Document 2qNo8qryNBQOBJG19nJeJp7J6

i t: IRC Summary Analyte Peak Name PFOA 2 S_13C_PFOA PFNA 2 S_13C_PFNA PFOS 2 S_13C-PFOS PFDA 2 S_13C-PFDA PFUnA 2 S_13C-PFUnA PFDS 2 PFDoA2 S_13C-PFDOA PFTrA 2 PFTeA2 p. 1 Created with Analyst Reporter Printed: 14/02/2010 6:41:00 PM RT (Expected) 1.38 (1.36) 1.38(1.36) 2.34 (2.44) 2.30 (2.44) 2.35 (2.53) 2.36 (2.53) 3.32(3.34) 3.31 (3.34) 4.12(4.06) 4.12(4.06) 4.13 (4.10) 4.76 (4.64) 4.76 (4.64) 5.29(5.13) 5.74(5.56) Area 1629900 2766100 355520 2154600 1159300 6761100 156690 2111500 171520 172740 1260200 163950 199680 142130 108440 Modified? No No No No No No No No No No No No No No No Calculated Ion Ratio (Expected Value) 2.50 4.24 0.29 1.77 0.31 1.82 0.15 2.03 0.20 0.20 0.32 0.28 0.34 0.35 0.39 Page 27 of 242 237 f r C o lilitib lS Analytical Services1* Quantitative Peak Review Created with Analystfcdporter Printed: 14/02/2010 6:41:00 PM PFC 5.0ppb 2.30 2.30 PFOA 1 413.0/169.0 Da c Baseline Missed r Wrnnn Peak ^_____ 2^5^_______ 13C-PFOA 417.0/372.0 Da a Baseline Missed __ n Wrnnn Peak___ I 2.36 PFNA 1 463.0/419.0 Da Baseline Missed p Wrnnn Ppak 13C-PFNA 468.0/423.0 Da Baseline a Missed r, Wrnnn Peak PFOS 1 499.0/80.0 Da c Baseline Missed i-` Wrnnn Ppak 4.12 1 13C-PFOS 503.0/80.0 Da Baseline Missed n \A/rnnn Ppak L _ i_ PFDA 1 513.0/469.0 Da Baseline Missed n Wrnnn Peak 13C-PFDA 515.0/470.0 Da Baseline Missed r- Wrnnn Ppak PFUnA 1 563.0/519.0 Da Baseline Missed __ n Wrnnn Peak 13C-PRJnA 565.0/270.0 Da g Baseline Missed __ n Wrnnn Peak___ PFDS 1 599.0/80.0 Da g Baseline Missed n Wrnnn Peak 13C-PFOS 503.0/80.0 Da Baseline Missed ___n Wrnnn Peak___ PFDoA 1 613.0/569.0 Da c Baseline Missed r Wrnnn Peak 13C-PFDOA 615.0/169.0 Da g Baseline Missed n Wrnnn Psak -.I PFTrA 1 663.0/619.0 Da c Baseline Missed n Wrnnn Peak 13C-PFDOA 615.0/169.0 Da Baseline Missed r Wrnnn Peak___ PFTeA 1 713.0/669.0 Da c Baseline Missed Wrnnn Peak 13C-PFD0A 615.0/169.0 Da d Baseline Missed p Wrnnn Peak___ Before After Page 28 of 242 238 Col ib ia p. 3 Created with Analyst Reporter Printed: 14/02/2010 6:41:00 PM Ion Ratio Confirmation PFC 5.0ppb PFOA2 413.0/369.0 Da l Baseline c Missed c Wrong Peak i J 4. j ___i:_f.___iU> ! PFUnA 2 563.0/269.0 Da c Baseline c Missed a Wrong Peak PFNA2 463.0/219.0 Da Baseline o Missed Wrong Peak I 2 4-. 3 ; r : : : : PFDS2 599.0/99.0 Da Baseline c Missed Wrong Peak PFOS2 499.0/99.0 Da d Baseline Missed Wrong Peak ::: 10*<> 1 i 4. 6 t :on <,i PFDoA 2 613.0/169.0 Da D Baseline Missed o Wrong Peak 3l IK." - PFDA2 513.0/269.0 Da c Baseline Missed Wrong Peak PFTrA 2 663.0/169.0 Da Baseline c Missed Wrong Peak PFTeA2 713.0/169.0 Da Baseline Missed Wrong Peak Before After Page 29 of 242 239 jTM. Cilllnfjbfs 3 Analytical Services" Created with Analyst im porter Printed: 14/02/2010 6:41:00 PM Project Data File Acquisition Method Ewan's Projects\PFCs 02081 ObACalLong.wiff PFCkinetexLong.dam Result Table Algorithm Used Instrument Name 02081 OSamplesLong.rdb IntelliQuan API 5000 Sample Name Acquisition Date Acquisition Method Sample ID Sample Comment PFC 10ppb 2/8/2010 6:53:02 PM PFCkinetexLong.dam LCMS2-85E Injection Vial Injection Volume Sample Type Dilution Factor Weight to Volume 6 5 Standard 1.00 0.00 Results Summary Analyte Name Analyte RT (Expected) PFOA1 1.34 (1.36) IS Name 13C-PFOA IS Area 3016300 PFNA 1 2.29 (2.42) 13C-PFNA 2357300 PFOS 1 2.35 (2.53) 13C-PFOS 6895700 PFDA 1 3.34 (3.34) 13C-PFDA 2127100 PFUnA 1 4.12(4.06) 13C-PFUnA 172090 PFDS 1 4.12(4.10) 13C-PFOS 6895700 PFDoA 1 4.76 (4.63) 13C-PFDoA 225140 PFTrA 1 5.29 (5.14) 13C-PFDOA 225140 PFTeA 1 5.74(5.74) 13C-PFDoA 225140 Analyte Area 1492100 2910500 8049100 2332600 1784200 8526300 1395800 925940 716720 Exp Cone (ng/mL) 10.000 10.000 10.000 10.000 10.000 10.000 10.000 10.000 10.000 Calc. Cone (ng/mL) 10.200 Accuracy (%) 102 10.800 108 11.000 110 10.400 104 11.000 110 10.900 109 11.400 114 11.700 117 11.900 119 ./ Mod? No No No No No No No No No -2L / I L f f t C Page 30 of 242 240 S 7 C o lu m b ia < 3 Analytical Services" IRC Summary Analyte Peak Name PFOA 2 S_13C_PFOA PFNA2 S_13C_PFNA PFOS 2 S_13C-PFOS PFDA2 S_13C-PFDA PFUnA2 S_13C-PFUnA PFDS 2 PFDoA2 S_13C-PFDoA PFTrA 2 PFTeA2 RT (Expected) 1.35 (1.36) 1.35(1.36) 2.30 (2.44) 2.28 (2.44) 2.34(2.53) 2.33 (2.53) 3.34 (3.34) 3.35 (3.34) 4.12 (4.06) 4.12(4.06) 4.12 (4.10) 4.76 (4.64) 4.76 (4.64) 5.29 (5.13) 5.74 (5.56) p. 5 Created with Analyst Reporter Printed: 14/02/2010 6:41:00 PM Area 3733500 3016300 850370 2357300 2557600 6895700 349340 2127100 378600 172090 2766600 414280 225140 306170 228950 Modified? No No No No No No No No No No No No No No No Calculated Ion Ratio (Expected Value) 2.50 2.02 0.29 0.81 0.32 0.86 0.15 0.91 0.21 0.10 0.32 0.30 0.16 0.33 0.32 Page 31 of 242 241 C oIilf??bis iL*Jf Analytical Services" Quantitative Peak Review 1.35 Created with A n a ly s t^ ! porter Printed: 14/02/2010 6:41:00 PM PFC 10ppb 2.28 PFOA 1 413.0/169.0 Da a Baseline o Missed n Wrnnn Peak PFOS 1 499.0/80.0 Da Baseline Missed i Wrnnn Ppak 13C-PFOA 417.0/372.0 Da Baseline d Missed n Wrnnn Peak___ 2.33 13C-PFOS 503.0/80.0 Da o Baseline Missed n Wrnnn Peak PFNA 1 463.0/419.0 Da o Baseline o Missed n Wrnnn Peak 3.34 1. PFDA 1 513.0/469.0 Da Baseline Missed i Wrnnn Ppak 1 13C-PFNA 468.0/423.0 Da d Baseline Missed p Wrnnn Peak 13C-PFDA 515.0/470.0 Da Baseline Missed n Wrnnn Pfiflk PFUnA 1 563.0/519.0 Da c Baseline c Missed ___h Wrnnn PoaK___ 13C-PFUnA 565.0/270.0 Da a Baseline Missed ___n Wrnnn Peak___ PFDS 1 599.0/80.0 Da Baseline Missed n Wrnnn Peak 13C-PFOS 503.0/80.0 Da Baseline Missed __ n Wrnno PfioK___ 4.76 PFDoA 1 613.0/569.0 Da c Baseline Missed p Wrnnn Paak 5.74 13C-PFDOA 615.0/169.0 Da Baseline Missed n Wrnnn Pfiak life4- PFTrA 1 663.0/619.0 Da Baseline Missed n Wrnnn Peak___ ,1 13C-PFDOA 615.0/169.0 Da c Baseline Missed n Wrnnn Ppak PFTeA 1 713.0/669.0 Da c Baseline o Missed P' Wrnnn Peak___ 13C-PFDOA 615.0/169.0 Da Baseline Missed n Wrnnn Peak___ Before After 242 Page 32 of 242 Columbia Analytical p. 7 Created with Analyst Reporter Printed: 14/02/2010 6:41:00 PM Ion Ratio Confirmation PFC 10ppb IT PFOA 2 413.0/369.0 Da c Baseline Missed c Wrong Peak 4, .i PFUnA2 563.0/269.0 Da Baseline Missed Wrong Peak I i :l _ 4 :: ` - m ' ` M - i|. 1. PFNA2 463.0/219.0 Da Baseline Missed Wrong Peak PFOS2 499.0/99.0 Da Baseline Missed Wrong Peak PFDA2 513.0/269.0 Da g Baseline c Missed c Wrong Peak 4, - L ........ PFDS2 599.0/99.0 Da Baseline Missed Wrong Peak i:4. Jl *' ',ii ss PFDoA2 613.0/169.0 Da Baseline Missed Wrong Peak I s ......... 5,fc: 9 ......... ........... I i! Ii PFTrA2 663.0/169 0 Da Baseline Missed Wrong Peak PFTeA2 713.0/169.0 Da g Baseline a Missed g Wrong Peak Before After Page 33 of 242 243 Created with A n a ly s f Reporter Printed: 14/02/2010 6:41:00 PM Project Data File Acquisition Method Ewan's ProjectstPFCs 02081 Ob\CalLong.wiff PFCkinetexLong.dam Result Table Algorithm Used Instrument Name 02081 OSamplesLong.rdb IntelliQuan API 5000 Sample Name Acquisition Date Acquisition Method Sample ID Sample Comment PFC 20ppb 2/8/2010 7:00:35 PM PFCkinetexLong.dam LCMS2-85F Injection Vial Injection Volume Sample Type Dilution Factor Weight to Volume 7 5 Standard 1.00 0.00 Results Summary Analyte Name Analyte RT (Expected) PFOA 1 1.35 (1.36) PFNA 1 2.28 (2.42) PFOS 1 2.33 (2.53) PFDA 1 3.30 (3.34) PFUnA 1 4.12(4.06) PFDS 1 4.12(4.10) PFDoA 1 4.76 (4.63) PFTrA 1 5.28 (5.14) PFTeA 1 5.74 (5.74) IS Name 13C-PFOA 13C-PFNA 13C-PFOS 13C-PFDA 13C-PFUnA 13C-PFOS 13C-PFDoA 13C-PFDOA 13C-PFDOA IS Area 2888500 2279400 7033400 2039400 164330 7033400 225670 225670 225670 Analyte Area 2577000 4677900 14114000 4081100 2860500 14304000 2435400 1476200 1021200 Exp Cone (ng/mL) 20.000 20.000 20.000 20.000 20.000 20.000 20.000 20.000 20.000 Calc. Cone (ng/mL) 18.400 Accuracy (%) 92 17.900 90 18.800 94 19.000 95 18.400 92 18.500 93 19.800 99 18.600 93 17.100 85 v/ Mod? No No No No No No No No No 2^/7 'J -K * Page 34 of 242 244 / x Columbia C* J Analytical Services'' IRC Summary Analyte Peak Name PFOA 2 S_13CPFOA PFNA 2 S_13C_PFNA PFOS 2 S_13C-PFOS PFDA2 S_13C-PFDA PFUnA2 S_13C-PFUnA PFDS 2 PFDoA2 S_13C-PFDoA PFTrA 2 PFTeA2 RT (Expected) 1.34(1.36) 1.35(1.36) 2.29 (2.44) 2.29 (2.44) 2.32(2.53) 2.32(2.53) 3.29 (3.34) 3.33 (3.34) 4.11 (4.06) 4.12(4.06) 4.12(4.10) 4.76 (4.64) 4.76 (4.64) 5.28 (5.13) 5.74(5.56) Created with A nalyst^lporter Printed: 14/02/2010 6:41 ;0 PM Area 6202500 2888500 1501800 2279400 4486000 7033400 632970 2039400 656460 164330 4656800 651490 225670 479330 356280 Modified? No No No No No No No No No No No No No No No Calculated Ion Ratio (Expected Value) 2.41 1.12 0.32 0.49 0.32 0.50 0.16 0.50 0.23 0.06 0.33 0.27 0.09 0.32 0.35 Page 35 of 242 245 p. 10 Created with Analyst Reporter Printed: 14/02/2010 6:41:00 PM Quantitative Peak Review 1.35 i 2.28 PFC 20ppb 2.29 PFOA 1 413.0/169.0 Da c Baseline c Missed r- Wronn Peak i 2.33 1 .n .*s ) ii PFOS 1 499.0/80.0 Da c Baseline Missed r. Wronn Peak 4.12 PFUnA 1 563.0/519.0 Da c Baseline Missed n Wronn Poak 13C-PFOA 417.0/372.0 Da Baseline Missed __ n Wronn Peak___ 13C-PFOS 503.0/80.0 Da d Baseline Missed 4^2 i PFNA 1 463.0/419.0 Da o Baseline Missed n Wronn Peak 3.30 i PFDA 1 513.0/469.0 Da Baseline Missed 4^2 1 13C-PFNA 468.0/423.0 Da c Baseline Missed __ n Wronn Peak 13C-PFDA 515.0/470.0 Da c Baseline Missed n Wronn Peak 2.32 4d 45 13C-PFUnA 565.0/270.0 Da Baseline Missed p Wronn Peak 2 lUrb ',G*i a J5 4I 45 On PFDS 1 599.0/80.0 Da Baseline Missed n Wronn Pflflk_____ 1 13C-PFOS 503.0/80.0 Da Baseline Missi p Wronn Peak PFDoA 1 613.0/569.0 Da Baseline c Missed 11 Wronn Peak 5.74 13C-PFDOA 615.0/169.0 Da Baseline Missed p Wronn Peak PFTrA 1 663.0/619.0 Da Baseline Missed ___n Wronn Paak___ *r,L 13C-PFDOA 615.0/169.0 Da Baseline Missed ___ p Wronn Peak PFTeA 1 713.0/669.0 Da c Baseline Missed ___i Wronn Peak 13C-PFDOA 615.0/169.0 Da Baseline Missed ___p Wronn Peak___ Before After 246 Page 36 of 242 Columbia A n alytica l Ion Ratio Confirmation p. 11 Created with Analyst Reporter Printed: 14/02/2010 6:41:00 PM PFC 20ppb PFOA 2 413.0/369.0 Da l Baseline c Missed o Wrong Peak 1 '7 4. r ::::: PFUnA 2 563.0/269.0 Da Baseline Missed c Wrong Peak PFNA2 463.0/219.0 Da c Baseline c Missed Wrong Peak PFOS2 499.0/99.0 Da Baseline Missed c Wrong Peak Lw* .......... 4. i ._______i .... _ PFDS2 599.0/99.0 Da a Baseline Missed Wrong Peak J -5 i[4. 6.. PFDoA2 613.0/169.0 Da Baseline Missed Wrong Peak PFDA2 513.0/269.0 Da Baseline Missed U Wrong Peak PFTrA 2 663.0/169.0 Da Baseline Missed Wrong Peak ?, 5.5 ' 7 ili4 PFTe/k2 713.0/169).0 Da Baseline c: Missed g Wrong Peak Before After Page 37 of 242 247 Columbia Created with A nalysP R ^orter Printed: 14/02/2010 6:41:00 PM Project Data File Acquisition Method Ewan's ProjectsVPFCs 020810b\CalLong.wiff PFCkinetexLong.dam Result Table Algorithm Used Instrument Name 020810SamplesLong.rdb IntelliQuan API 5000 Sample Name Acquisition Date Acquisition Method Sample ID Sample Comment PFC 50ppb 2/8/2010 7:08:10 PM PFCkinetexLong.dam LCMS2-85G Injection Vial Injection Volume Sample Type Dilution Factor Weight to Volume 8 5 Standard 1.00 0.00 Results Summary Analyte Name Analyte RT (Expected) PFOA 1 1.38 (1.36) IS Name 13C-PFOA PFNA 1 2.31 (2.42) 13C-PFNA PFOS 1 2.36 (2.53) 13C-PFOS PFDA 1 3.33 (3.34) 13C-PFDA PFUnA 1 4.12(4.06) 13C-PFUnA PFDS 1 4.12(4.10) 13C-PFOS PFDoA 1 4.76(4.63) 13C-PFDOA PFTrA 1 5.30 (5.14) 13C-PFDOA PFTeA 1 5.73(5.74) 13C-PFDoA IS Area 2896200 2153900 6959900 1935900 163690 6959900 227850 227850 227850 Analyte Area 7236800 12661000 37073000 10412000 7761500 33566000 6008800 3923300 2949500 Exp Cone (ng/mL) 50.000 50.000 50.000 50.000 50.000 50.000 50.000 50.000 50.000 Calc. Cone (ng/mL) 51.500 Accuracy (%) 103 51.300 103 50.000 100 50.900 102 50.300 101 50.500 101 48.500 97 48.900 98 50.800 102 Mod? No No No No No No No No No *^ i / Cs' Page 38 of 242 248 f { C o lu m b ia l L 3 Analytical! Services" IRC Summary Analyte Peak Name PFOA 2 S_13C_PFOA PFNA 2 S_13CPFNA PFOS 2 S_13C-PFOS PFDA 2 S_13C-PFDA PFUnA2 S_13C-PFUnA PFDS 2 PFDoA2 S_13C-PFDoA PFTrA 2 PFTeA2 RT (Expected) 1.38(1.36) 1.38 (1.36) 2.33 (2.44) 2.31 (2.44) 2.36(2.53) 2.36 (2.53) 3.33 (3.34) 3.33 (3.34) 4.12 (4.06) 4.13 (4.06) 4.12(4.10) 4.76 (4.64) 4.75 (4.64) 5.29 (5.13) 5.74 (5.56) Created with Analyi?'f^^porter Printed: 14/02/2010 6:41:00 PM Area 17086000 2896200 3977000 2153900 12374000 6959900 1652600 1935900 1983000 163690 12510000 2079000 227850 1260000 1256900 Modified? No No No No No No No No No No No No No No No Calculated Ion Ratio (Expected Value) 2.36 0.40 0.31 0.17 0.33 0.19 0.16 0.19 0.26 0.02 0.37 0.35 0.04 0.32 0.43 Page 39 of 242 249 VMe /ices" Quantitative Peak Review 1.38 1.38 p. 14 Created with Analyst Reporter Printed: 14/02/2010 6:41:00 PM PFC 50ppb 2.31 2.31 PFOA 1 413.0/169.0 Da Baseline Missed n Wronn Peak 2.36 PFOS 1 499.0/80.0 Da Baseline Missed n Wrnnn Pnak PFUnA 1 563.0/519.0 Da c Baseline Missed __ n Wrnnn Peak___ 13C-PFOA 417.0/372.0 Da Baseline Missed r.,Wronn PrrK | 2.36 1 13C-PFOS 503.0/80.0 Da Baseline Missed n Wrnnn Pnak 4.13 1 13C-PFUnA 565.0/270.0 Da d Baseline d Missed n Wronn Peak .L PFNA 1 463.0/419.0 Da d Baseline Missed n Wrnnn Peak__ '.Ci^.J PFDA 1 513.0/469.0 Da Baseline Missed n Wrnnn Pnak PFDS 1 599.0/80.0 Da c Baseline Missed n Wrnnn Peak 13C-PFNA 468.0/423.0 Da Baseline Missed n Wrnnn Pnak 5.33 1 13C-PFDA 515.0/470.0 Da Baseline Missed n Wrnnn Peak 13C-PFOS 503.0/80.0 Da Baseline Missed n Wrnnn Pnak PFDoA 1 613.0/569.0 Da Baseline o Missed 13C-PFDoA 615.0/169.0 Da Baseline Missed PFTrA 1 663.0/619.0 Da Baseline Missed ____n Wrnnn Peak___ 13C-PFDOA 615.0/169.0 Da o Baseline Missed n Wrnnn Peak___ on i3 [ PFTeA 1 713.0/669.0 Da g Baseline 0 Missed n Wrnnn Peak 13C-PFDoA 615.0/169.0 Da c Baseline 0 Missed n Wrnnn Pnak Before After Page 40 of 242 250 /% C b iu ttlb lB l L 4 Analytical Services" Created with AnalysIPf^Dorter Printed: 14/02/2010 6:41:00 PM Ion Ratio Confirmation ...: 1.38 :i I k. Aj "I H ....... ................... PFOA2 413.0/369.0 Da d Baseline Missed Wrong Peak PFNA 2 463.0/219.0 Da c Baseline Missed Wrong Peak PFC 50ppb | &4 .. ...... N - 4 -- PFOS2 499.0/99.0 Da Baseline Missed Wrong Peak PFDA2 513.0/269.0 Da Baseline Missed Wrong Peak PFUnA2 563.0/269.0 Da c Baseline Missed c Wrong Peak PFDS 2 599.0/99.0 Da Baseline Missed Wrong Peak PFDoA2 613.0/169.0 Da Baseline Missed o Wrong Peak PFTrA 2 663.0/169.0 Da