 I %- 5.41 { V| 0- min 5.00 6.00 7.00 PFHxA FC3G_015S034 100-, 6.33 8.98e3 l 42836 %- 5.10 5.84 0 5.00 6.00 7.00 PFHpA FC3G 015S034 PFNA FC3G 015S034 PFDA FC3GJ015S034 100- 7.99 f 1.80e3 ;; 6281 . j! 12.08 9.90 8.00 10.00 12.00 PFUnA FC3G 015S034 100-n 8.49 O S F 3.12e2 1 12.35 a 1 1413 11-8\4 1/ % , ;:, h ^ 0^ 11rrr ,T,,vri .^rrrrrrrn 0110 8.00 10.00 12.00 PFDoA FC3G 015S034 100- _ 912 175R 5.63e2 12;26 1519 . 8.17 %- S .v t5 ., 0 - -------- ---------- min 8.00 10.00 12.00 PFHxS-1 FC3G_015S34 100 A 6.83e2 \ 2262 %H J6.66 } \ l J .. 7.00 \ 8.02 min 8.00 PFHxS-2 FC3G 015S034 100- JT4.52e2 1761 %- o7.00 rr min 8.00 PFHxS-3 FC3G 015S034 100^ /J2.94e2 l 903 %- 6.63 / '/ o- "`W-- ....... . . . min 7.00 8.00 PFOS-1 FC3G 015S034 100- f"4.60e3 j 10689 %u 0- 1 - y-rrrrrrrTT 8.00 10.00 12.00 PFOA-1 FC3GJ315S034 100- _ 7.05 \ 2.22e4 f. \ 83570 7.00 8.00 PFBS-1 FC3G_015S034 100-3 6.47 %- 5.00 6.00 7.00 PFOS-2 FC3G 015S034 100 f 2.36e3 r. 5575 % ; H ; 11.39 12.05 0- ------- --V min 8.00 10.00 12.00 PFOA-2 FC3G_J)15S034 100- 7.09 T5,78e3 J 20971 %- 7.00 8.00 PFBS-2 FC3G,,015S034 100- 6.44 2.19e3l 10268 i %- il , 111imi-^ rrj?!Tfftr?:m mm 5.00 6.00 7.00 PFOSA FC3GJ315S034 loo-q 9.99 1.71e2~| 635 8 %: 7.93 o: 8.00 10.00 11.90 min 12.00 PV by LEH 15-Jan~13, SV by AP 16-Jan-13. NOTE: OPR Conen. & LOD units = ng/mL, Sampie and Lab BLK Conen. & LOD units = ng/L. Page 141 of 307 www.axysanalytical.com Quantify Sample Report MassLynx 4.1 SCN627 Dataset G:\Masslynx\lnst_G\PFC.PRO\FC\FC3G_015-B.qld Last Altered: Tuesday, January 15, 2013 14:23:27 Pacific Standard Time Printed: Wednesday, January 16, 2013 11:54:43 Pacific Standard Time ID: L18989-13.R, Name: FC3G_015S034 Description: 1,WG42428,15/4000uL Date: 15-Jan-2013 Time: 04:44:56 13C2-PFOA FC3G 015S034 100- 7,09 f 2.05e5 I I 829906 %-- / 0- 7.00 t-t min 8.00 13C4-PFOA FC3G 015S034 100- 7.09 ff_7.63e4 M 308093 %- o - J - w . .. "t-t min 7.00 8.00 13C4-PFOS-1 FC3G 01SS034 100- 8.29 | 1.17e4 44365 %- 11 1 o- 8.00 10.00 min 12.00 13C4-PFOS-2 FC3G 015S034 100- 8.29 8.52e3 33364 %- . 0 ..L - -- - .....-- min 8.00 10.00 12.00 1802-PFHxS-l FC3G 015S034 100- 7.29 i"9.80e3 | | 41216 %7 0 - / '' n min 7.00 8.00 1802-PFHXS-2 FC3G 015S034 100- 7.29 f7.35e3 30799 %" 0- / '' -.... 7.00 8.00 13C4-PFBA FC3G__015S034 mn 10T 5.19 f2.16e4 i 102104 5.00 6.00 7.00 13C2-PFHxA F C 3 G 0 15S034 100-j 6.31 4.86e4 223037 %- il 5.00 6.00 7.00 13C5-PFNA FC3G 015S034 13C2-PFDA FC3G_015S034 100- 7.99 I 8.25e4 292369 %- 8.00 10.00 12.00 13C2-PFDoA FC3G 015S034 100- 9.12 fi-1 4 e 5 i. 474258 %i: - I:-, tt min 8.00 10.00 12.00 13C2-PFOUEA FC3G 015S034 100- 7.33 I 2.78e4 J102115 %- o- / 7.00 .... 8.00 PV by LEH 15-Jan-13, SV by AP 16-Jan-13. NOTE: OPR Conen. & LOD units = ng/mL, Sample and Lab BLK Conen. & LOD units = ng/L. Page 142 of 307 www.axysanalytical.com Quantify Sample Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\lnst_G\PFC.PRO\FC\FC3G_015-B.qld Last Altered: Tuesday, January 15, 2013 14:23:27 Pacific Standard Time Printed: Wednesday, January 16, 2013 11:54:43 Pacific Standard Time ID: L18989-13,R, Name: FC3G_015S034 Description: 1,WG42428,15/4000uL Date: 15-Jan-2013 Time: 04:44:56 # Name 1 PFBA 2 PFPeA 3 PFHxA 4 PFHpA 5 PFOA-1 6 PFOA-2 7 PFNA 8 PFDA 9 PFUnA 10 PFDoA 11 PFBS-1 12 PFBS-2 13 PFHxS-1 14 PFHxS-2 15 PFHxS-3 16 PFOS-1 17 PFOS-2 18 PFOSA 19 13C2-PFOA 20 13C4-PFOA 21 13C4-PFOS-1 22 13C4-PFOS-2 23 1802-PFHxS-1 24 1802-PFHxS-2 25 13C4-PFBA 26 13C2-PFHxA 27 13C5-PFNA 28 13C2-PFDA 29 13C2-PFDoA 30 13C2-PFOUEA IS# Trace RT 25 212.99>168.98 5.21 26 262.98 >218.... 5.95 26 312.97> 268.98 6.33 26 362.97> 318.98 6.68 19 412.97> 368.98 7.05 19 412.97> 168.80 7.09 27 462.96 >418.... 7.46 28 512.96 > 468.... 7.99 28 562.96 >518.... 8.49 29 612.95 >568.... 9.12 23 298.94> 79.96 6.47 24 298.94 > 98.95 6.44 23 398.84 > 79.96 7.29 24 398.84> 98.96 7.29 23 398.84> 118.70 7.29 21 498.93> 79.96 8.17 22 498-93> 98.96 8.23 21 498 > 78 9.99 20 414.97 > 369.... 7.09 416.97 >371.9 7.09 30 503 > 79.96 8.29 30 503 > 98.96 8.29 30 402.9>84 7.29 30 402.9>103 7.29 30 216.99>171.98 5.19 30 314.97>269.98 6.31 30 46796>422.97 7.46 30 514.96 >469.96 7.99 30 614.95 > 569.... 9.12 458.98 >393.98 7.33 Area 8433 3613 8979 7298 22220 5781 2192 1798 312 563 4559 2186 683 452 294 4604 2363 171 205116 76278 11715 8516 9796 7354 21611 48587 72891 82467 114189 27837 IS Area 21611 48587 48587 48587 205116 205116 72891 82467 82467 114189 9796 7354 9796 7354 9796 11715 8516 11715 76278 27837 27837 27837 27837 27837 27837 27837 27837 27837 ng/L 8.891 2.591 3.608 3.106 7.562 8.358 0.383 11.388 9.942 0.894 2.108 2.332 12.840 10.485 0.441 71.387 23.778 36.455 33.353 36.883 37.384 16.577 18.844 25.119 22.590 19.978 21.214 LOD 0.1776 0.1052 0.9408 0.0210 0.1431 0.1307 0.4145 0.2169 0.0157 1.5459 0.1995 0.0327 0.0776 0.0932 %Rec 94.5 94.5 96.6 88.3 97.7 99.0 65.9 74.9 99.8 89.8 79.4 101.1 S/N 77 27 98 30 0 304 54 12 3 5 106 91 0 6 10 90 57 26 0 0 864 258 585 8178 41 355 2636 844 728 0 Noise 494 552 438 888 0 69 163 529 404 288 197 113 0 312 91 119 98 24 0 0 51 129 70 4 2464 629 116 346 651 0 Height 38045 14779 42836 26436 83570 . 20971 8762 6281 1413 1519 20804 10268 2262 1761 903 10689 5575 635 829906 308093 44365 33364 41216 30799 102104 223037 306152 292369 474258 102115 IS Height Sample size 102104 0.4768 223037 0.4768 223037 0.4768 223037 0.4768 829906 0.4768 829906 0.4768 306152 0.4768 292369 0.4768 292369 0.4768 474258 0.4768 41216 0.4768 30799 41216 30799 0.4768 0.4768 0.4768 41216 0.4768 44365 0.4768 33364 0.4768 44365 0.4768 308093 0.4768 0.4768 102115 0.4768 102115 0.4768 102115 0.4768 102115 0.4768 102115 0.4768 102115 0.4768 102115 0.4768 102115 0.4768 102115 0.4768 0.4768 Factor2 Detection... 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MMi 1.0 MMi 1.0 MMI 1.0 bb 1.0 MM 1.0 bb 1.0 MM 1.0 MM 1.0 bb 1.0 MM 1.0 MM 1.0 bb . 1.0 bb . 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 bb PV by LEH 15-Jan-13, SV by AP 16-Jan-13. NOTE: OPR Conen. & LOD units = ng/mL, Sample and Lab BLK Conen. & LOD units = ng/L. Page 143 of 307 www.axysanalytical.com Quantify Sample Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\lnst_G\PFC.PRO\FC\FC3G_015-B.qld Last Altered: Tuesday, January 15, 2013 14:23:27 Pacific Standard Time Printed: Wednesday, January 16, 2013 11:54:43 Pacific Standard Time ID: L18989-14.R, Name: FC3GJJ15S035 Description: 1,WG42428,15/4000uL Date: 15-Jan-2013 Time: 05:01:49 PFBA FC3G_015S035 100- 5.21 1.03e4 i; 35887 %- 4.07 1 6.14 5.00 6.00 7.00 PFPeA FC3G_015S035 100-1 5.95 4.11e3 160001 5.60 6.40 4.11 l V . 5.00 6.00 7.00 PFHxA FC3G__015S035 100- 6.36 _ 1.42e4 61393 i %- r ill 5.00 6.00 7.00 PFHpA FC3G,,015S035 100- 6.73 _ 9.46e3 l 31255 M %4.03 5.64,6.01 5.00 6.00 7.00 PFOA-1 FC3G_015S035 100- 7.09 A 3.14e4 M 115666 %- 0-- - "- 7.00 8.00 PFOA-2 FC3G_015S035 100- 7.09 r 9.43e3 ^ 35849 %- 7.00 8.00 PFNA FC3G 015S035 PFDA FC3G_015S035 _ 7.93 100n 2.42e3 8454 %p , 9.78 11-5112 23 8.00 10.00 12.00 PFUnA FC3G__015S035 100- 12.41 11.96- n a1j u0..o38o ^v 1 f| ,1 , V f l ! 1i! 0-Wrrr- T-pr min 8.00 10.00 12.00 PFDoA FC3G_015S035 cI ri#100 7.70 1 9.03 2.96e2 11,.87 % Wmi 0 8.00 10.00 12.00 PFBS-1 FC3G_015S035 100- 6.47 5-14e3~| 21617 5.00 6.00 7.00 PFBS-2 FC3G_015S035 100- 6.47 2.35e3 1. 11399 m % 5.00 6.00 7.00 PFHxS-1 FC3G_015S035 100- 1*9.7' 1e2 | | 2981 ^6.66 1 \ 7.00 r8? mtn 8.00 PFHxS-2 FC3G 015S035 100" - %: A 5.77e2 ; : 2454 6.63 o7.00 ~ .... -r min 8.00 PFHxS-3 FC3G 015S035 100- %- o- - >- ...--r-.-Ap..- " min 7.00 8.00 PFOS-1 FC3G 015S035 100 A 6.39e3 i ! 14737 % ;: il 0 i . min 8.00 10.00 12.00 PFOS-2 FC3G 015S035 100- j\ 3.52e3 : ; 9355 %~ ; i 0 - min 8.00 10.00 12.00 PFOSA FC3G_015S035 100-, 9.90 1.83e2~| 736 6 %-- B-85 f i } a 2 3 11'66 qA 8.00 10.00 12.00 PV by LEH 15-Jan-13, SV by AP 16-Jan-13. NOTE: OPR Conen. & LOD units = ng/mL, Sample and Lab BLK Conen. & LOD units = ng/L C Page 144 of 307 www.axysanalytical.com Quantify Sample Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\lnst_G\PFC.PRO\FC\FC3G_015-B.qld Last Altered: Tuesday, January 15, 2013 14:23:27 Pacific Standard Time Printed: Wednesday, January 16, 2013 11:54:43 Pacific Standard Time ID: L18989-14.R, Name: FC3G_015S035 Description: 1,WG42428,15/4000uL Date: 15-Jan-2013 Time: 05:01:49 13C2-PFOA FC3G_015S035 100- 7.09 r 2.55e5 f l 1007994 %- 13C4-PFOA FC3G_015S035 100n _ 7.09 i 8.91e4 1355915 %- 7.00 8.00 13C4-PFBA FC3G_015S035 100- 5.21 i 2.91e4 ; 114066 .; 7.00 8.00 13C2-PFHxA FC3G_015S035 100- 6.36 5.83e4 260598 %- 13C4-PFOS-1 FC3G__015S035 100 8.23 ,f~1.33e4 6 50145 % sgiliiL 8.00 10.00 12.00 13C5-PFNA FC3G_015S035 100- 7.46 9.03e4 A 386666 / % 13C4-PFOS-2 FC3G_015S035 100- 8.17 i 1.09e4 : 39814 % 8.00 10.00 12.00 13C2-PFDA FC3G_015S035 _ 7.93 100n 8.84e4 i 307549 % 1802-PFHxS-1 FC3G_015S035 100- _ 7.29 k 1.11e4 f \ 43554 %' 7.00 8.00 13C2-PFDoA FC3G_015S035 100- 9.03 1.39e5 626521 1802-PFHxS-2 FC3G__015S035 100- 7.29 I " 8.830.3 f \ 35264 7.00 8.00 13C2-PFOUEA FC3G_ 015S035 100 7.33 [3 .2 0 e 4 ,116674 5.00 6.00 7.00 5.00 6.00 7.00 7.00 8.00 8.00 10.00 12.00 8.00 10.00 12.00 7.00 8.00 PV by LEH 15-Jan-13, SV by AP 16-Jan-13. NOTE: OPR Conen. & LOD units = ng/mL, Sample and Lab BLK Conen. & LOD units = ng/L. _, m Page 145 of 307 www.axysanalytical.com Quantify Sample Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\lnst_G\PFC.PRO\FC\FC3G_015-B.qld Last Altered: Tuesday, January 15, 2013 14:23:27 Pacific Standard Time Printed: Wednesday, January 16, 2013 11:54:43 Pacific Standard Time ID: L18989-14.R, Name: FC3GJJ15S035 Description: 1,WG42428,15/4000uL Date: 15-Jan-2013 Time: 05:01:49 # Name 1 PFBA 2 PFPeA 3 PFHxA 4 PFHpA 5 PFOA-1 6 PFOA-2 7 PFNA 8 PFDA 9 PFUnA 10 PFDoA 11 PFBS-1 12 PFBS-2 13 PFHxS-1 14 PFHxS-2 15 PFHxS-3 16 PFOS-1 17 PFOS-2 18 PFOSA 19 13C2-PFOA 20 13C4-PFOA 21 13C4-PFOS-1 22 13C4-PFOS-2 23 1802-PFHxS-1 24 1802-PFHxS-2 25 13C4-PFBA 26 13C2~PFHxA 27 13C5-PFNA 28 13C2-PFDA 29 13C2~PFDoA 30 13C2-PFOUEA IS# Trace RT 25 212.99M68.98 5.21 26 262.98 > 218--. 5.95 26 312.97> 268.98 6.36 26 362.97> 318.98 6.73 19 412.97> 368.98 7.09 19 412.97> 168.80 7.09 27 462.96 >418.... 7.46 28 512.96 > 468.... 7.93 28 562.96 > 518.... 8.58 29 612.95 > 568.... 9.03 23 298.94> 79.96 6.47 24 298.94 > 98.95 6.47 23 398.84 > 79.96 7.29 24 398.84> 98.96 7.29 23 398.84> 118.70 7.29 21 498.93> 79.96 8.17 22 498.93> 98.96 8.17 21 498 > 78 9.90 20 414.97 >369.... 7.09 416.97 >371.9 7.09 30 503 > 79.96 8.23 30 503 > 98.96 8.17 30 402,9>84 7.29 30 402.9>103 7.29 30 216.99>171.98 5.21 30 314.97>269.98 6.36 30 467.96>422.97 7.46 30 514.96 >469.96 7.93 30 614.95 > 569.... 9.03 458.98 >393.98 7.33 Area 10321 4112 14158 9463 31374 9433 2108 2415 212 296 5140 2350 971 577 404 6390 3523 183 255025 89118 13263 10944 11062 8828 29115 58343 90312 88418 138966 32044 IS Area 29115 58343 58343 58343 255025 255025 90312 88418 88418 138966 11062 8828 11062 8828 11062 13263 10944 13263 89118 32044 32044 32044 32044 32044 32044 32044 32044 32044 ng/L 8.908 2.715 5.418 3.730 9,598 12.272 0.232 12.595 9.792 1,591 2.500 3.299 17.739 13.571 0.470 84.173 30.781 39.725 41.257 40.088 43.195 21.496 21.779 29.956 23.312 23.401 27.058 LOD 0.2523 0.0300 0.1729 0.4032 0.2396 0.1028 0.3737 0.1652 0.0628 0.0956 0.0716 %Rec 100.6 110.4 95.0 98.6 95.8 103.3 77:1 78.1 107.4 83.6 83.9 116.4 S/N 93 21 135 43 420 0 25 48 4 3 107 180 38 61 76 94 68 20 0 0 307 516 0 1383 186 485 1682 699 1214 0 Noise 388 765 453 725 276 0 385 176 319 378 202 63 78 40 15 157 138 37 0 0 163 77 0 26 614 537 230 440 516 0 Height IS Height Sample size 35887 114066 0.4303 16000 260598 0.4303 61393 260598 0.4303 31255 260598 0.4303 115666 1007994 0.4303 35849 1007994 0.4303 9495 386666 0.4303 8454 307549 0.4303 1276 307549 0.4303 1203 626521 0.4303 21617 43554 0.4303 11399 . 35264 0.4303 2981 43554 0.4303 2454 35264 0.4303 1140 43554 0.4303 14737 50145 0.4303 9355 39814 0.4303 736 50145 0.4303 1007994 355915 0.4303 355915 0.4303 50145 116674 0.4303 39814 116674 0.4303 43554 116674 0.4303 35264 116674 0.4303 114066 116674 0.4303 260598 116674 0.4303 386666 116674 0.4303 307549 116674 0.4303 626521 116674 0.4303 116674 0.4303 . Factor2 Detection... 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 bb 1.0 bb 1.0 MM 1.0 MMI 1.0 MMI 1.0 bb! 1.0 MM 1.0 MM 1.0 bb 1.0 MM 1.0 MM 1.0 bb 1.0 MM 1.0 MM 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 MM 1.0 bb 1.0 bb 1.0 bb 1.0 bb PV by LEH 15-Jan-13, SV by AP 16-Jan-13. NOTE: OPR Conen. & LOD units = ng/mL, Sample and Lab BLK Conen. & LOD units = ng/L. Page 146 of 307 www.axysanalytical.com Quantify Sample Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\lnst_G\PFC.PRO\FC\FC2G_455-B.qld Last Altered: Tuesday, January 08, 2013 12:06:04 Pacific Standard Time Printed: Thursday, January 10, 2013 12:48:05 Pacific Standard Time ID: WG42273-101 ,,BLK Name: FC2G_455S010 Description: 1,WG42273,15/4000uL Date: 18-Dec-2012 Time: 20:35:06 PFBA FC2G 455S010 PFPeA FC2G_455S010 100- 6.06 1.71e2 1 825 1 6.69 IIs 4-.-9--0 1j A,, %- If * ft J t ! \\<71o3 PFHxA FC2G 455S010 5.00 6.00 7.00 PFHpA FC2G_455S010 100- 6.74 3.43e3l 13572 1 % 4-06 5.52^ 5.00 6.00 7.00 PFNA FC2G__455S010 100- 7.49 3.48e2 A 1525 % 6.63 j j min 7.00 8.00 PFDA FC2G_455S010 100- _ 7.99 1.19e3 ' I 4136 %tt 11.28 12.35 " 10.26^ \ * 08.00 10.00 12.00 PFUnA FC2G_455S010 100- f %- 8.88 i> if V/'v U l 0J \ ! v 8.00 10.00 12.44 Tjn min 12.00 PFDoA FC2G_455S010 100 , , 9-48 12.11 A Va 5 9 i r v ' *, M (H r 8.00 10.00 12.00 PFHxS-1 FC2G 455S010 100- 7.25 A 7.02e1 294 %: / i _ / o: 7.00 min 8.00 PFHxS-2 FC2G455S010 100- 6.63 ,, I a _ 7.20 : A '1 1.38g1 % . j \ 44 6.911 \ ' 07.00 8.00 min PFHxS-3 FC2G_455S010 100-- 3.76.135e1 ~p\ 195 A %- 6.72 * f \7.73 07.00 8.00 PFOS-1 FC2G 455S010 PFOA-1 FC2G 455S010 PFOA-2 FC2G 455S010 PFBS-1 FC2G 455S010 PFOS-2 FC2G_455S010 100n 8_.23 11.55 12.32 f":3.86e1 I 160 AiiPlWAVi 8.00 10.00 12.00 PFBS-2 FC2G_455S010 100- 542 6.51 4.06 I A 5.85 |i 6-74 ; Mil | I l-A EM ... 5.00 6.00 7.00 PFOSA FC2G_455S010 100- 9-75 11.49 9-33 ,, ^11.87 %1 if A ! . v V lil7-14 J A f AA I i-i-rAA.X irJ i min 8.00 10.00 12.00 PV by LHE 08-Jan-13, SV by AP 10-Jan-13. NOTE: OPR Conen. & LOD units = ng/mL, Sample and Lab BLK Conen. & LOD units = ng/L. Page 147 of 307 www.axysanalytical.com Quantify Sample Report MassLynx 4.1 SCN627 Dataset: G:\Massiynx\lnst_G\PFC.PRO\FC\FC2G_455-B.qld Last Altered: Tuesday, January 08, 2013 12:06:04 Pacific Standard Time Printed: Thursday, January 10, 2013 12:48:05 Pacific Standard Time ID: WG42273-101,,BLK Name: FC2G__455S010 Description: 1,WG42273,15/4000uL Date: 18-Dec-2012 Time: 20:35:06 13C2-PFOA FC2G 455S010 100- 7.11 JT 1.49e5 | | 611324 %-- o7.00 tt min 8.00 13C4-PFOA FC2G 455S010 100^ 7.11 JT5.19e4 i \ 212896 % ;V \ !: '\ 07.00 -T-T min 8.00 13C4-PFOS-1 FC2G 455S010 100- 8.23 r 8.25e3 || 31409 % I; ;: 08.00 10.00 min 12.00 13C4-PFOS-2 FC2G 455S01 100-n 8.23 F 7.21e3 28397 %- | i 0 I t ,.. min 8.00 10.00 12.00 1802-PFHxS-1 FC2G 455S010 100- 7.30 I~7.36e3 30098 %- / 0 7.00 i min 8.00 1802-PFHxS-2 FC2G 455S010 100" 7.30 I~5.69e3 M 22933 %- 07.00 8.00 13C4-PFBA FC2G 455S010 100- 5.18 i 2.31e4 1 83825 I %- 4.03 5.00 600 700 13C2-PFHxA FC2G_455S010 100- 6.36 5.55e41 281948 1 %- 5.00 6.00 7.00 13C5-PFNA FC2G__455S010 100- 7.46 5.10e4 !\ 211952 ; ` % 7.00 8.00 13C2-PFDA FC2G_455S010 100-, _ 7.99 5.72e4 210925 13C2-PFDoA FC2G 455S010 oAt-pNrn8.00 10.00 12.00 13C2-PFOUEA FC2G 455S010 PV by LHE 08-Jan-13, SV by AP 10-Jan-13. NOTE: OPR Conen. & LOD units = ng/mL, Sample and Lab BLK Conen. & LOD units = ng/L. Page 148 of 307 www.axysanalytical.com Quantify Sample Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\lnstJ3\PFC.PRO\FC\FC2G_455-B.qid Last Altered: Tuesday, January 08, 2013 12:06:04 Pacific Standard Time Printed: Thursday, January 10, 2013 12:48:05 Pacific Standard Time ID: WG42273-101,,BLK Name: FC2G_455S010 Description: 1,WG42273,15/4000uL Date: 18-Dec-2012 Time: 20:35:06 # Name 1 PFBA 2 PFPeA 3 PFHxA 4 PFHpA . 5 PFOA-1 6 PFOA-2 7 PFNA 8 PFDA 9 PFUnA 10 PFDoA 11 PFBS-1 12 PFBS-2 13 PFHxS-1 14 PFHxS-2 15 PFHxS-3 16 PFOS-1 17 PFOS-2 18 PFOSA 19 13C2-PFOA 20 13C4-PFOA 21 13C4-PFOS-1 22 13C4-PFOS-2 23 1802-PFHxS-l 24 1802-PFHxS-2 25 13C4-PFBA 26 13C2-PFHXA 27 13C5-PFNA 28 13C2-PFDA 29 13C2~PFDoA 30 13C2-PFOUEA . IS# Trace RT 25 212.99>168.98 5.20 26 262.98 >218.... 6.06 26 312.97> 268.98 6.37 26 362.97> 318.98 6.74 19 412.97> 368,98 7.11 19 412.97> 168.80 27 462.96 >418.... 7.49 28 512.96 >468.... 7.99 28 562.96 >518.... 29 612.95 > 568.... 8.97 23 298.94> 79.96 24 298.94 > 98.95 23 398.84 > 79.96 7.25 24 398.84> 98.96 7.20 23 398.84> 118.70 7-35 21 498.93> 79.96 22 498.93> 98.96 8.23 21 498 > 78 9.90 20 414.97 > 369.... 7.11 416.97 >371.9 7.11 30 503 > 79.96 30 503 > 98.96 8.23 8.23 30 402.9>84 7.30 30 402.9>103 7.30 30 216.99>171.98 5.18 30 314.97>269.98 6.36 30 467.96>422.97 7.46 30 514.96 >469.96 7.99 30 614.95 > 569..,. 9.03 458.98 >393.98 7.43 Area 460 171 579 3425 231 348 1187 159 70 14 36 39 5 149098 51922 8248 7211 7359 5689 23054 55504 50999 57235 106658 21450 IS Area 23054 55504 55504 55504 149098 149098 50999 57235 57235 106658 7359 5689 7359 5689 7359 8248 7211 8248 51922 21450 21450 21450 21450 21450 21450 21450 21450 21450 ng/L 0.265 0.319 0.096 1.483 0.180 0.539 0.355 67.925 24.981 30.985 36.572 31.835 34.544 20.262 22.659 20.979 19.448 24.669 21.933 LOD 0.0027 0.2877 0.2745 0.1005 0.1406 0.1207 0.5711 0.4803 0.3928 0.0235 0.2142 0.1931 0.2962 0.2296 0.3700 1.4979 0.0350 0.0942 0-1855 0.1059 %Rec S/N 6 4 12 98 5 4 21 3 0 7 0 94.3 104..1 86.1 101.6 88.4 96.0 84.4 94.4 87.4 81.0 102.8 109.7 3 2 8664 350 460 366 427 283 37 2476 0 572 445 621 Noise 238 206 226 138 180 31 359 194 198 209 19 31 0 6 0 123 56 31 71 . 608 68 78 71 81 2266 114 0 369 1066 138 Height 1370 825 2698 13572 923 1525 4136 670 294 44 195 160 48 611324 212896 31409 28397 30098 22933 83825 281948 211952 210925 474214 85552 IS Height 83825 281948 281948 281948 611324 611324 211952 210925 210925 474214 30098 22933 30098 22933 30098 31409 28397 31409 212896 85552 85552 85552 85552 85552 85552 85552 85552 85552 Sample size 0.5000 0.5000 0.5000 0.5000 0.5000 0.5000 0.5000 0.5000 0.5000 0.5000 0.5000 0.5000 0.5000 0.5000 0.5000 0.5000 0.5000 0.5000 0.5000 0.5000 0.5000 0.5000 0.5000 0.5000 0.5000 0.5000 0.5000 0.5000 0.5000 0.5000 Factor2 Detection... 1.0 MM 1.0 MM 1.0 MM 1.0 bb 1.0 MMI 1.0 1.0 MM 1.0 MMI 1.0 1:0 MMI 1.0 1.0 1.0 MMI 1.0 MM 1.0 MMI 1.0 1.0 MMI 1.0 MM 1.0 bb 1.0 bb 1.0 bb 1.0 MM 1.0 bb 1.0 bb 1.0 MM 1.0 MM 1.0 bb 1.0 bb 1.0 bb 1.0 bb PV by LHE 08-Jan-13, SV by AP 10-Jan-13. NOTE: OPR Conen. & LOD units = ng/mL, Sample and Lab BLK Conen. & LOD units = ng/L. Page 149 of 307 www.axysanalytical.com Quantify Sample Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\lnst_G\PFC.PRO\FC\FC3G_015-B.qld Last Altered: Tuesday, January 15, 2013 14:23:27 Pacific Standard Time Printed: Wednesday, January 16, 2013 11:54:43 Pacific Standard Time ID: WG42428-101 ,,BLK Name: FC3G_015S022 Description: 1,WG42428,15/4000u L Date: 15-Jan-2013 Time: 01:21:16 PFBA FC3G_015S022 mn 100"> 5.23 I" 7.50e2 2758 4.09 I \ \ L6U."34 7.11 PFPeA FC3G_015S022 100", 6f 2 4.33 6.08 i ]IM}lI [1,6.87 if f 4.95 ,|l PFHxA FC3G_015S022 100- 6.36 _ 9.88e2 | 4230 j 6.87 , 5.04 \ 5.97 .1 / PFHpA FC3G_015S022 100-, 6.68 3.05e3 A PFOA-1 FC3G 015S022 7.72 PFOA-2 FC3G 015S022 5.00 6.00 7.00 5.00 6.00 7.00 5.00 6.00 7.00 5.00 6.00 7.00 7.00 8.00 PFNA FC3G 015S022 PFDA FC3G_015S022 mn 799 1 0 th r 1.45e3 1 4513 %i | 9`3911.16 .J 1-78 (.1, ' v \n /''M vv''/v'' 8.00 10.00 12.00 PFUnA FC3GJ115S022 100-, 1 %- 11-34 12:26 10.32 j\ MM f\ jv j Vs/ l! 0^ 8.00 10.00 12.00 PFDoA FC3G__015S022 100- 9.21 f 3.39e2 | 1592 12.32 % 888l|10,02i\MsA V lv 8.00 10.00 12.00 PFBS-1 FC3G_015S022 100- 5.86, -4.44 f1 6.97 VA- J i \jt A. ! 5.00 6.00 7.00 PFBS-2 FC3GJD15S022 100-4-03 5'36 4.74 6.44 i II 'Mn.vT\ .K7iO-i-t i 5.00 6.00 7.00 PFHxS-1 FC3G_015S022 7 -31 100 7.89e1 A 362 / \ " / l i'T . ^------------------------- min 7.00 8.00 PFHxS-2 FC3G 015S022 100- 2.18e1 7- 7.33;2.18e1;66 66 : 6.95/ 7 o- n^rrn-T-rr mm 7.00 8.00 PFHxS-3 FC3G 015S022 1001^6.63 : 2.301,1 ?\ 80 7.00 II/t%V \J 0- \ 7.90 . i i * i mi.n 7.00 8.00 PFOS-1 FC3G 015S022 100^ f 3.38e2 1 838 12.11 %n \ 1113 o- / V '-'-v "" ' --------------- =.......... min 8.00 10.00 12.00 PFOS-2 FC3G 015S022 100- %- 9.45 n o - -.. At . 8.00 10.00 i I Ivj. , -TTTT min 12.00 PFOSA FC3G__015S022 10.08 1001 1 .5 5 e ll 10.26 74 11.96 i%- 8.11 9.42 ( CH . 8.00 10.00 12.00 PV by LEH 15-Jan-13, SV by AP 16-Jan-13. NOTE: OPR Conen. & LOD units = ng/mL, Sample and Lab BLK Conen. & LOD units = ng/L. Page 150 of 307 www.axysanalytical.com Quantify Sample Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\lnst_G\PFC.PRO\FC\FC3G_015-B.qld Last Altered: Tuesday, January 15, 2013 14:23:27 Pacific Standard Time Printed: Wednesday, January 16, 2013 11:54:43 Pacific Standard Time ID: WG42428-101,,BLK Name: FC3G_015S022 Description: 1,WG42428,15/4000uL Date: 15-Jan-2013 Time: 01:21:16 13C2-PFOA FC3G 015S022 100- 7.09 4 2.36e5 942503 %~ 0- . L 7.00 TT min 8.00 13C4-PFOA FC3G 015S022 100- 7.09 A 9.48e4 A 360067 111 %Z 0- ..-- . min 7.00 8.00 13C4-PFOS-1 FC3G 015S022 100- 8.35 1.35e4 53506 0- lipM-.., .. , min 8.00 10.00 12.00 13C4-PFOS-2 FC3G 015S022 100- 8.35 r 1.04e4 p1 38459 %r jj 0 min 8.00 10.00 12.00 1802-PFHxS-1 FC3G 015S022 100n 7.33 1.20e4l 44812 / ' %-- 0 J ^ :*TTi min 7.00 8,00 oo 1802-PFHxS-2 FC3G 015S022 7.33 8.29e3A 32521 \. \ %" 0- : 7.00 13C4-PFBA FC3G_015S022 I100- 5.21 f 3.56e4 136463 % 4.241 kL 5.00 6.00 7.00 13C2-PFHxA FC3G 015S022 100~] 6.34 7.37e4 1 325908 i: %" 13C5-PFNA FC3G_015S022 100 7.49 8.18e4?. 319316 ; ' %- 0" r-- min 5.00 6.00 7.00 0 7.00 8.00 13C2-PFDA FC3G_015S022 7.99 100n 8.54e4 I,i 3 00842 %- 0^4 8.00 10.00 12.00 13C2-PFDoA FC3GJ15S022 100- 9.18 1.52e5 655873 8.00 10.00 12.00 13C2-PFOUEA FC3G_015S022 100- 7.43 2-86e4A %- 7.00 8.00 PV by LEH 15-Jan-13, SV by AP 16-Jan-13. NOTE: OPR Conen. & LOD units = ng/mL, Sample and Lab BLK Conen. & LOD units = ng/L. Page 151 of 307 www.axysanalytical.com Quantify Sample Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\lnst_G\PFC.PRO\FC\FC3G_015-B.qld Last Altered: Tuesday, January 15, 2013 14:23:27 Pacific Standard Time Printed: Wednesday, January 16, 2013 11:54:43 Pacific Standard Time ID: WG42428-101,,BLK Name: FC3G_015S022 Description: 1,WG42428,15/4000uL Date: 15-Jan-2013 Time: 01:21:16 # Name 1 PFBA 2 PFPeA 3 PFHxA 4 PFHpA 5 PFOA-1 6 PFOA-2 7 PFNA 8 PFDA 9 PFUnA 10 PFDoA 11 PFBS-1 12 PFBS-2 13 PFHxS-1 14 PFHxS-2 15 PFHxS-3 16 PFOS-1 17 PFOS-2 18 PFOSA 19 13C2-PFOA 20 13C4-PFOA 21 13C4-PFOS-1 22 13C4-PFOS-2 23 1802-PFHxS~1 24 1802-PFHxS-2 25 13C4-PFBA 26 13C2-PFHxA 27 13C5-PFNA 28 13C2-PFDA 29 13C2-PFDoA 30 13C2-PFOUEA IS# Trace RT 25 212.99>168.98 5.23 26 262.98 >218.... 26 312.97> 268.98 6.36 26 362.97> 318.98 6.68 19 412.97> 368.98 7.09 19 412.97> 168.80 7.14 27 462.96 >418.... 7.49 28 512.96 > 468.... 7.99 28 562.96 >518.... 8.61 29 612.95 >568.... 9.21 23 298.94> 79.96 24 298.94 > 98.95 23 398.84 > 79.96 7.33 24 398.84> 98.96 7.33 23 398.84> 118.70 7.33 21 498.93> 79.96 8.23 22 498.93> 98.96 8.29 21 498 > 78 10.08 20 414.97 > 369.... 7.09 416.97 >371.9 7.09 30 503 > 79.96 8.35 30 503 > 98.96 8.35 30 402.9>84 7.33 30 402.9>103 7.33 30 216.99>171.98 5.21 30 314.97>269.98 6.34 30 467.96>422.97 7.49 30 514.96 >469.96 7.99 30 614.95 > 569.... 9.18 458.98 >393.98 7.43 Area 750 988 3051 883 191 153 1447 298 339 79 22 23 338 115 16 235898 94833 13502 10440 11991 8290 35648 73682 81823 85410 152295 28605 IS Area 35648 73682 73682 73682 235898 235898 81823 85410 85410 152295 11991 8290 11991 8290 11991 13502 10440 13502 94833 28605 28605 28605 28605 28605 28605 28605 28605 28605 ng/L 0.093 0.710 0.125 62.969 28.189 38.987 37.942 41.894 39.106 25.374 26.517 26.165 21.710 24.724 20.787 LOD 0.1117 0.2766 0.2744 0.4157 0.0237 0.0189 0.0749 0.0858 %Rec S/N 10 17 69 0 29 0 13 4 7 87.5 117.5 108.3 105.4 116.4 108.6 105.7 110.5 109.0 90.5 103.0 103.9 5 1 3 7 3 8 0 0 463 422 0 0 194 4093 4487 846 1029 0 Noise 275 286 242 168 0 31 0 356 233 213 44 23 67 60 28 121 73 9 0 0 116 91 0 0 705 80 71 356 638 0 Height 2758 4230 11511 2772 916 839 4513 903 1592 362 66 80 838 242 74 942503 360067 53506 38459 44812 32521 136463 325908 319316 300842 655873 103559 IS Height Sample size 136463 0.5000 325908 0.5000 325908 0.5000 325908 0.5000 942503 0.5000 942503 0.5000 319316 0.5000 300842 0.5000 300842 0.5000 655873 0.5000 44812 0.5000 32521 0.5000 44812 32521 0.5000 0.5000 44812 0.5000 53506 0.5000 38459 0.5000 53506 0.5000 360067 0.5000 0.5000 103559 0.5000 103559 0.5000 103559 0.5000 103559 0.5000 103559 0.5000 103559 0.5000 103559 0.5000 103559 103559 0.5000 0.5000 0.5000 Factor2 Detection... 1.0 MM 1.0 1.0 MMI 1.0 MM 1.0 MMI 1.0 bbl 1.0 MMI 1.0 MMI 1.0 MMI 1.0 MMI 1.0 1.0 1.0 MMI 1.0 MMI 1.0 MMI 1.0 MMI 1.0 MMI 1.0 MM 1.0 MM 1.0 MM 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 MM 1.0 bb 1.0 bb 1.0 bb 1.0 bb PV by LEH 15-Jan-13, SV by AP 16-Jan-13. NOTE: OPR Conen. & LOD units = rig/mL, Sample and Lab BLK Conen. & LOD units = ng/L. C_ _. Page 152 of 307 www.axysanalytical.com Quantify Sample Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\lnst_G\PFC.PRO\FC\FC2G_455-B.qld Last Altered: Tuesday, January 08, 2013 12:06:04 Pacific Standard Time Printed: Thursday, January 10, 2013 12:48:05 Pacific Standard Time ID: WG42273-102,,SPM Name: FC2G_455S007 Description: 1,WG42273,15/4000uL Date: 18-Dec-2012 Time: 19:42:48 PFBA FC2G_455S007 lo o - r.3.8c64 g 131606 IM; X - -m min 5.00 6.00 7.00 PFPeA FC2G 455S007 100- 5.48e4 | 283626 I %~ 8is 0- ............. .IiV H Mmin 5.00 6.00 7.00 PFHxA FC2G 455S007 100- 9.79e4~] 484791 .1 i'i 0~-............... --'-- *-- min 5.00 6.00 7.00 PFHpA FC2G 455S007 100- 1.01e5 '> 432354 %a 0- " min 5.00 6.00 7.00 PFOA-1 FC2G 455S007 100- A 8.80e4 \ 361588 %~ ; > o- -- 7.00 , -----tt min 8.00 PFOA-2 FC2G_455S007 1002 _ 7.11 , 2.41e4 99768 %- o7.00 8.00 PFNA FC2G__4~7554CS007 100- 9.22e4_| 399544 1 /' 7.00 ... t-t min 8.00 PFDA FC2G 455S007 100- F 1-11e5 j 404793 %: . o- min 8.00 10.00 12.00 PFUnA FC2G_455S007 100- (" 1.2765 [j 557533 %- i 0 M ,ill , ' 0 min 8.00 10.00 12.00 PFDoA FC2G 455S007 100-3 F 1.53e5 668149 %- I 0-1 nr min 8.00 10.00 12.00 PFBS-1 FC2G 455S007 100- 2.56e4 ` 126716 i; %z j; A 0J * min 5.00 6.00 7.00 PFBS-2 FC2G_455S007 100-} 6.47 65901 %- o5.00 6.00 7.00 PFHxS-1 FC2G_455S007 100 2.'12e4 ?: 76588 min 7.00 8.00 PFHxS-2 FC2G 455S007 100- . ' 1.18e4 / \ 43383 %- o- -- 2 -- 7.00 -r min 8.00 PFHxS-3 FC2G 455S007 400- A 7.28e3 : i 26303 %~ 0J 7.00 -- min 8.00 PFOS-1 FC2G 455S007 100- r 1.95e4 1 53920 9.90 0- min LOO 10.00 12.00 PFOS-2 FC2G 455S007 100- ! 1.35e4 H 44854 %z 0-* min 8.00 10.00 12.00 PFOSA FC2G 455S007 100- 2.36e4] 80783 !! %: ii 0-* - .... 8.00 10.00 12.00 PV by LHE 08-Jan-13, SV by AP 10-Jan-13. NOTE: OPR Conen. & LOD unite = ng/mL, Sample and Lab BLK Conen. & LOD units = ng/L. 10 Page 153 of 307 www.axysanalytical.com Quantify Sample Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\lnst_G\PFC.PRO\FC\FC2G^455-B.qld Last Altered: Tuesday, January 08, 2013 12:06:04 Pacific Standard Time Printed: Thursday, January 10, 2013 12:48:05 Pacific Standard Time ID: WG42273-102,,SPM Name: FC2G_455S007 Description: 1,WG42273,15/4000uL Date: 18-Dec-2012 Time: 19:42:48 13C2-PFOA FC2G 455S007 100n 7.11 f 1.51e5 |4 616888 ` %~ / ~X., 7.00 8.00 13C4-PFOA FC2G 455S007 100- 7.11 f 5.36e4 M214360 %- 13C4-PFOS-1 FC2G 455S007 100- 8.23 f 8.56e3 | 30493 %- 0 - / x -.. -7-r min 7.00 8.00 08.00 10.00 12.00 13C4-PFBA FC2G 455S007 100- 5.11 f2.32e4 1 73392 %- CqO o- ----^---------1------------------ min 5.00 6.00 7.00 13C2-PFHxA FC2G 455S007 100-- 6.34 5.39e4 281173 > %- i 0~----------------- l-- 5.00 6.00 7.00 13C5-PFNA FC2G 455S007 13C4-PFOS-2 FC2G 455S007 100n 8.23 I 6.39e3 I 23217 %~ 1| || o8.00 10.00 , min 12.00 1802-PFHxS-1 FC2G 455S007 100-j 7.30 ^ 7.93e3 f \ 30189 /r 0- / 7.00 .. . min 8.00 1802-PFHxS-2 FC2G 455S007 100- 7.25 A 5.98e3 / \ 23816 %- 0- 1 7.00 8.00 13C2-PFDA FC2G_455S007 100- _ 7.93 5.49e4 i 201955 %- 13C2-PFDoA FC2G__455S007 100- 9.06 f" 9.83e4 446526 %- 13C2-PFOUEA FC2G 455S007 i-L- 8.00 10.00 12.00 8.00 10.00 12.00 PV by LHE 08-Jan-13, SV by AP 10-Jan-13. NOTE: OPR Conen. & LOD units = ng/mL, Sample and Lab BLK Conen. & LOD units = ng/L. Page 154 of 307 www.axysanalytical.com Quantify Sample Report MassLynx 4.1 SCN627 Dataset: G:\Massiynx\lnst_G\PFC.PRO\FC\FC2G_455-B.qld Last Altered: Tuesday, January 08, 2013 12:06:04 Pacific Standard Time Printed: Thursday, January 10, 2013 12:48:05 Pacific Standard Time ID: WG42273-102,,SPM Name: FC2G_455S007 Description: 1,WG42273,15/4000uL Date: 18-Dec-2012 Time: 19:42:48 # Name 1 PFBA 2 PFPeA 3 PFHxA 4 PFHpA 5 PFOA-1 6 PFOA-2 7 PFNA 8 PFDA 9 PFUnA 10 PFDoA 11 PFBS-1 12 PFBS-2 13 PFHxS-1 14 PFHxS-2 15 PFHxS-3 16 PFOS-1 17 PFOS-2 18 PFOSA 19 13C2-PFOA 20 13C4-PFOA 21 13C4-PFOS-1 22 13C4-PFOS-2 23 1802-PFHxS-1 24 1802-PFHxS-2 25 13C4-PFBA 26 13C2-PFHxA 27 13C5-PFNA 28 13C2-PFDA 29 13C2-PFDoA 30 13C2-PFOUEA IS# Trace RT 25 212.99>168.98 5.11 26 262.98 > 218.... 5.95 26 312.97> 268.98 6.34 26 362.97> 318,98 6.69 19 412.97> 368.98 7.11 19 412.97> 168.80 7.11 27 462.96 >418.... 7.46 28 512.96 >468.... 7.93 28 562.96 >518.... 8.50 29 612.95 >568.... 9.06 23 298.94> 79.96 6.45 24 298.94 > 98.95 6.47 23 398.84 > 79.96 7.30 24 398.84> 98.96 7.30 23 398.84> 118.70 7.30 21 498.93> 79.96 8.23 22 498.93> 98.96 8.23 21 498 > 78 9.90 20 414.97 > 369.... 7.11 416.97 >371.9 7.11 30 503 > 79.96 8.23 30 503 > 98.96 30 402.9>84 8.23 7.30 30 402.9>103 7.25 30 216.99>171.98 5.11 30 314.97>269,98 6.34 30 467.96>422.97 7.46 30 514.96 >469.96 7.93 30 614.95 > 569.... 9.06 458.98 >393.98 7.39 Area 38623 54795 97900 101464 88021 24078 92152 110967 126707 152836 25582 13860 21175 11791 7278 19513 13536 23624 150918 53590 8562 6394 7930 5976 23236 53882 53397 54892 98261 20751 IS Area 23236 53882 53882 53882 150918 150918 53397 54892 54892 98261 7930 5976 7930 5976 7930 8562 6394 8562 53590 20751 20751 20751 20751 20751 20751 20751 20751 20751 ng/L 19.001 17.749 19.999' 19.031 19.476 20.396 19.805 22.765 20.906 20.176 43.287 39.868 40.075 36.686 41.211 38.784 43.532 22.482 33.307 12.892 16.622 16.760 17.729 18.756 10.555 11.369 11.352 9.640 11.746 10.609 LOD 0.0476 0.1425 0.1427 0.0310 0.0422 0.0974 0.3304 0.2250 0.3883 0.2360 0.1440 0.1411 0.0971 0.0431 0.1417 0.0128 0.0082 0.0619 0.0992 0.1256 %Rec 95.0 88.7 100.0 95.2 97.4 102.0 99.0 113.8 104.5 100.9 108.2 99.7 100.2 91.7 103.0 97.0 108.8 112.4 92.5 107.4 92.3 93.1 98.5 104.2 88.0 94.7 94.6 80.3 97.9 106.1 S/N 429 1429 5471 2295 0 0 1979 1080 1195 2966 2429 1243 0 0 0 157 384 1021 0 269 313 468 0 1295 176 3468 4426 428 401 253 Noise 307 198 89 188 0 0 202 375 466 225 52 53 0 0 0 343 117 79 0 798 97 50 0 18 418 81 52 472 1112 329 Height 131606 283626 484791 432354 361588 99768 399544 404793 557533 668149 126716 65901 76588 43383 26303 53920 44854 80783 616888 214360 30493 23217 30189 23816 73392 281173 229687 201955 446526 83449 IS Height 73392 281173 281173 281173 616888 616888 229687 201955 201955 446526 30189 23816 30189 23816 30189 30493 23217 30493 214360 83449 83449 83449 83449 83449 83449 83449 83449 83449 Sample size 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1-0000 Factor2 Detection... 1.0 bb 1.0 bb 1.0 MM 1.0 bb 1.0 bb 1.0 bb 1.0 MM 1.0 bb 1.0 bb 1.0 bb 1,0 bb 1.0 bb 1.0 MM 1.0 MM 1.0 MM 1,0 MM 1.0 MM 1.0 MM 1.0 bb 1.0 bb 1.0 MM 1.0 MM 1.0 MM 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 bb PV by LHE 08-Jan-13, SV by AP 10-Jan-13. NOTE: OPR Conen. & LOD units = ng/mL, Sample and Lab BLK Conen. & LOD units = ng/L. Page 155 of 307 www.axysanalytical.com Quantify Sample Report MassLynx 4.1 SCN627 Dataset: G :\M as s ly nx \ln s t_ G \P F C .P R O \F C \F C 3G _ 015-B.qld Last Altered: Tuesday, January 15, 2013 14:23:27 Pacific Standard Time Printed: Wednesday, January 16, 2013 11:54:43 Pacific Standard Time ID: WG42428-102,,SPM Name: FC3G_015S019 Description: 1,WG42428,15/4000uL Date: 15-Jan-2013 Time: 00:30:21 PFBA FC3G 015S019 100- 5.19 A 6.14e4 ;; 242972 h f: \ o- rrr min 5.00 6.00 7.00 PFPeA FC3G 015S019 100m 5.93 7.67e4 1 327328 1 %- 05.00 6.00 7.00 PFNA FC3G 015S019 PFDA FC3G_015S019 7.99 100^ f 1.68e5 | 602678 PFHxS-1 FC3G__015S019 100 _ 7.33 3.46e4 | 128809 %- 07.00 8.00 _ 8.00 10.00 12.00 PFHxS-2 FC3G__015S019 7.33 100m 1.86e4 A :67739 l \ %- 7.00 8.00 PFHxA FC3G 015S019 100- 6.33 1.46e5l 655296 ;; %~ !: 5.00 6.00 7.00 PFUnA FC3G_015S019 100- 8.58 f 1.88e5 842752 %' 8.00 10.00 12.00 PFHxS-3 FC3G 0155019 PFHpA FC3G 015S019 100- 6.73 1.40e5 568185 % j V*nfr?r mi.n 5.00 6.00 7.00 PFOA-1 FC3G 015S019 100- 7.09 m 1.46e5 579316 %-- 0- . - TM -r-T min 7.00 8.00 PFOA-2 FC3G 015S019 100- 7.09 !'\ 3.37e4 ; 135987 %- 0- i 7.00 i 8.00 PFDoA FC3G 15S019 100" 9.18 F 2.45e5 |! 1086839 PFBS-1 FC3G_015S019 6.47 _ 100- 3.95e4 175396 %- PFBS-2 FC3G_015S019 100m 6.47 2 .0 7 e 4 l 90863 !! 8.00 10.00 12.00 PFOS-1 FG3G 015S019 r ------- -- -- ^ 5.00 6.00 7.00 PFOS-2 FC3G_015S019 100- _ 8.35 2.25e4 70707 %- 11 - 8.00 10.00 12.00 5.00 6.00 7.00 PFOSA FC3G_015S019 9.99 100- 2.60e4 | 91252 I %-- 8.00 10.00 12.00 PV by LEH 15-Jan-13, SV by AP 16-Jan-13. NOTE: OPR Conen. & LOD units = ng/mL, Sample and Lab BLK Conen. & LOD units = ng/L. Page 156 of 307 www.axysanalytical.com Quantify Sample Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\lnst_G\PFC.PRO\FC\FC3G_015-B.qld Last Altered: Tuesday, January 15, 2013 14:23:27 Pacific Standard Time Printed: Wednesday, January 16, 2013 11:54:43 Pacific Standard Time ID: WG42428-102,,SPM Name: FC3G_015S019 Description: 1,WG42428,15/4000uL Date: 15-Jan-2013 Time: 00:30:21 13C2-PFOA FC3G 015S019 100n 7.09 i2.17e5 Q861524 %" 13C4-PFOA FC3G 015S019 100- 7.09 j f 9.14e4 f \ 373243 %- 0- -- ------- ------m t -t min 7.00 8.00 i 7.00 | 8.00 13C4-PFBA FC3GJ315S019 100- 5.21 F 3.59e4 A 138692 %- -4.03 13C2-PFHxA FC3G_015S019 6.33 100- 6:85e4 309223 %- 5.00 6.00 7.00 5.00 6.00 7.00 13C4-PFOS-1 FC3G_015S019 1001 8.35 1.20e4 44307 %: 0- 8.00 10.00 12.00 13C5-PFNA FC3G_015S019 100- 7.49 7.52e4 A 304183 I \ %- 7.00 8.00 13C4-PFOS-2 FC3G_015S019 100 _ 8.35 9.85e3 36201 %' 8.00 10.00 12.00 13C2-PFDA FC3GJ)i5S019 100- 7.99 F 8.25e4 f: 293260 i\ %- 8.00 10.00 12.00 1802-PFHXS-1 FC3G_015S019 100~- 7 -3 3 _ 1,14e4 l| " 44529 R %-- 7.00 8.00 13C2-PFDoA FC3GJ015S019 100-1 9.18 f" 1.50e5 I 668909 8.00 10;00 12.00 1802 -PFHxS-2 FC3G 015S019 100- 7.29 f7.93e3 . 1||29137 7.00 8.00 13C2-PFOUEA FC3G,,015S019 100- 7.38 2.98e4 - 113697 f | %- /\ ------J.---- -- . 7.00 8.00 PV by LEH 15-Jan-13, SV by AP 16-Jan-13. NOTE: OPR Conen. & LOD units = ng/mL, Sample and Lab BLK Conen. & LOD units = ng/L. Page 157 of 307 www.axysanalytical.com Quantify Sample Report MassLynx 4,1 SCN627 Dataset: G:\Masslynx\lnst_G\PFC.PRO\FC\FC3G_015-B.qld Last Altered: Tuesday, January 15, 2013 14:23:27 Pacific Standard Time Printed: Wednesday, January 16, 2013 11:54:43 Pacific Standard Time ID: WG42428-102,,SPM Name: FC3G_Q15S019 Description: 1,WG42428,15/4000uL Date: 15-Jan-2013 Time: 00:30:21 # Name 1 PFBA 2 PFPeA 3 PFHxA 4 PFHpA 5 PFOA-1 6 PFOA-2 7 PFNA 8 PFDA 9 PFUnA 10 PFDoA 11 PFBS-1 12 PFBS-2 13 PFHxS-1 14 PFHxS-2 15 PFHxS-3 16 PFOS-1 17 PFOS-2 18 PFOSA 19 13C2-PFOA 20 13C4-PFOA 21 13C4-PFOS-1 22 13C4-PFOS-2 23 1802-PFHxS-1 24 1802-PFHxS-2 25 13C4-PFBA 26 13C2-PFHX 27 13C5-PFNA 28 13C2-PFDA 29 13C2-PFDoA 30 13C2-PFOUEA IS# Trace RT 25 212.99>168.98 5.19 26 262.98 >218.... 5.93 26 312.97> 268.98 6.33 26 362.97> 318.98 6.73 19 412.97> 368.98 7.09 19 412.97> 168.80 7.09 27 462.96 >418.... 7.49 28 512.96 >468.... 7.99 28 562.96 >518.... 8.58 29 612.95 >568.... 9.18 23 298.94> 79.96 6.47 24 298.94 > 98.95 6.47 23 398.84 > 79.96 7.33 24 398.84> 98.96 7.33 23 398.84> 118.70 7.33 21 498.93> 79.96 8.35 22 498.93> 98.96 8.35 21 498 > 78 9.99 20 414.97 > 369.... 7.09 416.97 >371.9 7.09 30 503 > 79.96 8.35 30 503 > 98.96 8.35 30 402.9>84 7.33 30 402.9>103 7.29 30 216.99>171.98 5.21 30 314.97>269.98 6.33 30 467.96>422.97 7.49 30 514.96 >469.96 7.99 30 614.95 >569.... 9.1:8 458.98 >393.98 7.38 Area 61431 76675 145635 140305 145709 33686 134348 167763 188112 245386 39499 20661 34616 18554 10103 33380 22503 26025 217149 91367 11956 9846 11355 7931 35927 68491 75185 82535 149576 29758 IS Area 35927 68491 68491 68491 217149 217149 75185 82535 82535 149576 11355 7931 11355 7931 11355 11956 9846 11956 91367 29758 29758 29758 29758 29758 29758 29758 29758 29758 ng/L 19.238 19.201 22.266 21.141 23.709 22.684 21.815 22.345 23.057 22.506 44.406 44.042 43.108 41.942 41.538 46.832 42.920 23.726 30.081 13.579 16.594 17.199 19.067 17.981 12.291 11.847 11.556 10.083 11.671 10.812 LOD 0.0133 2.0076 0.1034 0.0757 0.1837 0.1068 0.1062 0.3346 0.0948 0.0181 0.0058 0.0483 0.1077 %Rec 96.2 96.0 111.3 105.7 118.5 113.4 109.1 111.7 115.3 112.5 111.0 110.1 107.8 104.9 103.8 117.1 107.3 118.6 83.6 113.2 92.2 95.6 105.9 99.9 102.4 98.7 96.3 84.0 97.3 108.1 S/N 692 973 2870 1760 0 524 23501508 2553 1648 3174 5257 0 3256 49 398 315 2656 0 222 452 468 175 0 393 2318 6290 583 380 0 Noise 351 337 228 323 0 260 229 400 330 660 55 17 0 21 728 240 224 34 0 1683 98 77 254 0 353 133 48 503 1758 0 Height 242972 327328 655296 568185 579316 135987 537357 602678 842752 1086839 175396 90863 128809 67739 35944 95358 70707 91252 861524 373243 44307 36201 44529 29137 138692 309223 304183 293260 668909 113697 IS Height 138692 309223 309223 309223 861524 861524 304183 293260 293260 668909 44529 29137 44529 29137 44529 44307 36201 44307 373243 113697 113697 113697 113697 113697 113697 113697 113697 113697 Sample size 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 Factor2 Detection... 