Document 3Jm4jO50M6jzXR514ME1N7qKE
AR 226-0405
BIODEGRADATION
TEST SUBSTANCE Identity: PreefrefrirueodrotoocatsanPesFuOlSfoAnAy,laFmiCd-o1(2et8hoyrl)aascetthaetem;ajmoarycoalmspoobneent of
FC-127, FC-129, FC-109, FC-109-X or R1904. (Glycine, N-
ethyl-N-[(heptadecafluorooctyl)suifonyll-, potassium salt, CAS #
2091-517)
Rise5m0ar%kPso:tassTihuemtfelsutorsoamalpklyle ciasrFbCo-x1y2l9a.te,T1h8e%stbuudtyy-ldceafribniteodl,co2m8p%oswiattieorn,
and 4% ethanol. from proprietary
3TMhidsaitsaabamsiensorincdoinctartaidnigcittiiosn
to the formulation available: a mixture of 42% test
substance, 32% water, fluoroalkyl carboxylate
14% 2-butoxyethanol, 4% compounds. Test material
ethanol, and was from 3M
8%
C4+-C7
Deutschland production batch 2304.
mTihxetfuorleloofwitnhgestuesmtmsaurbsytiasnacbebrinevaiawtaetderb/eocragaunsiectshoelvteesnttssaolmuptlieoni.s a Data does not accurately relate biodegradation of the test sample with that of the test substance.
METHOD:
Method: OECD 301E
Type: Aerobic
GLP: No
Year completed: 1984
Contact time: 28 days Inoculum: Secondary
Effluentof
a
domestic
sewage
plant
RESULTS
Mean DOC removal after 28 days: 80%
Remarks: to be 13.5
Organic mg/100 mg
carbon content of the test material sample by a carbon analyzer.
was
determined
CONCLUSIONS
No reliable conclusions can be derived from this study. Submitter: 3M Company, Environmental Laboratory, P.O. Box 33331, St. Paul, Minnesota, 55133
000367
DATA QUALITY
Reliability: instrument
Kiimisch ranking used in this study
3. to
deTtheermdiigneestTiOveCpirsoncoetduargegroefstshieve
enough
tcoalbcruelaaktetdhTe OcaCrbiosn2-f2l%uorcionmepbaornedds.toTthhee 1T3O.C5%isotbhtearienfeodrebyinaancacluyrsaitse.. The
TprheesseentreasnudltsnoatreofetxhpeecPteerfdltuoorboeocrteapnreessuelnftoantyilvaemiodfo(tehtehoyrlg)aacneitcastoel.venLtasck
characterizationoftest substance and confirmation of test`concentrations.
REFERENCES
This study was conducted at Research and Consulting Company AG, Ch-
4452 Itingen / Switzerland at the request of the 3M Company.
OTHER
Last changed: 5/17/00
000368
ce:Inte"RronalL.CorBreoshpoonnde-nce21-24-05
-
oD. R. RICKER - CONMERCIAL CHEMICALS DIV. = 236-1310
fom EB. A. REINER - ENVIRONMENTAL LABORATORY/SE & PC = 21-245
ep OECD BIODEGRADATION TESTS ON @Ggl29yAND FC-170C
J
3M
WnedhaPvCe-17r0ecceifvreodm cD.opiReeseseofofthe3MOEGCeDrmaSncyr.eening Tests on FC-129 TshhciecsurreapstrueolldtuysctroepfisretshreeenatdFiCl-ty1h2e9daecgstrtuauaddlayblsienu.csocrerpTethicistbliylrietsiyunldtiocfadtoteehsisthnaott Product te biodegradation because the instrument used to mSTPehoeaenscruiurfmmeieoctnhtotTodOt.CaulsmeodeTrthehgioandnO,iEtcChDbicustaSrcsbrttoeuhneedynid(niTigOsgCe)stnteousittsveessdtorpeoarsnogUcVend-oeuptnreoerursgeuhqoluffitarotteheebdarieagkesH Chan e tnheatcar trhbeonbubtoynldsC.arbiThteorlesfoarned, etthhaensoelreisnultthsi,s rpreoadlulcytoanrley biodegradable.