Baseline c Missed Wrong Peak PFTeA2 713.0/169.0 Da Baseline u Missed Wrong Peak Before After Page 41 o f 242 251 p. 16 Created with Analyst Reporter Printed: 14/02/2010 6:41:00 PM Project Data File Acquisition Method Ewan's Projects\PFCs 020810b\CalLong.wiff PFCkinetexLong.dam Result Table Algorithm Used Instrument Name 02081 OSamplesLong.rdb IntelliQuan API 5000 Sample Name Acquisition Date Acquisition Method Sample ID Sample Comment PFC 20ppb ICV 2/8/2010 7:30:54 PM PFCkinetexLong.dam LCMS2-77J Injection Vial Injection Volume Sample Type Dilution Factor Weight to Volume 9 5 Quality Control 1.00 0.00 Results Summary Analyte Name Analyte RT (Expected) PFOA 1 1.38(1.36) IS Name 13C-PFOA PFNA 1 2.33(2.42) 13C-PFNA PFOS 1 2.36 (2.53) 13C-PFOS PFDA1 3.33(3.34) 13C-PFDA PFUnA 1 4.11 (4.06) 13C-PFUnA PFDS 1 4.12(4.10) 13C-PFOS PFDoA 1 4.76 (4.63) 13C-PFDOA PFTrA 1 5.29 (5.14) 13C-PFDOA PFTeA 1 5.74 (5.74) 13C-PFDOA IS Area 2771800 2335500 6969700 1968300 154400 6969700 217390 217390 217390 Analyte Area 2843400 5206100 15447000 4333800 3245900 15777000 2671400 1712600 1043200 Exp Cone (ng/mL) 20.000 20.000 20.000 20.000 20.000 20.000 20.000 20.000 20.000 Calc. Cone (ng/mL) 21.200 Accuracy (%) 106 19.500 97 20.800 104 20.900 104 22.300 111 20.800 104 22.600 113 22.400 112 18.100 91 j Mod? No No No No No No No No No -A i1 '^7 /(U "< Page 46 of 242 252 la IRC Summary Analyte Peak Name PFOA2 S_13C_PFOA PFNA2 S_13C_PFNA PFOS2 S_13C-PFOS PFDA2 S_13C-PFDA PFUnA2 S_13C-PFUnA PFDS2 PFDoA2 S_13C-PFDoA PFTrA 2 PFTeA2 Created with A nalysP R ^orter Printed: 14/02/2010 6:41:00 PM RT (Exp RT ) 1.39 (1.36) 1.40(1.36) 2.33 (2.44) 2.31 (2.44) 2.37 (2.53) 2.36 (2.53) 3.33 (3.34) 3.32(3.34) 4.13(4.06) 4.12 (4.06) 4.12(4.10) 4.77 (4.64) 4.75 (4.64) 5.29 (5.13) 5.74 (5.56) Area 6554000 2771800 1566300 2335500 4995900 6969700 656620 1968300 755100 154400 5118100 808950 217390 600370 411830 Modified? No No No No No No No No No No No No No No No Ratio Confirms ID YES No YES No YES No YES No YES No YES YES No YES YES Page 47 of 242 253 Created with AnalysPR*eporter Printed: 14/02/2010 6:41:00 PM Quantitative Peak Review i138 i1.40 PFOA 1 413.0/169.0 Da g Baseline o Missed r Wrnnn Peak 13C-PFOA 417.0/372.0 Da Baseline Missed ___n Wrnnn Peak___ l PFOS 1 499.0/80.0 Da c Baseline Missed n Wrnnn Peak 13C-PFOS 503.0/80.0 Da a Baseline a Missed n. Wrnnn Peak 4.12 PFC 20ppb ICV 1i 2,31 PFNA 1 463.0/419.0 Da Baseline Missed in Wrnnn Pnak 3.33 ; 4*5 13C-PFNA 468.0/423.0 Da Baseline Missed ___n Wrnnn Peak___ PFDA 1 513.0/469.0 Da Baseline a Missed n Wrnnn Peak 13C-PFDA 515.0/470.0 Da Baseline Missed n Wrnnn Peak PFUnA 1 563.0/519.0 Da c Baseline d Missed ___r Wrnnn Peak__ PFDoA 1 613.0/569.0 Da Baseline Missed r Wrnnn Peak 5.74 13C-PFUnA 565.0/270.0 Da Baseline Missed ___ n Wrnnn Peak -,.4 1 13C-PFDOA 615.0/169.0 Da Baseline Missed n Wrnnn Peak 4.7 tn PFDS 1 599.0/80.0 Da Baseline Missed ___ n Wrnnn Peak 5.29 4e?. l 13C-PFOS 503.0/80.0 Da Baseline Missed ___n Wrnnn Peak___ r)Oj 7 J*4 PFTrA 1 663.0/619.0 Da o Baseline Missed ____n Wrnnn Peak___ 13C-PFDOA 615.0/169.0 Da Baseline u Missed ___n Wrnnn Peak___ PFTeA 1 713.0/669.0 Da Baseline Missed ___ n Wrnnn Peak___ 13C-PFDOA 615.0/169.0 Da Baseline Missed n Wrnnn Peak Before After 254 Page 48 of 242 Columbia Analytical Ion Ratio Confirmation 1.39 Created with AnalystRR&fiorter Printed: 14/02/2010 6:41:00 PM PFC 20ppb ICV i PFOA2 413.0/369.0 Da c Baseline Missed d Wrong Peak PFUnA 2 563.0/269.0 Da a Baseline Missed Wrong Peak PFNA2 463.0/219.0 Da Baseline o Missed o Wrong Peak ..4. 12- L PFDS 2 599.0/99.0 Da Baseline Missed Wrong Peak PFOS 2 499.0/99.0 Da Baseline Missed Wrong Peak i*'i 4', ? X*- 4. 7 ________ L _ PFDoA2 613.0/169.0 Da Baseline Missed o Wrong Peak PFDA2 513.0/269.0 Da Baseline Missed Wrong Peak "i !. "i f 'H - 5 . PFTrA2 663.0/169.0 Da Baseline Missed Wrong Peak : = .1 '4 : `: L _ J I PFTe/\ 2 713.0/16$3.0 Da Baseline j Missed c Wrong Peak Before After Page 49 of 242 255 Created with Analyst importer Printed: 15/02/2010 2:34:00 PM Analyte Name: Internal Standard: PFBA 1 13C-PFBA Data File Acquisition Date Acquisition Method Project 020810\CalShort.wiff 2/9/2010 3:06:42 AM PFCkinetexShort.dam Ewan's Projects\PFCs Result Table Algorithm Used Instrument Name 02081 OSamplesShortedit.rdb IntelliQuan API 5000 Regression Equation:________y = 0.106 x + 0.00604 (r = 0.9986; Exp Cone (ng/mL) # of Values Mean Calc Cone (ng/mL) 0.1 1 0.09 0.5 1 0.49 1 1 1.05 5 1 5.33 10 1 11.09 20 1 18.67 50 1 49.88 % Accuracy 87 98 105 107 111 93 100 / STD NaN NaN NaN NaN NaN NaN NaN %CV NaN NaN NaN NaN NaN NaN NaN u Page 1 of 245 256 JT 'f C o fe ltn ljis t i Analytical Services" Created with AnalyV Importer Printed; 15/02/2010 2;34:00 PM Analyte Name; Internal Standard: PFPeA 1 13C-PFHxA Data File Acquisition Date Acquisition Method Project 020810\CalShort.wiff 2/9/2010 3:06:42 AM PFCkinetexShort.dam Ewan's Projects\PFCs Result Table Algorithm Used Instrument Name 02081 OSamplesShortedit.rdb IntelliQuan API 5000 Regression Equation: Exp Cone (ng/mL) 0.1 0.5 1 5 10 20 50 y = 0.0955 x + 0.002 (r = 0.9976) # of Values Mean Calc Cone (ng/mL) 1 0.07 1 0.49 1 1.10 1 5.50 1 11.59 1 19.02 1 48.83 % Accuracy 73 99 110 110 116 95 98 7 STD NaN NaN NaN NaN NaN NaN NaN %CV NaN NaN NaN NaN NaN NaN NaN Page 2 o f 245 257  Columbia J & Analytical Services" Createci with Anal^t^^eporter Printed: 15/02/2010 2:34:00 PM Analyte Name: Internal Standard: PFBS 1 180-PFHS Data Fife Acquisition Date Acquisition Method Project Regression Equation: Exp Cone (ng/mL) 0.1 0.5 1 5 10 20 50 020810\CalShort.wiff 2/9/2010 3:06:42 AM PFCkinetexShort.dam Ewan's Projects\PFCs Result Table Algorithm Used Instrument Name 02081 OSamplesShortedit.rdb IntelliQuan API 5000 J y = -0.00191 xA2 + 0.354 x + -0.00625 (r = 0.9989) # of Values Mean Calc Cone (ng/mL) % Accuracy STD %CV 1 0.09 94 NaN NaN 1 0.49 99 NaN NaN 1 1.03 103 NaN NaN 1 5.16 103 NaN NaN 1 10.75 107 NaN NaN 1 18.57 93 NaN NaN 1 50.67 101 NaN NaN / X .X y 13 14 15 16 17 16 IS ! t 21 23 24 25 ?6 27 26 2S 31 32 33 34 35 K Aneliti'Zone/ISCone AX Page 3 of 245 258 lymbia S trvfe ftr Created with AnaiyS' Importer Printed: 15/02/2010 2:34:00 PM Analyte Name: Internal Standard: PFHxA 1 13C-PFHxA Data File Acquisition Date Acquisition Method Project 020810\CalShort.wiff 2/9/2010 3:06:42 AM PFCkinetexShort.dam Ewan's Projects\PFCs Result Table Algorithm Used Instrument Name 02081 OSamplesShortedit.rdb IntelliQuan API 5000 Regression Equation: Exp Cone (ng/mL) 0.1 0.5 1 5 10 20 50 y = -0.000377 xA2 + 0.108 x + 0.00572 (r = 0.9988) # of Values Mean Calc Cone (ng/mL) % Accuracy 1 0.10 97 1 0.49 98 1 1.01 101 1 5.09 102 1 10.91 109 1 18.56 93 1 50.50 101 7 STD NaN NaN NaN NaN NaN NaN NaN %CV NaN NaN NaN NaN NaN NaN NaN Page 4 of 245 259 Created with Anal^Ps't^feporter Printed: 15/02/2010 2:34:00 PM Analyte Name: Internal Standard: PFHpA 1 13C-PFHxA Data File Acquisition Date Acquisition Method Project Regression Equation: Exp Cone (ng/mL) 0.1 0.5 1 5 10 20 50 020810\CalShort.wiff 2/9/2010 3:06:42 AM PFCkinetexShort.dam Ewan's Projects\PFCs Result Table Algorithm Used Instrument Name 02081 OSamplesShortedit.rdb IntelliQuan API 5000 y = -1,93e-005 xA2 + 0.0388 x + 0.00229 (r = 0.9986) / # of Values Mean Calc Cone (ng/mL) % Accuracy 1 0.09 94 1 0.51 101 1 0.96 96 1 5.32 106 1 10.88 109 1 18.39 92 1 50.45 10} STD NaN NaN NaN NaN NaN NaN NaN %CV NaN NaN NaN NaN NaN NaN NaN ~2^(( Page 5 of 245 260 Created with AnalyiV F^lporter Printed: 15/02/2010 2:34:00 PM Analyte Name: Internal Standard: PFHxS 1 180-PFHS Data File Acquisition Date Acquisition Method Project Regression Equation: Exp Cone (ng/mL) 0.1 0.5 1 5 10 20 50 020810\CalShort.wiff Result Table 02081 OSamplesShortedit.rdb 2/9/2010 3:06:42 AM Algorithm Used IntelliQuan PFCkinetexShort.dam Instrument Name API 5000 Ewan's ProjectsVPFCs 7y = -0.00198 xA2+ 0.335 x + 0.00261 (r = 0.9986) * " # of Values Mean Calc Cone (ng/mL) % Accuracy STD %CV 1 0.10 97 NaN NaN 1 0.48 95 NaN NaN 1 1.03 103 NaN NaN 1 5.09 102 NaN NaN 1 10.91 109 NaN NaN 1 18.44 92 NaN NaN 1 50.77 102/ NaN NaN S y s' * s' u i; ie i? 20 25 K 27 M 3l !? 33 3 35 Jfi O 35 ^ l ( b rite Page 6 of 245 261 S e rv ic e s " Created with Analyst Reporter Printed: 15/02/2010 2:34:00 PM Project Data File Result Table Instrument Name Ewan's Projects\PFCs 020810\CalShort.wiff 02081 OSamplesShortedit.rdb API 5000 Sample Name Acquisition Date Acquisition Method Injection Vial IB 2/9/2010 3:06:42 AM PFCkinetexShort.dam 1 Injection Volume Sample Type Dilution Factor Weight to Volume 5 Unknown 1.00 0.00 Results Summary Analyte Peak Name IS Name PFBA 1 13C-PFBA PFPeA 1 13C-PFHXA PFBS 1 180-PFHS PFHxA 1 13C-PFHXA PFHpA 1 13C-PFHXA PFHxS 1 180-PFHS SJ80-PFHS 13C-PFDA SJ3C-PFDA 13C-PFDA IS Area 0 0 0 0 0 0 0 0 Analyte RT (Exp RT ) 0.00(1.27) 0.00 (3.60) 0.00 (4.26) 5.34 (5.31) 6.23 (6.23) 0.00 (6.32) 0.00 (6.31) 0.00(7.65) Analyte Area 0 0 0 44083 13368 0 0 0 Calc. Cone (ng/mL) N/A N/A N/A N/A N/A N/A N/A N/A Modified? No No No No No No No No 262 Created with Analy^'F^eporter Printed: 15/02/2010 2:34:00 PM IRC Summary Analyte Peak Name PFBA2 PFPeA2 PFBS2 PFHxA 2 PFHpA2 PFHxS2 S_13C-PFBA S_13C-PFHxA RT (Exp R T ) 0.00(1.27) 0.00 (3.60) 0.00(4.26) 0.00 (5.31) 6.23 (6.22) 0.00 (6.32) 0.00(1.26) 0.00(5.30) Area 0 0 0 0 29758 0 0 0 Modified? No Calc (Exp) MRM Ratio 0.00(1.00) Ratio Confirms ID No No 0.00(1.00) No No 0.00 (0.40) No No 0.00 (0.10) No No 2.23 (3.03) No No 0.00 (0.40) No No 0.00(13.55) No No 0.00(13.06) No Page 10 of 245 263 Quantitative Peak Review p. 28 Created with Analyst Reporter Printed: 15/02/2010 2:34:00 PM IB PFBA? 213.0/169.0 Da Baseline Missed n Wrnnn Peak 13C-PFBA 217.0/172.0 Da d Baseline Missed n Wrnnn Pftak 40 45 PFPeA 1 263.0/219.0 Da d Baseline Missed n Wrnnn Pftak 13C-PFHXA 315.0/270.0 Da Baseline Missed n Wrnnn Pftak PFBS 1 299.0/80.0 Da Baseline Missed n Wrnnn Peak . i6.23 *1 55 50 55 PFHpA 1 363.0/169.0 Da Baseline Missed n Wrnnn Peak j | 180-PFHS 403.0/103.0 Da Baseline Missed n Wrnnn Paak 13C-PFHxA 315.0/270.0 Da c Baseline Missed n Wrnnn Paak 55 50 PFHxA 1 313.0/269.0 Da Baseline Missed n Wrnnn Peak 45 50 55 60 13C-PFHXA 315.0/270.0 Da Baseline Missed n Wrnnn Paak 55 50 G5 70 PFHxs"l 399.0/80.0 Da Baseline o Missed n Wrnnn Peak 55 50 55 T m mm 180-PFHS 7u 403.0/103.0 Da Baseline Missed n Wrnnn Peak 55 bfl SJ80-PFHS 403.0/103.0 Da Baseline Missed n Wrnnn Peak___ 7 0 75 13C-PFDA 515.0/470.0 Da Baseline Missed ____n Wrnnn Peak___ S_13C-PFDA 515.0/470.0 Da Baseline Missed n Wrnnn Peak___ Before After 13C-PFDA 515.0/470.0 Da u Baseline Missed n Wrnnn Peak___ Page 11 o f 245 264 Ion Ratio Confirmation Created with Analyst'F?fporter Printed: 15/02/2010 2:34:00 PM IB PFBA2 213.0/169.0 Da Baseline c Missed Wrong Peak PFPeA2 263.0/219.0 Da Baseline Missed o Wrong Peak PFBS2 299.0/99.0 Da Baseline Missed Wrong Peak PFHxA 2 313.0/119.0 Da Baseline Missed Wrong Peak ferriage isrd av# le PFHpA2 363.0/319.0 Da Baseline Missed d Wrong Peak PFHxS2 399.0/99.0 Da Baseline Missed Wrong Peak S_13C-PFDA 515.0/470.0 Da Baseline Missed Wrong Peak NB. PFBA and PFPeA do not have qualifying ion transitions. Before After N/A Baseline Missed Wrong Peak Page 12 o f 245 265 p. 30 Created with Analyst Reporter Printed: 15/02/2010 2:34:00 PM Project Data File Acquisition Method Ewan's Projects\PFCs 020810\CalShort.wiff PFCkinetexShort.dam Result Table Algorithm Used Instrument Name 02081 OSamplesShortedit.rdb IntelliQuan API 5000 Sample Name Acquisition Date Acquisition Method Sample ID Sample Comment PFC 0.10ppb 2/9/2010 3:35:22 AM PFCkinetexShort.dam LCMS2-85A Injection Vial Injection Volume Sample Type Dilution Factor Weight to Vojume 2 5 Standard 1.00 0.00 Results Summary Analyte Name Analyte RT (Expected) PFBA1 1.26 (1.27) PFPeA 1 3.60 (3.60) PFBS 1 4.26 (4.26) PFHxA 1 5.31 (5.31) PFHpA 1 6.24 (6.23) PFHxS 1 S 180PFHS S 13CPFDA 6.33 (6.32) 6.33(6.31) 7.68 (7.65) IS Name 13C-PFBA 13C-PFHxA 180-PFHS 13C-PFHxA 13C-PFHxA 180-PFHS 13C-PFDA 13C-PFDA IS Area 4200800 4591100 2619300 4591100 4591100 2619300 2744000 2744000 Analyte Area 63935 41155 71072 73959 27344 91988 2619300 2744000 Exp Cone (ng/mL) 0.10 0.10 0.10 0.10 0.10 0.10 1.00 1.00 Calc. Cone (ng/mL) 0.09 Accuracy <%) 87 0.07 73 0.09 0.10 0.09 0.10 94 97 95 97 1.08 108 1.00 100 Mod? NO No No No No No No No z J ^ U Page 13 of 245 266 Columbia IRC Summary Analyte Peak Name PFBA2 PFPeA2 PFBS 2 PFHxA2 PFHpA2 PFHxS2 S_13C-PFBA S_13C-PFHxA p. 31 Created with Analyst Reporter Printed: 15/02/2010 2:34:00 PM RT (Expected) 1.26(1.27) 3.60 (3.60) 4.26 (4.26) 5.31 (5.31) 6.24(6.22) 6.33 (6.32) 1.26(1.26) 5.31 (5.30) Area 63935 41155 28769 7450 74839 36235 4200800 4591100 Modified? No No No No No No No No Calculated Ion Ratio (Expected Value) 1.00 1.00 0.40 0.10 2.74 0.39 65.70 62.08 Page 14 of 245 267 S e rv ic e s " Quantitative Peak Review p. 32 Created with Analyst Reporter Printed: 15/02/2010 2:34:00 PM PFC O.IOppb PFBA 1 213.0/169.0 Da Baseline Missed n Wrnnn Peak 13C-PFBA 217.0/172.0 Da Baseline Missed i Wrnnn Pnak PFBS 1 299.0/80.0 Da Baseline Missed n Wrnnn Peak 180-PFHS 403.0/103.0 Da Baseline Missed n Wrnnn Peak PFPeA 1 263.0/219.0 Da Baseline Missed n Wrnnn Peak 13C-PFHxA 315.0/270.0 Da Baseline g Missed n Wrnnn Peak ioe Bte5 | PteS S 4IX* PFHxA 1 313.0/269.0 Da Baseline Missed n Wrnnn Peak 13C-PFHXA 315.0/270.0 Da a Baseline Missed n Wrnnn Peak PFHpA 1 363.0/169.0 Da Baseline Missed n Wrnnn Peak 13C-PFHxA 315.0/270.0 Da d Baseline Missed n Wrong Peak PFHxS 1 399.0/80.0 Da Baseline Missed n3^ZEQQfl_ESk_ 180-PFHS 403.0/103.0 Da Baseline Missed Wrnnn S_180-PFHS 403.0/103.0 Da Baseline Missed ____n Wrnnn Peak___ 13C-PFDA 515.0/470.0 Da o Baseline o Missed n Wrnnn Peak___ Before After S_13C-PFDA 515.0/470.0 Da Baseline Missed n Wrnnn Peak 13C-PFDA 515.0/470.0 Da d Baseline Missed ___n Wrnnn Peak___ Page 15 of 245 268 Created with A n a ly s ^ ip o rte r Printed: 15/02/2010 2:34:00 PM Ion Ratio Confirmation PFC 0.10ppb 1 PFBA2 213.0/169.0 Da Baseline Missed a Wrong Peak PFPeA2 263.0/219.0 Da Baseline a Missed Wrong Peak PFBS2 299.0/99.0 Da o Baseline Missed Wrong Peak PFHxA 2 313.0/119.0 Da Baseline Missed Wrong Peak PFHpA2 363.0/319.0 Da Baseline Missed Wrong Peak PFHxS2 399.0/99.0 Da Baseline c Missed d Wrong Peak S_13C-PFDA 515.0/470.0 Da Baseline Missed Wrong Peak NB. PFBA and PFPeA do not have qualifying ion transitions. Before