1.0 bb 1.0 bb 1.0 MM 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 MM 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 MM 1.0 MM 1.0 MM 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 MM 1.0 bb 1.0 bb PV by LEH 15-Jan-13, SV byAP 16-Jan-13. NOTE: OPR Conen. & LOD units = ng/mL, Sample and Lab BLK Conen. & LOD units = ng/L. Page 158 of 307 www.axysanalytical.com __________________________ PR- _____________________ Sample List Report MassLynx4.1 SCN627 Sample List: G:\Massiynx\lnst_G\_Master.PRO\SampieDB\FC2G_445.SPL Last Modified: Thursday, December 13, 2012 11:30:57 Pacific Standard Time Printed: Thursday, December 13, 2012 14:52:46 Pacific Standard Time Page 1of 1 Page Position (1,1) File Name Sample ID File Text Bottle 1 FC2G_445S001 MeOH,, . 2 FC2G_445S002 MeOH,, 3 FC2G_445S003 FC-LIN-42221W500-A,, 4 FC2G_445S004 FC-LIN-42221W500-A,, 5 FC2G_445S005 FC-LIN-42221W500-B,, 6 FC2G_445S006 FC-LIN-42221W500-C,, 7 FC2G_445S007 FC-LIN-42221W500-D,, 8 FC2G_445S008 FC-LIN-42221W500-E,, 9 FC2G_445S009 FC-LIN-42221W50Q-F,, 10 FC2G_445S010 FC-LIN-42221W500-G,, 11 FC2G_445S011 FC-LIN-42221W500-H,, 12 FC2G_445S012 MeOH,, 13 FC2G_445S013 MeOH,, 14 FC2G_445S014 FC-42221W500-SAR2,, 15 FC2G_445S015 FC-42221W500-SAR,, 16 FC2G_445S016 FC-LIN-42221W500-D,, 17 FC2G_445S017 FC-LIN-42221W500-D,, 18 FC2G_445S018 WG42214-1Q3,,SAR 19 FC2G_445S019 WG42214-102,,SPM 20 FC2G_445S02Q MeOH,, 21 FC2G_445S021 MeOH,, 22 FC2G_445S022 WG42214-101,,BLK 23 FC2G_445S023 L18938-1,, 24 FC2G_445S024 L18938-2,, 25 FC2G_445S025 L18938-3,, 26 FC2G_445S026 L18955-1,, 27 FC2G_445S027 L18955-2,, 28 FC2G_445S028 L18955-3,, 29 FC2G_445S029 L18955-4,, 30 FC2G__445S030 L18955-5,, 31 FC2G_445S031 L18955-6,, 32 FC2G_445S032 L18955-7,, 33 FC2G_445S033 L18970-1,, 34 FC2G_445S034 L18970-2,, 35 FC2G_445S035 L18970-3,, 36 FC2G_445S036 L18970-4,, 37 FC2G_445S037 FC-LIN-42221W500-D,, 38 FC2G_445S038 FC-LIN-42221W500-D,, 39 FC2G_445S039 MeOH,, 40 FC2G 445S040 MeOH,, 1,,15uL 1:8,A 1,,15uL 1:8,A 1,,15uL 1:1,A 1,,15uL 1:1,A 1., 15uL 1:1,B 1,, 15uL 1:1,C 1., 15uL 1:1,D 1,,15uL 1:1,E 1,,15uL 1:1,F 1.. 15uL 1:2,A 1,,15uL 1:2,B 1..15uL 1:8,A 1,,15uL 1:8,A 1,,15uL 1:2,C 1,,15uL 1:2,D 1,,15uL 1:1,D 1,,15uL 1:1,D 1,WG42214,15/4000uL 1:2,E 1,WG42214,15/4000uL 1:2,F 1,,15uL 1:8,A 1,,15uL 1:8,A 1,WG42214,15/4000uL 1:6,E 1,WG42214,15/4000uL 1:6,F 1,WG42214,15/4000uL 1:7,A 1.WG42214,15/4000uL 1:7,B 1,WG42214,15/4000uL 1:7,C 1.WG42214,15/4000uL 1:7,D 1,WG42214,15/4000uL 1:7,E 1,WG42214,15/4000uL 1:7,F 1,WG42214,15/4000uL 1:8,B 1,WG42214,15/4000uL 1:8,C 1,WG42214,l5/4000uL 1:8,D 1,WG42214,15/4000uL 1:8,E 1,WG42214,15/4000uL 1:8,F 1,WG42214,15/4000uL 1:4,E 1.WG42214,15/4000uL 1:4,F 1,,15uL 1:1,D 1,,15uL 1:1,D 1,,15uL 1:8,A 1,,15uL 1:8,A SignOut Inj VoL & 15.0 I - 15.0 15.0 15.0 15.0 I 15.0 15.0 J 15.0 15.0 15.0 15.0 15.0 15.0 15.0 15.0 15.0 15.0 15.0 15.0 15.0 15.0 15.0 15.0 15.0 15.0 15.0 15.0 15.0 15.0 15.0 15.0 15.0 15.0 15.0 15.0 15.0 Page 159 of 307 www.axysanalytical.com Quantify Compound Summary Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\Inst_G\PFC.PRO\FC\FC2G_445-A1 .qld Last Altered: Friday, December 14, 2012 11:01:10 Pacific Standard Time Printed: Sunday, December 16, 2012 09:33:39 Pacific Standard Time Method: G:\Masslynx\Master Methods\PFC\FC_060_10_01.mdb 03 Dec 2010 17:21:03 Calibration: 14 Dec 2012 11:01:10 Compound name: PFBA # ID Name Type RT 1 FC -LIN-42221W 500-A ,, FC2G_445S004 Standard 5.13 2 FC -LIN-42221W 500-B ,, FC2G_445S005 Standard 5.16 3 FC-LIN-42221W 500-C,, FC2G_445S006 Standard 5.14 4 FC-LIN-42221W 500-D,, FC2G_445S007 Standard 5.18 5 FC-LIN-42221W 500-E,, FC 2G _ 4 45 S 0 0 8 Standard 5.11 6 FC-LIN-42221W 500-F,, FC2G_445S009 Standard 5.14 7 F C -LIN -42221W 500-G ,, FC 2G _ 4 45 S 0 1 0 Standard 5.11 8 FC-LIN-42221W 500-H,, FC 2G _445S011 Standard 5.20 Area 1702 3260 11699 42289 213591 421406 953630 1826622 IS Area 29460 25526 29193 27354 24645 25200 21251 16912 Std. Conc 0.500 1.250 5.000 20.000 100.000 200.000 500.000 1250.000 Compound name: PFBA Coefficient of Determination: RA2 = 0.999416 Calibration curve: -2.74527e-006 * xA2 + 1.0445 * x + 0.100781 Response type: Internal Std ( Ref 25 ), Area * ( IS Conc. / IS Area ) Curve type: 2nd Order, Origin: Exclude, Weighting: 1/x, Axis trans: None ng/L 0.567 1.371 4.508 17.665 99.497 192.121 516.166 1244.856 %Rec 113.5 109.7 90.2 88.3 99.5 96.1 103.2 99.6 S/N 30 40 49 90 2015 2159 3615 12024 Acq.Date 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 Acq.Time 16:56:55 17:14:37 17:32:19 17:50:01 18:07:43 18:24:28 18:4 1 :21 18:58:15 Detection... MM MM MM MM MM MM MM MM PV by LIU 14-Dec-12, SV by AP 16-Dec-12. NOTE: Std. Concn. & LOD units = ng abs. Excluded points denoted with an 'X' in the Detection Flag column. Page 160 of 307 www.axysanalytical.com Quantify Compound Summary Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\Inst_G\PFC.PRO\FC\FC2G_445-A1 .qld Last Altered: Friday, December 14, 2012 11:01:10 Pacific Standard Time Printed: Sunday, December 16, 2012 09:33:39 Pacific Standard Time Compound name: PFPeA # ID Name Type RT 1 FC -LIN-42221W 500-A ,, FC2G_445S004 Standard 5.96 2 FC -LIN-42221W 500-B ,, FC2G_445S005 Standard 5.96 3 FC-LIN-42221W 500-C,, FC2G_445S006 Standard 5.98 4 FC-LIN-42221W 500-D,, FC2G_445S007 Standard 5.98 5 FC-LIN-42221W 500-E,, FC2G_445S008 Standard 5.96 6 FC-LIN-42221W 500-F,, FC2G_445S009 Standard 5.98 7 FC-LIN-42221W 500-G ,, FC2G_445S010 Standard 5.95 8 FC-LIN-42221W 500-H,, FC 2G _445S011 Standard 5.98 Area 1948 4081 15995 60142 293936 566115 1246496 2438345 IS Area 66835 60698 64980 58266 53679 48323 43496 35274 Std. Conc 0.500 1.250 5.000 20.000 100.000 200.000 500.000 1250.000 Compound name: PFPeA Coefficient of Determination: RA2 = 0.999656 Calibration curve: -2.17e-005 * xA2 + 0.692047 * x + -0.0732216 Response type: Internal Std ( Ref 26 ), Area * ( IS Conc. / IS Area ) Curve type: 2nd Order, Origin: Exclude, Weighting: 1/x, Axis trans: None ng/L 0.611 1.272 4.375 18.014 95.340 204.560 505.025 1247.545 %Rec 122.3 101.7 87.5 90.1 95.3 102.3 101.0 99.8 S/N 86 92 325 742 10920 11971 41155 36887 Acq.Date 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 Acq.Time 16:56:55 17:14:37 17:32:19 17:50:01 18:07:43 18:24:28 18:4 1 :21 18:58:15 Detection... MM MM MM MM MM MM MM MM PV by LIU 14-Dec-12, SV by AP 16-Dec-12. NOTE: Std. Concn. & LOD units = ng abs. Excluded points denoted with an 'X' in the Detection Flag column. Page 161 of 307 www.axysanalytical.com Quantify Compound Summary Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\Inst_G\PFC.PRO\FC\FC2G_445-A1 .qld Last Altered: Friday, December 14, 2012 11:01:10 Pacific Standard Time Printed: Sunday, December 16, 2012 09:33:39 Pacific Standard Time Compound name: PFHxA # ID Name Type RT 1 FC -LIN-42221W 500-A ,, FC2G_445S004 Standard 6.37 2 FC -LIN-42221W 500-B ,, FC2G_445S005 Standard 6.36 3 FC-LIN-42221W 500-C,, FC2G_445S006 Standard 6.37 4 FC-LIN-42221W 500-D,, FC2G_445S007 Standard 6.37 5 FC-LIN-42221W 500-E,, FC2G_445S008 Standard 6.36 6 FC-LIN-42221W 500-F,, FC2G_445S009 Standard 6.36 7 FC-LIN-42221W 500-G ,, FC2G_445S010 Standard 6.32 8 FC-LIN-42221W 500-H,, FC 2G _445S011 Standard 6.36 Area 3763 7458 27050 100408 472991 888540 1813293 3315686 IS Area 66835 60698 64980 58266 53679 48323 43496 35274 Std. Conc 0.500 1.250 5.000 20.000 100.000 200.000 500.000 1250.000 Compound name: PFHxA Coefficient of Determination: RA2 = 0.999663 Calibration curve: -0.000150762 * xA2 + 1.08956 * x + 0.0730969 Response type: Internal Std ( Ref 26 ), Area * ( IS Conc. / IS Area ) Curve type: 2nd Order, Origin: Exclude, Weighting: 1/x, Axis trans: None ng/L 0.553 1.286 4.521 18.962 98.317 208.462 492.664 1252.147 %Rec 110.6 102.9 90.4 94.8 98.3 104.2 98.5 100.2 S/N 85 211 611 3750 10164 21372 61073 44296 Acq.Date 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 Acq.Time 16:56:55 17:14:37 17:32:19 17:50:01 18:07:43 18:24:28 18:4 1 :21 18:58:15 Detection... MM MM MM MM MM MM MM MM PV by LIU 14-Dec-12, SV by AP 16-Dec-12. NOTE: Std. Concn. & LOD units = ng abs. Excluded points denoted with an 'X' in the Detection Flag column. Page 162 of 307 www.axysanalytical.com Quantify Compound Summary Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\Inst_G\PFC.PRO\FC\FC2G_445-A1 .qld Last Altered: Friday, December 14, 2012 11:01:10 Pacific Standard Time Printed: Sunday, December 16, 2012 09:33:39 Pacific Standard Time Compound name: PFHpA # ID Name Type RT 1 FC -LIN-42221W 500-A ,, FC2G_445S004 Standard 6.74 2 FC -LIN-42221W 500-B ,, FC2G_445S005 Standard 6.74 3 FC-LIN-42221W 500-C,, FC2G_445S006 Standard 6.74 4 FC-LIN-42221W 500-D,, FC2G_445S007 Standard 6.74 5 FC-LIN-42221W 500-E,, FC2G_445S008 Standard 6.74 6 FC-LIN-42221W 500-F,, FC2G_445S009 Standard 6.74 7 FC-LIN-42221W 500-G ,, FC2G_445S010 Standard 6.69 8 FC-LIN-42221W 500-H,, FC 2G _445S011 Standard 6.74 Area 3179 6544 28341 104254 530786 1004495 2055822 4086324 IS Area 66835 60698 64980 58266 53679 48323 43496 35274 Std. Conc 0.500 1.250 5.000 20.000 100.000 200.000 500.000 1250.000 Compound name: PFHpA Coefficient of Determination: RA2 = 0.999397 Calibration curve: -6.94479e-005 * xA2 + 1.19636 * x + -0.14655 Response type: Internal Std ( Ref 26 ), Area * ( IS Conc. / IS Area ) Curve type: 2nd Order, Origin: Exclude, Weighting: 1/x, Axis trans: None ng/L 0.600 1.204 4.498 18.089 99.883 211.217 488.032 1253.279 %Rec 119.9 96.3 90.0 90.4 99.9 105.6 97.6 100.3 S/N 56 77 548 1098 11928 13584 22109 87183 Acq.Date 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 Acq.Time 16:56:55 17:14:37 17:32:19 17:50:01 18:07:43 18:24:28 18:4 1 :21 18:58:15 Detection... MM MM MM MM MM MM MM MM PV by LIU 14-Dec-12, SV by AP 16-Dec-12. NOTE: Std. Concn. & LOD units = ng abs. Excluded points denoted with an 'X' in the Detection Flag column. Page 163 of 307 www.axysanalytical.com Quantify Compound Summary Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\Inst_G\PFC.PRO\FC\FC2G_445-A1 .qld Last Altered: Friday, December 14, 2012 11:01:10 Pacific Standard Time Printed: Sunday, December 16, 2012 09:33:39 Pacific Standard Time Compound name: PFOA-1 # ID Name Type RT 1 F C -L IN -4 2 22 1 W 5 0 0-A ,, FC 2G _ 4 45 S 0 0 4 Standard 7.11 2 F C -L IN -4 2 22 1 W 5 0 0-B ,, FC 2G _ 4 45 S 0 0 5 Standard 7.11 3 FC-LIN-42221W 500-C,, FC 2G _ 4 45 S 0 0 6 Standard 7.11 4 FC-LIN-42221W 500-D,, FC 2G _ 4 45 S 0 0 7 Standard 7.11 5 FC-LIN-42221W 500-E,, FC 2G _ 4 45 S 0 0 8 Standard 7.11 6 FC-LIN-42221W 500-F,, FC 2G _ 4 45 S 0 0 9 Standard 7.11 7 FC-LIN-42221W 500-G ,, FC2G_445S010 Standard 7.06 8 FC-LIN-42221W 500-H,, F C 2 G _ 4 4 5 S 0 1 1 Standard 7.11 Area 3480 6169 25268 94311 452340 853031 1776266 3356814 IS Area 178974 163290 176604 164434 147281 145888 125019 100831 Std. Conc 0.500 1.250 5.000 20.000 100.000 200.000 500.000 1250.000 Compound name: PFOA-1 Coefficient of Determination: RA2 = 0.999878 Calibration curve: -9.37217e-005 * xA2 + 1.07512 * x + 0.092653 Response type: Internal Std ( Ref 19 ), Area * ( IS Conc. / IS Area ) Curve type: 2nd Order, Origin: Exclude, Weighting: 1/x, Axis trans: None ng/L 0.565 1.179 4.707 19.151 103.692 199.162 497.215 1251.114 %Rec 113.0 94.3 94.1 95.8 103.7 99.6 99.4 100.1 S/N 85 32 0 1407 0 0 0 0 Acq.Date 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 Acq.Time 16:56:55 17:14:37 17:32:19 17:50:01 18:07:43 18:24:28 18:4 1 :21 18:58:15 Detection... MM MM MM MM MM MM MM MM PV by LIU 14-Dec-12, SV by AP 16-Dec-12. NOTE: Std. Concn. & LOD units = ng abs. Excluded points denoted with an 'X' in the Detection Flag column. Page 164 of 307 www.axysanalytical.com Quantify Compound Summary Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\Inst_G\PFC.PRO\FC\FC2G_445-A1 .qld Last Altered: Friday, December 14, 2012 11:01:10 Pacific Standard Time Printed: Sunday, December 16, 2012 09:33:39 Pacific Standard Time Compound name: PFOA-2 # ID Name Type RT 1 F C -L IN -4 2 22 1 W 5 0 0-A ,, FC 2G _ 4 45 S 0 0 4 Standard 7.11 2 F C -L IN -4 2 22 1 W 5 0 0-B ,, FC 2G _ 4 45 S 0 0 5 Standard 7.11 3 FC-LIN-42221W 500-C,, FC 2G _ 4 45 S 0 0 6 Standard 7.11 4 FC-LIN-42221W 500-D,, FC 2G _ 4 45 S 0 0 7 Standard 7.11 5 FC-LIN-42221W 500-E,, FC 2G _ 4 45 S 0 0 8 Standard 7.11 6 FC-LIN-42221W 500-F,, FC 2G _ 4 45 S 0 0 9 Standard 7.11 7 FC-LIN-42221W 500-G ,, FC2G_445S010 Standard 7.06 8 FC-LIN-42221W 500-H,, F C 2 G _ 4 4 5 S 0 1 1 Standard 7.11 Area 659 1818 6596 22890 113491 221628 480485 888554 IS Area 178974 163290 176604 164434 147281 145888 125019 100831 Std. Conc 0.500 1.250 5.000 20.000 100.000 200.000 500.000 1250.000 Compound name: PFOA-2 Coefficient of Determination: RA2 = 0.999698 Calibration curve: -2.23765e-005 * xA2 + 0.282497 * x + -0.00875009 Response type: Internal Std ( Ref 19 ), Area * ( IS Conc. / IS Area ) Curve type: 2nd Order, Origin: Exclude, Weighting: 1/x, Axis trans: None ng/L 0.500 1.450 4.793 17.796 99.005 196.690 510.440 1245.993 %Rec 100.0 116.0 95.9 89.0 99.0 98.3 102.1 99.7 S/N 50 96 0 0 0 0 0 0 Acq.Date 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 Acq.Time 16:56:55 17:14:37 17:32:19 17:50:01 18:07:43 18:24:28 18:4 1 :21 18:58:15 Detection... bb bb bb bb bb bb bb bb PV by LIU 14-Dec-12, SV by AP 16-Dec-12. NOTE: Std. Concn. & LOD units = ng abs. Excluded points denoted with an 'X' in the Detection Flag column. Page 165 of 307 www.axysanalytical.com Quantify Compound Summary Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\Inst_G\PFC.PRO\FC\FC2G_445-A1 .qld Last Altered: Friday, December 14, 2012 11:01:10 Pacific Standard Time Printed: Sunday, December 16, 2012 09:33:39 Pacific Standard Time Compound name: PFNA # ID Name Type RT 1 FC -LIN-42221W 500-A ,, FC2G_445S004 Standard 7.49 2 FC -LIN-42221W 500-B ,, FC2G_445S005 Standard 7.46 3 FC-LIN-42221W 500-C,, FC2G_445S006 Standard 7.49 4 FC-LIN-42221W 500-D,, FC2G_445S007 Standard 7.49 5 FC-LIN-42221W 500-E,, FC2G_445S008 Standard 7.49 6 FC-LIN-42221W 500-F,, FC2G_445S009 Standard 7.49 7 FC-LIN-42221W 500-G ,, FC2G_445S010 Standard 7.46 8 FC-LIN-42221W 500-H,, FC 2G _445S011 Standard 7.49 Area 2996 6297 26363 95907 471902 917096 1926313 3754168 IS Area 61446 64296 62761 57763 52387 51976 44006 33246 Std. Conc 0.500 1.250 5.000 20.000 100.000 200.000 500.000 1250.000 Compound name: PFNA Coefficient of Determination: RA2 = 0.999897 Calibration curve: 2.97143e-005 * xA2 + 1.04569 * x + -0.0125033 Response type: Internal Std ( Ref 27 ), Area * ( IS Conc. / IS Area ) Curve type: 2nd Order, Origin: Exclude, Weighting: 1/x, Axis trans: None ng/L 0.571 1.136 4.832 19.055 103.082 201.344 495.377 1251.356 %Rec 114.3 90.9 96.6 95.3 103.1 100.7 99.1 100.1 S/N 31 258 1068 2531 0 0 0 0 Acq.Date 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 Acq.Time 16:56:55 17:14:37 17:32:19 17:50:01 18:07:43 18:24:28 18:4 1 :21 18:58:15 Detection... MM MM MM MM MM MM MM MM PV by LIU 14-Dec-12, SV by AP 16-Dec-12. NOTE: Std. Concn. & LOD units = ng abs. Excluded points denoted with an 'X' in the Detection Flag column. Page 166 of 307 www.axysanalytical.com Quantify Compound Summary Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\Inst_G\PFC.PRO\FC\FC2G_445-A1 .qld Last Altered: Friday, December 14, 2012 11:01:10 Pacific Standard Time Printed: Sunday, December 16, 2012 09:33:39 Pacific Standard Time Compound name: PFDA # ID Name Type RT 1 FC -LIN-42221W 500-A ,, FC2G_445S004 Standard 7.99 2 FC -LIN-42221W 500-B ,, FC2G_445S005 Standard 7.93 3 FC-LIN-42221W 500-C,, FC2G_445S006 Standard 7.99 4 FC-LIN-42221W 500-D,, FC2G_445S007 Standard 7.99 5 FC-LIN-42221W 500-E,, FC2G_445S008 Standard 7.99 6 FC-LIN-42221W 500-F,, FC2G_445S009 Standard 7.99 7 FC-LIN-42221W 500-G ,, FC2G_445S010 Standard 7.93 8 FC-LIN-42221W 500-H,, FC 2G _445S011 Standard 7.99 Area 4595 9683 30905 115554 552400 1032872 2264803 4575060 IS Area 70921 65473 67478 62623 63392 57749 60934 58399 Std. Conc 0.500 1.250 5.000 20.000 100.000 200.000 500.000 1250.000 Compound name: PFDA Coefficient of Determination: RA2 = 0.998772 Calibration curve: -0.00024797 * xA2 + 1.05686 * x + 0.327338 Response type: Internal Std ( Ref 28 ), Area * ( IS Conc. / IS Area ) Curve type: 2nd Order, Origin: Exclude, Weighting: 1/x, Axis trans: None ng/L 0.426 1.370 4.896 20.743 101.028 213.460 474.551 1264.185 %Rec 85.2 109.6 97.9 103.7 101.0 106.7 94.9 101.1 S/N 32 133 286 1048 1346 4803 5790 6641 Acq.Date 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 Acq.Time 16:56:55 17:14:37 17:32:19 17:50:01 18:07:43 18:24:28 18:4 1 :21 18:58:15 Detection... MM MM MM MM MM MM MM MM PV by LIU 14-Dec-12, SV by AP 16-Dec-12. NOTE: Std. Concn. & LOD units = ng abs. Excluded points denoted with an 'X' in the Detection Flag column. Page 167 of 307 www.axysanalytical.com Quantify Compound Summary Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\Inst_G\PFC.PRO\FC\FC2G_445-A1 .qld Last Altered: Friday, December 14, 2012 11:01:10 Pacific Standard Time Printed: Sunday, December 16, 2012 09:33:39 Pacific Standard Time Compound name: PFUnA # ID Name Type RT 1 FC -LIN-42221W 500-A ,, FC2G_445S004 Standard 8.50 2 FC -LIN-42221W 500-B ,, FC2G_445S005 Standard 8.50 3 FC-LIN-42221W 500-C,, FC2G_445S006 Standard 8.53 4 FC-LIN-42221W 500-D,, FC2G_445S007 Standard 8.53 5 FC-LIN-42221W 500-E,, FC2G_445S008 Standard 8.53 6 FC-LIN-42221W 500-F,, FC2G_445S009 Standard 8.50 7 FC-LIN-42221W 500-G ,, FC2G_445S010 Standard 8.50 8 FC-LIN-42221W 500-H,, FC 2G _445S011 Standard 8.56 Area 3886 9165 35480 126694 671038 1344974 2816578 5587121 IS Area 70921 65473 67478 62623 63392 57749 60934 58399 Std. Conc 0.500 1.250 5.000 20.000 100.000 200.000 500.000 1250.000 Compound name: PFUnA Coefficient of Determination: RA2 = 0.997578 Calibration curve: -0.000337294 * xA2 + 1.33425 * x + -0.0467692 Response type: Internal Std ( Ref 28 ), Area * ( IS Conc. / IS Area ) Curve type: 2nd Order, Origin: Exclude, Weighting: 1/x, Axis trans: None ng/L 0.528 1.294 4.770 18.316 97.651 221.955 472.106 1265.057 %Rec 105.6 103.6 95.4 91.6 97.7 111.0 94.4 101.2 S/N 60 88 384 1322 2940 7104 10581 17560 Acq.Date 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 Acq.Time 16:56:55 17:14:37 17:32:19 17:50:01 18:07:43 18:24:28 18:4 1 :21 18:58:15 Detection... MM MM MM MM MM MM MM MM PV by LIU 14-Dec-12, SV by AP 16-Dec-12. NOTE: Std. Concn. & LOD units = ng abs. Excluded points denoted with an 'X' in the Detection Flag column. Page 168 of 307 www.axysanalytical.com Quantify Compound Summary Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\Inst_G\PFC.PRO\FC\FC2G_445-A1 .qld Last Altered: Friday, December 14, 2012 11:01:10 Pacific Standard Time Printed: Sunday, December 16, 2012 09:33:39 Pacific Standard Time Compound name: PFDoA # ID Name Type RT 1 FC -LIN-42221W 500-A ,, FC2G_445S004 Standard 9.09 2 FC -LIN-42221W 500-B ,, FC2G_445S005 Standard 9.09 3 FC-LIN-42221W 500-C,, FC2G_445S006 Standard 9.12 4 FC-LIN-42221W 500-D,, FC2G_445S007 Standard 9.09 5 FC-LIN-42221W 500-E,, FC2G_445S008 Standard 9.12 6 FC-LIN-42221W 500-F,, FC2G_445S009 Standard 9.09 7 FC-LIN-42221W 500-G ,, FC2G_445S010 Standard 9.09 8 FC-LIN-42221W 500-H,, FC 2G _445S011 Standard 9.12 Area 4341 9683 38200 144155 706897 1522557 3461389 6343367 IS Area 93234 84855 100297 91532 94481 101933 110521 112180 Std. Conc 0.500 1.250 5.000 20.000 100.000 200.000 500.000 1250.000 Compound name: PFDoA Coefficient of Determination: RA2 = 0.999521 Calibration curve: -0.000307507 * xA2 + 0.924823 * x + 0.130548 Response type: Internal Std ( Ref 29 ), Area * ( IS Conc. / IS Area ) Curve type: 2nd Order, Origin: Exclude, Weighting: 1/x, Axis trans: None ng/L 0.463 1.340 4.808 20.433 100.284 208.066 484.187 1269.169 %Rec 92.6 107.2 96.2 102.2 100.3 104.0 96.8 101.5 S/N 49 126 428 1897 8277 12111 10729 16794 Acq.Date 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 Acq.Time 16:56:55 17:14:37 17:32:19 17:50:01 18:07:43 18:24:28 18:4 1 :21 18:58:15 Detection... MM MM MM MM MM MM MM MM PV by LIU 14-Dec-12, SV by AP 16-Dec-12. NOTE: Std. Concn. & LOD units = ng abs. Excluded points denoted with an 'X' in the Detection Flag column. Page 169 of 307 www.axysanalytical.com Quantify Compound Summary Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\Inst_G\PFC.PRO\FC\FC2G_445-A1 .qld Last Altered: Friday, December 14, 2012 11:01:10 Pacific Standard Time Printed: Sunday, December 16, 2012 09:33:39 Pacific Standard Time Compound name: PFBS-1 # ID Name Type RT 1 FC -LIN-42221W 500-A ,, FC2G_445S004 Standard 6.49 2 FC -LIN-42221W 500-B ,, FC2G_445S005 Standard 6.47 3 FC-LIN-42221W 500-C,, FC2G_445S006 Standard 6.49 4 FC-LIN-42221W 500-D,, FC2G_445S007 Standard 6.49 5 FC-LIN-42221W 500-E,, FC2G_445S008 Standard 6.47 6 FC-LIN-42221W 500-F,, FC2G_445S009 Standard 6.49 7 FC-LIN-42221W 500-G ,, FC2G_445S010 Standard 6.45 8 FC-LIN-42221W 500-H,, FC 2G _445S011 Standard 6.47 Area 944 1769 6729 26283 125842 219038 439326 780518 IS Area 9306 8155 9974 9157 7654 7157 6135 4060 Std. Conc 1.000 2.500 10.000 40.000 200.000 400.000 1000.000 2500.000 Compound name: PFBS-1 Coefficient of Determination: RA2 = 0.998845 Calibration curve: 1.84294e-005 * xA2 + 1.33009 * x + 0.460742 Response type: Internal Std ( Ref 23 ), Area * ( IS Conc. / IS Area ) Curve type: 2nd Order, Origin: Exclude, Weighting: 1/x, Axis trans: None ng/L 1.027 2.589 8.782 38.475 221.475 411.492 956.132 2513.525 %Rec 102.7 103.6 87.8 96.2 110.7 102.9 95.6 100.5 S/N 177 199 928 6178 15154 32828 44106 61314 Acq.Date 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 Acq.Time 16:56:55 17:14:37 17:32:19 17:50:01 18:07:43 18:24:28 18:4 1 :21 18:58:15 Detection... MM MM MM MM MM MM MM MM PV by LIU 14-Dec-12, SV by AP 16-Dec-12. NOTE: Std. Concn. & LOD units = ng abs. Excluded points denoted with an 'X' in the Detection Flag column. Page 170 of 307 www.axysanalytical.com Quantify Compound Summary Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\Inst_G\PFC.PRO\FC\FC2G_445-A1 .qld Last Altered: Friday, December 14, 2012 11:01:10 Pacific Standard Time Printed: Sunday, December 16, 2012 09:33:39 Pacific Standard Time Compound name: PFBS-2 # ID Name Type RT 1 FC -LIN-42221W 500-A ,, FC2G_445S004 Standard 6.49 2 FC -LIN-42221W 500-B ,, FC2G_445S005 Standard 6.49 3 FC-LIN-42221W 500-C,, FC2G_445S006 Standard 6.49 4 FC-LIN-42221W 500-D,, FC2G_445S007 Standard 6.49 5 FC-LIN-42221W 500-E,, FC2G_445S008 Standard 6.47 6 FC-LIN-42221W 500-F,, FC2G_445S009 Standard 6.47 7 FC-LIN-42221W 500-G ,, FC2G_445S010 Standard 6.43 8 FC-LIN-42221W 500-H,, FC 2G _445S011 Standard 6.47 Area 370 922 3517 13781 66054 115161 225115 390955 IS Area 7048 6816 6816 6371 5206 5242 3840 2738 Std. Conc 1.000 2.500 10.000 40.000 200.000 400.000 1000.000 2500.000 Compound name: PFBS-2 Coefficient of Determination: RA2 = 0.999182 Calibration curve: -9.57371e-006 * xA2 + 1.05321 * x + -0.22778 Response type: Internal Std ( Ref 24 ), Area * ( IS Conc. / IS Area ) Curve type: 2nd Order, Origin: Exclude, Weighting: 1/x, Axis trans: None ng/L 1.114 2.529 9.035 37.200 217.479 376.960 1011.489 2497.700 %Rec 111.4 101.2 90.4 93.0 108.7 94.2 101.1 99.9 S/N 32 136 416 2829 7804 23419 34911 45765 Acq.Date 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 Acq.Time 16:56:55 17:14:37 17:32:19 17:50:01 18:07:43 18:24:28 18:4 1 :21 18:58:15 Detection... bb bb bb bb bb bb bb bb PV by LIU 14-Dec-12, SV by AP 16-Dec-12. NOTE: Std. Concn. & LOD units = ng abs. Excluded points denoted with an 'X' in the Detection Flag column. Page 171 of 307 www.axysanalytical.com Quantify Compound Summary Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\Inst_G\PFC.PRO\FC\FC2G_445-A1 .qld Last Altered: Friday, December 14, 2012 11:01:10 Pacific Standard Time Printed: Sunday, December 16, 2012 09:33:39 Pacific Standard Time Compound name: PFHxS-1 # ID Name Type RT 1 FC -LIN-42221W 500-A ,, FC2G_445S004 Standard 7.30 2 FC -LIN-42221W 500-B ,, FC2G_445S005 Standard 7.30 3 FC-LIN-42221W 500-C,, FC2G_445S006 Standard 7.30 4 FC-LIN-42221W 500-D,, FC2G_445S007 Standard 7.30 5 FC-LIN-42221W 500-E,, FC2G_445S008 Standard 7.30 6 FC-LIN-42221W 500-F,, FC2G_445S009 Standard 7.30 7 FC-LIN-42221W 500-G ,, FC2G_445S010 Standard 7.30 8 FC-LIN-42221W 500-H,, FC 2G _445S011 Standard 7.30 Area 843 1763 5780 21905 106920 198806 395234 689052 IS Area 9306 8155 9974 9157 7654 7157 6135 4060 Std. Conc 1.000 2.500 10.000 40.000 200.000 400.000 1000.000 2500.000 ng/L 1.021 2.923 8.425 35.862 210.774 418.652 966.396 2509.441 Compound name: PFHxS-1 Coefficient of Determination: RA2 = 0.999195 Calibration curve: 1.13524e-005 * xA2 + 1.1886 * x + 0.41678 Response type: Internal Std ( Ref 23 ), Area * ( IS Conc. / IS Area ) Curve type: 2nd Order, Origin: Exclude, Weighting: 1/x, Axis trans: None %Rec 102.1 116.9 84.2 89.7 105.4 104.7 96.6 100.4 S/N 228 0 0 0 0 0 0 0 Acq.Date 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 Acq.Time 16:56:55 17:14:37 17:32:19 17:50:01 18:07:43 18:24:28 18:4 1 :21 18:58:15 Detection... MM MM MM MM MM MM MM MM PV by LIU 14-Dec-12, SV by AP 16-Dec-12. NOTE: Std. Concn. & LOD units = ng abs. Excluded points denoted with an 'X' in the Detection Flag column. Page 172 of 307 www.axysanalytical.com Quantify Compound Summary Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\Inst_G\PFC.PRO\FC\FC2G_445-A1 .qld Last Altered: Friday, December 14, 2012 11:01:10 Pacific Standard Time Printed: Sunday, December 16, 2012 09:33:39 Pacific Standard Time Compound name: PFHxS-2 # ID Name Type RT 1 FC -LIN-42221W 500-A ,, FC2G_445S004 Standard 7.30 2 FC -LIN-42221W 500-B ,, FC2G_445S005 Standard 7.25 3 FC-LIN-42221W 500-C,, FC2G_445S006 Standard 7.30 4 FC-LIN-42221W 500-D,, FC2G_445S007 Standard 7.30 5 FC-LIN-42221W 500-E,, FC2G_445S008 Standard 7.30 6 FC-LIN-42221W 500-F,, FC2G_445S009 Standard 7.30 7 FC-LIN-42221W 500-G ,, FC2G_445S010 Standard 7.25 8 FC-LIN-42221W 500-H,, FC 2G _445S011 Standard 7.30 Area 351 883 3235 12711 57268 104543 213611 356435 IS Area 7048 6816 6816 6371 5206 5242 3840 2738 Std. Conc 1.000 2.500 10.000 40.000 200.000 400.000 1000.000 2500.000 Compound name: PFHxS-2 Coefficient of Determination: RA2 = 0.998903 Calibration curve: -1 .29242e-005 * xA2 + 0.974532 * x + -0.219288 Response type: Internal Std ( Ref 24 ), Area * ( IS Conc. / IS Area ) Curve type: 2nd Order, Origin: Exclude, Weighting: 1/x, Axis trans: None ng/L 1.144 2.617 8.991 37.095 203.944 370.394 1042.150 2487.173 %Rec 114.4 104.7 89.9 92.7 102.0 92.6 104.2 99.5 S/N 34 0 0 0 10638 7432 0 0 Acq.Date 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 Acq.Time 16:56:55 17:14:37 17:32:19 17:50:01 18:07:43 18:24:28 18:4 1 :21 18:58:15 Detection... bb bb bb bb bb bb bb bb PV by LIU 14-Dec-12, SV by AP 16-Dec-12. NOTE: Std. Concn. & LOD units = ng abs. Excluded points denoted with an 'X' in the Detection Flag column. Page 173 of 307 www.axysanalytical.com Quantify Compound Summary Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\Inst_G\PFC.PRO\FC\FC2G_445-A1 .qld Last Altered: Friday, December 14, 2012 11:01:10 Pacific Standard Time Printed: Sunday, December 16, 2012 09:33:39 Pacific Standard Time Compound name: PFHxS-3 # ID Name Type RT 1 FC -LIN-42221W 500-A ,, FC2G_445S004 Standard 7.30 2 FC -LIN-42221W 500-B ,, FC2G_445S005 Standard 7.30 3 FC-LIN-42221W 500-C,, FC2G_445S006 Standard 7.30 4 FC-LIN-42221W 500-D,, FC2G_445S007 Standard 7.30 5 FC-LIN-42221W 500-E,, FC2G_445S008 Standard 7.30 6 FC-LIN-42221W 500-F,, FC2G_445S009 Standard 7.30 7 FC-LIN-42221W 500-G ,, FC2G_445S010 Standard 7.25 8 FC-LIN-42221W 500-H,, FC 2G _445S011 Standard 7.30 Area 301 530 1815 7686 34687 65881 129524 214852 IS Area 9306 8155 9974 9157 7654 7157 6135 4060 Std. Conc 1.000 2.500 10.000 40.000 200.000 400.000 1000.000 2500.000 Compound name: PFHxS-3 Coefficient of Determination: RA2 = 0.999378 Calibration curve: -7.42791e-006 * xA2 + 0.398291 * x + 0.119303 Response type: Internal Std ( Ref 23 ), Area * ( IS Conc. / IS Area ) Curve type: 2nd Order, Origin: Exclude, Weighting: 1/x, Axis trans: None ng/L 1.163 2.635 7.926 37.658 205.297 418.995 971.484 2508.404 %Rec 116.3 105.4 79.3 94.1 102.6 104.7 97.1 100.3 S/N 75 520 205 0 0 0 0 0 Acq.Date 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 Acq.Time 16:56:55 17:14:37 17:32:19 17:50:01 18:07:43 18:24:28 18:4 1 :21 18:58:15 Detection... bb bb bb bb bb bb bb bb PV by LIU 14-Dec-12, SV by AP 16-Dec-12. NOTE: Std. Concn. & LOD units = ng abs. Excluded points denoted with an 'X' in the Detection Flag column. Page 174 of 307 www.axysanalytical.com Quantify Compound Summary Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\Inst_G\PFC.PRO\FC\FC2G_445-A1 .qld Last Altered: Friday, December 14, 2012 11:01:10 Pacific Standard Time Printed: Sunday, December 16, 2012 09:33:39 Pacific Standard Time Compound name: PFOS-1 # ID Name Type RT 1 FC -LIN-42221W 500-A ,, FC2G_445S004 Standard 8.23 2 FC -LIN-42221W 500-B ,, FC2G_445S005 Standard 8.23 3 FC-LIN-42221W 500-C,, FC2G_445S006 Standard 8.29 4 FC-LIN-42221W 500-D,, FC2G_445S007 Standard 8.23 5 FC-LIN-42221W 500-E,, FC2G_445S008 Standard 8.23 6 FC-LIN-42221W 500-F,, FC2G_445S009 Standard 8.23 7 FC-LIN-42221W 500-G ,, FC2G_445S010 Standard 8.23 8 FC-LIN-42221W 500-H,, FC 2G _445S011 Standard 8.23 Area 763 1662 5671 20621 110728 201138 440275 786051 IS Area 10054 10200 10723 9486 9214 8227 7488 5039 Std. Conc 1.000 2.500 10.000 40.000 200.000 400.000 1000.000 2500.000 Compound name: PFOS-1 Coefficient of Determination: RA2 = 0.999693 Calibration curve: 2.7728e-005 * xA2 + 1.05152 * x + 0.198925 Response type: Internal Std ( Ref 21 ), Area * ( IS Conc. / IS Area ) Curve type: 2nd Order, Origin: Exclude, Weighting: 1/x, Axis trans: None ng/L 1.110 2.600 8.861 36.986 204.433 413.788 980.906 2504.839 %Rec 111.0 104.0 88.6 92.5 102.2 103.4 98.1 100.2 S/N 23 23 18 320 936 1500 2000 2485 Acq.Date 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 Acq.Time 16:56:55 17:14:37 17:32:19 17:50:01 18:07:43 18:24:28 18:4 1 :21 18:58:15 Detection... MM MM MM MM MM MM MM MM PV by LIU 14-Dec-12, SV by AP 16-Dec-12. NOTE: Std. Concn. & LOD units = ng abs. Excluded points denoted with an 'X' in the Detection Flag column. Page 175 of 307 www.axysanalytical.com Quantify Compound Summary Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\Inst_G\PFC.PRO\FC\FC2G_445-A1 .qld Last Altered: Friday, December 14, 2012 11:01:10 Pacific Standard Time Printed: Sunday, December 16, 2012 09:33:39 Pacific Standard Time Compound name: PFOS-2 # ID Name Type RT 1 FC -LIN-42221W 500-A ,, FC2G_445S004 Standard 8.23 2 FC -LIN-42221W 500-B ,, FC2G_445S005 Standard 8.23 3 FC-LIN-42221W 500-C,, FC2G_445S006 Standard 8.23 4 FC-LIN-42221W 500-D,, FC2G_445S007 Standard 8.23 5 FC-LIN-42221W 500-E,, FC2G_445S008 Standard 8.29 6 FC-LIN-42221W 500-F,, FC2G_445S009 Standard 8.23 7 FC-LIN-42221W 500-G ,, FC2G_445S010 Standard 8.23 8 FC-LIN-42221W 500-H,, FC 2G _445S011 Standard 8.29 Area 524 948 3809 14211 72388 133090 280510 532049 IS Area 7580 6871 7462 8114 6988 6470 5370 3443 Std. Conc 1.000 2.500 10.000 40.000 200.000 400.000 1000.000 2500.000 Compound name: PFOS-2 Coefficient of Determination: RA2 = 0.999675 Calibration curve: 9.87089e-005 * xA2 + 0.862929 * x + 0.352919 Response type: Internal Std ( Ref 22 ), Area * ( IS Conc. / IS Area ) Curve type: 2nd Order, Origin: Exclude, Weighting: 1/x, Axis trans: None ng/L 1.033 2.468 10.226 35.976 210.588 409.504 979.408 2504.844 %Rec 103.3 98.7 102.3 89.9 105.3 102.4 97.9 100.2 S/N 17 39 118 338 856 1370 1853 1977 Acq.Date 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 Acq.Time 16:56:55 17:14:37 17:32:19 17:50:01 18:07:43 18:24:28 18:4 1 :21 18:58:15 Detection... bb bb bb bb bb bb bb bb PV by LIU 14-Dec-12, SV by AP 16-Dec-12. NOTE: Std. Concn. & LOD units = ng abs. Excluded points denoted with an 'X' in the Detection Flag column. Page 176 of 307 www.axysanalytical.com Quantify Compound Summary Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\Inst_G\PFC.PRO\FC\FC2G_445-A1 .qld Last Altered: Friday, December 14, 2012 11:01:10 Pacific Standard Time Printed: Sunday, December 16, 2012 09:33:39 Pacific Standard Time Compound name: PFOSA # ID Name Type RT 1 FC -LIN-42221W 500-A ,, FC2G_445S004 Standard 9.90 2 FC -LIN-42221W 500-B ,, FC2G_445S005 Standard 9.87 3 FC-LIN-42221W 500-C,, FC2G_445S006 Standard 9.90 4 FC-LIN-42221W 500-D,, FC2G_445S007 Standard 9.90 5 FC-LIN-42221W 500-E,, FC2G_445S008 Standard 9.93 6 FC-LIN-42221W 500-F,, FC2G_445S009 Standard 9.90 7 FC-LIN-42221W 500-G ,, FC2G_445S010 Standard 9.90 8 FC-LIN-42221W 500-H,, FC 2G _445S011 Standard 9.93 Area 542 1454 5000 21170 112866 229818 560574 1006244 IS Area 10054 10200 10723 9486 9214 8227 7488 5039 Std. Conc 0.500 1.250 5.000 20.000 100.000 200.000 500.000 1250.000 Compound name: PFOSA Coefficient of Determination: RA2 = 0.999004 Calibration curve: 0.00101176 * xA2 + 2.20331 * x + -0.379861 Response type: Internal Std ( Ref 21 ), Area * ( IS Conc. / IS Area ) Curve type: 2nd Order, Origin: Exclude, Weighting: 1/x, Axis trans: None ng/L 0.613 1.336 3.974 18.251 96.015 208.426 497.907 1088.040 %Rec 122.5 106.9 79.5 91.3 96.0 104.2 99.6 87.0 S/N 68 278 192 1567 1898 4612 6474 4989 Acq.Date 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 Acq.Time 16:56:55 17:14:37 17:32:19 17:50:01 18:07:43 18:24:28 18:4 1 :21 18:58:15 Detection... MM MM MM MM MM MM MM MMX PV by LIU 14-Dec-12, SV by AP 16-Dec-12. NOTE: Std. Concn. & LOD units = ng abs. Excluded points denoted with an 'X' in the Detection Flag column. Page 177 of 307 www.axysanalytical.com Quantify Compound Summary Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\Inst_G\PFC.PRO\FC\FC2G_445-A1 .qld Last Altered: Friday, December 14, 2012 11:01:10 Pacific Standard Time Printed: Sunday, December 16, 2012 09:33:39 Pacific Standard Time Compound name: 13C2-PFOA # ID Name Type RT 1 F C -L IN -4 2 22 1 W 5 0 0-A ,, FC 2G _ 4 45 S 0 0 4 Standard 7.11 2 F C -L IN -4 2 22 1 W 5 0 0-B ,, FC 2G _ 4 45 S 0 0 5 Standard 7.11 3 FC-LIN-42221W 500-C,, FC 2G _ 4 45 S 0 0 6 Standard 7.11 4 FC-LIN-42221W 500-D,, FC 2G _ 4 45 S 0 0 7 Standard 7.11 5 FC-LIN-42221W 500-E,, FC 2G _ 4 45 S 0 0 8 Standard 7.11 6 FC-LIN-42221W 500-F,, FC 2G _ 4 45 S 0 0 9 Standard 7.11 7 FC-LIN-42221W 500-G ,, FC2G_445S010 Standard 7.06 8 FC-LIN-42221W 500-H,, F C 2 G _ 4 4 5 S 0 1 1 Standard 7.11 Area 178974 163290 176604 164434 147281 145888 125019 100831 Compound name: 13C2-PFOA Response Factor: 1.01462 RRF SD: 0.0551777, % Relative SD: 5.43827 Response type: Internal Std ( Ref 20 ), Area * ( IS Conc. / IS Area ) Curve type: Rf IS Area 62157 54677 61363 56742 47889 45943 40127 30166 Std. Conc 36.000 36.000 36.000 36.000 36.000 36.000 36.000 36.000 ng/L 34.055 35.321 34.039 34.274 36.374 37.556 36.848 39.533 %Rec 94.6 98.1 94.6 95.2 101.0 104.3 102.4 109.8 S/N 1348 0 0 2093 0 0 0 0 Acq.Date 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 Acq.Time 16:56:55 17:14:37 17:32:19 17:50:01 18:07:43 18:24:28 18:4 1 :21 18:58:15 Detection... MM MM MM MM MM MM MM MM PV by LIU 14-Dec-12, SV by AP 16-Dec-12. NOTE: Std. Concn. & LOD units = ng abs. Excluded points denoted with an 'X' in the Detection Flag column. Page 178 of 307 www.axysanalytical.com Quantify Compound Summary Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\Inst_G\PFC.PRO\FC\FC2G_445-A1 .qld Last Altered: Friday, December 14, 2012 11:01:10 Pacific Standard Time Printed: Sunday, December 16, 2012 09:33:39 Pacific Standard Time Compound name: 13C4-PFOA # ID Name Type RT 1 F C -L IN -4 2 22 1 W 5 0 0-A ,, FC 2G _ 4 45 S 0 0 4 Standard 7.11 2 F C -L IN -4 2 22 1 W 5 0 0-B ,, FC 2G _ 4 45 S 0 0 5 Standard 7.11 3 FC-LIN-42221W 500-C,, FC 2G _ 4 45 S 0 0 6 Standard 7.11 4 FC-LIN-42221W 500-D,, FC 2G _ 4 45 S 0 0 7 Standard 7.11 5 FC-LIN-42221W 500-E,, FC 2G _ 4 45 S 0 0 8 Standard 7.11 6 FC-LIN-42221W 500-F,, FC 2G _ 4 45 S 0 0 9 Standard 7.11 7 FC-LIN-42221W 500-G ,, FC2G_445S010 Standard 7.06 8 FC-LIN-42221W 500-H,, F C 2 G _ 4 4 5 S 0 1 1 Standard 7.11 Compound name: 13C4-PFOA Response Factor: 4156.9 RRF SD: 921.465, % Relative SD: 22.1671 Response type: External Std, Area Curve type: Rf Area 62157 54677 61363 56742 47889 45943 40127 30166 IS Area Std. Conc 12.000 12.000 12.000 12.000 12.000 12.000 12.000 12.000 ng/L 14.953 13.153 14.762 13.650 11.520 11.052 