Document 3NgL3LvQaoxnOqJRxa21zbnza

georgia marble company georgia calcium products division- p.o. box sss.tate, georgia 30177 40-4/333-25 n October 4, 1975 Mr. Julius K. Nemeth Bondex International Brunswick, Ohio 44212 Dear Mr. Nemeth: Per your request we are happy to enclose a completed material safety data sheet on our materials and also a letter which describes the trace elements present in our rock. If we can be of further help, just let us know. Yours truly GEORGIA MARBLE COMPANY Calcium Products Divisions /am cc: Mr. W. H. Runge, Jr. Mr. C. L. Gillingham Enclosure Robert F. Hall Technical Director a .Jim BON-01044 MATERIAL SAFETY DATA SHEET lApOi.)v<V hv V ; jwisiv'i:': . > l i!x ' f *..M ,, ,V: . ' w * r \7V\\i1 aI-tl'iTf's's -'JAMf Section i Calcium Products Division , GEORGIA tlARBLf. COitPAr-iY street Aooness 34 60 Cumberland .Parkv/av, N. W. ctv-atate. AMD zip CODE Atlanta, Ga . 30339 EMERGENCY TELEPHONE MO (404) 432-0131 CHEMICAL NAME AN3 SYNONYMS Calcium Carbonate: CHEMICAL FAMILY VRAD2 NAME FORMULA A \ L! PPrroauctf; PIGMENTS PAINTS. PRESERVATIVES. & SOLVENTS % TLV (Units* SOLVENTS n -- TLV CATALYST VEHICLE ADDITIVES t OTHERS HAZARDOUS MIXTURES OF OTHER LIQUIDS, SOLIDS, OR GASES . \ , % TLV lUn.ts) FfBOILlMGr POINT/Cf)' - y '> \ | VAPOR PRESSURE (mm Hg.) ; Vapor oensity <air=i) : 'SOLUBILITY, IN WATER ; ,.PP;A?.ANCE AND ODOR i. i . - * S88iBBBcfjalfuiai7iCTd SPECIFIC GRAVITY (HSC^1) Very Slight PERCENT VOLATILE BY yOLUME t%) EVAPORATION RATE (........................ ?) ' .^jg3B9]^BgBfiSn3^^n9lmHgy&TH* FLASH POINT (METHOD USEOI EXTINGUISHING MEOIA SPECIAL FIRE FIGHTING PROCEDURES FLAMMABLE LIMITS L^ 2Z. UNUSUAL FIRE AND EXPLOSION HAZARDS 2.71 Let Uel BON -01045 IMHISHOLD LIMiT V-V.L'C 30 m.p.p.c.f. or 10 mo./rooters 3 (seo attachmpnt-g m ,-wi no iMI.HotNCV ANI) HRS! A.C PrtC.CEOURES STABILITY UNSTABLE STABLE INCOMPATABILITY (Materials to avoid) hazardous decomposition products CONDITIONS TO AVOID NONE HAZARDOU. POLYMERIZATION MAY OCCUR WILL NOT OCCUR CONDITIONS TO AVOID ---------------------- M-- ------- ------+ -- fnyn^Bia iH |gi ;^i n $!?EP!^0 BE TAKEN IN CASEMATERtAM^IELEASED OR SPILLEO iib u a" ------------------------- - ............................ . waste disposal method NONE m. RESPIRATORY PROTECTION (Specify type) VENTILATION LOCAL EXHAUST NONE MECHANICAL (General) SPECIAL OTHER PROTECTIVE GLOVES OTHER PROTECTIVE EQUIPMENT EYE PROTECTION Use applicable Nuisance Dust protection if TLV is exceeded, PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING OT"ER PRECAUTIONS NONE BON-01046 WW.; m.o JurJ^uva^KO-pivtofi*' ->'!/ 4 H***"*.. t.i .$. Public H*W' 5fvk 1W TwinbwA Pkw*v RofvilU,*W. !<* TUt-M5ra ., EOWARO.it BAif.fi Pt Chiimwri ' Oivi.iort of OctupaliOMl He*l(h ` i'ii-iiyfcnit 0p*lmeflt of Hatri.fcu'O. Pmntwyh/Aru* 1.7liU HI. 71/ " ANDREW D. HOSEY, Vice Chairmen Bv;w of 0eCwp4f*vul Safety 4 Health U. Sc Puhlte Health Service . . * 1014 Btoedwsv, Cincmrvin. OKo *5202 ret. M3 - 608 HOWARD 6. AYER. Vke Chaltman-elect Bureau of Occupational Safety 4 Health U $. tHJbttc Haallh Service 1014 &ro,dway. Cincinnati, Ohio-45707 T.I. 510 - 4-53 AMERICAN CONFERENCE of ^ GOVERNMENTAL INDUSTRIAL HYGIENISTS a - -. Mr..Robert P. Ball Georgia Marble Company ~:z.Box 356 'v/ '. GejaegtaA-:; '30177'; < ''7--.-,V/-`. / - /Dear, 5' - ' " v'v`. fife*'6* ' ". BOARD OF DIRECTORS IW-7 IRVING H. DAVIS Division of Occupational Health Michigan Department of Heai'h 35C0 North Logan Street Lansing, Michigan 46914 HURON L. VAUGHAN Mississippi Division of Occupational Health P. O. eox 1700 Jackson, Mississippi 39205 JEREMIAH R. LYNCH Bureau of Occupational Safety & Health U. S. Public Health Service 1014 Broadway, Cincinnati, Ohio 452C2 VERNON E. ROSE, Secretary-Treasurer Bureau of Occupational Safety & Health U. S. Public Health Service 1014 Broadway, Cincinnati, Ohio 45202 Tel. 513 - 684-3557 April 30, 1970 Attachment i'1 ' war Letter'af-April' 2^;;'Oup^.Cpnference has classified calcium inert,..orv;b.i^sance.:'dust.;vv'qonseq.ueD.tly, .the:recommended =: .. ". ami-'en^Oel^Va'-c'a^l'imett^^J.COpy;;of*opr;',1969 Threshold Limit Values, booklet. . recommended TLV is-. .;V-.y' -2^-* .