After N/A o Baseline Missed Wrong Peak Page 16 o f 245 269 p. 34 Created with Analyst Reporter Printed: 15/02/2010 2:34:00 PM Project Data File Acquisition Method Ewan's Projects\PFCs 020810\CalShort.wiff PFCkinetexShort.dam Result Table Algorithm Used Instrument Name 02081 OSamplesShortedit.rdb IntelliQuan API 5000 Sample Name Acquisition Date Acquisition Method Sampfe ID Sample Comment PFC 0.5ppb 2/9/2010 3:44:57 AM PFCkinetexShort.dam LCMS2-85B Injection Vial Injection Volume Sample Type Dilution Factor Weight to Volume 3 5 Standard 1.00 0.00 Results Summary Analyte Name Analyte RT (Expected) PFBA 1 1.26(1.27) PFPeA 1 3.60 (3.60) PFBS 1 4.26 (4.26) PFHxA 1 5.31 (5.31) PFHpA 1 6.24 (6.23) PFHxS 1 S 180PFHS S 13CPFDA 6.33(6.32) 6.33(6.31) 7.68 (7.65) IS Name 13C-PFBA 13C-PFHxA 180-PFHS 13C-PFHXA 13C-PFHxA 180-PFHS 13C-PFDA 13C-PFDA IS Area 4133000 4554300 2687100 4554300 4554300 2687100 2965500 2965500 Analyte Area 238600 223910 450860 266230 100000 434270 2687100 2965500 Exp Cone (ng/mL) 0.50 0.50 0.50 0.50 0.50 0.50 1.00 1.00 Calc. Cone (ng/mL) 0.49 Accuracy (%) 98 0.49 99 0.49 99 0.49 98 0.51 101 0.48 95 1.03 103 1.00 100 Mod? No No No No No No No No v & Page 17 o f 245 270 IRC Summary Analyte Peak Name PFBA2 PFPeA2 PFBS 2 PFHxA2 PFHpA2 PFHxS2 S_13C-PFBA S_13C-PFHxA Created with A naly^'fleporter Printed: 15/02/2010 2:34:00 PM RT (Expected) 1.26 (1.27) 3.60 (3.60) 4.26 (4.26) 5.31 (5.31) 6.23 (6.22) 6.33 (6.32) 1.26(1.26) 5.31 (5.30) Area 238600 223910 167620 24915 350840 165980 4133000 4554300 Modified? No No No No No No No No Calculated Ion Ratio (Expected Value) 1.00 1.00 0.37 0.09 3.51 0.38 17.32 17.11 Page 18 of 245 271 Quantitative Peak Review p. 36 Created with Analyst Reporter Printed: 15/02/2010 2:34:00 PM PFC 0.5ppb Tim* iw PFBA 1 213.0/169.0 Da g Baseline c Missed n Wrnnn Peak 13C-PFBA 217.0/172.0 Da o Baseline Missed n Wrnnn Peak PFPeA 1 263.0/219.0 Da Baseline Missed n Wrnnn Peak ifl ss e,a 13C-PFHxA 315.0/270.0 Da Baseline o Missed n Wrnnn Poak PFBS 1 299.0/80.0 Da Baseline Missed n Wrnnn Peak 180-PFHS 403.0/103.0 Da o Baseline o Missed n Wrnnn Psak Tim* mm PFHxA 1 313.0/269.0 Da d Baseline Missed n Wrnnn Peak 13C -P F H X A 315.0/270.0 Da Baseline Missed n Wrnnn Peak PFHpA 1 363.0/169.0 Da Baseline Missed n Wrnnn Peak 13C-PFHxA 315.0/270.0 Da d Baseline o Missed n Wrnnn Peak PFHxS 1 399.0/80.0 Da Baseline a Missed n Wronn Peak 180-PFHS 403.0/103.0 Da Baseline Missed n Wrnnn Peak SJ80-PFHS 403.0/103.0 Da Baseline Missed ___n Wrnnn Peak 13C-PFDA 515.0/470.0 Da Baseline Missed ___ n Wrnnn Peak___ SJ3C-PFDA 515.0/470.0 Da Baseline d Missed ___ n Wrnnn Paak Before After 13C-PFDA 515.0/470.0 Da a Baseline Missed n Wrnnn Peak___ Page 19 of 245 272 S e rv ic e s " p. 37 Created with Analyst Reporter Printed: 15/02/2010 2:34:00 PM Ion Ratio Confirmation PFBA2 213.0/169.0 Da Baseline Missed Wrong Peak 3.60 - I PFPeA2 263.0/219.0 Da Baseline Missed Wrong Peak PFC 0.5ppb 4.16-- PFBS2 299.0/99.0 Da Baseline Missed Wrong Peak PFHxA 2 313.0/119.0 Da a Baseline Missed Wrong Peak 6.- Thisirageisnotavaiable PFHpA2 363.0/319.0 Da Baseline Missed Wrong Peak PFHxS2 399.0/99.0 Da Baseline Missed d Wrong Peak S_13C-PFDA 515.0/470.0 Da Baseline Missed Wrong Peak NB. PFBA and PFPeA do not have qualifying ion transitions. Before After N/A Baseline Missed Wrong Peak Page 20 of 245 273 p. 38 Created with Analyst Reporter Printed: 15/02/2010 2:34:00 PM Project Data File Acquisition Method Ewan's Projects\PFCs 020810\CalShort.wiff PFCkinetexShort.dam Result Table Algorithm Used Instrument Name 02081 OSamplesShortedit.rdb IntelliQuan API 5000 Sample Name Acquisition Date Acquisition Method Sample ID Sample Comment PFC 1.Oppb 2/9/2010 3:54:29 AM PFCkinetexShort.dam LCMS2-85C Injection Vial Injection Volume ' Sample Type Dilution Factor Weight to Volume 4 5 Standard 1.00 0.00 Results Summary ?Analyte Name Analyte RT (Expected) PFBA1 1.27 (1.27) IS Name 13C-PFBA IS Area 4089300 PFPeA 1 3.60 (3.60) 13C-PFHxA 4523600 PFBS 1 4.26 (4.26) 180-PFHS 2661400 PFHxA 1 5.31 (5.31) 13C-PFHXA 4523600 PFHpA 1 6.23 (6.23) 13C-PFHxA 4523600 PFHxS 1 S 180PFHS S 13CPFDA 6.32(6.32) 6.32 (6.31) 7.66(7.65) 180-PFHS 13C-PFDA 13C-PFDA 2661400 2843300 2843300 Analyte Area 478990 483470 944980 514540 179220 920280 2661400 2843300 Exp Cone (ng/mL) 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 Calc. Cone (ng/mL) 1.05 Accuracy (%) 105 1.10 110 1.03 103 1.01 0.96 1.03 101 96 103 1.06 106 1.00 100 Mod? No No No No No No No No Page 21 of 245 274 IRC Summary Analyte Peak Name PFBA 2 PFPeA2 PFBS 2 PFHxA2 PFHpA2 PFHxS2 S_13C-PFBA S_13C-PFHxA Created with AnalysPReporter Printed: 15/02/2010 2:34:00 PM RT (Expected) 1.27(1.27) 3.60 (3.60) 4.26 (4.26) 5.31 (5.31) 6.23 (6.22) 6.32 (6.32) 1.26(1.26) 5.31 (5.30) Area 478990 483470 352080 47014 664500 341970 4089300 4523600 Modified? No No No No No No No No Calculated Ion Ratio (Expected Value) 1.00 1.00 0.37 0.09 3.71 0.37 8.54 8.79 Page 22 o f 245 275 Services" p. 40 Created with Analyst Reporter Printed: 15/02/2010 2:34:00 PM Quantitative Peak Review 4 7*4 r+4 '" 1 I S 5 i| Je5 X ., 1*5 1 .^ bD*4_._L_ I:OeS 6 0*1 f J 404 20*4 3.60 PFC 1.0ppb 10*6 8 80,5 | 6.0*5 40*5 :o*5 05 0 15 PFBA 7 ;-o 213.0/169.0 Da C Baseline a Missed n Wrnnn Peak 4.^6 i s*5 5 | l es 50*4 35 40 45 50 T*m mm PFBS 1 299.0/80.0 Da Baseline Missed n Wrnnn Peak .: 'r t*< I ... 6[ (Mil 55 60 65 ?fi 05 '0 15 Tun*, mm 13C-PFBA 20 217.0/172.0 Da c Baseline a Missed n Wrnnn Peak B#S 7*5 6*5 e 5*5 * .6 1 ?5 1*5 1 65 60 65 Tim, mm 180-PFHS 70 403.0/103.0 Da Baseline Missed n Wrnnn Peak 12*6 13*4 S 86*5 i 6 0*5 S 4 3*5 15.31 45 50 55 60 JO 35 40 <5 45 50 55 60 PFPeAl 263.0/219.0 Da Baseline Missed n Wrnnn Peak 5.31 io*$ & i 46 6U 56 60 13C-PFHXA 315.0/270.0 Da Baseline Missed _____ n Wrnnn Peak_____ 12*6 10*6 s 60*6 4(MS 2 0*5 I 45 6 6 55 611 PFHx a I 313.0/269.0 Da Q Baseline Missed n Wrnnn Peak 25*5 6.^2 ! -.5*5 I 1 10.5 50*4 55 60 65 70 13C-PFHxA 315.0/270.0 Da Baseline Missed n Wrnnn Peak m5 7*5 6.32 6*5 fr 5.5 i r 4.5 I 1(5 55 l 60 65 70 PFHpAl 363.0/169.0 Da Baseline Missed r Wrnnn Peak W5 '5 6*5 jv ss > 4.5 1 7*5 1.0 I 13C-PFHxA 315.0/270.0 Da Baseline a Missed n Wrnnn Peak 7#5 6.5 e s*s % 46 f !*S 2*5 1*5 I P F H x i"i 399.0/80.0 Da Baseline Missed n Wrnnn Peak t*5 7.^6 7*5 6.5 f J 3*5 2.5 1*5 180-PFHS 403.0/103.0 Da Baseline Missed n Wrnnn Peak 8*5 7*5 6.5 & 5*5 t "*5 X 7*5 2*5 1.5 t7.66 51 6 65 ?<l 70 75 80 65 70 75 a.0 5 70 >S 90 85 S_180-PFHS 403.0/103.0 Da Baseline Missed n Wrnnn Peak_____ 13C-PFDA 515.0/470.0 Da Baseline Missed n Wrnnn Peak_____ S 13C-PFDA 515.0/470.0 Da o Baseline Missed n Wrnnn Peak 13C-PFDA 515.0/470.0 Da Baseline Missed n Wrnnn Peak Before After Page 23 of 245 276 f % C o lu m b ia Analytical ServiaK" p. 41 Created with Analyst Reporter Printed: 15/02/2010 2:34:00 PM Ion Ratio Confirmation 1.27 3:60 PFC 1.0ppb PFBA2 213.0/169.0 Da a Baseline Missed Wrong Peak :on CArf 1 PFPeA2 263.0/219.0 Da Baseline Missed d Wrong Peak PFBS2 299.0/99.0 Da Baseline d Missed Wrong Peak PFHxA 2 313.0/119.0 Da d Baseline Missed Wrong Peak s SCtH PFHpA2 363.0/319.0 Da Baseline Missed Wrong Peak ooo Tima mtn PFHxS2 399.0/99.0 Da Baseline Missed Wrong Peak S_13C-PFDA 515.0/470.0 Da Baseline Missed Wrong Peak NB. PFBA and PFPeA do not have qualifying ion transitions. Before After N/A Baseline Missed Wrong Peak Page 24 of 245 277 p. 42 Created with Analyst Reporter Printed: 15/02/2010 2:34:00 PM K Project Data File Acquisition Method Ewan's Projects\PFCs 020810\CalShort.wiff PFCkinetexShort.dam Result Table Algorithm Used Instrument Name 02081 OSamplesShortedit.rdb IntelliQuan API 5000 Sample Name Acquisition Date Acquisition Method Sample ID Sample Comment PFC 5.0ppb 2/9/2010 4:04:01 AM PFCkinetexShort.dam LCMS2-85D Injection Vial Injection Volume Sample Type Dilution Factor Weight to Volume 5 5 Standard 1.00 0.00 Results Summary Analyte Name Analyte RT (Expected) PFBA1 1.27 (1.27) IS Name 13C-PFBA IS Area 4014300 PFPeA 1 3.60 (3.60) 13C-PFHxA 4518700 PFBS 1 4.26 (4.26) 180-PFHS 2647300 PFHxA 1 5.31 (5.31) 13C-PFHxA 4518700 PFHpA 1 6.22 (6.23) 13C-PFHxA 4518700 PFHxS 1 S 180PFHS S 13CPFDA 6.32 (6.32) 6.32 (6.31) 7.66 (7.65) 180-PFHS 13C-PFDA 13C-PFDA 2647300 3213800 3213800 Analyte Area 2290700 2382800 4686000 2458900 941350 4379000 2647300 3213800 Exp Cone (ng/mL) 5.00 5.00 5.00 5.00 5.00 5.00 1.00 1.00 Calc. Cone (ng/mL) 5.33 Accuracy {%) 107 5.50 110 5.16 5.09 103 102 5.32 5.09 106 102 0.93 93 1.00 100 Mod? No No No No No No No No 4 (iO 1? J ib Page 25 of 245 278 IRC Summary Analyte Peak Name PFBA2 PFPeA2 PFBS 2 PFHxA2 PFHpA2 PFHxS2 SJ3C-PFBA S_13C-PFHxA p. 43 Created with Analyst Reporter Printed: 15/02/2010 2:34:00 PM RT (Expected) 1.27(1.27) 3.60 (3.60) 4.26 (4.26) 5.31 (5.31) 6.22 (6.22) 6.32 (6.32) 1.27 (1.26) 5.31 (5.30) Area 2290700 2382800 1791000 225570 2709700 1657900 4014300 4518700 Modified? No No No No No No No No Calculated Ion Ratio (Expected Value) 1.00 1.00 0.38 0.09 2.88 0.38 1.75 1.84 Page 26 o f 245 279 Quantitative Peak Review p. 44 Created with Analyst Reporter Printed: 15/02/2010 2:34:00 PM PFC 5.0ppb PFBA 1 213.0/169.0 Da Baseiine Missed n Wrnnn Peak 13C-PFBA 217.0/172.0 Da Baseline Missed n Wrnnn Peak PFPeA 1 263.0/219.0 Da Baseline Missed n Wrnnn Peak 13C-PFHXA 315.0/270.0 Da Baseline Missed n Wrnnn Peak PFBS 7 299.0/80.0 Da Baseline Missed n Wrnnn Peak 180-PFHS 403.0/103.0 Da Baseline Missed n Wrnnn Peak PFHxATMi 313.0/269.0 Da a Baseline Missed n Wrnnn Peak 13C-PFHxA 315.0/270.0 Da Baseline Missed -Wrong Peak PFHpA 1 363.0/169.0 Da o Baseline Missed n Wrnnn Peak 13C-PFHXA 315.0/270.0 Da Baseline Missed n Wrnnn Peak PFHxS 1 399.0/80.0 Da Baseline Missed n Wrnnn Peak 180-PFHS 403.0/103.0 Da Baseline Missed n Wrnnn Peak S_180-PFHS 403.0/103.0 Da Baseline Missed n Wrnnn Peak___ 13C-PFDA 515.0/470.0 Da Baseline Missed n Wrnnn Peak SJ3C-PFDA 515.0/470.0 Da Baseline Missed ___n Wrnnn Peak___ Before After 13C-PFDA 515.0/470.0 Da Baseline Missed ___n Wrnnn Peak___ Page 27 o f 245 280 ti&l Services" p. 45 Created with Analyst Reporter Printed: 15/02/2010 2:34:00 PM Ion Ratio Confirmation 1.27 PFBA2 213.0/169.0 Da o Baseline a Missed Wrong Peak PFPeA2 263.0/219.0 Da Baseline Missed Wrong Peak PFC 5.0ppb tc * s 10i .'uei PFBS2 299.0/99.0 Da Baseline Missed Wrong Peak PFHxA 2 313.0/119.0 Da Baseline Missed Wrong Peak PFHpA2 363.0/319.0 Da o Baseline Missed Wrong Peak PFHxS2 399.0/99.0 Da Baseline Missed Wrong Peak S_13C-PFDA 515.0/470.0 Da Baseline Missed Wrong Peak NB. PFBA and PFPeA do not have qualifying ion transitions. Before After N/A Baseline Missed Wrong Peak Page 28 of 245 281 Services" p. 46 Created with Analyst Reporter Printed: 15/02/2010 2:34:00 PM Project Data File Acquisition Method Ewan's ProjectsVPFCs 020810\CalShort.wiff PFCkinetexShort.dam Result Table Algorithm Used Instrument Name 02081 OSamplesShortedit.rdb IntelliQuan API 5000 Sample Name Acquisition Date Acquisition Method Sample ID Sample Comment PFC10ppb 2/9/2010 4:13:34 AM PFCkinetexShort.dam LCMS2-85E Injection Vial Injection Volume Sample Type Dilution Factor Weight to Volume 6 5 Standard 1.00 0.00 Results Summary Analyte Name Analyte RT (Expected) PFBA 1 1.27(1.27) PFPeA 1 3.60 (3.60) PFBS 1 4.26 (4.26) PFHxA 1 5.31 (5.31) PFHpA 1 6.22 (6.23) PFHxS 1 S 180PFHS S 13CPFDA 6.32 (6.32) 6.31 (6.31) 7.65 (7.65) IS Name 13C-PFBA 13C-PFHxA 180-PFHS 13C-PFHxA 13C-PFHxA 180-PFHS 13C-PFDA 13C-PFDA IS Area 4039300 4527400 2676900 4527400 4527400 2676900 2957400 2957400 Analyte Area 4764700 5021600 9581100 5139400 1913100 9153300 2676900 2957400 Exp Cone (ng/mL) 10.00 10.00 10.00 10.00 10.00 10.00 1.00 1.00 Calc. Cone (ng/mL) 11.10 Accuracy (%> 111 11.60 116 10.70 107 10.90 109 10.90 109 10.90 109 1.03 103 1.00 100 Mod? No No No No No No No No ^5 it & Lb Page 29 of 245 282 IRC Summary Analyte Peak Name PFBA2 PFPeA2 PFBS 2 PFHxA2 PFHpA2 PFHxS2 S_13C-PFBA S_13C-PFHxA p. 47 Created with Analyst Reporter Printed: 15/02/2010 2:34:00 PM RT (Expected) 1.27(1.27) 3.60 (3.60) 4.26 (4.26) 5.31 (5.31) 6.23 (6.22) 6.32 (6.32) 1.26(1.26) 5.30 (5.30) Area 4764700 5021600 3769400 466950 5644600 3569800 4039300 4527400 Modified? No No No No No No No No Calculated Ion Ratio (Expected Value) 1.00 1.00 0.39 0.09 2.95 0.39 0.85 0.88 Page 30 of 245 283 iismbia Created with A n a lyft Reporter Printed: 15/02/2010 2:34:00 PM Quantitative Peak Review 7*6 1 .^ fr ** I 565 2*6 1*5 in I is : PFBA 7 213.0/169.0 Da c Baseline Missed n Wrnnn Peak i , 5 0eS 15 I 40 4 b 511 pfbsT 299.0/80.0 Da Baseline Missed n Wrnnn Peak 6.22 | i*6 -;f. l no sb 8 1*5 1| , f OS >0 15 Tims mm 13C-PFBA 2i 217.0/172.0 Da c Baseline Missed n Wrnnn Peak 6[ b5 B ScS 4*6 !" 1*5 55 5.0 55 Tim mm 180-PFHS n 403.0/103.0 Da Baseline Missed 2*6 1 OeS & $ 60eS * 40*5 n Wrnnn Peak 5.30 2 05 45 I 5C 55 50 PFHpAI 363.0/169.0 Da Baseline Missed n Wrnnn Peak 7*b 6.^1 <>6 Ve S*5 1i **' ?< M I '. tie 65 ?0 13C-PFHxA 315.0/270.0 Da Baseline Missed n Wrnnn Peak 7*5 7.^5 6.5 t | "4*5 5e5 ?5 )p 75 90 65 S 180-PFHS 403.0/103.0 Da Baseline Missed n Wrnnn Peak 13C-PFDA 515.0/470.0 Da Baseline Missed n Wrnnn Peak 1GeC 00e5 | SQeS | 0*5 20*5 30 I )5 PFC 10ppb 12*0 ,4.6 I 60*6 5.30 i 4 0*6 :os l 40 45 45 5 0 55 Ml PFPe/Tl 263.0/219.0 Da Baseline Missed n Wrnnn Peak 1: 5.31 10*6 8 0*5 1 60*S * 40*5 2 0*5 I 45 50 55 0 Tim* min PFHxA 1 313.0/269.0 Da Baseline Missed n Wrnnn Peak 25*6 6.32 7D*6 ^ 15*6 |i 10*6 5 0*5 13C-PFHxA 315.0/270.0 Da c Baseline c Missed n Wrnnn Peak 1 2*6 1 D* & s8uftetSs 3 40*5 ?0*5 I 45 5b 55 Tun* man 13C-PFHXA $0 315.0/270.0 Da Baseline Missed n Wrnnn Peak ?5 6.^1 8*6 t^ ^ 4*6 | 0*5 2*5 1*6 55 60 65 TO 55 bb 66 PFHxsl 180-PFHS 399.0/80.0 Da 403.0/103.0 Da Baseline Missed D Baseline Missed n Wrnnn Peak_____ n Wrnnn Peak 7*6 6*5 " | 3e5 ?