Document 37zN1N0LaEnq61QZR4wdo39Z6

MATERIAL SAFETY DATA SHEET TRA COATINGS CORPORATION P. 0. BOX 216 CORTLAND, OHIO 44410 For Information Call: (216) 924-5757 Date revised: September 1990 SECTION I - IDENTIFICATION Product Name: TRA 4SA-230 Chemical Name: Fluorochemical mixture SECTION II - HAZARDOUS COMPONENTS _____ Material;&tl v 1,1,1 Trichloroethane Trichlorotrifluoroethane Naptha 73% 18% 2% 350 ppm 1000 ppm 500 ppm SECTION III - PHYSICAL DATA Boiling point: 165.4 F Vapor pressure: 350 (mm Hg) Vapor Density: 4.54 (Air=1) Solubility in water: Negligible Appearance/Odor: Translucent/Ethereal Specific Gravity: 1.21 (water=1) Percent volatile by volume: 93% Evaporation rate: 0.35 (Ether=l) SECTION IV - FIRE AND EXPLOSION HAZARD DATA Flash point: None Flammable limits: lei- ueiExtinguishing media: Special firefighting procedures: Use self contained respiratory equipment. Unusual fire and explosion hazards: Vapors and solids can be decomposed by intense heat releasing HCL and toxic fumes. SECTION V - HEALTH HAZARD DATA Threshold limit value: 350 ppm Effects of overexposure: Overexposure may lead to slight anesthetic feeling, possible irritation to eyes, nose, and throat. Continued exposure can result in headaches, fatigue, dizziness, nausea and gradual suppression of consciousness. Emergency and first aid procedures: Move patient to fresh air and if conscious give artificial respiration Page 1 DO 087051. CONFIDENTIAL or oxygen, NEVER administer adrenalin. Any clothing that > has been wet should be removed and skin allowed to air dry complet ly and th n treated with lanolin cream. Ey s should b flushed with lukewarm water for 15 minutes. SECTION _yi - REACTIVITY DATA Stability: stable Conditions to avoid: Open flame or intense heat. Incompatible materials to avoid: Sodium, potassium, and sulfuric acid (above 100C) Hazardous decomposition products: HCL and toxic fumes during decomposition. Hazardous polymerization: will not occur Conditions to avoid: SECTION VII ~ SPILL OR LEAK PROCEDURES Steps to be taken in case material is spilled: Avoid breathing high concentrations of the vapors and avoid repeated contact of the liquid with skin and clothing. Flush spilled area with water. Be sure sufficient fresh air enters the area or it should be vacated. Waste disposal method: Contain and soak up with sand or earth. Dispose in accordance with Federal, State, and local regulations. SECTION VIII ~ SPECIAL PROTECTION INFORMATION Respiratory protection type: None when coatings are used in properly designed and operated units. Ventilation: Exhaust to maintain tlv. Protective gloves: Neoprene (Normally not necessary) Eye protection: Safety glasses (Normally not necessary) Other protective equipment: SECTION IX - SPECIAL PRECAUTIONS Precautions to be taken in handling and storing: Avoid spills, intense heat and open flame. Other precautions: Avoid spills, repeated contact with skin, and prolonged breathing of vapors. Although there is no flash point, do not expose to open flame or intense heat, toxic and corrosive gases can form. When using do not contaminate tobacco products. Always wash thoroughly after handling. Store in a cool dry place. Page 2 DO 087052 CONFIDENTIAL Hlth Hairi Infonation Lj___Btnoaure/Health Effect, Inhalation: Ingestion: Skin Contact: Eyi Contact; Chronic Exposure; Aggravation of Pre-existing Conditions: B.. flSSIAlfl Inhalation: lngeation: Skin Exposure: Eye Exposure: -3sectioh 5 Inhalation may cause irritation of the upper respiratory tract. Symptoms of overexposure may include fatigue, confusion, Headache, dizziness and drowsiness. Peculiar skin sensations (e.g. pins and needles) or numbness may be produced. Very high concentrations may cause unconsciousness and death. Swallowing nay cause abdominal spasms and other symptoms that parallel over-exposure from inhalation. Aspiration of material Into the lungs can cause chemical pnetaonltie, which may ba fatal. May cauaa skin irritation. May cauaa eye irritation, redness, tearing. have caused temporary corneal damage. Splashes Reports of chronic poisoning describe anemia, leucopenla, and bona marrow hypoplasia. Liver and kidney damage may occur. Repeated or prolonged contact has a defatting action, causing drying, redness, dermatitis. Persons with pre-existing skin disorders or impaired liver or kidney function may be more susceptible to the effects of this substance. Alcoholic beverage consumption can enhance the toxic effects of this substance. If lnheled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. CALL A PHYSICAL IMMEDIATELY. Give water to rinse mouth and get medical attention immediately. Haver give anything by mouth to an unconscious parson. Remove any contaminated clothing. Ulpe off excess from skin. Wash skin with plenty of water for at least 15 minutes. Get msdical attention promptly. Hash eyes with plenty of water for at least 15 minutes, lifting lover and upper eyelids occasionally. Get medical attention immediately. C. TOXICITY DATA (RTECS, 1982) Oral rat LD50: 5000 mg/kg* Skin rabbit LD50: 12.124e/kg. Inhalation mouse LC50: 5320 ppm/6H. Aquatic Toxicity rating: Tlm96: 100-10 ppm. Mutation references cited. Reproductive effects cited. Occupational Control Measures Airborne Exposure Limits: Ventilation System: Pesonal Respirators: (NI0SH Approved) Skin Protection: Eye Protection: -4- SECTION 6 -OSHA Permissible Exposure Limit (PEL): 200 ppm (IVA) i 300 ppm (Celling), 500 ppm (Peak). -ACCIH Threshold Limit Value (TLV): 100 ppm (TVA); 150 ppm (STEL). A