9.653 7.257 %Rec 124.6 109.6 123.0 113.8 96.0 92.1 80.4 60.5 S/N 0 278 342 0 0 0 0 0 Acq.Date 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 Acq.Time 16:56:55 17:14:37 17:32:19 17:50:01 18:07:43 18:24:28 18:4 1 :21 18:58:15 Detection... MM MM MM MM MM MM MM MM PV by LIU 14-Dec-12, SV by AP 16-Dec-12. NOTE: Std. Concn. & LOD units = ng abs. Excluded points denoted with an 'X' in the Detection Flag column. Page 179 of 307 www.axysanalytical.com Quantify Compound Summary Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\Inst_G\PFC.PRO\FC\FC2G_445-A1 .qld Last Altered: Friday, December 14, 2012 11:01:10 Pacific Standard Time Printed: Sunday, December 16, 2012 09:33:39 Pacific Standard Time Compound name: 13C4-PFOS-1 # ID Name Type RT 1 FC -LIN-42221W 500-A ,, FC2G_445S004 Standard 8.23 2 FC -LIN-42221W 500-B ,, FC2G_445S005 Standard 8.23 3 FC-LIN-42221W 500-C,, FC2G_445S006 Standard 8.29 4 FC-LIN-42221W 500-D,, FC2G_445S007 Standard 8.23 5 FC-LIN-42221W 500-E,, FC2G_445S008 Standard 8.23 6 FC-LIN-42221W 500-F,, FC2G_445S009 Standard 8.23 7 FC-LIN-42221W 500-G ,, FC2G_445S010 Standard 8.23 8 FC-LIN-42221W 500-H,, FC 2G _445S011 Standard 8.29 Area 10054 10200 10723 9486 9214 8227 7488 5039 Compound name: 13C4-PFOS-1 Response Factor: 0.248214 RRF SD: 0.0245457, % Relative SD: 9.88892 Response type: Internal Std ( Ref 30 ), Area * ( IS Conc. / IS Area ) Curve type: Rf IS Area 22841 20301 23325 21380 18798 18995 16675 14160 Std. Conc 18.000 18.000 18.000 18.000 18.000 18.000 18.000 18.000 ng/L 17.734 20.243 18.522 17.876 19.747 17.451 18.093 14.336 %Rec 98.5 112.5 102.9 99.3 109.7 96.9 100.5 79.6 S/N 400 499 438 506 576 277 293 195 Acq.Date 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 Acq.Time 16:56:55 17:14:37 17:32:19 17:50:01 18:07:43 18:24:28 18:4 1 :21 18:58:15 Detection... MM MM MM MM MM MM MM MM PV by LIU 14-Dec-12, SV by AP 16-Dec-12. NOTE: Std. Concn. & LOD units = ng abs. Excluded points denoted with an 'X' in the Detection Flag column. Page 180 of 307 www.axysanalytical.com Quantify Compound Summary Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\Inst_G\PFC.PRO\FC\FC2G_445-A1 .qld Last Altered: Friday, December 14, 2012 11:01:10 Pacific Standard Time Printed: Sunday, December 16, 2012 09:33:39 Pacific Standard Time Compound name: 13C4-PFOS-2 # ID Name Type RT 1 FC -LIN-42221W 500-A ,, FC2G_445S004 Standard 8.23 2 FC -LIN-42221W 500-B ,, FC2G_445S005 Standard 8.23 3 FC-LIN-42221W 500-C,, FC2G_445S006 Standard 8.29 4 FC-LIN-42221W 500-D,, FC2G_445S007 Standard 8.29 5 FC-LIN-42221W 500-E,, FC2G_445S008 Standard 8.23 6 FC-LIN-42221W 500-F,, FC2G_445S009 Standard 8.23 7 FC-LIN-42221W 500-G ,, FC2G_445S010 Standard 8.23 8 FC-LIN-42221W 500-H,, FC 2G _445S011 Standard 8.29 Area 7580 6871 7462 8114 6988 6470 5370 3443 Compound name: 13C4-PFOS-2 Response Factor: 0.183845 RRF SD: 0.0230781, % Relative SD: 12.553 Response type: Internal Std ( Ref 30 ), Area * ( IS Conc. / IS Area ) Curve type: Rf IS Area 22841 20301 23325 21380 18798 18995 16675 14160 Std. Conc 18.000 18.000 18.000 18.000 18.000 18.000 18.000 18.000 ng/L 18.052 18.408 17.402 20.643 20.221 18.527 17.518 13.227 %Rec 100.3 102.3 96.7 114.7 112.3 102.9 97.3 73.5 S/N 110 234 297 390 226 201 285 91 Acq.Date 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 Acq.Time 16:56:55 17:14:37 17:32:19 17:50:01 18:07:43 18:24:28 18:4 1 :21 18:58:15 Detection... bb bb bb bb bb bb bb bb PV by LIU 14-Dec-12, SV by AP 16-Dec-12. NOTE: Std. Concn. & LOD units = ng abs. Excluded points denoted with an 'X' in the Detection Flag column. Page 181 of 307 www.axysanalytical.com Quantify Compound Summary Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\Inst_G\PFC.PRO\FC\FC2G_445-A1 .qld Last Altered: Friday, December 14, 2012 11:01:10 Pacific Standard Time Printed: Sunday, December 16, 2012 09:33:39 Pacific Standard Time Compound name: 18O2-PFHxS-1 # ID Name Type RT 1 FC -LIN-42221W 500-A ,, FC2G_445S004 Standard 7.30 2 FC -LIN-42221W 500-B ,, FC2G_445S005 Standard 7.30 3 FC-LIN-42221W 500-C,, FC2G_445S006 Standard 7.30 4 FC-LIN-42221W 500-D,, FC2G_445S007 Standard 7.30 5 FC-LIN-42221W 500-E,, FC2G_445S008 Standard 7.30 6 FC-LIN-42221W 500-F,, FC2G_445S009 Standard 7.30 7 FC-LIN-42221W 500-G ,, FC2G_445S010 Standard 7.30 8 FC-LIN-42221W 500-H,, FC 2G _445S011 Standard 7.30 Area 9306 8155 9974 9157 7654 7157 6135 4060 Compound name: 18O2-PFHxS-1 Response Factor: 0.215533 RRF SD: 0.0256414, % Relative SD: 11.8967 Response type: Internal Std ( Ref 30 ), Area * ( IS Conc. / IS Area ) Curve type: Rf IS Area 22841 20301 23325 21380 18798 18995 16675 14160 Std. Conc 18.000 18.000 18.000 18.000 18.000 18.000 18.000 18.000 ng/L 18.904 18.638 19.840 19.872 18.891 17.481 17.070 13.304 %Rec 105.0 103.5 110.2 110.4 105.0 97.1 94.8 73.9 S/N 409 822 0 943 0 0 1927 0 Acq.Date 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 Acq.Time 16:56:55 17:14:37 17:32:19 17:50:01 18:07:43 18:24:28 18:4 1 :21 18:58:15 Detection... MM MM MM MM MM MM MM MM PV by LIU 14-Dec-12, SV by AP 16-Dec-12. NOTE: Std. Concn. & LOD units = ng abs. Excluded points denoted with an 'X' in the Detection Flag column. Page 182 of 307 www.axysanalytical.com Quantify Compound Summary Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\Inst_G\PFC.PRO\FC\FC2G_445-A1 .qld Last Altered: Friday, December 14, 2012 11:01:10 Pacific Standard Time Printed: Sunday, December 16, 2012 09:33:39 Pacific Standard Time Compound name: 18O2-PFHxS-2 # ID Name Type RT 1 FC -LIN-42221W 500-A ,, FC2G_445S004 Standard 7.30 2 FC -LIN-42221W 500-B ,, FC2G_445S005 Standard 7.30 3 FC-LIN-42221W 500-C,, FC2G_445S006 Standard 7.30 4 FC-LIN-42221W 500-D,, FC2G_445S007 Standard 7.30 5 FC-LIN-42221W 500-E,, FC2G_445S008 Standard 7.30 6 FC-LIN-42221W 500-F,, FC2G_445S009 Standard 7.30 7 FC-LIN-42221W 500-G ,, FC2G_445S010 Standard 7.25 8 FC-LIN-42221W 500-H,, FC 2G _445S011 Standard 7.30 Area 7048 6816 6816 6371 5206 5242 3840 2738 Compound name: 18O2-PFHxS-2 Response Factor: 0.153548 RRF SD: 0.0251138, % Relative SD: 16.3557 Response type: Internal Std ( Ref 30 ), Area * ( IS Conc. / IS Area ) Curve type: Rf IS Area 22841 20301 23325 21380 18798 18995 16675 14160 Std. Conc 18.000 18.000 18.000 18.000 18.000 18.000 18.000 18.000 ng/L 20.097 21.866 19.031 19.406 18.038 17.974 14.997 12.590 %Rec 111.7 121.5 105.7 107.8 100.2 99.9 83.3 69.9 S/N 0 423 0 619 251 0 0 0 Acq.Date 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 Acq.Time 16:56:55 17:14:37 17:32:19 17:50:01 18:07:43 18:24:28 18:4 1 :21 18:58:15 Detection... bb bb bb bb bb bb bb bb PV by LIU 14-Dec-12, SV by AP 16-Dec-12. NOTE: Std. Concn. & LOD units = ng abs. Excluded points denoted with an 'X' in the Detection Flag column. Page 183 of 307 www.axysanalytical.com Quantify Compound Summary Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\Inst_G\PFC.PRO\FC\FC2G_445-A1 .qld Last Altered: Friday, December 14, 2012 11:01:10 Pacific Standard Time Printed: Sunday, December 16, 2012 09:33:39 Pacific Standard Time Compound name: 13C4-PFBA # ID Name Type RT 1 FC -LIN-42221W 500-A ,, FC2G_445S004 Standard 5.13 2 FC -LIN-42221W 500-B ,, FC2G_445S005 Standard 5.14 3 FC-LIN-42221W 500-C,, FC2G_445S006 Standard 5.14 4 FC-LIN-42221W 500-D,, FC2G_445S007 Standard 5.18 5 FC-LIN-42221W 500-E,, FC2G_445S008 Standard 5.13 6 FC-LIN-42221W 500-F,, FC2G_445S009 Standard 5.14 7 FC-LIN-42221W 500-G ,, FC2G_445S010 Standard 5.07 8 FC-LIN-42221W 500-H,, FC 2G _445S011 Standard 5.16 Area 29460 25526 29193 27354 24645 25200 21251 16912 Compound name: 13C4-PFBA Response Factor: 1.06091 RRF SD: 0.0338595, % Relative SD: 3.19155 Response type: Internal Std ( Ref 30 ), Area * ( IS Conc. / IS Area ) Curve type: Rf IS Area 22841 20301 23325 21380 18798 18995 16675 14160 Std. Conc 12.000 12.000 12.000 12.000 12.000 12.000 12.000 12.000 ng/L 12.158 11.852 11.797 12.060 12.358 12.505 12.013 11.257 %Rec 101.3 98.8 98.3 100.5 103.0 104.2 100.1 93.8 S/N 196 284 213 242 140 82 75 62 Acq.Date 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 Acq.Time 16:56:55 17:14:37 17:32:19 17:50:01 18:07:43 18:24:28 18:4 1 :21 18:58:15 Detection... MM MM MM MM MM MM MM MM PV by LIU 14-Dec-12, SV by AP 16-Dec-12. NOTE: Std. Concn. & LOD units = ng abs. Excluded points denoted with an 'X' in the Detection Flag column. Page 184 of 307 www.axysanalytical.com Quantify Compound Summary Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\Inst_G\PFC.PRO\FC\FC2G_445-A1 .qld Last Altered: Friday, December 14, 2012 11:01:10 Pacific Standard Time Printed: Sunday, December 16, 2012 09:33:39 Pacific Standard Time Compound name: 13C2-PFHxA # ID Name Type RT 1 FC -LIN-42221W 500-A ,, FC2G_445S004 Standard 6.37 2 FC -LIN-42221W 500-B ,, FC2G_445S005 Standard 6.36 3 FC-LIN-42221W 500-C,, FC2G_445S006 Standard 6.36 4 FC-LIN-42221W 500-D,, FC2G_445S007 Standard 6.36 5 FC-LIN-42221W 500-E,, FC2G_445S008 Standard 6.36 6 FC-LIN-42221W 500-F,, FC2G_445S009 Standard 6.36 7 FC-LIN-42221W 500-G ,, FC2G_445S010 Standard 6.32 8 FC-LIN-42221W 500-H,, FC 2G _445S011 Standard 6.36 Area 66835 60698 64980 58266 53679 48323 43496 35274 Compound name: 13C2-PFHxA Response Factor: 2.284 RRF SD: 0.151209, % Relative SD: 6.62038 Response type: Internal Std ( Ref 30 ), Area * ( IS Conc. / IS Area ) Curve type: Rf IS Area 22841 20301 23325 21380 18798 18995 16675 14160 Std. Conc 12.000 12.000 12.000 12.000 12.000 12.000 12.000 12.000 ng/L 12.812 13.091 12.197 11.932 12.503 11.138 11.421 10.906 %Rec 106.8 109.1 101.6 99.4 104.2 92.8 95.2 90.9 S/N 3315 3192 5218 1610 3043 2177 1922 2803 Acq.Date 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 Acq.Time 16:56:55 17:14:37 17:32:19 17:50:01 18:07:43 18:24:28 18:4 1 :21 18:58:15 Detection... MM MM MM MM MM MM MM MM PV by LIU 14-Dec-12, SV by AP 16-Dec-12. NOTE: Std. Concn. & LOD units = ng abs. Excluded points denoted with an 'X' in the Detection Flag column. Page 185 of 307 www.axysanalytical.com Quantify Compound Summary Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\Inst_G\PFC.PRO\FC\FC2G_445-A1 .qld Last Altered: Friday, December 14, 2012 11:01:10 Pacific Standard Time Printed: Sunday, December 16, 2012 09:33:39 Pacific Standard Time Compound name: 13C5-PFNA # ID Name Type RT 1 FC -LIN-42221W 500-A ,, FC2G_445S004 Standard 7.46 2 FC -LIN-42221W 500-B ,, FC2G_445S005 Standard 7.46 3 FC-LIN-42221W 500-C,, FC2G_445S006 Standard 7.49 4 FC-LIN-42221W 500-D,, FC2G_445S007 Standard 7.49 5 FC-LIN-42221W 500-E,, FC2G_445S008 Standard 7.46 6 FC-LIN-42221W 500-F,, FC2G_445S009 Standard 7.49 7 FC-LIN-42221W 500-G ,, FC2G_445S010 Standard 7.46 8 FC-LIN-42221W 500-H,, FC 2G _445S011 Standard 7.49 Area 61446 64296 62761 57763 52387 51976 44006 33246 Compound name: 13C5-PFNA Response Factor: 2.26666 RRF SD: 0.186811, % Relative SD: 8.2417 Response type: Internal Std ( Ref 30 ), Area * ( IS Conc. / IS Area ) Curve type: Rf IS Area 22841 20301 23325 21380 18798 18995 16675 14160 Std. Conc 12.000 12.000 12.000 12.000 12.000 12.000 12.000 12.000 ng/L 11.869 13.972 11.871 11.920 12.295 12.072 11.643 10.358 %Rec 98.9 116.4 98.9 99.3 102.5 100.6 97.0 86.3 S/N 4801 5026 2521 4915 2428 4295 787 0 Acq.Date 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 Acq.Time 16:56:55 17:14:37 17:32:19 17:50:01 18:07:43 18:24:28 18:4 1 :21 18:58:15 Detection... MM MM MM MM MM MM MM MM PV by LIU 14-Dec-12, SV by AP 16-Dec-12. NOTE: Std. Concn. & LOD units = ng abs. Excluded points denoted with an 'X' in the Detection Flag column. Page 186 of 307 www.axysanalytical.com Quantify Compound Summary Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\Inst_G\PFC.PRO\FC\FC2G_445-A1 .qld Last Altered: Friday, December 14, 2012 11:01:10 Pacific Standard Time Printed: Sunday, December 16, 2012 09:33:39 Pacific Standard Time Compound name: 13C2-PFDA # ID Name Type RT 1 FC -LIN-42221W 500-A ,, FC2G_445S004 Standard 7.99 2 FC -LIN-42221W 500-B ,, FC2G_445S005 Standard 7.93 3 FC-LIN-42221W 500-C,, FC2G_445S006 Standard 7.99 4 FC-LIN-42221W 500-D,, FC2G_445S007 Standard 7.99 5 FC-LIN-42221W 500-E,, FC2G_445S008 Standard 7.99 6 FC-LIN-42221W 500-F,, FC2G_445S009 Standard 7.99 7 FC-LIN-42221W 500-G ,, FC2G_445S010 Standard 7.93 8 FC-LIN-42221W 500-H,, FC 2G _445S011 Standard 7.99 Area 70921 65473 67478 62623 63392 57749 60934 58399 Compound name: 13C2-PFDA Response Factor: 2.74408 RRF SD: 0.348433, % Relative SD: 12.6976 Response type: Internal Std ( Ref 30 ), Area * ( IS Conc. / IS Area ) Curve type: Rf IS Area 22841 20301 23325 21380 18798 18995 16675 14160 Std. Conc 12.000 12.000 12.000 12.000 12.000 12.000 12.000 12.000 ng/L 11.315 11.753 10.543 10.674 12.289 11.079 13.317 15.029 %Rec 94.3 97.9 87.9 89.0 102.4 92.3 111.0 125.2 S/N 678 870 601 594 502 368 384 531 Acq.Date 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 Acq.Time 16:56:55 17:14:37 17:32:19 17:50:01 18:07:43 18:24:28 18:4 1 :21 18:58:15 Detection... MM MM MM MM MM MM MM MM PV by LIU 14-Dec-12, SV by AP 16-Dec-12. NOTE: Std. Concn. & LOD units = ng abs. Excluded points denoted with an 'X' in the Detection Flag column. Page 187 of 307 www.axysanalytical.com Quantify Compound Summary Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\Inst_G\PFC.PRO\FC\FC2G_445-A1 .qld Last Altered: Friday, December 14, 2012 11:01:10 Pacific Standard Time Printed: Sunday, December 16, 2012 09:33:39 Pacific Standard Time Compound name: 13C2-PFDoA # ID Name Type RT 1 FC -LIN-42221W 500-A ,, FC2G_445S004 Standard 9.09 2 FC -LIN-42221W 500-B ,, FC2G_445S005 Standard 9.09 3 FC-LIN-42221W 500-C,, FC2G_445S006 Standard 9.12 4 FC-LIN-42221W 500-D,, FC2G_445S007 Standard 9.09 5 FC-LIN-42221W 500-E,, FC2G_445S008 Standard 9.12 6 FC-LIN-42221W 500-F,, FC2G_445S009 Standard 9.06 7 FC-LIN-42221W 500-G ,, FC2G_445S010 Standard 9.09 8 FC-LIN-42221W 500-H,, FC 2G _445S011 Standard 9.12 Area 93234 84855 100297 91532 94481 101933 110521 112180 Compound name: 13C2-PFDoA Response Factor: 4.0314 RRF SD: 0.770044, % Relative SD: 19.1012 Response type: Internal Std ( Ref 30 ), Area * ( IS Conc. / IS Area ) Curve type: Rf IS Area 22841 20301 23325 21380 18798 18995 16675 14160 Std. Conc 12.000 12.000 12.000 12.000 12.000 12.000 12.000 12.000 ng/L 10.125 10.368 10.666 10.620 12.468 13.312 16.441 19.651 %Rec 84.4 86.4 88.9 88.5 103.9 110.9 137.0 163.8 S/N 416 420 595 324 645 629 256 536 Acq.Date 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 Acq.Time 16:56:55 17:14:37 17:32:19 17:50:01 18:07:43 18:24:28 18:4 1 :21 18:58:15 Detection... MM MM MM MM MM MM MM MMX PV by LIU 14-Dec-12, SV by AP 16-Dec-12. NOTE: Std. Concn. & LOD units = ng abs. Excluded points denoted with an 'X' in the Detection Flag column. Page 188 of 307 www.axysanalytical.com Quantify Compound Summary Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\Inst_G\PFC.PRO\FC\FC2G_445-A1 .qld Last Altered: Friday, December 14, 2012 11:01:10 Pacific Standard Time Printed: Sunday, December 16, 2012 09:33:39 Pacific Standard Time Compound name: 13C2-PFOUEA # ID Name Type RT 1 FC -LIN-42221W 500-A ,, FC2G_445S004 Standard 7.39 2 FC -LIN-42221W 500-B ,, FC2G_445S005 Standard 7.39 3 FC-LIN-42221W 500-C,, FC2G_445S006 Standard 7.43 4 FC-LIN-42221W 500-D,, FC2G_445S007 Standard 7.43 5 FC-LIN-42221W 500-E,, FC2G_445S008 Standard 7.43 6 FC-LIN-42221W 500-F,, FC2G_445S009 Standard 7.43 7 FC-LIN-42221W 500-G ,, FC2G_445S010 Standard 7.39 8 FC-LIN-42221W 500-H,, FC 2G _445S011 Standard 7.43 Compound name: 13C2-PFOUEA Response Factor: 1955.92 RRF SD: 309.787, % Relative SD: 15.8384 Response type: External Std, Area Curve type: Rf Area 22841 20301 23325 21380 18798 18995 16675 14160 IS Area Std. Conc 10.000 10.000 10.000 10.000 10.000 10.000 10.000 10.000 ng/L 11.678 10.379 11.925 10.931 9.611 9.711 8.525 7.240 %Rec 116.8 103.8 119.3 109.3 96.1 97.1 85.3 72.4 S/N 1298 2638 1273 1578 1184 0 1148 0 Acq.Date 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 13-Dec-12 Acq.Time 16:56:55 17:14:37 17:32:19 17:50:01 18:07:43 18:24:28 18:4 1 :21 18:58:15 Detection... MM MM MM MM MM MM MM MM PV by LIU 14-Dec-12, SV by AP 16-Dec-12. NOTE: Std. Concn. & LOD units = ng abs. Excluded points denoted with an 'X' in the Detection Flag column. Page 189 of 307 www.axysanalytical.com Quantify Sample Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\Inst_G\PFC.PRO\FC\FC2G_445-A1 .qld Last Altered: Friday, December 14, 2012 11:01:10 Pacific Standard Time Printed: Sunday, December 16, 2012 09:33:39 Pacific Standard Time Method: G:\Masslynx\Master Methods\PFC\FC_060_10_01.mdb 03 Dec 2010 17:21:03 Calibration: 14 Dec 2012 11:01:10 ID: FC-LIN-42221W500-A,, Name: FC2G_445S004 Description: 1,,15uL Date: 13-Dec-2012 Time: 16:56:55 PFBA FC2G_445S004 100 5.13 1 .7 0 e 3 6.47 7.03 PFPeA FC2G_445S004 100 5.96 1.95e3 9789 % PFHxA FC2G 445S004 min 5.00 6.00 7.00 min 5.00 6.00 7.00 PFHpA FC2G_445S004 100 6.74 3.18e3 12881 PFOA-1 FC2G 445S004 % :4.06 min min 5.00 6.00 7.00 PFOA-2 FC2G 445S004 min min PFNA FC2G 445S004 PFDA FC2G_445S004 100 _ 7.99 4.60e3 16544 PFUnA FC2G 445S004 % 12.02 min min 8.00 10.00 12.00 PFDoA FC2G_445S004 100 _ 9.09 4.34e3 19182 % PFBS-1 FC2G 445S004 min min 8.00 10.00 12.00 PFBS-2 FC2G_445S004 100 6.49 3.70e2 1549 % min min 5.00 6.00 7.00 PFHxS-1 FC2G 445S004 PFHxS-2 FC2G 445S004 min PFHxS-3 FC2G 445S004 100- 7.30 3.01e2 1183 PFOS-1 FC2G_445S004 100 8.23 7.63e2 2299 PFOS-2 FC2G_445S004 100 8.23 5.24e2 1715 PFOSA FC2G 445S004 %- % % 7.78 11.4912.17 min 0 7.00 r-r min 8.00 0 8.00 min 10.00 12.00 8.00 min 10.00 12.00 PV by LIU 14-Dec-12, SV by AP 16-Dec-12. NOTE: Std. Concn. & LOD units = ng abs. Excluded points denoted with an 'X' in the Detection Flag column. Page 190 of 307 www.axysanalytical.com Quantify Sample Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\Inst_G\PFC.PRO\FC\FC2G_445-A1 .qld Last Altered: Friday, December 14, 2012 11:01:10 Pacific Standard Time Printed: Sunday, December 16, 2012 09:33:39 Pacific Standard Time ID: FC-LIN-42221W500-A,, Name: FC2G_445S004 Description: 1,,15uL Date: 13-Dec-2012 Time: 16:56:55 13C2-PFOA FC2G 445S004 100- 7.11 1.79e5 731049 %- 13C4-PFOA FC2G_445S004 100 7.11 6.22e4 ,257916 % 13C4-PFOS-1 FC2G 445S004 0 - ^^1 =rr min 7.00 8.00 0 7.00 min 8.00 13C4-PFBA FC2G 445S004 13C2-PFHxA FC2G 445S004 13C5-PFNA FC2G 445S004 13C4-PFOS-2 FC2G 445S004 min 13C2-PFDA FC2G 445S004 18O2-PFHxS-1 FC2G 445S004 18O2-PFHxS-2 FC2G 445S004 min 13C2-PFDoA FC2G 445S004 min 13C2-PFOUEA FC2G 445S004 min min min min min min min PV by LIU 14-Dec-12, SV by AP 16-Dec-12. NOTE: Std. Concn. & LOD units = ng abs. Excluded points denoted with an 'X' in the Detection Flag column. Page 191 of 307 www.axysanalytical.com Quantify Sample Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\Inst_G\PFC.PRO\FC\FC2G_445-A1 .qld Last Altered: Friday, December 14, 2012 11:01:10 Pacific Standard Time Printed: Sunday, December 16, 2012 09:33:39 Pacific Standard Time ID: FC-LIN-42221W500-A,, Name: FC2G_445S004 Description: 1,,15uL Date: 13-Dec-2012 Time: 16:56:55 # Name 1 PFBA 2 PFPeA 3 PFHxA 4 PFHpA 5 PFOA-1 6 PFOA-2 7 PFNA 8 PFDA 9 PFUnA 10 PFDoA 11 PFBS-1 12 PFBS-2 13 PFHxS-1 14 PFHxS-2 15 PFHxS-3 16 PFOS-1 17 PFOS-2 18 PFOSA 19 13C2-PFOA 20 13C4-PFOA 21 13C4-PFO S-1 22 13C4-PFOS-2 23 18O2-PFHxS-1 24 18O2-PFHxS-2 25 13C4-PFBA 26 13C2-PFHxA 27 13C5-PFNA 28 13C2-PFDA 29 13C2-PFDoA 30 13C2-PFOUEA IS# Trace RT 25 212.99>168.98 5.13 26 262.98 > 218.... 5.96 26 312.97> 268.98 6.37 26 362.97> 318.98 6.74 19 4 12 .97 > 368.98 7.11 19 4 12 .97 > 168.80 7.11 27 462.96 > 418.... 7.49 28 512.96 > 468.... 7.99 28 562.96 > 518.... 8.50 29 612.95 > 568.... 9.09 23 298.94> 79.96 6.49 24 298.94 > 98.95 6.49 23 398.84 > 79.96 7.30 24 398.84> 98.96 7.30 23 398.84> 118.70 7.30 21 4 98 .93 > 79.96 8.23 22 498.93> 98.96 8.23 21 498 > 78 9.90 20 4 14 .97 > 369.... 7.11 4 16 .97 > 371.9 7.11 30 503 > 79.96 8.23 30 503 > 98.96 8.23 30 402.9>84 7.30 30 402.9>103 7.30 30 216.99>171.98 5.13 30 314.97>269.98 6.37 30 467.96>422.97 7.46 30 514.96 >469.96 7.99 30 614.95 > 569.... 9.09 458.98 >393.98 7.39 Area 1702 1948 3763 3179 3480 659 2996 4595 3886 4341 944 370 843 351 301 763 524 542 178974 62157 10054 7580 9306 7048 29460 66835 61446 70921 93234 22841 IS Area 29460 66835 66835 66835 178974 178974 61446 70921 70921 93234 9306 7048 9306 7048 9306 10054 7580 10054 62157 22841 22841 22841 22841 22841 22841 22841 22841 22841 ng/L 0.567 0.611 0.553 0.600 0.565 0.500 0.571 0.426 0.528 0.463 1.027 1.114 1.021 1.144 1.163 1.110 1.033 0.613 34.055 14.953 17.734 18.052 18.904 20.097 12.158 12.812 11.869 11.315 10.125 11.678 LOD 0.1235 0.1432 0.0553 0.0671 0.0637 0.3039 0.3157 0.1922 0.0746 0.1321 0.4630 0.1519 0.1535 0.0147 0.0076 0.0453 0.0839 0.0270 %Rec 113.5 122.3 110.6 119.9 113.0 100.0 114.3 85.2 105.6 92.6 102.7 111.4 102.1 114.4 116.3 111.0 103.3 122.5 94.6 124.6 98.5 100.3 105.0 111.7 101.3 106.8 98.9 94.3 84.4 116.8 S/N 30 86 85 56 85 50 31 32 60 49 177 32 228 34 75 23 17 68 1348 0 400 110 409 0 196 3315 4801 678 416 1298 Noise 203 114 211 230 159 46 399 511 270 391 27 48 12 46 16 102 101 32 542 0 99 256 99 0 490 101 52 375 1018 70 Height 6057 9789 17937 12881 13536 2309 12456 16544 16158 19182 4755 1549 2767 1559 1183 2299 1715 2163 731049 257916 39456 28278 40323 28046 96083 334313 249216 254000 423361 90284 IS Height 96083 334313 334313 334313 731049 731049 249216 254000 254000 423361 40323 28046 40323 28046 40323 39456 28278 39456 257916 90284 90284 90284 90284 90284 90284 90284 90284 90284 Sam ple size 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 Factor2 Detection... 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 bb 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 bb 1.0 MM 1.0 bb 1.0 bb 1.0 MM 1.0 bb 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 bb 1.0 MM 1.0 bb 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM PV by LIU 14-Dec-12, SV by AP 16-Dec-12. NOTE: Std. Concn. & LOD units = ng abs. Excluded points denoted with an 'X' in the Detection Flag column. Page 192 of 307 www.axysanalytical.com Quantify Sample Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\Inst_G\PFC.PRO\FC\FC2G_445-A1 .qld Last Altered: Friday, December 14, 2012 11:01:10 Pacific Standard Time Printed: Sunday, December 16, 2012 09:33:39 Pacific Standard Time ID: FC-LIN-42221W500-B,, Name: FC2G_445S005 Description: 1,,15uL Date: 13-Dec-2012 Time: 17:14:37 PFBA FC2G_445S005 100 5.16 3.26e3 13201 6.45 7.08 min 5.00 6.00 7.00 PFPeA FC2G 445S005 PFNA FC2G 445S005 PFDA FC2G 445S005 PFHxA FC2G 445S005 min PFUnA FC2G 445S005 PFHpA FC2G 445S005 min PFDoA FC2G 445S005 PFHxS-1 FC2G 445S005 min PFHxS-2 FC2G 445S005 min PFHxS-3 FC2G 445S005 min PFOS-1 FC2G 445S005 min min min PFOA-1 FC2G 445S005 PFOA-2 FC2G 445S005 min min PFBS-1 FC2G_445S005 100- 6.47 1.77e3 9224 %- PFBS-2 FC2G 445S005 min min 5.00 6.00 7.00 PFOS-2 FC2G_445S005 8.23 100 9.48e2 3407 % PFOSA FC2G 445S005 8.00 min 10.00 12.00 min min min PV by LIU 14-Dec-12, SV by AP 16-Dec-12. NOTE: Std. Concn. & LOD units = ng abs. Excluded points denoted with an 'X' in the Detection Flag column. Page 193 of 307 www.axysanalytical.com Quantify Sample Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\Inst_G\PFC.PRO\FC\FC2G_445-A1 .qld Last Altered: Friday, December 14, 2012 11:01:10 Pacific Standard Time Printed: Sunday, December 16, 2012 09:33:39 Pacific Standard Time ID: FC-LIN-42221W500-B,, Name: FC2G_445S005 Description: 1,,15uL Date: 13-Dec-2012 Time: 17:14:37 13C2-PFOA FC2G 445S005 13C4-PFOA FC2G 445S005 13C4-PFOS-1 FC2G 445S005 13C4-PFOS-2 FC2G 445S005 18O2-PFHxS-1 FC2G 445S005 18O2-PFHxS-2 FC2G 445S005 13C4-PFBA FC2G 445S005 min 13C2-PFHxA FC2G 445S005 min 13C5-PFNA FC2G 445S005 min 13C2-PFDA FC2G 445S005 min 13C2-PFDoA FC2G 445S005 min 13C2-PFOUEA FC2G 445S005 min min min min min min PV by LIU 14-Dec-12, SV by AP 16-Dec-12. NOTE: Std. Concn. & LOD units = ng abs. Excluded points denoted with an 'X' in the Detection Flag column. Page 194 of 307 www.axysanalytical.com Quantify Sample Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\Inst_G\PFC.PRO\FC\FC2G_445-A1 .qld Last Altered: Friday, December 14, 2012 11:01:10 Pacific Standard Time Printed: Sunday, December 16, 2012 09:33:39 Pacific Standard Time ID: FC-LIN-42221W500-B,, Name: FC2G_445S005 Description: 1,,15uL Date: 13-Dec-2012 Time: 17:14:37 # Name 1 PFBA 2 PFPeA 3 PFHxA 4 PFHpA 5 PFOA-1 6 PFOA-2 7 PFNA 8 PFDA 9 PFUnA 10 PFDoA 11 PFBS-1 12 PFBS-2 13 PFHxS-1 14 PFHxS-2 15 PFHxS-3 16 PFOS-1 17 PFOS-2 18 PFOSA 19 13C2-PFOA 20 13C4-PFOA 21 13C4-PFO S-1 22 13C4-PFOS-2 23 18O2-PFHxS-1 24 18O2-PFHxS-2 25 13C4-PFBA 26 13C2-PFHxA 27 13C5-PFNA 28 13C2-PFDA 29 13C2-PFDoA 30 13C2-PFOUEA IS# Trace RT 25 212.99>168.98 5.16 26 262.98 > 218.... 5.96 26 312.97> 268.98 6.36 26 362.97> 318.98 6.74 19 4 12 .97 > 368.98 7.11 19 4 12 .97 > 168.80 7.11 27 462.96 > 418.... 7.46 28 512.96 > 468.... 7.93 28 562.96 > 518.... 8.50 29 612.95 > 568.... 9.09 23 298.94> 79.96 6.47 24 298.94 > 98.95 6.49 23 398.84 > 79.96 7.30 24 398.84> 98.96 7.25 23 398.84> 118.70 7.30 21 4 98 .93 > 79.96 8.23 22 498.93> 98.96 8.23 21 498 > 78 9.87 20 4 14 .97 > 369.... 7.11 4 16 .97 > 371.9 7.11 30 503 > 79.96 8.23 30 503 > 98.96 8.23 30 402.9>84 7.30 30 402.9>103 7.30 30 216.99>171.98 5.14 30 314.97>269.98 6.36 30 467.96>422.97 7.46 30 514.96 >469.96 7.93 30 614.95 > 569.... 9.09 458.98 >393.98 7.39 Area 3260 4081 7458 6544 6169 1818 6297 9683 9165 9683 1769 922 1763 883 530 1662 948 1454 163290 54677 10200 6871 8155 6816 25526 60698 64296 65473 84855 20301 IS Area 25526 60698 60698 60698 163290 163290 64296 65473 65473 84855 8155 6816 8155 6816 8155 10200 6871 10200 54677 20301 20301 20301 20301 20301 20301 20301 20301 20301 ng/L 1.371 1.272 1.286 1.204 1.179 1.450 1.136 1.370 1.294 1.340 2.589 2.529 2.923 2.617 2.635 2.600 2.468 1.336 35.321 13.153 20.243 18.408 18.638 21.866 11.852 13.091 13.972 11.753 10.368 10.379 LOD 0.0240 0.1450 0.1580 0.0377 0.0737 0.0240 0.0876 0.2643 0.2250 0.0567 0.1829 0.1418 0.1125 0.2232 0.0653 0.1583 0.1162 0.0153 0.0090 0.0377 0.0825 0.0118 %Rec 109.7 101.7 102.9 96.3 94.3 116.0 90.9 109.6 103.6 107.2 103.6 101.2 116.9 104.7 105.4 104.0 98.7 106.9 98.1 109.6 112.5 102.3 103.5 121.5 98.8 109.1 116.4 97.9 86.4 103.8 S/N 40 92 211 77 32 96 258 133 88 126 199 136 0 0 520 23 39 278 0 278 499 234 822 423 284 3192 5026 870 420 2638 Noise 332 227 180 355 830 75 98 274 475 347 46 26 0 0 4 181 88 16 0 785 76 111 38 66 334 94 55 280 902 31 Height 13201 20930 37907 27371 26944 7193 25288 36593 41784 43782 9224 3537 6416 3276 2036 4217 3407 4512 673331 218379 37779 25998 31376 27830 94930 301384 278797 243932 378629 81277 IS Height 94930 301384 301384 301384 673331 673331 278797 243932 243932 378629 31376 27830 31376 27830 31376 37779 25998 37779 218379 81277 81277 81277 81277 81277 81277 81277 81277 81277 Sam ple size 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 Factor2 Detection... 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 bb 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 bb 1.0 MM 1.0 bb 1.0 bb 1.0 MM 1.0 bb 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 bb 1.0 MM 1.0 bb 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM PV by LIU 14-Dec-12, SV by AP 16-Dec-12. NOTE: Std. Concn. & LOD units = ng abs. Excluded points denoted with an 'X' in the Detection Flag column. Page 195 of 307 www.axysanalytical.com Quantify Sample Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\Inst_G\PFC.PRO\FC\FC2G_445-A1 .qld Last Altered: Friday, December 14, 2012 11:01:10 Pacific Standard Time Printed: Sunday, December 16, 2012 09:33:39 Pacific Standard Time ID: FC-LIN-42221W500-C,, Name: FC2G_445S006 Description: 1,,15uL Date: 13-Dec-2012 Time: 17:32:19 PFBA FC2G 445S006 PFPeA FC2G 445S006 PFHxA FC2G 445S006 PFHpA FC2G 445S006 PFOA-1 FC2G 445S006 PFOA-2 FC2G 445S006 PFNA FC2G 445S006 min PFDA FC2G 445S006 min PFUnA FC2G 445S006 min PFDoA FC2G 445S006 min PFBS-1 FC2G 445S006 min PFBS-2 FC2G 445S006 min PFHxS-1 FC2G 445S006 min PFHxS-2 FC2G 445S006 min PFHxS-3 FC2G 445S006 min PFOS-1 FC2G 445S006 min PFOS-2 FC2G 445S006 min PFOSA FC2G 445S006 min min min min min min min PV by LIU 14-Dec-12, SV by AP 16-Dec-12. NOTE: Std. Concn. & LOD units = ng abs. Excluded points denoted with an 'X' in the Detection Flag column. Page 196 of 307 www.axysanalytical.com Quantify Sample Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\Inst_G\PFC.PRO\FC\FC2G_445-A1 .qld Last Altered: Friday, December 14, 2012 11:01:10 Pacific Standard Time Printed: Sunday, December 16, 2012 09:33:39 Pacific Standard Time ID: FC-LIN-42221W500-C,, Name: FC2G_445S006 Description: 1,,15uL Date: 13-Dec-2012 Time: 17:32:19 13C2-PFOA FC2G 445S006 13C4-PFOA FC2G 445S006 13C4-PFBA FC2G 445S006 min 13C2-PFHxA FC2G 445S006 13C4-PFOS-1 FC2G 445S006 min 13C5-PFNA FC2G 445S006 13C4-PFOS-2 18O2-PFHxS-1 18O2-PFHxS-2 FC2G 445S006 FC2G 445S006 FC2G_445S006 J100%- 8.29 7.46e3 27410 min 0 - 100%- min 0 7.30 9.97e3 41115 100q %- / V , -T min 0- 7.30 6.82e3 26464 min 8.00 10.00 12.00 7.00 8.00 7.00 8.00 13C2-PFDA FC2G 445S006 13C2-PFDoA FC2G 445S006 13C2-PFOUEA FC2G 445S006 min min min min min min PV by LIU 14-Dec-12, SV by AP 16-Dec-12. NOTE: Std. Concn. & LOD units = ng abs. Excluded points denoted with an 'X' in the Detection Flag column. Page 197 of 307 www.axysanalytical.com Quantify Sample Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\Inst_G\PFC.PRO\FC\FC2G_445-A1 .qld Last Altered: Friday, December 14, 2012 11:01:10 Pacific Standard Time Printed: Sunday, December 16, 2012 09:33:39 Pacific Standard Time ID: FC-LIN-42221W500-C,, Name: FC2G_445S006 Description: 1,,15uL Date: 13-Dec-2012 Time: 17:32:19 # Name 1 PFBA 2 PFPeA 3 PFHxA 4 PFHpA 5 PFOA-1 6 PFOA-2 7 PFNA 8 PFDA 9 PFUnA 10 PFDoA 11 PFBS-1 12 PFBS-2 13 PFHxS-1 14 PFHxS-2 15 PFHxS-3 16 PFOS-1 17 PFOS-2 18 PFOSA 19 13C2-PFOA 20 13C4-PFOA 21 13C4-PFO S-1 22 13C4-PFOS-2 23 18O2-PFHxS-1 24 18O2-PFHxS-2 25 13C4-PFBA 26 13C2-PFHxA 27 13C5-PFNA 28 13C2-PFDA 29 13C2-PFDoA 30 13C2-PFOUEA IS# Trace RT 25 212.99>168.98 5.14 26 262.98 > 218.... 5.98 26 312.97> 268.98 6.37 26 362.97> 318.98 6.74 19 4 12 .97 > 368.98 7.11 19 4 12 .97 > 168.80 7.11 27 462.96 > 418.... 7.49 28 512.96 > 468.... 7.99 28 562.96 > 518.... 8.53 29 612.95 > 568.... 9.12 23 298.94> 79.96 6.49 24 298.94 > 98.95 6.49 23 398.84 > 79.96 7.30 24 398.84> 98.96 7.30 23 398.84> 118.70 7.30 21 4 98 .93 > 79.96 8.29 22 498.93> 98.96 8.23 21 498 > 78 9.90 20 4 14 .97 > 369.... 7.11 4 16 .97 > 371.9 7.11 30 503 > 79.96 8.29 30 503 > 98.96 8.29 30 402.9>84 7.30 30 402.9>103 7.30 30 216.99>171.98 5.14 30 314.97>269.98 6.36 30 467.96>422.97 7.49 30 514.96 >469.96 7.99 30 614.95 > 569.... 9.12 458.98 >393.98 7.43 Area 11699 15995 27050 28341 25268 6596 26363 30905 35480 38200 6729 3517 5780 3235 1815 5671 3809 5000 176604 61363 10723 7462 9974 6816 29193 64980 62761 67478 100297 23325 IS Area 29193 64980 64980 64980 176604 176604 62761 67478 67478 100297 9974 6816 9974 6816 9974 10723 7462 10723 61363 23325 23325 23325 23325 23325 23325 23325 23325 23325 ng/L 4.508 4.375 4.521 4.498 4.707 4.793 4.832 4.896 4.770 4.808 8.782 9.035 8.425 8.991 7.926 8.861 10.226 3.974 34.039 14.762 18.522 17.402 19.840 19.031 11.797 12.197 11.871 10.543 10.666 11.925 LOD 0.1862 0.1455 0.1435 0.0310 0.0256 0.0777 0.2961 0.2250 0.8740 0.2199 0.1295 0.1200 0.1603 0.1411 0.0084 0.0142 0.0484 0.0575 0.0281 %Rec 90.2 87.5 90.4 90.0 94.1 95.9 96.6 97.9 95.4 96.2 87.8 90.4 84.2 89.9 79.3 88.6 102.3 79.5 94.6 123.0 102.9 96.7 110.2 105.7 98.3 101.6 98.9 87.9 88.9 119.3 S/N 49 325 611 548 0 0 1068 286 384 428 928 416 0 0 205 18 118 192 0 342 438 297 0 0 213 5218 2521 601 595 1273 Noise 821 240 221 219 0 0 101 385 396 397 35 41 0 0 35 846 107 79 0 726 93 92 0 0 469 60 101 417 727 74 Height 40612 78143 135112 119980 103440 26117 107814 110308 151846 169630 32067 17121 20790 12445 7179 15630 12587 15218 733596 248304 40862 27410 41115 26464 100060 314460 253833 250344 432776 94053 IS Height 100060 314460 314460 314460 733596 733596 253833 250344 250344 432776 41115 26464 41115 26464 41115 40862 27410 40862 248304 94053 94053 94053 94053 94053 94053 94053 94053 94053 Sam ple size 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 Factor2 Detection... 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 bb 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 bb 1.0 MM 1.0 bb 1.0 bb 1.0 MM 1.0 bb 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 bb 1.0 MM 1.0 bb 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM PV by LIU 14-Dec-12, SV by AP 16-Dec-12. NOTE: Std. Concn. & LOD units = ng abs. Excluded points denoted with an 'X' in the Detection Flag column. Page 198 of 307 www.axysanalytical.com Quantify Sample Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\Inst_G\PFC.PRO\FC\FC2G_445-A1 .qld Last Altered: Friday, December 14, 2012 11:01:10 Pacific Standard Time Printed: Sunday, December 16, 2012 09:33:39 Pacific Standard Time ID: FC-LIN-42221W500-D,, Name: FC2G_445S007 Description: 1,,15uL Date: 13-Dec-2012 Time: 17:50:01 PFBA FC2G 445S007 PFPeA FC2G 445S007 PFHxA FC2G 445S007 PFHpA FC2G 445S007 PFOA-1 FC2G 445S007 PFOA-2 FC2G 445S007 min min min min min PFNA FC2G 445S007 PFDA FC2G 445S007 PFUnA FC2G 445S007 PFDoA FC2G_445S007 100- 9.09 1 .4 4 e 5 659398 % PFBS-1 FC2G 445S007 PFBS-2 FC2G 445S007 min min min 0 min min 8.00 10.00 12.00 PFHxS-1 FC2G 445S007 100- 7.30 2.19e4 81274 %- PFHxS-2 FC2G 445S007 100- 7.30 1.27e4 49203 %- PFHxS-3 FC2G 445S007 100- 7.30 7.69e3 29594 %- PFOS-1 FC2G 445S007 100- 8.23 2.06e4 54010 %- PFOS-2 FC2G_445S007 100^ 8.23 1 .42e4 46891 %: PFOSA FC2G 445S007 07.00 =f min 8.00 07.00 =r min 8.00 07.00 r=f min 8.00 V 0- 8.00 9.93 10.00 min 12.00 0^ 8.00 min 10.00 12.00 min min PV by LIU 14-Dec-12, SV by AP 16-Dec-12. NOTE: Std. Concn. & LOD units = ng abs. Excluded points denoted with an 'X' in the Detection Flag column. Page 199 of 307 www.axysanalytical.com Quantify Sample Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\Inst_G\PFC.PRO\FC\FC2G_445-A1 .qld Last Altered: Friday, December 14, 2012 11:01:10 Pacific Standard Time Printed: Sunday, December 16, 2012 09:33:39 Pacific Standard Time ID: FC-LIN-42221W500-D,, Name: FC2G_445S007 Description: 1,,15uL Date: 13-Dec-2012 Time: 17:50:01 13C2-PFOA FC2G 445S007 100- 7.11 1 .6 4 e 5 655272 %- 13C4-PFOA FC2G_445S007 100 7.11 5.67e4 1215664 % 13C4-PFOS-1 FC2G 445S007 07.00 =rr min 8.00 0 7.00 min 8.00 13C4-PFBA FC2G 445S007 13C2-PFHxA FC2G 445S007 13C5-PFNA FC2G 445S007 13C4-PFOS-2 FC2G 445S007 min 13C2-PFDA FC2G 445S007 18O2-PFHxS-1 FC2G 445S007 18O2-PFHxS-2 FC2G 445S007 min 13C2-PFDoA FC2G 445S007 min 13C2-PFOUEA FC2G 445S007 min min min min min min min PV by LIU 14-Dec-12, SV by AP 16-Dec-12. NOTE: Std. Concn. & LOD units = ng abs. Excluded points denoted with an 'X' in the Detection Flag column. Page 200 of 307 www.axysanalytical.com Quantify Sample Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\Inst_G\PFC.PRO\FC\FC2G_445-A1 .qld Last Altered: Friday, December 14, 2012 11:01:10 Pacific Standard Time Printed: Sunday, December 16, 2012 09:33:39 Pacific Standard Time ID: FC-LIN-42221W500-D,, Name: FC2G_445S007 Description: 1,,15uL Date: 13-Dec-2012 Time: 17:50:01 # Name 1 PFBA 2 PFPeA 3 PFHxA 4 PFHpA 5 PFOA-1 6 PFOA-2 7 PFNA 8 PFDA 9 PFUnA 10 PFDoA 11 PFBS-1 12 PFBS-2 13 PFHxS-1 14 PFHxS-2 15 PFHxS-3 16 PFOS-1 17 PFOS-2 18 PFOSA 19 13C2-PFOA 20 13C4-PFOA 21 13C4-PFO S-1 22 13C4-PFOS-2 23 18O2-PFHxS-1 24 18O2-PFHxS-2 25 13C4-PFBA 26 13C2-PFHxA 27 13C5-PFNA 28 13C2-PFDA 29 13C2-PFDoA 30 13C2-PFOUEA IS# Trace RT 25 212.99>168.98 5.18 26 262.98 > 218.... 5.98 26 312.97> 268.98 6.37 26 362.97> 318.98 6.74 19 4 12 .97 > 368.98 7.11 19 4 12 .97 > 168.80 7.11 27 462.96 > 418.... 7.49 28 512.96 > 468.... 7.99 28 562.96 > 518.... 8.53 29 612.95 > 568.... 9.09 23 298.94> 79.96 6.49 24 298.94 > 98.95 6.49 23 398.84 > 79.96 7.30 24 398.84> 98.96 7.30 23 398.84> 118.70 7.30 21 4 98 .93 > 79.96 8.23 22 498.93> 98.96 8.23 21 498 > 78 9.90 20 4 14 .97 > 369.... 7.11 4 16 .97 > 371.9 7.11 30 503 > 79.96 8.23 30 503 > 98.96 8.29 30 402.9>84 7.30 30 402.9>103 7.30 30 216.99>171.98 5.18 30 314.97>269.98 6.36 30 467.96>422.97 7.49 30 514.96 >469.96 7.99 30 614.95 > 569.... 9.09 458.98 >393.98 7.43 Area 42289 60142 100408 104254 94311 22890 95907 115554 126694 144155 26283 13781 21905 12711 7686 20621 14211 21170 164434 56742 9486 8114 9157 6371 27354 58266 57763 62623 91532 21380 IS Area 27354 58266 58266 58266 164434 164434 57763 62623 62623 91532 9157 6371 9157 6371 9157 9486 8114 9486 56742 21380 21380 21380 21380 21380 21380 21380 21380 21380 ng/L 17.665 18.014 18.962 18.089 19.151 17.796 19.055 20.743 18.316 20.433 38.475 37.200 35.862 37.095 37.658 36.986 35.976 18.251 34.274 13.650 17.876 20.643 19.872 19.406 12.060 11.932 11.920 10.674 10.620 10.931 LOD 0.5435 0.1739 0.1626 0.0310 0.0340 0.0822 0.2635 0.2250 0.0640 0.2051 0.0515 0.1004 0.1488 0.0676 0.0978 0.1281 0.0284 0.0080 0.0529 0.1137 0.0208 %Rec 88.3 90.1 94.8 90.4 95.8 89.0 95.3 103.7 91.6 102.2 96.2 93.0 89.7 92.7 94.1 92.5 89.9 91.3 95.2 113.8 99.3 114.7 110.4 107.8 100.5 99.4 99.3 89.0 88.5 109.3 S/N 90 742 3750 1098 1407 0 2531 1048 1322 1897 6178 2829 0 0 0 320 338 1567 2093 0 506 390 943 619 242 1610 4915 594 324 1578 Noise 1662 372 128 379 262 0 154 404 410 348 20 23 0 0 0 169 139 46 313 0 68 74 40 41 370 176 49 395 1247 52 Height 149855 275802 481227 416250 368520 91209 389749 423187 541926 659398 125309 65986 81274 49203 29594 54010 46891 71784 655272 215664 34283 29041 37377 25317 89509 284126 241058 234751 403706 81606 IS Height 89509 284126 284126 284126 655272 655272 241058 234751 234751 403706 37377 25317 37377 25317 37377 34283 29041 34283 215664 81606 81606 81606 81606 81606 81606 81606 81606 81606 Sam ple size 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 Factor2 Detection... 