*S 1*5 7.65 l 70 76 80 Tun mm S 13C-PFDA 745 4*6 S- 595 1" 1*5 86 7.65 l <* 70 75 0 85 Tn*. rw> 13C-PFDA 515.0/470.0 Da 515.0/470.0 Da Baseline Missed Baseline Missed n Wrnnn Peak_____ n Wrnnn Peak_____ Before After Page 31 o f 245 284 Ion Ratio Confirmation 3.60 p. 49 Created with Analyst Reporter Printed: 15/02/2010 2:34:00 PM PFC 10ppb PFBA2 213.0/169.0 Da Baseline Missed Wrong Peak 6 23 PFPeA2 263.0/219.0 Da Baseline Missed Wrong Peak PFBS2 299.0/99.0 Da Baseline Missed Wrong Peak PFHxA 2 313.0/119.0 Da Baseline q Missed Wrong Peak 6:3 PFHpA2 363.0/319.0 Da Baseline Missed Wrong Peak PFHxS2 399.0/99.0 Da Baseline Missed Wrong Peak SJ3C-PFDA 515.0/470.0 Da Baseline a Missed Wrong Peak NB. PFBA and PFPeA do not have qualifying ion transitions. Before After N/A Baseline Missed Wrong Peak Page 32 o f 245 285 Created with Analyst'Reporter Printed: 15/02/2010 2:34:00 PM Project Data File Acquisition Method Ewan's ProjectsVPFCs 020810\CalShort.wiff PFCkinetexShort.dam Result Table Algorithm Used Instrument Name 02081 OSamplesShortedit.rdb IntelliQuan API 5000 Sample Name Acquisition Date Acquisition Method Sample ID Sample Comment PFC 20ppb 2/9/2010 4:23:09 AM PFCkinetexShort.dam LCMS2-85F Injection Vial Injection Volume Sample Type Dilution Factor Weight to Volume 7 5 Standard 1.00 0.00 Results Summary Analyte Name Analyte RT (Expected) PFBA1 1.26(1.27) PFPeA 1 3.59 (3.60) PFBS 1 4.25 (4.26) PFHxA 1 5.30 (5.31) PFHpA 1 6.22 (6.23) PFHxS 1 S 180PFHS S 13CPFDA 6.32 (6.32) 6.31 (6.31) 7.66 (7.65) IS Name 13C-PFBA 13C-PFHxA 180-PFHS 13C-PFHxA 13C-PFHxA 180-PFHS 13C-PFDA 13C-PFDA IS Area 4227700 4795800 2734400 4795800 4795800 2734400 3316000 3316000 Analyte Area 8381600 8721900 16168000 8985200 3405200 15045000 2734400 3316000 Exp Cone (ng/mLj 20.00 20.00 20.00 20.00 20.00 20.00 1.00 1.00 Calc. Cone (ng/mL) 18.70 Accuracy <%) 93 19.00 95 18.60 93 18.60 93 18.40 18.40 92 92 0.94 94 1.00 100 Mod? No No No No No No No No Page 33 of 245 286 IRC Summary Analyte Peak Name PFBA2 PFPeA2 PFBS 2 PFHxA2 PFHpA2 PFHxS2 S_13C-PFBA S_13C-PFHxA p. 51 Created with Analyst Reporter Printed: 15/02/2010 2:34:00 PM RT (Expected) 1.26 (1.27) 3.59 (3.60) 4.25 (4.26) 5.30 (5.31) 6.22(6.22) 6.31 (6.32) 1.26(1.26) 5.30 (5.30) Area 8381600 8721900 6711000 837810 9866600 6194000 4227700 4795800 Modified? No No No No No No No No Calculated Ion Ratio (Expected Value) 1.00 1.00 0.42 0.09 2.90 0.41 0.50 0.53 Page 34 of 245 287 Created with Analyst' Reporter Printed: 15/02/2010 2:34:00 PM Quantitative Peak Review :*c 4<w,. 0$ [1 .2 6 I I 11 i0 PFBA 1 213.0/169.0 Da Baseline Missed n Wrnnn Peak 3et a 4 .2 5 1 3S 4(1 45 56 1^ .. Se-i j 1*5 2*6 iti 05 10 !5 Tim*, mm 13C-PFBA 20 217.0/172.0 Da C Baseline Missed n Wrnnn Peak 7*5 4*5 | 55 ** | 6 2*6 le i I 55 60 65 70 PFBS 1 299.0/80.0 Da Baseline Missed n Wrnnn Peak '0*6 6 . 2 2 805 * 60*5 JO5 180-PFHS 403.0/103.0 Da Baseline Missed n Wrnnn Peak 1 :*<i i 0*6 2 8 0*6 $| 6 0*5 S 40*5 ro*5 5 .^ 0 S', hD 65 70 PFHpA'i 363.0/169.0 Da Baseline Missed n Wrnnn Peak 46 50 55 Thti* mm 13C-PFHxA 60 315.0/270.0 Da Baseline Missed n Wrnnn Peak 75 6*6 ci 5*5" -5 | >5 2*5 1*5 5'. 6 .3 1 & 60 65 8*5 6 M S 4*5 2*5 70 70 7 .^ 6 75 80 85 S 180-PFHS 403.0/103.0 Da C Baseline Missed n Wrnnn Peak_____ 13C-PFDA 515.0/470.0 Da Baseline Missed n Wrnnn Peak IS6 S 10*6 1 50*6 I3 .5 9 PFC 20ppb : iti 10i6 (i OvS | 6 0*6 * 40*5 2*b I 30 35 40 45 45 50 55 60 PFPeA~1 263.0/219.0 Da Baseline Missed _____________n Wrnnn Peak_____ 25*6 5 .3 0 20*6 6 , ! 1()*6 50*5 45 i SO 55 2 * ! 5 60 PFHxXl 313.0/269.0 Da Baseline a Missed _____________n WranaPfiak_____ 4*6 - 6 . 3 2 13C-PFHXA 315.0/270.0 Da C Baseline Missed n Wrnnn Peak 5[ 10*6 80*S 4 0*5 20*5 45 50 55 Tun*, mm 60 13C-PFHxA 315.0/270.0 Da Baseline Missed n Wrnnn Peak 7*5 6 . 3 1 3*6 i ^ 2*6' I 1*6 f& 485 | 3*6 2*5 lei 1 55 (C 65 70 55 60 65 7 PFHxSI 180-PFHS 399.0/80.0 Da Baseline Missed n Wrnnn Peak 6e5 g. 6*5 | 4*5 S 403.0/103.0 Da ' o Baseline Missed n Wrnnn Peak 8*5 g 6*5 s- 1 <*5 2*5 I 70 75 00 Tim* mm S 13C-PFDA 515.0/470.0 Da 65 9 75 * 0 T r , ntn 13C-PFDA 515.0/470.0 Da 15 Baseline Missed n Wrnnn Peak_____ Baseline Missed n Wrnnn Peak_____ Before After Page 35 of 245 288 S e rv ic e s " Ion Ratio Confirmation 1.26 p. 53 Created with Analyst Reporter Printed: 15/02/2010 2:34:00 PM PFC 20ppb _ 4. PFBA2 213.0/169.0 Da Baseline Missed d Wrong Peak PFPeA2 263.0/219.0 Da Baseline o Missed Wrong Peak PFBS2 299.0/99.0 Da Baseline c Missed d Wrong Peak -6^2- ... ....... 6; 1............. PFHpA2 363.0/319.0 Da o Baseline Missed a Wrong Peak 55 60Timmtm6.5....?.0. PFHxS2 399.0/99.0 Da Baseline a Missed o Wrong Peak S_13C-PFDA 515.0/470.0 Da Baseline Missed Wrong Peak NB. PFBA and PFPeA do not have qualifying ion transitions. Before After PFHxA 2 313.0/119.0 Da Baseline Missed Wrong Peak Thistriageisrd amiable N/A Baseline Missed Wrong Peak Page 36 o f 245 289 Columbia Analytical Services" Created with A n a ly ff Reporter Printed: 15/02/2010 2:34:00 PM Project Data File Acquisition Method Ewan's Projects\PFCs 020810\CalShort.wiff PFCkinetexShort.dam Result Table Algorithm Used Instrument Name 02081 OSamplesShortedit.rdb IntelliQuan API 5000 Sample Name Acquisition Date Acquisition Method Sample ID Sample Comment PFC 50ppb 2/9/2010 4:32:41 AM PFCkinetexShort.dam LCMS2-85G Injection Vial Injection Volume Sample Type Dilution Factor Weight to Volume 8 5 Standard 1.00 0.00 Results Summary Analyte Name Analyte RT (Expected) PFBA1 1.27 (1.27) PFPeA 1 3.59 (3.60) PFBS 1 4.25 (4.26) PFHxA 1 5.30 (5.31) PFHpA 1 6.23 (6.23) PFHxS1 S 180PFHS S 13CPFDA 6.32(6.32) 6.33 (6.31) 7.67 (7.65) IS Name 13C-PFBA 13C-PFHxA 180-PFHS 13C-PFHxA 13C-PFHxA 180-PFHS 13C-PFDA 3C-PFDA IS Area 4234600 4753100 2676100 4753100 4753100 2676100 3257900 3257900 Analyte Area 22387000 22184000 34874000 21291000 9090100 31836000 2676100 3257900 Exp Cone (ng/mL) 50.00 50.00 50.00 50.00 50.00 50.00 1.00 1.00 Calc. Cone (ng/mL) 49.90 Accuracy (%) 100 48.80 98 50.70 101 50.50 101 50.40 50.80 101 102 0.93 93 1.00 100 Mod? No No No No No No No No ' ^ U0 Page 37 of 245 290 IRC Summary Analyte Peak Name PFBA2 PFPeA2 PFBS 2 PFHxA2 PFHpA2 PFHxS2 S_13C-PFBA S_13C-PFHxA p. 55 Created with Analyst Reporter Printed: 15/02/2010 2:34:00 PM RT (Expected) 1.27 (1.27) 3.59(3.60) 4.26 (4.26) 5.31 (5.31) 6.24 (6.22) 6.33 (6.32) 1.27(1.26) 5.31 (5.30) Area 22387000 22184000 16796000 2281900 22816000 15495000 4234600 4753100 Modified? No No No No No No No No Calculated Ion Ratio (Expected Value) 1.00 1.00 0.48 0.11 2.51 0.49 0.19 0.22 Page 38 of 245 291 lumbia Quantitative Peak Review p. 56 Created with Analyst Reporter Printed: 15/02/2010 2:34:00 PM PFC 50ppb Before After Page 39 of 245 292 Ion Ratio Confirmation 1.27 3:59 p. 57 Created with Analyst Reporter Printed: 15/02/2010 2:34:00 PM PFC 50ppb PFBA2 213.0/169.0 Da Baseline Missed Wrong Peak PFPeA2 263.0/219.0 Da d Baseline Missed Wrong Peak PFBS2 299.0/99.0 Da Baseline Missed o Wrong Peak >*6 fr 6ei ?. *e6 S 3** 6 .2 4 i leS 55 60 r. n PFHpA 2 363.0/319.0 Da Baseline Missed Wrong Peak 6*6 | 3*6 2 2*6 1*6 6. f 3 65 60 65 7* PFHxS 2 399.0/99.0 Da Baseline Missed Wrong Peak 6*5 21 K 2*5 SJ3C-PFDA 515.0/470.0 Da D Baseline Misse Wrong Peak NB. PFBA and PFPeA do not have qualifying ion transitions. Before After PFHxA 2 313.0/119.0 Da a Baseline Missed d Wrong Peak N/A o Baseline Missed o Wrong Peak Page 40 of 245 293 p. 58 Created with Analyst Reporter Printed: 15/02/2010 2:34:00 PM Project Data File Acquisition Method Ewan's Projects\PFCs 020810\CalShort.wiff PFCkinetexShort.dam Result Table Algorithm Used Instrument Name 02081 OSamplesShortedit.rdb IntelliQuan API 5000 Sample Name Acquisition Date Acquisition Method Sample ID Sample Comment PFC 20ppb ICV 2/9/2010 5:01:26 AM PFCkinetexShort.dam LCMS2-77J Injection Vial Injection Volume Sample Type Dilution Factor Weight to Volume 9 5 Quality Control 1.00 0.00 Results Summary Analyte Name Analyte RT (Expected) PFBA 1 1.27 (1.27) IS Name 13C-PFBA PFPeA 1 3.61 (3.60) 13C-PFHxA PFBS 1 4.27 (4.26) 180-PFHS PFHxA 1 5.32 (5.31) 13C-PFHxA PFHpA 1 6.24 (6.23) 13C-PFHxA PFHxS 1 S 180PFHS 6.34 (6.32) 6.34 (6.31) 7.68 (7.65) 180-PFHS 13C-PFDA 13C-PFDA IS Area 4090400 4533900 2648500 4533900 4533900 2648500 3123300 3123300 Analyte Area 9226300 9681900 17751000 9358200 3733600 16240000 2648500 3123300 Exp Cone (ng/mL) 20.00 20.00 20.00 20.00 20.00 20.00 1.00 1.00 Calc. Cone (ng/mL) 21.30 Accuracy (%) 106 22.30 112 21.40 107 20.60 21.40 103 107 20.90 104 0.96 96 1.00 100 Mod? No No No No No No No No -Tiol fCl Page 45 of 245 294 IRC Summary Analyte Peak Name PFBA2 PFPeA2 PFBS2 PFHxA 2 PFHpA2 PFHxS2 S_13C-PFBA S_13C-PFHxA p. 59 Created with Analyst Reporter Printed: 15/02/2010 2:34:00 PM RT (Exp RT) 1.27(1.27) 3.61 (3.60) 4.26 (4.26) 5.32(5.31) 6.25 (6.22) 6.34 (6.32) 1.27(1.26) 5.32 (5.30) Area 9226300 9681900 7371700 939420 10767000 6702600 4090400 4533900 Modified? No No No No No No No No Ratio Confirms ID YES YES YES YES YES YES No No Page 46 of 245 295 p. 60 Created with Analyst Reporter Printed: 15/02/2010 2:34:00 PM Quantitative Peak Review PFC 20ppb ICV = SO*5 05 i I 15 U5 5f5 bi 4i*5 1M 1*6 ;o 05 >0 l IS 20*4 15f i lDoS 3.61 60*5 2D JO 35l 40 1ij&e 40*5 | EM 2 4(w5 20*5 46 I PFBA 7 213.0/169.0 Da 1 3C-PFBA 217.0/172.0 Da P FPeA 'i 263.0/219.0 Da 1 3C-PFHXA 315.0/270.0 Da c Baseline Missed c Baseline Missed C Baseline o Missed C Baseline o Missed n Wronn Peak 4*C 4.27 )*( *fe ,*c s l*C IS 40 1 45 n Wrnnn Peak ;5 us S 5*5 |s *1*5s 2*S 6.34 50 55 60 Twi*IMl55 70 n Wrnnn Peak 20*6 8 )5*4 |i .... 606 45 60 1 55 60 n Wrnnn Peak 12*G 'feu 1$ BUS RB*5 2 40ef. 20*5 00*0 45 5.32 50 TunIenr55 Cl) PFBS 1 180-PFH S PFHxa I 130 -P F H x A 299.0/80.0 Da 403.0/103.0 Da 313.0/269.0 Da 315.0/270.0 Da o Baseline Missed Baseline a Missed Baseline Missed Baseline Missed _______n Wrnnn Peak______ n Wrnnn Peak n Wrnnn Peak n Wrnnn Pnak V (.(US ss 6.24 o 1 os i:g 10*6 e rD*c. | COeS 2 4 0e5 roe? n 45 50 iTim<mii55 4*6 *6 3e6 I S \t6 *0 55 6C i 95 7*5 6,34 5 4e TM5 1 ?wS 7 66 60 l 65 7 PFHpAI 13C -P F H X A P F H x il 1 80-PFH S 363.0/169.0 Da 315.0/270.0 Da 399.0/80.0 Da 403.0/103.0 Da o Baseline c Missed Baseline Missed Baseline o Missed Baseline Missed ______n Wrnnn Peak______ /s 6.34 !: iz i*e. '.5 Si [ 55 '0 f#soni n Wrnnn Peak 7.^8 71) 75Timemm 90 n Wrnnn Peak U97**S55 7.68 *3I& *Z*163**t*,S556S 95 70 75 I 90 3** 9.5 n Wrnnn Peak u9U*sS5 7.68 ** :4if*e*55sS 70 75 l 80 95 S 180-PFH S 13C-PFD A S 1 3C-PFDA 1 3C-PFD A 403.0/103.0 Da 515.0/470.0 Da 515.0/470.0 Da 515.0/470.0 Da o Baseline o Missed o Baseline Missed Baseline Missed c Baseline Missed r Wrnnn Peak______ n Wrnnn Peak______ n Wrnnn Peak______ n Wrnnn Peak______ Before After Page 47 o f 245 296 Ion Ratio Confirmation 1 .2 7 3.61 p. 61 Created with Analyst Reporter Printed: 15/02/2010 2:34:00 PM PFC 20ppb ICV PFBA2 213.0/169.0 Da g Baseline c Missed o Wrong Peak PFPeA2 263.0/219.0 Da Baseline Missed Wrong Peak PFBS2 299.0/99.0 Da Baseline Missed Wrong Peak PFHxA 2 313.0/119.0 Da Baseline Missed Wrong Peak Thismage s rd wabble PFHpA2 363.0/319.0 Da Baseline Missed Wrong Peak PFHxS2 399.0/99.0 Da Baseline Missed d Wrong Peak S_13C-PFDA 515.0/470.0 Da g Baseline Missed Wrong Peak NB. PFBA and PFPeA do not have qualifying ion transitions. Before After N/A d Baseline a Missed d Wrong Peak Page 48 o f 245 297 f% C o lu m b ia 4 * 3 Analytical Services'' Created with AnalysPFffciorter Printed: 14/02/2010 6:41.00 PM Project Data File Acquisition Method Ewan's Projects\PFCs 020810b\CalLong.wiff PFCkinetexLong.dam Result Table Algorithm Used Instrument Name 02081 OSamplesLong.rdb IntelliQuan API 5000 Sample Name Acquisition Date Acquisition Method Sample ID Sample Comment PFC 20ppb CCV 2/8/2010 7:23:19 PM PFCkinetexLong.dam LCMS2-85F Injection Vial Injection Volume Sample Type Dilution Factor Weight to Volume 7 5 Quality Control 1.00 0.00 Results Summary A n a ly te N am e A n a ly te RT (E xpe cted) PFOA 1 1 .3 7 (1.36) IS N a m e 13C -P F O A PFNA 1 2.31 (2.42) 13C -P F N A PFOS 1 2 .3 5 (2.53) 13C -P F O S PFDA 1 3 .3 4 (3.34) 13C -P F D A PFUnA 1 4 .1 2 (4 .0 6 ) 13 C -P F U n A PFDS 1 4 .1 2 (4 .1 0 ) 13C -P F O S PFDoA 1 4 .7 6 (4.63) 13C -P F D O A P F T rA 1 5 .2 9 (5 .1 4 ) 13C -P F D O A PFTeA 1 5 .7 4 (5.74) 13C -P F D O A IS A re a 2998700 2406700 7240000 2357900 175930 7240000 223730 223730 223730 A n a ly te A rea 2732300 4688200 14289000 4270400 2867900 14642000 2346700 1564500 1050700 Exp Cone (n g /m L ) 2 0 .0 0 0 2 0 .0 0 0 2 0 .0 0 0 20 .000 2 0 .000 2 0 .0 0 0 2 0 .0 0 0 2 0 .0 0 0 2 0 .0 0 0 C a lc. C o ne (n g /m L ) 1 8 .8 0 0 A ccura cy (% ) 94 17 .000 85 1 8 .5 0 0 93 1 7 .2 0 0 86 1 7 .3 0 0 86 1 8 .4 0 0 92 1 9 .3 0 0 96 1 9 .9 0 0 99 1 7 .7 0 0 89 7 M od? No No No No No No No No No Page 42 of 242 298 / ? Columbia w J Analytical Services'' Created with AnalysPf&jborter Printed: 14/02/2010 6:41:00 PM IRC Summary A n a ly te Peak Nam e PFOA2 S_13C_PFOA PFNA 2 S_13C_PFNA PFOS 2 S_13C-PFOS PFDA2 S_13C-PFDA PFUnA2 S_13C-PFUnA PFDS 2 PFDoA2 S_13C-PFDoA PFTrA 2 PFTeA2 RT (E xp RT ) 1.36(1.36) 1.37 (1.36) 2.32 (2.44) 2.29 (2.44) 2.35 (2.53) 2.33 (2.53) 3.32(3.34) 3.32(3.34) 4.13(4.06) 4.11 (4.06) 4.12 (4.10) 4.76 (4.64) 4.75(4.64) 5.28(5.13) 5.74(5.56) A rea 6503700 2998700 1438500 2406700 4648000 7240000 660130 2357900 704840 175930 4892700 676160 223730 548290 386040 M o d ifie d ? No No No No No No No No No No No No No No No R a tio C o n fir m s ID YES No YES No YES No YES No YES No YES YES No YES YES Page 43 of 242 299 Created with Analyft-lW porter Printed: 14/02/2010 6:41:00 PM Quantitative Peak Review l LL PFOA 1 413.0/169.0 Da l Baseline c Missed r Wrnnn Peak 13C-PFOA 417.0/372.0 Da Baseline Missed ___n Wronn Peak___ PFC 20ppb CCV 1- 2.31 i 2.29 i PFNA 1 463.0/419.0 Da g Baseline d Missed r Wrnnn Paak 13C-PFNA 468.0/423.0 Da Baseline c Missed n Wrnnn Paak PFOS 1 499.0/80.0 Da Baseline Missed n Wrnnn Paak "i 4 .1 2 13C-PFOS 503.0/80.0 Da o Baseline Missed n Wrnnn Paak PFDA 1 513.0/469.0 Da Baseline d Missed n Wrnnn Peak 4.12 13C-PFDA 515.0/470.0 Da Baseline Missed n Wrnnn Paak 2 .3 3 PFUnA 1 563.0/519.0 Da g Baseline o Missed r: Wrnnn Peak 13C-PFUnA 565.0/270.0 Da Baseline Missed n Wrnnn Peak Time mm PFDS 1 599.0/80.0 Da Baseline Missed __ p W rn n n PftftK __ 5 .2 9 \ mL 13C-PFOS 503.0/80.0 Da Baseline Missed ___n Wrnnn Peak___ PFDoA 1 613.0/569.0 Da u Baseline a Missed r Wrnnn Peak 13C-PFDOA 615.0/169.0 Da Baseline Missed n Wrnnn Peak_ jji_ PFTrA 1 663.0/619.0 Da Baseline Missed ___n Wrnnn Pp.ak___ ,,L 13C-PFD0A 615.0/169.0 Da c Baseline Missed n Wrnnn Peak PFTeA 1 713.0/669.0 Da g Baseline c Missed r Wrnnn Paak 13C-PFDOA 615.0/169.0 Da Baseline Missed 11 Wrnnn Pnak___ Before After 300 Page 44 of 242 / T Columbia Analytical San/icss' Ion Ratio Confirmation 1.36 Created with AnalystBR^Drter Printed: 14/02/2010 6:41:00 PM PFC 20ppb CCV PFOA2 413.0/369.0 Da c Baseline Missed Wrong Peak PFNA2 463.0/219.0 Da d Baseline Missed Wrong Peak , *1 ? T' 4 Ia PFUnA 2 563.0/269.0 Da d Baseline o Missed o Wrong Peak ; ... 