TiIohneeaatcicroueSnrsuauatlgoetef.sstteohfdTihsetpshameerotlieFracCelu-sl1ue7ld.0teCsgrsaAcdtgoauantidfniyi,ornmarheooofuwmreovtrehperer,evpuisotoelhufeysueltrhBeOy4 sDluelnttesestsitglsllycol " .* Pmoilceucruele thies aflamcotstthactertthaeinlpyerfnlotuorboiodpeogrrtaidoend.of the FC-170C TeCFhoavretohn9odi0nafctaaptvoearinstidoit2ngh4eessometfgiortCnehpeposmererettshp1or0d0ocdounumcgfsteisdrp.mrotodthTuehcdetegirwmnaheadiabelsieulritethtdyeheoTpfOecCrafltlhcfeuuoorlraUoVt--ed Tborcodubcaes.ed oTnhe fmoeramsuulraetdionTOCinffoorrmaFtCi-o1n29iswas381m3g.5%C; peirts 100 mg Calculated ToC is about 228. BmDeoacttaauhsoSeihnegaotfst,otheadCwauesattkohmeesaernds raeinsndaalptprsreogputroliaatotuoerry TP0raCogdemuncecttiheosEdnwvuoisureloddn,melwnietkaelalrye Pmolrteintbeiropdreegtradtahbelsee rtheasnalttsheayndacttuhailnklythaarte. these products are
EAR/mb
Attachment: OECD Screening Tests on FC-170C and FC-129 000369
i
Ei
tele tor
cr cc
ald 5%
RES &COE NSULA TINR GCOMC PANH Y AG
i
pwftetone x
P Wo bp ergede
a ee Net--
PROJECT 034244
.
=
=
READY BIODEGRADABILITY
i)
5
"MODIFIED OECD SCREENING TEST
For Fuaomas FEE|
id
A
Bi a
wt
3
il
"
REPORT
A ki
A
Jii
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PhoP.n0e. 06B1ox/ 9C8H-45425.252 ItTienlgeexn 96S6wit1z3e6rlRaCnCdCH
4
000370
i
RFCLCUORPARDOJEFCCT-120934244
CONTENTS
PREFACE 1 INTRODUCTION
2
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|i
Page
h
+i
3
i
i1
a
i
2.1 Chemicals
2.2 Experimental design
:
a
i
a
1
3 RESULTS
s
I
3.1 Degradation of test compound
5
4
3.2 Degradation of standard compound (aniline)
s
4 concLuston
5 REFERENCE
a
s TABLES AND FIGURES
s
;
s
|
611
"
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i
ii
:i
ii :
i
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1
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000371
ik RCC PROJECT 034244
TY
`
Project
spor
sty monitor
o3az0a
P1FosrtSfayacrnhis6a4,n3 s bo ems
| 3
He
|I
|I
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:
||
4
resting amity nec | Research and Consulting Company AG
|
I A I| CH-4452 Itingen/Switzerland
Hi
Date Hy % 19847 hoh
i
sestasens manietanin! gah eriotien
||
Start of experiments August 17, 1984
|
Suen 08 comiasion , "sven 15, 190
renting
Stanndnatien, proseoceht, resort, Co |
Srweeern ane Cansuting company 45
000372
|
- FRCLCUORPARDOJEFCCT-120934244
a
ii
1 INTRODUCTION
dTheegroabdjaebcitliitvyesofofFLtUheORApDrasFaCn-t129tesitn waer2e8 dtaoysfobliloodwastrhaedabtiio-on tfelsatsksby byfoclolloowriingmettrhiec DmOCethoofdsthe chemical in the incubation
2 MATERIALS AND METHODS
+
2.1 Chemicals
The following chamicals were tested
Standard compound:
APunriiltiyn:e 99.5 %
Test compound
Fluorad FC-129
Campasition.
