Document 3J1jJ6Zoxp7N7Bje9qBn3DwYn

HAZARD COMMUNICATION DE 008356 I Union Carbide Chemicals and Plastics Inc., Solvents and Coatings Materials Division, Brownsville, Texas Facility, is firmly committed to providing all of its employees with a safe and healthy work environment. It is a matter of company policy to provide our employees with information about hazardous chemicals on the worksite through our hazard communication program, which includes container labeling. Material Safety Data Sheets (MSDSs) and employee information/traini-ng. Ms. Belia Cortez (Site Managerl and Mr. Dub Garnett (Environmental Project Manager will have the overall responsibility for coordinating the hazard communication program for Union Carbide's Brownsville. Texas Facility. Ms. Cortez and/or Mr. Garnett will make our written hazard communication program available, upon request, to employees, their designated representatives, the Assistant Secretary of Labor for Occupational Safety and Health and the Director of the National Institute for Occupational Safety and Health. LIST OF HAZARDOUS CHEMICALS Mr. Garnett will compile a list of all hazardous chemicals that will be used on the worksite by reviewing container labels and Material Safety Data Sheets. The list will be updated as necessary. It will be kept by Mr. Garnett in his office in the bookcase and will be readily available for any employee or contractor as needed. (See attached list of hazardous chemicals.) LABELING It is the policy of this company to ensure that each container of hazardous chemicals on a jobsite is properly labeled. The labels will list: o The contents of the container o Appropriate hazard warnings; and o The name and address of the manufacturer, importer or other responsible party To further ensure that employees are aware of the chemical hazards of materials used in their work areas, it is our policy to label all secondary containers. Secondary containers will be labeled with either an extra copy of the manufacturer's label, or with a sign or generic label that lists the container's contents and appropriate hazard warnings. This responsibility has been assigned to Mr. Dub Garnett. DE 008357 HAZARD COMMUNICATION-Pg. 2 MATERIAL SAFETY DATA SHEETS Copies of Material Safety Data Sheets for all hazardous chemicals to which employees may be exposed are kept in the bookcase located in Mr. Dub Garnett's office and are readily accessible to employees in the work area during each work day. Mr. Dub Garnett is responsible for obtaining, maintaining and updating the file to Material Safety Data Sheets. EMPLOYEE TRAINING Employees are to attend a training sesion on hazardous chemicals in their work area at the time of their initial work assignment. The training sesion will cover the following: o An overview of the hazard communication requirements o A review of the chemicals present in their workplace operations. o The location and availability of our written communication program, a list of hazardous chemicals and Material Safety Data Sheets. o Methods and observation techniques that may be used to detect the presence or release of hazardous chemicals in the work area. o The physical hazards of the chemicals in the work area. o The health hazards of the chemicals in the work area, including signs and symptons of exposure and any medical condition known to be aggravated by exposure to the chemical. o How to lessen or prevent exposure to hazardous workplace chemicals by using good work practices, personal protective equipment, etc. o Emergency procedures to follow if employees are exposed to hazardous chemicals. o An explanation of our hazard communication program, including how to read labels and Material Safety Data Sheets to obtain appropriate hazard information. When a new type of product is introduced into a work area or the chemical composition of a product changes, Mr. Dub Garnett will review the above items as they are related to the new chemicals. NON-ROUTINE TASKS Periodically employees are required to perform non-routine tasks. Prior to starting work on such projects, each affected employee will be informed by Mr, Dub Garnett about hazards to which they may be exposed and appropriate protective and safety measures. PE 008358 HAZARD COMMUNICATION Pg. 3 INFORMING OTHER EMPLOYERS To ensure that the employees of other contractors have access to information on the hazardous chemicals at a jobsite, it is the responsibility of Mr, Dub Garnett to provide the other contractors the following information: o Where the MSDSs are available; o The name and location of the hazardous chemicals to which their employees may be exposed and any appropriate protective measures required to minimize their exposure; and o an explanation of the labeling system used at the jobsite Each contractor bringing chemicals onto a jobsite must provide us with the appropriate hazard information on those substances to which our own employees may be exposed to on a jobsite. Belia Cortez Site Manager DE 008359 EMPLOYEE TRAINING PROGRAM Our employee training program has been developed on the basis of groups or types of hazardous chemicals used and the common hazards associated with the group or type of chemicals. (See the chapter in this manual entitled "Common Hazards on Construction Sites.") For specific hazard information on individual substances, the Material Safety Data Sheets (MSDSs) must be reviewed. The training will cover the following: 1. An overview of the hazard communication requirements. 2. A review of the chemicals present on jobsites 3. The location, availability and contents of our written hazard communication program and MSDSs. 4. How to detect the release or presence of hazardous chemicals in the work area. 5. Physical and health hazards of the chemicals in the work area. 6. How to lessen or prevent exposure to hazardous chemicals by using good work practices, personal protective equipment, etc. 7. Emergency and first aid procedures. 8. How to read labels and MSDSs to obtain hazard information. 9. The location of MSDSs. OVERVIEW OF THE HAZARD COMMUNICATION REQUIREMENTS The Hazard Communication Standard (HAZCOM) is intended to ensure that both employers and employees are aware of potential hazards associated with chemicals in their work places. CHEMICALS ON JOBSITES We use a variety of products. Many of these products contain one or more hazardous chemicals. Most of the products we use can be grouped by their basic function or use. We will discuss which products fit in each group and will identify the associated hazards and how to detect and control them through engineering or administrative controls, as well as through the use of personal protective equipment. A list of the chemicals potentially found on our sites is attached to our written hazard communication program. WRITTEN HAZARD COMMUNICATION PROGRAM We have a written program that outlines how we will provide you with information about hazardous workplace chemicals. It is our company policy on hazardous substances. Among other things, it includes: o a list of hazardous substances on our jobsites o our procedures for maintaining MSDSs o our employee training program o a statement outlining how information will be exchanged among contractors on our worksites PHYSICAL AND HEALTH HAZARDS OF WORKPLACE CHEMCIALS You will be trained about the hazards of chemicals in your work areas. The training will include the following information: o the measures you can take to protect yourself from the hazards; o our company procedures that provide you with protections, such as work practices, personal protective equipment, engineering controls, etc. o the physical and health effects of the (groups) of chemicals; o how to detect the presence of a chemical; and o general emergency and first aid procedures HOW TO READ LABELS AND MATERIAL SAFETY DATA SHEETS Labels: you should read product labels before working with a hazardous substance. Each label will have the identity of the hazardous chemical and a hazard warning. Original container labels will also have the name and address of the manufacturer. The label should serve as a reminder of the information we are presenting in this training session and of the information found in no more detail on the Material Safety Data Sheet. It is essential that you read the hazard warning and use the chemical as prescribed by the label. If you have questions about a specific label, ask your supervisor or refer to the MSDSs. Material Safety Data Sheets: MSDSs provide a great deal of information about the chemicals we use. The chemical manufacturers are responsible for providing us the MSDSs. MSDSs for chemicals potentially found on our worksites are available from Mr. Dub SarpAtt,------- the,material__ Safety Data Sheets are located in his Qf-f.tS.Qi DE 008361 ITTXic WAH^ B3LE CAUTION [MICALS FLAMifl \ HAZARDOUS Cl WARNING MAX/ J.E CAUTION TOXK iCALS FLAMMAOl Hazar< ommunicatl JZARDOUS CHETtfXIC WARNING- ON TOXIC WA A Guide for the Construction industry MMABLE CA LHEMICAl S iRDOUS KIC w `IF rA Meeting the Occupational Safety and Health linistration's Mandate A American Subcontractors Association, Inc. he AUnOv'twrffAMmm Associated Builders and Contractors, Inc. National Association of Home Builders DE 008362 Table of Contents Introduction to the OSHA Hazard Communication Standard ........................................................................... Page I Common Hazards on Construction Sites .................................................................................................................. Page 4 Your Written Hazard Communication Program ..................................................................................................... Page 8 Employee Training ............................................................................................................................................. Page 11 How to Read and Understand an MSDS .................................................................................................................. Page 13 Contractors' Obligation under EPA's Community Right-to-Know Regulations ........................................... Page 19 Hazard Communication Compliance Checklist....................................................................................................... Page 34 "What If... " Answers to Anticipated Problems ................................................................................................. Page 35 Federal HazCom Assistance and State Enforcement ..................................................................................... :... page 37 Sample Forms and Letters .............................................................................................................................................. Page 40 Text of Hazard Communication Standard -- FederalRegister Publication ......................................... Page 47 Glossary ................................................................................................................................................................................ Page 83 \ DE 008363 Foreword The associations participating in publication of this guide to compliance with the Hazard Communication Standard are indebted to Terence J. Burke and Lois Phillips of the law firm, Herzog, Engstrom, Burke, Koplovitz, Cavalier & Lyman in Albany. N.Y. This firm serves as chapter attorney for the Northeastern Subcontractors Association, a chapter affiliated with the American Subcontractors Association. Burke and Phillips did the original research and writing. The generous contribution of their professional expertise helped make this manual possible. construction industry. Ov ofthe contentions in this bttfonon u that compliance tk the HazardCommunication Standard, as presently nnni u tnfeesibfe in the conurucnon industry. While this manual represents ourbestpossible odnee as to how a construction company should attempt to comply with the standard, contractors should consult ifft appropriate counselfor advice as to thetr compliance obfigeaons under the starred DE 008364 CHAPTER ONE Introduction to the OSHA Hazard Communication Standard The U.S. Department of Labor's Occupational Safety and Health Administration (OSHA) has issued a new standard which affects every single contractor and builder in the construction industry. The rule is called the Hazard Communication Standard (or "HazCom" for short), and it requires all contractors to educate their employees about the hazardous chemicals they are exposed to in the work place and the methods necessary to protect themselves. Many contractors are under the mistaken impression that they don't have many hazardous chemicals in the work place, but the term "hazardous chemical" applies to every thing from paint to concrete to wood dust Contractors also will be very unused to complying with a "performancebased" regulation such as HazCom. Unlike other OSHA standards which generally require contractors to follow certain guidelines to ensure a safe workplace, HazCom will require contractors to inventory the chemicals used by their own employees and then train them about the dangers associated with those chemicals. While it is natural for most business owners to put off dealing with government regulations, the time has come for hazard communication. Considering the construction industry's past problems with such substances as asbestos, hazard communication--done properly--oould save you thousands of dollars in fines and protect you from possible liability suits from your employees. Compliance with HazCom will not be a simple task and will require a commitment of your time. Above all, you must make a good faith effort to comply and be prepared to document it. ' This manual has been designed with the construction contractor in mind, and the sample programs and forms have been designed for the average construction firm. Don't let the subject matter intimidate you. While HazCom was designed to protect your employees, this manual was designed to help you comply with as few headaches as possible. What am / required to do? You will need to train all employees who may be exposed to hazardous chemicals about the dangers assoc iated with those chemicals and the protective measures they need to take. Under HazCom, there are four major elements of compliance: 1. Material Safety Data Sheets (MSDSs) 2. Labels 3. Employee Training 4. A Written Hazard Communication Program Material Safety Data Sheets (MSDSs) Your first step toward compliance is to make sure you have an MSDS for every hazardous substance you use. Since September 1987, you should have been receiving MSDSs with every shipment of hazardous substances. (See - the chapter entitled "Common Hazards on Construction Sites") It is the responsibility of suppiiers/distributors to provide MSDSs with the products they are selling. Nonethe less, you still may have trouble getting the MSDSs from suppliers who are unaware of their responsibilities. If you don't receive an MSDS with a shipment, it's your responsi bility to ask for one. How do you know if a product requires an MSDS? If it is tagged or labeled with any key words such as "danger." "caution," "flammable," "warning," etc., that is a signal to you to get an MSDS from the supplier. Put any requests to a supplier for an MSDS in writing. This will be part of your good faith effort to comply should you get inspected by OSHA. (See the chapter entitled "Sample Forms and Letters") In order to simplify this process, you may want to designate one employee to coordinate your compliance efforts. That person should set up a system to collect all incoming MSDSs and set up an easily understood filing and retrieval system. Without an organized system, you could easily be overwhelmed with paper. The MSDSs will vary in length from two to twenty pages, depending on the make-up of the substance. These documents should give you a complete breakdown on the hazards associated with the products you are using and will be a key to effective employee training. (See the chapter entitled "How to Read and Understand an MSDS") One note of caution if your supplier lends to be a retail outlet, such as a hardware store or a lumber yard: retailers only have to supply MSDSs to customers who have commercial accounts. For all other customers, the retailer must supply the address and telephone number of the manufacturer from which an MSDS can be obtained. It will be a smart move to get into the habit of automatically asking for MSDSs with your purchases if you have a commercial account or the address and telephone number if you don't have an account. Once you have an MSDS on a product, though, it's not necessary to get one with every shipment of that product. You only need to obtain another one if the chemical make-up of the product changes. OSHA does urge all employers who have difficulty obtaining MSDSs from suppliers and/or manufacturers to As noted m theforeword to this manual the participating associations are presently involvedin a legalchallenge to the Hatard Communication Standard Pending the resolution ofthis htiganon. the participating associations make no warranty that the information contained herein will necessarily he accepted by OSHA contict their local OSHA office for assistance. Again, keep careful documentation of all correspondence with suppliers and manufacturers, as well as correspondence with your local OSHA office. Once all of your MSDSs have been assembled, you must keep copies of them at a central location on all jobsites, such as trailers or trades. All employees must be made aware of the location and be given access to the MSDSs upon request They are for their benefit as well as yours. Labels You will also need to make sure that every incoming hazardous product has a label identifying the chemical with appropriate hazard warnings. You will be able to use the MSDSs and the labels as a check on one another. If a product has a warning label, but no MSDS or vice versa, you will need to request either the label or MSDS from the supplier. As with MSDSs, make sure all requests for labels are carefully documented. Labels on the products must be in English, easily understandable, and not defaced. The product labels will essentially be a synopsis of the MSDSs, but they should never be considered to be a substitute for MSDSs. The label will be the employee's immediate source of information, with the MSDS as a backup. If a hazardous substance is transferred into a portable container to be used by several employees or on several shifts, each portable container must be appropriately labeled with the hazard information from its source. For instance, if paint is transferred from a large drum into smaller containers which are not labeled, then you must label those containerswith the hazard warnings from the drum. However, if the person making the transfer is going to use the substance immediately, no labeling is required on the portable container. When you review the labels, determine whether your employees will understand the symbols and terminology used. You will need to provide an explanation of the labeling system to your employees during training. It's a good bet if you can't figure it out, then your employees won't be able to either, so contact the supplier or manufac turer for assistance. Should an emergency occur, the label will be the first thing the employee looks at, so it should say what to do in an emergency. The word "danger" on the label, without more explanation, won't help after an accident occurs. Employee Training Once you have your MSDS and labeling system in place, you'll need to transmit this information to your employees. Who has to be trained? Remember, you must inform and train not only those employees actually exposed to hazardous substances during their routine job duties, but also any employee who could potentially be exposed from unexpected releases or emergency situations. For example, an employee who only handles sealed containers of chemi cals and normally would not be exposed, may become exposed to a hazard if the container leaks or spills. Likewise, an office worker may not be exposed to hazards in the office, but may be exposed if he or she routinely goes on site to deliver messages, etc. Generally, office personnel will not be required to be trained, since office products are not classified as hazardous substances. However, if there is an employee who is principally responsible for the copying machine and handles the chemicals associated with it, then they would have to be trained about the dangers. To actually train your employees-about the hazards of every site they are working on may seem like a monumental task, particularly if you have hundreds of chemicals. You are allowed to train your employees by chemical categories (See the chapter entitled "Employee Training.")You are not expected to have a chemist's knowledge about hazard ous substances. Your task is to make your employees aware of what they are working with. That means telling them: 1. How to spot hazards; 2. What the physical and health hazards are of that chemical (See the chapter "Common Hazards on Construction Sites."); 3. What they need to do to protect themselves; 4. What they need to do in an emergency: 5. The location and content of your company's written hazard communication program (to be discussed next). You or your designated representative must train employ ees before they are exposed to a hazardous substance. Even if an employee says he was trained already on the substance by another employer, you should do it again since he is now your employee and your responsibility. You should also stress to your employees that they have an important role in making this program work. It may be wise to conduct the training right after an employee has completed his tax and immigration forms, and then have him "signoff" that he has received the hazard communication training. (See the chapter entitled "Sample Forms and Letters.*') Written Hazard Communication Program Under HazCom, you are also required to have a written hazard communication program for your company. This is also very important because during an OSHA inspection, it is likely to be one of the first things the inspector is going to ask to see. Essentially, the written program is a description of everything you are doing to comply with HazCom. It must also be made available to employees and employee representatives should they ask to see it. The written program has to be maintained at all of your jobsites. Basically, the written program must outline how you are going to meet your MSDS, labeling and training responsibil ities. (See chapter entitled "Sample Written Hazard Com munication Program") Your written program must also contain your inventory list of chemicals used on your jobsites. You need to reference them as they appear on the MSDS, but, for your own understanding, you may want to -) DE 008366 list the chemical ind common names of the substances. This will help with any updating you will eventually need to do. The program must also deal with how you will meet your responsibilities on multi-employer jobsites, i.e. most construction sites. What are my responsibilities to other contractors on site? Probably the most difficult part of compliance for contractors will be the multi-employer worksite require ments of HazCom. This provision requires you to inform your employees about the hazards they may be exposed to by other contractors working on the same site. Under the multi-employer requirements, you must obtain from other contractors working in the same area of the site at the same time as your employees: 1. The MSDSs for the products the other contractors are using around your employees or find out the location of their MSDSs on site; 2. An explanation of the labeling system other contractors are using; 3. Information about the precautionary measures your employees need to take to protect themselves during normal operating conditions and in emergencies. The coordination of this process will be left to the individual contractors, but it may be wise to try and find out who the other contractors will be on a jobsite before work begins. You should then contact those other contractors and ask them for the appropriate information. U will probably be easier to make contact before a job begins because employees of different contractors are always coming and going once the job begins. In addition, you must include this information in your own training of your employees, and the steps you take to comply with the multi-employer require ments must be outlined in your written hazard com munication program. (See the chapter entitled "Sample Written Hazard Communication Program") Is that all? Hazard communication isn't a one-shot deal. This is going to be an ongoing process as long as you are in business. Considering the nnmfrftt employees who pass through this, industry, you' wili probably bey..->conducting employee training fairly frequently. In addi tion, every time a new hazard is introduced in the workplace, you will also need to do training on that substance.The same is true if a product's chemical make-up changes. You'll know when that happens because your supplier should send a new MSDS on the product. Ail contractors will be relying on one another to get the appropriate information to train their own employees. If you don't prepare your own company, you'll run the risk of forcing other contractors into non-compliance The following chapters will help you develop your hazard communication program by discussing each of the main elements in more detail. In addition, there will be helpful hints and answers to the many questions that will no doubt come to mind. Once you have gone through the manual, you'll then want to read the "What If..." chapter, which will help you anticipate problems on die jobsite. \ i 3 DE 008367 CHAPTER TWO Common Hazards on Construction Sites One of the most time-consuming tasks you will face in getting your company ready for HazCom will be trying to inventory all the chemicals that you use. Trades that use fewer hazardous substances will find the process easier. Since no contractor, even one in the same trade, will be using the same products as another, there is no standard method or shortcut for doing the inventory. How Do I Know What Hazardous Chemicals / Use? Builders and contractors are not required to determine which of their products are covered by HazCom. Hazard determination is the responsibility of the product's manu facturer, distributor or importer. If a product is accompanied by a Material Safety Data Sheet (MSDS), then you are on notice that it is made up of one or more hazardous chemicals. Another due is if the label contains any of the key "danger" words such as "caution," "flammable," "warning," "corrosive," "irritant," "toxic," etc. If you spot such words, you should already have an MSDS for the product If not contact the supplier or manufacturer for one. For each one of these products, you will need to identify. 1. How to spot the presence or release of the chemicai(s); 2. Any physical or health hazards associated with it 3. Any protective measures an employee needs to take while working with the product 4. Emergency procedures necessary in case of an accident All of this information can be found on the MSDS accompanying the product However, since some MSDSs can be quite lengthy, you may have to sort through some of the excess information that manufacturers may supply on the forms. When you review the hazards of the products you are using, you should note the difference between a physical and a health hazard. A substance presents a physical hazard if it is flammable, explosive or reactive. A substance presents a health hazard if exposure to it can cause acute (immediate) or chronic Gong-term) health problems in a person exposed to it This may seem like an enormous amount of information if you're dealing with hundreds of products that can be potentially classified as "hazardous." Indeed, it will be a time-consuming task, but it won't be necessary to go through all of this information on each substance when you train your employees. OSHA does allow you to train in categories and most of your products will fan into a few categories. In other words, many products will be handled in the same manner. However, many products will also fall into more than one category, so you need to make sure you include it in each discussion of every category it fits in. Once you have identified which of the products you use are hazardous, you should be able to classify them in categories. Generally, most hazardous substances used on construction sites will fall into one or more of the following categories: 1. Flammables and combustibles 2. Compressed gases 3. Toxins (Systemic poisons, dusts, fumes, corrosives, irritants) Flammables and Combustibles Obviously the main physical hazards posed by prodv ts in this category are their ability to cause fires and-or explosions. Some of the most obvious examples are kerosene, gasoline and alcohol, but there are also unfamiliar chemicals which also fall into this category, such as heptane, benzene and acetone. Many times these unfamiliar names are present in common products such as paints, glues and sealants. These products could also present health hazards as well, if there is prolonged exposure. When you discuss the flammable nature of products in this category while training your employees, you should particularly discuss which ones present bigger threats. In addition, you should wam them about tools or actions that may ignite flammable products such as welding tools, torches or cigarette smoking. It is also important to instruct employees about the proper ventilation necessary when using these products and the importance of cleaning up spills quickly. You should also note that some flammables give off invisible vapors which can accumulate and/or travel (example: certain types of glues). These vapors can be ignited by sparks or beat, such as from power tools, and can cause serious injury and damage. Compressed Gases Of all the hazardous substances present on construction sites, compressed gases are the easiest to spot because they are packaged in steel cylinders. Generally, products such as oxygen, LP gas, freon and hydrogen are packaged as compressed gases. One of the biggest dangers of compressed gases involves damage to those cylinders. If the valve stem of a cylinder breaks or is sheared ofT, the cylinder could literally take ofT like a rocket or a torpedo. In addition, some compressed gases may present a fire hazard if their cylinders leak. Others may actually remove oxygen from the air. It is important to read the individual labels and As noted in theforeword to this manual, the participating associations are presently involved in a fetal challenge to the Haiard Communication Standard Pending the resolunon of this brigaaon. the pamcipanng essocunons make no warranty that the information contained herein hiIt necessanh he accepted hi OSHA DE 008368 MSDSs on compressed gases. When training employees on compressed gases, they should be informed about the potential hazards and the proper storage, handling and emergency procedures associated with these gases. Toxins Toxins are a general dass of substances which can pose a health hazard to those using them. However,just because a substance is toxic, this does not automatically mean it is a significant health threat A toxin is any substance which may harm the body, but it is important to consider the concentration of the chemical and the length of exposure. The MSDS accompanying toxins should tell you the acceptable limits of exposure, and that is the key to proper usage without harm to the employee. Toxins should not be grouped into one massive category, because of the sheer number of them present on construction sites and their wide variety. Your particular trade may require additional categories for products unique to your trade, but toxins can usually be grouped in the following classes: 1. Systemic Poisons 2. Corrosives 3. Irritants, Dusts and Fumes Systemic Poisons A systemic poison is a chemical which can cause serious damage to an organ or system of the body, such as the liver or nervous system. Exposure to these substances is usually through breathing, but they can also be swallowed or absorbed through the skin. Systemic poisons are often in the form of harmful vapors and gases and, when they are breathed in by an employee, can pass through the lungs and into the blood stream, thereby attacking an organ or system of the body. The most deadly aspect about many of these poisons is that it may take years for the employee to experience the side effects. That is why it is important for employees to take precautionary measures when working with them. . Systemic poisons can have more immediate and notice able effects if an employee should accidentally get them on his skin. This can occur with many solvents used on construction sites. The poison may pass through the skin and into the body. In addition, you should also caution employees about the effects of swallowing these poisons. This can happen if employees don't carefully wash them selves before eating, drinking or smoking. Corrosives A product is a corrosive if it falls into the group of chemicals which damage the body on contact. The most obvious example for construction is the assortment of acids used in many trades, btjt simple items such as cleaning products and paint remover can also be corrosives. Wet concrete also is a skin corrosive. The most important points to stress when training employees about corrosives are how to eliminate exposures and how to wear protective gear which guards the skin, lung, nasal passages, and the eyes. Emergency procedures should also be emphasized because of the immediate effects of corrosives should there be an accident. These precautions should also be stated on the labels of the products. Irritants, Dusts and Fumes Of all of the toxins, irritants are the least harmful but damaging nonetheless. Like systemic poisons, irritants can have a harmful effect on the lungs and other organs. Like corrosives, they also can have a harmful effect on skin and eyes. Generally, a product is an irritant instead of a poison or corrosive if it is in a smaller quantity or concentration. Employees should take the same precautions against irritants as they do with poisons and corrosives, and training should stress proper protective gear and adequate ventilation. As with all toxins, employees should stop work immediately if they feel ill when they are working with these products. They should then check the label of the product they are working with for first aid information. Wood dust, sand and cement give off deadly dusts which can then accumulate in the lungs and nose and damage the eyes. These are nuisance dusts, but some can cause chronic health problems. It is important that employees know of protective gear they should wear when performing oper ations such as sanding, grinding and mixing. In some cases involving systemic poisons, gloves and/or respirators may be necessary. As always, the best reference will be the MSDS. In addition, you will need to indude these dusts and fumes in your inventory list of hazardous products attached to your written HazCom program. Are There Any Substances / Can Exclude from Training? In general, there are two classes of products which don't have to be included in your hazard communication train ing: articles and consumer products. However, these exemp tions have been carefully and narrowly crafted by OSHA. So before you assume anything is exempted from the standard, take careful note of the following definitions of these exemptions. Articles An article is generally a solid product which is already in its end form when it is used on a construction site and doesn't release hazardous substances under normal condi tions of use. Pipes, wood, glass, tools and insulation are all articles. One problem with the article exemption is what happens when you cut or form those products during the course of work. The wood will give off wood dust, the glass will give off fragments, insulation can give off fibers, etc. Another problem is with materials such as particleboard, which gives off molecular amounts of formaldehyde even when they are not cut. If there is a hazard associated with these products, then your distributor should send an MSDS with it when you purchase it. When you receive a lumber shipment, you should get an MSDS on the dangers associated with wood dust. You don't need to train your employees about the 5 DE 008369 dingers of wood, just wood dust Don't overreict to this by including everything under the sun in your training pro gram. Items such as doors, tables, saws and drills are articles, period. Consumer Products Many common consumer products also do not have to be included in your hazard communication program, but a great deal depends on how you use them in the work place. Many products found at local hardware stores and retail outlets that are used by contractors can be considerai consumer products. However, you may exempt them from your program only if they are packaged in the same form and concentration as Joe Consumer can purchase them, and only if you use the products for the same duration and frequency as Joe Consumer uses them. In other words, if you purchase products at a hardware store but they are marked "for industrial use only," then you would still have to include the products in your HazCom program. Also, if you buy large quantities of a hazardous product at a retail outlet, then these would have to be included. Just because you bought them at a retail establishment does not automatically mean the products are exempt If there is any doubt that you may not be using these products as a consumer uses them, then you would be wise to include them in your HazCom program. Can Anyone Just Tell Me What Hazardous Substances I'm Using? A word of warning: Be wary of anyone who claims to have a standard list of everything you are using. No two construction companies will be alike, and unfortunately there are no shortcuts. Remember, OSHA designed HazCom to be a performance standard and that means you'll need to assess your own company. No one else will be-able to do it for you. Watch your labels and look for MSDSs. The following is a list of common hazardous substances often found on construction sites. It is by no means a complete list, so it should only be used as a guide. You also can use it as a model when you inventory your own company. \ DE 008370 HAZARD CATEGORIES D E 008371 Hazard Categories for Common Construction Products Mi Am MM Mtataaa VtttaMtart Im C^tePM CskvOMii CMhMmHi CM Chaw* CmI T* CMMtf Air Caartwi Pfim Mi MM r foaOl FnaNHini) GMfctt Ctainn Gtan HM tiiuw KM tawata Kataaan MM Um If Cm UWhI X X X X X X X X X X X X X X X X MM RvMtfMXX) DMriSfMh MwMcAtal Ntatal fatal Mta __________ X X X X X X X X FiMCmi fn*ni X X Cm X XX X X X X X Hkm M XX X X X X X X XXX X X X x XX XXX XX X X XX X X X X X XX XX X X XX X XX X XX X X XX XX XX X XX X DE 008372 WRITTEN HAZARD COMMUNICATION D E 008373 CHAPTER THREE Your Written Hazard Communication Program As part of HtzCom, all construction employers are required to have a written hazard communication program for their companies. This written document will be the key to complying with HazCom and will provide the frame work for managing your hazard communication program. You can think of your written program as your company's policy or operating procedure on hazardous substances. Your written program will most likely be one of the first documents that the OSHA compliance officer will want to review during an inspection of your worksite. It must be complete, accurate, current and understandable. It also must contain specific information: 1. A list of the hazardous chemicals on your worksite. (The list may be developed for the workplace as a whole, or for individual work areas. A sample inventory sheet can be found after the sample program.) 2. A statement describing how you, as an employer, will meet your obligations under HazCom for labeling, MSDSs and employee training. 3. A description of how you, as an employer, will inform employees of the hazards they might encounter when they perform non-routine tasks. 4.An explanation of how you, as an employer on a multiemployer worksite, will inform other employers about the hazardous chemicals you bring on site which are used around their employees. Your written program must state: -- how copies of MSDSs will be made available to other employers; -- how you will inform other employers of the precautionary measures that need to be taken to protect employees under normal working con-' ditions and in emergencies: and -- how you will inform other employers of the labeling system you're using on the worksite. The following few pages set out a sample written hazard communication program. It can be adopted for use by your company. Simply retype it and add the appropriate informa tion, or tailor it to your individual company. Introduction' Sample Written Hazard Communication Program_______________________________________ _________ (N,m* 01 Company) is firmly committed to providing all of its employees with a safe and healthy work environment It is a matter of company policy to provide our employees with information about hazardous chemicals on the worksite through our hazard communication program, which includes container labeling. Material Safety Data Sheets (MSDSs) and employee information/training. ----------------------fftonw-.g* pwon or position)will have the overall responsibility for coordinating the hazard communication program for(Name oi company)(Namt ot parson or portion)_________________ will make our written hazard communication program available, upon request to employees, their designated represent atives. the Assistant Secretary of Labor for Occupational Safety and Health and the Director of the National Institute for Occupational Safety and Health. List of Hazardous Chemicals ---------------- fljf* Pyy? ? p?**.*^___________ will compile a list of all hazardous chemicals that will be used on the worksite by reviewing container labels and Material Safety Data Sheets. The list will be updated as necessary. It will be kept ------------------CSSLlSP) _~(See the attached list of hazardous chemicals.) i As notedin theforeword to tkis manual, the participating associations artpresently impliedin a legalchallenge to the Haiard Communication Standard. Pending the resolution of this negation, the participating associations make no warranty that the information contained herein will necessarily be accepted hv OSHA DE 008374 Labeling It is the policy of this company to ensure that each container of hazardous chemicals on a jobsite is properly labeled. The labels will list the contents of the container appropriate hazard warnings;'and the name and address of the manufacturer, importer or other responsible party To further ensure that employees are aware of the chemical hazards of materials used in their work areas, it is our policy to label all secondary containers. Secondary containers will be labeled with either an extra copy of the manufacturer's label, or with a sign or generic label that lists the container's contents and appropriate hazard warnings. This responsibility has been assigned to is*TSSTli Material Safety Data Sheets Copies of Material Safety Data Sheets for all hazardous chemicals to which employees may be exposed are kept rioctton)and are readily accessible to employees in the work area during each work shift. (Nme ot position or tnon> j$ responsible for obtaining, maintaining and updating the tile of Material Safety Data Sheets. " ^ Employee Training Employees are to attend a training session on.hazardous chemicals in their work area at the time of their initial work assignment The training session will cover the following: An overview of the hazard communication requirements. A review of the chemicals present in their workplace operations. The location and availability of our written hazard communication program, a list of hazardous chemicals and Material Safety Data Sheets. Methods and observation techniques that may be used to detect the presence or release of hazardous chemicals in the work area. The physical hazards of the chemicals in the work area. The health hazards of the chemicals in the work area, including signs and symptoms of exposure and any medical condition known to be aggravated by exposure to the chemical. How to lessen or prevent exposure to hazardous workplace chemicals by using good work practices, personal protective equipment etc. Emergency procedures to follow if employees are exposed to hazardous chemicals. An explanation of our hazard communication program, including how to read labels and Material Safety Data Sheets to obtain appropriate hazard information. When a new type of product is introduced into a work area or the chemical composition of a product changes. (tyon or pwisw>) will review the above items as they are related to the new chemicals. Non-Routine Tasks Periodically employees are required to perform non-routine tasks. Prior to starting work on such projects, each affected employee will be informed by (prion or potion) about hazards to which they may be exposed and appropriate protective and safety measures. Informing Other Employers To ensure that the employees of other contractors have access to informatior on the hazardous chemicals at a jobsite, it is the responsibility of(psrionor portion)to provide the other contractors the following information: e where the MSDSs are available; e the name and location of the hazardous chemicals to which their employees may be exposed and any appropriate protective measures required to minimize their exposure; and an explanation of the labeling system used at the jobsite. Each contractor bringing chemicals onto a jobsite must provide us with the appropriate hazard information on those substances to which our own employees may be exposed to on a jobsite. I 9 DE 008375 INVENTORY OF HAZARDOUS CHEMICALS D E 008376 Inventory of Haiardous Chemicals Hazardous Chemical Common Name Hx2>,uLr ASfifZT#* xX*JJ muz z </4s Jc/Ajtr tiOTV SZr l 00 0/(- " " i$ A'PS /Jut'9-0 A t X0-J So ft ZofcAfi & AT A OAJK MP t '* G&S i/ju/APA A/ 2 A" $X'/C A/ Product Name 4A/6T Manufacturer PAX*?* oj?A MSDS Mm Reen Receded xX<$> ju $t A tf it i to DE 008377 Hazardous Chemical Inventory of Hazardous Chetnkab Common Name Product Name Manufacturer MSDS llaa Been Received ' .. * , * to E>E 008378 llatardoa Chemical Inventory of Hazardous Chentkih CoimiKMi Name Product Name Manufacturer MSDS 11< Keen Received * \ 10 DE 008379 MSDS D E 008380 CHAPTER FIVE How to Read and Understand an MSDS Manufacturers, importers, distributors and suppliers are required to provide you with Material Safety Data Sheets (MSDSs) for each of their hazardous chemicals. As a contractor, you are required to maintain a file of MSDSs for the hazardous chemicals you use. According to OSHA, you will be able to determine a hazardous substance by ~ referring to the MSDS and the label. The OSHA standard specifies the information required on each data sheet, and all information must be written in English. An MSDS must precede or accompany the initial shipment but does not have to be physically attached to it If you receive subsequent shipments of the same item, a new MSDS is not required to be sent to you unless the chemical make-up of the product changes. Review the MSDSs you receive for accuracy and completeness, and make sure you have the latest version on file. When an MSDS includes new information on a ' substance you use or a new compound has been added to it, additional employee training will be required. To ensure proper recordkeeping and maintenance of MSDSs, you should: 1. Make sure any employee who purchases supplies for your company is on the lookout for MSDSs. 2. Include a request for an MSDS and a label that meets the requirements of the Hazard Communication Stand ard on all purchase orders. 3. Ask for an MSDS for any material bearing a label indicating it is a hazard unless an MSDS is already on file. (See the sample letters in Chapter Ten.) 4. To deal with the multi-employer situation, you may request information from other contractors on the site about hazardous substances and chemicals known to be at the site. While MSDSs will appear in many different formats, they will contain essentially the same information. The information on an MSDS is extremely technical in nature and should be used as a reference or as a backup to information contained on a label. An MSDS tracking OSHA Form 174 (see sample, page 16) would offer the following information: Section I - Identification 1. Chemical name, as it appears on the label. 2. Manufacturer's name and address. 3. Emergency telephone number in the event of an emergency involving the substance. 4. Date prepared and the signature of the preparer. Section II - Hazardous Ingredients/Identity /reformation 1. Hazardous Components: Contains the specific chemical identity, its formula, and any common names it is known by. 2. OSHA Permissible Exposure Limits (PEL): PEL is the permissible maximum amount of the chemical a person may be safely exposed to without harm. 3. American Conference of Governmental Industrial Hygienists Threshold Limit Value (TLV): TLV is the concentration of a chemical in the air that can be breathed for five consecutive eight-hour workdays by most persons without harmful effects. It is generally expressed in parts per million. .4 Other limits recommended: Any other recommended limitation on the use of the chemical by any agency, scientific group, or organization should be included. Section III - Physical/Chemical Characteristics 1. Boiling Point: The temperature at which a liquid boils. 2. Vapor Pressure (mm Hg): Vapor pressure measures a liquid's tendency to evaporate. The higher the pressure, the fester it will evaporate. 3. Vapor Density: Indicates the weight of the vapor compared with the weight of an equal volume of air. If a vapor is heavier than air (vapor density greater than 1), it will sink to the ground. If it is lighter than air (vapor density less than I), it will rise. For example, with flammable materials, when the vapor density is greater than 1, vapors tend to collect in the lowest spot. A contractor must be alert to vapors traveling to an ignition source, then flashing back to the vapor source. Care must also be taken to ensure that vapors do not displace oxygen. 4. Solubility in Water: Indicates whether the chemical can mix with water in any ratio without separating. 5. Appearance and Odor: A brief description of the chemical's color and smell. 6. Specific Gravity: Ratio of the weight of the material to the weight of an equal volume of water. The specific gravity determines whether the material floats or sinks in water. Specific gravity values less than or equal to I indicate that water should not be used to extinguish a fire involving the substance unless the water comes from automatic sprinklers. 7. Melting Point: Indicates the temperature at which a solid changes to a liquid. 8. Evaporation Rate (Butyl Acetate = 1): Indicates the temperature at which a substance evaporates. As notedin theforeword to this manual the pamripattnf associations ore presently tnuolred in a trial challrntr to the Hasord Communication Standard Pcndiny the resolution ofthis lin/otton. the partietpattnt associations make no warranty that the information cotnamed herein will necessarily be accepted by OSHA. 13 DE 008381 Section IV - Fire and Explosion Hazard Data 1. Flash Point: Indicates the lowest temperature at which a liquid gives off enough vapor to ignite in air when exposed to a flame. When the flash point is between 100 and 110 degrees Fahrenheit, extra care must be taken in hot environments. The liquid's temperature could be high enough to be ignitable if an ijpiition source is introduced. Such sources might be cigarette smoking, electrical equipment and wiring, cutting and welding, or static electricity. A red diamood is required on all liquids classified by OSHA as flammable (flash point values of 99.9 degrees F or below). 2. Flammable Limits: IndiaUes the range of vapor concen trations which will explode when an ignition source is present The "Lower Explosive Limit" (LEL) is the minimum amount of vapor in the air that can be ignited. The "Upper Explosive Limit" (UEL) is the maximum amount of vapor in the air that will sustain fire. 3. Extinguishing Media: Materials suitable for putting out a fire involving the identified chemical. These fire fighting agents are water fog, foam, alcohol foam, carbon dioxide, and dry chemicaL The four classes of fires are: Gass A --paper, wood, straw, doth Gass B --flammable and combustible liquids Gass C --fire involving energized electrical equipment Class D --combustible metals Testing laboratories dassify fire extinguishers based on the class of fire they are designed to put out. For example: Gass A fire can be fought with water, Gass B fires with carbon dioxide, foam or dry chemical; Gass C fires with carbon dioxide or dry chemicals; Gass D fires with special extinguishing compounds. 4. Special Fire Fighting Procedures: Indicates the chem ical's special characteristics when it comes in contact with fire, such as whether it is difficult to put out; whether it will re-ignite sppntaneously; whether it is extinguished by water or other firefighting agents. This subsection will also indicate any required protective equipment needed when fighting the fire, as well as evaluate any toxidty of the material on anyone fighting the fire. 5. Unusual Fire and Explosion Hazards: Indicates any spedal types of hazards requiring attention. The description will indicate whether the chemical is difficult to extinguish, will re-ignite spontaneously, and how it reacts with water and other extinguishing agents. For example, if water is applied to a combustible liquid with a flash point above 212 degrees F, it may foam violently or boil over, endangering workers and fire fighters. Section V - Reactivity Data 1. Stability: Indicates conditions that contribute to the stability or instability of a chemical when it is exposed to heat, pressure, or excessive shock during storage, use, misuse or transport Look to this section to identify specific conditions to be avoided. These warnings, for example, may be "reacts violently with water" or "avoid sudden shock." 2. Incompatibility (materials to avoid): Indicates various materials or conditions you must keep the chemical sway from to avoid adverse reactions. For example, a substance which ignites or explodes when it comes in contact with the chemical. 3. Hazardous Decomposition or By-products: Indicates gases or vapors which are released when the chemical is burned or decomposes. It tells you what hazardous substances your employees may be exposed to as a result of beating, working or burning the chemical. 4. Hazardous polymerization: Polymerization is a chem ical reaction where molecules of the chemical combine with molecules of another material to form a larger, different material. This reaction is accompanied by the release of large amounts of energy which can produce fire or other hazards. Polymerization can occur when the chemical comes in contact with certain plastics, rubber or coatings. This section of the MSDS will indicate possible storage conditions which could result in polymerization. It will also indicate any inhibitors --chemicals which can be added to prevent or delay polymerization -- and the expected time period in which an inhibitor is used up. Section VI - Health Hazard Data 1. Route(s) of Entry: A chemical may enter the body either through inhalation, by contact with the skin or eyes, or by being swallowed. 2. Health Hazards: Indicates any long-term (chronic) or short-term (acute) effects of a chemical on the human body. 3. Carcinogenicity: Indicates whether the chemical causes cancer. It is important that your employees understand that not all hazardous substances cause cancer when an individual is exposed to them. .4 Signs and Symptoms of Exposure: Indicates and describes the effects of exposure to the chemical, such as an employee's appearance, and the most common resulting sensations, for example, headache, dizziness or nausea. 5. Medical Conditions Severely Aggravated By Exposure: Indicates how the chemical will affect any pre-existing medical conditions. 6. Emergency and First Aid Procedures: Indicates first-aid procedures to use in order to reduce the hazardous effects of the chemical. The techniques covered will deal only with inhalation of the chemical, and skin or eye contact with it You must emphasize that these are emergency procedures only, and an exposed employee should be examined by a doctor as soon as possible. td DE 008382 Section VH Precautions for Safe Handling and Use 1. Steps to be Taken in Case Material is Released or Spilled: Indicates precautions such as avoid breathing gases and vapors; avoid contact with liquids and solids; remove ignition sources; use of special equipment for dean ups. This section abo gives recommended tech* niques to use in controlling land or water spills. 2. Waste Disposal Methods: Indicates proper disposal of the chemical and contaminated materials. 3. Precautions to Take in Handling and Storing: Indicates ^.safe handling and storage procedures to be taken to - avoid hazardous reactions. This section will emphasize incompatibility or polymerization problems which , could occur during storage or handling of the chemical. 4. Other Precautions: Indicates special precautions to use in handling or dispasing of the chemical. Section vm - Control Measures The measures indicated in this section should be taken whenever the chemical is handled or disposed of during normal use. They are not measures to be used solely during emergencies or accidental spills. 1. Respiratory Protection: If needed, specifies type of respirators required by OSHA when the chemical is used, even as a precautionary measure in noo-emergeocy situations. 2. Ventilation: Indicates ventilating systems needed to prevent overexposure to the chemical. "Local exhaust** ventilation is a system with high speed and tow volume that will capture a chemical quickly after it has been released. The objective is to prevent the substance from reaching the employee's breathing zone. "Mechanical (general) ventilation" is the regular ventilation system used to beat and/or cool an enclosed area in a permanent facility. 3. Protective Gloves: Indicates whether or not gloves must be worn when the chemical is handled. If gloves are required for skin protection, the type of material they should be made of will be indicated. .4 Eye Protection: Indicates appropriate eye protection, such as face shields, safety goggles or glasses. 5. Other Protective Clothing or Equipment: Indicates protective equipment, such as aprons or boots, and the materials they should be made of to effectively prevent skin contact i 15 DE 008383 Material Safety Data Sheet May be used to comply With OSHA's Hazard Communication Standard. 29 CfR 1910.1200. Standard must be coneuHed tor specific raquiremants. KltNIlT'r (At Uma an LaM end UK) Section 1 Menutodurer's Name Addreee (MmOar. Smc OTy, SM* and ZP Oods) U.S. Department of Labor Occupational Safety and Htalth Administration (Non-Mandatory Form) A " Form Approved OMB No. 1211-0072 rNote: Sane spaces are net penrtnad any aem a nor eoptoetxr or no Hbrmsaan a a i same. apaea mar oe mer*ed o ndcjv ner Emergency TeNphwa Number Telephone Number tor WormsSon Due Prepared Signature of Preparer fapSbnaQ Section R -- Hazardous tngiadtanla/idartttty Intormetlon Hazardous Componarts (Specific Chemical MetOy; Common Nama(s)) OSH* PEL ACQIH TVV Other Units Recommended H (aoeanto Section ill -- Ptiyaleal/Chemleat Characteristics Section IV -- Fire and Explosion Hazard Data FM Pont (Method Used) EiMgutfng Mtdt Specs* Fee Fighting Procedures 1 Unueuei Fee end Espieecn Hazards (Reproduce locally) Flammable Units LEL UEl OSH* 174. Scot 1965 DE 008384 Section V - BtoctMty Pott Snotty Unatafcfa staata IneotnpatlblWy (Malaria* (o A*oM) Hazardoia DaoornpoaNon or OypreducM Kazartoua PotywartiaSon May Odour VM Not Occur CondMona to Aaoid CondMona to Aaoid Section V) -- HmMi Haard Mi RoutaM of E/riry: InhaMon? Haalrii Hatarda (Aem and Chmte) 8Hn? Carcmoganeity: WTP? MAC Monograpfta? &gna and Sytnpcoma of Expoaura Madical Condition! Oanafaty *>KlKi By Expoaura Ematganey and fit* Aid Procaduraa Section VII -- Precautions lor Ssfa Handing and Uaa Sfapa to Pa Tafcan in Caaa MMartal ta Hafaaaad or Bpilxd Waca Oapoaaf Maetod Pracaoeona to Ba Takan in HanAng and Storing Othar Pracautona Sactlon Vlll -- Control Msssuret fiaapiwory Pratacten fttacfy Typt) ~ vonwtbon Locaf Exftaual Macriancal (OartaraQ PltMCtTVV Qtcwtt w* Pram* Ctothmg or Equywnt Spadat Otm Eya Pr stoc&on Paga 2 mglow? 06HA Hagutotad? uao DE 008385 CHAPTER SIX Contractors' Obligation under EPA's Community Right-to-Know Regulations Because HazCom has been extended to the construction industry, some contractors will also have to start complying with the Environmental Protection Agency's Community Rjght-to-Know reporting regulations. These are separate, but related requirements. Contractors who must maintain Material Safety Data Sheets (MSDSs) under HazCom may also have to report certain information to state and local emergency "pfauming commissions and their local fire departments. Will All Contractors Have to Comply with This? Not every contractor will have to comply with these reporting requirements. As of April 30,1989, contractors who have a hazardous substance in excess of 10,000 lbs. (approximately 1,250 gallons) must report it to their state and local emergency planning commission and their fire department. A list of the state emergency response commis sions can be found at the end of this chapter. The reporting of hazardous substances must either be in the form of a list of the chemicals or the actual MSDSs. Then, on March 1,1990, those contractors must submit the Tier One form (attached at the end of the chapter) to those same three reporting agencies. Should the agencies want more information, they will request that you fill out the Tier Two form (also attached). On each succeeding March 1, you will be required to submit another Tier One form on substances present in the workplace in excess of 10.000 lbs. Since these quantities are so large, these rules will probably not apply to many chemicals for a typical contractor. However, a large painting contractor may have large amounts of paint, a roofer may have large amounts of tar, or a land developer may have his own diesel fuel or gasoline supply which would have to be reported. You will have to survey your own company to see what you have large amounts of on hand. If you do have any substances in excess of 10.000 lbs., make sure you do report them because non-compliance could bring about penalties of as much as S25.000 per day. EPA has established a Chemical Emergency Prepared ness Program Hotline to answer questions regarding the reporting requirements in this chapter. (This is not an information line for OSHA's Hazard Communication Standard.) The number is 1-800-535-0202 (202-479-2449 in Washington, D.C.). v 19 DE 008386 MATERIAL SAFETY DATA SHEET. Version Jan. 1992 Sigma Aldrich Corporation 1001 West Saint Paul Ave., Milwaukee. Wl 53233. USA Sigma Aldrich For Emergency Contact USA/Canada 800-325-5832 800-231-8327 Outside USA/Canada 314-771-5765 414-273-3850 NO STRUCTURE ---------------------- IDENTIFICATION ......... ................. PRODUCT #: 11110 NAME: ASBESTOS FIBRES CAS#: 1332-21-4 ADDITIONAL INFORMATION MAK VALUE (CH) 0.05 MG/M3 (1987) MAK VALUE (D) 0.02 MG/M3 (1988) THIS COMPOUND IS LISTED AS A CARCINOGEN OR POTENTIAL CARCINOGEN BY: NATIONAL TOXICOLOGY PROGRAM ---------------------- TOXICITY HAZARDS ---------------------- DATA NOT AVAILABLE --------------------- HEALTH HAZARD DATA -------------------- CHRONIC EFFECTS OTHER HEALTH HAZARDS HARMFUL BY INHALATION AND IN CONTACT WITH SKIN. DANGER OF CUMULATIVE EFFECTS. MAY CAUSE CANCER. FIRST AID TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. AFTER CONTACT WITH SKIN. WASH IMMEDIATELY WITH PLENTY OF SOAP AND WATER. DE 008387 IN CASE OF CONTACT WITH EYES, RINSE IMMEDIATELY WITH PLENTY OF WATER AND SEEK MEDICAL ADVICE. IF NECESSARY ------------------------ PHYSICAL DATA ------------------------ SOLUBILITY: WATER-INSOLUBLE APPEARANCE AND ODOR FORM - FIBRES COLOR -LIGHT GREY --------------FIRE AND EXPLOSION HAZARD DATA-------------- UNUSUAL FIRE AND EXPLOSIONS HAZARDS HAZARDOUS POLYMERIZATION WILL NOT OCCUR. ADDITIONAL INFORMATION NONCOMBUSTIBLE. ........................... REACTIVITY DATA ........................... DATA NOT AVAILABLE ----------------- SPILL OR LEAK PROCEDURES---------------- STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED AVOID RAISING DUST. PUCE IN APPROPRIATE CONTAINER. WASH SPILL SITE WITH SOAP SOLUTION. FLUSH SPILL AREA WITH COPIOUS AMOUNTS OF WATER. WASTE DISPOSAL METHOD BURY IN A LANDFILL SITE APPROVED FOR THE DISPOSAL OF CHEMICAL AND HAZARDOUS WASTES. THIS MATERIAL AND ITS CONTAINER MUST BE DISPOSED OF IN A SAFE WAY. OBSERVE ALL FEDERAL STATE, AND LOCAL UWS. -- PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE -- WEAR DUST MASK. IN CASE OF INSUFFICIENT VENTIUTION, WEAR SUITABLE RESPIRATORY EQUIPMENT. WEAR SUITABLE GLOVES. CHEMICAL SAFETY GOGGLES. WEAR SUITABLE PROTECTIVE CLOTHING. AVOID CONTACT WITH SKIN AND EYES. DO NOT BREATHE DUST. AVOID EXPOSURE- OBTAIN SPECIAL INSTRUCTIONS BEFORE USE. COfcJTAINER SHOULD BE OPENED ONLY BY A TECHNICALLY QUALIFIED PERSON. KEEP CONTAINER TIGHTLY CLOSED. USE ONLY IN WELL VENTIUTED AREAS. REGUUTORY INFORMATION TRANSPORT IMDG-CODE 9 2590 9 9 SWISS POISON LIST CLASSIFICATION: 1* ----------ADDITIONAL PRECAUTIONS AND COMMENTS----------- ADDITIONAL INFORMATION TRK * 500*000 FIBERS/M3 OCCUPATIONAL EXPOSURE TO THE DUST CAN RESULT IN MESOTHELIOMA , SQUAMOUS CELL CARCINOMA AND ADENOCARCINOMA OF THE LUNG AFT ER A LONG LATENT PERIOD. THE ABOVE INFORMATION IS BELIEVED TO BE CORRECT BUT DOES NOT PURPORT TO BE ALL INCLUSIVE AND SHALL BE USED ONLY AS A GUIDE. SIGMA ALDRICH SHALL NOT BE HELD LIABLE FOR ANY DAMAGE RESULTING FROM HANDLING OR FROM CONTACT WITH THE ABOVE PRODUCT. SEE REVERSE SIDE OF INVOICE OR PACKING SUP FOR ADDITIONAL TERMS AND CONDITIONS OF SALE. DE 008389 MATERIAL SAFETY DATA SHEET 0HS02110 JCCUPATIONAL HEALTH SERVICES, INC. 450.SEVENTH AVENUE, SUITE 2407 NEW YORK, NEW YORK 10123 (800) 445-MSDS <2II.) 967-1100 EMERGENCY CONTACT: JOHN S. BRANSFORD, JR. <615; - SUBSTANCE IDENTIFICATION SUBSTANCE: ASBESTOS CAS-NUMBER 1332-21-4 RTEC-NUMBER Cl6475000 RECEIVED TRADE NAMES/SYNONYMSl JIlN ASBESTOS FIBER: ASBESTOS FIBRE: CHRYSOTILE: CROCIDOLITE: ACTINOLITE: AMOSITE: ANTHOPHYLITE: TREMOLITE: CALIDREN HRBgs CALIDRIA R C 244: CHLOROBESTOS 25: FARM 410-120: FERODO CSC: OHS02110 CHEMICAL FAMILY: FIBROUS SILICATES CERCLA RATINGS (SCALE 0-3): HEALTH-3 FIRE-0 REACTIVITY-0 PERSISTENCE=3 NFPA RATINGS (SCALE 0-4): HEALTH-3 FIRE-0 REACTIVITY-0 COMPONENTS AND CONTAMINANTS COMPONENT: ASBESTOS FORMS MAY INCLUDE: PERCENT: 100 COMPONENT: AMOSITE CAS# 12172-73-5 COMPONENT: ACTINOLITE CAS# 77536-66-4 COMPONENT: ANTHOPHYLITE CAS# 77536-67-5 COMPONENT: CHRYSOTILE CAS# 12001-29-5 COMPONENT: CROCIDOLITE CAS# 12001-28-4 COMPONENT: . 5# 77536-68-6 OTHER CONTAHl... EXPOSURE LIMlVi^^^v'^ ASBESTOS: '*" 0.2 FIBER 05.0 MICRONS IN LENGTH)/CC OSHA TWA (ALL FORMS) 1.0 FIBER 05.0 MICRONS IN LENGTH)/CC OSHA 30 MINUTE EXCURSION LIMIT (ALL FORMS) 0.5 FIBER 05.0 MICRONS IN LENGTH)/CC ACGIH TWA (AMOSITE)j ACGIH Ai-CONFIRMED HUMAN CARCINOGEN. 2.0 FIBERS 05.0 MICR0N8 IN LENBTHWCC ACGIH TWA (CHRYSOTILE)} ACGIH A1-CONFIRMED HUMAN CARCINOGEN. 0.2 FIBER 05.0 MICRONS IN LENGTH)/CC ACGIH TWA (CROCIDOLITE)} ACGIH A1-CONFIRMED HUMAN CARCINOGEN. 2.0 FIBERS 05.0 MICRONS IN LENGTHI/CC ACGIH TWA (OTHER FORMS) ACGIH A1-CONFIRMED HUMAN CARCINOGEN. . 0.1 FIBER 05.0 MICRONS IN LENGTH)/CC NIOSH RECOMMENDED S HOUR TWA (ALL FORMS); DE 008390 0.5 FIBER 05.0 MICRONS IN LENGTH)/CC NIOSH RECOMMENDED 15 MINUTE CEILING (ALL FORMS) 1 POUND CERCLA SECTION 103 REPORTABLE QUANTITY SUBJECT TO SARA SECTION 313 ANNUAL TOXIC CHEMICAL RELEASE REPORTING SUBJECT TO CALIFORNIA PROPOSITION 65 CANCER AND/OR REPRODUCTIVE TOXICIT- WARNING AND RELEASE REQUIREMENTS- (FEBRUARY 27, 1987) PHYSICAL DATA DESCRIPTION! COLOR AND COMPOSITION VARY WITH TYPE OF ASBESTOS AND AREA Mi MAY BE WHITE, BROWN, OR BLUE FINE, SLENDER, FLAXY FIBERS. BOILING POINT: 4046 F (2230 C) MELTING POINT* 3134 F (1723 C) SPECIFIC GRAVITY: 2.5 SOLUBILITY IN WATER: INSOLUBLE FIRE AND EXPLOSION DATA FIRE AND EXPLOSION HAZARD "ELIGIBLE FIRE HAZARD WHEN EXPOSED TO HEAT OR FLAME. FIREFIGHTING MEDIA: DRY CHEMICAL, CARBON DIOXIDE, HALON, WATER SPRAY OR STANDARD FOAM (1987 EMERGENCY RESPONSE GUIDEBOOK, DOT P 5800.4). FOR LARGER FIRES, USE WATER SPRAY, FOG OR STANDARD FOAM (1937 EMERGENCY RESPONSE GUIDEBOOK, DOT P 5800.4). FIREFIGHTING: NO ACUTE HAZARD. MOVE CONTAINER FROM FIRE AREA IF POSSIBLE. AVOID BREATHINGVAPORS OR DUSTS} KEEP UPWIND. TRANSPORTATION DEPARTMENT OF TRANSPORTATION HAZARD CLASSIFICATION 49CFR172.101: ORM-C DEPARTMENT OF TRANSPORTATION LABELING REQUIREMENTS 49CFR172.101 AND SUh---NONE DEPARTMENT OF TRANSPORTATION PACKAGING REQUIREMENTS: 49CFR173.1090 EXCEPTIONS: 49CFR173.1090 TOXICITY DE 008391 ASBESTOS: .2 FIBERS/CC/19 YEARS CONTINUOUS INHALATION-HUMAN TCLO; MUTAGENIC " (RTECS); TUMORIGENIC DATA (RTECS). ACT-INOL ITE . AMOSITEs MUTAGENIC DATA (RTECS>5 TUMORIGENIC DATA (RTECS). ANTHQPHYLITE: MUTAGENIC DATA (RTECS): TUMORIGENIC DATA (RTECS). CHRYSOTILE: 2.8 FIBERS/CC/5 YEARS INHALATION-HUMAN TCLO: 300 MG/KG INTRAPERITONEAL--RAT LDLO; MUTAGENIC DATA (RTECS); TUMOR I GENIC DATA - "; . CROC IDOL I TE: 300 MG/KG I NTRAPER ITONEAL-RAT MUTAGENIC DATA (RTECS); TUM=_- : : DATA (RTECS). TREMOLITE: TUMORIGENIC DATA (RTECS). CARCINOGEN STATUS: OSHA CARCINOGEN; KNOWN HUMAN CARCINOGEN (NTP); HUMAN SUFFICIENT EVIDENCE, ANIMAL SUFFICIENT EVIDENCE (IARC CLASS-1). OCCUPATIONAL EXPOSURE TO CHRYSOTILE, AMOSITE, MIXTURES CONTAINING CRO'~. ff-j. AND OTHER FORMS OF ASBESTOS HAS RESULTED IN A HIGH INCIDENCE OF LUNG CAN-ZEP. AND PLEURAL AND PERITONEAL MESOTHELIOMAS. GASTROINTESTINAL CANCERS WEPt INCREASED IN WORKERS EXPOSED TO AMOSITE, CHRYSOTILE, OR MIXED FIBERS CONTAINING CROCIDOLITE. AN EXCESS OF LARYNGEAL CANCER HAS ALSO BEEN REPORTS:. ASBESTOS IS AN EYE, SKIN, AND MUCOUS MEMBRANE IRRITANT. SMOKING ENHANCES THE RISK OF LUNG CANCER FROM EXPOSURE. HEALTH EFFECTS AND FIRST AID NHALATIONi ..SBESTOS: IRRITANT/CARCINOGEN. ACUTE EXPOSURE- MAY CAUSE ACUTE IRRITATION AND COUGHING. CHRONIC EXPOSURE- PROLONGED INTENSE EXPOSURE MAY CAUSE ASBESTOSIS, AN INTERSTITIAL FIBROSIS OF LUNG TISSUE WHICH MAY DEVELOP FULLY WITHIm r- YEARS, BUT ONSET IS TYPICALLY DELAYED 20-40 YEARS AFTER FIRST EXPOSURE. FATAL EXPOSURE MAY BE AS BRIEF AS 3 MONTHS DURING CHILDHOOD. THE I'vItial SYMPTOM IS A PROGRESSIVE EXERTIONAL DYSPNEA, FOLLOWED BY A DRY COUGH AMD EXPECTORATION, CHEST PAIN, DECREASED VITAL CAPACITY, TACHYPNEA, PERSISTED DRY RALES, CYANOSIS, CLUBBING OF THE FINGERS AND TOES, ANOREXIA, WEAKNESS, AND WEIGHT LOSS. RADIOLOGIC STUDIES MAY SHOW A DIFFUSE INCREASE IN LUNG DENSITY AND PLEURAL CALCIFICATION. SPONTANEOUS PLEURAL EFFUSION HAS OCCURRED IN ASBESTOS-EXPOSED WORKERS AS EARLY AS 3-4 YEARS AFTER INITIAL EXPOSURE. ASBESTOS. WORKERS SHOW AN INCREASE IN PLEURAL AND PERITONEAL MESOTHELIOMAS, BRONCHOGENIC CARCINOMA, LUNG CANCER, CANCERS OF THE GASTROINTESTINAL TRACT INCLUDING THE ESOPHAGUS, STOMACH, COLON, AND RECTUM, AND CANCER OFVTHE LARYNX. MESOTHELIAL TUMORS ARE CHARACTER]ZEr BY BLOODY EFFUSION WITH PAIN, DYSPNEA, COUGH, WEIGHT LOSS, FATIGUE, HYPONATREMIA, AND DEATH! THE LATENT PERIOD FOR MESOTHELIOMA IS 3.5-'' YEARS; FOR LUNG CANCER, 15-30 YEARS. THE INCIDENCE OF LUNG CANCER AMD PULMONARY FIBROSIS IN ASBESTOS-EXPOSED WORKERS IS INCREASED BY CIGAKE: ts. SMOKING, FIRST AID- REMOVE FROM EXPOSURE AREA TO FRESH AIR IMMEDIATELY. IF BREAD*.::=-. HAS STOPPED, PERFORM ARTIFICIAL RESPIRATION. KEEP PERSON WARM AND AT -l."' TREAT SYMPTOMATICALLY AND SUPPORTIVELY. GET MEDICAL ATTENTION IMMEBIATZl. - SKIN CONTACT: ASBESTOS: ACUTE EXPOSURE- DIRECT CONTACT MAY CAUSE IRRITATION. ASBESTOS FIEEF" PENETRATE THE SKIN AND RESULT IN "ASBESTOS CORNS", DUE TO THICKF:'' - THE SKIN AROUND THE IMPLANTED FIBER. THESE USUALLY-.OCCUR ON THE DE 008392 AND FOREARMS. THESE CORNS DO NOT LEAD TO SKIN TUMORS AND DISAPP5- REMOVAL OF THE FIBERS. CHRONIC EXPOSURE- REPEATED OR PROLONGED CONTACT MAY CAUSE DERMATIT 'c -EFFECTS AS IN ACUTE EXPOSURE. FIRST AID- REMOVE CONTAMINATED CLOTHING AND SHOES IMMEDIATELY. WASH L! AREA WITH SOAP OR MILD DETERGENT AND LARGE AMOUNTS OF WATER UNTIL NO EVIDENCE OF CHEMICAL REMAINS (APPROXIMATELY 15-20 MINUTES). GET MEDICAL ATTENTION IMMEDIATELY. EYE CONTACTS ASBESTOSt ACUTE EXPOSURE- DIRECT CONTACT MAY CAUSE IRRITATION WITH REDNESS DUE Tli MECHANICAL ACTION. CHRONIC EXPOSURE- REPEATED OR PROLONGED EXPOSURE MAY CAUSE CONJUNCTIVITIS. FIRST AID- WASH EYES IMMEDIATELY WITH LARGE AMOUNTS OF WATER OR NORMAL SALINE OCCASIONALLY LIFTING UPPER AND LOWER LIDS, UNTIL NO EVIDENCE OF CHEMICAL REMAINS (APPROXIMATELY 15-20 MINUTES). GET MEDICAL ATTENTION IMMEDIATELY. INGESTIONS ASBESTOS: ACUTE EXPOSURE- INGESTION MAY CAUSE GASTROINTESTINAL IRRITATION. CHRONIC EXPOSURE- REPEATED OR PROLONGED INGESTION OF ASBESTOS FIBERS MAY BE INVOLVED IN CANCERS OF THE BUCCAL CAVITY AND PHARYNX, ESOPHAGUS,. STOMACH. COLON, AND RECTUM. INGESTION OF ASBESTOS-CONTAMINATED RICE HAS BEEN SUGGESTED AS THE CAUSE FOR A HIGH INCIDENCE OF STOMACH CANCER IN JAPAN. FIRST AID- REMOVE BY GASTRIC LAVAGE OR EMESIS. MAINTAIN BLOOD PRESSURE AND AIRWAY. GIVE OXYGEN IF RESPIRATION IS DEPRESSED. DO NOT PERFORM GASTRIC LAVAGE OR EMESIS IF VICTIM IS UNCONSCIOUS. GET MEDICAL ATTENTION IMMEDIATELY. (DREISBACH, HANDBOOK OF POISONING, 11TH ED.) ADMINISTRATION OF GASTRIC LAVAGE OR OXYGEN SHOULD BE PERFORMED BY QUALIFIED MEDICAL PERSONNEL. ANTIDOTE; NO SPECIFIC ANTIDOTE. TREAT SYMPTOMATICALLY AND SUPPORTIVELY. REACTIVITY SECTION REACTIVITY: \ STABLE UNDER NORMAL TEMPERATURES AND PRESSURES. INCOMPATIBILITIES: ASBESTOS: TRI-N-BROMOMELAMINE: EXPLOSIVE REACTION. SODIUM HYDROXIDE; POSSIBLE EXPLOSION. CARBON TETRACHLORIDE: .FORMATION OF EXPLOSIVE DI- AND TRI-CHLOROBUTYLENT EPOXIDE. CHLOROSULFONIC ACID; EXOTHERMIC REACTION. NITRIC ACID; EXOTHERMIC REACTION. OLEUM:EXOTHERMIC REACTION. SULFURIC ACID: EXOTHERMIC REACTION. OXIDIZING MATERIALS: VIGOROUS REACTION. PHOSPHORUS TRICHLORIDE: PREPARATORY HAZARD (EXPLOSIVE) WHILE DISTI< CARBON DIOXIDE STREAM. DE 008393 ^COMPOSITION: iHERMAL DECOMPOSITION MAY RELEASE ACRID SMOKE AND IRRITATING FUMES. POLYMERIZATION: HAZARDOUS POLYMERIZATION HAS NOT BEEN REPORTED TO OCCUR UNDER NORMAL TEMPERATURES AND PRESSURES. STORAGE-DISPOSAL OBSERVE ALL FEDERAL, STATE AND LOCAL REGULATIONS WHEN STORING OR DISFCCir:.OF THIS SUBSTANCE. FOR ASSISTANCE, CONTACT THE DISTRICT DIRECTOR OF THE ENVIRONMENTAL PROTECTION AGENCY. STORAGE** ASBESTOS WASTE, SCRAP, DEBRIS, BAGS, CONTAINERS, EQUIPMENT, AND ASBESTOS-CONTAMINATED CLOTHING, CONSIGNED FOR DISPOSAL, WHICH MAY PRODUCE IN ANY REASONABLY FORESEEABLE USE, HANDLING, STORAGE, PROCESSING, DISPOSAL, 0.` TRANSPORTATION AIRBORNE CONCENTRATIONS OF ASBESTOS FIBERS IN EXCESS OF THE EXPOSURE LIMITS PRESCRIBED SHALL BE COLLECTED AND DISPOSED OF IN SEALED IMPERMEABLE BAGS, OR OTHER CLOSED, IMPERMEABLE CONTAINERS. CONDITIONS TO AVOID ASBESTOS SHALL BE HANDLED, MIXED, APPLIED, REMOVED, CUT, SCORED, OR OTHERWISE WORKED IN A WET STATE SUFFICIENT TO PREVENT THE EMISSION OF AIRBORNE FIBERS :* EXCESS OF THE EXPOSURE LIMITS. 29CFR 1910.1001 (C> (2) SPILLS AND LEAKS WATER-SPILL: V THE CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT OF 1986 ' (PROPOSITION 65) PROHIBIT^.CONTAMINATING ANY KNOWN SOURCE OF DRINKING WATER WITH SUBSTANCES KNOWN TO CAUSE CANCER AND/QR REPRODUCTIVE TOXICITY. OCCUPATIONAL-SPILLi ' ADEQUATELY WET OR MIX WITH WATER TO FORM A SLURRY. SEAL MATERIAL IN A LEAK-TIGHT CONTAINER WHILE WET. LABEL CONTAINERS AS SPECIFIED IN 29CFR 1910.1001. REPORTABLE QUANTITY (RQ): 1 POUND E SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT (SARA) SECTION 304 - i HAT A RELEASE EQUAL TO OR GREATER THAN THE REPORTABLE QUANTITY FOR Tr! I _ SUBSTANCE BE IMMEDIATELY REPORTED TO THE LOCAL EMERGENCY PLANNING COMM! nr. AND THE STATE EMERGENCY RESPONSE COMMISSION (40 CFR 355.40). IF THE PEL'.: -t'-i THIS SUBSTANCE IS REPORTABLE UNDER CERCLA SECTION 103, THE NATIONAL ** CENTER MUST BE NOTIFIED IMMEDIATELY AT (900) 424-8802 OR (202) 426-2h METROPOLITAN WASHINGTON, D.C. AREA (40 CFR 302.6). DE 008394 PROTECTIVE EQUIPMENT SECTION VENTILATION: PROVIDE LOCAL EXHAUST OR PROCESS ENCLOSURE VENTILATION TO MEET PUBLISHEFEXPOSURE LIMITS. ASBESTOS: VENTILATION SHOULD MEET THE REQUIREMENTS IN 29CFR1910.1001<F>. RESPIRATOR: THE FOLLOWING RESPIRATORS ARE THE MINIMUM LEGAL REQUIREMENTS AS SET FORTH BY THE OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION FOUND IN 29 CFP19K-. SUBPART 2. REQUIRED RESPIRATORS FOR ASBESTOS AIRBORNE CONCENTRATION (TWA): REQUIRED RESPIRATOR: NOT IN EXCESS OF 2 FIBERS/CC HALF-MASK AIR-PURIFYING RESPIRATOR EQUIPS WITH HIGH EFFICIENCY FILTERS. NOT IN EXCESS OF 10 FIBERS/CC FULL FACEPIECE AIR-PURIFYING RESPIRATOREQUIPPED WITH HIGH EFFICIENCY FILTERS. T IN EXCESS OF 20 FIBERS/CC ANY POWERED AIR-PURIFYING RESPIRATOR EQUIPPED WITH HIGH-EFFICIENCY FILTERS. ANY SUPPLIED-AIR RESPIRATOR OPERATED IN CONTINUOUS FLOW MODE. NOT IN EXCESS OF 200 FIBER FULL FACEPIECE SUPPLIED-AIR RESPIRATOR OPERATED IN PRESSURE DEMAND MODE. GREATER THAN 200 FIBERS/CC FULL FACEPIECE SUPPLIED-AIR RESPIRATOR OR UNKNOWN CONCENTRATION. ' OPERATED IN PRESSURE DEMAND MODE AND EQUIPPED WITH AN AUXILIARY POSITIVE PRESSURE SELF--CONTANIED BREATHING APPARATUS. NOTE: RESPIRATORS ASSIGNED FOR HIGHER ENVIRONMENTAL CONCENTRATIONS MAY BE USED AT LOWER CONCENTRATIONS. iV **?.,* * THE FOLLOWING RE3&mAfORS%AND MAXIMUM USE CONCENTRATIONS ARE RECOMMENDATIONS BY THE U.S. DEPARTMENT OF.HEALTH AND HUMAN SERVICES, NIOSH POCKET GUIDE TO CHEMICAL HAZARDS OR NIOSH-CRITERIA DOCUMENTS) OR DEPARTMENT OF LABOR, 29CFR1910 SUBPART'-Z. THE SPECIFIC RESPIRATOR SELECTED MUST BE BASED ON CONTAMINATION LEVELS FOUND IN THE WORK PLACE AND BE JOINTLY APPROVED BY THE NATIONAL INSTITUTE OF OCCUPATIONAL SAFETY AND HEALTH AND THE MINE SAFETY AND HEALTH ADMINISTRA"12`. ASBESTOS: ANY DETECTABLE CONCENTRATION: ANY SUPPLIED-AIR RESPIRATOR WITH A FULL FACEPIECE AND OPERATED '.