1 - 5. 4 ........... i 1 PFDS2 599.0/99.0 Da c Baseline Missed Wrong Peak ' . .b.n.......6.'. PFTe"/\ 2 713.0/16$3.0 Da Baseline 3 Missed Wrong Peak Before After PFOS 2 499.0/99.0 Da Baseline Missed o Wrong Peak PFDoA2 613.0/169.0 Da d Baseline Missed Wrong Peak PFDA2 513.0/269.0 Da Baseline Missed Wrong Peak ............5.1 1.(1 PFTrA 2 663.0/169.0 Da Baseline Missed Wrong Peak CO Page 45 of 242 301 Servisses* p. 66 Created with Analyst Reporter Printed: 15/02/2010 2:34:00 PM Project Data File Acquisition Method Ewan's ProjectsVPFCs 020810\CalShort.wiff PFCkinetexShort.dam Result Table Algorithm Used Instrument Name 02081 OSamplesShortedit.rdb IntelliQuan API 5000 Sample Name Acquisition Date Acquisition Method Sample ID Sample Comment PFC 20ppb CCV 2/9/2010 4:51:51 AM PFCkinetexShort.dam LCMS2-85F Injection Vial Injection Volume Sample Type Dilution Factor Weight to Volume 7 5 Quality Control 1.0 0 0 .0 0 Results Summary Analyte Name Analyte RT (Expected) PFBA1 1.26(1.27) PFPeA 1 3.59(3.60) PFBS 1 4.26 (4.26) PFHxA 1 5.31 (5.31) PFHpA 1 6.24 (6.23) PFHxS 1 S 180PFHS S 13CPFDA 6.33 (6.32) 6.33 (6.31) 7.68 (7.65) IS Name 13C-PFBA 13C-PFHxA 180-PFHS 13C-PFHxA 13C-PFHxA 180-PFHS 13C-PFDA 13C-PFDA IS Area 4199600 4858000 2765600 4858000 4858000 2765600 3228800 3228800 Analyte Area 8447400 8849500 16466000 8982200 3540400 15250000 2765600 3228800 Exp Cone (ng/mL) 20.00 20.00 20.00 20.00 20.00 20.00 1.00 1.00 Calc. Cone (ng/mL) 18.90 Accuracy (%) 95 19.00 95 18.70 94 18.30 92 18.90 18.50 94 93 0.97 97 1.00 100 Mod? No No No No No No No No > lio Z -l1 Page 41 o f 245 302 lytubia IRC Summary Analyte Peak Name PFBA2 PFPeA2 PFBS2 PFHxA 2 PFHpA 2 PFHxS2 S_13C-PFBA S_13C-PFHxA p. 67 Created with Analyst Reporter Printed: 15/02/2010 2:34:00 PM RT (Exp RT) 1.26(1.27) 3.59 (3.60) 4.26 (4.26) 5.31 (5.31) 6.24 (6.22) 6.33 (6.32) 1.26 (1.26) 5.31 (5.30) Area 8447400 8849500 6771900 875300 9806100 6248700 4199600 4858000 Modified? No No No No No No No No Ratio Confirms ID YES YES YES YES YES YES No No Page 42 of 245 303  Columbia J Analytical Son/kts" Quantitative Peak Review p. 68 Created with Analyst Reporter Printed: 15/02/2010 2 :3 4 : 0 0 PM PFC 20ppb CCV Before After Page 43 of 245 304 p. 69 Created with Analyst Reporter Printed: 15/02/2010 2:34:00 PM Ion Ratio Confirmation _E1.26 3.59 PFC 20ppb CCV Tm, mm PFBA2 213.0/169.0 Da Baseline Missed o Wrong Peak PFPeA2 263.0/219.0 Da Baseline d Missed o Wrong Peak PFBS2 299.0/99.0 Da o Baseline Missed Wrong Peak 1 .L PFHpA2 363.0/319.0 Da Baseline Missed Wrong Peak PFHxS2 399.0/99.0 Da Baseline Missed Wrong Peak S_13C-PFDA 515.0/470.0 Da Baseline o Missed Wrong Peak NB. PFBA and PFPeA do not have qualifying ion transitions. PFHxA 2 313.0/119.0 Da Baseline Missed Wrong Peak ferriage is rdavaiable N/A Baseline q Missed Wrong Peak Before After Page 44 of 245 305 p. 70 A cquisition D ate V ial P osition S a m p le N a m e 1 2 /8 /20 1 0 18:00 1 IB 2 2 /8 /20 1 0 18:22 2 PFC O .IO ppb 3 2 /8 /2 0 1 0 18:30 3 PFC 0.5ppb 4 2 /8 /2 0 1 0 18:37 4 PFC 1.0ppb 5 2/8 /20 1 0 18:45 5 PFC 5.0ppb 6 2 /8 /20 1 0 18:53 6 PFC 10ppb 7 2 /8 /2 0 1 0 19:00 7 PFC 20ppb 8 2/8 /20 1 0 19:08 8 PFC 50ppb 9 2 /8 /2 0 1 0 19:23 7 PFC 20ppb CCV 10 2 /8 /2 0 1 0 19:30 9 PFC 20ppb IC V 11 2 /8 /2 0 1 0 2 0 :5 4 41 K 1 0 0 0 9 1 1-001 12 2 /8 /2 0 1 0 21:01 42 K1000911-002 13 2 /8 /2 0 1 0 2 1 :09 43 K 1 0 0 0 9 1 1-003 14 2 /8 /2 0 1 0 2 1 :1 6 44 K1000911-004 15 2 /8 /2 0 1 0 21:24 45 K 1 0 0 0 9 1 1-005 16 2 /8 /2 0 1 0 21:31 46 K 1 0 0 0 9 1 1-006 17 2 /8 /2 0 1 0 2 1 :3 9 47 K 1 0 0 0 9 1 1-007 18 2 /8 /2 0 1 0 21:46 48 K 1 0 0 0 9 1 1-008 19 2 /8 /2 0 1 0 2 1 :5 4 49 K 1 0 0 0 9 1 1-009 20 2/8/2010 22:02 50 K 1 0 0 0 9 1 1-010 21 .2 /8 /2 0 1 0 2 2 :0 9 51 K 1 0 0 0 9 1 1-011 22 2/8/2010 22:17 52 K1000911-012 23 2/8/2010 22:24 53 K 1 0 0 0 9 1 1-013 24 2/8/2010 22:32 54 K 1 0 0 0 9 1 1-014 25 2/8/2010 22:39 55 K 1 0 0 0 9 1 1-015 26 2/8/2010 22:47 56 K1000911-016 27 2/8/2010 22:55 57 K1000911-017 28 2/8/2010 23:02 58 K1000911-018 29 2/8/2010 23:10 59 K 1 0 0 0 9 1 1-019 30 2/8/2010 23:17 60 K Q 1000532-05 31 2 /8 /2 0 1 0 2 3 :2 5 61 K Q 1 0 0 0 5 3 2 -0 6 32 2 /8/2010 23:32 62 KQ 1000532-04 33 2 /8/2010 23:40 63 K1000821-001 34 2 /8/2010 23:48 64 K Q 1000453-01 35 2 /8 /20 1 0 23:55 65 KQ 1000453-02 ^ 2 /9/2010 0:03 66 KQ 1000453-03 37 ^ ^ / 9 / 2 0 1 0 0:10 21 K 1 0 0 0 96 8 -0 0 1 38 2 /9/2010 0:18 22 K1000968-002 39 2 /9/2010 0:25 23 K1000968-003 40 2 /9 /20 1 0 0:33 24 K1000968-004 41 2 /9 /2 0 1 0 0 :4 0 25 K1000968-005 42 2 /9 /20 1 0 0:48 26 K 1000968-006 43 2/9/2010 0:55 27 K1000968-007 44 2 /9 /20 1 0 1:03 28 K 1000968-008 45 2 /9 /2 0 1 0 1:11 29 K1000968-009 46 2 /9 /2 0 1 0 1:18 30 K1000968-010 47 2 /9 /2 0 1 0 1:26 31 K 1 0 0 0 9 6 8 -0 1 1 48 2 /9 /2 0 1 0 1:33 32 K1000968-012 49 2 /9 /2 0 1 0 1:41 33 K1000968-013 50 2 /9 /2 0 1 0 1-49 34 K 1000968-014 51 2 /9 /2 0 1 0 1 :5 6 35 K 1000968-015 52 2/9/2010 2:04 36 K1000968-016 53 2 /9 /20 1 0 2:11 37 K 1000968-017 54 2/9/2010 2:19 38 K 1000968-018 55 2/9/2010 2:26 39 K1000968-019 56 2/9/2010 2:34 40 K1000968-020 57 2 /9 /2 0 1 0 2:42 67 KQ 1000620-03 58 2 /9/2010 2:49 68 KQ 1000620-04 A cquisition M ethod P F C kin e te xLo n g .d a m P F C kin e te xLo n g .d a m P F C kin e te xLo n g .d a m P F C kin e te xLo n g .d a m P F C kin e te xLo n g .d a m P F C kin e te xLo n g .d a m P F C kin e te xLo n g .d a m P F C kin e te xLo n g .d a m P F C kin e te xLo n g .d a m P F C kin e te xLo n g .d a m P F C kin e te xLo n g .d a m P F C kin e te xLo n g .d a m P F C kin e te xLo n g .d a m P F C kin e te xLo n g .d a m P F C kin e te xLo n g .d a m P F C kin e te xLo n g .d a m P F C kin e te xLo n g .d a m P F C kin e te xLo n g .d a m P F C kin e te xLo n g .d a m P F C kin e te xLo n g .d a m P F C kin e te xLo n g .d a m P F C kin e te xLo n g .d a m P F C kin e te xLo n g .d a m P F C kin e te xLo n g .d a m P F C kin e te xLo n g .d a m P F C kin e te xLo n g .d a m P F C kin e te xLo n g .d a m P F C kin e te xLo n g .d a m P F C kin e te xLo n g .d a m P F C kin e te xLo n g .d a m P F C kin e te xLo n g .d a m P F C kin e te xLo n g .d a m P F C kin e te xLo n g .d a m P F C kin e te xLo n g .d a m P F C kin e te xLo n g .d a m P F C kin e te xLo n g .d a m P F C kin e te xLo n g .d a m P F C kin e te xLo n g .d a m P F C kin e te xLo n g .d a m P F C kin e te xLo n g .d a m P F C kin e te xLo n g .d a m P F C kin e te xLo n g .d a m P F C kin e te xLo n g .d a m P F C kin e te xLo n g .d a m P F C kin e te xLo n g .d a m P F C kin e te xLo n g .d a m P F C kin e te xLo n g .d a m P F C kin e te xLo n g .d a m P F C kin e te xLo n g .d a m P F C kin e te xLo n g .d a m P F C kin e te xLo n g .d a m P F C kin e te xLo n g .d a m P F C kin e te xLo n g .d a m P F C kin e te xLo n g .d a m P F C kin e te xLo n g .d a m P F C kin e te xLo n g .d a m P F C kin e te xLo n g .d a m P F C kin e te xLo n g .d a m File N a m e 02081 O btC alLong.w iff 0 2 0 81 0 b \C a lL o n g.w iff 02081 O btC alLong.w iff 0 2 0 8 1 O btC alLong.w iff 0 2 0 8 1 O btC alLong.w iff 0 2 0 81 0 b \C a lL o n g.w iff 02081 O btC alLong.w iff 0 2 0 81 0 b \C a lL o n g.w iff 02081 O btC alLong.w iff 02081 O btC alLong.w iff 02081 O btS a m ple sL o n g .w iff 0 2 0 8 1 0 b \S a m p le sL o n g .w iff 02081 O btS a m ple sL o n g .w iff 02081 O b tS a m ple sL o n g .w iff 0 2 0 8 1 0 b \S a m p le sL o n g .w iff 02081 O btS a m ple sL o n g .w iff 02081 O btS a m ple sL o n g .w iff 02081 O btS a m ple sL o n g .w iff 02081 O btS a m ple sL o n g .w iff 02081 O b tS a m ple sL o n g .w iff 0 2 0 8 1 O btS a m ple sL o n g .w iff 02081 O btS a m ple sL o n g .w iff 02081 O btS a m ple sL o n g .w iff 02081 O btS a m ple sL o n g .w iff 0 2 0 8 1 0 b \S a m p le sL o n g .w iff 02081 O btS a m ple sL o n g .w iff 02081 O btS a m ple sL o n g .w iff 02081 O btS a m ple sL o n g .w iff 02081 O btS a m ple sL o n g .w iff 02081 O btS a m ple sL o n g .w iff 02081 O btS a m ple sL o n g .w iff 02081 O btS a m ple sL o n g .w iff 02081 O btS a m ple sL o n g .w iff 02081 O btS a m ple sL o n g .w iff 02081 O btS a m ple sL o n g .w iff 02081 O btS a m ple sL o n g .w iff 02081 O btS a m ple sL o n g .w iff 02081 O b tS am plesLong.w iff 02081 O btS a m ple sL o n g .w iff 02081 O b tS am plesLong.w iff 02081 O btS a m ple sL o n g .w iff 02081 O b tS am plesLong.w iff 02081 O btS a m ple sL o n g .w iff 02081 O b tS am plesLong.w iff 02081 O btS a m ple sL o n g .w iff 02081 O b tS a m ple sL o n g .w iff 02081 O btS a m ple sL o n g .w iff 02081 O btS a m ple sL o n g .w iff 02081 O b tS am plesLong.w iff 02081 O btS a m ple sL o n g .w iff 02081 O btS am plesLong w iff 02081 O btS a m ple sL o n g .w iff 02081 O btS a m ple sL o n g .w iff 02081 O btS a m ple sL o n g .w iff 02081 O b tS am plesLong.w iff 02081 O btS am plesLong.w iff 02081 O b tS am plesLong.w iff 02081 O btS a m ple sL o n g .w iff Inst IS A re a C ounts 9 7 .2 3 2198200 2150700 2119100 2111500 2127100 2039400 1935900 2357900 1968300 2512500 2083500 2400200 2369600 2521100 2224100 2347900 2106600 2328400 2355200 2468000 2278600 2235100 2227400 2614100 2632800 2639200 2376700 2419900 2560600 2412900 2564200 3603100 2633300 2721500 2759400 2675300 2837200 2691200 2170500 2575600 2634200 2338800 2593000 2591600 2271400 2291100 2448400 2379200 2308700 2253600 2563500 2428300 2563900 2398200 2174000 2263400 2374100 v/ J i u - f t 306 p. 71 A cq u isitio n D ate Vial Position S am ple N am e 1 2/9/2010 3:06 1 IB 2 2/9/2010 3:35 2 PFC O.IOppb 3 2/9/2010 3:44 3 PFC 0.5ppb 4 2/9/2010 3:54 4 PFC 1.0ppb 5 2/9/2010 4:04 5 PFC 5.0ppb 6 2/9/2010 4:13 6 PFC1Qppb 7 2/9/2010 4:23 7 PFC 20ppb 8 2/9/2010 4:32 9 2 /9 /2 0 1 0 4:51 y 8 PFC 50ppb 7 PFC 20ppb CCM 10 2 /9 /2 0 1 0 5:01 9 PFC 20ppb ICV 11 2 /9 /2 0 1 0 6 :4 6 41 K 1 0 0 0 9 1 1 -0 0 1 12 2/9 /20 1 0 6:56 42 K1000911-002 13 2 /9 /2 0 1 0 7:05 43 K1000911-003 14 2/9/2010 7:15 44 K1000911-004 15 2/9 /20 1 0 7:24 45 K1000911-005 16 2/9 /20 1 0 7:34 46 K1000911-006 17 2/9/2010 7:43 47 K1000911-007 18 2 /9 /20 1 0 7:53 48 K1000911-008 19 2/9 /20 1 0 8:03 49 K1000911-009 20 2/9/2010 8:12 50 K1000911-010 21 2 /9 /2 0 1 0 8 :2 2 51 K 1 0 0 0 9 1 1 -0 1 1 22 2 /9 /2 0 1 0 8:31 52 K1000911-012 23 2 /9 /2 0 1 0 8:41 53 K1000911-013 24 2/9/2010 8:50 54 K1000911-014 25 2/9/2010 9:00 55 K1000911-015 26 2/9/2010 9:09 56 K1000911-016 27 2/9/2010 9:19 57 K1000911-017 28 2/9/2010 9:29 58 K1000911-018 29 2/9/2010 9:38 59 K1000911-019 30 2/9/2010 9:48 60 KQ 1000532-05 31 2 /9 /2 0 1 0 9 :5 7 61 K Q 1 0 0 0 5 3 2 -0 6 32 2/9/2010 10:07 62 K Q 1000532-04 33 2/9/2010 10:55 21 K 1 0 0 0 9 6 8 -0 0 1 34 2/9/2010 11:04 22 K1000968-002 35 2/9/2010 11:14 23 K1000968-003 36 2/9/2010 11:23 24 K1000968-004 37 2/9/2010 11:33 25 K1000968-005 38 2/9/2010 11:42 26 K1000968-006 39 2/9/2010 11:52 27 K1000968-007 40 2 /9 /2 0 1 0 12:01 28 K1000968-008 41 2 /9 /2 0 1 0 12:11 29 K1000968-009 42 2 /9/2010 12:20 30 K1000968-010 43 2 /9/2010 12:30 31 K 1 0 0 0 9 6 8 -0 1 1 44 2/9/2010 12:40 32 K1000968-012 45 2/9/2010 12:49 33 K1000968-013 46 2/9/2010 12:59 34 K1000968-014 47 2/9/2010 13:08 35 K1000968-015 48 2/9/2010 13:18 36 K1000968-016 49 2 /9/2010 13:27 37 K1000968-017 50 2/9/2010 13:37 38 K1000968-018 51 2 /9 /2 0 1 0 1 3 :4 6 39 K1000968-019 52 2/9/2010 13:56 40 K1000968-020 53 2 /9/2010 14:06 67 KQ 1000620-03 54 2/9/2010 14:15 68 KQ 1000620-04 55 2/9/2010 16:46 7 PFC 20ppb CCV 56 2/9/2010 16:56 23 KQ 1000620-01 57 2/9/2010 17:05 24 KQ 1000620-02 58 2/9/2010 17:15 22 KQ 1000620-05 59 2/9/2010 17:24 21 K Q 1 0 0 0 6 2 0 -0 6 A cquisition M ethod P FC kinetexS hort.dam P FC kinetexS hort.dam P F C kinetexS hort.dam PFC kinetexS hort. dam P FC kinetexS hrt, dam P FC kinetexS hrt, dam P FC kinetexS hort.dam P FC kinetexS hort.dam P FC kinetexS hort.dam P FC kinetexS hort.dam P FC kinetexS hort.dam P F C kinetexS hort.dam P F C kinetexS hort.dam P F C kinetexS hort.dam P FC kinetexS hort.dam P F C kinetexS hort.dam P FC kinetexS hort.dam P F C kinetexS hort.dam P F C kinetexS hort.dam P F C kinetexS hort.dam P F C kinetexS hort.dam P F C kinetexS hort.dam P FC kinetexS hort.dam P F C kinetexS hort.dam P F C kinetexS hort.dam P F C kinetexS hort.dam P F C kinetexS hort.dam P FC kinetexS hort.dam P F C kinetexS hort.dam P F C kinetexS hort.dam P FC kinetexS hrt, dam P FC kinetexS hort.dam P F C kinetexS hort.dam P F C kinetexS hort. dam P F C kinetexS hort.dam P FC kinetexS hrt, dam PFC kinetexS hort.dam P F C kinetexS hort.dam P F C kinetexS hort.dam PFC kinetexShort. dam P F C kinetexS hort.dam P F C kinetexS hort.dam P F C kinetexS hort.dam PFC kinetexS hort.dam PFC kinetexShort.dam P F C kinetexS hort.dam P FC kinetexS hort.dam P FC kinetexS hort.dam P F C kinetexS hort.dam P FC kinetexS hort. dam P FC kinetexS hort.dam PFC kinetexS hort.dam P F C kinetexS hort.dam P FC kinetexS hort.dam P FC kinetexS hort.dam P FC kinetexS hort.dam P FC kinetexS hort.dam P FC kinetexShort. dam PFC kinetexS hort.dam File N am e 020810\C alS hort.w iff 020810\C alS hort.w iff 020810\C alS hort.w iff 02081 OVCalShort. w iff 02081 O X C alS hort.w iff 0 2 0 8 1 OVCalShort.w iff 020810\C alS hort.w iff 020810\C alS hort.w iff 020810\C alS hort.w iff 020810\C alS hort.w iff 020810\S am plesS hort.w iff 020810\S am plesS hort. w iff 020810\S am plesS hort.w iff 0 2 0 8 1 OVSamplesShort. w iff 020810\S am plesS hort. w iff 020810\S am plesS hort.w iff 0 2 0 8 1 O VSam plesShort.w iff 02081 OVSamplesShort. w iff 020810\S am plesS hort. w iff 020810\S am plesS hort,w iff 020810\S am plesS hort.w iff 02081 O VSam plesShort.w iff 020810\S am plesS hort.w iff 02081 O VSamplesShort. w iff 02081 OVSamplesShort. w iff 02081 OVSamplesShort. w iff 02081 OVSamplesShort. w iff 02081 OVSamplesShort. w iff 02081 OVSamplesShort.w iff 02081 OVSamplesShort. w iff 02081 OVSamplesShort. w iff 02081 O VSam plesShort.w iff 02081 O VSam plesShort.w iff 02081 O VS am plesShort.w iff 02081 O VS am plesShort.w iff 020810\S am plesS hort.w iff 02081 O VSam plesShort.w iff 02081 O VS am plesShort.w iff 02081 O VS am plesShort.w iff 02081 O VS am plesShort.w iff 02081 O VS am plesShort.w iff 02081 O VS am plesShort.w iff 02081 O VSam plesShort.w iff 02081 O VS am plesShort.w iff 02081 O VSam plesShort.w iff 02081 O VSam plesShort.w iff 02081 O VS am plesShort.w iff 02081 O VS am plesShort.w iff 02081 O VS am plesShort.w iff 02081 O VSam plesShort.w iff 02081 O VS am plesShort.w iff 02081 O VS am plesShort.w iff 02081 O VS am plesShort.w iff 02081 O VS am plesShort.w iff 02091 OVCalShort. w iff 02091 O VSamplesShort.wiff 02091 O VSamplesShort.wiff 02091 OVSamplesShort. w iff 02091 OVSam plesShort.w iff IS P e a k A re a (c o u r 0 2744000 2965500 2843300 3213800 2957400 3316000 3257900 3228800 3123300 4639400 4186200 4335800 4331900 4658500 4217300 4572000 4525200 4211300 4377000 4862200 4209400 3692800 4233000 4149500 4358600 4680100 4170300 4549400 4359600 4200600 4457300 5140400 5160100 5105600 4189100 4413900 4342000 5041100 4419900 4747500 4581000 4121500 4777100 4580700 4274300 4641000 4894400 4569300 4648100 4305000 4136100 4586500 4359900 3653800 4280400 4022000 3961000 4230300 t^l 307 rep Run#: 105462 earn: Petroleum HC/SMCDONALD Number o f Copies to make: 1 tl Lab Code Client ID Preparation information tsencnsneet Prep WorkFlow: OrgExtAq(14) Prep Method: Method B# V Method /Test Matrix Amt. Ext. Status: Draft Prep Date/Time: 2/4/10 07:33 AM P H Int. Voi Final Voi Surr Amt Spike An t K1000911-001 2.... Kt0009M-002 3 K1000911-003 1 : K10(H19! 