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Ttrw- C(W> Hie 4/ EPA SUPPORT DOCUMENT ---------- is REGULATORY STANDARDS AND SOLUBILITIES OF CONSTITUENTS OF CONCERN . and references CuP-fuO+ni 'uTO /H~wO tlnaii-H -*- v/ 1>^ 4? June, 1966 DTH 000033845 REGULATOR* STANDARDS AND SOLUBILITIES OF CONSTITUENTS OF CONCERN ConponS ftsgulatory Standard (ng/1) REF Solubility <mg/l) REF Acenaphthene fry* Acenapthylene Acetonitrile Acrylic acid Acrylonitrile Aldrin Allyl alcohol Anthracene 'Benzene Benzidine Benzo(a)pyrene ' 4 Ber-o(b)flouranthene Benzo(g,h,i#) perylene *-< Benzo(k)fluoranthene Bis-2-ethylhexylphthalate --Bis (chlorcroethyl )ether Bis(2-chloroethyl)ether BrcncxJ i chi oronethane . If 3-Butadiene Cacodylic acid -A' Carbon disulfide Carbon tetrachloride Chlordane Chlorobenzene Chloroform Chioronethane > Chrysene X Cresols Di benz{a/h)anthracene Di-n-butvl phthalate O' O' O' O' O' O' O' O' O' O' O' O' 2.8 1.5x10-4 1.1 x 10*3 0.18 2 i 3 3 1.2 x 10-3 1.5x10-7 3.0 x 10-* 2 x 10-5 i 1 1 4 3.4 3.9 , 1.0 x 106 6 6 6 7.9 x 104 0.18 5.1 x 105 0.05 1.8 x 103 400 1.2 x 10- 3 1.4 x 10- 2 6 6 6 6 6 6 6 7.0 x 10-4 4.3 x 10-3 6 0.70 3 0.4 3.8 x 10-9 1 2.2 x 104 3.1 x 10-5 i 1.0 x 104 0.21 3 3.5 x.10-4 1 735 0.35 2 8.3 x 105 3.5 2 2.9 x lO3 2.7 x 10-4 i 800 2.2 x 10-5 i 0.56 1.1 2 4.7 x 102 5.0 x 10-4 i ,, . 8.2 x 103 6.5 x 103 2 x 10-4 4 1.8 x lO"3 1.8 2 3.1 x 104 7 x 10-7 4. 5.0 x 10*4 3.5 3 13 O' 7 6 6 6 6 6 6 6 6 6 6 6! Ji.~ It DTH 000033846 REGULATORS STANDARDS AND SOLUBILITIES Of CONSTITUENTS OF CONCERN Compound 1,2-Di chlorobenzene 1,3-Dichlorobenzene 1,4-Dichlorobenzene 3,3'-Dichlorobenzidine Dichlorodifluoro- methane 1,1-Dichloroethene 1,2-Dichloroethene (both isoners) 1,2-Dichloroethane Di chloroneuhane 2,4-Dichlorophenol Diethyl phthalate 7,12-Dimethylbenz- (a)anthracene 2,6-Dimethylphenol 3,4-Dimethylphenol Dimethyl terephthalate 2, 4-Dinitrophenol 2,4-Dinitrotoluene 1, 2-Diphenylhydrazine Epichlorohydrin Ethyl benzene Ethylene dibrcmide Fluoranthene Fluorene Formaldehyde Fcrmic acid Heptachlor He xabrorobenzene Kexacnlorobenzene Hexachlorobutadiene He xachloroe thane Ideno(l,2,3,cd)- pyrene Iaophorone Regulatory Standard (tng/1) REF 3.2 3.B 3.6 2.1 x 10*5 2 10 10 1 7.0 . 3.0 x 10-4 0.35 2 1 8,9 3.8 x 10-4 0.056 0.11 350 1 1 3 3 2.1 x 10-3 3.5 x 10-3 3.5 0.07 1.1 x.10-4 4.5 x 10-5 3.5 x 10-3 3.5 8.5 x 10-7 . / a Z 70 1.0 x 10-5 0.07 2.1 x 10-5 4.5 x 10-3 2.5 x 10-2 2 x 10-4 7.0 3 3 3 3 1 1 1 2 1 2 1 3 1 1 1 4 2 Solubility (mg/1) 100 123 79 4 REF 6 6 6 6 2250 3500 (cis) 6300 (trans) 8520 2.0 x 104 4.6 x 103 896 6 6 6 6 6 6 6 4.4 x 10-3 6 5.6 x 103 240 1.8 x 103 6.0 x 104 152 4.3 x 103 0.21 1.7 4.0 x 105 0.18 6.0 x 10-3 50 5.3 x 10-4 6 6 6 6 6 6 6 6 6 6 6 6 K4- . .DTH 000033847 M. REGULATORY STANDARDS AND SOLUBILITIES OF