Document 3NmVJKJ4GaDD2Bky7nGKone80
THE USE OF AROCLORS IN FORMULATING HIGH STYRENE COPOLYMER SURFACE COATINGS
(Marbon 9200)
iiwwrw. ji.iiia
No. P-149
:
.......... ... ---
February 1, 1953
This booklet has been prepared as a guide to formulating a variety of surface coatings with MARBON* 9200 resin using Monsanto AROCLORS** as the plasticizer and resin. High styrene copolymer resins formulated with AROCLORS make excellent paint vehicles -- and are relatively easy to formulate. The types of coatings described include coatings for concrete, stucco and masonry, interior architectural paints, clear lacquers, aluminum paints and bronzing liquids.
Monsanto AROCLORS are inert chlorinated bi' and polyphenyls which show excellent compatibility with high styrene copolymer resins. Compounded with Marbon 9200, the AROCLORS produce a wide variety of specialized and general purpose coating vehicles which show excellent re sistance to corrosive influences, including acids, alkalies and moisture.
The techniques presented in this booklet for preparing the protective coatings are in accordance with information prepared by the Marbon Corporation.
! Monsanto
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* Trade Name Reg. U.S. Pat. Off. Marbon Corporation, Gary, Indiana ** Trade Name Reg. U.S. Pat. Off. Monsanto Chemical Company
DSW 323035
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STLCOPCB4074683
GENERAL PHYSICAL CHARACTERISTICS OF AROCLORS 1254 AND 5460
Form
Color
Acidity -- Maximum (Mgm. KOH per Gm.) Average Coefficient of Expansion cc/cc/C
Typical Density Specific Gravity 25/25C (77/77F) Pounds per Gallon--*25C (77F)
AROCLOR 1254 Light yellow viscous liquid 150 Max. (APHA) 0.015
0.00066 (25-65C)
1.538 12.82
AROCLOR 5460 Yellow transparent resin 2.0 Max. NPA 0.07
0.00179 (25-124C)
1.740 14.50
Distillation Range -- ASTM D-20 (Mod.) CoIT. C
Evaporation Loss-%-ASTM D-6 Mod. 163C............... ..................._....... 5 hrs. 100C.......................... ................. 6 hrs.
Flash Point-Cleveland Open Cup............... C op
Fire Point-Cleveland Open Cup..................C F
Pour Point-ASTM D-97.....r.........................-C 'F
Softening Point-ASTM E-28........... -
~..C F
. Refractive Index-D-line -- 20C
Viscosity-Saybolt Universal Sec. (ASTM-D-88) 210F (98.9C)
130F (54.4C) 100F (37.8C)
365-390
1.1 to 1.3 0.0 to 0.2
None
None
10 50 -- ------1.639-1.641
44-48 260-340 1800-2500
280o-335 at 5 mm. Hg.
0.03 1.5 to 1.7 (at 260-5 hrs.) None
None
------------
-- 100 to 105.5 212 to 222 1.660-1.665
------------* -------
DSW 323036
STLCOPCB4074684
SOlSIYlYITY 6f" AROCLORS IN 100 MILLILITERS OF VARIOUS SOLVENTS
.Type of Solvent
(@ 25CJ
1254
(@ Hot)
5460 (@ 25C)
Drying Oil _ Tung Oil "' Linseed Oil
*
S S
s s
S S
Ester -` - Amyl Acetate ' Butyl Acetate "Cellosolve Acetate : Cottonseed Oil Dibutyl Phthalate Diethyl Phthalate ~ v Ethyl Acetate
SS
S
SS
S
SS
S
SS
S
S S s
SS
s
SS
s
Ether Alcohol Carbitol Cellosolve
j^jiDiethylene Glycol
Hydrocarbon Benzene
_ Gasoline Kersosene-
' Mineral Spirits - Paraffin
Pine Oil Toluene ^Turpentine Xylene
173 (26C) S I
VS vs vs vs SS
s vs vs vs
259 (98C) S I
VS vs vs vs
s s vs vs vs
SS s I
`
143 S S s SS s 142 S 178
Hydroxy*--derivatives Amyl Alcohol n-Butyl Alcohol
i_,, Ethyl Alcohol (3-A) Methyl Alcohol
s s 10 (27C) 15 (26C)
s s 28 (75C) 22.2 (65C)
.
S S 2 SS
Ketone
-
Acetone
---
s S 260
Miscellaneous *iCWWer
. -
II
. i. - . .
i-u t.-*.i-;------"--- -
.
I -- Insoluble S .-- Soluble
SS -- Slightly Soluble VS -- Very Soluble
Figures show grains of Aroclor per 100 Milliliters ` of solvent at 23*C unless otherwise indicated.