< PRESSURE-DEMAND OR OTHER POSITIVE PRESSURE MODE IN COMBINATION AN AUXILIARY SELF-CONTAINED BREATHING APPARATUS OPERATED If PRESSURE-DEMAND OR OTHER POSITIVE PRESSURE MODE. ANY SELF-CONTAINED BREATHING APPARATUS WITH FULL FACEPIECE AI DE 008395 OPERATED IN A PRESSURE-DEMAND OR OTHER POSITIVE PRESSURE ____ -SCAPE- ANY AIR-PURIFYING FULL FACEPIECE RESPIRATOR WITH A HIGH-EFFICI PARTICULATE FILTER. ANY APPROPRIATE ESCAPE-TYPE SELF-CONTAINED BREATHING APPARATUS. FOR FIREFIGHTING AND OTHER IMMEDIATELY DANGEROUS TO LIFE OR HEALTH CO*'D i ^ SELF-CONTAINED BREATHING APPARATUS WITH FULL FACEPIECE OPERATED IN PREEF/jc-r DEMAND OR OTHER POSITIVE PRESSURE MODE. SUPPLI ED-AIR RESPIRATOR WITH FULL FACEPIECE AND OPERATED IN PRESSURE- DE:-:. OR OTHER POSITIVE PRESSURE MODE IN COMBINATION WITH AN AUXILIARY SELF-CONTAINED BREATHING APPARATUS OPERATED IN PRESSURE-DEMAND OP OTHEF POSITIVE PRESSURE MODE. CLOTHING: EMPLOYEE MUST WEAR APPROPRIATE PROTECTIVE (IMPERVIOUS) CLOTHING AND EQUIPMENT TO PREVENT REPEATED OR PROLONGED SKIN CONTACT WITH THIS SUBSTANCE. ASBESTOS: PROTECTIVE CLOTHING SHOULD MEET THE REQUIREMENTS FOR PROTECTIVE WORK CLOTHING AND EQUIPMENT IN 29CFR1910.1001CH>. GLOVES: "MPLOYEE MUST WEAR APPROPRIATE PROTECTIVE GLOVES TO PREVENT CONTACT WITm THIS JBSTANCE. ASBESTOS: PROTECTIVE GLOVES SHOULD MEET THE REQUIREMENTS FOR PROTECTIVE WORK CLCTs-.; AND EQUIPMENT IN 29CFR1910.1001<H) AND 29CFR1910.1101<D). EYE PROTECTION: EMPLOYEE MUST WEAR SPLASH-PROOF OR DUST-RESISTANT SAFETY GOGGLES TO PREVENT EYE CONTACT WITH THIS SUBSTANCE. CONTACT LENSES SHOULD NOT BE WORN. ASBESTOS: PROTECTIVE EYE EQUIPMENT SHOULD MEET THE REQUIREMENTS FOR PROTECTIVE WORK CLOTHING AND EQUIPMENT IN 29CFR1910.1001(H). - "* AUTHORIZED*BY- OCCUPATIONAL HEALTH SERVICES, INC. ` CREATION DATE* 02/08/85 REVISION DATE: 04/12/89 *-*****************************************#*****<Ht*#***************.^-- * -- * - DE 008396 mt a ***- i u w e SC received agc.ca -MAY. , 419% irn F1M HAZARD tTMWCt AM KARA 70* < MUIIM MATERIAL SAFETY DATA SMgfa Qim Noj 3141 Rev. Nou 3 Data Prepared: 0-*/0?/(7 Wanville |_________________________________ ._________________ I PRODUCT IDENTIFICATION_________________ Trad* Nemetal ^TRANSITECORl PLATE Generic Name ASBESTOS CEMENT BOARD Chamlcat Name CAS #: NA Formula: MIXTURE Manutaeturar. MANV1LLE SPECIALTY PRODUCTS CROUP AddrearP.O. BOX BIOS City: DENVER State CO Zip: S0217 Telephone (303)874-3120 Emergency: 7 if PBODUCT1NOSED1ENT.--.r. INGREDIENT NAME CAS NUMBS! % CHRYSOTILE asbestos FIBER PORTLAND CEMENT SILICA FLOUR 1333-31-4 CSBB7-1S-1 7C31-BS-B SB 35 24 CUTTING. ORILLING. OR OTHERWISE ABRADING THIS PROOUCT WILL RELEASE ASBESTOS FIBER SEE HEALTH HAZARD INFORMATION BELOW. -- PEL ana Tlv (exeeot is noted) 3 r/cc 5 ng/n' (RESPIRABLE OUST) 1 1 e> v *> * " < >. * {..*;*< . ->f\' .itt- :^HVICALiPATA:MJ>^-v-> Appearance and Odor SOLID CRAY SHEET - NO ODOR- y.l oiling Point Vapor Preteure Water Solubility fli) : Vapor Denaity (Alrsl) : NA na NEGLIGIBLE na Evaporation Rata (NA Specific Gravity (water w 1 ) : Maltlns Point NA % Volatile by Volume: 0 * 1 ) : na i. c i ! y.":* <KRC AMO XPLOSON.&ATA::>v;~ --'ifj*' A^. \ <~-r. - - Flash Point (Method) : NONFLAMMABLE Flammable Limits: LEU na % USu na Extinguishing Madie na Unusual Fire or Explosion Hazards NONE % NFPA Flammable/Combustlbla Liquid Classification: na Auto-Ignition Temperature na Special Fire-Fighting Proceduree NONE * 'HEALTH -HAZABOS.:-left*.: SummaryfRIaka. Summary: EXCESSIVE EXPOSURE'TO HIGH CONCENTRATIONS OF AIRBORNE ASBESTOS FIBERS CAN CAUSE CHRONIC PULMONARY DISEASE. THIS PRODUCT IS CONSIDERED A KNOWN HUMAN CARCINOGEN BY NTP. IARC ANO OSHA. Medical conditions whieh may be aggravated: PRE-EXISTING UPPER RESPIRATORY ANO LUNG DISEASE SUCH AS BUT NOT LIMITED TO BRONCHITIS. EMPHYSEMA. AND ASTHMA. Target Organic) : RESPIRATORY ANO PULMONARY SYSTEM. Acute Health Effeete THERE ARE NO. ACUTE SIGNS OR SYMPTOMS ASSOCIATED WITH ASBESTOS. Chronic H**Ith Effeete THE DISEASE ASSOCIATED WITH OVEREXPOSURE ARE CHRONIC, GENERALLY TAKIM 'ROM 10 T3 ' 40 YEARS TO BECOME APPARENT. Primary Entry Route!*] : INHALATION. DE 008397 MAV 3 SCternary ri o w O j t ot TRANSITE CORE PLATE MSOS: 3141 Rev: 2 /Pag 2 L:______ ___________ V. HEALTH HAZAROS B. Signs/Symptoma of Overexposure Inhelftion EXCESSIVE EXPOSURE TO HIGH CONCENTRATIONS OF AIRBORNE ASBESTOS FIBER .AN CAUSE CHRONIC PULMONARY DISEASE AND CANCER. Skin Contiet FIBERS CAN BECOME IMBEDDED IN SKIN AND IN SOME CASES RESULT IN ASBESTOS 'CORNS' ; ii Skin Absorption: NONE IngtttiOfr CURRENT STUDIES ESTABLISH NO RELATIONSHIP BETWEEN Cl DISEASES AND THE INGESTION OF ASBESTCS ! FIBERS as CURRENTLY FOUND IN ENVIRONMENT AND OCCUPATIONAL SETTINGS. Eyat: AS WITH ANY OUST. EXCESSIVE EXPOSURES CAN CAUSE TRANSIENT EXPOSURE. -, V. HEALTH HAZARDS C. Fh-at Ald/Emergency Procedural Inhalation: REMOVE TO FRESH AIR. Skin Contact WASH OR SHOWER THOROUGHLY USING SOAP AND WARM WATER. Skin Abtorptioic NA Ingestion na Eyar FLUSH WITH COPIOUS QUANTITIES OF WATER. i VL REACTIVITY DATA .. MATERIAL IS STABLE. Chamleal Incompatibilities NONE known Condition* to Avoid NONE IN OESIGNEO USE. HAZARDOUS POLYMERIZATION CANNOT OCCUR. Hazardous Deeompotltlon Produett: NONE * VJL SPftt<OR EJEAK 'PHOCEOURCS'.' n-4-" ' Proeadura't for Splll/Leefc VACUUM CLEAN SPILLAGE AND DUST CREATED OURING FABRICATION. IF SWEEPING IS NECESSAARY VET DOWN SPILLAGE. USE RESPIRATORY PROTECTION AS REOUIRED. Watt* Management OUST OR SCRAP CREATED DURING FABRICATION OR DEMOLITION MUST BE DISPOSEO ACCORDING TO NESHAP (40 CFR G1, SUBPART M). STATE AND LOCAL REGULATIONS MAY ALSO APPLY. . v;;<i: ,ynL specul-protection information. .. ^ Goggles RECOMMENDED WHEN USING POWER CUTTING TOOLS. Gloves: NOT NORMALLY REOUIRED. Respirator. USE APPROVED RESPIRATOR. SUCH AS 3M MODEL 9B00 OR EQUIVALENT FOR PROTECTION AGAINST PNEUMOCONIOSIS PRODUCING DUST. Ventilation CONTROL WITH MECHANICAL DUST COLLECTION EQUIPMENT TO WITHIN TLV. (SEE AMERICAN NATIONAL STANDARDS INSTITUTE BOOKLET. 39.2. 1971). other USE SPECIAL CLOTHING AS REOUIRED BY OSHA STANDARD FOR EXPOSURE TO ASBESTOS DUST 29 CFR 1910. 1001(0). Special Contlderetlort* for repair/maifttenanee of contaminated equipment USE ALL PROPER PROTECTIVE EQUIPMENT WHEN POSSIBILITY OF EXPOSURE TO ASBESTOS DUSTS EXISTS. h^SPECIALRRECAtfnONSi.TH:*: Storage Segregation Hazard Classes: carcinogen. e ALWAYS SEGREGATE MATERIALS BY MAJOR HAZARD CLASS Special Handling/Storage: STORE FLAT. Other SMOKING GREATLY INCREASES THE CHANCE FOR ASBESTOS-RELATED LUNG DISEASE. IF YOU WORK WITH ASBESTOS 00 NOT SMOKE. Prapartd/Revisad by: KENNETH A. ROSE RTS Title: MANAGER. PRODUCT SAFETY A* of the cite of preparation o< this dccur-.er.L the foregoing information is believed to be accurate in: is rrewoee in , good f :n tc comply with applicable federal anc state lewis). However, no wa-ra-.ty or representation with '-sc:c: to seen DE 008398  a* * mon MPA riM MAZAHe TM0(.T Sm tf?A W tor tuu*4 inittow. i( ntLtlYtU ----------------------------------------------------- HAY 41089 MATERIAL SAFETY DATA SHIFT MSOS CEN No- 11M Rev. No.' 2 Date Ravlaad: 04/07/BS - i Tredt NameUI'rTRANSITiStli^^Generic Name CALCIUM SILICATE BOARD Chamieal Name MIXTURE L PRODUCT IDENTIFICATION CAS m NONE ASSIGNED Formula: MIXTURE ManufaeturarMANVILLE BUILDING materials CORF. AddreerP.O. SOX Slot City: DENVER State CO Zip: B021T Telephone (303)7a-3t20 Emergency: >,: J-:*"H PRODUCT INOREDCKTI INGREDIBIT NAME CAS NUMBER CALCIUM SILICATE CALCIUM SILICATE REINFORCING FILLER MANMADE ORGANIC FIBER NATURAL ORGANIC FIBER 1344-SS-2 10t0t-3B-0 G002-1G-4 SBGM-C1-4 THIS PRODUCT TYPICALLY CONTAINS UP TO 3.0ft OUARTZ. THE PEL IS CALCULATED ON THIS SASIS. 1 ft PEL eno TlV (excaoi as noted) SS-7! 1S-2! 4-B 4- REF: ttlO.lOOO TABLE 23 10 mg/M> XSIOt * 2 ! RESPIRABLE OUARTZ (OSHA) BASED ON 3.0ft RESPIRABLE OUARTZ THE. PEL. 2.0 ir.g/M> Appaaranaa and Odor: gray SHEET - NO ODOR. ii Soiling Point Vapor Pretsure Witar Solubility (W : Vapor Oanalty (Air* II : NA NA NIL na Evaporation Rata ( * 1 I : na Spaalfic brevity (water all: i.s Malting Point NA K Volatlla by Volume o K'l?' f&ixs: Flaeh Point (Mathodl : NONFLAMMABLE Flammabla Limits: LIL: na ft UEL: NA Extinguishing Madia: NA Unusual Rra or Explosion Haxarde NONE ;BRE:.iAJC?.XPifflSIOiy NFPA Flammabla/Combuatlbla Liquid Classification: na ft Auto-Ignition Temperature NA l Spaeial Fire-Fighting Procedure* NONE % Summary: OUST CREATED DURING FABRICATION TYPICALLY CONTAINS O.OX RESPIRABLE OUARTZ. STUDIES USING TYPICAL WORK PRACTICES DEMONSTRATE NO RESPIRABLE QUARTS LEVEL ABOVE 2.0 Mg/M>. THIS PRODUCT IS NOT CONSIDERED A CARCINOGEN BY NTP. IARC AND OSHA. Madieal conditions which may ba aggravated: PRE-EXISTING UPPER NOT LIMITED TO BRONCHITIS. EMPHYSEMA AND ASTHMA. Target Organic) : EYES AND RESPIRATORY SYSTEM. Acute Health Effacte no known acute health hazards. RESPIRATORY ANO LUNG DISEASE SUCH AS. BUT Chronic Health Effect* FAILURE TO FOLLOW SAFE HANDLING PRACTICES WHEN FABRICATING. INSTALLING OR DISMANTLING THIS PRODUCT CAN GENERATE FREE CRYSTALLINE SILICA DUST ABOVE THE PEL. LONG TERM. UNPROTECTED EXPOSURES TO LEVELSABOVE THE PEL MAY CAUSE LUNG OISEASE (SILICOSIS). Primary Entry RoutaU) : INHALATION. ICMv'W'e '*SC. .ii tail ri.i eritaitiit Aim- OwMt. a*a TMt fiirMtie murMi la ah vw ** im.iiii enivu if *a Wit n < .. a.u.c-. PE 008399 m t om * t -w C o5g TIUMSITE :i MSOS: 11M Rev: 2 /Pag* 2 | ........... ' -"V.- HEALTH HAZARDS B. Signa/Symptoms-of Overexposure Inhalation: CONGESTION t IRRITATION OF THE THROAT.NASAL PASSAGES A UPPER RESPIRATORY SYSTEM. Skin Contact NONE ! Skin Absorption: none | Ingestion: NONE i Eyes: TEMPORARY IRRITATION OR INFLAMMATION. i I ___________ ________________________________________________________________ ________________________ __ |f . - ,, . . V-HBALTW HAZARDS C- First Ald/Emergeney Procedure* ____________ | Inhalation REMOVE TO FRESH AIR. | Skin Contact na | Skin Absorption: NA ! Ingestion: NA Eyac FLUSH WITH COPIOUS QUANTITIES OF WATER. j - " , VL REACTIVITY: DATA' . ' MATERIAL IS STABLE. Chemical Incompatibilities: STRONG ACIDS. Conditions to Avoid NONE IN DESIGNEO USE. HAZARDOUS POLYMERIZATION CANNOT OCCUR. Haterdout Decomposition Products: NONE ; ~ ... . .. viL SPtU. OH LEAKPROCEPURgS" Procedures tor Spill/Leak: VACUUM OUST CREATED OURING FABRICATION. IF SWEEPING IS NECESSARY USE A OUST SUPPRESSANT. . Waste Management WASTES GENERATED DURING FABRICATION. DEMOLITION OR BREAKAGE ARE NOT HAZARDOUS WASTES AS DEFINED BY RCRA (40 CFR PART2S1). COMPLY WITH FEDERAL.STATE A LOCAL REGULATIONS. METHOD OF DISPOSAL - LANDFILL. RO - NA. :VE .SPECIAL.iPAQTZCTlOfit'INFORMATION - Goggles: GOGGLES OR FACE SHIELD SHOULD BE USED DURING CUTTING, MILLING OR ABRAXDINQ. -* Gloves: NOT NORMALLY REOUIRED. Respirator: USE A RESPIRATOR SUCH AS 3M t>00 OR EOUIVALENT FOR PROTECTION AGAINST PNEUMOCONIOSIS PRODUCING DUST. Ventilation USE SUFFICIENT NATURAL OR MECHANICAL VENTILATION TO MAINTAIN DUST CONCENTRATIONS BELOV PEL (TLV). other: MAINTAIN GOOD HOUSEKEEPING PRACTICES TO INSURE MINIMUM DUST LEVELS. Speelal Considerations for repalr/maintanance of contaminated equipment USE RESPIRATORY PROTECTION if it is NECESSARY TO CUT OR ABRADE MATERIAL. \ Storage Segregation Hazard Classes: na ALWAYS SEGREGATE MATERIALS BY MAJOR HAZARD CLASS Special Handling/Storage: Special Workplace Engineering Controls: POWER CUTTING EQUIPMENT SHOULD BE EOUIPPCD FOR OUST COLLECTION. Other: Preparad.'iTtvised by: KENNETH A. ROBERTS Title: MGR.. ENVIRONMENTAL SERVICE! As of tr.c d:t* of preparation of this dccumsnL the foregoing information is oclisvad to bs accurate and is r-c/ioad in ; good faith tc comply with aoplieabls federal aid state lawftl However, no warranty or representation with rcsrrrt to such ; informaticn it intended or givan wts] .t. cnet-ie 1 DE 008400 T IE R ONE T IE R TWO D E 008401 Federal Regtatw I Vul. 52. No. 199 / Thursd'y. October 15. I9U7 / Rules and Regulations 38367 EMERGENCY AND HAZARDOUS Tigr one CHM,CAL inventory AttiqtK luftrmtltt* >7 Typt FOR OFUFICttIAL ONLY fB ____ or _____ p*e*> Form Approved OMt No. 2050-0072 ] '"Si i i rri rn i 1 "3 ,&!s2?m m rm X Cartlltettlon (JU*d **4 tijn j/itr comp)cii*{ alt itetiont) I 0*Fllty WW pandity at 1*W that t KM M0tatty suimM Mid m t***l.ar with *ha wiwmatch aubmmad m thrt and a* attaenad aoevnants. and mat MIM an my km*y af tnaaa +m*mu**t nwattiaa *ar aMammf rtw vrtwmatian. i wm mat lha luamtttad wtwmai*" rt trua. actual# and cawdWf Nama and atletat titta a< aatar a*itnoritae taoFasMiai>ea in WdlQht fUnQa At Pound* From_________ To_____ 00 0 01 100 02 1000 00 10.000 .04 100.000 05 1 000.000 05 10.000.000 07 50.000.000 01 100.000.000 00 $00,000,000 10 1 W*n 19 999 999 99.999 999 999 9 999 999 49 999 999 99 999 999 499 999 999 999 999 999 htghar tttan 1 N*on DE 008402 38368 Federal Register / Vol. 52. No. 199 / Thursday. October IS. 1987 / Rules and Regulations TIER ONE INSTRUCTIONS QENERAL INFORMATION Submission of IMs form Is rsqubod by Tills III of tha Suporfund Amendments and Resutherlxatlen Aet el mi. Section 212, Pubtta Lew at-4SS. Ttte purpose of this form Is to provide State and toed offletita and tha puMc with Information on tha general types and toeattono of haiardous chsmleato present at your fadMy dwtog tha past year. YOU MUST PROVIDE AU. INFORMATION REQUESTED ON THIS FORM. You may substitute tha Tier Too form for this Tier One form. {The Tier Two form provides detssed toformatton and must be submitted In response to a epedfto request from State or local othdaia.) WHO MUST SUBMIT THIS FORM Sa-ttion 312 of This til requires that this owner or opera tor of a faeSty submit tMs form If. larder regulations tov piementlng the Occupational Salary and Health Act of 1970. the owner or operator Is requk-ed to prepare or have svalable Material Safety Data Sheets (MSDSI for haiardous ehattnieala present at tha taeaty. MSDS re quirements are specified In the Oeooattonat Safety and Health Administration (OSHA) Haiard Cemmiatlcatton Standard, found to Title 29 of the Cade ot Federal Regu lations at $1910.1200. WHAT CHEMICALS ARE INCLUDED You mutt report the Information reputed on this form for every haiardous ehomieal for which you art reputed lo prepare or have avalable an M5DS wider the Haiard Communication Standard. However. OSHA regWtttont and Tide Ft exempt some chemleale from reperttog. Section 1910.1200(b) of the OSHA reputedone ewrendy provides the folowtng exemptions: (i) Any haitrdoue watte as such tarm to denned by the Sold Waste Otopos* Aet. as smsndsd 142 U S C. 9901 at tea.| When subject lo regWsdone Is sued inder that Aet: |l) Tobacco or tobacco products: (I Wood or wood products: (hr) 'Article**- dsflned under $1910.1200 (b| as a manufaetwed Ram: e Which b formed to a Specific shape or design durtog manufacture: e Which has end use funcbon(a) dependent to whole ar to pert open the shape or design dwtog end uee: and e Which dees net release. or otherwise rest* to exposure to a haiardous chemical under nor mal contfttona of use. 1*1 Feed. (Sups, cosmetics or aleohoie beverages to a ratal ettaMshmsnt which arc paekaoed lor tats to eonswnert: (*f) Foods, drugs, tr cosmetics totsnded for per sonal consumption by smptoyess whlo to the wortplaet; I Ml Any conoumar product or haiardouo oubstanet. at thosa tsrmt art doftood to tha Conaianar Product Safety Aet (IS U.S.C. 12S1 at sag.) respectively, where the employer can demonstrate R la used to me worSpiaee to the seme memaree normal consumer use. and which use reauRt to a duration and fre quency of aspoeurs which Is net greater than expo sures experienced by eeneianers: and (vS) Any drug, at that term to deftoed to the Federal Food. Drug, and Cosmetic Aet (21 U.S.C. 301 er seq.l, whenR Is to add. ftoaf tarm tar Wroct awmnfatratton to tha patient (l.e., tsbtots er pPs). naddRton. Section 311(e) ef TRto Rl exekides the foaowtog substances: (I) Any food, food odWttvo. color addMv*. drug, or cosmetic regitetsd by the Food and Drug Admini stration: (I) Any substance present as t sold to any manufactwed Ram to the extant exposure to the subotancs does not occur under normal ccndhtone of use; () Arry substance to the extent R Is used for per sonal. lardy, or household purposes, or Is present to the same form and concentration as a product paelfaped for dlftrtoutlon and uae by tha general pubic: (hr) Any substance to tha extant R Is used to a re search laboratory or a hospital er ether medtoal l*clRy wider the (Sract eieervttton of a teehNcaiy dualfled todMdual; (v) Any substance to the extent R le used to routine agrteWtwm operations er to a fsnarer new for sals by a rataler to the Wtlmate customer. Also. mMmum reporting thresholde have been eatab(shed under TRto HI. Section 312. You need to report only those haiardous chemleale that wars present it yew lactoty St any time durtog the precedtog calendar year at er above the toveto leted below: o January to Ooeombor 1997 (or first year of reporttog) ...10.000 toe. o January to Oocember 19(9 (or second year of rsporttog) ...10.000 toe. e January te December lilt (or thbd year of reporttop) .. ,iero toe. * EPA wto pubHh (he Itoel threshold, effective to the third year, after tdOttonai analysis. e For extremity haiardous substances...SOOtos. or the threshold doming quinttty. whichever to toss, from the first year of rsporttog and there after. WHEN TO SUBMIT THIS FORM SeQtorWtg March 1. 19M. owners or operators must sub mit the Tier On# form (or substitute the Tier Two form| on or before March 1 el every year. 1 DE 008403 21 Federal RegUlsr / Vol. 52. No. 199 / Thursday. October 15. 1987 / Rules end Regulations 3*361 INSTRUCTIONS nun read tktit Iwineflui tanfmttj. Print mr tjpt til rttpenut. WHERE TO SUBMIT THIS FORM Sana ana comploiod tannwy tout la oaeh rittaWtMtol organlzattona: 1. Your Stata emergency doming conantaaton 2. Your loed emergency piereSng consist!** S. Ttia Ara department with luriodetton avar yotr faeaty. PENALTIES Any ownor or eparatar at a faeaty who faaa ta oubnst or aupplas Ids# Ttor Ooa formation atiat D* labto to tha Urstod Stataa for a CM penally of to (a 325.000 for aaeh such dotation. Each day a dotation eondroiat dial oanttltutt a aaparata vfotadon. In addtton. any ebtran may commanea a eM action on No or hat own behalf against any ownar or oparalor who fast to submit Tlar Ona for mation. You may uoa tha Tlar Two form at a wortrthaat lor completing Tlar Ona. FPng ti tha Tlar Two " chamteal formation taction thoUd halp you aatambla yotr Tlar .Ona ratpenaaa. K yotr ratpontat raquba mora than ona paga. 11 In tha paga nonpar at tha top of tha form. REPORTING PERIOO Entar tha approprlata eUandar yaar. beginning Jamary I Mwi awAaa ^Lr--w-V--lf--TSe-r--vI area* FACILITY IDENTIFICATION Entar tha compiata nama of yotr lactty (and oempany NantHlar whoro approprlatol. Intar tha Ad ttroat addratt ar atata read. If a atraat addratt la not eveiebto, antar oPiar approprlata UtfitW- art that daacnba tha phytlotf location of your faeaty (a.g.. lon^tuda and tttttuda). Inekida city, atata. and dp oada. Entar tha primary Standard Industrial Claialfleatlon (SIC) coda and tha Dun k Sradttraat numbar for yotr faelty. Tha fbiancld offlear of yotr faeaty ohotOd ba abto to proytda tha Oat k Bradatraat nurtSjer. H your Arm doaa not have tHa formation, contact tha atata or regional efAoa of Dial k Iradatraot to obtabt your faeaty mmber or hare ona aaatgnad. OWNER/OFERATOR Entar tha ownar * or operator's M nama. maang *daraaa. and phono rurnPar. EMEROENCY CONTACT Enter the name. Ada. and wort phono ntrrp#r of at laaat one toed poraon or otflc* that ean act aa a ralarrd V omargoney ratpondora naad assistance In rtspondng to a chamteal accident at tha facSty Provide an tmergency phone number where aueh emer gency formation we be avalabto 24 hows a day. every day. I PHYSICAL AND HEALTH HAZARDS Doaerlpllena. Amounts, and Locations TNs section regress aggregate formation on cnemlcab by hazard calagortea aa dafHad In 40 CFR 370 3 Tha two health hazard categories and three physical haz ard categories are a conaoldatlon of tha 23 hazard cate gories defkted In the OSHA Hazard Comnnstieattan Stan dard. M CFR igio.1200. For each hazard typo. Indi cate the told amounti and gsnerd locations of al spps. cable chemicals present at yore facety dretig the paat year. o What teats shored I use? CdctAsts si amolfs as weight M pounai To eontrort gas or IquM voAena to wg|gnt Si potetdt. mrefy by an approprlata density fac tor. o What about mbctreosT If a chonSed M pari of a mbtttee. you hare me option ef roporttog either the weight of the on to* mtxtre* or otSy the portion et the mtiiure that l* a particular hazardous ehemted |* g , a hazardous Solution weighs fOO P# but Is composed of otSy 3% of a particular hazardous chsmled. you ean Meat* either loops, of the mbitur* or S p*. of the ehonsed). Select the option consistent wtth your Section 311 rsporthg of tha ehonsed on tho MSOS or 1st ef MSOS ehomleslt. o Whore do I cotsit a chamical that Is a nr# reac tivity physical hazard and an knmedat* (acuta) haafth hazardT Add tha chanSod's weight to your total* for si three hatd d categories and tnotode As Wesson P af three cat#gone*. Marty chanSeaM fal fo mors than on# hazard ootagory. which rasunt p double-eountyig. MAXIMUM AMOUNT Tha amounts of ehanSeal* you have on hand may vary Svoughout tha yaar. The peak weights -- greatest tingle-day weights dretog the year -- are added together P IN* column to determine tho maximum weight for each hazard typo. Since th* pose* for dtiftrant ehonsed* often occur on dtffersnt day*. ttS* mxxXrvjm arant wl seem artlflelaly tsgp To complete ns* and tne foOewmg sections, you msy chaos* to use tho Tier Two form at a wortsheet To dsttrmpt th* Maxfum Amount. 1. List a* of your hazardous ehonscsit SidtvfduiOy 2. For oaeh ehonScd... s. Meat* al phyded and health hazard* that th* charmed presents IncOde si ChanSeaM. even H they ar* present for only a short pe riod of dm# durbig the year. 2 V __________________________________DE 008404 22 38370 Federal Refilter / Vol. 52. No. 109 / Thuriday, October 15,1087 / Rules and Regulation! b. Eatknate the mixlmwn weight ki powide that wia praaant at yow faebty an any aki^e 3. For cash hazard type -- begMktg ath Fka and re peating far al phyeleal and health hazard typee... a. Add (ha maxkraxn weight* of al ehandcala you Meated aa tha partterfar hazard typa. b. Leek at tha ITeportkig Pangea at tha bottom at tha Ttar Ona (arm. FM tha approprtata range Mue ooda. e. Enter Me range value aa tha Maxknwn Amouit. EXAMPLE: :-ft' S You ara uahg tha Tier Two form aa a wotkahaet and have iatad raw welgnt ki peunda ,, t' for each of you- hazardoue chanVcala. You have marked an X kt tha knmedbte (acuta) hazard oofeann far phanol and awfwle acid. Tha maxknwn amowit raw weight you latad ware to.000 be. and SO tie. reepecthah. You add theta together to reach a total of 10.030 be. F Than you took at tha Itaportktg Itanga at tha f bottom of your Tier Ona form and Arid that tha value of 03 correeponde to 10.050 be. Enter ) 03 aa your Maximum Amount for knmadUta i (eoutel hazard! matarlab. f You ahe marked an X kt tha Fire hazard box for phenol. Whan you calculate ymr Maximum Amount totala for Ike hazard!, add tha 10.000 b. weight again. AVERAQE OAILY AMOUNT Thla eokxnn thotid repretent tha average daky amount ot ehomleala of each hazard typo that wart praaant at your faebty at any point during tha yaar. To determine Me amount: 1. (Jet al of your hazardoua cheMeelt Mvtduaiy (tame aa for MaxXnum Amowit). 3. For oaeh ehomlcrt... a. Mfcatt al phyticb end health hazard! that tha chemical preianta (tame aa lor Maxi mum Amount). b Ettknato tha average welt kt peunda that waa praaam at yow faebty throughout me yaar. Ta do Me, total ai daty weignta and dMda by tha number of daya the chemical waa ereeem on tha aka. 3 For each hazard typa -- beginning with Fka and repeating for al phydeb and healtn hazvdt... a Add tha average weight! of al ehemlealt you Mteatod for tha parttcUar hazard typa. b Look at tha Raportktg Pangea at the bottom of the Tier One form. FM the appropriate range value coda. c Enter Me range vakia aa tha Average Daly Amowit. EXAMPLE: You ara uabg tha Tier Two form, and have marked an X kt tha knmedbte (acuta) hazard OQvm tot ncowi ana pnvnpi. mcovin n praaant at ymr faebty 100 daya during tha yew. and the eum of tha daky watehta la 100.000 be. by dvfcpng 100.000 be. by 100 daya on-aMa. you caietttte an Average Oaky Amount at 1.000 be. for nbottna. Fhenolle proaom at your faebty SO Oaya during tha yaar. and tha eum of tha dirty welghte la tO.OOO be. by rtdibng 10.000 ba by 10 daya on-eRe. you calculate an Average Daky Amount at ZOO ba. for phanol. You than add tha tea average dady amount* together ta reach a total af 1.300be. Thenyoulook at tha Reportkig Panga on ymr Ttar Ona form and hnd that tha value 03 eorreaoenda to 1.300 ba. Enter 03 aa your Average Daly Amoirtt tor knmedate Iacuta) Hazard. You alto marked an x ki tha Fka hazard column tor phanol. Whan you Calcutta your Average Oaky Amount for hro hazard!, uee the 300 b. weight again. NUMBER OP OAYt ON-SITE Enter the uattatt number of daya that a alngia chemical wkldn that hazard category waa praaant on-aha. >. EXAMPLE: >' At your faebty. fdcotkia It preient tor 100 tfayt and phoagene la praaam for ISO daya Enter ISO ki tha apace prodded GENERAL LOCATION Enter tha general location wttNn your (acPty where each hazard may ba found. General locatlone ehoUd Include tha name! or Identtftcatlone of bidding*. tank fleldi. Iota, ehede. or other auch arete. For each hazard typa. Ht tha location! of al appieable ehenVcale. Aa an alternative you may alto attach a ttta plan and ht tha aha coordktato* related to tha appropri ate locatlone. M you do ao. check tha Site Flan box. EXAMPLE: On yow worktheet you have marked an X ki tha Fka hazard cokirm for acetone and butane. You noted that that* ara kept kt tteei Ovm kt Room C of tha Main Butting. and kt praatwtzad eykndart In Storaga Shad 13. raapaetlvaiy. You coWd antar Main buidktg and Storaga Shad t3 aa tha Oanarai Loeatlena of yow fka hazard!- However, you chooao to attach a aka plan and ht coerdkiatet. Cheek tha She Plan boa at tha too ot tha eokxnn and antar aha coorrtnata* for tha Matt Butdkrg and Sioraga Shad 13 under Oanarai Location! tf you need more apace to hi locatlont. attach an addttonal Tier One form and continue yow hi on tha proper Kne Humber al page* CERTIFICATION TNt mutt be completed by tha owner or operator or the officially Oatignalad representative ol lha owner or op erator. Enter yow tul name and otticlal tine Sign your name and antar tha cwrent data 3 23 DE 008405 Federal Refilter / Vol. SI No. 199 / Thursday. October 15. 1967 / Rules and Regulations 38371 1370.41 Tier M emergency and hazardous chemical Inventory fono. (a) The form set oat in paragraph (b) of this Section must be completed and submitted as requited in 1370.25(c). In lieu of the form set out in paragraph (b) of this section, the facility owner or operator may submit a Stale or local form that contains Identical content. (b) Tier H Emergency and Hatatdous Chemical Inventory Form. anjjwo coos mss ss a \ I DE 008406 24 3M72 Faderal RcgUtcr / Vol. 52, No. 199 / Thursday, October 15. 1987 / Rule* and Regulation* o Q 25 00 38374 Federal Register / Vol- 52, No. 199 / Thursday. October IS. 19B7 / Rules end Regulations TIER TWO INSTRUCTIONS GENERAL INFORMATION Submission #1 this Tier Two form (when requested) Is required by Title III el the tuperfund Amendments end Reeutherttetlen Act et ISM, Section SIX, PubH* Lsw M-43*. The purceee et this Tier Two term Is te provide Stete end lecel etllelsls end the pubMo wtth speettle Intermetlen on hazardous chemicals present at your taeSIty durtnq the past year. YOU MUST PROVIDE ALL INFORMATION REQUESTED ON THIS FORM TO FULFILL TIER TWO REPORTING REQUIREMENTS. TNs term may also be used as a wortshoot far completing the Tier One term or may be submitted St place of the Tier One farm. WHO MUST SUBMIT THIS FORM Section stX of Title SI request that the owner er opera tor of a faeSty submit Me Tier Two farm N so requested by a State emergency planning conn*tlon. a teed emergency planneig committee, er a Are department wtth (urteGebost ever the taedty. TNs rsqusst may apply te the owner er operator af any teeaty that Is required, under rsgtiatlone tmptementtng the Occupational Salaty and Hsaftn Act of tl?0. ta pre part or have tvaiabie a Matartal Salaty Data Shaat (MSOSI for a hazardous charmed present at the tsebty. MSOS requbementa ere epeeffied bt the Oeeupatlond Safety and Hsdth Administration (OSHA) Hazard CommwUcatlent Standard, found bi Title 2t ot the Cede of Federal Regulations at 1*10.1200. - WHAT CHEMICALS ARE INCLUDED You must report the btfermatlon requbed on this term for etch hazardous chemical lor which Tier Twe btfermatlon It requested. However. OSHA regulations and Title SI exempt tome ehemleaie from reportnq. Section 1*10.1200(b) of the OSHA regiiatlone currently provides me lotowbig eiempllorw: (I) Anr haztrdeue watte at such term It defined by the Setd Watte Otspesd Act at tmsndsd (42 U.S.C. 1*01 at taq.l whan tub)act to reguationa Issued imder that Act: (l| Tobacco or tobacco product*: () Weed er weed products; (fvpArttclea-- defined under |lt0.1200(b) at a marvfaetwad Sam: e Which It formed te a specific shape er design durtig menufaetwe: * Which has and utt funetlen(t) dependant kt Whole er bi paH open the shape or design dwbig and utt: and * Which dees net release, or etherwtst resist bi txposwe te a hazardous chemical under nor msI conGtlont of utt. (v) Feed. Gugs. cosmetics or alcohoSc berarsges bi a ratal sttabishment wtuelt are packaged tor tale te consumers: fwlj Foods, drugs, or eosmstlet bitsndsd ter per. tent) consumption by employ*** wns* In the workplace. I Ml Any eonewner product er hazardoue tubstanct. at thee* terms era defined bi the Conesanar Product Safety Act (IS U.S.C. 12*1 at t*q.| respectively, where the employer can demonstrate s Is used bi the worbplaca In the tarns manner at normal ceneumer uaa. end which u*a reeWta bi a duratlen and trequaney af expoeure which It not greater then expoturet espertenced by cenaumera Ml Any (bug. a* that farm la defined bi the Federal Feed. Drug, and Coemetic Act (Xt U.S.C. 30i er teq.l. when b la bt seed, tbiar form for Greet admim-ttratten t* the patient (l.*.. tableta or pat). bi addRIon. Section 311 (e) of TSt* IS excludes the fotow. tig substances: ft) Any feed, food eddRfv*. color eddtiv*. drug, or eetmtde regiSated by the Food and Drug Adminttratlen: III Any tubttanc* pretem at a eeM In any manufaeturad Sam te the extent exposure to the tub ttanc* does not ecew under normal eondHIont et use: () Any substance te the extent S la used ter pertonal. femSy. er household pwpotes. or it prtttnt bi ths tarns form and eoneantratlon at a product pack aged tor Gstrtoutlon and ut* by the general pwbkc: |hf) Any tubttanc* to the extent S Is used bi s re- starch laboratory or a hotpfiaf or ether medtaal facs- Sy under the dbect eupenntlen of a tactinicaty qualfied bidhtdual: |v) Any tubttanc* to the extern S I* uaed bi routha agrteuSirel eperetlons er la a tertRzer hew for aale by a rataSer ta the iStbnata cuetemer. Alee, nUnbnwn reporting threahoM* have been titabHhed tor Tier One under TSt* SI. Section 312. You need te report enty those hazardous Chanucah that were pr*. tem at yaw taebty at any tbn* Owing the precedkig cal endar year at or above the tevete Stlsd below: * January te December 1337 (er first year of rooorttiql --10.000 bt. * January to December 11*3 (or second year ef repertbig) ...10.000 bt. * January te December 1*33 (or ttd year et reporting) ...zero bt " EFA wS pubsah the final throoheW. effective bi the third year, after adGtienal analysts. * For extremely hazardous substsnesi...S00 bs. or the tnrsshoW planning quantity, which ever it bat. from the firs) year af repertbig end thereafter. A requesting official may fcnh the retponees requbed wi der Tier Two by tpeelfybig partlewar chenVciK or groups ol ehenUeali. Suen requests apply to hazardous chemlealt regarGeia el ettaMahed threthoMt. 1 DE 008409 27 Federal Register / Vtil. 52. No. 1!)9 / Thursday. October 15. 10P7 / Rules und Regululiuns mstmucnoNS Pleas* ntd Ihtf liuintelitti were/ully. Prim ar rye* til ntptruu. WHEN TO SUfeMIT THIS FORM Owneri or operators mutt submit the Tie* Two form to the requesting agency within SO Otyt of receipt of t writton request from an authortzed otflotal. WHERE TO SUBMIT THIS FORM Sand the completed Ttar Two form to the"requeettog aganey. PENALTIES Any owner or oparator who ytolataa any Tiar Two report* Ing reqwamants ahal ba labia to tha Unitad Stataa for a CM penalty of I* to S2S.OOO for each auch vloiatlon. Each day a violation contkiMt that eonr.ttuta a taparata violation. You may uaa tha Tier Two form at a worksheet for completing the Tier One form Ffeng In the Tier Two Chemical Information taction thould hefe you aaaambla yow Tier One retponeea. K your reepontaa require more than one page. IS ki the page number at tha top of tha form. REPORTING PERIOD Enter tha appropriate calendar year, begkvWtg January t and anong December 31. PACIUTY IDENTIP1CATION Enter tha fid name of yetr faePty (and company Identi fier where appropriate). Enter the fid street atfckott or state road. If a atraet address la not avalabte. enter other appropriate Identifi ers that deterfee the physical location of your faePty (e.g., longitude and latitude). Include city, state, and tip coda. Enter the prtnary Standard Industrial Classification (SIC) coda and the Dial 3 Bradetreet number lor your faePty. Tha fbiandal officer of you faePty thould ba able to pro vide tha Dun ft Sradttreet number. If your fkm does not have this Information, contact tha state or re^onal office of Dun 3 Sradttreet to obtain yow faePty number or have one assigned. OWNERfOPCRATOR Enter the owner's or operator's hd name. maPng ad dress. end phone manbar. EMERDENCY CONTACT Enter tha name, title, and work phone number of at least one local person or office who can act at a referral If emergency responders need assistance In responding to a chemical accident at tha faePty. Provide an emergency phone number where such emer gency chemical kiformatien we be avaiaMe 24 hove a day. every day. CHEMICAL INFORMATION: Desarfpllen. Hatarda. Amounts, and Lecatlene Tha mam section of the Tier Two form requires specific Information on amounts and locations of hazardous chemicals, as defined m tha OSHA Hazard Comnwecatlon Standard. a What untie shoetd I use? CaicUate ai amounts aa weight In pounds. Te convert gas or Squid voAana to weight m pounds, imjtbfy by an appropriate density fac tor. a What about mbctieoe? If a chemical la part of a mixture, you have me option of reporting either the weight of the en tire mixture or only the portion ol the mixture that le a parttetsar haiardoue chemical (e g . P a hazardous eodtton weighs too be. but le composed of onfy $% of a particular hazardous chemical, you can Meat# either 100 ba. of tho mixture or 3 fee. of the chemical. Select tha option consistent with your Section 311 roportbg of tho chemical on tho MSDS or let of MSDS chomlcali. CHEMICAL DESCRIPTION 1. Enter tho Chemical Abstract Service number ICASP). For mbeturet. enter the CAS numbor of the mix ture at a whole If It hat bean assigned a number dhllnct trom Ha components. For a mixture that hat no CAS number, leave this ham blank or report the CAS numbers of aa many constituent eherreeale at pottfele. If you are wfthhoMng the name of a chemical In ac cordance with emeria apocffiad ki Tub p. Section 322. enter the generic chemical data (a g.. let toluene dhoeynate aa organic Itocynate) and check tha box marked Trade Secret. Trade secret Information should bo submitted to EPA and mint Include a substantiation. Pleaae refer to Section 322 of This HI for delated kiformatlon on how to oompty wtth trade secret roauestt. 2. Enter the chemical name or common name of each hazardous chemical. 3. Circle ALL Sppfteable descriptors: pure or mixnr#, and told. Squid, or gat. EXAMPLE: You have Ours chlorine gee on hand, at wcl at two mixtures that contain Squid CNortna You writs 'chlorine' and enter the CASS Then you circle 'pure' and 'mix' -- at waft aa `ftq'and `gat . 3837! V I 2 DE 008410 38376 Federal Register / Vol. 52. No. 199 / Thursday. October 15. 1987 / Rules and Regulations PHYSICAL AND HEALTH HA2ARDS Far each chemical you have Hied, cheek el the physical and health hazard boats that apply. Theta hazard cate goric* are defined ki 40 CFR 370.3. The two health haz ard cataoortet and three phytleal hazard categories are a eoneoMatlon el the 23 hazard cataoortet defined W the OSHA Hazard Communication Standard. 2t CFR 1S10.1200. MAXIMUM AMOUNT t. For each hazardoua chamleal. tttknatt the greatett amount present at your lacSty on any single day Str ing the reporting period. 2. Find the appropriate range value code kt Table I. 3. Enter thta range value ea the Matdnum Amount. Table t REPORTINQ RANOES Rang# Weight Range In Poutde Valua From... To... 00 0 01 too 02 1,000 03 10.000 04 100.000 OS 1.000.000 06 10.000.000 07 50.000.000 01 100.000.000 0 500.000.000 10 1 Mon 9 591 I.Kt 99.199 191.119 1.999.119 4t.tM.Ml 99 999.999 4M.M9.M! M9.M9.MI Nghor than 1 Mon If you are using tNt form at a worksheet for com pleting Tier One. enter the aetual weight In pounds In the shaded specs below the response blocks. Do tNt tor both Maxlmun Amowit end Average Daty Amount. EXAMPLE: You received one large shipment of a solvent mixture last year. The shipment Med you S.OOOgalon storage tank. You knew that the solvent content 10% benzene. vMch It a hazardous ehemeel. You figure that 10% of 5.000 galone la 500 galena. You also know that the density of benzeni It 7.21 pounds par gelon. so you mutpiy 500 by 7.2t to gat a weight of 3.545 pounds. Than you look at Table I and find that tht range value 02 corresponds to 3.045. You enter 02 as the Maximum Amount. (If you are using the form as a worksheet lor completing e Tier One form, you shoUd write *3.545 In the ahaded area.) AVERAOE DAILY AMOUNT 1. For each hazardous chamleal. ettknate the average weight at pounds that wat present at you' faesty str ing the year. To do this, total ai daly welghta and Adds by the lumber el days the chamleal wee present on the the. 2. Find the appropriate .range value kt Table I. 3. Enter ttta range value at the Average Daty Amount. EXAMPLE: The S.OOO-galon shipment el solvent you re ceived lest year was graduaty used up and completely gone ki 315 days. The etan of the daly vokjme levels kt the tank It S2S.2SO gatona. By (SvMng S2S.250 gatona by StS days en-alte. you calculate an average defy amotatt el 2.S50 Batons. You aveedy know that the solvent cootaria 10% benzene. wMctt la a hazardous chemical Saves 10% of 2.S50 la 215. you figure that you had an average of 2(3 gaSona el benzene. You aMo know that the density of benzene la 7.20 pounds per gaton. ae you nriultfcty 2S5 by 7.2S to get a weight of 2.ISO potmde. Then you look at Table I and find that the range value 02 eorrependa to 2.150. You enter 02 as the Average Oaly Amount. (If you are using the form at a worksheet for completing a Tier One form, you should write 2.150 kt the shaded area.) NUMBER OP DAY! ON-SITE Enter the number of daya that the hazardoua chemical was fouid on-shs. EXAMPLE: Ths solvent composed of 10% benzene wat present for 315 days at you tacBty. Enter 315 in the (pace provided. STORAOE CODES AND STORAGE LOCATIONS List el non-confldentlal chemical locations In this column, along with storage types/eondhlons associated with each location. Storage Codea: Indicate the types and conditions ol storage present. a. Loot el Table //. For each location, find the appropriate storage type I a). Enter the corretoonUng codele) In front of the parenthe ses. b. Look er Table ///. For each storage type, find the temperature and prestue condi tions. Emar the appacabie prestue code kt the frit (pace wttnki the parenthates Enter the applceb<e temperatue code kt the last tpaet within ths parenthatat. 1 i 29 DE 008411 Federal Register / Vol. 52. No. 199 / Thursday, October IS. 1987 / Rules and Regulations Tble II - STORAOE TYPES CODES Typos of Storaoo A Above gowtd tank Below ground tar* C Tank Ineldo tx**ng e Stoat drum E Plastic ar non-tnataBc drum F Can o Carboy H SSo 1 Fbor drum J Bag K box L Cylndar M Oats botttaa or fugs N Plastic bottles ar luge O Tota bkt p Tar* wagon o Ral ear R Other Optional attaehmanta: If you ehooee to attach one of the fosoelno. check the appropriate Attaehmanta boa at the bottom of the Tier Tare term. a. A trie plan with the eoordkiatea kvScated tor btMnga. Iota, areat. ete. throughout your faotty. b. A Mat of tiro coordinate abbreviation] that correspond to buMnga. lota, areas, ete. throughout your feeaty. EXAMPLE: You have bentene In the main room of the main btddng. and In tar* 1 m tank Md to. You attach a site plan with ooeromatsa ae foSowe: mam buMng O-t. tark haw to i-S. PI m the Stareg* Location aa fotowa: >-t ( Tank t | 0-2 (Mam Room) Table III - TEMPERATURE AND PREI CONDITIONS COOES Storage Condhtons (PRESSURE) Antalent pressure Greater than ambient prassro last than antbtant praattra (TEMPERATURE) Antbtant temoeratvre Oraatar than arnbtant tomperahr^ Lata than ambient temporatire but not cryogenic Cryogenic eondttona y. -an :v,-- EXAMPLE: The bentene St the makt buSdbtg la kept In a tank Inelda the btAdktg. at ambient preaatre and teas than ambient temperature. Table II ehowe you that the coda for a tank ktalda a btAdtag la C. Table III ehowa you that coda for ambient preeeure la 1. and the coda for leee than ambient temperature la S. You enter: C(t.S) J "'"'V.''' 'PwW'w'VaV/wjwnrA1 ; * rv Storage Lecatlen*:. Provide a brief desorption of the precise location of the chemical, so that emergency responders can locate the area aaaSy. Yau may fktd R advantageous to provide the optional site plan ar ska cooriSnates as exptakied below. For each chemical, Meats at a minimum the butdkig or lot. AdOttanafy. where practical, the room or area may be kvSested. You may respond kt narrative form wtth appropriate site eoordnates or abbreviations. N the ehemlcal Is present ki mors than one buldkvg. tat. or area location, continue yoir responses down the page as needed. H the chemical exists everywhere at the plant site sknitaneousfy. you may report that the chemi cal Is ubtaiitoue at the atte. Under Title SI. Section 324, you may elect to withhold location ktformatlen on a specific chemical from dvctoeure to the pcCSc. n you choose te do ao`. e Enter the word confidential' kt the Non-Confldantlal Location section of the Tier Two form. e On a separata Tier Two Confidential Location Information Sheet, enter the name and CAS* of each chemical for which you are keeping the location confidential. e Enter the appropriate location and storage In formation. aa desorfeed above for nen-conltdentlaf locations. a Attach the Tier Two Confidential Location In formation Sheet to the Tier Two form. This separates confidential locatlone from other kv formatton that wd be Oadoeed to the pupae. CERTIFICATION. This must be completed by the owner or operator or the offtaiafy designated representative of the owner or op erator. Enter your tul nemo and official title. Sign your name and enter the etarem date. I 3837. \ (FR Doe. 87-23642 Filed 10-13-67:10:46 am) 30 DE 008412 STATE EMERGENCY RESPONSE COMMISSIONS Alabama Alabama Emergency Response Commission Department of Envfrenmantal Management 1751 Federal Drive Montgomery, Alabama 36100 (205) 271-7700 Alaaka Alaska Emergency Response Commission P.O. Bos 0 Junaau, Alaska 09811 (907) 465-2600 American 8amoa Tsrritorial Emarganey Managamartt Coordination Office Amariean Samoan Govammant Pago Pago, Amariean Samoa 96709 Intamakonal (664) 633-2331 Arlxona Anxona Emarganey Response Commission Division o! Emergency Services 5636 East MeDowel Road Phoenix. Arizona 65006 (602) 244-0504 Commonwealth of Northern Mariana islands Ofltee of tw Governor CNMI Saipan. CNMI 06050 Iniemaliona! (670) 322-0520 Connectlent Cormaedeut Emarganey Response Commission Department of Envronment Protection Stale Capitol Buidfog Room 161 165 Capitol Avenue Hartford, Cortneebeut 06106 (203) 566-4017 Dataware Delaware Commission on Hazardous Materials Department of Pubic Safety Administration Center Dover. Deiaware 19901 (302) 834-4531 or 736-4321 District of Columbia Office of Emergency Preparedness 2000 14th SreeL NW 6th Floor Washington, D.C. 20009 (202) 727-6161 Arkansas Florida Arkansas Hazardous Materials Emarganey Response Commission PO. Bos 9563 8001 National Drive Littie Reek, Arkansas 72210 (501)562-7444 Florida Emergency Response Commission Florida Department of Community Affairs 2740 Cemerview Drive Tallahassee. Florida 32399 (904) 467-4915 California Georgia CaKfomia Emarganey Response Commission Office of Emarganey Services 2600 Meadowview Road Scramanto.'California 05832 (916) 427-4201 Colorado Georgia Emergency Response Commission Georgia Department ol Natural Resources 205 Outer Street. SE Floyd Towers East ABanta. Georgia 30334 (404) 6564713 Colorado Emergency Planning and Community Right-teKnow Commission Division of Disaster Emer gency Services Camp George West * Golden. Colorado 60401 (303) 273-1624 Guam Civil Defense Emergency Services Office Government of Guam P.O Box 2877 Aguana. Guam 96910 FTS 550-7230 Hawal Hawaii Emergency Response Commission Hawaii Department of Heaiti Environmental Epidemiology Program P.O. Box 3376 Honolulu. Hawaii 06801 (606) 5462076 or 546-5632 Idaho Idaho Emergency Response Commission Department of Health 6 Welfare State House Boise. Idaho 63720 (206) 334-5696 IHnofe KSnois Emergency Response Commission Mmols Emarganey Servians 6 Disaster Agency Attn: Hazmat Section 110 E. Adams Street Springfield. IMnois 62706 (217) 7824694 Indians Indiana Department of Environmental Management Emergency Response Branch 5500 West Bradbury Street Indianapolis. Indiana 46241 (317) 2465176 Iowa Iowa Emergency Response Commission 301 East 7th Street Das Moines. Iowa 50319 (515) 281-6175 Kanaaa Stale Emergency Response Commission Kansas Department of Health and Environment Forbes Field. Building 728 Topeka. Kansas 66620 (913) 2961690 Kentucky Kentucky Emergency Response Commission Kentucky Disaster and Emergency Services Boone National Guard Center Frankfort, Kentucky 40601 (502) 564-8682 Louistana Louisiana Emergency Response Commission Department of Public Safety 6 Correction' Office of Public Safety P.O. Box 66614 Baton Rouge, Louisiana 70896 (504) 025-6117 Maine Bureau of Labor Standards Ann: SARA Stale Office Building Station 62 Augusta. Maine 04333 (207)2804291 ' Maryland Governor's Management Advisory Counol Maryland Emergency Management 6 Civil Defense 2 Sudbrook Lane East East Pikesville, Maryland 21208 (301)4664422 Massachusetts Title Three Emergency Response Commission Department of Environmental Quality Engineering One Winter Street Boston. Massachusetts 02108 SERC (617) 292-5851 LEPCInfo (617)8761361 Michigan Michigan Department ot Natural Resources Environmental Response Division Tide III Notification P.O. Bos 30028 Lansing. Mehigan 46909 (517) 373-9693 31 DE 008413 Minnesota Minnesota Emergency Response Commission Division of Emergency Services Stale Capitol Room B-5 St Paul, Minnatota 55t55 (612) 296-2233 Mississippi NSssissippi Emergency Response Commission Misiiitippi Emergency Managamant Agency P.O. Box 4501 Foridren Station Jackson. Mississippi 39216-0501 (601)352-9100 Missouri Missouri Emargancy Rasponsa Commission Missouri Dapartmant ot Natural Resourcas P.O Box 3133 Jefferson City. Missouri 65102 (314) 751-7929 Montana Montana Emargancy Response Commission Environmental Sciences Division Dapartmant of Health 4 Environmental Sciences Cogswell Building A-107 Helena. Montana 59620 (406) 444-3948 Nebraska Nebraska Emergency Response Commission Nebraska Department ol Environmental Control Technical Serwces Section PO. Box 94677 Stale House Station Lincoln, Nebraska 66509 (402) 471-4230 Nevada Nevada Division ol Emergency Management 2525 South Carson Street Carson City, Nevada 89710 (702) 865-4240 or 885-5300 I New Hampshire Statt Emargancy Managamant Agency State Office Park South 107 Pleasant Street Concord, New Hampshire 03301 (603) 271-2231 New Jersey New Jersey Emergency Response Commission SARA TiSe III Protect Department ol Environmental Quality CN-402 Trenton. New Jersey 00625 (609) 292-6714 New Mexico New Mexico Emergency Response Commission New Mexico Department of Public Salety P.O. Box 1628 Santa Pe. New Mexico 87504-1628 (505) 827-9226 New York New York Emergency Response Commission New York State Department el Environmental Conservation Bureau of Spfl Preveneon 4 Response SOWolt Road. Room 326 Albany. New York 12233-3510 (518) 457-4107 North Carolina North Carolina Emergency Response Commission Division of Emergency Management North Carolina Department of Crime Control and Pubhe Salety 116 West Jones Street Raleigh. North Carolina 27611 (919) 733-2126 North Dakota North Dakota State Department ol Health 1200 Missoun Avenue PO Box 5520 Bismarck. North Dakota 58502-5520 (701) 224-2370 Ohio Ohio Emergency Response Commission Ohio Environmental Proteeeon Agency Office of Emergency Response P.O. Box 1049 Columbus. Ohio 43266-0149 (614) 461-4300 Oklahoma Oklahoma Emergency Response Commission Office of Civi Defense P.O. Box 53365 Oklahoma City, Oklahoma 73152 (405) 521-2481 Oregon Oregon Emergency Response Commission c/0 State Eire Marshal 3000 Market Street Plaza Suite 534 Salem, Oregon 97310 (503) 378-2885 Pennsylvania Pennsylvania Emergency Response Commission SARA Title III Officer PEMA Response 4 Recovery PO Box3321 Hamsburg. Pennsylvania 17105 (717) 783-8150 Puerto Rico Puerto Rico Emergency Response Commission Environmental Quality Board P.O. Box 11488 Santurce. Puerto Rico (809) 722-1175 or 722-2173 Rhode Island Rhode Island Emergency Response Commission Rhode Island Emergency Management Agency State House M 27 Providence. Rhode Island 02903 (401)421-7333 South Carolina South Carolina Emergency Response Commission Division of Pubhe Salety Programs Office ol the Governor 1205 Pendleton Street Columbia. South Carolina 29201 (803) 734-0425 South Dakota South Dakota Emergency Response Commission Department of Water 4 Natural Resources Joe Foss Building 523 Egst Capitol Pierre. South Dakota 57501-3181 (605) 773-3151 Tennessee Tennessee Emergency Response Commission Tennessee Emergency Management Agency 3041 Sidco Dnve Nashville. Tennessee 37204 (615) 252-3300 (800) 258-3300 Texas Texas Emergency Response Commission Division of Emergency Management 5805 Lamar Austin. Texas 76752 (512) 465-2138 Utah Utah Hazardous Chemical Emergency Response Commission Department ol Health 288 North 1460 West PO Box 16690 Salt Lake City. Utah 64116-0690 (801) 538-6101 Vermont Department of Labor and Industry 120 Stale Street Montpelier. Vermont 05002 (802) 828-2286 32 de 008414 Virgin Island* U.S. Virgin Islands Emergency Raspensa Commission Til* HI 179 Alton* St Thomas. VI 00602 (809) 774-3320 Ext 169 er 170 ... Virginia Virginia Emergency Raspensa Counci Department of Waste Management James Monroe.BuMng lilt Root 101 Mot* 14li Sleet Richmond. Virginia 23219 (804) 225-2999 Washington Washington Emergency Response Commission Division of Emargtney Management 4220 East Marin Way. Maitstop PT-11 Olympia. Washington 98504 (206) 753-5255 West Virginia West Virginia Emergency Response Commission Department of Natural Resources Cspttol Building. Room 669 1800 Washington Street. East Charleston, West Vxginia 25X5 (304) 348-2754 Wisconsin Division of Emergency Governor 4802 Sheboygan Avenue Room 99A P O Box 7865 Madison, Wisconsin 53707 (606) 266-3232 Wyoming Wyoming Emergency Management Agency Comprehensive Emergency Management 5500 Bishop Boulevard P O Box 1709 Cheyenne. Wyoming 8fe003 (307) 777-7566 EPA REGIONAL OFFICES Region - Stitt 4 - Alabama 10 - Alaska 8 - American Some* 8 - Aritona 8 - Arkansas 8 - California 6-Colorado 9 - Commonwealth of Northern Mariana Islands 1 - Connecticut 3-Delaware 3 - District of Columbia 4-Florid* 4 - Georgia 8 - Guam 8 - Hawaii 10 - Idaho 8 - Mlnol* 5-Indiana 7 - Iowa 7 - Kansas 4 - Kentucky 8-Louieana 1 - Main* 3 - Maryland 1 - Massachusetts 8 - Michigan 8-Minnesota 4 - Mississippi 7 - Missouri 9 - Montana 7- Nebraska 8- Nevada 1 - New Hampshire 2 - New Jersey 6 - New Mexico 2 - New York 4 - North Carolina 8 - North Dakota 8-Ohio 6 - Oklahoma 10 - Oregon 3 - Pennsylvania 2 - Puerto Rice 1 - Rhode Island 4 - South Carolina 8 - South Dakota 4 - Tennessee 8-Texas 8-Utsh 1 - Vermont 2 - Virgin Islands 3 - Virginia 10 - Washington 3 - West Virginia 5 - Wisconsin Contact the Preparedness Coordinator at the Regional Office Region 1 Region 4 Region 6 EPA - Region 1 New England Regional Laboratory 60 Westview Street Lexington. MA 02173 (617) 860-4300 Ext. 221 EPA Region 4 345 Courttand Street NE Atlanta. GA 30365 (404) 257-3931 Region 5 EPA Region 8 One Denver Place 999 18th Street Suite 1300 Denver. CO 80202-2413 (303) 293-1723 Region 2 EPA Region 2 Woodbridge Avenue Edison. NJ 08837 (201) 321-6656 EPA - Region 5 230 South Dearborn Street Chicago. IL 60604 (312) 886-1964 Region 6 Region 9 EPA - Region 9 215 Fremont Street San Francisco. CA 94105 (415) 974-7460 Region 3 EPA Region 3 841 Chestnut Street Philadelphia. PA 19107 (215) 597-0607 EPA - Region 6 Allied Bank Tower 1445 Ross Avenue Dates. TX 75202-2733 (214) 655-2270 Region 10 EPA Region 10 1200 6th Avenue Seattle. WA 96101 (206) 442-1263 Region 7 EPA - Region 7 726 Minnesota Avenue Kansas City. Kansas 66101 (913) 236-2606 33 DE 008415 HAZARD COMMUNICATION COMPLIANCE CHECKLIST D E 008416 CHAPTER SEVEN Hazard Communication Compliance Checklist HazCom is "performance-oriented rale." OSHA has set certain objectives you must reach, but it is not dictating the methods you use to achieve those objectives. This checklist will help you prepare for the kind of questions OSHA might ask you in determining whether your company has complied. A lot of work will go into earning the right to say "yes" to each question, but this checklist ' gives you a way to keep trade of your company's progress in reaching full compliance. Planning andAdministration of Your Company's Program: 1. Have we reviewed the requirements of the HazCom rale? 2 Has an employee been designated to be responsible for coordinating our written hazard communication program? 3. Have we prepared a written hazard communication program? (It is recommended this program be placed in a loose-leaf binder for ease in updating. See Chapter Three.) 4. Do we have a system for responding to medical requests for chemical information during a medical emergency? 5. Have we developed our emergency procedures and incorporated them into our Standard Operating Procedures? 6. Do we have a policy for exchanging hazard infor mation with other contractors? 7. Do we have a system for documenting that we have informed other contractors about the hazards we have on the jobsite and how they are classified? (Assign this responsibility to the project manager.) 8. Have we reviewed all existing company policies and operating procedures for their compliance with the HazCom Standard and amended them where necessary? Identification of Hazardous Substances: 1. Do we have an inventory list of all chemicals used in the workplace? 2. Is a list of all hazardous chemicals available at the jobsite? 3. Do we have a procedure for checking that we have received an MSDS from the manufacturer for incoming chemicals and that we have received any updates? (MSDSs need not be sent with every shipment after the initial MSDS is received, but t new MSDS should be sent whenever a chemical is changed or the MSDS is revised.) .4 Do we review incoming container labels to see if they have the chemical's name and appropriate hazard warnings? (The label should be an immediate warning and should summarize the most important information found in the MSDS.) 3. Have we developed labels, placards or batch tickets to be used when any product is removed from its original container or when it is mixed by us? Employee Training Programs: 1. Have we developed a system for communicating the information in MSDSs to all company employees? 2 Do we have procedures for employee training to provide information on chemical hazards at both initial assignment and whenever new information becomes available? 3. Are our employees familiar with the different types of chemicals and the hazards associated with them? 4. Do our employees understand how to detect the presence or release of hazardous chemicals in the workplace? S. Are our employees trained in proper work practices and personal protective equipment in relation to the hazardous chemicals in their work area? 6. Does our training program provide information on appropriate first aid, emergency procedures and the likely symptoms of overexposure? 7. Does our training program include an explanation of labels and warnings that are used in each work area? 8. Does the training describe where to obtain MSDSs and bow employees may use them? 9. Do we have a recordkeeping system to show that employees have been informed of hazards? _ 10. Do employees not routinely exposed to chemicals know where to find the MSDS forms and how to use them? i A s noted in theforeword to dot manual the pemcipadng associations errpresently invokedin e lefolchallenft to the Harold Communication Standard Pending the resobaion ofthis dotation, the parnexpednt associations make no warranty that the information contained herein will necessarily be accepted by OSHA. 34 DE 008417 CHAPTER EIGHT "What If..." Simple Answers to Anticipated Problems As you hive made your way through this manual, you have no doubt had a number of questions about how HazCom is actually going to work on construction sites. You also are probably wondering what you are going to do when you hit a snag in the system. The following question and answer discussion hopefully will provide some answers to your questions. Q. What if a labeled product arrives without the Material Safety Data Sheet? A. Since the product is labeled as hazardous, you should make a good-faith effort to obtain the MSOS. Do the following: 1. Type the sample letter requesting the MSDS or the label (See the chapter entitled "Sample Forms and Letters") and send it to the manufacturer/supplier as soon as possible. 2. Keep a copy of your letter in your files and document when you sent it 3. Send a follow-up letter in thirty days if you have still not received the requested information. 4. Record the receipt of the MSDS when it arrives and file it 5. Continue to keep records of each request you have made and the response received. Q. What if/ live in a small town and deal with only a few retail outlets or suppliers, and / have trouble getting MSDSs or labels from them? / don't want to alienate them by harassing themfor the information. A. If you have trouble getting the information from the local suppliers, write them a letter requesting the information in a friendly or business-like tone stating you are trying to fulfill the requirements of the OSHA Hazard Communi cation Standard. Keep copies of this correspondence. If it appears likely that this wifi not do any good, write directly to the manufacturer of the product and document this as well. OSHA also.urges employers to contact their local OSHA office for assistance if they have problems obtaining MSDSs from suppliers or manufacturers. Q. Is there a complete list ofhazardous chemicals used in construction? A. There are hundreds of thousands of chemicals which qualify as hazardous under HazCom. Obviously, not all of them are used in constructiqn, but many are. There is no definitive list of chemicals used in construction and you should be wary of purchasing one from a company which says they have one. Every construction firm will have to evaluate its own products, which is the intention of HazCom. No two companies or jobsites will be alike, even in the same specialty trade. Q. Who is responsiblefor the accuracy ofthe MSDSs? A. It is the responsibility of the manufacturer to provide accurate information on the MSDSs. No one expects you to be a chemist Q. What if I receive the MSDS to a product separate from the shipment and the MSDS doesn't identify the product by its common name? How do / know which product it belongs with? A. Until manufacturers understand their own obligations under HazCom, this situation is likely to occur. All MSDSs should identify the common identity of the product. If you receive one which doesn't regardless of whether it came with the product contact the manufacturer for the infor mation. You need the information for training and your employees need it for reference and emergencies. Q, What if/ receive an MSDS with one or more blank spaces? Do / assume that those sections don V apply? A. If a section of an MSDS doesn't apply, then the box should read "not applicable" or "N/A." If nothing is filled in, you should contact the manufacturer requesting the information. (See the chapter entitled "Sample Forms and Letters.") Q. How do / know if the chemical make-up of a product changes? A. It is the responsibility of the manufacturer to provide you with a new MSDS when the chemical make-up of a product changes. It is then your responsibility to inform your employees about the changes. Q. Do labels and MSDSs have to be translated into foreign languages if the majority of workers do not read or understand English? A. While labels and MSDSs must be in English, you are not required to have them translated. You must still make an effort to train these employees. Contact your local OSHA office for assistance. As noted in theforewordto this manual the participating associations an presently involved in a legal challenge to the Hazard Communication Standard. Pending the resolution of this litigation, the participating aisociationj make no warranty that the information contained herein mil necessarily be accepted by OSHA. 3S DE 008418 Q. On the other hand, what do I do if I use some specialised products that are only available from foreign suppliers? Do I have to translate MSDSs and labels myself? A. If you rely on foreign supplies, it is the responsibility of the importer of the product to translate labels and MSDSs. As with requests for missing labels and MSDSs, make sure you put requests for translations in writing and keep them on file. Q. Do workers have to be trained whenever a different brand ofa product is used? A. No. Retraining must take place when new hazards are introduced, not when one brand is substituted for another. Q. Who is responsible for training employees on construction sites? A. Each contractor is responsible only for his or her own employees. However, you must train your employees about the hazards other contractors working in the same area may be exposing your employees to and what protective and emergency measures they have to take. You must get this information from the other contractors) and the same information will be requested from you. Q. Who will coordinate this exchange of information between contractors? A. It is up to the individual contractors to get the information from other contractors on site. However, the simplest method wilt be to find out who the other contrac tors will be before work begins and contact them. Keep careful documentation of this effort Q. What if another contractor has never heard of HazCom? A. This will probably be a major problem in the early years of compliance. As in the last answer, the best thing to do is to contact the other contractor. (See the chapter entitled "Sample Forms and Letters.") 'litis will be part of your good faith effort to comply. Q. Can't tjust hire a consultant to bring my company into compliance? A. HazCom is going to be an ongoing process as long, as you are in business. You can hire someone to do it for you. but only if you are confident of their knowledge of the requirements. Unfortunately, a number of unrcputable "safety consultants" will be popping up all over the country hoping to cash in on contractors' confusion over the standard. There are a number of reputable outfits providing good services, but you will need to be able to tell the good from the bad. Q. Do lhave to keep records of my employee training? A. While it is not a requirement of HazCom. it is strongly recommended that you keep a record of all employees trained and have them sign off on it. (See the chapter entitled "Sample Forms and Letters.'*) Otherwise, you will have no proofof an employee's training. It could be vital in liability cases. Q. What are the penaltiesfor non-compliance? A. Violations of HazCom and other OSHA standards are punishable by civil and criminal penalties which could go as high as several thousand dollars. In addition, failure to implement a hazard communication program could result in a liability suit directed at your company and increased insurance rates. Q. What ifI'm a small contractor? Do l really need to worry about compliance? A. There is no exemption from compliance for small contractors. The penalties for non-compliance can be just as severe, the liability risk just as great and the insurance rates just as high for small contractors who fail to comply. Q. What ifI'm doing repair work on a project that has long since been completed. How do / know what hazards already exist on the project? A. Under HazCom, on repair work you are required only to provide the best known information about the hazards of the items already installed. You do not need labels and MSDSs on those products if they are not available, but you should make sure your employees are informed. i 36 DE 008419 CHAPTER NINE Federal HazCom Assistance and State Enforcement Because of (he complexity of HazCom, OSHA has appointed "Hazard Communication Coordinators" in its ten regional offices around the country (see following list of offices). These coordinators are there to assist you with any questions or problems you may have with establishing a hazard communication program within your company, as well as assisting you with tracking down MSDSs, labels and other information necessary to comply. Some contractors need to also be aware that federal OSHA does not enforce the standard in all states and territories. In some cases, state OSHAs will be enforcing the standard's requirements. These state OSHAs are known by a variety of acronyms such as MOSHA, WISHA, VOSHA, etc., and these agencies have just as much authority, and sometimes more authority, than federal OSHA in handing out citations, fines, and sometimes jail sentences for safety violations. r However, only those states which have an "OSHAapproved" state plan can enforce the standard. Those states are: Alaska, Arizona, California (after July 1, 1989), Hawaii, Indiana, Iowa, Kentucky, Maryland, Michigan, Minnesota, Nevada, New Mexico, North Carolina, Oregon, Puerto Rico, South Carolina, Tennessee, Utah, Vermont, Virginia, Virgin Islands, Washington, and Wyoming (see following list of state OSHA offices). In some instances, these states may have additional requirements that exceed the requirements of the federal standard. You may want to contact your local state agency for All other state and local HazCom or "Right-to-Know" regulations are preempted by the federal standard, and federal OSHA will conduct HazCom inspections in all other states. Don't be confused by "state vs. federal" HazCom enforcement All contractors will be expected to comply with essentially the same standard. -------------------------- U.S. Department of Labor--------------------------Regional OSHA Offices with Hazard Communication Coordinators REGION I (CT, MA, ME, NH, RI, VT) 133 Portland Street Boston, MA 02114 (617) 565-7164 REGION VI (AR, LA, NM, OK, TX) 525 Griffin Square, Room 602 Dallas, TX 75202 (214) 767-4731 REGION II (NJ, NY, PR, VI) 201 Varick Street Room 670 New York, NY 10014 (212) 337-2348 REGION Vn (IA, KS, MO, NE) 911 Walnut Street Room 406 Kansas City, MO 64106 (816) 426-5861 REGION III (DC, DE, MD, PA, VA, WV) Gateway Building, Suite 2100 3535 Market Street Philadelphia, PA 19104 (215) 596-1201 REGION Vm (CO, MT, ND, SD, UT, WY) Federal Building, Room 1576 1961 Stout Street Denver, CO 80294 (303) 844-3061 REGION IV (AL, FL, GA, KY, MS, NC, SC, TN) 1375 Peachtree Street N.E., Suite 587 Atlanta. GA 30367 (404) 347-3573 REGION IX (AZ, CA, HI, NV) 71 Stevenson Street, Room 415 San Francisco, CA 94105 (415)995-5672 REGION V (IL, IN, MI, OH. WI) 32nd Floor, Room 3244 230 South Dearborn Street Chicago, IL 60604 (312) 353-2220 REGION X (AK, ID, OR, WA) Federal Office Building, Room 6003 909 First Avenue Seattle, WA 98174 (206) 442-5930 37 DE 008420 ---------------------- States with OSHA-Approved State Plans-----------------------In thefollowing states and territories, HasCom is enforced by these state agencies: ALASKA Alaska Department of Labor P.O.Box 1149 Juneau, AK 99802 (907)465-2700 ARIZONA Industrial Commission of Arizona ' 800 W. Washington Phoenix, AZ 85007 (602) 255-5795 CALIFORNIA (alter July 1,1989) California Department of Industrial Relations 525 Golden Gate Avenue San Francisco, CA 94102 (415) 577-3356 HAWAII Hawaii Department of Labor and Industrial Relations 825 Mililani Street Honolulu, HI 96813 (808) 548-3150 INDIANA Indiana Department of Labor 1013 State Office Building 100 North Senate Avenue Indianapolis, IN 46204 (317) 232-2663 IOWA Iowa Division of Labor Services 1000 E. Grand Avenue Des Moines, IA 50319 (515)281-3447 KENTUCKY Kentucky Labor Cabinet U.S. Highway 127 South Frankfort, KY 40601 (502) 564-3070 MARYLAND Maryland Division of Labor and Industry Department jf Licensing and Regulation 501 St Paul Place Baltimore, MD 21202 (301) 333-4176 MICHIGAN Michigan Department of Labor 309 N. Washington P.O. Box 30015 Lansing, MI 48909 (517) 373-9600 MINNESOTA Minnesota Department of Labor and Industry 444 Lafayette Road Sl Paul, MN 55101 (612) 296-2342 NEVADA Nevada Department of Industrial Relations Division of Occupational Safety and Health Capitol Complex 1370 S. Curry Street arson City, NV 89710 (702) 885-5240 NEW MEXICO New Mexico Environmental Improvement Division Health and Environment Department P.O. Box 968 Santa Fe, NM 87504 (505) 827-2850 NORTH CAROLINA North Carolina Department of Labor 4 West Edenton Street Raleigh, NC 27603 (919) 733-7166 i 38 DE 008421 OREGON Accident Prevention Division . Oregon Department of Insurance and finance Labor and Industries Building Salem. OR 97310 (503) 378-3304 PUERTO RICO Puerto Rico Department of Labor and Human Resources Prudencio Rivera Martinez Building 505 Munoz Rivera Avenue Halo Rey, PR 00918 (809)754-2119-22 SOUTH CAROLINA South Carolina Department of Labor 3600 Forest Drive P.O. Box 11329 Columbia, SC 29211 (803) 734-9594 TENNESSEE Tennessee Department of Labor 501 Union Building Suite A, 2nd Floor Nashville, TN 37219 (615)741-2582 UTAH Utah Occupational Safety and Health 160 East 300 South P.O. Box 5800 Salt Lake City, UT 84110 (801) 530-6900 VERMONT Vermont Department of Labor and Industry 120 State Street ,, r Montpelier, VT 05602 (802) 828-2765 VIRGIN ISLANDS Virgin Islands Department of Labor Box 890 Christianstcd St Croix, VI00820 (809) 773-1994 VIRGINIA Virginia Department of Labor and Industry P.O. Box 12064 Richmond, VA 23241 (804) 786-2376 WASHINGTON Washington Department of Labor and Industries General Administration Building Room 334-AX-31 Olympia, WA 98504 (206) 753-6307 WYOMING Wyoming Department of Occupational Health and Safety 604 East 25th Street Cheyenne, WY 82002 (307) 777-7786 39 DE 008422 w DE 008423 CHAPTER TEN Sample Forms and Letters Substanct Inventory Control Sheet Jobsite Name (if applicable): ______Date Purchased:------------------------------------------------------------------------------------- Chemical Name: .-------------------------------------------------------Synonyms:------------------------------------------------------ --- Trade Names:____________ ______________________ Manufacturer Name: Address: ------------ -------------------------------------------------------------------------------------------------------------------------------- __________ Telephone Number. - Supplier Name:--------------------------------------------------------------------------------------------------------------------------------------- Address: -------------------------------------------------------------------------------------------------------------------------------------------- . Telephone Number__________________________________________________________ Label Statements: --------------------------------------------------------------------------------------------------------------------------------- MSDS Cross Reference Number ! MSDS received with shipment? Yes No (If no, attach copy of letter sent to manufacturer requesting MSDS.) Updated MSDS received?' Yes No If yes: Date received:Date new MSDS was added to MSDS file: Does MSDS contain new health or physical hazard information? Yes No Must new employee training be scheduled? Yes O No Date training held: ______ _____________________ Where substance is used: Location Frequency Quantity Used By 1. 2____________________ _____________________ 3______________________ ________________________ 4. SI 6- T 7 Completed by:_____________ ____________________________ Date: i As noted in theforewordso this manual the participating associations are presently involved in a legal challenge to the Hazard Commumcanon Standard, rending the resolution ofthis litigation, the participating associations make no warranty that the information contained herein mil necessarily be accepted by OSH t 40 DE 008424 Sample MSDS Information Posting The Occupational Safety and Health Administration requires all employers to make information on any hazardous chemicals in their workplace available to all employees. Vital information about the nature pf these substances, safety precautions, and emergency procedures may be found in the Material Safety Data Sheets (MSDSs). MSDSs For This Workplace Are Located At Location Location(s) Location(s) Person(s) Responsible for MSDSfs) Phone A copy of this company's written hazard communication program is located at Sample Letter Requesting an MSDS (Place all letters on your company letterhead.) Date Name and Address of/ chemical manufacturer, importer or supplier Dear: In order to comply with the OSHA Hazard Communication Standard, we will need an accurate and current Material Safety Data Sheet for all hazardous products purchased from your company. The enclosed list shows the produces) for which we do not have an MSDS.' Please send us the MSDSs concerning these products. All correspondence should be directed to the address above. If you have any questions concerning this matter, please contact (name) at (telephone number, including area code). Thank you for your timely response to this request Sincerely, 41 DE 008425 Follow-up Letter to Request for MSDS (*Placa on company lattarhaad) Date Name and Address of/ chemical manufacturer, importer or supplier Dear----------------------------- : Recently we sent you a request for Material Safety Data Sheets on products purchased from your company. To date, we have not received the requested MSDSs. A second copy of the list of products for which we need MSDSs is enclosed. In order for our firm and yours to be in compliance with the federal Hazard Communication Standard, you must provide us with current accurate MSDSs for all hazardous products we have purchased from you. Your prompt attention to this matter is appreciated. Sincerely, Purchase Order Requesting an MSDS TO: (Seller) RE: Purchase Order No. .for The OSHA Hazard Communication Standard requires us to maintain and distribute Material Safety Data Sheets (MSDSs) for all chemical substances and hazardous materials used by our employees. To meet these requirements, we request a current, completed MSDS for the following purchased items: ITEM NUMBER PRODUCT NAME (Identify chemicals by the item numbers and product names appearing on the purchase order, including any trade names, code numbers, or stock numbers.) MSDSs should be sent to the address below on or before the date the produces) will be delivered to us. (shipping address or office address) 42 DE 008426 Follow-up Letter to Purchase Order Request for MSDS (Place on company letterhead Name and Address of/ chemical manufacturer, importer or supplier Dear: Recently we requested current and complete Material Safety Data Sheets for the following items purchased pursuant to Purchase Order Number____________________________________________________________________ : ITEM NUMBER PRODUCT NAME (Identify chemicals by the item numbers and product names appearing on the purchase order, including any trade names, code numbers, or stock numbers.) In order for our firm and yours to be in compliance with the federal Hazard Communication Standard, you must provide us with current, accurate MSDSs for all chemicals we have purchased from you. Your prompt attention to this matter is appreciated. Sincerely, Sample Letter Requesting Additional MSDS Information Name and Address of/ chemical manufacturer, importer or supplier Dear_; In an effort to comply with the OSHA Hazard Communication Standard, my company is seeking additional information on products produced by your company. The MSDS's forwarded to us appear deficient as follows: 1. Paint Thinner #340 -- no health effects listed. 