CCKSTITtnS OF CONCERN t Ccnpexnd Regulatory Standard (mg/1) REF Solubility (g/l) REF Methyl ethyl ketone 1.8 Methyl ethyl ketone peroxide 0.28 Naphthalene ---------- -- q Nitrobenzene 0.018 Nitrogen dioxide 35 N-N itrcsod iphenylar-. i ne 7.1 x 10"3 Pentaehlorobenzene 0.026 Fentachloronitro- benzene 0.28 Fentachlorophenol 1.1 Fhenanthrene Phenol 3.5 m-Phenylenedi amine 0.21 Phosphine 0.011 Phorate 0.007 Polychlorinated biphenyls 8.1 x 10" fyrene fyridine 0.07 Sodium diethyldithio_ carbamate 1.1 * Styrene 7 1,2,4,5-Tetrachloro- benzene 1,1,2,2-Tetrachloro- 0.011 ethane 1.8 x 10-3 Tetrachloroethylene 6.9 x 10"* 2,2,A,6-Tetrachloro- phenol . 0.35 2,3,5,6-Tetrachloro- terephthalate 1.8 Tetraethyl lead 3.5 x 10"6 Thallic oxide 0.014 2 2 2 2 1 3 2 2 2 3 2 5 1 2 3 3 3 a i * 2 3 2 2 2.7 x 105 31.7 0.14 0.07 14 1 9.3 x 10* 50 3.1 x 10"2 0.13 miscible 6 2.9 x 103 150 1.0 x 103 0.8 \ ' 6 7 6 6 6 6 6 6 6 6 6 6 6 6 6 *- DTH 000033848 'V- REGULATORY STANQARIS AND SOLUBILITIES OF CONSTITUENTS OF CONCERN Compound Thallium acetate Thalliim carbonate Thallium chloride Thallium nitrate Thallium aelenite Thallium sulfate Toluene 1,2,4-Trichloro- benzene * 1,1,1-Trichloroethane 1,1,2-Tr:rhloroethane * Trichloroethylene Tr ichlorofluorcree thane 2,4,6-Trichloropbenol 2,4,5-Trichlorophenol 2,4,5-Trichlorophen- oxy acetic acid * 1,1,2-Trichloro- 1,2,2-trifluoroethane Vinyl chloride * Xylene Regulatory Standard (mg/1) REF 0.01B 0.014 0.018 0.018 0.018 0.018 10.5 2 2 2 2 2 2 2 0.7 1.2 6.1 x 10-3 3.2 x 10-3 10.5 1.8 x 10"3 3.5 3 11 1 1 2 1 2 1.1 3 1050 ` 0.002 2 1 Solubility (ng/1) REF X Z H > <ZT l-o tr=> 535 30 1.5 x 103 4.5 x 103 1.1 X 103 800 1.2 x 103 6 6 6 6 6 6 6 2.7 x 103 198 6 6 / \ \j DTH 000033849 REFERENCES FOR TABLE 1 1. U.S. EPA. 2985. Health Assessment Document for Trichloroethylene. EPA 600/8-82/006F. (PB-85-249-696>. 2. U.S. EPA. 1986. Verified Reference Doses (RFDs) of the U.S. EPA ORD/ECAO-CIN-4 75. January 1986. 3. U.S. EPA. 1986. Verified Reference Doses (RFDs) of the U.S. EPA ORD/ECAO-CIN-475. May 1986. 4. .... _____ 1535. Ambient Water Quality Criteria for Poly nuclear Aromatic Hydrocarbons, EPA 440/5-80-069 (PB-81-117806); U.S. EPA. 1982. Ambient Water Quality Criteria for Polynuclear Aromatic Hydrocarbons. EPA 440/5-80-069. Errata. Program Office Draft (Table A). 5. U.S. EPA, "Summary of Acceptable Daily Intakes (ADI) for Oral Exposure," Internal Review Draft, ECAO-CIN-0432 (May 1985). 6. U.S. EPA. Office of Emergency and Remedial Response, "Draft Superfund Public Health Evaluation Manual," EPA Contract No. 68-01-7090 (October 1985). 7. Callahan et^. l., 1979. Water-related Environmental Fate of 129 Priority Pollutants,.Volumes I and II, Office of Water and Waste Management, EPA-440/4-79-029a, EPA Contract No. 68-01-3852 and 68-01-3867. (PB-80-204-373 and PB-80-204381). 