I
osVJ323<>37 '2'
STLCOPCB4074685
50-V::- ' ^General ^Physical CharacteristJcs.of rMarbon 9200.Resini_ ~
Marbon 9200 is a high styrene copolymer resin which is soluble in a wide variety of solvents. Four differ' ent viscosity-type resins are available, ranging from. high viscosity to very low viscosity. Determined on a No. 4 Ford Cup, the viscosity in seconds of 30% solutions of these "graded viscosity" resins in xylene are as fol
lows:
_ "
-
.
(1) HV (2) MV
(3) LV
(*) LLV
350-400 sec. 110-130 sec. 60 - 80 sec. Below 40 sec.
Marbon 9200 resin has the following general properties:
Softening Point Volatile Content Specific Gravity Colors & Appearance Color in Solution
482C. 0.5% or less Approximate 1.05 White granules Nearly colorless
Solubility
Marbon 9200 has very good solubility in most types of solvents except the alcohols and straight aliphatic ^ hydrocarbons. Aliphatics can be used as diluents, however, even in large proportions. Of the hydrocarbons in
general, those with a Kauri-Butanol value above 50 can be classified as "solvents", those with a K-B value below 50 as "diluents". A good solvent combination is a mixture of 40 parts aromatic and 60 parts aliphatic solvent. The viscosity of a 20% solution of the MV resin in a good solvent mixture will be approximately 35-45 cps.
_ Solution rate of the resin granules is outstanding, and solutions can be prepared almost instantaneously. The resin particles have no tendency to form hard-to-disperse lumps when the resin is stirred in the solvent. Solvent wetting of the resins is very rapid.
Solubility of Marbon 9200 Determined on 10% Solutions at Room Temperature
3Solvent --
Denatured Ethyl Alcohol
Carbon Tetrachloride
Ethylene Dichloride
Butyl Acetate
Methyl Ethyl Ketone
Acetone
Trojuoil Sovasol 14
"
Apcosol 47
Toluene
Shell TS-28
Hi-Flash Naptha 2-50-W
Turpentine
K-B Value --
Solubility Characteristics
- -.
. .
40 32 : 46 105 70 t 86
-.
-` --- -- - -
.; ..
--
I D-2 D-2 D-2* D-l*
L t L I D-l D-l D-l ~D-3
* Slight Precipitate Formed
Key to Ratings:
I: Insoluble
L: Limited Swelling and/or Softening
D: Dissolves--
.
I: Low Viscosity Solution
2: > Medium Viscosity Solution
3: High Viscosity Solution .
:; <1-
-
OSW 323038
STLCOPCB4074686
Viscosity of Resin Sojytiqns.. ^,,i .rC-r,- ?trsrs:Ttrt r'
1 r,,ei -
While the average viscosity of a solution of Marbon 9200 MV in a solvent mixture with K-B value above
50 is about 35-45 cps., the viscosity characteristics of the resin can be changed. The viscosity can be lowered
to about half its original value by mechanical working, as for instance, or. a rubber mill. As an example, the
viscosity of a solution based on MV 9200 can be decreased from 30 cps. to 15 cps. by milling the resin for
15 minutes at 120-150F.
.
Viscosity at various solids content can be controlled quite easily by the . proper blending of the four vis
cosity-grades of the resins.
-
Viscosity of Solutions Containing Marbon 9200 and Other Constituents
."
'
These viscosities are obtained when Marbon 9200 MV is dissolved in Toluene to make a 33-1/3% solu tion and mixed with the second components dissolved in a separate,portion of Toluene.
The mixture of the two solutions forms a solution of 30% total solids content. All viscosities were de termined on a Brookfield Viscometer (#1 spindle) and are reported in centipoises.
. ..... . VISCOSITIES
Percent Marbon 9200 in Blend
D/D Boiled Linseed Oil Kettle Bodied Soybean Oil Raw Tung Oil Super Beckacite 1001 Dures 219 Pentalyn A FF Wood Rosin 20 cps Parlon Aroclor 4465 Chlorafin 42 Chlorafin. 70 Marbon 9200
_ , .
t ..-..
.-
.-
.
-' " . /-
-
~ .
10 - ---
-- -- - -----
- ----8.7
-
*7.3 --
9.3
20 50 9.5 - ` _
75 166
8.3 _------;
182
10.0 - 12.0
14.0
.--
181
----- - 194
--- - - 205
15.0 73 195
14.0
75
358.0 ---
204 ' ' 342
14.0 69 191 -- -- 184
17.0 78 201
.1- ' r--
--
95 385 388 385 379 396 388 376 418 377 376 378 --
Melting Point, C, "My" Grade (Krumbhaar Mercury Method)7
: . `V. . z~
"r*
Color of Solution (40% resin in nitration grade xylene) 7. . (U. S. Bureau of Standards Rosin Colors)
100 -- . -----. - ..--- .