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 bb 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 bb 1.0 MM 1.0 bb 1.0 bb 1.0 MM 1.0 bb 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 bb 1.0 MM 1.0 bb 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM PV by LIU 14-Dec-12, SV by AP 16-Dec-12. NOTE: Std. Concn. & LOD units = ng abs. Excluded points denoted with an 'X' in the Detection Flag column. Page 201 of 307 www.axysanalytical.com Quantify Sample Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\Inst_G\PFC.PRO\FC\FC2G_445-A1 .qld Last Altered: Friday, December 14, 2012 11:01:10 Pacific Standard Time Printed: Sunday, December 16, 2012 09:33:39 Pacific Standard Time ID: FC-LIN-42221W500-E,, Name: FC2G_445S008 Description: 1,,15uL Date: 13-Dec-2012 Time: 18:07:43 PFBA FC2G 445S008 100- 5.11 2.14e5 693898 %- PFPeA FC2G_445S008 100 5.96 _ 2.94e5 1375798 % PFHxA FC2G 445S008 0 - li -m min 5.00 6.00 7.00 0 min 5.00 6.00 7.00 PFNA FC2G 445S008 7.49 100- 4.72e5 1888519 %- PFDA FC2G_445S008 7.99 100 5.52e5 2030209 % PFUnA FC2G 445S008 07.00 min 8.00 0 8.00 1 1 1 1 1 1 1 1 1 1 1 1 1 min 10.00 12.00 PFHxS-1 FC2G 445S008 PFHxS-2 FC2G 445S008 PFHxS-3 FC2G 445S008 PFHpA FC2G 445S008 min PFDoA FC2G 445S008 min PFOS-1 FC2G 445S008 PFOA-1 FC2G 445S008 min PFBS-1 FC2G 445S008 min PFOS-2 FC2G 445S008 PFOA-2 FC2G 445S008 min PFBS-2 FC2G 445S008 min PFOSA FC2G 445S008 min min min min min min min min PV by LIU 14-Dec-12, SV by AP 16-Dec-12. NOTE: Std. Concn. & LOD units = ng abs. Excluded points denoted with an 'X' in the Detection Flag column. Page 202 of 307 www.axysanalytical.com Quantify Sample Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\Inst_G\PFC.PRO\FC\FC2G_445-A1 .qld Last Altered: Friday, December 14, 2012 11:01:10 Pacific Standard Time Printed: Sunday, December 16, 2012 09:33:39 Pacific Standard Time ID: FC-LIN-42221W500-E,, Name: FC2G_445S008 Description: 1,,15uL Date: 13-Dec-2012 Time: 18:07:43 13C2-PFOA FC2G 445S008 13C4-PFOA FC2G 445S008 13C4-PFOS-1 FC2G 445S008 13C4-PFOS-2 FC2G 445S008 18O2-PFHxS-1 FC2G 445S008 18O2-PFHxS-2 FC2G 445S008 13C4-PFBA FC2G 445S008 min 13C2-PFHxA FC2G 445S008 min 13C5-PFNA FC2G 445S008 min 13C2-PFDA FC2G 445S008 min 13C2-PFDoA FC2G 445S008 min 13C2-PFOUEA FC2G 445S008 min min min min min min min PV by LIU 14-Dec-12, SV by AP 16-Dec-12. NOTE: Std. Concn. & LOD units = ng abs. Excluded points denoted with an 'X' in the Detection Flag column. Page 203 of 307 www.axysanalytical.com Quantify Sample Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\Inst_G\PFC.PRO\FC\FC2G_445-A1 .qld Last Altered: Friday, December 14, 2012 11:01:10 Pacific Standard Time Printed: Sunday, December 16, 2012 09:33:39 Pacific Standard Time ID: FC-LIN-42221W500-E,, Name: FC2G_445S008 Description: 1,,15uL Date: 13-Dec-2012 Time: 18:07:43 # Name 1 PFBA 2 PFPeA 3 PFHxA 4 PFHpA 5 PFOA-1 6 PFOA-2 7 PFNA 8 PFDA 9 PFUnA 10 PFDoA 11 PFBS-1 12 PFBS-2 13 PFHxS-1 14 PFHxS-2 15 PFHxS-3 16 PFOS-1 17 PFOS-2 18 PFOSA 19 13C2-PFOA 20 13C4-PFOA 21 13C4-PFO S-1 22 13C4-PFOS-2 23 18O2-PFHxS-1 24 18O2-PFHxS-2 25 13C4-PFBA 26 13C2-PFHxA 27 13C5-PFNA 28 13C2-PFDA 29 13C2-PFDoA 30 13C2-PFOUEA IS# Trace RT 25 212.99 >1 6 8.98 5.11 26 262.98 > 218.... 5.96 26 312.97> 268.98 6.36 26 362.97> 318.98 6.74 19 4 12 .97 > 368.98 7.11 19 4 12 .97 > 168.80 7.11 27 462.96 > 418.... 7.49 28 512.96 > 468.... 7.99 28 562.96 > 518.... 8.53 29 612.95 > 568.... 9.12 23 298.94> 79.96 6.47 24 298.94 > 98.95 6.47 23 398.84 > 79.96 7.30 24 398.84> 98.96 7.30 23 398.84> 118.70 7.30 21 4 98 .93 > 79.96 8.23 22 498.93> 98.96 8.29 21 498 > 78 9.93 20 4 14 .97 > 369.... 7.11 4 16 .97 > 371.9 7.11 30 503 > 79.96 8.23 30 503 > 98.96 8.23 30 402.9>84 7.30 30 402.9>103 7.30 30 216.99>171.98 5.13 30 314.97>269.98 6.36 30 467.96>422.97 7.46 30 514.96 >469.96 7.99 30 614.95 > 569.... 9.12 458.98 >393.98 7.43 Area 213591 293936 472991 530786 452340 113491 471902 552400 671038 706897 125842 66054 106920 57268 34687 110728 72388 112866 147281 47889 9214 6988 7654 5206 24645 53679 52387 63392 94481 18798 IS Area 24645 53679 53679 53679 147281 147281 52387 63392 63392 94481 7654 5206 7654 5206 7654 9214 6988 9214 47889 18798 18798 18798 18798 18798 18798 18798 18798 18798 ng/L 99.497 95.340 98.317 99.883 103.692 99.005 103.082 101.028 97.651 100.284 221.475 217.479 210.774 203.944 205.297 204.433 210.588 96.015 36.374 11.520 19.747 20.221 18.891 18.038 12.358 12.503 12.295 12.289 12.468 9.611 LOD 0.0620 0.1293 0.1420 0.0310 0.0120 0.1465 0.3144 0.2803 0.2991 0.2661 0.3180 0.1003 0.2587 0.2160 0.2118 0.0168 0.0163 0.0708 0.0630 0.0243 %Rec 99.5 95.3 98.3 99.9 103.7 99.0 103.1 101.0 97.7 100.3 110.7 108.7 105.4 102.0 102.6 102.2 105.3 96.0 101.0 96.0 109.7 112.3 105.0 100.2 103.0 104.2 102.5 102.4 103.9 96.1 S/N 2015 10920 10164 11928 0 0 0 1346 2940 8277 15154 7804 0 10638 0 936 856 1898 0 0 576 226 0 251 140 3043 2428 502 645 1184 Noise 344 126 241 180 0 0 0 1508 961 343 37 38 0 20 0 325 277 203 0 0 59 114 0 79 536 92 88 464 606 60 Height 693898 1375798 2444874 2149474 1887327 464435 1888519 2030209 2825081 2839802 555471 296430 397302 210529 126405 304510 236747 385730 622565 200398 34203 25644 30217 19848 74871 278673 214225 232629 390455 71587 IS Height 74871 278673 278673 278673 622565 622565 214225 232629 232629 390455 30217 19848 30217 19848 30217 34203 25644 34203 200398 71587 71587 71587 71587 71587 71587 71587 71587 71587 Sam ple size 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 Factor2 Detection... 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 bb 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 bb 1.0 MM 1.0 bb 1.0 bb 1.0 MM 1.0 bb 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 bb 1.0 MM 1.0 bb 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM PV by LIU 14-Dec-12, SV by AP 16-Dec-12. NOTE: Std. Concn. & LOD units = ng abs. Excluded points denoted with an 'X' in the Detection Flag column. Page 204 of 307 www.axysanalytical.com Quantify Sample Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\Inst_G\PFC.PRO\FC\FC2G_445-A1 .qld Last Altered: Friday, December 14, 2012 11:01:10 Pacific Standard Time Printed: Sunday, December 16, 2012 09:33:39 Pacific Standard Time ID: FC-LIN-42221W500-F,, Name: FC2G_445S009 Description: 1,,15uL Date: 13-Dec-2012 Time: 18:24:28 PFBA FC2G_445S009 100n 5.14 4.21e5 1329855 % PFPeA FC2G 445S009 100- 5.98 5.66e5 1 2418352 %- PFHxA FC2G_445S009 100 6.36 8.89e5 4279719 % PFHpA FC2G 445S009 0 n min 5.00 6.00 7.00 0 - ................... 'I min 5.00 6.00 7.00 0 min 5.00 6.00 7.00 PFNA FC2G 445S009 PFDA FC2G 445S009 PFUnA FC2G 445S009 PFDoA FC2G 445S009 PFOA-1 FC2G 445S009 min PFBS-1 FC2G 445S009 PFOA-2 FC2G 445S009 min PFBS-2 FC2G 445S009 min PFHxS-1 FC2G 445S009 min PFHxS-2 FC2G 445S009 min PFHxS-3 FC2G 445S009 min PFOS-1 FC2G 445S009 min PFOS-2 FC2G 445S009 min PFOSA FC2G 445S009 min min min min min min min PV by LIU 14-Dec-12, SV by AP 16-Dec-12. NOTE: Std. Concn. & LOD units = ng abs. Excluded points denoted with an 'X' in the Detection Flag column. Page 205 of 307 www.axysanalytical.com Quantify Sample Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\Inst_G\PFC.PRO\FC\FC2G_445-A1 .qld Last Altered: Friday, December 14, 2012 11:01:10 Pacific Standard Time Printed: Sunday, December 16, 2012 09:33:39 Pacific Standard Time ID: FC-LIN-42221W500-F,, Name: FC2G_445S009 Description: 1,,15uL Date: 13-Dec-2012 Time: 18:24:28 13C2-PFOA FC2G 445S009 13C4-PFOA FC2G 445S009 13C4-PFOS-1 FC2G 445S009 13C4-PFOS-2 FC2G 445S009 18O2-PFHxS-1 FC2G 445S009 18O2-PFHxS-2 FC2G 445S009 13C4-PFBA FC2G 445S009 min 13C2-PFHxA FC2G 445S009 min 13C5-PFNA FC2G 445S009 min 13C2-PFDA FC2G 445S009 min 13C2-PFDoA FC2G 445S009 min 13C2-PFOUEA FC2G 445S009 min min min min min min min PV by LIU 14-Dec-12, SV by AP 16-Dec-12. NOTE: Std. Concn. & LOD units = ng abs. Excluded points denoted with an 'X' in the Detection Flag column. Page 206 of 307 www.axysanalytical.com Quantify Sample Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\Inst_G\PFC.PRO\FC\FC2G_445-A1 .qld Last Altered: Friday, December 14, 2012 11:01:10 Pacific Standard Time Printed: Sunday, December 16, 2012 09:33:39 Pacific Standard Time ID: FC-LIN-42221W500-F,, Name: FC2G_445S009 Description: 1,,15uL Date: 13-Dec-2012 Time: 18:24:28 # Name 1 PFBA 2 PFPeA 3 PFHxA 4 PFHpA 5 PFOA-1 6 PFOA-2 7 PFNA 8 PFDA 9 PFUnA 10 PFDoA 11 PFBS-1 12 PFBS-2 13 PFHxS-1 14 PFHxS-2 15 PFHxS-3 16 PFOS-1 17 PFOS-2 18 PFOSA 19 13C2-PFOA 20 13C4-PFOA 21 13C4-PFO S-1 22 13C4-PFOS-2 23 18O2-PFHxS-1 24 18O2-PFHxS-2 25 13C4-PFBA 26 13C2-PFHxA 27 13C5-PFNA 28 13C2-PFDA 29 13C2-PFDoA 30 13C2-PFOUEA IS# Trace RT 25 212.99>168.98 5.14 26 262.98 > 218.... 5.98 26 312.97> 268.98 6.36 26 362.97> 318.98 6.74 19 4 12 .97 > 368.98 7.11 19 4 12 .97 > 168.80 7.11 27 462.96 > 418.... 7.49 28 512.96 > 468.... 7.99 28 562.96 > 518.... 8.50 29 612.95 > 568.... 9.09 23 298.94> 79.96 6.49 24 298.94 > 98.95 6.47 23 398.84 > 79.96 7.30 24 398.84> 98.96 7.30 23 398.84> 118.70 7.30 21 4 98 .93 > 79.96 8.23 22 498.93> 98.96 8.23 21 498 > 78 9.90 20 4 14 .97 > 369.... 7.11 4 16 .97 > 371.9 7.11 30 503 > 79.96 8.23 30 503 > 98.96 8.23 30 402.9>84 7.30 30 402.9>103 7.30 30 216.99>171.98 5.14 30 314.97>269.98 6.36 30 467.96>422.97 7.49 30 514.96 >469.96 7.99 30 614.95 > 569.... 9.06 458.98 >393.98 7.43 Area 421406 566115 888540 1004495 853031 221628 917096 1032872 1344974 1522557 219038 115161 198806 104543 65881 201138 133090 229818 145888 45943 8227 6470 7157 5242 25200 48323 51976 57749 101933 18995 IS Area 25200 48323 48323 48323 145888 145888 51976 57749 57749 101933 7157 5242 7157 5242 7157 8227 6470 8227 45943 18995 18995 18995 18995 18995 18995 18995 18995 18995 ng/L 192.121 204.560 208.462 211.217 199.162 196.690 201.344 213.460 221.955 208.066 411.492 376.960 418.652 370.394 418.995 413.788 409.504 208.426 37.556 11.052 17.451 18.527 17.481 17.974 12.505 11.138 12.072 11.079 13.312 9.711 LOD 0.1639 0.1506 0.1595 0.0310 0.0120 0.1384 0.2684 0.3685 0.3945 0.4362 0.3113 0.1783 0.2510 0.3856 0.0193 0.0087 0.0848 0.0674 %Rec 96.1 102.3 104.2 105.6 99.6 98.3 100.7 106.7 111.0 104.0 102.9 94.2 104.7 92.6 104.7 103.4 102.4 104.2 104.3 92.1 96.9 102.9 97.1 99.9 104.2 92.8 100.6 92.3 110.9 97.1 S/N 2159 11971 21372 13584 0 0 0 4803 7104 12111 32828 23419 0 7432 0 1500 1370 4612 0 0 277 201 0 0 82 2177 4295 368 629 0 Noise 616 202 200 288 0 0 0 787 801 535 28 20 0 51 0 340 306 170 0 0 108 113 0 0 1000 108 48 569 664 0 Height 1329855 2418352 4279719 3914694 3549623 915353 3613896 3780743 5692922 6477421 934487 467050 702437 377231 235487 510564 419479 783225 603779 188669 29955 22679 26502 19603 81556 234401 206700 209295 417578 73343 IS Height 81556 234401 234401 234401 603779 603779 206700 209295 209295 417578 26502 19603 26502 19603 26502 29955 22679 29955 188669 73343 73343 73343 73343 73343 73343 73343 73343 73343 Sam ple size 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 Factor2 Detection... 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 bb 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 bb 1.0 MM 1.0 bb 1.0 bb 1.0 MM 1.0 bb 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 bb 1.0 MM 1.0 bb 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM PV by LIU 14-Dec-12, SV by AP 16-Dec-12. NOTE: Std. Concn. & LOD units = ng abs. Excluded points denoted with an 'X' in the Detection Flag column. Page 207 of 307 www.axysanalytical.com Quantify Sample Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\Inst_G\PFC.PRO\FC\FC2G_445-A1 .qld Last Altered: Friday, December 14, 2012 11:01:10 Pacific Standard Time Printed: Sunday, December 16, 2012 09:33:39 Pacific Standard Time ID: FC-LIN-42221W500-G,, Name: FC2G_445S010 Description: 1,,15uL Date: 13-Dec-2012 Time: 18:41:21 PFBA FC2G 445S010 100- 5.11 9.54e5 2819195 %- PFPeA FC2G 445S010 100- 5.95 1.25e6 5486431 %- 1 PFHxA FC2G 445S010 100- 6.32 1.81e6 9542781 %- PFHpA FC2G 445S010 100- 6.69 2.06e6 1 8084141 %- PFOA-1 FC2G_445S010 100q 7.06 1 .78e6 7387648 %- PFOA-2 FC2G 445S010 0 - l/ n min 5.00 6.00 7.00 0- _ n l min 5.00 6.00 7.00 0 ,1 min 5.00 6.00 7.00 0 min 5.00 6.00 7.00 0-- 7.00 min 8.00 PFNA FC2G 445S010 PFDA FC2G 445S010 min PFUnA FC2G 445S010 100- 8.50 2.82e6 10940871 PFDoA FC2G 445S010 100- 9.09 3.46e6 13828879 PFBS-1 FC2G_445S010 6.45 100 4.39e5 1805813 PFBS-2 FC2G 445S010 %- %- % L kmin 0- J r ................. min 0- ................ t min 0 min 8.00 10.00 12.00 8.00 10.00 12.00 5.00 6.00 7.00 PFHxS-1 FC2G 445S010 PFHxS-2 FC2G 445S010 PFHxS-3 FC2G 445S010 PFOS-1 FC2G 445S010 PFOS-2 FC2G 445S010 PFOSA FC2G 445S010 min min min min min min min min PV by LIU 14-Dec-12, SV by AP 16-Dec-12. NOTE: Std. Concn. & LOD units = ng abs. Excluded points denoted with an 'X' in the Detection Flag column. Page 208 of 307 www.axysanalytical.com Quantify Sample Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\Inst_G\PFC.PRO\FC\FC2G_445-A1 .qld Last Altered: Friday, December 14, 2012 11:01:10 Pacific Standard Time Printed: Sunday, December 16, 2012 09:33:39 Pacific Standard Time ID: FC-LIN-42221W500-G,, Name: FC2G_445S010 Description: 1,,15uL Date: 13-Dec-2012 Time: 18:41:21 13C2-PFOA FC2G 445S010 13C4-PFOA FC2G 445S010 13C4-PFOS-1 FC2G 445S010 13C4-PFOS-2 FC2G 445S010 18O2-PFHxS-1 FC2G 445S010 18O2-PFHxS-2 FC2G 445S010 13C4-PFBA FC2G 445S010 min 13C2-PFHxA FC2G 445S010 min 13C5-PFNA FC2G 445S010 min 13C2-PFDA FC2G 445S010 min 13C2-PFDoA FC2G 445S010 min 13C2-PFOUEA FC2G 445S010 min min min min min min min PV by LIU 14-Dec-12, SV by AP 16-Dec-12. NOTE: Std. Concn. & LOD units = ng abs. Excluded points denoted with an 'X' in the Detection Flag column. Page 209 of 307 www.axysanalytical.com Quantify Sample Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\Inst_G\PFC.PRO\FC\FC2G_445-A1 .qld Last Altered: Friday, December 14, 2012 11:01:10 Pacific Standard Time Printed: Sunday, December 16, 2012 09:33:39 Pacific Standard Time ID: FC-LIN-42221W500-G,, Name: FC2G_445S010 Description: 1,,15uL Date: 13-Dec-2012 Time: 18:41:21 # Name 1 PFBA 2 PFPeA 3 PFHxA 4 PFHpA 5 PFOA-1 6 PFOA-2 7 PFNA 8 PFDA 9 PFUnA 10 PFDoA 11 PFBS-1 12 PFBS-2 13 PFHxS-1 14 PFHxS-2 15 PFHxS-3 16 PFOS-1 17 PFOS-2 18 PFOSA 19 13C2-PFOA 20 13C4-PFOA 21 13C4-PFO S-1 22 13C4-PFOS-2 23 18O2-PFHxS-1 24 18O2-PFHxS-2 25 13C4-PFBA 26 13C2-PFHxA 27 13C5-PFNA 28 13C2-PFDA 29 13C2-PFDoA 30 13C2-PFOUEA IS# Trace RT 25 212.99 >1 6 8.98 5.11 26 262.98 > 218.... 5.95 26 312.97> 268.98 6.32 26 362.97> 318.98 6.69 19 412.97> 368.98 7.06 19 412.97> 168.80 7.06 27 462.96 > 418.... 7.46 28 512.96 > 468.... 7.93 28 562.96 > 518.... 8.50 29 612.95 > 568.... 9.09 23 298.94> 79.96 6.45 24 298.94 > 98.95 6.43 23 398.84 > 79.96 7.30 24 398.84> 98.96 7.25 23 398.84> 118.70 7.25 21 4 98 .93 > 79.96 8.23 22 498.93> 98.96 8.23 21 498 > 78 9.90 20 414.97 > 369.... 7.06 416.97 > 371.9 7.06 30 503 > 79.96 8.23 30 503 > 98.96 8.23 30 402.9>84 7.30 30 402.9>103 7.25 30 216.99>171.98 5.07 30 314.97>269.98 6.32 30 467.96>422.97 7.46 30 514.96 >469.96 7.93 30 614.95 > 569.... 9.09 458.98 >393.98 7.39 Area 953630 1246496 1813293 2055822 1776266 480485 1926313 2264803 2816578 3461389 439326 225115 395234 213611 129524 440275 280510 560574 125019 40127 7488 5370 6135 3840 21251 43496 44006 60934 110521 16675 IS Area 21251 43496 43496 43496 125019 125019 44006 60934 60934 110521 6135 3840 6135 3840 6135 7488 5370 7488 40127 16675 16675 16675 16675 16675 16675 16675 16675 16675 ng/L 516.166 505.025 492.664 488.032 497.215 510.440 495.377 474.551 472.106 484.187 956.132 1011.489 966.396 1042.150 971.484 980.906 979.408 497.907 36.848 9.653 18.093 17.518 17.070 14.997 12.013 11.421 11.643 13.317 16.441 8.525 LOD 0.3272 0.1367 0.1715 0.0310 0.0120 0.1584 0.3104 0.2250 0.8537 1.0257 0.4177 0.1748 0.1684 0.0237 0.3608 0.0231 0.0451 0.0968 0.1915 0.0223 %Rec 103.2 101.0 98.5 97.6 99.4 102.1 99.1 94.9 94.4 96.8 95.6 101.1 96.6 104.2 97.1 98.1 97.9 99.6 102.4 80.4 100.5 97.3 94.8 83.3 100.1 95.2 97.0 111.0 137.0 85.3 S/N 3615 41155 61073 22109 0 0 0 5790 10581 10729 44106 34911 0 0 0 2000 1853 6474 0 0 293 285 1927 0 75 1922 787 384 256 1148 Noise 780 133 156 366 0 0 0 1405 1034 1289 41 26 0 0 0 572 449 282 0 0 96 69 11 0 849 117 227 589 1712 58 Height IS Height 2819195 63446 5486431 224421 9542781 224421 8084141 224421 7387648 538275 2032274 538275 7777143 178490 8136139 226144 10940871 226144 13828879 438419 1805813 21861 902602 14088 1306717 21861 742338 14088 434415 21861 1144079 28164 831838 19581 1825826 28164 538275 168417 168417 28164 66524 19581 66524 21861 66524 14088 66524 63446 66524 224421 66524 178490 66524 226144 66524 438419 66524 66524 Sam ple size 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 Factor2 Detection... 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 bb 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 bb 1.0 MM 1.0 bb 1.0 bb 1.0 MM 1.0 bb 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 bb 1.0 MM 1.0 bb 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM PV by LIU 14-Dec-12, SV by AP 16-Dec-12. NOTE: Std. Concn. & LOD units = ng abs. Excluded points denoted with an 'X' in the Detection Flag column. Page 210 of 307 www.axysanalytical.com Quantify Sample Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\Inst_G\PFC.PRO\FC\FC2G_445-A1 .qld Last Altered: Friday, December 14, 2012 11:01:10 Pacific Standard Time Printed: Sunday, December 16, 2012 09:33:39 Pacific Standard Time ID: FC-LIN-42221W500-H,, Name: FC2G_445S011 Description: 1,,15uL Date: 13-Dec-2012 Time: 18:58:15 PFBA FC2G 445S011 PFPeA FC2G 445S011 PFHxA FC2G 445S011 PFHpA FC2G 445S011 PFOA-1 FC2G 445S011 PFOA-2 FC2G 445S011 PFNA FC2G 445S011 min PFDA FC2G 445S011 min PFUnA FC2G 445S011 min PFDoA FC2G 445S011 min PFBS-1 FC2G 445S011 min PFBS-2 FC2G 445S011 min PFHxS-1 FC2G 445S011 min PFHxS-2 FC2G 445S011 min PFHxS-3 FC2G 445S011 min PFOS-1 FC2G 445S011 min PFOS-2 FC2G 445S011 min PFOSA FC2G 445S011 min min min min min min min PV by LIU 14-Dec-12, SV by AP 16-Dec-12. NOTE: Std. Concn. & LOD units = ng abs. Excluded points denoted with an 'X' in the Detection Flag column. Page 211 of 307 www.axysanalytical.com Quantify Sample Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\Inst_G\PFC.PRO\FC\FC2G_445-A1 .qld Last Altered: Friday, December 14, 2012 11:01:10 Pacific Standard Time Printed: Sunday, December 16, 2012 09:33:39 Pacific Standard Time ID: FC-LIN-42221W500-H,, Name: FC2G_445S011 Description: 1,,15uL Date: 13-Dec-2012 Time: 18:58:15 13C2-PFOA FC2G 445S011 13C4-PFOA FC2G 445S011 13C4-PFOS-1 FC2G 445S011 13C4-PFOS-2 FC2G 445S011 18O2-PFHxS-1 FC2G 445S011 18O2-PFHxS-2 FC2G 445S011 13C4-PFBA FC2G 445S011 min 13C2-PFHxA FC2G 445S011 min 13C5-PFNA FC2G 445S011 13C2-PFDA FC2G 445S011 min 13C2-PFDoA FC2G 445S011 min 13C2-PFOUEA FC2G 445S011 min min min min min min min PV by LIU 14-Dec-12, SV by AP 16-Dec-12. NOTE: Std. Concn. & LOD units = ng abs. Excluded points denoted with an 'X' in the Detection Flag column. Page 212 of 307 www.axysanalytical.com Quantify Sample Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\Inst_G\PFC.PRO\FC\FC2G_445-A1 .qld Last Altered: Friday, December 14, 2012 11:01:10 Pacific Standard Time Printed: Sunday, December 16, 2012 09:33:39 Pacific Standard Time ID: FC-LIN-42221W500-H,, Name: FC2G_445S011 Description: 1,,15uL Date: 13-Dec-2012 Time: 18:58:15 # Name 1 PFBA 2 PFPeA 3 PFHxA 4 PFHpA 5 PFOA-1 6 PFOA-2 7 PFNA 8 PFDA 9 PFUnA 10 PFDoA 11 PFBS-1 12 PFBS-2 13 PFHxS-1 14 PFHxS-2 15 PFHxS-3 16 PFOS-1 17 PFOS-2 18 PFOSA 19 13C2-PFOA 20 13C4-PFOA 21 13C4-PFO S-1 22 13C4-PFOS-2 23 18O2-PFHxS-1 24 18O2-PFHxS-2 25 13C4-PFBA 26 13C2-PFHxA 27 13C5-PFNA 28 13C2-PFDA 29 13C2-PFDoA 30 13C2-PFOUEA IS# Trace RT 25 212.99>168.98 5.20 26 262.98 > 218.... 5.98 26 312.97> 268.98 6.36 26 362.97> 318.98 6.74 19 4 12 .97 > 368.98 7.11 19 4 12 .97 > 168.80 7.11 27 462.96 > 418.... 7.49 28 512.96 > 468.... 7.99 28 562.96 > 518.... 8.56 29 612.95 > 568.... 9.12 23 298.94> 79.96 6.47 24 298.94 > 98.95 6.47 23 398.84 > 79.96 7.30 24 398.84> 98.96 7.30 23 398.84> 118.70 7.30 21 4 98 .93 > 79.96 8.23 22 498.93> 98.96 8.29 21 498 > 78 9.93 20 4 14 .97 > 369.... 7.11 4 16 .97 > 371.9 7.11 30 503 > 79.96 8.29 30 503 > 98.96 8.29 30 402.9>84 7.30 30 402.9>103 7.30 30 216.99>171.98 5.16 30 314.97>269.98 6.36 30 467.96>422.97 7.49 30 514.96 >469.96 7.99 30 614.95 > 569.... 9.12 458.98 >393.98 7.43 Area 1826622 2438345 3315686 4086324 3356814 888554 3754168 4575060 5587121 6343367 780518 390955 689052 356435 214852 786051 532049 1006244 100831 30166 5039 3443 4060 2738 16912 35274 33246 58399 112180 14160 IS Area 16912 35274 35274 35274 100831 100831 33246 58399 58399 112180 4060 2738 4060 2738 4060 5039 3443 5039 30166 14160 14160 14160 14160 14160 14160 14160 14160 14160 ng/L 1244.856 1247.545 1252.147 1253.279 1251.114 1245.993 1251.356 1264.185 1265.057 1269.169 2513.525 2497.700 2509.441 2487.173 2508.404 2504.839 2504.844 1088.040 39.533 7.257 14.336 13.227 13.304 12.590 11.257 10.906 10.358 15.029 19.651 7.240 LOD 0.2164 0.1830 0.0019 0.1523 0.0310 0.0120 0.0804 0.1920 0.3995 0.2250 1.9786 3.6719 1.0640 0.1999 0.3882 0.4125 0.0157 0.0824 0.1160 %Rec 99.6 99.8 100.2 100.3 100.1 99.7 100.1 101.1 101.2 101.5 100.5 99.9 100.4 99.5 100.3 100.2 100.2 87.0 109.8 60.5 79.6 73.5 73.9 69.9 93.8 90.9 86.3 125.2 163.8 72.4 S/N 12024 36887 44296 87183 0 0 0 6641 17560 16794 61314 45765 0 0 0 2485 1977 4989 0 0 195 91 0 0 62 2803 0 531 536 0 Noise 440 268 377 179 0 0 0 2473 1256 1446 46 31 0 0 0 733 766 632 0 0 89 128 0 0 787 64 0 406 841 0 Height IS Height 5294785 48508 9870934 180233 16680690 180233 15587718 180233 13981256 420804 3715083 420804 13590439 122614 16424977 215978 22063054 215978 24287154 451307 2815345 13847 1421163 8691 2159335 13847 1151307 8691 675435 13847 1821830 17369 1513933 11737 3154100 17369 420804 122551 122551 17369 53946 11737 53946 13847 53946 8691 53946 48508 53946 180233 53946 122614 53946 215978 53946 451307 53946 53946 Sam ple size 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 Factor2 Detection... 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 bb 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 bb 1.0 MM 1.0 bb 1.0 bb 1.0 MM 1.0 bb 1.0 MMX 1.0 MM 1.0 MM 1.0 MM 1.0 bb 1.0 MM 1.0 bb 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MMX 1.0 MM PV by LIU 14-Dec-12, SV by AP 16-Dec-12. NOTE: Std. Concn. & LOD units = ng abs. Excluded points denoted with an 'X' in the Detection Flag column. Page 213 of 307 www.axysanalytical.com _________ tm ______ppc- \ _________________ Sample List Report MassLynx 4.1 SCN627 Sample List: G:\Masslynx\lnst_G\_Master.PRO\SampleDB\FC2G_455.SPL Last Modified: Tuesday, December 18, 2012 16:01:48 Pacific Standard Time Printed: Tuesday, December 18, 2012 16:07:45 Pacific Standard Time .' Page 1 of 1 Page Position (1,1) J.IW-: ? c A t File Name Sam ple ID File Text Bottle Signln SignDut Inj VoL 1 FC2G 455S001 MeOH,, 1,,15uL ' 1:8,A 2 FC2G 455S002 MeOH,, 1,,15uL 1:8,A 3 FC2G 45.5S003 FC-LIN-42221W500-A,, 1,,15uL 1:1,A 4 FC2G 455S004 FC-LIN-42221W500-D,, 1,,15uL 1:1,D 5 FC2G 455S005 FC-UN-42221W500-D,, 1,,15uL 1:1 ,D 6 FC2G 455S006 WG42273-104,,SAR 1,WG42273,15/4000uL 3:2,B 7 FC2G 455S007 WG42273-102,,SPM 1,WG42273,15/4000uL 3:2,C 8 FC2G 455S008 MeOH,, 1,,15uL . 1:8,A 9 FC2G 455S009 MeOH,, 1,,15uL . 1:8,A 10 FC2G 455S010 WG42273-101,,BLK 1,WG42273,15/4000uL 3:2,D 11 FC2G 455S011 L18989-1,, 1,WG42273,15/4000uL 3:2,E 12 FC2G 455S012 L18989-2,, 1,WG42273,15/4000uL 3:2,F 13 FC2G 455S013 L18989-3,, 1.WG42273,15/4000uL 3:3,A 14 FC2G 455S014 L18989-4,, 1,WG42273,15/4000uL 3:3,B 15 FC2G 455S015 L18989-5,, 1,WG42273,15/4000uL 3:3,C 16 FC2G 455S016 L18989-6,, 1,WG42273,15/4000uL 3:3,D 17 FC2G 455S017 L18989-7,, 1,WG42273,15/4000uL 3:3,E 18 FC2G 455S018 L18989-8,, 1,WG42273,15/4000uL 3:3,F 19 FC2G 455S019 L18989-9,, 1,WG42273,15/4000uL 3:4,A 20 FC2G 455S020 L18989-10,, 1,WG42273,15/4000uL 3:4,B 21 FC2G 455S021 L18989-11,, 1,WG42273,15/4000uL 3:4,C 22 FC2G 455S022 WG42273-103,,DUP 1,WG42273,15/4000uL 3:4, D 23 FC2G 455S023 L18989-12,, 1,WG42273,15/4000uL 3:4,E 24 FC2G 455S024 L18989-13,, 1,WG42273,15/4000uL 3:4,F 25 FC2G 455S025 L18989-14,, 1,WG42273,15/4000uL 3:5,A 26 FC2G 455S026 L18992-1,, 1,WG42273,15/4000uL 3:5,B 27 FC2G 455S027 L18992-2,, 1,WG42273,15/4000uL 3:5,C D ' f -. L -_ .. -- -_ -- -- ~ -. 7 - " ---" - T I_ --- - - - - - - -, - - 15.0 15.0 15.0 15.0 15.0 15.0 15.0 15.0 15.0 15.0 15.0 15.0 15.0 \ 15.0 15.0 15.0 15.0 . 15.0 15.0 ^ 15.0 15,0 15.0 15.0 15.0 15.0 1.5.0 15.0 28 FC2G 455S028 FC-LN-42221W500-D,, 1,,15.uL 1:1, D - - 15.0 29 FC2G 455S029 FC-LI N-42221 W500-D,, 1,,15uL 30 FC2G 455S030 MeOH,, 1,,15uL 31 FC2G 455S031 MeOH,, 1,,15uL 1:1, D ' 1:8,A 1:8,A - L -- 7 15.0 __ 15.0 ^ 15.0 Page 214 of 307 www.axysanalytical.com Quantify Sample Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\lnst_G\PFC.PRO\FC\FC2G_455-B.qld Last Altered: Tuesday, January 08, 2013 12:06:04 Pacific Standard Time Printed: Thursday, January 10, 2013 12:48:05 Pacific Standard Time ID: FC-LIN-42221W500-D,, Name: FC2G_455S004 Description: 1,,15uL Date: 18-Dec-2012 Time: 18:49:50 PFBA FC2G_455S004 100- 5.18 4.55e4 148574 5.00 6.00 7.00 PFPeA FC2G 455S004 100- 5.96 6.33e4 " 320827 %- l |; 0 - ^4mrrrn min 5.00 6.00 7.00 PFHxA FC2G 455S004 100- 6.36 1.15e5 577808 %: . : j 0 -- ---..............i -- --- min 5.00 6.00 7.00 PFHpA FC2G_455S004 100- 6.69 _ 1.19e5 487609 %- o5.00 6.00 7.00 PFNA FC2G 455S004 PFDA FC2G_455S004 100- 7.93 1.38e5 1 492967 PFUnA FC2G_45SS004 _ 8.50 100- 1.44e5 612888 % ( PFDoA FC2G_455S004 100-, 9.06 f 1.54e5 I 665636 %- PFHxS-1 FC2G 455S004 100- 7.25 /T2.57e4 i \ 98811 %- 8.00 10.00 12.00 PFHxS-2 FC2G 455S004 100- 7.30 A 1.34e4 / 50461 %' 0 ,, 7.00 i i , min 8.00 o: J 8.00 8.00 10.00 12.00 PFHxS-3 FC2G_455S004 100- 7.25 8.26e3 30973 7.00 8.00 8.00 10.00 12.00 PFOS-1 FC2G_455S004 100- 8.23 r 2.37e4 I 65039 %- 9.90 8.00 10.00 12.00 PFOA-1 FC2G 455S004 100^ 7.11 A 1.05e5 M 430210 %: I \ - !\ 0-J . U -___ ______ 7.00 8.00 PFBS-1 FC2G_455S004 100 6.45 2.96e4 | 142625 %- 05.00 6.00 7.00 PFOS-2 FC2G__455S004 100- f~4L8i5.213e4 52888 8.00 10.00 12.00 PFOA-2 FC2G 455S004 100- 7.11 JT 2-77e4 Q 113863 %- ' i 0" . .. 7.00 8.00 PFBS-2 FC2G_455S004 100 16.5447e4 l 75453 1 J\ 5.00 6.00 7.00 PFOSA FC2G_455S004 100- 9.90 2.28e4l 80135 1 % 8.00 10,00 12.00 PV by LHE 08-Jan-13, SV by AP 10-Jan-13. NOTE: OPR Conen. & LOD units = ng/mL, Sample and Lab BLK Conen. & LOD units = ng/L. Page 215 of 307 www.axysanalytical.com Quantify Sample Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\lnst_G\PFC.PRO\FC\FC2G__455-B.qld Last Altered: Tuesday, January 08, 2013 12:06:04 Pacific Standard Time Printed: Thursday, January 10, 2013 12:48:05 Pacific Standard Time ID: FC-LIN-42221W500-D,, Name: FC2G_455S004 Description: 1,,15uL Date: 18-Dec-2012 Time: 18:49:50 13C2-PFOA FC2G 455S004 7.11 100" I " 1.87e5 n 754666 %- o - / ' ... . . min 7.00 8.00 13C4-PFOA FC2G 455S004 100n 7.06 A 6.41e4 / 251133 %~ ' = 0- ......... . , min 7.00 8.00 13C4-PFOS-1 FC2G 455S004 in 8.23 1.03e4 | 39661 % |! 0- min 8.00 10i00 12.00 13C4-PFOS-2 FC2G 455S004 100- 8.23 f 7.82e3 E|;i| 30978 %-- j: 0 ill; min 8.00 10i00 12.00 1802-PFHxS-1 FC2G_455S004 100n 7.30 fT 9.76e3 i t 35470 %~ 0-J 7.00 8.00 13C4-PFBA FC2G 455S004 13C2-PFHxA FC2G_455S004 100' 6.34 6.66e4 325053 %- 13C5-PFNA FC2G_455S004 100- 7.46 6.56e4 277931 : \ %- 13C2-PFDA FC2G 455S004 mn 100 J . 7-9 Ii f 7.39e4 268434 %Hj 1 13C2-PFDOA FC2G__455S004 100-1 9.06 f 9.73e4 429607 %z min 0- . min 0-- i-V -... 5.00 6.00 7.00 7.00 8.00 0 ^ - 1 - TM TM min 8.00 10.00 12.00 0-r 8.00 10.00 12.00 1802-PFHxS-2 FC2G_455S004 100 7.30 6.82u3 1 28975 %" 7.00 8.00 13C2-PFOUEA FC2G_455S004 100- 7.39 2:26e4~J| 90898 : : %- 0-4 7.00 w f =pT7 min 8.00 PV by LHE 08-Jan-13, SV by AP 10-Jan-13. NOTE: OPR Conen. & LOD units = ng/mL, Sample and Lab BLK Conen. & LOD units = ng/L. Page 216 of 307 www.axysanalytical.com Quantify Sample Report MassLynx 4.1 SCN627 Dataset: G:\Massiynx\lnst_G\PFC.PRO\FC\FC2G_455-B.qld Last Altered: Tuesday, January 08, 2013 12:06:04 Pacific Standard Time Printed: Thursday, January 10, 2013 12:48:05 Pacific Standard Time ID: FC-LIN-42221W500-D,, Name: FC2G_455S004 Description: 1,,15uL Date: 18-Dec-2012 Time: 18:49:50 # Name 1 PFBA 2 PFPeA 3 PFHxA 4 PFHpA 5 PFOA-1 6 PFOA-2 7 PFNA 8 PFDA 9 PFUnA 10 PFDoA 11 PFBS-112 PFBS-2 13 PFHxS-1 14 PFHxS-2 15 PFHxS-3 16 PFOS-1 17 PFOS-2 18 PFOSA 19 13C2-PFOA 20 13C4-PFOA 21 13C4-PFOS-1 22 13C4-PFOS-2 23 1802-PFH xS-l 24 1802-PFHxS-2 25 13C4-PFBA 26 13C2-PFHxA 27 13C5-PFNA 28 13C2-PFDA 29 13C2-PFDoA 30 13C2-PFOUEA . IS# Trace RT 25 212.99>168.98 5.18 26 262.98 >218.... 5.96 26 312.97> 268.98 6.36 26 362.97> 318.98 6.69 19 412.97> 368.98 7.11 19 412.97> 168.80 7.11 27 462.96 >4 1 8.... 7.46 28 512.96 > 468.... 7.93 28 562.96 >5 1 8.... 8.50 29 612.95 > 5 6 8 ,... 9.06 23 298.94> 79.96 6.45 24 298.94 > 98.95 6.47 23 398.84 > 79.96 7.25 24 398.84> 98.96 7.30 23 398.84> 118.70 7.25 21 498.93> 79.96 8.23 22 498.93> 98.96 8.23 21 498 > 78 9.90 20 414.97 > 369.... 7.11 416.97 > 371.9 7.06 30 503 > 79.96 8.23 30 503 > 98.96 8.23 30 402.9>84 7.30 30 402.9>103 7.30 30 216.99>171.98 5.18 30 314.97>269.98 6.34 30 467.96>422.97 7.46 30 514.96 >469.96 7.93 30 614.95 > 5 6 9 .... 9.06 458.98 >393.98 7.39 Area 45497 63301 115119 119037 105234 27721 113135 137589 144066 . 153785 29617 15379 25652 13409 8264 23725 15076 22802 187308 64121 10329 7824 9756 6818 29865 66645 65558 73922 97271 22615 IS Area ng/L 29865 17.406 66645 16.584 66645 19.007 66645 18.057 187308 18.757 187308 18.920 65558 19.805 73922 20.927 73922 17.642 97271 20.513 9756 40.713 6818 38.781 9756 39.453 6818 36.569 9756 38.010 10329 39.088 7824 39.606 10329 18.056 64121 34,549 15.425 22615 18.402 22615 18.818 22615 20.016 22615 19.635 22615 . 12.448 22615 12.903 22615 12.789 22615 11.912 22615 10.669 11.562 LOD 0.0463 0.1275 0.1452 0.0310 0.0603 0.0709 . 0.2704 . 0.5169 0.1125 0.0015 0.2422 0.1116 0.1829 0.1242 0.0463 0.2727 0.0126 0.0394 0.0832 0.0281 %Rec 87.0 82.9 95.0 90.3 93.8 94.6 99.0. 104.6 88.2 102.6 101.8 97.0 98,6 91.4 95.0 97.7 99.0 90.3 96.0 128.5 102.2 104.5 111.2 109.1 103.7 107.5 106.6 99.3 88.9 115.6 S/N 388 2367 3401 1991 0 0 1257 954 1718 1500 2627 2465 0 331 858 279 260 710 0 415 288 448 1174 0 106 3724 0 820 423 1234 Noise 383 136 170 245 0 0 390 517 357 444 54 31 0 153 36 233 203 113 0 606 138 69 30 0 877 87 0 327 1016 74 Height 148574 320827 577808 487609 430210 113863 490086 492967 612888 665636 142625 75453 98811 50461 30973 65039 52888 80135 754666 251133 39661 30978 35470 28975 92484 325053 277931 268434 429607 90898 IS Height 92484 325053 325053 325053 754666 754666 277931 268434 268434 429607 35470 28975 35470 28975 35470 39661 30978 39661 251133 90898 90898 90898 90898 90898 90898 90898 90898 90898 Sample size 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1-0000 Factor2 Detection... 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 MM 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 MM 1.0 MM 1.0 MM 1.0 bb 1.0 MM 1.0 bb 1.0 bb 1.0 MM 1.0 bb 1.0 MM 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 bb PV by LHE 08-Jan-13, SV by AP 10-Jan-13. NOTE: OPR Conen. & LOD units = ng/mL, Sample and Lab BLK Conen. & LOD units = ng/L. 0_, Page 217 of307 www.axysanalytical.com Quantify Sample Report MassLynx 4.1 SCN627 Dataset: G:\MassIynx\lnst_G\PFC.PRO\FC\FC2G_455-B.qld Last Altered: Tuesday, January 08, 2013 12:06:04 Pacific Standard Time Printed: Thursday, January 10, 2013 12:48:05 Pacific Standard Time ID: FC-LIN-42221W500-D,, Name: FC2G_455S028 Description: 1,,15uL Date: 19-Dec-2012 Time: 01:53:10 ooi ' PFBA FC2G 455S028 5.16 f " 4.10e4 141011 ;; %~ !A 0- ttt mih 5.00 6.00 7.00 PFPeA FC2G 455S028 io n 5.98 5.61 e4 278739 !| % - ;; o- !- \ -rrm min 5.00 6.00 7.00 PFHxA FC2G 455S028 100n - 6.37 9.74e4 I 484497 it %- n o5.00 6.00 7.00 PFHpA FC2G_455S028 100- 6.74 1,08e5 454795 | %- 5.00 6.00 7.00 PFOA-1 FC2G_455S028 100- 7.11 .7 9.00e4 ,367406 7.00 8.00 PFOA-2 FC2G_455S028 100- 7.11 /' 2.54e4 ' 103379 %- 07.00 8.00 PFNA FC2G__455S028 100- 7 AO 9.91e4 A 404222 M ; 7.00 ^ A min 8.00 PFHxS-1 FC2G 455S028 PFDA FC2G 455S028 1001" 1.17e5 1 421843 %~ m M, 0-1 8.00 10.00 min 12.00 PFHxS-2 FC2G_455S028 100- 7.30 A 1.14e4 f \ 45905 %- 7.00 8.00 PFUnA FC2G 455S028 100- f 1.27e5 i 556113 %|1| 0 \A j 8.00 10.00 r min 12.00 PFHxS-3 FC2G__455S028 100- 7.30 A 6.84e3 i \ 26461 7.00 8.00 PFDoA FC2G 455S028 100- r 1.34e5 ! 541445 %i o: n min 8.00 10.00 12.00 PFOS-1 FC2G_455S028 100- 8.23 r 2.09e4 60602 8.00 9.90 10.00 12.00 PFBS-1 FC2G 455S028 100- 2.63e4 h 126264 %- 0 - . ----------- L I mm 5.00 6.00 7.00 PFOS-2 FC2G_455S028 100- _ 8.23 1.42e4 47419 /l 8.00 10.00 12.00 PFBS-2 FC2G_455S028 100-1 647 1 .3 5 e 4 l 67305 II %- o5.00 6.00 7.00 PFOSA FC2G_455S028 9;90 100^ 2 .0 1 e 4 l 67420 8.00 10.00 12.00 PV by LHE 08-Jan-13, SV by AP 10-Jan-13. NOTE: OPR Concn. & LOD units = ng/mL, Sample and Lab BLK Concn. & LOD units = ng/L. Page 218 of 307 www.axysanalytical.com Quantify Sample Report MassLynx 4.1 SCN627 Dataset G:\Masslynx\lnst_G\PFC.PRO\FC\FC2G_455-B.qld Last Altered: Tuesday, January 08, 2013 12:06:04 Pacific Standard Time Printed: Thursday, January 10, 2013 12:48:05 Pacific Standard Time ID: FC-LIN-42221W500-D,, Name: FC2G_455S028 Description: 1,,15uL Date: 19-Dec-2012 Time: 01:53:10 13C2-PFOA FC2G_455S028 100- _ 7.11 4 1.62e5 1 682835 %- 7.00 8.00 13C4-PFBA FC2G__455S028 100- 5.13 S 2.60e4 %- 4.06 i -L 5.00 6.00 7.00 13C4-PFOA FC2G 455S028 100- 7.11 5.19e4 ; 1213907 %- \ /" \ 0- 7.00 ~r~r min 8.00 13C2-PFHxA FC2G_455S028 100-i 6.36 5.64e4 281006 13C4-PFOS-1 FC2G 455S028 8.23 100-n r 9.30e3 1 34762 % ~ I[f \InI 0 - .j J A m . ,, 8.00 10.00 ttttt min 12.00 13C5-PFNA FC2G__455S028 100- 7.46 5.88e4 A 245524 %- 13C4-PFOS-2 FC2G 455S028 100- 8.23 ; 7.32e3 1 28023 % -_ il 0 - ^ --------- -- TTTTr min 8.00 10.00 12.00 13C2-PFDA FC2G_455S028 100- _ 7.93 , 5.96e4 I 209570 %- 1802-PFHXS-1 FC2G 455S028 100- 7.30 |~9.17e3 |4 37990 0- : 7.00 ... - min 8.00 1302-PFDoA FC2G_455S028 100- 9.03 8.51 e4 360513 1802-PFHxS-2 FC2G 455S028 100-, 7.30 / 5.63e3 : \ 20561 %- o- / 7.00 x ..., 8.00 13C2-PFOUEA FC2G_455S028 100- 7:39 _ 2.05e4 j \ 83993 I \ %- -- 5.00 6.00 7.00 7.00 8.00 8.00 10.00 12.00 -- 8.00 10.00 12.00 7.00 8.00 PV by LHE 08-Jan-13, SV by AP 10-Jan-13. NOTE: OPR Conen. & LOD units = ng/mL, Sample and Lab BLK Conen. & LOD units = ng/L. IC Page 219 of 307 www.axysanalytical.com Quantify Sample Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\lnst_G\PFC.PRO\FC\FC2G_455-B.qld Last Altered: Tuesday, January 08, 2013 12:06:04 Pacific Standard Time Printed: Thursday, January 10, 2013 12:48:05 Pacific Standard Time ID: FC-LIN-42221W500-D,, Name: FC2G_455S028 Description: 1,,15uL Date: 19-Dec-2012 Time: 01:53:10 # Name 1 PFBA 2 PFPeA 3 PFHxA 4 PFHpA 5 PFOA-1 6 PFOA-2 7 PFNA 8 PFDA 9 PFUnA 10 PFDoA 11 PFBS-1 12 PFBS-2 13 PFHxS-1 14 PFHxS-2 15 PFHxS-3 16 PFOS-1 17 PFOS-2 18 PFOSA 19 13C2-PFOA 20 13C4-PFOA 21 13C4-PFOS-1 22 13C4-PFOS-2 23 1802-PFHXS-1 24 1802-PFHxS-2 25 13C4-PFBA 26 13C2-PFHxA . 27 13C5-PFNA 28 13C2-PFDA 29 13C2-PFDoA 30 13C2-PFOUEA IS# Trace RT 25 212.99>168.98 5.16 26 262.98 >218.... 5.98 26 312.97> 268.98 6.37 26 362.97> 318.98 6.74 19 412.97> 368.98 7.11 19 412.97> 168.80 7.11 27 462.96 > 4 1 8 .... 7.49 28 512.96 >468.... 7.93 28 562.96 > 518.... 8.47 29 612.95 >568.... 9.03 23 298.94> 79.96 6.47 24 298.94 > 98.95 6.47 23 398.84 > 79.96 7.30 24 398.84> 98.96 7.30 23 398.84> 118.70 7.30 21 4 98 .93> 79.96 8.23 22 498.93> 98.96 8.23 21 498 > 7 8 . 9.90 20 414.97 > 369.... 7.11 416.97 >3 7 1,9 7.11 30 503 > 79.96 8.23 30 503 > 98.96 8.23 30 402.9>84 7.30 30 402.9>103 7.30 30 216.99>171.98 5.13 30 314.97>269.98 6.36 30 467.96>422.97 7.46 30 514.96 >469.96 7.93 30 614.95 > 5 6 9 .... 