PcaortbaosxsyiluamtefluoroSOalk%yl +
uaButteyrl giyeel Ethanol
2168 71 Cackibol az
=~
Batch: 2304
|
uater solubility
'2 9/1 at 25 degrees cantigrade
|
The test chemical was supplied by 3M Deutschland GmbH, on
li I
July 10, 1984
2.2 Experimental design
The study was run according to the OECD method (1)
i
|
000373
FRCLCUORPARDOJEFCCT-120534244
3 RESULTS
5
i;
I
:
3.1 Degradation of test compound
ifi
FTihegurreesults are presented in Sample Form Sheet No 1 and.
I: |
3.2 Degradation of standard compound (aniline)
i| i
FThiegurreas2ults are presented in Sample Fhorm Sheat No 2 and
H;
4 concLuszon
fi|
97% conditions within 28 days to 90 %
The standard, aniline, was degraded within seven days to
i! ir
The compound is considered to be readily desradsable
|
S REFERENCE
it
3O0E1CDE:Gui"dReelaidnyeBifoodregtreaidtaibniglitoyf.CheMmodiicfailesd OECD Screening Test
i
:i df
>
i i
000374
|
RFeLeUORPARDOJEFCCT-120934244
5
;
SAMPLE FORM SHEET FOR THE MODIFIED OECD SCREENING TEST. NO 1
TDeatset/Sotfansdtaarrdt moaftetreisatl.. Theoretical test canc
FAluugoursatd 17F,E-1129984 19.8 mg C/1
a
CIanrocbuolnuma:nals(yesAce.RrA:-BeifrfTaleiucghe,nnitTchoaonrfuiAalu,tdoommCneh)asltyiscerse1w1a,ge
plant SNLpa ow
-- Pg,
A
Method-No. 451-75 U
#1
Oranie
carton
er cancant of test material. 100
t mg teste materia, l Swepd itese
| |
correspond to: 13.5 mg organic carbon =
= kat
e S20tocmkl/1s0o0l0utimoln ofofnutthreietnetst somlauttee iroina)l (734.5 mg/100 ml, dilution P AperAoT se
B. Carbon determinations
:
Pewid
Cr oe |
CultTureTmedTium a Nloask Amnaallvyaseess TchoTehneocorr
:
hae e*n* amragf/etLenr xandanys
0,
i
ilfWiIer, |
ceoeseseeeeeeeeee
TmgL/l 00 0 (CO 77 M 14 2 21 27. z2e9 vi ll
atsneodsltutwiimotanhterwiiatlh 1 tnoculum
ai
19.8 17.5 *s* "3.3 3.6 38 4.0
22 19.8 17.6 ee 41 41 40 37
A
atea2
mie----- 19.8 17.6 **s 3.7 3.9 3.9 3.9
|
: | bi =.19.8 17.7 sss 3.8 3.6 4.1 3.6
i
2
b2
19.8 17.7 ++ 3.8 3.5 4.2 3.6
H
soe m2e---S 19.8 17.7 eee 38 3.6 42 34
I
Mstieosnlteurtaimloantenruwitiartliheonutt but with
Blank
S ccalra he e- 0173m D21.L78 D 11e .82 S 11.14 R n 21..46S21.19
k
inoculum
[EcEl3+Ec2
1.0 23 15 13 20 202
Value determined with carbon analyser
o ALL DOC values determined after centrifugation
+++ Samples lost during analysis
|
000375
RFCLCloRPARDOJEFCC.T130534244
Sample form sheet No. 1 cont
: Evalustion of raw data
'
|
I
y
Filask
P# 0GEa0psranaavalatierow