8. U.S. EPA. Office of Drinking Water, "Cis-1,2-Dichloroethylene, Health Advisory," Internal Review Draft (September 1985). 9. U.S. EPA. Office of Drinking Water', "Trans-1,2-Dichloroethylene, Health Advisory," Internal Review Draft (September 1985). 10. U.S. EPA. Office of Drinking Water, "Ortho- meta-, and paradichlorobenzenes, Health Advisory," Internal Review Draft (September 1985). 11. U.S. EPA. Office of Drinking Water, *1,1,1-Trichloroethane, Health Advisory," Internal Review Draft (September 1985). DTH 000033850 H e a lth -based m her Ha te r S o lu b ility Wefei Is CL o HJ CL IN "C * IW N tt O o 1 *o IN tw O CL o Q <* fl ^*IWp4 b 2 < E in i e * K m iEC U-l VO CL sc' we Chemical Name I. wtf * "5 rj m p>. *3 ** h >-- --II s *3 * c h It 1 CD m Li j % hH ri, x7 <wIVMT XCi*1 .. m a: ~ DTH 000033851 T able o f Health-Rased Nuwbers DTH 000033852 | , 2-Trans-d ichloroothyleno (156-60-5) 0.4 nrj/L R fl) 6300 mq/f. (20*C) fra n Hazard P ro file fo r l,2-Trans-1ichloro -ethylene/F irst. D ra ft/ OOW H e a lth A d v is o ry f o r Ttans-1,2-D ichloroethylene/ D ra ft/S e p t. 30, 1905 <it *t>> +> miU) C f U t1 j i.. -- .* *.. u si a -< s g a fc s 1h s\ m JC. ti-- SV) O' mfB i +s* ** *S,S3 iIunN mu - IN < r oI o VmC <N _ IQ 2al* % tis Xa/ W *N# U. --<y^ 0> JD* 8 E -- > uu c bb^ aa*g il| 88 S c--r pfN < *ege otafcrf < PlMatKM o <fc g-'T ir*^ 1 ^1o +/ w dl K?CJSk> 21 Ov C <1 /:* if1 *1 M& -- -*-J ** V. * c ' -fi c <* g? in i c o *^ w C `fiL'n l st ts gr s~ Ct CV Iu.t1* is b. --- "T 12 KIt 5I k. <N x E It K *J INI gE 2 - KC *-- C <"> I? 2-- DTH 000033853 I > t 7 i fVSI ini 0 *$ CD --I gS 25 * | Mr g I <eNg C Ip ** N > , DTH 000033854 Hater S o lu b ility H ealth-based Number .VC <b re-l +J J It ct X _-- C i. * g o Ifcri Nw *4 ou O FI <N iw * "C 2 VC b_ fii re ** jf K ool g o <v t* w ^ Tid $ f= *c e oa, F| n *in ,V--j $ t Chemical Now* DTH 000033855 7/18/06 u u fM & tO *0 2 VO i * )2 5 . >-- c ?o ?o 1 */ ^ ot S C 10 . o o Sw . r g K u,, '4 ~ Is tr> r- 5 * i CM A < fN 01M 97 r MT * 1 o O' fM O>' < -- DTH 000033856 1870 Full Text ERA TENTATIVE LIST OF HAZARDOUS WASTE CONSTITUENTS TO BE PROPOSED FOR TESTING FOR POSSIBLE CONTROL UNDER RCRA (Undated) Table 1 -- HAlAAPOUt MASTS CONSTITUENTS SUBJECT TO TESTING CHLMICA1. Acataaida. M-(*ainothioaaM*thyl) Acataaida. 2-fluoro Acatophanona Aaaoniua vanadate Sanaa1 eklaiKa p-Saiiaoquinona 2.2'-8ioitrane la< 2-ehloroethoiylaathanv Bia(2-chloroiaoptupyl lathai Sroauacatona 4-at uaobana y 1 cyan i4e roaofoia 1 -8i uao-4 -pheuoiy bantana Carbonyl fluoride Chloral 2-Chlotoiiaiiaotr ictiior I Ja 4*ctilo(gUuui < uiilui 14a 2-chloroethyi vinyl ether Chlorna|>hazina 1(o-Chlorophany1 Ithioutea Cyanogen Uuanla aalta and aataia Oauaoaycin Oia(oaoaathane Pi butyl pnthalate 1. 