-- --
~ ---
--
__
484
185
-WW
Tolerance for Aliphatic Solvents: (Krumbhaar Method)
-. (At Room Temperature) - Tolerance for Mineral Spirits, %
: Tolerance for Troluoil, %
73 75
- Note: 40% Solutions of the MV resin in xylene, diluted with the aliphatic solvent
J until clouding occurred . . . . percentages indicate the aliphatic solvent content
of the mixture at the cloud point.
.
.
'; ; . r ,,
r ;.
~ ..................
"
: PROPERTIES OF MARBON "9200" RESIN FILMS
Marbon 9200 films show excellent resistance to alkalis, acids, salt solutions, alcohol, mineral and motor
oils ... . much higher, in fact, than conventional paint vehicles based on drying oils. The films are not re
sistant to gasoline, however.
.
~
The following performance characteristics are obtained on films cast from 40% solutions in xylene: . -
Drying Rate end Transfer Resistance
Note:
Dry to touch (minutes) Dry to transfer (hours)
25 6
Dry to toueh . . . measured by recording the time elapsed until a ball of cotton leaves no fibers on the film when dabbed with light pressure.
Dry to transfer . . . -measured by recording the time elapsed until newsprint from a 3-day old news paper would leave no imprint on the film under approximately 120 psi pressure.
*4- .
DSW 323039 STLCOPCB4074687
Appearance of Dry Film
Refractive Index Appearance Color Gloss 18 months daylight aging
1.581 Transparent Colorless Excellent No Change
Rim Hardness
Sward Rocker Pencil Hardness Shore "D" Hardness
62 6-H 83
Note: Pencil Hardness according to Wilkinson Pencil Method after 48 hours drying.
Shore **D" Hardness determined on *4" molded disc.
Resistance Towards Yellowing
Fade-Ometer Exposure 46 S.F. Hrs. Fade-Ometer Exposure 150 S.F. Hrs.
No Change Slight Yellowing
Films based on Marbon 9200 are tough, clear, and show very good resistance against yellowing.
Chemical Resistance of Rims
Films for the following tests were prepared by dip-coating clear glass slides and allowing them to dry for one week at room temperature. The slides were then placed in a desiccator at room temperature and 90% RH. Spots of the reagents were placed on the films and allowed to remain for the time indicated.
Exposed to
.
30 min.
48 hrs.
5% Sodium Hydroxide Ammonium Hydroxide, (Cone.) 10% Sodium Phosphate Com Oil Butter Nitric Acid, (Cone.) Sulfuric Acid, (Cone.) Acetic Acid, (Cone.) Hydrochloric Acid, (Cone.) Oleic Acid
No Change
.M
44
M 44
M 44
St 44
44 44
. 44 44 '
44 44
44 44 '
44 44
. .
No Change
44 44
44 44
44 44
44 44
Cloudy * No Change
44 44
44 . 44
M 44
* Films -- clouded by concentrated nitric acid after 48 hours exposure -- cleared, and the cloudiness disappeared after rinsing with water and drying at room temperature.
The following indications of Marbon 9200 films' chemical resistance is shown by the following tests run by the ASTM D-543-43 (modified) method:
Resistance at 25C. to:
3% Sulfuric Acid 30% Sulfuric Acid 1% Sodium Hydroxide 10% Sodium Hydroxide Denatured Ethyl Alcohol Distilled Water 10% Sodium Chloride 3% Hydrogen Peroxide Mineral Oil 10 SAE Motor Oil Gasoline, Reg. 80 Octane
% Wt. Change after Immersion
24 hrs.
7 days
+ 0.2 + 0.2 -f 0.4 + 0.4 + 0.8* + 0.4 + 0.3 + 0.4 + 0.6 + 0.1 Dissolved
* Cloudy to opaque
.
+ 0.3 + 0.02 + 0.4 + 0.2 + 2.5* + 0.4 + 0.3 + 0.5 + 0.3 + 0.2
% Wt. Change Immersed 7 days
Dried 7 days
--0.05 --0.05 --0.03 --0.03 + 0.1* --0.03 --0.03 --0.02 --0.02 + 0.1
------------------- --------------------------------------------------- -
5
DSW 323040
STLCOPCB4074688
*TT . : ~ : - GUIDE TO FORMULATION OF COATINGS
Function of the AROCLOR5
. . ..
Monsanto AROCLORS are a series of liquid and solid chlorinated polyphenyls. Used with high styrene
copolymer resins, AROCLOR 1254 (liquid) serves as a plasticizer; AROCLOR 5460 (solid) serves as a
fortifying resin.
.'
Compounding Paints With Marbon 9200 and AROCLORS
Two basic methods may be used for compounding surface coatings with Marbon 9200 and AROCLORS. The first is by making up dry chips; the second uses ball or pebble mills, or multi-roll paint mills to grind the paint directly. Formulation by the dry chip method ordinarily gives coatings with better gloss.