mTBiiOnCoencseosncentrations toe TaoiEimTd i vw ee er ae |
|
202. 1. zm mo2tl-ml3t 400 wee ss me 8 90 i! |
mean D =
o
oo
--meaeat
+++ 87 85 88 90 4H|
for day x
++ Samples lost during analysis i
i
|
;
|
|
|
ili||
000376
Al
Ee "Rec PROJECT 034244
8
SAMPLE FORMSHEET FOR THE MODIFIED OECD SCREENING TEST. NO 2
TTDeahsteieorSeottfaincsdatalarrdttenomtfatestreosietam.ls Inoculum ssc. Efluent
Aanufgiuiscte 17, 1984 of a domestic sen1c9g.n4 0MasCt1
|
Carbon analTyhaRear-birTMaearttgph,noidTc-honenarusAl4u5to5tu7ma0lyser 11,
A: cOorrgraensipconcdarbtao.n 5co7n4tenmst oofrestaerset emaatteorniiald. 100 mg test material
i
Stock solution of the test material (25 nasi)
3. Garten determinations
Bulture metton
Folnask
analyses owThnieeor
Dac sx oem 7
Waetrttaen
dnp a
a
i||
aosMnionanlteirtwraiCaeloanntneuwnititarlhient 1 Treceiin
a1 2
194 124 0 24 12 18 19 194 19 24 18 1a 14 23
i
|
maSin ee 2 a2 20 12 1 24
A |
2
sve TR IIE 2s 194 109 27 16 14 10 24
|i
02b-12e0b2 asa 11s 29 17 17 19 24
i| |
FSFiooloaurtrailotnnewoitstihoonust Blank
TTI ITI 07 27 18 14 24 24
|||
frecuiin
wPSo L025 1s 1a 20 20.
I:
SES
2
ns
I
. Value calculated
|
*+ ALL DOC valuss determined after centrifugation
i
i
000377
-
"RACNCILIPNREOJECT 034244
'
Sample forashestlo. 2 cont
hFolank
#Tx 0d0Ea0ysenaaual
sitar yw
| i|
nSDiOenCne-stcaoncentrations POBt onwiT eeae 00100 9 100 00 99 ||
2a m2t-n3e 2 D2 4 ---aiil 100 94 98 96 100 99
i
!i
ean po. o2i2e 97 97 58 100 9s
i for day x II
. i
|
:
;>
i
000378
||
on
Hi i
i: Ee ii\ i al
aLerrlLi Hi a7g|
1 : i Hli 1 i ro
al
Ho esn]|hl .Tiy | TaHi i 7 i Jin
7 ; | i y n p---
TR
i 0 i hio | i | i a A
| uo he
hee o LlL !
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7
pl |
al
I = on |
Sheet!
[mopoffct2e
TTTTT 1
[C 150B %FF CSOi LID7 S: SO2N(C2HE)| C_ Ha_C| 00Ke|
[_11/91NOTE:CARBONRATIOSAREC4,C5,C6,07,08=2.5%05% 3% 2% 42%|
|
[21a%Bu --t -- v [ [ ic --eT osoT vel
[eewarer [1]
[a%emanor
1
[1
1
TT
1
|FRacON JoowPonents|
| Iw |MWCARBON[%Carbon |
|___42.00%|ceF17so|aN(C6o23H] EIC1H4a2]C000.K71s%
| 2.00%|c7FisSOoN(| CoHs57)3I] CH213C20] 0-0.K46s%
[__.00%[CeF13S02| N(Ca5H235] )OH1220C] 000.K69e%]
[__0.50%[CSF11SO2|N(C427H3]5)O1H028]C000.K11e%]
[__2.50%[caroso| aN(Co4H23s] )CHoaec000.K57s%
[ 1a%|caHoOC|H|2CH1P62O]CH2oOe]H?8O.30H%]
[_aw [ l| om [ao 6]re 24o2n .00%
[_sewlwarer | 1 48]
of 0.00%
[Coooowfroras| 11
|
| 21.00%
f
.
Page 1
000381