1-004 5 K1000911-005 K1000911-006 7 K1000911-007 < K1000911-008 ? K1000911-009 fe K1000911-010 T K1000911-011 1.2 K10009U-012 13 K1000911-013 14 K1000911-014 KSJ K1000911-015 Q w K000911-016 17 K1000911-017 18 K1000911-018 19 K1000911-019 zq;. KQ1000532-04 21 KQ1000532-05 22 KQ1000532-06 Field B lank ti 1 Btlyson "Raw" Ellyson "Treated" Davis "Raw" Davis "Treated" O live ''Raw" O live "Treated" Carriage H ills "Raw" Carriage H ills "Treated" Watson " R a w " .... Watson "Treated" Kingsfield Road "Treated" Cantonment "Raw" Cantonment "Treatment" N ine M ile Road ''Raw" Nine M ile Road "Treated" No. 6 W ell Plant "R a w " y/ No. 6 W ell Plant "Treated" .-m b :> LCS DLOS et S S i/ P FO A/PFO A PFOA - PFOA PFO A/PFO A PFOA : PFOA . PFO A/PFO A fS p s p A V " - ; / P FO A/PFO A m PFOA PFOA P FO A/PFO A V ' PFOA PFOA t / PFO A/PFO A PFOA >PFOA PFOA / PFOA P F O A 'P F O A i / PFO A/PFO A PFOA P IO A y PFO A/PFO A PFOA ' PFOA V PFO A/PFO A PFOA / PFOA y ? PFO A/PFO A PFOA / PFOA :: :: : W ater W ater W ater Water '% W ater W ater W ater W ater W ater W 'attr W ater W ater W ater W ater W ater VVpr. W ater Water . W ater L iq u id L iq u id Liqu id: / ^ --' w J lX r :/ ' 4 "j s' H M s' r: S' I I / I I . ! .... j j 1j ? :' x AM - s^ Y ;: ' s S \ r Nr ~ KM M a C om m ents: l-S- L O f J 6 Z 'f t \ A Surrogate ID: I f 1. K ]V ft\L C ifl4 : M 6 S h IM -t fr Spike ID: Witnessed By: x-------- Amlvs,: ____ ________________________________________________ Printed 2 4 10 13:45 Assisted By: Preparation inform ation Benchsheet p e t-oa <--7 Page 1 Prep Run#: 105462 Team: Petroleum HC/SMCDONALD Number o f Copies to make: 1 3 Lab Code C lient ID l K 1000911-001 2 K1000911-019 3 K 1000911-018 4 K1000911-017 5 K1000911-016 6 K 1000911-015 7 K1000911-014 8 K 1000911-013 9 K 1000911-012 10 K 1000911-011 I t K1000911-010 12 K 1000911-009 13 K 1000911-008 14 K 1000911-007 & K 1000911-006 CO. 16 K 100 0911-005 17 K 1000911-004 18 K 1000911-003 19 K 1000911-002 20 KQ1000532-05 21 KQ1000532-06 22 K Q 1000532-04 Spiking Solutions Field Blank # 1 No. 6 W ell Plant "Treated" No. 6 W ell Plant "Raw" Nine M ile Road "Treated" Nine M ile Road "Raw" Cantonment "Treatment" Cantonment "Raw" Kingsfield Road "Treated" Kingsfield Road "Raw" Watson "Treated" Watson "R aw " Carriage H ills "Treated" Carriage H ills "Raw" Olive "Treated" Olive "Raw" Davis "Treated" Davis "Raw" Ellyson "Treated" Ellvson "Raw" LCS DLCS MB Preparation information tsencnsneet Prep WorkFIow: OrgExtAq(14) Prep Method: Method Status: Prepped Prep Date/Time: 2/4/10 07:33 AM B # Method /Test .01 PFOA/PFOA .01 PFOA/PFOA .01 PFOA'PFOA .01 P FO ATFO A .01 PFOA/PFOA .01 PFOA/PFOA .01 PFOA/PFOA .01 PFOA'PFOA .01 PFO ATFO A .01 PFO ATFO A .01 PFOA'PFOA .01 PFOA/PFOA .01 P FO A TFO A .01 PFOA'PFOA .01 PFOA'PFOA .01 PFO APFO A .01 PFOA'PFOA .01 PFO ATFO A .01 PFOA'PFOA PFOATFOA P F O A 'P F O A PFOATFOA pH Matrix / Water W ater Water / Water W ater W ater 1 Water / Water W ater X Water W ater Water W ater y Water W ater W ater Water Water 'W ater L iq u id Liquid L iq u id A m t. Ext. 20 0.0000m L 20 0.0000m L 20 0.00 00m L 20 0.00 00m L 20 0.0000m L 20 0.00 00m L 20 0.0000m L 2 0 0.00 00m L 200.00 00m L 2 0 0 .0 0 0 0 m l. 200.00 00m L 2 0 0.00 00m L 200.00 00m L 2 0 0.00 00m L 2 0 0.00 00m L 2 0 0.00 00m L 2 0 0.00 00m L 2 0 0.00 00m L 200.00 00m L 2 0 0.00 00m L 2 0 0 .0 0 0 0 m l. 200.00 00m L Final Voi S am ple Description l.OOmL l.OOmL l.OOmL l.OOmL l.OOmL l.OOmL l.OOmL l.OOmL l.OOmL l.OOmL l.OOmL l.OOmL l.OOmL l.OOmL l.OOmL l.OOmL 1 OOmL l.OOmL l.OOmL l.OOmL l.OOmL l.OOmL iV Name. Perfluorinated Surfactant Isotopes 1ppm Inventory ID 5362 K 100 0911-001 K 1 0 0 0 9 1 1-007 K 100 0911-013 K 1 0 0 0 9 1 1-019 io .oohL 10.0 0 | i L lO.OOpL io .oo^ L K 1000911-002 K 1 0 0 0 9 1 1-008 K 1 0 0 0 9 1 1-014 KQ1000532-04 lO.OOpL o.oopL o.oopL lo.oopL K 10 0 0 9 11-003 K 1 0 0 0 9 1 1-009 K .1 0 0 0 9 11-0 15 K Q 100 053 2-0 5 lO.OOjlL 10.00JlL lo.oopL i o .oo^i L Logbook Ref: LCMS2-26C K 1000911-004 K 1000911-010 K 1000911-016 KQ 1000532-06 10.00nL o.oopL lo.oonL o.oopL K 1000911-005 K 1 0 0 0 9 1 1-011 K 100 0911-017 lo.oo[tL lo.oonL o.oopL Expires On: 09/09/2009 K 1000911-006 K 1000911-012 K 1000911-018 o.oopL lo.oo(LL 1 0 .0 0 |l L Name: Perfluorinated Surfactants Targets 2ppm Inventory ID KQ1000532-05 10.0OpL KQ1000532-06 lo.OOpL 13189 Logbook Ref: LCMS2-76P Expires On: 10/29/2010 Printed 2 5 10 11:28 Preparation Information Bcnchsheet Page Prep Run#: 105462 Team: Petroleum HC/SMCDONALD Preparation Steps Step: Started: Finished: By: Extraction 2/4/10 07:33 2/5/10 11:28 SMC DONALD Preparation information isenctisneet Prep WorkFIow: OrgExtAq(14) Prep Method: Method Status: Prepped Prep Date/Time: 2/4/10 07:33 AM 310 Comments: --- ' Reviewed By: Chain o f Custody Relinquished By: Received By: Printed 2 5 10 1 1 :28 " " " Date: ~2-4 ,-- ^ Date: Date: 10 Extracts Examined / Yes \ No Preparation Information Benchsheet Page V J D IU IIlU Id Analytical Services p. 75 www.caslab.com February 22, 2010 Analytical Report for Service Request No: K1000968 David Anderson Camp Dresser & McKee, Incorporated 325 John Knox Road Building M, Suite 100 Tallahassee, FL 32303 RE: Baron & Budd, P.C./95779-753I9 Dear David: Enclosed are the results of the samples submitted to our laboratory on February 03, 2010. For your reference, these analyses have been assigned our service request number K1000968. Analyses were performed according to our laboratory's NELAP-approved quality assurance program. The test results meet requirements of the current NELAP standards, where applicable, and except as noted in the laboratory case narrative provided. For a specific list of NELAP-accredited analytes, refer to the certifications section at www.caslab.com. All results are intended to be considered in their entirety, and Columbia Analytical Services, Inc. (CAS) is not responsible for use of less than the complete report. Results apply only to the items submitted to the laboratory for analysis and individual items (samples) analyzed, as listed in the report. Please call if you have any questions. My extension is 3281. You may also contact me via Email at PDivvela@caslab.com. Respectfully submitted, Columbia Analytical Services, Inc. Prade Project Chemist PD/afs Page 1 of v c < r ASTM A2LA CARB CAS Number CFC CFU DEC DEQ DHS DOE DOH EPA ELAP GC GC/MS LUFT M MCL MDL MPN MRL NA NC NCASI ND NIOSH PQL RCRA SIM TPH tr Acronyms p' 76 American Society for Testing and Materials American Association for Laboratory Accreditation California Air Resources Board Chemical Abstract Service registry Number Chlorofluorocarbon Colony-Forming Unit Department of Environmental Conservation Department of Environmental Quality Department of Health Services Department of Ecology Department of Health U. S. Environmental Protection Agency Environmental Laboratory Accreditation Program Gas Chromatography Gas Chromatography/Mass Spectrometry Leaking Underground Fuel Tank Modified Maximum Contaminant Level is the highest permissible concentration of a substance allowed in drinking water as established by the USEPA. Method Detection Limit Most Probable Number Method Reporting Limit Not Applicable Not Calculated National Council of the Paper Industry for Air and Stream Improvement Not Detected National Institute for Occupational Safety and Health Practical Quantitation Limit Resource Conservation and Recovery Act Selected Ion Monitoring Total Petroleum Hydrocarbons Trace level is the concentration of an analyte that is less than the PQL but greater than or equal to the MDL. 2 Inorganic Data Qualifiers # The result is an outlier. See ease narrative. # The control lim it criteria is not applicable. See case narrative. 3 The analyte was found in the associated method blank at a level that is significant relative to the sample result as defined by the DOD o rN E L A C standards. E The result is an estimate amount because the value exceeded the instrument calibration range. J The result is an estimated value that was detected outside the quantitation range. ( j Tlie analyte was analyzed for, but was not detected ("Non-detect") at or above the M R L/M D L. DOD -QSM 4 1 definition: .Analyte was not detected and is reported as less than the LOD or as defined by the project. The detection lim it is adjusted for dilution, i The M R L /M D L o r LO Q /LO D is elevated due to a matrix interference. X See case narrative. Q See case narrative. One or more quality control criteria was outside the lim its. Metals Data Qualifiers # The control lim it criteria is not applicable. See case narrative. J The result is an estimated value that was detected outside the quantitation range. E The percent difference for the serial dilution was greater than 10%, indicating a possible matrix interference in the sample. M The duplicate injection precision was not met. N The M a trix Spike sample recovery is not w ithin control lim its. See case narrative. S The reported value was determined by the Method o f Standard Additions (M SA). The analyte was analyzed for, but was not detected ("Non-detect") at or above the M R L/M D L. DOD -OSM 4 1 definition: Analyte was not detected and is reported as less than the LOD or as defined by the project. The detection lim it is adjusted for dilution. W The post-digestion spike fo r furnace A A analysis is out o f control lim its, w hile sample ubsoibance is less than 50% o f spike absorbance. i The M R L /M D L or LO Q /LO D is elevated due to a matrix interference. X See case narrative. + The con-elation coefficient for the M S A is less than 0.995. Q See case narrative. One or more quality control criteria was outside the lim its. Organic Data Qualifiers # The result is an outlier. See case nanative. # The control lim it criteria is not applicable. See case narrative. A A tentatively identified compound, a suspected aldol-condensation product. B The analyte was found in the associated method blank at a level that is significant relative to the sample result as defined b y the DOD o rN E L A C standards. C The analyte was qualitatively confirmed using GC/MS techniques, pattern recognition, or by comparing to historical data. D The reported result is from a dilution. E The result is an estimate amount because the value exceeded the instrument calibration range. J The result is an estimated value that was detected outside the quantitation range. N The result is presumptive. The analyte was tentatively identified, but a confirmation analysis was not performed. p The GC or HPLC continuation criteria was exceeded. The relative percent difference is greater than 40% between the two analytical results. U The analyte was analyzed for, but was not detected ("Non-detect") at or above the M R L/M D L. DO D -Q SM 4 1 definition: A nalyte was not detected and is reported as less than the LOD or as defined by the project. The detection lim it is adjusted for dilution. i The M R L /M D L or LO Q /LO D is elevated due to a chromatographic interference. X See case nanative. Q See case narrative. One or more quality control criteria was outside the limits. Additional Petroleum Hydrocarbon Specific Qualifiers F The chromatographic fingerprint o f the sample matches the elution pattern o f the calibration standard. L The chromatographic fingerprint o f the sample resembles a petroleum product, but the elution pattern indicates thepresence o f a greater amount o f lighter molecular weight constituents than the calibration standard. H The chromatographic fingerprint o f the sample resembles a petroleum product, but the elution pattern indicates the presence o f a greater amount o f heavier molecular weight constituents than the calibration standard. O The chromatographic fingerprint o f the sample resembles an o il, but does not match the calibration standard. Y The chromatographic fingerprint o f the sample resembles a petroleum product eluting in approximately the correct carbon range, but the elution pattern does not match the calibration standard. Z The chromatographic fingerprint does not resemble a petroleum product. 