Method A: Pre-mix all dry ingredients thoroughly, then make up the batch on a differential speed, two-
roll mill (as used in rubber compounding) with roll temperature of approximately 120-130F. As soon as
the band has formed, turn on cold water to chill both rolls to prevent temperature from rising above 150F.
, Wetting of the pigments is normally very rapid and only a few minutes dispersion time is required. When
pigment dispersion is complete, the batch is sheeted off the mill and granulated after cooling. Chips are then
dissolved in the solvent; plasticizers, oils, or other liquid additives are stirred in; and after proper straining,
the paint is ready for use.
~
' Method B: Add 90% of total solvent in the fbrmulation'to a mixing vessel and add the Marbon slowly -with rapid agitation. .
: When all the resin has been added, but before it has completely dissolved, add in the remaining compon
ents of the vehicle. . _
-
.
~ Stir the mixed vehicle ingredients for about 30 minutes, which normally will be sufficient time for dis solving the resin granules. The vehicle may appear slightly cloudy due to trapped air but it is actually solu bilized and ready for transfer to a ball mill for further processing. _
Addrthe vehicle to the ball mill and introduce the pigments and roll the batch for 16 to 48 hours, depend ing on the fineness of the grind desired. Flat paints require about 16 hours; semi-gloss paints, 16 to 24 hours; high gloss enamels up to 48 hours.
After the grinding, the batch is removed and the 10c/c solvent originally withheld is used to flush out
the ball mill and then stirred into the paint. The batch will reach maximum consistency after a week's aging.
It should then be strained and packaged.
.
- -.-
In some formulations where the pigments are not too hard and where a very fine grind is not required,
the pigments may simply be stirred into the vehicle and proper dispersion obtained by grinding on a three-
roll paint mill.
- : - - -^ :
::
- --
TYPICAL FORMULATIONS
Surface coatings, formulated with high-styrene copolymer resins and AROCLORS, dry to the touch in minutes, rather than the many hours or even days which is characteristic of oil base paints. -The paints age well, show very little tendency for the pigment to settle, and are always free of "skinning". __
Cobalt and zinc driers are recommended in some of the "guide" formulations. These metals used in
combination do not appear to affect the shelf life of the paints but often induce greater hardness of the ap
plied film, possibly through more complete solvent release or possibly through some action on the resins them
selves. Lead driers are not recommended.
~~
Driers are not essential in paints formulated with AROCLORS and Marbon 9200; many formulations give films of suitable hardness and elasticity and derive no appreciable benefit from the use of driers.
. The following typical formulations are intended as guides. Except for Marbon 9200 resins and ARO-
CLORS 1254, 5460 *-- materials that are exactly equivalent to the brand name products cited may, if necessary,
be substituted.
...
DSW 323041 STLCOPCB4074689
Material
MARBON "9200" MV MONSANTO AROCLOR 5460 MONSANTO AROCLOR 1254 Raw Tung Oil
Lecithin TS-28
'
CLEAR VEHICLE
Supplier
1
2 2 .--
3
4
%/wt.
17.60 9.11 8.39 1.655 0.545 62.70
Lbs./Gallon
1.43 0.74 0.68 0.135 0.044 5.08
100 Gallons
16.30 5.10 5.43 1.73 0.51 70.20
Dry Time (dust free) Viscosity (#4 FordCup) Specific Gravity Refractive Index
100.00
1 hour 53 seconds 0.947 1.516
8.11
100.00
Many satisfactory MARBON "9200" vehicles can be made up simply by varying types and amounts of plasticizers, extenders, etc. This particular vehicle will give a very clear film and serves as the base for many types of paints and enamels. When large amounts of high oil-absorption pigments must be used, the LV or LLV MARBON "9200" resin is recommended.
Material
MARBON "9200" LLV MONSANTO AROCLOR 1254 Ethyl Alcohol D-5 (s)
CLEAR LACQUER
Supplier 1 2
--
5
%/wt.
40. 10.
5. 45.
Lbs./Ga!lon
3.15 0.789 0.395 3.55
100 Gallons
36.00 6.30 7.80
49.90
Dry Time (dust free) Viscosity (#4 Ford Cup) Sward Rocker Hardness
100.0
7.884
20 minutes 311 seconds 50 (oven-dried)
100.00
This lacquer has excellent clarity. When applied to non-porous surfaces, maximum hardness is not attained for several weeks.
For rapid drying to high hardness, methyl ethyl ketone or ethyl acetate may be used as the solvent.
GENERAL PURPOSE ALUMINUM ENAMEL
Material
MARBON "9200" LV MONSANTO AROCLOR 5460 MONSANTO AROCLOR 1254 W. G. Mica, 325 Mesh (1) Aluminum Paste Xylene Mineral Spirits
Supplier
1 2 2 6 7
--------
'
. ---
%/wt.
7.40 13.40 6.00 8.00 8.55 22.40 33.60
Lbs./Gallon
0.634 1.148 0.515 0.685 0.730 1.92 2.86
100 Gallons
7.22 7.92 4.10 2.92 5.75 26.60 44.00
(1) Alcoa #1371 or equivalent.