2. Speedy Varnish -- no physical hazard listed. Please be advised that for us to comply with the Hazard Communication Standard and to provide adequate training for our employees, we must have complete MSDSs, particularly with reference to the above-identified items. Your cooperation will be appreciated. Sincerely, 43 DE 008427 1 HAZARDOUS COMMUNICATION EMPIOYEE TRATNTNO 1.00 p E 00S428 Sampl* Employ** Training R*cord Jobsite (if applicable): ------------ :----------------------------------- --------------Employee's Name: --------------------------------------------------------------------Department Trainees):------------------------------------------------ ---------Dute and Tim* of Training:----------------------------------------.------------------Substances Covered/Which Work Areas/Special Procedures Required: Employee's signature attesting to the training: Jobsite (if applicable): -----------------------------------------------------------------Employee's Name: ______________________________________________ Department Trainees):___________________________________________ Date and Time of Training:_______________________________________ Substances Covered/Which Work Areas/Special Procedures Required: Emoloyee's signature attesting to the training: Jobsite (if applicable): ___________________________________________ Employee's Name: ______________________________________________ Department Trainees):___________________________________________ Date and Time of Training:_______________________________________ Substances Covered/Which Work Areas/Special Procedures Required: Employee's signature attesting to the training: 44 Date: Date: Date: DE 008429 Sample Letter to Other Contractors on the Same Construction SHe (Place on company letterhead.) Date r Name and Address of/ other contractor Dear------------------------------: Employees of our company will be working on the (location) construction site at the same time as your company. Our employees may be in close proximity to hazardous substances your company may produce, store or use on site. In order to comply with the OSHA Hazard Communication Standard, all contractors who could cause hazard exposures to another company's employees are required to exchange information about the hazardous chemicals used on site. Please advise us where your MSDSs are kept and give us any information regarding any precautionary measures needed to protect employees, any foreseeable emergency situations, and your labeling system used in the work site. Ail correspondence should be directed to the address above. We are enclosing similar information on the hazardous chemicals our company will have on the site. Thank you for your timely response to this request If you have any questions concerning this matter, please contact (name) at (telephone number, including the area code). Sincerely, Follow-up Letter to Other Contractors on the Same Construction Site (Place on company letterhead.) Date Name and Address of/ other contractor Dear: Recently we requested that you advise us where your MSDSs are kept for all hazardous substances produced, used or stored on (location) construction site. We also requested information regarding any precautionary measures to protect employees during normal operations and in foreseeable emergencies and your labeling system used on the work site. In order for your firm and ours to be in compliance with the OSHA Hazard Communication Standard, we must receive the requested information. Your prompt attention to this matter would be appreciatedSincerely. 45 DE 008430 FEDERAL REGISTER D E 008431 Monday August 24, 1987 t Part III Department of Labor Occupational Safety and Health Administration 29 CFR Parts 1910, 1915, 1917, 1918, 1926, and 1928 Hazard Communication; Final Rule 47 DE 008432 31852 Federal Reciter / Vol. 52. No- 163 I Mondy. August 24. 1997 / Rules and Regulations DEPARTMENT Of LABOR themselves, are available from the Committee submitted its final report to OSHA Docket Office. Dockets H-022 the Assistant Secretary for Occupational Safety and HeaTOt and H-022D, Occupational Safety and Occupational Safety and Health which Administration Health Administration. 200 Constitution recommended categorization and a* cfr farta mo. lots. i*tr. mo. Avenue. NW.. Room N3670. Washington. DC 20210: telephone ranking of chemical hazards, as well as provisions for labels, material safety im, and 1120 (202)523-7894. data sheets, and training programs (or (Docket Mo. H-022O) L Background all workers. The National Institute for Haxard Communication .aciNCt: Occupational Safety and 'Health Administration (OSHA): Labor. Acnom Final role. summary: OSHA is ravisint Its Hazard Communication Standard (HCS) (29 CFR 1910.1200). which currently applies to the manufeeturin| sector, to cover all employers with employees exposed to hazardous chemicals in their workplaces. Expansion of the scope of the HCS requires non-manufacturing employers to establish hazard communication programs to transmit information on the hazards of chemicals to their employees by means of labels on containers, material safety data sheets, and training programs. This action will reduce the incidence of chemically-related occupational illnesses and infuries in nonmanufacturing workplaces. dates: Effective September 23.1967. The tevised standard published today requires that chemical manufacturers, importers, and distributors ensure that material safety data sheets are provided with the next shipment or hazardous chemicals to non-manufacturing employers or distributors after September 23.1887. All employers in the non-manufacturing sector are to be in compliance with all provisions of Ore standard by May 23.1961. son FURTHER MPOAMATWN contact: Mr. fames F. Foster. Office of Information and Consumer Affairs. Occupational Safety and Health Administration. 200 Constitution Avenue. NW,, Room N3637. Washington. DC 20210: telephone (02)523-8151. SUPPLEMENTAAV MPOMSATIOM References to the rulemaking record ate made in the text of this preamble, and the following abbreviations have been used: A. Hittory of OSHA't Hazard Communication Standard When Congress passed the Occupational Safety and Health Act of 1970.29 U.S.C. 651 at rtf (the Act). It included language in section 6(b)(7) stating that any occupational safety or health standard promulgated by the Secretary of Labor under section 8(b) rulemaking authority "shall prescribe the use of labels or other appropriate forms of warning as are necessary to insura that employees are apprised of all hazards to which they are exposed, relevant symptoms and appropriate emergency treatment, and proper conditions and precautions of safe use or exposure." Whenever OSHA has promulgated a substance-specific rule to address the hazards of a particular chemical, this Congressional directive has been followed. However, given the universe of chemicals present in American workplaces (as many as 575.000 hazardous chemical products), and the time-consuming nature of OSHA's rulemaking process, it soon became clear that little Information would be available to employees if this substanee-by-substance approach were the only one pursued. The Agency thus decided to address the issue of hazard information transmittat on a generic basis. OSHA's experience, as well as our rulemaking record to date, supports the view that when employees have access to. and understand, the nature of the chemical hazdrds they are exposed to during the course of their employment, they are better able to participate in their employers' protective programs, and take steps to protect themselves, hi addition, providing employers with complete chemical hazard information enables them to better design and implement protective programs. Together these actions will result in more effective worker protection and the occurrence of fewer Occupational Safety and Health (NIOSH) published a criteria documem in 1974 which also recommended a standard to OSHA. The document, entitled "A Recommended Standard... An Identification System for Occupationally Hazardous Materials." included provisions for labels and material safety data sheets. In 1976. Congressman Andrew Maguire from New lersey and the Health Research Croup petitioned OSHA to issue a standard to require the labeling ofall workplace chemicals The House of Representatives' Committee on Government Operations (1976 and 1977) recommended that OSHA enforce the health provisions of the Act by requiring manufacturers to disclose any to\ic ingredients in their products, and byrequiring all employers to disclose this information to workers. On January 28.1977. OSHA initiated the public participation phase of the rulemaking process on these issues by publishing an advance notice ol proposed rulemaking (ANPR) on chemical labeling in the Federal Register (42 FR 8372). The ANPR requested comments and information on the need for such a standard, and the particular provisions that should be included The Agency received eighty-one comments. Most supported the need for the rule, but opinions as to the specific approaches to be pursued varied significantly. On January 16.1981. OSHA published a notice of proposed rulemaking (KPRM) entitled "Hazords Identification" 146 FR 4412). The rule would have required manufacturing employers to assess the hazards in their workplaces using specified procedures, and to label containers. The requirements were quite different from the comprehensive approach previously recommended by the Standards Advisory Committee and NIOSH as they did not include provisions for material safety data sheet H-022. Ex.: Exhibit number in Docket illnesses and injuries due to exposure to development or training. H-022. which includes Dockets H-022A chemicals. See. e.f.. 48 FR 53282-64. and H-022B. 53321. 53323-24. 53327-29 (Nov. 25. OSHA withdrew the NPRM on February 12.1981 (46 FR 12214) for Ex.: Exhibit number in Docket H-022D 1963): 47 FR 12093-12101 (Mar. 18.1982). further consideration of reguletory for exhibits collected since ths 1985 In 1974. OSHA established a altematives. A new NPRM was Court remand. * Standards Advisory Committae on published on March 19.1982. and was Tr.: Public hearing transcript page Hazardous Materials Labeling under entitled "Hazard Communication" (47 number. section 7(b) of the Act to develop FR 12092). It proposed to require Copies of the official list of entries in guidelines for the Implementation of producers of chemicals to evaluate them the record, as well as the exhibits section 0(b)(7). On )une 6.1975. the to determine their hazards, label 48 DE 008433 Federal Register / Vol. 52. No- 1G3 / Monday. August 24, 1987 / Rules and Regulations 31853 containers. and provide malarial lately developed in the manufacturing sector data iheata to manufacturing purehatera first regardless of the eventual coverage of their products. The standard alio of the rule. OSHA believed that proposed that all employers in the requiring the development of the manufacturing sector have a hazard chemical hazard information in communication program, label in-plant manufacturing would lead to its containers, maintain and provide aecaii increased availability in the other to material safety data sheets, and train sectors without the standard specifically workers. The proposal also invited requiring the transmittal of hazard comments on whether non- information to those sectors. The manufacturing employers should be Agency acknowledged that hazardous subject to the nile. chemicals are pervasive throughout Following a period for written comments, informal public hearings, and a post-hearing comment period. OSHA published the final Hazard Communication Standard on November 25.1983 (48 FR 83280). The provisions of the final rule ere very similar to those described above for the proposal, is.. chemical manufacturers and importers art required to evaluate the hazards of the chemicals they produce or import, and all manufacturers ars required to have hazard communication programs for their employees exposed to hazardous chemicals. This comprehensive standard was designed to reduce the hazards faced by industry and that chemical source Injuries and illnesses have been recorded In all industry sectors. See. e.g.. 48 FR 53282-87.5ee oho United Steelworker* l. 763 FJtd at 737. The Agency planned to make a decision regarding the explicit coverage of the non-manufacturing sectors ones tbs HCS was in effect and a determination could be made as to whether the other industries were, in fact obtaining the information they needed. OSHA believed that the Act give* the Secretary of Labor and the Agency the authority to regulate the most hazardous industry first under section 6(g), 26 U.S.C. 655(g). which states in part: manufacturing workers when they In determining the priority for establishing handle chemicals without adequate standards under this section, the Secretary Information on. among other things, the physical and health hazards of the chemicals, safe handling precautions, and emergency and first aid procedures. See. e g.. 48 FR S3321. OSHA found that shall give due regard to the areeney of the need for mandatory safaty and haallh standards for particular industries, trades, crafts, occupations, businesses, workplaces or work environments. inadequate communication regarding B. Court Challenge* chemical hazards presents a significant risk to workers. See. e.g.. 48 FR S3321. Accord United Steelworker* ofAmerica v. Auchter. 763 Fid 728.735 (3d eir. 1965) {United Steelworker* i) ("|I)nadequate communication is itself a hazard, which the standard can eliminate or mitigate."). The HCS was challenged in the U.S. Court of Appeals for the Third Circuit (hereinafter refenred to as "the Court" or "the Third Circuit") on several grounds. The Court issued its decision on May 24.1985 {United Steelworker* I, 763 FJd 726 (3d Cir. 1985)). The standard was upheld in most respects, OSHA decided to limit the scope of but three issues were remanded to the coverage of the HCS to the manufacturing sector based on an Agency for reconsideration. The decision was not appealed. analysis of the chemical source illnesses First, the Court concluded that the and injuries occurring in each Industrial definition of trade secrets ineorporeted sector. {See discussion at 48 FR 53264- by OSHA included chemical identity 60.) In particular, since the purpose of Information that was readily the standard is to reduce the occurrence discoverable through reverse of such incidents. OSHA determined engineering and. therefore, was that the rule should focus on those "broader than the protection afforded industrial sectors where they are trade secrets by state lew." The Court recorded most frequently. The Agency directed the Secretary of Labor to found that over half of these incidents reconsider a trade secret definition orcur in manufacturing, although which would not include chemical manufacturing accounts for only about Identity information that Is readily 3D percent of total employment! Thus discoverable through reverse OSHA decided that the greatest need for engineering. Seeond. the Court held the transmittal of chemical hazard trade seeret access rule in the standard information is in the mahufacturing invalid insofar as it limited access to sector. The Agency further recognized health professionals, but found the that since chemicals are developed and access rule otherwise valid. The produced in the manufacturing sector, Secretary was directed io adopt a rule the hazard information would have to be permitting eccess by employees and their collective bargaining representatives to trade secret chemical identities. OSHA complied with the Court orders regarding the two trade secret issues in a separate rule, published in final form on September 30. 1966 (51 FR 54560). The third issue remanded to OSHA involved the scope of the standard's coverage. As noted, the HCS currently applies to employers and employees in the manufacturing sector. The Court refected the Secretary's contention that section 6(g) gave him the flexibility to regulate the most hazardous sector first before commencing rulemaking for other sectors in which workers ere exposed, to a lesser extent, to the same hazards. The Court agreed that section 6(g) "clearly pemits the Secretary to set priorities for the use of the Agency's resources, and to promulgate standards sequentially." 763 T2i at 736. The Court also acknowledged that "there is substantial evidence tn the record that the manufacturing sector has the highest incidence rate of chemical exposures which the Agency hss authority to regulate." id. at 737. However, the Court held that it is not enough merely to establish that the sector selected for coverage presents greater hazards than those that have been left for later rulemaking. Civen the record evidence of high levels of exposure to hazardous chemicals in several job settings outside the manufacturing sector, the Secretary was required to explain "why coverage of worker* outside the manufacturing sector would bave seriously impeded the rulemaking process" or "why it is not feasible for the same standard to be applied in other sectors where workers are exposed to similar hazards." Id. at 738. The Court was not persuaded that the HCS would provide protection to uncovered workers because chemical hazard warnings would be found on container labels and detailed information on material safety data sheets would become increasingly available in the unregulated sectors as a result of being required in manufacturing. Id. There was considerable record evidence that indicated that workers in the non manufacturing industries are exposed to chemical hazards. The Court concluded that the Secretary had not stated why it would not be feasible to require employers In non-manufaetunng industries to give workers material safety data sheets and training as required in the manufacturing sector. Id. The Court maintained that the Act required an explanation why the same information, that is. labels, material 49 DE 008434 31854 Fodtral Register / Vol. 52. No. 183 / Monday. August 24. 1907 / Rules and Regulations safety data sheets, and training, is not manufacturing. there wat a need for needed for worker* in other sector* more direct evidence of the feasibility of similarly exposed to haiardoos expanded coverage, particularly in tha chemicals. Id at 7JW9. Therefore, as araa of economic feaaibility. previously indicated. OSHA was Accordingly. OSHA believad it was directed by the Court to reconsider the necessary and appropriate to initiate application of the standard to further rulemaking. OSHA employees in the notHnanufacturinf commitsioned a study of the economic industries and to order its application to impact of extending the HCS to the fifty these other sector* unless the Secretary major non-manufacturing Industry can state reason* why this application group* within its jurisdiction, and iaaued would not be feasible. It should be noted an Advance Notice of Proposed that in previous OSHA litigation, the Rulemaking (ANPR) seeking public Courts have defined "feasibility" in comment on present hunts terms of OSHA rules a* meaning communication praeticea outside "capable of being done." American manufacturing, and the likely impact of Textile Manufacturers Institute v. extending the HCS to Industrie* Donovan. 452 US. 49a 509-509 significantly different from the (1960KATM11. prototypical manufacturing worksites on .OSHA decided not to appeal this which the original standard was based. decision. As stated in the preamble to SO FR 48794 (Nov. 27.1985). Over two the final rule (49 FR 53286): hundred responses were received. Based It should be emphasised that the Agency does noi believe that employee* In other industries ere not exposed to hazardous on this newly acquired evidence and on the previous rulemaking record. OSHA was in the process of drafting a chemicals, or that they should not be proposed rule which it expected to informed ot those hazards. OSHA has merely exercised Its discretion to establish rulemaking pnortties. and chosen to first regulate those Industries with the greatest demonstrated need. OSHA was prepared to evaluate tha HCS' effectiveness bt getting information to downstream employers, and to extend the standard If necessary. In fact, tha Agency initiated the process on March 4.1685, prior to the Court decision, when the Assistant Secretary publish for notice end comment followed by promulgation of a final rule in early 1988. On lanuary 27,1987, however, the United Steelworker* of America. AFUCIO-CLC and Public Citizen, lne., petitioners in the 1985 challenge, filed a Motion For An Order Enforcing The Court's Judgment end Holding Respondent In Civil Contempt. Petitioner* claimed that the Court's 1985 order had not authorized OSHA to asked the National Advisory Committee embark on further fact gathering: that on Occupational Safety and Health OSHA should have made a feasibility (NACOSH) to give OSHA its determination on the 1985 rulemaking recommendation on the need and record. Petitioner* also argued that even feasibility of expanding the scope of the If further fact gathering had been HCS to other industries. On June 21. allowed by the Court's order. OSHA'* 1985. NACOSH adopted the following pace wat unduly alow. recommendation: In response. OSHA noted that the (NACOSH) strongly endorse* the OSHA effort to promulgate a Hazard Court's 1985 order did not specify thal OSHA should act on the (hen-existing Communication Standard and selection of tha record. OSHA believed that seeking manufacturing stetor for its Initial scope of coverage. It is the consensus recommendation of the Committee that the scope of the current Hazard Commvnieattoa Standard thoeld be expanded to cover all employees in all Industrie* at a* early a time as possible. Complete Implementation may require phasing In gradually. The BIS further evidence on feasibility In non manufacturing was appropriate in light of its statutory obligation to issue rules that are well grounded in a factual record. OSHA alto asserted that, consistent with Supreme Court precedent, the Agency should be IBureau of LaMr Statistics) incidence rates of permitted to exercise itt discretion in occupations) Illnesses, and other appropriate determining the appropriate rulemaking factors, should be primary considerations in expanding the coverage. The Commute* further recommends that OSHA establish a task force to address these issues. Meanwhile. OSHA'* review of the rulemaking record showed that while there was considerable evidence procedures for complying with the Court's remand order, lastly, the Agency argued that Itt schedule to complete the rulemaking was reasonable and did not constitute undue delay. On May 29.1987. the Court Issued a concerning the need tor huard decision holding that the Court'* 1985 communication in other industrial, and remand order required consideration of general support fora finding that tha the feasibility of an expanded standard HCS would be feasible for non without further rulemaking. United Steelworkers ofAmerica. AFL-CiOCLC v. Pendergrass. No. 83-3554 (3d Clr.) [United Steelworkers If). The Court declared that adequate notice had been provided to non-manufacturers during the original rulemaking that Ihey might be covered by the HCS. Id. slip op. at *10,18-17. that the answers to the remaining question* OSHA may ha\ e had regarding feasibility were "selfevident" or "readily ascertainable" irom the original record, id. at 15.17. and that further fact finding was "unnecessary". id. at 15. The Court ordered the Agency to issue, within 80 days of its order, "a hazard communication standard applicable to all workers covered by the OSHA Act. including those which have not been covered In the hazard communication standard at presently written, or a statement of rcaaont iv hy. on the bails of tha present administrative record, a hazard communication standard is not feasible." Id. at 19. OSHA ii responding to the Court order by issuing this final rule expanding the scope of the HCS' coverage to ail workers within OSHA's jurisdiction. OSHA continues to believe that it should have been permitted to follow the rulemaking procedures In the Act by Issuing a notice of proposed rulemaking and developing a public record prior to promulgating a final rule. However, as discussed in the following section regarding feasibility, the Agency does not have sufficient evidence in the current record to indicate that the rule would be infeasible for any part of ihe non-manufacturing sector. OSHA recognizes that information submitted during a norma) rulemaking process might have resulted in further changes to the provisions to better address feasibility or practicality concerns. In light of the fact that there may be additional information regarding the feasibility or practicality of the rule as it applies to some non-manufacturing sectors, the Agency invites persons io provide such information and any recommendations for further rulemaking within sixty day* of the date of publication of this final rule. OSHA will then evaluate these submissions and determine whether any additional rulemaking is required. Data or evidence related to feasibility should be addressed to: Directorate of Health Standards Programs. Occupational Safety and Health Administration. Attention: Hazard Communication. 200 Constitution Avenue. NW.. Room Nina. Washington. DC. 20210. SO 008435 * Federal Register / Vol. 52. No. 163 / Monday. August 24. 1987 / Ruler and Regulations 31855 C. Feasibility ofthe Standard technical aspects of the standard- employees chemical hazard information In the context of OSHA standard etting. feasibility conitralnte limit the extent to which standards can address health and safety concerns within the workplace. Section 6(b)(5) of the Act 29 U.S-C 655(b)(5). Feasibility analysis involves an inquiry to determine whether a standard is both technologically and economically capable of being dons.AThll. 452 U.S. at 512-13 and 513 n.3l (I960). As the Third Circuit has indicated, "the Secretary was able to determine that the harard communication standard could feasibly be applied in the manufacturing sector.'* United Steelworkers II. slip op. at 16. The Court further noted that OSHA had concluded in the final rule that importers and distributors could feasibly comply with the HCS baaed on the evidence in the record and that "this is equally true of all non-manufacturer user employers. Plainly, the ease with which the same information can be utilized by those employers can be easily determined from the information already In the record." Id. at 18. The Third Circuit has ordered expansion of the HCS to all workers unless OSHA can give reasons why the HCS is scientific evaluation of chemicals to in the manner prescribed by the HCS. determine their hazards and creation of As noted previously, development of the material safety data sheets and warning evidentiary record for the HCS began as labels--remain a burden on those early as 1974. In that year. N10SH producing or importing hazardous recommended that OSHA adopt a chemicals. The technical expertise standard requiring aII employers to needed to develop the chemical hazard implement a system of labels, placards information, and Its associated costs, is and material safety data sheets in their subsumed within the current rule ' workplaces to inform employees about covering manufacturers, and it has been the chemical hazards to which they may found feasible. All other requirements in be expostd. (H-022. Ex. 4). The NIOSH the HCS. such as maintaining material recommended standard, like the HCS. safety data sheets, developing a written included requirements that employers hazard communication program, and ensure that chemicals in the workplace designing and implementing chemical are marked with hazard warnings and hazard training, are conventional and that material safety data sheets are common buaineas practices that are "tiled in the establishment" where they administrative in nature, and no are "readily available for examination technological barriers prevent their by workers". Id. at 3. This hazard development and implementation. identification and warning system was OSHA has mandated such practices for designed to additionally "help in the some non-manufacturing workplaces education of employees and provide the since the early 1970 s. See. eg.. 29 CFR data necessary for employers to take 1915.97 (requiring material safety data proper action to safeguard their sheets and chemical hazard training for employees." Id. at 1. NIOSH concluded shipyard workers); 1917.22 (requiring that such a chemical hazard marine terminal workers be instructed communication program was as to the chemical hazards presented by appropriate for all employers. See. also cargo): 1918.86 (requiring chemical comments of the Air Transport hazard instruction for longshore Association. H-022. Ex. 5-J ("(T)he infeasible for particular industries, and workers): 1928.21 (requiring chemical airlines have no general objection to the has forbidden OSHA from gathering further evidence. hazard training for construction workers). See. also. H-022. Ex. 99 (NIOSH) Criteria. . . [except that it] should clearly delineate the OSHA concludes that the original (journal article regarding usefulness of responsibility of the manufacturer HCS rulemaking record (Docket H-022). material safety data sheets, written by supplying the necessary data on the does not contain credible evidence Dow Chemical Company Material Safety Data Sheets.") indicating the standard would be representatives and published in The 1975 report of the Standards infeasible for any industrial sector. In December 1957). Advisory Committee on Hazardous fact. OSHA believes that the original OSHA also believes that the economic Materials Labeling (H-022. Ex. 3). record on the whole supports a finding feasibility of extending the current HCS recommended a "total system" that the performance-oriented HCS is to tha non-manufacturing sector is approach to chemical hazard feasible for all industries. In addition, supported by the record. Simply pub communication not unlike the the Agency's experience under the economic feasibility is established by comprehensive approach of the current present HCS and other pertinent OSHA evidence that the standard will not HCS. The Advisory Committee, which standards, the promulgation and threaten the regulated industry's "long included representatives of non- implementation of State and local right- term profitability.*' A TMI. 452 U.S. at manufacturers, recommended labeling to-know laws, and evidence and data 531 n.55. Costs associated with and placarding systems, the creation gathered by the Agency since the 1985 expanding the standard to cover non- and availability of material safety data Court order (Docket H-C22D). further manufacturing workplaces will stem sheeta. and amployee education and supports OSHA's conclusion that non- from the initial start-up eosts and the training programs for alt workers manufacturing employers are "capable'* less substantial recurring program potentially exposed to hazardous of implementing the HCS for their implementation and upkeep costs for chemicals. The Committee recognized employees potentially exposed to maintaining material safety data sheets that these practices "are not new and hazardous chemicals. received from manufacturers, importers, novel concepts" but "well established in OSHA found that the HCS is distributors, and other employers: many industries and professional technologically feasible for creating labels for in-house containers associations as well as regulated by manufacturers, and believes it is clearly of hazardous chemicals: developing a various governmental agencies and technologically feasible for non- written hazard communication program, international agreements." Id. at 3. The manufacturers as well. Twelve of the including a list of hazardous chemicals Advisory Committee made "no OSHA-approved Slate plan States have present in the workplace: and distinction among employees in different already extended the rule to cover the developing and implementing chemical sectors of the economy." United non-manufacturing sector, and the hazard training. Steelworkers II. at 7. requirements are being epforced in those After careful analysis of the original As the Court has stated, id. at 8. the States as workplace standards. This HCS rulemaking record. OSHA 1977 ANPR requested public comment experience provides practical evidence of the technological feasibility of tha requirements of the rule. The more concludes that, as a whole. It supports a finding that non-manufacturers are economically capable of providing from all interested persons on whether a ehemical hazard communication atandard ahould be promulgated by 51 DE 008436 31856 Federal Reenter / Vol. 52. No. 163 / Monday. August 24. 1987 / Rules end Regulation* OSHA. Comments o the Standards to employees, and providing information safety data sheet policy and program Advisory Committee's recommended and training to employees regarding the "[UJnder this program, a material safety standard were specifically requested. chemical hazards present in the data sheet is recognized as a basic Although OSHA did not receive comment from employers in every Industrie! sector, those non manufacturers that did respond supported a comprehensive hasard communication system for their workplaces. For example. Sea-Land Service. Inc. (H-022. Ex. 2A-6). workplace to be economically feasible. See. oho H-022. Exs. 2A-2 (Schirmer Engineering Corporation); 2A-31 (Union Electric Company): 2A-32 (Texaco); 2A3* (American Trucking Association. Inc.). Moreover, comments received from non-manufacturers at later stages of the source of information for practical health, safety and environmental information. The MSDS whether generated internally or obtained from a supplier is used to communicate relevant data within the company and to outside customers. It is the responsibility of our various operating supported requirements for container original rulemaking also indicate they companies to distribute copies of each labels (consistent with transportation are capable of implementing the MSDS to customers and company labels already in place), the availability performance-oriented HCS. In fact, there facilities for employee instruction and/ of material safety data sheets to persons are comments which indicate that many or information." Tr. 2439. Their company in the workplace, and individual tnininf of these requirements were already facilities Include such non- programs. Panhandle Eastern Pipe Line being implemented in the non manufacturing operations as petroleum Company (H-022. Ex. 2A-7) and manufacturing sector. production. TmcUine Gas Company (H-022. Ex. 2A- For example, the Western Agricultural Similarly.Exxon. Inc. testified that it 9) both "agree|dj that employees need Chemicals Association indicated that Its too provides material aafety data sheets information about the product with members provide material safety data to all customers; "(Wje consider a which they work" and that this could be sheets to anyone who requests them, material safety data sheet a matter of accomplished by reouiring suppliers of including customers in the non public information that's part of our hazardous chemicals to label containers manufacturing sector (Tr. 2873). Their literature, regularly available to anyone with the "degree and nature of the representative further stated that "|i)n who requests it." Tt. 1708-09. See. oho. hazard" and by requiring user the agricultural field. I would say most Shell testimony at Tr. 1712 and 2500. and employers to "inform employees of the technical products have material aafety Uniroyal Chemicals at Tr. 1464: hazard." Those companies had already data sheets. I would say maybe 753 to Therefore, bated on the developed "a special manual of data for 803 of the Inerts have them . . ." (Tr. recommendations of N10SH. the all chemicals, solvents and cleaners 2881). Standards Advisory Committee and the used in (their] operations and There was also testimony from comments received from non- maintenance* employee representatives, including manufacturers and their representatives Wisconsin Electric Power Company those in the non-manufacturing sector participating in the lengthy rulemaking. (H-022, Ex. 2A-30). stated that given such as airline mechanics, that they OSHA condudes that the original record adequate labels and material safety requested and were able to obtain as a whole indicates that non- data sheets from chemical material safety data sheets horn manufacturers are capable of complying manufacturers and suppliers, chemical manufacturers for products in use in with the HCS. As long as chemical users such as they "would be in a their facilities. Tr. 2619-21.3131.3828. suppliers provide adequate chemical positron to prepare their own Material One union testified that a foint hazard information in the form of labels Safety Oats Sheets, hazard placard employee-employer safety committee and material safety data sheets to non systems, proper labeling of auxiliary received every material safety data manufacturers using the chemicals, and secondary containers and training sheet it requested, and that the union those user employers. like the of personnel who may use or otherwise then trained workers to be able to use manufacturers who use hazardous contact this material* Recognizing the the information. Tr. 2824-A. chemicals which they themselves did need for "proper labeling, storage, Another non-manufacturing union not manufacture or import, can develop handling and instructions in the use of representative, the International hazard communication programs and hazardous materials.* Wisconsin Brotherhood of Painters and Allied provide employees information and Electric Power Company had already Trades, indicated that It shared training on the chemical hazards in the "developed and put into effect a collected material safety data sheets workplace. Hazardous Materials Control Program." with employers who needed such In light of the evidence in the original Southern Cas Association (SGA) (H- information. "(T]o contractors who rulemaking record. OSHA concludes 022. Ex. 2A-7S) also believed that make requests of us for information, we that non-manufacturers can incorporate suppliers and manufacturers of do provide them material safety data the HCS' administrative practices and hazardous materials should be required sheets, write-ups on the chemicals and provide chemical hazard information to to provide proper labeling, warnings and the products . . . We do everything-- their employees. OSHA believes all other hazard information to all our union does eveiything they can as a employers can ensure that containers of employers using these materials. SGA service to our contractor members to chemicals are maintained with proper further suggested that OSHA promulgate provide them with the Information they hazard warnings just as an employer a standard directing all employers "to need to operate safely. . . ." Tr. 2101-2. would maintain labels or marks on establish required training for Other large companies with containers to ensure that employees employees that may handle or otherwise manufacturing as well as non- comprehend their contents and intended be exposed to any hazardous materials." manufacturing establishments testified uses. Likewise, all employers are able to These comments and others filed in that information was made available acquire and maintain up-to-date response to OSHA's 1*77 ANPR indicate throughout their corporations, and they material safety data sheets for that many non-manufacturers consider provide information to all customers hazardous chemicals lust at they are maintaining labels received on chemical containers, making material safety data sheets received from suppliers available regardless of Industry. For example. Atlantic Richfield Company testified that they have a company-wide material able to acquire and maintain up-to-daie cost information and performance specifications on those very same 52 DE 008437 Federal Rentier / Vol. 52. No. 163 / Monday. August 24. 1967 / Rule* end Regulation* 31857 chemical*. OSHA alio conclude* that it i* (eacible for employer* to Inform and train their worker* regarding the chemical hazard* preient in the workplace |u*t a* employer* are capable of training their worker* to perform their |ob* in an efficient and speedy manner. The** conclusions art further eupported by the experience and evidence gathered by the Agency tinea promulgation of the HCS for manufacturer* in IMS. At thi* time. OSHA ha* no evidence indicating that the profitability of manufacturer* generally, or even chemical manufacturer* in SIC 20 (by far the moil economically burdened by tba HCS. tee 48 FR 53333}. ha* been threatened by complying with the HCS. Maniifacturer* have had the considerable cotta of evaluating, collectively, hundred* of thousand* of chemical* for their hazard* and creating corresponding label* and material safety data sheet* since November IMS, at well as the eost* of implementing an in-plant program by May IMS. After thorough analysis. OSHA determined that the current HCS would not impose a substantial burden on manufacturer* and that the HCS was economically feasible for them. Set 48 FR 53333. Experience to date in implementation of the rule support* that finding. For example, if manufacturer* wera experiencing significant feasibility problem* in complying with the rule, OSHA would have expected to receive numerous substantive comment* regarding'those problem* in response to the 1985 ANPR questions addressing feasibility concerns. However, although some manufacturing employer* objected to some requirement*, substantive comments demonstrating infeasibility were not received, which appear* to support OSHA's conclusion that compliance with the HCS wa*. and continues to be. economically feasible for manufacturers and indicates th* standard is also feasible for nonmanufacturers. In fact, some manufacturcrs'took the opportunity to state their continuing support for the rule and its requirements. See. eg- H022D. Ex. 2-14. (The Chemical Manufacturers Association "strongly believes that the substantive provisions of the Hazard Communication Standard are sound as a matter of science and policy."): Ex. 2-87 (Economics laboratory. Inc. "considers hazard communication worth the effort."} Generally, the HCS edits to nonmanufacturers would be a function of the number of hazardous chemicals in the workplace, and the number of employees exposed to hazardous chemical*. If employee* are not Communication Standard are potentially exposed to hazardous economically feasible for all of the non- chemical* in a particular work manufacturing industries. operation, the proposed standard doe* OSHA it also aware (hit many not apply. Also, to the extent that employers in the manufacturing sector employer* are voluntarily providing have been able to satisfy tome of their information, or providing information in responsibilities under the HCS by using order to comply with other regulation* compliance materials obtained from or laws, this should significantly reduce various sources. Trade associations, for die burden of compliance with this rule. example, have frequently been Approximately 32 States and several instrumental in assisting their members localities already have hazard in developing programs suitable for their communication/right-to-know laws type of Industrial facility. This is covering non-manufacturing industries particularly appropriate given the indicating that many other* seeking to performance orientation of the HCS. and rotect the safety and health of workers the flexibility employers are permitted ave concluded that industry can to design appropriate compliance comply with these type* of program*. Sample written programs and requirements. In fact, a* evidenced in other written materials, as well as th* original rulemaking record, many training programs regarding the companies involved in interstate requirements of the rule, have been commerce would benefit from developed and provided to association promulgation of a uniform Federal members and have facilitated standard as it would preempt different compliance efforts. The ability of and potentially conflicting State and associations to accomplish this local law* and lessen overall successfully demonstrates technical compliance burdens. 48 FR 53283. Set feasibility and enhances economic alto, eg- H-022D. Ex. 2-83 (The feasibility. Trade associations in states American Gas Association "believe* covering non-manufacturing workplaces that a Federal Standard, rather than a under their right-to-know rules have also variety of differing state regulations, been able to develop materials to assist would best serve the need* of th* their member* to comply. Materials natural gas industry, the employees in developed for these State laws or for the our industry, and the general public as manufacturing sector under the current well"}: Ex. 2-1M (The National HCS could be adapted for the non Constructor* Association has found that manufacturing workplaces newly "(i]t has been nearly impossible to covered by the HCS. establish uniform interstate policy" and There have also been a number or "can clearly tee th* wisdom of having services provided by consultants in the one workable/cost-effective government private sector. These range from very regulation that addresses hazard specific items, such as computer communication.") programs to manage information, to a Although the original HCS record comprehensive compliance strategy, contained no evidence to indicate the where a consultant will devise an entire HCS would be economically infeasible program to enable a facility to eomply. for non-manufacturing. OSHA Such services will often minimize the recognized that potential feasibility concerns could arise, for example, with small businesses, businesses with large burden of compliance by minimizing the time the facility staff must spend to develop and implement a program. The employee turnover (such at retail stores availability of such programs also and construction companies), and provide* support for th* conclusion that businesses with rapid turnover of the rule is feasible. hazardous chemicals in the workplace For large companies, the burden per (such as warehouse* and marine cargo facility will often be minimized by operations). However, based on the corporate development of a original HCS rulemaking record, and standardized program. It can be additionally bated on: (1) The apparent expected that most corporations with successful implementation of the present multiple facilities will use this approach HCS by manufacturers: (2) the (this has occurred in the manufacturing implementation of other Federal sector as well). communication standards and of State Therefore. OSHA concludes that plan States' laws by non-manfacturers: similar resources will be available to and. (3) on regulatory impact and employer* in the non-manufacturing regulatory flexibility analytes prepared sectors, which further demonstrates that by the Agency since the 1985 Court the rule is feasible for implementation in order and summarized in Section 111 of all sectors. In fact, given the pre-existing this document. OSHA concludes that the coverage of non-manufacturing under provisions in the current Hazard various state rules, and the extent of the 53 DE 008438 S1858 federal Register / Vol. 52. No. 163 / Mondcy. August 24. 1307 / Rules nd Regulations materials developed la response to the employees in every SIC code Safety and Health met to discuss s draft current HCS which would also bo designation are exposed to hazardous proposed standard prepared by OSHA pplicabl* in non-manufacturing, chemicals, and that it is therefore not to expand the tcope of the HCS to the additional development of such appropriate to exempt any particular non-manuficturing Industrie!. The draft materials should require considerably industry sector. For example. OSHA has ropoaed rule wa* very similar to the less effort and be easier for non- received suggestions that retail ntl standerd being promulgated herein. manufacturers to obtain. establishments be exempted since OSHA bet reviewed the Nevertheless. OSHA recognises that employee exposure to chemicals is recommendations of the Construction the unique characteristics of some believed to be unlikely in these types of Advisory Committee, and incorporated businesses render certain provisions of fecilities. However, there is testimony in a number of the suggested revisions into the current standard unnecessary or the original rulemaking record from Ins this document to tailor the rule for the ineffective in communicating the hsssrds of chemicals to workers. The Agency has thus madt soma modifications to tha standard to anaure United Food and Commercial Workers International Union (Tr. 3069-97) that demonstrates that workers in such facilities are exposed to hazardous construction industry, and for other Industries which have similar concerns due to similar differences in work operations from the typical that Its provisions ate practical and effective In communicating hsurds to all workers. Cf. AtMl, *M US. at S31 chemicals, and therefore do need the protections afforded by coveraga under the HCS: manufacturing establishment. Other recommendations called for more substantive chenges to the HCS, n.32 (OSHA may use eost-sffactiveness Wblli supermarkets don't use hmtdreds of affecting the obligations of chemical analyses and choose the lass costly of fcaiardous chemicals Ilk* tome manufacturers and others, and OSHA two equally effective standards). The inclusion of these "tailoring" provisions it consistent with the Agency's action in tailoring the original HCS to make It practical and cost-effective for all manufacturers. See 29 CFR 1910.1200(b) manufacturing laduitrit*. a large number of workan are exposed to tbs doian or so they do use. Chemicals used include caustic and acid eltsning compound*, solvents, waxes, paints and disinfectants. .. let me relate to you one ease within oar union where workers were overexposed to so ontdatibed does not believe they are supported by the record or appropritte to incorporate into this Final rule without further opportunity for notice and comment from those affected. It is Important' to note, however, the! despite the (3HS). Now that the coverage of the substance. A group ot supermarket woektrt recommended changes there were no standerd it being expanded to non* began expenenong dizziness, upper indications tint members of the manufacturing employer* at wslL it is necessity to tailor tbs standard to tha unique characteristic* o! these nonmanufacturing employers. The tailoring provision*, explained tn Section 0 of respiratory tract Irritation and headaches .. . Net untit worksn started to talk with one another did they start to tusptet a possible link betwsen their iUnosa and a certain solvent that wee need to remove old price labels bom merchandise Construction Advisory Committee believe that It is infeasible to implement htzird communication programs tn the construction Industry, in fact, ss OSHA has noted previously, the construction this preamble, an based on the original called Cerety XC-M. Industry has been subject to training record in the HCS rulemaking, and also on Agency experience In implementing the current rule; Stete plan State experience in implementing expended versions of the current rule and comments submitted to the Agency In response to the ANPR published in November 1905. OSHA believes that tha knowledge and txperienca gained during the paat few ytare of implementation and enforcement of the current rule must be taken into consideration when oafUng a rule to appropriately apply to the nonmanufacturing sector. See Tr. 3086-69. See oho Tr. 414 end Tr. 1640-43. The testimony further relates other incidents, at well at the various activities the union had to pursue to obtain information for exposed workers--including chemical analysis of products to determine their contents. This illustrates the need for application of the standard In industries such at retail stores, at well as those Industries whtre chemieal exposures are more Obvious. For additional testimony regarding the extent of chemical exposures in the non-manufacturing sector, see. if., hospital workers: Tr. requirements concerning chemical hazards for many years (see 29 CFR 1926.21). In preparing the draft proposed rule, and subsequently this final rule. OSHA did review the Report on Occupational Health Standards for the Construction Industry which wts submitted by the Construction Advisory Committee to the Assistant Secretary on May 16.1980. In that report the Committee addressed recommendations for labels, material safety date sheet*, and training--all of the major components of the HCS. Of particular concern to the The Agency's position Is thst sQ employees are entitled to information regtrding the chemieal hazards they are exposed to in the workplace, and that a uniform Federal hazard communication standard is the best method to ensure that information Is provided. This position is consistent with the Act (protecting all employees to the extent feasible), as wel) as svitb the Court's decision upon review of the rule. Therefore, this final rule addresses 411-14.2736-41. and 3036(". .. hospital workers are exposed to formaldehyde, ethylene oxide, cleaning agents which are often very caustic . ..'') (Tr. 411): barbers and beauticians: Tr. 416-16 (". . . work around hair dyas ... known to cause cancer ..."); longshore worker*: Tr. 3143: utility workers: Tr. 417.3078.3130; worker* in dry cleaners end liundries: Tr. 416.4064-90 (" . . . (B)eyond the chlorinsted solvents that yonr dry clsanar* use. Committee at that time was that construction employer* do not have access to the necessary information upon which to develop appropriate signs and Isbell or material safety data sheets, and therefore must depend upon suppliers for such information. "ICjonstruction employer* may not always be aware ol the hazard associated with a particular product or device if the item* are not accompanied upon purchase by appropriate labels communicating chemieal hazards to all exposed employees. some desners and laundries also use dyes .. ."k farmworker*: Tr. 2290. and data sheets. . .OSHA agrees that this lack of information has been a It should be empSsslzed that la preparing a detailed regulatory impact analysis for the expansion of the scope D. Construction Advisory Committee Recommendations problem for all downstream user* of chemicals, and thus developed the approach Incorporated into the HCS-- of the HCS. OSHA bis accumulated On |unt 23.1967, ths Construction producers or importers of chemicals are evidence to indicate tbtt some Advisory' Committee on Occupational responsible for evaluating the hazards 54 DE 008439 Federal Register / Vol. S2. No. 163 / Monday. Augmt 2d. 1887 / Rules end Regulations 31859 end trentmittini that Information to It was interesting to note that construction employers and employees, downstream employers or usera of the although the Construction Advisory in addition, it will alto be printed in 29 materials. Under the expanded rule, Committee was essentially maintaining CFR Parts 19111917. end 1911 for the construction employers would be the that hazard communication in use of maritime employers and recipients in this downstream low of construction could be treated as a employees (at new 11915.99.1917.28. information. separate issue, meny of the chenges the and 1916.90. respectively), and will be The HCS did not exist at the time of members were recommending'would referenced in Part 1928 covering the report and the Committee thus often have required substantive changes agricultural eotploymentt. recommended that a solution to the problem of lack of information "would be to modify and extend the existing in the requirements for the manufacturing sector. As noted above, the Committee expects to receive tables Federal Community Right-to-Know Law OSHA standard for material safety data sheets which now applies only to ship repairing, shipbuilding, and snip breaking (29 CFR ISIS, 1916 and 1917). The modified standard would require manufacturers or formulators of harmful materials or agents to supply material safety data sheets along with their products in such a fashion that they reach construction employers." Shipbuilding and ship repairing are in the manufacturing sector, and covered by the requirements of the 1963 final rule--ship breaking will be covered by these expanded provisions. Therefore, OSHA is doing what was recommended in 1980. i.e., extending the existing OSHA standard for material safety data sheets to construction. The Advisory Committee concluded that although tha hazard information may have been difficult for construction employers to acquire in the pash "such information was fundamental to the preparation of warning signs, labels, training programs, and other important Job safety ana health activities." The Construction Advisory Committee is now recommending that the construction industry be regulated under a separate standard for Hazard Communication, rather than being treated as any other downstream employer who uses chemicals. The rationale is that construction sites are unique among industrial workplaces and should be addressed in a vertical standard specific to the industry. Although OSHA hat found this argument persuasive for a few health standards, where there are fundamental differences in control strategies to achieve permissible exposures for a chemical in a fixed site facility versus on containers and material safety data sheets from Its suppliers. This Is certainly consistent with OSHA's approach in the rule. But the Committee is also recommending that the labels on containers being shipped to construction contain additional information, and that the requirements for materiel safety data sheets be slightly different as well They also recommended changes in the hazard determination provisions, while maintaining that hazard determinations must be accomplished in the manufacturing sector. These recommendations serve to support OSHA's view that in an approach which requires a downstream flow of information, the relationship between the requirements for producers and downstream users are so inter* dependent thst separation of them into two separate standards would be logically inconsistent. And furthermore, since the requirements for hazard determinations, labels, and material safety data sheets were based on an extensive rulemsking record, and are not industry-specific. It would not be appropriate to modify those requirements at this point. Two separate standards would also require cross-referencing provisions from one rule to another to ensure proper information transmittal, a ' regulatory format which would be unnecessarily confusing to the regulated community. OSHA believes it is more effective to list, in one standard, the obligations of chemical producers. Importers, and suppliers with those of the users so that employers using hazardous chemicals will be aware of the content and quality of the hazard information they are entitled to receive Expansion of OSHA's HCS will also have an impact on employers' obligations under another Federal law to Inform Stats and local communities.of the hazardous chemicals present in the workplace. On October 17.1986. the President signed into law the Supefund Amendments and Reauthorization Act of 1986 ("SARA"). Part ol the new law. Title M. the Emergency Planning and Community Right-to-Know Act of 1968. encourages and supports emergency planning efforts at the State and local level and provides citizens and local governments with information concerning potential chemical hazards present in their communities. Two provisions in the new law. sections 311 and 312. mandate that employers required under the Occupational Safety and Health Act of 1970 and regulations under that Act to prepare or have available material aafety data sheets for hazardous chemicals in their workplaces, must also submit chemical hazard information to State and local governments. Specifically, employers required by the OSHA HCS to create or maintain material aafety date sheets for employees must also submit to the State emergency response commissions, the local emergency planning committee and the local fire department: (1) A material safety data sheet for each hazardous chemical for which a data sheet is available (section 311): and (2) an emergency end hazardous chemical Inventory form (section 312). The public may request material safety data sheets and inventory information from the local planning committee. Because all manufacturing employers the construction site, it does not appear from their suppliers. Furthermore, it are currently subject to the OSHA HCS to be appropriate In this situation which would not be spproprtate to indicate simply involves transmittal of requirements for chemical and required to create or maintain data sheets for the hazardous chemicals information, that can be accomplished on any type of site. Arguments regarding transient workers, mobile work sites, etc. can appropriately be made for other manufacturers end importers in a standard which purports to cover solely the construction industry, at would have to be done to accommodate all of the present in their workplaces, they must also comply with the community reporting requirements of the Emergency Planning and Community Right-to-Know non-manufactunng users of chemicals as welt. The problems raided can be dealt with more effectively by modifying tha provisions of the current rule to address them, rather than preparing completely separata standards for each industry. recommendations of the Committee. Therefore, construction employers are included with all other employers in this standard. However. OSHA will print the rule in full in 29 CFR Part 1926 (in 1 1926.59) for ease of referenct for ' Act. An expanded HCS covering nonmanufacturers will require nonmanufacturers to provide chemical hazard information not only to their employees but alto to the surrounding communities. 55 DE 008440 31860. Federal Remitter / Vol. 52. No. 163 / Monday. August 24, 10B7 / Rules and Regulations On January 27.1967. EPA proposed for construction, and in 29 CFR Parts whether the state law appears to be "at regulations to implement the community 1915.1917. and 1918. tor the use of the least as effective as" the Federal data sheet and inventory reporting maritime industry (at new || 1915.99. standard. The "at least as effective as" requirements. A detailed explanation of 1917.28. and 1918.90. respectively). test applies only to state standards the EPA proposal can be found at 52 FR 2836 (lanuary 27.1967). A final rule is (a) Purpose adopted under an approved State plan. 29 U.S.C. 667(c)(2). In enacting OSHA expected to be published in the near future. OSHA has prepared a All references to the manufacturing sector. SIC Codes 20 to 39. have been Congress rejected provisions which would have permitted stales to enforce preliminary estimate of the costa of deleted to reflect the expansion of the laws which were "not in conflict with" expansion of the EPA requirements into scope to all employers and employees. It or "at least as effective as" Federal the non-manufacturing sector. This should be noted that these changes have OSHA standards. See Senate Comm on . estimate is addressed further in the been made throughout the provisions of Labor and Public Welfare. 93d Cong.. 1st ' section of this preamble dealing witb the the rule, wherever die HCS currently Sees- Legislative History of the regulatory impact analysis for the final addresses employers and employees in Occupational Safety and Health Act of rule. the manufacturing sector rather than EPA has established a toD-free hotline employers and employees in general. 1970. at 56.706 (Comm. Print 1971). Instead. Congress enacted section is to answer questions concerning the requirements: Chemical Emergency Preparedness Program Hotlina. 1-600/ 535-0202: in Washington. DC at 1*202/ 479-2449. It. Summary and Explanation of the Issues and tha Provisions of the Final Standard This final rule it both an expansion and revision of the current HCS. The regulatory text presented herein includes the unchanged provisions of tha present rule, at well at those which OSHA it changing. This was done to ensure that readers can dearly follow where these changes would appear in the standard. As explained below, the substantive changes were found to be necessary and appropriate for a hazard communication atandard covering all workers exposed to hazardous chemicals. OSHA is also making several corrections and minor technical amendments to the standard. OSHA f;nds prior public notica and commant for there minor amendments to tha unnecessary because of their non substantive nature. S U.S.C. 553(b): 29 CFR 1911.5. The discussion which follows will address the changed provisions of tha Despite the expansion of covered employers from manufacturers to all employers, however. OSHA retains in this final rule tha distinction between chemical manufacturers and importers who produce or import hazardous chemicals, and downstream employers who merely use the chemicals. Only the former are to prepare the technical hazard information for labels and materials ssfetv data sheets accompanying hazardous chemicals, whereas all employers are to pass this information on to their workers potentially exposed to the chemicals through a comprehensive hazard communication program which includes individual training. The original Hazard Communication Standard included, at 29 CFR 1910.1200(a)(2). a generally-worded. statement concerning the Agency's position regarding the preemptive effect of the standard. This parapaph has been revised to more explicitly state the Agency's position regarding preemption based on the provisions of the Act and related legal actions. This final rule significantly expands the number of Industrial groups to which the Federal standard applies, and thus It significantly expands the area in which providing that Federally-approved State plans are the exclusive alternative to preemption. Since the promulgation of OSHA's original Hazard Communication Standard, a number of court decisions have dealt with the effect of express and implied Federal preemption upon stale and local hazard communication or *Tight-to-know" laws. United Steelworkers ofAmerica v.Auchter. 7C3 F.2d 728.733-38 (3d Cir. 1985) (Federal Hazard Communication Standard expressly preempts state hazard disclosure laws in manufacturing sector): NewJersey State Chamber of Commerce v. Hughey. 774 F.2d 587 (3d Cir. 1985) (provisions of New Jersey right-to-know law which pertain primarily to community or environmental safety and health are not expressly preempted: right-to-know laws subject to implied preemption if they make it impossible to comply with Federal law or pose an obstacle to objectives of the Federal Act): Manufacturers Association of TriCounty v. Knepper. 601 F.2d 130 (3d Cir. 1988) (similar holding in connection with Pennsylvania right-to-know law). The revised paragraph (a)(2) rule, as well as the issues related to state and local laws will be preempted. specifically provides that both state and these changes. A detailed summary and Section 16(a) of the Act. 29 U.S.C. local laws pertaining to occupational explanation of the current rule's 667(a). provides that a state may assert hazard communication-are preempted provisions is only provided when lurisdiction through any court or agency by the Federal standard. In the one court necessary for the discussion of the over "any occupational safety or health decision which has addressed the modification. For a complete issue with respect to which no standard question, the United States Court of explanation of the existing provisions, is in effect under section 6." Conversely, Appeals for the Sixth Circuit ruled that please see the preamble to the current where OSHA has issued a standard, the Federal Hazard Communication HCS (48 FR 53334-40). The current rule section 18 expressly preempts states Standard preempts local at well as state is codified at 29 CFR 1910.1200. and was from asserting jurisdiction through any laws. Ohio Manufacturers Association published at 48 FR 53340-46. The court or agency over the issue addressed v. City ofAkron. 801 F.2d 624 (1986) The modified trade secret provisions are discussed at 51 FR 3459a by that standard, unless a Federallyapproved State plan is in efTeet. 29 court noted that the text of i 1910.1200(a)(2) did not mention This discussion is organized by U.S.C. 667(a) and (b): 29 CFR 1901.2. localities and referred only to paragraph of the standard, and is The express preemption provisions of preemption of "state" laws. Id. at 827. presented in the order these paragraphs the Act apply to all state or local laws 831-832. Nevertheless, relying upon appear in the HCS. 1 which relate to an issue covered by a refereoees to local as well as stale laws For ease of reference. OSHA will be Federal standard, without regard to in the preamble to the 1983 standard, the printing the same rule in full in 29 CFR whether the state law would conflict court correctly inferred that OSHA had Part 1910 (In 11910.1200) for general with, complement, or supplement the intended to preempt all non-Federal industry. 29 CFR Part 1928 (in 11926.59) Federal standard, and without regard to occupational hazard communication 56 -DE 0Q8441 Federal Register / Vol. 52. No. 1B3 / Monday. August 24. 1987 / Rules end Regulations 31651 law*. Id. at 132. Therefor*, la accordance with tht Court decision. laboratory workers within OSHA's jurisdiction. breakage, and these employees are in fact potentially exposed by virtue of the OSHA is making technics! amendment It should also be noted that OSHA Is presence of these hazardous chemicals to paragraph (a)(2) ao that It explicitly stale* that tha HCS preempts local worker right-to-know law*. The revised I 1910.1200(a)(2) not only currently proceeding with a specific rulemaking to directly address "Occupational Exposure to Toxic Substances in Laboratories'* (SI FR in their workplaces. Because of this potential exposure, they need Information to protect themselves from the hazards of these chemicals in the defines hazard communication a* an 26860: July 24.1986). When that rule event such an emergency situation "issue*' under the terms of the Act. but also enumerate* the generic areas addressed by the standard for purpose* becomes final. Its provisions may supplement the information transmittal requirements of the HCS by directly occurs. However. OSHA has considered the extent of information necessary or of establishing the parameters of preemption. Thus any State or local government provision requiring the preparation of material safety data sheets, labeling of chemical* and identification of their hazard*, development of written hazard communication programs including lists of hazardous chemicals present In the workplace, and development and implementation of worker chemical hazard training for the primary purpose of assuring worker safety and health, would be preempted by the HCS unless it was established under the authority of an OSHA-approved State plan. reducing hazardous chemical exposures in laboratories by requiting, among other things, safe work practice*. A* noted in that proposaL the final nil* might modify the general Information and training requirements in the HCS to Incorporate other aspects of that standard. Any changes in tha application of the HCS provisions to laboratories will be addressed in detail in the final rule for laboratories and will be based on that rulemaking record (Docket H-1S0). Coverage determined by *exposure." The HCS covers situations where employees "may be exposed" to appropriate In this type of operation, and the practicality of requiring such work operations to be subject to all of the provisions of the rule. The primaryneed is to ensure that these employees know how to acquire and use the hazard Information available to them, and to handle an emergency exposure Situation. As in laboratory operations, maintaining lists of chemicals where the chemicals present may change on short notice, sometimes on a daily basis, is not a useful requirement. Similarly, obtaining material safety data sheets for every chemical in s Mated container that passes through a facility--even if it (b) Scope and Application hazardous chemicals (paragraph (b)(2)).. is there less than s day in soma Laboratories. With regard to the coverage of laboratories, specifically addressed in paragraph (b)(3). OSHA conclude* that the current rule's provisions, requiring only that labels and material safety data sheets received with incoming ehemicals be maintained and thot the general training of paragraph (h) be provided, are feasible for non-manufaeturing laboratories as well. See. eg., comments of the Massachusetts Institute of Technology. H-022D. Ex. 2-120 ("We agree that the Hazard Communication Standard's requirements for labs are adequate.. .. We expect our compliance costs to remain at the current level of spending because the majority of these are start* up cost* and some activities have been absorbed and integrated within existing programs.") OSHA believes that these somewhat limited hazard communication requirements for manufacturing laboratories are also appropriate for non-manufacturing laboratories be'eause both share the operating conditions that distinguish them from the typical industrial workplace: they commonly use small quantities of many different hazardous and such exposure is defined to include potential exposure as well as actual exposure. This Ia to ensure that employees receive information about all chemical hazards In their work areas, and that they are prepared to deal with any unexpected releases or emergency situations, as well as exposures during the normal course of employment. OSHA concluded that employee* are entitled to information regarding the chemical* to which they are exposed in their work areas. It should be noted, however, that individual facilities and workplaces may have some employees who are covered since their work involve* exposure to hazardous chemicals, and other* who are not covered because their work does not. For example. In a retail department store, maintenance workers or worker* In a graphic arts department may be covered since their jobs involve exposure to chemicals, but an accountant in tha billing department would not be likely to experience exposure that would require coverage by the HCS. There are a number of work aituations where employees only handle sealed aituations--would result in a considerable amount of paperwork, with little discemable benefit for the employee* Involved. Therefore. OSHA has added a provision, paragraph (b){4). to limit the duties of employers for those work operations where employees only handle sealed containers that are not intended to be opened under normal conditions of use. (Some States which have adopted nght-to-know laws have also recognized the practical problems of coverage in this area, and have included provisions limiting coverage of workplaces where chemicals are handled in aealed containers. See. ep. Tennessee Hazardous Chemical Right to Know Law. Tennessee Code Annotated. 50-3-2001 through 50-3-20019) In these situations, employers must not remove labels affixed to incoming containers of hazardous chemtcalx.mutt maintain and provide access to material safety data sheets that are received for hazardous chemicals while the chemicals are in the workplace, and obtain material safety data sheets when they are not received but an employee requests one: and must train employees in accordance with the provisions of the rule to ensure they are chemicals for short periods of time; the containers of chemicals, and under protected in the event of s spill or leak. conditions and purposes of the use of normal conditions of use would not open The employees in these operations the chemical* frequently change, often the containers and would not expeet to will always have access to the label unpredictably; msny substance* are of experience any measurable exposure to information, which will provide unknown toxicity: and many worker* the chemicals. Such work operations appropriate hazard warnings and be a are highly trained. Compare 48 FR Include, for example, warehousing, retail visual reminder of the potential hazards $3287-89. with 51 FR 26803-84. OSHA sales, marine cargo handling, and if exposure occurs Employees will also concludes that the same HCS provisions trucking terminal*. It is reasonable to be trained regarding the general classes tailored for manufacturing laboratories assume, however, that all sueh of chemical hazards faced and the are appropriate forth* protection of all containers are subject to leakage and means by which they esn protect 57 DE 008442 % 31882 Ftdctsl Reciter / Vol. 52. No. 163 / Monday. Auguit 24. 