2-DtctilurotienaeiMr 1. 1-OictilorotienMne 1,4-Oiehlor obeusane 1.I-Olchloruathana 1. J-llltiiiutupf upanol 2. i~t'iclilwiwt*r'i|*anol SA-HathylaMthytdtthaophnpliaia il.ydluealrule a a *bi at-1 liy I t liy 1 aa i ua cas mo. 791-08-2 440-l*-7 *a-a*-2 7801-77-4 *4-17-1 104-71-4 1444-71-7 111-41-1 108-40-1 **-i: : I47J2-79-* 77-2S-2 101-77-3 IS 1-70-4 77-8 7-4 21J4-8V-2 7214-27-1 110-77-8 4*4-01-1 724442-1 704-48-1 *4-77-7 20810-81-1 74-*-l 84-74-2 *7-7-l *41-7 1-1 104-44-7 77-J4-I *4-2 1-1 4I4-21-* liMM-MW *4-78-4 2/-OV-B Sutichronlc Toildlv Taat lug 8o Ineuf Oat* data Hydtalyala Taatlug 8o InauTT data data 8lode*cailat ion Taatlua Mu Ineuf. data data Soil Sorption TaatIna No IneufT data data 2-20-27 Pubsahad fey TMt WWEAU OP NATIONAL APPAM8. INC.. Waahwgion. O.C 20037 DTH 000033857 CURRENT DEVELOPMENTS Table I -- aOAUPOUt MATt COMirmitMTI, 8UUCCT TO T88T1MC (Con t) CIIDUCAL CAS MO. Biaathyl plithalate 4.t-Olnltro-o-cycluhaylpenol Bndr(n 1J1-1I-3 lll-d-i 401-20-2 72-20-1 Sthylana-bielithiocarbaaic add EthylaatKacrylata 111-14-4 7-1J-2 Slycidylaldehyda 7H-14-4 Karachioropbane 10-10-4 Naraathyl-tatra-phosphate laoaatrola Malaic anhydride taltic hydioiid* Mlononllrl l tot li*cry lout tr i 1* M* 1 lirilvlIUOJ Mi ( nT 1 Oil.ti Mr Netnyl chlorocarbonata 1 -Uaplithylaaina 117-11-4 no-la-i los-n-i 12i-IJ-l 101-77-J 124-18-7 74-H 1 -1 75-U/-1 71-22-1 114-12-7 Ui-otine and aalta ,-ai troaniline 14-11-1 100-01-1 p-Nitruphenol 100-02-7 Paraldehyde 111-11-7 Pent settlorobenune 108-11-1 Pentachloroathane 71-01-7 fhfMCttin o-Phrny]thiour* Pho9n tnhydrida 12-44-2 101-M1-1 71-44-1 1-44-1 2-PicoItn Propananttrile. 101-04-a 107-lob 107-12-11 I`iul, J-chlaiu 142-7a 7 in and t*l(8 1.2.4.i-TettechieroManaena Tateeethyldi thiapyraphoephata Ml-07-2 1-14-J M81-24-1 71-11-1 e-Teluidine hydrochloride 1M-21-1 t 1 chlorooethaoethi ol Trypan kina 114-42-1 72-17-1 . Sutochronlc Torlcltv Taatina VO ll)*uf. ltd liti X X Hydrolysis Tailina Vo Iniul. dot* dot* X X X X X X 1X X X X X X X X X X X X X X X X X X X X X XX Taat ina Me maul. data data X X X X X X X X X X X X X X X X X 1811 T**t1 no Vo In*u t . Itti dot* X X X X X X DTH 000033858 APPENOU A REFERENCE AIR CONCENTRATIONS (RACs) fOR THRESHOLD constituents Constituent Nasiauii Annual Average ftiwwj Level Concentration (ug/3) acetonitrile acetophenone acrolein aliamnuo phosphide ellyl alcohol ant loony bar nan banian cyanide benzidine bi*(2-ethylhey1)phtha lete breoDoetha'ne calc nan cyanide carpon disulfide cnlordane 2-ch loro* 1.3-DutaS iene chloreoethane chraniim ]]] capper cyanide cresols cyanide(free) cyanogen di-n*butyl phthalate p-dichlerobenzene diehlorodifluoreeethane 2,4-dIchlorephenoT l.J-dichloropropene diethyl phthalate dMethoete 2.4-dinltrophenol diphenylaoine endosulfan endnn flour ine forosldehyde