9.03 458.98 >393.98 7.39 Area 41016 56070 97374 108302 89975 25352 99068 116730 127263 133628 26264 13548 21609 11398 6839 20943 14192 20137 162308 51893 9298 7322 9166 5634 26015 56401 58805 59559 85139 20521 IS Area 26015 56401 56401 56401 162308 162308 58805 59559 59559 85139 9166 5634 9166 5634 9166 9298 7322 9298 51893 20521 20521 20521 20521 20521 20521 20521 20521 20521 ng/L 18.018 17.353 18.998 19.405 18.506 19.967 19.334 22.058 19.347 20.362 38.412 41.330 35.341 37.610 33.443 38.330 39.840 17.721 36.992 12.484 18.254 19.409 20.723 17.880 11.950 12.033 12.642 10.577 10.291 10.492 LOD 0.1348 0.1330 0.1480 0.0301 0.1145 0.2740 0.3416 0.1607 0.0350 0.2375 0.2087 0.1376 0,3291 0.0381 0.2614 0.0182 0.0454 0.0723 0.0243 %Rec 90.1 86.8 95.0 97.0 92.5 99.8 96.7 110.3 96.7 101.8 96.0 103.3 88.4 94.0 83.6 95.8 99.6 88.6 102.8 104.0 101.4 107.8 115.1 99.3 99.6 100.3 105.4 88.1 85.8 104.9 S/N 569 1780 3135 4653 2065 494 3124 1526 901 1370 1818 2906 483 1061 205 399 393 729 0 179 363 165 0 1255 116 2408 0 601 442 1294 Noise 248 157 155 98 178 209 129 276 617 395 69 23 177 43 129 152 121 92 0 1192 96 169 0 16 776 117 0 349 816 65 Height 141011 278739 484497 454795 367406 103379 404222 421843 556113 541445 126264 67305 85496 45905 26461 60602 47419 67420 682835 213907 34762 28023 37990 20561 90343 281006 245524 209570 360513 83993 IS Height 90343 281006 281006 281006 682835 682835 245524 209570 209570 360513 37990 20561 37990 20561 37990 34762 28023 34762 213907 83993 83993 83993 83993 83993 83993 83993 83993 83993 Sample size 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 Factor2 Detection... 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1,0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1,0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 MM 1.0 bb 1.0 bb. 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 bb PV by LHE 08-Jan-13, SV by AP 10-Jan-13. NOTE: OPR Concn. & LOD units = ng/mL, Sample and Lab BLK Concn. & LOD units = ng/L. Page 220 of 307 www.axysanalytical.com _________________________________________________________P F ^ Sample List Report M ______________________________________________________________________________;___________________________________________________________ MassLynx 4.1 SCN627 Sample List: G:\Masslynx\lnst_G\JVlaster.PRO\SampleDB\FC3G_015.SPL Last Modified: Monday, January 14, 2013 15:51:45 Pacific Standard Time Printed: Monday, January 14, 2013 15:58:34 Pacific Standard Time Page 1 of 1 Page Position (1,1) File Name Sample ID File Text Bottle s i^nln SignOut Inj VoL 1 FC3G 015S001 MeOH,, 1,,15uL 1:8,A 2 FC3G 015S002 MeOH,, 1,,15uL 1:8,A - - 3 FC3G 015S003 FC-Ll N-42420W500-A,, 1,,15uL 2:1,A - 4 FC3G 015S004 FC-LIN-42420W500-A,, 1,,15uL 2:1,A - - 5 FC3G 015S005 FC-Ll N-42420W500-B,, 1,,15uL 2:1,B - " 6 FC3G 015S006 FC-LIN-42420W5Q0-C,, 1,,15uL 2:1,C 7 FC3G 015S007 FC-LIN-42420W500-D,, 1,,15uL 2:1,D " 8 FC3G 015S008 FC-LI N-42420W500-E,, 1,,15uL 2:1,E - " 9 FC3G 015S009 FC-LIN-42420W500-F,, 1,,15uL 2:1,F - 10 FC3G 15S010 FC-LI N-42420W500-G,, 1,,15uL 2:2,A - 11 FC3G 015S011 FC-Ll N-42420W500-H,, 1,,15uL 2:2,B - - 12 FC3G 015S012 MeOH,, 1,,15uL 1:8,A " 13 FC3G 015S013 MeOH,, 1,,15uL 1:8,A " 14 FC3G 015S014 FC-42420W500-SAR2,, 1,,15uL 2:2,C - 15 FC3G 015S015 FC-42420W500-SAR,, 1,,15uL 2:2,D - 16 FC3G 015S016 FC-LIN-42420W500-D,, 1,,15uL 2:1,D - 17 FC3G 15S017 FC-LIN-42420W500-D,, 1,,15uL 2:1,D* - 18 FC3G 015S018 WG42428-103,,SAR 1,WG42428,15/4000uL 2:2,E- - - 19 FC3G 015S19 WG42428-102,,SPM 1,WG42428,15/4000uL 2:2,F - ** " 20 FC3G 015S020 MeOH,, 1,,.15uL 1:8,A 21 FC3G 015S021 MeOH,, 1,,15uL 1:8,A " 22 FC3G 015S022 WG42428-101 ,,BLK 1.WG42428,15/4000uL 2:3,A ' " " 23 FC3G 015S023 L18989-1 ,R, 1,WG42428,15/4000uL 2:3,B- - - 24 FC3G 015S024 L18989-2,R, 1,WG42428,15/4000uL 2:3,C " - 25 FC3G 015S025 L18989-3,R, 1,WG42428,15/4000uL 2:3,D - - 26 FC3G 015S026 L18989-4,R, 1,WG42428,15/4000uL 2:3,E - 27 FC3G 015S027 L18989-5,R, 1,WG42428,15/4000uL 2:3,F - - 28 FC3G 015S028 L18989-6,R, 1,WG42428,15/4000uL 2:4,A- - 29 FC3G 015S029 L18989-7,R, 1,WG42428,15/4000uL 2:4,B -- 30 FC3G 015S030 L18989-8,R, 1,WG42428,15/4000uL 2:4,C -" 31 FC3G 015S031 L18989-9,R, 1,WG42428,15/4000uL 2:4,D - 32 FC3G 015S032 L18989-10.R, 1,WG42428,15/4000uL 2:4,E 33 FC3G 015S033 L18989-12,R, 1,WG42428,15/4000uL 2:4,F* 34 FC3G 015S034 L18989-13,R, 1,WG42428,15/4000uL 2:5,A - 35 FC3G 015S035 L18989-14.R, 1,WG42428,15/4000uL 2:5,B - 36 FC3G 015S036 FC-LIN-42420W500-D,, 1,,15uL 37 FC3G 015S037 FC-LIN-42420W500-D,, 1,,15uL 38 FC3G 015S038 MeOH,, 1,,15uL 2:1,D 2:1,D 1:8,A "r 1 ;t 39 FC3G 015S039 MeOH,, 1,,15uL 1:8,A -i "4 ' "j -4 -4 "T -1 "j* l -i "*] "* "" " ""I --* -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -J 15.0 15.0 15.0 15.0H 15.0 15.0 15.0 ) 15.0 15.0 15.0 j 15.0 " 15.0 15.0 15.0 15.0 15.0 15.0 15.0 15.0 15.0 15.0 15.0 15.0 15.0 15.0 15.0 15.0 15.0 15.0 15.0 15.0 15,0 15.0 15.0 15.0 15.0 15.0 15.0 15.0 Page 221 of 307 www.axysanalytical.com Quantify Compound Summary Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\Inst_G\PFC.PRO\FC\FC3G_015-A1.qld Last Altered: Tuesday, January 15, 2013 10:48:13 Pacific Standard Time Printed: Tuesday, January 15, 2013 11:33:51 Pacific Standard Time Method: G:\Masslynx\Master Methods\PFC\FC_060_10_01.mdb 03 Dec 2010 17:21:03 Calibration: 15 Jan 2013 10:48:13 Compound name: PFBA # ID Name Type RT 1 F C -L IN -4 2 42 0 W 5 0 0-A ,, F C 3G _0 1 5 S 00 4 Standard 5.21 2 FC -LIN-42420W 500-B ,, FC3G _015S005 Standard 5.19 3 FC-LI N -42420W 500-C ,, FC3G _015S006 Standard 5.19 4 FC-LI N -42420W 500-D ,, FC3G _015S007 Standard 5.23 5 FC-LIN-42420W 500-E,, FC3G _015S008 Standard 5.24 6 FC-LIN-42420W 500-F,, FC3G _015S009 Standard 5.23 7 FC-LI N -4 2 4 2 0 W 5 0 0 -G ,, FC 3G _ 0 15 S 0 1 0 Standard 5.23 8 FC-LIN-42420W 500-H,, FC 3G _015S011 Standard 5.24 Area 2152 5517 17665 63528 301419 500633 1092578 2094684 IS Area 37393 38330 38179 37645 35113 30026 24526 20307 Std. Conc 0.500 1.250 5.000 20.000 100.000 200.000 500.000 1250.000 Compound name: PFBA Coefficient of Determination: RA2 = 0.999381 Calibration curve: -4.99187e-005 * xA2 + 1.05696 * x + 0.203358 Response type: Internal Std ( Ref 25 ), Area * ( IS Conc. / IS Area ) Curve type: 2nd Order, Origin: Exclude, Weighting: 1/x, Axis trans: None ng/L 0.461 1.442 5.062 18.984 97.717 190.827 518.258 1243.976 %Rec 92.2 115.3 101.2 94.9 97.7 95.4 103.7 99.5 S/N 10 48 377 575 6913 5 7187 5 Acq.Date 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 Acq.Time 20:15:53 20:32:54 20:49:47 21:06:48 21:23:49 21:40:42 21:57:35 22:14:36 Detection... MM MM MM MM MM MM MM MM PV by JLIU, SV by KJC 4-Jan-13. Calver conc in ng. Page 222 of 307 www.axysanalytical.com Quantify Compound Summary Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\Inst_G\PFC.PRO\FC\FC3G_015-A1.qld Last Altered: Tuesday, January 15, 2013 10:48:13 Pacific Standard Time Printed: Tuesday, January 15, 2013 11:33:51 Pacific Standard Time Compound name: PFPeA # ID Name Type RT 1 FC -LIN-42420W 500-A ,, FC3G _015S004 Standard 5.95 2 FC -LIN-42420W 500-B ,, FC3G _015S005 Standard 5.95 3 FC-LI N -42420W 500-C ,, FC3G _015S006 Standard 5.97 4 FC-LI N -42420W 500-D ,, FC3G _015S007 Standard 5.95 5 FC-LIN-42420W 500-E,, FC3G _015S008 Standard 5.97 6 FC-LIN-42420W 500-F,, FC3G _015S009 Standard 5.97 7 FC-LI N -4 2 4 2 0 W 5 0 0 -G ,, FC 3G _ 0 15 S 0 1 0 Standard 5.95 8 FC-LIN-42420W 500-H,, FC 3G _015S011 Standard 5.97 Area 2502 6331 20792 80737 379493 670319 1417364 2925513 IS Area 72936 77481 77682 73854 68145 58258 47890 40957 Std. Conc 0.500 1.250 5.000 20.000 100.000 200.000 500.000 1250.000 Compound name: PFPeA Coefficient of Determination: RA2 = 0.999699 Calibration curve: -8.27166e-006 * xA2 + 0.698255 * x + 0.0299181 Response type: Internal Std ( Ref 26 ), Area * ( IS Conc. / IS Area ) Curve type: 2nd Order, Origin: Exclude, Weighting: 1/x, Axis trans: None ng/L 0.547 1.361 4.557 18.749 95.772 198.161 511.694 1245.910 %Rec 109.3 108.9 91.1 93.7 95.8 99.1 102.3 99.7 S/N 50 141 429 1512 8374 16850 22502 50663 Acq.Date 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 Acq.Time 20:15:53 20:32:54 20:49:47 21:06:48 21:23:49 21:40:42 21:57:35 22:14:36 Detection... MM MM MM MM MM MM MM MM PV by JLIU, SV by KJC 4-Jan-13. Calver conc in ng. Page 223 of 307 www.axysanalytical.com Quantify Compound Summary Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\Inst_G\PFC.PRO\FC\FC3G_015-A1.qld Last Altered: Tuesday, January 15, 2013 10:48:13 Pacific Standard Time Printed: Tuesday, January 15, 2013 11:33:51 Pacific Standard Time Compound name: PFHxA # ID Name Type RT 1 FC -LIN-42420W 500-A ,, FC3G _015S004 Standard 6.36 2 FC -LIN-42420W 500-B ,, FC3G _015S005 Standard 6.34 3 FC-LI N -42420W 500-C ,, FC3G _015S006 Standard 6.36 4 FC-LI N -42420W 500-D ,, FC3G _015S007 Standard 6.34 5 FC-LIN-42420W 500-E,, FC3G _015S008 Standard 6.36 6 FC-LIN-42420W 500-F,, FC3G _015S009 Standard 6.36 7 FC-LI N -4 2 4 2 0 W 5 0 0 -G ,, FC 3G _ 0 15 S 0 1 0 Standard 6.33 8 FC-LIN-42420W 500-H,, FC 3G _015S011 Standard 6.34 Area 4834 11980 36978 140318 632521 1071639 2165990 4181689 IS Area 72936 77481 77682 73854 68145 58258 47890 40957 Std. Conc 0.500 1.250 5.000 20.000 100.000 200.000 500.000 1250.000 Compound name: PFHxA Coefficient of Determination: RA2 = 0.999940 Calibration curve: -0.000124546 * xA2 + 1.13695 * x + 0.261958 Response type: Internal Std ( Ref 26 ), Area * ( IS Conc. / IS Area ) Curve type: 2nd Order, Origin: Exclude, Weighting: 1/x, Axis trans: None ng/L 0.469 1.402 4.796 19.866 98.807 198.222 505.086 1248.015 %Rec 93.8 112.1 95.9 99.3 98.8 99.1 101.0 99.8 S/N 142 213 688 6800 15254 26475 49340 50289 Acq.Date 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 Acq.Time 20:15:53 20:32:54 20:49:47 21:06:48 21:23:49 21:40:42 21:57:35 22:14:36 Detection... MM MM MM MM MM MM MM MM PV by JLIU, SV by KJC 4-Jan-13. Calver conc in ng. Page 224 of 307 www.axysanalytical.com Quantify Compound Summary Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\Inst_G\PFC.PRO\FC\FC3G_015-A1.qld Last Altered: Tuesday, January 15, 2013 10:48:13 Pacific Standard Time Printed: Tuesday, January 15, 2013 11:33:51 Pacific Standard Time Compound name: PFHpA # ID Name Type RT 1 FC -LIN-42420W 500-A ,, FC3G _015S004 Standard 6.73 2 FC -LIN-42420W 500-B ,, FC3G _015S005 Standard 6.73 3 FC-LI N -42420W 500-C ,, FC3G _015S006 Standard 6.73 4 FC-LI N -42420W 500-D ,, FC3G _015S007 Standard 6.73 5 FC-LIN-42420W 500-E,, FC3G _015S008 Standard 6.73 6 FC-LIN-42420W 500-F,, FC3G _015S009 Standard 6.73 7 FC-LI N -4 2 4 2 0 W 5 0 0 -G ,, FC 3G _ 0 15 S 0 1 0 Standard 6.73 8 FC-LIN-42420W 500-H,, FC 3G _015S011 Standard 6.73 Area 3752 10472 39072 144182 638236 1139370 2262452 4711523 IS Area 72936 77481 77682 73854 68145 58258 47890 40957 Std. Conc 0.500 1.250 5.000 20.000 100.000 200.000 500.000 1250.000 Compound name: PFHpA Coefficient of Determination: RA2 = 0.999912 Calibration curve: -4.45074e-005 * xA2 + 1.15968 * x + 0.0851693 Response type: Internal Std ( Ref 26 ), Area * ( IS Conc. / IS Area ) Curve type: 2nd Order, Origin: Exclude, Weighting: 1/x, Axis trans: None ng/L 0.459 1.325 5.132 20.144 97.204 203.894 498.311 1250.282 %Rec 91.8 106.0 102.6 100.7 97.2 101.9 99.7 100.0 S/N 105 189 1062 3803 12076 27466 53152 91806 Acq.Date 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 Acq.Time 20:15:53 20:32:54 20:49:47 21:06:48 21:23:49 21:40:42 21:57:35 22:14:36 Detection... MM MM MM MM MM MM MM MM PV by JLIU, SV by KJC 4-Jan-13. Calver conc in ng. Page 225 of 307 www.axysanalytical.com Quantify Compound Summary Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\Inst_G\PFC.PRO\FC\FC3G_015-A1.qld Last Altered: Tuesday, January 15, 2013 10:48:13 Pacific Standard Time Printed: Tuesday, January 15, 2013 11:33:51 Pacific Standard Time Compound name: PFOA-1 # ID Name Type RT 1 FC -LIN-42420W 500-A ,, FC3G _015S004 Standard 7.14 2 FC -LIN-42420W 500-B ,, FC3G _015S005 Standard 7.09 3 FC-LI N -42420W 500-C ,, FC3G _015S006 Standard 7.14 4 FC-LI N -42420W 500-D ,, FC3G _015S007 Standard 7.14 5 FC-LIN-42420W 500-E,, FC3G _015S008 Standard 7.14 6 FC-LIN-42420W 500-F,, FC3G _015S009 Standard 7.14 7 FC-LI N -4 2 4 2 0 W 5 0 0 -G ,, FC 3G _ 0 15 S 0 1 0 Standard 7.09 8 FC-LIN-42420W 500-H,, FC 3G _015S011 Standard 7.09 Area 4717 12440 40626 149341 692014 1197420 2464122 4933775 IS Area 251816 264525 265618 265755 240757 211297 180448 143912 Std. Conc 0.500 1.250 5.000 20.000 100.000 200.000 500.000 1250.000 Compound name: PFOA-1 Coefficient of Determination: RA2 = 0.999854 Calibration curve: -1.8414e-005 * xA2 + 1.0081 * x + 0.265557 Response type: Internal Std ( Ref 19 ), Area * ( IS Conc. / IS Area ) Curve type: 2nd Order, Origin: Exclude, Weighting: 1/x, Axis trans: None ng/L 0.406 1.416 5.199 19.811 102.573 202.861 491.806 1252.684 %Rec 81.1 113.3 104.0 99.1 102.6 101.4 98.4 100.2 S/N 39 74 0 0 0 0 0 0 Acq.Date 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 Acq.Time 20:15:53 20:32:54 20:49:47 21:06:48 21:23:49 21:40:42 21:57:35 22:14:36 Detection... MM MM MM MM MM MM MM MM PV by JLIU, SV by KJC 4-Jan-13. Calver conc in ng. Page 226 of 307 www.axysanalytical.com Quantify Compound Summary Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\Inst_G\PFC.PRO\FC\FC3G_015-A1.qld Last Altered: Tuesday, January 15, 2013 10:48:13 Pacific Standard Time Printed: Tuesday, January 15, 2013 11:33:51 Pacific Standard Time Compound name: PFOA-2 # ID Name Type RT 1 FC -LIN-42420W 500-A ,, FC3G _015S004 Standard 7.14 2 FC -LIN-42420W 500-B ,, FC3G _015S005 Standard 7.09 3 FC-LI N -42420W 500-C ,, FC3G _015S006 Standard 7.09 4 FC-LI N -42420W 500-D ,, FC3G _015S007 Standard 7.14 5 FC-LIN-42420W 500-E,, FC3G _015S008 Standard 7.14 6 FC-LIN-42420W 500-F,, FC3G _015S009 Standard 7.14 7 FC-LI N -4 2 4 2 0 W 5 0 0 -G ,, FC 3G _ 0 15 S 0 1 0 Standard 7.09 8 FC-LIN-42420W 500-H,, FC 3G _015S011 Standard 7.09 Area 1255 2315 9021 34651 171424 286450 592967 1165768 IS Area 251816 264525 265618 265755 240757 211297 180448 143912 Std. Conc 0.500 1.250 5.000 20.000 100.000 200.000 500.000 1250.000 Compound name: PFOA-2 Coefficient of Determination: RA2 = 0.999777 Calibration curve: -9.45627e-006 * xA2 + 0.244644 * x + 0.0399976 Response type: Internal Std ( Ref 19 ), Area * ( IS Conc. / IS Area ) Curve type: 2nd Order, Origin: Exclude, Weighting: 1/x, Axis trans: None ng/L 0.570 1.124 4.835 19.037 105.039 200.887 492.779 1252.495 %Rec 113.9 90.0 96.7 95.2 105.0 100.4 98.6 100.2 S/N 77 83 169 1499 0 0 0 0 Acq.Date 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 Acq.Time 20:15:53 20:32:54 20:49:47 21:06:48 21:23:49 21:40:42 21:57:35 22:14:36 Detection... MM MM MM MM MM MM MM MM PV by JLIU, SV by KJC 4-Jan-13. Calver conc in ng. Page 227 of 307 www.axysanalytical.com Quantify Compound Summary Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\Inst_G\PFC.PRO\FC\FC3G_015-A1.qld Last Altered: Tuesday, January 15, 2013 10:48:13 Pacific Standard Time Printed: Tuesday, January 15, 2013 11:33:51 Pacific Standard Time Compound name: PFNA # ID Name Type RT 1 FC -LIN-42420W 500-A ,, FC3G _015S004 Standard 7.55 2 FC -LIN-42420W 500-B ,, FC3G _015S005 Standard 7.55 3 FC-LI N -42420W 500-C ,, FC3G _015S006 Standard 7.55 4 FC-LI N -42420W 500-D ,, FC3G _015S007 Standard 7.55 5 FC-LIN-42420W 500-E,, FC3G _015S008 Standard 7.55 6 FC-LIN-42420W 500-F,, FC3G _015S009 Standard 7.55 7 FC-LI N -4 2 4 2 0 W 5 0 0 -G ,, FC 3G _ 0 15 S 0 1 0 Standard 7.49 8 FC-LIN-42420W 500-H,, FC 3G _015S011 Standard 7.49 Area 3856 10365 36435 144493 643515 1146232 2391985 5089518 IS Area 76162 83747 83846 83869 79478 71910 55823 45876 Std. Conc 0.500 1.250 5.000 20.000 100.000 200.000 500.000 1250.000 Compound name: PFNA Coefficient of Determination: RA2 = 0.999798 Calibration curve: 7.51007e-005 * xA2 + 0.972924 * x + 0.183187 Response type: Internal Std ( Ref 27 ), Area * ( IS Conc. / IS Area ) Curve type: 2nd Order, Origin: Exclude, Weighting: 1/x, Axis trans: None ng/L 0.436 1.338 5.169 21.027 98.921 193.521 508.363 1247.932 %Rec 87.2 107.0 103.4 105.1 98.9 96.8 101.7 99.8 S/N 43 144 578 13918 0 22371 36654 0 Acq.Date 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 Acq.Time 20:15:53 20:32:54 20:49:47 21:06:48 21:23:49 21:40:42 21:57:35 22:14:36 Detection... MM MM MM MM MM MM MM MM PV by JLIU, SV by KJC 4-Jan-13. Calver conc in ng. Page 228 of 307 www.axysanalytical.com Quantify Compound Summary Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\Inst_G\PFC.PRO\FC\FC3G_015-A1.qld Last Altered: Tuesday, January 15, 2013 10:48:13 Pacific Standard Time Printed: Tuesday, January 15, 2013 11:33:51 Pacific Standard Time Compound name: PFDA # ID Name Type RT 1 FC -LIN-42420W 500-A ,, FC3G _015S004 Standard 8.05 2 FC -LIN-42420W 500-B ,, FC3G _015S005 Standard 8.05 3 FC-LI N -42420W 500-C ,, FC3G _015S006 Standard 8.05 4 FC-LI N -42420W 500-D ,, FC3G _015S007 Standard 8.05 5 FC-LIN-42420W 500-E,, FC3G _015S008 Standard 8.05 6 FC-LIN-42420W 500-F,, FC3G _015S009 Standard 8.05 7 FC-LI N -4 2 4 2 0 W 5 0 0 -G ,, FC 3G _ 0 15 S 0 1 0 Standard 8.05 8 FC-LIN-42420W 500-H,, FC 3G _015S011 Standard 8.05 Area 5923 14790 48705 185619 879693 1420377 3073619 6104199 IS Area 75970 97950 95963 98960 93731 81150 83939 84417 Std. Conc 0.500 1.250 5.000 20.000 100.000 200.000 500.000 1250.000 ng/L 0.433 1.246 5.225 20.576 107.421 206.864 471.682 1274.461 Compound name: PFDA Coefficient of Determination: RA2 = 0.998644 Calibration curve: -0.000311529 * xA2 + 1.07752 * x + 0.469487 Response type: Internal Std ( Ref 28 ), Area * ( IS Conc. / IS Area ) Curve type: 2nd Order, Origin: Exclude, Weighting: 1/x, Axis trans: None %Rec 86.5 99.7 104.5 102.9 107.4 103.4 94.3 102.0 S/N 89 377 356 1253 4480 4875 8972 3540 Acq.Date 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 Acq.Time 20:15:53 20:32:54 20:49:47 21:06:48 21:23:49 21:40:42 21:57:35 22:14:36 Detection... MM MM MM MM MM MM MM MM PV by JLIU, SV by KJC 4-Jan-13. Calver conc in ng. Page 229 of 307 www.axysanalytical.com Quantify Compound Summary Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\Inst_G\PFC.PRO\FC\FC3G_015-A1.qld Last Altered: Tuesday, January 15, 2013 10:48:13 Pacific Standard Time Printed: Tuesday, January 15, 2013 11:33:51 Pacific Standard Time Compound name: PFUnA # ID Name Type RT 1 F C -L IN -4 2 42 0 W 5 0 0-A ,, F C 3G _0 1 5 S 00 4 Standard 8.61 2 F C -L IN -4 2 42 0 W 5 0 0-B ,, F C 3G _0 1 5 S 00 5 Standard 8.61 3 FC-LI N -4 2 4 2 0 W 5 0 0 -C ,, F C 3G _0 1 5 S 00 6 Standard 8.61 4 FC-LI N -4 2 4 2 0 W 5 0 0 -D ,, F C 3G _0 1 5 S 00 7 Standard 8.61 5 FC-LIN-42420W 500-E,, F C 3G _0 1 5 S 00 8 Standard 8.61 6 FC-LIN-42420W 500-F,, FC3G _015S009 Standard 8.64 7 FC-LI N -4 2 4 2 0 W 5 0 0 -G ,, FC 3G _ 0 15 S 0 1 0 Standard 8.61 8 FC-LIN-42420W 500-H,, FC 3G _015S011 Standard 8.58 Area 5269 14561 51692 199149 946327 1622024 3473490 7620483 IS Area 75970 97950 95963 98960 93731 81150 83939 84417 Std. Conc 0.500 1.250 5.000 20.000 100.000 200.000 500.000 1250.000 Compound name: PFUnA Coefficient of Determination: RA2 = 0.998354 Calibration curve: -0.000255394 * xA2 + 1.17845 * x + 0.314693 Response type: Internal Std ( Ref 28 ), Area * ( IS Conc. / IS Area ) Curve type: 2nd Order, Origin: Exclude, Weighting: 1/x, Axis trans: None ng/L 0.439 1.247 5.224 20.315 104.927 213.112 468.725 1266.699 %Rec 87.9 99.8 104.5 101.6 104.9 106.6 93.7 101.3 S/N 74 240 724 1495 4936 8175 9193 7802 Acq.Date 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 Acq.Time 20:15:53 20:32:54 20:49:47 21:06:48 21:23:49 21:40:42 21:57:35 22:14:36 Detection... MM MM MM MM MM MM MM MM PV by JLIU, SV by KJC 4-Jan-13. Calver conc in ng. Page 230 of 307 www.axysanalytical.com Quantify Compound Summary Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\Inst_G\PFC.PRO\FC\FC3G_015-A1.qld Last Altered: Tuesday, January 15, 2013 10:48:13 Pacific Standard Time Printed: Tuesday, January 15, 2013 11:33:51 Pacific Standard Time Compound name: PFDoA # ID Name Type RT 1 FC -LIN-42420W 500-A ,, FC3G _015S004 Standard 9.24 2 FC -LIN-42420W 500-B ,, FC3G _015S005 Standard 9.24 3 FC-LI N -42420W 500-C ,, FC3G _015S006 Standard 9.24 4 FC-LI N -4 2 4 2 0 W 5 0 0 -D ,, F C 3G _0 1 5 S 00 7 Standard 9.21 5 FC-LIN-42420W 500-E,, F C 3G _0 1 5 S 00 8 Standard 9.21 6 FC-LIN-42420W 500-F,, FC3G _015S009 Standard 9.24 7 FC-LI N -4 2 4 2 0 W 5 0 0 -G ,, FC 3G _ 0 15 S 0 1 0 Standard 9.21 8 FC-LIN-42420W 500-H,, FC 3G _015S011 Standard 9.18 Area 6475 15981 64757 244382 1081028 2106076 4341857 9446096 IS Area 136364 132608 158117 159917 146991 148678 149909 173162 Std. Conc 0.500 1.250 5.000 20.000 100.000 200.000 500.000 1250.000 Compound name: PFDoA Coefficient of Determination: RA2 = 0.998632 Calibration curve: -0.000280667 * xA2 + 0.86988 * x + 0.251461 Response type: Internal Std ( Ref 29 ), Area * ( IS Conc. / IS Area ) Curve type: 2nd Order, Origin: Exclude, Weighting: 1/x, Axis trans: None ng/L 0.366 1.374 5.370 20.934 104.702 209.250 470.764 1285.038 %Rec 73.2 109.9 107.4 104.7 104.7 104.6 94.2 102.8 S/N 111 224 717 2177 3889 11005 9659 11577 Acq.Date 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 Acq.Time 20:15:53 20:32:54 20:49:47 21:06:48 21:23:49 21:40:42 21:57:35 22:14:36 Detection... MM MM MM MM MM MM MM MM PV by JLIU, SV by KJC 4-Jan-13. Calver conc in ng. Page 231 of 307 www.axysanalytical.com Quantify Compound Summary Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\Inst_G\PFC.PRO\FC\FC3G_015-A1.qld Last Altered: Tuesday, January 15, 2013 10:48:13 Pacific Standard Time Printed: Tuesday, January 15, 2013 11:33:51 Pacific Standard Time Compound name: PFBS-1 # ID Name Type RT 1 F C -L IN -4 2 42 0 W 5 0 0-A ,, F C 3G _0 1 5 S 00 4 Standard 6.51 2 FC -LIN-42420W 500-B ,, FC3G _015S005 Standard 6.47 3 FC-LI N -42420W 500-C ,, FC3G _015S006 Standard 6.49 4 FC-LI N -42420W 500-D ,, FC3G _015S007 Standard 6.49 5 FC-LIN-42420W 500-E,, FC3G _015S008 Standard 6.49 6 FC-LIN-42420W 500-F,, FC3G _015S009 Standard 6.49 7 FC-LI N -4 2 4 2 0 W 5 0 0 -G ,, FC 3G _ 0 15 S 0 1 0 Standard 6.47 8 FC-LIN-42420W 500-H,, FC 3G _015S011 Standard 6.49 Area 1250 2925 10293 41241 176606 287793 574749 1021844 IS Area 11409 11723 12752 11961 10750 9307 7532 5162 Std. Conc 1.000 2.500 10.000 40.000 200.000 400.000 1000.000 2500.000 Compound name: PFBS-1 Coefficient of Determination: RA2 = 0.999617 Calibration curve: 1.18725e-005 * xA2 + 1.39094 * x + 0.824691 Response type: Internal Std ( Ref 23 ), Area * ( IS Conc. / IS Area ) Curve type: 2nd Order, Origin: Exclude, Weighting: 1/x, Axis trans: None ng/L 0.825 2.636 9.852 44.008 211.633 398.208 978.718 2507.622 %Rec 82.5 105.4 98.5 110.0 105.8 99.6 97.9 100.3 S/N 141 544 2250 2292 36944 15577 76153 48512 Acq.Date 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 Acq.Time 20:15:53 20:32:54 20:49:47 21:06:48 21:23:49 21:40:42 21:57:35 22:14:36 Detection... MM MM MM MM MM MM MM MM PV by JLIU, SV by KJC 4-Jan-13. Calver conc in ng. Page 232 of 307 www.axysanalytical.com Quantify Compound Summary Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\Inst_G\PFC.PRO\FC\FC3G_015-A1.qld Last Altered: Tuesday, January 15, 2013 10:48:13 Pacific Standard Time Printed: Tuesday, January 15, 2013 11:33:51 Pacific Standard Time Compound name: PFBS-2 # ID Name Type RT 1 F C -L IN -4 2 42 0 W 5 0 0-A ,, F C 3G _0 1 5 S 00 4 Standard 6.51 2 FC -LIN-42420W 500-B ,, FC3G _015S005 Standard 6.49 3 FC-LI N -42420W 500-C ,, FC3G _015S006 Standard 6.49 4 FC-LI N -42420W 500-D ,, FC3G _015S007 Standard 6.47 5 FC-LIN-42420W 500-E,, FC3G _015S008 Standard 6.47 6 FC-LIN-42420W 500-F,, F C 3G _0 1 5 S 00 9 Standard 6.51 7 FC-LI N -4 2 4 2 0 W 5 0 0 -G ,, FC 3G _ 0 15 S 0 1 0 Standard 6.47 8 FC-LIN-42420W 500-H,, FC 3G _015S011 Standard 6.47 Area 706 1423 5529 20643 93835 150714 292314 526024 IS Area 8167 9543 9276 8817 8538 6193 5239 4007 Std. Conc 1.000 2.500 10.000 40.000 200.000 400.000 1000.000 2500.000 Compound name: PFBS-2 Coefficient of Determination: RA2 = 0.999469 Calibration curve: -4.58769e-005 * xA2 + 1.05926 * x + 0.33002 Response type: Internal Std ( Ref 24 ), Area * ( IS Conc. / IS Area ) Curve type: 2nd Order, Origin: Exclude, Weighting: 1/x, Axis trans: None ng/L 1.157 2.223 9.821 39.540 187.968 420.913 990.315 2501.618 %Rec 115.7 88.9 98.2 98.8 94.0 105.2 99.0 100.1 S/N 67 198 717 4112 8405 18009 31388 51919 Acq.Date 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 Acq.Time 20:15:53 20:32:54 20:49:47 21:06:48 21:23:49 21:40:42 21:57:35 22:14:36 Detection... MM MM MM MM MM MM MM MM PV by JLIU, SV by KJC 4-Jan-13. Calver conc in ng. Page 233 of 307 www.axysanalytical.com Quantify Compound Summary Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\Inst_G\PFC.PRO\FC\FC3G_015-A1.qld Last Altered: Tuesday, January 15, 2013 10:48:13 Pacific Standard Time Printed: Tuesday, January 15, 2013 11:33:51 Pacific Standard Time Compound name: PFHxS-1 # ID Name Type RT 1 FC -LIN-42420W 500-A ,, FC3G _015S004 Standard 7.33 2 FC -LIN-42420W 500-B ,, FC3G _015S005 Standard 7.33 3 FC-LI N -42420W 500-C ,, FC3G _015S006 Standard 7.33 4 FC-LI N -42420W 500-D ,, FC3G _015S007 Standard 7.33 5 FC-LIN-42420W 500-E,, FC3G _015S008 Standard 7.33 6 FC-LIN-42420W 500-F,, FC3G _015S009 Standard 7.33 7 FC-LI N -4 2 4 2 0 W 5 0 0 -G ,, FC 3G _ 0 15 S 0 1 0 Standard 7.33 8 FC-LIN-42420W 500-H,, FC 3G _015S011 Standard 7.33 Area 1177 2758 8511 35764 152325 267940 516587 912450 IS Area 11409 11723 12752 11961 10750 9307 7532 5162 Std. Conc 1.000 2.500 10.000 40.000 200.000 400.000 1000.000 2500.000 Compound name: PFHxS-1 Coefficient of Determination: RA2 = 0.999732 Calibration curve: 5.25128e-006 * xA2 + 1.256 * x + 0.720654 Response type: Internal Std ( Ref 23 ), Area * ( IS Conc. / IS Area ) Curve type: 2nd Order, Origin: Exclude, Weighting: 1/x, Axis trans: None ng/L 0.904 2.798 8.991 42.269 202.336 411.296 978.341 2506.565 %Rec 90.4 111.9 89.9 105.7 101.2 102.8 97.8 100.3 S/N 0 0 139 281 0 10903 0 0 Acq.Date 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 Acq.Time 20:15:53 20:32:54 20:49:47 21:06:48 21:23:49 21:40:42 21:57:35 22:14:36 Detection... bb MM MM MM MM MM MM MM PV by JLIU, SV by KJC 4-Jan-13. Calver conc in ng. Page 234 of 307 www.axysanalytical.com Quantify Compound Summary Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\Inst_G\PFC.PRO\FC\FC3G_015-A1.qld Last Altered: Tuesday, January 15, 2013 10:48:13 Pacific Standard Time Printed: Tuesday, January 15, 2013 11:33:51 Pacific Standard Time Compound name: PFHxS-2 # ID Name Type RT 1 FC -LIN-42420W 500-A ,, FC3G _015S004 Standard 7.33 2 FC -LIN-42420W 500-B ,, FC3G _015S005 Standard 7.33 3 FC-LI N -42420W 500-C ,, FC3G _015S006 Standard 7.33 4 FC-LI N -42420W 500-D ,, FC3G _015S007 Standard 7.33 5 FC-LIN-42420W 500-E,, FC3G _015S008 Standard 7.33 6 FC-LIN-42420W 500-F,, FC3G _015S009 Standard 7.33 7 FC-LI N -4 2 4 2 0 W 5 0 0 -G ,, FC 3G _ 0 15 S 0 1 0 Standard 7.33 8 FC-LIN-42420W 500-H,, FC 3G _015S011 Standard 7.33 Area 630 1261 4912 17711 86045 141803 284063 503432 IS Area 8167 9543 9276 8817 8538 6193 5239 4007 Std. Conc 1.000 2.500 10.000 40.000 200.000 400.000 1000.000 2500.000 Compound name: PFHxS-2 Coefficient of Determination: RA2 = 0.999170 Calibration curve: -3.85889e-005 * xA2 + 1.00334 * x + 0.0966945 Response type: Internal Std ( Ref 24 ), Area * ( IS Conc. / IS Area ) Curve type: 2nd Order, Origin: Exclude, Weighting: 1/x, Axis trans: None ng/L 1.288 2.274 9.407 35.989 181.967 417.389 1012.035 2493.009 %Rec 128.8 90.9 94.1 90.0 91.0 104.3 101.2 99.7 S/N 89 0 0 3728 0 4240 7540 0 Acq.Date 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 Acq.Time 20:15:53 20:32:54 20:49:47 21:06:48 21:23:49 21:40:42 21:57:35 22:14:36 Detection... MM MM MM MM MM MM MM MM PV by JLIU, SV by KJC 4-Jan-13. Calver conc in ng. Page 235 of 307 www.axysanalytical.com Quantify Compound Summary Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\Inst_G\PFC.PRO\FC\FC3G_015-A1.qld Last Altered: Tuesday, January 15, 2013 10:48:13 Pacific Standard Time Printed: Tuesday, January 15, 2013 11:33:51 Pacific Standard Time Compound name: PFHxS-3 # ID Name Type RT 1 FC -LIN-42420W 500-A ,, FC3G _015S004 Standard 7.33 2 FC -LIN-42420W 500-B ,, FC3G _015S005 Standard 7.33 3 FC-LI N -42420W 500-C ,, FC3G _015S006 Standard 7.33 4 FC-LI N -42420W 500-D ,, FC3G _015S007 Standard 7.33 5 FC-LIN-42420W 500-E,, FC3G _015S008 Standard 7.33 6 FC-LIN-42420W 500-F,, FC3G _015S009 Standard 7.33 7 FC-LI N -4 2 4 2 0 W 5 0 0 -G ,, FC 3G _ 0 15 S 0 1 0 Standard 7.33 8 FC-LIN-42420W 500-H,, FC 3G _015S011 Standard 7.33 Area 282 625 3012 10989 51386 82734 155131 296727 IS Area 11409 11723 12752 11961 10750 9307 7532 5162 Std. Conc 1.000 2.500 10.000 40.000 200.000 400.000 1000.000 2500.000 Compound name: PFHxS-3 Coefficient of Determination: RA2 = 0.998390 Calibration curve: 1.13903e-005 * xA2 + 0.382314 * x + 0.115235 Response type: Internal Std ( Ref 23 ), Area * ( IS Conc. / IS Area ) Curve type: 2nd Order, Origin: Exclude, Weighting: 1/x, Axis trans: None ng/L 0.863 2.208 10.815 42.899 223.279 413.136 942.917 2517.457 %Rec 86.3 88.3 108.2 107.2 111.6 103.3 94.3 100.7 S/N 25 51 102 0 0 4172 0 0 Acq.Date 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 Acq.Time 20:15:53 20:32:54 20:49:47 21:06:48 21:23:49 21:40:42 21:57:35 22:14:36 Detection... MM MM MM MM MM MM MM MM PV by JLIU, SV by KJC 4-Jan-13. Calver conc in ng. Page 236 of 307 www.axysanalytical.com Quantify Compound Summary Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\Inst_G\PFC.PRO\FC\FC3G_015-A1.qld Last Altered: Tuesday, January 15, 2013 10:48:13 Pacific Standard Time Printed: Tuesday, January 15, 2013 11:33:51 Pacific Standard Time Compound name: PFOS-1 # ID Name Type RT 1 F C -L IN -4 2 42 0 W 5 0 0-A ,, F C 3G _0 1 5 S 00 4 Standard 8.41 2 F C -L IN -4 2 42 0 W 5 0 0-B ,, F C 3G _0 1 5 S 00 5 Standard 8.41 3 FC-LI N -4 2 4 2 0 W 5 0 0 -C ,, F C 3G _0 1 5 S 00 6 Standard 8.41 4 FC-LI N -4 2 4 2 0 W 5 0 0 -D ,, F C 3G _0 1 5 S 00 7 Standard 8.41 5 FC-LIN-42420W 500-E,, FC3G _015S008 Standard 8.35 6 FC-LIN-42420W 500-F,, F C 3G _0 1 5 S 00 9 Standard 8.41 7 FC-LI N -4 2 4 2 0 W 5 0 0 -G ,, FC 3G _ 0 15 S 0 1 0 Standard 8.35 8 FC-LIN-42420W 500-H,, FC 3G _015S011 Standard 8.35 Area 1211 2764 9055 33164 162731 271377 560878 1099194 IS Area 13097 14831 14361 14492 14226 11098 8899 6445 Std. Conc 1.000 2.500 10.000 40.000 200.000 400.000 1000.000 2500.000 Compound name: PFOS-1 Coefficient of Determination: RA2 = 0.999890 Calibration curve: 6.88659e-005 * xA2 + 1.057 * x + 0.600346 Response type: Internal Std ( Ref 21 ), Area * ( IS Conc. / IS Area ) Curve type: 2nd Order, Origin: Exclude, Weighting: 1/x, Axis trans: None ng/L 1.006 2.605 10.163 38.306 191.828 405.150 1006.719 2497.579 %Rec 100.6 104.2 101.6 95.8 95.9 101.3 100.7 99.9 S/N 34 44 126 522 1675 1808 3373 3626 Acq.Date 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 Acq.Time 20:15:53 20:32:54 20:49:47 21:06:48 21:23:49 21:40:42 21:57:35 22:14:36 Detection... MM MM MM MM MM MM MM MM PV by JLIU, SV by KJC 4-Jan-13. Calver conc in ng. Page 237 of 307 www.axysanalytical.com Quantify Compound Summary Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\Inst_G\PFC.PRO\FC\FC3G_015-A1.qld Last Altered: Tuesday, January 15, 2013 10:48:13 Pacific Standard Time Printed: Tuesday, January 15, 2013 11:33:51 Pacific Standard Time Compound name: PFOS-2 # ID Name Type RT 1 F C -L IN -4 2 42 0 W 5 0 0-A ,, F C 3G _0 1 5 S 00 4 Standard 8.41 2 F C -L IN -4 2 42 0 W 5 0 0-B ,, F C 3G _0 1 5 S 00 5 Standard 8.41 3 FC-LI N -4 2 4 2 0 W 5 0 0 -C ,, F C 3G _0 1 5 S 00 6 Standard 8.41 4 FC-LI N -42420W 500-D ,, FC3G _015S007 Standard 8.35 5 FC-LIN-42420W 500-E,, FC3G _015S008 Standard 8.35 6 FC-LIN-42420W 500-F,, F C 3G _0 1 5 S 00 9 Standard 8.41 7 FC-LI N -4 2 4 2 0 W 5 0 0 -G ,, FC 3G _ 0 15 S 0 1 0 Standard 8.35 8 FC-LIN-42420W 500-H,, FC 3G _015S011 Standard 8.35 Area 650 1840 6360 22836 118969 190358 387780 759759 IS Area 10291 11508 11454 11374 11600 8840 6993 5284 Std. Conc 1.000 2.500 10.000 40.000 200.000 400.000 1000.000 2500.000 Compound name: PFOS-2 Coefficient of Determination: RA2 = 0.999861 Calibration curve: 3.41978e-005 * xA2 + 0.951493 * x + 0.236478 Response type: Internal Std ( Ref 22 ), Area * ( IS Conc. / IS Area ) Curve type: 2nd Order, Origin: Exclude, Weighting: 1/x, Axis trans: None ng/L 0.946 2.777 10.251 37.683 192.444 401.314 1012.010 2496.000 %Rec 94.6 111.1 102.5 94.2 96.2 100.3 101.2 99.8 S/N 37 78 131 314 1585 1716 2172 4089 Acq.Date 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 Acq.Time 20:15:53 20:32:54 20:49:47 21:06:48 21:23:49 21:40:42 21:57:35 22:14:36 Detection... MM MM MM MM MM MM MM MM PV by JLIU, SV by KJC 4-Jan-13. Calver conc in ng. Page 238 of 307 www.axysanalytical.com Quantify Compound Summary Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\Inst_G\PFC.PRO\FC\FC3G_015-A1.qld Last Altered: Tuesday, January 15, 2013 10:48:13 Pacific Standard Time Printed: Tuesday, January 15, 2013 11:33:51 Pacific Standard Time Compound name: PFOSA # ID Name Type RT 1 FC -LIN-42420W 500-A ,, FC3G _015S004 Standard 9.99 2 FC -LIN-42420W 500-B ,, FC3G _015S005 Standard 9.99 3 FC-LI N -42420W 500-C ,, FC3G _015S006 Standard 9.99 4 FC-LI N -42420W 500-D ,, FC3G _015S007 Standard 9.99 5 FC-LIN-42420W 500-E,, FC3G _015S008 Standard 9.99 6 FC-LIN-42420W 500-F,, FC3G _015S009 Standard 9.99 7 FC-LI N -4 2 4 2 0 W 5 0 0 -G ,, FC 3G _ 0 15 S 0 1 0 Standard 9.99 8 FC-LIN-42420W 500-H,, FC 3G _015S011 Standard 9.99 Area 538 1521 7114 28634 115291 222311 531646 1222304 IS Area 13097 14831 14361 14492 14226 11098 8899 6445 Std. Conc 0.500 1.250 5.000 20.000 100.000 200.000 500.000 1250.000 Compound name: PFOSA Coefficient of Determination: RA2 = 0.999179 Calibration curve: 0.000885926 * xA2 + 1.63384 * x + -0.0818517 Response type: Internal Std ( Ref 21 ), Area * ( IS Conc. / IS Area ) Curve type: 2nd Order, Origin: Exclude, Weighting: 1/x, Axis trans: None ng/L 0.502 1.179 5.491 21.565 85.380 199.217 514.627 1246.747 %Rec 100.5 94.3 109.8 107.8 85.4 99.6 102.9 99.7 S/N 24 233 362 1027 2887 3310 6334 10787 Acq.Date 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 Acq.Time 20:15:53 20:32:54 20:49:47 21:06:48 21:23:49 21:40:42 21:57:35 22:14:36 Detection... MM MM MM MM MM MM MM MM PV by JLIU, SV by KJC 4-Jan-13. Calver conc in ng. Page 239 of 307 www.axysanalytical.com Quantify Compound Summary Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\Inst_G\PFC.PRO\FC\FC3G_015-A1.qld Last Altered: Tuesday, January 15, 2013 10:48:13 Pacific Standard Time Printed: Tuesday, January 15, 2013 11:33:51 Pacific Standard Time Compound name: 13C2-PFOA # ID Name Type RT 1 FC -LIN-42420W 500-A ,, FC3G _015S004 Standard 7.09 2 FC -LIN-42420W 500-B ,, FC3G _015S005 Standard 7.09 3 FC-LI N -42420W 500-C ,, FC3G _015S006 Standard 7.14 4 FC-LI N -42420W 500-D ,, FC3G _015S007 Standard 7.14 5 FC-LIN-42420W 500-E,, FC3G _015S008 Standard 7.14 6 FC-LIN-42420W 500-F,, FC3G _015S009 Standard 7.14 7 FC-LI N -4 2 4 2 0 W 5 0 0 -G ,, FC 3G _ 0 15 S 0 1 0 Standard 7.09 8 FC-LIN-42420W 500-H,, FC 3G _015S011 Standard 7.09 Area 251816 264525 265618 265755 240757 211297 180448 143912 Compound name: 13C2-PFOA Response Factor: 0.948092 RRF SD: 0.0386688, % Relative SD: 4.07859 Response type: Internal Std ( Ref 20 ), Area * ( IS Conc. / IS Area ) Curve type: Rf IS Area 92297 97615 93648 93639 85495 75636 60059 47536 Std. Conc 36.000 36.000 36.000 36.000 36.000 36.000 36.000 36.000 ng/L 34.532 34.299 35.900 35.922 35.643 35.359 38.028 38.318 %Rec 95.9 95.3 99.7 99.8 99.0 98.2 105.6 106.4 S/N 0 0 0 0 0 0 0 0 Acq.Date 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 Acq.Time 20:15:53 20:32:54 20:49:47 21:06:48 21:23:49 21:40:42 21:57:35 22:14:36 Detection... MM MM MM MM MM MM MM MM PV by JLIU, SV by KJC 4-Jan-13. Calver conc in ng. Page 240 of 307 www.axysanalytical.com Quantify Compound Summary Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\Inst_G\PFC.PRO\FC\FC3G_015-A1.qld Last Altered: Tuesday, January 15, 2013 10:48:13 Pacific Standard Time Printed: Tuesday, January 15, 2013 11:33:51 Pacific Standard Time Compound name: 13C4-PFOA # ID Name Type RT 1 FC -LIN-42420W 500-A ,, FC3G _015S004 Standard 7.14 2 FC -LIN-42420W 500-B ,, FC3G _015S005 Standard 7.09 3 FC-LI N -42420W 500-C ,, FC3G _015S006 Standard 7.09 4 FC-LI N -42420W 500-D ,, FC3G _015S007 Standard 7.09 5 FC-LIN-42420W 500-E,, FC3G _015S008 Standard 7.09 6 FC-LIN-42420W 500-F,, FC3G _015S009 Standard 7.14 7 FC-LI N -4 2 4 2 0 W 5 0 0 -G ,, FC 3G _ 0 15 S 0 1 0 Standard 7.09 8 FC-LIN-42420W 500-H,, FC 3G _015S011 Standard 7.09 Compound name: 13C4-PFOA Response Factor: 6728.38 RRF SD: 1520.44, % Relative SD: 22.5974 Response type: External Std, Area Curve type: Rf Area 92297 97615 93648 93639 85495 75636 60059 47536 IS Area Std. Conc 12.000 12.000 12.000 12.000 12.000 12.000 12.000 12.000 ng/L 13.718 14.508 13.918 13.917 12.707 11.241 8.926 7.065 %Rec 114.3 120.9 116.0 116.0 105.9 93.7 74.4 58.9 S/N 1032 0 409 510 258 731 0 419 Acq.Date 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 Acq.Time 20:15:53 20:32:54 20:49:47 21:06:48 21:23:49 21:40:42 21:57:35 22:14:36 Detection... MM MM MM MM MM MM MM MM PV by JLIU, SV by KJC 4-Jan-13. Calver conc in ng. Page 241 of 307 