= - :%ii . V'An ao'!be>-.a^h/i'shd^t^^''^e^-7hrashoi(i.'L'djn^::Yaiues' Committee.is considering' >' SeLdusts.L".--No\Sinal.action has been . ... a^aUfsaetidttywesre^'-"taken, I would Lor 10' milligrams per " :"y>; : ,-t ;. . " BON-01047 TLVs Threshold Limit Values for Chemical Substances in Workroom Air Adopted by ACGIH for 1973 Attachment 2 Xnlxanrr Pnrliriilnlr.w In eon I rant lo rihrogettic which cause s<",'tr Iisstif In Lie funned in lungs when mliiiled in exci'S-uv" iitnounts, so-called "miLvinee" dusts have a long history of little adverse elleei on lungs and do not produce .significant organic disease: or toxic effect, when exposures are kepi, under reasonable control. The nuisance dusts have also been called (biologicallyt "inert" dusts, but the latter term is inappro priate to the extent, that there is no dust which tloes not evoke some cellular response in the lung when inhaled in sufficient amount. However, the lung-tissue reaction caused by inhalation of nuisance dusts has tile following characteristics: 1; The archi tecture of the air spaces remains intact. 2) Collagen (scar tissue) is not formed to a significant extent. 3) The tissue reaction is potentially reversible. Excessive concentrations of nuisance dusts in the workroom air may seriously reduce visibility firon oxide), may cause unpleasant, deposits in fhoeyes.eurs and nasal passages (Portland Cement dust), or cause injury j.o the skin or mucous membranes by chemical or mechanical action per se or by the rigorous skin cleansing procedures necessary for 1 heir removal. A threshold limit of lOmg/nv1, or 30 inppcf, of total dust < l% quartz is recom mended for substances in these categories and for. which no specific threshold limits have" been assigned. This limit, for a normal workday, docs not. apply to brief exposures at higher concentrations. Neither does it. apply to those substances which may cause physiologic impairment at lower concentra tions but for which a threshold limit lias not Vet been adopted, dome nuisance particu lates arc given in Appendix E. BON -01048 Jim Waiter Research Corp. 10301 NINTH STREET NORTH - ST PETEFJSfiURG. FLOR! ? A 33 703 PHOM:.' .313 b'.-'S 11^1 July 21, 1971 Mr. Robert Hall, Technical Director Georgia Calcium Products Division The Georgia Marble Company Box 356 Tate, Georgia 30177 Dear Mr. Hall: The following data are presented in response to your request for a report on the concentration of heavy metals in Georgia Marble's calcium carbonates. These analyses were made on July, 1970, samples taken from the Tate, Georgia, and Gantt's Quarry, Alabama, deposits. All values are reported as weight percent. Component Antimony Arsenic Barium Beryllium Bismuth Cadmium Chromium Cobalt Copper Lead Manganese Mercury Molybdenum Nickel Selenium Vanadium Zinc Tate, Ga., CaC03 <.005 .00001 (.11 ppm) <.001 ^..001 <.0005 <.0001 .0004 <.0001 .0015 .0003 .007 <.0002 (w/fa) <.001 .*.001 . . .0053 <.001 .0066 Alabama CaCO^ Analytical Method <005 Emission Spectrograph ,000006(.06ppm)Gutzeit Technique <.001 Emission Spectrograph *.001 Emission Spectrograph <.0005 Emission Spectrograph <,0001 Atomic Absorption .0004 Atomic Absorption <.0001 Atomic Absorption .0015 Atomic Absorption .0003 Lead Sulfate Precipitatio .004 . y Emission Spectrograph <.ooo2 xmi) Atqmic Absorption <.001 r 7 Emission Spectrograph <.001 Emission Spectrograph .0070 Atomic Absorption-MOHMM <.001 Emission Spectrograph .0064 Atomic Absorption Values reported with a less-than sign (<) are given as the lower limit of detection for the test method used. This means that the element was not seen, but if it is present it will be in a concentration less than the value reported. If you would like more detail on these analyses, please write or call. Very truly yours, JES:bt John E. Sheridan Group Leader-Testing A subsidiary of iBUT Jim Walter CORPORATION BON-01049