1987 / Rules nd Regulations themselves from Diet* hazard* when Other exemptions. The HCS include* there I* a spilt or leak. The training mutt a number of specific, total exemptions alee address the availability and uie of from the requirements of the rule for tubstanee-tpcctfic information found on certain types of chemicals. This rule label* and material tafety data sheets, adds thr>e categories of exemptions: where available. These requirements food, drugs, cosmetics, or alcoholic thould provide employees handling only beverages in a retail establishment sealed containers of chemicals with the packaged for retail aale (paragraph information they need. (b)(6)|vi): consumer products (paragraph This limited provision alto addresses (bjifijjvii)): and certain pharmaceuticals tome of the concern* rtited by (paragraph (b)(6Hviii. repreaentative* of industries with these Food, dragt. cosmetics, alcoholic type* of workplaces. (See. eg. Exs. 2-53, beverages. The current HCS include* an 2-75,2-201. and 2-214). Although they exemption for food, drugs, or cosmetics generally were arguing that this type of brought into the workplace for employee operation warrant* exclusion from the consumption. These type* of exposures rule. OSHA does not agree that no arc not related to an employee's work, protection under the HCS is required in and therefore do not need to be covered these situations. As already described, a under the HCS. potential for exposure doe* exist, and The expansion of the HCS into the therefore such employees must be non-manufacturing sector will result in appropriately covered. OSHA believe* many of these types of products being the limited coverage detcribed will present in workplace* (e.g.. liquor effectively protect employee* while stores) where they are not intended for recognizing the constraint* of the employee consumption, and where they particular work operations involved normally would not result in employee with regard to the applicability of the exposure because they are packaged for current rule to these types of work. sate to consumers. Although some of Labeling exemption. The HCS these products may meet the definition includes a number of labeling of a "hazardous chemical" (e g., vinegar exemptions to ensure that OSHA does is acetic acid), when packaged for retail not provide duplicative coverage for sale they do not pose a hazard to products which are already labeled workers that is any different than the under the rules of another Federal hazards of such products in their home*. ageney. It should be reemphasized that The label information required by other these exemptions fin paragraph (b)(4) of Federal agencies for food*, drugs, the original rule: paragraph (b)(5) in this cosmetic*, and alcoholic beverages final rule) are only from the container should thus provide sufficient protection labeling requirements under paragraph for workers, and OSHA has exempted (0--all other provisions of the rule are these products from coverage under the still in effect. A minor correction is rule. It should be noted that this is not being made, however, to these an exemption for facilities of any exemptions to indicate that when particular industry, as all facilities may medical or veterinary devices are have other chemicals in use that would labeled in accordance with the labeling be covered by the HCS. In addition, requirements of the Food and Drug since these products are exempted, Administration (FDA) under authority of employers which package them for retail the Federal Food, Drug, and Cosmetic aale would not have to furnish material Act (21 U.S.C. 301 et teg.), those Items safety data sheet* to distributor* are exempted from HCS labeling receiving the products. requirements. AH other Items regulated Consumerproduct*. The current rule by FDA under that Aet were listed in the provide* a labeling exemption for HCS labeling exemption. Medical and consumer products when they are veterinary device* were inadvertently labeled in accordance with the omitted from the list of items that might requirements of the Consumer Product be subject to FDA labeling requirements under the Federal Food. Drug, and Cosmetic Aet. and they are exempted from HCS labels for the same reasons that the other items are exempt when subject to labeling under FDA. See 46 FR 53289. To ensure that all these FDA ' regulated items are treated in the same manner and that devises arc exempted from HCS labeling If subject to FDA Isbeling. paragraph IbHSHii) is amended by adding medical and veterinary devices. Safety Commission (CPSC). CPSC requites consumer products which contain hazardous substances lobe appropriately labeled. Examples of consumer product* would include such items as oven cleaner csint stripper, and adhesive, which may be found in various types of workplaces. In addition to the specific labeling exemption. OSHA has been interpreting the rule as not being applicable to consumer product* when used as a consumer would use them. OSHA is now adding this interpretation to the rule itself, paragraph (b](6)(vi). stating that where such consumer products are used m the workplace in a a manner comparable to normal conditions of consumer use. resulting in a duration and frequency of exposure to employees which is no greater than exposures experienced by ordinary consumers, under such condition* the chemical would not have to be included in the employer's hszard communication program. This position is consistent with OSHA'* reason for orginally limiting the exemption for hazardous consumer products used in the course of employment to only an exemption from HCS labeling, and not material safety data sheet and training requirments. "OSHA recognize*. . . that there may be situations where worker exposure is significantly greater than that of consumers, and that under these circumstances, substances which are safe for contemplated consumer use may pose unique hszard* In the workplace." 48 FR 53289. However, to th* extent that workers are exposed to the substances in a manner similar to that of the general public, there is no need (or any HCS requirement*. One example of such a differentiation in exposure situation* involves the use of abrasive cleaners in the workplace. Where these are used intermittently to clean a sink, much as they would be used at home, the cleaners would not be covered under the standard. But if they are used to clean out reactor vessels, thus resulting in a much greater level of exposure, they would be covered. Or if an employee cleans sinks all day long, thus resulting in more frequent exposures, the abrasive would also be included in the hazard communication pror*m. Thu* workplaces which only have chemicals which are consumer product* used in the same way and as frequently as the general public would normally use them, would not have to have a hazard communication program. It should be noted that OSHA intends to read this exemption narrowly. Where an employer is uncertain whether the duration and frequency of exposure to these products is comparable to consumer use. an employer should obtain or develop the material safety data sheet and make it available to employees. In response to questions raised in the 1985 ANPR. OSHA received s few comments on the use of consumer products in the non-manufacturing sector. A number indicated that overexposure may occur from the use of such product*, or that the frequency and duration of workplace exposure is typically greater than that experienced 58 DE 008443 Federal Register / Vol. 52. No. 163 / Monday. August 24. 1987 / Rule* and Regulation* 31663 by consumer* (Ex*. 2-59.2-63,2-100.2- 120. and 2-164). Other* stated that tha exposure wai eompersb)* to consumer use (Ex*. 2-46 and 2-63). There were several that felt the label provided enough information, and no additional requirement* were needed to protect employee* (Ex*. 2-75.2-79.2-99.2-107. end 2-116J. while other* felt the employer thouid be required to requeat materiel tafety data (heat* becauta employee* are not getting enough information (Ex*. 2-103.2-126. and 2163). On* auggetted that th* label not* that a material tafety d*t* aheet ia available on teouctt (Ex. 2-100). while another contended that when a product i* uted by a professional. it i* no longer a contumer product (Ex. 2-109). OSHA believe* that the contumer product exemption in thi* final rule take* all of theie concern* into consideration. and ttrike* a balance between the practical contideration* of acquiring and maintaining material tafety data cheat* on CPSC regulated product* which employee* are expoied to at horn* a* well a* at work, and the worket'a need for more hazard information than a CPSC label when expoiuret art greater or more frequent than typical public ut* of the chemical would generate. A number of State* adopting right-towork law* have alto developed contumer product exemption*. (See. e./Wiscontin "Employee*' Right to Know Law": Ulinoit 'Toxic Subtianeea Ditcloture to Employee* Act") However, moat of these rule* have taken a broader approach to the contumer product exemption, generally eliminating coverage of auch product* unices exposure it "significantly greater" than consumer expoturt during the "principal consumer use." OSHA considered and rejected such language (ot the contumer product exemption. It would be very difficult from an enforcement perspective to determine when expoturt to a consumer product it 'significantly greater" than consumer expoturt. The key eltment* of concern tn OSHA are at stated in the consumer product exemption Included hi this rule--that the contumer product be uted in the tame manner at a consumer would use it (end therefor* at intended by the manufacturer when preparing the label information), and that the duration and frequency of exposure be essentially the tame a* would be experienced by a consumer (and thus the label wtming* would provide adequate protection.) A broader exemption than this would not be appropriate to protect worker* from occupational exposure* that w-er* not annetpaltd by tha manufacturer whan the label*, and Ihu* the protective measure*, were developed. Application to Office Products. A number of question* have been raised about the application of the rule to office product* that may contain hazardous chemical*. It I* OSHA'* determination that office product* such a* pencil*, pen*, typewriter ribbon*, and th* like, are "article*" under tha nil* end therefore exempted, paragraph (b)[6)(iv). Employer* are not therefore required to implement a program for auch product*. OSHA hat alto determined that intermittent occasional use of a copying machine to make copies it not covered by the nil*. The copying machine would alto be considered an article for purposes of this standard. However, if a firm hat a copying machine operator who i* responsible for handling tha chemical* associated with it* ut*. or who operate* the machine frequently, that individual would be entitled to information under the rule. Medicine. The rule, paragraph (b)(6)(vii). alto include* an exemption for drug* when they art solid, and are in final form for direct administration to the patient (/.e.. pill* or tablets). Employee* handling such finished drug product* would not be expoied to the chemical* involved, and would not need information other than that supplied on the container label under FDA requirement*. (The State of North Carolina adopted a similar exemption in their Hazard-Commonication Standard. 1) NCAC s7C.101(a)(99)). Wood dust. At OSHA hat received a number of questions regarding the application of the wood and wood product* exemption to wood dust. OSHA would like to reiterate it* Interpretation regarding the wood and wood product exemption in paragraph (b)[6)(iii) of this final rule. The wood and wood products exemption we* included in the HCS for two reason*. First, the pretence and identity of wood and wood product* in the workplace i* "unmistakable" and second their hazard* (/.e.. flammability or combustibility) are well-known to worker*. 46 FR 53268. Because wood and wood product*, characteristic hazards art self-evident, regulation* requiring formal notification were not thought to be necessary. Wood and wood product* "are not expected to be hazardous for purpose* of this standard." Id. at 53333. OSHA never Intended, however, that wood dust be excluded from the standard's coverage under the wood and wood product* exemption. Wood dutt i* not generally a wood "product." but is ersated a* a byproduct during manufacturing operations Involving sawing, sanding, and shaping of wood. Wood dust does not share solid wood products' "selfevident" hazard characteristics that supported the exemption of wood product* from the HCS' coverage. Except for the chemical additives present in the wood, products such as lumber, plywood, and paper are easily recognizable in the workplace and pose e risk of fire that it obvious and wellknown to the employees working with them. The potential for exposure to wood dust within the workplace, eapecielly with regard to respirable article*, is not self-evident, nor ere it* ezerd* through inheletion so wellknown that hazard communication program* are unnecessary. "Wood dust" Is * recognized health hazard, with exposure limit* recommended by the American Conference of Governmental Industrial Hygienist* (ACGIH) to control employee expoiuret to the subttence. Under the provision* of the HCS. this meins thst wood dutt is to be considered a hazardous chemical (paragraph (d)(3)(H)). and therefore subject to the requirements of the rule including ' material eafety date sheets end training. (c) Definitions The only changes to the definitions in the current HCS are those that need to be made to accomplish the expansion of the HCS. The reference to SIC Codes 20 through 39 is being deleted from the definition of "chemical manufacturer" to be consistent with the extent scope of the rule. Any employer who produces hazardous chemical for "use or distribution" is considered * "chemical manufacturer" under the HCS. end must prepare and preside the tppropriaie hazard information. OSHA has modified the definition of "container" to exempt "engines, fuel tenks. or other operating systems In a vehicle." The Agency he* received some questions regarding the need for labeling such parts of * vehicle in applying the rule to the manufacturing sector. Expansion into non-manufacturing will greatly increase the number of vehicles involved In work operations, and thus OSHA determined that this clarification will ensure that the Agency's position ' regarding this Issue is dear--vehicles do not have to bear labels regarding hazardous chemicals used to operate them. This does not exempt such chemicals from coverage by the rule--it simply eliminates the need to Itbel ones they are placed into the vehicle. The definition of "distributor" has also been changed to reflect the 59 DE 008444 31854 Federal Register / Vol. 52. No. 1M / Monday. August 24. 1987 / Rules and RegjUtions extended icope of the rule. A that all employers are covered by the 'distributor" meeni" butlnets. other standard. In addition, the definition of than e chemical minufaeturer or "employer" is amended to indicate that importer. which supplies hazardous the term includes contractors and chemicals to other distributors or to subcontractors. This reflects the employers." Among other things, definition of employer used in OSH.Vs distributors must transmit hazard construction standards. Similarly, the information they receive from chemical definition of "workplace" has been manufacturers and importers to all their modified to specifically include job sites employer customer*. and projects. Under the current rule. OSHA defined Hazard warning. While OSHA is not employee" as someone working in the modifying the definition of "hazard manufacturing sector, and stated that warning" contained in the current rule, those employees in manufacturing the Agency wishes to reiterate the intent whose jobs did not involve routine to help employers better understand and potential exposure to hazardous comply with the requirements. "Hazard chemicals would not generally be wanting" means "any words, pictures, covered by the rule. Examples related to symbols, or combination thereof which the manufacturing sector were provided. convey the hazard(s) of the chemicalls) This was intended to limit the coverage in the containers)." "Appropriate primarily to those employee* in the hazard warnings" are to be put on industry who were actually involved in container labels. (See final rule production operations. However, since paragraphs (f)fl)(ii) and (f)(S)fii)|. Sinee the scope of the entire standard is being the rule covers "physical" and "health" expanded to cover employees in all hazardt. specific information regarding types of work operations, the definition these would be required on a label to has been modified to clarify that comply. workers who are exposed to hazardous Many labels at the time the HCS was chemicals as part of their assigned jobs promulgated includes only would generally be covered under the precautionary statements, rather than rule, except for those who only providing necessary information about encounter hazardous chemicals in non- the specific htzerds of the chemicals. routine. isolated instances. OSHA Thus employees encountered statements believes most office workers, and many such as "avoid inhalation" on virtually other workers, are not exposed to the every chemical container, but were not hazardous chemicals covered by the provided with statements regarding HCS in such a way that the rule would what type or severity of effect inhalation apply to those types of work operations. could be expected to produce. Ihe rule, therefore, simply defines a Therefore. OSHA's standard requires covered "employee" as any "worker identity and hazard information on who is exposed to hazardous chemicals labels. Although employers can choose under normal operating conditions or in to provide additional statements. forseeable emergencies" and further OSHA's requirements are limited to thar states that "workers such as office required to convey the hazards to the workers or bank tellers who encounter hazardous chemicals only in non workers. Under the OSHA scheme, other data regarding protective routine. isolated instances are not covered." "Norma! operating conditions" an those which employees measures, first aid. etc., are to be included on the material safety data sheet or in training, rather than encounter in performing their job duties appearing on the label itself. This in their assigned work areas. For approach is in keeping with the example, if the receptionist in a facility Agency's evaluation of available data receives and delivers a telephone on effectiveness of labels which message for someone in a different work area where hazardous chemicals are present, this does not mean that the indicates thit the more detail there is on a label, the less likely it is that employees will read and aet on the receptionist would be covered under the rule by virtue of the one potential exposure from delivering the message. However, if performance of the receptionist's job entails walking through the production area every day. and thus being potentially exposed during the performance bf regular duties, that job would be covered under the rule. The definitions of "employer" and "importer" are also amended to indicate information. The purpose of die label is to serve as an immediate visual warning of the chemical hazards in the workplace. (See generally. 48 FR 5330003). There have been misinterpretations of the requirements made based on statements in the preamble to the current rule concerning various labeling systems (see 48 FR 53301). This preamble discussion involves formal yf labels, and it not an unqualified endorsement of any particular labeling system. It simply states that any lorm-i may be used, at long as the label includes the information regarding the chemical hazards required by the standard. It should be noted that it can be expected that tome labels prepared in accordance with any of the available labeling systems can be expected to be found to be deficient. Again, the preamble discussion cited merely reemphasized that employers are not constrained to use any particular format or wording, but art constrained by the necessity to comply with the requirements of die rule concerning the information to be provided--the identity, the hazards, and for containers leaving the workplace, the name and address of the responsible party. The terms `'physical" and "health" hazards are already defined in the rule, and these are the specific hazards that are to be "conveyed" in an "appropriate" hazard warning. There are some situations where the specific target organ effect is not known. Where this is the case, a more general warning statement would be permitted. For example, if the only information available it an ICw test result, "harmful If Inhaled" may be the only type of statement supported by the data and thus may be appropriate. It will not necessarily be "appropriate" to warn on the label about every hazard listed in the MSDS The data sheet is to address essentially everything thit is known (bout the chemical. The selection of hazards to be highlighted on the label will involve tome assessment of the weight of the evidence regarding each hazard reported on the data sheet. This does not mean, however, that only acute hazards are to be covered on the label, or that well-substantiated hazards can be omitted from the label because they appear on the data sheet.. It may be "appropriate" to provide less detailed information on the chemical hazards in sn In-plsnt labeling system, where MSDSs and training are readily available, than on a label plsced on a container leaving the workplace, where it may provide the only hazard information in certain situations and where there it no guarantee that the downstream employees htndlmp or using the chemical will fully understand the less detailed label. This difference m appropriatenest allows employers io establish standardized in-plant labeling systems, as long at training regarding the use of these systems it conducted, and MSDSs provide the required, detailed information. 60 DE 008445 Federal Register f Vol. 52. No. 163 / Monday. A.gut 28. 1987 / Rule* and Regulations 31865 Article. OSHA to not modifylm sheet prepared for a lead pipe would bt eg.. Alabama Act 6S-6S8; Tennessee definition of "artiele" but would! :o available to a worker repairing the pip* "Hazardous Chemical Right to Know provide lomt clarification regard:--, th* some years following installation. The Law.") Agency'* interpretation. Releases of employer would provide the employees Under these provisions (paragraph very email quantitiei of chemical* are with general Information concerning th* (e)(2)). the employers must exchange not contidered to be covered by the rule. hazards of the operation* they were material safety data sheets, as well as So if a few moleculet or a trace amount performing in lieu of specific information information about precautionary are released, the item to still an article on the pip* Itself. measures necessary to protect and therefore exempted, in an earlier discussion fat this preamble, application of the rule to office products was discussed and it was stated that items such as pens or pencils an to be considered articles- Other example* would be; emissions bom tin* when in use; emissions from toner on piece* of paper, or emissions from newly varnished furniture. Furthermore. It should be niterated that the HCS to limited to hazardous chemicals "known to be present" (paragraph (b)(2)). and does not require any chemical analysis or testing to (d) Hazard Determination OSHA is not modifying the current rule's hazard determination requirements. The burden of evaluating chamicals to determine whether they are hazardous remains on th* chemical manufacturers and importers who produce or import them and on those user employers who choose not to rely on the evaluations mad* by their suppliers and instead evaluate th* chemicals themselves. A detailed explanation of these provisions can be found at 48 FR 332K-89.83335-38. employees end an indication of the type of labeting system in use. where exposures may occur to another employer's employees. Each employer will then have th* information necessary to inform and train their employees. This will help ensure that all employees have sufficient information to protect themselves in the workplace, regard!*** of which amployer uses the hazardous chemical. Consistent with the performanceorientation of the nil*, the provision* do not specify how this coordination is to be accomplished. This is best left to the determine or verify such prtsence. See fej Written Hazard Communication discretion of the parties involved. In 48 FR 93334-33. Thus although one may Program many cases, it would probably be most assume that molecule* an being emitted from an item, under the standard on* does not "know" that a particular hazardous chemical is "present** The article exemption applies solely to the ultimate end use--intermediat* users which result In exposure are covered and require hazard information to be provided. Th* following an examples of items which would nquin information for intermediate use prior to being finally installed: encapsulated asbestos insulation where the normal installation Involves hammering th* material into opening*, thus releasing the asbestos; tiles to be placed on a ship's hull which contain lead that is released during installation; and glass mercury switches to be Installed in equipment, a percentage of which are expected to break during this installation process. In these cases, installation is the "normal condition of use" for the employees Installing the items, and thus hazard information 1* required for these intermediat* use*. Once installed, these items would be articles and thus exempted. Under the current rule, a written hazard communication program must be developed and implemented for each workplace. Since the current rule cover* fixed manufacturing sites. It did not sppear to be necessary to specifically state that the written program be available at the site. With expansion to non-manufacturing, however, particularly In th* construction industry where a firm may have multiple sites, the standard must be tailored to specifically state that the intent is to maintain the written program at each site. Employee* will then be able to access the information as required. The current written hazard communication program requirements include a provision that requires manufacturing employer* to provide hazard Information to on-site contractor employers who have employees who may be exposed to the hazards generated by the manufacturer (current paragraph (e)(l)(iii)). The current standard does not address the reverse situation, i.e.. where a contractor employer brings hazardous materials efficient tor the genera! contractor to coordinate the function. For example, the general eonlracor could keep and make available material safety data sheets in the office on the sit*. It should be emphasized that the exchange of information is limited to those situations where exposures of other employers' employees may occur. Given the nature of multi-employer work site* in construction, there would be many situations where subcontractors responsible for various phases of the building protect would not have employees present during other phases and thus no such exchange would be required. For example, if the electricians are not working near, or at the same time as. the paving contractor, then no interchange is required. But if a painting contractor's workers are using flammable solvents In an area where another subcontractor Is welding pipes, this information exchange is vital to ensure proper protection of employees. If) Label* end Other Farm* of Warning A tailoring provision has been added Although installation of an item may on-site, and exposes the manufacturer's concerning shipments which consist of render the exemption temporarily void (until the Item is installed. Information employees to them. Since the expanded solid metal. OSHA considers this rule will affect more worksites with change to be necessary since the must still be provided If there Is a work arrangements of this type (eg., problem addressed will occur more potential for exposure). OSHA doe* not construction), and the need for an believe that the possibility that exposure exchange of hazard information Is frequently in shipments to the nonmanufaeturing sector than has been could occur when the Item to repaired or obvious. OSHA has revised the the ease in the manufacturing sector. worked on need be considered in th* determination of when information must be transmitted downstream. Employer* requirements to tailor it to address the multi-employer workplace. (This was suggested in comments submitted In (Paragraph (f)(2)). Solid metal is often considered to be an "article" under the rule, and thus exempt. Where the metal of employees performing repairs must response to the ANPR. See Ex. 2-233. is not an "article" since its downstream provide the best information they have concerning the potential exposures. There would be no way to ensure, for example, that a materia) safety data comment* from the National Constructors Association. In addition, this situation has also been addressed in existing State right-to-know laws. See. use results in hazardous chemical exposure to employee* working with it. a provision has been added which allows shippers of this type of material 61 DE 008446 3H6# - -Federal Register / Vol. 52. No. 163 / Monday. Auyt 24. 19B7 / Rule* and Regulations to end the libel information once, or from wholesale distributors as is to be kept at a central location in thi* similar to material aafaty data sheet mora commonly done In the type of situation, as along as the trantmlttal. a* Ion* ai the materia! i* the .manufacturing sector. Under the current employer ensures thst the employees same and it 1$ bein| (hipped to the asm* HCS. distributor* of hazardoua can immedisteiy obtain the information customer. In these situations, there chemicals must automatically provide in an emergency, paragraph (g)(9). should be no hatard to anyone handling commercial customers material safety OSHA believes that this provision the metal from the time It is produeed In data sheets (paragraph (gH7)). Retail tailors tha HCS so that It remains solid form, anti! the time someone works distributors.nowtvar. often a*U to practical yet effective, in getting on it in a way that releases a chemical businesses and the genaral.publie and workers the hazard information they hazard. Since the label Information frequently have no way of knowing who need. This was also supported by a tiansmitted would only reflect tha a particular purchaser la. Under the number of ANPR commenters (see. e g.. , ciiemical hazards released when It is current rule, retail distributor* might Ex*. 3-13.3-107.3-114.3-118. and 2- later worked on, the label would sot have to give material safety data sheets 117). provide any hazard information that Is to each cuitomer to ensure that ' Tha current rale, as well as the needed by thosa handling the materia! in transit. It must be emphasized that commercial customers get tha expanded standard, allows downstream information they need under the HCS. A employer* to rely on upstream chemical this exception is only for the solid mete! Itself--any hazardous chemicals present in con{unction with the metal is such a form that employees may be exposed when handling the material (ex. cutting fluids, lubricants, and greases), require labels with each shipment This tailoring provision, therefore, does not diminish worker protection--worker* get the hazard information they need. specific statement regarding mail distributor* i*. thatefor*. included in paragraph (g)(7) to addrtas this practical problem. Those ratal) distributor* who sail hazardous chemicals to employers must provide a malarial safety data sheet upon request, and must post a sign or otherwise inform the employer* that an MSDS I* available. According to Schneider Hardware of Bankavilla. Inc. manufacturers and importer* to provide MSDSs. However, there is a duty for downstream users to request an MSDS when they don't receive one at the time of the first shipment. There have been tome question* regarding how the downstream user will know a data sheet ii required without doing a hazard evaluation. Such an evaluation it not necessary. If the label indicates a (g) Materia!Safety Data Sheet* this la a reasonable approach (Ex. 3- hazard, the employer will know he Under the hazard determination provisions, a requirement is included which indicates that tharc are situations where the percentige cut-off for mixtures would oot apply--when the released chemical is particularly hazardous, or when it could exceed an 179): IIOSHA does require commercial customers to get inlormatltm through a retail outlet I do net foresee any problem! with that strantemcntThe menulsctomo eoutd tupply us with the toiformattan. ae they ere required to now for eUpment* to minutsctorfng plant*, and we eould make it needs dst* sheet and mutt request one if it is not received- If there are no hazard* on the label, the downstream user can assume the product it not hizardous and a data aheat it not required. (hj Employee Information and Training established permissihle exposure limit or Threshold Limit Value when released (paragraph (d)(5)(iv)|. Although this is dearly arequirement of the rule, tee also 48 FR 53MB. the meterial safety data sheet provisions for disclosure of hazardous ingredient Identities did not address that particular situation. Cisarly it was OSHA's intent to have aU hazardous Ingredients of mixtures listed available to cuitomer* upon tequeet W* would sotrely keep the ahaeta in a Hie drawer and post a tign informing customer* of their availability. We hive leu than 100 chemicals thst would probsbiy be affected, end keeping information on those would require at most, one file drewer. It would net be burdensome. The reteil distributors likely affected art those selling building supplies, hardware, etc. Retail distributor* will OSHA is not making any modifications to the current rule's information and training provisions. These requirement* remain performance-oriented and designed so that each employer will adequately address the hazard* posed by chemicals in the workplace. An explanation of these provisions can be found at 48 FR on a material safety data shaft, avan have to assets their product tinea, and 53310-12.53337-38. those In very small concentrations, whaibtr or not they nave commercial One question that does arise when the hazard determination account*, to determine whether they regarding training is whether it needs to provisions of paragraph (d) mandats must comply with this provision. It is be done specifically on each chemical, (hit they are to be eontidtrad clear that most other type* of retail or whether employers can train hazardous for purposes of tha HCS. As establishments (eg., grocery stores, regarding categories of hazards. Either noted in the HCS preamble discussion of clothing stores, etc.) would not. method would be acceptable. See 48 FR the materiel safety data aheat With regard to the maintenance of 53313.53338. If employees ere exposed provisions: "Employers must also list material safety data sheets so that they to a small number of chemicals, the ingredients present in concentrations of ar* readily available to employees, employer may with to discuss the less than one percent If there ii evidence whereas manufacturing facilities ar* particular hazards of each one. Where that the permissible exposure limit may generally fixed work silt* with fixed there are large number* of chemicals, be exceeded or If it could present locations for these maffrials, in soma the trtining regarding hazards could be health hazard in those concentrations." type* of norunsnufacturing work done on categories (e.g.. flammsbie Id. at 53337. Thi* obvious oversight has operations, employee* must travel liquids: carcinogens), with employees been corrected by a minor amendment between work areas during a workshifL being referred to substance-specific to the rule. Paragraph (|l(2](iHC)(5). For example, employees involved in Information on the labels and MSDSs. Another situsuon which raises servicing oil and gaa wells may have a Similarly, the re-training occurs when practicality concerns because of tha central office location, but then travel by the hazard changes, not just when s new expansion of the scope ofThe rule truck to the well* to perform their work. chemical is introduced into the involves employers who purchase These remote locations may not have workplace. If the new chemical has hazardous chemicals from local retail any staff, or may not have an office hazards which employees have been distributors, rather than directly from facility. OSHA has added a provision to trained about, no re-training occurs. If the ehemieal manufacturer or Importer, the MSDS requirements to allow MSDSs the chemical has a bszard they have not 62 DE 008447 Federal Register / Vol 52. No. 163 / Monday. August 24. 1987 / Rules and Regulation* 31857 been trained about, re-trainint would be limited to that haurd. HI Trade Seatit Paragraph HH) of current rule itatee that "JiJf. following the iaauance of a citation and any protective ordcra. the chemical manufacturer, importer, or employer continue* to withhold the information. the matter It rtferrable lo the Occupational Safety and Health Review Commission for enforcement of the citation. ..." Thii proviaion wai worded in tueh a manner that it left the imprettion that OSHA could refer the matter to the Review Commission. Tbit li incorrect at e matter of law. An enforcement proceeding 1* referred to the Review Committion when a citation it ittued by OSHA. and it subsequently contacted by the employer receiving the citation. Therefore, OSHA hat made a technical amendment to paragraph (i) fil) to reflect the applicable procedural law. (j) Effective Dote* The expantion of the rule to cover all employer* become* effective nine montht from the date of promulgation of the final standard. Sine* the chemical hazard information for label* and materia) ttfety data theett hat already been generated in the manufacturing teetor. and in many caatt bat alto been diitributed in non-manufacturing due to State law requirement* and voluntary trammlttal by suppliers. on* month ahould be tuffieient time for chemical manufacturer*, Importer*, and dittributon to initiate provition of material tafety data thteta to other diatributor* and to cuitomer* in the nonmanufacturing lector. An additional eight montht it being provided tor non* manufacturer* to complete preparation of a written haurd communication program for each facility and to conduct employee training. It ahould be noted that thi* eight month period for compliance only applie* to thoae employet* which are newly covered under the expanded provition*-* employer* in SIC Code*'20 through H ere covered under the current HCS end ire already requited to be in compliant* with the provition* of that rule. Tboat tailoring proviiiont that apply to manufacturing workplace!, tuch at the coniumer product exemption, go into effect Immediately for Ihote faclliliet. Appendice* A end8 OSHA It not amending Appendix A'e diteutfion of the heelt) neurdi poted by chemical*, or Appendix B't diicuteIon of hazard determination. They remain applicable to alt chemical manufacturers, importers, and employer! performing haurd determinations. Appendix C The reference tourcet lilted in thi* non-mandatory appendix have been updated to reflect currently available source*. Appendix D The recent rulemaking on trad* tecrett added a new Appendix D regarding the evaluation of th* validity of trade secret claim*. SI FR 34500. Th* full text of this appendix hat been reprinted in this document at well. Ut Analyses of Regulatory Impact. Regulatory Flexibility, and Environmental Impact The following It a summary of the regulatory impact and regulatory flexibility anilytii prepared by OSHA for the revision of the Heurd Communication Standard which extend* the scope of the existing ttandard to tha nonmanufacturing ttetor. The full text of th* document may be examined and copied in OSHA't Docket Office. 200 Constitution Avenue. NW,, Room N3670, Washington. DC 20210; telephont (202) $23-7894. Economic Anolytii At part of OSHA't effort! to gather information concerning the economic feasibility of extending the coverage of th* HCS to inetude workplaces in the nonmtnufacturing sector, the )ACA Corporation performed a study examining the benefits, costs, and overall economic impact of such a revision. This report was used is th* basis for the regulatory impact analytic prepared by OSHA. The analytis reflect* the extent to which employer* in tha nonmanufacturing sector ate currently subject to state right-to-know laws and art voluntarily implementing their own hazard communication programs. Tht analytis also takes into account OSHA't existing policy regarding flit uta of consumer product* and training requirements already imposed on employer* by other OSHA standards. With respect to consumer products covered by the HCS. OSHA Instruction CPL 2-2.38A ("Inspection Procedures for the Haurd Communication Standard. 29 CFR 1910.1200") states; A common tense approach muit bt employed whenever e product la ueed in e manner almilar to which It could be uied by s coniumer. thue mulling In levele of expoeure comparable to coniumer expoeure. The frequency end duralion of uie ahould be considered. For example. It may not be necesssiy to have a dale ehett tor a can of cteanier ueed to clean tht (ink in an employee rtetroom. However. If evch citanaer ia seed in large quantities lo clean proceee equipment. H ahould be addressed in the Haurd Communicalion Program. This policy hat bten incorporated into the revieione to the HCS. and was taken into account when evaluating dati describing the number of heurdoui chemical* in the viriouz two-digit SIC groups that could be affected by exteneian of the HCS to the nonmanufacturing ttetor. Attesting the net impact of the training proviiiont required identifying and deducting the costs of existing OSHA standards which already require employer* to provide the types of information and training activities prescribed in the HCS. This was done for construction (11926211). thipbresking (11915.97). marine terminals (1191722). and longshoring (11916.80). However, it was not possible to eeparately identify and deduct the existing turning costs for subtttncespeciflc standard* that currently apply to the nonmanufecturingtector. Thus, the compliance costs presented In thi* analyii* are lomewhat overstated. In extending the rule for manufacturing to the nonmanufacturing aector. OSHA hai made revision* io reflect unique aspect* of some-work operations. For exsmple. the etendard allows MSDSs to be mtintiined at central locations in circumstances where employees must travel between wotk operations during a workshift. provided that the information can be obtained immediately in in emergency. This provision i* expected to lower costs in SIC groups 07.08.09.13. 48.49. and 73. (See Tablt 1 for a description of tht SICs.) The standard also allows for limited coverage in those work situetiont where employees handle chemicals in sealed containers ihst are not opened under normal conditions of use. and thus have little potential for measurablt exposuus. Employers would be required to letve warning labels on contsiners. and make avalleble any MSDSs received with the containers. Employers would alto hive to be trained in accordance with the standard, with particular tmphttii on procedures to follow if there is a spill or leak of the hazsrdous chemicals in the normally tested containers. Afiected establishments would not have to mske special efforts to obtain and keep MSDSs that art not received with the chemicals, and no written plan ior complying with th* HCS would be required. This prevision It expected to 63 DE 008448 518S8 Fdett Register / Vol. 52. No. 163 / Monday, August 24. 1987 / Rules and Regulations result In lower east* In SIC groups 42. 44.45.47. SI. end Si Thus the changes made to establish more appropriate provisions for unique work situations should result in lower costs than would be experienced if the HCS for manufacturing were extended Major Croup XX Security and commodity brokers, dealers, exchanges, and servlets Major Croup 6X Insurance Mtjor Croup M. Insurance ogtnta. broken, end service Mtjor Creep *S. Real eatata Major Croup M. Combinations of real state, insurenet. toast, law office eases are assumed to be occupationally related: the 20 percent reduction ii applied to this 5 percent of all cases among occupationally exposed worker* in the Donmuiufaeturing sector.) However, the full reduction of chronic illnesses and cancers will not occur to the nonmenufscturtng sector without Major Croup S7. Holding and other Immediately: rather, the reduction for revision. brvttnnem offices these cases Is phased in over time. For Table 1 --SIC Groups Covered ie the OSHA Analysis Division A. Agriculture. Forestry, and Fishing Major Croup 01. crops Msjor Croup 02. livestock Msjor Croup 07. Msjor Croup (Ml Msjor Croup Oh trapping Agricultural production-- Agricultural production-- Apicaltural strvicea Forestry Fishisf. kuating. and Division B- Mining Major Croup IX OO and gas eitractjou Division C. Constmchse Division L Services Mejor Croup 70. Hotels, rooming houses, camps, tad other lodging places Major Croup 72. Personal amnees Major Croup 72. Baaineaa aerviett Major Croup 7X Automotive repair. services, and garages Major Croup 7X Mueetlafieoiie repair services Mtjor Croup 7X Motion pictures Mejor Croup 7X Amusement and recreation ervieta. except motion ptetune Mejor Croup ax Health Senrieee Major Croup *2. Legal Servtcae Major Group XX Education Services Major Croup (3. Social Strvicea Major Croup H Museums, art galleries, chronic illnesses, the standard is expected to reduce 1 percent of the cases in the first year. 2 percent in the aecond year, and ao on. until it reaches the full reduction of 20 percent. For cancer cate* end cancer deaths, the standard is expected not to have en effect for the tint 10 yeer*. then It Is expected to reduce 2 percent of the cates in the eleventh yeer. 4 percent in the twelfth yeer. end to on until it reaches the full reduction ot 20 percent. Benefit! were monetized using two independent approaches. The first took into account medical eottg and lost Msjor Croup IS. Building construction-- Itnsral contractora and operative builders Major Croup IX Construction ether then building construction--gentrel contractors Major Croup 17. Construction special trad* contractora Division E. Transportation. Communication. Electric. Css. tnd Sanitary Ssrvicvs Msjor Croup SO. Railroad transportation Major Croup 41. Local aad suburban transmit and Intaturban highway pessangtr transportation Major Croup 4X Motor fraight tranrpsntUon and warehousing Major Croup 44. Water transportation Msior Croup 4E Transportation by air Maior Croup 4& Pips lints, except neturel *' Msior Croup 47. Transportation serv ices Msjor Croup 4X Communication Major Croup 4X Electric. gat. and sanitary services Division F. Wholesale Trade Ms jor Croup SO. Wholesale trade--durable goods Msior Croup $1. IVhotesate trad*-- nondurable goods Division C. Retail Trade Maier Croup $X Building materials, hardwsta. gtrdtn supply, and eiobila bom* detlsra Msior Croup SX * Csosrsl aitfchaadisa torsi bottnlcsl end xoologicsl cardan* Mejor Croup M. Membership organiuthms Major Croup IX Mitcellanaoa* services The analysis of the benefits, costa, end economic impact* of extending the HCS to the nonetenufaeturing sector ere projected for 40 year*. At indicated, the analysis reflects requirement* of state right-to-know lew* and voluntarily implemented hazard communication programs. Ritk Evelualian/BtntfiaAna/yttt For this analysis CfSHA eatimsted the percentage of worker* exposed to hazardous chemicals. The percentage and number* of exposed worker* art ihown in Table 2 * by SIC group. The analysis of risks end benefit* proceeds from the current annuel incidence of chemical-related injuries and iUneaaet in the norunanufaeturing teeter. For workers in thia lector, meatum of acute chemical aource injuries end nineties ineloded nonlost workday (NLWDJ Injuries (13.671) and LWD Illnesses (3X240): end fetellUee (102). Meetores (or ehrente illnemt Indudr. chronic Ulnett cate* (17.153). etneer cam (25.388), and cancer deaths (1X600). The cancer cases category tamings incurred by each victim. This "human capital" approach resulted in first-year benefits of S56.3 million, and a 40 year present value of Sft.66 billion (summarized in Table 3). A second estimate of benefits was made using the "wiliingness-to-psy" approach. This approach resulted in first-year benefits of SS6&7 million, and a 40 year present value of *54.8 billion (Table 3). To provide comparability with the estimates of compliance costs, benefits were attributed to the states with rijhlto-know laws in proportion to the there of hazard eommunicition costs projected for firms in those steles. Under the "human capital" approach the present value of the 40 year stream of benefits from the extension of the HCS. after deducting stales with right-toknow-lawt, it S3JO billion (1985 dollars). Under the willingoess-to-pay approach, the present value of the 40year stream of benefits from extension of ths HCS is S31.0 billion, after deducting the amount attributable to elate* with right-to-know law*. The monetized benefit* of hazard communication in the nonmenufaeturing Major Croup H Food stores Msior Croup 55. Automotive dssleta and gasoline service stations Major Croup SX Apparel and aceeatory torsi Maior Croup 57. Furniture, horns furnlthing, and squipasnt slsrtt Msior Croup Sg. Eating sod drinking places Ms|or Croup IX Miscellaneous retail Division H. Finance, lniurehcf. and Real Estatt Msjor Croup (0. Banking include* esnetr death*. (Not* that table* used in the computer model* for this tntlytls may vary slightly from these figure* dua to rounding.) The benefits of the standard mult from Its expected reduction of occupational injuries and Ulnesaea that are chemically related. Specifically. OSHA projects that the standard will avert 20 percent ot three injuries and illnesses. (Five percent of aD eanecr actor, whether monetized in terms of human capital or willingness to pey. are presented after discounting (at 10 percent). Such discounting does not convey the magnitude of the expected number of Injuries. [Unities and deaths that should b* averted by the extension of hazard communication to the nonmanufaeturing sector. The actual number of NLWD cate*. LWD case*, chronic Illness cates, cancer eastx Msior Croup *1. Credit tgsndaa other tkaa banks Tahtea 1 w 10 appear ai iha tag aI tkn track. cancer deaths, and other fatalities that re expected to be everted in the first. 64 DE 008449 * . . Fadertl Register / Vol. 52. No- 163 / Monday. August 24. 1987 / Ruins and Regulation} 3lfl9 twentieth, and fortieth yeer* an the standard, at well *s in terms of total presented In Table 4. present value over forty year*. Present The number* of cate* prezented in values were calculated using a 10 Table 4 an projection* of cate* that will percent discount rate. Table 6 present* be everted by the *tat* right-to-know the eosts by provision. tew* and the extension of the HCS. The total cost attributable to hazard Approximately 43 percent of these cate* communication law* during the first wilt be averted a* a mult of the hazard year the expanded HCS is effective Is communication right-to-know) law* $1.28 billion (1985 dolltrs). The first year of the ttate*. The remaining 57 percent cost associated with complicnce with uniquely nlate to the extention of HCS state right-to-know laws is $597.3 million end trsnilate Info the following: 148.400 and $687.3 million with the Federal HCS. cancer cate* and 74.200 cancer death*. The present value of the total HCS- 119.200 chronic ditabiing Ulneitet. related compliance costs over the 40 44S.500 lo*t work day cate*. 702.000 year period i* $1.57 billion. non-Ioat work day caeca, and about 653 Recordkeeping activities are required non-cancer fatalitie* avoided over the in the maintenance of MSDSs. As shown next 40 year*. Thii aetimate It believed in Table 6. the Year 1 eosts for tbit to be contervative tine* OSHA aaaumed function amount to $44.9 million (1983 that only 5 percent of all cancer* an dollars). The costs for the twentieth and occupationally related. fortieth years are $8.0 and $13.3 million. The original Regulatory Impact The present value of the coat* over 40 Analytic (RIA) for the HCS in year* ii $84.8 million. manufacturing included eatimatea of benefit* ariting from the reduction of the Economic Impacts incidence of chemical fire* In the In order to assets the potential manufacturing teetor. Using the RIA'* economic impacts of expanding the methodology and newer data obtained hazard communication standard. OSHA from the U.S. Fire Administration'* studied the impact of the first yeer cotta National Fire Incidence Reporting on typical establishments that have not System. OSHA has determined that implemented any of the provision*. No extension of the HCS to the allowance was made for partial nonmanufaeturing sector would yield compliance. If establishments can pat* first-year benefit* (i.e.. the value of through or absorb first year costs, it is property damage* and losses avoided) assumed that they can afford the of 51.6 million (1B85 dollar*). For the minimal recurring costs related to twentieth and fortieth years, the training new employees and the estimates are $2.2 and S2.9 million, introduction of new hazards. Table 7 respectively. The present value of the presents tbe average compliance costs, 40-year stream of benefits Is $20.3 assuming no current compliance, for million (using a 10 percent discount typical establishment! in each SIC rate). Code. Typical establishment* in the Extending the HCS to the preponderance for SICs (over 80 nonmanufacturing sector will alto yield percent) would incur compliance costa benefits by eliminating the need for of lea* than $700 In the first year. employ ert to comply with multiple state In only one of the SIC* does the and be*I right-to-know laws with average total first year cost exceed $800 differing requirements. The estimated per establishment. The average first benefits for the first year amount to year cost per exposed employee in all $39.6 million (1965 dollars|. For the SIC* ia less than $250. or less than S5.00 twentieth and fortieth yeer*. tha benefit* per worker per week. are S09.5 and SI25.5 mlUknv Table 8 present* a comparison of the respectively. The present'vatue of the post-tax compliance costa to a typical 40-year stream of benefit* it S57f million firm'* revenues and profits. A typical (using a 10 percent discount rate). establishment'* pre-tax compliance cost Compliance Cost$ w-itl be a negligible percentage (less than ene-half of one percent) of the Compliance cast* were estimated (or establishment's average annual revenue five items: preparation of a written in over 98 percent of the SIC*. The only hszerd communication program: exceptions. SIC 83 (Social Service) and container labeling: provision of MSDSt: SIC 86 (Membership Organizations), art maintenance of MSDSt: and Information primarily composed of nonprofit and naming. establishments that are characterized by Tab'e 5 provides a summery of total relatively inelastic demand (or their regulatory costs, the eosls attributable services. Given the magnitude of the to slate right-to-know laws and the eosts compliance coat* in relation to revenue, attributable to the extention of the end the fact that tha affected Industry OSHA standard. Cotta art presented far sectors art predominantly atrvict the first, twentieth, end fortieth year of providers, which are necessarily characterized by localized marVet; it appear* likely that most firms will pass the compliance costa on to their customers. The post-tax compliance cost as a percent of profits is lest than two percent in most (over 80 percent) of the SICs. Typical firms in these SICs should be eble to absorb the cotta even if they cannot pats them on to their customers. Given the small absolute magnitude of the compliance coat*, and the fact that the analysis wa* conducted using first year compliance costs which are aignificantly higher than the recurring compliance casts for subsequent years, the expaniion of the hazard communication standard should have little or no economic impact on typical firms. Community Ri$ht-to-Know The cost of extending the Supetlund Amendments and Reauthorization Act (SARA) requirements for community right-to-know to the non-manufacturing sector was also estimated. Under Title III of SARA, establishments holding a given hazardous chemical in amounts greater than specified threshold quantities must report these chemicals and their quantities to State and local emergency planning committees and the local fire department. Cost estimates were based on EPA's projected phase-in threshold quantities of 10.000 pounds of hazirdou* chemicals in the first two years, and 500 pounds in the third and subsequent yeer* that the requirements apply to the non-manufacturing sector. The estimated costs for the first and second years are S8.614.300 ar.d $3,524,000. respectively. Third and fourth vear costs were estimated to be $63,492,800 and $32,738,300. The economic impact of extending SARA to nonmanufaeturing was also estimated by OSHA. The third year verage total cost of SARA was combined with OSHA's recurring average total coat* of the'Hszard Communication Standard to estimate the Impact. The analysis indicated that the economic impact per facility of extending SARA to nonmanufaeturing ia minor, and that cost* incurred by affected establishments could be passed on to the consumer. OSHA believes that the extension of SARA to nonmanufaeturing will not affect the feasibility of the Hazerd Communication Standard. Regulator}' Flexibility As is shown in Table 9. a maiontv of establishments in all of the potentially Impacted StCa art small businesses uith fewer than 20 employees Thus, the average compliance costs for small firms 65 DE 008450 <* 31870 Federal Reglatar / Vol. 52. No. 183 / Monday. August 24. 1987 / Rules and Regulations are very similar lo those for typical firms. No diaproportionete economic Impact i foreieen for email Dime. Moi establishments In the potentially affected SICi are eervlce provider*, which typically compete on the baeii of many factor* (eg, location, ipedalixed ten-ice. customer relation*, etc.) to addition to price. Atiumin| *U (inn* try to pate their compliance eoit on to Ihtir customer*, minor price differential* of lest than one-half of one percent shown InTable 10, are unlikely to adversely effect the overall competitive position of small entities. As can be seen from Teble 10. the cost differential between small and Urge firms in over 80 percent of the SIC* t* anticipated to be lest than 0.2 percent of revenue. In SICs 83 and 68 the difference it about 2 percent However, thesa SICs art dominated by non-profit firms which are less likely to be subject to price competition. Envintimtntaf Impacts ' At the time the current HCS was promulgated In the Federal Register (41 FR 53280), OSHA stated that the standard was unlikely to result to the occurrence of significant health or environmental impact* outside of th* workplace. The extension of the HCS does not entail any change from th* current HCS in terms of Impacts outside the workpiece. A* concluded previously, the labeling of container* will not have a direct or significant impact on air or water quality, land or energy use. or solid waste disposal outside of th* workplace. Similarly, the requirements for preparation of a written compliance plan, provision and maintenance of MSDSs. and provision of Information and training should have no adverse environmental impact IV. Clearance of Information Collection Requirements On March 31.1883. the Office of Management and Budget (OMB) published a new 5 CFR Part 132a implementing the Information collection provisions of the Paperwork Reduction Act of 1980.44 U.S.C. 3501 rt stq. (48 FX 13680). Part 1320. which became effective on April 30.1883. sets forth procedures for agencies to follow in obtaining OMB clearance for information collection requirements. The sections of the Hsiard Communication Standard which may create recordkeeping requirements are paragraph* (o) hatard determination: (e) written hatard communication program: (0 labels and other appropriate form* of warning: (g) materia) safety data sheets: (h) Information and training: and (i) trad* secret*. to accordance with the provisions of the Paperwork Reduction Act and th* regulation* issued pursuant thereto. OSHA certifies thet It hat aubmttted th* information collection requirements contained to its rule on hatard communication to OMB for review under aaction 3504(h) of that Act. V. Stats Plan Applicability The 25 States with their own OSHAapproved occupational safety and health plan* must adopt a comparable standard within six months of the publication date of a final standard. These States include: Alaska. Artxona. California. Connecticut (for State and local government employees only). Hawaii. Indiana. Iowa. Kentucky, Maryland. Michigan. Minnesota. Nevada. New Mexico. New York (for State and local government employees only). North Carolina. Oregon. Puerto Rico. South Carolina. Tennessee. Utah. Vermont. Virginia. Virgin Islands. Washington, and Wyoming. Until such time as a State standard is promulgated. Federal OSHA will provide interim enforcement assistance, as appropriate. (Thirteen (13) of these States (Alaska. California. Iowa. Maryland. Michigan, Minnesota. New Mexico. North Carolina. Oregon. Tennessee. Vermont, Washington, and Wyoming) have atreedy expanded the scope of their haterd communication standard/rightto-know law to cover private aector. non-manufacturing workplaces.) Although State HCS becomes effective in aecordonee with Slate promulgation provisions, and it enforceable upon promulgation. OSHA rnuat also review and approve the etendard to assure that it ia "at least as fleetivt" as the Federtl standsrd. OSHA Intends to closely scrutinise State atandard* submitted under current or future State plsns to assure not only equet or greater effectlvens*. but also that any additional requirements do not conflict with, or adversely effect, the effectiveness of ths national application of OSHA's standard. Because the HCS Is "eppliable to products" in that It permits th* distribution snd use of hazardous chemicals in commerce only if they are to labeled container* accompanied by materiel safety dati sheets. OSHA must dttetmine in its review whether any State plin standsrd provisions whld differ from the Federal at* "required by compelling local condition* and do not unduly burden toteretate commerce." Section 18(c) of th* Act 28 UJS.C. 862(C). VL Authority. Signature, and th* Final Rule This document was prepared under the direction of |ohn A. Pendergrass. Assistant Secretary of Labor for Occupational Safety and Health. U.S. Department of Labor. 200 Constitution Avanuc. NW., Washington. DC 20210. For the reasons set out In the presmble. and under the authority of section 41 of the Longshore and Harbor Workers' Compensation Act (33 U.S-C. 841). section 107 of the Contract Work Hour* end Safety Standards Act (Construction Safety Act) (40 U.S.C 333). aeetions 4.6 end 8 of the Occupational Safety and Health Act of 1870 (29 U.S.C. 853.655.857). Secretary or Labor's Order No. 8-83 (45 FR 35736) and 29 CFR Pari 1011. and 5 U.S.C 553. the Occupational Safety and Health Administration hereby emends Pert* 1910.1915.1917.1918.1926. end 1925 of Title 29 of the Code of Federal Regulations, as set forth below. list of Subjects to 29 CFR Fsrts 1910. 1915.1*17.1*11.1929. and 1928 Hazard communication. Occupational safety and health. Right-to-know. labeling. Material ttfetjprieta sheets: Employee training. Signed at Washington. DC this ttih dev ot August 11*7. John A. Pendergrass. Atsnienl Secretory forOccupannnelSofriy ondHtahh. Taoue 2 --Women Exposure to Hazardous Chemicals Sic Ot. ___ Stc 02 Industry 1 , Total numoer of stsbtisNnent Total employment Pweent ot ontii etoostd to hazsroous enonveait Hum&e* i exposed employees 31.731 10.191 604.025 124.03* 70 352 BH 70 86 227 66 DE 008451 Reyiler / Vol. 52. No. 163 / Monday. August 24. 1967 / Rule* nd Regulation! atari Table 2.--Worker Exposure to Hazardous Chemicals--Contmu*d tnduttry Tottl number of MUbkthrMM ToUl P*te*nef omef, meiMio burOoui dmiKM Numw el lipuM mptoyeci {IT ....... ........ .......... - - 5.704 sir rtf -. 2.117 SIC Of SIC 13. sir . . ........... - ----------------------------------------------------------------------------------- .................. . ................ ...... ............ 3.666 31.572 166.012 SIC 16 sir it ... .... ... ...................... . *4,702 320,206 SiC 49 ............. ..... ........... ................ -....... - 16.536 s*c , ,, .................... .............. ........... . sir. a? ........................................................... s*r AA ... ................ ................. ... sir ii ................................................. 15.539 99,90$ IJ4I 1,111 Sic 46. sir. aj ....................... ....................... .............. 656 30.763 SIC 4f sir 40 .............. ............ ...................... ........... ............... ............ J2.tio 15.571 sir sn.......................................................... ............................. $ir 51 . . ............................. ................... ... sir ............................ . ... ................................... . SIC sa..................................... ............................ .............................. SIC *4 _ . ......................... sic ss . ... SIC M ....................................................................... SIC ST .... . . SIC SO sir so ................................................... sir on ........................................... ........... sic 01 ............................. ....................... sir. at 900.172 If1.74$ 66756 2fJ1f 137.393 173 f02 99,022 93736 309.650 261.694 34.949 43.409 17.695 sir i............................. ................................................. ...................... sir A4 ....................................... ....... . .... sir s ...................... Sit AA .......................... sir at 30.139 99.706 101.400 2J37 1STBT sir. to ........................ ........................ SIC T9 ............................. Sir. 73............ ....................................... 44,997 ISA 373 7|i (fi SIC. TS. ............. ........... .................................. SIC TS............................ ......................... Sir TS................................. SIC T9.................................................. .. ... ............... SIC 60 ..... _. ............... SIC 81.................................................... SIC 69..................................................... SIC 83...................... .............................. SIC 84............................................. SIC 86......................................... SIC 89.............................. . . 12V431 97 900 19339 59.064 365.756 116.661 33 380 \ 66 M0 | 1.592 j 63 774 ! 117.155 T*N.................................. .!--------4--.-5-0--3-.-6--7-6-- Soute* US. 0*p*nm*M of UfcOf, OSHA. Office 0) RrffullUyr Arjlyv,. 456.476 20.223 13.546 591.714 1.137.953 791.192 2.406.916 324.206 265.576 1423.465 176.013 400.365 16.405 297.113 1.321.116 690.566 3.357.161 2.295.451 992.091 2.230.449 2.699.939 1,050.399 1.004.669 714.294 5.479.933 2.133.914 1,991.409 733.201 346,214 1.190103 536.223 1,077.550 13.752 138 466 ' 1.273 343 1.056.970 4.092.820 713.798 316.365 218.808 757.267 6.167.936 670.317 1.174.0S2 1.182 651 39.021 724.283 1.200.885 58.100436 70 321.635 70 14 156 20 2710 70 414 200 70 796 497 70 554 324 70 1.654 841 40 129 682 20 57.116 20 264 699 70 124 609 40 196.158 60 11.0*3 40 106645 s 66056 40 356.234 10 335717 25 573 663 50 331.026 5 111.522 20 539.366 60 1 U021S $ 50.233 $ 35713 25 1 369 906 20 426723 5 64 070 5 35660 $ 17.311 5 59.505 $ 26611 5 S3 676 $ 668 $ 6.924 25 316 336 50 534.335 50 2.046410 50 356 699 60 169619 30 65.042 20 151.457 60 3.700.745 5 33.516 10 117.405 5 53.133 25 755 5 36 214 5 60 0*4 18.391.096 Table 3.--Estimated Benefits^ Hazard Communication tMiKora of 1985 doften) Typ of tftfury/irwws. Btnofm--T,*r t 20 40 TPV HUMAN CAPITAL APPROACH NLWO- * Loti Mtnmpi..................................................... ............ MMulnm_______ . ................................. ........... ........ LWD: Loll urnng, .. ................ , ___ ,, ,, ............. or 1.3 25 93 17 46 13* 30 3 15 2 28.3 57 1 209 3 67 DE 008452 31872 Federal ltefijulBr / Vol 82. Ko. 1S3 / Monday. August 24, 1957 / Rulei and Regulations Tuu 3.--Estimated Benefits of Hazard Communication--Continued (MMont 011995 dollar*) Typtoftafury/antn Benefit*--Year t ZO AO TPV Cnroote Conor. tiftipfflf fAftf Fatattet: UM eameijt.. Totti ------------- ------ - ............. . ............. -------- ---- --- -------------------------- '0.9 20.3 21 0 0 44 S6.3 MZ 7229 149 4 951.6 2*9.9 7.3 1A87.3 *9.5 1.3656 404.1 1.9096 9064 13 0 4.159.3 192 2 2.967 5 562 9 1.735 2 675 9 596 66591 Mwn WUJN&KESS-TaPAY APPROACH FattSAM Sovcc JACA Corporation Report .................. 5*6 974 4 6t.7 0 72.S 5997 107.6 6664 2.173 7 14.529.0 1239 17.6J0.7 211.9 1.3711 4.121.6 29.951.2 255.3 35.591.2 9045 5.099 9 9.924 3 39.9120 1461 54.597 4 Tabu 4.--Injures, Illnesses, ano Fatalities Averted bv Hazard Communication in the Nonmanufacturing Sector Year Commu 1 20 40 tative total Niwn linn Ca"cer cate* <Tnr*r iluM niwt> iwn n* riminiM Naneanear 4MN.. FEDERAL AND STATE STANDARDS COMBINED ...... _ ................ IMPACT OF FEDERAL STANDARD ALONE 17.000 10 700 150 0 0 p 30600 19.600 &200 0.200 4.100 20 60600 39.20Q 11 600 17.000 6.500 90 1.354 500 - 665 600 230 100 266.500 143.300 1.200 6600 S 500 76 o o o 16.000 10 200 3*200 4.248 2,100 10 31 400 20.300 6 100 8.806 4 400 41 702.00C 446.500 119.200 146.400 74.200 6S3 Source: U.S. Oeperenent at labor. OHSA. ONce el Regiiawy Anlyn. Tabu S.--Summary or Hazard Communication Com (MWontoMMSdoAar*) Tabu S.--Summary of Hazard Communication Costs--Continued (ViNont el 199$ dollar*) Source. US. Depanmew-ol Labor. OHSA. Oltice o' Raputatory Analytic. Year 1................. SO............. o Total State OHSA Year 1.294.5 214.5 394.0 50T.3 101.3 104.0 9672 1132 200.0 T0t*i prtttM -j Total ) Stilt OHSA 1 9 096 4 * 1.3593 1.570.1 I 68 DE 008453 Fcdaral Reghttr / Vol. 52. No. 163 / Monday. August 24. 1987 / Rules and Regulation! 31873 Table 6.--Summary of Federal HCS Costs sy Provision (MMont of 1965 Mm) Ytaf Uhv tain MSOS'a labat* *ng WrtI* in Tram. *6 Providt MSOSl Tottlt III 12.6 137.4 472.6 6.0 20.3 S.7 76 7 4ft .............. ............... 13J 4 6.4 13S.S ... .................... ....................... 144 170.6 170.6 1064.6 Souret: U S. Oapaitmant of Labor. OKSA. Otlca of Regulatory Analyst. Table 7.--Summary or HCS Costs per Establishment Not m Compliance With HCS tins dotei*) 18 3 687 2 25 1132 56 2000 86 9 15701 kndutoy I Fra yaar Avaraga cost* oar MUWiMV mam Avaraga cotta par aapoatd amptoya* Sacondytar Average costs Pftf statastv mtfit Avfttftg* eosts per exposed employee fttft 01............................. .*................................................ Sift 09 ........................ .. ....... ..................... Sift 0? ............... .................... ............ ............................... .......... Sift Oft ........ ................... .. ...................................................................... sr. oft .... .................. Sift 1* ........................................... .......................................... Sift 1ft ....... ................................. ................. . Sift 1ft ....... ....... ............. Sift 17 ..................................................................................... SIC 40................ ......... ................................................................................... SIC 41........................................... ............................. . .... SIC 49 ................ .................................................... Sir. 44 ....................................... SIC 46 ....................... SIC 46..................................... ........................................... SIC 47 . . .................. SIC 4* ............ . ... ... ............ .. . ......... .. SIC 49................................ .... ...................... ............ SIC sn .......... ......... .................. SIC St SIC 62............... _......................................... ................................................. SIC S3............................. ......................... _ .......................... SIC S4...................................................... .... ............ SIC ss . ............................ ...... . . SIC SS.................................... SIC 57.................... .................................... ....................... SIC SR............... ................ .............. _ SIC 59 .............................. ............ SC SO.............. sc Si ........ .. SC S2 ........ .................... SIC S3 ............................. SIC S4.............. sic ss.......... ' ...................... sc ss-......... . _ SIC S7 -- . SC 70.............. .. . SIC 73 SC 73 _ _....................... I SC 75.......... ......................... 1 SC 78 ........ sic 78 ..... . .............. _ .......................... i SC 78 .... sic so -- . _ . .............. .............. . sc si .................... .5........................................ SC S3 ............................. SC S3.................................. SIC 84 SC 66 502 475 400 358 904 487 190 225 ISO 603 265 273 442 882 461 396 319 798 472 700 339 972 923 437 265 2SI 337 921 410 217 312 290 299 909 239 419 409 900 444 361 325 991 946 981 242 297 937 09 273 45 56 too 54 242 36 31 19 92 96 76 96 30 40 40 115 50 95 238 234 68 50 92 60 149 190 76 194 61 76 79 46 155 166 161 167 97 140 62 190 ft 3 117 57 153 46 132 ft 149 *32 23 26 26 6 72 12 94 14 51 11 12 55 72 55 15 15 64 14 32 20 27 t8 31 6 6 17 7 jr> 6 10 16 5 0 6 12 37 16 43 14 1$ 26 20 57 7 10 11 31 6 3 3 6 4 5 5 3 3 3 7 3 4 4 3 5 4 2 3 7 11 4 4 s 5 3 4 4 4 3 3 5 3 3 5 4 5 i 5 6 2 ! c ( 4 69 DE 008454 81874 ~ Fdtal RegUtef / Vot. 52. No. 18: .day. Auguat 21. 1B87 / Rule* md Regulations Tu 7. Summary os HCS Com sen Establishment Not m Compliance With HCS-Conbtmad (IMS doMral Induaay ac aa Sourer U.S. OapartnaM o Labor, OSHA. Office ot Regulator Analysis. first year Avriji COM M tftsbfctfv mtnt Averts COCtlpM lipoid Stcond yttr Average Certs per estaMsn- ment Average costs per exposed etrptoyee 312 14* 10 . S tarn 8--Analysis os Post-Tax Fipst-Yeaa Compliance Costs IIMSdoUrs) SIC 01 SIC 02. SIC 07 SIC 0* SIC 06 SIC 13 SIC 15 SIC 18 SIC 17 SIC 40 Sic 41 SIC 42 SIC 44 SIC 45 SIC 46__ SIC 47 sic 48 SIC 49 Sic so SIC 51SIC 52 Sic 53 SIC 54 SIC 55 SIC 56 SIC 57 SIC 58 SIC 59 sc 60,,. SIC 61 sc 63 SIC 63. sc 64 sc 65 . sc 66 sc 67 sc 70,, sc 73 sc 73 sc 75 _ sc 76 sc 7* sc 79 sc 60 Sic 81 sc *3 sc 83__ sc 83 sc *4 sc *6..,, kndusay Average annual revenue per ettabktnmenl Average coal at a percent of revenue per ettaMtnmanl Average"** income per estabhehmant Average post, tax cast per eatattsnment Poti (at cost as a pereant o' net meome per ettabMiwnenl 3.7*4.100 11.275.400 388.800 1.681.100 7*7.500 6.1*5.900 18.700 1.419.700 372.400 2.5*4.100 411.400 730.100 2.214.300 5.900.000 20.569.600 31.900 5.347.900 16.269.000 1.866.900 3.371.500 793.900 5.702.000 2.0*9.700 2.016.100 507.600 371.400 333.500 939.100 14.970.900 2.565.300 1.856.900 12.911.400 230.400 339.400 561.600 798.300 6C7.000 238.500 531.600 351.800 187.100 915.900 782.100 198.300 456.000 NA NA NA NA NA 0018 0.004 0.171 0.021 0.039 0.009 0.019 0.01* 0.045 0.023 0.0S9 0.037 0.020 0.015 0.002 0 046 0.006 0005 0.025 0.021 0042 0.007 0.015 0.022 0.052 0.07* 0.088 0.039 0.003 0.009 0017 0.002 0107 0 090 . 0.036 0.052 0.067 0.219 0.0*4 0.10* 0.174 0 043 0044 0.293 0.053 0.1M 1.763 1.7*3 0.094 1.007 103.3*2 417.190 7.195 42.228 19.938 346.405 19.601 56.7*9 10.800 111.11* 13.165 21.903 141.715 70.600 1.069.619 14.974 390.397 732.105 28.004 57.31* 20.639 138.646 25.07* 16.12* 1*.796 11.513 11.122 20.729 509.007 41.395 135.554 43B.9M 15.959 27.749 54.251 167.643 34.59* 10.3*3 21.264 8.795 7.671 31.630 51.619 6.342 10.032 NA NA NA NA NA 377 356 3M 268 33* 373 113 169 127 453 214 205 331 669 346 399 339 519 3S4 535 251 379 343 337 199 316 352 341 307 1*32d4 167 177 330 178 311 306 375 333 386 344 263 360 436 183 315 353 253 45* 205 035 009 5 13 064 14 ;M 057 0.30 1 17 041 163 094 0 33 0 94 003 1.99 0.06 0 08 1.36 0 93 1.33 030 096 303 100 168 337 1 16 006 039 017 004 1 11 0 83 033 019 0 88 361 1 57 3 35 3 II 013 0 50 687 1 81 NA NA NA NA NA DE 008455 - Federal Rcfhtw / Voi. 52, No. 193 / Mondiy, August 24. 1987 / Rule* nd Regulations 318" orTable fl.-AnAi.vats Post-Tax First-Year Compliance Costs--Continued industry (itflS doKtrsl Average annual revenue per eataoetbmeni Average com *ae percent el revenue per eftabkahmeni Average net income per ttabtenmem ------------ " ' "1r--- Average posttai cost per ettabucnment Pott ux cwi as 6 patcar.t e* ntt mcomtptv stabtiftnmrrt ClT ft* 290.500 Soiree: US. department of Labor. OSHA, Office of Regulatory Anatyja. 0.107 11.03* 234 2.12 Table 9--Hstaslishmehts With Fewer Than Twenty Employee* SIC code Tout number e( tatabktbmema Number ol eMab* tstewama Mil M IB employ ee* Percent el attabtthmtnta exth 1 Ip 1* employ ee* 01________ 02________ 07_______ ft* 09_______ 13________ 15_______ 16________ 17_______ 40___ 41________ 42..... 44_______ 45_______ 46_______ 47_______ 46_______ 4______ _ so_____ 31,731 10.994 65.704 2.117 2.180 31.57' 166.012 44.702 320206 11.539 15 267 *4.561 1.346 6*1 59 30.7*3 10.31* 15.571 169.451 27.440 B.S74 61.92* 1.B52 2.06* 26.037 154.81* 37.4*4 294.650 15,756 11.896 *0.622 6.S17 8.514 724 26.420 6.612 10.822 133233 86 17 *4 7 7 62 as *4 92 95 79 95 3 75 75 92 84 70 78 Tabu 9.--Establishments With Fewer Than Twenty Employees-- worntnuca SIC code Total numbai ol ettabkthments Number ol ettalp hanmenta wrtn 1 lo 1* employeet Pcent ol eatabSabmonls anit1 to employee* 51 52 53________ <u 55 56___ .., 57________ 59. 59.--TM... B0________ 6182 *3 84 5 M. 67 70________ 181.745 66.756 14.109 137.393 173.902 29.181 23.562 309.650 244.849 12.475 12.912 4.380 10.998 17277 32.714 S24 2.7*0 44,887 166.562 60.097 1.863 114.739 152.120 23.174 20.474 241292 227.903 6.319 9.561 3.079 72*3 15.809 26.099 486 2239 34.893 *7 90 60 4 88 as *7 7* 93 51 74 70 66 II 6 93 0 79 Table Q.