www.axysanalytical.com Quantify Compound Summary Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\Inst_G\PFC.PRO\FC\FC3G_015-A1.qld Last Altered: Tuesday, January 15, 2013 10:48:13 Pacific Standard Time Printed: Tuesday, January 15, 2013 11:33:51 Pacific Standard Time Compound name: 13C4-PFOS-1 # ID Name Type RT 1 F C -L IN -4 2 42 0 W 5 0 0-A ,, F C 3G _0 1 5 S 00 4 Standard 8.41 2 FC -LIN-42420W 500-B ,, FC3G _015S005 Standard 8.35 3 FC-LI N -4 2 4 2 0 W 5 0 0 -C ,, F C 3G _0 1 5 S 00 6 Standard 8.41 4 FC-LI N -42420W 500-D ,, FC3G _015S007 Standard 8.35 5 FC-LIN-42420W 500-E,, FC3G _015S008 Standard 8.35 6 FC-LIN-42420W 500-F,, F C 3G _0 1 5 S 00 9 Standard 8.41 7 FC-LI N -4 2 4 2 0 W 5 0 0 -G ,, FC 3G _ 0 15 S 0 1 0 Standard 8.35 8 FC-LIN-42420W 500-H,, FC 3G _015S011 Standard 8.35 Area 13097 14831 14361 14492 14226 11098 8899 6445 Compound name: 13C4-PFOS-1 Response Factor: 0.24213 RRF SD: 0.0283045, % Relative SD: 11.6898 Response type: Internal Std ( Ref 30 ), Area * ( IS Conc. / IS Area ) Curve type: Rf IS Area 29158 30071 31360 31268 30024 25821 23870 18603 Std. Conc 18.000 18.000 18.000 18.000 18.000 18.000 18.000 18.000 ng/L 18.551 20.370 18.913 19.142 19.570 17.751 15.397 14.308 %Rec 103.1 113.2 105.1 106.3 108.7 98.6 85.5 79.5 S/N 423 270 369 474 473 629 193 65 Acq.Date 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 Acq.Time 20:15:53 20:32:54 20:49:47 21:06:48 21:23:49 21:40:42 21:57:35 22:14:36 Detection... MM MM MM MM MM MM MM MM PV by JLIU, SV by KJC 4-Jan-13. Calver conc in ng. Page 242 of 307 www.axysanalytical.com Quantify Compound Summary Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\Inst_G\PFC.PRO\FC\FC3G_015-A1.qld Last Altered: Tuesday, January 15, 2013 10:48:13 Pacific Standard Time Printed: Tuesday, January 15, 2013 11:33:51 Pacific Standard Time Compound name: 13C4-PFOS-2 # ID Name Type RT 1 F C -L IN -4 2 42 0 W 5 0 0-A ,, F C 3G _0 1 5 S 00 4 Standard 8.41 2 FC -LIN-42420W 500-B ,, FC3G _015S005 Standard 8.35 3 FC-LI N -4 2 4 2 0 W 5 0 0 -C ,, F C 3G _0 1 5 S 00 6 Standard 8.41 4 FC-LI N -42420W 500-D ,, FC3G _015S007 Standard 8.35 5 FC-LIN-42420W 500-E,, FC3G _015S008 Standard 8.35 6 FC-LIN-42420W 500-F,, F C 3G _0 1 5 S 00 9 Standard 8.41 7 FC-LI N -4 2 4 2 0 W 5 0 0 -G ,, FC 3G _ 0 15 S 0 1 0 Standard 8.35 8 FC-LIN-42420W 500-H,, FC 3G _015S011 Standard 8.35 Area 10291 11508 11454 11374 11600 8840 6993 5284 Compound name: 13C4-PFOS-2 Response Factor: 0.192381 RRF SD: 0.0213861, % Relative SD: 11.1165 Response type: Internal Std ( Ref 30 ), Area * ( IS Conc. / IS Area ) Curve type: Rf IS Area 29158 30071 31360 31268 30024 25821 23870 18603 Std. Conc 18.000 18.000 18.000 18.000 18.000 18.000 18.000 18.000 ng/L 18.346 19.892 18.985 18.907 20.083 17.796 15.228 14.764 %Rec 101.9 110.5 105.5 105.0 111.6 98.9 84.6 82.0 S/N 883 283 490 274 932 412 333 251 Acq.Date 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 Acq.Time 20:15:53 20:32:54 20:49:47 21:06:48 21:23:49 21:40:42 21:57:35 22:14:36 Detection... MM MM MM MM MM MM MM MM PV by JLIU, SV by KJC 4-Jan-13. Calver conc in ng. Page 243 of 307 www.axysanalytical.com Quantify Compound Summary Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\Inst_G\PFC.PRO\FC\FC3G_015-A1.qld Last Altered: Tuesday, January 15, 2013 10:48:13 Pacific Standard Time Printed: Tuesday, January 15, 2013 11:33:51 Pacific Standard Time Compound name: 18O2-PFHxS-1 # ID Name Type RT 1 FC -LIN-42420W 500-A ,, FC3G _015S004 Standard 7.33 2 FC -LIN-42420W 500-B ,, FC3G _015S005 Standard 7.33 3 FC-LI N -42420W 500-C ,, FC3G _015S006 Standard 7.33 4 FC-LI N -42420W 500-D ,, FC3G _015S007 Standard 7.33 5 FC-LIN-42420W 500-E,, FC3G _015S008 Standard 7.33 6 FC-LIN-42420W 500-F,, FC3G _015S009 Standard 7.33 7 FC-LI N -4 2 4 2 0 W 5 0 0 -G ,, FC 3G _ 0 15 S 0 1 0 Standard 7.33 8 FC-LIN-42420W 500-H,, FC 3G _015S011 Standard 7.33 Area 11409 11723 12752 11961 10750 9307 7532 5162 Compound name: 18O2-PFHxS-1 Response Factor: 0.200124 RRF SD: 0.0242557, % Relative SD: 12.1203 Response type: Internal Std ( Ref 30 ), Area * ( IS Conc. / IS Area ) Curve type: Rf IS Area 29158 30071 31360 31268 30024 25821 23870 18603 Std. Conc 18.000 18.000 18.000 18.000 18.000 18.000 18.000 18.000 ng/L 19.552 19.481 20.318 19.115 17.891 18.011 15.767 13.865 %Rec 108.6 108.2 112.9 106.2 99.4 100.1 87.6 77.0 S/N 190 0 0 560 0 3189 2995 0 Acq.Date 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 Acq.Time 20:15:53 20:32:54 20:49:47 21:06:48 21:23:49 21:40:42 21:57:35 22:14:36 Detection... MM MM MM MM MM MM MM MM PV by JLIU, SV by KJC 4-Jan-13. Calver conc in ng. Page 244 of 307 www.axysanalytical.com Quantify Compound Summary Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\Inst_G\PFC.PRO\FC\FC3G_015-A1.qld Last Altered: Tuesday, January 15, 2013 10:48:13 Pacific Standard Time Printed: Tuesday, January 15, 2013 11:33:51 Pacific Standard Time Compound name: 18O2-PFHxS-2 # ID Name Type RT 1 FC -LIN-42420W 500-A ,, FC3G _015S004 Standard 7.33 2 FC -LIN-42420W 500-B ,, FC3G _015S005 Standard 7.33 3 FC-LI N -42420W 500-C ,, FC3G _015S006 Standard 7.33 4 FC-LI N -42420W 500-D ,, FC3G _015S007 Standard 7.33 5 FC-LIN-42420W 500-E,, FC3G _015S008 Standard 7.33 6 FC-LIN-42420W 500-F,, FC3G _015S009 Standard 7.33 7 FC-LI N -4 2 4 2 0 W 5 0 0 -G ,, FC 3G _ 0 15 S 0 1 0 Standard 7.33 8 FC-LIN-42420W 500-H,, FC 3G _015S011 Standard 7.33 Area 8167 9543 9276 8817 8538 6193 5239 4007 Compound name: 18O2-PFHxS-2 Response Factor: 0.148217 RRF SD: 0.0207067, % Relative SD: 13.9705 Response type: Internal Std ( Ref 30 ), Area * ( IS Conc. / IS Area ) Curve type: Rf IS Area 29158 30071 31360 31268 30024 25821 23870 18603 Std. Conc 18.000 18.000 18.000 18.000 18.000 18.000 18.000 18.000 ng/L 18.897 21.412 19.957 19.025 19.187 16.181 14.808 14.532 %Rec 105.0 119.0 110.9 105.7 106.6 89.9 82.3 80.7 S/N 1381 0 634 1087 1646 831 0 0 Acq.Date 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 Acq.Time 20:15:53 20:32:54 20:49:47 21:06:48 21:23:49 21:40:42 21:57:35 22:14:36 Detection... MM MM MM MM MM MM MM MM PV by JLIU, SV by KJC 4-Jan-13. Calver conc in ng. Page 245 of 307 www.axysanalytical.com Quantify Compound Summary Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\Inst_G\PFC.PRO\FC\FC3G_015-A1.qld Last Altered: Tuesday, January 15, 2013 10:48:13 Pacific Standard Time Printed: Tuesday, January 15, 2013 11:33:51 Pacific Standard Time Compound name: 13C4-PFBA # ID Name Type RT 1 F C -L IN -4 2 42 0 W 5 0 0-A ,, F C 3G _0 1 5 S 00 4 Standard 5.21 2 FC -LIN-42420W 500-B ,, FC3G _015S005 Standard 5.17 3 FC-LI N -42420W 500-C ,, FC3G _015S006 Standard 5.17 4 FC-LI N -42420W 500-D ,, FC3G _015S007 Standard 5.23 5 FC-LIN-42420W 500-E,, F C 3G _0 1 5 S 00 8 Standard 5.21 6 FC-LIN-42420W 500-F,, F C 3G _0 1 5 S 00 9 Standard 5.21 7 FC-LI N -4 2 4 2 0 W 5 0 0 -G ,, FC 3G _ 0 15 S 0 1 0 Standard 5.19 8 FC-LIN-42420W 500-H,, F C 3 G _ 0 1 5 S 0 1 1 Standard 5.21 Area 37393 38330 38179 37645 35113 30026 24526 20307 Compound name: 13C4-PFBA Response Factor: 0.982279 RRF SD: 0.0724374, % Relative SD: 7.37442 Response type: Internal Std ( Ref 30 ), Area * ( IS Conc. / IS Area ) Curve type: Rf IS Area 29158 30071 31360 31268 30024 25821 23870 18603 Std. Conc 12.000 12.000 12.000 12.000 12.000 12.000 12.000 12.000 ng/L 13.055 12.977 12.394 12.257 11.906 11.838 10.460 11.113 %Rec 108.8 108.1 103.3 102.1 99.2 98.6 87.2 92.6 S/N 385 137 56 307 247 276 110 125 Acq.Date 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 Acq.Time 20:15:53 20:32:54 20:49:47 21:06:48 21:23:49 21:40:42 21:57:35 22:14:36 Detection... MM MM MM MM MM bb MM MM PV by JLIU, SV by KJC 4-Jan-13. Calver conc in ng. Page 246 of 307 www.axysanalytical.com Quantify Compound Summary Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\Inst_G\PFC.PRO\FC\FC3G_015-A1.qld Last Altered: Tuesday, January 15, 2013 10:48:13 Pacific Standard Time Printed: Tuesday, January 15, 2013 11:33:51 Pacific Standard Time Compound name: 13C2-PFHxA # ID Name Type RT 1 FC -LIN-42420W 500-A ,, FC3G _015S004 Standard 6.36 2 FC -LIN-42420W 500-B ,, FC3G _015S005 Standard 6.34 3 FC-LI N -42420W 500-C ,, FC3G _015S006 Standard 6.36 4 FC-LI N -42420W 500-D ,, FC3G _015S007 Standard 6.36 5 FC-LIN-42420W 500-E,, FC3G _015S008 Standard 6.34 6 FC-LIN-42420W 500-F,, FC3G _015S009 Standard 6.36 7 FC-LI N -4 2 4 2 0 W 5 0 0 -G ,, FC 3G _ 0 15 S 0 1 0 Standard 6.33 8 FC-LIN-42420W 500-H,, FC 3G _015S011 Standard 6.34 Area 72936 77481 77682 73854 68145 58258 47890 40957 Compound name: 13C2-PFHxA Response Factor: 1.94279 RRF SD: 0.155326, % Relative SD: 7.99498 Response type: Internal Std ( Ref 30 ), Area * ( IS Conc. / IS Area ) Curve type: Rf IS Area 29158 30071 31360 31268 30024 25821 23870 18603 Std. Conc 12.000 12.000 12.000 12.000 12.000 12.000 12.000 12.000 ng/L 12.875 13.263 12.750 12.157 11.683 11.613 10.327 11.332 %Rec 107.3 110.5 106.3 101.3 97.4 96.8 86.1 94.4 S/N 1873 5235 2508 2940 2714 1874 1928 1008 Acq.Date 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 Acq.Time 20:15:53 20:32:54 20:49:47 21:06:48 21:23:49 21:40:42 21:57:35 22:14:36 Detection... MM MM MM MM MM MM MM MM PV by JLIU, SV by KJC 4-Jan-13. Calver conc in ng. Page 247 of 307 www.axysanalytical.com Quantify Compound Summary Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\Inst_G\PFC.PRO\FC\FC3G_015-A1.qld Last Altered: Tuesday, January 15, 2013 10:48:13 Pacific Standard Time Printed: Tuesday, January 15, 2013 11:33:51 Pacific Standard Time Compound name: 13C5-PFNA # ID Name Type RT 1 FC -LIN-42420W 500-A ,, FC3G _015S004 Standard 7.55 2 FC -LIN-42420W 500-B ,, FC3G _015S005 Standard 7.49 3 FC-LI N -42420W 500-C ,, FC3G _015S006 Standard 7.49 4 FC-LI N -42420W 500-D ,, FC3G _015S007 Standard 7.55 5 FC-LIN-42420W 500-E,, FC3G _015S008 Standard 7.55 6 FC-LIN-42420W 500-F,, FC3G _015S009 Standard 7.55 7 FC-LI N -4 2 4 2 0 W 5 0 0 -G ,, FC 3G _ 0 15 S 0 1 0 Standard 7.49 8 FC-LIN-42420W 500-H,, FC 3G _015S011 Standard 7.49 Area 76162 83747 83846 83869 79478 71910 55823 45876 Compound name: 13C5-PFNA Response Factor: 2.18642 RRF SD: 0.127832, % Relative SD: 5.8466 Response type: Internal Std ( Ref 30 ), Area * ( IS Conc. / IS Area ) Curve type: Rf IS Area 29158 30071 31360 31268 30024 25821 23870 18603 Std. Conc 12.000 12.000 12.000 12.000 12.000 12.000 12.000 12.000 ng/L 11.946 12.738 12.228 12.268 12.107 12.737 10.696 11.279 %Rec 99.6 106.1 101.9 102.2 100.9 106.1 89.1 94.0 S/N 0 4568 8334 0 0 8344 0 4659 Acq.Date 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 Acq.Time 20:15:53 20:32:54 20:49:47 21:06:48 21:23:49 21:40:42 21:57:35 22:14:36 Detection... MM MM MM MM MM MM MM MM PV by JLIU, SV by KJC 4-Jan-13. Calver conc in ng. Page 248 of 307 www.axysanalytical.com Quantify Compound Summary Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\Inst_G\PFC.PRO\FC\FC3G_015-A1.qld Last Altered: Tuesday, January 15, 2013 10:48:13 Pacific Standard Time Printed: Tuesday, January 15, 2013 11:33:51 Pacific Standard Time Compound name: 13C2-PFDA # ID Name Type RT 1 FC -LIN-42420W 500-A ,, FC3G _015S004 Standard 8.05 2 FC -LIN-42420W 500-B ,, FC3G _015S005 Standard 8.05 3 FC-LI N -42420W 500-C ,, FC3G _015S006 Standard 8.05 4 FC-LI N -42420W 500-D ,, FC3G _015S007 Standard 8.05 5 FC-LIN-42420W 500-E,, FC3G _015S008 Standard 8.05 6 FC-LIN-42420W 500-F,, FC3G _015S009 Standard 8.05 7 FC-LI N -4 2 4 2 0 W 5 0 0 -G ,, FC 3G _ 0 15 S 0 1 0 Standard 8.05 8 FC-LIN-42420W 500-H,, FC 3G _015S011 Standard 7.99 Area 75970 97950 95963 98960 93731 81150 83939 84417 Compound name: 13C2-PFDA Response Factor: 2.75069 RRF SD: 0.466721, % Relative SD: 16.9674 Response type: Internal Std ( Ref 30 ), Area * ( IS Conc. / IS Area ) Curve type: Rf IS Area 29158 30071 31360 31268 30024 25821 23870 18603 Std. Conc 12.000 12.000 12.000 12.000 12.000 12.000 12.000 12.000 ng/L 9.472 11.842 11.124 11.506 11.350 11.425 12.784 16.497 %Rec 78.9 98.7 92.7 95.9 94.6 95.2 106.5 137.5 S/N 716 827 1068 1869 700 619 527 677 Acq.Date 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 Acq.Time 20:15:53 20:32:54 20:49:47 21:06:48 21:23:49 21:40:42 21:57:35 22:14:36 Detection... MM MM MM MM MM MM MM MM PV by JLIU, SV by KJC 4-Jan-13. Calver conc in ng. Page 249 of 307 www.axysanalytical.com Quantify Compound Summary Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\Inst_G\PFC.PRO\FC\FC3G_015-A1.qld Last Altered: Tuesday, January 15, 2013 10:48:13 Pacific Standard Time Printed: Tuesday, January 15, 2013 11:33:51 Pacific Standard Time Compound name: 13C2-PFDoA # ID Name Type RT 1 FC -LIN-42420W 500-A ,, FC3G _015S004 Standard 9.24 2 F C -L IN -4 2 42 0 W 5 0 0-B ,, F C 3G _0 1 5 S 00 5 Standard 9.21 3 FC-LI N -42420W 500-C ,, FC3G _015S006 Standard 9.24 4 FC-LI N -4 2 4 2 0 W 5 0 0 -D ,, F C 3G _0 1 5 S 00 7 Standard 9.21 5 FC-LIN-42420W 500-E,, F C 3G _0 1 5 S 00 8 Standard 9.21 6 FC-LIN-42420W 500-F,, FC3G _015S009 Standard 9.24 7 FC-LI N -4 2 4 2 0 W 5 0 0 -G ,, FC 3G _ 0 15 S 0 1 0 Standard 9.21 8 FC-LIN-42420W 500-H,, FC 3G _015S011 Standard 9.18 Area 136364 132608 158117 159917 146991 148678 149909 173162 Compound name: 13C2-PFDoA Response Factor: 4.30677 RRF SD: 0.537271, % Relative SD: 12.475 Response type: Internal Std ( Ref 30 ), Area * ( IS Conc. / IS Area ) Curve type: Rf IS Area 29158 30071 31360 31268 30024 25821 23870 18603 Std. Conc 12.000 12.000 12.000 12.000 12.000 12.000 12.000 12.000 ng/L 10.859 10.239 11.707 11.875 11.368 13.369 14.582 21.613 %Rec 90.5 85.3 97.6 99.0 94.7 111.4 121.5 180.1 S/N 684 721 867 1318 1065 574 800 882 Acq.Date 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 Acq.Time 20:15:53 20:32:54 20:49:47 21:06:48 21:23:49 21:40:42 21:57:35 22:14:36 Detection... MM MM MM MM MM MM MM MMX PV by JLIU, SV by KJC 4-Jan-13. Calver conc in ng. Page 250 of 307 www.axysanalytical.com Quantify Compound Summary Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\Inst_G\PFC.PRO\FC\FC3G_015-A1.qld Last Altered: Tuesday, January 15, 2013 10:48:13 Pacific Standard Time Printed: Tuesday, January 15, 2013 11:33:51 Pacific Standard Time Compound name: 13C2-PFOUEA # ID Name Type RT 1 FC -LIN-42420W 500-A ,, FC3G _015S004 Standard 7.43 2 FC -LIN-42420W 500-B ,, FC3G _015S005 Standard 7.43 3 FC-LI N -42420W 500-C ,, FC3G _015S006 Standard 7.38 4 FC-LI N -42420W 500-D ,, FC3G _015S007 Standard 7.43 5 FC-LIN-42420W 500-E,, FC3G _015S008 Standard 7.43 6 FC-LIN-42420W 500-F,, FC3G _015S009 Standard 7.43 7 FC-LI N -4 2 4 2 0 W 5 0 0 -G ,, FC 3G _ 0 15 S 0 1 0 Standard 7.43 8 FC-LIN-42420W 500-H,, FC 3G _015S011 Standard 7.38 Compound name: 13C2-PFOUEA Response Factor: 2752.2 RRF SD: 447.183, % Relative SD: 16.2482 Response type: External Std, Area Curve type: Rf Area 29158 30071 31360 31268 30024 25821 23870 18603 IS Area Std. Conc 10.000 10.000 10.000 10.000 10.000 10.000 10.000 10.000 ng/L 10.595 10.926 11.395 11.361 10.909 9.382 8.673 6.759 %Rec 105.9 109.3 113.9 113.6 109.1 93.8 86.7 67.6 S/N 4601 0 0 1446 0 2673 9550 2944 Acq.Date 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 14-Jan-13 Acq.Time 20:15:53 20:32:54 20:49:47 21:06:48 21:23:49 21:40:42 21:57:35 22:14:36 Detection... MM MM MM MM MM MM MM MM PV by JLIU, SV by KJC 4-Jan-13. Calver conc in ng. Page 251 of 307 www.axysanalytical.com Quantify Sample Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\Inst_G\PFC.PRO\FC\FC3G_015-A1.qld Last Altered: Tuesday, January 15, 2013 10:48:13 Pacific Standard Time Printed: Tuesday, January 15, 2013 11:33:51 Pacific Standard Time Method: G:\Masslynx\Master Methods\PFC\FC_060_10_01.mdb 03 Dec 2010 17:21:03 Calibration: 15 Jan 2013 10:48:13 ID: FC-LIN-42420W500-A,, Name: FC3G_015S004 Description: 1,,15uL Date: 14-Jan-2013 Time: 20:15:53 PFBA FC3G 015S004 100 5.21 5.21 2.15e3 r 2.15e3 10125 10125 % 1 5.56 7.07 4.03 0 min 5.00 6.00 7.00 PFPeA FC3G 015S004 100- 5.95 2.50e3 10914 %- 5.45 0 - min 5.00 6.00 7.00 PFHxA FC3G_015S004 100 6.36 4.83e3 23057 % 0 min 5.00 6.00 7.00 PFHpA FC3G_015S004 100 6.73 3.75e3 min 5.00 6.00 7.00 PFOA-1 FC3G 015S004 PFNA FC3G 015S004 PFDA FC3G 015S004 PFUnA FC3G 015S004 PFDoA FC3G 015S004 PFBS-1 FC3G 015S004 PFHxS-1 FC3G 015S004 min PFHxS-2 FC3G 015S004 min min PFHxS-3 FC3G 015S004 min min min PFOS-1 FC3G_015S004 100 8.41 1.21e3 3446 % 11.31 12.14 PFOS-2 FC3G 015S004 min min 8.00 10.00 12.00 PFOA-2 FC3G 015S004 min min PFBS-2 FC3G_015S004 100- 6.51 7.06e2 3255 %- -4.03 6.16 min 0 min 5.00 6.00 7.00 PFOSA FC3G 015S004 min PV by JLIU, SV by KJC 4-Jan-13. Calver conc in ng. Page 252 of 307 www.axysanalytical.com Quantify Sample Report MassLynx 4.1 SCN627 Dataset: G :\M asslynx\ln st_ G \P F C .P R O \F C \F C 3G _ 015 -A 1.qld Last Altered: Tuesday, January 15, 2013 10:48:13 Pacific Standard Time Printed: Tuesday, January 15, 2013 11:33:51 Pacific Standard Time ID: FC-LIN-42420W500-A,, Name: FC3G_015S004 Description: 1,,15uL Date: 14-Jan-2013 Time: 20:15:53 13C2-PFOA FC3G 015S004 13C4-PFOA FC3G 015S004 13C4-PFOS-1 FC3G 015S004 13C4-PFBA FC3G 015S004 13C2-PFHXA FC3G 015S004 13C5-PFNA FC3G 015S004 PV by JULI, SV by KJC 4-Jan-13. Calver cone in ng. 13C4-PFOS-2 FC3G 015S004 1802-PFHxS-l FC3G 015S004 1802-PFHXS-2 FC3G 015S004 13C2-PFDA FC3G 015S004 13C2-PFDOA FC3G 015S004 min 13C2-PFOUEA FC3G 015S004 m Page 253 of 307 www.axysanalytical.com Quantify Sample Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\Inst_G\PFC.PRO\FC\FC3G_015-A1.qld Last Altered: Tuesday, January 15, 2013 10:48:13 Pacific Standard Time Printed: Tuesday, January 15, 2013 11:33:51 Pacific Standard Time ID: FC-LIN-42420W500-A,, Name: FC3G_015S004 Description: 1,,15uL Date: 14-Jan-2013 Time: 20:15:53 # Name 1 PFBA 2 PFPeA 3 PFHxA 4 PFHpA 5 PFOA-1 6 PFOA-2 7 PFNA 8 PFDA 9 PFUnA 10 PFDoA 11 PFBS-1 12 PFBS-2 13 PFHxS-1 14 PFHxS-2 15 PFHxS-3 16 PFOS-1 17 PFOS-2 18 PFOSA 19 13C2-PFOA 20 13C4-PFOA 21 13C4-PFO S-1 22 13C4-PFOS-2 23 18O2-PFHxS-1 24 18O2-PFHxS-2 25 13C4-PFBA 26 13C2-PFHxA 27 13C5-PFNA 28 13C2-PFDA 29 13C2-PFDoA 30 13C2-PFOUEA IS# Trace RT 25 212.99 >1 6 8.98 5.21 26 262.98 > 218.... 5.95 26 312.97> 268.98 6.36 26 362.97> 318.98 6.73 19 412.97> 368.98 7.14 19 412.97> 168.80 7.14 27 462.96 > 418.... 7.55 28 512.96 > 468.... 8.05 28 5 62 .96 > 518.... 8.61 29 612.95 > 568.... 9.24 23 2 98 .94 > 79.96 6.51 24 2 98 .94 > 98.95 6.51 23 398.84 > 79.96 7.33 24 398.84> 98.96 7.33 23 398.84> 118.70 7.33 21 4 98 .93 > 79.96 8.41 22 4 98 .93 > 98.96 8.41 21 498 > 78 9.99 20 414.97 > 369.... 7.09 416.97 > 371.9 7.14 30 503 > 79.96 8.41 30 503 > 98.96 8.41 30 402.9>84 7.33 30 402.9>103 7.33 30 2 1 6 .9 9 > 1 71.98 5.21 30 314.97>269.98 6.36 30 467.96>422.97 7.55 30 514.96 >469.96 8.05 30 614.95 > 569.... 9.24 458.98 >393.98 7.43 Area 2152 2502 4834 3752 4717 1255 3856 5923 5269 6475 1250 706 1177 630 282 1211 650 538 251816 92297 13097 10291 11409 8167 37393 72936 76162 75970 136364 29158 IS Area 37393 72936 72936 72936 251816 251816 76162 75970 75970 136364 11409 8167 11409 8167 11409 13097 10291 13097 92297 29158 29158 29158 29158 29158 29158 29158 29158 29158 ng/L 0.461 0.547 0.469 0.459 0.406 0.570 0.436 0.433 0.439 0.366 0.825 1.157 0.904 1.288 0.863 1.006 0.946 0.502 34.532 13.718 18.551 18.346 19.552 18.897 13.055 12.875 11.946 9.472 10.859 10.595 LOD 0.0135 0.0919 0.0399 0.1409 0.0656 0.3215 0.0408 0.1170 0.0254 0.0376 0.0551 0.0069 %Rec 92.2 109.3 93.8 91.8 81.1 113.9 87.2 86.5 87.9 73.2 82.5 115.7 90.4 128.8 86.3 100.6 94.6 100.5 95.9 114.3 103.1 101.9 108.6 105.0 108.8 107.3 99.6 78.9 90.5 105.9 S/N 10 50 142 105 39 77 43 89 74 111 141 67 0 89 25 34 37 24 0 1032 423 883 190 1381 385 1873 0 716 684 4601 Noise 990 220 162 152 519 65 340 242 298 251 36 49 0 31 36 102 71 68 0 355 126 47 238 22 426 183 0 384 880 24 Height 10125 10914 23057 16082 20192 5041 14554 21436 22052 28001 5046 3255 4505 2752 886 3446 2630 1628 1010883 366986 53492 41289 45336 30979 163796 342470 288608 274796 601392 111169 IS Height 163796 342470 342470 342470 1010883 1010883 288608 274796 274796 601392 45336 30979 45336 30979 45336 53492 41289 53492 366986 111169 111169 111169 111169 111169 111169 111169 111169 111169 Sam ple size 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 Factor2 Detection... 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 bb 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM PV by JLIU, SV by KJC 4-Jan-13. Calver conc in ng. Page 254 of 307 www.axysanalytical.com Quantify Sample Report MassLynx 4.1 SCN627 Dataset: G :\M asslynx\ln st_ G \P F C .P R O \F C \F C 3G _ 015 -A 1.qld Last Altered: Tuesday, January 15, 2013 10:48:13 Pacific Standard Time Printed: Tuesday, January 15, 2013 11:33:51 Pacific Standard Time ID: FC-LIN-42420W500-B,, Name: FC3G_015S005 Description: 1,,15uL Date: 14-Jan-2013 Time: 20:32:54 PFBA FC3G 015S005 PFPeA FC3G 015S005 PFHxA FC3G 015S005 PFNA FC3G 015S005 PFDA FC3G 015S005 PFUnA FC3G 015S005 PFHxS-1 FC3G_015S005 - 7 77 100 ]2 .7 6 e 3 7 '\ 10898 / \ PFHxS-2 FC3G 015S005 1 0 0 - 1 ,2 6 e 3 7 \ 4234 %\ PFHxS-3 FC3G 015S005 1 0 0 - 6 .2 5 e 2 7 \ 1987 \ %1 ii iiU iii Ii nrrrr i min 7.00 8.00 o- i i i i iii i i r i min 7.00 8.00 07.00 8.00 PV by JULI, SV by KJC 4-Jan-13. Calver cone in ng. PFHpA FC3G 015S005 PFOA-1 FC3G 015S005 PFOA-2 FC3G 015S005 PFDoA FC3G 015S005 PFBS-1 FC3G 015S005 PFBS-2 FC3G 015S005 PFOS-1 FC3G 015S005 PFOS-2 FC3G 015S005 PFOSA FC3G 015S005 m Page 255 of 307 www.axysanalytical.com Quantify Sample Report MassLynx 4.1 SCN627 Dataset: G :\M asslynx\ln st_ G \P F C .P R O \F C \F C 3G _ 015 -A 1.qld Last Altered: Tuesday, January 15, 2013 10:48:13 Pacific Standard Time Printed: Tuesday, January 15, 2013 11:33:51 Pacific Standard Time ID: FC-LIN-42420W500-B,, Name: FC3G_015S005 Description: 1,,15uL Date: 14-Jan-2013 Time: 20:32:54 13C2-PFOA 13C4-PFOA 13C4-PFOS-1 13C4-PFBA FC3G_015S005 100n 5.17 3.83e4 143553 -4 .0 9 tt min 5.00 6.00 7.00 13C2-PFHXA FC3G 015S005 100- 6.34 7.75e4 342906 %- o - iiintimi min 5.00 6.00 7.00 13C5-PFNA FC3G_015S005 7.49 100 8.37e4 327169 % 0 7.00 8.00 PV by JULI, SV by KJC 4-Jan-13. Calver cone in ng. 13C4-PFOS-2 FC3G_015S005 100- 8.35 1.15e4 44535 1802-PFHxS-l FC3G 015S005 8.00 10.00 12.00 13C2-PFDA 13C2-PFDOA 1802-PFHXS-2 FC3G 015S005 13C2-PFOUEA m Page 256 of 307 www.axysanalytical.com Quantify Sample Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\Inst_G\PFC.PRO\FC\FC3G_015-A1.qld Last Altered: Tuesday, January 15, 2013 10:48:13 Pacific Standard Time Printed: Tuesday, January 15, 2013 11:33:51 Pacific Standard Time ID: FC-LIN-42420W500-B,, Name: FC3G_015S005 Description: 1,,15uL Date: 14-Jan-2013 Time: 20:32:54 # Name 1 PFBA 2 PFPeA 3 PFHxA 4 PFHpA 5 PFOA-1 6 PFOA-2 7 PFNA 8 PFDA 9 PFUnA 10 PFDoA 11 PFBS-1 12 PFBS-2 13 PFHxS-1 14 PFHxS-2 15 PFHxS-3 16 PFOS-1 17 PFOS-2 18 PFOSA 19 13C2-PFOA 20 13C4-PFOA 21 13C4-PFO S-1 22 13C4-PFOS-2 23 18O2-PFHxS-1 24 18O2-PFHxS-2 25 13C4-PFBA 26 13C2-PFHxA 27 13C5-PFNA 28 13C2-PFDA 29 13C2-PFDoA 30 13C2-PFOUEA IS# Trace RT 25 212.99>168.98 5.19 26 262.98 > 218.... 5.95 26 312.97> 268.98 6.34 26 362.97> 318.98 6.73 19 412.97> 368.98 7.09 19 412.97> 168.80 7.09 27 462.96 > 418.... 7.55 28 512.96 > 468.... 8.05 28 5 62 .96 > 518.... 8.61 29 612.95 > 568.... 9.24 23 298.94> 79.96 6.47 24 298.94 > 98.95 6.49 23 398.84 > 79.96 7.33 24 398.84> 98.96 7.33 23 398.84> 118.70 7.33 21 4 98 .93 > 79.96 8.41 22 4 98 .93 > 98.96 8.41 21 498 > 78 9.99 20 414.97 > 369.... 7.09 416.97 > 371.9 7.09 30 503 > 79.96 8.35 30 503 > 98.96 8.35 30 402.9>84 7.33 30 402.9>103 7.33 30 216.99>171.98 5.17 30 314.97>269.98 6.34 30 467.96>422.97 7.49 30 514.96 >469.96 8.05 30 6 14 .95 > 569.... 9.21 458.98 >393.98 7.43 Area 5517 6331 11980 10472 12440 2315 10365 14790 14561 15981 2925 1423 2758 1261 625 2764 1840 1521 264525 97615 14831 11508 11723 9543 38330 77481 83747 97950 132608 30071 IS Area 38330 77481 77481 77481 264525 264525 83747 97950 97950 132608 11723 9543 11723 9543 11723 14831 11508 14831 97615 30071 30071 30071 30071 30071 30071 30071 30071 30071 ng/L 1.442 1.361 1.402 1.325 1.416 1.124 1.338 1.246 1.247 1.374 2.636 2.223 2.798 2.274 2.208 2.605 2.777 1.179 34.299 14.508 20.370 19.892 19.481 21.412 12.977 13.263 12.738 11.842 10.239 10.926 LOD 0.0642 0.2371 0.2163 0.2821 0.0089 0.0087 0.0403 0.0492 %Rec 115.3 108.9 112.1 106.0 113.3 90.0 107.0 99.7 99.8 109.9 105.4 88.9 111.9 90.9 88.3 104.2 111.1 94.3 95.3 120.9 113.2 110.5 108.2 119.0 108.1 110.5 106.1 98.7 85.3 109.3 S/N 48 141 213 189 74 83 144 377 240 224 544 198 0 0 51 44 78 233 0 0 270 283 0 0 137 5235 4568 827 721 0 Noise 408 189 248 217 656 95 265 142 267 296 23 30 0 0 39 180 73 25 0 0 217 157 0 0 1048 65 72 419 801 0 Height 19656 26769 52648 41080 48425 7853 38135 53536 64070 66499 12582 6029 10898 4234 1987 8004 5707 5815 1043751 393569 58666 44535 46481 37907 143553 342906 327169 346543 577699 113503 IS Height 143553 342906 342906 342906 1043751 1043751 327169 346543 346543 577699 46481 37907 46481 37907 46481 58666 44535 58666 393569 113503 113503 113503 113503 113503 113503 113503 113503 113503 Sam ple size 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 Factor2 Detection... 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM PV by JLIU, SV by KJC 4-Jan-13. Calver conc in ng. Page 257 of 307 www.axysanalytical.com Quantify Sample Report MassLynx 4.1 SCN627 Dataset: G :\M asslynx\ln st_ G \P F C .P R O \F C \F C 3G _ 015 -A 1.qld Last Altered: Tuesday, January 15, 2013 10:48:13 Pacific Standard Time Printed: Tuesday, January 15, 2013 11:33:51 Pacific Standard Time ID: FC-LIN-42420W500-C,, Name: FC3G_015S006 Description: 1,,15uL Date: 14-Jan-2013 Time: 20:49:47 PFBA FC3G 015S006 100- 5.19 1.77e4 72128 %- PFPeA FC3G 015S006 7.07 l/ 5.00 6.00 7.00 PFNA FC3G 015S006 PFDA FC3G 015S006 PFHxA FC3G 015S006 PFUnA FC3G 015S006 PFHxS-1 FC3G 015S006 PFHxS-2 FC3G 015S006 PFHxS-3 FC3G 015S006 PV by JULI, SV by KJC 4-Jan-13. Calver cone in ng. PFHpA FC3G 015S006 PFOA-1 FC3G 015S006 PFOA-2 FC3G 015S006 PFDoA FC3G 015S006 PFBS-1 FC3G 015S006 PFBS-2 FC3G 015S006 PFOS-1 FC3G 015S006 PFOS-2 FC3G 015S006 PFOSA FC3G 015S006 m Page 258 of 307 www.axysanalytical.com Quantify Sample Report MassLynx 4.1 SCN627 Dataset: G :\M asslynx\ln st_ G \P F C .P R O \F C \F C 3G _ 015 -A 1.qld Last Altered: Tuesday, January 15, 2013 10:48:13 Pacific Standard Time Printed: Tuesday, January 15, 2013 11:33:51 Pacific Standard Time ID: FC-LIN-42420W500-C,, Name: FC3G_015S006 Description: 1,,15uL Date: 14-Jan-2013 Time: 20:49:47 13C2-PFOA FC3G_015S006 100n 7.14 2.66e5 1056061 13C4-PFOA FC3G 015S006 100- 7.09 f\ 9.36e4 \368880 %- 13C4-PFOS-1 FC3G_015S006 100 8.41 % 7.00 -r min 8.00 o7.00 --i r min 8.00 0 8.00 10.00 12.00 13C4-PFBA FC3G_015S006 100n 5.17 3.82e4 157004 -4.07 tt min 5.00 6.00 7.00 13C2-PFHXA FC3G 015S006 100- 6.36 7.77e4~i 355924 %- j o - 11mtti11 min 5.00 6.00 7.00 13C5-PFNA FC3G_015S006 7.49 100 8.38e4 324037 % 0 7.00 8.00 PV by JULI, SV by KJC 4-Jan-13. Calver cone in ng. 13C4-PFOS-2 FC3G 015S006 1802-PFHxS-l FC3G 015S006 1802-PFHXS-2 FC3G 015S006 13C2-PFDA FC3G 015S006 13C2-PFDOA FC3G 015S006 13C2-PFOUEA FC3G 015S006 m Page 259 of 307 www.axysanalytical.com Quantify Sample Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\Inst_G\PFC.PRO\FC\FC3G_015-A1.qld Last Altered: Tuesday, January 15, 2013 10:48:13 Pacific Standard Time Printed: Tuesday, January 15, 2013 11:33:51 Pacific Standard Time ID: FC-LIN-42420W500-C,, Name: FC3G_015S006 Description: 1,,15uL Date: 14-Jan-2013 Time: 20:49:47 # Name 1 PFBA 2 PFPeA 3 PFHxA 4 PFHpA 5 PFOA-1 6 PFOA-2 7 PFNA 8 PFDA 9 PFUnA 10 PFDoA 11 PFBS-1 12 PFBS-2 13 PFHxS-1 14 PFHxS-2 15 PFHxS-3 16 PFOS-1 17 PFOS-2 18 PFOSA 19 13C2-PFOA 20 13C4-PFOA 21 13C4-PFO S-1 22 13C4-PFOS-2 23 18O2-PFHxS-1 24 18O2-PFHxS-2 25 13C4-PFBA 26 13C2-PFHxA 27 13C5-PFNA 28 13C2-PFDA 29 13C2-PFDoA 30 13C2-PFOUEA IS# Trace RT 25 212.99>168.98 5.19 26 262.98 > 218.... 5.97 26 312.97> 268.98 6.36 26 362.97> 318.98 6.73 19 412.97> 368.98 7.14 19 412.97> 168.80 7.09 27 462.96 > 418.... 7.55 28 512.96 > 468.... 8.05 28 5 62 .96 > 518.... 8.61 29 612.95 > 568.... 9.24 23 298.94> 79.96 6.49 24 298.94 > 98.95 6.49 23 398.84 > 79.96 7.33 24 398.84> 98.96 7.33 23 398.84> 118.70 7.33 21 4 98 .93 > 79.96 8.41 22 4 98 .93 > 98.96 8.41 21 498 > 78 9.99 20 414.97 > 369.... 7.14 416.97 > 371.9 7.09 30 503 > 79.96 8.41 30 503 > 98.96 8.41 30 402.9>84 7.33 30 402.9>103 7.33 30 216.99>171.98 5.17 30 314.97>269.98 6.36 30 467.96>422.97 7.49 30 514.96 >469.96 8.05 30 614.95 > 569.... 9.24 458.98 >393.98 7.38 Area 17665 20792 36978 39072 40626 9021 36435 48705 51692 64757 10293 5529 8511 4912 3012 9055 6360 7114 265618 93648 14361 11454 12752 9276 38179 77682 83846 95963 158117 31360 IS Area 38179 77682 77682 77682 265618 265618 83846 95963 95963 158117 12752 9276 12752 9276 12752 14361 11454 14361 93648 31360 31360 31360 31360 31360 31360 31360 31360 31360 ng/L 5.062 4.557 4.796 5.132 5.199 4.835 5.169 5.225 5.224 5.370 9.852 9.821 8.991 9.407 10.815 10.163 10.251 5.491 35.900 13.918 18.913 18.985 20.318 19.957 12.394 12.750 12.228 11.124 11.707 11.395 LOD 0.0044 0.0902 0.1022 0.1579 0.1218 0.1030 0.7367 0.0190 0.0046 0.0308 0.0457 %Rec 101.2 91.1 95.9 102.6 104.0 96.7 103.4 104.5 104.5 107.4 98.5 98.2 89.9 94.1 108.2 101.6 102.5 109.8 99.7 116.0 105.1 105.5 112.9 110.9 103.3 106.3 101.9 92.7 97.6 113.9 S/N 377 429 688 1062 0 169 578 356 724 717 2250 717 139 0 102 126 131 362 0 409 369 490 0 634 56 2508 8334 1068 867 0 Noise 191 219 248 152 0 205 237 499 313 378 20 37 203 0 112 212 159 66 0 903 147 90 0 59 2783 142 39 325 757 0 Height 72128 94191 170385 161879 160252 34563 137190 177519 226802 271378 44055 26571 28190 18280 11385 26702 20746 23880 1056061 368880 54308 44158 51584 37197 157004 355924 324037 347325 656524 115363 IS Height 157004 355924 355924 355924 1056061 1056061 324037 347325 347325 656524 51584 37197 51584 37197 51584 54308 44158 54308 368880 115363 115363 115363 115363 115363 115363 115363 115363 115363 Sam ple size 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 Factor2 Detection... 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM PV by JLIU, SV by KJC 4-Jan-13. Calver conc in ng. Page 260 of 307 www.axysanalytical.com Quantify Sample Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\lnst_G\PFC.PRO\FC\FC3G_015-A1.qld Last Altered: Tuesday, January 15, 2013 10:48:13 Pacific Standard Time Printed: Tuesday, January 15, 2013 11:33:51 Pacific Standard Time ID: FC-LIN-42420W500-D,, Name: FC3G_015S007 Description: 1,,15uL Date: 14-Jan-2013 Time: 21:06:48 PFBA FC3G 015S007 PFPeA FC3G 015S007 PFHxA FC3G 015S007 PFNA FC3G 015S007 PFDA FC3G 015S007 PFUnA FC3G 015S007 PFHxS-1 FC3G 015S007 PFHxS-2 FC3G 015S007 PFHxS-3 FC3G 015S007 PV by JULI, SV by KJC 4-Jan-13. Calver cone in ng. PFHpA FC3G 015S007 PFOA-1 FC3G 015S007 PFOA-2 FC3G 015S007 PFDoA FC3G 015S007 PFBS-1 FC3G 015S007 PFBS-2 FC3G 015S007 PFOS-1 FC3G 015S007 PFOS-2 FC3G 015S007 PFOSA FC3G_015S007 9.99 100- 2.86e4 99782 %- 8.00 10.00 12.00 m Page 261 of 307 www.axysanalytical.com Quantify Sample Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\lnst_G\PFC.PRO\FC\FC3G_015-A1.qld Last Altered: Tuesday, January 15, 2013 10:48:13 Pacific Standard Time Printed: Tuesday, January 15, 2013 11:33:51 Pacific Standard Time ID: FC-LIN-42420W500-D,, Name: FC3G_015S007 Description: 1,,15uL Date: 14-Jan-2013 Time: 21:06:48 13C2-PFOA FC3G 015S007 13C4-PFOA FC3G 015S007 13C4-PFOS-1 FC3G_015S007 100- 8.35 1 ,45e4 55563 13C4-PFBA FC3G 015S007 13C2-PFHXA FC3G 015S007 8.00 10.00 12.00 13C5-PFNA FC3G 015S007 PV by JULI, SV by KJC 4-Jan-13. Calver cone in ng. 13C4-PFOS-2 FC3G 015S007 1802-PFHxS-l FC3G 015S007 1802-PFHXS-2 FC3G 015S007 13C2-PFDA FC3G 015S007 13C2-PFDOA FC3G 015S007 13C2-PFOUEA FC3G 015S007 m Page 262 of 307 www.axysanalytical.com Quantify Sample Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\Inst_G\PFC.PRO\FC\FC3G_015-A1.qld Last Altered: Tuesday, January 15, 2013 10:48:13 Pacific Standard Time Printed: Tuesday, January 15, 2013 11:33:51 Pacific Standard Time ID: FC-LIN-42420W500-D,, Name: FC3G_015S007 Description: 1,,15uL Date: 14-Jan-2013 Time: 21:06:48 # Name 1 PFBA 2 PFPeA 3 PFHxA 4 PFHpA 5 PFOA-1 6 PFOA-2 7 PFNA 8 PFDA 9 PFUnA 10 PFDoA 11 PFBS-1 12 PFBS-2 13 PFHxS-1 14 PFHxS-2 15 PFHxS-3 16 PFOS-1 17 PFOS-2 18 PFOSA 19 13C2-PFOA 20 13C4-PFOA 21 13C4-PFO S-1 22 13C4-PFOS-2 23 18O2-PFHxS-1 24 18O2-PFHxS-2 25 13C4-PFBA 26 13C2-PFHxA 27 13C5-PFNA 28 13C2-PFDA 29 13C2-PFDoA 30 13C2-PFOUEA IS# Trace RT 25 212.99>168.98 5.23 26 262.98 > 218.... 5.95 26 312.97> 268.98 6.34 26 362.97> 318.98 6.73 19 412.97> 368.98 7.14 19 412.97> 168.80 7.14 27 462.96 > 418.... 7.55 28 512.96 > 468.... 8.05 28 5 62 .96 > 518.... 8.61 29 6 12 .95 > 568.... 9.21 23 298.94> 79.96 6.49 24 298.94 > 98.95 6.47 23 398.84 > 79.96 7.33 24 398.84> 98.96 7.33 23 398.84> 118.70 7.33 21 4 98 .93 > 79.96 8.41 22 498.93> 98.96 8.35 21 498 > 78 9.99 20 414.97 > 369.... 7.14 416.97 > 371.9 7.09 30 503 > 79.96 8.35 30 503 > 98.96 8.35 30 402.9>84 7.33 30 402.9>103 7.33 30 216.99>171.98 5.23 30 314.97>269.98 6.36 30 467.96>422.97 7.55 30 514.96 >469.96 8.05 30 6 14 .95 > 569.... 9.21 458.98 >393.98 7.43 Area 63528 80737 140318 144182 149341 34651 144493 185619 199149 244382 41241 20643 35764 17711 10989 33164 22836 28634 265755 93639 14492 11374 11961 8817 37645 73854 83869 98960 159917 31268 IS Area 37645 73854 73854 73854 265755 265755 83869 98960 98960 159917 11961 8817 11961 8817 11961 14492 11374 14492 93639 31268 31268 31268 31268 31268 31268 31268 31268 31268 ng/L 18.984 18.749 19.866 20.144 19.811 19.037 21.027 20.576 20.315 20.934 44.008 39.540 42.269 35.989 42.899 38.306 37.683 21.565 35.922 13.917 19.142 18.907 19.115 19.025 12.257 12.157 12.268 11.506 11.875 11.361 LOD 0.0766 0.1079 0.0819 0.1218 0.2051 0.1075 0.0564 0.1320 0.0155 0.0178 0.0312 0.0236 %Rec 94.9 93.7 99.3 100.7 99.1 95.2 105.1 102.9 101.6 104.7 110.0 98.8 105.7 90.0 107.2 95.8 94.2 107.8 99.8 116.0 106.3 105.0 106.2 105.7 102.1 101.3 102.2 95.9 99.0 113.6 S/N 575 1512 6800 3803 0 1499 13918 1253 1495 2177 2292 4112 281 3728 0 522 314 1027 0 510 474 274 560 1087 307 2940 0 1869 1318 1446 Noise 482 254 102 156 0 87 39 552 589 478 86 22 463 17 0 167 246 97 0 740 117 157 86 33 515 120 0 195 533 82 Height 277157 383441 695418 593000 609477 130403 540922 691429 881123 1040393 196622 89957 130257 64214 42122 87281 77361 99782 1072138 377462 55563 42980 47904 36129 158352 351583 326064 363683 703192 119249 IS Height 158352 351583 351583 351583 1072138 1072138 326064 363683 363683 703192 47904 36129 47904 36129 47904 55563 42980 55563 377462 119249 119249 119249 119249 119249 119249 119249 119249 119249 Sam ple size 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 Factor2 Detection... 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM PV by JLIU, SV by KJC 4-Jan-13. Calver conc in ng. Page 263 of 307 www.axysanalytical.com Quantify Sample Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\lnst_G\PFC.PRO\FC\FC3G_015-A1.qld Last Altered: Tuesday, January 15, 2013 10:48:13 Pacific Standard Time Printed: Tuesday, January 15, 2013 11:33:51 Pacific Standard Time ID: FC-LIN-42420W500-E,, Name: FC3G_015S008 Description: 1,,15uL Date: 14-Jan-2013 Time: 21:23:49 PFBA FC3G 015S008 PFPeA FC3G 015S008 PFHxA FC3G 015S008 PFNA FC3G 015S008 PFDA FC3G 015S008 PFUnA FC3G 015S008 PFHxS-1 FC3G 015S008 PFHxS-2 FC3G 015S008 PFHxS-3 FC3G 015S008 PV by JULI, SV by KJC 4-Jan-13. Calver cone in ng. PFHpA FC3G 015S008 PFOA-1 FC3G 015S008 PFOA-2 FC3G 015S008 PFDoA FC3G 015S008 PFBS-1 FC3G 015S008 PFBS-2 FC3G 015S008 PFOS-1 FC3G 015S008 PFOS-2 FC3G 015S008 PFOSA FC3G 015S008 m Page 264 of 307 www.axysanalytical.com Quantify Sample Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\lnst_G\PFC.PRO\FC\FC3G_015-A1.qld Last Altered: Tuesday, January 15, 2013 10:48:13 Pacific Standard Time Printed: Tuesday, January 15, 2013 11:33:51 Pacific Standard Time ID: FC-LIN-42420W500-E,, Name: FC3G_015S008 Description: 1,,15uL Date: 14-Jan-2013 Time: 21:23:49 13C2-PFOA FC3G_015S008 100n 7.14 2.41e5 957584 7.00 T-r min 8.00 13C4-PFOA FC3G 015S008 100- 7.09 IT8 .5 5 e 4 J V,I \343729 %- o7.00 --i r min 8.00 13C4-PFOS-1 FC3G_015S008 100 8.35 1 .42e4 54947 % 0 8.00 10.00 12.00 13C4-PFBA FC3G 015S008 13C2-PFHXA FC3G 015S008 13C5-PFNA FC3G 015S008 PV by JULI, SV by KJC 4-Jan-13. Calver cone in ng. 13C4-PFOS-2 1802-PFHxS-l 1802-PFHXS-2 13C2-PFDA 13C2-PFDOA 13C2-PFOUEA m Page 265 of 307 www.axysanalytical.com Quantify Sample Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\Inst_G\PFC.PRO\FC\FC3G_015-A1.qld Last Altered: Tuesday, January 15, 2013 10:48:13 Pacific Standard Time Printed: Tuesday, January 15, 2013 11:33:51 Pacific Standard Time ID: FC-LIN-42420W500-E,, Name: FC3G_015S008 Description: 1,,15uL Date: 14-Jan-2013 Time: 21:23:49 # Name 1 PFBA 2 PFPeA 3 PFHxA 4 PFHpA 5 PFOA-1 6 PFOA-2 7 PFNA 8 PFDA 9 PFUnA 10 PFDoA 11 PFBS-1 12 PFBS-2 13 PFHxS-1 14 PFHxS-2 15 PFHxS-3 16 PFOS-1 17 PFOS-2 18 PFOSA 19 13C2-PFOA 20 13C4-PFOA 21 13C4-PFO S-1 22 13C4-PFOS-2 23 18O2-PFHxS-1 24 18O2-PFHxS-2 25 13C4-PFBA 26 13C2-PFHxA 27 13C5-PFNA 28 13C2-PFDA 29 13C2-PFDoA 30 13C2-PFOUEA IS# Trace RT 25 212.99>168.98 5.24 26 262.98 > 218.... 