system of local exhaust is recommended to keep employee exposures below the Airborne Exposure Limits. Local exhaust ventilation Is generally preferred because it can control the emissions of the dust or vapor at its source, preventing dispersion of It Into the general work area. Please refer to the ACCIH document, "Industrial Ventilation, A Manual of Recommended Prectlcea", most recent edition, for details. If the TLV la exceeded, a half mask chemical cartridge resprlrator may be worn up to ten times the TLV or the maximum use concentration specified by the respirator supplier, whichever is less. Wear Impervious protective clothing, Including boots, gloves, lab coat, apron or coveralls to prevent skin contact. Use chemical safety goggles and/or a full face shield where splashing is possible.Contact lenses should not be worn when working with this material. Maintain eya wash fountain and quick-drench facilities in work area. Storage and Special Information SECTIOH 7 Protect against physical damage. Store in a cool, dry well-ventilated location, away from any area where the fire hazard may be acute. Outside or detached storage Is preferred. Separate from oxidizing materials. Containers should be bonded and grounded for transfers to avoid static sparks. Storage and use areas should be Ho Smoking areas. Use non-sparking type tools and equipment. The information contained herein is provided In good faith and Is believed to be correct as of the date hereof. However, Malllnckrodt, Inc. makes no repre sentation as to the comprehensiveness or accuracy of the Information. It Is expected that individuals receiving the information will exercise their in dependent judgment in determining Its appropriateness for a particular purpose. Accordingly, Malllnckrodt, Inc. will not be responsible for damages of any kind resulting from the use of or reliance upon such Information. NO REPRESENTATIONS, OR WARRANTIES, EITHER EXPRESS OR IMPLIED, OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE OR OF ANY OTHER NATURE ARE MADE HEREUNDER WITH RESPECT TO THE INFORMATION SET FORTH HEREIN OR TO THE PRODUCT TO WHICH THE INFORMATION REFERS. HiUlackr4t Inc. Science Produce* filvlelon P.0. Sox H Parle, Kentucky 40361 3 087053 CONFIDENTS! TOLDEHB Material Safety Data Sht Eaergency Telephone Number 314-982-5000 Effective Dete: 06-22-65 PRODUCT IDENTIFICATION: Synonyms: Hethylbenzene; Toluol; Fbenylme thane Formula CAS Ho.: 106-86-3 Holecular Weight: 92.14 Hazardous Ingredients: Hot applicable. Chemical Formula: CH3C6H5 PRECAUTIONARY MEASURES WARNING! FLAMMABLE! HARMFUL IF SWALLOWED OR INHALED. Keep away from heat, sparks and flame. Keep container closed. Use with adequate ventilation. Avoid breathing vapor. Wash thoroughly after handling. BIBRCEHCTT/FIRSI AID If aval lowed, give water to rinse mouth. Never give unconscious person. If inhaled, remove to fresh air. If not breathing, breathing is difficult, give oxygen. In all cases call a physician. anything by mouth to an give artificial respiration. If SEE SECTION 5. DOT Hazard Class: Flanable Liquid Physical Data 5ECTIQB 1 Appearance: Clear, colorless liquid. Odor: Aromatic benzene-like. Solubility: 0.05 ga/lOOgn water @ 20*C (68*F>. Bolling Point: 111*C (23l*F)' Vapor Density (Air-1):3.14 Melting Point: -95*C (-139*F). Vapor Pressure (mm Hg):22 @ 20*C (68*F Specific Gravity: 0.66 Evaporation Rate:2.24 Fire and Explosion Information Fire: -2SECTION 2 Flammable. Vapors can flow along surfaces to distant Ignition source and flash back. Flash Point: 4*C <40*F) (closed cup). Autoignition temperatures: 460*C (896*F). Flammable limits In air, % by volume: 131 1.27, uel 7.1. Explosion: Above flash point, vapor-alr mixtures are explosive within flammable limits noted above. Contact with strong oxidizers may cause fire and explosions. Fire Extinguishing Media: Special Information: Reactivity Data Stability: Hazardous Decomposition Products: Dry chemical, foam or carbon dioxide. Water may be used to flush spills away from exposures and to dilute spills to non-flammable mixtures. In the event of a fire, wear full protective clothing end NI0SH-approved self-contained breathing apparatus with full facepiece operated in the pressure demand or other positive pressure mode. SECTION 3 Stable under ordinary conditions of use and storage. Containers may burst when heated. Toxic gases and vapors (e.g., carbon dioxide and monoxide) may be released in a fire Involving toluene. Hazardous Polymerization: Incompatibilities: Will not occur. Heat, flame, strong oxidizers, acids nitric and sulfuric, nitrogen tetraoxlde, will attack some forms of plastics, rubber, coatings. Uak/Spill Disposal Infornation SECT I OH 4 Remove all sources of ignition. Use non-sparking tools and equipment. Clean-up personnel require protective clothing and respiratory protection from flammable vapors. Small spills may be absorbed on paper towels and evaporated In a fume hood. Allow enough time for fumes to clear hood, then Ignite paper in a suitable location away from combustible materials. Contain and recover liquid for reclamation when possible. Larger spills and lot sizes can be collected as hazardous waste and atomized in a suitable RCRA approved combustion chamber, or absorbed with vermlcullte, dry sand, earth or similar material for disposal as hazardous waste In a RCRA approved facility. Do not flush to sewer! Reportable Quantity (RQ)(CUA/CERCLA) : 1000 lbs. Ensure compliance with local, state and federal regulations. DO 087054 CONFTDFNTTAl.