3 p. 77 p. 78 Columbia Analytical Services, Inc. Kelso, WA State Certifications, Accreditations, and Licenses Program Alaska DEC UST Arizona DHS Arkansas - DEQ California DHS Colorado DPHE Florida DOH Hawaii DOH Idaho DHW Indiana DOH Louisiana DEQ Louisiana DHH Maine DHS Michigan DEQ Minnesota DOH Montana DPHHS Nevada DEP New Jersey DEP New Mexico ED North Carolina DWQ Oklahoma DEQ Oregon - DHS South Carolina DHEC Utah DOH Washington DOE Wisconsin DNR Wyoming (EPA Region 8) Number UST-040 AZ0339 88-0637 2286 - E87412 - - C-WA-01 3016 LA050010 WA0035 9949 053-999-368 CERT0047 WA35 WA005 - 605 9801 WA200001 61002 COLU C1203 998386840 - ACIL 4 Case Narrative 5 COLUMBIA ANALYTICAL SERVICES, INC. p. 80 Client: Project: Date Received: Sample Matrix: Camp Dresser & McKee, Inc. Baron & Budd, P C 02/03/10 to 02/04/10 Water Service Request No.: K1000968 CASE NARRATIVE All analyses were performed consistent with the quality assurance program of Columbia Analytical Services, Inc. (CAS). This report contains analytical results for samples designated for Tier III validation deliverables including summary forms and all of the associated raw data for each of the analyses. When appropriate to the method, method blank results have been reported with each analytical test. Sample Receipt Twenty water samples were received for analysis at Columbia Analytical Services between 02/03/10 and 02/04/10. The samples were received in good condition and consistent with the accompanying chain of custody form. The samples were stored in a refrigerator at 4C upon receipt at the laboratory. Perlluorinated Sulfonic Acids and Perfluorinated Carboxylic Acids by HPLC/MS Surrogate Exceptions: The recovery of Perlluoro-n-[l,2-13C2]undecanoic Acid in Field Blank 2, Bronson "Raw", W & Avery "Raw", West Well Plant "Treated", F:Scott "Raw", Bronson "Treated" MS, and Bronson "Raw" DMS was outside the control limits listed in the results summary. The limits are default values temporarily in use until sufficient data points are generated to calculate statistical control limits. Based on the method and historic data, the recoveries observed were in the range expected for this procedure. No further corrective action was taken. The recovery ofPerf!uoio-n-[l,2,3,4-13C4] butanoic acid, Perfluoro-n-[l,2-13C2]undecanoic Acid and Perfluoro-n[1.2-13C2]dodecanoic Acid in University Parkway "Treated" were outside the control limits listed in the results summary. The limits are default values temporarily in use until sufficient data points are generated to calculate statistical control limits. Based on the method and historic data, the recoveries observed were in the range expected for this procedure. No further corrective action was taken. The recovery of Perfluoro-n-[l,2-13C2]undecanoic Acid and Perfluoro-n-[l,2-13C2]dodecanoic Acid in McCory "Treated", Lillian "Raw", ", Lillian "Treated", West Pensacola "Raw", West Pensacola "Treated", W & Avery "Treated", West Well Plant "Raw", F:Scott "Treated", and Bronson "Raw" DMS were outside the control limits listed in the results summary. The limits are default values temporarily in use until sufficient data points are generated to calculate statistical control limits. Based on the method and historic data, the recoveries observed were in the range expected for this procedure. No further corrective action was taken No other anomalies associated with the analysis of these samples were observed. Approved by Date 6 o p. 81 Chain of Custody Documentation 7  S S S f s* - CHAIN O F CU STO D Y PROJECT NAME PROJECT NUMBER PROJECT MANAGER 1317 South 13th Ave. Kelso, WA 98626 (360)577-7222 (800)695-7222x07 FAX (360) 636-1068 *\sJW J - 4 f 3 r f C COMPANY ADDRESS __________U m __ .____________ _______ i ; d tW-o V y v i v L U L , CITY STATE 'ZIP V /l I I E-MAfL ADDRESS m \ <UL J fc L . i l- l % PHONE # g -fp ~ x u ~ H iF i SAMPLER'S SIGNATURE PAGE SR#: OF 3 COC # SAMPLE I.D. F, eU KZ p-*-C--' ^ RA^> " L>sTv'Wi'W Pa* *i ~ TtLm ^ * DATE TIME X .2../0 Oo 0 2-1.N O S /2 S 22. LAB I.D. MATRIX / / o2 J / <0/ W/*- /w / ^ / <e<d/ 'O / ^ / C / ^ f / lL )f if // / /A cCcsrY v fhc (o<-.f" * PvnfiiAjft-f l' R a *v 1 CO 0 ura AVj %| Jtcfii<sl /-i /|rfl<\ 1 08^8 ogss 0125 ~P /0 0 4 V* K IP JL V X X Br^fx/oA v'R.ftv-> >f REPORT REQUIREMENTS ___ 1. Routine Report: Method Blank, Surrogate, as required ___ II. Report Dup., MS, MSD as required ___III, Data Validation Report (includes all raw data) _N]V. CLP Deliverable Report /0/5 /cWJ \f '? INVC(ICE INFORMATION P.O. # Bill To: X V Total Metals: Al A s S b B a B e B C a C d C o C r C u Fe P b M g M n M o Ni K A g N a S e Sr T l Sn V Z n Hg Dissolved Metals: A l A s S b B a B e B C a C d C o C r C u F e P b M g M n M o N i K A g N a S e S r T l S n V Z n H g 'INDICATE STATE HYDROCARBON PROCEDURE: AK CA Wl NORTHWEST OTHER: TURNAROUND REQUIREMENTS SPECIAL INSTRUCTIONS/COMMENTS: 24 hr. 48 hr. ____ 5 Day V Standard (10-15 working days) 'X Provide FAX Results (CIRCLE ONE) yLv. EDD RELINQUISHED BY: Signature Printed Name Date/Time Firm Requested Report Date ________________________ A-----------------------------------------------------------------------------------------------------ha. V K RECEIVED BY: X\ K RELINQUISHED BY: RECEIVED BY: /Z.O 2. I. IO oco 2.2.IO -/Z - Signature , DateTTime Signature a Date/Time Signature/ urmfme u Avr.cf O D rA VAvrM / r * \ s C J ) / A / 2\?r. n- A 5 Printed Name Firm Printed Name Firm Printed Name Firm" RCOC #1 07-f0i Columbia Analytical Services* CHAIN O F CU STO D Y 1317 South 13th Ave. Kelso. WA 98626 (360)577-7222 (800) 695-7222x07 FAX (360) 636-1068 PROJECT NAME PROJECT NUMBER PROJECT MANAGER T S 3 / J ________________ 1 1 A Z w J t i / v i i Y i CJ ) M zPAGE SR#: Itim-Lf OF 3 COC # "Trc^aJ ' ~ UTraM^ " ^cnJcA 11 M.- / avj' Lm J + P<V\JTA c o /f t _____' ' PJV/C.1 2 .2 . / 0 2,. 2-/0 / o r ^ i., a -/o /<?4l 2 ,2 -o 2 .2 - / 0 IXC>3 /2- 6-^ 2 . -U? 5L X X U/ ; A ` /Uv 2 .1 .Ai /Z3-4 to )A us<h " 7>q*4.--) L Ussv\. p\+^Jr VV fCA vJ>--*- u>v> r *1 F - ' f c c U Vvfvvj l.X fa . 2 ./fc> 2 -2 ./ REPORT REQUIREMENTS ___ I. Routine Report: Method Blank, Surrogate, as required ___ II. Report Dup., MS, MSD as required ___III. Data Validation Report (includes all raw data) 'y c lV. CLP Deliverable Report y l V. EDD MS Qoo /J 0 5 6* /3 /Z (yOj "2 - 31 ^U J INVOICE INFORMATION P.O. # _______________ Bill To: _______ X i Total Metals: Al A s S b B a B e B C a C d C o C r C u Fe P b M g M n M o Ni K A g N a Se S r T l S n V Z n Hg Dissolved Metals: A l A s S b B a B e B C a C d C o C r C u F e P b M g M n M o N i K A g N a S e S r T l S n V Z n Fig INDICATE STATE HYDROCARBON PROCEDURE: AK CA Wl NORTHWEST OTHER:. TURNAROUND REQUIREMENTS SPECIAL INSTRUCTIONS/COMMENTS: ______24 hr. ______ 48 hr. ____ 5 Day Standard (10-15 working days) f Provide FAX Results Requested Report Date .(CIRCLE ONE) p RELINQUISHED BY: Signature Printed Name Date/Time Firm \ K RECEIVED BY: M i lwW . 2 -/./ Signature Date/Time uak/~A ^ * W w o - Cji? Printed Name Firm \ a RELINQUISHED BY: f ? 4 '& Signature 2.1.1 o Date/Time Printed Name Firm RECEIVED BY: Qnature^ FToh S Printed Name z./%/fo O Z o Dat/1'fme , 4- C Firm RCOC #1 0 7 'OS Columbia Analytical Services'* CHAIN O F CU STO D Y 1317 South 13th Ave. Kelso, WA 98626 (360)577-7222 (800)695-7222x07 FAX (360) 636-1068 PROJECT NUMBER -^ ^ ^ ~3s 3 /? , t'C ! PROJECT MANAGER f v .____________ ______ UASjn L - h r J u L K j y M COMPANY`ADDRESS * _ _ . i W f i Ic -o_______________ m _______ /r>OM / ///<&A? CIT" IP E-MAIL ADDRESS T a il *d ^ /Y \e a / PH0NE` k^S O ^ SAMPLER'S SIGNATURE`S FAX# 1 2 o <i / o f J7 &O / &p: SAMPLE I.D. DATE TIME LAB I.D. MATRIX / i5- / D_^2 _ fJo, fo fi**- : a >o 2,.2'fe /Hot) -a. 2 ./ PAGE SR#: U0^OLe)( 3OF COC #_______ REMARKS X REPORT REQUIREMENTS ___ I. Routine Report: Method Blank, Surrogate, as required ___ II. Report Dup., MS, MSD as required ___III. Data Validation Report (includes all raw data) Y IV. CLP Deliverable Report INVOICE INFORMATION P.O. # _______________ Bill To: ______ Circle which m etals are to be analyzed: Total Metals: A l A s S b B a B e B C a C d C o C r C u Fe Pb M g M n M o Ni K A g N a Se S r T l Sn V Z n Hg Dissolved Metals: A l A s S b B a B e B C a C d C o C r C u F e P b M g M n M o N i K A g N a S e S r T l S n V Z n H g ' INDICATE STATE HYDROCARBON PROCEDURE: AK CA Wl NORTHWEST OTHER:_ TURNAROUND REQUIREMENTS SPECIAL INSTRUCTIONS/COMMENTS: ______24 hr. ______ 4 8 hr. ____ 5 Day Standard (10-15 working days) .(CIRCLE ONE) Provide FAX Results ^0. V. EDO Requested Report Date oo P RELINQUISHED BY: S ignature P rinted N am e " Date/Time Firm \ Signature RECEIVED BY: Z -f./o Date/Time Printed Name Firm \ RELINQUISHED BY: 2. j . / o /fe0 Signature . DateTTime D AiaJ ecoA Oj \j\ Printed Name Firm RECEIVED BY: Signj&'Tjrea D atti-07//TTiip^Jrieetp Printed Name / *G RCOC #1 0 7 .O A i Columbia 9 Analytical Services' CHAIN O F CU STO D Y 1317 South 13th Ave. Kelso, WA 98626 (360)577-7222 (800)695-7222x07 FAX (360) 636-1068 lr \ P* PAGE SR#: OF 3_____ COC # .3-/6 ev* U . * / 1 1 ^ 'A*" 1 H^yler u.aq 'LTf*ui,4i %0\ <3l3 if n .-A T/ft-l "Vo" os 33 Cu; X X M 'S ^ T -rrt'l /Vii"FcRr.'/-VfWA7o^+A XTSjFpr - - T r ^ U i 1 08^3 O O TF o ?23 C' T: ? T X AleA/I.-jW " 0 0 2 . MaovAt /il.M-rVror if " \r T REPORT REQUIREMENTS ___ I. Routine Report: Method Blank, Surrogate, as required ___ II. Report Dup., MS, MSD as required ___III. Data Validation Report (includes all raw data) X IV. CLP Deliverable Report X v- edd INVOICE INFORMATION P.O. # _______________ Bill To: Circle which m etals are to be analyzed: Total Metals: A l A s S b B a B e B C a C d C o C r C u Fe P b M g M n M o Ni K A g N a S e S r T l S n V Z n Hg Dissolved Metals: A l A s S b B a B e B C a C d C o C r C u F e P b M g M n M o N i K A g N a S e S r T l S n V Z n H g INDICATE STATE HYDROCARBON PROCEDURE: AK CA Wl NORTHWEST OTHER: TURNAROUND REQUIREMENTS SPECIAL INSTRUCTIONS/COMMENTS: ______24 hr. ______ 48 hr. _____ 5 Day (CIRCLE ONE) Standard (10-15 working days) Provide FAX Results Requested Report Date Container Supply Number 16394 16394 0001 RELINQUISHED BY: Signature Printed Name Date/Time Firm V REC EIVED BY: Signature 7. ' DA^M Printed Name z j -< Date/Time <2J) a a Firm K K RELINQ UISHED BY : Signature tJ Printed Name 2 3 ./0 Date/Time C o i\ Firm / t ' Printed D7 H // R f .n n #1 0 7 /n Client / Project:/ Received: Cooler Receipt and Preservation Form UL ___________ Opened: ,__________ Servic^R^quest K10 (^ Y ) By: P- 86 f^ 1. Samples were received via? Mail ( \ Fed UPS DHL Pi Hand Delivered 2. Samples were received in: (circle) c Cooler^ 3. Were custody seals on coolers? NA If present, were custody seals intact? Box N N Envelope HIf yes, how many and where?_ i- If present, were they signed and dated? NA N Cooler Temp C 7/ 9.0 fa Temp Blank *C J.b .Z t.j .f Thmermmommetemr * Ul 9.W W ____ Cooler/COC , tD r Tracking Num ber 7. Packing material used. Inserts Saggiest Bubble Wrap Gel Packs (WetlcS'-i Sleeves Other_______ NA Filed \P ~%r y 8. Were custody papers properly filled out (ink, signed, etc.)? 9. Did all bottles arrive in good condition (unbroken)? Indicate in the table below. NA ) NA ) N N 10. Were all sample labels complete (i.e analysis, preservation, etc.)? NA $ ) N 11. Did all sample labels and tags agree with custody papers? Indicate major discrepancies in the table on page 2. NA m N 12. Were appropriate bottles/containers and volumes received for the tests indicated? na (y N 13. Were the pH-preserved bottles (see SMO GENSOP) received at the appropriate pH? Indicate in the table below ^ YN 14. Were VOA vials received without headspace? Indicate in the table below. 15. Was C12/Res negative? Sample ID on Bottle Sample ID on COC tY N YN Identified by; Sample ID i Bottle Count Out of HeadA Bottle Type Temp apace Broke pH ^ Reagent Volume Reagent Lot added Number Initials Time Notes, Discrepancies, & Resolutions: 12 Page__1__ of_ V_/ L /IU ^ & IK 4 1 J tlU M I L /V I V X l l V .I Cooler Receipt and Preservation Form P.<87 x Client / Project:_____ Received: W l / z o __________________ Service Request K10 0 0 0pened:_ a L>a > By:. [/ 1. Samples were received via? Mail ^ f e d ExTj UPS DHL PDX Courier Hand Delivered 2. Samples were received in: (circle) ^ C o o titp Box Envelope Other______________________ 3. Were custody seals on coolers? NA ( T j N If yes, how many and where? Jifre-N_____ If present, were custody seals intact? ($> N If present, were they signed and dated? Cooler Temp C i.s -a 3 /./ O. 7 Temp Blank C Thermometer ID `(b Z7 7 Z-C? .m Cooler/COC ID v -- Tracking Number NA N HfC,^ ile c T ' **-- --* 7. Packing material used. Inserts c^tiseiS sc, ^^trBfleWrd^ Gel Packs ^WetTce vSleeves Other 8. Were custody papers properly filled out (ink, signed, etc.)? NA N 9. Did all bottles arrive in good condition (unbroken)? Indicate in the table below. NA N 10. Were all sample labels complete (i.e analysis, preservation, etc.)? NA N 11. Did all sample labels and tags agree with custody papers? Indicate major discrepancies in the table on page 2. 12. Were appropriate bottles/containers and volumes received for the tests indicated? 13. Were the pH-preserved bottles (see SMO GENSOP) received at tire appropriate pH? Indicate in the table below NA <Z> N NA <> N YN 14. Were VOA vials received without headspace? Indicate in the table below. YN 15. Was C12/Res negative? &YN Sample ID on Bottle Sample ID on COC Identified by: Sample ID Bottle Count Out of Head' Bottle Type ; Temp spade Broke pH Volume Reagent Lot Reagent added Number Initials Time Notes, Discrepancies, & Resolutions: 13 Page 1 of p. 88 Perfluorinated Sulfonic Acids and Perfluorinated Carboxylic Acids by HPCL/MS 14 Client: Project: Sample Matrix: Sample Name: Lab Code: Analytical Report Camp Dresser & McKee, Incorporated (CDM) Baron & Budd, P.C./95779-75319 Water Field Blank 2 K 1000968-001 p. 89 Service Request: K 1000968 Date Collected: 2/ 2/10 0800 Date Received: 2/ 3/10 Units: ng/L Basis: NA Perfluorinated Sulfonic Acids and Perfluorinated Carboxylic Acids by HPLC/MS Analytical Method: PFOA Prep Method: Method Analyte Name Perfluoro-n-tetradecanoic acid Perfluoro-n-tridecanoic acid Perfluorobutanesulfonate Perfluorobutanoic Acid Perfluorodecane Sulfonate Perfluorodecanoic Acid Perfluorododecanoic Acid Perfluoroheptanoic Acid Perfluorohexanesulfonate Perfluorohexanoic Acid Perfluorononanoic Acid Perfluorooctanesulfonate Perfluorooctanoic Acid Perfluoropentanoic Acid Perfluoroundecanoic Acid Result Q ND U ND U ND u 0.47 J ND u ND u ND u ND u 0.19 J 0.23 J ND u 0.18 J ND u 0.33 J ND u MRL Dilution Date Date Extraction Analysis MDL Factor Extracted Analyzed Lot Lot Note 5.0 0.46 5.0 0.95 5.0 0.029 1 2/8/10 2/9/1000:10 105653 190530 1 2/8/10 2/9/1000:10 105653 190530 1 2/8/10 2/9/1010:55 105653 190530 5.0 0.11 5.0 0.095 5.0 0.48 1 2/8/10 2/9/1010:55 105653 190530 1 2/8/10 2/9/1000:10 105653 190530 1 2/8/10 2/9/1000:10 105653 190530 5.0 0.85 5.0 0.081 5.0 0.030 1 2/8/10 2/9/1000:10 105653 190530 1 2/8/10 2/9/1010:55 105653 190530 1 2/8/10 2/9/1010:55 105653 190530 5.0 0.11 5.0 0.12 5.0 0.046 5.0 0.066 5.0 0.11 5.0 1.3 1 2/8/10 2/9/1010:55 105653 190530 1 2/8/10 2/9/1000:10 105653 190530 1 2/8/10 2/9/1000:10 105653 190530 1 2/8/10 2/9/1000:10 105653 190530 1 2/8/10 2/9/1010:55 105653 190530 1 2/8/10 2/9/1000:10 105653 190530 Surrogate Name