5.97 26 312.97> 268.98 6.36 26 362.97> 318.98 6.73 19 412.97> 368.98 7.14 19 412.97> 168.80 7.14 27 462.96 > 418.... 7.55 28 512.96 > 468.... 8.05 28 5 62 .96 > 518.... 8.61 29 6 12 .95 > 568.... 9.21 23 298.94> 79.96 6.49 24 298.94 > 98.95 6.47 23 398.84 > 79.96 7.33 24 398.84> 98.96 7.33 23 398.84> 118.70 7.33 21 4 98 .93 > 79.96 8.35 22 498.93> 98.96 8.35 21 498 > 78 9.99 20 414.97 > 369.... 7.14 416.97 > 371.9 7.09 30 503 > 79.96 8.35 30 503 > 98.96 8.35 30 402.9>84 7.33 30 402.9>103 7.33 30 2 1 6 .9 9 > 1 71.98 5.21 30 314.97>269.98 6.34 30 467.96>422.97 7.55 30 514.96 >469.96 8.05 30 6 14 .95 > 569.... 9.21 458.98 >393.98 7.43 Area 301419 379493 632521 638236 692014 171424 643515 879693 946327 1081028 176606 93835 152325 86045 51386 162731 118969 115291 240757 85495 14226 11600 10750 8538 35113 68145 79478 93731 146991 30024 IS Area 35113 68145 68145 68145 240757 240757 79478 93731 93731 146991 10750 8538 10750 8538 10750 14226 11600 14226 85495 30024 30024 30024 30024 30024 30024 30024 30024 30024 ng/L 97.717 95.772 98.807 97.204 102.573 105.039 98.921 107.421 104.927 104.702 211.633 187.968 202.336 181.967 223.279 191.828 192.444 85.380 35.643 12.707 19.570 20.083 17.891 19.187 11.906 11.683 12.107 11.350 11.368 10.909 LOD 0.0579 0.1299 0.1480 0.1310 0.0720 0.0349 0.1484 0.0173 0.0462 0.0366 %Rec 97.7 95.8 98.8 97.2 102.6 105.0 98.9 107.4 104.9 104.7 105.8 94.0 101.2 91.0 111.6 95.9 96.2 85.4 99.0 105.9 108.7 111.6 99.4 106.6 99.2 97.4 100.9 94.6 94.7 109.1 S/N 6913 8374 15254 12076 0 0 0 4480 4936 3889 36944 8405 0 0 0 1675 1585 2887 0 258 473 932 0 1646 247 2714 0 700 1065 0 Noise 160 206 193 208 0 0 0 685 799 1144 19 49 0 0 0 272 255 133 0 1334 116 51 0 19 534 123 0 465 577 0 Height 1108375 1728053 2947189 2509939 2750171 682666 2418926 3067496 3943127 4450521 708659 408264 543837 321200 180229 456383 404127 383237 957584 343729 54947 47235 41229 31148 131545 334627 307047 325898 614569 109805 IS Height 131545 334627 334627 334627 957584 957584 307047 325898 325898 614569 41229 31148 41229 31148 41229 54947 47235 54947 343729 109805 109805 109805 109805 109805 109805 109805 109805 109805 Sam ple size 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 Factor2 Detection... 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM PV by JLIU, SV by KJC 4-Jan-13. Calver conc in ng. Page 266 of 307 www.axysanalytical.com Quantify Sample Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\lnst_G\PFC.PRO\FC\FC3G_015-A1.qld Last Altered: Tuesday, January 15, 2013 10:48:13 Pacific Standard Time Printed: Tuesday, January 15, 2013 11:33:51 Pacific Standard Time ID: FC-LIN-42420W500-F,, Name: FC3G_015S009 Description: 1,,15uL Date: 14-Jan-2013 Time: 21:40:42 PFBA FC3G 015S009 PFPeA FC3G 015S009 PFHxA FC3G 015S009 PFNA FC3G 015S009 7.55 100 - 1.15e6 4232489 %- \\ 7.00 PFHxS-1 FC3G 015S009 8.00 PFDA FC3G 015S009 8.05 100- F 1.42e6 5162865 %- PFUnA FC3G_015S009 100- 8.64 | 1.62e6 6976139 %- 'i 1i I iVi Ti r| i i i i | i i i T -p -n -rp -r min 8.00 10.00 12.00 i|ih 8.00 10.00 12.00 PFHxS-2 FC3G 015S009 PFHxS-3 FC3G 015S009 PV by JULI, SV by KJC 4-Jan-13. Calver cone in ng. PFHpA FC3G 015S009 100- 6.73 1.14e6 1 4502942 %- I1 5.00 6.00 7.00 PFDoA FC3G 015S009 PFOA-1 FC3G 015S009 100- 7.14 1 ,20e6 4803563 %- iJ V , 7.00 8.00 PFBS-1 FC3G 015S009 PFOA-2 FC3G 015S009 100- 7.14 2.86e5 1172249 %- iJ 7.00 8.00 PFBS-2 FC3G 015S009 PFOS-1 FC3G 015S009 PFOS-2 FC3G 015S009 PFOSA FC3G 015S009 m Page 267 of 307 www.axysanalytical.com Quantify Sample Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\lnst_G\PFC.PRO\FC\FC3G_015-A1.qld Last Altered: Tuesday, January 15, 2013 10:48:13 Pacific Standard Time Printed: Tuesday, January 15, 2013 11:33:51 Pacific Standard Time ID: FC-LIN-42420W500-F,, Name: FC3G_015S009 Description: 1,,15uL Date: 14-Jan-2013 Time: 21:40:42 13C2-PFOA FC3G_015S009 100n 7.14 2.1 1e5 846753 7.00 T-r min 8.00 13C4-PFOA FC3G 015S009 100- FT 7.14 7.56e4 \ 304003 V% I o- -T-r min 7.00 8.00 13C4-PFOS-1 FC3G_015S009 100 8.41 % 0 8.00 10.00 12.00 13C4-PFBA FC3G 015S009 13C2-PFHXA FC3G 015S009 13C5-PFNA FC3G 015S009 PV by JULI, SV by KJC 4-Jan-13. Calver cone in ng. 13C4-PFOS-2 FC3G 015S009 1802-PFHxS-l FC3G 015S009 1802-PFHXS-2 FC3G 015S009 13C2-PFDA FC3G 015S009 13C2-PFDOA FC3G 015S009 13C2-PFOUEA FC3G 015S009 m Page 268 of 307 www.axysanalytical.com Quantify Sample Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\Inst_G\PFC.PRO\FC\FC3G_015-A1.qld Last Altered: Tuesday, January 15, 2013 10:48:13 Pacific Standard Time Printed: Tuesday, January 15, 2013 11:33:51 Pacific Standard Time ID: FC-LIN-42420W500-F,, Name: FC3G_015S009 Description: 1,,15uL Date: 14-Jan-2013 Time: 21:40:42 # Name 1 PFBA 2 PFPeA 3 PFHxA 4 PFHpA 5 PFOA-1 6 PFOA-2 7 PFNA 8 PFDA 9 PFUnA 10 PFDoA 11 PFBS-1 12 PFBS-2 13 PFHxS-1 14 PFHxS-2 15 PFHxS-3 16 PFOS-1 17 PFOS-2 18 PFOSA 19 13C2-PFOA 20 13C4-PFOA 21 13C4-PFO S-1 22 13C4-PFOS-2 23 18O2-PFHxS-1 24 18O2-PFHxS-2 25 13C4-PFBA 26 13C2-PFHxA 27 13C5-PFNA 28 13C2-PFDA 29 13C2-PFDoA 30 13C2-PFOUEA IS# Trace RT 25 212.99>168.98 5.23 26 262.98 > 218.... 5.97 26 312.97> 268.98 6.36 26 362.97> 318.98 6.73 19 412.97> 368.98 7.14 19 412.97> 168.80 7.14 27 462.96 > 418.... 7.55 28 512.96 > 468.... 8.05 28 562.96 > 518.... 8.64 29 612.95 > 568.... 9.24 23 298.94> 79.96 6.49 24 2 98 .94 > 98.95 6.51 23 398.84 > 79.96 7.33 24 398.84> 98.96 7.33 23 398.84> 118.70 7.33 21 4 98 .93 > 79.96 8.41 22 4 98 .93 > 98.96 8.41 21 498 > 78 9.99 20 414.97 > 369.... 7.14 416.97 > 371.9 7.14 30 503 > 79.96 8.41 30 503 > 98.96 8.41 30 402.9>84 7.33 30 402.9>103 7.33 30 2 1 6 .9 9 > 1 71.98 5.21 30 314.97>269.98 6.36 30 467.96>422.97 7.55 30 514.96 >469.96 8.05 30 614.95 > 569.... 9.24 458.98 >393.98 7.43 Area 500633 670319 1071639 1139370 1197420 286450 1146232 1420377 1622024 2106076 287793 150714 267940 141803 82734 271377 190358 222311 211297 75636 11098 8840 9307 6193 30026 58258 71910 81150 148678 25821 IS Area 30026 58258 58258 58258 211297 211297 71910 81150 81150 148678 9307 6193 9307 6193 9307 11098 8840 11098 75636 25821 25821 25821 25821 25821 25821 25821 25821 25821 ng/L 190.827 198.161 198.222 203.894 202.861 200.887 193.521 206.864 213.112 209.250 398.208 420.913 411.296 417.389 413.136 405.150 401.314 199.217 35.359 11.241 17.751 17.796 18.011 16.181 11.838 11.613 12.737 11.425 13.369 9.382 LOD 118.9377 0.2008 0.3825 0.2250 0.0461 0.0820 0.1182 0.0161 0.0518 0.1242 0.0229 0.0044 0.0517 0.0720 0.0105 %Rec 95.4 99.1 99.1 101.9 101.4 100.4 96.8 103.4 106.6 104.6 99.6 105.2 102.8 104.3 103.3 101.3 100.3 99.6 98.2 93.7 98.6 98.9 100.1 89.9 98.6 96.8 106.1 95.2 111.4 93.8 S/N 5 16850 26475 27466 0 0 22371 4875 8175 11005 15577 18009 10903 4240 4172 1808 1716 3310 0 731 629 412 3189 831 276 1874 8344 619 574 2673 Noise 393438 175 196 164 0 0 189 1059 853 815 75 34 84 118 68 412 350 222 0 416 67 76 11 26 410 150 32 478 1042 38 Height 1855019 2956717 5190074 4502942 4803563 1172249 4232489 5162865 6976139 8964105 1167220 610202 911714 501759 285200 745767 600727 735982 846753 304003 42004 31488 34584 21433 113120 280566 269017 295754 597960 100842 IS Height 113120 280566 280566 280566 846753 846753 269017 295754 295754 597960 34584 21433 34584 21433 34584 42004 31488 42004 304003 100842 100842 100842 100842 100842 100842 100842 100842 100842 Sam ple size 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 Factor2 Detection... 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 bb 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM PV by JLIU, SV by KJC 4-Jan-13. Calver conc in ng. Page 269 of 307 www.axysanalytical.com Quantify Sample Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\lnst_G\PFC.PRO\FC\FC3G_015-A1.qld Last Altered: Tuesday, January 15, 2013 10:48:13 Pacific Standard Time Printed: Tuesday, January 15, 2013 11:33:51 Pacific Standard Time ID: FC-LIN-42420W500-G,, Name: FC3G_015S010 Description: 1,,15uL Date: 14-Jan-2013 Time: 21:57:35 PFBA FC3G 015S010 PFPeA FC3G 015S010 PFHxA FC3G 015S010 PFNA FC3G 015S010 PFDA FC3G 015S010 PFUnA FC3G 015S010 PFHxS-1 FC3G 015S010 PFHxS-2 FC3G 015S010 PFHxS-3 FC3G 015S010 PV by JULI, SV by KJC 4-Jan-13. Calver cone in ng. PFHpA FC3G 015S010 PFOA-1 FC3G 015S010 PFOA-2 FC3G 015S010 PFDoA FC3G_015S010 100- 9.21 4.34e6 18023478 %- PFBS-1 FC3G 015S010 PFBS-2 FC3G 015S010 8.00 10.00 12.00 PFOS-1 FC3G 015S010 8.35 100- r 5.61e5 1368011 %- V 9 ?9 8.00 10.00 12.00 PFOS-2 FC3G_015S010 8.35 100 3.88e5 1194386 % 0 8.00 10.00 12.00 PFOSA FC3G 015S010 m Page 270 of 307 www.axysanalytical.com Quantify Sample Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\lnst_G\PFC.PRO\FC\FC3G_015-A1.qld Last Altered: Tuesday, January 15, 2013 10:48:13 Pacific Standard Time Printed: Tuesday, January 15, 2013 11:33:51 Pacific Standard Time ID: FC-LIN-42420W500-G,, Name: FC3G_015S010 Description: 1,,15uL Date: 14-Jan-2013 Time: 21:57:35 13C2-PFOA FC3G 015S010 13C4-PFOA FC3G 015S010 13C4-PFOS-1 FC3G 015S010 13C4-PFBA FC3G 015S010 13C2-PFHXA FC3G 015S010 13C5-PFNA FC3G 015S010 PV by JULI, SV by KJC 4-Jan-13. Calver cone in ng. 13C4-PFOS-2 FC3G 015S010 100- 8.35 6.99e3 22920 %- -si cccCoonD cc^oo 1802-PFHxS-l FC3G 015S010 100- 26355 %- 8.00 t i' i' i i' i' i i r min 10.00 12.00 'll 7.00 8.00 13C2-PFDA FC3G 015S010 13C2-PFDOA FC3G 015S010 1802-PFHXS-2 FC3G 015S010 10 0- 7.33 5.24e3 18010 %- iJ ' I' P 7.00 8.00 13C2-PFOUEA FC3G 015S010 min m Page 271 of 307 www.axysanalytical.com Quantify Sample Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\Inst_G\PFC.PRO\FC\FC3G_015-A1.qld Last Altered: Tuesday, January 15, 2013 10:48:13 Pacific Standard Time Printed: Tuesday, January 15, 2013 11:33:51 Pacific Standard Time ID: FC-LIN-42420W500-G,, Name: FC3G_015S010 Description: 1,,15uL Date: 14-Jan-2013 Time: 21:57:35 # Name 1 PFBA 2 PFPeA 3 PFHxA 4 PFHpA 5 PFOA-1 6 PFOA-2 7 PFNA 8 PFDA 9 PFUnA 10 PFDoA 11 PFBS-1 12 PFBS-2 13 PFHxS-1 14 PFHxS-2 15 PFHxS-3 16 PFOS-1 17 PFOS-2 18 PFOSA 19 13C2-PFOA 20 13C4-PFOA 21 13C4-PFO S-1 22 13C4-PFOS-2 23 18O2-PFHxS-1 24 18O2-PFHxS-2 25 13C4-PFBA 26 13C2-PFHxA 27 13C5-PFNA 28 13C2-PFDA 29 13C2-PFDoA 30 13C2-PFOUEA IS# Trace RT 25 212.99>168.98 5.23 26 262.98 > 218.... 5.95 26 312.97> 268.98 6.33 26 362.97> 318.98 6.73 19 412.97> 368.98 7.09 19 412.97> 168.80 7.09 27 462.96 > 418.... 7.49 28 512.96 > 468.... 8.05 28 5 62 .96 > 518.... 8.61 29 6 12 .95 > 568.... 9.21 23 298.94> 79.96 6.47 24 298.94 > 98.95 6.47 23 398.84 > 79.96 7.33 24 398.84> 98.96 7.33 23 398.84> 118.70 7.33 21 4 98 .93 > 79.96 8.35 22 498.93> 98.96 8.35 21 498 > 78 9.99 20 414.97 > 369.... 7.09 416.97 > 371.9 7.09 30 503 > 79.96 8.35 30 503 > 98.96 8.35 30 402.9>84 7.33 30 402.9>103 7.33 30 216.99>171.98 5.19 30 314.97>269.98 6.33 30 467.96>422.97 7.49 30 514.96 >469.96 8.05 30 6 14 .95 > 569.... 9.21 458.98 >393.98 7.43 Area 1092578 1417364 2165990 2262452 2464122 592967 2391985 3073619 3473490 4341857 574749 292314 516587 284063 155131 560878 387780 531646 180448 60059 8899 6993 7532 5239 24526 47890 55823 83939 149909 23870 IS Area 24526 47890 47890 47890 180448 180448 55823 83939 83939 149909 7532 5239 7532 5239 7532 8899 6993 8899 60059 23870 23870 23870 23870 23870 23870 23870 23870 23870 ng/L 518.258 511.694 505.086 498.311 491.806 492.779 508.363 471.682 468.725 470.764 978.718 990.315 978.341 1012.035 942.917 1006.719 1012.010 514.627 38.028 8.926 15.397 15.228 15.767 14.808 10.460 10.327 10.696 12.784 14.582 8.673 LOD 0.0005 0.0132 0.2808 0.1341 1.1128 0.3674 0.2142 0.1213 0.0149 0.2999 0.0216 0.0724 0.0624 0.0027 %Rec 103.7 102.3 101.0 99.7 98.4 98.6 101.7 94.3 93.7 94.2 97.9 99.0 97.8 101.2 94.3 100.7 101.2 102.9 105.6 74.4 85.5 84.6 87.6 82.3 87.2 86.1 89.1 106.5 121.5 86.7 S/N 7187 22502 49340 53152 0 0 36654 8972 9193 9659 76153 31388 0 7540 0 3373 2172 6334 0 0 193 333 2995 0 110 1928 0 527 800 9550 Noise 543 259 216 159 0 0 245 1262 1586 1866 29 35 0 126 0 406 550 283 0 0 153 69 9 0 870 124 0 588 794 9 Height IS Height 3900374 95829 5833103 238596 10668906 238596 8433429 238596 10217171 751674 2491062 751674 8991793 211667 11320552 310075 14579862 310075 18023478 634663 2238738 26355 1113917 18010 1718023 26355 951715 18010 486245 26355 1368011 29511 1194386 22920 1794902 29511 751674 246167 246167 29511 88586 22920 88586 26355 88586 18010 88586 95829 88586 238596 88586 211667 88586 310075 88586 634663 88586 88586 Sam ple size 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 Factor2 Detection... 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM PV by JLIU, SV by KJC 4-Jan-13. Calver conc in ng. Page 272 of 307 www.axysanalytical.com Quantify Sample Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\lnst_G\PFC.PRO\FC\FC3G_015-A1.qld Last Altered: Tuesday, January 15, 2013 10:48:13 Pacific Standard Time Printed: Tuesday, January 15, 2013 11:33:51 Pacific Standard Time ID: FC-LIN-42420W500-H,, Name: FC3G_015S011 Description: 1,,15uL Date: 14-Jan-2013 Time: 22:14:36 PFBA FC3G 015S011 PFPeA FC3G 015S011 PFHxA FC3G 015S011 PFNA FC3G 015S011 100- 7.49 5.09e6 V18762150 %- 7.00 PFHxS-1 FC3G 015S011 8.00 PFDA FC3G 015S011 8.05 100- (T 6.10e6 I 20749386 %- PFUnA FC3G_015S011 8.58 100 7.62e6 30035668 % 1/ i i I i i TtTi i i i i i i i i i i i i i i i mm 8.00 10.00 12.00 0 8.00 10.00 12.00 PFHxS-2 FC3G 015S011 PFHxS-3 FC3G 015S011 PV by JULI, SV by KJC 4-Jan-13. Calver cone in ng. PFHpA FC3G 015S011 PFOA-1 FC3G 015S011 PFOA-2 FC3G 015S011 PFDoA FC3G 015S011 PFBS-1 FC3G 015S011 PFBS-2 FC3G 015S011 PFOS-1 FC3G 015S011 8.35 100- P 1.10e6 2514590 %- V i 9^ 9 8.00 10.00 12.00 PFOS-2 FC3G_015S011 8.35 100 ,60e5 % 0 8.00 10.00 12.00 PFOSA FC3G 015S011 m Page 273 of 307 www.axysanalytical.com Quantify Sample Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\lnst_G\PFC.PRO\FC\FC3G_015-A1.qld Last Altered: Tuesday, January 15, 2013 10:48:13 Pacific Standard Time Printed: Tuesday, January 15, 2013 11:33:51 Pacific Standard Time ID: FC-LIN-42420W500-H,, Name: FC3G_015S011 Description: 1,,15uL Date: 14-Jan-2013 Time: 22:14:36 13C2-PFOA FC3G 015S011 13C4-PFOA FC3G 015S011 13C4-PFOS-1 FC3G 015S011 13C4-PFBA FC3G 015S011 13C2-PFHXA FC3G 015S011 13C5-PFNA FC3G 015S011 PV by JULI, SV by KJC 4-Jan-13. Calver cone in ng. 13C4-PFOS-2 FC3G 015S011 1802-PFHxS-l FC3G 015S011 1802-PFHXS-2 FC3G 015S011 13C2-PFDA FC3G 015S011 13C2-PFDOA FC3G 015S011 13C2-PFOUEA FC3G 015S011 m Page 274 of 307 www.axysanalytical.com Quantify Sample Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\Inst_G\PFC.PRO\FC\FC3G_015-A1.qld Last Altered: Tuesday, January 15, 2013 10:48:13 Pacific Standard Time Printed: Tuesday, January 15, 2013 11:33:51 Pacific Standard Time ID: FC-LIN-42420W500-H,, Name: FC3G_015S011 Description: 1,,15uL Date: 14-Jan-2013 Time: 22:14:36 # Name 1 PFBA 2 PFPeA 3 PFHxA 4 PFHpA 5 PFOA-1 6 PFOA-2 7 PFNA 8 PFDA 9 PFUnA 10 PFDoA 11 PFBS-1 12 PFBS-2 13 PFHxS-1 14 PFHxS-2 15 PFHxS-3 16 PFOS-1 17 PFOS-2 18 PFOSA 19 13C2-PFOA 20 13C4-PFOA 21 13C4-PFO S-1 22 13C4-PFOS-2 23 18O2-PFHxS-1 24 18O2-PFHxS-2 25 13C4-PFBA 26 13C2-PFHxA 27 13C5-PFNA 28 13C2-PFDA 29 13C2-PFDoA 30 13C2-PFOUEA IS# Trace RT 25 212.99>168.98 5.24 26 262.98 > 218.... 5.97 26 312.97> 268.98 6.34 26 362.97> 318.98 6.73 19 412.97> 368.98 7.09 19 412.97> 168.80 7.09 27 462.96 > 418.... 7.49 28 512.96 > 468.... 8.05 28 562.96 > 518.... 8.58 29 612.95 > 568.... 9.18 23 298.94> 79.96 6.49 24 298.94 > 98.95 6.47 23 398.84 > 79.96 7.33 24 398.84> 98.96 7.33 23 398.84> 118.70 7.33 21 4 98 .93 > 79.96 8.35 22 498.93> 98.96 8.35 21 498 > 78 9.99 20 414.97 > 369.... 7.09 416.97 > 371.9 7.09 30 503 > 79.96 8.35 30 503 > 98.96 8.35 30 402.9>84 7.33 30 402.9>103 7.33 30 2 1 6 .9 9 > 1 71.98 5.21 30 314.97>269.98 6.34 30 467.96>422.97 7.49 30 514.96 >469.96 7.99 30 614.95 > 569.... 9.18 458.98 >393.98 7.38 Area 2094684 2925513 4181689 4711523 4933775 1165768 5089518 6104199 7620483 9446096 1021844 526024 912450 503432 296727 1099194 759759 1222304 143912 47536 6445 5284 5162 4007 20307 40957 45876 84417 173162 18603 IS Area 20307 40957 40957 40957 143912 143912 45876 84417 84417 173162 5162 4007 5162 4007 5162 6445 5284 6445 47536 18603 18603 18603 18603 18603 18603 18603 18603 18603 ng/L 1243.976 1245.910 1248.015 1250.282 1252.684 1252.495 1247.932 1274.461 1266.699 1285.038 2507.622 2501.618 2506.565 2493.009 2517.457 2497.579 2496.000 1246.747 38.318 7.065 14.308 14.764 13.865 14.532 11.113 11.332 11.279 16.497 21.613 6.759 LOD 662.9949 0.0140 0.2056 0.1181 1.1581 1.4137 0.6197 0.0506 0.5707 0.1620 0.2414 0.0468 0.0072 0.0713 0.0745 0.0069 %Rec 99.5 99.7 99.8 100.0 100.2 100.2 99.8 102.0 101.3 102.8 100.3 100.1 100.3 99.7 100.7 99.9 99.8 99.7 106.4 58.9 79.5 82.0 77.0 80.7 92.6 94.4 94.0 137.5 180.1 67.6 S/N 5 50663 50289 91806 0 0 0 3540 7802 11577 48512 51919 0 0 0 3626 4089 10787 0 419 65 251 0 0 125 1008 4659 677 882 2944 Noise 1290144 232 416 190 0 0 0 5861 3850 3045 76 36 0 0 0 694 526 354 0 469 318 72 0 0 545 209 36 451 738 23 Height IS Height 7055448 68400 11775853 210699 20933800 210699 17456350 210699 20590308 605737 4844712 605737 18762150 169750 20749386 305304 30035668 305304 35251636 650347 3668703 17840 1877622 14336 2831564 17840 1639389 14336 934732 17840 2514590 20527 2150387 17955 3817710 20527 605737 196532 196532 20527 68997 17955 68997 17840 68997 14336 68997 68400 68997 210699 68997 169750 68997 305304 68997 650347 68997 68997 Sam ple size 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 Factor2 Detection... 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MM 1.0 MMX 1.0 MM PV by JLIU, SV by KJC 4-Jan-13. Calver conc in ng. Page 275 of 307 www.axysanalytical.com Quantify Sample Report MassLynx 4.1 SCN627 Dataset G:\Masslynx\lnst_G\PFC.PRO\FC\FC3G_015-B.qld Last Altered: Tuesday, January 15, 2013 14:23:27 Pacific Standard Time Printed: Wednesday, January 16, 2013 11:54:43 Pacific Standard Time ID: FC-LIN-42420W500-D,, Name: FC3G_015S016 Description: 1,,15uL Date: 14-Jan-2013 Time: 23:39:26 PFBA FC3G_015S016 ioo r ' 6.c08e4 ;; 256363 ; j\ tt min 5.00 6.00 7.00 PFPeA FC3G 015S016 ioo-q %~ 7.73e4 | 365329 j I; i \\ 0- ---- min 5.00 6.00 7.00 PFHxA FC3G 015S016 100- 1 ,4 2 e 5 1. 681325 %~ :. 0 5.00 6.00 7.00 PFHpA FC3G 015S016 100- 1.39e5 ), 567485 %- M 0 - -- ---------- ---- m -|n 5.00 6.00 7.00 PFOA-1 FC3G 015S016 100^ %-- h 1.52e5 ! \ 605973 / v - ... . 0- 7.00 8.00 PFNA FC3G 015S016 PFDA FC3G_015S016 100-, 7.99 [ " 1.80e5 | 651089 %i PFUnA FC3G_015S016 in n 8.58 100^ r 1-92e5 | 877365 %~ PFDoA FC3G 015S016 100- 9.18 r 2.24e5 H 940818 %- PFBS-1 FC3G 015S016 100- 6.47 4.21 e4 i 197084 i. ;1 %- ' f\ 0 V fj l PTi' i i I 8.00 10.00 Tj-rr mm 12.00 8.00 tjtt mm 10.00 12.00 0 - tt min 8.00 10.00 12.00 0 - -------------------- ......m in 5.00 6.00 7.00 PFHxS-1 FC3G__015S016 100- r 3.32e4 f \ 127638 l\ - min 7.00 8.00 PFHxS-2 FC3G 015S016 100- 1,95e4 A 74740 j %- j o7.00 \_ t min 8.00 PFHxS-3 FC3G 015S016 1001.04e4*l 38961 A %: 0 - / " .......... min 7.00 8.00 PFOS-1 FC3G 015S016 100- %- 3.28e4 I 90496 i 0 min 8.00 10.00 12,00 PFOS-2 FC3G 015S016 r 2.23e4 1 73451 % ; 8.00 10.00 12.00 o CoO o> ooI 1 PFOA-2 FC3G_015S016 100-j 7.09 : 3.65e4 ;148035 %- 07.00 8.00 PFBS-2 FC3G 015S016 100- 6.47 2.08e4 l % !\ o- ; ^ 5.00 6.00 7.00 PFOSA FC3G_015S016 9.96 100q 2.33e4 l " 79478 I; %' 8.00 10.00 12.00 PV by LEH 15-Jan-13, SV by AP 16-Jan-13. NOTE: OPR Conen. & LOD units = ng/mL, Sample and Lab BLK Conen. & LOD units = ng/L. Page 276 of 307 www.axysanalytical.com Quantify Sample Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\lnst_G\PFC.PRO\FC\FC3G_015-B.qld Last Altered: Tuesday, January 15, 2013 14:23:27 Pacific Standard Time Printed: Wednesday, January 16, 2013 11:54:43 Pacific Standard Time ID: FC-LIN-42420W500-D,, Name: FC3G_015S016 Description: 1,,15uL Date: 14-Jan-2013 Time: 23:39:26 13C2-PFOA FC3G 015S016 100- 7.09 I, 2.60e5 t \ 1067822 %- M ./ v . . 0- 7.00 -r min 8.00 13C4-PFOA FC3G 015S016 100- 7,09 JT9.03e4 fjft367569 %- 0 i/ 7.00 i 8.00 13C4-PFBA FC3G_015S016 mn 519 100^ Ir 3.54e4 158181 %- 4.03 : 05.00 6.00 7.00 13C2-PFHxA FC3G_015S016 100 6.34 7.15e4 351755 % 5.00 6.00 7.00 13C4-PFOS-1 FC3G 015S016 100- 8.35 fl.3 7 e 4 | 51452 o: rI jm'rl I . t , I I I lI I I )| t l , min 8.00 10.00 12.00 13C4-PFOS-2 FC3G 015S016 I 00! 8.35 T 1.08e4 A 41238 %" a i M 0" 8.00 10.00 min 12.00 1802-PFHxS-l FC3G 015S016 io-q 7.33 1.21e4l 47826 || %" / O-* 7.00 8.00 13C5-PFNA FC3G_015S016 7.49 100 8.04e4 A. 325964 , \ % 13C2-PFDA FC3GJ115S016 100- 7.99 9.19e4 I 321618 %- 13C2-PFDOA FC3G__015S016 100- 9.18 1.41e5 626698 %- 1802-PFHxS-2 FC3G 015S016 100- 7.33 9.22e3 36260 %- ..i 7.00 8.00 13C2-PFOUEA FC3G 015S016 7.00 8.00 8.00 10.00 12.00 8.00 10.00 12.00 PV by LEH 15-Jan-13, SV by AP 16-Jan-13. NOTE: OPR Conen. & LOD units = ng/mL, Sample and Lab BLK Conen. & LOD units = ng/L. Page 277 of 307 www.axysanalytical.com Quantify Sample Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\lnst_G\PFC.PRO\FC\FC3G_015-B.qld Last Altered: Tuesday, January 15, 2013 14:23:27 Pacific Standard Time Printed: Wednesday, January 16, 2013 11:54:43 Pacific Standard Time ID: FC-LIN-42420W500-D,, Name: FC3G_015S016 Description: 1,,15uL Date: 14-Jan-2013 Time: 23:39:26 # Name 1 PFBA 2 PFPeA 3 PFHxA 4 PFHpA 5 PFOA-1 6 PFOA-2 7 PFNA 8 PFDA 9 PFUnA 10 PFDoA 11 PFBS-1 12 PFBS-2 13 PFHxS-1 14 PFHxS-2 15 PFHxS-3 16 PFOS-1 17 PFOS-2 18 PFOSA 19 13C2-PFOA 20 13C4-PFOA 21 13C4-PFOS-1 22 13C4-PFOS-2 23 1802-PFHxS-1 24 1802-PFHxS-2 25 13C4-PFBA 26 13C2-PFHxA 27 13C5-PFNA 28 13C2-PFDA 29 13C2~PFDoA 30 13C2-PFOUEA IS# Trace RT 25 212.99>168.98 5.21 26 262.98 > 218.... 5.97 26 312.97> 268.98 6.34 26 362.97> 318.98 6.73 19 412.97> 368.98 7.09 19 412.97> 168.80 7.09 27 462.96 >4 1 8.... 7.49 28 512.96 > 468.... 7.99 28 562.96 >5 1 8..,. 8.58 29 612.95 > 568.... 9.18 23 298.94> 79.96 6.47 24 298.94 > 98.95 6.47 23 398.84 > 79.96 7.33 24 398.84> 98.96 7.33 23 398.84> 118.70 7.33 21 498.93> 79.96 8.35 22 498.93> 98.96 8.35 21 498 > 78 9.96 20 414.97 >3 6 9.... 7.09 416.97 >371.9 7.09 30 503 > 79.96 8.35 30 503 > 98.96 8.35 30 402.9>84 7.33 30 402 .9> 103 7.33 30 216.99>171.98 5.19 30 314.97>269.98 6.34 30 467.96>422.97 7.49 30 514.96 >469.96 7.99 30 614.95 >569.... 9.18 458.98 >39.3.98 7.38 Area 60827 77279 141553 139300 151530 36455 142621 180194 192089 223579 42072 20795 33160 19453 10442 32824 22329 23260 259773 90287 13657 10809 12097 9219 35388 71487 80408 91873 140527 30005 IS Area 35388 71487 71487 71487 259773 259773 80408 91873 91873 140527 12097 9219 12097 9219 12097 13657 10809 13657 90287 30005 30005 30005 30005 30005 30005 30005 30005 30005 ng/L 19.340 18.539 20.716 20.106 20.575 20.503 21.652 21.541 21.120 21.812 44.396 38.082 38.704 37.814 40.291 40.254 38.778 18.625 36.417 13.419 18.799 18.725 20.146 20.730 12.007 12.263 12.257 11.132 10.875 10.902 LOD 0.0166 0.3440 0.1133 0.0504 0.1051 0.1255 0.2935 0.0186 0.0041 0.0397 0.0379 0.1825 %Rec 96.7 92.7 103.6 100.5 102.9 102.5 108.3 107.7 105.6 109.1 111.0 95.2 96.8 94.5 100.7 100.6 96.9 93.1 101.2 111.8 104.4 104.0 111.9 115.2 100.1 102.2 102.1 92.8 90.6 109.0 S/N 718 900 1897 2255 0 0 0 614 1936 1914 3718 2023 0 0 178 352 589 807 0 798 499 421 0 0 135 2403 8945 727 946 179 Noise 357 406 359 252 0 0 0 1060 453 492 53 45 0 0 219 257 125 98 0 460 103 98 0 0 1169 146 36 442 662 679 Height 256363 365329 681325 567485 605973 148035 575991 651089 877365 940818 197084 91030 127638 74740 38961 90496 73451 79478 1067822 367569 51452 41238 47826 36260 158181 351755 325964 321618 626698 121616 IS Height Sample size 158181 351755 1.0000 1.0000 351755 351755 1067822 1067822 1.0000 1.0000 1.0000 1.0000 325964 321618 1.0000 1.0000 321618 626698 1.0000 1.0000 47826 36260 47826 1.0000 1.0000 1.0000 36260 1.0000 47826 1.0000 51452 41238 51452 1.0000 1.0000 1.0000 367569 121616 121616 121616 121616 121616 121616 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 121616 1.0000 121616 121616 1.0000 1.0000 1.0000 Factor2 Detection... 1.0 bb 1.0 bb 1.0 MM 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 MM 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 bb PV by LEH 15-Jan-13, SV byAP 16-Jan-13. NOTE: OPR Conen. & LOD units = ng/mL, Sample and Lab BLK Conen. & LOD units = ng/L. Page 278 of 307 www.axysanalytical.com Quantify Sample Report MassLynx 4.1 SCN627 Dataset: G:\Masslynx\lnst_G\PFC.PRO\FC\FC3G_015-B.qld Last Altered: Tuesday, January 15, 2013 14:23:27 Pacific Standard Time Printed; Wednesday, January 16, 2013 11:54:43 Pacific Standard Time ID: FC-LIN-42420W500-D,, Name: FC3G_015S036 Description: 1,,15uL Date: 15-Jan-2013 Time: 05:18:50 PFBA FC3G 015S036 100- 5.23 r 6.23e4 | 270678 %- o - iT min 5.00 6.00 7.00 PFPeA FC3G 015S036 100- 5.95 7.43e4 342135 1 : %- 0 - ...i- 5.00 6.00 7.00 PFNA FC3G 015S036 PFDA FC3G_015S036 mr> 7 -99 100 f 1.67e5 [| 610139 PFHxS-1 FC3G 015S036 8.00 10.00 12.00 PFHxS-2 FC3G_015S036 100- 7.33 1.84e4 A .71183 ; \ %- 7.00 8.00 PFHxA FC3G 015S036 100- 6.36 1 .3 7 e 5 l 636877 %- : ; \;! 0 - min 5.00 6.00 7.00 PFHpA FC3G 015S036 100^ 6.73 1.38e5 h 571581 M %-- M \\ CH...... - - min 5.00 6.00 7.00 PFOA-1 FC3G 015S036 100-, - 7.14 A 1.39e5 / ; 546704 %- o- TTf 7.00 i min 8.00 PFOA-2 FC3G 015S036 too- 7.14 a 3.37e4 / \ 134999 %- } 0- ' ...... 7.00 8.00 PFUnA FC3G_015S036 100- _ 8.52 1.81e5 804510 %' PFDoA FC3G_015S036 100- 9.12 2.21 e5 i 965190 %- PFBS-1 FC3G 015S036 100- 6.47 3.76e4 1 169036 h % - \\ PFBS-2 FC3G_015S036 100-q 6.49 1.95e4 85942 8.00 10.00 12.00 8.00 10.00 12.00 o: min 5.00 6.00 7.00 o: 5.00 6.00 7.00 PFHxS-3 FC3G_015S036 10 0 n- 1 7.33 .04e4 A : 39987 1 %- , 7.00 8.00 PFOS-1 FC3G_015S036 100- 8.29 r 3.31 e4 M 98019 % ;i \ 8.00 10.00 min 12.00 PFOS-2 FC3G__015SQ36 100- 8.29 Ii 2.31 e4 81004 08.00 10.00 12.00 PFOSA FC3G_015S036 9.96 100n 2.24e4~) 76289 1 %- 8.00 10.00 12,00 PV by LEH 15~Jan~13, SV by AP 16-Jan~13. NOTE: OPR Conen. & LOD units = ng/mL, Sample and Lab BLK Conen. & LOD units = ng/L. Page 279 of 307 www.axysanalytical.com Quantify Sample Report MassLynx 4.1 SCN627 Dataset: G :\M a s s ly n x \ln s tJ 3 \P F C .P R O \F C \F C 3 G _ 0 1 5-B.qld Last Altered: Tuesday, January 15, 2013 14:23:27 Pacific Standard Time Printed: Wednesday, January 16, 2013 11:54:43 Pacific Standard Time ID: FC-LIN-42420W500-D,, Name: FC3G_015S036 Description: 1,,15uL Date: 15-Jan-2013 Time: 05:18:50 13C2-PFOA FC3G 015S036 100- 7.14 f f 2.46e5 1992812 %: / o- ' 7.00 - min 8.00 13C4-PFOA FC3G 015S036 100- 7.09 f 8.69e4 g|352889 % 07.00 . ~rr min 8.00 13C4-PFOS-1 FC3G 015S036 100- 8.29 ri.3 3 e 4 50333 %. 0 - ;V 8.00 10.00 12.00 13C4-PFBA FC3G_015S036 100^ _ 5.21 ! 3.50e4 144745 5.00 6.00 7.0 1302-PFHxA FC3G__015S036 100- 6.36 7.17e4 332503 %: :\ ... ---- 5.00 6.00 7.00 13C5-PFNA FC3G_015S036 100-, 7.49 8.16e4 322312 : s %- 7.00 8.00 13C4-PFOS-2 FC3G 015S036 100m 8.29 r 1-05e4 : | 40542 %- 8.00 10.00 12.00 13C2-PFDA FC3G_015S036 mn 7" 1001 T8.91e4 M1 335265 %- I 8.00 10.00 12.00 1802-PFHxS-l FC3G 01SS036 100- 7.33 1.14e4"l 45094 J j / 7.00 .. 8.00 13C2-PFDoA FC3G_015S036 100- 9.12 f 1.35e5 I 604215 %- S 8.00 10.00 12.00 1802-PFHxS-2 FC3G 015S036 100-: 7.33 8.57e3 ' l 36796 y % j 07.00 8.00 13C2-PFOUEA FC3G 015S036 PV by LEH 15-Jan-13, SV by AP 16-Jan-13. NOTE: OPR Concn. & LOD units = ng/mL, Sample and Lab BLK Concn. & LOD units = ng/L. Page 280 of 307 www.axysanalytical.com Quantify Sample Report MassLynx 4,1 SCN627 Dataset: G:\Masslynx\lnst_G\PFC.PRO\FC\FC3G_015-B.qld Last Altered: Tuesday, January 15, 2013 14:23:27 Pacific Standard Time Printed: Wednesday, January 16, 2013 11:54:43 Pacific Standard Time ID: FC-LIN-42420W500-D,, Name: FC3G_015S036 Description: 1,,15uL Date: 15-Jan-2013 Time: 05:18:50 # Name 1 PFBA 2 PFPeA 3 PFHxA 4 PFHpA 5 PFOA-1 6 PFOA-2 7 PFNA 8 PFDA 9 PFUnA 10 PFDoA 11 PFBS-1 12 PFBS-2 13 PFHxS-1 14 PFHxS-2 15 PFHxS-3 16 PFOS-1 17 PFOS-2 18 PFOSA 19 13C2-PFOA 20 13C4-PFOA 21 13C4-PFOS-1 22 13C4-PFOS-2 23 1802-PFHxS-1 24 1802-PFHxS-2 25 13C4-PFBA 26 13C2-PFHxA 27 13C5-PFNA 28 13C2-PFDA 29 13C2-PFDoA 30 13C2-PFOUEA IS# Trace RT 25 212.99>168.98 5.23 26 262.98 >2 1 8.... 5.95 26 312.97> 268.98 6.36 26 362.97> 318.98 6.73 19 412.97> 368.98 7.14 19 412.97> 168.80 7.14 27 462.96 >4 1 8.... 7.49 28 512.96 >4 6 8.... 7.99 28 562.96 >5 1 8.... 8.52 29 612.95 > 568.... 9.12 23 298 .94> 79.96 6.47 24 298.94 > 98.95 6.49 23 398.84 > 79.96 7.33 24 398.84> 98.96 7.33 23 398.84> 118.70 7.33 21 498.93> 79.96 8.29 22 498.93> 98.96 8.29 21 498 > 78 9.96 20 414.97 > 369.... 7.14 416.97 >371.9 7.09 30 503 > 79.96 8.29 30 503 > 98.96 8.29 30 402.9>84 7.33 30 402.9>103 7.33 30 216-99>171.98 5.21 30 314.97>269.98 6.36 30 467.96>422.97 7:49 30 514.96 >469.96 7.99 30 614.95 >5 6 9.... 9.12 458.98 >393.98 7.43 Area 62286 74317 136909 138060 138521 33685 140347 167398 181101 220724 37596 19490 34126 18425 10440 33084 23090 22377 245538 86950 13292 10504 11395 8567 34986 71704 81559 89071 135341 30547 IS Area 34986 71704 71704 71704 245538 245538 81559 89071 89071 135341 11395 8567 11395 8567 11395 13292 10504 13292 86950 30547 30547 30547 30547 30547 30547 30547 30547 30547 ng/L 20.039 17.773 19.966 19.865 19.890 20.040 21.002 20.617 20.528 22.370 42.087 38.412 42.337 38.544 42.778 41.705 41.276 18.413 35.742 12.923 17.971 17.874 18.641 18.922 11.660 12.082 12.211 10.601 10.288 11.099 LOD 0.0058 0.0116 0.0791 0.0816 0.0247 0.0219 0.0782 0.1182 0.3104 1.1940 0.0248 0.0031 0.0515 0.0485 %Rec 100.2 88.9 99.8 99.3 99.5 100.2 105.0 103.1 102.6 111.9 105.2 96.0 105.8 96.4 106.9 104.3 103.2 92.1 99.3 107.7 99.8 99.3 103.6 105.1 97.2 100.7 101.8 88.3 85.7 111.0 S/N 1273 1090 3287 2428 0 0 0 962 1638 2358 7185 2455 8257 991 2241 994 346 1591 4321 1774 670 449 0 196 31 1739 11832 597 729 0 Noise 213 314 194 235 0 0 0 634 491 409 24 35 16 72 18 99 234 48 230 199 75 90 0 183 4654 191 27 562 829 0 Height 270678 342135 636877 571581 546704 134999 571240 610139 804510 965190 169036 85942 131746 71183 39987 98019 81004 76289 992812 352889 50333 40542 45094 35796 144745 332503 322312 335265 604215 119051 IS Height Sample size 144745 332503 332503 332503 992812 992812 322312 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 335265 335265 604215 1.0000 1.0000 1.0000 45094 35796 45094 35796 1.0000 1.0000 1.0000 1.0000 45094 1.0000 50333 40542 50333 352889 1.0000 1.0000 1.0000 1.0000 119051 1.0000 1.0000 119051 1.0000 119051 119051 119051 119051 119051 1.0000 1.0000 1.0000 1.0000 1.0000 119051 119051 1.0000 1.0000 1.0000 Factor2 Detection... 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 MM 1.0 bb 1.0 bb 1.0 bb 1.0 bb . 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 bb 1.0 bb PV by LEH 15-Jan-13, SV byAP 16-Jan-13. NOTE: OPR Conen. & LOD units = ng/mL, Sample and Lab BLK Conen. & LOD units = ng/L. Page 281 of 307 www.axysanalytical.com Matrix Codes for Table 1a NPW = Non-Potable Water DrW = Drinking Water S = Solid T = Tissue AXYS Analytical Services Ltd. Table 1a NELAP A ccredita tion Held by AXYS A nalytical Services Ltd. fo r Chlorinated Dioxins/Furans, Chlorinated Pesticides, PCBs and PAHs Accreditation Method Codes and Explanation for Table 1a Code No. Accreditation Certificate Applicable A X Y S Method and Description Method Reference 1 EPA 1613B MLA-017, performance based implementation of EPA1613B (G C /H R M S ) 2 EPA 8290 MLA-017, performance based implementation of EPA 8290 (G c /H R M S ) 3 AXYS MLA-017 MLA-017, performance based implementation of EPA 1613B, 8290 (G C /H R M S ) 4 EPA 608 MLA-007, performance based implementation of EPA 608 (G C /EC D ) 5 EPA 8270C or 8270D MLA-007, performance based modification of 8270C /D (G C /LR M S ) 6 E P A 8081Aor8081B MLA-007, performance based implementation of EPA 8 0 8 1 A/B (G C /E C D ) 7 EPA 1668A MLA-010, performance based implementation of EPA 1668A (G C /H R M S ) 8 SM 6630B MLA-007, performance based implementation of SM 18-20 6630B (G C /EC D ) 9 EPA 1625B MLA-021, performance based modification of EPA 1625B (G C /LR M S ) 11 EPA 625 MLA-007, performance based modification of EPA 625 (g C /LR M S) 20 EPA 8270C or 8270D MLA-021, performance based modification of EPA 82 70 C /D (G C /LR M S ) 21 EPA 1625B MLA-007, performance based modification of EPA 1625B (G C /LR M S ) ACC-101 Rev 08, 08-Nov-2012 P ^ e r o J l Page 282 of 307 www.axysanalytical.com TABLE 1a PCDD/F - Polychlorinated Dioxins and Furans Dioxins Dioxins and Dibenzofurans 1,2,3,4,6,7,8-HpCDD 1,2,3,4,6,7,8-HpCDF 1,2,3,4,7,8,9-HpCDF 1,2,3,4,7,8-HxCDD 1,2,3,4,7,8-HxCDF 1,2,3,6,7,8-HxCDD 1,2,3,6,7,8-HxCDF 1,2,3,7,8,9-HxCDD 1,2,3,7,8,9-HxCDF 1,2,3,7,8-PeCDD 1,2,3,7,8-PeCDF 2,3,4,6,7,8-HxCDF 2,3,4,7,8-PeCDF 2,3,7,8-TCDD 2,3,7,8-TCDF OCDD OCDF Total TCDD Total TCDF Total PeCDD Total PeCDF Total HxCDD Total HxCDF Total HpCDD Total HpCDF PCBs - Polychlorinated biphenyls PCB 1 2-Chlorobiphenyl PCB 3 4-Chlorobiphenyl PCB 4 2,2'-Dichlorobiphenyl PCB 5 2,3-Dichlorobiphenyl PCB 15 4,4'-Dichlorobiphenyl ACC-101 Rev 08, 08-Nov-2012 AXYS Analytical Services Ltd. New York State Department of Health Lab ID 11674 NELAP Primary NP W S California Department of Public Health Lab ID 01138CA NELAP Secondary NP W S 1 2 12 12 12 12 12 12 12 12 12 12 12 12 12 1 12 12 12 12 1 1 1 1 1 1 1 1 State of Florida Department of Health Lab ID E871007 NELAP Primary Dr. NP WW S T 1, 2, 3 1, 2, 3 1, 2, 3 1, 2, 3 1, 2, 3 1, 2, 3 1, 2, 3 1, 2, 3 1, 2, 3 1, 2, 3 1, 2, 3 1, 2, 3 1, 2, 3 1, 2, 3 1, 2, 3 1, 2, 3 1, 2, 3 1, 2, 3 1, 2, 3 1, 2, 3 1, 2, 3 1, 2, 3 1, 2, 3 1, 2, 3 1, 2, 3 2, 3 2, 3 2, 3 2, 3 2, 3 2, 3 2, 3 2, 3 2, 3 2, 3 2, 3 2, 3 2, 3 2, 3 2, 3 2, 3 2, 3 2, 3 2, 3 2, 3 2, 3 2, 3 2, 3 2, 3 2, 3 2, 3 2, 3 2, 3 2, 3 2, 3 2, 3 2, 3 2, 3 2, 3 2, 3 2, 3 2, 3 2, 3 2, 3 2, 3 2, 3 2, 3 2, 3 2, 3 2, 3 2, 3 2, 3 2, 3 2, 3 2, 3 State of New Jersey Department of Environmental Protection Lab ID CANA005 NELAP Secondary Dr. NP WW S T 122 122 122 122 122 122 122 122 122 122 122 122 122 122 122 122 122 22 22 22 22 22 22 22 22 Virginia Division of Consolidated Laboratory Services Lab ID 460224 NELAP Secondary NP W S T 1, 2 2 1, 2 2 1, 2 2 1, 2 2 1, 2 2 1, 2 2 1, 2 2 1, 2 2 1, 2 2 1, 2 2 1, 2 2 1, 2 2 1, 2 2 1, 2 2 1, 2 2 1, 2 2 1, 2 2 22 22 22 22 22 22 22 22 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 P39e2oJl Page 283 of 307 www.axysanalytical.com TABLE 1a PCB 18 PCB 19 PCB 31 PCB 37 PCB 44 PCB 52 PCB 54 PCB 66 PCB 77 PCB 81 PCB 87 PCB 101 PCB 104 PCB 105 PCB 109 PCB 114 PCB 118 PCB 123 PCB 124 PCB 126 PCB 138 PCB 141 PCB 151 PCB 153 PCB 155 PCB 156 PCB 157 PCB 167 PCB 169 PCB 170 PCB 180 PCB 183 PCB 187 PCB 188 PCB 189 PCB 202 2,2 ',5-T richlorobiphenyl 2,2 ',6-T richlorobiphenyl 2,4',5-Trichlorobiphenyl 3,4,4'-Trichlorobiphenyl 2,2',3,5'-Tetrachlorobiphenyl 2,2',5,5'-Tetrachlorobiphenyl 2,2',6,6'-Tetrachlorobiphenyl 2,3',4,4'-Tetrachlorobiphenyl 3,3',4,4'-Tetrachlorobiphenyl 3,4,4',5-Tetrachlorobiphenyl 2,2',3,4,5'-Pentachlorobiphenyl 2,2',4,5,5'-Pentachlorobiphenyl 2,2',4,6,6'-Pentachlorobiphenyl 2,3,3',4,4'-Pentachlorobiphenyl 2,3,3',4,6-Pentachlorobiphenyl 2,3,4,4',5-Pentachlorobiphenyl 2,3',4,4',5-Pentachlorobiphenyl 2,3',4,4',5'-Pentachlorobiphenyl 2,3',4',5,5'-Pentachlorobiphenyl 3,3',4,4',5-Pentachlorobiphenyl 2,2',3,4,4',5'-Hexachlorobiphenyl 2,2',3,4,5,5'-Hexachlorobiphenyl 2,2',3,5,5',6-Hexachlorobiphenyl 2,2',4,4',5,5'-Hexachlorobiphenyl 2,2',4,4',6,6'-Hexachlorobiphenyl 2,3,3',4,4',5-Hexachlorobiphenyl 2,3,3',4,4',5'-Hexachlorobiphenyl 2,3',4,4',5,5'-Hexachlorobiphenyl 3,3',4,4',5,5'-Hexachlorobiphenyl 2,2',3,3',4,4',5-Heptachlorobiphenyl 2,2',3,4,4',5,5'-Heptachlorobiphenyl 2,2',3,4,4',5',6-Heptachlorobiphenyl 2,2',3,4',5,5',6-Heptachlorobiphenyl 2,2',3,4',5,6,6'-Heptachlorobiphenyl 2,3,3',4,4',5,5'-Heptachlorobiphenyl 2,2',3,3',5,5',6,6'-Octachlorobiphenyl ACC-101 Rev 08, 08-Nov-2012 AXYS Analytical Services Ltd. New York State D ep artm en t of Health Lab ID 11674 NELAP Primary NP S W 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 C a lifo rn ia D ep artm en t of Public Health Lab ID 01138CA NELAP Secondary NP S W State of Florida D ep artm en t of Health Lab ID E871007 NELAP Primary Dr. NP WW S T 77 77 77 77 77 77 7 77 77 77 77 77 77 77 77 77 77 State of New Jersey Departm ent of E n v iro n m e n ta l Protection Lab ID CANA005 NELAP Secondary Dr. NP WW 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 S 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 T Virginia Division of Consolidated Laboratory Services Lab ID 460224 NELAP Secondary NP S W 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 77 7 77 77 77 77 77 77 77 77 77 77 T Page 284 of 307 www.axysanalytical.com AXYS Analytical Services Ltd. TABLE 1a PCB 205 PCB 206 PCB 208 PCB 209 Aroclor 1260 Aroclor 1254 Aroclor 1221 Aroclor 1232 Aroclor 1248 Aroclor 1016 Aroclor 1242 2,3,3',4,4',5,5',6-Octachlorobiphenyl 2,2',3,3',4,4',5,5',6-Nonachlorobiphenyl 2,2',3,3',4,5,5',6,6'-Nonachlorobiphenyl Decachlorobiphenyl Pesticides 4,4'-DDD 4,4'-DDE 4,4'-DDT Aldrin Alpha-HCH Beta-HCH cis-Chlordane (alpha-Chlordane) Chlordane, technical