100.0
8.49
100.00
Dry Time (dust free) Viscosity (#4 Ford Cup) PVC Pigment Volume Binder Volume
10 minutes 14 seconds 31%
8.67 ' 19.24
This general purpose enamel is a low-cost aluminum finish for miscellaneous interior uses. Appearance, application and protection are good.
DSW 323042
7
STLCOPCB4074690
SPECIAL ALUMINUM ENAMEL
Material
MARBON "9200" MV MONSANTO AROCLOR 5460 (1) Aluminum Paste Xylene
,
Supplier
1
2
7.
' -- `
%/wt.
13.40 13.40 17.05 56.20
Lbs./Gadon
1.13 1.13 1.44 4.75
100 Gallons
13.00 8.00 12.00 67.00
(1) Alcoa #1571 or equivalent.
100.0
8.45
100.00
This special aluminum enamel is a better grade finish with more brillance than the general purpose and with better weather'durability. Heat-aging tests on unprimed steel panels coated with this coating show that prolonged exposure to 500F. causes practically no change in the film. Flexibility and metal adhes
ion are excellent.
Weathering tests on the enamel applied to a steel exhaust stack and to miscellaneous metal parts show
only a slight chalking of the finish after one year.
Tests on the use of this special enamel over roofing felt, asphalt, pitch and roofing paper show this enamel to be comparable to other high quality aluminum paints. For use over roofing compositions, it might be
preferable to use a large aluminum flake such as as in Alcoa Std. Paste #240, Stamford Plating Paste,
or Reynolds #37 Paste.
GOLD BRONZE DECORATIVE FINISH
Material
MARBON "9200" MV MONSANTO AROCLOR 5460 MONSANTO AROCLOR 1254 Pale Gold Brilliant No. 137 SC100 Mineral Spirits
Supplier
1 2. 2 9 10 --
%/wt.
16.53 7.84 4.35
26.04 18.27 26.97
Lbs./Ga!!on
1.685 0.800 0.444 2.69 1.862 2.740
100 Gallons
19.00 5.50 3.50 4.70
25.80 41.50
100.00
10.22
100.00
PVC Pigment Volume Binder Volume
16.8% 4.7 28.00
This is a decorative finish for miscellaneous uses -- the less leafing of the pigment the better, since the resin can then form a protective film over the metal pigment and reduce the tendency to discolor. This enamel is recommended for interior uses only.
CONCRETE FLOOR PAINTS
The Tile Red and the Light Oak formulae listed here are similar to formulations that meet Federal Spe cification TT-P-91A.
TILE RED CONCRETE FLOOR PAINT
Material
MARBON 9545 Chips MARBON 9548 Chips MARBON 9551 Chips MARBON 10829 Chips MONSANTO AROCLOR 5460 MONSANTO AROCLOR 1254 Raw Tung Oil AFA X2280 Cobalt Naphth. (6%) Zinc Naphth. (8%) TS-28
Supplier
1 1 1 1 2 2
--
11 8 8 4
%/wt.
2.62 14.60 15.90
3.54 5.70 6.84 2.05 0.045 0.02 0.035 48.65
.
Lbs./Gallon
0.2715 1.40 1.529 0.3398 0.547 0.658 0.197 0.0043 0.0019 0.0033 4.66
100 Gadens
1.33 8.35 11.20 2.29 3.93 5.25 2.52 0.054 0.024 0.038 64.50
100.00
9.61
100.00
DSW 323043
8-
STLCOPCB4074691
PVC Pigment Volume Binder Volume
21.8% 7.61 27.38
Light Oak Concrete Floor Paint
Material
MARBON 9545 Chips MARBON 9551 Chips MARBON 9556 Chips MARBON 10829 Chips MONSANTO AROCLOR 5460 MONSANTO AROCLOR 1254 Raw Tung Oil AFA X2280 Cobalt Naphth. (6%) Zinc Naphth. (8%) TS-28
-
Supplier
1 1 1 1 2 2 -- 11 8 8 4
%/wt.
2.62 15.90 14.60
3.54 5.70 6.84 2.05 0.045 0.02 0.035 48.65
Lbs./Gallon
0.237 1.500 1.38 0.334 0.54 0.646 0.194 0.0042 0.0019 0.0033 4.599
160 Gallons
1.17 11.00 8.80 2.15
3.73 5.17 2.48 0.053 0.036 0.085 63.50
100.00
9.44
100.00
PVC Pigment Volume Binder Volume
22.8% 7.93
26.89
These concrete paints dry down to glossy, tough, scuff-resistant coatings with excellent water and alkali resistance, good adhesion and where exposed to the weather, very good durability.