foroic acid 10 soc 0.25 0.25 5 0.25 SO SO 0.5 s 10* 17 0.7 25 200 5 i 10*3 2.5 0.7 1.000 SO 100 17 25 10 10 170 2.5 0.2S 10 1.0 1.0 <25 0.01 0.05 so * 2 s 10*s 1700 237 DTH 000033859 APPElUin A leant tnued) U& Constituent Nat mu* Annual Average firetaid Level Concentration (ug/3) hoptachlor hesaenloroc yelopentadions hydrocyanic acid hydrogen chloride hydrogen sulfide isodutyl alcohol load mrtury etholoyl aethosyehlor ethyl ethyl ketone etnyl hydrazine ethyl parathion nickel nickel cyanide nvtnc oaide n ttroOenzene pentaehlorodenzene pentaehloropheno1 phenol pheny lenedianne phonytaercuric acetate phosphine KBs Potass u* cyanide potass iis* stiver cyanide pyridine aelenious acid oelonourea Silver silver cyanide aeditas cyanide Strychnine 1.2.4.$*tetrachlorodenzene 7.3.7.0-tetrach1orodidenzo*p-dio*in 7.3.7.0-tetrachlorophonol tetraethyl lead 01 S 17 a*nu* of ISO for three Minute average ?.S 750 0.09 1.7 73 SO 75 7 a 10*3 * 7.5 10 ' 17 75 0.5 1.7 75 100 5 0 00 0.75 7 * 10'4 SO 170 S 7.S S S 100 75 0.75 0.7S S 10"* 10 1 10"4 238 DTH 000033860 APPINOlX A (continued) Constituent Narwun Annual Average firmeid level Concentration (ug/3) . thallic onde Ihs 11 turn thsl liter (1) ocetate thill iter (1) carbonate thill turn (1) chloride thill iter (1) nitrite tfwlliu* selenite thilliiis (I) sulfate toluene 1.2.4-trichtoroOenxene trichloroeonof1uoroMetnane 2.A.5-trichloropheno1 vanditir pentoxide ^ vinyl chloride 0.2S MO OS 0.25 OS OS OS OS MO 17 2S0 100 17 0.05 239 DTH 000033861 APPENDIX B risk specific ooses for carcinogenic constituents AT 10*5 RISX lEVEl Constityent Risk Specific Odsp IuR/"3) Aery1amide Acrylonitn le Aldrin Anilmt Arsenic X ene(a)anthracene t Benzene Benzole)pyrene # Beryl In* Bis(Z-ch1oroethyl)ether Bis(2-chlorethyl)ether Cadmisn Cerbon tetrachloride I-Chloro-C.J-epo*ypropene Chloroform ChloroMihyl methyl ether Chromii* (hesavalent) OOT Dibenz|*.h)anthracene 1.2-Dibrcmo-e-chleropropane 1.2-Dibronethane 1,4-Oichlorooenzene ' 1.2-Oichloraethene * 1.1-0ichloroethylone Dteldrin Oiethylst i Ibestrol 0eeethy In itrose*me 2.4-Ointtrotolwone Otoeane Ethylene oeide Mesachlorofeanzene Mesaehlorobutadiene Hydrazine Hydrofine Sulfate J-Methy lcho lanthrene Methylene chloride 4,4-Methylene-bit*2-ch1oroani1i ne 10*3 10*1 10*3 10*3 10*2 10*3 10'3 10*2 10`3 10*3 10*1 10*7 10`3 10*4 10'2 10*4 1C*3 10*4 10*1 10*1 10*3 10*5 10*4 10*1 10*1 10*1 iO*3 10 3 JO*3 ft 10*1 240 I DTH 000033862 WPDU 8 (continued) Constituent ><(k Specific Dose (ug/eiS) tJZHl&r ^ Picsel (certonyl t Suosglflde) 2-Pitropropene P-Pitroso-n-ethjrlure* P'NitrosopynroliOine 8enuctiloronitro6ensene Pronenide Keserpine 1.1.2.2-Tetrechloroethsne TetroeMoroetnylene Thiourt* Trichloroethylene 3 10** * * 10** 1 i 10** 2 10** 1 10"1 2 3 10** 2 * 10** 21 2 10"* 8 241 DTH 000033863