--Establishments with Fewer Than Twenty Employees-- Continued SIC code Total number ol *Mab(atanenta Number el estabkthmentt extn 1 lo 19 employ- eet et tubfctNV*nlS nmIti u tmptor m 72 71.............. 75-----------76 78 9* 90. 1... 62----------ia __________ 14 as............ at_____ 159272 284.6*4 121.431 57.900 15.331 50.991 365.759 21210 11.(61 1.592 11.757 26.103 146.112 241.553 116.344 55.543 13.314 42.916 33(296 11.659 11.197 17.069 US0 16.416 23,179 95 6* 95 95 17 $4 93 09 60 74 79 63 92 Source. U.S Department ol Labor. OSHA. OffiC* ot Regulatory Anaiyiit From Chapter 5 ot Ibe JACA Raoon 141 Column 2 dmoed by Column t. Tabu io.--Analysis of impact on Smallest versus Largest Establishment* 1Comparing average coals a* a percent ot revenue) ' SC code Averege cottas* percent ol rtvtrt* per eitabiisnmem 250+ employee* Averege cost u a pereemol ravafua par etubMitmerit l-tl' ifiiptoyMi Orfference neostuft ptreem ot revenue due louiol e*i*6HN mtmt 01___ 02___ 07___ 0#__ 09___ 13___ 15___ 18___ 17___ 40___ 41___ 42___ 44___ 45___ 45___ 47___ 4*___ 0.003 0.001 0.03* 0.007 0.002 0.002 0003 0.007 0017 0.00* 0.007 0.007 0.007 0.00* 0.000 0003 0.002 0044 0.00* 01*9 001* 0.021 0035 0044 0064 0055 0.052 0 246 0.103 0060 0105 0174 0101 0.041 0 040 0.006 0151 0011 001* 0033 0 042 0057 0046 0 075 0240 0096 0 053 0 096 0 174 0 00* 0 039 71 DE 008456 31876. - Federal Register / Vol. 52. No. 103 / Monday. August 24. 1987 / Rules and Regulation; Twe 10.--Analysis or Impact on Smallest Versus Largest Estasushments--Continued . [Compamg Mtiji costa M a percent of revenue] SlCeod* Average coal 8* a percent o4 revenue per eatabhariment 250+ employee* Average cottas a percent e> revenue per eatabhan. mem 1-1* employees Otterenee m cost as a percent o< revenue due to sue ot eitibhtn. menu Af ...... .. ...... ................ ...... ifft ... ......... ..................... ........................... .- 2 ......................... ............ ....... . -.......................................................... U ... -............................................ . - - ... .......................................... ........................................ M ...... ... ................................... .. ? .................................................... u................................. ............................................... ... ____ . ___ .... .... ................................... ft ................................ ........................................................... HI .... ................ .................. 19 .. ............... ................................................... *3.............. .... ................................. Hi ................................. ... . . ... .. M................... ................ .............................. .............................................................. 67................................. 7ft . ... ........................... ? . 78 .. ................ 78 78 ................ 7* nn 89 . M Ai .. . . 88 ................................ 88 .............................. .................. _ . . ..... Source u.S. Department el Ubor. OHSA. Offce el Regutatoiy Anatyue. 0002 0.002 0.006 0.000 0.002 0.002 0.002 0.002 0.002 0.000 0.003 0.001 0.000 0.003 0.000 0002 0.009 0001 0.003 0 071 0 007 OQgj 0 004 0099 0.007 0 01$ 0269 0 110 0 0?5 0 426 0 033 0.035 0006 004* 0037 0036 004$ 002* 0.054 0.044 0 104 0117 0 156 0.055 0012 0.036 0026 0.069 0.179 0124 0.054 0096 0 263 0 34$ 0204 0151 0.205 0 113 0071 0370 0077 0915 2 293 0259 2 109 0.210 0 047 0 034 0032 0 038 0026 0 052 0038 0 162 01U 0 ISO 0 051 0011 0 038 0 025 0069 0 177 0 119 0053 0 093 0 267 ` 0 339 0 175 0 148 0 106 0 106 0 055 0 101 -0041 0 890 1 665 0 226 207 0 202 OSHA it amending Paris 1010.1915, 1017.1918.1928. and 1920 of Title of the Code of Federal Refutations at follows: PART 1*10--OCCUPATIONAL SAFETY AND HEALTH STANDARD* 1. The authority citation for Subpart Z of Part 1910 contimiea to read at follows: Authority: Sect. A A Occupational Safctr and Hralth Act 12* UJ.C. ISA S57): Secretary of Labor a Order No. 12-711 FA 17*4): *-7t (41 FA ZSOth or t-*3 (41 FA IST38) aa applicable, and 29 CFA Fan ltll. Section 1B101000 Tablet Z-l. Z-2. Z~3 alto tltued under S U.S.C. SJJ. Section 1*10.1000 not tltued under 2t CFA Part ltll. ticept for "Aradnle" and "Cotton Dual" liitlnp in Table Z-l. Section 1*10.1001 not timed under See. 107 of Contract Work Hours and Safety Standard! Act. 40 U-S.C 322. Section 1(10-1002 not iiauad under 2* US.C. 892 or 28 CFA Part ltll: alio iiaued under * US.C. SSI. Section! 1*10.1001 through 1*10.101* alw timed under 28 U.S.C. 153 Section 1810.102S lao timed under 28 U.S.C. 8S3 and 2 U5C. 253. Section 1810.1042 alio limed untlar S US.C.SS1 erae*. Section 1810104S and 1810.1017 alio iimad under 28 U.S.C. 822. Sectiona 1810.1100.1810.1498 and 1*101200 alto lamed under 5 U.S.C. SSI PART 1915--OCCUPATIONAL SAFFTY AND HEALTH STANDARDS FOR SHIPYARD EMPLOYMENT 2. The authority citation for Part 191S li reviled to read aa follows: Authority: Sec. 41. Lonfihore end Harbor Worken' Compensation Act (33 U.S.C. S41b eca 4. A S. Occupational Safety and Health Act of 1*7012S U.S C. SSI. SSS. 8S7): Steratiiy of Labor's Order No. 12-71 (38 FA S7S4). S-78 (41 FA 2S0S*|. or 8-81 (IS FA 3S7J0) applicable: 29 CFA Part tail. Section 1S1S.M alto limed under S U S C 221. PART 1917-MARINE TERMINALS 3. The authority citation for Purl 1917 ii reviled to read' aa follows: Authority: Sec 41. Lonpihore ind Harbor Worken' Compensation Act 111 L' S C *411 ect 4.8.8 Occupntinr.il Selen and Health Act of 1*70 (29 U S C 851. SSS SS7| Secretin of Labor'i Order No 12-71118 FR 87MI a-7* (41 FA 2MIS9). or 9-81148 FA ISMGI ii applicable: 2* CFA Part 1911 Station 1117.21 alio timed undw S U S C 553. PART 1919--SAFETY AND HEALTH REGULATIONS FOR LONGSHORING 4. The authority citation for Port 1918 it reviled lo read aa follow!- Authority: Sec. 41 Lonpshon and Harbor Worken' Compensation Act 111 U S C *411 72 DE 008457 Federal Regialer / Vol. 51 No. 163 / Monday. August 24. 1987 / Rule* and Regulation* 31677 eei lilOccupational Safety and Health political aubdivision of a atate. Act of 1*70 12* U.S.C. M3. US. UPp Seoetaiy or Labor * Order No. 12-71 (36 FR 87*4). 6-7* (41 re 23034). or MS (* re *3738). at applicable. Section 1*11.10 .Ito liiiwd wider S U.S.C 333 and 2* CFR Part 1*11. pertaining to the aubjeet. Evaluating the potential hazards of chemieala. and communicating information concerning hazard* and appropriate protective meaturea to employees, may include, for example, but la not limited to. proviaion* PART 12--SAFETY AND HEALTH REGULATIONS FOR CONSTRUCTION for. developing and maintaining a written hazard communication program for the workplace, including list* of 5. The authority citation for Subpart D hazardous chemical* present; labeling of of Part 1928 la revised to read aa follows: Authority. Sec. 107. Contract Wotk Hoot* and Safety Standards Act (Construction Safety Act)(40U.S.C.333):secs, t.ll Occupational Safety and Health Act ofl(70 (2* us e *33. *33. U7): Secretary of Labor'* Order No. 12-71 (3* FR I7ML *-7* (41 FR 25059). or Ml (4* re 3373*]. as applicable. container* of chemical* in the workplace, a* well as of containers of chemical* being shipped to other workplaces: preparation and distribution of material safety data sheets to amployee* and downstream employers: and dcvalopmant and Implementation of employee training program* regarding hazard* of Section 1926.3* also Issued wider * US.C. chemicals and protective measures. 333 and 29 ere Part 1*11. Under section 18 of the Act no state or political aubdivision of a state may PART 1*2*--OCCUPATIONAL SAFETY adopt or enforce, through any court or AND HEALTH STANOAROS FOR agency, any requirement relating to the AGRICULTURE issue addressed by thi* Federal 6. The authority citation for Pari 1928 Is revised to read aa follows: standard, except pursuant to a Federally-approved state plan. (b) Scopt and application. (1) This Authority: Secs. and A Occupational Sjfety and Health Act of 1*70129 U.S.C. *33. (57): Secretary of Labor's Order* 12-71 (3* FR PM). 6-7* (41 re 25059). or M] (4* FR 35738). as applicable: 2* CFR Part 1911. Section t*2JL21 also issued under 5 US.C. 533 section require* chemical manufacturer* or importer* to assess the hezardt of chemicals which they produce or import and all employers to provide information to their employees about tha hazardous chemical* to which they are exposed, by mean* of a hazard PARTS 1910,1*15,1917, 1911, 1928 and 1928--[AMENDED] communication program, label* and other forma of warning, material safety data sheets, and information and training, in addition, this section 7. Parts 1910.1915.1917.1918. and requires distributors to transmit the 1926 art amended by reviling 11910.1200 as aet forth below, and by adding If 191S.99.1917.26.1916.90. and required lnformetion to employers. (2) This section applies to any chemical which is known to be present 1926.69 to contain the Identical taxi of the revised 11910.1200. including Apendicea A. B. C and O of 1910.1300: In the workplace in such a manner that employees msy be exposed under normal conditions of use or in * foreseeable emergency. I---- Hazard communieaUan. (3) This section applies to laboratories (a) Parpote. (l)The purpose of this only a* follows: section is to ensure that the httird* of (I) Employer* ihtll ensure that labels all chemicals produced or imported are oo Incoming containers of hazardous evaluated, and that infonnetion ehemictlt are not removed or defaced: concerning their hazards')* transmitted (ii) Employers shall maintain any to employer* and tmployres. Thi* materia) safety data sheets that are ttantmitta) of information i* to be received with incoming shipment* of accomplished by meant of hazardous chemicals, and ensure that comprehensive hitard communication they are readily accessible to laboratory programs, which are to include employees: and. container labeling and other forma of (iii) Employers shall ensure that minting, materiel safety data shaeta and laboratory employees are eppnsed of employee training. the hazerds of the chemicals in their *21 This occupational safety and workplaces in accordance with health standard ia intended to addreat paragraph (h) of this section. comprehensively the ttaue of evaluating (4) In work operations where the potential hazards of chemicals, and employees only handle chemical* in communicating information concerning hazard* and appropriate protective measute* to employees, and to preempt setled containers which are not opened under normal conditions of use (such as are found in marine cargo handling, snv legal requirements of a state. or warehousing, or retail sales), this section applies to these operations only a* follows: (i) Employers shtll ensure that lahels on incoming container* of hazarduus chemicals are not removed or defsced: (ii) Employer* thafi maintain copies of any material safety dal* sheets that are received with incoming shipments of the seeled containers of hazardous chemicals, shall obtain a material safety data sheet for lealed container* of hazardous chemicals received without s material safety data sheet if an employee requests the material snfety data shtet. and shall snsure that the materi.il safety data sheets are readily accessible during each work shift to employers when they ere in their work areo(s); and. (iii) Employer* shtll ensure thut employee* are provided with information and training in accordance with paragraph (h) of this section (except for the location and availability of the written haztrd communication program under paragraph (hHl)tiii)). to the extent necessary to protect them > the event of a spill or leak of a hazarduus chemical from a sesled container. (5) This section does not require labeling of the following chemicals: (i) Any pesticide as such term ts defined in the Federal Insecticide. Fungicide, and Rodenticide Act (7 U.S.C 136 et seq.). when subject to the labeling requirements of that Act tnd labeling regulations issued under thst Act by the Environmental Protection Agency; (ii) Any food, food additive, color additive, drug, cosmetic, or medical or veterinary device, including materials intended for ute at ingredients in such product* (e g. flavors and fragrances) as such terms are defined in the Federal Food. Drug, and Cosmetic Act (21 U.S.C. 301 et teg.) and regulations issued undrr that Act. when they art subject to thr labeling requirements under that Act In the Food and Drug Administration: (iii) Any distilled spirits (beverage alcohols), wint. or malt beverage intended for nonindustrial use. at such terms are defined in the Federal Alcohol Administration Act (27 U.S.C. 201 et teg.) and regulations issued under thst Act. when subject to the labeling requirement* of thst Act and labeling regulations issued under that Act by the Bureau of Alcohol Tobacco, and Firearms: and. (iv) Any consumer product or hazardous substance as those terms are defined in the Consumer Product Safely Act (15 U.S.C. 2051 et seq) and Federal Hazardous Substsnees Act (15 U.S C 1201 et seq.) respectively, when subtect to a consumer product safety standard or labeling requirement ol those Acts or regulations issued under those Acts bv 73 DE 008458 31878 Federal Register / Vol. SI No. lf / Monday. August 24. 1887 / Rule and Regulations Ihr Consumer Product Safety Commission. (fit 1 hit lection does not apply to: jil Any hazardous waste us such term is defined by the Solid Waste Disposal Act. as amended by the Resource Conservation and Recovery Act of 1978. as amended (42 U.S.C- 0001 at sec.), when subject to refutations Issued under tbut Act by the Environmental Protection Agency: (ii) 1 obaeco or tobacco products: |i:i| Wood or wood products: (iv I Articles: |v) Food. drop, cosmetics, or alcoho^c beverages in a retail establishment which are packaged for salr to consumers: fvlj Foods, drugs, or cosmetics intended for personal consumption by employees while In the workplace: (viij Any consumer product or hazardous substance, as these terms art defined in the Consumer Product Safety Act (IS U.S.C. 2051 ef leg.) and Federal Hazardous Substances Act (IS U.S.C. I2tn er zeq.) respectively, where Ihe employer cen demonstrate It is used in the workplace in the ssme manner at normal consumer use. and which use results in s duration and frequency of exposure which is not greater than exposures experienced hy consumers: and. (% iii] Any drug, as that term la defined in the Federal Food. Drug, and Cosmetic Act (21 U.S.C. 301 ef icq.). when It is in sniid. final form for direct administration to ihe patient (i.e. tablets or pills). |c) Definitions. "Article'' means a manufactured item: (i) Which is formed to a specific shape or design during manufacture: (li) which has end use function(s) dependent in whole or in part upon its shape or design during end ase: and (Hi) which does not release, or otherwise result in exposure to. a hazardous ehrtnlcti). tinder normal conditions of use. "Assistant Secretary" means the Assistant Secretary of Labor for Occupational Safety and Health. U.S. Deportment qf Labor, or dtralgnea. "Chemical" means any element, chemical compound or mixture of elements and/or compounds. "Chemical manufacturer" means an employer with t workplace where chemical(s) are produced lor use or distribution. "Chemicel name" means the scientific designation of a chemical in accordance with the nomenclature system developed by the International Union of Pure and Applied Chemistry (IUPAC) or the Chemicel Abstracts Service (CAS) rules of nomenclature, or a name which will eleeriy identify thr chemical for the purpose of conducting a hazard evaiuotion. "Combustible liquid" means any liquid having a flashpoint at or above 100 F (37.8 *CJ. but below 200 * F (93.3 * C). except any mixture having components with flashpoints o( 200 *F (93ji *C). or higher, the total volume of which make up 99 percent or more of the total volume of the mixture. "Common name" meant any designation or identification such as code name, cede number, trade name, brand name or generic name used to identify a chemical other than by its chemical name. "Compressed gas" means: (i) A gat or mixture of gases having, in a container, an absolute pressure exceeding 40 pal at 70 *F (21.1 *C): or (ii) a gas or mixture of gases having, in a container, an absolute pressure exceeding 104 pal at 130 *F (S4.4 *C) regardless of the pressure at 70 'F (21.1 *C): or (Hi) A liquid having a vapor pressure exceeding 40 pai at 100 *F (37J *C) as determined by ASTM D-323-72. "Container" means any bag. barrel bottle, box. can. cylinder, drum, reaction vessel, storage tank, or the like that contains a hazardous chemical For purposes of this section, pipes or piping systems, and engines, fuel tanka, or other operating s.vstemi in a vehicle, are not considered to be containers. "Designated representative" means any individual or organization to whom an employee gives written authorization to exercise such employee's rights under this section. A recognized or certified collective bargaining agent shall be treated outomatleally as a designated representative without regard to written employee authorization. "Director" means the Director. National institute for Occupational Safety and Health. U.S. Department of Health and Human Services, or designee. "Distributor" means a business, other than a ckemicxl manufacturer or importer, which supplies hezardous chemicals to other distributors or to employers. "Employee" means a worker who may be exposed to hazardous chemicals under normal operating conditions or tn foreseeable emergencies. Workers surit as office workers or bank tellers who encounter hazardous chemicals only in non-routine, isolated instances are not covered. "Employer" means a person engeged in t business where chemicals ere either used, distributed, or tre produced for use or distribution. Including a contractor or subcontractor. "Explosive" means a ehcn.iccl that causes a sudden, almost instantaneous release of pressure, ges. and heal whrn subjected to sudden shock. prts*u~e. or high temperature. "Exposure" of "exposed" means that an employee It subjected tu hazarduus chemical in tha course of employment through any route of entry (inhr-leiinn. ingestion, skin contact or absorption, etc.), and includes potential fe.g accidental or possible) exposure. "Flammable" means a chemical that falls into one of the following categories- (i) "Aerosol flammable" means an aeiotol that when tested by the method described lit 18 CFR 1500.45. yields a flame projection exceeding 18 inthes at full valve opening, or a flashback (a flame extending back to the valve) at any degree of valve opening: (ii) "Cas. flammable'' means: (A) A gas that al ambient temperature and pressure, forms a flammable mixture with eit at a concentration of thirteen (13) percent by volume or lest: or (B) A gas that, at ambient temperature and pressure, forms a range of flammable mixtures with air wider than twelve (12) percent hy volume, regardless of the lower limit: (iii) "Liquid, flammable" means any liquid having a flashpoint below 100 'F (37J *C). except any mixture having components with flashpoints o( 100 'F (37.8 *C) or higher. Ihe total of which make up 99 percent or more of the total volume of the mixture: fiv) "Solid, flammeble" means a solid, other than a blasting agent or explosive as defined in 1190.109(a). that is liable to cause Are through friction, absorption of moisture, spontaneous chemical change, or retained heat from manufacturing or processing or which can be ignited readily and when ignited burns so vigorously and persistently as to create a srnoui hazard. A chemical shall he considered to'be a flammable solid if. when tested by the method described in 1C CFR 1500 44. it leii.-les and burns with a self sustaineti flame al a rate greater than one-tenth o: an inch per second along its major axis. "Floshpoint" means the minimum temperature at which a liquid pves off vapor in sufficient conecnlrition to ignite when tested as follows: (i) Tagliabue Closed Tester (See American National Standard Method o( Test for Flash Point by Tag Closed Tester. 211.24-1979 (ASTM D 56-70)) for liquids with a viscosity of less than 4$ Savholt University Seconds (SUS) el ton *F 137.8 *C). that do not contain suspended solids and do not have a 74 DE 008459 Federal Register / Vol. 52. No. 183 / Monday. August 24. 1902 / Ruler end Regulations 31079 tendency to form a turfact film nndet control of and used only by the person teat; or who transfers It from a labeled |ii) Peniky-Marteni Closed Teeter container and only within the work shift (See American National Standard In which it is transferred. Method of Teat for Flaih Point by "Importer" meant the first butinast Peniky-Marlena Cioted Teeter. Z11.7- with employees within the Customs 1979 (ASTM D 95-79)) for liquids with a Territory of the United States which viecoelty eqoal to or greater than 45 SUS receives hazardous chemicals produced at 100 *F (37.8 *Q, or that contain in other countries for the purpose of suspended solids, or that have a supplying them to distributors or tendency to form a surface Film under employers within the United States. test; or "Label" means any written, printed, or (iii) Setaflash Cioted Tetter (see graphic material, displayed nn or aflixed American National Standard Method of to container* of hazardous chemicals. Test (or Flash Point by Setaflash Closed "Matarial safety data sheet (MSDS)" Tester (ASTMD 3278-78)) means written or primed materiel Organic peroxides, which undergo concerning a hazardous chemical which autoaccelerating thermal decomposition, It prepared in accordance with are excluded from any of the flashpoint paragraph (g) of this section. determination methods specified above. "Mixture" meent any combination of `'Foreseeable emergency" meant any two or more chemicali if the potential occurrence such aa. but not combination is not. in whole or in perl, limited to. equipment failure, rupture of the result of a chemical reaction. containers, or failure of control "Organic peroxide" means an organic equipment which could result in an compound that contains the bivalent -O- uncontrolled release of hazardous O-strueture and which may be chemical Into the workplace. considered to be structural derivative "Hazardous chemical" means any of hydrogen peroxide where one or both chemical which is a physical hazard or a of the hydrogen atoms has been health hazard. replaced by an organic radical. "Hazard warning" meant any words, "Oxidizer" means a chemical other pictures, symbols, or combination then a blasting agent or explosive aa thereof appearing on a label or other defined in 11910.109(e). that initiates or appropriate form of warning which promotes combustion In other materials, convey the hazard(a) of the ehemical(s) thereby causing Tire either of itself or in the container)!). through the release of oxygen or other "Health hazard" means a chemical for gases. which there it italistlcally significant "Physical hazard" means a chemical evidence bated on at least one study for which there is scientifically valid conducted in accordance with evidence that it is e combustible liquid, established scientific principles (hat a compressed gas. explosive, flammable, acute or chronic health affects may an organic peroxide, an oxidizer, occur in exposed employees. The term pyrophoric, unstable (reactive) or water- "health hazard" includes chemicels ratetiva. which are carcinogens, toxic or highly "Produce" means to manufacture, inxic aaentt. reproductive toxins, rr.tanis. corrosives, sensitizer*, process, formulate, or repackage. "Pyrophoric" tnrans a chemical that hepstntoxint, nephrotoxint, will ignite eponteneously in air at a neuroioxins. agents which act on th temperature of 130 *F (M. *C) or below. hematopoietic system, and agenta which "Responsible party" meant someone damage the lungs, akin. eye*, or mucous who can provide additional information membranes. Appendix A provides further definitions and explanations of on the hazardous chemical and appropriate emergency procedures, if the scope of health hazards covered by necessary. this section, and Appendix B describes the criteria to be used to determine "Specific chemical identity" means the chemical name. Chemical Abstracts whether or not a chemical it to be considered hazardous foe purposes of this stsndard. "Identity" meins any chemical or common name which is indicated on the material safety data sheet (MSDS) for the chemical. The identity used shat) permit cross-references tdbe made among the required list of hazardous chemicals, the label and the MSDS. "Immtdlatf use" mean* that the hazardous chamieal will ba under tht Service (CAS) Registry Number, or any other information that reveals the prtcite chemical designation of the substance. "Trade secret* mesne any confidential formula, pattern, process, device, information or compilation of information that it used in an employer's business, end that gives the employer an opportunity to obtain an advantage over competitors who do not know or use It. Appendix D eels out the criteria to be used in evaluating trade accrete. "Unstable (reactive)" meins a chemical which in the pure state, or as produced or transported, will vigorously polymerize, decompose, condense, or will become self-reactive under conditions of shockt. pressure or temperature. "Use" means to package, handle, react, or transfer. "Wnler-rescllie" means a chemical (hut reacts with water to release u gas that is either flammable or presents a health hazard. "Work area" means a room or defined spare in workplace where htzardous chemicals arc produced or used, and where employees sre present. "Workplace" means an establishment, job site, or project, at one geographical location containing one or more work areas. (d) Hazard determination. (1) Chemical manufacturers end importers shall evaluate chemicals produced in their workplaces or imported by them to determine if they ere hazerdous. Employers are not required to evaluate chemicels unless they choose not to rely on the evsluetion performed by the chemical manufacturer or importer for the chemical to satisfy this requirement (2) Chemical manufacturers, importers or employers evaluating chemicals shall identify end consider the available scientific evidence concerning such hazards. For health hazards, evidence which is statistically significant and which is based on at least one positive study conducted in accordance with established scientific principles is considered to be sufficient to establish n hazardous effect if the results of the study meet the definitions of health hazards in this section. Appendix A shell be consulted for the scope of health hazards covered, and Appendix B shall be consulted for the criteria to be followed with respect tolhe completeness of the evaluation, and the date to be reported. (3) The chemical manufacturer, importer or employer evaluating chemicals shall treat the following sources at establishing that the chemicels listed in them ere hazardous: (i) 29 CFR Pari 1910. Subpart Z. Toxic and Hazardnut Substances. Occupational Safety end Health Administration (OSHA): or. (ii) Threshold Limit Values lor Chemical Substances and Physical Agents in the Work Environment. American Conference ol Governmental Industrial Hygienists (ACCIH) (latest edition). 75 DE 008460 31880 Federal Register / Vol. 52. No. 163 / Monday. Aogual 24. 1887 / Rule* and Regulation! The chcmicet manufacturer, importer, or a health hazard to employees in those (Iii) The methods the employer will employer U rtill responsible tor concentrations, the mixture shall be use to inform the other emplovtr(s) of evaluating the haxarda aisodated with assumed to present tht same hazard. the labeling tysiern used in the the chemical* In the** source li*ti In (S) Chemical manufacturers, workplace. accordance with the requirements of importer*, or employer* evaluating (3) The employer mey rely on an thl* ttandard. chemicals shall describe in writing the existing hazard communication program (4) Chemical manufacturera. Importers procedures they use to determine the to comply with thest requirements, and employers evaluating chemical* hazard* of the chemical they evaluate. provided that it meets the criteria (hall treat tha following sources a* The written procedures are to be made established in this paragraph (ej. establishing that a chemical is a available, upon request to employees, (4) The employer ihaU make the carcinogen or potential carcinogen for their designated representatives, the written hazard communication propram hazard communication purposes: Assistant Secretary and the Director. available, upon request, to employees, 01 National Toxicology Frogram Tht written description may be their designated representatives, the (NTP). Annual Report on Carcinogens Incorporated into the written hazard Assistant Saaatary and tht Director, in (latest edition): communication program required under accordance with the requirements of 29 (ii) International Agency for Research paragraph (e) of this section. CFR 191020(a). on Cancer (IARC) Monographs (latest (e) Written hazard communication (f) Labels and etherforms of warning. editions): or program. (1) Employers shall devslop, (1) The chemicil manufacturer. importer, (iii) 29 CFR Part 1910. Subpart Z. implement, and maintain at tha or distributor shall ensure that each Toxic and Hazardous Substance*. workplace. a written hazard container of hatsrdoua chemicals Occupational Safety and Health communication program for their leaving tha workplace Is labeled, legged Administration. workplaces which at least describes or marked with the following Not*.--'The Itefitny of Toxic Effects of Chemical Substances published by tha National Instinit* for Occupational Safety how the criteria specified In paragraph* (t). (gk and (h) of this section for labels and other forms of warning, matarial Information: (1) Identity of the hazardous chsmlcatfs): and Health indicate* whether a chemical has been lound by NTP or IARC to be a potential carcinogen. safety data sheet*, and employe# information snd training will be mst and which also includes the following: (ii) Appropriate hazard warnings: and (Iii) Name and addrtss of the chemical msnufseturer. imporltr. or other (5) The chemical manufacturer, (i) A list of (he htxardous chemicals responsible party. importer or employer shall determine known to be present using an idantity (2) For solid metal (such *s s steel the hazards of mixtures of chemicals as that is referenced on the appropriate beam or a metal casting) that is not follows: material safety data sheet (the list may exempted at an article dot to its ft) li a mixture has been tested as a be compiled for the workplace as a downstream utt. tha required label may whole to determine Its hazards, the whole or for individual work areas); be transmitted to the customer tt the results of such testing shall be used to and. time of the lntial shipment and need not determine whether the mixture is (ii) The methods the employer will us* be included with subsequent shipments hazardous; to inform employee* of the hazards of to the tame employer unless the (ii) If a mixture has not been tested as non-routine tasks (for exsrapl*. ihe information on the label changes. The a whole to determine whether the cleaning of reactor vessels), and tha Itbel may be transmitted with the initial mixture it a health hazard, the mixture hazards associated with chemicals shipment itself, or with the material shall be assumed to present the same contained in unlabeled pipes in their safety data sheet that Is to be provided health hazards at do the components work areas. prior to or at the time of the first which comprise one percent (by weight (2| Multi-employer workplaces. shipmenL This exception to requiring or volume) or greater of the mixture, Employers who produce, us*, or store libels on every container of hazardous except that the mixlute shall be hazardous chemicals at a workplace in chemicals Is only for the solid metsl assumed lo present s carcinogenic such a way that the employees of other itself and does not apply to hazardous hazard if it contains s component In mployer(s| msy bt exposed (for chemicals used In conjunction with, or concentrations of 0.1 percent or greater example, employees of a construction known to be prtsent with, the metal and which it considered to be a carcinogen contractor working on-site) shall to which employees handling the metsl under paragraph (d)(4) of this section: additionally ensure that (he hazard msy be exposed (for example, cutting (iii) If a mixture ha* not been tested a* communication programs developed and fluids or lubricants). a whole to determine whether the implemented under this paragraph (e) (3) Chemical manufacturers. mixture is a physical hazard, the Include tht following: Importers, or distributors shall ensure chemical manufacturer, importer, or (i) The methods the employer will uss that each container of hazardous employer may use whatever to provide the other employerfs) with a chemicsti leaving the workplace It scientifically valid data it available to copy of the materiel safety data sheet labeled, tagged, or marked in evaluate the physical hazard potential or to make ft available at a central accordance with this section in a of the mixture: and. location in the workplace, for each manner which does not conflict with the (iv) If the chemical manufacturer, haxardou* chemical the other requirements of the Hazardous importer, or employer hat evidence to employer(t)' employees msy bt exposed Miteritls Transportation Act (49 U.S C. indicate that a component present in the to while working: 1601 et set}.) and regulstion* issued mixture in concentrations of less than one percent (or in the cate of (ii) The methods the employer will utt under that Act by the Department of to inform tht other employer!t) of any Transportation. carcinogens, less than 0.1 percent) could precautionary measures that netd to be (4) If the hazardous chemical It be released in concentrations which taken to protect employees during the regulated by OSHA in a subtlanee- would exeeed an established OSHA workplace's normal operating tpeciflc health standard the chemical permissible exposure limit or ACCIH conditions and In fortsttsblt manufacturer. Importer, distributor or Threshold Limit Value, or could present emergencies: and. employer shall snsur* that the label* or 76 pE 008461 * Federal Register / Vol. 52. No- 163 / Monday. August 24. 1987 / Rule* nd Regulation! 31M1 other (etms of warning uaed are in accordance with the requirements of that standard. (5) Except as provided in para(raphe (f)(6) end (HI?) the employer ahall enturt that each container of hazardous chemieala in the workplace la labeled, taned or marked with the following information: (i) Identity of the hazardous chcmical(a) contained therein; and |ii) Appropriate hazard warnings. (6) Tne employer may use signs, placards, process sheets. batch tickets, operating procedures, or other such written meterieii In lieu of affixing label* to individual atnlionary process containers, a* long at the alternative method identifies the containers to which it is applicable and convey* the information required by paragraph (f)(5) of thia section to be on a label. The written materials shall be readily accessible to the employees In their work are* throughout each work ahift. (7) The employer it not required to label porteble container* into which hazardous chemicals art transferred from labeled containers, and which art intended only for the immediate uae of the employee who perform* the transfer. (81 The employer thall not remove or deface existing labels on Incoming container* of hazardous chemicals, unless the container is immediately marked with the required information. (9) The employer shall ensure that labels or other form* of warning are legible, in English, and prominently displayed on the container, or readily available in the work area throughout each work ehift. Employer* having employees who tpeik other language* may add the information in their language to the material presented, ae long a* the information It presented In Entlish as well. (in) The chemical manufacturer, importer, distributor or employer need not affix new libels to comply with this section if existing labels already convey the required information. (g) Materiel tnfety dgta theels. (1) Chemical manufacturers and importers shall obtain or. develop a material safety data sheet for each hazardous chemiea! they product or import Employers ahall have o material safety data sheet for esch hazardous chemical which they use. (Z) Each material safety data ahett shall be in English and snail contain at least the following information: (i) Tht identity used on the label, and. except a* provided for tig paragraph (i) of this taction on tradt secrets: (A) If tht hazardous chemiea) is a single substance, it* chemical and common namt(e): (B) If the hazardous chemical Is a mixture which has been tested ae a whole to determine it* hezarda. the chemical and common nsme(s) of the ingredients which contribute to thee* known hazard*, and the common name(s) of the mixture itself: or. (C) If the hazardous chemical 1* a mixture which has not been tested a* a xvholr (/) The chemical and common name(s) of all ingredients which have been determined to be health hazard*, and which comprise ID or greater of the composition, except that chemical* identified e* carcinogen* under paragraph (d)(4) of this atetion shall bo listed if tht concentrations are 0.1% or greater: and. (2) The chemical and common name(t) of all ingredients which hove been determined to be health hazard*, and which comprise lea* than 1% (0.1% for carcinogens) of the mixture. If there ia evidence that the ingreditnt(a) could be released from the mixture In concentrations which would exceed an established OSHA permissible exposure limit or ACGIH Threshold Limit Value, or could present a health hazard to empioyeei: end. (3) The chemical and common name(t) of all ingredient* which have been determined to present a physical hazard when present in the mixture: (ii) Physical and chemical characteristics of the hezerdout chemical (auch at vapor pressure, flash pointy. (iii) The physical hazard* of the hazardous chemical, including the potential for fire, explosion, and reactivity: (iv) The health hazards of the hazardous chemical, including signs and aymptoma of exposure, and any medical conditions which are generally recoonized as being aggravated by exposure to the chemical: (v) The primery toutc(a) of entry. (vl) The OSHA permissible exposure limit ACC1H Threshold Umil Value, and any other exposure limit used or recommended by the chemical manufacturer, importer, or employer preparing the meterial aalety data sheet, where available: (vii) Whether the htzirdoua chemical it listed In the National Toxicology Program (NTP) Annual Report on Coremogent (latest edition) or hee been found to be a potential carcinogen In the International Agency for Research on Cancer (1ARC) Monographs (laical editions), or by 05HA; (vlii) Any generally applicable precaution* for safe handling and use which art known to tht chtmica) manufacturer, importer or employer preparing the material safely data sheet, including appropriate hygienic practices, protective measures during repair and maintenance of contaminated equipment, and procedures for clean-up of spills and teaks: (ix) Any generally applicable control measure* which ere known to the chemical manufacturer, importer or employer preparing the materiel safety date sheet, such at appropriate engineering controls, work practices, or personal protective equipment: (x) Emergency and first aid procedures: (xi) The dale of preparation of the material safety data sheet or the last change to it and. (xii) The name, address end telephone number of the chemical manufacturer, importer, employer or other responsible party preparing or distributing the material safety date sheet who can rovide additional information on the azardou* chemical and appropriate emergency procedures, ii necessary. (3) If not relevant information is found for any given category on the material safety data iheet the chemical manufacturer, importer or employer preparing the meterial safety data sheet thill mark it to indicate that no applicable Information was found. (4) Where complex mixtures have similar hazards and contents (i e. (he chemical ingredients are essrniially the same, but the specific composition varies from mixture to mixture), the chemical manufacturer, importer or employer may prepare one material safety data ahett to apply to all of these similar mixtures. (5) The chemical manufacturer, importer or employer preparing the material safety date sheet shall ensure that the information recorded accurately reflects the scientific evidence used in making the hazard determinatum I: the chemical manufacturer, imoc-rter or employer preparing the material suleii data sheet becomes nefcly aware oi any significant information regarding the hazard* of a chemical, or ways to protect against the hazards, this new information shall be added to the material safety data sheet within three monlhi. U the chemical ia not currently being produced or imported the chemical manufacturer or importer shatl add the information to the material sslety data sheet before the chemical is Introduced Into the workplace again. (6) Chemical manufacturers or importer* shell ensure that distributors and employers are provided an appropriate material safety data sheet with thtir Inlitial shipment, snd with the first shipment afttt a material safety 77 DE 008462 31082 Federal Register / Vol. 52. No- 163 / Monday, August 24. 1987 / Rules and Regulations data sheet Is updated. The chemical manufacturer or importer thall either provide material aafety data sheets with lha shipped containers or send them to the employer prior lo or at the time of the shipment If the material aafety data sheet la not provided with a shipment that has been labeled as a hazardous chemicaL the employer ahell obtain one from the chemical manufacturer, importer, or distributor as soon as possible. (7) Distributors shall ensure that material aafety data sheets, and updated information, are provided to other distributors and employers. Retail distributors which sell hazardous chemicals to commercial customers shall provide a material aafety data sheet to such employers upon request, and shall post a sign or otherwise inform them that a material safety data sheet is available. Chemical manufacturers, importers, and distributors need not provide materiat aafety data sheets to retail distributors which have informed them that the retail distributor does not sell the product to commercial customers or open the sealed container to use it in their own workplaces. (8) The employer shall maintain copies of the required material aafety data sheets for each hazardous chemical in the workplace, and shall ensure that they are readily accessible during each uoik shift to employees when they are in their work area(a). (9) Where employees must travel between workplaces during a workshift, /.r.. their work Is carried out at more than one geographical location, the material safety data sheets may be kept at a central location at the primary workplace facility. In this situation, the employer shall ensure that employees can immediately obtain the required information in an emergency. (10) Material aafety data sheets may be kept in any form, including operating procedures, and may be designed to cover groups of hazardous chemicals in a work area where it may be more appropriate to address the hazards of a process rather than individual hazardous chemicals. However, the employer shall ensure that in all cases the required information is provided for each hazardous chemical, and is readily accessible during each work shift to employees when they are in In their work areas(s). til) Material safety data sheets shall also be made readily available, upon request, to designated representatives and to the Assistant secretary. In accordance with the requirements of 29 CFR 1910.20 (e). The Director ahull slao be given aceest to malarial aafety data aheeta in the same manner. fh> Employee information and training. Employers shall provide employees with Information and training on hazardous chemicsls in their work area at the time of their initial assignment, and whenever a new hazard la introduced into their work area. (1) Information. Employees shall be informed of: (1) The requirements of this section: Hi) Any operations in their work ares voere hazardous chemicals are present: and. (iii) The location and availability of the written hazard communication program, including the required list(s) of hazardous chemicals, and material safaty data sheets required by this section. (2) Training. Employee training shall include at least: (i) Methods and observations that may be used to detect the presence or release of a hazardous chemical in the work area (such as monitoring conducted by the employer, continuous monitoring devices, visual appearance or odor of hazardous chemicals when being released, etc.): fii) The physical and health hazards of the chemicals in the work area: (iii) The meaturet employees can taka to protect themselves from these hazards, including specific procedures the amployer hat implemented to rotect employees from exposure to azardoua chemicals, such as appropriate work practices, emergency procedures, and personal protective equipment to be used: and. (iv) The details of the hazard communication program developed by the employer, including an explanation of the labeling system and the material safely data sheet, and how employees can obtain and use the appropriate hazard information. (i) Trade tecrets. (1) The chemical manufacturer, importer, or employer may withhold the specific chemical Identity, including the chemical name and other specific identification of a hazardous chemical, from the material aafety data sheet, provided that: fi) The claim that the information withheld la a trade secret can ba supported: (ii) Information contained in the material aafety data sheet concerning the properties and effects of the hazardous chemical is disclosed: (iii) The material aafety data sheet indicates that the specific chemical identity is being withheld as a trade secret: and. (iv) Tht specific chemical identity Is made available to health professionals, employees, and designated representatives in accordance with the applicable provisions of this paragraph. (2) Where a treating physician or nurse determines that a medical emergency exists and tht specific chemical identity of a hazardous chemical I* necessary for emergency or first-aid treatment, the chemical manufacturer, importer, or employ er shall immediately disclose the specific chemical identity of a trade secret chemical to that treating physician or nurse, regardless of the existence of a written statement of need of a confidentiality agreement. The chemical manufacturer, importer, or employer may require a written statement of need ana confidentiality agreement, in accordance with the provisions of paragraphs (i)(3) and (4) of this section, as soon as circumstances permit. (3) In non-emetgency situations, a chemical manufacturer. Importer, or employer shall upon fequeat. disclose a specific chemical identity, otherwise permitted to be withheld under paragraph (f)(1) of this section, lo a health professional (i.a. physician, industrial hygienist, toxicologist, epidemiologist, or occupational health nurse) providing medical or other occupational haaltb services to exposed amployee(s). and to employees or designated representatives, if: (I) The request la in writing: (ii) The request describes with reasonable detail one or more of the following occupational health needs for the information: (A) To attest the hazards of the chemicals to which employees will be exposed: (B) To conduct or assess sampling of the workplace atmosphere to determine employee exposure levels; (C) To conduct pre-assignment or periodic medical surveillance of exposed employees: (D) To provide medical treatment to exposed employees:' (E) To select or attest appropriate personal protective equipment lor exposed employeet: (F) To design or assess engineering controls or other protective measures for exposed employees: and. (C)To conduct studies to determine the health effects of exposure. (iii) The request explains in detail why the disclosure of the specific chemical Identity la essential and that, in lieu thereof, the disclosure of the following information to the health professional, employee, or designated representative, would not satisfy the purposes described in paragraph (i)(3)(ii) of this section: 78 DE 008463 * Federal Rcgistet / Vo!. 52. No. 163 / Monday. August 24. 1987 / Rules and Regulations 31803 (A) The pfoparttet and effect* of the chemical; (B) Meaiurt* for controlllni workers' exposure to the chemleak (C) Methods of monitoring and analyzing worker exposure to tha chemical: and. (0) Method* of diagnosing and treating harmful exposure* to the chemical: (is)The request includes a description of the procedures to be used to maintain the confidentiality of th* disclosed information: and. (v) The health professional and th* employer or contractor of tha services of the health professional (i.a. downstream employer, labor organization, or individual employee), employee, or designated representative, agree in a written confidentiality agreement that the health professional, employee, or designated representative, will not aaa the trade secret information for any purpose other than the health need(s) tsserted and agree not to release die information under any circumstances other thsn to OSHA. a* provided in paragraph (1)18) of this section, except as authorized by the terms of the agreement or by the chemical manufacturer. Importer, or employer. (41 The confidentiality agreement authorized by paragraph (i)(3M<v) of this section: (1) May restrict the use of th* information to the health purpose* indicated in the written statement of need: (ii) May proride for appropriate legal remedies in the event of e breach of the agreement. including stipulation of a reasonable pre-estimate of likely damages: and. (iii) Mny not Include requirements for the posting of a penalty bond. (S) Nothing in this standard la meant to preclude the parties from pursuing non-contractusl remedies to tha extent permitted by iaw. (C) H the health professional, employee, or designated representative receiving the trade secret information decides that there is a need to disclose tt to OSHA, the'chemical manufacturer, importer, or employer who provided th* information ahatl be informed by lira health professional, employee, or designated representative prior to. or at the same time ss. such disclosure. (7) If the chemical manufacturer, importer, or employer denies s written request for disclosure of a specific chemical Identity, the denial must: (i) Be provided to thewealth professional employee, or designated representative, within thirty days of Ihs request: |ii) Be in writing: (iii) Include evidence to anpoort th* claim that the specific chemical Identity is a trade serret: (iv) State the specific reasons why th* request is being denied: and. (v) Explain in detail how alternative Information may tatitfy the specific medical or occupational health need w-itliout revealing the specific chemical identity. (8) The health professional employe*, or designated representative whoa* request for information is denied under paragraph (l|(3) nf this section may refer the request and the written denial of tha request to OSHA for consideration. (9) When e health professional employe*, or designated representative refer* the denial to OSHA under paragraph (i)|8) of this section. OSILA shall consider the evidence to determine if: (i) The chemicel manufacturer. Importer, or employer has supported the claim that th* specific chemical identity la a trade secret: (ii) The health professional employee, or designated representKtive hat supported the claim that there it a medical or occupational health need for the information: and. (iii) The health professional, employee, or designated representative ha* demonstrated adequate meen* to protect the confidentiality. (10) (iJ If OSHA determines that the specific chemical identity requested under paragraph (i)[3) of this section is not a bona fide trad* secret or that it it a trade secret but the requesting health professional, employee, or designated representative hat a legitimate medical or occupational health need for the information, hot executed a written confidentiality agreement and has shown adequate meant to protect the confidentiality of the information, th* chemical manufacturer. Importer, or employer will be subject to citation by OSHA. (11) If a chemical manufacturer, importer, or employer demonstrates to OSHA that the execution of a confidentiality agreement would not provide sufficient protection against th* potential harm from the unauthorized disclosure of a trade secret specific chemical identity, the Assistant Secretary may issue such order* or impose such eddltionsl limitations or conditions upon the disclosure of the requested chemical information as may be appropriate to assure thst the occupations) health services are provided without an undue risk of harm to the chemicel manuleeturtr. importer, or employer. (11] If a citation for a failure to releese specific chemical identity information is contested by the chemical manufacturer, importer, or employer, the matter wi*l he adjudicated before the Occupational Safety and Health Review Commission in accordance with the Act's enforcement scheme and the applicable Commission rules of procedure. In accordance with the Commission rules, when a chemical manufacturer, importer, or employer continues to withhold the information during the contest, the Administrate c law Judge may review th* citation and supporting documentation in cemcro or issue appropriate orders to protect the confidentiality or such matters. (121 Notwithstanding the existence of a trade secret claim, a chemical manufacturer, importer, or employer shell, upon request, disclose to the Assistnnl Secretary any information which this section requires the chemical manufucturcr. importer, or employer to make available. Where there is a trade Secret claim, suck claim shall be made, no later thsn *t the time the inlurmstion is provided to the Assistant Secretary so that suitable determinations of trade secret status can be made end the necessary protections can be implemented. 113) Nothing In this paragraph shall be construed a* requiring the disclosure under any circumstances of process or percentage of mixture information which is a trade secret (j) Effective dotes. |1) Chemical manufacturers, importer*, and distributors shall ensure thst material safety data sheets are provided vvith the next shipment of hazardous chemicals to employers after September 23.19C7. (2) Employers in the nonmanufacturing sector shall be in compliance with all provisions of Ihis section by May 23.1988 (Note: Employers in the manufacturing sector (SIC Codes 2C through 39) are already required to be in compliance with this section.) Appendix A Is i -- Itxaltb llstsrd Definitions (.Uundowry) Although tsfriy hazards related to ihr physiol characteristics (I chemical cn he objectively defined in terms of letling requirements (e g. (lsmms biliiy I. health hazard definitions are leit precise and mure subjective. Health hststds may oust measurable changes in the buoy--such as decreaitd pulmonary function These changes are generally Indicated by the occurrence of signs and symptoms in th* exposed employees--such as shortness of brveth. a non-measurable. lubtrctiv* feeling Employees exposed to such heterdt must be apprised of both the change in body function and the eignt end symptoms thi may oerur to signal that change 79 DE 008464 318M Ftdtral Re|ftlg / Vol. 52. No. 1B3 / Monday. August 24. 1987 / Rule* snd Regulations The determination of occupation*) heatth hazards is complicated by the fact that many el the elfeeti of aipia and symptom* occur commonly in non-oceupationally txpoaad populations. to that alfteti of axpoaur* art difficult to teparatt trim normally oconrinf llinetitt. Occationally. a tubtlanea canat an affect that la rarely tttn bi Iht population at large. tuch at angioaarcemai eauttd by vinyl chloride exposure. tbua making H aaaiae to aacertain that the occupational expotura vu the primary ctutalive factor. More often, however, the effect! are common, tuck aa hint cancer. The tituetion it further complicated by the fact that moat chemicalt have not been adequately letted to determine their health haurd potential, and data do not axial to eubetantiata theta affects. There have been many allampta to categorize effeett and to daftne them in varioue ijr. Gtnarally. the terma ''acuta" and "chronic" art uird to delineate between aflacta on the baaia of eeverity or deration. "Acute" effeett utually occur rapidly aa a reiult of rhort-tetm expoaum. and art of thort duration. "Chronic" affacta generally occur at a rttult oflong-term axpoaur*. and are of long duration. The acute effeett referred to moet frequently art Ihotc defined by the American National Standardi Inetltuta (ANSI) atandard for Precautionary Labeling of Hazardout lndualnat Chemical! (ZI2B.1-1M2)-- irritation, eorroiivity. aeneitieition end lethal doee. Although there are important health effect*, they do not adequately cover the considerable range of acute tffecta which may occur aa a rtfult of occupational exposure. tuch aa. for example, narcotia. Similarly, the term chronic aflect la often uied to cover only carcinngenlcity, teratogenicity, and mutagenicity. There elfecta art ebvioutly a concern in the workplace, but again, do not adaquateiy cover the arte of chiontc tffecta. excluding, for example, blood dytertaita (tuch at anemia), chronic bronchilit and liver atrophy. The goal of defining precisely. in measurable termt. every possible health effect that may occur In the workpiece aa a rttult of chemical expeaurta cannot realniically be accomplithrd. Thli doee not negate the need lor emplnyeet to be informed of tuch effeett and protected from them. Appendix B. which it alao mandatory, outlines the principle! and procedural of hazardous aiimmvnt. Ter puno"i of th:e eectien. any chamieala which rei any of the following definitions, at determined by the criteria act forth in Appendix B are health haurdc 1. Carcinogen A chemical ia contidared to be a carcinogen if: la) It h been evaluated by Iht International Agency fnr Reatarch on Cancer (IARC). and found to be t carcinogen or poirntiel cercinogen: or (h) It la titled it a carcinogen or potential carcinogen In the Annual Report an Carcinogen publiahcd by the National Toxicology Program (NTP1 (fetrat edition), oe. (c) It it regulated by OSHA aa a carcinogen. Z. Corrosive- A chemical that cauata viaiblt dattruetion of. or irreveraiblt alteration! In. living tiaiuc by chemical action at tht alia of contact For example, a chemical it eonaldered to be conotive if. when letted on the intact thin ef albino rabbit! by the method detcribcd by the U.S. Department of Tranaportation in Appendix A to *4 CFR Pert 171, It dcitroyi or ehengea trreveratbly the ttructurt of the ttaiue at the aite of contact following an txpoturt period of four boors. Tbit term shall not refer to iction on inanimate surfaces. 1. Highly toxic: A chemical falling wtthtn any of the following categories: (a) A chemical that hat a median lathal dote (LDwl of SO milligrama or laaa per kilogram of body weight whan administered orally to albino rata weighing between 300 and MO grama each. fb) A chemical that haa a median lathal dost (LDm) of 300 milligrama or lata per kilogram ef body weight when administered by continuous contact for 14 hour* (or lata if death oecutu within 24 hours) with the bate akin of albino rabbits weighing batwaen two and three kilograms each. (c) A chemical that hat a median lethal concentration (LCw) in air of 200 parts per million by volume or lets ef gat or vapor, or 2 milligrama par liter- eat of mitt. fume, or dust, whan admin, red by continuous inhalation for one hour (or lata U death occurs within oni hour) to albino rata weighing between 200 and MO grama each. A Irritant.- A chemical which ia not eonotivt. but which cauata a reversible inflammatory affect on living bnut by chtmleal action at the tile of contact A chemical ia a akin irritant t(. whan tatted on the intact akin of albino rubbitt by the melhoda of IS CFR 1300.41 for four hours axpoaur* or by other appropriate ttchnlqutt. it reiulla In an empirical tcort of five or more. A chemical it an tyt irritant if aa dtttnnined under the procedure Hated in 16 CFR 1100.42 or other appropriate tachnlquti. S. Seruitiier. A chemical that cauata a substantial proportion el txpottd people or animalt to develop an allergic reaction fai normal tlaiue after repeated ixposurt to the chemical. B. Toxic A chemical falling within any of the following categoriet: (a) A chemical that hat a median lethal doit (LDm) of more than 50 milligrams par kilogram bin not more than 500 milligram! per kilogram of body weight when adminlitered orally to albino rx'.x weighing between 200 end 300 grame each. (b| A chemical that hae a median lethal dott (LDm) ef mor* than 200 milligrama par kilogram but not more .then 1.000 milligram! per kilogram of body w*ight whan administered by continuous contact for 24 hours (or lata If death occurs within 24 hours) with the bars akin of albino rabbits waighing between two and three kilograms tech. (c) A ehemiecl that hat a median lethal concentration (LCu) In air of mort than 200 parti per million but not mort than 2.000 pant per million by volume ol gaa or vapor, or mort than two milligrama per liter but not mor* than 20 milli|ramt par liter of mlat. fume, oe dual when administered by continuous Inhalation foe ent hour (or lr if death occurs within one hour) to albino rati weighing between 200 end 500 grsma each 7. Target oifon effeett. The following it a target organ categorization of tffccte which may occur, including ezampiei of signs and symptoma and chamieala which hait been found to can* such tflecta. These example! art presented to llluatntt the range and diversity of affrcla and hatanii found tn the workplace, and the broad icope emptoyen must consider in this area, but are not Intended to ba aH-industvt. a. Hepatotexins: Chamieala which product liver damage Signs t Symptoms: Jaundice: liver enlargement Ovexocalr Carbon tetrachloride: nitroaaminea b. Nephrotoxinr Chemicals which product kidney damagt Signs 6 Symptoms: Edema: proteinuria Chemicali: Halogcnalcd hydrocarbons: uranium e. Neurotozma: Chemicali which produce their primary toxic afltcii on the nervoua eyattia Signs 6 Symptoms: Narcosis: behavioral changes: decrease in motor functions Chemicali: Mercury: carbon disulfide d. Agtnu which act on tht blood or hematopoietic tynem: Decrease hemoglobin function: deprive the body tittuei ef oxygen Signs 6 Symptoma: Cyanosis: iota of consdouantaa Chemicals: Carbon monoxide: cyenidet a. Agents which damage the lung' Chemicalt which trrilsta or damage the pulmonary Lisaue Signs S Symptoma: Cough: tighmeai in cheat: shortntii ef breath Chimicatr. Silica: asbtatot f. Reproductive loxini: Chemicali which affect tht reproductive capabilities Including chromosomal damage (mutations) and aflacta on (etuats (leritogeneile) Signs t Symptoma: Birth defect!: sterility Chemical!- Ltad: DBCP g. Cutaneous hixarda: Chemicals which aflact tha dermal layer of the body Signs 6 Svmptomt: Diluting ef tht skin: raahtt: Irritation Chamieala-. Kttonai: chlSnnated compound! b. Eye hazards: Chamieala which aflect the eye or vtiual capacity S-.gnt 6 Symptoma: Conjunctivitis comnil damage Chemicalt: Organic aolvants: acids Appendix I to |---------. Hazard Determination (Mandatory) The quality ef a hazard communication program la largely dependent upon the adequacy and accuracy ef the hazard determination. The hazard determination requirement of thia atandard la performanceoriented Chemical manufacturers, importers, and employer! evaluating chemicali are noi required to follow any specific method! for 80 DE 008465 Federal Refiner / Vol. 52. No. 163 / Monday. August 2<. 1867 / Rules end Regulation! 31885 determining hazard*. bat they must ba tbit to LARC Monographs an the Evaluation efthe Brftuooxanrte Car* Basts demonstrate lhal they have adequately Carcinogenic Risk ef Chemicals to Man ascertained the hazards of the chemicals Geneva: World Health Organization. Ibavi >nO fat m*m produced or imported in aeeordanc* with lb* criteria eel forth in thie Appendix. Haiard evaluation ia a precaaa which reliee heavily on the profeiilona) (tidgmeni of the evalualor. partlcularly in the area of chronic hatarda. The performance-orientation of the hazard determination done not dlmlniah the duty of the chemical manufacturer, importer or employer to conduct a thoroufh evaluation, examtnini all relevant data and producing a acientifically defensible evaluation. For purpoaee of thie etandard. the following criteria ahall ba wed In making Villard determination! that meat the requirement! of thin etandard. 1. Carcinogenicity. Aa deaerfbed in paragraph (d)(4) and Appendix A of tMa auction, a determination by the National Toxicology Program, the International Agency for gatearch on Cancer, ar OSHA that a chemical ia a carcinogen or potemit) International Agency for Reatirch on Cancer. 1*72-Preaent. (Multivoiume work). Summarita ere available in eupplement velumea. 41 Shtridan Street Albany. NY 12210. Industrie! Hygiene end Toxicology, byFA. Petty )ohn Wiley ft Sons. Inc. New York. NY (Multivoiume work). Clinical Toxicology of CommercialProducts Cletaon. Goiitlln. and Hodgt Casarttt and Doull's Toxicology: The Basie Science efPersons Doull. Klaaiaen. and Amdut. MtcmUlaa Publizhtng Co. Inc. New York. NY. Industrial Toxicology, by Alice Hamilton end Harriet L Hardy Publicising Sdcncta Group, tnc. Acton. MA. Toxicology ofthe Eye. by W. Morten Grant fttvuo amt Wa--a> a-- cm ihsj tiee hmi r. (jfm *r imi lc-- WMOO Wt Wki *, > li*-- s-wwa. Saw UM04 CA wpt KTf* MU**** J***# Scot* imwi uwki WCt u--e* Icmci mu * NWI mi Pwm t*a+ a/ *+%*bcu Nm ^r* Fm CA Wut* *aa% CAS Ugigra CancKEnnw 09*mm Cmmt fam Cmmava (AMMFng ItkMumf twefimw Inwm faamat Wbmuc* *a*aaa carcinogen aril) be eonafdered eondative Charlta C Thomaa. 3C1-J27 Earl Lawrenca IAb tcuci Cmactm evidence for purpoeei of thie taction. t Human dotm What* avallabla, epidemiological aludiet and eatt reporta of advene heellh effecte that! ba eontldtrad fat the evaluation. 5. Animal deitr. Human avidanet of health effteta in txpoaed populationt ia generally not available tor Die mefority of chemicals produced or ated In the woriplaca. Theretora. the available retulte of toxicological telling in animal populationt ahall be tied to predict tha health afiecti that may be experienced by expoted worker*. In particular, the definitions of certain aeata hatarda refer to ipeeinc animal tatting rttultt (ate Appendix A). 4. Adeeuacy end reporting ofdate. Tha reaulti of any aludiet which an designed and conducted according to tslabllahed adentitle principle*. and which report atatleticelly aignifreanl conduiiona regarding the health efiecta of a chemical ihtu be a auffldenl bttia for a haiard determination and Avenue. Springfield. 0. Recognition ofHealth Hatotds in Industry William A. Burgeaa. John Wiley end Sons. (05 Third Avenue. New York. NY 10151 ChemicalHotords ofthe Workplace Nick H. Procter and |amet P. Hughes. )J*. Liplncott Company. Winchtiter Terrace. New York. NY 10022. Handbook ofChemistry endPhysic* Chemical Rubber Company. 11001 Cranwood Parkway. CitvsUnd. OH 4412ft. Threshold Limit Valuer for Chemical Substances end PhysicalAgents in the Work Environment endBiological Exposure Indicts with Intended Changes American Conference of Governmental induitriel Hygitnieta |ACCIH).ft500 Cltnway Avenue. Bldg. D-ft. Cincinnati. OH 45211. Information on the phyelca! hatirdt of chemicals may be found in publications soc--o** toe i Imwc*. m ccmm* <hm, %am u*a CA IM0I 0Nnsnai uaray maivi mam am Hmm *jMc 0mam 1btib~^ aaaaamt Nmw haam. Pa NlUMOtMW imam Can. OW Ow* taap Ai, Himpl VA ftjwm. vc. ttts In Inc mw.. to til. 0C wow 0Oinqi Pfrmm O fctti 1rfiiv *00 AMMIl ii Uw tVML MW, tun 300. W>wfn. DC tOOQt MTU Occvnwow Stwty baaammOtm Pamt Oma CAt a*m am writ wawm Iawxw Oam wntMtO# MAnWi Tmam *n Oamam ATfCt Ctmam UwnwrMinrtMin DVAO taammm Snvrvt am inmtwhn %aa*m %**** ($A*tSi C 0ACaA* Imcaf mricb ipww Tm cunfi Cam mwei*Mucw Of am HAUiSoui yarnm Tchnc Aimim* Dm reported on any material tardy data sheet. of the National Fire Protection %mam The dtemictl manufacturer, importer, or employer may alio report the reaulta ot ether acientifically valid atudita which lend w refute the finding! of haiard. Association. Boston. MA. Note.--The following documents may be puTchaaed from the Superintendent of Document!. Uj Government Printing Office. CCA* ICflAAf OcBMtcnw mam t** |Ut nw tee No Oaa. St- HflawWn* mm*. Hi 9790 Appendix C It I-- information Sawrcoa Washington. DC 20102. (Adriaoty) OccupationalHealth Guidelines Appendix D Is I_____ DaCxUtoo of "Trade The following it a lilt of available data NIOSH/OSHA (NIOSH Pub. No. >1-123) teeter (Mandatory) | I aourcea whidt the chemical manulaetarer, importer, diatributor. or employer may with to coniult to evaluate the hezerdt of chemlcali they product or import: --Any information in their own company (ilea, tuch aa toxicity letting reaulta or (linen Kpentnct of company employeta. --Any information obtained from Ihe supplier of the chemical, auch aa material MOSH Pocket Cuide to Chemical Hatotds MOSH Pub. No. 65-114 Registry of Toxic Effects of Chemical Substances MOSH Pub. Ns. 10-102 Miscellaneous Documents published by the National Institute for Occupational Safety and Health: Criteria documents The following it a reprint of the Restatement of Tons section 751. comment b (Iftlft): b. Definition oftrade secret. A trede aacrtt mev conaiat of any formula, pattern, device or compilation of information which ic used in one's butineia. and w hich gtrta him an opportunity to obtain an advantage over atfeiy dale aheeti or product eafety builttina. Special Hazard Reviews competitors who do not know or use It It --Any pertinent information obtained from the following tource lift (leleet editions should be ated): Occupational Hazard Aasaaimems. Current Intelligence Bulletins. OSHA's Central Industry Standards tit CFR may be a formula tor a chemical compound, a prortas ef manufacturing, treating or preserving materials, a pattern fur a m.rhine Cundented Chemical Dictionary Pen mot or othtr device. or a list of customers it Via Noatrind Reinhold Ob., 135 Weal lOtk KTP Annual Report on Corcmogtnt and differs from other secret information in a Street. New York. NY 10C20 Summary ofthe Annual Report on business (ate 1751 of the Rtsiolemrni of The Merck Index: An Encyclopedia el Chtmicalt end Drugs Cartmoftent. National Technical Information Service Torts which la not included in this Appendix) In that It la not simply information at to Mttck and Company. Inc. 12* E. Lincoln Are. Rahway. K| Of065. (NT1S). 5285 Port Royal Road. Springfield. VA 22161: (103) 461-4050. single or ephemeral events in tha conduct of the buainats. as. for esamplc- the amount or 81 DE 008466 % 51688 Federal RegUtar / Vol. 82, No. 163 / Monday. August 24. 1907 / Rules and Regulations ether ttnni of eott bid far t contract at tht tilery of corlitn employee*. or the ttevrity investment* made or contemplated, or tht dttt fined for the announcement of o new policy or for brtnfiJH eot t new model or the like. A trade were! It procett or device for contlnaoui ate is the epimtJORt of the buainea*. Centrally It relttei to the productloo of good*. ei. for rumple, o machine or formula for the production of on article. It mty. however, relate to the tele of poedi or to other operation* to the bottom, tuch at t code for determining diteeanta. rebatet or other coneetalone In e price Hat or eatalotu*. or e Hat of apedatiaed cattomete. or t method of bookkeeping or other office management. Secrecy. The aubfcel matter of a trade aecret moat be secret. Matter* of public knowledge or of central knowledge In an htdiatry cannot be tpproprleted by one ae hit ttael. Matter* which art completely diaeloted by the pood* which one market* cannot be hit etcret SobataaHatty, e trad* aecret I* known only in the pertieuler buiineea in which It It Mod. h I# not requisite that only the proprietor of the butincte know It. He may. without loeinp hli protection, communicate It to employee* involvud bi It* ute. He may likewiat exatmmieale It to other* pltdped to etcrecy. Other* may ala* knew of It independently, as. for example, when they hart discovered the proceti or lormul* by Independent Invention and era keepinp it item. Ntvtrlhtlett. eobttenUal elemenl of atcrecy mutt exist. to that, except by the sir of improper meant, there would bo dilfieulty In acquiring the Information. An exact definition of e tredt aecret la not poaiiblt. Some factor* to bo considered in drtemtininp whether pivtn iafeemttion It one* tredt aecret arr |I| The extent to which tht Information fa known ootald* of hit bflilneat: (21 tht extent ae which H it known by employee* and elher* Involved In bit buiineta: (3) the extent of awaturet taken by him to puard the ircrrcy of the information; (4) the value of the information to him and bit competitor*: (5) tht amount of oftort or money expendtd by him in devetoptnp the information: ft) the taat or difficulty with which the Information could be propetly acquired or duplicated by other*. Afora/ly andprior on A trade aecret mty be a device or proceti which la patentable: but it need not be that. It may bt a device or proceti which i* cltotly anticipated in the prior trt or one which la merely a mechanical improvement that a pood mechanic cat. make. Novelty end invention art not rtquiaHt foe a trade itcret at they ere for patentability. Thtit requirement* art eaatntlil to patentability bteauat a patent protect* apainat unlicensed sai of tha patented device or proceti evtn by on* who diacover* tt properly throuph independent research. The patent monopoly it a reward to the Invostor. But tuch It not the cate with * trade start, ft* protection U not bated on * policy of rewardinp or otherwii* eneeurepinp the development of eectet prooftae* or device*. The protection ! merely tptlntt breach of faith and icprthenalble meant of learning another'a aecret. For tbit limited protection K it not ipproptiate to requite alto the kind of novelty end InvenHon which ia a ruquiaita of patentability. The nature of tht aecret it, however, an important factor in determining the kind of relief Dial la appropriate apalnet on* who la tabled to liability under the rule turd in thlt etclion. Thu*. U the aecret coniiate of e device or procei* which li t novel invention, on* wns acquiree the tecret wrongfully it ordlntrily en|oined from further u*t of it end i* required to account for the profit* derived from hit peat oat. li. on the other hind, the aecret conilata of mrohanical improvement* that a pood mechanic can nuke wilhoul rttort to the eecrct. the wronpdoer'i liability mey be limited to demepti. end an injunction eptmit future uee of the improvement! medt with the aid of the ttertt mty bt inappropriate. I. Section 1915.97 would be reviled io read *e follow*; f 1911.97 Health and aentunorv. The provielona of this eeetion shell apply to ahip repairing, shipbuilding end thipbreaking. except where indicated otherwiie. (a) The employer ehall provide all necetttiy control*, and the employee* thill be prelected by suitable personal protective equipment against tha hazards identified under 11915.99 of this part and those hazard* for which specific precaution! are required in Subparta B. C. and D of this part. (b) The employer ehall provide adequete washing facilities for employee* engaged in the application of paints or coating* or In other operations where contaminant* can. by (ngeation or absorption, be detrimental to the health of (he employees. The employer shill encourage good peraontl hygiene practice* by Informing the employee* of the need tor removing surface contaminant* by thorough washing or hand* and faee prior to eating or amoking. (c) The employer ehall not permit employees to eit or imoke in area* undergoing surface preparation or preservation or where shipbreaking operation* product atmospheric contaminant*. (d) The employer ehall not permit employees engaged In ship repair work on a vessel to work in the immediate vieinity of uncovered garbage and shall ensure that employees working beneath or on the outboard side of a vessel are not aubjeet to contamination by drainage or waste from overboard discharges. (e) No minor under 18 yean or age thill be employed in shipbreaking or related employment!. (. Section 1928.21 would be emended by adding paragraph (e)(5) a* follow*: 11*29.71 AppUeaM* standard* In 29 CFR Part 1910. (a)*** (5) Hazard communication-- 1 1910.1200. |Fit Doc. 17-19137 Filed 0-1M7; l:i am) ftujMO coot atia-at-w I 82 DE 008467 Glossary Absorption The protest by which substance can be readily taken into the hdy. lor example. some chemicals cu be sbaotbed through unbroken skin. Arid A fundamental eategory of cbemiceli characterized by having available motive hydrogen end requiring in itksK to neutrsfitt (hen. Acids tain bum* paper ted tod have pH values of 0 to 6. They truy catne tevere borne Acute Effect - Advene effect which has severe lymptotni developing ripidly end commg quickly to < crisis. Compete "Chronic EflecT. Acute Totidty - Acute effects raahtng from t single doee ofor exposure toi substance. OrdinitSy ined to denote effect* in experiment^ teimeb ACGIH American Conference of Governmetrtel Industrial Hygienist* in negsmtaiiou of professional penonnel m governmentef sgenda or educational mttitMioM who ere employed in occupational safety end hertb program Adenoeerclnoine A tumor originating in e (lend. Adenoeit Any dime of e fiend. Adhetian - A anion of two turfices tbet ere normelly separate. ActomI A fine ipny of pnrtidet sufficiently smell it ne to resist settlinf or tednnencstion (for cumpie; smoke or liogh Air Line Respirator A reapititor that is connected to e compressed bresthinj in source by e base. The err a delivered continuously as intermittently in e sufficient volume to meet the wesrer'i breetbinf requirements. Air A respiretor that uses ehemkah to remove specific petes snd vapors from the air er that toes a mechenicsl fiber to lemeve pnrtiniUtc mallet. An air purifying rtspintcr must only be used when there a sufficient otygen to sustain life and the air contaminant led is below the concentration limrn of the device. Altai - A substance capable of combining with hydropen ions. They are alio called bases, and may cause severe buns to the skin. Akata turn bunts paper blue and have pH values from f to 14. ARerfic Reaction . An abnormal phyriofogiesl response to a chemical or physcal stimuli by a sensitive person. Alopecia - Lorn of hair. Amenorrhea Abaence of menstruation. Analfcsia Lon of sensitivity to pain. Anaphytasls - Extreme senaitivrty reauttinf from prior oootaa with t cherruai ot protein. Anemia - A deficiency of rod blood cdb. Anesthetic A chemical that cauaet a total or partial loat of sensation. Over esposurt to anemhetio cu catae impaired judgment, dazrnem. drowsincB. headache. unconsciouBses, sad cvea death. Examples iadude; alcohol, paint remove, and degiealuL Anhydride An oxide ot compound which when combined with water produce an acid or base. Anhydrtam - Doe not contain water. Anoadi Loss of the setae of stneO. Anorexia - Lee of appetite. Anotie - A lack of oxygen from inhaled air tilerxBy without oxygen. See Hypoxia. I ANSI American National Standard! hatitute o a privately funded, voluntary membership organieifon that identifiat Mactriaf and pubHe needs foe national consensus ttanditdi and cootdinatea development of tudi standard Antidote A remedy to relieve, prevent, or counteract the effects of a gsmon Appearance A description of a substance at normal mom temperature and norma) atmcapheric conditiona Appearance includes the color, site, and comsatncy of a material AM - American Petroietun Intitule a a voluntary membership orgtmriuon of the petroleum iadtatry. Aquatic Taaidty - The advene eScoa to marine life that result from briny exposed to toxic substance. Aqaeoaa - A waler-baaed sotatioa. Argyrts Local or genesalixed impregnation (griy-b)ue cokxl of the Kxls iroues with silver. Arowwtfc - Fragrant or of matted odor. Often applied to a group of hydrncarhnm and their derivttivex such as benene. toluene, syiene. Asphyxia Unconsdotaaas due to interference with the oxygen of the Hood. Aspbyiinm A vapor or gas that can cause uneoroesousness or death by suffocation (lack of oxygen). Most simple asphyiiams are harmful to the body only when they become so concentrated that they reduce otygen in the air (normally about 21 percent) to dangerous levels (It percent lower) Asphyttoon a one of the principal potential haxards of working in confined and endcaed tpncea Asphyahafoa A condition that causes asphyxia, suffocation See abo Asphytuni ASTM. American Society for Testing and Materials is the world's largest source of voluntary consettsia standards for materials, products, systems, and vertices ASTM it a resource for sampling and testing method!, health and safety aspects of materials, safe performance guidelines, effects of physical and btofogKal agents and chemtcah. Asthma A discs* characterised by recurring attacks of difficult breathing, wheesng. and cough due to spasmodic contraction of (he bronchioles Asymptomatic - Showing no symptom. Atoxin - Loss of power of muade coordination. Alas Atmosphere. I unit of pressure equal to 760 mmHg Imenurs) ai sea let el Atmosphere Supplying Respirator * A respirator that provides breathing air from a source other than the surrounding atmosphere. There are two types sir line and sdficomaincd breathing appuatta. Atrophy A wasting or diminution m the soe of a pan of the body Aato-lgnkfon Temperature The temperature to which a closed, ot neatlv closed container must be hated in order that the flammable liquid, when introduced into the container, will igniir spontaneously or bum 1AL - British Anu-Lewisrie - A name for the drug dimecaptol a treatment for toxic mhalatjouu artier Cream A aearn for use on human skin to protect tgainsr injury from contact with specific typer of harmful agents. Base - See AikaE CM Bfood<fontng mechanism effects. Benign Not recurrent or not tending to progress. Biodegradable Capable of beitq broken down into innccuoia products by the action of living things. Blohaxard This a combination of the words btofogicil and harard. and n u<cd to describe infectiota agenu presenting a risk or potential rak to the well.being of man or animals either directly through infection, or indirectly through disruption of the environment. 