The concrete surface should be dry and free from dirt and concrete dust. Except in special cases, (very dense surfaces) acid etching or wire-brushing is seldom necessary. For the prime coat the paint should be thinned with the specific solvent at a rate of one quart of solvent per gallon of paint. The concrete should preferably be allowed to age for about 2 months if possible, before painting.
Since concrete is a permeable material, the prevention of blistering of a paint film and at the same time the creation of a durable film depends to a great extent upon the proper PVC. These are high gloss paints with a PVC of 22%. Under severely wet conditions, this PVC should probably be increased to perhaps 30-35%, at some sacrifice in gloss.
Material
MARBON 9566 Chips MARBON 9551 Chips MARBON 10829 Chips Diatomaceous Silica AROCLOR 5460 70% Chlorinated Paraffin Raw Tung Oil Lecithin Aluminum Stearate Cobalt Naphth. (6%) Zinc Naphth. (8%) Hi-Flash Coal Tar Naphtha Mineral Spirits (low odor)
INTERIOR WALL PAINTS Flat White
Supplier
1 1 l 12 2 15
--
3 13
8 8
--
--
%/wt.
32.38 10.50
1.62 4.40 2.52 2.16 0.57 0.26 0.40 0.06 0.012 23.00 22.18
Lbs./Gallon
3.14 1.02 0.157 0.427 0.2445 0.209 0.0553 0.0252 0.0388 0.0058 0.00117 2.23 2.15
100 Gallons
18.42 7.60 1.03 2.23 1.69 1.46 0.70 0.30 0.42 0.07 0.013
31.58 32.85
PVC Pigment Volume Binder Volume
100.00
34.88% 11.77 21.97
9.703
100.00
9 DSW 323044
STLCOPCB4074692
Flat Gray
Material
MARBON 9200 (MV) _
:
TiO, (NC-NY)
China Clay
Diatomaceous Silica
^
Aluminum Stearate
Chrome Oxide A9341
P-33 Carbon Black
Raw Tung Oil
Extra Fine Talc
70% Chlorinated Paraffin
MONSANTO AROCLOR 1254
Lecithin
Cobalt Naphth. (6%)
Zinc Naphth. (8%)
Hi-Flash Coal Tar Naphtha
Mineral Spirits (low odor)
Supplier
: I--16
- -: -17 . 12 13 19 20
'-- 18 15 2 3 8 8 -- --
%/wt.
r ; 15.18 20.94 6.23 _ 4.37 6.40 0.71 0.12 0.56 1.10 2.14 2.50 0.26 0.006
. 0.12 ___ 22.80
21.98
--
100.00
PVC
"
.-
36.5%
Pigment Volume
12.96
.
_ . . Binder Volume
- 22.51
Light Green Gloss
Material
MARBON 9200 MV
MARBON 9543 Chips
MARBON 10829 Chips
MARBON 9551 Chips
MARBON 9545 Chips
.
MARBON 10849 Chips
MARBON 9556 Chips
MONSANTO AROCLOR 5460
MONSANTO AROCLOR 1254" '
Raw Tung Oil
AFA 81069
Cobalt Naphth. (6%)
Zinc Naphth. (8%)
Hi-Flash Coal Tar Naphtha
Mineral Spirits (low odor)
Supplier
%/wt.
1 1 1 1 .1 1 1 2 '2 - --.. *21
8 --'_
1.93
11.65
3.55
15.93
2.62
. . 1.14
1.00
5.70
__ --6.84
--
2.05
0.044
= 0.023
' 0.033
. 24.25 ' 23.25
Lbs./Gallon 1.579 2.081
- 0.619 0.435 0.04 0.0706 0.012 0.0557 0.1093 0.213 0.2485 0.0258 0.0006
. 0.00116 _2.268
2.185
9.943
Lbs./Gallon 0.1766 1.066 0.324 1.459 0.240" 0.104 0.091 0.520 0.622 0.188 0.004
- 0.002 0.003 2.22 2.12
100 Gallons 18.00 5.95
- 2.88 2.26 0.43 0.21 0.79 6.72 0.47 1.51 1.98 0.28 0.008 0.014 31.10 33.40
100.00
_r.. _
100 Gallons 2.01 6.22 2.11
_ 10.84 1.13
. -.1.04 0.58 3.59 5.00 2.43 0.05
- _ 0.025 0.035
-30.97 34.05
ioo.oo
9.15
100.00
-
-- -- -
- . Dry Time (dust free)
Viscosity (#4 Ford Cup)
PVC
Pigment Volume
Binder Volume
.
26 minutes 63 seconds 23.59% . 8.12 26.94
-"
_ -
I The white and gray are typical low-sheen interior wall paints. Various modifications can be made to
- satisfy any particular requirement. Wet-edge time is easily controlled by the proper choice of solvents;
.consistency can be varied (in the ball mill basic formula) without changing the solids content simply by
using various proportions of the high and the low viscosity MARBON 9200 resins; sheen and gloss can
be improved by the use of increased amounts of the LLV resin.
