Document 3N9XBboK6bYnQ6dOo0kYM6736

i . ARN6-0066 Centre Analytical Laboratories, Inc. | 3Ph0o4n6eR:e(s8e1a4r)c2h31D-r6iv0e32 Fax: (814) 231-S1t2at5e3Coorll(e8g1e4.) P23A11-61850610 i Analytical Report A Fluorochemical Characterization of Drinking Water Samples Pensacola, Fl (W2176) A Centre Analytical Laboratory Report No. 023-007D n Testing Laboratory Centre Analytical Laboratory, Inc. || 3048 Research Drive' State College, PA 16801 3M Environmental Laboratory Contact " Kent R. Lindstrom Bldg. 2-3E-09 A St. PaPu.lO,.MBNox5353133331-3331 Phone: (651) 778-5352 1 Requester RB Kris J. Hansen, Ph.D. 3M Environmental Technology& Safety Services Bldg. 2-36-09 0 P.O. Box 33331 St. Paul, MN 55133-3331 1 Pacerors 60322 i 1 Introduction | cRooolasehuciltcsaadlrfeLraobrmoerPpaoetrnotsreaidecsof,loran,ct,hFle.(aTnahlCeysCiesonotorrfsenasihseeureyiensuoEmfnbdveririonaknsimsnagingwinaeltdeLrtaobsotarhmaetppolrreoysj.eTcrtehceei1sv2e3ad.bm0y0s7Cewnatrrse |] (SpLeCciIfMicSMfSuo)rwocahsermeicqaulesctheadrafcrtelrlizsaatmipolnesb.y aAuodtcahvoofm1a6lsoagmrpaipehsyweraonrdeceemivmeadsfso aspneacilryom.atry H "Thesampleswerepreparedandanalyzedby LCIMSIMSforthefolowing stoffuorochemicas: a Table 1: Target Analysis i" Pertuorooctane Sulfonyarmide [Prosa | a a Os Prac goats tices (GLPs). sTnoe arnaloyftictailsmsethcodwussedgwoesnavadidaalecdobry nCeni0rUe,STEhPeAvaGlidatLonaprortocyol andross areon lewithCentre.Datapresented here i theHighest cualty Gataavaiable af116 ime. n 2 Sample Receipt a ciTonhldelievcistdaiumoanlpldsaeatsmepswlewereceornestuanboitmneisrtuspepdwleiiernde.inrdCeihcveaiidivuneaodl.fplcaSusasttimcopdlcyeonsftoawriemnreaertsiroeancnedsivwpeerdreoesnenn0ot2te/d1p5ri/ne0sA0et.rtTvaehcdh.emsoSnaitmopA.elne H 3 Holding Times sThteaaynaolfyttihceaalnmaeltytheosdofunsaedrewsetsfovralloidnagteerdpeargiaoidnsshtaasmnaoxtbiemeunmdehtoemnnginiedm.e of 14 days. The un a pacez0es 00323 B 4 Methods - Analytical andPreparatory R 4444.1 SLaCmpMlSeIPMreSparationforLGIMSMS Analysis Samples werenial treated with 200 ulof 250 mL sodium thiosulfate souion to remove B diLTrsehGcseiMadrScudaaIelrdMiScdahgnlaeondraiwtlnyahes.seisf.SSiosPlAtiEdefcotoprlhtdyaumsmvieniltiwheexar5tsrpmatocitht.iioeoofnnn4eol(0fuS%stPeaEdmm)pewtlwiheaahwsn1aa0slu0stn%erdwmaaentttsoehfrapesnrrooeupl(ta.ooraen,CAutph"5eTShmPeslEaepmlcapuaalrtreeitscwogfsneofr HB `mceotnhcaenntarlatwioansofctolhieecstaemdplfoersapnarliyostirosanbsyiyLsCis/.MS/MS. This treatment resulted in an eightfold B 412 SampleAnalysisby LCMSIMS n Sle esa stn leo ess US i aost In HPLC, an sliuotofextracti injected and passed trough a uic-phase chromatographic B o`tHrhcPgeoLlaqunCmuincis.decpmBoaramoaspbteoiiduonno,pdnhsEa,tSsheieMn,caSltfuhdpefirnoiagvnoniaffdiiuteottshreyeoacisharanarampeliitydcataiaelnfnseo.ddrtfaEohcrlceeuasrctacaohltaesiropamncretaaearirynyipssghtfeiaoncsoaeramanoialnulyntyozhtpieenocrgfoamatloouwdmi.ndaferFerrlleaaolntawigvgeieuonttfgyo 0 mkniodwntefmlpeorraotcuhreems;icmaollaerocuobssearrveedioaninzdedq,uafnrtaigtmaetnedteadg,aiannstdsdetteactned.. lons characterise of AHowlett Packard HP1100 HPLC system coupled 0 a Micromass Ulm MSwIasuMseSd(0 RB `(aSnRdMM)S. ISMaSmpmleetshowdesr o. euseextdrfaocrtaenda loynsi2s/2a2n/d00nsarnudmaennatlypzaerdambeytMerSs/cMaSn obne 2f/o2u3n/d00i. aTthaechHmPeLnCt n 5 Analysis n 54 ACaTl-piabirnactailiobnrationcurvewasanalyzed at thebeginningandendoftheanalyicalsequence - f5o0r0t,haencdo1m0p0o0unndgso(fpipntt)eTrhesetr.Teshpeocanlsiebroaftitohne pqouiannttistwaetironeipornepvaerrseudsatth0e,2co5n,ce5n0t,rat10i0o,n2w5a0s,. Rn pcclooettuleiadtrfaoocnrceecvopaetcfahfebilcpioeeifnnttr.