Document 3N4QR1kjNVyzbDQd15Qa5yZo6
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^NNt^ Tenneco Polymers
AfennscoCompBR)
$ll, ill H70
MATERIAL SAFETY DATA
(Approve! by U.S. Daparimant ol Labor as "assantlalty similarm to FOHU 0SHA-20)
NUMBER
159
SECTION I IDENTIFICATION OF PRODUCT
MANUfACUMCm NAME TENNECO POLYMERS. INC., RESEARCH A DEVELOPMENT
EMEAOEMCY TELEPHONE NO.
609-386-9200
RIVER ROAD, P.0. BOX 129, FLEMINGTON, NEW JERSEY 08822
THA0C MAMf AMO SYNONYMS
TENNECO PVC COPOLYMER DISPERSION RESIN 0565, 0665 (0565-1)
CHEMICAL NAME AND SYNONYMS
VINYLCHLORIDE - VINYL ACETATE COPOLYMER, VC/VAc COPOLYMER
CHEMICAL FAMILY
CHLOROHYDROCARBON COPOLYMER
MOLECULAR FORMULA
{CH2CHC1 JxtCHgCHOCOCH^y
MOL. WT.
SECTION II HAZARDOUS COMPONENTS OF MIXTURES
.COMPONENT
THRESHOLD % LIMIT
VALUE
COMPONENT
% THRESHOLD LIMIT VALUC
fUNfTfl ,
(UttfTSI
0SHA Standard 1910.93q(*1017) on vinyl chloride sets a permissible exposure limit of
Ippm averaged over any 8 hr. period and 5ppm over apy 15 minute period. On the basis that polyvinyl chloride may contain and release small amounts of monomer, the Standard
SECTION III
AFVEARANCE AHD OOOR
rfhite powder, faint ester odor.
CKLINC FOIHT (DECREES FAHRENHEIT)
Not applicable
VAFOR FRESSURE (MM. OF MERCURY)
Not applicable
VAFOR DCMTY
Nol applicable
SOLUOUJTYM WATER
Negligible
PHYSICAL DATA
-oMcEcLRTWEOEsFFOaIHhTrenheit) jjot applicable
Softens about 140 - 160*F.
SFCOFTC GRAVITY (WATER I)
1.4 aFCnRwCEeNrsThVtO) LATILE
Approximately IX (Moisture)
EVAFORATION rate PUTYLACCTATE 1)
Not applicable
SECTION IV FIRE AND EXPLOSION HAZARD DATA
n^oiHijjggFYMCTHoii, Ignition about 735*F
for PVC (ASTH D-19291
FLAMMABLE UMITS
UMEN
PERCENT BY VOLUME)
Not applicable
IIFFER
FMCEXfMGUIBMMQ MEDIA
Water spray, carbon dioxide or dry chemical.
FECIAL FMC-FIGHTtMO FROCEOURES
T
UCC 080357
Water spray or fog may be helpful In reducing flame Intensity and absorbing /
irritating funes.
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_____________________________________ '
unusualfireandexflomomhaxabob NFPA lists Ignition temperature of 1274*F for dust cloud.
Produces combustible gases abov$ 570*F. Fire conditions produce hydrogen chloride,
requiring protective equipment.
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>* At mu si Twwes PMi*nn
totoummd Ifom eovcbi unbybC ftv T*rrc toosyw--s to too bccvtih tnfl TaPiwem Ptoynun dost rqI sttvffw sv Most fsipofisibiliy lor ms r toMtHCS up*' ***
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SECTION V HEALTH HAZARD DATA
ITHAESMOLD LIMIT VALUE
See Section II
wFienoAovEiwxrouM None expected - Inert resim See Section IX. Prolonged breathing ol concentrated dust may be harmful. (Processing at high temperatures produces fwes irritating to eyes and respiratory tract requiring local exhaust).
MEMCMCV AND FIRST AJO PROCEDURES
Ordinary measures of personal hygiene. In case of exposure in hot processing move to fresh air, flush eyes with water.
SECTION VI REACTIVITY OATA
STABILITY
UNSTABLE STABLE
INCOMPATIBILITY
None in ordinary use.
Normalconditions to avoid processing temperature, about 350*F,
X
causes slow darkening and decomposition. Higher heat increases rate and evolution of HC1.
Soluble in certain ketones and organic solvents.
MATAROODS DECOMPOSITION PRODUCTS
Thermal dec omposition prod uces .HC1, and CO and COg-(above-570*F). -- .
*-**
HAZARDOUS POLYMERIZATION
MAT OCCUR WILL NOT OCCUn
CONDITIONS TO AVOID
None in ordinary use. X
i SECTION VII is onteps to be Taken in Case material released spilled
SPILL OR LEAK PROCEDURES
Sweep up and remove to disposal container.
WASTE DISPOSAL METHOO
Bury in an approved landfill.
. SECTION VIII SPECIAL PROTECTION INFORMATION
reswratortprotection csf-eNTWRii m case or concentraiea oust, use bureau of Mines approved dust respiratory (NIOBM TC-21C-132 or equivalent). See Sections II and IX.
VENTILATION
'ffolfproces s ing.
'"V&nt to elevated stack.
TS'r'cfnlfniir?' handling.
TMVentilate enclosed spaces.
PROTECTIVE OLOVES
EYE PROTECTION
Not ordinarily reoulred.
Safetv glasses.
other protective ciMPMSNT None required for ordinary handling. For hot processing local exhaust, safety glasses and gloves are recoRmended.
SECTION IX SPECIAL PRECAUTIONS
raccAunoNSToscTAKENiNMANDUNOANosTowNo OSHA Standard 11)10.93q(7l6l 7) requires monitoring and other precautions In storage, handling and use of polyvinyl chloride, and also labeling f PVC "Contains Vinyl Chloride-Vinyl Chloride Is a Cancer-Suspect Agent". New PVC ",sins with a low monomer content make it easier to operate below .the OSHA action level
of 0.5ppm in a processor's work area, assuring normal conditions and ventilation, simplifying compliance with some of the regulatory requirements. Further developments
on resins and on regulations are pending.
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I DATE
I NAME AND TITLE
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UCC 080358
I.