`
'
Hiding-power, non-sagging properties and washability are good. Can-stability, non-settling and non-skin
ning properties are superior to oil base paints.
~'
The light green formula will produce a gloss finish with excellent coverage for use on kitchen and bath room walls.
]
-10 -
DSw 323045 STLCOPCB4074693
The best of low odor solvents should be used for these interior applications. Any of the low odor thinners (of K. B. values of 20-35) can be used in combination with the best high K. B. solvents, such as Drakes D-5 (s) or SC-150. Viscosity and dry time will vary. Whatever solvent combination is used, the K. B. should be about 55 or higher.
COLORED TRIM ENAMELS Dark Green Gloss Enamel
Material
Supplier
MARBON 9200 MV MARBON 9557 Chip Chrome Green A4464 MARBON 9551 Chip China Clay MARBON 9545 Chip Zinc Oxide XX50 MARBON 11790 Chip Bentone #34 MONSANTO AROCLOR 5460 MONSANTO AROCLOR 1254
1 1 11 1 17 1 22 1 23 2 2
Raw Tung Oil Hi-Flash Coal Tar Naphtha
--
--
Mineral Spirits (low odor)
--
Chip For mula %/wt.
1.346 25.00 --" . 10.03 --
2.50 -------0.72 -- 5.70 4.83 2.09 24.25 23.53
Basic Formula
%/wt.
17.11 '--
15.00 -- 6.02 -- 1.75 -- 0.50 5.70 4.83 2.09
24.25 23.53
Lbs./Gal.
1.58 -- 1.385 -- OJ55 -- 0.162 -- 0.046 0.527 0.446 0.1936 2.24 2.16
100 Gals.
18.00 -- 4.20
-- 2.40
-- 0.346 -- 0.32 3.63 3.56 2.48 30.68 34.10
100.00
Dry Time (dust free) Viscosity (#4 Ford Cup) PVC Pigment Volume Binder Volume Sward Rocker Hardness
100.00
45 minutes 130 seconds 20.06%
7.27 27.67 45
9.294
100.00
Medium Blue Gloss Enamel
Material
Supplier
MARBON 9200 LV
1
MARBON 9552 Chip Lithoponc (low oil) MARBON 9565 Chip Titanium Calcium MARBON 12011 Chip Monastral Blue Lake BL282 MARBON 9545 Chip Zinc Oxide XX50 MONSANTO AROCLOR 5460 Hi-Flash Coal Tar Naphtha Mineral Spirits (low odor)
1 14
1 16
1 24
1 22
2
--
.-----
Chip For mula %/Wt.
1:01 9.44
--
10.86
--
17.83
. -----
3.55
--
10.95 23.66 22.70
%/wt.
22.14
--
6.61
--
7.00
--
4.46
--
2.48 10.95 23.66 22.70
Basic Formula
Lbs./Gal. 2.032
----- t
0.607
` -----
0.643
--
0.409
--
0.228 1.005 2.172 2.083
100.00
Dry Time (dust free) Viscosity (#4 Ford Cup) PVC Pigment Volume Binder Volume Sward Rocker Hardness
100.00
45 minutes 230 seconds
20.82% 7.89
30.00 45
9.18
100 Gals. 23.16
--
1.69
--
2.37
--
3.35
_
0.48 6.93 29.79 31.83
100.00
OSW 323046
STLCOPCB4074694
Medium Red Gloss Enamel
Material
--j~ - * -- . ... Chip For'r "Supplier mula %/Wt.
7o/Wt.
MARBON 9200 LV
1 -"
1.24
MARBON 9552 Chip 1 9.44
Lithopone (low oil)
I* . . _ ~--
MARBON 9565 Chip
1 10.86
Titanium Calcium
16 . --
MARBON 12010 Chip 1 17.83
BON Red Lake RL586
24 . -- -
MARBON 9561 Chip 1 3.31
Rex Orange X1939
11 --
MONSANTO AROCLOR 5460 2
10.95
Hi'Flash Goal Tar Naphtha
--1
23.66
Mineral Spirits (low odor)
--
22.70
22.14 --- 6.61 -- 7.00 -- 4.46 ;-- 2.48 10.95 23.66 22.70
Basie Formula
Lbs./GaL 100 Gals.
2.032
23.16
---
--
0.606
1.69
---
--
0.642
2.37
' -- . . - --`
0.409
2.90
. -- ' . -- '
0.228
0.46
1.005
6.93
2.161
29.65
2.083
31.83
_ -. -- -
100.00
Dry Time (dust free) Viscosity (#4 Ford Cup) PVC Pigment Volume Binder Volume Sward Rocker Hardness
100.00
45 minutes 213 seconds
20.80% 7.42
28.26 45
9.165
100.00
WHITE EXTERIOR MASONRY PAINTS (Stucco, Concrete, Concrete Block, etc.)