83 DE 008468 Bfeicfic Mf-Utt TV time required for fives species. otjan. or tine to dirrmute half of i substance which it taka is. Biopsy Removal end nettmtion of tine front the Kviaf body. LD - Stood effects. BoMnf Point - The temponure u whfoh t liquid chinpa to vapor sue at a kivert presort. The botliiq point s anally expressed hi dtfreo Fahrenheit at tea level pressure (760 mmH*, or one ttmophere). For mixtures. the rntria/ boitoif point or the boflint ranfe may be fives. Flammable materials with low boihof poimi feneraRy premt jpeciil Gre heaiA. Some appreisratc bodtaf poiatE Propane -44*F Anhydrous Ammoede 2P F Butane 31* F *' Gasoline 100* F Atlyl chloride 113* F Ethylene Clycoi 3*7* F BOM or BnMIma - Bureau of Mines. U5. Department ofhttcrior. Bondfof The interconnectinfof two objecti by mean of a damp and bare wire, la purptne i to prevent a satic dochatfe (iparlt) whea maafcntnf a (tammabie liquid from one eontamer to another. The conductive path provided by dantpa which make contact with the chatfed objecs and a low rtsauarr Bubble able which iBowt the dhatfe to equdat. See Oroundiap. Bradycarida - A slow heartbeat is which the pube rue fads bdow <0. See abo Tachycardia. Breathing Zone The area of the ambient environment it which a person breathes. Brondikk Inflammation of the bronchial tuba in the Imps. Buffer - A tubstanee capable in solution of neutraloinf both adds and baso and thereby maintaining the orifinal aridity or basidty of die Johnson. Bsflt Derafty - Masof powdered or ftanoUttd solid material per unit of volume. C Defrees Centigrade. a temperature scale where water both at I00*C and fteete at 0"C *C * 5/9 (*F 32V "C", or CeMiif The maaimom allowable human espcaure limit for an airborne substance which is not to he exceeded even momentarily. Also see PEL and TLV. ea - Approximately. CAA - Clan Ait Act was enacted by Control to refulato/'reduce air pollution. CAA is adimnbured by the Environmental Protection Afency. Cartmoftn - A substance or tfent capable of caurinf or produdnf cancer in mammals, indudinf humans. A chemical is Bonridered to be a carcinofea if. (a) It has been evaluated by the International Afency for Research on Cancer (IARC) end found u be a cudnofea or potential carcinogen; or (b) It b listed as a careinofen or potential careunfcn is the Annual Report on aronogens (laic* edition), publiAed by the Natfotwl Toxnfogy Program (NTPkor (c) It is refulated by OSHA a aroacpca. Car Cancer or arrange*. Cardrofenhjry The ability to produce cancer. Ctrcinoaa - A malijnaa tumor. A form of cancer. CAS - Chemical AhuacO Service a an orfaniation under the American Chemical Society. CAS abstraea and indexes chemical literature from all over the world in "Chemial Abstraea.* "CAS Numbed* tre wd to identify specific chemicals or tmxum. Cataty* A substance which, without chanfinf itself, causa t chemial reaction to proceed Easier. * Cttaetct - A toa of transparency of the crystalline lens of the eye or of ia apsule. Csuwie - The ability of as alkali tocstae buns. Set AlkaK. ce - Cubic centimeter is a volume measurement in the metric system which equal hi opacity to one mfllfliter (ml). One quin a about 946 cubic centimeters CHBng Uask - A conccnniuoa that s not to be exceeded. Sec abo ~C* or Ce&if. CeBbif Vatoefi) A maximum esubtbbed level which no human exposure should ever excced. Cewtral Nervous System The brim snd spinal coni These nffsmwpmisc and coordinate the activity of the entire nervous system Sensory impulses arc tranxmrned into the central nervous system, and motor imputsa are transmitted out. CERCLA - Comprehensive Environmental Response. Compensation, and Lia bility Act of I9B0. The Act requires that the Coot Guard National Response Center be notified in the event of t hstardoot substance release. The Act also provides for a fond (the Superfund) to be used for the cleanup of abandoned haordoui wtree dapoacl aura. Cends - The Iowa end of the utens extending into the iipru. CFTI Code of Federal Heftdauom. A collection of the refutations that hate been ptomulfaind under US. Law. Chtndikl Any dement, chemical compound or misture of eiemena and/or compoundi where chemialfs) are distributed. Chemical Cartridfe Rapicalor * A respirator that uks various chemical substanca to purify inhaled air ofcertain faao and vapors. Thb type of tespnator is effective for concentrations no more than ten time the TLV of the contaminant, if the comaminem ha wining propenio (odor or irritation) bdow the TLV. Chemical Chartfe (Reaction) - Oianfe of companion in prnpenies due to rearrangement of dementi, atoms or molecules. Chemieai Coapoanf * A substance componet) of definite proportion! by weight of two or more eiemena, and whose properties differ from Ihose of til elements. Abo me Mixture. Chemieai Family A froup of individual eiemena or compounds with a common feneral name. Example: ketona. alcohols. Chemical Name The name fiven to a chemical in the nomenclature ssetem developed by the International Union of Putt and Applied Chemistry tlUPAO or the Chemical Ahnrecs Service (CAS). Chemieai PiwemonMa Inflammation of the lunp caused by accummulatHin of fluids due to chemical irritation. CHEMTREC - Chemical Transposition Emerfcncy Center b a national center exubibbed by the Chemial Manufacturers Association (CMA) to relay pertinent emciftncy information conceminf specific chemiab on requests from individ uals. CHEMTREC ha a 24-hour toll-free telephone number (SOO-424-9JOO) to help respond to chemical tntaponation emergencies. CMocnea* An scne-lile eruption from contact with chlorinated naphthalenes and polyphenyb actinf on swat flands Chronic * Persistent, prolonged. and/or repated effeca which are the result of reputed exposure to low concentrations of chemical substance over a kmf period of time. Compare with Acute. Chronic Effect An advene effect on a human or animal body, with symptoms which develop slowly ova a ionf period of time or which recut frequently Compare with Acute. Chronic Expoanre long-term contact with a substance. Chronic Toxicity - Advene effeeo resultinf from repested doses of ot exposures to t subnance ova s relatively protonged period of lime. Ordinarily used to denote effeca in experimental tnintab. Otm Air Act - Sec CAA. Chan Water Act Federal law enacted to rejulatt/reduct mater pollution CWA a adminaured by the Environmental Protection Afency. CMA Chemial Mtnufsclurtn Asrociaiion. See CHEMTREC. PE 008469 CO Carbon monoxide. A ectorim. odorfeat. flammable tad very toxic gat produced by the incomplete cuntbuaioo of carbon. H in aha aby-produa of "wiy chemical procsiaro. i . Carbon dioxide it t hen;, ooiorte* gas which it produced by the combustion and deeompcritiou e( oipaic sobetaacs end at t byproduct of men; chcmtetl proceaea. CC>2 wri not bora tad it relatively non-toxic (although high concentrations, cxpccialy ia confined span. eta cretie hazardous oxygen defocnl eflyironmcna) COC - Cleveland Opea Cop a 1Sash point ton method. CwnboHMe- A term mad by NFTA. POT. tad ocfaerx to damfy ctnam tiqoidt (hit will bum. on (be beta offlash pome. Both NFTA tad DOT generally define "combustible liquith* at hewn 1 flash point of 100* F (37.t* C.) or higher but below 200* F (933* CV Aho sec Flammable- Nonliquid ssbaaacet such at wood and paper ait daaafied a "oedmary eombuetfeim' by NFTA. CombnstMe UqoU - Any liquid having a flashpoint a or abort IDO* F (37.1* CL but below 200* F (93J* CL except any atixtare having components with flashpoints of 200* F (93J* C) or higher, the total vehane of which make up ninety-nine percea (99%) or more of the total volume of toe atintare. Common Name Aay identification. soch a code aame. code number, aide name, brand name, or generic tame, ether than its chemical tame, mad to identify a chemical. Cumpirard Gaa (a) A ga or mixture of gases having, it a container, an staoiute pressure exceeding 40 pri a 70* F (21.1 C*); or (b) A ga at mixture of gases having, in t container, an absolute preaura exceeding 10* pai a 130* F (34 4* C) reganflea of the pitatae M 70* F (21.1* CL or (c) A liquid having a vapor proaure exceeding 40 pri it 100* F (37.1* C) a determined by ASTM D-323-72. Cone - See "Concentration.' Concentration - The relative amount of a sabstance when combined or mixed s other substances. Example* 2 ppm hydrogen sulfide in air, or a SO percent ic solution. Condltlona 10 Avoid - Conditions encountered during handling or storage which could cause a substance to become unstable Confined Space -.Any tret which ha limited openings lor entry and exit that would make escape difficult is an emergency, has a lack of ventilation, contains known and potential heard* and ia not attended nor designated far eontmuom human occupancy. Conjunctivitis - InlUmmatiem of the conjunctiva, the delicate membrane that lines the eyelid! and coven the eycbalk Contact Dermatitis Caused by contact with a primary mhaat, 1 shin irritant at the area of skin coutaa. Container - Any bag. barrel beetle, box. can, cylinder, drum, reaction read, forage rank, or the tike that contains hazardous chemical For purposes of MSDS or HatCom, pipes or piping systems are uot couridend to be containers. Cornea - Transparent nructure of the external layer of the eyehriL Corrosive A chemical that auma visible destruction ol at irreversible sllentiotts in. living throe by chemici! action at toe she cfcoatari. Thii term shafl not refer to action on inanimate surfaces CPSC - Consumer Products Safety Commhwon has ropoisibSity far regulating hazardous materiab whan they appar in consumer goods. For CFSC putpoaes. haeards are defined m the Hazardous Subattaces Act and the Tchoo Treueatiua Packaging Acs of 1970. Curettage - dancing of diseased surface. Cutaneous Hazards - Cherniak which irritate the torn. Cutaneous Toiletry. See Dermal Toxighy. A Clan Water Ad wit eroded regulate/reduce water poBunon. It n sdminmered by ETA. Cyanosis - Btuencm of the skin, generally mused by lack of oxygen. Cyst A me containing a liquid. Meat cysts are harmless Cytology The aoentific study of celt. DASHO Designated Agency Safety aad Health Official is the executive official of a Federal Department oc Agency who is reapoaeibte far safety and occupation^ health mitten within a Federal agency, aad is 10 draignsttd or appomted by the head of the agency. DftoaapoelHon - Breakdown of t material or mbsunor (by heal chemical reaction, ductrolysh, decay, or other processes) into para or dements or ampler Dimly - The mss (weight) per ooit volume of a substance. For example, lead is modi more denae than eluaamaa Dipiiml - A substance dial reduce! a toddy functional activity or an instinctive desire, such as eppetiri Denari Adating 10 the skin. Denari Toxicity Advene effects resulting front toia exposure to a substance. Ordimrdy used to denote cflaca ia experimental aasmak. Dermatitis. laflimmatiou of Ike skin. Also sea Irritant. Seminar, and Comet Dermatol. DHHS - U.5. Department of Hcakh and Human Servicer (replaced U.S. Depanmem of Health, Education and Welfare). NIOSH and the Public Health Service (PHS) art part of DHHS. Dfet - A barrier constructed to control or confine batxrdoui substances and prevent them from catering sewers dachas, stream* or other (lowing water* Dkrtiou Ventiblion Air Dow designed to dilute contaminants to acceptable levels- Abo see General Variation or Exams DOL - U.S. Depanmem of Labor. OSHA and MSHA are part of DOL Done The term toed to express the amount ofenergy or substance absorbed in a unit volume of an organ or individual done rate is the dcac delivered per unit of time. DOT VS. Department of Transportation regulates transportation of chemicals and other substance* Dry Cbemlcri A powdered lire exungubhinf agent usually composed of sodium bicarbonate, potassium bicarbonate, etc. Dysfunction - Any abnormality or impairment of an organ. Byamenorrhea - Painful menstruation. DyapMc An abnormality of development. Dysprlea - labored or difficult breathing, shortness of breath. Ectopic pregnancy - The fertilized ovum becomes implanted outside of the mens. Earns A skin disease or disorder, one specific type ol dermautil Edema - An abnormal accumulation of dear watery fluid in the tistura Element - A substance composed entirely of one kind of atom. Elements ate designated by chemical lymbok. Emphysema A lung disease in which the prgeacc of air in the connccuve tissues of the hmgs causes swelling or inflammation. Endocrine Glands - Glands that regulate body activity by secreting hormones, rndountil-- - The mucous membrane Kiting the uterus. Environmental Toxicity . Information obtained as a result of conducting environments) testing designed 10 study the effects on sqmtic tnd plant (He. ETA - U5. Environmental Protection Agency. Epidemiology Strong corcetocd with the study of disease in t general population. Determination of the incidence (rase of occurrence) and dmribution of a particular disease (as by age. sex, or occupation) which may provide information about the cause of the dwesse. DE 008470 Eptooxh - NoueHeext hcmcrrhupe from the m. rplitul-- The this membrane covering internal and edema! sorfscts of the wdy. Europe Prindpel ferrule an hormone. Evaporation Rate-The rate at winch* material anil vaporize (evaporate) when compand to the know* nte of vaporization of standard materiel. The evaporation rate eta be taefoi m evaluating the heakh and lot hearth of a material. The destituted standard material usually normal butyl acetate (NBUAC or n-lnAc), with a vaporiiarion nte deagnuod aa 1.0. Vaporization rates of other solvents or mattriab ate tbea classified ac FAST evapontini if grater than 3.0. Examples; Methyl Ethyl Ketoae (MEK) * 3.*, Acetone * 5.6, Hexane |J. MEDIUM evapontini if 0.8 to 3.0. Examples: 190 proof (95%) Ethyl Alcohol 1.4, VM k F Naphtha * 1.4, MIM 14 SLOW evapontini if lot than 04. Examples: Xyteae 0.6, bobnryt Alcohol 0.6, Normal Butyl Alcohol 0.4, Water 0J, Mineral Spain 0.1. Eapkaaive - A chemical that causes a sadden, almost iraasttneoai release of prtwirt, pa, and heat when mbjoaed to sudden Pock, prorate, or hi|h temperature. Exposure or Exposed State of beint open end vulnerable to a htsatdom chemical m the course of employment by inhalation, inpgion, aba contact, absorption, or any other course; mdudet potential (accidental or possible) exposure. EatlngubMng Medls - The firefighting substance to be used to control t material in the event of a fire. It is usually named by its pneric name, suck a log. foam, water, etc. Eye Proewlhm Recommended safety {lasses, dtenscal splash topic*, xce shiekk, etc. to be utilized when handtint a haxardow metetaL F - Fahrenheit is a scale for mcasutint temperature. On the Fahrenheit scale, water both at 212* and freaes at 32*. *F 9/5 (C) * 32. f/ce Fibers per cubic centimeter of air. FACOSH Federal Advisory Council for Occupational Safety and Health is a joint nuiupment-labor council that advisa the Secretary of Libor on matters reiitint to the occupational safety and health of federal emptoyte*. FDA U5. Food and Dru| Adminsiratioa. Fetal - Penxmtng to the fetua. Fetus The devefopini youn| in the atrrus front the seventh week of goutioa until birth. FFSHC Field Federal Safety ind Health Count* are orpnieed throu|hoot the country to improve federal safety and health propama al the 6dd levd and within a geographic location. FHCP - Federal Hixsrd Commueicaticn Fregrtai Fibrosis - An abnormal thirkeamg of fibrous niri tame, uauaBy in the loop. F1FRA - Federal Insecticide, Furi|icidc and Rodeatidde Act requires that certain useful poisons, such as chemical pcariddo. sold to the puttie contain libels that arry heahh hazard wtrsinp to prmecl asm. h is admMnered by ERA. Fine AM - Emerjency measures to be taken when a person is suffering from overexposure to hxzaidotn material, before regular medical help an be obtained. Ffemmabie - A chemical that mchides one of the following augeriec (a) "Aeroaoi. Flammable-" An arioso! that yields a flame projection exceeditg 18 inches at fall valve opening. or a flashback (a flame extendin{ back to the valve) at any degree of valve opening; (b) "Gas, flammable.* (1) A ps that, it ambient temperature and premure, forms a flammable mixture with air at a concentration of 13 percent by volume or leas: or (2) A pi that, at ambient temperature and pressure, forms a range of flammable mixtures with air wider than 12 percent by volume, regardtae of the tower Haste (c) liquid, flammable.* Any liquid havirt| flashpoint below 100" F (37 8 CL except any mixture havtnf components with flashpoints of 100 F (37.1* C) or higher, the total of which make up 99 percent or more of the local volume of mixture. (d) "Solid, flammable.* A solid. ocher than a Hasting agent or expksn.es that is liable lo ause fire through friction, absorption of morsrure. tporttanenr chemical change, or retained heat from manufacturing or procemtng. re which can be ignited readily and when ignited bunts so vigorously and petsaxertfly as to create a serious hazard. A solid a flammable solid if it ignites and buns with a arif-staumnd flame it a tare greater than one tenth of ta mch per second along in mqjoe tin. Flaabbnch - Occurs when flame front a torch burns heck into the tip. the torch, or the haae. h is often accompanied by a hoeing or sqmling sound with a smoky or dttjpfOfcMd 0ML Flashpoint The minimum temperature at which a liquid gives off a vapor m saffideoc concentration to ignite when seated by the fodowmg methods: (a) Tagfiabne Cloned Tester (see American National Standard Method of Test for Flap Feint by Tag Closed Tcmer. ZIIJ4 1979 (ASTM D56-79JJI (b) FenskyMinen Closed Tester (see American National Standard Method of Teat for Flash Font by Fetnky-Marieni Closed Terser. Zl 1.7-1979 (ASTM D93-79JL (e) Setaflash Dosed Tester (see Amerian National Standard Method of Test for Flab Faint by Setaflash Ckned Tester [ASTM D 3278-78)). Foreseeable Emergency Any potential occurrence such as. but not limited to. equipment failure, rupture of containers, or failure of control equipment uhich could result in an unoootrolled release of a hazardous chemical into the wortplace or environment Forunrie - The scientific expression of the chemical composition of a material (eg, water it HjO, sulfuric arid is HjSO*. sulfur dioxide is SOj). Fame Smoke, vapor or gas. especially when irritating or offensive. Fume Fever - An acute condition anted by a brief high exposure to the freshly generated fumes of metal such is had or magnesium. Gangrene - Oath of tisue combined with putrefaction GaaSroantcrMs Inflammation of the stomach end intestines. g Gnat is a metric unit of weight. One ounce U.S. (evcirdupotsl ts about 28.4 grama. Generri Elbaaat A system for exhausting sir containing contaminants from a general wort tree. Also see Local Exhaiat Generic Name A designation or identifiaiion used to identify chemical by other than its chemical name (eg., code name, code number, trade name, and brand name). Generic Pertaining to or carried by genii. Hereditary. Gestation The development of the fetus bom conception to birth. 8^8 Grams per kilogram is an expression of dote used in oral and dermal toxicology testing to denote grams of a substance dosed per kilogram of animat body weight. Abo set kg (kilogram). Grounding. The procedure used to any an etccincal charge to ground through a conductive path. A typial ground may be connected directly to a conductive water pipe or to i grounding but tnd ground rod. See Bonding. Gynecology - The study of the reproductive otgans in women. Hand Froteetlow - Specific type of gloves or other hand protection requited to prevent harmful exposure to hazatdot* materials. Huarrions Chemical - Any chemical whose presence or use is a physical harard or a heahh hazard. 86 DE 008471 Material - A material tint it characterized by one or more of the following (1) has a flashpoint below 140*. doted cup, or subject to sponuneoa heating: (2) tai * threshold Inmt vilse below 500 ppm for (03 ind vapors, below 500 mg/m for femes, ud below 25 mppef for dt*K (3) single onl dow LD50 or below 500 ntg/kgeftady weight; (4) it subject to polymerization which route in the reteese of large tmoette of energy: (5) * Hrofig osidmng or reducing tfenc (6) camca first detree bunt to stem is short time eapoture. or is systematically losie on comiet with the doe: and/or (7) in the course of norm! operations imy produce (huts, gases, fumes, vapors, mitt. or smoke which have one or more of the above thtrsemteia Hazard Warning - Words, pictures, symbols, or combination thereof presented on a label or other appropriate form to inform of the presence of various materials or hazards. Hazardous Chemical Aey chemical whose presence or use is a physical heard or a hesfih hazard DCS Hazard CommunicalioB Standard an OSHA refutation. Health Hazard - A chemical for which thee is significant evidence, based on tt lean one scudy conducsed in accordance with tsateistedaacitufic principles, that acute or chronic beafth effects msy occur in etpoaed employees. The term "health heard" indudes chemicals which are eaicinopns. soak or highly torie agents, reproductive seisins, ttriizno, corroarvo, sensitizers. tepstotosins. nephrosoams, neurotosin, afents which act on the hematopoietic system, end spents which damafe the tonfs. skis, eyes, or mucous membranes. Hematoiocy - The study of blood. Hematoma A blood dot under the surface of the shin. Hematopoietic System The Mood focmint mechanism of the human body. Hematuria - The presence of blood in the urine. Hemofiobi* * An iron-conuimtif conjufated protein or respiratory ptftneM occumng in the ted Mood cds of vertebrates. Hepntolasln A substance that causes injury to the liver. HifMy Toxic A chemical fating within any of the foflowinf categories: (a) A chemical with a median lethal dose (LD50) of SO millifTams or leas per kilogram of body weight when administered orally to albino rats weifhm| between 200 and 300 frame each. (b) A chemical with a median lethal dose (LD50) of 200 miUiframs or less per kilogram of body weight when administered by continous contact for 24 hours (or lem if death occun within 24 hours) with the bare skin of albino rabbits weighing between 2 and 3 kilogram* each. (c) A chemical that has a median lethal concentration (LC50) in air of 200 parts per million by volume or less of gas or vapor, or 2 mflligrana per hter or less of mist. fume, or dot, when administered by continuous inhslstion for one boor (or Vest ifdesth occurs within ooe hour) to albino rats weighing between 200 and 300 grama CMh. HMIS Hazardous Material Information System it as MSDS file maintained by the Department of Define and eooatne MSDS* and transportation data for products purchased by DOD and GSA. Hormones - Act t chemical memengen to body organs. Hydrocarbons - Chemicals composed solely of carbon and hydrogen, which are the basic building Modes of al organic ctemkab. Hygroscopic Readily absorte measure from the air. HyprppMa - Increase in volume of a (sue or organ earned by the growth of new cells. Hypoxia Insufficient oxygen, cxpecssHy ts sppfied to body ceils. IARC - International Agency A Research on Cancer. IgnttaMe-CapaWe of being set afire. Imnvket* - Liquids which will not mix with each otter but will form 2 separate layers or will remit in doudinew or turbidity. Impervious - A material that does not allow another substance to pass through nr penetrate h. liieompadMe Materials that could cause dangerous reactions by direct contact with one another are described ts incompatible. fafiammalloa A morbid senes of reactions produced in the tissues by an irmani It is marked by an afflux of Mood with exudation of plasma and leukocytes Ingestion Taking in by the mouth. Male See Inhalation. Inhalation - Breathing in of a substance in tite form of a gas. vapor, fume. mtn. or dust laMbfeor - A chemical added to another substance to prevent an unwanted chemical change. fnntguale A term used to designate compounds that generally dn not contain carbon. Source miser other than vegetable or animal. Examples are tulfunc acid andak. fatal - See Imotebic. laanhtble. Incapable of being dtedved in a liquid. Intreutiihto - Within the mens. IrodocycHt Inflammation of both his and ciliary body of the eye. Irritant A chemical which is not corrosive, but which causes a reversible inflammatory effect on living tame by chemical action at the site of contact Irritating An irritating material, as defined by DOT. is a liquid or uslid substance which, upon contact with fire or when exposed to ait. gives of! dangerous or intensely irritating fumes (not including pcwonom materials). See Poison. Class A and Poaon. Class B [tcemia. Local and temporary anemia due to the obstruction of the circulation in a pan of the body. kg - Kilogram s a metric unit of weight about 2.2 US pounds Alio see; kg.; and mg L - Liter is a metric unit of capacity of volume. A U.S. quart s about ti' 10 ol a Hter. Label - Notice attached to a container, bearing information concernm; its contents. Lacrimatina Secretion and discharge of tears Lactation The secretion of imtk by the breasts. Latent Period The period of time between exposure and the fire! numfestation of damage. Lavage A washing of a hollow organ, such ts the stomach. l Lethal Concentration is the concentration of s substance being tested that vrifl kflL 1XL Lethal Concentration Low. lowest concentration of a gas or vapor capable of killing a specified specks, over a specified time. LCSt - The concentration of a matentl in ait that will kill 50 percent of s group of test animals with s single exposure (usually 1 to 4 hours) The LC50 tv eipressed as pan of material per million pans of sir. by volume (ppm) for gives and vxpore, or as mkiogtams of material per liter of ltr (g/ll or milligrams of material per cubic meter of an (mg/m) for dusts and mots, as well as for gases and vapors. LD Lethal Dote it the quantity of a substance being tested that will kill LDL Lethal Dcse Low. lowest administered dose of s mstenal capiNe of killing a specified tea species. LD50 A single dtae of material expected to kill SO percent of a group ol tent animals. The LD dote is usually expressed as milligrams or grams ol material per kilogram of animat body weight (mg/kg or g/kg) The material may he tdminotered by mouth or applied to the skin 87 DE 008472 Lad IwUjikJtte* - Lead ibaorptioo resuhmg from inhalation of lead dot or fumea or from swaBowini lead diat. LEL. or LFL Lower Explosive limit or Lower Flammable Limit of a vapor or gas the lowest concentration (towen percentage of the sthatance in the air) that will produce a flash of fire when an ignition source (heal, arc. or ftame) d promt. At concentration lower thaa the LEL. the mixture ia too lean" to bum. Abo ace UEL Lesion. Any damage 10 a base. Lethaf CooenWrotton - LC - A cooeentratioo of a aehaunoe that d euflident kffl a tat aahntL Lethal Concenandon SI LCtt - See LCiO. Lethal Done LO - An amoum ofa tubcunce that is suflidenl to kin a tea aramaL Lethaf Doae SI LOSI Sne LOSO. Lenkeada - A diaetae of the Mood marked by peniatent increase in white Mood celts, aaocaated with charges in the spleen, the bone marrow, or the lymphatic nodes. Local Eahanst A system for capturing and exhausting contaminants from the air at the point where the contaminants are produced (welding, grinding. sanding, other procean* or operations). Alao see General ExhnaaL Lfai - Linear feet per minute. a unit of sir velocity. M - Meter is a unit of length ia the metric system. One meter is about 39 inches. m - Cubic meter is a metric measure of volume, approximately 35.3 cubic fees or IJ cubic yardL Mslilac - A feeling of teneral discomfort, tfbtre*. or useasines, an "out-of-sorts" feeling. MUgnant - Tending to become progressively worse and to result in death, often used m describing turnon. Mammary - Pertaining to the breast. Mechanical Eahanst - A postered device, such as a motor-driven fen, or stream venturi tube, for removing contaminants ftum a workplace, vemeL or enclosure. Mechanical FMer Respirator - A respirator used to protect agsinss sirbome paniculate matter like dusts, mists, metal fumes, and smoke. Mechanical filter respirators do nor provide protection against gases, vapors, or oxygen deficient atmospheres. Melting Pofnf The temperature at which t solid substance changes to a liquid state. Menorrhagia * Excessive metouuntion. Menstruation Periodic discharge of Mood from the vagina from a noo-pregnant uterus. MESA Mining Enforcement tad Safety Adminomion. Mttahofisca The physical and chemical processes by which living organisms produce the aeceaary coup to maintain lift. Mttastaaca - The transfer of disease from one organ or part to another not directly connected with iL Meter - A unit of length; equivalent to 39J? inches. mg - Milligram is a metric unit of weight which is one thousandth of a gram. mg/kg Milligrams of substance per kilogram of body weight is an esprosion of toxicoicgici] dose. mg/m - Milligram* per cubic meter is t unit for rtprcwing concmtraiHin ofOusts, gases, or mas m as. Micron- Micron is a unit of fcngth equal to one millionth of a meter. A micron is approximately I /23,000 of an inch. MM- Mild. Mfel Suspended liquid droplets generated by condensation from the grow to the liquid state, or by breaking up a liquid tmo a dopened suie. such as splashing, foaming or tomtong. Mot is formed when a finely divided liquid n suspended m air. Mixture - Any combination of two or more chemicals if the combination n rax. in whole or part, the result of a chemical reaction. ad - MiBBiter is a metric amt ofcapacity, equal in volume to one cutw .-entimeier (cc), or approximately 1/16 of a cubic inch. One thousandth of a liter MW-MBA snmKg - MiTlimeten (mm) of mercury (Hg) is a unit of measurement for low pressures or partial vacuum. Molecular Weight. Weight (mass) ofa molecule hated on the turn of the aiixmc weights of the atoms Hist make up the aiotacute. pprf Million perridcs per cubic loot is a unit for expressing concentration of parrida of a substance suspended in ait. Exposure limits for mineral dtitu oihca. graphite. Portland cement, moaner dusts, and others), formerly expressed as mppcL are now more commonly expremod m tng/m. MSDS - Material Safety Data Sheet MSHA Mine Safety and Health Administration. U.S. Department of Labor Mutagen - A substance or agent capable of altering the genetic material m a Using cdl. MW - See Molecular Weight N - Nitrogen b a colorless, odorless, and tasteless gas that will mx burn aral will not support combustion. The earth's atmosphere fair) is about 78 percent nitrogen. At higher concentrations, nitrogen can displace oxygen and become a lethal asphyxiant See Asphyxiant Narcotoa - A stale ofstupor, unconsciousness, or arrested sanity produced by the influence of narcotics or other chemicals. Nausea - Tendency to vomit feeling of sickness at the stomach NCI National Cancer Institute b that pari of the National Institutes of Health which studies cancer causa and prevention as well as diagnosis, treatment, and rehabilitation of cancer patients. Necrosis - Local death of tissue. Neo - See Neoplasia. NronaUi - The first 4 week after birth. NeopWs A oondtuon characterized by the presence of new growths (tumors) Nephrotoxhi A substance that causa injury to the kidneys Narotoxkt A material that affects the nerve cells and may produce emotional or behavioral abnormalities. Neutrafae To eliminate potential hazard! by inactivating strong acids, caustics, and oxidtzen. For example, acids can be neutialned by adding an appropriate amount of antic substance (alkali or bese) to the spill. NFPA National Fire Protection Association is an international membership organization which piomotcs/tmprovo fire protection and prevention, and estaMbha safeguards against kas of life and property by fire. Best known on the industrial scene for the National Fire Coda--16 voluma of axles, standards, recommended prsctica and manvab developed (and pcnodKzlly u[xlatcdl hv NFPA technical committee*. ng Nanogrem. one-billionth of grant. NIOSIt - National Institute ft* Occupational Safety and Health, t S I'uMn Health Service, U.S. Department of Health and Human Sconces IDHHS). among other tctivbia, tests and cemfia respiratory protective devices and air sampling detector tubes, recommends occupational exposure limiu for various suborners, and assists OSHA and MSHA in occupational safety and health investigations and research. 88 DE 008473 NonftMMfcfe - Not eaSy jpked. at if ignited, net banting rapidly. Non SpnrUnt Took Took mode (ram beryflium-cnppei or elummurti-bronte (rally radoce die possMky of igniting dak, p or flimmible vapors. Although these look may emit souse sparks when striking metal, the sparks have a low hat content end me Ml Htefy to ignite man (Unusable Squids. NOx Oxides ofnitrogen which ere undesirable u poDutasts. NO> emanom art regulated by EPA wider die Qcn Air Acl NPIRS National Pesticide Information Retrieval System is an aotomated data base opented by Purdue Uaivertity contenting infcnnadoci on EPA regmered pesticides, inefuding reference Sc MSPSs. NRC National Response Center is a notification center which mast be ailed when significant oil or chemical spA or other environment-related accidents occur. The tod-free telephone mmber k 1-*00-4244*01 NTT National Tosicoto|y Program. The NTP pubfhbei 4a Annual Repoet on Carcinogeil. Nysta|moa - Spasmic, invoiuntary motion of the eyrhafc, in thher a horaontal. vertical or eircutar patten. Odor - A description of the smell of the substance. Odor Threshold The ksweat concentration of a sutatanoe's vapor, it air, that an besneSad OKactoty - Relating to the tense of srned. ORgaria - Scanty nr tow volume of arinc Oral - Used m or taken into the body tbroufb the mouth. OFAP - Office of Federal Agency Programs is the orjsniatioRt! unit of OSHA which provides federal agencies with (uidanoe to develop and implement occupational artery and health programs for Codeni emptoyeca Oral Toxicity - Adverse effects re*uHin( from taking a substance into the body by mouth. Ordinarily used to denote effects in experimental animals. Otgatik Peroslde - An organic compound that may be considered a structural derivative of hydrogen pcioxide. Organogeiuk The secretion of taues into different organs in embroyonic development. OSHA Occupational Safety and Health Administration. US. Department of Labor. Ovary - The female sex gland in which ova (cgp) are formed. Overexpoamt Exposure to a hasardew material beyond the allowable exposure levels. OnbMkm The process in which an ovum (efg) k discharged from an ovary. Om - Egg OxHatton. A racoon in which a tubetanoe pornbars with oxygen. Oxidation-Redaction Rtacdat A chemical reaction in which an atom or molecule loses electrons to another atom or molecule. Oxldber - A chemical other than a blasting agent nr explosive that initials or promotes oombustion in ether mxteriak. ausing fire eitherby itself or through the release of oxygen other gssea. Oxidizing Agent - A chemical or substance that brinp about an oiidation reaction. Papanleobon Smear (Pap Smear) -Tot most commonly used to detea cancer of the uterus and cervix. Pathoioffe - Pertaining to or caused by disease. Pathology - Scientific study d ahemdona produced by disease PEL - Pcmuwbte Exposure Limit is sn exposure limit established by OSHA's tegulstory authority. It may be a time weighted average fTWA) limn or a maximum concentration exposure limit See atso TLV. Percent VoMta-Percent volatile by volume is the percentage of a liquid or 4id (by volume) thai wfll evaporate at an ambient temperature of 70*FI unless v'tne other temperature is specified). Examples: butane, gasoline, and perm thinner (mineral spirits) ire 100 percent volatile: their individual evaporation rates vary, but in time, each wH evaporate oompfestly. Personal Protective CgsIpMt - PPE. Devices worn by the wotktr to protect tftinx fetordi it the eaviroamtat Hesptrston. item, and car protectors are etaatptaL pH The tymbol retating the hydrogen ion (H-) concentration to that of a given standard solution. A pH of 7 it neutral. Numbers increasing from 7 to 14 radiate greater alkalinity. Numbers deceasing from 7 to 0 indiale greater acidity Physical Hazard A chemical for which there is scsentifially valid evidence that it k a combustible liquid, a compttsmd gas, explosive, flammable, an organic peroxide, aa oxidan, pyrophoric, ratable (reactive) or wxiet-tractive Plactaa A stmenre that grows on the we* of the mens during pregnancy, through which the fetal a nourished. PMCC - Perwky-Maneae Owed Cup See Ftaah Point Pnrranctwlnak- A conditiou of the lung in which there is permanent deposition of particalaie mane and the tkaue reaction to its presence. It may range (rom relatively karmlea fora of iron oxide deposition to destructive forms of nidus. Token. Clra A - A DOT term for extremely dangerois poisons--pononow giset or liqxidt that, m very small amounts, either as gas or as vapor of the liquid, mixed with air, art dangerous to Sfc. Examples: phosgene, cyanogen. hydrocyanic acid, nitrogen peroxide. Poison. Clra - A DOT term for liquid, solid, paste or temtsolid substances-- other thin Clan A poisons or irritating materials--that are known (or presumed on the bask of animal too) to be so toxic to humans that they are a heard to hahh daring transportation. Polymerization - A chemical reaction hr which one or more small molecules combine to form larger molecules. A hazardous pobmrmmm a a reaction trial takes place at such a rate that targe amounts of energy are released If hazardous polymeriatkm an occur with a given material, the MSDS usually will list conditions that could nut the taction and--since the material usually contains a polymerization inhibitor--the length of time during which the inhibitor will be effective. ppb Pam per billion is the concentration of a gas or vapor in an--parts (by volume) of the gas or vapor in a billion pans of air. Usually used to express extremely low concentrations of unusually toxic gases or vapors: also the concentration of a particular substance in a liquid or solid ppm Pam per million is the concentration of a gas or vapor in air--peas (by volume) of (he gas or vapor in a million pern of air: also the concentration of a particular substance in a liquid or solid mmi imunf tunn. pal Pounds per square inch (for MSDS purposes) k the pressure a matm.il cxrru on the walk of a confining vessel or enclosure. For technical accuracy, pressure mutt be expressed as png (pounds per square inch gauge) or psu (pounds per square inch sbaohae: that is, puge pressure plus sa level atmospheric pressure, or png plus approximately 14.7 pounds per square inch). Abo see mmHg PH - Sa Pulmonary. Pulmonary. Retating to. or asociaied with, the lungs. Pulmonary Agent - Chemicals that may damage the lungs Pulmonary Edesnn - Fluid in the lungs. Pyrophoric - A chemial (hat will ignite spontaneously in air at a temperature cvf I30*F (54 4*C) or heiow. RCRA - Resource Conservation and Recovery Act is environmental legislation timed st controlling the generation. Hating, storage, transportation and disposal of hazardous wasus. It is admmatertd by EPA. See abo CERCLA Reaction A chcmicil transformation or change The interaction of two or mote substances to form new substances. 89 DE 008474 Rescdvt - Sa Umttbte. .. Rtucttvby- Chemical reaction with the teieae of energy. Undesirable effects-- tuch a piuuure buildup. temperature increase. formation of noxiota. lone or cottouvc by-prodaa-may occur beotuae of the reactivity of substance to beating. burning. dnect eoauct with ocher maleriab. or other conditions in me or in nonce. Rcdachty Agent U i redaction reaction (which always ocean aimhaneoody with ati oxidation fraction) the reducing agent it the characri or rebalance which (1) combine! with oxygen or (2) kaei electrona to da reaction. See aho Oxidation. Oxkktioii-Redoaiou Reaction. REL . The NIOSH REL (Recommended Exposure Limit) ia the hi|hest allow able attbome concentration which is not expeaed to injure the woriten. It may be Vxpreaed as a ceiling limit or as a tinre-wtjghtcd avenge (TWA). Reproductive Toths- Chcmieala which have a M(itive tffea on the reproductive capabilities, including chromosomal damage (mutationt) and birth defects to the (eta (tentogetun). Rrspirasory Protection - Devices that wi* protea the wearer's respiratory system from overexposure by inhalation of airborne conuminams. Respiratory protection it used when s worker mat work in an area where he/shc might be exposed to concentration in exam of the allowable exposure bunt. Respiratory System The breathing system thtt includes the lungs and the ah passages (trachea or "windpipe,* larynx, mouth, and nose) to the sir outside the body, pin the estocttied nervous and dttttlatory supply. Respirator A device designed to protea the wearer from the inhalation of contaminated air. Respiratory Disease Any disease which affects the lungs or the respiratory tract Respiratory IrrhaMa - Any chemical that produces a reversible inflammatory effect on the respiratory system. Routes of Entry -The means by which material may gain accem to the body, for example, inhalation, ingestion, and skin contact Safety Can - An OSHA-approvod dosed container which has the fallowing chsraaeroticx (I) a capacity of not more than S gallons (19 theta); (2) a springdosing lid and spout coven (3) Rash-uresting screen; ltd (4) designed to safdy relieve internal procure if exposed to (ire. Saturation - The maximum concentration of matter thtt can be daolved in a solution at a given temperature. Sarcoma - A malignant tumor arising in connective times such as bone or cartilage. Sdf-Conttbwd Breathing Appantut - A respiratory protection device that consista of a supply or a metro of respirable sir, oxygen, or oxygen generatiro material, curried by the wearer. Setistttec- A chemical that sines t substantial proportionatesposed people or tmmits to develop an tltergic reaction in norma! tmue after repeated exposure to the chemical. SETA - SetaSash Gated Tata. Sue Ftsah Point SKcoab A disease of the lungs earned by the iahalaooa of silica duo. Skn-Skm. "Skin" - A notation (sometimo toed with REL or TLV exposure data) which' indicate that the staled substance may be absorbed by Ibe skin, mucora membranes, and eyes--eilhe airborne or by direct contact--and thtt this additional exposure must be considered put of the snal exposure to avoid exceeding the PEL or TLV far that substance. Skin Absorption. Ability of some haiardow ehemieali to pas direaiy through the skm and enter the bioodstgatm. Skis Seiutetur See Senritoer. Skkx Toxicity See Dermal Toxicity. SOx Oxides of sulfur. Sobs Solution. SoWdHyhswuter-A term etpressing the percentage of a material thv wrtghn thtt win dtssoivt in water at ambient temperature. Solubility mformain<n can be tuefsi fa determining spiR dean-up methods and re-cttinguohtng agents and raethoch far a material Solvent. A substance, usually a liquid, in which other substances are disunited The tram common solvent is water. SOs-Oxida of sulfas. Species - On the MSDSs, species refers to the test ammaH--usually rats, mw, or rabbis--wed to obtain the toxicity tot data reported. Spedfic Chemical Identity The chemiesl name. Chemical Ab*ract< Sx.-rvu.-c (CAS) Rcgntry Numba, or any precise chemical damnation of a substance Spedfic Gravity The weight of a material compared in the weight of an equal volume of water is an sxpremion of the density (or heaviness) of a maienal msolobte materials with specific gravity ofkm than 1.0 will float in (or ont water materials with specific gravity greater that 1.0 win sink in water. Mott (but not an) damnable liquids have specific gravity leas than 1.0 and. K not soluble, wilt float on water--an important consideration lot fee tuppremon Sp> nr Leak Prntsdmst - The methods, equipment and precautions that are designed lo dan up a contain rebnances that have spilled or leaked Splash Proof Goggles - Eye protection made of a non-cormise maienal that fits snugly agatnn the facet and ha indirect vemilttion pons. Spontaneously Combustible A material that ignites as s resub of retaining heal horn ptoceming. or which will osidize to generate heal and ignite, or which absorbs moisture to generate heat and ignite. Squamous - Scaly or pUietikc. SfabBMy The ability of a material to remain unchanged. For MSDS purposes, t material is stable if it remaim in the same form under expected and reasonable conditions of storage or use. Conditions which may cause instabthtv I dangerous change) are stated: for example, temperatures above 150F: shock bom dxopptng SILL Short Term Exposure Untie (ACGIH terminology). See al<o TLV Stenosis Nanowing of a body passage or opening. StccsMa A complex molecule among which are the male and female set hormones. Stupor. partial or nearly complete unconsciousness. Subeataneuoua Beneath the layers of the skin. Supplied Ah Respirators Air line respirators o( self-contained bretihmg apparatus. Syt System or systemic. Systemic Poison A poison which spreads throughout the hodt. affecting all body systems and organs. Its advene effect a not localised ut one spot or area Systemic Toildty - Advene effects caused by a substance which affects the hnb in a general rather than local manna. Synonym Anotbet name or names by which a material is known Methyl alcohoL for example, is ibo known as methanol or wood alcohol Tachycardia Escesrively rapid heartbeat. See abo Bndycarida. Target Organ Effects - The fallowing is a target organ categorisation of effects which may occur, including examples of signs and symptoms and chemical' which have been found to cause such effects. These examples are presented to iffujtrate the range and diversity of effects and haiaids found in the workplace and the broad scope employers mutt consider in thtt area, but are not intended to be all mduabre. a. HepuSoiint - Chemicals that produce liver damage. Signs and Symptoms Jaundice: liver enlargement. Chemicals - Catbon tetrachloride: mltosammes 90 I DE 008475 b. Ntfferetoitai Chemkih that produce kidney damage. Signs sod Symptom-EderMipraewurit- Chemiak - Halogenttod kydrocutoat; uranriwi. c Nccrototta Cherniak thai predict their prinary tonic eflccti on the DOVM lyWHL Si|m ind Symptom - Narcosis; behavioral changes; decrease in motor faacbtw. Chemicals- Mercury carton disulfide. d. Agents which act ost Bk hematopoietic syuten Cherniak thtt decrease hemoglobin funaioa; deprive the body towel of oxygen. Signs tod Symptom Cytrais torn of cooekmam Cherniak Carbon monoxide; cyinido. e. Agents which daarept the hap - chemiah thtt Mate or damage the pofanontiy dmae. Signs tad Symptom Cough. tightness in dot. short of breath. Cherniak - SSct; tsbema. f. Keprodnctlvc toxin Cherniak thtt affect the reproductive capabilities nsdudrnp ehromotomtl damage (muutiom) end effect! oe fetuses (teraiopenan). Signs and Symptom - Birth defects; sterility. Chemiab - Lead. Dibutyl ehioraphenot (DBCP). f. Cutaneous htarfc-Cherniak which affect the dermal layer of the body. Signs and Symptom - Defatting of the irc rashes irritation. Cherniak - Ketones chlorinated compounda h. Eye hoards - Chemkak which affect the eye or ritual apacity. Signs and symptom Conjunoiviti*: comeal damage. Cherniak Organic solvents; adds. Tarpet Orpan Toil* - A toxic substance that attacks a specific otpan of the body. For example, overeapocure to carbon tetrachloride on atae liver damape. TCC Tap (Tapliabue) Doaod Cop. See Flash Bonk. TCL Tosie Concentration Low, the lowtal concentration of a pas or vapor capable of producing a deftoed toiic effea hi a unified lest tpcoes over a specified time. TDl Toxic Doae Low, lowed administered dote of a material capable of producing a defined lose effect in a feocificd led ipecim Temp - Temperature. Ter-See Teratogen. Tentopcn-A suhatarm or agent, expamtre to which by a pregnant female, can result in miUormatioat in the feme. Tfi-Toxic effectfiV Thermal Deeomporittoa The breakdown of a material when hated. Threshold Limit Vtfee. TLV and PEL TV Threshold Unit Value (TLV) B a wfe txpoaure levei in by the American Conference of Governmental Industrial Hijienots (ACGIH1. A FermusiHe Expcaure limit IPEL1 h a similar level set by OSH V. fceh refer * sirterte ;c ecatnccn? ?f mbstaoca xnd me ue.n in evtvrure fevd mte ha4 most meek ao rnx trnagiy fer * tcvtm s a-.31 ite ixy. writ "to inraftd Jeus-Thre nregTiq dlLV* ne rvmV v Twm ^mtouad VmW 'Ut-niM T* a be --v-- ^ \ yr*i ' ***0 * -11.^ g* -rt t* names* v*mx (b) Shoet-Tem-Expoanre Umh (TLV-STELl This is the maximum concentration to which workers an be etpoacd for 1 penod up tn IS minutes continuously without sufferinp from (I) remanon. (21 chronic nr irreversible thaue change. or (31 narcoxk of sufficient degree to impau etf-rexcue or reduce work efficiency. No more than (our IS-mmute exposure periods per day are permuted with at least 60 minutes between thaee cxpocure periods. (e) Cedbip (TIV-C) - The concentration that should not be exceeded even momentarily. NOTE; IT any of the above TLV$ is exceeded, a potential haxatd ftom that substance is presumed to tiki Thmhna A ringing or singing sound in the on. TLV - See Threshold limn Value. TOC - TAG Open Cup. See Rash Point Tost A anil of pressure, eqtml to 1/760 atmosphere. Toxemia - fuwoorop by way of the blood stream Toxic - A chemical faUmp within any of the following' atepories: (a) A chemktl with a median lethal dose (LDSOI of more than 0 mifliptams per kflopwn but not more than 500 milligrams per kilrgtarn of body weipht when ndminisured orally to albino rats weiphmf between 200 and 300 prams cock. (b) A chemical that his a median lethal dose (LDSOl of more than 300 milliprarm per kflopram but nor more than 1.000 mi11i|raira per kilogram of body weipht when administered by continuous contact for 21 hours tot lea if death occurs within 24 hours) with the bare skin of albino rahhus weiphinp between two or three kilograms each (c) A chemical that has 1 median lethal concentration (LC50I m air of more than 200 pare per million but not more than 2.000 pans per million hv volume of pas or vapor, or more than two milligrams per liter hut not more than 20 nrittipnm per trier of mat fume, or dun. w hen adminturred by continuous inhalation for one hour (or lea if death occurs within one hour) to albino rats weighing between 200 and 300 grams each Toxic Substance - Any substance which an cause acute or chronic injury 10 the human body, or which a suspected of being able to cause dtwascs or injury under some oondmora. Toiletry The sum of idverse effects resulting from exposure to s mitrnil. generally by the mouth, skm. or respiratory tract Trade Name - The trademark name or commercial trade name for a material or product Transpiacesitil - An agent that causes physical defects in the developing rmtmo TSCA - Toxic Substances Control Act (Federal Environmental legislation administered by EPA) regulates the manufacture, handling, and ux of matmals daaified as "toxic substances.' TWA Time Weighted Avenge exposure is the airborne concentration ol a material to which a person o exposed, averaged over the total expnsute time, generally the total workday (i to 12 hours). Ako see TLV. UEL or UFL - Upper Explosive Limit or Upper Flammable Limit of a vapor or gas; the highest concentration (highest percentage of the substance tn aul that will produce a flash of fire when an ignition source (hat. arc. or flamel is piesem At higher concentrauom. the mixture a too "rich' to bum Abo see LEL UG Mierogram. one-raJliumb -if 1 grim. IsackWr . Tseng e-in retro rr rcer j-v.1r.-31 .r.e- _ baag-sevant n-n*--g -r aiue. Cuodt Vaan - ` re=r=1 sc. e -ae at - - ....... DE 008476 USDA - US Department of Apriodtare. llttras - A tntaeufar orpaa which hohk tad nourishes the frown* fens. Vapor - The p*eota font of a solid at liquid suhstuee to H evipomex Vapor dtnrity-The wtipfat of a vapor or pas compand to the wdftii of an equal volume o( ait is am exprtsrioe of the density of the vapor or in. Materials Kphter than air kavr vapor deniiosi lea than 1.0 (etaaspto: acetylene. methane, hydropen). Materials heavier than air (exampfcc propane, hydrofen sulfide, ethane, butane, chlorine, sailor dioxide) have vapor dceriact prater than 1.0. Ah vapon and pxscs *31 nix with air, bat the fiphter matenah wifi tend to ise and dissipate (unless confined). Heavier vapon and pates are Btdy to concentrate m low places--atonp or under toon. in sumps, seven, and manhole*, in trenches pod ditches--where they may create fire or heakh hazards. Vapor petaaart The prtsnre exerted by a sstnrited vspor above its own liquid in s doted eontamet. When quaKfymp control tots are performed on products, the test temperature is ususfiy I0CTF. and the vapor piemure is expreaed a pouts* per square inch (psag or pda), hot vapor prana reported on MSDSs srt in miHttneters of mercury (mmHp) at 6I*F(20* C), unless toted oiberwae. Three Isas ere important to remember 1. Vapor pressure of a substance at IOO*F wiD always be bipher that the vspor praaure o( the sufaBsaee at fil*F (20*C). 2. Vapor pressure reported on MSDSs is mmHp art usually very low ptemure; 760 mmHp is equivalent to 14.7 pounds per square inch. 3. The lower the boilinp point of substance, the bipher as vapor pressure. VrnHhrtau See Genera! Exhsost. Local Eihaust and Mechanical Ethaust Ventfletroo. VenaicaMe An expanded naa (hydrated maptraium-ahinimum-ttoe silicateI tasd as sorbeat lor spK control and dean-up. Vcrt%e-A fcehnp of revolvinf in space; dizziness fiddmo. Vheeahy Resbttnce to flow exhibited by a fiurd. VoiaOby A measure of how quickly a substance forms s vapor at otdmarv ttnptdtm Water Dispoaai Methods Proper disposal methods fix contaminated material, rtcovsitd Squids or solids, and thesr containers Water-Reactive A chemical that reacts with water to release a pxt that n either flammable or preacnq a health hazard. Work Area-A room or defined space in a workplace where hazardous chemicals are produod or ant aad where employees are proem. Workplace - Aa esubiubmeat at one peopraphical location containtnj one nr more wort arras Zinc Faaw Fever - A condition broupht on by inhalttion of sine otide fume characterized by flulike symptoms with a metallic taste m the mouth, couyhmp weakness fetipwe. muscular pun. and nausea, followed by fever and chills The onset of symptoms occur four to twelve houn after exposure. I h 92 DE 008477 employee TRAININC 00 O 8 Hazard Communication: An Employee Training Log i American Subcontractors Association, Inc. M Associated Builders and Contractors, Inc. National Association of Home Builders pE 008479 Jazard Communication: An Employee Training Log A component of Hazard Communication: A Compliance Kit for the Construction Industry Published by American Subcontractors Association Inc. Associated Builders and Contractors Inc. National Association of Home Builders Inc, i These associations hove joined in sponsoring die compliance kit: ADSC: The international Association of Foundation Drilling Contractors Air Conditioning Contractors Association American Fire Sprinkler Association American Road and Transportation Builders Association American Rolling Door Institute Associated Landscape Contractors of America Associated Specialty Contractors Association of the Wall & Ceiling Industries-international' Ceiling and interior Systems Construction Association Concrete Sawing & Drilling Association Door & Operator Dealers Association Independent Electrical Contractors Insulation Contractors Association of America National Association of Cold Storage Contractors National Association of Minority Contractors National Association of the Remodeling Industry National Glass Association National Hispanic Association of Construction Enterprises National Ornamental is Miscellaneous Metals Association National Utility Contractors Association Systems Builders Association Women Construction Owners and Executives USA Copyright 01989 by the American Subcontractors Association, the Associated Builders and Contractors, and the National Association of Home Builders. All rights reserved. DE 008480 Foreword This training log is one of five components that make up the education package titled "Hazard Com munication: A Compliance Kit for the Construction Industry." This full compliance kit was produced jointly by the American Subcontractors Association (ASA), the Associated Builders and Contractors Inc. (ABC), and the National Association of Home Build ers (NAHB). It is intended to assist construction employers in meeting the requirements of the Occu pational Safety and Health Administration's (OSHA) Hazard Communication Standard. Although not a requirement of the Standard, re cordkeeping of employee training sessions has been strongly recommended by OSHA. If inspected, the employer who uses this log will be able to provide record of ongoing employee training. In addition, the log serves as a convenient reference tool for the employer who must juggle training for many differ ent employees during the course of the construction season. HOW TO USE THIS LOG The log provides space to record the training of four employees per page. For quick reference, the log includes room at the top of each page to record the dates of training covered on that page (e.g.. front June 4, 1989 to June 10, 1989). In addition, there is an alphabetical cross-reference at the back of the log to assist you in quickly locating all training sessions attended by a particular employee. For this reason, it is important to record the training of only four employees per page, and then also log each train ed employee's name in the cross-reference sec tion. (When training several employees at a session, we recommend that you fill out all information for one employee, then write "SAME AS ABOVE" for all other employees who attend that same training session.) For more information regarding this or other com ponents of the Compliance Kit, contact one of the three sponsoring associations: American Subcontractors Association 1004 Duke Street Alexandria, Virginia 22314 (703) 684-3450 Associated Builders and Contractors, Inc. 729 15th Street, N.W. Washington, D.C. 20005 (202) 637-8800 National Association of Home Builders, Inc. 15th and M Streets, N.W. Washington, D.C. 20005 (202) 822-0200 i( DE 008481 CHAPTER FOUR Employee Training All employers are required to train their employees on hazardous chemicals in their work area at the time of their initial work assignment and whenever a new hazard b introduced into the workplace. Additional training, how* ever, b not necessary when you substitute one brand of a product for another. The heart of HazCom b employee training, because employees need to know the hazards they will encounter on thejob and then accept responsibility for using thb informa tion to protect themselves. No employer can police every action of hb employees, therefore, an important part of any training program should be impressing upon employees that thb information b provided so that they can assist in creating a safe workplace. Although HazCom does not require extensive record keeping of training sessions, it b strongly recommended that the time, place, names of employees trained, and content of all hazard communication training sessions be documented. Employees should sign an attendance sheet indicating that they attended specific sessions. The following b a model employee training program that you can adapt for your company's use. In addition, your national association has developed a companion training video which can assist you in fulfilling your training obligations. Contact your association for further information. A Model Hazard Communication Employee Training Program Our employee training program has been developed on the basis of groups or types of hazardous chemicals used and the common hazards associated with the group or type of chemicals. (See the chapter in this manual entitled "Common Hazards on Construction Sites.") For specific hazard information on individual substances, the Material Safety Data Sheets (MSDSs) must be reviewed. The training will cover the following: 1. An overview of the hazard communication requirements. 2. A review of fhe chemicals present on jobsites. 3. The location, availability and contents of our written hazard communication program and MSDSs. 4. How to detect the release or presence of hazardous chemicals in the work area. 5. Physical and health hazards of the chemicals in the work area. 6. How to lessen or prevent exposure to hazardous chemicals by using good work practices, personal protective equipment, etc. 7. Emergency and first aid procedures. 8. How to read labels and MSDSs to obtain hazard information. 9. The location of our MSDSs. Overview of the Hazard Communication Requirements The Hazard Communication Standard (HazCom) is intended to ensure that both employers and employees are aware of potential hazards associated with chemicals in their workplaces, (Chapter One of this manual provides a summary of the specific requirements of HazCom.) Chemicals on JobeRet We use a variety of products. Many of these products contain one or more hazardous chemicals Most of the products we use can be grouped by their basic function or use. We will discuss which products fit in each group and will identity the associated hazards and how to detect and control them through engineering or administrative controls, as well as through l As noted In theforeword to this manual, the participating associations are presently involved in o legal challenge to the Hatard Commumcanon Standard. Pending the resolution ofthis litigation, the partaparmg associations make no warranty ttet the information contained herein will necessarily he accepted hr ()SHA II DE 008482 the use of personal protective equipment A list of the chemicals potentially found on our sites is attached to our written hazard communication program. (See the chapter entitled "Common Hazards on Construction Sites" for more details on this.) Written Hazard Communlcatfon Program We have a written program that outlines how we will provide you with information about hazardous workplace chemicals. It is our company policy on hazardous substances. Among other things, it includes: a a list of hazardous substances on our jobsites, e our procedures for maintaining MSDSs. e our employee training program. a a statement outlining how information will be exchanged among contractors on our worksites. . Physical and Health Hazards of Workplace Chemicals You will be trained about the hazards of chemicals in your work areas. (This may be done by category of hazards, but the employee should be made aware that information is available on the specific hazards of individual chemicals through Material Safety Data Sheets.) The training will include the following information: the measures you can take to protect yourself from the hazards; our company procedures that provide you with protections, such as work practices, personal protective equipment, engineering controls, etc.; the physical and health effects of the (groups of) chemicals; a how to detect the presence of a chemical; and a general emergency and first aid procedures. How to Read Labels and Malarial Safety Data Sheets Labels: You should read product labels before working with a hazardous substance. Each label will have the identity of the hazardous chemical and a hazard warning. Original container labels will also have the name and address of the manufacturer. The label should serve as a reminder of the information we are presenting in this training sessibn and of the information found in more detail on the Material Safety Data Sheet It is essential that you read the hazard warning and use the chemical as prescribed by the label. If you have questions about a specific label, ask your supervisor or refer to the MSDS. Material Safety Data Sheets: MSDSs provide a great deal of information about the chemicals we use. The chemical manufacturers are responsible for providing us with MSDSs. MSDSs for chemicals potentially found on our worksites are available ------------ (joejjion)________ (Refer to Chapter Five of this manual for information about how to read and understand MSDSs.) t 12 DE 008483 t r a in in g sessio n DE 008484 IVaiiiing sessions from____s/-2- fj- & (taw lo tPlA/ltO G/U2-A Employee'* t //-ZC-?/ Date of training Jobsuite (iItf appliicaboltec); AUi/lT . oSuuobssiatannccceaarn/haazuarod* cccoveted / c>.S< C/StAJUTT Department traineafa) .. J?'p//lA ToMS 2 />Jtc T(TeTJt/ Special precautionary requirement* covered Emrloyee'i aignatore atleating tqjme training 6 c t*/sa/<S> . /AZ6'9/ Date 4AJTO/U/Q <ZfjiSA/Z A Employee'* name 0*06. ZJ JnbftltC (If SppHetble) . Alaejj7 at aj4o 24 /icj.s. Department trainer(a) //'ZC~9/ Date of training Ac/MSUA1 oSubnsutnancccessm/hiazards covered 6AAm err #/>//(ATOMS f PtOTfC-r/i'iS Special precautionary requirement! covered *4yii.PVllb C e. Employee* signature attesting to the training Date SAastos J?AjAv/D //'Z'<r/ Employee's name Date of training 810C. ZS3 Jobsite (if applicable) ^LAT DDefMpafrttmmpeHntt ItrraaiSnetmr(fsr)t CM/io/pt/v/yi _S_u_b_s_ta_n_c_evs/hazards covered /0J.S.(SA/Laj-7T ASSfi/MPToAS 4 SAiT^cry** Special precautionary requirements covered Entptoyeajrtignatore attesting to the training *- dr-~v^lyV^frT< rr /A^>?/ Date A) >>*, ______________________i/'Z ?/ Employee's name Date of training 8LO<Zlf? Jobsite (If applicable) Substsnces/hszards covered dL&M7 Hi'&JAoZP /Uj.S. CA)Aa>7T Department trainerfa) ' JZfsPMProMs r fAtrecT/vf ^ c tvsajQ Special orecautionary1 requirement! covered rVii/, A I <Vrv\______________ Employee* signature attesting to the training //2C 'fJ Dale DE 008485 IVaiiiing sessions from //~24.r. 9/ lO //-2-t-?/ W** Pd6>vL 6&AJU6r-l- //-ZC'<7/ Employee* name Date Of training %/)<*. 2S? Jobsmitee (vI*f applicable) CM#C At/ ti sn t oSuubwstanncccevs/fhWac(aridw* vcoveted amc/ir Department trainerfs) s> CAJPajCTT #ffis#/}Tt>Z PjiCTreer/t/ CCc -r*//Aj4-. Special precautionary requirements covered /M26'<9 / Employees signature attestmy to the training Date /HAAJOt. t/4Z<S>V2Employee'* name Date of training 06. ZSJ J>obvwftfitt.ev (iIfi t-pnpMH.ct-btie.w) CM#o/msuA4 . dSouubnstinanccesms/hi amds covered /)L0Jt7 A? 4/Jo 34/ 6lJ. S. M/tAJ tfTT Department trainer(s) JjZffJL&A. CAXteS D/A2- Employee'i name Date of training Bi. DC. ZS9 CM#oH4/<//V} Jobsite (If applicable) Substtnees/hizirds covered MJ&A.T >Q/&.S. CAfLufTT Deptrtmenl frtinerfs) ' #/>/*4 reAS 4 Special precautionary requirements coveted Ccarj/SMC. X.. tgA-r i>% htA"7 Employee* ai|nattire attesting to tbe traimnj //'2~9/ Date C/)*L toeicl Employee's name jLOCZCf Jobsite (If applicable) Mj#r Jou.S. Department trainer(s) r />#*ret7-svf Special pricabtlMiar require ns covered u jULL Employee's signature attesting to the training //~U' 9/ Date of training CMto M) VM Substances/haurds covered //-2'f/ Date DE 008486 Tbinin? sessinns from - ^ ~ ^2/- 27" 0** to 2-%L- 9<L-- l)jSf w.. GARv&tt . /- 27'?Z~ Employee's Mine Date of training ( 7S9 Acc jvarTAjefr/juatags>s /wevroty &/? jobsite (if applicable) Substances/haards covereda/a t/tjPo v S C/SArtf**ca cy^/c'^ act #t0 S/*tfS /At tS/S ZZaeM /m rats 0**k Department trainer(a) Speci itftKgpdbnary requirements cmaered Employee's signature attesting to the training ____ P/9u/ /?laA/e> Employee's Mine jobsite (if applicable) ins. Department trainees) zsr ......... A)..GA&aJZTT Special precautionary requirements covered Employee's signature attesting to the training J *2 7-5 2^ Date Date of training 2 - 2 C-f-L Substanees/hazards covered MA Z t)Zl) v*/t C&7~/ S' l -2c- T Dale A/a lZft? ZdULL&A}__________ Employees name jobsite (if applicable) zsy <ks. s. a/itvarr Department trainees) Special precautionary requirements covered Employee's sigMture attesting to the training Date of training 7//JZ22P CS> *** * v/tt 2ti T/ & tv Substances/hazards covered Date .-X4 /1 ut'i Employee's name e z. jobsite (if applicable) Dvb Ps/A/err Department trainer(s) Sp cial precautionary requirements covered tployees signature attesting the trainine Z-Z7- 7^ Date of training MZ-/23D C 0 Ml/4770AS Substances/hazards covered Z-27- 7 Z DE 008487 IVauiing sessions from f Employee* name ff\-&}'{fau^A Jobsite (If applicable) #46. 2-^9 Department trainees) ZcZ. . Special precautionary requirements covered Employee'* signature attesting Z s4J? /? ?2- Aft** t/Af'S* 7' 0 to z - ZV' TZUm Dele of training 2-ZV"~?ZSubstances/haurds covered /)Zc ZiJfisf'AjVt'Z s' /& sAcjye*' fi(*. AUjL____ j&uisJ?CLJzf-__________ Employee* name Date of training Jobsite (if applicable) 2*2 & 2 <rf Department trainer(s) &-S- Special precautionary requirements covered :st^j^)J^remm| ^ Employee's signature attestij A< S!/ AAA A___ fj-.^z> Employee's name Jobsite (if applicable) 3i#c zs9 Department trainer(s) Special precautionary requirements covered Substances/haurds covered Att Xl>AtT&jUr S S# SA A' 0vt/vit/&/A Dale -4 v- Date of training 2 tv Substances/haurds covered die <r^S rAAAS f /AJ /hZ)S S<-7''&*' M A2Zj? nr/** VA//A T/&4J Employee's signature attesting to the training X-. H. LJaG^NEKL- Employee's name Jobsite (if applicable) 3lC %'2 Sf Department trainer(s) 4^ -5, 77 ry requiremmeenets coverned Date Date of training ZA9-7-L Substances/haurds covered A) l ^ jr`i>srA4<? s*S 0fQ>C SAZrrW P 6-tr* t* s < C * -77 4 tj ees signature attesting to the UMning Date DE 008488 IVainingsessions from 2 ---------- lo --2 't-*'. Z,~. Employee's name Jobsite (If applicable) fate. zS9 Department trainees) 7L Special precautionary requirement! covered . ______ Entpoyees signature attesting (o the training Date of training Z-Z*-7 Z-______________________________ ______ Substances/hatards covered jf/f 2J0 C* ** ^ ^6 /i^C <Li>#X,r2x/<:&* /A> S<7?oas Date /?AM #1._____j&AJP.LtAA. Empfoyee's name Jobsite (if applicable) _________________t-J><Z ZS'f Department trainees) 6J. jC. 6/9XajT'T Special precautionary requirements coveted Employee's signature attesting to the training Date of training _____ __________________________________________ Substances/hatards covered s4tc ujS72>AJr.`3 ''0 /**>Z SAC 7' <2*0 ______________ //42Z4J?D t6n**to<//4rA-rso/S _____________ ^ - a. h -9 __________ Date A&Jie- 2?. f/SMerz Employee's name Jobsite (if applicable) 3ts>c zs9 Department trainerfs) Special precautionary re covered fs signature attesting to the training Date of training 2 LV f'2'_________________________________________ Substances/hatards covered fjSjgsrziA/s<s /XJ /JdZAZD fete** </a/ic&__________ ______________ ^ -g^a,_______________________ Date a a/ Employee's name Orfy/t Z& $ Jobsite (if applicable) faz>c %iz sf Department trainees) 42-S, &/92xJ 77~ Special Mlmionary requirements covered Employee's signiture attesting to theifaining Date of training ZIV'9^ Substanees/hazards covered A i ^ jrt>*rz*J<? 07j>r Date 3. DE 008489 lainin sessions from Z 2 7-? 2Oat to <7/72to 2 Employees name $J>6. Z-^? Jobsite (if applicable) D/jJ? 64/lA;rr Department trainees) Date of training Substances/hazards covered SMetaOprecimtionaMQrequiremenU covered *^jUsrr%4L.Aj*2s. Employee's signature attesting to the tqjping <3--- 3-7 Date IMc ($SZ3A7'c> <&>y>2Employees name 3?tj)G zsy Jobsite (if applicable) Department trainer(s) Special precautionary requirements covered ^ AfJ Employee'Aignature attesting to the training 2-Z 7- fZDate of training M624AJ) Substances/hazards covered -TV CAJjZ z - 2. to* ~2-- 2.