(1)U0as.in9n8dg5cl(oi1gnf2eiari0.er9ne7tg0r)oe.fssdieotnerwmiitnhat1i/xo-nw(e7i)ghwtoirneg., ctehteesrlmoipnee,d.y-iAntecrcoeprt tanod B CalbrationstandardsarepreparedusingthesameSPE procedure usedforsamples. E `tCchaorlnobcureganhttoiruaottniocnthsheeacrkeasnwtaiaitnyhidsniasr+ds2sw0eeq%rueeonfcahnea.elyazCceotdmupapleviraialonducieecalliys (eavbeirayintehdreeIto tfhiev.e ssatmanpdlaerdInjaecntiaolnsy) a Fortheresulsreporiedhere,calibration creriaweremet. 0 Paceaors G0321 5.2 Blanks exhEtxretarlcaotctwiieoonvnbelablncalknbksrsastwhieoroneusptnraohendpaaarrvde.edFaaonnyrdthaaerngsaeletySzaenadalwymittehspiepvreieerseeyoxntetaxsatcrtla,ocontiaobbnobvlaetchwhaeeeocfsoncsnoacrmekmpnpltleissoa,inotTnhoef a Insirument blanks in the form of dean methanolsolventwere also analyzedafer every high- a lhseaavmveplelceaaslniybprrtaeatsriogonenttsotadahnnedaraeradst,heapnridonssaetfnrttuemreaktnntoobrwnsbahoivgahe-enltehcveoekmlplsloaiwsmainpetlv.eesl.caAglarianl,onthestbalnadnekrs.shoFuolrd npout 53 Surrogates | `Surrogatespikesare not acomponoefnthte LC/MS/MS analytical method. 54 MMaattirxixspSkpeiskweosre prepared for every sample at a concentration of 100 nolL usinga |" `compounds of interest. Matrix spike recoveries are given in Attachment C. | FTcioeemspssopufinodersssowafemrpnoleearlMssoC,-pGrFeZip0oaHdrseGpdaiovkene srreecovoeovroeareliresssaamfpooleas2saotcgoaivmceonpnncaeAnntaacotfhomsneonfpt 1C0a.0TnhyaLFl0usei8anggalel indicatingtht tis samplewaspossiblyspkedat 1000 ptInsteadof 100 pt. B 55 AlDlupslaimcplaetsewsere analyzedin Atachment. duplicate. Resulsaregivenalongwith the sampleresus in a " 56 2LM5oaivnblgoawLcracataLetpCoiSvarslyshoorCwssopceniodktveredlwrooywilrt1Seh0caoa-mv5ecpr0oyl%mefp)osoruAPlnaRdOeoSfs.ncTehoovrstasatn2dta5frdarnw1da2cs5or0maplneoLcc.nitesIdwnaaanrdawnaasysfsouonfdhbooems. 130% in each LCS. " 57 Sample Related Comments H Fireoludgbhlanakhsyapmerpclaersbccaornstiisdtgeedwoafseamdpdteydctoonttaieneerms.pFyocrotnytaminielralnidotafnetdryypsee a|dwaintethrfsitaemreed. `mannerastheother samples. H 6 Data Summary PleaseseeAtachment 5for adetaed isingoftheanaytcaresus. u 7 Data/Sample Retention || a Sagflm0epeclrtoesnsimcaarGiatnapitosasabryciChnioovnfeetdndeoonrmeotnitehvaafbelremheedrieapatnidshsaruddcopuysrsopotrhsearresstsapreedcIi.doAtla | 60325 uo Pacedors mn 8 Attachments n oatsCunt 02 Hm nn n 65 Atm aisSoa(PldmLae sooSsin 84 AromnseRann mi:n B 9 Signatures B B a tetris A2rf a Po -- . oe 3-Rb-00 H ObA LeroLabsembers ConaDns i u ss CG0326 EOE OE EOE EE EEE EE WW WWW 3M t Envior mental Laboratory C[hFaion orf Causotody0Recque]. TrlLFabCorartoerpyAnalyTtiacanl Zol1i 7A12l5 ] RE me ra [romper ~~" lpnove Oefd FE. ---- x aaa LC] LS E a a oe nem feee e H JelelalH eleic T H T pp [romp|| wale Pensacola FL iE F dI mest EEar 7acetic C rnpIFSFT )T t 7 ee0)T t P7 ticn [H niiS ememe imoresH a 3Hl ar H PrePt T FFmnm ism Sotiofllodteoe r P , AA t A H EH| [Fmp n clzsaiica ateep sa a dn |H r HEt AEE H HEy E er d[reio lly Dni--ile------r | =r {apir e iBili|see ----s a-- fp om ense 1 rmr en.asmaet [EAH LAGE CT I Eppes HHH TRON ee EEE EE EE DERE E EE EEE = 3M Envir mental Laboratory Chainof CustodyReque. orLaboratoryAnalytical 17127 IL SET Ia ee ---- 1---- --] ic = Gi ] [vr|J |th mciea ne]H OwuaprcepioFeL, FET TE 7rm Br i mr SERRE [=fm 2aai SSiialan e H EN m H I PH H 8 oH [Camecoi -- C= a ] HH Ie TbFe {PlI l ocr [om = ou| C ig | y e ==_] a ee 00308 BEEr u / ii La ER eEy egyre EAN Centre Analytical # STl RP Teao Nb .o R rator Inci . e ~~s, | [-- "I EN rie ga = R |O ---- 00329