Delta-HCH Dieldrin Endosulphan I Endosulphan II Endosulphan sulphate Endrin Endrin aldehyde trans-Chlordane (gamma-Chlordane) Gamma-HCH (Lindane) Heptachlor Heptachlor epoxide Hexachlorobenzene Methoxychlor Mi rex New York State D ep artm en t of Health Lab ID 11674 NELAP Primary NP S W 7 7 7 7 7, 11 7, 11 7, 11 7, 11 7, 11 7, 11 7, 11 7 7 7 7 5, 7 5, 7 5, 7 5, 7 5, 7 5, 7 5, 7 C a lifo rn ia D ep artm en t of Public Health Lab ID 01138CA NELAP Secondary NP S W 11 5 11 5 11 5 11 5 11 5 11 5 11 5 State of Florida D ep artm en t of Health Lab ID E871007 NELAP Primary Dr. NP WW S T 11 5 11 5 11 5 11 5 11 5 11 5 11 5 11 5 11 5 11 5 11 5 11 5 55 5, 11 5 11 5 11 5 11 5 4646 4646 4646 4646 4646 4646 55 11 5 11 5 11 5 11 5 4646 21 5 9 5 4, 8 6 8 6 5 ACC-101 Rev 08, 08-Nov-2012 State of New Jersey Departm ent of E n v iro n m e n ta l Protection Lab ID CANA005 NELAP Secondary Dr. NP WW 7 7 7 7 S 7 7 7 7 T Virginia Division of Consolidated Laboratory Services Lab ID 460224 NELAP Secondary NP S W 77 77 77 77 11 5 11 5 11 5 11 5 11 5 11 5 11 5 T 11 11 11 11 11 11 5, 11 11 4 4 4 4 4 4 11 11 4 4 5 5 5 5 5 5 5 5 5 6 6 6 6 6 6 5 5 6 5 6 P,ge4 oJl Page 285 of 307 www.axysanalytical.com TABLE 1a PAH Anthracene Pyrene Benzo[ghilperylene Indeno[1,2,3-cdlpyrene Benzo[blfluoranthene Fluoranthene Benzo[k]fluoranthene Acenaphthylene Chrysene Benzo[a]pyrene Dibenz[ahlanthracene Benz[alanthracene Acenaphthene Phenanthrene Fluorene Naphthalene AXYS Analytical Services Ltd. New York State D ep artm en t of Health Lab ID 11674 NELAP Primary NP S W C a lifo rn ia D ep artm en t of Public Health Lab ID 01138CA NELAP Secondary NP S W State of Florida D ep artm en t of Health Lab ID E871007 NELAP Primary Dr. NP WW S T 9 20 9 20 9 20 9 20 9 20 9 20 9 9 20 9 20 9 20 9 20 9 20 9 20 9 20 9 20 9 20 9 20 9 20 9 20 9 20 9 20 9 20 9 9 20 9 20 9 20 9 20 9 20 9 20 9 20 9 20 9 20 State of New Jersey Departm ent of E n v iro n m e n ta l Protection Lab ID CANA005 NELAP Secondary Dr. NP WW S T Virginia Division of Consolidated Laboratory Services Lab ID 460224 NELAP Secondary NP S W T 9 20 9 20 9 20 9 20 9 20 9 20 9 9 20 9 20 9 20 9 20 9 20 9 20 9 20 9 20 9 20 ACC-101 Rev 08, 08-Nov-2012 Pa9e 5 o J l Page 286 of 307 www.axysanalytical.com AXYS Analytical Services Ltd. Matrix Codes for Table 1b NPW = Non-Potable Water DrW = Drinking Water S = Solid T = Tissue Table 1b NELAP A ccredita tion Held by AXYS A nalytical Services Ltd. fo r Perfluorinated O rganic Compounds Accreditation Method Codes and Explanation for Table 1b Code Accreditation Certificate Applicable AXYS Method and Description No. Method Reference 12 AXYS MLA-041 13 AXYS MLA-043 14 AXYS MLA-060 MLA-041, laboratory performance based method (LC/MS-MS) MLA-043, laboratory performance based method (LC/MS-MS) MLA-060, laboratory performance based method (LC/MS-MS) TABLE 1b State of Florida Department of Health Lab ID E871007 NELAP Primary Dr. NP S WW T Minnesota Department of Health Lab ID 232-999-430 NELAP Primary! Dr. NP S T WW State of New Jersey Department of Environmental Protection Lab ID CANA005 NELAP Secondary Dr. NP S T WW PFC - Perfluorinated Organic Compounds Perfluorobutanoate (PFBA) Note Perfluoropentanoate (PFPeA) Note Perfluorohexanoate (PFHxA) Note Perfluoroheptanoate (PFHpA) Note Perfluorooctanoate (PFOA) Note Perfluorononanoate (PFNA) Note Perfluorodecanoate (PFDA) Note Perfluoroundecanoate (PFUnA) Note Perfluorododecanoate (PFDoA) Note Perfluorobutanesulfonate (PFBS) Perfluorohexanesulfonate (PFHxS) Perfluorooctanesulfonate (PFOS) Perfluorooctane sulfonamide (PFOSA) 14 14 12 13 14 14 12 13 14 14 12 13 14 14 12 13 14 14 12 13 14 14 12 13 14 14 12 13 14 14 12 13 14 14 12 13 14 14 12 13 14 14 12 13 14 14 12 13 14 14 12 13 14 14 12 13 14 14 12 13 14 14 12 13 14 14 12 13 14 14 12 13 14 14 12 13 14 14 12 13 14 14 12 13 14 14 12 13 14 14 12 13 14 14 12 13 14 14 12 13 14 14 12 13 14 14 12 13 14 14 12 13 14 14 12 13 14 14 12 13 14 14 12 13 14 14 12 13 14 14 12 13 14 14 12 13 14 14 12 13 14 14 12 13 14 14 12 13 14 14 12 13 Note: Accreditations by Minnesota Department of Health and New Jersey Department of Environmental Protection are against the corresponding acid form of the anion shown. ACC-101 Rev 08, 08-Nov-2012 Page6ofC ^ Page 287 of 307 www.axysanalytical.com AXYS Analytical Services Ltd. Table 2: Canadian and US State Specific A ccredita tion Held by AXYS A nalytical Services Ltd. Matrix Codes for Table 2 NP W = Non-Potable Water Dr. W = Drinking Water W = Aqueous S = Solid T = Tissue Ser = Serum/Plasma U = Urine Accreditation Method Codes and Explanation for Table 2 Code No. Accreditation Certificate Method Reference Applicable A X Y S Method and Description 1 EPA 1613 3 AXYS MLA-017 7 EPA 1668A 10 A XYS MLA-007 12 A XYS MLA-041 13 A XYS MLA-043 14 A XYS MLA-060 15 A XYS MLA-010 16 A XYS MLA-028 17 A XYS MLA-033 18 A XYS MLA-021 19 A XYS MLA-075 22 AXYS MLA-901 23 AXYS MLA-042 24 AXYS MLA-070 25 AXYS MLA-079 26 AXYS MLA-059 27 AXYS MLA-064 28 EPA 1668C 29 AXYS MLA-021 MLA-017 Performance based implementation of EPA 1613B (G C /H R M S ) MLA-017 Performance based implementation of EPA 1613B (g C /H R M s ) MLA-010 Performance based implementation of EPA 1668A (g C /H R M s ) M LA-007 Performance based modification of EPA 8270C /D , 8081A/B (G C /LR M S and G C /E C D ) MLA-041 Laboratory performance based method (LC/M S-M S) MLA-043 Laboratory performance based method (LC/M S-M S) MLA-060 Laboratory performance based method (LC/M S-M S) MLA-010 Performance based implementation of EPA 1668A (G C /H R M S ) MLA-028 Laboratory performance based method (G C /H R M S) MLA-033 Performance based implementation of EPA 1614 (G c /H R M S ) MLA-021 Performance based modification of EPA 82 70 C /D (G C /LR M S ) MLA-075 Performance based implementation of EPA 1694 (LC /M S-M S ) MLA-901 Laboratory performance based method (G C/LR M S) MLA-042 Laboratory performance based method (LC/M S-M S) MLA-070 Laboratory performance based method (LC/M S-M S) MLA-079 Laboratory performance based method (LC/M S-M S) MLA-059 Laboratory performance based method (LC/M S-M S) MLA-064 Laboratory performance based method (LC/M S-M S) MLA-010 Performance based implementation of EPA 1668C (G C /H R M S ) MLA-021 Performance based modification of EPA 1625 (G C /LR M S ) ACC-101 Rev 08, 08-Nov-2012 Pa9e 7 o J l Page 288 of 307 www.axysanalytical.com TABLE 2 PCDD/F - Polychlorinated Dioxins and Furans 1 ,2 ,3 ,4 ,6 ,7 ,8 -H p C D D 1 ,2 ,3 ,4 ,6 ,7 ,8 -H p C D F 1 ,2 ,3 ,4 ,7 ,8 ,9 -H p C D F 1 ,2 ,3 ,4 ,7 ,8 -H x C D D 1 ,2 ,3 ,4 ,7 ,8 -H x C D F 1 ,2 ,3 ,6 ,7 ,8 -H x C D D 1 ,2 ,3 ,6 ,7 ,8 -H x C D F 1 ,2 ,3 ,7 ,8 ,9 -H x C D D 1 ,2 ,3 ,7 ,8 ,9 -H x C D F 1 ,2 ,3 ,7 ,8 -P e C D D 1,2 ,3 ,7 ,8 -P e C D F 2 ,3 ,4 ,6 ,7 ,8 -H x C D F 2,3 ,4 ,7 ,8 -P e C D F 2 ,3 ,7 ,8 -T C D D 2 ,3 ,7 ,8 -T C D F OCDD OCDF PCBs - Polychlorinated biphenyls PCB 1 2-Chlorobiphenyl PCB 2 3-Chlorobiphenyl PCB 3 4-Chlorobiphenyl PCB 4 2,2'-Dichlorobiphenyl PCB 5 2,3-Dichlorobiphenyl PCB 6 2,3'-Dichlorobiphenyl PCB 7 2,4-Dichlorobiphenyl PCB 8 2,4'-Dichlorobiphenyl PCB 8/5 PCB 9 2,5-Dichlorobiphenyl PCB 10 2,6-Dichlorobiphenyl PCB 11 3,3'-Dichlorobiphenyl PCB 12 3,4-Dichlorobiphenyl PCB 13 3,4'-Dichlorobiphenyl PCB 14 3,5-Dichlorobiphenyl ACC-101 Rev 08, 08-Nov-2012 AXYS Analytical Services Ltd. Canadian Association for Laboratory Accreditation (CALA) Washington State Department of Ecology Accreditation no.: A 2637 Lab. ID: C404 W S Pulp T Ser U NP S W 33333 33333 33333 33333 33333 33333 33333 33333 33333 33333 33333 33333 33333 33333 33333 33333 33333 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 10 10 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 10 15 15 15 15 15 15 15 15 15 15 15 15 28 28 28 28 28 28 28 28 28 28 28 28 28 28 28 28 28 28 28 28 28 28 28 28 28 28 28 28 P39eSoJl Page 289 of 307 www.axysanalytical.com TABLE 2 PCB 15 4,4'-Dichlorobiphenyl PCB 16 2,2',3-T richlorobiphenyl PCB 16/32 PCB 17 2,2 ',4-T richlorobiphenyl PCB 18 2,2',5-Trichlorobiphenyl PCB 19 2,2 ',6-T richlorobiphenyl PCB 20 2,3,3'-Trichlorobiphenyl PCB 21 2,3,4-T richlorobiphenyl PCB 22 2,3,4'-Trichlorobiphenyl PCB 23 2,3 ,5 -T richlorobiphenyl PCB 24 2,3 ,6 -T richlorobiphenyl PCB 24/27 PCB 25 2,3 ',4-T richlorobiphenyl PCB 26 2,3',5-Trichlorobiphenyl PCB 27 2,3',6-Trichlorobiphenyl PCB 28 2,4,4'-Trichlorobiphenyl PCB 29 2,4 ,5 -T richlorobiphenyl PCB 30 2,4 ,6 -T richlorobiphenyl PCB 31 2,4',5-Trichlorobiphenyl PCB 32 2,4',6-Trichlorobiphenyl PCB 33 2,3',4'-Trichlorobiphenyl PCB 33/20/21 PCB 34 2,3',5'-Trichlorobiphenyl PCB 35 3,3',4-Trichlorobiphenyl PCB 36 3,3',5-Trichlorobiphenyl PCB 37 3,4,4'-Trichlorobiphenyl PCB 38 3,4,5-T richlorobiphenyl PCB 39 3,4',5-Trichlorobiphenyl PCB 40 2,2',3,3'-Tetrachlorobiphenyl PCB 41 2,2',3,4-Tetrachlorobiphenyl PCB 41/71/64/68 PCB 42 2,2',3,4'-Tetrachlorobiphenyl PCB 42/59 PCB 43 2,2',3,5-Tetrachlorobiphenyl PCB 44 2,2',3,5'-Tetrachlorobiphenyl ACC-101 Rev 08, 08-Nov-2012 AXYS Analytical Services Ltd. Canadian Association for Laboratory Accreditation (CALA) Accreditation no.: A 2637 W S Pulp T Ser 10, 15 15 10 10, 15 10, 15 10, 15 15 15 10, 15 15 15 10 10, 15 10, 15 15 10, 15 15 15 10, 15 15 15 18 15 15 15 15 15 15 10, 15 15 10 15 10 15 10, 15 10, 15 15 10 10, 15 10, 15 10, 15 15 15 10, 15 15 15 10 10, 15 10, 15 15 10, 15 15 15 10, 15 15 15 10 15 15 15 15 15 15 10, 15 15 10 15 10 15 10, 15 10, 15 15 10 10, 15 10, 15 10, 15 15 15 10, 15 15 15 10 10, 15 10, 15 15 10, 15 15 15 10, 15 15 15 10 15 15 15 15 15 15 10, 15 15 10 15 10 15 10, 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 Washington State Department of Ecology Lab. ID: C404 U NP S W 28 28 28 28 28 28 28 28 28 28 28 28 28 28 28 28 28 28 28 28 28 28 28 28 28 28 28 28 28 28 28 28 28 28 28 28 28 28 28 28 28 28 28 28 28 28 28 28 28 28 28 28 28 28 28 28 28 28 28 28 P39e9oJ l Page 290 of 307 www.axysanalytical.com TABLE 2 PCB 45 PCB 46 PCB 47 PCB 47/48/75 PCB 48 PCB 49 PCB 49/43 PCB 50 PCB 51 PCB 52 PCB 52/73 PCB 53 PCB 54 PCB 55 PCB 56 PCB 56/60 PCB 57 PCB 58 PCB 59 PCB 60 PCB 61 PCB 62 PCB 63 PCB 64 PCB 65 PCB 66 PCB 66/80 PCB 67 PCB 68 PCB 69 PCB 70 PCB 70/76 PCB 71 PCB 72 PCB 73 2,2',3,6-Tetrachlorobiphenyl 2,2',3,6'-Tetrachlorobiphenyl 2,2',4,4'-Tetrachlorobiphenyl 2,2',4,5-Tetrachlorobiphenyl 2,2',4,5'-Tetrachlorobiphenyl 2,2',4,6-Tetrachlorobiphenyl 2,2',4,6'-Tetrachlorobiphenyl 2,2',5,5'-Tetrachlorobiphenyl 2,2',5,6'-Tetrachlorobiphenyl 2,2',6,6'-Tetrachlorobiphenyl 2,3,3',4-Tetrachlorobiphenyl 2,3,3',4'-Tetrachlorobiphenyl 2,3,3',5-Tetrachlorobiphenyl 2,3,3',5'-Tetrachlorobiphenyl 2,3,3',6-Tetrachlorobiphenyl 2,3,4,4'-Tetrachlorobiphenyl 2,3,4,5-Tetrachlorobiphenyl 2,3,4,6-Tetrachlorobiphenyl 2,3,4',5-Tetrachlorobiphenyl 2,3,4',6-Tetrachlorobiphenyl 2,3,5,6-Tetrachlorobiphenyl 2,3',4,4'-Tetrachlorobiphenyl 2,3',4,5-Tetrachlorobiphenyl 2,3',4,5'-Tetrachlorobiphenyl 2,3',4,6-Tetrachlorobiphenyl 2,3',4',5-Tetrachlorobiphenyl 2,3',4',6-Tetrachlorobiphenyl 2,3',5,5'-Tetrachlorobiphenyl 2,3',5',6-Tetrachlorobiphenyl ACC-101 Rev 08, 08-Nov-2012 AXYS Analytical Services Ltd. Canadian Association for Laboratory Accreditation (CALA) Accreditation no.: A 2637 W S Pulp T Ser 10, 15 10, 15 15 10 15 15 10 15 15 15 10 15 15 15 15 10 15 15 15 15 15 15 15 15 15 15 10 15 15 15 15 10 15 15 15 10, 15 10, 15 15 10 15 15 10 15 15 15 10 15 15 15 15 10 15 15 15 15 15 15 15 15 15 15 10 15 15 15 15 10 15 15 15 10, 15 10, 15 15 10 15 15 10 15 15 15 10 15 15 15 15 10 15 15 15 15 15 15 15 15 15 15 10 15 15 15 15 10 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 Washington State Department of Ecology Lab. ID: C404 U NP S W 28 28 28 28 28 28 28 28 28 28 28 28 28 28 28 28 28 28 28 28 28 28 28 28 28 28 28 28 28 28 28 28 28 28 28 28 28 28 28 28 28 28 28 28 28 28 28 28 28 28 28 28 28 28 28 28 28 28 Page 10 o f-mJ Page 291 of 307 www.axysanalytical.com TABLE 2 PCB 74 PCB 74/61 PCB 75 PCB 76 PCB 77 PCB 78 PCB 79 PCB 80 PCB 81 PCB 82 PCB 83 PCB 83/108 PCB 84 PCB 85 PCB 85/120 PCB 86 PCB 87 PCB 87/115/116 PCB 88 PCB 89 PCB 90 PCB 91 PCB 92 PCB 93 PCB 94 PCB 95 PCB 95/93 PCB 96 PCB 97 PCB 97/86 PCB 98 PCB 99 PCB 100 PCB 101 PCB 101/90/89 2,4,4',5-Tetrachlorobiphenyl 2,4,4',6-Tetrachlorobiphenyl 2,3',4',5'-Tetrachlorobiphenyl 3,3',4,4'-Tetrachlorobiphenyl 3,3',4,5-Tetrachlorobiphenyl 3,3',4,5'-Tetrachlorobiphenyl 3,3',5,5'-Tetrachlorobiphenyl 3,4,4',5-Tetrachlorobiphenyl 2,2',3,3',4-Pentachlorobiphenyl 2,2',3,3',5-Pentachlorobiphenyl 2,2',3,3',6-Pentachlorobiphenyl 2,2',3,4,4'-Pentachlorobiphenyl 2,2',3,4,5-Pentachlorobiphenyl 2,2',3,4,5'-Pentachlorobiphenyl 2,2',3,4,6-Pentachlorobiphenyl 2,2',3,4,6'-Pentachlorobiphenyl 2,2',3,4',5-Pentachlorobiphenyl 2,2',3,4',6-Pentachlorobiphenyl 2,2',3,5,5'-Pentachlorobiphenyl 2,2',3,5,6-Pentachlorobiphenyl 2,2',3,5,6'-Pentachlorobiphenyl 2,2',3,5',6-Pentachlorobiphenyl 2,2',3,6,6'-Pentachlorobiphenyl 2,2',3,4',5'-Pentachlorobiphenyl 2,2',3,4',6'-Pentachlorobiphenyl 2,2',4,4',5-Pentachlorobiphenyl 2,2',4,4',6-Pentachlorobiphenyl 2,2',4,5,5'-Pentachlorobiphenyl ACC-101 Rev 08, 08-Nov-2012 AXYS Analytical Services Ltd. Canadian Association for Laboratory Accreditation (CALA) Washington State Department of Ecology Accreditation no.: A 2637 Lab. ID: C404 W S Pulp T Ser U NP S W 15 15 10 10 15 15, 22 10 28 28 15 15 15 15 28 28 15 15 10, 15 10, 15 15 10, 15 15 15 28 28 28 28 15 15 15 15 28 28 15 15 15 15 28 28 15 15 15 15 28 28 15 15 15 15 28 28 15 15 15 15 28 28 15 15 15 15 28 28 10 10 10, 15 10, 15 10 10, 15 15 28 28 15 15 15 15 28 28 10 10 15 15 10 15 15 28 28 15 15 15 15 28 28 10 10 10 15 15 15 15 28 28 15 15 15 15 28 28 15 15 15 15 28 28 10, 15 10, 15 10, 15 15 28 28 15 15 15 15 28 28 15 15 15 15 28 28 15 15 15 15 28 28 15 15 15 15 28 28 10 10 15 15 10 15 15 28 28 15 15 15 15 28 28 10 10 15 15 10 15 15 28 28 10, 15 10, 15 10, 15 15, 22 28 28 15 15 15 15 28 28 15 15 15 15 28 28 10 10 10 Page 11 o f-mJ Page 292 of 307 www.axysanalytical.com TABLE 2 PCB 102 PCB 103 PCB 104 PCB 105 PCB 105/127 PCB 106 PCB 107 PCB 107/109 PCB 108 PCB 109 PCB 110 PCB 111 PCB 112 PCB 113 PCB 114 PCB 115 PCB 116 PCB 117 PCB 118 PCB 118/116 PCB 119 PCB 120 PCB 121 PCB 122 PCB 123 PCB 124 PCB 125 PCB 126 PCB 127 PCB 128 PCB 129 PCB 130 PCB 131 PCB 131/142 PCB 132 2,2',4,5,6'-Pentachlorobiphenyl 2,2',4,5',6-Pentachlorobiphenyl 2,2',4,6,6'-Pentachlorobiphenyl 2,3,3',4,4'-Pentachlorobiphenyl 2,3,3',4,5-Pentachlorobiphenyl 2,3,3',4',5-Pentachlorobiphenyl 2,3,3',4,5'-Pentachlorobiphenyl 2,3,3',4,6-Pentachlorobiphenyl 2,3,3',4',6-Pentachlorobiphenyl 2,3,3',5,5'-Pentachlorobiphenyl 2,3,3',5,6-Pentachlorobiphenyl 2,3,3',5',6-Pentachlorobiphenyl 2,3,4,4',5-Pentachlorobiphenyl 2,3,4,4',6-Pentachlorobiphenyl 2,3,4,5,6-Pentachlorobiphenyl 2,3,4',5,6-Pentachlorobiphenyl 2,3',4,4',5-Pentachlorobiphenyl 2,3',4,4',6-Pentachlorobiphenyl 2,3',4,5,5'-Pentachlorobiphenyl 2,3',4,5',6-Pentachlorobiphenyl 2,3,3',4',5'-Pentachlorobiphenyl 2,3',4,4',5'-Pentachlorobiphenyl 2,3',4',5,5'-Pentachlorobiphenyl 2,3',4',5',6-Pentachlorobiphenyl 3,3',4,4',5-Pentachlorobiphenyl 3,3',4,5,5'-Pentachlorobiphenyl 2,2',3,3',4,4'-Hexachlorobiphenyl 2,2',3,3',4,5-Hexachlorobiphenyl 2,2',3,3',4,5'-Hexachlorobiphenyl 2,2',3,3',4,6-Hexachlorobiphenyl 2,2',3,3',4,6'-Hexachlorobiphenyl ACC-101 Rev 08, 08-Nov-2012 AXYS Analytical Services Ltd. Canadian Association for Laboratory Accreditation (CALA) Washington State Department of Ecology Accreditation no.: A 2637 Lab. ID: C404 W S Pulp T Ser U NP S W 15 15 15 15 15 15 15 15 28 28 28 28 15 15 15 15 28 28 15 15 10 10 15 15 10 28 28 15 15 15 15 28 28 15 15 15 15 28 28 10 10 10 15 15 15 15 28 28 15 15 15 15 28 28 10, 15 10, 15 10, 15 15 28 28 15 15 15 15 15 15 15 15 28 28 28 28 15 15 15 15 28 28 10, 15 10, 15 15 15 10, 15 15 15 15 28 28 28 28 15 15 15 15 28 28 15 15 15 15 28 28 15 15 15 15, 22 28 28 10 10 10 15 15 15 15 28 28 15 15 15 15 28 28 15 15 15 15 28 28 15 15 15 15 28 28 15 15 15 15 28 28 15 15 15 15 28 28 15 15 10, 15 10, 15 15 10, 15 15 15 28 28 28 28 15 15 15 15 28 28 10, 15 10, 15 10, 15 10, 15 10, 15 10, 15 15 15 28 28 28 28 10, 15 10, 15 10, 15 15 28 28 15 15 15 15 28 28 10 10 10 15 15 15 15 28 28 Page 12 o f-mJ Page 293 of 307 www.axysanalytical.com TABLE 2 PCB 133 2,2',3,3',5,5'-Hexachlorobiphenyl PCB 134 2,2',3,3',5,6-Hexachlorobiphenyl PCB 134/143 PCB 135 2,2',3,3',5,6'-Hexachlorobiphenyl PCB 136 2,2',3,3',6,6'-Hexachlorobiphenyl PCB 137 2,2',3,4,4',5-Hexachlorobiphenyl PCB 138 2,2',3,4,4',5'-Hexachlorobiphenyl PCB 138/163/164 PCB 139 2,2',3,4,4',6-Hexachlorobiphenyl PCB 140 2,2',3,4,4',6'-Hexachlorobiphenyl PCB 141 2,2',3,4,5,5'-Hexachlorobiphenyl PCB 142 2,2',3,4,5,6-Hexachlorobiphenyl PCB 143 2,2',3,4,5,6'-Hexachlorobiphenyl PCB 144 2,2',3,4,5',6-Hexachlorobiphenyl PCB 144/135 PCB 145 2,2',3,4,6,6'-Hexachlorobiphenyl PCB 146 2,2',3,4',5,5'-Hexachlorobiphenyl PCB 147 2,2',3,4',5,6-Hexachlorobiphenyl PCB 148 2,2',3,4',5,6'-Hexachlorobiphenyl PCB 149 2,2',3,4',5',6-Hexachlorobiphenyl PCB 149/139 PCB 150 2,2',3,4',6,6'-Hexachlorobiphenyl PCB 151 2,2',3,5,5',6-Hexachlorobiphenyl PCB 152 2,2',3,5,6,6'-Hexachlorobiphenyl PCB 153 2,2',4,4',5,5'-Hexachlorobiphenyl PCB 154 2,2',4,4',5,6'-Hexachlorobiphenyl PCB 155 2,2',4,4',6,6'-Hexachlorobiphenyl PCB 156 2,3,3',4,4',5-Hexachlorobiphenyl PCB 157 2,3,3',4,4',5'-Hexachlorobiphenyl PCB 158 2,3,3',4,4',6-Hexachlorobiphenyl PCB 158/160 PCB 159 2,3,3',4,5,5'-Hexachlorobiphenyl PCB 160 2,3,3',4,5,6-Hexachlorobiphenyl PCB 161 2,3,3',4,5',6-Hexachlorobiphenyl PCB 162 2,3,3',4',5,5'-Hexachlorobiphenyl ACC-101 Rev 08, 08-Nov-2012 AXYS Analytical Services Ltd. Canadian Association for Laboratory Accreditation (CALA) Washington State Department of Ecology Accreditation no.: A 2637 Lab. ID: C404 W S Pulp T Ser U NP S W 15 15 15 15 15 15 15 15 28 28 28 28 10 10 10 15 15 10, 15 10, 15 15 10, 15 15 15 28 28 28 28 10, 15 10, 15 10, 15 15 28 28 15 15 15 15, 22 28 28 10 10 10 15 15 15 15 28 28 15 15 15 15 28 28 10, 15 10, 15 10, 15 15 28 28 15 15 15 15 15 15 15 15 28 28 28 28 15 15 15 15 28 28 10 10 15 15 10 15 15 28 28 10, 15 10, 15 10, 15 15, 22 28 28 15 15 15 15 28 28 15 15 15 15 28 28 15 15 15 15 28 28 10 10 10 15 15 15 15 28 28 10, 15 10, 15 10, 15 15 28 28 15 15 15 15 28 28 10, 15 10, 15 10, 15 15, 22 28 28 15 15 15 15 28 28 15 15 10, 15 10, 15 15 15 10, 15 15, 22 28 28 28 28 10, 15 10, 15 10, 15 15 28 28 15 15 10 10 15 15 10 28 28 15 15 15 15 28 28 15 15 15 15 28 28 15 15 15 15 28 28 15 15 15 15 28 28 Page 13 o f-mJ Page 294 of 307 www.axysanalytical.com TABLE 2 PCB 163 PCB 164 PCB 165 PCB 166 PCB 167 PCB 168 PCB 169 PCB 170 PCB 170/190 PCB 171 PCB 172 PCB 172/192 PCB 173 PCB 174 PCB 174/181 PCB 175 PCB 176 PCB 177 PCB 178 PCB 179 PCB 180 PCB 181 PCB 182 PCB 183 PCB 184 PCB 185 PCB 186 PCB 187 PCB 187/182 PCB 188 PCB 189 PCB 190 PCB 191 PCB 192 PCB 193 2,3,3',4',5,6-Hexachlorobiphenyl 2,3,3',4',5',6-Hexachlorobiphenyl 2,3,3',5,5',6-Hexachlorobiphenyl 2,3,4,4',5,6-Hexachlorobiphenyl 2,3',4,4',5,5'-Hexachlorobiphenyl 2,3',4,4',5',6-Hexachlorobiphenyl 3,3',4,4',5,5'-Hexachlorobiphenyl 2,2',3,3',4,4',5-Heptachlorobiphenyl 2,2',3,3',4,4',6-Heptachlorobiphenyl 2,2',3,3',4,5,5'-Heptachlorobiphenyl 2,2',3,3',4,5,6-Heptachlorobiphenyl 2,2',3,3',4,5,6'-Heptachlorobiphenyl 2,2',3,3',4,5',6-Heptachlorobiphenyl 2,2',3,3',4,6,6'-Heptachlorobiphenyl 2,2',3,3',4,5',6'-Heptachlorobiphenyl 2,2',3,3',5,5',6-Heptachlorobiphenyl 2,2',3,3',5,6,6'-Heptachlorobiphenyl 2,2',3,4,4',5,5'-Heptachlorobiphenyl 2,2',3,4,4',5,6-Heptachlorobiphenyl 2,2',3,4,4',5,6'-Heptachlorobiphenyl 2,2',3,4,4',5',6-Heptachlorobiphenyl 2,2',3,4,4',6,6'-Heptachlorobiphenyl 2 ,2 ',3 ,4 ,5 ,5 ',6 -H e p ta c h lo ro b ip h e n y l 2,2',3,4,5,6,6'-Heptachlorobiphenyl 2,2',3,4',5,5',6-Heptachlorobiphenyl 2,2',3,4',5,6,6'-Heptachlorobiphenyl 2,3,3',4,4',5,5'-Heptachlorobiphenyl 2,3,3',4,4',5,6-Heptachlorobiphenyl 2,3,3',4,4',5',6-Heptachlorobiphenyl 2,3,3',4,5,5',6-Heptachlorobiphenyl 2,3,3',4',5,5',6-Heptachlorobiphenyl AXYS Analytical Services Ltd. Canadian Association for Laboratory Accreditation (CALA) Washington State Department of Ecology Accreditation no.: A 2637 Lab. ID: C404 W S Pulp T Ser U NP S W 15 15 15 15 15 15 15 15 28 28 28 28 15 15 15 15 28 28 15 15 15 15 15 15 15 15 28 28 28 28 15 15 15 15 28 28 10, 15 10, 15 10, 15 15 28 28 15 15 15 15, 22 28 28 10 10 10 10, 15 10, 15 10, 15 15 28 28 15 15 15 15 28 28 10 10 15 15 10 15 15 28 28 15 15 15 15 28 28 10 10 10, 15 10, 15 10 10, 15 15 28 28 10, 15 10, 15 10, 15 15 28 28 10, 15 10, 15 10, 15 15 28 28 10, 15 10, 15 10, 15 15 28 28 10, 15 10, 15 10, 15 15 28 28 10, 15 10, 15 10, 15 15, 22 28 28 15 15 15 15 28 28 15 15 15 15 28 28 10, 15 10, 15 10, 15 15 28 28 15 15 15 15 28 28 10, 15 10, 15 10, 15 15 28 28 15 15 15 15 15 15 15 15, 22 28 28 28 28 10 10 10 15 15 10, 15 10, 15 15 10, 15 15 15 28 28 28 28 15 15 15 15 28 28 10, 15 10, 15 10, 15 15 28 28 15 15 15 15 28 28 10, 15 10, 15 10, 15 15 28 28 ACC-101 Rev 08, 08-Nov-2012 Page 14 o f-mJ Page 295 of 307 www.axysanalytical.com AXYS Analytical Services Ltd. TABLE 2 Canadian Association for Laboratory Accreditation (CALA) Accreditation no.: A 2637 Washington State Department of Ecology Lab. ID: C404 W S Pulp T Ser U NP S W PCB 194 PCB 195 2,2',3,3',4,4',5,5'-Octachlorobiphenyl 2,2',3,3',4,4',5,6-Octachlorobiphenyl 10, 15 10, 15 10, 15 10, 15 10, 15 15, 22 10, 15 15 28 28 28 28 PCB 196 2 ,2 ',3 ,3 ',4 ,4 ',5 ,6 -O c ta c h lo ro b ip h e n y l 15 15 15 15 28 28 PCB 196/203 PCB 197 2,2',3,3',4,4',6,6'-Octachlorobiphenyl 10 10 10, 15 10, 15 10 10, 15 15 28 28 PCB 198 2,2',3,3',4,5,5',6-Octachlorobiphenyl 10, 15 10, 15 10, 15 15 28 28 PCB 199 2,2',3,3',4,5,5',6'-Octachlorobiphenyl 10, 15 10, 15 10, 15 15 28 28 PCB 200 2,2',3,3',4,5,6,6'-Octachlorobiphenyl 15 15 15 15 28 28 PCB 201 2,2',3,3',4,5',6,6'-Octachlorobiphenyl 10, 15 10, 15 10, 15 15 28 28 PCB 202 2 ,2 ',3 ,3 ',5 ,5 ',6 ,6 -O c ta c h lo ro b ip h e n y l 15 15 15 15 28 28 PCB 203 2,2',3,4,4',5,5',6-Octachlorobiphenyl 15 15 15 15 28 28 PCB 204 PCB 205 2,2',3,4,4',5,6,6'-Octachlorobiphenyl 2,3,3',4,4',5,5',6-Octachlorobiphenyl 15 15 10, 15 10, 15 15 10, 15 15 15 28 28 28 28 PCB 206 2 ,2 ',3 ,3 ',4 ,4 ',5 ,5 ',6 -N o n a c h lo ro b ip h e n y l 10, 15 10, 15 10, 15 15 28 28 PCB 207 PCB 208 2 ,2 ',3 ,3 ',4 ,4 ',5 ,6 ,6 '-N o n a c h lo ro b ip h e n y l 2 ,2 ',3 ,3 ',4 ,5 ,5 ',6 ,6 '-N o n a c h lo ro b ip h e n y l 10, 15 10, 15 10, 15 10, 15 10, 15 10, 15 15 15 28 28 28 28 PCB 209 Decachlorobiphenyl 10, 15 10, 15 10, 15 15 28 28 Total Monochlorobiphenyls 15 15 15 15 28 28 Total Dichlorobiphenyls 10, 15 10, 15 10, 15 15 28 28 Total Trichlorobiphenyls 10, 15 10, 15 10, 15 15 28 28 Total Tetrachlorobiphenyls 10, 15 10, 15 10, 15 15 28 28 Total Pentachlorobiphenyls 10, 15 10, 15 10, 15 15 28 28 Total Hexachlorobiphenyls 10, 15 10, 15 10, 15 15 28 28 Total Heptachlorobiphenyls 10, 15 10, 15 10, 15 15 28 28 Total Octachlorobiphenyls 10, 15 10, 15 10, 15 15 28 28 Total Nonachlorobiphenyls 10, 15 10, 15 10, 15 15 28 28 Total Decachlorobiphenyls Total Polychlorinated biphenyls 10 10 10 10 10 10 Aroclors Aroclor 1260 Aroclor 1254 Aroclor 1268 Aroclor 1221 Aroclor 1232 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 ACC-101 Rev 08, 08-Nov-2012 Page 15 o f-mJ Page 296 of 307 www.axysanalytical.com TABLE 2 Aroclor 1248 Aroclor 1016 Aroclor 1242 Aroclor 1242/1016 Pesticides 2 ,4 '-D D D 2 ,4 '-D D E 2 ,4 '-D D T 4 ,4 '-D D D 4 ,4 '-D D E 4 ,4 '-D D T Aldrin Alpha-HCH Beta-HCH cis-Chlordane (alpha-Chlordane) cis-Nonachlor Delta-HCH Dieldrin Endosulphan I Endosulphan II Endosulphan sulphate Endrin Endrin aldehyde Endrin ketone Gam m a-HCH (Lindane) Heptachlor Heptachlor epoxide Hexachlorobenzene Hexachlorobutadiene Methoxychlor Mirex Oxychlordane Toxaphene trans-Chlordane (gamma-Chlordane) ACC-101 Rev 08, 08-Nov-2012 AXYS Analytical Services Ltd. Canadian Association for Laboratory Accreditation (CALA) Washington State Department of Ecology Accreditation no.: A 2637 Lab. ID: C404 W S Pulp T Ser U NP S W 10 10 10 10 10 10 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 16 10, 16 10, 16 10, 16 10 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 16 10, 16 10, 16 10, 16 10, 16 10, 16 16 10, 16 10, 16 10, 16 10 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 10, 16 16 16 16 16 16 16 16 16 16 16 16 16 16 16 16 16 16 16 16 16 16 16 16 16 16 16 16 Page 16 o f-mJ Page 297 of 307 www.axysanalytical.com TABLE 2 trans-Nonachlor BDE - Brominated Diphenylethers BDE 7 2,4-d ib ro m o d ip h en yle th e r BDE 8 2,4 '-d ib ro m o d ip h e n y le th e r BDE 10 2,6-d ib ro m o d ip h en yle th e r BDE 11 3,3 '-d ib ro m o d ip h e n y le th e r BDE 12 3,4 -dibrom odiphenyle the r BDE 13 3,4 '-d ib ro m o d ip h e n y le th e r BDE 15 4,4'-dibromodiphenylether BDE 17 2,2',4-tribromodiphenylether BDE 25 2,3',4-tribromodiphenylether BDE 28 2,4,4'-tribromodiphenylether BDE 30 2,4 ,6 -trib ro m o d ip h en yleth er BDE-33 2',3,4-tribromodiphenylether BDE 35 3,3',4-tribromodiphenylether BDE 37 3,4,4'-tribromodiphenylether BDE 47 2,2 ',4 ,4 '-te tra b ro m o d ip h e n y le th e r BDE 49 2,2 ',4 ,5 '-te tra b ro m o d ip h e n y le th e r BDE 66 2,3 ',4 ,4 '-te tra b ro m o d ip h e n y le th e r BDE 75 2 ,4 ,4 ',6 -te tra b ro m o d ip h e n y le th e r BDE 77 3,3 ',4,4 '-te tra b ro m o d ip h e n y le th e r BDE 85 2 ,2 ',3,4,4'-p en tab ro m o d ip h e n y le th e r BDE 99 2 ,2 ',4,4',5-p en tab ro m o d ip h e n y le th e r BDE 100 2,2',4,4',6-pentabromodiphenylether BDE 105 2,3,3',4,4'-pentabromodiphenylether BDE 116 2,3,4,5,6-pentabromodiphenylether BDE 119 2,3',4,4',6-pentabromodiphenylether BDE 126 3 ,3 ',4 ,4 ',5-p en tab ro m o d ip h e n y le th e r BDE 140 2,2',3,4,4',6'-hexabromodiphenylether BDE 153 2,2',4,4',5,5'-hexabromodiphenylether BDE 154 2,2',4,4',5',6-hexabromodiphenylether BDE 155 2,2',4,4',6,6'-hexabromodiphenylether BDE 166 2,3,4,4',5,6-hexabromodiphenylether BDE 181 2,2',3,4,4',5,6-h ep tab ro m o d ip h en yleth er ACC-101 Rev 08, 08-Nov-2012 AXYS Analytical Services Ltd. Canadian Association for Laboratory Accreditation (CALA) Washington State Department of Ecology Accreditation no.: A 2637 Lab. ID: C404 W S Pulp T Ser U 16 10, 16 10, 16 10, 16 NP W 16 S 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 Page 17 o f-mJ Page 298 of 307 www.axysanalytical.com AXYS Analytical Services Ltd. TABLE 2 BDE-183 BDE 190 BDE 206 BDE 207 BDE 208 BDE 209 2,2 ',3 ,4 ,4 ',5 ',6 -h e p ta b ro m o d ip h e n y le th e r 2,3 ,3 ',4,4',5,6-h ep tab ro m o d ip h en yleth er 2,2 ',3,3 ',4 ,4 ',5 ,5 ',6 -n o n a b ro m o d ip h e n y le th e r 2 ,2 ',3,3',4,4',5,6,6'-no n ab ro m o dip he ny le the r 2,2 ',3,3 ',4 ,5 ,5 ',6 ,6 '-n o n a b ro m o d ip h e n y le th e r Decabromodiphenylether PFC - Perfluorinated Organic Compounds Perfluorobutanoate (PFBA) Perfluoropentanoate (PFPeA) Perfluorohexanoate (PFHxA) Perfluoroheptanoate (PFHpA) Perfluorooctanoate (PFOA) Perfluorononanoate (PFNA) Perfluorodecanoate (PFDA) Perfluoroundecanoate (PFUnA) Perfluorododecanoate (PFDoA) Perfluorobutanesulfonate (PFBS) Perfluorohexanesulfonate (PFHxS) Perfluorooctanesulfonate (PFO S) Perfluorooctane sulfonamide (PFOSA) PAH Anthracene Pyrene Benzo[ghi]perylene Benzo[e]pyrene Indeno[1,2,3-cd]pyrene Perylene Benzo[b]fluoranthene Fluoranthene Benzo[j/k]fluoranthenes Benzo[k]fluoranthene Acenaphthylene Chrysene W 17 17 17 17 17 17 14 14 14 14 14 14 14 14 14 14 14 14 14 29 29 29 29 29 29 29 29 29 29 29 29 Canadian Association for Laboratory Accreditation (CALA) Accreditation no.: A 2637 S Pulp T Ser 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 17 12 13 23 12 13 23 12 13 23 12 13 23 12 13 23 12 13 23 12 13 23 12 13 23 12 13 23 12 13 23 12 13 23 12 13 23 12 13 23 29 18 29 18 29 18 29 18 29 18 29 18 29 18 29 18 18 29 18 29 18 Washington State Department of Ecology Lab. ID: C404 U NP W 17 17 17 17 17 17 S ACC-101 Rev 08, 08-Nov-2012 Page 18 o f-mJ Page 299 of 307 www.axysanalytical.com TABLE 2 Benzo[a]pyrene Dibenz[ah]anthracene Benz[a]anthracene Acenaphthene Phenanthrene Fluorene Naphthalene 1-Methylchrysene 1-Methylnaphthalene 1-Methylphenanthrene 1 ,2-D im e th y ln a p h th a le n e 1,2,6-T rimethylphenanthrene 1,4 ,6 ,7 -Te tram eth yln ap hth alen e 1,7-Dimethylfluorene 1,7-Dimethylphenanthrene 1,8-Dimethylphenanthrene 2-Methylanthracene 2-Methylfluorene 2-Methylnaphthalene 2-Methylphenanthrene 2/3 -M ethyldibenzo th io p henes 2,3,5-T rimethylnaphthalene 2,3,6-T rimethylnaphthalene 2,4-D im eth yld ib en zo th iop h en e 2,6 -D im eth yln ap hth alen e 2,6 -D im eth ylp he na nth re ne 3-Methylfluoranthene/ Benzo(a)fluorene 3-M ethylp h en an thren e 3,6 -D im e th y lp h e n a n th re n e 5/6-Methylchrysenes 5,9 -D im eth ylch ry se ne 7 -M e th y lb en zo (a)p yre n e 9/4-Methylphenanthrenes Biphenyl C1-Acenaphthenes ACC-101 Rev 08, 08-Nov-2012 AXYS Analytical Services Ltd. Canadian Association for Laboratory Accreditation (CALA) Washington State Department of Ecology Accreditation no.: A 2637 Lab. ID: C404 W S Pulp T Ser U NP S W 29 29 29 29 18 18 29 29 18 29 29 29 29 18 18 29 29 18 29 29 18 29 29 29 29 29 29 29 29 29 29 29 29 29 29 29 29 29 29 29 29 29 29 29 29 29 29 29 29 29 29 29 29 29 29 29 29 29 29 29 29 29 29 29 29 29 29 29 29 29 29 29 29 29 29 29 29 Page 19 o f-mJ Page 300 of 307 www.axysanalytical.com TABLE 2 C1-Benz(a)anthracenes/chrysenes C1-Benzofluoranthenes/ Benzopyrenes C1-Biphenyls C1-Dibenzothiophene C1-Fluoranthenes/Pyrenes C1-Fluorenes C1-Naphthalenes C1-Phenanthrenes/Anthracenes C2-Benz(a)anthracenes/Chrysenes C2-Benzofluoranthenes/ Benzopyrenes C2-Biphenyls C2-Dibenzothiophene C2-Fluoranthenes/Pyrenes C2-Fluorenes C2-Naphthalenes C2-Phenanthrenes/Anthracenes C3-Benz(a)anthracenes/Chrysenes C3-Dibenzothiophene C3-Fluoranthenes/Pyrenes C3-Fluorenes C3-Naphthalenes C3-Phenanthrenes/Anthracenes C4-Benz(a)anthracenes/Chrysenes C4-Dibenzothiophene C4-Fluoranthenes/Pyrenes C4-Naphthalenes C4-Phenanthrenes/Anthracenes Dibenzothiophene Retene PPCP (Pharmaceutical and Personal Care Products) Acetaminophen Azithromycin Caffeine Carbadox AXYS Analytical Services Ltd. Canadian Association for Laboratory Accreditation (CALA) Washington State Department of Ecology Accreditation no.: A 2637 Lab. ID: C404 W S Pulp T Ser U NP S W 29 29 29 29 29 29 29 29 29 29 29 29 29 29 29 29 29 29 29 29 29 29 29 29 29 29 29 29 29 29 29 29 29 29 29 29 29 29 29 29 29 29 29 29 29 29 29 29 29 29 29 29 29 29 29 29 29 29 19 19 19 19 19 19 19 19 ACC-101 Rev 08, 08-Nov-2012 Page 20 o f-mJ Page 301 of 307 www.axysanalytical.com TABLE 2 C a rb am azep ine Cefotaxime Ciprofloxacin Clarithromycin Clinafloxacin Cloxacillin Dehydronifedipine Digoxigenin Digoxin Diltiazem 1,7-Dimethylxanthine Diphenhydramine Enrofloxacin Erythromycin Flumequine Fluoxetine Lincomycin Lomefloxacin Miconazole Norfloxacin Norgestimate Ofloxacin Ormetoprim Oxacillin Oxolinic acid Penicillin G Penicillin V Roxithromycin Sarafloxacin Sulfachloropyridazine Sulfadiazine Sulfadimethoxine Sulfamerazine Sulfamethazine Sulfamethizole ACC-101 Rev 08, 08-Nov-2012 AXYS Analytical Services Ltd. Canadian Association for Laboratory Accreditation (CALA) Washington State Department of Ecology Accreditation no.: A 2637 Lab. ID: C404 W S Pulp T Ser U NP S W 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 Page 21 o f-mJ Page 302 of 307 www.axysanalytical.com TABLE 2 Sulfamethoxazole Sulfanilamide Sulfathiazole Thiabendazole Trimethoprim Tylosin Virginiamycin Anhydrochlortetracycline (AC TC ) Anhydrotetracycline (ATC) Chlortetracycline (C TC ) Demeclocycline Doxycycline 4-Epianhydrochlortetracycline (EACTC) 4-Epianhydrotetracycline (EATC) 4-Epichlortetracycline (ECTC) 4-Epioxytetracycline (EO TC ) 4-Epitetracycline (ETC) Isochlortetracycline (IC TC ) Minocycline Oxytetracycline (O TC ) Tetracycline (TC) Bisphenol A Furosemide Gemfibrozil Glipizide Glyburide Hydrochlorothiazide 2-hydroxy-ibuprofen Ibuprofen Naproxen Triclocarban Triclosan Warfarin ACC-101 Rev 08, 08-Nov-2012 AXYS Analytical Services Ltd. Canadian Association for Laboratory Accreditation (CALA) Washington State Department of Ecology Accreditation no.: A 2637 Lab. ID: C404 W S Pulp T Ser U NP S W 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 Page 22 o f .mJ Page 303 of 307 www.axysanalytical.com TABLE 2 Albuterol A m phetam ine Atenolol Atorvastatin Cimetidine Clonidine Codeine Cotinine Enalapril Hydrocodone Metformin Oxycodone Ranitidine Triamterene Alprazolam Amitriptyline Amlodipine Benzoylecgonine Benztropine Betamethasone Cocaine DEET (N,N-diethyl-m-toluamide) Desmethyldiltiazem Diazepam Fluocinonide Fluticasone propionate Hydrocortisone 10-hydroxy-amitriptyline Meprobamate Methylprednisolone Metoprolol Norfluoxetine Norverapamil ACC-101 Rev 08, 08-Nov-2012 AXYS Analytical Services Ltd. Canadian Association for Laboratory Accreditation (CALA) Washington State Department of Ecology Accreditation no.: A 2637 Lab. ID: C404 W S Pulp T Ser U NP S W 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 Page 23 o fJmS Page 304 of 307 www.axysanalytical.com AXYS Analytical Services Ltd. TABLE 2 Paroxetine Prednisolone Prednisone Promethazine Propoxyphene Propranolol Sertraline Simvastatin Theophylline Trenbolone Trenbolone acetate Valsartan Verapamil HBCDD alpha-hexabromocyclododecane (a-HBCDD) beta-hexabromocyclododecane (b-HBCDD) gamma-hexabromocyclododecane (g-HBCDD) TBBPA Tetrabromobisphenol A BPA and MPE 4,4'-dihydroxy-2,2-diphenylpropane (Bisphenol A) (BPA) Mono-(2-ethyl-5-hydroxyhexyl) phthalate (MEHHP) Mono-(2-ethyl-5-oxohexyl) phthalate (MEOHP) Mono-(3-carboxypropyl) phthalate (MCPP) Mono-2-ethylhexyl phthalate (MEHP) Mono-benzyl phthalate (MBzP) Mono-butyl phthalate (MBP) (n + iso) Mono-cyclohexyl phthalate (MCHP) Mono-ethyl phthalate (MEP) Mono-iso-nonyl phthalate (MiNP) Mono-methyl phthalate (MMP) Canadian Association for Laboratory Accreditation (CALA) Washington State Department of Ecology Accreditation no.: A 2637 Lab. ID: C404 W S Pulp T Ser U NP S W 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 24 24 24 25 26 26 26 26 26 26 26 26 26 26 26 ACC-101 Rev 08, 08-Nov-2012 Page 24 o f-mJ Page 305 of 307 www.axysanalytical.com AXYS Analytical Services Ltd. TABLE 2 Canadian Association for Laboratory Accreditation (CALA) W ashing to n State D epartm ent of Ecology Accreditation no.: A 2637 Lab. ID: C404 W S Pulp T Ser U NP S W Parabens Benzylparaben (Benzyl 4-hydroxybenzoate) Butylparaben (n-Butyl 4-hydroxybenzoate and isobutyl 4hydroxybenzoate) Ethylparaben (Ethyl 4-hydroxybenzoate) Isopropylparaben (Isopropyl 4-hydroxybenzoate) Methylparaben (Methyl 4-hydroxybenzoate) n-Propylparaben (Propyl 4-hydroxybenzoate) 27 27 27 27 27 27 Table 1 and Table 2 - Explanation o f Terms Used: NELAP = National Environmental Laboratory Accreditation Program Non-potable water = water not fit for consumption without treatment as it may contain pollutants, contaminants, minerals or infective agents. Surface water, ground water, rainwater, effluents as well as any other non-drinking water sources are included in this category. Solid = environmental solid sample. Soil, sediment, biosolids, hazardous waste, mixed phase samples with significant solids content are included in this category. Performance based implementation = methodology follows that of the method reference but modifications deemed by AXYS as minor 1may apply, results meet method reference data quality standard. Performance based modification = modifications deemed by AXYS as significant2 have been made to method reference protocol, results meet method reference accuracy standard. The suitability of the methodology for any method prescriptive applications should be assessed based on the modifications made and the specific work requirements. Performance based method = an in-house AXYS method, published method reference not applicable. GC/LRMS = gas chromatography, low resolution mass spectrometry detection. GC/HRMS = gas chromatography, high resolution mass spectrometry detection. GC/ECD = gas chromatography, electron capture detection. LC/MS-MS = liquid chromatography, mass spectrometry-mass spectrometry detection. ACC-101 Rev 08, 08-Nov-2012 Page 25 o f .mJ Page 306 of 307 www.axysanalytical.com AXYS Analytical Services Ltd. Note 1: Performance Based Implementation - Examples of Minor Modifications - use of additional isotopically labeled references - adjustment of calibration range - adjustment of clean-up technique - use of a different extraction of same general type (example soxhlet vs soxhlet Dean Stark) - addition of matrix type using same principles (example addition of tissue matrix using same detection principle and similar extraction type) Note 2: Performance Based Modification - Examples of Significant Modifications - different acquisition conditions using same detection principle (example MS SIM vs. full scan) - different internal control limits while meeting method reference accuracy standard ACC-101 Rev 08, 08-Nov-2012 Page 26 of mS ' Page 307 of 307