-27- 7Z __ Employees name Jobsite (if applicable) Department trainer(s) Special precautionary requirements covered Employee's signature attesting to the training Date of training Substances/hazards covered Date Employee's name Jobsite (if applicable) `l Department trainees) Special precautionary requirements covered Employees signature attestina to the trainint Date of training Substances/hazards covered Date DE 008490 lYaming sessions from Employee's name Jobsite (if applicable) Department trainerf*) Special precautionary requirements covered Employee's signature attesting to the training to ttatt Date of training Substances/hazards covered Date t Employee's name Jobsite (if applicable) Department trainees) Special precautionary requirements covered Employee's signature attesting to the training Date of training Substances/hazards covered Date Employees name Jobsite (if applicable) Department trainees) Special precautionary requirements covered Employee's signature attesting to the training Date of training Substances/hazards covered Date Employees name Jobsite (if applicable) < Department trainees) Special precautionary requirements covered Employee's signature attesting to the training Date of training Substances/hazards covered 3 DE 008491 TVaininc sessions from Employees name Jobsite (if applicable) Department trainees) Special precautionary requirements covered Employee's signature attesting to the training to tfcie Date of training Substances/hazards covered Date Employee's name Jobsite (if applicable) Department trainees) Special precautionary requirements covered Employee's signature attesting to the training Date of training Substances/hazards covered Date Employees name Jobsite (if applicable) Department trainees) Special precautionary requirements covered Employee's signature attesting to the training Date of training Substances/hazards covered Date Employee's name Jobsite (if applicable) l Department trainees) Special precautionary requirements covered Employee's signature attesting to the training Date of training Substances/hazards covered Date 3 DE 008492 TVaining RMonns from Employee's name Jobsite (if applicable) Department trainees) Special precautionary requirements covered Employee's signature attesting to the training tn Dtte Date of training Substances/hazards covered Date Employee's name Jobsite (if applicable) Department trainees) Special precautionary requirements covered Employee's signature attesting to the training Date of training Substances/hazards covered Date Employee's name Jobsite (if applicable) Department trainees) Special precautionary requirements covered Employee's signature attesting to the training Date of training Substances/hazards covered Date Employee's name Jobsite (if applicable) Department trainees) 1 Special precautionary requirements covered Employees signature attesting to the training Date of training Substances/hazards covered Date Date DE 008493 IVaininP sessions from Employee's name Jobsite (if applicable) Department trainees) Special precautionary requirements covered Employee's signature attesting to the training to Dmt Date of training Substances/hazards covered Date Employee's name Jobsite (if applicable) Department trainees) Special precautionary requirements covered Employee's signature attesting to the training Date of training Substances/hazards covered Date Employee's name jobsite (if applicable) Department trainees) Special precautionary requirements covered Employee's signature attesting to the training Employee's name Jobsite (if applicable) Department trainees) i Special precautionary requirements covered Employees signature attesting to the training Date of training Substances/hazards covered Date - Date of training Substances/hazards covered D*r DE 008494 Ifcliniiig sessions from Employee's name Jobsite (if applicable) Department trainees) Special precautionary requirements covered Employee's signature attesting to the training tn Date Date of training Substances/hazards covered Date Employee's name Jobsite (if applicable) Department trainees) Special precautionary requirements covered Employee's signature attesting to the training Date of training Substances/hazards covered Date Employee's name Jobsite (if applicable) Department trainees) Special precautionary requirements covered Employee's signature attesting to the training Date of training Substances/hazards covered Date Employee's name Jobsite (if applicable) I Department trainees) Special precautionary requirements covered Employee's signature attesting to the training 6 Date of training Substances/hazards covered Date DE 008495 DE 008496 W U k SSOHD V f c m Envioyct'i MR Alphabetical Cross-Reference AD Fite Nvtn Employe** mmt Pap N*ei Employee'! ntnc B Pfe Number Employee'! Mine E Pift Number Employee'! mm C Pi|t Number Employee! Mine F Pipe Number I 79 DE 008497 Employe'* ** Alphabetical Cross-Reference GJ Fife Number Employe* mm Fy Number Employe*'* mmt H Fife Number Employe* K Fife Number Employ* i mm I ft|t Number Employe* L Page Number I 80 DE 008498 Employtt't Alphabetical Cross-Reference Mp h|t Number bifki^m Mint fage Number Employee! mmt N faft Number Employee* Q fijt Number Employee) 0R fife Number Employee'* uuo* fife Number 4 81 DE 008499 Emp*oyt' mmt Alphabetical Cross-Reference S hp Number Employee v fife Number Employees mim T P|t Number Employee's W h|f Number Employee'* umc U h(t Number Employe's' X Peje Number T 82 DE 008500 Es*toyM'> mm Alphabetical Cross-Reference Yz h*t NmMt E9<oj'i Mme fip N>Mn I B3 DE 008501 MSDS D E 008502 BJilt' Healthcare Corporation Burdick & Jackson Division 1953 Souin Harvey Sireel Muskegon Ml 49442 USA information/emergency telephone no 616 726 3171 cnemtrec ieieonone no 800 424 9300 Canadian emergency telephone no 613 996 6666 MATERIAL SAFETY OATA SHEET I. Identification _ cnemicai name -----------^sm________ chemical family_______ Aliphatic Hydrocarbon Synonyms___________ n-Hexane______________ DOT proper snipping name Hexane_________________ DOT hazard class______ Flammable Liquid DOT identification no ---- UNI 208 ______ moiecmat weigh! 86.T 8 formulaCfiHm CAS no 110-54-3 HEXANE II. Physical and Chemical Data boiling pomi. 760mm Hg 68.7C freezing point~953Cevaporation rate (BuAc= 1) ca 10 vaoor pressure at 20C tj volatiles by volume . 124 mm Hg vapor density (air=l) 3.0. solubility in water @ 20C 0.014?c ca 100 specific gravity (H.0= 1) <3 20C 0.659 stability_______________________ hazardous polymerization Not expected to occur._____________________________________ aooearance and odor conditions to avoid Clear, colorless liquid with a mild hydrocarbon odor._____________ Heat, sparks, open flame, open containers, and poor ventilation. materials to avoid Strong oxidizing agents. hazardous decomposition productsIncomplete combustion can generate carbon monoxide and othertoxic vapors. ill. Fire and Explosion Hazard Data ... , --... .. ............. Mash point, itest method)~26C (Tag closed cup)aut0 ,gnitron temperature flammable limits in air % by volume: lower limit - ^upper limn unusual fire and explosion hazards_________Very volatile and extremely flammable.______ 22SC 7.S extinguishing media Carbon dioxide, dry chemical or foam. special fire fighrmg procedures Water will not be effective in extinauishina a fire and may spread it. but a water spray can be used to cool exposed containers. Wear full protective clothing and self-contained breathing apparatus. Heat will build pressure and may rupture closed storage containers. IV. Hazardous Components - - Hexane and isomers%______________________________ ca 100 7|_y SO ppm________ no 110-54-3 ''urdick & Jackson's Disclaimer: The information and recommendations presented in this Material Safety Oata Sheet are based on sources believed to ,e reliable on the date hereof. Burdick & Jackson makes no representation on its completeness or accuracy it is the user's responsibility to determine the product s suitability for its intended use. the product's safe use. and the product's proper disposal No representations or warranties, either express or implied, of merchantability or fitness for a particular purpose or of any other nature are made with respect to the information provided in this Material Safety Data Sheet or to the product to which such information refers. Burdick & Jackson neither assumes nor authorizes any other person to assume for it. any other or additional liability or responsibility resulting from the use of. or reliance upon, this information DE 008503 V. Health Hazards Occupational Exposure Limits - OSHA TWA STEL Ceiling 50 ppm not listed - not listed ACCIH TLV-TWA 50 ppm TLV-STEL - not listed (15-min) NIOSH 10 hour TWA- 100 ppm 15 min Ceiling -510 ppm Concentration Immediately Dangerous to Health OSHA/NIOSH 5,000 ppm Odor Threshold NSC NIOSH not listed not listed Carcinogenic Data Hexane is not listed as a carcinogen by IARC, NTP, OSHA, or ACCIH. Primary Routes of Entry Hexane may exert its effects through inhalation, skin absorption, and ingestion. Industrial Exposure: Route of Exposure/Siqns and Symptoms Inhalation: Exposure can cause dizziness, numbness of extremities, and into, !tion. Eye Contact: Liquid and high vapor concentration can be irritating. Skin Contact: Prolonged or repeated skin contact can cause irritation and dermatitis through defatting of skin. Ingestion: Can cause gastrointestinal tract discomfort. Effects of Overexposure Hexane is a mild eye and mucous membrane irritant, primary skin irritant, central nervous system depressant and neurotoxin. Acute exposure causes irritation, narcosis, and gastrointestinal tract irritation. Chronic inhalation causes peripheral neuropathy. No systemic toxicity has been reported. Medical Condition Aggravated by Exposure Preclude from exposure those individuals susceptible to dermatitis. DE 008504 Storage: Hexane should be protected from temperature extremes and direct sunlight. Proper storage of hexane must be determined based on other materials stored and their hazards and potential chemical incompatibility. In general, hexane should be stored in an acceptably protected and secure flammable liquid storage room. Other: Emergency eye wash fount.-ins and safety showers should be available in the vicinity of any potential exposure. Ground and bond metal containers to minimize static sparks. VII. Spill and Disposal Data________________________________________________________ Spill Control: Protect from ignition. Wear protective clothing and use approved respirator equipment. Absorb spilled material in an absorbent recommended for solvent spills and remove to a safe location for disposal by approved methods. If released to the environment, comply with all regulatory notification requirements. Waste Disposal: Dispose of hexane as an EPA hazardous waste. Contact state environmental agency for listing of licensed hazardous waste disposal facilities and applicable regulations. Hazardous waste number: DOOI(lgnitable). VIII. SARA/Title III Data Hazard Classification Imme." ate Health Yes (irritant) Delayed Health Yes Fire Yes Sudden Release No Reactive No Chemical Listinqs Extremely Hazardous Substance CERCLA Hazardous Substances Toxic Chemicals No No N'o Hexane is not subject to the reporting requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA) and 40CFR Part 372. This product does not contain any other toxic chemical above 1concentration or a carcinogen above 0.1 % concentration. Revision Date: July, 1989 KEY ca Approximately na Not applicable C Ceiling STEL TLV TWA BuAc Short Term Exposure Level (IS minutes) Threshold Limit Value Time Weighted Average (8 hours) Butyl Acetate CERCLA Comprehensive Environmental Response, Compensation and Liability Act NSC National Safety Council ("Fundamentals of Industrial Hygiene," 3rd. Ed.. 1988) DE 008505 Emergency First Aid Inhalation: Immediately remove to fresh air. If not breathing, administer mouth-to-mouth rescue breathing. If there is no pulse administer cardiopulmonary resuscitation (CPR). Contact physician immediately. Eye Contact: Rinse with copious amounts of water for at least IS minutes. Get emergency medical assistance. Skin Contact: Flush thoroughly for at least 15 minutes. Wash affected skin with soap and water. Remove contaminated clothing and shoes. Wash clothing before re-use, and discard contaminated shoes. Get emergency medical assistance. Ingestion: Call local Poison Control Center for assistance. Contact physician immediately. Aspiration Hazard - Do not induce vomiting. Safety Measures and Equipment Ventilation: Adequate ventilation is required to protect personnel from exposure to chemical vapors exceeding the PEL and to minimize fire hazards. The choice of ventilation equipment, either local or general, will depend on the conditions of use, quantity of material, and other operating parameters. Respiratory: Use approved respirator equipment. Follow NIOSH and equipment manufacturer's recommendations to determine appropriate equipment (air-purifying, air-supplied, or self-contained breathing apparatus). Eyes: Safety glasses are considered minimum protection. Goggles or face shield may be necessary depending on quantity of material and conditions of use. Skin: Protective gloves and clothing are recommended. The choice of material must be based on' chemical resistance and other user requirements. Generally, neoprene or nitrile rubber offer acceptable chemical resistance. Individuals who are acutely and specifically sensitive to hexane may require additional protective equipment. DE 008506 Vi \ t ; ' , rCsZtL.) . fjg /ro y -::L MATERIAL SAFETY DATA SHEET 0HS02110 I CC 'IONAL HEALTH SERVICES. INC. 0 StVENTH AVENUE, SUITE 2407 -:w YOR*:-, NEW YORK 10123: 300) 445-iisDS <212> 967-1100 EMERGENCE CONTACT*. JOHN 3. BRANSFORD, JR. (615) 392-1 i?.': SUBSTANCE IDENTIFICATION JBSTANCE: ASBEST03 CAS-NUMBER 1332-21-4 RTEC-NUMBER Cl6475000 <ADE NAMES/SYNONYMS: ASBESTOS FIBEFf: ASBESTOS FIBRE* CHRYSOTILE: CROC IDOL I TEs ACTlNOLITEl AM0S1TE: ANTHOPHYLITE1 TREMOLITE CALIDREN HPP: CAL I DR IA R C 244: CHLOROBESTOS 25: FAFM 410-120: FERODO CSC: 0HS02110 (EMICAL FAMILY: FIBROUS SILICATES !RCLA RATINGS (SCALE 0-3): HEALTH=3 FIRE-0 REACTIV1TY*0 PERSISTENCE'S PA RATINGS (SCALE 0-4): HEALTH*3 FIRE*0 REACTIVITY0 COMPONENTS AND CONTAMINANTS IMPONENT: ASBESTOS FORMS MAY INCLUDE: PERCENT: 100 IMPONENT: AMOSITE CAS# 12172-73-5 iMPONENT: ACTINOLITE CAS# 77536-66-4 IMPONENT: ANTHOPHYLITE CAS# 77536-67-5 MPONENT: CHRYSOTILE CAS# 12001-29-5 'MPONENT: CROCIDOLITE CAS# 12001-28-4 MPONENT: TREMOLITE CAS# 77536-68-6 HER CONTAMINANTS: NONE POSURE LIMIT: ASBESTOS: 0.2 FIBER 05.0 MICRONS IN LENGTH)/CC OSHA TWA (ALL FORMS) 1.0 FIBER 05.0 MICRONS IN LENGTH)/CC OSHA 30 MINUTE EXCURSION LIMIT (ALL FORMS) O.S FIBER 05.0 MICRONS IN LENGTH)/CC ACGIH TWA (AMOSITE)} ACGIH A1-CONFIRMED HUMAN CARCINOGEN. 2.0 FIBERS 05.0 MICRONS IN LENGTH)/CC ACGIH TWA (CHRYSOTILE)5 ACF'`` A1-CONFIRMED HUMAN CARCINOGEN. 0.2 IBER 05.0 MICRONS IN LENGTH)/CC ACGIH TWA (CROCIDOLITE); ACGIH A1-CONFIRMED HUMAN CARCINOGEN. 2.0 FIBERS 05.0 MICRONS IN LENGTH) /CC ACGIH TWA (OTHER FORMS) ACGIH A1-CONFIRMED HUMAN CARCINOGEN. 3.1 FIBER 05.0 MICRONS IN LENGTH)/CC NIOSH RECOMMENDED 8 HOUR TWA (ALL FORMS)} DE 008507 nO>'-Ol-l??! Cr?:~ FPrn t TO O.S FIBER l-Z.O MICRONS IN LENGTH)/CC NIOSH RECOMMENDED IS . -MINUTE CEILING (ALL FORMS) 1 FOUND CERCLA SECTION ICC REFORTA&LE QUANTITY SUBJECT TO SARA SECTION 313 ANNUAL TOXIC CHEMICAL RELEASE REPORTING SUBJECT TO CALIFORNIA PROPOSITION 65 CANCER AND/OR REPRODUCTIVE TOXICITY WARNING AND RELEASE REQUIREMENTS- (FEBRUARY 27, 1987) PHYSICAL DATA DESCRIPTION! COLOR AND COMPOSITION VARY WITH TYPE OF ASBESTOS AND AREA MINES* MAY BE WHITE, BROWN, OR BLUE FINE, SLENDER, FLAXY FIBERS. BOILING POINT! 4046 F (2230 C> MELTING POINTi 3134 F (1723 C> SPECIFIC GRAVITY! 2.5 SOLUBILITY IN WATER! INSOLUBLE FIRE AND EXPLOSION DATA F"RE AND EXPLOSION HAZARD I ELIGIBLE FIRE HAZARD WHEN EXPOSED TO HEAT OR FLAME. FIREFIGHTING MEDIA! DRY CHEMICAL, CARBON DIOXIDE, HALON, WATER SPRAY OR STANDARD FOAM (1987 EMERGENCY RESPONSE GUIDEBOOK, DOT P 5800.4). e-OR LARGER FIRES, USE WATER SPRAY, FOG OR STANDARD FOAM (1987 EMERGENCY RESPONSE GUIDEBOOK, DOT P 3800.4). FIREFIGHTING! NO ACUTE HAZARD. MOVE CONTAINER FROM FIRE AREA IF POSSIBLE. AVOID BREATHING VAPORS OR DUSTS! KEEP UPWIND. TRANSPORTATION DEPARTMENT OF TRANSPORTATION HAZARD CLASSIFICATION 49CFR172.101! ORM-C DEPARTMENT OF TRANSPORTATION LABELING REQUIREMENTS 49CFR172. 101 AND SUBFART E: V'-Mg \ DEPARTMENT OF TRANSPORTATION PACKAGING REQUIREMENTS! 49CFR173. 1090 EXCEPTIONS: 49CFR173.1090 TOXICITY DE 008508 > ftgc'-'STQS; 1. .-1BEKS/CC/19 YEARS CONTINUOUS INHALATION-HUMAN TCLO; MUTAGENIC DATA (RTECS): TUMOR I GENIC DATA (PtTECS> . ACTINOLITE. AMDS HE: MUTAGENIC DATA (RTECS); TUMORIGENIC DATA (RTECS). AnTHQPHYLITE: MUTAGENIC DATA (RTECS)s TUMORIGENIC DATA (RTECS). CHftYSOTlLE* 2.8 FIBERS/CC/5 YEARS INHALATION-HUMAN TCLO; '00 MG/LG INTRAPERITONEAL-RAT LDLO: MUTAGENIC DATA (RTECS); TUMORIGENIC DATA (RTECS). CROC IDQLI TEi "00 MG/KG INTRAPERITONEAL-RAT MUTAGENIC DATA (RTECS) s TUMORIGENIC DATA (RTECS). TREMOLITE: TUMORIGENIC DATA (RTECS). CARCINOGEN STATUS* OSHA CARCINOGEN; KNOWN HUMAN CARCINOGEN (NTP>; HUMAN SUFFICIENT EVIDENCE, ANIMAL SUFFICIENT EVIDENCE <1ARC CLASS-1). OCCUPATIONAL EXPOSURE TO CHRYSOTILE, AMOSITE, MIXTURES CONTAINING CROCIDOLITE, AND OTHER FORMS OF ASBESTOS HAS RESULTED IN A HIGH INCIDENCE OF LUNG CANCER,. AND PLEURAL AND PERITONEAL MESOTHELIOMAS. GASTROINTESTINAL CANCERS WERE INCREASED IN WORKERS EXPOSED TQ AMOSITE, CHRYSOTILE, OR MIXED FIBERS CONTAINING CROCIDOLITE. AN EXCESS OF LARYNGEAL CANCER HAS ALSO BEEN REPORTED. ASBESTOS IS AN EYE, SKIN, AND MUCOUS MEMBRANE IRRITANT. SMOKING ENHANCES THE RISK OF LUNG CANCER FROM EXPOSURE. HEALTH EFFECTS AND FIRST AID INK UION: ASBbjTOS: IRRITANT/CARCINOGEN. ACUTE EXPOSURE- MAY CAUSE ACUTE IRRITATION AND COUGHING. CHRONIC EXPOSURE- PROLONGED INTENSE EXPOSURE MAY CAUSE ASBESTOSIS, AN INTERSTITIAL FIBROSIS OF LUNG TISSUE WHICH MAY DEVELOP FULLY WITHIN 7-9 YEARS, BUT ONSET IS TYPICALLY DELAYED 20-40 YEARS AFTER FIRST EXPOSURE. FATAL EXPOSURE MAY BE AS BRIEF AS 3 MONTHS DURING CHILDHOOD. THE INITIAL SYMPTOM IS A PROGRESSIVE EXERTIONAL DYSPNEA, FOLLOWED BY A DRY COUGH AND EXPECTORATION, CHEST PAIN, DECREASED VITAL CAPACITY, TACHYPNEA, PERSISTENT DRY RALES, CYANOSIS, CLUBBING OF THE FINGERS AND TOES, ANOREXIA, WEAKNESS, AND WEIGHT LOSS. RADIOLOGIC STUDIES MAY SHOW A DIFFUSE INCREASE IN LUNG DENSITY AND PLEURAL CALCIFICATION. SPONTANEOUS PLEURAL EFFUSION HAS OCCURRED IN ASBESTOS-EXPOSED WORKERS AS EARLY AS 3-4 YEARS AFTER INITIAL EXPOSURE. ASBESTOS WORKERS SHOW AN INCREASE IN PLEURAL AND PERITONEAL MESOTHELIOMAS, BRONCHOGENIC CARCINOMA, LUNG CANCER, CANCERS OF THE GASTROINTESTINAL TRACT INCLUDING THE ESOPHAGUS, STOMACH, COLON, AND RECTUM, AND CANCER OF THE LARYNX. MESOTHELIAL TUMORS ARE CHARACTERIZED BY BLOODY EFFUSION WITH PAIN, DYSPNEA, COUGH, WEIGHT LOSS, FATIGUE, HYPONATREMIA, AND DEATH. THE LATENT PERIOD FOR MESOTHELIOMA IS 3.5-30 YEARS; FOR LUNG CANCER, 15-30 YEARS. THE INCIDENCE OF LUNG CANCER AND PULMONARY FIBROSIS IN ASBESTOS-EXPOSED WORKERS IS INCREASED BY CIGARETTE SMOKING. 1RST AID- REMOVE FROM EXPOSURE AREA TO FRESH AIR IMMEDIATELY. IF BREATHING HAS STOPPED, PERFORM ARTIFICIAL RESPIRATION. KEEP PERSON WARM AND AT REST. TR' " SYMPTOMATICALLY AND SUPPORTIVELY. GET MEDICAL ATTENTION IMMEDIATELY. KIN CONTACT: 3BEST0S: ACUTE EXPOSURE- DIRECT CONTACT MAY CAUSE IRRITATION. ASBESTOS FIBERS MAY PENETRATE THE SKIN AND RESULT IN "ASBESTOS CORNS", DUE TO THICKENING OF THE SKIN AROUND THE IMPLANTED FIBER. THESE USUALLY OCCUR ON THE HANDS DE 008509 t'lTi AND FOREARMS. THESE CORNS DO NOT LEAD TO SfIN TUMORS AND DISAPPEAR ON REMOVAL OF THE FIBERS. CHRONIC EXFOSURE- REPEATED OR FROLONGED CONTACT MAY CAUSE DERMATITIS AND EFFECTS AS IN ACUTE EXPOSURE. t FIRST AID- REMOVE CONTAMINATED CLOTHING AND SHOES IMMEDIATELY. WASH AFFECTED AREA WITH SOAP OR MILD DETERGENT AND LARGE AMOUNTS OF WATER UNTIL NO EVIDENCE OF CHEMICAL REMAINS {APPROXIMATELY 15-20 MINUTES). GET MEDICAL ATTENTION IMMEDIATELY. EYE CONTACTi ASBESTOS: ACUTE EXPOSURE- DIRECT CONTACT MAY CAUSE IRRITATION WITH REDNESS DUE TO MECHANICAL ACTION. CHRONIC EXPOSURE- REPEATED OR PROLONGED EXPOSURE MAY CAUSE CONJUNCTIVITIS. FIRST AID- WASH EYES IMMEDIATELY WITH LARGE AMOUNTS OF WATER OR NORMAL SALINE, OCCASIONALLY LIFTING UPPER AND LOWER LIDS, UNTIL NO EVIDENCE OF CHEMICAL REMAINS (APPROXIMATELY 13-20 MINUTES). GET MEDICAL ATTENTION IMMEDIATELY. INGESTION: ASBESTOS: ACUTE EXPOSURE- INGESTION MAY CAUSE GASTROINTESTINAL IRRITATION. CHRONIC EXPOSURE- REPEATED OR PROLONGED INGESTION OF ASBESTOS FIBERS MAY BE INVOLVED IN CANCERS OF THE BUCCAL CAVITY AND PHARYNX, ESOPHAGUS, STOMACH, COLON, AND RECTUM. INGESTION OF ASBESTOS-CONTAMINATED RICE HAS BEEN SUGGESTED AS THE CAUSE FOR A HIGH INCIDENCE OF STOMACH CANCER IN JAPAN. FIRST AID- REMOVE BY GASTRIC LAVAGE OR EMESIS. MAINTAIN BLOOD PRESSURE AND AIRWAY. GIVE OXYGEN IF RESPIRATION IS DEPRESSED. DO NOT PERFORM GASTRIC LAVAGE OR EMESIS IF VICTIM IS UNCONSCIOUS. GET MEDICAL ATTENTION IMMEDIATELY. <DREISBACH, HANDBOOK OF POISONING, 1ITH ED.) ADMINISTRATION OF GASTRIC LAVAGE OR OXYGEN SHOULD BE PERFORMED BY QUALIFIED MEDICAL PERSONNEL. ANTIDOTE: NO SPECIFIC ANTIDOTE. TREAT SYMPTOMATICALLY AND SUPPORTIVELY. REACTIVITY SECTION REACTIVITY: STABLE UNDER NORMAL TEMPERATURES AND PRESSURES. INCOMPATIBILITIES: ASBESTOS: 7RI-N-BROMQMELAMINE: EXPLOSIVE REACTION. SODIUM HYDROXIDE: POSSIBLE EXPLOSION. "ARSON TETRACHLORIDE: FORMATION OF EXPLOSIVE Dl- AND TRI-CHLOROBUTYLENE EPOXIDE. CHLOROSULFONIC ACID: EXOTHERMIC REACTION. NITRIC ACID: EXOTHERMIC REACTION. OLEUM:EXOTHERMIC REACTION. SULFURIC ACID: EXOTHERMIC REACTION. OXIDIZING MATERIALS: VIGOROUS REACTION. PHOSPHORUS TRICHLORIDE: PREPARATORY HAZARD (EXPLOSIVE) WHILE DISTILLING CARBON DIOXIDE STREAM. " IN DE 008510 DtCUMPOSITIONi THERMAL DECOMPOSITION may RELEASE acrid SMCtE AND IRRITATING FUMES. POLYMERIZATION* hazardous polymerization has not been reported to occur UNDER normal TEMPERATURES AND PRESSURES. STORAGE-DISPOSAL OBSERVE ALL FEDERAL, STATE AND LOCAL REGULATIONS WHEN STORING OR DISPOSING OF THIS SUBSTANCE. FOR ASSISTANCE, CONTACT THE DISTRICT DIRECTOR OF THE ENVIRONMENT PROTECTION AGENCY. STORAGE** ASBESTOS WASTE, SCRAP, DEBRIS, BAGS, CONTAINERS, EQUIPMENT, AND ASBESTOS-CONTAMINATED CLOTHING, CONSIGNED FOR DISPOSAL, WHICH MAY PRODUCE IN ANY REASONABLY FORESEEABLE USE, HANDLING, STORAGE, PROCESSING, DISPOSAL, OR TRANSPORTATION AIRBORNE CONCENTRATIONS OF ASBESTOS FIBERS IN EXCESS OF THE EXPOSURE LIMITS PRESCRIBED SHALL BE COLLECTED AND DISPOSED OF IN SEALED IMPERMEABLE BAGS, OR OTHER CLOSED, IMPERMEABLE CONTAINERS. CONDITIONS TO AVOID 'BESTOS SHALL BE HANDLED, MIXED, APPLIED, REMOVED, CUT, SCORED, OR OTHERWISE ..JRKED IN A WET STATE SUFFICIENT TO PREVENT THE EMISSION OF AIRBORNE FIBERS IN EXCESS OF THE EXPOSURE LIMITS. 29CFR 1910.1001 <C> (2) SPILLS AND LEAKS WATER-SPILL: THE CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT OF 1986 (PROPOSITION 65) PROHIBITS CONTAMINATING ANY KNOWN SOURCE OF DRINKING WATER WITH SUBSTANCES KNOWN TO CAUSE CANCER AND/OR REPRODUCTIVE TOXICITY. OCCUPATIONAL-SPILL: ADEQUATELY WET OR MIX WITH WATER TO FORM A SLURRY. SEAL MATERIAL IN A LEAKLOTHING AND EQUIPMENT TO PREVENT REPEATED OR PROLONGED SKIN CONTACT WITH THIS SUBSTANCE. ASBESTOS: PROTECTIVE CLOTHING SHOULD AMENDMENTS AND REAUTHORIZATION ACT (SARA) SECTION CO THAT A RELEASE EQUAL TO OR GREATER THAN THE REPORTABLE QUANTITY FOR THIS SUBSTANCE BE IMMEDIATELY REPORTED TO THE LOCAL EMERGENCY PLANNING COMMITTEE AND THE STATE EMERGENCY RESPONSE COMMISSION <40 CFR 335.40). IF THE RELEASE OF THIS SUBSTANCE IS REPORTABLE UNDER CERCLA SECTION 103, THE NATIONAL RESPONSE CENTER MUST BE NOTIFIED IMMEDIATELY AT (800) 424-8802 OR (202) 426-2675 IN THE METROPOLITAN WASHINGTON, D.C. AREA (40 CFR 302.6). DE 008511 PROTECTIVE EQUIPMENT SECTION VENTILATIONi 'provide local exhaust UR process ENCLOSURE VENTILATION TO MEET PUBLISHED E SURE LIMITS. ASBESTOS* VENTILATION SHOULD MEET THE REQUIREMENTS IN 29CFR1910.1001<F>. RESPIRATORS THE FOLLOWING. RESPIRATORS ARE THE MINIMUM LEGAL REQUIREMENTS AS SET FORTH BY THE OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION FOUND IN 29 CFR1910, SUBPART 2. REQUIRED RESPIRATORS FOR ASBESTOS AIRBORNE CONCENTRATION <TWA>: REQUIRED RESPIRATOR; NOT IN EXCESS OF 2 FIBERS/CC HALF-MASK AIR-PURIFYING RESPIRATOR EQUIFFED WITH HIGH EFFICIENCY FILTERS. NOT IN EXCESS OF 10 FIBERS/CC NOT IN EXCESS OF 20 FIBERS/CC NC' IN EXCESS OF 200 FIBER- FULL FACEPIECE AIR-FURIFYING RESPIRATOR EQUIPPED WITH HIGH EFFICIENCY FILTERS. ANY POWERED AIR--PURIFYING RESPIRATOR EQUIPPED WITH HIGH-EFFICIENCY FILTERS. ANY SUPPLIED-AIR RESPIRATOR OPERATED IN CONTINUOUS FLOW MODE. FULL FACEPIECE SUPPLIED-AIR RESPIRATOR OPERATED IN PRESSURE DEMAND MODE. GREATER THAN 200 FIBERS/CC FULL FACEPIECE SUPPLIED-AIR RESPIRATOR OR UNKNOWN CONCENTRATION. OFERATED IN PRESSURE DEMAND MODE AND EQUIPPED WITH AN AUXILIARY POSITIVE PRESSURE SELF-CONTANIED BREATHING APPARATUS. NOTE: RESPIRATORS ASSIGNED FOR HIGHER ENVIRONMENTAL CONCENTRATIONS MAY BE USED AT LOWER CONCENTRATIONS. THE FOLLOWING RESPIRATORS AND MAXIMUM USE CONCENTRATIONS ARE RECOMMENDATIONS BY THE U.S. DEPARTMENT OF HEALTH AND HUMAN SERVICES, NIOSH POCKET GUIDE TO CHEMICAL HAZARDS OR NIOSH CRITERIA DOCUMENTS} OR DEPARTMENT OF LABOR, 29CFR1910 SUBPART Z. THE SPECIFIC RESPIRATOR SELECTED MUST fiiE BASED ON CONTAMINATION LEVELS FOUND IN THE WORK PLACE AND BE JOINTLY APPROVED BY THE NATIONAL INSTITUTE OF OCCUPATIONAL SAFETY AND HEALTH AND THE MINE SAFETY AND HEALTH ADMINISTRATION. ASBESTOS* AT ANY DETECTABLE CONCENTRATION* ANY SUPPLIED-AIR RESPIRATOR WITH A FULL FACEPIECE AND OPERATED IN PRESSURE-DEMAND OR OTHER POSITIVE PRESSURE MODE IN COMBINATION WITH AN AUXILIARY SELF-CONTAINED BREATHING APPARATUS OPERATED IN PRESSURE-DEMAND OR OTHER POSITIVE PRESSURE MODE. ANY SELF-CONTAINED BREATHING APPARATUS WITH FULL FACEPIECE AND DE 008512 7 - ' OPERATED IN A PRESSURE-DEMAhu OR: OTHER FOSITJVE PRESSURE MODE. ESPAFE" ANY AIR-PURIFYING FULL FACEPIECE RESFIROTOR- WITH A HIGH-EFPirifn-v PARTICULATE FILTER. ANY APPROPRIATE ESLAPE-TYPE SELF-CONTAINED BREATHING APPARATUS FOR FIREFIGHTING AND OTHER IMMEDIATELY DANGEROUS TO LIFE OR HEALTH CONDI MOMS: SELF-CONTAINED BREATHING APPARATUS WITH FULL FACEPIECE OPERATED IN FRESSUTt' DEMAND OR OTHER POSITIVE PRESSURE MODE. SUPPLIED-AIR RESPIRATOR WITH FULL FACEPIECE AND OPERATED IN PRESSURE-DEMAND OR OTHER POSITIVE PRESSURE MODE IN COMBINATION WITH AN AUXILIARY SELF-CONTAINED BREATHING APPARATUS OPERATED IN PRESSURE-DEMAND OP OTHER POSITIVE PRESSURE MODE. CLOTHINGI EMPLOYEE MUST WEAR APPROPRIATE PROTECTIVE (IMPERVIOUS) CLOTHING AND EQUIPMENT TO PREVENT REPEATED OR PROLONGED SKIN CONTACT WITH THIS SUBSTANCE. ASBESTOS* PROTECTIVE CLOTHING SHOULD MEET THE REQUIREMENTS FOR PROTECTIVE WORK CLOTHING AND EQUIPMENT IN 29CFR19I0. 1001<H>. GLOVES EMPLOYEE MUST WEAR APPROPRIATE PROTECTIVE GLOVES TO PREVENT CONTACT WITH THIS SUBSTANCE. ASBESTOS! PROTECTIVE GLOVES SHOULD MEET THE REQUIREMENTS FOR PROTECTIVE WORK CLOTHING AND EQUIPMENT IN 29CFR1910. 1001(H) AND 29CFR1910.1101<D>. EYE PROTECTION! EMPLOYEE MUST WEAR SPLASH-PROOF OR DUST-RESISTANT SAFETY GOGGLES TO PREVENT EYE CONTACT WITH THIS SUBSTANCE. CONTACT LENSES SHOULD NOT BE WORN. ASBESTOS! PROTECTIVE EYE EQUIPMENT SHOULD MEET THE REQUIREMENTS FOR PROTECTIVE WORK CLOTHING AND EQUIPMENT IN 29CFR1910.1001<H>. AUTHORIZED BY- OCCUPATIONAL HEALTH SERVICES, INC. *** **** *******#*******#*#*****#***#* ****#****************** tkjuo cUjou -p-'Y 7 1,11 f1 3 <11 DE 008513 EXXON DIESEL 2 EJfcONCOMPANY. USA I orie o 1**0* COWoomiox OATE ISSUED: OS/15/89 SUPERSEDES DATE: 0C/01/I9 MATERIAL SAFETY DATA SHEET EXXON COMPANY. U.S.i. P.O. BOX 2IS0 HOUSTON. TX 77252-2180 A IDENTIFICATION AND EMERGENCY INFORMATION PRODUCT NAME EXXON DIESEL 2 CHEMICAL NAME Petroleum Distillate Fuat PRODUCT APPEARANCE AND ODOR Claar liquid, yellow color Faint petroleum hydrocarbon odor MEDICAL EMERSENCT TELEPHONE NUMBER 1713) SSS-3434 PRODUCT COOS 072700 - 0077 CAS NUMBER CS47S-34-S B. COMPONENTS AND HAZARD INFORMATION COMPONENTS CAS NO. OP COMPONENTS `'least Fuat No. 2 SS47S-34-C aaa Saction E for Haalth and Hazard Information. Saa Sactlen H for additional Environmental Information. HAZARDOUS MATERIALS IDENTIFICATION STSTEM (HMIS) Haalth rtanuBimy Reactivity BASIS 12 0 Raconmandad by Exxon EXPOSURE LIMIT FOR TOTAL PRODUCT 100 pom (SOO mQ/m3) for an S-hour workday BASIS Racomnandad by Exxon APPROXIMATE CONCENTRATION 100% C PRIMARY ROUTES OF ENTRY . AND EMERGENCY AND FIRST AID PROCEDURES EYE CONTACT If aplaanad Into tha ayaa, fluah with claar watar for IS mlnutaa or until Irritation subaldaa. If Irritation para lata, call a physician. SKIN In easa of akin contact, rameva any contaminated clothing and wash akin thoroughly with aoap and watar. -- INHALATION Ovarexpoaura may causa gasping, nauaaa and dlsoriantatlon. vapor praaaura la vary lew. vapor inhalation undar amblant conditions la normally not a problem. If overcome by vapor from hot product, remove from axpoaura and call a physician immediately. If breathing la irregular or has stopped, start resuscitation, sdxilnistar oxygen, If available. I .OESTION If Ingested, DO NOT Indues vomiting; call a pnyalelan immediately. HI-017JWWW001I DE 008514 EXXON OlESEL 2 D. FIRE AND EXPLOSION HAZARD INFORMATION FLASH POINT (MINIMUM) -COMBUSTIBLE - Per OOT 4* CFR 173. US 60'C ( 140* F) ASTM 0 *3. Pensky Martana Closed Cup AUTOIONITION TEMPERATURE Greater than 204'C (400'F) NOTE: Non-marina product may Pa 52'C (125`F) minimum Flash to moat No. 2 Olaaal Fuat Oil (*$TM o 97S). Saasona! blanaa may Pa at low as 38'C (100'Ft. NATIONAL FIRE PROTECTION ASSOCIATION (NFPA) - HAZARD IDENTIFICATION Hastth Flaxaablllty Raactlvlty BASIS 02 0 Recommended by tho National Ftra Protaction Association HAN0L1N0 PRECAUTIONS This ItputO IS volatlla and gives OFF invlslbla vapors. Either tha liquid or vapor may sattis in low araas or traval soma dlstanca along tha ground or surface to ignition sources wnsra they nay ignite or explode. Kaep produet away from Ignition sources, such as heat, sparks, pilot lights, statte electricity, and open flames. FLAMMABLE OR EXPLOSIVE LIMITS (APPROXIMATE PERCENT BY VOLUME IN AIR) Estimated values: Lower Flammable Limit 0.9% Upper Flammable Limit 7% EXTINGUISHING MEOIA AND FIRE FIOHTINO PROCEDURES Foam, water spray (fog), dry ehemieat, carbon dioxide and vaporizing liquid typo extinguishing agents may alt be suitable for extinguishing fires Involving this type of product, depending on size or potential size of firs and circumstances related to the situation. Plan fire protection and resoonse strategy through consultation with local fire protection authorities or appropriate speeieilets. The following procedures for this type of product ere baaed on the recommendations in the National Fire Protection Association's *Flre Protection Quids on Hazardous Materials*, Eighth Edition (1984): Use dry chemical, foam or carbon dioxide to extinguish the fire. Water may be ineffective, but water should be used to keep fire-exposed containers cool. If a leak or spill has ignited, use water spray to disperse the vapors and to protect men attempting to stop a leak. Water spray may be used to flush spills away from exposures. Minimize breathing of gases, veoor. fumes or decomposition proaiets. Use supplled-alr breathing equipment for enclosed or confined spaces or at otherwise needed. NOTE: The Inclusion of the phrase "water may be Ineffective* Is to indicate that although water can be used to eoot and protect exposed materia), water may net extinguish the fire unless used under favorable conditions by experienced fire fighters trained In fighting alt types of flammable liquid fires. DECOMPOSITION PROOUCTS UNDER FIRE CONDITIONS Fumes, smoke, carbon isonexlda, aldehydes and ether decomposition products, in the case of Incomplete combustion. EMPTY* CONTAINER MRNINB `Empty* containers retain residue (liquid- and/or vapor) and can be dangerous. 00 NOT PRESSURIZE, CUT, WELD. 9RAZI. SOLDER, DRILL, ORINO OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME. SPARKS. STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION; THEY MAY EXPLODE AND CAUSE INJURY OR DEATH, Do not attempt to clean since residue Is difficult to remove. 'Empty* drums should be completely drained, properly bunged end promptly returned to a drum reeondttionar. All other containers Should be disposed of tn an environmentally safe manner end In accordance with governmental regulations. For vork on tanks refer to Occupational Safety and Health AMtntatratten regulations, ANSI Z49.1, and ether governmental and inAittrlal references pertaining to cleaning, repairing, welding, or ether contemplated operations. ____________ m-imiwmt PAGE: 2 DATE ISSUEO: 0S/IS/S9 SUPERSEDES OATE: 08/01/89 DE 008515 EXXON DIESEL 2 I E HEALTH AND HAZARD INFORMATION VARIABILITY AMOND individuals - - Health studies have shown that many petroleum hydrocarbons and aynthatle lubricant* pose potential human health risks which way vary from parson to parson, as a precaution, exposure to liquids, vapor*, islets or fumes should be Minimized. EFFECTS OF OVEREXPOSURE (Signs and syaptoan of exposure) Prolonged or repeated liquid contact with the akin will dry and dafat the skin, leading to possible irritation and dermatitis. High vapor conesntratIons (greater than approximately 1000 com. attainable at temperatures wall above ambient) are irritating to the eyea and the respiratory tract, and may cause headaches, dizziness, anesthesia, drowstrteea, unconsciousness, and other central nervous system effects, including death. NATURE OF HAZARD ANO TOXICITY INFORMATION Prolonged or repeated akin contact with this product tends to remove skin oils, possibly leading to Irritation and dermatitis: however, based on human experience and available toxleologteal data, this product Is judged to be neither a 'corrosive* nor an 'irritant* by OSHA criteria. Product contacting the eyes may cause eye Irritation. Lifetime akin painting studies conducted by the American Petroleum Institute, Exxon and others have shown that similar products boiling between 175-370"C (350-700"F) usually produce skin tumors and/or akin eancar in laboratory mica. The degree of earctnogenie response was weak to noderate with a relatively long latent period. The liapl teat ions of these results for hunans have not been determined. Limited studies on oils that are very active carcinogens have shown that washing the animals' skin with soap and water between applications greatly redueea tumor formation. These studies demonstrate the effectiveness of eiaansing the skin after contact. Potential risks to humans can be minimized by observing good work practices and personal hygiene procedures generally recommendsd for petroleun products. Sea Section I for recommenced protection and precautions. Laboratory animal studies have shown that prolonged and repeated inhalation exposure to light hydrocarbon vapors in the same naphtha boiling range as this product can produce adverse kidney effects in male rats. However, these effects were not observed In similar studies with female rats and mala and female mice and In limited studies with other animal species. Additionally, In a number of human studies, there was no clinical evidence of such offsets at normal occupational levela. It is therefore highly unltkeiy that the kidney affects observed in male rats have significant Implications for hunans.exposed at or below the recommended vapor limits in the workplace. Product has a low order of acute oral and dermal toxicity, but minute amounts aspirated into the lungs during Ingestion or vomiting nay cause mild to severs pulmonary injury and possibly death. This protttet is judged to have an acute oral LD30 (rat) greater than 5 g/kg of body weight, end an acute dermal LDSO (rabbit) greater than 3.IS g/kg of body weight. Inhalation of components of exhaust from burning, such as carbon monoxtda. may cause death at high concentrations. Long-term repeated exposure of laboratory animals to whole diesel exhaust has resulted in an increased ineidenee of lung caneer. Exposure to exhaust fro* burning and dieset exhaust should be Minimized. PRE-EXISTINB MEDICAL CONDITIONS WHICH NAT BE AOORAVATED BY EXPOSURE Petroleun Solvsnts/Petroleum Hydrocarbons - Skin contact may aggravate an existing dematltis. I I m-ommwxpoa PAQE: 3 DATE ISSUED: 08/15/89 SUPERSEDES OATE: 08/01/89 008516 F. PHYSICAL DATA EXXON DIESEL 2 TM following data arc approx I sets or typleal value* and should not be used for precise design purposes. B01LINQ RmNGE -too-350'C ( 330*030* F ) VAPOR PRE5SURE Less than 1 mm Hg e 20* C SPECIFIC ORAVITY (1B.S C/1B.S C) 0.S6 VAPOR OENSITT (AIR t) Greater than 5 MOLECULAR VEIOHT Approximately 212 average PERCENT VOLATILE ST VOLUME 100 pH Essentially neutral EVAPORATION RATE 1 ATM. AND 2S C 177 F) (n-UTTL ACETATE 1) 0.02 POUR. CONQEALINB OR MELTINQ POINT is*c io*n Pour Point by ASTM 0 S? SOLUBILITY IN WATER P 1 ATM. AND 21 C (77 F) Negligible; less than o.i% VISCOSITY 2.7 CS O 40' C G REACTIVITY This produet la stable and will not react violently with aster. Hazardous polymerization *111 not occur. Avoid contact with strong oxidants such as liquid chlorine, concentrated oxygen. *odium hypochlorite or calcium hypochlorite. K ENVIRONMENTAL INFORMATION STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED S*ut off and eliminate all Ignition sources. Keep people away. Recover free product. Add sand. ?arth or other suitable absorbent to spill area. Minimize breathing vapors. Minimize skin contact, ventilate confined spaces. Open all windows and doers. Keep product out of savers and watercourses by diking or Impounding. Advise authorities if product has entered or may enter sewers, watercourses, or extensive land areas. Assure conformity with applicable governmental regulations. Continue to observe precautions for volatile, combustible vapors from absorbed material. THE FOLLOWINO INFORMATION MAY BE USEFUL IN COMPLY 1NQ WITH VARIOUS STATE AND FEDERAL LAWS AND REOULATIONS UNOER VARIOUS ENVIRONMENTAL STATUTES: REPORTABLE QUANTITY (RQ). ERA REGULATION 40 CFR 302 (CERCLA Section 102) No SO for produet or any constituent greater than l% or 0.1% (carcinogen). THRESHOLD PLANNIM QUANTITY (TPQ), SPA REGULATION 40 CFR SBB (SARA Sections 201-304) No TPO for produet or any constituent greater than t% or 0.1% (carcinogen). TOXIC CHEMICAL RELEASE REP0RT1NQ, SPA REOULATION 40 CFR 372 (SARA Section 313) No toxic chemical is present greater than 1% or 0.1% (carcinogen). HAZARDOUS CHEMICAL REPORTINQ, SPA REOULATION 40 CFR 370 (SARA Sections 311-312) Acute Chronic Fire Pressure Reaettve EPA HAZARD CLASSIFICATION COOS: Hazard Hazard xxx Hazard Hazard xxx Hazard Not Applicable I ** OtllMWHMtl PAGE: 4 OATI ISSUED; OS/15/09 SUPERSEDES DATE; OS/OI/89 DE 008517 l PROTECTION AND PRECAUTIONS Exxon diesel 2 VENTILATION use only with ventilation sufficient to prevent exceeding recommended exposure Unit or buildup of exploalv* concentrations of vapor In air. RESPIRATORY PROTECTION usa auppl lad-air raaplratory protact (on in confined or aneleaad apaeaa. if naadad. PROTECTIVE GLOVES Usa chemical-realetant gloves, If naadad. to avoid prolonged or rapaatad akin contact. EYE PROTECTION use aplaah goggles or faca antald when aya contact may occur. OTHER PROTECTIVE EQUIPMENT Ufa ehontcal-raatatant apron or other tmpervtoua clothing. If naadad. to avoid eontaminating regular clothing, which could raault In prolonged or rapaatad akin contact. WORK PRACTICES / ENGINEERING CONTROLS keep contaInara etoaad whan not in uaa. Do not atore near heat, aparka, flame or atrong oxidants. In order to prevent fire or explocton hazarda, uaa appropriate equipment. Information on electrical equipment appropriate for uaa with thla product may oa found in the lateat edition of tha National Electrical Coda <NFPA-?o). Thla document it avattaola from tne National Fire Protection Association, Batterymarch Park. Oulney. Maaaachuaatta 022BS. PERSONAL HYQIENt Minimize breathing vapor, mlet or fumae. Avoid prolonged or repeated contact with akin. Remove contaminated elothlngt launder or dry-clean before ra-uaa. Remove contaminated ahoaa and thoroughly clean before re-uae*. Placard If oll-eoaked. Cleanae akin thoroughly after contact, before braaka and maala. and at end of work period. Product le readily removed from akin by waterloaa hand cleanera followed by waahlng thoroughly with aoap and water. J. TRANSPORTATION AND OSHA RELATED LABEL INFORMATION TRANSPORTATION INCtOENT INFORMATION For further Information relative to apllla raaultIng from tranaportatlon Ineldenta. refer to lateat Department of Tranaportatlon Emergancy Reaponee Guidebook for Hazardous. Matariaia Ineldenta. 00T P 8*00.3. DOT IDENTIFICATION NUMBER Fuel Oil, No. 2 / Combuattble Liquid / NA 1**3 OSHA RtQUIRED LABEL INFORMATION In comet lane* with hazard and rlght-to-know requirement*, the following OSHA Hazard warnings ahould be found on a label, bill of lading or invoice accompanying thla ahtpment. OANOERI COMBUSTIBLE LONQ-TERM, REPEATED EXPOSURE MAY CAUSE SKIN CANCER Note; Product label wilt contain additional non-OSHA related information. m-omsmeob PAGE: B DATE ISSUED: 08/18/55 SUPERSEDES DATE: 0B/01/BS DE 008518 EXXON OIESEL 2 he Information and recommendations contained herein arc, to the best of Exxon's knowledge and oelief. aeeurste and reliable aa of the data Issued. Exxon doaa not warrant or guarantee their accuracy or reliability, and Exxon shall not ba 1 labia for any loss or damage anting out of tho uaa tharaof. Tha Infonaatlon and racotimandatlont ara offorad for tho utar't eonaldaratlon and oxaatnatlon, and It la tha uaor'a raaponalbllIty to satisfy Itaalf that thay ara aultabla and complete for its particular uaa. If buyar rapackagat this produet, lagal council should ba conaultod to Insure proper health, safety and other necessary Infonaatlon is Included on tha container. Tha Environmental Information Included under Section H hereof at well as the Hazardous Materials Identification System (HMtSl and National Fire Protection Association (NFPA) ratings have been included by Exxon Company, U.S.A. In order to provide additional health and hazard classification Information. The ratings recoamended are baaed upon tho criteria supplied by the developers of these rating systeM, together with Exxon's interpretation of the available data. FOR ADDITIONAL INFORMATION ON HEALTH EFFECTS CONTACT: DIRECTOR OF INDUSTRIAL HVOIENE EXXON COMPANY, U.S.A. P 0. BOX 2ISO ROOM 31ST HOUSTON. TX 77252-2 ISO (713) CSf-2443 FOR OTHER PRODUCT INFORMATION CONTACT: MANAGER. MARKETING TECHNICAL SERVICES EXXON COMPANY, U.S.A. P. 0. BOX 2 ISO ROOM 23SS HOUSTON. TX 772S2-2180 (713) 3<-S94g oinmnaoen PAGE: B DATE ISSUED: 08/13/89 ..SUPERSEDES DATE: 0S/01/89 DE 008519 business confidential PAGE 1 UNION CAP'S IDE C DPP. INTERNAL CHEMICAL DATA SHEET MAMP : GAS i'iL IME '8f--110 OCTANE> CA* MlJMtEP: 0flOSOO**..!? DATE: Oc LA31 REVISION DATE: ij 04 -Si 3 VMClH'i MS: GASOLINE HFPfi HAZARD SIGNAL HEALTH: 1 F1 PE: ? PEACTIVTV: Ci UNUSUAL REACT IVI TV! JC C" HAZARD 11GNAL HE-AlTH! 3 FIRE: 3 REACTIVITY: APPEARANCE! COLORLESS LIQUID .MrtV BE COLORED WITH VARIOUS DYES . ODOR: GASOLINE THE MAIM HAZARDS FIRE AMD EXPLOSION. IRRITANT TO SLIM. VAPORS APE MODERATELY POISONOUS. EMERGENCY PROCEDURES FIRE EXTINGUISH FIRES til IT H! t. REGULAR FOAM . DRV CHFMICAl DR COE: FOR SMALL SPILL FIRES. LOU SOUJDILITV IN i.'ATER. DANGER OF PL OAT IMG PIRE. -IN EYE FLUSH WITH WATER. GET MEDICAL ATTENTION IF DISCOMFORT REP SI STS. ON SKIN REMOVE CONTAMINATED CLOTHING AND MASH SKIN '-IJTH SOAP AND WATER. IN CASE OF MASSIVE EXPOSURE* OP IF DISCOMFORT PERSISTS* GET MEDICAL ATTENTION. SHALLOWED GIVE TWO GLASSES OP WATER OR MILK HT ONCE. DO NOT INDUCE VOMITING. GET MEDICAL ATTENTION AT ONCE. 11IHAL ED v Oc'-O-i-'c'i 1 REMOVE VICTIM TO FRESH AIR. ADM!HI STEP ARTIFICIAL RESPIRATION* AS NEEDED OXYGEN MAY Df? ADMINISTERED DY AUTHORIZED PERSONNEL. "ET MEDICAL ATTENT ION DE 008520 r.U SI ME ? S COMP I DENT 1 PL GA? OL11 IE < S5-) 1 i'i OC T ANE' 0 0 i'i:? 0 0G619 SPILLAGE AVOID IC'NiriOn SOURCE". ISSUE i.lHENim;. U`E PPQTECTIVE EQUIPMENT. ISOLATE PMIi COLLECT FOP IMC1 HERAT I ON. AVOID DISCHARGE TO SE-'ER: Pdf' i.iATFPi.iRV; . FIFE AND EXRLQiIOM CONCENTRATION: 1 OP*: FLASH POINT: -45 DEG.C. TO -3* PEG.C. 'CC> AUTOIGNITION TEMPERATURE: 80 PEG.C. - 458 DEG.C. FLAMMABLE LIMITS 'VOLUME PERCENT IN *IP.J> 1.4 CLFL,' - T.8 ..UFL> explds 1 on hasards VRPOPS FOPM EXPLOSIVE MIXTURE MITH RIP. TOXIC CONDUCTION PRODUCTS CARBON MONOXIDE STAB1L1TV--THERMAL. I HPACT GENERALLY STAPLE TO 500 - SO1.1 DEG. C. NO EVIDENCE OF SENSITIVITY TO MECHANICAL SHOCK. CHEMICAL DATA CONCENTRATION: 10 OX. FOPMULRxCOMF'OS ITI OH C5 HI TO C? H0 CHEMICAL FAMILYxDESCPIPT10N HYDROCARBON REACTIVITY l.iITH OXIDISING AGENTS REACTION WITH STRONG OXIDIZERS 'LIQUID OX'i GEN. CHROMIC ACID? PERMANGANATES, ETC. . > MAY PE HAZARDOUS AND SHOULD EE AVOIDED. DE 008521 pl.l:I NESS CONFIDENTIAL GA7 OL I ME *f-- 11 0 oc TAME > 0 0 0>: 0 iTGG19 PAGE acid: home alt al is HOME I.IATEP HOME flIP HflV OXIDIZE IN LIPOID PHASE WITH AJP TO ALCOHOLS AMD LETONES OP* AT MOPE PIGOFOOS CONDITIONS:. ORGANIC ACIDS' AMD CflPPOM O.'IDES. VflPGP FLflMMflPLE IN fllP. OTHER CHEMICALS PEACTS MITH CHLQPINE IN PRESENCE OF SUNLIGHT TO FORM CHLORINATED HYDROCAR PONS' AND HYDROGEN C HLCP1 PE . REACTION IS VERY VIGORGOi. HEALTH DATA CONCENT PAT ION! tOU*< TMA--A HOUP NO DATA ODOP THRESHOLD 0.3 PPM PROTECTIVE CLOTHING MO DATA EFFECT OF LICOID OP SOLID DM EYES MINOR IRRITATION SIMILAR TO THAT EXPERIENCED MITH LIPOID HAND SOAP. ON SC IN Ml HUP IRRITATION. PROLONGED OF EXTENSIVE EXFOSOFE CAUSES DRYING AND DEFATTINA. < DE 008522 PUS 1 NESS C ONF l DENT t AL GASOLINE '"85-110 OCTANE> OOOGO0861? PV SK IN ABSORPTION SKIM PENETRATION POSE* HU PhTA ACUTE - HUT A SIGNIFICANT HAZARD. CHRONIC BY INGESTION SINGLE OPAL POSEt HU DATA NAY CAUSE NAUSEA* VOMITING* AND DIARRHEA. MOT TESTED. PAGE 4 EFFECT OF VAPOR OR DUST OH EYES HOT A SIGNIFICANT HAZARD. UN SKIN HOT AT SIGNIFICANT HAZARD. INHAI.ED-ACUTE inhalation pose* NO DATA LON CONCENTRATIONS MAY CAUSE DIZZINESS AND IRRITATION OF EYES* NOSE* AND THROAT. HIGHFP CONCENTRATION1 `SO00 PRM OP MOPE-' NAY CAUSE DIZZINES'* MUCOUS MFMPPANE IRRITATION* HNp ANESTHESIA. inhalep-chronic NOT TESTED. MAY CONTAIN BENZENE WHICH IS CLASSED AS A CARCINOGEN. PHYSICAL DATA CONCENTRAT ION:ICON SPECIFIC GRAVITY* 0.6* 3 0'0 PEG.C. FOILING POINT: *0 TO 00 DEG.C. 3 "Gu MM HG < VAR IABLE> PP'EEZIMG POINT: -*ft TO -100 PEG.C. tVARIABLE'S VAPOR PPEiSUPJE: 10-15 MM HG 3 0 DEG.C. (VAPIABLE'1 COEFFICIENT OF EXPANSION: NOT A'-'AIl ARI. E DE 008523 BU linens C Of fF I BF.NT I PL GA;. (iLINE IJS5-110 i'iCTANE* 0 i'i i.l* il r**r.(=. 19 WOP DENSITY: 3. 0-4.0 I0LUB1LITV ttf MATER: NEGLIGIBLE V11C 011TY: NOT AVAILABLE FAGE HANDLING AML- I-TOFAGE RECOMMENDA7 I OH-I- NORMAL STORAGE TEMF'EPATURE! AMBIENT NORMAL STORAGE PRFISUF'E: PILLING PATIO: NO DATA R1HO SPHERIC MITH NITROGEN BLANKET . DOT HAZARD CLAi^t FLAMMABLE LIQUID HANDLING AND STORAGE materials UNSUITABLE POLYETHYLENE SUITABLE TTEEL COPPER i'TA INL ESI IT EEL BAf ED PHFNOLIC ALUMINUM BOO? TEFLON NIO EL CERAMIC I ZINC EMVIPONMENT AL A5PEC TC- HATER BI0DEGPADAB1L1 TV NO DATA! PROBABLY POORLY BIODEGRADED. AC'IJAT 1C sn IC F OB I AL TOK t CITY 40.0 MA.-L* TEST SPECIES' RAINBOW TROUT. ABSORBABILITY ON CARBON FROM MATER NO DATA! PROBABLY HIGHLY ABSORBABLE. AIR! D13FOCAL OPTIONS ADSORPTION ON CARBON PROBABLY LOMj INCINERATION Is FEASIBLE. DE 008524 NUTO H 33 E^ONCOMPANY. USA ft omvon Of fxxoa e0fOXA1)0*i DATE ISSUED- 06/01/89 SUPERSEDES DATE: OS/19/89 MATERIAL SAFETY DATA SHEET EXXON COMPANY, U.S.-A. P.O. BOX 2180 HOUSTON. TX 77282-2180 A IDENTIFICATION AND EMERGENCY INFORMATION PRODUCT NAME NUTO H 33 CHEMICAL NAME Patrolaum Lubricating Oil PRODUCT APPEARANCE AND ODOR Claar liquid, yallow color Mild, bland patrolaum odor MEDICAL EMERGENCY TELEPHONE NUMBER (713) 696-3434 PRODUCT COOt 363010 - 0133S CAS NUMBER Comp lax Mixtura CAS Number not applicaole B. COMPONENTS AND HAZARD INFORMATION COMPONENT* CAS NO. OF COMPONENTS APPROXIMATE CONCENTRATION Lubrtesting Ott Baa* Stock 4742-t4*7 or 64742-BS-O or 64742-BS-R or 72633-B7-1 Ureater then 99% Proprietary addtttvaa Mixture Lasa than IX Sea Section t for Health and Hazard InforeatIon. Sea Section H for additional Environmental InforeatIon. HAZARDOUS MATERIALS IDENTIFICATION SYSTEM THMXS) Health FI i It tty Reactivity i0 BASIS Recommended By Exxon EXPOSURE LIMIT FOR TOTAL PRODUCT S mg/m3 for oil nlat In air BASIS 05MA Raoulat Ion 29 CFR It10.1000 S mg/m3 for oil nlat Recommended By the American Conference of Governmental Induetrlal Hyglentata (ACOIH) 5 mg/n3 for eiat in air Recommended by Exxon PRIMARY ROUTES OF ENTRY ' AND EMERGENCY AND FIRST AID PROCEDURES EYE CONTACT If aplaahed Into the eyee. fluah with dear water for IB einutea or until irritation eubeidea. If irritation para lata, call a phyaieian. Mt-tiMmosil DE 008525 NUTO H 33 SKIN < in case of akin contact, remova any contaminated clothing and wash akin thoroughly with *oac and water. INHALATION vapor praaaura la vary lev. Vapor Inhalation undor ambient eondltlona la normally not a problem. tf overcome by vaoer from hot product, immediately rarova from exposure and call a phyatelan. If breathing la irregular or haa atoppad. atart raauaeitation; administer ' 'oxygen, If available. tf overexposed to oil mat. remove from further axpoaura until exceoalva oil mat condition aubatoaa. INGESTION If Ingested, DO NOT Induce vomiting; call a phyatelan immediately. D. FIRE AND EXPLOSION HAZARD INFORMATION FLASH POINT (MINIMUM) 19S" C (311* F) ASTM 0 13. Cleveland Open cup AUTOIONITION TEMPERATURE Greater than 3<0'C (SOO'F) NATIONAL FIRE PROTECTION ASSOCIATION (NFPA) > HAZARD IDENTIFICATION Health Flammability Reactivity 1AS1S 11 0 Reeomnended by Exxon HANOLINO PRECAUTIONS uae produet with caution around heat, sparks, pilot llghta, atatlc electricity, and open flame. FLAMMA1LE ON EXPLOSIVE LIMITS (APPROXIMATE PERCENT ST VOLUME IN AIR) Eatlaeted vatuea; Lower Flammable Limit 0.1% Upper Flammable Limit 7% EXTINGUISHING MEDIA AND FIRE FIOHTINO PROCEDURES Foan, water apray (fog), dry chemical, carbon dioxide and vaporizing liquid type extlngutehtng aganta may all be auttable for extlngutehtng flrea Involving thla type of product, depending on alze or potential alze of fire and ctreumetancaa related to the altuatton. Plan fire protection and reaponae etrategy through eonaultatlon with local fire protection autherlttee or appropriate epeeletlata. The following proeeduroa for thla type of product are baaed on the racommendations in the National Fire Protection Aaaoclatlon'a `Fire Protection Guide on Hazardoue Material*-. Eighth Edition (1114); Uae water apray, dry chemical, foam or carbon dioxide to extlnguteh the fire, uae water to keep ftre-exooaed container* coot. If a leak or aptII haa not Ignited, uae water apray to diaper** the vapor* and to provide protection for men attempting to atop a leak. Water apray may be used to fluah apt 11a away from exposures. Minimize breathing of gaaea, vapor, fume* or deeompoaltlen product*. Uae auppliod-alr breathing equipment for ancloaed or confined apace* or a* othere Ia* needed. DECOMPOSITION PROOUCTS UNDER FIRE CONDITIONS Fume*, amok*, carbon monoxide, aulfur oxide*, aldehyde* and other deeompoaltlen product*, in the eeae ef incomplete combustion. "EMPTY* CONTAINER WARNING 'Empty* container* r*t*ln residue (liquid and/or vapor) and can be dangerous. 00 NOT PRESSURIZE, CUT. WELD, MAZE. SOLDER. DRILL, ORINO OR EXPOSE SUCH CONTAINERS TO HEAT. FLAME. SPARKS. STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION; THEY MAY EXPLODE AND CAUSE INJURY OR OEATH. Oo net attempt to clean sine* residue la difficult to remove. 'Empty* drums should be completely drained, prooerly bunged and promptly returned to a drum reconditloner. Alt other container* should be disposed of In an environmentally safe manner and In accordance with governmental regulations. For work on tanks refer to Occupational Safety and Health Administration regulations, ANSI Z41.1, and ether governmental and industrial references pertaining to cleaning, repairing, welding, or other contemplated operations. 1 Mt-omanmMa PAOE: DATE ISSUED; OE/01/89 SUPERSEDES DATE; 03/19/89 DE 008526 NUTO H 33 E HEALTH AND HAZARD INFORMATION VARIABILITY AMOM INDIVIDUALS Health studies have shown that man/ petroleum hydrocarbon* and aynthatlc lubricants pots 'potantlal human haalth rieka which may vary from parson to paraon. As a praeautlon. exposure to ttqulda. vapors, aitsta or turns* should ba mminlzad. EFFECTS OF OVEREXPOSURE (Sign* and syaptoms or exposure) Prolonged or rapaatad akin contact may eausa akin irritation. NATURE OF HAZARD AND TOXICITY INFORMATION In accordance with the current OSHA Hazard Communication Standard criteria, this product does not require a cancer hazard warning. Thla la because the product t* formulated from base stock* which are severely hydrotreated, severely solvent extracted, and/or proceasad by mild hydrotreatment and extraction. Alternatively, It may constat of components not otherwise affsetad by IARC criteria, auch a* atmospheric distillate* or synthetically derived materials, and as such la not characterized by current IARC classIfleet ion criteria. Prolonged or repeated akin contact with this product tends to remove skin oils, possibly loading to Irritation and dermatltla; however, based on human experience and available toxicological data, this product 1* judged to be neither a 'corrosive* nor an `irritant* by OSHA criteria. Produet contacting the eye* may cause eye Irritation. Product has a low order of acute oral and dermal toxicity, but minute amounts aspirated Into the lungs during Ingestion or vomiting may cause mild to sever* pulmonary Injury and possibly death. This product is judged to have an aeute oral LDSO (rat) greater than S g/kg of body weight, and an acute dermal LOSO (rabbit) greater than 3.1* g/kg of body weight. iRE-EXISTING MEDICAL CONDITIONS WHICH MAY SE AGGRAVATED SY EXPOSURE None Recognized F. PHYSICAL DATA The following data are approximate or typical values and should not be used for precise design purposes. B01LIH0 RAMIE IBP Approximately 3B3`C (BSO'F) by ASTM 0 3BB7 VAPOR PRESSURE Less than O'. 01 mm Hg e 30* C SPECIFIC ORAVXTY (1B.B C/IB.B C) O.SB MOLECULAR WEIOHT Not determined VAPOR DENSITY (AIR 1) greater than S PERCENT VOLATILE BY VOLUME Negligible from open container in 4 hours e 3B'C (100 F) pH Essentially neutral EVAPORATION RATE P 1 ATM. AM) 3S C (77 F) (n-BUTYL ACETATE 1) Lees then 0.01 POUR, C0NQEAL1NQ OR MELTINQ POINT -37* C (-3B* F ) Pour Point by ASTM 0 B7 SOLUBILITY IN WATER * 1 ATM. AND 2S C (77 F) Negligible; less than 0.IX VISCOSITY 33 cSt e 40* C I I41-OJ77WWWOOP PAGE: 3 OATE ISSUED: OS/Ot/89 SUPERSEDES OATE: 05/19/B9 DE 008527 G REACTIVITY This product ts Stable and will not raset violently with water. Hazardous polymerization wl'1 not occur. Avoid contact with strong oxidants such as llould chlorine, eoncantratad . - oxygen, sodium hypochlorlta or ealctum hypochlorite. K ENVIRONMENTAL INFORMATION STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Recover free product. Add sand, earth or other suitable absorbent to spin area. Minimize breathing vapors. Minimize sain contact. Open all windows and doors. Keep prottJCt out of sewers and watercourses by diking or impounding. Advise authorities If produet has entered or nay enter sewers, watercourses, or extensive land areas. Assure conformity with applicable governmental regulations. THE FQLLOWIM INFORMATION MAT BE USEFUL IN COMPLYIM WITH VARIOUS STATE AND FEDERAL LAWS AND PECULATIONS UNDER VARIOUS ENVIRONMENTAL STATUTES! REPORTABLE QUANTITY (RQ). ERA RE0ULAT10N 40 CFR SOS (CERCLA Section 10S) No RO for product or any constituent greater than IX or 0.1X (carcinogen). THRESHOLD PLANNINO QUANTITY (TPQ), EPA REQULATION 40 CFR SSB (SARA Sections 301-304) No TPQ for protMet or any constituent greater than IX or 0.IX (carcinogen). TOXIC CHEMICAL RELEASE REPORTIHQ. EPA REQULATION 40 CFR 373 (SARA Section 313) No toxic chemical Is present greater than IX or O.IX (carcinogen). HAZARDOUS CHEMICAL REPORTINQ, EPA REQULATION 40 CFR 370 (SARA Sections 311-313) Acute Chronic Fire Pressure Reactive EPA HAZARD CLASSIFICATION CODE: Hazard Hazard Hazard Hazard Hazard Not Applicable XXX I. PROTECTION AND PRECAUTIONS VENTILATION Use local exhaust to capture vapor, mists or fumes. If necessary. Provide ventilation sufficient to prevent exceeding recommended exposure limit or buildup of explosive concentrations of vapor In air. No smoking, flame or other ignition sources. RESPIRATORY PROTECTION Use supplled-alr respiratory protection In confined or enclosed spaces. If needed. PROTECTIVE QLQVES Use chemical-resistant gloves. If needed, to avotd prolonged or repeated skin contact. EYE PROTECTION Use splash goggles or face shield when eye contact may occur. OTHER PROTECTIVE EQUIPMENT Use chemlcalrreslstant apron or ether impervious clothing, if needed, to avoid contaminating regular etethlng, which could result In prolonged or repeated skin contact. WORK PRACTICES / EN0INEER1NQ CONTROL! Keep containers closed whan not In use. Do not store near heat, sparks, flame or strong oxidants. In order to prevent fire er explosion hazards, use appropriate equipment. Information on electrical equipment appropriate for use with this product may be found in the latest edition of the National Electrical code (NFPA-TO). This document ts available from the National Fire Protection Association, Batterymarch Park, Quincy, Massachusetts 023BB. MA-StHHWHOeb FADE: 4 DATE ISSUED: 04/01/89 SUPERSEDES OATE: 09/19/49 DE 008528 NUTO M 32 * 'ERSONAL HYQIENC Mlnfmtzt breathing voor. mt*t or fUfftOS. Avoio prolonged or rtooatod Contact with Skin Remove contaminated clothing: launder* or dryelwn befon* rt-uat. Remove contaminated sr>oas anp thoroughly clean before r#*uee: discard if oii-eoeked. Cleanse skin thoroughly aftar contact, bafora braaka ano naala, and at and of work paMod. Product is raadiiy removed from skin by watarlaat hand elaanara followed by washing thoroughly with soap and water. J. TRANSPORTATION AND OSHA RELATED LABEL INFORMATION TRANSPORTATION INC10ENT INFORMATION For further Information relative to spills resulting trot, transportation incidents. rsfer to lataat Department of TranaportatIon Emergency Raaponaa Guidebook for Hezerdous Matartals Incloants, DOT P 3900.3. DOT IDENTIFICATION NUMBER Not app Heebie OSHA REQUIRED LAEEL INFORMATION In conollinca with hazard and right-to-know reculremente. tha following OSHA Hazard Warnings should ba found on a label, pm of lading or invoice accompanying this shipment. (OSHA Hazard Warnings not applicable for thla product: therefore, no OSHA warnings would appear on tha label.) Note: Produet label will contain additional non-OSHA related Information. Tha information and rscomwandattons contained herein era, to tha bast of Exxon's knowledge and belldf, accurate and reliable at of tha date laaued. Exxon dees net warrant or guarantee their accuracy or reliability, and Exxon shall net be liable for any Iota or damga arising out of the use thereof. The information and recoinsndatlons are offered for the user'* consideration arid examination, and It Is the uear'a responsibility to satisfy Itself that they are editable and complete for its particular use. It buyer repackages this product, legal eouncll should be consulted to insure proper health, safety and ottvs* necessary infonaatton le Included on the container. The Environmental Infonaatton Included under Section H hereof ae well ae the Hazardous Materials identtfI cat Ion System (HMIS) end National Fire Protection Association (MFPA) ratings hava been Included by Exxon Coepany, U.S.A. In order to provide additional health and hazard classification infonaatton. The ratings recommended are bated upon the criteria supplied by the developers of these rating systems, together with Exxon's Interpretation of the available data. FOR ADDITIONAL INFORMATION ON HEALTH EFFECTS CONTACT- DIRECTOR OF INDUSTRIAL HVQIENE EXXON COMPANY. U.S.A. P. 0. BOX aiBO ROOM SIBT HOUSTON, TX 7Taa-ai*o (713) <88*2449 FOR OTHER PRODUCT INFORMATION CONTACT: MANAOER. MARKET(NO TECHNICAL SERVICES EXXON COMPANY, U.S.A. P. 0. BOX 3 ISO ROOM 2355 HOUSTON. TX 77282*210 (713) BBB-BB4B 1 M1-0177IWWHOOP PAGE: B DATE ISSUED: 06/01/69 SUPERSEDES DATE: 05/19/69 DE 008529 WTO H 88 E^ON COMPANY. USA 4 0 tXXOX COWOtUMIM DATE ISSUED: 08/01/89 SUPERSEDES DATE: 05/19/89 MATERIAL SAFETY DATA SHEET EXXON COMPANY. U.S.A. P.O. BOX 3180 HOUSTON. TX 77352-2180 A IDENTIFICATION AND EMERGENCY INFORMATION PRODUCT NAME WTO H 88 CHEMICAL NAME Patrolaum Lubricating Oil PRODUCT APPEARANCE AND ODOR Clear liquid, yellow color Mild, bland petroleum odor MEDICAL EMERQENCY TELEPHONE NUMSER (713) 888-3434 PRODUCT COOE 383018 - 01337 CAS NUMSER Complex Mixture CAS Number not applicable B. COMPONENTS AND HAZARD INFORMATION COMPONENTS CAS NO. OP COMPONENTS APPROXIMATE CONCENTRATION Lubricating Oil Saaa Stock 84742-84-7 or *4743-88-0 or 73823-87-1 Oreater than 99X Proprietary addlttvea Mixture Leea than IX Sac Section E for Health and Hazard Information. See Section H for additional Environmental Information. HAZARDOUS MATERIALS IDENTIFICATION SYSTEM (HMIS) Health PI II tty Reactivity BASIS 1 1 0 Recommended by Exxon EXPOSURE LIMIT FOR TOTAL PRODUCT S mg/m3 for oil miat In air S mg/mi for oil al8t BASIS OSHA Regulation 38 CFR 1810.1000 Recommended by the American Conference of. Governmental induetriat Hygteniete (AcatH) S mg/n3 for miat In air Recommended by Exxon PRIMARY ROUTES OF ENTRY AND EMERGENCY AND FIRST AID PROCEDURES EVE CONTACT If epteehed Into the eyes, flueh with elear. water for IS minutes or until irritation lubeidea. If irritation pereiata. eall a phyalcian. SKIN 1 In eaaa of akin contact, ranova any eontaalnatad clothing and wash akin thoroughly with soap and watar. 9i*ei7miwNOtt) pE 008530 MJTO H 68 INHALATION vapor praaaur# is vary low. Vapor inhalation undar ambient conditions la normally not a problem. If ovareoma By vapor from hot product, immadlataly ramova from exposure and call a physician. If breathing IS Irragutar or has atopoad. start resuscitation: administer oxygon. If available. If overexposed to oil mist, remove from further exposure until excessive oil mist condition subsides. INGESTION If Ingested. 00 NOT Induce vomiting; call a physician immadlataly. D. FIRE AND EXPLOSION HAZARD INFORMATION FLASH POINT (MINIMUM) 220'C (428* F) AST* 0 82. Cleveland Open Cuq AUTOIONtTlON TEMPERATURE Qreater than 20`C (SOO'F) NATIONAL FIRE PROTECTION ASSOCIATION (NFPA) - HAZARD IDENTIFICATION Health FIs--ability Reactivity BASIS 1 1 0 Recommended by txxon HANDLING PRECAUTIONS Use produet with caution around heat, sparks, pilot lights, statle electricity, and open flame. FLAMMABLE OR EXPLOSIVE LIMITS (APPROXIMATE PERCENT BY VOLUME IN AIR) Estimated valuee: Lower Flammable Limit 0.8X Upper Flammable Limit T% EXTINOUISHINB MEDIA AND PIRE FIOHTINO PROCEDURES Foam, water spray (fog), dry chemical, carbon dioxide and vaporising liquid type extIngutshlng agents may all be suitable for extlngulahing fires Involving this type of product, depending on site or potential else of fire and circumstances related to the eltuatton. Plan fire protection and response strategy through consultation with local fire protection authorities or appropriate specialists. ' The following procedures for this type of proAiet are based on the recommendsttons In the National Fire Protection Association's 'Fire Protection guide on Hazardous Materials'. Eighth Edition (1BB4)i Use water spray, dry chemical, foam or carbon dioxide to extinguish the fire. Use water to keep fire-exposed containers cool. If a leak or spill has not Ignited, use water spray to disperse the vapors and to provide protection for men attempting to step a leak. Water spray nay be used to flush spit is away from exposures. Minimise breathing of gases, vapor, fumes or daeomposttlon preduets. Use Supplled-alr breathing equipment for enclosed or confined spaces or as otherwise needed. DECOMPOSITION PRODUCTS UNDER FIRS CONDITIONS Fumes, smoke, carbon monoxide, eulfur oxides, aldehydes and other decomposition products, in the eaee of incomplete combustion. EMPTY* CONTAINER WARN1NB 'Empty* containers retain residue (liquid and/or vapor) and can be dangerous. DO NOT PRESSURIZE. CUT. weld, braze, SOLDER, drill, grind or expose such containers to heat. FLAME. SPARKS. STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION; THEY MAY EXPLOOE AND CAUSE INJURY OR OEATH. Do not attempt to dean since residue is difficult to remove. 'Empty* drums should be completely drained, property bunged and promptly returned to a drum recondttloner. Alt other eontalnara should be disposed of In an environmentally safe manner and In accordance with governmental regulations. For work on tanks refer to Occupational Safety and Health Administration regulations, ANSI Z8.1. and other governmental and in*istriat references pertaining to cleaning, repairing, welding, or other contemplated operations. I 41-oimmmtti PAGE: DATE ISSUEO: 06/01/89 SUPERSEDES DATE: 05/18/89 DE 008531 NUTO H (I l E HEALTH AND HAZARD INFORMATION VARIABILITY amonq individuals -Health atudlaa hava shown that many petroleum hydrocarbons and synthetic lubricants poaa potential human health risks which may vary from person to parson. As a precaution, exposure to liquids, vapors, mists or fumes should be minimized. EFFECTS OF OVEREXPOSURE (Signs and symptoms of exposure) Prolonged or repeated skin contact may cause skin Irritation. NATURE OF HAZARD ANO TOXICITY INFORMATION In accordance with the current OSHA Hazard Communication Standard criteria, this product does not require a cancer hazard warning. This la because the product is formulated from base stocks which are severely hydrotreated, severely solvent extracted, and/or processed by mild hydrotreatment and extraction. Alternatively, It may consist of components not otherwise affected by IARC criteria, such as atmospheric distillates or synthetically derived materials, and as such Is not characterized by current IARC classification criteria. Prolonged or repeated skin contact with this product tends to remove skin oils, possibly leading to Irritation and dermatttts; however, eased on human experience and available toxicological data, this product Is Judged to be neither a `corrosive* nor an `irritant* by OSHA criteria. Product contacting .the eyas may cause eye Irritation. Product has a low order of acuta oral and dermal toxicity, but minute amounts aspirated into the lungs during ingestion or vomiting may cause mild to severe pulmonary injury and possibly death. This product is Judged to have an acute oral LDBO (rat) greater than S g/kg of body weight, and an acute dermal LOSO (rabbit) greater than a.It g/kg of body weight. PRE'EXISTINQ MEDICAL CONDITIONS WHICH MAY BE AOORAVATED BY EXPOSURE Nona Recognized F. PHYSICAL DATA The fotlowing data era approximate or typical values and should not be used for precise design purposes. B0IL1NQ RAME IBP Approximately 3B3`C (StO'F) by ASTM 0 aSS7 VAPOR PRESSURE Less than O.OI aim Hg a 30'C SPECIFIC ORAVITY (1B.B C/1B.B C) O.SS VAPOR DENSITY (AIR 1) Qreater than S MOLECULAR VEIQKT Not determined PERCENT VOLATILE BY VOLUME Negligible from open container In 4 hours 0 3B`C (100'F) P Essentially neutral EVAPORATION RATE 1 ATM. ANO 2B C (77 F) (n-BUTYL ACETATE 1) Lass than 0.01 POUR. CONOEALINB OR MELTINO POINT -37*C (* 17* F ) Pour Point by ASTM D BT SOLUBILITY IN WATER 1 ATM. AND 31 C (77 F) Negligible; leas thanO.tX VsIStCOcsStITYa so* c i HI'OlfTSfWMOQfl FADE: 3 J DATE ISSUED: 06/01/89 SUPERSSflES DATE: 09/19/89 DE 008532 NUTO H G REACTIVITY Thi* produet la (table and Mill net raaet violently wttn water. Hazardou* polymerization will not occur. Avoid contact with *'rong oxidante euch aa liquid chlorine, concentrated oxygen, eodtum hypochlorite or calcium hypochlorite. K ENVIRONMENTAL INFORMATION STEPS TO II TAKEN IN CASE NATEAIM. It NELEASEO OR SKILLED Recover free product. Add aand, earth or other auttable abaorbent to aplli area, minimize breathing vapora. Minimize akin contact. Open all windowa and doora. Keep product out of aewera and watareouraea by diking or impounding. Advlae author it lea If product haa entered or laay enter aewera. watareouraea. or exteneive land araaa. Aaaure conformity with applleablo governmental regulation*. THE FOLLOWING INFORMATION NAT >t USEFUL IN COMPLYING WITH VARIOUS STATE AND FEDERAL LAWS ANO REGULATIONS UNOER VARIOUS ENVIROWENTAL STATUTES! REFORTASLE OUANTZTT (RG), ERA REGULATION 40 CFR SOS (CERCLA Section tot) No RO for produet or any eonatftuent greater than 1% or 0.IX (carcinogen). THRESHOLD FLAWING QUANTITY (TFO), ERA REGULATION 40 CFR 31B (SARA Sect Iona SOI >904) No TFO for product or any eonatltuent greatar than IX or O.IX (carcinogen). TOXIC CHENICAL RELEASE REFORTINO, ERA REGULATION 40 CFR 379 (SARA Section 313) No toxic ehemlcal la preaent greatar than IX or 0.1X (earel nogen).' HAZARDOUS CHENICAL RESORTING. ERA REGULATION 40 CFR 370 (SARA Section* 311-313) Aeuta Chronic Fire Freature Reactive ERA HAZARD CLASSIFICATION COOt: Hazard Hazard Hazard Hazard Hazard Not Applicable xxx I. PROTECTION AND PRECAUTIONS VENTILATION Uaa local axhauat to eaptura vapor, alat* or fume*, if necaaaary. Provide ventilation aufflclant to pravant exceedIng recommended expoaura Halt or buildup of exploalve concentration* of vapor In air. No aaoklng, flame or other Ignition aoureea. RESFIRATORT PROTECTION Uae aupplled-alr raaplratory protection in confined or enetoaed apace*, if needed. PROTECTIVE GLOVES uae chemical-raatatant glove*, If needed, to avoid prolonged or repeated akin eontaet. EYE PROTECTION Uae aplaah goggle* or face ahleld when eye eontaet may occur. OTHER PROTECTIVE EOUtPNtNT Uaa chemleal-raalatant apron or other Impervlou* clothing. If needed, to avoid contaminating regular etothlng, which could raawlt In prolonged or repeated akin eontaet. WORK PRACTICES / ENGINEERING CONTROLS Keep container* cloaad when net in uaa. Do not atora near boat, aparka. flame or atrong oxtdanta. In order to prevent fire or axploalon hazard*, uaa appropriate equipment. Information on electrical equipment appropriate for uaa with thi* product may be found in the tataat edition of the National Electrical Code (NFPA-70J. Thi* document 1* available from the National Flra Protest Ion Aaaoelatlen, Satterymarch Park. Quincy. Naataehueetta 023tS. iM-stronmoop RAGE: 4 OATE ISSUED: 04/01/89 SUPERSEDES OATE: 09/19/89 DE 008533 NUTO H personal hyoiene minimize breathing vaoor. mat or fumes. Avoid prolonged or raoaatad contact with akin. Remove contaminated elotning; laundar or dry-clean before ra-uaa. Remove eontamnatad anoaa and thoroughly clean before ra-uaa; Placard if oil-aoakad. Claanaa akin thoroughly aftar contact, bafora braaka and meele. and at and of work oarlod. Product la raadlly removed fro* skin by vsterleee band ctaanara followed by washing thoroughly with soap and watar. J. TRANSPORTATION AND OSHA RELATED LABEL INFORMATION TRANSPORTATION INCIDENT INFORMATION For furthar Information ralatlva to splits rasuttlng from transportation incidanta. rsfar to latsat Oscartiaant of Transportation Eaargancy Raaponaa Ouldabook for Hazardous tutorials Incidanta. DOT P BS00.3. DOT IDENTIFICATION NUMttR Not applicabla OSHA REQUIRED LABEL INFORMATION In compliance with hazard and rtgnt-to-know requirements, tho following OSHA Hazard Warnings should ba found on a labal, bill of lading or invoiea accompanying this shipment. (OSHA Hazard warnings not appHeabla for this product: tharsfora. no OSHA warnings would appaar on tho labol.) Nota: Product labal will contain additional non-OSHA rolatad Information. Tha Information and racoasaandstIons eontalnod harain ara, to tho boat of Exxon's knowledge and bellaf, accurata and rat labia as of tha data Issued. Exxon does not warrant or guarantee their accuracy or reliability, and Exxon shall not ba liable for any loss or damega arising out of tha use thereof. The Information and recommendations are offered for tho user's consideration and examination, and It It the user's responsibility to satisfy Itself that they are suitable and complete for its particular use. If buyer repackages this product, legal council should ba consulted to insure proper health, safety and other necessary Information is included on the container. The Envlrorsaantal Infonaetlon Included under Section H hereof as well as the Hazardous Materials Identification System (HMISI and National Fire Protection Association (NFPA) ratings have been Included by Exxon Company, U.S.A. In order to provide additional health and hazard classification Information. Tho ratings recommended are based upon the criteria supplied by the developers of these rating systems, together with Exxon's Interpretation of the available data. FOR ADDITIONAL INFORMATION ON HEALTH EFFECTS CONTACti DIRECTOR OF INDUSTRIAL HYOIENE EXXON COMPANY. U.S.A. P. 0. BOX aiSO ROOM 91ST Houston, tx TTasa-aieo (713) S5S-3443 FOR OTHER PRODUCT INFORMATION CONTACT: MANAGER. MARKETING TECHNICAL SERVICES EXXON COMPANY. U.S.A. P. O.-BOX J10 ROOM 33SS HOUSTON. TX 77293*3ISO (713) SSS-SS4S t<l-ot7;wmooa PAOE: B DATE ISSUED: 0S/01/B9 SUPERSEDES DATE: OS/ta/SS pE 008534 1 *0-3 15V-40 EJgONCOMPANY. USA * owwoe o* twwoe eoaroutio* DATE ISSUED: 03/01/91 SUPERSEDES DATE: 10/13/90 MATERIAL SAFETY DATA SHEET EXXON COMPANY, I'.S.A. P-0. 30* 2130 HOUSTON. TX 772S3-3130 A IDENTIFICATION AND EMERGENCY INFORMATION PRODUCT NAME XO-3 1SW-40 PRODUCT CATEOORY Petroleum Lubrteat trig DO PRODUCT APPEARANCE AND OOOR Clear, dark aMr liquid Mild, bland patreldtaa odor MEDICAL EMEROtNCT TELEPHONE NUMBER 1713) SB3-3434 PRODUCT COOS 211733 - 01732 B. COMPONENTS AND HAZARD INFORMATION COMPONENTS Diatlllatea (petroleum), paraffinic jr Jtetlllstet (petroleum), heavy paraffinic hydrotreated heavy aolvant-dewaxed CAS NO. OP COMPONENTS 34742-34-7 or 34742-33-0 APPROXIMATE CONCENTRATION Greater than 7S% Proprietary eddltlvea Mixture Lose than 25% All components of thla product are Hated on the U.S. TSCA inventory. See Section E for Health and Haiard Information. See Section H for additional Environmental Information. HAZARDOUS MATERIALS IDENTIFICATION SYSTEM (HMIS) Health PI earnability Reactivity BASIS 11 0 Roco--ended by Exxon EXPOSURE LIMIT FOR TOTAL PRODUCT S mg/m2 for oil Mist (aeroaol) In air BASIS OSHA Reoulatlon 23 CFR 1310.1000 8 mg/*3 for oil alat (aaroaot) Recommended by the American Conference of Ooverrmantal Industrial Hyp1anlata (AC3IH) 3- mg/m3 for miat (aeroeol) In air Recommended by Exxon C PRIMARY ROUTES OF ENTRY AND EMERGENCY AND FIRST AD PROCEDURES ETE CONTACT -If tplaehed Into the eye*, flush with clear'water for IE Minutes or until Irritation subsides. If irritation pert I ate, call a physician. XIN In case of akin contact, ramove any contaminated clothing end wash skin thoroughly with eoap and water. u-ewiamwoon DE 008535 XD-3 1SV-40 1M4ALATI0N `apor pressure la very lew, vapep inflation under ambient conditions < normally not a -eblem. If. overcome by vapor from hot product, immediately remove from exposure and eall a physician. If breathing is irregular op hat ateppad, ttapt ratutcitation: administer oxygen, if available. if overexposed to oil Mat. remove from further exposure until excaaatva oil Plat condition auoaldaa. INOtSTION If tngeated, DO NOT Induce vomiting: call a phytic Ian immediately. D. FIRE AND EXPLOSION HAZARD INFORMATION FLASH POINT (MINIMUM) 304'c OSS'F) ASTM o S3. Claval and Open Cup AUTOIONITION TEMPERATURE Not datapplnad NATIONAL FIRE PROTECTION ASSOCIATION (NFPA) HAZARD IDENTIFICATION Health Flaasaablltty Reactivity SASIS II 0 Racoppandad by Exxon HANOLINO PRECAUTIONS Uta product with caution around haat. tparxa. pitot l.lghta, atatle elaetrlclty. and open ftaee. FLAMIASLE OR EXPLOSIVE LIMITS (APPROXIMATE PERCENT IT VOLUME IN AIR) Eatlaatad valuaa: Lower Flappable Ltntt Q.RX Upper flappable Llnlt 7% EXTIN9UISHIN0 MEDIA AND FIRE FIOHTINB PROCEDURES Foaa, water apray (fog), dry chapteal. carbon dtoxtda and vaporizing liquid type axtingulahlng I Agents pay all be aultable for axtIngulahlng ftree Involving thia type of preduet, depending on tie or potential atza of fire and etrcunatancaa related to the eituatton. Plan fire protection nd reaoonea etrAtegy through conaultatlon with local fire protection author It let or approprlata apaelaltlata. The following proctdurtt for thia typo of produet are baaed on the racopeandatlona in the National Fire Protection Association's `Fire Protection guide on Hazardous Materiaia*. Eighth Edition (ISM): Uoe water apray, dry eheolcal, foam, or carbon dioxide to extlngulah the fire. Water or foan nay eauae frothing. Uaa water to keep fire-exposed eontalnera cool. Water apray pay be uaed to fluah spills away froe expoauraa. Minimize breathing of gaaea, vapor, funea or daeompoaition producta. uaa aupplled-atr breathing equipnent for aneloeed or confined apaeaa or aa otherwiae needed. DECOMPOSITION PROOUCTS UNDER FIRE CONDITIONS Fume, aneke, carbon monoxide, aul fur oxldea, aidehydea and other deeoepoattlon producta. in the eaee of incoeptete eoabustlon. EMPTY* CONTAINER WARNINE `Empty* eontalnera retain reaidue (liquid and/or vapor) and ean be dangeroue. DO NOT PRESSURIZE, CUT, WELD, SRAZE. SOLDER, ORILL. ORINO OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME. SPARKS. STATIC ELECTRICITY. OR OTHER SOURCES OF lONITIONt THEY MAY EXPLODE AND CAUSE INJURY OR OEATM. Oq not attempt to clean etnea residue te difficult to remove. `Empty* drum should be eomletely drained, properly bunged and promptly returned te a drum reeondittoner. All other eontalnera ahould be disposed of In an enyJ.ronmntat!y safe manner and in accordance with governmental'regulations. For work on tanks refer to Oeeupattonei Safety and Health Adminlatrstlon regulations, ANSI I4S.1, and other governmental and irxzjstrial references pertaining to cleaning, repairing, welding, or other contemplated operations. I PAQl! 3 OAT! ISSUED*. o7oT7*T SUPERSEDES OATEt 10/1S/SO I DE 008536 XO-3 ISM-40 1 E HEALTH AND HAZARD INFORMATION VARIABILITY MONO INDIVIDUALS Health studies Niva hown that many petroleum hydrocarbon* and synthetic lubricants poaa potential human health rlaka whien aay vary fro* parson to paraon. as a praeaution, exposure to-ltqutde. vapor*, miets or fumes should b* minimized. EFFECTS OF OVEREXPOSURE (Sign* and xyxptom* of exposure) Prolonged or repeated akin contact any eauaa akin Irritation. NATURE OF HAZARD ANO TOXICITY INFOtWATtON In aeeordanea with tha currant OSHA Hazard Communication Standard crttarta, thta oroduct doa* not require a cancar hazard warning. Thia ta baeauaa tha product t* formulated fro* baaa atock* which ara aavaraiy hydrotraatad. aevaraly aolvant extracted, and/or proceaaed by milo hydrotreatmant and axtraetion. Alternatively. It may cone 1 at of component* not otnarwiae affected by IARC critaria, aueh a* atnoapnarie diatillate* or aynthetically derived natertaia. and a* open la not characterizad by currant IARC claaaification criteria. Prolonged or rapaatad akin contact with thta product tend* to remove akin oil*, poaaibiy leading to Irritation and damatiti*. However, baaed on Kaaan axparlanca and available toxicological data, thia product la Judged to be neither a "corrosive* nor an `irritant* by OSHA critaria. Continuoua contact with uaed motor oil haa cauaed akin eancar in animal taata. ProAiet contacting tha ayoa nay eauaa eye irritation. Product haa a low order of acuta oral and darnel toxicity, but minute amount* aapiratad into tha lung* Airing Ingeatlon or vomiting nay eauaa mild to aavora pulmonary Injury and poaaibiy death. Thta product 1* judged to have an acuta oral LDBO (rat) greater than S g/kg of body weight, and an acuta dermal LOSO (rabbit) greater than 3. IS g/kg of body weight. -EXISTINO MEDICAL CONDITIONS MUCH MAT BE AQOKAVATCO BY EXPOSURE Nona Recognized F. PHYSICAL DATA The following data are approximate or typical value* and should not be used for precise design purposes. BOILINO RANOt ISP Approximately 303*0 (87S*F) VAPOR PRESSURE Lass than 0.01 mm Mg a 20*C SPECIFIC ORAVITY (1B.B C/1S.S C) O.ss MOLECULAR'VEIOHT Not determined VAPOR DENSITY (AIR 1) areater than B PERCENT VOLATILEBY VOLUME Nagliglble from open container In A hours e SB'C (iOO'F) pH Essentially neutral e EVAPORATION RATI 1 ATM. AMD SI C (77 F) (n-BUTYL ACETATE * 1) Las* than 0.01 POUR. CQNBEALtNB OR NELT1NI POINT "24*C ("11*F) Pour Point by ASTM 0 S7 SOLUBILITY IN WATER P t ATM. ANO II C (77 F) Negligible; less then 0.IX VISCOSITY 14.3 est S 10O*C < ut-WTtmoea PAQC: 3 DATE ISSUED: OB/OI/11 SUPERSEDES OATS: iO/iS/SO DE 008537 *0-3 1SW-4Q G REACTIVITY This product ts stable and wilt not raaet violently with watar. Haxardoua polymerization will net occur. Avoid contact with strong oxidants aueh aa liquid ehlorlna, concantratad oxygon, sodium hypochtorIta, calcium hypochtartta. ate. K ENVIRONMENTAL INFORMATION STEPS TO H TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Raeovor froa predict. Add aand, aarth, or other aultabto aoaorbant to apllt area. Minimize akin contact, keep proAiet out of aawara and watarcouraaa by diking or impounding. Adviae autnoritiaa if product ha* entered or may enter aawara, watarcouraaa, or axtenaive land araaa. Aaeure conformty with applicable governmental ragutattona. THE POLLOtfINO INFORMATION MAT SE USEFUL IN CONPLTINO WITH VARIOUS STATE AND FEDERAL LAVS AND REQULAT10NS UMICR VARIOUS ENVIROMMNTAL STATUTES: REPORTASLE QUANTITY (RQ), EPA REGULATION 40 CFR 90S (CERCLA Section lOi) No RO for production any eonatltuant graatar than 1% or 0.1% (carcinogen). THRESHOLD PLANNING QUANTITY (TPQ), EPA REGULATION 40 CFR 3SS (SARA Sections 301-304) No TFQ for proAiet or any constituent graatar than t% or 0.IX (carcinogen). TOXIC CHEMICAL RELEASE REPORTING. EPA REGULATION 40 CFR STS (SARA Sedtlen 313) No toxic ehomtea! la present graatar than 1% or 0.1% (carcinogen). HAZARDOUS CHEMICAL REPORTING. EPA REGULATION 40 CFR 370 (SARA Sections 311-31S) Acute Chrome Fire Pressure Reactive EPA HAZARD CLASSIFICATION CQOC: Hazard Hazard Hazard Hazard Hazard Not Applicable xxx l PROTECTION AND PRECAUTIONS VENTILATION Use local exhauat to capture vapor, mists or fumes. If necessary. Provide ventilation sufficient to prevent exceeding recommended exposure limit or buildup of explosive concentrations of vapor In air. No smoking, ftema or other ignition sources. RESPIRATORY PROTECTION Use supplied-air respiratory protection in confined or enclosed spaces, if needed. PROTECTIVE GLOVES Use chemical-resistant gloves. If needed, to avoid prolonged or repeated skin contact. EYE PROTECTION Use splash goggles or faee shield when eye contact may occur. OTHER PROTECTIVE EQUIPMENT Use enemies!