Heavy Bodied Satin Finish
*--" Material MARBON 9200 (MV) MONSANTO AROCLOR 5460 MONSANTO AROCLOR 1254 TiO, (Anatase) Zinc Oxide XX50 Extra Fine Talc TS-28
'
Supplier
1 2 2 16 22 18 4
%/wt.
13.80 6.81 6.80 17.80 5.09 17.70 32.00
Lbs./Gaffon 1.59 0.781 0.78 2.05 0.584 2.04 3.69
---
Viscosity (#4 Ford Cup) PVC Pigment Volume Binder Volume
100.00
11.51
966 seconds 36.5% 17.28 29.76
100 Gallons 18.12 5.40 6.24 6.40 2.15 8.70 52.00
100.00
DSW 323047
*12'
STLCOPCB4074695
Material
MARBON 10846 Chips MARBON 9543 Chips MARBON 9545 Chips MONSANTO AROCLOR 5460 MONSANTO AROCLOR 1254 Bentone #34 Raw Tung Oil Cobalt Naphth. (6%) Zinc Naphth. (8%) D-5 (s) SC-150
Lighter Body
Supplier 1 1 1. 2 2
23
8 8 5 10
%/Wt.
10.00 30.00 12.00
2.50 1.40 1.00 2.50 0.023 0.033 21.86 18.69
Lbs./Gaflon
1.09 3.26 1.31 0.275 0.154 0.11 0.275 0.0025 0.0036 2.38 2.15
100 Gallons
6.45 19.10 6.42
1.95 1.24 0.56 3.51 0.031 0.42 33.55 29.05
Dry Time (dust free) Viscosity (#4 Ford Cup) PVC Pigment Volume Binder Volume
100.00
11.01
40 minutes 260 seconds
29% 11.17 27.30
100.00
These two formulations are designed for use on stucco, concrete block, poured concrete walls, etc., where good sealing against moisture, attractive appearance, and alkali resistance is needed.
The heavy-bodied paint gives a satin finish with excellent sealing properties -- tests on new concrete blocks filled with water showed no penetration, blistering or leaking of the paint film after IS weeks. This is a full-chalking type paint for self-cleaning of the rough surfaces to which it is usually applied.
The lighter bodied paint is a chip-formula for stucco and concrete. It does not require ball-milling and is
considerably less viscous giving better brushing properties. A combination of Anatase and Rutile Ti02 is
used for controlled chalking with maximum durability.
1
The PVC of paints of this type is important in determining the durability and resistance to blistering; for very wet porous stucco walls the heavy bodied higher PVC paint is recommended. There may be instances where an even higher PVC will be necessary. For the more general uses the lighter bodied formula should prove satisfactory with probably better weather-durability.
Weathering tests for a year in South Florida (on paints of this type) on concrete, stucco, and masonite have shown good results.
For fresh work previously unpainted, a prime coat of the particular paint thinned with one quart of sol vent to one gallon of the paint should be used.
LIST OF SUPPLIERS
1. .Marbon Corporation 2. Monsanto Chemical Company 3. American Lechithin Company 4. Shell Chemical Corporation 5. Drake Petroleum Company 6. C. P. Hall Company 7. Aluminum Company of America 8. Advance Solvents and Chemicals Corporation 9. Crescent Bronze Powder Company 10. Central Solvents & Chemicals Company 11. Imperial Paper and Color Corporation 12. Johns Manville Corporation
13. American Cyanamid Company 14. Witco Chemical Company 15. Diamond Alkali Company 16. Titanium Pigments Corporation 17. Edgar Brothers 18. Innis, Speiden Company 19. Fred L. Brooke Company 20. R. T. Vanderbilt Company 21. General Electric Company 22. New Jersey Zinc Sales Company 23. National Lead Company 24. E. I. DuPont de Nemours and Company
'13'
DS\N 323048
STLCOPCB4074696
~vr-------
VlONSANTO
_U -
Birmingham Boston
-----
Charlotte
Chicago
--
Cincinnati
> - -
--
A if-
.
Cleveland
Detroit
Los Angeles
, - - --
New York
-'
Philadelphia
^
Portland (Ore.)
... ............ .
San Francisco
_ ___ __
Seattle
-. - -----
-
Twin Cities
*
............_
- _______
Monsanto Canada Ltd.? * - -*- - ^ *. v .1
Montreal Toronto
REPRESENTATIVES IN THE PRINCIPAL CITIES OF THE WORLD
__I
ig4ffios|oj
G: I r
ji n II j
r- ."V-- r>r` V,. .. .
"V v -. v
--
irfT 1^'ilsrm^Ta.r* ****< lit - fhrifc im H-. g --
For further information about The Us* of Aroclors in Formulating High Styrene Copolymer Surfac* Coatings contact th* nearest Monsanto offices
DSW 323049
STLCOPCB4074697