-reslatent apron or other impervious clothing. If needed, to evotd contaminating regular clothing, which could result in prolonged or repeated skin contact. WORK PRACTICES / ENGINEERING CONTROLS Keep containers closed when not In use. Do not store near heat, sparks, flame or strong oxidants. In order to prevent fire'or explosion hazards, use appropriate equipment. Information on electrical equipment appropriate for use with this product may be found in the latest edition of the National Eleetrleat Code (NfPA-70). This document is available from the National Fire Protection Association, Gatterymarch Park, Quincy, Masaachusetts oaats. PERSONAL HYGIENE Minimize breathing vapor, mist or fumes. Avoid prolonged or repeated contact with akin. Remove contaminated clothing; launder or dry-clean before re-use. Remove contaminated shoes and thoroughly dean before re-use; discard If ott-seaked. Cleanse skin thoroughly after contact, before breaks and meald, and at end of work period. Product le roadtly removed from akin by watarlasa hand deanere followed by washing thoroughly with soap and watar. ItlOlllWMog PAQCl 4 DATE ISSUED: 04/01/91 SUPERSEDES DATE: 10/14/90 DE 008538 XD-3 I5W-40 r J. TRANSPORTATION AND OSHA RELATED LABEL INFORMATION TRANSPORTATION .NCIOENT XNfORMATION for further Information relative to iptlu resulting from transportation Incidents. refer .to tataat Oapartmant of Transportation tnarganey Response Guidebook for Hazardous Materials Incident*. 00T P BBOO.3. DOT IDENTIPICATION NUMBER Not sDpiteable OSHA REQUIRED LABEL INFORMATION In eonottanca with hazard and Mght-to-know raautramanta. tha following OSHA Hazard Warnings should ba found on a labat. Bill of lading or tnvotea aeeonpanylng this shipment. (OSHA Hazard warnings not appltcabla for this product: thorafora. no OSHA warnings would appaar on tha tatool.) Nets: Product labal will contain additional non-OSHA ralatad Information. Tha Information and racoawandatlons cents Inad harain ara, to tha bast of taxon's knowlodge and belief, aeeurata and rat labia as of tha data lasuad. Exxon does not warrant or guarantee thstr 'curscy or rellabl1 tty, and Exxon snail not bo liable for any less or damage arising out of tisa thereof. The Information and racomaendatlona are offered for the user's consideration and examination, and It Is the user's responsibility to satisfy Itself that they are suitable and eeapleta for its particular use. If buyer repackages this produet, legal counsel should be consulted to Insure proper, heelth, safety and other necessary Information is included on the container. The Environmental Information Included under Section H hereof as well as the Hazardous Materials Identification System 1HMXS) and National Plre Protection Association (NFPA) ratings hsve been included by Exxon Company, U.S.A. In order to provide additional health and hszard classification Information. The rating* racoammndad are baaed upon the criteria supplied by the developers of those rating aystarn#, together with Exxen'e Interpretation of the available date. FOR ADDITIONAL INFORMATION ON HEALTH EFFECTS CONTACT: DIRECTOR OF INDUSTRIAL HYGIENE EXXON COMPANY, U.S.A. KELLOGG TOWER, ROOM ISO P. 0. BOX 3ISO HOUSTON. TX 773B3-31B0 (713) BBS-3443 FOR OTHER PR00UCT XNFORMATION CONTACT: MANAGER. MARKETING TECHNICAL SERVICES EXXON COMPANY, U.S.A. ROOM 3GSS P. O. BOX 31*0 HOUSTON, TX 77383-3ISO (713) SBG-S34* Mi-omwmoea 1 PAGE: S DATE ISSUED: 0B/01/SI SUPERSEDES DATE: 10/IB/BO DE 008539 XD-3 30 E)J<pNCOMPANY USA > oivnio* of txxoe toxfoxinoa 0A7| 1SSUE0: 10/16/90 SUPERSEDES DATE; MATERIAL SAFETY DATA SHEET EXXON COMPANY. U.S.A. P.O. BOX 31S0 HOUSTON. TX 7T2S3-31IO A IDENTIFICATION AND EMERGENCY INFORMATION PRODUCT NAME XO-3 30 CHEMICAL NAME Petroleum Lubricating Oil PRODUCT APPEARANCE AND ODOR Clear, oarx amber Mould Mild, bland petroleum odor MEDICAL EMEROENCT TELEPHONE NUMSER (713) 656-3434 PRODUCT CODE 211730 - 01730 CAS NUMSER Complex Mixture CAS Number not applicable B. COMPONENTS AND HAZARD INFORMATION COMPONENTS Distillates (petroleum). hydrotreated heavy paraffinic oDr lttmuai (petroleum), aolvent-dewaxed haavy paraffinic CAS NO. OP COMPONENTS 4743-54-7 or 4742-B5-0 APPROXIMATE CONCENTRATION Qreater than 65% Proprietary addltfvea Mixture Lea* than 15% Thl* product and all components are Hated on the U.S. TSCA Inventory. Saa Sactten E for Health and Hazard Information. Sea Section H for additional Environmental Information. HAZARDOUS MATERIALS IDENTIFICATION SYSTEM (HMIS) Health PI (Ifty Raaotivity BASIS t1 0 Recommended by Exxon EXPOSURE LIMIT FOR TOTAL PRODUCT 5 mg/m3 for ell mtat in air BASIS OSHA Regulation 3i CFR 1B10.1000 5 mg/*3 for oil mlat Racommandad by the American Conference of Qovarnmental Industrial Hyglanlata (ACOIH) 5 mg/m3 for mtat In air Racommandad by Exxon C PRIMARY ROUTES OF ENTRY AND EMERGENCY AND FIRST AID PROCEDURES EYE CONTACT .If splaahed Into the eyee. flush with clear water for IS minute* or until irritation aubsides. If irritation para lata, call a physician. tfl-ai77lrmeen DE 00854 XD-3 30 SKIM In case of akin contact, remove any contaminated clothing and wash akin thoroughly with soar and water. inhalation Vapor oraaaura la vary low. Vapor Inhalation unaar ambient condition! la normally not a problem. If overcome by vapor from hot product. Immediately remove from exposure and call a phyalelan. If braatnlng la Irregular or haa atoppad. etart reauecitatton: admlniatar oxygen. If available. If overexposed to oil mist, remove from further exposure until excessive oil ml at condition eubatdes. INGESTION If ingested, 00 NOT induce vomiting; call a physician tmnadlately. D. FIRE AND EXPLOSION HAZARD INFORMATION FLASH POINT (MINIMUM) 230* C (42I*F) astm o 92. Cleveland Open Cup AUTOIONITION TEMPERATURE Not determined NATIONAL FIRE PROTECTION ASSOCIATION (NFPA) HAZARD IDENTIFICATION Health Flamaabtltty Reactivity 9AS1S I I 0 Recommended by Exxon HANDLIM PRECAUTIONS Use product with caution around heat, sparks, pilot lights, static electricity, and opan flame. l | LAMMARLE OR EXPLOSIVE LIMITS (APPROXIMATE PERCENT tT VOLUME IN AIR) Estimated values: Lower Flammable Limit 0.9% Upper Flammable Limit 7% EXTINOUISHINO MEDIA AND FIRE FIOHTINO PROCEDURES Foam, water spray (fog), dry chemical, carbon dioxide and vaporizing Mould type extinguishing agents may alt be suitable for extinguishing fires Involving this type of product, depending on size or potential size of fire and circumstances related to the situation. Plan fire protection and response strategy through consultation with local fire protection authorities or appropriate speciaitiste. The following procedures for this type of product are based on the recommendations in the National Fire Protection Association's *Ftra Protection Qulde on Hazardous Materials*. Eighth Edition (1994): Use water spray, dry chemical, foam, or carbon dioxide to extinguish the fire. Water or foam may cause frothing. Use water to keep ftre*exposed containers cool. Water spray may ba used to flush spills away from axposures. Minimize breathing of gases, vapor, fumes or decomposition products. Use supplled-alr breathing equipment for enclosed or confined spaces or as otherwise needed. DECOMPOSITION PRODUCTS UNDER FIRE CONDITIONS Fumes, smoko, carbon monoxide, sulfur oxides, aldehydes and other decomposition products, in the ease Of incomplete combustion. EMPTY" CONTAINER WARNINB Empty" containers retain residue (liquid snd/or vapor) and can ba dangerous. 00 NOT PRESSURIZE, CUT, WELO. BRAZE, SOLOER. DRILL. ORINO 0R EXPOSE SUCH CONTAINERS TO HEAT. FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF I0NITI0N; THEY MAY EXPLOOE AND CAUSE Injury OR OEATH. Do not attempt to clean since residue Is difficult to remove. "Empty* drums should be completely drained, properly bunged and promptly returned to a drum recondltloner. All other containers should be disposed of*ln an environmentally safe manner and In accordance with governmental regulations. For work on tanks refer to Occupational Safety and Health Administration regulations, ANSI Z49.1, and other governmental and industrial references pertaining to cleaning, repairing, welding, or other contemplated operations. ift-atfraMMMP PAOE: 2 DATE ISSUED: 10/16/90 SUPERSEDES DATE: * DE 008541 XD-3 30 E HEALTH AND HAZARD INFORMATION VARIABILITY AMONG INOIVIOUALS Hesltn studies have shown that many petroleum hydrocarbons end synthetic lubricants boss ootentisl human health Malta which may vary from carton to parson. Aa a precaution, exposure to ItoulCl. vapors, miats or fumaa should bs minimized. EFFECTS OF OVEREXPOSURE (Signs and syeptoms of exposure) Prolonged or rapaatad akin contact may causa akin Irritation. NATURE OF HA2ARD ANO TOXICITY INFORMATION In accordance with tha currant OSHA Hazard Communlcation Standard criteria, this product does not rscuire a cancer hazard warning. This Is because the produet is formulated from base stocks which are severely hydrotreated, severely solvent extracted, and/or processed by mile hydrotreatmant and extraction. Alternatively. It may consist of components not otherwise affected by 1ARC criteria, such as atmospheric distillates or synthetically derived materials, and as suen le not characterized by currant IARC classification criteria. Prolonged or repeated skin contact with this product tends to remove skin oils, possibly leading to Irritation and dermatitis. However, based on human experience and available toxicological data, this product is judged to be neither a corrosive" nor an 'irritant* by OSHA criteria. Continuous contact with used motor oil has caused skin cancer in animal tests. Product contacting the eyes may cause eye Irritation. Product has a low order of acute oral and dermal toxicity, but minute amounts aspirated into the lungs during Ingestion or vomiting may cause mild to severe pulmonary injury and possibly death. This product Is Judged to have an acute oral LDSO (rat) greater than 9 g/kg of body weight, nd an aeute dermal L090 (rabbit) greater then 3.It g/kg of body weight. PRE-EXISTING MEDICAL CONDITIONS WHICH MAY BE AGGRAVATED BY EXPOSURE Nona Recognized F. PHYSICAL DATA The following date are approximate or typical values and should not bo used for precise design purposes. BOILING RANGE IBP Approximately 303* C (9TS*F) VAPOR PRESSURE Less than 0.01 mn Hg e 30*C SPECIFIC GRAVITY (1S.B C/1B.B C) 0.89 VAPOR DENSITY (AIR 1) Greater than S MOLECULAR WEIGHT Not determined PERCENT VOLATILE ST VOLUME Negligible from open container In 4 hours 0 3B* C (lOO'F) PH Essentially neutral EVAPORATION RATE P 1 ATM. ANO SB C (77 F) (n-BUTTL ACETATE 1) Lass than o.oi POUR, CONGEALING OR MELTING POINT -18* C (O'F) Pour Point by ASTM 0 B7 SOLUBILITY IN WATER P 1 ATM. AND 39 C (77 F) Negligible; laaa than 0.1* VISCOSITY 11.8 cSt 9 100*C l<l'017>tuwwoetl ~! PAGE: 3 OATE ISSUED: 10/16/90 SUPERSEDES OATE: &E 008542 I G REACTIVITY XO-3 30 Tht product It tttbtt and will not react violently with wtttr. Hazardous polymerize!ion will not occur. Avoid contact with ttrong oxidants such at Ilould chlorine, conctntratad oxygen, sodium hypochlorite or calcium hypochlorite. K ENVIRONMENTAL INFORMATION STEPS TO TAKEN IN CASE MATERIAL IS RELEASED OR SPILLEO Recover free produet. Add tend, earth, or other suitable absorbent to spill area. Minimize skin contact. Keep product out of aewera and watercoursaa by diking or Impounding. Advise authorities If product has entered or may enter sewers, watercourses, or extensive land areas. Assure conformity with applicable governmental regulations. THE FOLLOWING INFORMATION MAY SE USEFUL IN COMPLYINS WITH VARIOUS STATE AND FEDERAL LAWS AND REGULATIONS UNDER VARIOUS ENVIRONMENTAL STATUTES: REPORTARLE QUANTITY (RQ). ERA REOULATION 40 CFR 302 (CERCLA Section 102) No RO for product or any eonatltuent greater than IX or 0.IX (carcinogen). THRESHOLD PLANNING QUANTITY (TPQ), ERA REOULATION 40 CFR 3SS (SARA Sections 301-304) No TPO for product or any constituent greater than 1% or 0. IX (carcinogen). TOXIC CHEMICAL RELEASE REPORTINS, ERA REOULATION 40 CFR 373 (SARA Section 313) No toxic ehemteal le present greater than IX or O.IX (carcinogen). HAZARDOUS CHEMICAL REPORTING, ERA REOULATION 40 CFR 370 (SARA Sections 311-313) Acuta Chronic Fire Pressure Reactive 'A HAZARD CLASSIFICATION CODE: Hazard Hazard Hazard Hazard Hazard Not Applicable XXX I. PROTECTION AND PRECAUTIONS VENTILATION Use local exhaust to capture vapor, mists or fumes. If necessary. Provide ventilation sufficient to prevent exceeding recommended exposure Halt or buildup of explosive eoneentretIons of vapor In air. No smoking, flame or other Ignition sources. RESPIRATORY PROTECTION Use supplled-air respiratory protection In confined or enclosed spaces, if needed. PROTECTIVE GLOVES Use chemical-resistant gloves. If needed, to avoid prolonged or repeated sktn contact. EYE PROTECTION Use splash goggles or face Shield whan aye contact aiay occur. OTHER PROTECTIVE EQUIPMENT Use chemical-resistant apron or other impervious clothing, if needed, to avoid contaminating regular clothing, which.could result In prolonged or repeated akin contact. WORK PRACTICES / ENGINEERING CONTROLS Keep containers eloeed when not In use. Oo not store near heat, sparks, flame or strong oxidants. In order to prevent fire or explosion hazards, use appropriate equipment. Information on electrical equipment approprlata for use with this produet may be found In the latest edition of the National Electrical Coda (NFPA-70). This document is available from the National Fire Protection Association, tatterymarch Park, Quincy, Massachusetts 022SS. I RSONAL HYGIENE Minimise breathing vapor, mlat or fumes. Avoid prolonged or repeated contact with skin. Remove contaminated clothing; launder or dry-clean before re-use. Remove eontemlnated shoes and thoroughly clean before re-uae; discard if oll-aeaked. Cteanae skin thoroughly after contact, before breaks and meals, and at end of work period. Product la readily removed from skin by waterless hand eleaners followed by washing thoroughly with soap and water. Ml-ememoea PAGE: 4 " DATE ISSUED: 10/16/90 SUPERSEDES DATE: DE 008543 XO-3 30 J. TRANSPORTATION AND OSHA RELATED LABEL INFORMATION TRANSPORTATJON INCIDENT INFORMATION For Further Information relative to anil's resulting from transDortatIon incidents. refer to latest Department of TransportatIon Emarganey Raaponaa Guidebook for Hazardous Materials Incidents. DOT P 58003. DOT IDENTIFICATION NUMBER Not applicable OSHA REQUIRED LABEL INFORMATION In compliance with Hazard and right-to-know reouirements. the following OSHA Hazard warnings should be found on a label, bill of lading or invoice accompanying this shipment. (OSHA Hazard warnings not sop)Icable for this product; therefore, no OSHA warnings would appear on the label.) Note; Product label will contain additional non-OSHA related Information. 1 p i The Information and recommendations contained herein are, to the best of Exxon's knowledge and ellef, accurate and reliable as of the date Issued. Exxon does not warrant or guarantee their .ceuraey or reliability, and Exxon shall not be liable for any loss or damage arising out of the use thereof. The Information and recoirmendatIons are offered for the user's consideration and examination, and It it the user's responsibility to satisfy itself that they are suitable and eoneiete for Its particular usg. If buyer repackages this product, legal counsel should be consulted to Insure proper health, safety and other necessary Information Is included on the container. The Environmental Information Inoluded under Section H hereof as well as the Hazardous Materials Identification System (HMIJl and National Fire Protection Association INFRA) ratings have been Included by Exxon Company, U.S.A. In order to provide additional health and hazard classification information. The ratings recoamended are based upon the criteria supplied by the developers of these rating systems, together with Exxon's interpretation of the available data. FOR A00ITI0NAL INFORMATION ON HEALTH EFFECTS CONTACT: DIRECTOR OF INDUSTRIAL HYGIENE EXXON COMPANY, U.S.A. P. 0. BOX 3160 ROOM 31ST HOUSTON, TX 77353-31BO (713) 38-2443 FOR OTHER PRODUCT INFORMATION CONTACT; MANAGER. MARKETING TECHNICAL SERVICES. EXXON COMPANY, U.S.A. P. 0. BOX 3 ISO ROOM 33SS HOUSTON, TX 77253-3180 (T13) eSS-SSAt I m.omsnrwoon PAGE; S DATE ISSUED: 10/16/90 SUPERSEDES DATE; DE 008544 SUPERFLO ATF E^ONCOMPANY. USA ONIdOH Of IXXO* COWOU1IO* DATE ISSUEO: 0C/01/89 SUPERSEDES OATE: 05/19/89 MATERIAL SAFETY DATA SHEET EXXON COMPANY, U.S.A. P.O. BOX 2180 HOUSTON. TX 77252-2180 A IDENTIFICATION AND EMERGENCY INFORMATION PRODUCT NAME SUPERFLO ATF CHEMICAL NAMt Patrol aim Lubricating Oil PRODUCT APPEARANCE AND ODOR Claar rad 1louid Mild, bland petroleum odor MEDICAL EMERQENCY TELEPHONE NUMBER (713) BSC-3434 PROOUCT CODE 211957 - 01957 CAS NUMBER Complex Mixture CAS Humour not applicable a B. COMPONENTS AND HAZARD INFORMATION COMPONENTS CAS NO. OP COMPONENTS APPROXIMATE CONCENTRATION Lubricating Oil Baae Stock* 4743-84-7 or 4742-EB-O and 4741-97-S Greater tnan 90S Propriotary addlttvoa Mixture Laaa than 10% Saa Sactlon E For Haalth and Hazard Inforaatlon. Saa Saetlon H For additional Environmental lnfomatlon. HAZARDOUS MATERIALS IDENTIFICATION SYSTEM (HMIS) Haalth FI IHty Raaettvtty BASIS i t O Roe ndad by Exxon EXPOSURE LIMIT FOR TOTAL PRODUCT 5 mg/n3 For oil xilat In air BASIS OSHA Regulation 2t CFR 1910.1000 5 mg/m3 For oil ml at Recommended by the American ConFaronea oF Qovornitantal lnduttriai Hygioniata (AcaiH) 5 mg/m3 For mlet In air Recommended by Exxon C PRIMARY ROUTES OF ENTRY AND EMERGENCY AND FIRST AID PROCEDURES EYE CONTACT IF aplashed Into the eyea, Fluah with clean water For IB ulnutaa or until Irritation ubatdaa. If irritation paralata, call a phyaieian. SKIN 1 In eaaa of akin eontaet, remove any contaminated clothing and waah akin thoroughly with aoap and water. Ul-oj7?nmoon PE 008545 SUPERFLO atf INHALATION Vapor praaaura la vary lew. vapor Inhalation unear aiablant conet t Iona la normally not a problem. If overcome by vapor from hot product, immediately remove from exposure ane call a phyelclan. If breathing la Irregular or haa ttopoed. atart reauacitat ion; aominiater oxygen. If available. If overexpoaed to oil miat. remove from further axpoaura until exceaalve ell miat eonrMtlon aubaldea. ingestion If tngeeted, 00 NOT Induce vomiting; call a phyaietan immediately. D. FIRE AND EXPLOSION HAZARD INFORMATION FLASH POINT (MINIMUM) 160* C (330* F ) astm 0 93, Cleveland Open Cup AUTOIONITION TEMPERATURE Qreater than 333* C (4S0'F) NATIONAL FIRE PROTECTION ASSOCIATION (NFPA) - HAZARO IDENTIFICATION Health Platmaabl1Ity Reactivity SASIS . 1 1 0 Recommended by Exxon HANOLINO PRECAUTIONS Uae product with eautlon around heat, aparka, pilot 1Ighta, atatie electricity, and open flame. FLAMMASLE OR EXPLOSIVE LIMITS (APPROXIMATE PERCENT >T VOLUME IN AIR) Eatimeted valuea: Lower Flammable Limit O.tX Upper Flammable Limit 7% EXTINGUISHING MEDIA AND FIRE FIOKTING PROCEDURES Foam, water apray (fog), dry chemical, carbon dioxide and vaporizing liquid type extinguiahing agenta may all be aultable for extinguiahing firea Involving thia type of product, depending on aize or potential also of fire and elrcumataneaa related to the eltuatlon. Plan fire protection and reaponaa atratagy through conaultatten with loeal fire protection authorltlae or appropriate epectelttate. The following proceduree for thia type of product are baaed on.the reeommendatlone in the National Fire Protection Aeeoelatton'e "Fire Protection Guide on Hazardoue Materials', Eighth Edition (1114); Uae water apray. dry chemical, foam, or carbon dioxide to exttngutah the fire. Hater or foam may cauee frothing. Uae water to keep ftre-expoaed eontalnere cool. Hater apray may be uied to fluin epllla away from expoaurea. Minimize breathing of gaaea. vapor, fumee or daeompoaitton preduete. Uae aupptled-alr breathing equipment for eneloaed or confined apacaa or aa otherwiae needed. DECOMPOSITION PRODUCTS UNDER FIRE CONDITIONS Fumee, smoke, carbon monoxide, aulfur oxldea, aldehydee and other deeompoa1tion producta, in thq eaaa of incomplete combuation. "EMPTY* CONTAINER HARNIN8 "Empty* eontalnere retain reetdue (liquid and/or vapor) and can be dangeroue. 00 NOT PRESSURIZE. CUT, HELD, SRAZE, SOLOER. DRILL. GRIND OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME. SPARKS. STATIC ELECTRICITY, OR OTHER SOURCES OF IQNITION; THEY MAY EXPLODE ANO CAUSE INJURY OR DEATH. Ob net attempt to clean alnee realdue la difficult to remove. "Empty* druma ahould be completely drained, properly bunged and promptly returned to a drum raeondltloner. All other eontalnere ahould be dlepoaed of In an environmentally aafe manner and in accordance with governmental regutattone. For work on tanka refer to Occupational Safety and Health Admlnlatratlon regulations, ANSI Z4R.1. and other governmental and industrial references pertaining to cleaning, repairing, welding, or other contemplated operations. 1 m-atfIMWWMd ~ " PAGE; 3 DATE ISSUED: 0E/01/B9 SUPERSEDES DATE: OS/19/9 DE 008546 SUPERFIO ATF E HEALTH AND HAZARD INFORMATION VARIABILITY AMONQ INDIVIDUALS Health studies hav* shown that many pstrolsun hydrocarbon* and synthetic lubricants pose ' potential human health risk* which may wary from person to parson. As a precaution, exposure to liquids, vapors, alsts or funes should be minimized. EFFECTS OF OVEREXPOSURE (Signs and symptoms of exposure) Prolonged or repeated akin contact may cause akin Irritation. NATURE OF HAZARD AND TOXICITY INFORMATION In accordance with the current OSMA Hazard Communication standard criteria, this oroduet does not require a cancer hazard warning. This is because the product is formulated from base stocks whieh are severely hydrotreated, severely solvent extracted, and/or processed by mild hydrotreatnent and extraction. Alternatively, it may consist of component* net otherwise affected by IARC criteria, such as atmospheric distillates or synthetically derived materials, and as such is not characterized by current IARC classification criteria. Prolonged or repeated skin contact with this product tends to remove skin oils, possibly leading to Irritation and dermatitis: howaver. based on human experience end evallabla toxicological data, this product is Judged to be neither a "corrosive" nor an "Irritant* by OSHA criteria. Product contacting the eye* my eause eye irritation. Preset has a lew order of acute oral and dermal toxicity, but minute amounts aspirated into the lung* Miring Ingestion or vomiting my cause mild to savers pulmonary injury and possibly death. This product la Judged to have an acute oral LD90 (rat) greater than S g/kg of body weight, and an aeute dermal LDSO (rabbit) greater than 3.IS g/kg of body weight. PRECXISTIM MEDICAL CONDITIONS WHICH MAY SC AOORAVATEO 8Y EXPOSURE None Recognized F. PHYSICAL DATA The following data are approxlmta or typical values and should not be used for precise design purposes. 80ILIN0 RANQE IBP Approximately 348'C (4TS`F) VAPOR PRESSURE Lese than 0.01 mm Hg e 30`C SPECIFIC ORAVITY (1S.S C/1B.S C) O.SS VAPOR DENSITY (AIR 1) greater than 5 MOLECULAR WE10HT Not determined PERCENT VOLATILE ST VOLUME Negligible from open container in 4 houre 3t`C (100*F) PH Essentially hautral EVAPORATION RATI P 1 ATM. AND SB C (77 F) (n-BUTYL ACETATE t) Leas than 0.01 POUR. CONQEALINS OR MCLTINO POINT -40'C (*40"F) Pour Point by ASTM 0 ST SOLUBILITY IN WATER P 1 ATM. AND SB C (77 F) Regllglblei less than 0.1% VISCOSITY 7.0 eSt 100*C momwvwoen PAOE: 3 DATE ISSUED: 08/01/89 - SUPERSEDES DATE: OS/1S/8S DE 008547 SUPERFLO ATP a REACTIVITY This product Is stable and will not react violently with water. Hazardous polymerization will not occur. Avoid contact with strong oxidants suen as liquid culorlne, concentrated oxygen, sodium hypochlorite or calcium hypochlorite. K ENVIRONMENTAL INFORMATION STEPS TO IE TAKEN IN CASE MATERIAL IS RELEASED OR SRILLEO Recover free product. AM sand, earth. or other suitable absorbent to spill ares. Minmna akin contact. Kaap protkiet out of sewers ana watareouraa* by diking or inpounding, aovisa authorities if proauet hat antaraO or nay ontar sewers, watareouraaa, or extensive land araaa. Aaaura conform ty with aBP I 1 cabla governmental regulations. THE FOLLOWING INFORMATION MAT IE USEFUL IN COMPLYING WITH VARIOUS STATE AND FEDERAL LAWS AND REQULATIONS UNDER VARIOUS ENVIRONMENTAL STATUTES: REPORTAIL! QUANTITY (RO), EPA REOULATION 40 CPR SOS (CERCLA SactIon 102) No RQ for proMet or any conatltuant greater than IX or 0.1X (carcinogen). THRESHOLD PLANNINO QUANTITY (TPO), EPA REOULATION 40 CFR 311 (SARA Sact Iona 301-304) No TPQ for product or any eonatttuont graatar than IX or 0.1X (eareinogan). TOXIC CHEMICAL RELEASE REPORTINQ. EPA REOULATION 40 CPR 372 (SARA SactIon 313) No toxic chemical la praaant graatar than IX or 0.1X (eareinogan). HAZARDOUS CHEMICAL REPORTINQ, EPA REOULATION 40 CFR 370 (SARA Sections 311-312) Aeuto Chronic Flra Prosaura Raaetlva EPA HAZARD CLASSIFICATION COOS: Hazard Hazard Hazard Hazard Hazard Not Applicable XXX L PROTECTION AND PRECAUTIONS VENTILATION Use local axhauat to eaptura vapor, mats or fumes, if nacassary. Provide ventilation auffleiant to prevent exceeding recommended exposure limit or buildup of explosive concentratIona of vapor In air. Nosmoklng, flame or other Ignition aoureas. RESPIRATORY PROTECTION Use suppllad-air respiratory protection In confined or enclosed spaeaa, if naaded. PROTECTIVE OLOVES Use chemical-resistant gloves. If needed, to avoid prolonged or repeated akin contact. EYE PROTECTION Use splash gogglee or face shield when eye eontaet may occur. OTHER PROTECTIVE EQUIPMENT Uea chemical-resistant apron or other impervious clothing. If naaded. to avoid contaminating regular clothing, which eould result in prolonged or repeated akin contact. WORK PRACTICES / ENOINEERINB CONTROLS Keep containers closed when net in use. Do not store near heat, sparks, flame or strong oxidanta. In order to prevent fire or explosion hazards, use appropriate equipment. Information on eleetrleal equipment appropriate for use with this product nay be found in the latest edition of the National Eleetrleal Code (NFPA-70). This document la available from the National Fire Protection Association, Batterymareh Park, Quincy, Massachusetts 022ta. PERSONAL HY01ENE , Minimize breathing vapor, mist or fumes. Avoid prolonged or repeated contact with akin. Remove contaminated etothlng; launder or dry-clean before re-uaa. ' Remove contaminated shoes and thoroughly clean before re-use: discard If ol1-soaked. Cleanse skin thoroughly after eontaet, before breaks and meals, and at and of work period. Produet la readily removed from skin by waterless hand cleaners followed by washing thoroughly with aosp and water. Kl-emsnmeeo PAGE: 4 DATE ISSUED: 06/0I/B9 SUPERSEDES OATE: 05/19/89 PE 008548 superflo atf J. TRANSPORTATION AND OSHA RELATED LABEL INFORMATION TRANSPORTATION INCIOIHT INFORMATION For further informat Ion relative to ISl'll rMultinj From transportation Ineldente. raF*r to latest Oepartnant of Transportation Emergency Rasponaa Guidebook for Hazarooue Matariali Incidents, DOT P 5800.3. DOT IDENTIFICATION MJMSER Not appllcabla OSHA REOUtRED LAREL INFORMATION In eonpltsnee with hazard and right-to-know requirements, tha following OSHA Hazard warnings should bo found on a labol, bill of lading or tnvoleo accompanying this shipment. (OSHA Hazard warnings not appllcabla for this produet; tharafera. no OSHA warnings would appaar on tha labal.) No tar Product labal will contain additional non-OSHA ralatad information. Tha Information and racoamandatlons contained harain sra. to tha bast of Exxon's knowledge and belief, accurate and reliable as of the date Issued. Exxon does not warrant or guarantee their accuracy or reliability, and Exxon shall not be liable for any loss or damage arising out of the use thereof. The Information and recommendations are offered for the user's consideration and examination, and It Is the user's responsibility to satisfy l.tsetf that they are suitable and couplets for its particular use. If buyer repackages this produet, legal eounelt should be consulted to insure proper health, safety and other neeassary Information Is Included bn the container. The Environmental Information Included under Section H hereof as well as the Hazardous Materials Identlfleatlon System (HMXS) and National Fire Protection Association (NFPA) ratings have been included by Exxon Cospany, li.S.A. In order to provide additional health and hazard classification Information. The ratings recommended are based upon the criteria supplied by the developers of these rating syatesw, together with Exxon's interpretation of the available data. FOR ADDITIONAL INFORMATION ON HEALTH EFFECTS CONTACT: DIRECTOR OF INDUSTRIAL HVOIENf EXXON COMPANY. U.S.A. P. 0. SOX 2ISO ROOM 31ST HOUSTON. TX 7T2S2*2ISO (713) (38*3443 FOR OTHER PRODUCT INFORMATION CONTACT: MANAOER. MARKETINO TECHNICAL SERVICES EXXON COMPANY. U.S.A. P. 0. SOX 3 ISO ROOM 33SS HOUSTON. TX TT252*2ISO (713) S9S-BS4S moiJJwwwoon PAQE: DATE ISSUEO: 0S/01/89 SUPERSEDES OATE: 0S/1S/M X)E008549 HONEX MP ETjQONCOMPANY. USA * dnoio* o cxxoe coaroaMioa DATE ISSUED: 09/01/99 SUPERSEDES DATE: 03/19/M MATERIAL SAFETY DATA SHEET EX..ON COMPANY. U.S.A. P.O. BOX 3190 HOUSTON. TX 77252*3190 A IDENTIFICATION AND EMERGENCY INFORMATION PRODUCT NAME RONEX MP CHEMICAL NAM Petroleum Lubricating Grease PRODUCT APPEARANCE AND 000R Smooth dark groan grease Ml Id. bland odor MEDICAL EMERGENCY TELEPHONE NUMER (713) 939*3434 PRODUCT CODE 333194 - 03194 CAS NUMBER Complex Mixture CAS Number not appileabia B. COMPONENTS AND HAZARD INFORMATION COMPONENTS CAS NO. OF COMPONENTS APPROXIMATE CONCENTRATION ubrtesting Oil Base Stocks and Lithium Complex Soap Thickener 94743-34-T or 94743*93*0 and 94741*99*4 and 94742*37*0 and Mixture Greater than 93S Proprietary additives Mixture Lees than 7% See Saction ( for Health and Hazard Information. Saa Saetlon H for additional Environmental Information. HAZARDOUS MATERIALS IDENTIFICATION SYSTEM (HMIS) Haalth FI tllty RaaotlYlty BASIS 1 1 o Racommandad by Exxon EXPOSURE LIMIT FOR TOTAL PRODUCT 3 mg/m3 for oil mtat in air BASIS OSHA Regulation 39 CFR 1910.1000 S.mg/aS for oil mlat Recommended by the American Conference of Governmental Induetrlal Hygtenlata (ACOIH) 3 mg/m3 for mlat In air Racommandad by Exxon PRIMARY ROUTES OF ENTRY AND EMERGENCY AND FIRST AID PROCEDURES YE CONTACT I f lubricant geta into the ayaa, flush with clear water for is minutes or until irritation subsides. If Irritation persists, call a physician. tit-eiTisnnmsi) pE 008550 RONEX up tn ease of akin contact, remove any contaminated clothing ano wain akin with loap and watar. If injected under tna akin, ragardlaaa of tha aooaaranea of tna wound or ite.slze, contact a pnyalclan IMMEDIATELY. Delay nay eauaa loaa of affactad part of tha body. INHALATION vapor praaaura la vary low. Vapor Inhalation undar ambient conditions la normally not a problem. If overcome by vapor from hot produet, 'mmedlately remove from exposure and call a physician, tf breathing la Irregular or has stopped, start resuscitation; administer oxygen. If available, tf overexposed to oil mist, remove from further exposure until axcasalva oil mist condition subsides. INOESTION If Ingested, 00 NOT Induce vomiting; call a physician Immediately. D. FIRE AND EXPLOSION HAZARD INFORMATION PLASH POINT (MINIMUM) 22rc (OO'F) astm D t2, Cleveland Open Cup AUTOIONITION TEMPERATURE Oreater than We (SOO'F) NATIONAL FIRE PROTECTION ASSOCIATION (NPPA) - HAZARD IDENTIFICATION Health Flsssaablllty Reactivity RASIS 1 1 0 Recommended by Exxon HANOLINO PRECAUTIONS Use proAtet with eautton around heat, sparks, pilot lights, static electricity, and open flame. LAMMA1LE OR EXPLOSIVE LIMITS (APPROXIMATE PERCENT BY VOLUME IN AIR) Estimated values; Lower Flammable Limit 0-tS Upper Flammable Limit 7% EXTINOUISHINO MEDIA AND FIRE FIOHTINQ PROCEDURES Foam, watar spray (fog), dry chemical, carbon dioxide and vaporizing liquid type extinguishing agents may all be suitable for extinguishing fires involving this type of product, depending on size or potential size of fire and circumstances related to the situation. Plan firs protection and response strategy through consultation with local fire protection authorities or appropriate specialists. The following procedures for this type of produet are based on the recommendations in tha National Firs Protection Association's "Fire Protection Outdo on Hazardous Materials*. Eighth Edition (1BS4): Use water spray, dry ehemleal, foam or carbon dioxide to extinguish the fire. Use water to keep fire-exposed containers cool. If a leak or spill has net ignited, use water spray to disperse the vapors and to provide protection for sien attempting to stop a leak, water sprsy may be used to flush spills away from exposures. Minimize breathing of gases, vapor, fumes or decomposition products. Use supplled-air breathing equipment for enclosed or confined spaces or as otherwise needed. DECOMPOSITION.PRODUCTS UNDER FIRE CONDITIONS Fumes, smoke, carbon monoxide, motel oxides, aldehydes and other decomposition products, tn the ease of Incomplete eomPuatlen. EMPTY* CONTAINER MARNINO Empty* containers retain resKAio (liquid and/or vapor) and can be dangerous. DO NOT PRESSURIZE, CUT, VELO. BRAZE, SOLDER. ORILL, ORINO OR EXPOSE SUCH CONTAINERS TO HEAT. FLAME, SPARKS, STATIC ELECTRICITY. OR OTHER SOURCES OF IQNITION; THEY MAY EXPLOOE AND CAUSE INJURY OR OEATH. Do not attempt to clean sines residue is difficult to remove. 'Empty* drums should be completely drained, properly bunged and promptly returned to a drum reconditioner. All other eontatnerg should be disposed of in an environmentally safe manner and in accordance with governmental regulations. For work on tanks refer to Occupational Safety and Health Administration regulations, ANSI Z4B.1, and other governmental and induatrlal references pertaining to cleaning, repairing, welding, or other contemplated operations. MI-omMwxMM PACE: 2 OATE ISSUED: 0S/01/B9 SUPERSEDES DATE; OS/tS/89 DE 008551 RONEX MR E HEALTH AND HAZARD INFORMATION variability among individuals Health atudte* have ahown that many petroleum hydrocarbon* and aynthetlc lubricant* poa* DOtantlal human haalth plaka which may vary from peraon to paraen. A* a pracaution. exposure to liqulda. vapor*, mitt* or fume* ahould M mlntmizad. EFFECTS OF OVEREXPOSURE (Sign* and ayaptoma of axpoaura) Prolonged or rapaatad akin contact may cauaa akin Irritation. High praasura graaaa gun injection Injury, whara graaaa la injected through tha akin or any part of tho body, can cauaa aartoua dalayad aoft tlaaua damaga and ahould ba traatad imwadlataly aa a aurgieal amargancy. NATURE OF HAZARD AND TOXICITY INFORMATION Prolonged or rapaatad akin contact with thl* product tanda to remove akin oil*, poaaibty leading to Irritation and daraatttte; however, baaed on human experience and available toxieetogieat data, thla product la judged to ba neither a `corroaive* nor an `irritant* by OSHA criteria. Product contacting tha ayaa nay eauaa aye irritation. Product haa a low order of acuta oral and dermal toxtelty, but minute amount* aaplrated into the lung* during ingaatlon or vomiting My cauaa mild to aavara pulmonary Injury and poaaibty death. Thl* product la judged to have an acuta oral L090 (rat) greater than 8 g/kg of body weight, and an acuta darul LOBO (rabbit) greater than 3.18 g/kg of body weight. PRE*EXXSTINQ MEDICAL CONDITIONS WHICH MAY SE AGGRAVATED tY EXPOSURE Nona Recognized F. PHYSICAL DATA Tha following data are approximate or typleal value* and ahould not be ueed for preelaa daalgn purpoaea. ROILING RANGE IBP Approximately 310*C (BtO`F) by ASTM 0 3SST VAPOR PRESSURE Lea* than O.OI mm Hg * 30*C SPECIFIC GRAVITY (1I.G C/lt.i C) 0.93 VAPOR DENSITY (AIR 1) Greater than 8 MOLECULAR WEIGHT Not determined PERCENT VOLATILE GY VOLUME Negligible from open container In 4 hour* e 31* C (100*F) pH Eaaanttally neutral POUR, CONGEALING OR MELTING POINT 3<0'C plua (S0D`F glue) Dropping Point by ASTM 0 33tR EVAPORATION RATE 1 ATM. AND SB C (77 E) (n-GUTYL ACETATE t) Laaa than 0.01 SOLUBILITY IN WATER 1 ATM. AND 38 C (77 F) Negligible: laaa than 0.18 VISCOSITY 383 worked penetration, am/10, e 38*C. ASTM D 317 G. REACTIVITY `ni* product la atabtV and will net react violently with watar. Hazardou* polymerization will not occur. Avoid contact with atrong oxidant* aueh aa liquid chlorine, concentrated oxygen, odium hypochlorite or calcium hypochlorite. Mt-OifTMwMMb PAGE: 3 DATE ISSUED: 0C/01/89 SUPERSEDES DATE: 03/It/89 DE 008552 ONEX HP 1 K ENVIRONMENTAL INFORMATION STEPS-TO ( TAKEN IN CASE MATERIAL IS RELEASED OR SPILLEO Recover free product. Add ear*'. earth. or other suitable absorbent to spill arts. Minimize skin contact. Ksap product out of sowars and watarcouraas by diking or impounding. Advlsa author It las If produet has antarad or nay antar BaworB. watarcouraas. or axtanslva land araas. Assura conformity with applleabla governmental regulations. THE FOLLOWING INFORMATION MAT RE USEFUL IN COMPLYING WITH VARIOUS STATE AND FEDERAL LAWS AND REGULATIONS UNDER VARIOUS ENVIRONMENTAL STATUTES: REPORTABLE QUANTITY (RQ). EPA REGULATION 40 CFR 302 (CERCLA Section 102) No RQ for product or any constituent greater than 1% or 0.IX (carcinogen). THRESHOLD PLANNING QUANTITY (TPQ), EPA REGULATION 40 CFR 3SB (SARA Sections 301-304) No TPO for product or any constituent greater than IX or 0.1X (carcinogen). TOXIC CHEMICAL RELEASE REPORTING, EPA REGULATION 40 CFR 372 (SARA Section 313) No toxic chemical is present greater than t% or 0.IX (carcinogen). HAZAROOUS CHEMICAL REPORTING. EPA REGULATION 40 CFR 370 (SARA Sections 311-312) Acute Chrente Fire Pressure Reactive EPA HAZARD CLASSIFICATION COOS: Hazard Hazard Hazard Hazard Hazard Not Applicable XXX L PROTECTION AND PRECAUTIONS VENTILATION Use local exhaust to capture vapor, mists or fumes. If neeeasary. Provide ventilation sufficient te prevent exceeding recommended exposure limit or buildup of explosive concentrations of vapor In sir. No smoking, flame or other ignition sources. RESPIRATORY PROTECTION Use aucpiled-alr respiratory protection in confined or enclosed spaces, if needed. PROTECTIVE GLOVES Use chemical-resistant gloves. If needed, to avoid prolonged or repeated skin contact. EYE PROTECTION Use splash goggles or face shield when eye contact may occur. OTHER PROTECTIVE EQUIPMENT Use chemical-resistant apron or other Impervious clothing, If needed, to avoid eontamlnattrig regular clothing, whleh could result in prolonged or repeated akin contact. WORK PRACTICES / ENGINEERING CONTROLS keep containers elosed when not In use. Do not store near heat, sparks, flame or strong oxidants. In order to prevent flra or explosion hazards, use appropriate equipment. Information on eleetrleal equipment appropriate for use with this product may be found in the latest edition of the National Electrical Code (NFPA-70). This document Is available from the National Fire Protection Association. Batterymarch Park, Quincy. Massachusetts 022C9. PERSONAL HVQIENE Minimize breathing vapor, mist or fumes.. Avoid prolonged or repeated contact with skin. Remove contaminated clothing; launder or dry-clean before re-use. Remove contaminated shoes and thoroughly clean before re-usei discard if oil-soaked. Cleanse skin thoroughly after contact, before breaks and meals, and at end of work period. Product is readily raanvad from kin by waterless hand cleanera followed by waehing thoroughly with soap and water. 1 M>-emMWMOoii ' "' PAGE: 4 OATt ISSUEO: 04/01/69 SUPERSEDES DATE: 05/19/19 DE 008553 RONEX MP J. TRANSPORTATION AND OSHA RELATED LABEL INFORMATION TRANSPORTATION INCIDENT INFORMATION For further orr*tton relative to spills resulting from transportation Incidents. r*fr to latest Department of Transportation Emergency Response Outdeboo* for Hazardous Materials Incidents. DOT R 9RO0.3. DOT IDENTIFICATION NUMBER Not apel(cable OSHA REOUIREO LABEL INFORMATION In compliance with hazard and rtght-to-know reaulrements. the following OSHA Hazard Warnings should be found on a label, bill of lading or Invoice accompanying this shipment. (OSHA Hazard Warnings not applicable for this produet; therefore, no OSHA warnings would appear on the label.) Note; Produet label will contain additional non-OSHA related information. The Information and recommendation* contained herein ate, to the beat of Exxon's knowledge and belief, accurate and reliable as of the data issued. Exxon does not warrant or guarantee their accuracy or reliability, and Exxon shall not be liable for any loss or damage arising out of .ha use thereof. The information and recommendations are offered for the user's consideration snd examination, and It Is the user's responsibility to satisfy Itself that they are suitable and complete for Its particular use. If buyer repackages this product, legal council should be consulted to Insure proper health, safety and other necessary t rtfenaction Is Included on the container. The Environmental Information Included under Section H hereof as well as the Hazardous Mstarials Identification System (HMIS) snd National Fire Protection Association (NFPA) ratings have been included by Exxon Company, u.S.A. In order to provide additional health and hazard classification Information. The ratings recoamsndad are based upon the criteria supplied by the developers of these rating systaam, together with Exxon's Interpretation of the available data. FOR ADDITIONAL INFORMATION ON HEALTH EFFECTS CONTACT: OIRECTOR OF INDUSTRIAL HVOIENE EXXON COMFANY, U.S.A. P. 0. BOX 31*0 ROOM 3IBT HOUSTON. TX 7T2B2-21SO (713) (8**2443 FOR OTHER FRODUCT INFORMATION CONTACT; MANAGER, MARKETINO TECteilCAL SERVICES EXXON COMPANY, U.S.A. P. 0. BOX 21*0 ROOM 23SS HOUSTON. TX 77393-21*0 (713) BSB-8B4* MI.OITTAfWHMIl PAOE: 9 DATE ISSUED; OS/OI/89 SUPERSEDES DATE; 05/I9/B9 DE 008554 UNIREX N 2 EJfcONCOMPANY USA A OfrTtiO" O' tXXOX CQXfOfUtlOX OATE ISSUEO- 06/01/89 SUPERSEDES OATE: 05/19/89 MATERIAL SAFETY DATA SHEET EXXON COMPANY. U.S.A. P.0. BOX 2180 HOUSTON. TX 77282-2180 A IDENTIFICATION AND EMERGENCY INFORMATION PRODUCT NAME UNIREX N 3 CHEMICAL NAME Petroleum Lubricating Oreaaa PRODUCT APPEARANCE ANO 000R Smooth dark green graaa* Ml id. eland odor MEDICAL EMERGENCY TELEPHONE NUMBER (713) (Se-3434 PRODUCT CODE 418172 - 08172 CAS NUMBER Complex Mixture CAS Number not applicable B. COMPONENTS AND HAZARD INFORMATION COMPONENT! CAS NO. OP COMPONENTS APPROXIMATE CONCENTRATION Lubricating OM Baaa Stock* and Lithium Complax Soap Thickener 4742-84*7 or 4742*88*0 and Mlxtur* Greater than 97X sropnatary additive* Mlxtur* Laaa than 3% Saa Saetlon E for Haalth and Haxard Information. Saa Section H for additional Environmental Information. HAZARDOUS MATERIALS tDENTtPXCATION SYSTEM (HNIS) Haalth PI blllty Reactivity AS1S I 1 0 Recommended by Exxon EXPOSURE LXMXT POR TOTAL PRODUCT 5 mg/m3 for oil ml at In air BASIS OSHA Regulation 2B CFR 1810.1000 8 mg/m3 for oil mlat Recommended by the American Conference of Governmental InAiatrial Hyglentata (ACOIH) 5 mg/m3 for mat In air Recommended by Exxon PRIMARY ROUTES OF ENTRY AND EMERGENCY AND FIRST AID PROCEDURES EYE CONTACT If lubricant gata Into the eye*, fluah with.clear water for tS minute* or until irritation aubalde*. If Irritation peralata, call a phyalclan. KIN 1 In eaae of akin contact, remove any eontamlnatad clothing and waah akin ith aoap and water. If injected under the akin, regardlea* of the appearance of the wound or Ita alt*, contact a phyalclan IMMEDIATELY. Delay may eauae loaa of affected part of the body. Ki-omNwNoen DE 008555 UNIREX N 3 inhalation vapor pressure <i vary low. Vapor Inhalation under ambient condition* la normally not a proplam. If ovarcom* py vapor from hot product, immadlataly ramova from exposure and call a phyaielan. If breathing I* Irregular or ha* atoppad. atart raauscltat ion: administer oxygen, If avallapla. If overexposed to oil ntst. remove from further exposure until excessive oil nlwt condition suBaioe*. INGESTION If Ingested. DO NOT Induce vomiting; call a physician Immediately. D. FIRE AND EXPLOSION HAZARD INFORMATION FLASH POINT (MINIMUM) 246'c (4TS` F) ASTM 0 f3. Cleveland Open Cup AUTOIONITION TEMPERATURE Greater than 20`C (SOO'F) NATIONAL FIRE PROTECTION ASSOCIATION (NFPA) HAZARD IDENTIFICATION Health Flansabl1Ity Reactivity RAStS 1 I 0 Recommended by Exxon HANOLINQ PRECAUTIONS Use product with caution around heat, spark*, pilot lights, static electricity, and open flame. FLAMMARLE OR EXPLOSIVE LIMITS (APPROXIMATE PERCENT RV VOLUME IN AIR) Estimated values: Lower Flammable Limit O.RX Upper Flammable Limit 7% EXTINGUISHING MEDIA AND FIRE FIGHTING PROCEDURES foam, water spray (fog), dry ehamteal. carbon dioxide and vaporising liquid type extingutsning agents may alt be suitable for extinguishing fires involving this type of product, depending on size or potential size of fire and circumstances related to the situation. Plan fire protection and response strategy through consultation with local fire protection authorities or appropriate specialists. The following procedures for this type of product are baaed on the recommendations in the National Fire Protection Aasoclatton's 'fire Protection Guide on Hazardous Materials*. Eighth Edition (1SS4): Use water spray, dry chemical, foam or carbon dioxide to extinguish the firs. Use water to keep fire-exposed containers cool. If a leak or apt It has not ignited, use water spray to disperse the vapors and to provlds protection for men attempting to stop a leak. Water spray may be used to flush spills away from axposuraa. Minimize breathing of gases, vapor, fumes or decomposition products. Use aupptled-alr breathing aqulpment for anclosad or confined spaces or as otherwise needed. DECOMPOSITION PRODUCTS UNDER FIRE CONDITIONS fumes, smoke, carbon monoxide, metal oxldaa, aldehydes and other decomposition products, in the ease of Incomplete combustion. "EMPTY* CONTAINER WARNING "Empty* container* retain raaldua (liquid and/or vapor) and can be dangerous. 00 NOT PRESSURIZE. CUT. WELD, GRAZE, SOLDER. ORILL. GRIND OR EXPOSE SUCH CONTAINERS TO HEAT. FLAME. SPARKS. STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION; THEY MAY EXPLODE AND CAUSE INJURY OR DEATH. Do not attempt to clean since residue la difficult to remove. `Empty* drums should be completely drained, properly bunged and promptly returned to a drum raconditloner. All other container* should be disposed of in an environmental1y safe manner and In accordance with governmental regulation*. For work on tanks refer to Occupational Safety and Haalth Administration regulations, ANSI Z4R.I. and other governmental and industrial references pertaining to cleaning, repairing, welding, or other contemplated operations. ----------------------------------- 1-------------------------------------------------------------------------------------------------------------------------------------- m-ctftMWHMtl PAGE: 3 DATE ISSUED: 06/01/89 SUPERSEDES OATE: 05/19/89 DE 008556 UNIREX N 2 E HEALTH AND HAZARD INFORMATION VARIABILITY AMONG INDIVIDUALS 'Health atudlee have ihevn that many petroleum hydrocsreon* and ayntnatle lubricant* oeaa potential human naalth niki which may vary from carton to par ton. a* a pracaution. expoaure to Itauld*, vapor*, mat* or fumaa snould b* minimized EFFECTS OF OVEREXPOSURE (Sign* and aymptoms of exposure) Prolonged or rapaatad akin contact may cauaa akin Irritation. High praasura graaaa gun tnjaetlon Injury, where graaaa la injactad through tha akin or any part of th* body, can eauaa aarloua dalayad aoft tiaaua damaga and ahould ba traatad immadlataly a* a aurgtea! anarganey. NATURE OF HAZARD AND TOXICITY INFORMATION Prolongad or rapaatad akin contact with thit product tand* to ramova akin oil*, potaibly laadlng to Irritation and darmatltia; however, baaad on human experience and availabl# toxicological data, thla product I* judged to ba nalthar a 'corrosive* nor an 'irritant* by OSHA criteria. Product contacting tha ayaa may cauaa aya irritation. Produet haa a low ordar of acuta oral and darmal toxicity, but minute amount* aapiratad into tha lung* Airing ingaation or vomiting may eauaa mild to aevere pulmonary injury and poaaibiy death. Thla product la Judged to have an acuta oral LDSO (rat) greater than S g/kg of body weight, and an acuta dermal LDSO (rabbit) greater than 3.It g/kg of body weight. PRE-EXISTIMO MEDICAL CONDITIONS WHICH MAY BE AOSRAVATED BY EXPOSURE Nona Recognized F. PHYSICAL DATA The following data erg approximate or typical valuta and should not ba used for proeiao design purposes. BOILING RANOE IBP Approximately 3SS`C (T30`F) by ASTM D 2SBT VAPOR PRESSURE Less than 0.01 mm Hg a 20'C SPECIFIC GRAVITY (1B.B C/IB.B C) 0.93 VAPOR DENSITY (AIR 1) Greater than S MOLECULAR WEIGHT Not determined PERCENT VOLATILE BY VOLUME Negligible from open container In 4 hour* a 39'C (100'F) PH Essentially neutral EVAPORATION RATE P 1 ATM. AND 2B C (77 F) (h-BUTVL ACETATE 1) Lass than 0.01 POUR, CONGEALING OR MELTING POINT 304'c plua (SSO'F plua) Dropping Point by ASTM D 2399 SOLUBILITY IN WATER a 1 ATM. AND 2B C (77 F) Negligible; lea* than 0.IS VISCOSITY 280 worked penetration. om/tO, a 29*C. ASTM D 217 G REACTIVITY i Thla product IS stable and will net react violently with water. Hazardous polymerization will not oeeur. Avoid contact with strong oxidants sueh as liquid chlorine, concentrated oxygen, sodium hypoenlertta or cateiuo hypochlorite. m*omww>oo& PAGE: 3 DATE ISSUEO: 0S/O1/B9 SUPERSEDES-OATE: 05/19/89 X)E008557 UNtBEX N 3 K ENVIRONMENTAL INFORMATION STEPS TO at TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Recover free produet. Add tend, aartn. or other aultable abeorbent to aolll area. Uinmtia ' akin contact. Kaap produet out of eewere and watereouraee by diking or impounding. Advise authorities tf product naa antarad or may antar aawara. watareouraaa. or extensive land araaa. Aaaura conformity with appticabla governmental regulations. THE FOLLOWING INFORMATION MAT RE USEFUL IN COMPLYINO WITH VARIOUS STATE AND FEDERAL LAWS AND REOULATIONS UNDER VARIOUS ENVIRONMENTAL STATUTES: REPORTABLE QUANTITY (RQ), EPA REOULAYION 40 CFR 303 (CERCLA Saetlon 103) lha RO for xlnc eompounda la 1 pound. Thla product eontalna approximately 1.5X tine eompounoa THRESHOLD PLANNINO QUANTITY (TPQ), EPA REQULATION 40 CFR 3SS (SARA Sacttena 301-304) No TPO for produot or any eonatltuant greater than IX or O.IX (carclnogan). TOXIC CHEMICAL RELEASE REPORTINQ, EPA REQULATION 40 CFR 373 (SARA Section 313) Thla preajet eontalna approwlmataly 1.BX zinc eompounda. HAZARDOUS CHEMICAL REPORTINQ, EPA REQULATION 40 CFR 370 (SARA Seetlone 311-313) Acute Chronic Fire Preeaure Reaetlve EPA HAZARD CLASSIFICATION COOE: Hazard Hazard Hazard Hazard Hazard Not Applicable XXX I. PROTECTION AND PRECAUTIONS VENTILATION Uae local exhauat to eapture vapor, mata or fumaa. tf naeaaaary. Provide ventilation aufflelant to prevent exceeding recommended ewpoaure limit or buildup of axploalve eoncantratIona of vapor In air. No amoktng, flame or other ignition aoureaa. RESPIRATORY PROTECTION Uaa auppllad-air reaptratory protection In conftned or encloaad apacea, if needed. PROTECTIVE CLOVES Uaa chemtcal-ree.latant glovaa, tf needed, to avoid prolonged or repeated akin contact. EYE PROTECTION Uae aptaeh gegglea or faee ehtald whan eye contact may occur. OTHER PROTECTIVE EQUIPMENT Uae chemteel-reeiatant apron or other Impervtoua clothing. If needed, to avoid contaminating roller etothlng, which could raeult In prolonged or repeated akin contact. WORK PRACTICES / ENQINEERINQ CONTROLS Keep containert cloaed when not in uae. Do not etore near heat, aparke, flame or atrong oxidanta. In order to prevent fire or exploelon hazarde, uae appropriate equipment. Information on electrical equipment appropriate for uae with thla product nay ba found in the lateat edition of the National Eleetrleal Code (NFPA-70). Thla document la available from the National Fire, Protection Association, ietterynarch Park, Quincy, Maaeaehuaetta 03343. PERSONAL HYQIENE Minimize breathing vapor, mlet or fumea. Avoid prolonged or repeated contact with akin. Remove contaminated Clothing: launder or dry-clean before re-uae. Remove contaminated ehoaa and thoroughly etaan before re-uae; dlecard if oti-eoeked. Cleanae akin thoroughly after contact, before breake and meale, and at end of work period. Product la readily removed from akin by waterlaaa hand eleanare followed by waahfng thoroughly with aoap and water. to-ampnmeeb PAGE: 4 DATE ISSUEO: 04/01/89 SUPERSEDES DATE: 05/19/89 DE 008558 UNIBEX N 3 J. TRANSPORTATION AND OSHA RELATED LABEL INFORMATION transportation incident information For further information relative to spills resulting From transoortatton incidents. r*f*r -to lataat Department OF Tranaportatton Emergency Baaponaa Guidebook For Haxarooua Materials Inctdants. DOT R SSOO.3. DOT IDENTIFICATION NUMBER Not appt teable OSHA REQUIRED LABEL INFORMATION In compIlane* with hazard and rtght-to-know raautremante. tha Following OSH* Hazard Warning* anould ba Found on a labal. bin oF lading or invoiea accompanying tnia ahtpnant. (OSHA Hazard Warning* not applicable For tnia product: tnaraFora. no OSHA warning* would appaar on tha label.) Not*-. Product label will contain additional non-oSHA related inFormatlon. The InFormatlon and recoamendatIone contained herein arc, to the beat oF Exxon'a knowledge and beileF, accurate and reliable as of the date issued. Exxon does net warrant or guarantee their accuracy or reliability, and Exxon shall not be liable For any less or daamge arising out of the use thereof. The Infonaatlen and reeomaendatlens are offered for the user's consideration and examination, and It Is the user's responsibility to satisfy Itself that they are suitable and couplets For its particular use. If buyer repackages this product, legal council should be consulted to Insure proper health, safety and other necessary Infonaatlen Is Included on the container. The Environmental Infonaatlen Included under Section H hereof as well as the Hazardous Materials Identification System <t*(!S) and National Fire Protection Association (NFPA) ratings have been Included by Exxon Coapany, U.S.A. In order to provide additional health and hazard classification information. The ratings recoaawended are based upon the criteria supplied by the developers of these rating systems, together with Exxon's Interpretation of the available data. FOR ADDITIONAL INFORMATION ON HEALTH EFFECTS CONTACT: DIRECTOR OF INDUSTRIAL HYQIENl EXXON COMPANY, U.S.A. P. 0. BOX 3 ISO ROOM 31ST HOUSTON. TX T73B3-31BO (713) (SB-3443 FOR OTHER PRODUCT INFORMATION CONTACT: manager, marketing technical EXXON COMPANY. U.S.A. P. 0. BOX 31B0 ROOM 33SS HOUSTON, TX 77393-31B0 (713) (9S-SS4S services ttt-eiihfmeea PAGE: B OATE ISSUED: 0S/01/8? SUPERSEDES DATE: 05/19/89 pE 008559 JfiH 31 '92 12:52PM 77 UELDING-f.-IfltOST.SLPFLT- Oxygen Material Safety Data Sheet Industrial Get Division Air Products and Chemicals, Inc Allentown. PA 18195 T| (216)481-4911 TWX 510 651 3586 Telecopy (2'51 481-5900 CA-PUE-AIRPROO TELEX 547416 AIR _/. PRODUCTS IT. iMixatNcr moNi- 800-523-9374 m rfxumvtviA: 800--322-9092 muc oiti Issued: 13 April 1977 mot MAUt 1MO S1HONTMS Oxygen, LOX (Liquid only), MtviciiiNi Rev: 18 November 1987 GOX (Gee only) FOMMUU O, MW: 32.00 CHIWICAL NAU| ANO STNONTM) Oxygen CrtlMlCAl VAMllf Oxidizing gas CAS*7702-44-7 HEALTH HAZARD DATA 1rxniJwOLB UMI VAlVt N/A. Oxygen la not Hated as a carcinogen by NTP, IARC, or OSHA. s ru.rous ir iMciarto. cowtAcreo with pun. o* vasoa mhauo Oxygen Is nontoxic under most conditions of use and Is nacassary to support Die. Liquid oxygen o> cold gas win freeze tissues and can cause severe cryogenic (extremely low temperature) burns. ro*icoieoiCAi aeonmisa -- Oxygen la nontoxic under usual conditions of use- Breathing pure oxygen at one atmosphere, however, may produce cough and chest pains within 8-24 hours. Concentrations of 60% may produce thaae symptoms In aavaral days. At two atmoepheies symptoms occur In 2-3 hours. Partial pressure of oxygen In excess ol two atmospheres may produce a variety of central nervous system mcnifeste'ions including tingling of fingers and toes, visual and hearing disturbances, abnormal sensations, Impaired coo'dtnatlon, contu sion, muscle twitching, and seizures resembling those of epilepsy. Savers hezards may be present whan confusion and im paired judgment lead to operational errors. Infants exposed to oxygen levels In excess of 35-40% may suffer permanent visual Impairment or blindness due to retrolental fibroplaela. "icouutNotD neat aio murmur r If cryogen.c liquid or cold boll-off gas contacts a worker's skin or eyes, frozen ttaaues should be flooded o' soaked with tepid water (105-118?; 41-46C). DO NOT USE HOT WATER. Burns which result In blistering or deeper tissue freezing should be seen promptly by a physician. plash poiht NfA **4 FIRE ANO EXPLOSION HAZARD DATA Al/ro WHITEN T|MP tiAbtUAiil tiutri N/A N/A III Ull N/A N/A IXTIVOUISMIHO HtOUA N/A tllClWCAl CLAW'XICATKM CMU# HIA 'scscm rim rraHTwo nuctUUMtt Oxygen Is nonflammable, but supports and VIGOROUSLY ACCELERATES COMBUSTION of flemmablea. To fight fires, shut off aourcae of oxygen and fight tike conventional fire. UMU3UAI liM ANO IXH.OWON HAZAAOi ' '` Oxygen le nonflammable, but supports end VIGOROUSLY ACCELERATES COMBUSTION ol flammebles. Some materiel* which are noneombustlble In air will bum In the presence of oxygen. > BOIUNO POINT ) 9 1 atm - 297.3F {- 183.0C) PHYSICAL DATA MUZING POINT\f\ 9 1 ttrn -361.6F (-216.6Q vapor rriuunc mm N/A SOlUWLITY IN WATt* 9 77F (250.1 itm 3.16% by volume VAPOR OSMSlTT |Wtl/ SPtClPtC ORAVITY (At* f) 0 WF (20C), 1 atm 0.06309 9 66F (20Q, 1 atm 1.T0 UOUIO OINtiTY PVtv tt| m;ihc qravitv (m,o ii 9 bolting point, 1 atm 71.21 9 boiling point, i atm i u APP(AIUNC| ANO OOQ* Gtseous oxygan Is cotorlass and odortass. Liquid oxygan It pals blus and odoflat*. pE 008560 JCN 31 '92 12:53PM 77 UELDXN^-*--INC'l-rST REACTIVITY DATA S'Ailll** All UN3fAU KrtTtowhtehburn in air will bum violently In atmosphere tutu . approx. 25*/ oxygan. Soma materials will burn In pur* oxygan which ar* nottfUmmtbia tn *lr. AQftfUmWWt in ___ ipflciitiy ptUAiaum pfflflujtl, Japnan, oln4f yoiIuj* HfmmibVi? HAUQOQUS QtCOUPOtlTlOH WOOUCTI Non# H*1AaUTRMOeO^UljASTtOM MAYOceva VYTU MOTOCCU* CONDITIONS TO AVOID X Non* SPILL OR LEAK PROCEDURES -Jttrs to (I TAKEN IN C`ll UAtCMAL IS MlCAMO OH SPaltO Prtvent liquid oxygen from contacting grsase, oil, aaphalt or combustibles. V*ntllt* *r*a to evaporate and disperse oxygen. Flush area with large quantltlea ol water. DO NOT ENTER area* of high oxygen concentration, which can saturate clothing and increase Its flammability. Avoid smoking end contact with sources of ignition after exposure to concentration of oxygen higher than the normal atmosphere. wAjre oisrosAi methoo Allow liquid oxygen to evaporate In a well ventilated outdoor area. Vent oxygen gas to outeid* location. Disposal site should be remote from work areas, open (lame* or aourcaa of Ignition and combustible*. Flushing with water will Increase th* vaporizelion rata of th* liquid. Do not attempt to dispose of residual oxygen In compressed gas cylinders. Return cylinders to Air Products with residual pressure, the cylinder valve tightly closed and valve cap in place. NEsriAAioaT aotecitn n*Mitr >rtm N/A SPECIAL. PROTECTION INFORMATION VfcVflLAtfON LOCAL UHAUtT Pr* nat * Accumulation with or forced air. UICMAHICAL tOmrmUJ %nctMi OTHES Vents snouid be situated to avoid higher than normal concentration ol oxygen In work areas. OOllClivt GLOVES (Liquid) Loose-fitting gloves of Impermsabls malarial, such as leather. (Gas) Leather work gloves are recommended when handling compressed gas cylinders. lt PAOTECtlOM _(L_iqu_id_) _C_he_m_ic_al_go_g_glaa. or safety glasses. (Gas) Safa'ty glaasaa art recommended when handling high-pressure cylinde--rs. - N/A SPECIAL PRECAUTIONS* jVEf:>n lAAtlWO INFOftUAhON -- --_____ Oxygen shipment must be In sccordenes with Department of Transportation (DOT) ragulatione using DOT "OXIDIZER" label. Consult DOT regulations for details on the shipment of hazardous materials. "pf'jiu MANOUHG atCOMINDATIO*iS . Prevent contact of liquid oxygan with txpossd skin. Prsvant entrapment ol liquid in closed systems. Use only In well ven tilated areas. Cleanliness and compatibility of matarlala In contact with oxygan are essential especially Internal parts of pip ing systems. Some elastomers (o-nngi, valve state, ate.) art not compatible with oxygan. Open oxygen valves slowly. Com pressed gas cylinders contain oxygen at extremely nigh pressure end should be handled with care. Use a pressure-reducing regulator when eonneotlng to lower pressure piping eyttems. Secure cylinders whan In use. Never use direct llama to heat a compressed gat cylinder. Use a check valve to prevent back (low Into aloraga container*. Avoid dragging, rolling, or adding cylinders, even for a short distance. Us* a aultatta hand truck. For additional handling recommendations on compressed gas cylinders, consult Compressed Gas Association Pamphlet P-1. S'Ewal sroeAoe mcommemoatkin* ~-- ' Store liquid containers and cylinders In wall ventilated areas. Do not store cylinder* of oxygen within 20 ft. of flammable or combustible matarlala, especially oil or grease. Keep cylinders swsy from source of heat. Storage should not b# In heavy traffic areas to prevent accidental knocking over or damage from passing or falling objects. Valve caps should remain on cylinder* not connected lot use. Never lubricate valves or cylinder cap*. Segregate lull and amply cylinder*. Slotage areas should b* fra# of combuattble material. Avoid exposure to areas where tall or other corrosive chemicals are present. Sea ; Compressed Ges Association Pamphlet P-1 tor additional storage recommendations. j S'fC'Al AACKAOMO DICOMUENDATIONS l -------------------- _____ Gas*- ' oxygan containers meat DOT specifications or American Society of Mechanical Enoinaere (ASME) codes. Liquid oxyg S stored In vaeuum-lniulated containers masting DOT specification! or ASME codas. jrK AieouutxeAtiotii o mcAvmoNi ' Oxygen la not to bs usad at a substitute for compressed air. Applications such at cleaning, dusting, powering pneumatic tools, etc., are not aafe due to lubricating oils and other materials present. Use only with equipment specifically dsslgnsd 3nd cleaned for oxygen service. Consult Compressed Gat Association Pamphlet G-4.1, "Cleaning Equipment for Oxygan Serv es, lor details. Liquid oxygan la cryogenic liquid. Materials ol construction must b# selected lor compatibility with extrema- y low temperature*. Avoid us* of carbon steel end other materials which become brittle at low temperatures. Compressed y 8i,ogl" P* except by qualified producers of comprss**d gatts. Shipment of a comprassad gtt cylinder ! Hied without the permission of the owner Is a violation of Federal Law. ifoxygen concentration! exceeding 25V are suspected )r can occur, uaa oxygan monitoring equipment to teat for oxygan-enrlchad aimoapharaa. DE 008561 JON 31 '92 01S0SPM 77 IJELDING-S.-INDUST. 3UPPLY- X'Si/tl 12194 2 3l239*M5 TT VIILD1N9 P.ti MCI 19630 MATERIAL SAfETY DATA SHEET PACE 01 or 07 HC INDUSTRIES P.O. BOX 9*5 2*60 BOULEVARD Or THE GENERALS VALLEY FORCE, PENNSYLVANIA 1*4112 EMERGENCY CONTACT: CHENTREC l-SOO-424-9300 SUBSTANCE IDXNTXrXCATION SUBSTANCE! PR0PYL8NR CAS-NUMBER 115-07-) TRADE NAMIS/SYNONYMSi FROPENE; methyleiHint; methylethylene; i-propylcnc; i-rRortNt; us io77; C3H6; MCI 19830 CHEMICAL FAMILY: hydrocarbon, aliphatic MOLECULAR rORMIH.A: C-K3-C II C lX HOI.RCUI.ar WEIGHT: 42,06 CERCLA RATINCS (SCALE 03): HEALIH-I FIRE-3 REACTIVlTr-0 FERS1STENCE-0 NFFA RATINCS (SCALE 0"4)j HEALTH-1 flRE-A ntACTlVITY-I COMPONENTS AND CUN1A7UNAN19 COMPONENT 1 PROPYI.P.NP. CAS# 115-07-1 PERCENT 100 OTHER CONTAMINANT!! NOME niPORHAP I.TH1T.1: NO OCCUPATIONAL EXPOSURE LIMITS ESTABLISHED BY OSllA, ACOTH, OR NIOSH. PROPYLENE! SUBJECT TO SARA SECTION 313 ANNUAL TONIC CHEMICAL RELEASE REPORTING 1 PHYSICAL DATA DESCRIPTION! COLORLESS OAS. duilinu pointi -3j r ( -W c> MELTINC POINT! -301 v (-183 c) SPECIFIC gravity, 1.7855 G/L VAPOR PRESSURE! 7828 MMKG 8 21.1 C SOLUBILITY IN WATER; ASX VAPOR DENSITY! (AIR-1) 1.5 DE 008562 JAN 31 '92 01:09PM 77 ICLDING-S-IK'JST. HUF<=L . - 1 ''3 I ' 9 l 1 21 S7 * 3123996843 ?? WEL01HG pt o MG119ft30 FACE 02 OF 07 nnr. and'explosion data rir. and explosion iiaxardi. DANGEROUS tire hazard when exposed to heat or flams. VArOR-AIH MIAIUREI AXE EXPLOSIVE ABOVE FLASK POINT. VAPORS ARB HEAVIER THAN AIR,ANi) MAT IKAVLL A CONSIDERABLE DISTANCE TO A SOURCE Of IGNITION AND FUSI| PACK. DUE TO LOW bLWnROCONWlCTIVITT OF THE SUBSTANCE, FLOW OR AGITATION MAY GENERATE ELECIkOSTAT1C CHARGES RESULT IMG IN SPARKS WITH POSSIBLE IGNITION. flash point: -10* f (. JOO c) urritn cxplocivr hmjti ii.it LOWER EXPLOSIVE LIMIT! 2.0* aUIOIGNITION ICMP.: 051 P (855 C) i 1REPJCHTINC MEOJAi DRY CHEMICAL OR CARBON DIOXIDE (lyyU EMERGENCY RESPONSE GUIDEBOOK, DOT F 5000.5). ION LARGER FIRM, USE WATER SPRAY OR POG (1990 EMERGENCY RESPONSE GUIDEBOOK, DOT P 3800.5). FIREFIGHTING! HOVE CONTAINER FROM FIRE AREA IP YOU CAN DO IT WITHOUT RISK. APPLY COOLING WATER 70 SIDES OP CONTAINERS THAT ARE EXPOSED TO FLAMES UN1IL WELL APIKH FIRE JS OUT. SCAT AWAY FROM ENDS OF TANKS. FOR MASS1VF. FIRC IN CAflCO AREA, USE UNMANNED HOLDER OR MONITOR NOZZLESI IF THIS IS IMPOSSIBLE, WITHDRAW FROM AREA AND LET' PIRE BURN. WITHDRAW IMMEDIATELY IN CASE OP RISING SOUND FROM VENTING SAFETY DEVICE OR ANT DISCOLORATION OT TANK DUE TO FIRC. LET TANK, TANK CAR OR TANK TRUCK BURN UNl.r.SS LEAK cam BE STOPPED; with smaller tanks or cylinders, EXTINGUISH/ISOLATE FROM OlHER FLAMMABLES. ISOLATE TOR 1/2 MILE IN ALL DIRECTIONS IF. TANK, rail Cak OR tank truck is involved in tire 0990 chcrccncy RESPONSE GUIDEBOOK, DOT 1* S800.3, 0U1DE PACE 22). fcXlINGUlSH ONLY IT FLOW CAN BE STUFFED; USt WATER IN ri.OODJNG AMOUNTS AS FOC. COOL CONTAINERS WITH FLOODING AMOUNTS 0T WATER, APPLY FROM AS FAR A DISTANCE AS POSSIBLE, AVOID BREATHING TOXtC VAPORS, KEEP UPWIND. EVACUATE TO A RADIUS 01' 2300 FEET FOR UNCONTROLLABLE PIKES. CONSIDER EVACUAUON OP DOWNWIND ARF.a IF MATERIAL IS LOANING, 1 10P FLOW OF CAS (NKVA 323k, KIKtc HAZARD PROPMT!f.A f)K FLAMMABLE LIQUIDS. gasps, and volatile solids. 1910. TRANSPORTATION Mata DEPARTMENT OF TRANSPORTATION HAZARD CLASSIFICATION 49 CFR 172.J01I FLAMMABLE Ca6 DE 008563 JfiN 31 '92 01:09PM 77 WELDIN5_5_ 11111.!= T.3uFPLr- 19'31'91 21 5 7 S 311399694; 77 'JtLSIMJ F.o: EXCEPTIONS: *9 C7R J 7.1.306 MG119830 PACE 03 Of 07 TOXICITY PROPYLENE! CARCINOGEN STATUS: NONE (1ARC GROUP 3), ACUTE TOAICTY LEVEL: NO data avaILaELE. TARGET EFFECTS: CENTRAL NERVOUS SYSTEM DEPRESSANT; SIMPLE ASPHXIANT. ADDITIONAL DATA; STIMULANTS SUCH AS EPINEPHRINE MAY INDUCE VENTRICULAR FIBRILLATION. 1ir.Ai.TH EFFECTS AND FIRST AID INHALATION: PROPYLENE NARCOTIC. SEE INFORMATION on sinrLt asphyxiants, high concentrations hay cause mild MUCOUS MEMBRANE IRRITATION AND ANESTHESIA. HUMANS EXPOSED TO 6.L'.. FOR 2 MINUTES EXPERIENCED MILD INTOXICATION, PARESTHESIAS AND INABILITY TO CONCENTRATE. AT UNCONSCIOUSNESS OCCURRED IN 3 MINUTES. 35-40". RESULTED IN VOMITING AND VERTIGO. AU^SX FOR A FEW MINUTES CAUSED INITIAL REDDEN) NC OF inti EYELIDS, FACIAL riUSHlNU, LACK)MAT ION, COUCHING AND TLEXINC OF THE LEGS. NO VARIATION In KtSFIKAIORY OR PULSE RAIES OR EI.ECTROCaRDIOCaRaM3 wdRC NOTED. HOWEVER, STUDIES W11M DOGS HAVE RESULTED IN CARDIAC ARRYTHMIAS. REPEATED OK PROLONGED EXPOSURE KaS BEEN REPORTED TO CAUSE PA)N AND PARESTHESIAS OF IMF PINCERS AND POLYNEURITIS. RATS EXf-BED TO 5QOU"10,000 PPM FOR 103 WEEK) EXHIBITED SQUAMOUS METAPLASIA AND EPITHELIAL HYPERPLASIA OF THE NASAL CAVITY. EXPOSURE OP MICE TO MINIMAL NARCOTIC CONCENTRATION* CAUSED MODERATE 10 VERY 5>IC.NT PATTY DEGENERATION OP THE LIVER, SIMPLE ASPHYXIANTS: ACUTE EXPOSURE- THE SYMPTOMS UF ASPHYXIA DF.PF.NO ON THE RAPIDITY WITH WHICH THE Oxygen deficiency develops and how long it continues, in sudden acute ASPHYXIA, UNCONSCIOUSNESS MAY Dt IMMEDIATE. w:th $I.DW DP.VP.l OPMF.NT THERE MAY BE RAPID RKSPiKAliQN AND PULSE, AIR HUNGER, DIZZINE5S, REDUCED AWARENESS, TIGHTNESS IN IHE HEAD, TINGLING SENSATIONS, INCOORDINATION, FAULTY JUDGEMENT, EMOTIONAL INSTABILITY, AND RAPID FATIGUE. AS THE ASPHYXIA PROGRESSES, NAUSEA, VOMITING. COLLArSC, UNCONSCIOUSNESS, CONVULSIONS, DEEP COMA AND DEATH ARE POSSIBLE, CHRONIC EXPOSURE- NO DATA AVAILABLE. FIRST AID* REMOVE FROM EXPOSURE AREA TO FRESH AIR IMMEDIATELY. IT BREATHING HAS STUFFED, 01VE AK11FICIAL RESPIRATION. MAINTAIN AiRWAT anu BLOOD PRESSURE AND ADMINISTER UXYl.KN IF AVAILABLE. KEEP AFFECTED PT-RSON WaRH AND AT REST, TREAT SYMPTOMATICALLY ANIJ SUPPORTIVELY. ADMINISTRATION OP OXYGEN SHOULD BE PEKFURMbD ST QUALIFIED PERSONNEL. GET MEDICAL ATTENTION IMMEDIATELY. pE 008564 JAN 31 '32 31: 10PM 77 ICLDING_E_INM.ST. 3jppL.-- 11/31/*! i*is * sunt4S " JELSlx =.i CHRONIC tRl'OSURC- NO DATA AVAILABLE. Mr.msso r*ct ol of 07 HHSI AID- It IS UNLIKELY THAT EMERGENCY TREATMP.N1 WILL BE REQUIRED. IF adverse trrRcrs occur, get medical attention. IN CASE OP FROSTBITE, WARM APrECTED SKIN IN WARM WATER AT A TEMPERATURE Of 107 f. IP WARM WATER IS NOT AVAILABLE OR IMPRACTICAL 10 USE, GENTLT WRAr AMtUt.1) PAR I IN BLANKETS. ENCOURAGE VICTIM TO ERERCISE APrECTED PART WHILE II IS BEING HARMED. ALLOW CIRCULATION TO RETURN NATURALLY (HATHESON CAS, $TH ED.). GET MEDICAL ATTENTION IMMEDIATELY. EYE CONTACT: PROPYLENE I ACUTE tAPUSUKt- NO ADVERSE EFFECTS HAVE BEEN REPORTED PROM THe GAS. DUE TO RAPID EVAPORATION, THE LIQUID MAT CAUSE fRUSIBllL Willi K6UNE33, PAIN, AMO RUIRRF.n VISION. CHRONIC EXPOSURE NO DATA AVAILABLE. ilRST AID- IT IS UNLIKELY THAT CONTACT WITH THF. CaS PORH WILL REQUIRE EMERCENCT TREATMENT. IP CONTACT WITH LIQUIPTED OR COMPRESSED GaS OCCURS , WASH W11H LARGE AMOUNTS OP WARM WATER UNTIL NO EVIDENCE Of CHEMICAL REMAINS (APPROXIMATELY 13-20 MINUTES). GET MEDICAL ATTENTION IMMEDIATELY. INCEST ION: PROPYLENE: ACUiE EXPOSURE- INGESTION Of A GAS IS UNLIKELY. IP LIQUID IS SWALLOWED, IROSIBIIE DAMAGE OP LIPS, MOUTH AND MUCOUS MEMBRANES MAY OCCUR. CHRONIC EXPOSURE- NO DATA AVAILABLE FIRST AID- IT IS UNLIKELY THAT EMERGENCY TRP.A1MENT WILL BE REQUIRED. IP ADVERSE EPPPXTS OCCUR, TREAT SYMPTOMATICALLY AND SUrPUKl1VfctT AND GET MEDICAL ATTENTION. ANTIDOTE: NO SPECIFIC ANTIDOTE. TREAT SYMPTOMATICALLY ANl> SUPPORT!VELY. REACTIVITY REACTIVITY STABLE UNOF.R NORMAL TEMPERATURES AND PRESSURES. NCOMPATllIllTlESl * .OPYLENE: MINIUM NITRATE * 3ULPUR DIOXIDE? EXPLOSIVE POLYMER I EAT ION, NITROGEN OXIDEl POSSIBLE XONITION. NITROGEN TETRAOXIDEt VIOLENT REACTION, 0XIDIEER8: PtRP. AND EXPLOSION HAZARD. TR1PI.U0RTLM8TMYL HTPOPLUORITE; POSSIBLE EXPLOSIVE KEaCTIOH. SF.f. A1.R0 ALKCNCS. ALKENES: pE 008565 iji 77 gEv.ilN5 *. s MCI 19630 PACE 03 or 07 POLYMERIZATION! MAY UNDERGO EXPLOSIVE POLYHC.UZATION IN MIXTURES WITH LITHIUM NITRATE AND SULFUR DIOXIDE. MAY UNOERCO EXOTHERMIC POLYMERIZATION ON CONTACT WITH METAL COORDINATION COMPLEXES. SIOkAOL AMU UlSfOSAL OBSERVE ALL FEDERAL, STATE AND LOCAL REGULATIONS WHEN STORING OR DISPOSING OF THIS SUBSTANCE. EOR ASSISTANCE. CONTACT THE DISTRICT DIRECTOR OF THE ENVIRONMENTAL PROTECTION AGENCY. "STORAGE** STORE IN ACCORDANCE WITH 29 CFR 1910.110. PROTECT AGAINST PHYSICAL nAMAGE. STORE IN COOL. WELL-VENTILATED area of NONCOMBUSTIBLE CONSTRUCTION AWAY FROM SOURCES OF IGNITION. OUTSIDE OR DETaCHED STORAGE IS PREFERRED (NFPA 49, HAZARDOUS CHEMICALS DATA, 1973). BONDING AND GROUNDING! SUBSTANCES WITH LOU ELECTROCONDUCTIVITY, WHICH MAT BE IGNITED BY ELECTROSTATIC SPARKS, SHOULD BE STORED IN CONTAINERS WHICH MEET THE BONDING AND GROUNDING GUIDELINES SPECIFIED IN NFPA 77-1983. RECOMMENDED PRACTICE ON STATIC ELECTRICITY. STORE AWAY FROM INCOMPATIBLE SUBSTANCES. "DISPOSAL** DISPOSAL MUST BE IN ACCORDANCE WITH STANDARDS APPLICABLE TO GENERATORS Or HAZARDOUS WASTE, 40 CFR 262. EPA HAZARDOUS WASTE NUMBER D001. 100 FOUND CERCLA SECTION 103 REPORTABLE QUANTITY. CONDITIONS TO AV010 AVOID CONTACT WITH HEAT, SPARKS, FLAMES OR OTHER IGNITION SOURCES. VAPORS MaY BE EXPLOSIVE. DO NOT ALLOW CONTACT WITH SKIN; MATERIAL MAY CAUSE FROSTBITE. CONTENTS ARE UNDER PRESSURE; CONTAINERS MAY RUPTURE VIOLENTLY AND TRAVEL A CONSIDERABLE DISTANCE. SPILL AND LEAK PROCEDURES OCCUPATIONAL SPILL: SHUl OFF IGNITION SOURCES. DO NOl TOULH SPILLED MATERIAL. STOP LEAK ir YOU CAN DO IT WITHOUT RISK. USE WATER SPRAY TO REDUCE VAPORS. ISOLATE AREA UNTIL CAS HAS DISPERSED. NO SMOKING, FLAMES OR FLARES IN HAZARD AREAI KEEP UNNECESSARY PEOPLE AWAY; ISOLATE KAZARO AREA AND DENY ENTRY. VENTILATE CLOSED SPACES BEFORE ENTERING. PROTECTIVE EQUIPMENT DE 008566 1ji: ; J1 1 z: Ml-5 I it HCI1V830 PACE 06 or 07 N1 HaT JON: .OViDE LOCAL EXHAUST OX OENERAL DILUTION VENTILATION. VENTILATION fcQUIPMtNl must BE explosion proof. RESPIRATOR: 4 me FOLLOWING RESPIRATORS ARE RECOMMENDED flAStU UN iNMJKMATIUN PUUNO IN THE PHYSICAL OATA, TOXICITY AND HEALTH EJECTS SECTIONS, THEY AKE RANKED IN OHOER FROM MINIMUM TO MAXIMUM RESPIRATORY PROTECTION. THE SrtCiriC RESPIRATOR SELECTED MU5T BE RASED ON CONTAMINATION LEVELS FOUND IN THE WORK PLACE,.MUST NOT EXCEED THE WOkKINO Uni |$ OF inf. KE&P1KAIVK AND 66 JOINTLY Al'I'hOVM) BT lilt NAUUNAL INSTITUTE TOR OCCUPATIONAL SAPETT AND HEALTH AND THE MINE SaPETT AND HEALTH ADMINISTRATION (NIOSH'MSHA). ANY SUPPLIED-AIR RESMHaTOR OPERATED IN PRESSUKr.-OtNAhD OK UllIkK FUSHIVt PRCSStlRF. MOnr.. ANT 5ELP-C0NTAINED BREATHING APPARATUS. FOR niltMCiniNG AND OTHER IMMEDIATELY DANCbKOUS 10 Lilt UK HEALTH CONDITIONS: SELF CONTAINED SHEATHING APPARATUS WITH PULL FACEPIECE OPtKAJtD IN PRESSURE-DEMAND or othf.r--rosiTIVE PRESSURE mode, SUPPLIED'AIR RESPIRATOR WITH PULL PACF.Pir.CF. AND OPF.RATED IN PRESSURE*DEMAND OR OTHER POSITIVE PRESSURE MODE IN COMBINATION WITH AN AUXILIARY SELr-CONTAINCD BREATHING APPARATUS OPERATED IN PRESSURE-DEMAND OR OTHER POSITIVE PRESSURE MODE. CLOTHING: FUR THE GAS FORM, PROTECTIVE CLOTHING NOT REQUIRED. ir CONTACT WITH THE LIQUID TORN 18 POSSIBLE, EMPLOYEE MUST WEAR APPROPRIATE protective clothing aho equipment to prevent skin prom pressing. CLOVES: wr.AR ruu. PROTECTIVE, COLD JNSULATINO OLOVES. UYE PROTECTION: FOR THE GAS FORM EYE PROTECTION IS NOT REQUIRED BUT RECOMMENDED. WHERE THERE IS ANY POSSIBILITY OP CONTACT WITH THE LIQUID FORM, EMPLOYEE MUST wlak splash-phoof safety goggles and a paccsiueld to prevent.contact with this SUBSTANCE. CONTACT LENSES SHOULD NOT BE WORN. EMERGENCY WASH FACILITIES! WHERE THERE IS ANY POSSIBILITY THAT AN EMPLOTP-E'S EYES AND/OR SKIN NAY DC EXPOSED TO TNr. LIQUID FORM OP THIS 3U0STANCE, THE EMPLOYER SHOULD PROVIDE AN LYP. WASH FOUNTAIN AND QUICK DRENCH SHOWER WITHIN THE IMMEDIATE WORK AREA FOR EMERGENCY 1IRR. MG INDUSTRIES CREATION DATE: 05/07/90 REVISION DATEI 10/09/90 ADDITIONAL INFORMATION* THIS MSDS IS SUPPLIED PURSUANT TO OSHA REGULATIONS. OTHER GOVERNMENT REGULA TIONS MUST BE REVIEWED POR APPLICABILITY TO THIS rRODUCl. WE BELIEVE THE INFORMATION SOURCE IS RELIABLE AND THE INFORMATION IS ACCURATE AS Or THE DATE HEREOF, HOWEVER, ACCUkACY Ok COMM.r.TBNCSS IS NOT GUARANTEED AND NO WARRANIT JAM 31 ' 32 01:13PM 77 WELDING_*_ItCf3T. S'JFPL - 13K2 S S12399**45 *2 UtLSlNd * ? MCI 19830 MCE 07 OF 07 OF ANY TYPE IS GRANTED. THE INFORMATION RELATES ONLY TO THIS SPECIFIC PRODUCT. IF COMBINED WITH OTHER MATERIALS, ALL L'Um'UNtNJ PROPERTIES MUST BE CONSIDERED. DE 008568