Perfluoro-n-[l,2,3,4,5-13C5] nonanoic acid Perfluoro-n-[l,2,3,4-13C4] butanoic acid Perfluoro-n-[l,2,3,4-13C4] octanoic acid Perfluoro-n-[l,2-13C2] decanoic acid Perfluoro-n-[l,2-13C2] hexanoicacid Perfluoro-n-[ 1,2-13C2]dodecanoic Acid Perfluoro-n-[l,2-13C2]undecanoic Acid Sodium perfluoro-l-[l,2,3,4-13C4] octanesulfonate Sodium perfluoro-1-hexanef1802] sulfonate %Rec 98 73 94 100 75 60 48 * 71 70 Control Limits 50-150 50-150 50-150 50-150 50-150 50-150 50-150 50-150 50-150 Date Analyzed 2/9/10 00:10 2/9/10 10:55 2/9/10 00:10 2/9/10 00:10 2/9/10 10:55 2/9/10 00:10 2/9/10 00:10 2/9/10 00:10 2/9/10 10:55 Q Note Comments: Printed 2/23/10 13:37 \\Inilow2\Starlims\LimsReps\AnaiyticalReport.rpt Form 1A 15 SuperSct Reference: 10-0000135123 rev 00 Client: Project: Sample Matrix: Sample Name: Lab Code: Analytical Report Camp Dresser & McKee, Incorporated (CDM) Baron & Budd, P.C./95779-75319 Water University Parkway "Raw" KI000968-002 p. 90 Service Request: K1000968 Date Collected: 212/10 0812 Date Received: 2/ 3/10 Units: ng/L Basis: NA Perfluorinated Sulfonic Acids and Perfluorinated Carboxylic Acids by HPLC/MS Analytical Method: PFOA Prep Method: Method Analyte Name Perfluoro-n-tetradecanoic acid Perfluoro-n-tridecanoic acid Perfluorobutanesulfonate Perfluorobutanoic Acid Perfluorodecane Sulfonate Perfluorodecanoic Acid Perfluorododecanoic Acid Perfluoroheptanoic Acid Perfluorohexanesulfonate Perfluorohexanoic Acid Perfluorononanoic Acid Perfluorooctanesulfonate Perfluorooctanoic Acid Perfluoropentanoic Acid Perfluoroundecanoic Acid Result Q ND u ND u 0.12 J 0.18 J ND u ND u ND u 0.12 J 0.18 J 0.35 J ND u 0.31 J ND u 0.25 J ND u MRL 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 MDL 0.46 0.95 0.029 0.11 0.095 0.48 0.85 0.081 0.030 0.11 0.12 0.046 0.066 0.11 1.3 Dilution Date Date Extraction Analysis Factor Extracted Analyzed Lot Lot Note 1 2/ 8/10 2/9/10 00:18 105653 190530 1 2/ 8/10 2/9/10 00:18 105653 190530 1 2/ 8/10 2/9/10 11:04 105653 190530 1 2/ 8/10 2/9/10 11:04 105653 190530 1 2/ 8/10 2/9/10 00:18 105653 190530 1 2/ 8/10 2/9/10 00:18 105653 190530 1 2/ 8/10 2/9/10 00:18 105653 190530 1 2/ 8/10 2/9/10 11:04 105653 190530 1 2/ 8/10 2/9/10 11:04 105653 190530 1 2/ 8/10 2/9/10 11:04 105653 190530 1 2/ 8/10 2/9/10 00:18 105653 190530 1 2/ 8/10 2/9/10 00:18 105653 190530 1 2/ 8/10 2/9/10 00:18 105653 190530 1 2/ 8/10 2/9/10 11:04 105653 190530 1 2/ 8/10 2/9/10 00:18 105653 190530 Surrogate Name Perfluoro-n-[l,2,3,4,5-13C5] nonanoic acid Perfluoro-n-[l,2,3,4-13C4] butanoic acid Perfluoro-n-[l,2,3,4-13C4] octanoic acid Perfluoro-n-[l,2-13C2] decanoicacid Perfluoro-n-[l,2-13C2] hexanoicacid Perfluoro-n-[1,2-13C2]dodecanoic Acid Perfluoro-n-[1,2-13C2]undecanoic Acid Sodiumperfluoro-l-[l,2,3,4-13C4] octanesulfonate Sodium perfluoro-1-hexane[1802]sulfonate %Rec 78 55 78 100 62 55 54 60 71 Control Limits 50-150 50-150 50-150 50-150 50-150 50-150 50-150 50-150 50-150 Date Analyzed 2/9/10 00:18 2/9/10 11:04 2/9/10 00:18 2/9/10 00:18 2/9/10 11:04 2/9/10 00:18 2/9/10 00:18 2/9/10 00:18 2/9/10 11:04 Q Note Comments: Printed 2/23/10 13:37 \VInflow2\Starlims\LimsReps\AnalyticaIReport.ipt Form 1A 16 SuperSet Reference: 10-0000135123 rev 00 Client: Project: Sample Matrix: Sample Name: Lab Code: Analytical Report Camp Dresser & McKee, Incorporated (CDM) Baron & Budd, P.C./95779-75319 Water University Parkway "Treated" K1000968-003 p. 91 Service Request: K1000968 Date Collected: 2/ 2/10 0822 Date Received: 2/ 3/10 Units: ng/L Basis: NA Perfluorinated Sulfonic Acids and Perfluorinated Carboxylic Acids by HPLC/MS Analytical Method: PFOA Prep Method: Method Analyte Name Perfluoro-n-tetradecanoic acid Perfluoro-n-tridecanoic acid Perfluorobutanesulfonate Perfluorobutanoic Acid Perfluorodecane Sulfonate Perfluorodecanoic Acid Perfluorododecanoic Acid Perfluoroheptanoic Acid Perfluorohexanesulfonate Perfluorohexanoic Acid Perfluorononanoic Acid Perfluorooctanesulfonate Perfluorooctanoic Acid Perfluoropentanoic Acid Perfluoroundecanoic Acid Result Q ND U ND U 0.13 J 0.55 J 0.18 J ND U ND u ND u 0.18 J ND u ND u 0.26 J ND u 0.14 J ND u MRL 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 MDL 0.46 0.95 0.029 0.11 0.095 0.48 0.85 0.081 0.030 0.11 0.12 0.046 0.066 0.11 1.3 Dilution Date Date Extraction Analysis Factor Extracted Analyzed Lot Lot Note 1 2/ 8/10 2/9/10 00:25 105653 190530 1 2/ 8/10 2/9/10 00:25 105653 190530 1 2/ 8/10 2/9/10 11:14 105653 190530 1 2/ 8/10 2/9/10 11:14 105653 190530 1 2/ 8/10 2/9/10 00:25 105653 190530 1 2/ 8/10 2/9/10 00:25 105653 190530 1 2/ 8/10 2/9/10 00:25 105653 190530 1 2/ 8/10 2/9/10 11:14 105653 190530 1 2/ 8/10 2/9/10 11:14 105653 190530 1 2/ 8/10 2/9/10 11:14 105653 190530 1 2/ 8/10 2/9/10 00:25 105653 190530 1 2/ 8/10 2/9/10 00:25 105653 190530 1 2/ 8/10 2/9/10 00:25 105653 190530 1 2/ 8/10 2/9/10 11:14 105653 190530 1 218/10 2/9/10 00:25 105653 190530 Surrogate Name Perfluoro-n-[l,2,3,4,5-13C5] nonanoic acid Perfluoro-n-[l,2,3,4-13C4] butanoic acid Perfluoro-n-[l,2,3,4-13C4] octanoic acid Perfluoro-n-[l,2-13C2] decanoicacid Perfluoro-n-[l,2-13C2] hexanoic acid Perfluoro-n-[ 1,2-13C2]dodecanoic Acid Perfluoro-n-[1,2-13C2]undecanoic Acid Sodium perfluoro-l-[l,2,3,4-13C4] octanesulfonate Sodium perfluoro-1-hexane[1802]sulfonate %Rec 86 11 * 86 100 75 43 * 47 * 63 75 Control Limits 50-150 50-150 50-150 50-150 50-150 50-150 50-150 50-150 50-150 Date Analyzed 2/9/10 00:25 2/9/10 11:14 2/9/10 00:25 2/9/10 00:25 2/9/10 11:14 2/9/10 00:25 2/9/10 00:25 2/9/10 00:25 2/9/10 11:14 Q Note Comments: Printed 2/23/10 13:37 \\Infiow2\Starlims\LimsReps\AnalyticalReport.ipt Form 1A 17 Superset Reference: 10-0000135123 rev 00 Client: Project: Sample Matrix: Sample Name: Lab Code: Analytical Report Camp Dresser & McKee, Incorporated (CDM) Baron & Budd, P.C./95779-75319 Water McCoiy "Raw" K 1000968-004 p. 92 Service Request: K1000968 Date Collected: 2/ 2/10 0848 Date Received: 2/ 3/10 Units: ng/L Basis: NA Perfluorinated Sulfonic Acids and Perfluorinated Carboxylic Acids by HPLC/MS Analytical Method: PFOA Prep Method: Method Analyte Name Perfluoro-n-tetradecanoic acid Perfluoro-n-tridecanoic acid Perfluorobutanesulfonate Perfluorobutanoic Acid Perfluorodecane Sulfonate Perfluorodecanoic Acid Perfluorododecanoic Acid Perfluoroheptanoic Acid Perfluorohexanesulfonate Perfluorohexanoic Acid Perfluorononanoic Acid Perfluorooctanesulfonate Perfluorooctanoic Acid Perfluoropentanoic Acid Perfluoroundecanoic Acid Result Q ND U ND U 0.35 J 0.42 J ND U ND u ND u 0.46 J 1.7 J 1.1 J ND u 0.95 J 5.2 0.88 J ND u MRL 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 MDL 0.46 0.95 0.029 0.11 0.095 0.48 0.85 0.081 0.030 0.11 0.12 0.046 0.066 0.11 1.3 Dilution Date Date Extraction Analysis Factor Extracted Analyzed Lot Lot Note 1 2/ 8/10 2/9/10 00:33 105653 190530 1 2/ 8/10 2/9/10 00:33 105653 190530 1 2/ 8/10 2/9/10 11:23 105653 190530 1 2/ 8/10 2/9/10 11:23 105653 190530 1 2/ 8/10 2/9/10 00:33 105653 190530 1 2/ 8/10 2/9/10 00:33 105653 190530 1 2/ 8/10 2/9/10 00:33 105653 190530 1 2/ 8/10 2/9/10 11:23 105653 190530 1 2/ 8/10 2/9/10 11:23 105653 190530 1 2/ 8/10 2/9/10 11:23 105653 190530 1 2/ 8/10 2/9/10 00:33 105653 190530 1 2/ 8/10 2/9/10 00:33 105653 190530 1 2/ 8/10 2/9/10 00:33 105653 190530 1 2/ 8/10 2/9/10 11:23 105653 190530 1 2/ 8/10 2/9/10 00:33 105653 190530 Surrogate Name Perfluoro-n-[l,2,3,4,5-13C5] nonanoic acid Perfluoro-n-[l,2,3,4-13C4] butanoic acid Perfluoro-n-[l,2,3,4-1304] octanoic acid Perfluoro-n-[l,2-13C2] decanoic acid Perfluoro-n-[l,2-13C2] hexanoicacid Perfluoro-n-[1,2-13C2]dodecanoic Acid Perfluoro-n-[l ,2- 13C2]undecanoic Acid Sodiumperfluoro-l-[l,2,3,4-13C4] octanesulfonate Sodium perfluoro-1-hexane[1802]sulfonate %Rec 97 68 93 100 71 56 60 74 83 Control Limits 50-150 50-150 50-150 50-150 50-150 50-150 50-150 50-150 50-150 Date Analyzed 2/9/10 00:33 2/9/10 11:23 2/9/10 00:33 2/9/10 00:33 2/9/10 11:23 2/9/10 00:33 2/9/10 00:33 2/9/10 00:33 2/9/10 11:23 Q Note C om m ents: Printed 2/23/10 13:37 \\Inflow2\Starhms\LimsReps\AnalyticalReport.rpt Form 1A 18 SuperSet Reference: 10-0000135123 rev 00 Client: Project: Sample Matrix: Sample Name: Lab Code: Analytical Report Camp Dresser & McKee, Incorporated (CDM) Baron & Budd, P.C./95779-75319 Water McCory "Treated" K1000968-005 p. 93 Service Request: KI000968 Date Collected: 2/ 2/10 0858 Date Received: 2/ 3/10 Units: ng/L Basis: NA Perfluorinated Sulfonic Acids and Perfluorinated Carboxylic Acids by HPLC/MS Analytical Method: PFOA Prep Method: Method Analyte Name Perfluoro-n-tetradecanoic acid Perfluoro-n-tridecanoic acid Perfluorobutanesulfonate Perfluorobutanoic Acid Perfluorodecane Sulfonate Perfluorodecanoic Acid Perfluorododecanoic Acid Perfluoroheptanoic Acid Perfluorohexanesulfonate Perfluorohexanoic Acid Perfluorononanoic Acid Perfluorooctanesulfonate Perfluorooctanoic Acid Perfluoropentanoic Acid Perfluoroundecanoic Acid Result Q ND U ND U 0.35 J 0.40 J 0.12 J ND U ND u 0.54 J 1.8 J 1.0 J ND u 0.88 J 5.0 0.82 J ND u MRL 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 MDL 0.46 0.95 0.029 0.11 0.095 0.48 0.85 0.081 0.030 0.11 0.12 0.046 0.066 0.11 1.3 Dilution Date Date Extraction Analysis Factor Extracted Analyzed Lot Lot Note 1 2/ 8/10 2/9/10 00:40 105653 190530 1 2/ 8/10 2/9/10 00:40 105653 190530 1 2/ 8/10 2/9/10 11:33 105653 190530 1 2/ 8/10 2/9/10 11:33 105653 190530 1 2/ 8/10 2/9/10 00:40 105653 190530 1 2/ 8/10 2/9/10 00:40 105653 190530 1 2/ 8/10 2/9/10 00:40 105653 190530 1 2/ 8/10 2/9/10 11:33 105653 190530 1 2/ 8/10 2/9/10 11:33 105653 190530 1 2/ 8/10 2/9/10 11:33 105653 190530 1 2/ 8/10 2/9/10 00:40 105653 190530 1 2/ 8/10 2/9/10 00:40 105653 190530 1 2/ 8/10 2/9/10 00:40 105653 190530 1 218/10 2/9/10 11:33 105653 190530 1 2/ 8/10 2/9/10 00:40 105653 190530 Surrogate Name Perfluoro-n-[l,2,3,4,5-13C5] nonanoic acid Perfluoro-n-[l,2,3,4-13C4] butanoic acid Perfluoro-n-[l,2,3,4-13C4] octanoic acid Perfluoro-n-[l,2-13C2] decanoicacid Perfluoro-n-[l,2-13C2] hexanoicacid Perfluoro-n-[ 1,2-13C2]dodecanoic Acid Perfluoro-n-[ 1,2-13C2]undecanoic Acid Sodium perfluoro-l-[l,2,3,4-13C4] octanesulfonate Sodium perfluoro-1-hexane[ 1802Jsulfonate %Rec 77 66 82 100 72 47 * 49 * 60 81 Control Limits 50-150 50-150 50-150 50-150 50-150 50-150 50-150 50-150 50-150 Date Analyzed 2/9/10 00:40 2/9/10 11:33 2/9/10 00:40 2/9/10 00:40 2/9/10 11:33 2/9/10 00:40 2/9/10 00:40 2/9/10 00:40 2/9/10 11:33 Q Note Comments: Printed 2/23/10 13:37 \\Inflow2\StarUms\LimsReps\AnalyticalReport.rpt Form 1A 19 SuperSet Reference: 10-0000135123 rev 00 Client: Project: Sample Matrix: Sample Name: Lab Code: Analytical Report Camp Dresser & McKee, Incorporated (CDM) Baron & Budd, P.C./95779-75319 Water Dunaway "Raw" K1000968-006 p. 94 Service Request: K 1000968 Date Collected: 2/ 2/10 0929 Date Received: 2/ 3/10 Units: ng/L Basis: NA Perfluorinated Sulfonic Acids and Perfluorinated Carboxylic Acids by HPLC/MS Analytical Method: PFOA Prep Method: Method Analyte Name Perfluoro-n-tetradecanoic acid Perfluoro-n-tridecanoic acid Perfluorobutanesulfonate Perfluorobutanoic Acid Perfluorodecane Sulfonate Perfluorodecanoic Acid Perfluorododecanoic Acid Perfluoroheptanoic Acid Perfluorohexanesulfonate Perfluorohexanoic Acid Perfluorononanoic Acid Perfluorooctanesulfonate Perfluorooctanoic Acid Perfluoropentanoic Acid Perfluoroundecanoic Acid Result Q ND U ND U 0.15 J 0.29 J ND U ND U ND u 0.15 J 0.56 J 0.34 J ND u 0.47 J ND u 0.33 J ND u MRL 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 MDL 0.46 0.95 0.029 0.11 0.095 0.48 0.85 0.081 0.030 0.11 0.12 0.046 0.066 0.11 1.3 Dilution Date Date Extraction Analysis Factor Extracted Analyzed Lot Lot Note 1 2/ 8/10 2/9/10 00:48 105653 190530 1 2/ 8/10 2/9/10 00:48 105653 190530 1 2/ 8/10 2/9/10 11:42 105653 190530 1 2/ 8/10 2/9/10 11:42 105653 190530 1 2/ 8/10 2/9/10 00:48 105653 190530 1 2/ 8/10 2/9/10 00:48 105653 190530 1 2/ 8/10 2/9/10 00:48 105653 190530 1 2/ 8/10 2/9/10 11:42 105653 190530 1 2/ 8/10 2/9/10 11:42 105653 190530 1 2/ 8/10 2/9/10 11:42 105653 190530 1 2/ 8/10 2/9/10 00:48 105653 190530 1 2/ 8/10 2/9/10 00:48 105653 190530 1 2/ 8/10 2/9/10 00:48 105653 190530 1 2/ 8/10 2/9/10 11:42 105653 190530 1 2/ 8/10 2/9/10 00:48 105653 190530 Surrogate Name Perfluoro-n-[l,2,3,4,5-13C5] nonanoic acid Perfluoro-n-[l,2,3,4-13C4] butanoic acid Perfluoro-n-[l,2,3,4-13C4] octanoic acid Perfluoro-n-[l,2-13C2] decanoicacid Perfluoro-n-[l,2-13C2] hexanoic acid Perfluoro-n-[1,2-13C2]dodecanoic Acid Perfluoro-n-[l,2-13C2]undecanoic Acid Sodium perfluoro-l-[l,2,3,4-13C4] octanesulfonate Sodium perfluoro-1-hexane[1802]sulfonate %Rec 94 68 85 100 75 68 68 75 85 Control Limits 50-150 50-150 50-150 50-150 50-150 50-150 50-150 50-150 50-150 Date Analyzed 2/9/10 00:48 2/9/10 11:42 2/9/10 00:48 2/9/10 00:48 2/9/10 11:42 2/9/10 00:48 2/9/10 00:48 2/9/10 00:48 2/9/10 11:42 Q Note Comments: Printed 2/23/10 13:37 \\Inflow2\Starlims\LimsReps\AnalyticalReportrpt Form 1A 20 SuperSet Reference: 10-0000135123 rev 00 Client: Project: Sample Matrix: Sample Name: Lab Code: Analytical Report Camp Dresser & McKee, Incorporated (CDM) Baron & Budd, P.C./95779-75319 Water Dunaway "Treated" K1000968-007 p. 95 Service Request: K 1000968 Date Collected: 2/ 2/10 0939 Date Received: 2/3/10 Units: ng/L Basis: NA Perfluorinated Sulfonic Acids and Perfluorinated Carboxylic Acids by HPLC/MS Analytical Method: PFOA Prep Method: Method Analyte Name Perfluoro-n-tetradecanoic acid Perfluoro-n-tridecanoic acid Perfluorobutanesulfonate Perfluorobutanoic Acid Perfluorodecane Sulfonate Perfluorodecanoic Acid Perfluorododecanoic Acid Perfluoroheptanoic Acid Perfluorohexanesulfonate Perfluorohexanoic Acid Perfluorononanoic Acid Perfluorooctanesulfonate Perfluorooctanoic Acid Perfluoropentanoic Acid Perfluoroundecanoic Acid Result Q ND U ND u 0.14 J 0.15 J ND u ND u ND u 0.093 J 0.55 J 0.33 J ND u 0.38 J ND u 0.18 J ND u MRL 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 MDL 0.46 0.95 0.029 0.11 0.095 0.48 0.85 0.081 0.030 0.11 0.12 0.046 0.066 0.11 1.3 Dilution Date Date Extraction Analysis Factor Extracted Analyzed Lot Lot Note 1 2/ 8/10 2/9/10 00:55 105653 190530 1 2/ 8/10 2/9/10 00:55 105653 190530 1 2/ 8/10 2/9/10 11:52 105653 190530 1 2/ 8/10 2/9/10 11:52 105653 190530 1 2/ 8/10 2/9/10 00:55 105653 190530 1 2/ 8/10 2/9/10 00:55 105653 190530 1 2/ 8/10 2/9/10 00:55 105653 190530 1 2/ 8/10 2/9/10 11:52 105653 190530 1 2/ 8/10 2/9/10 11:52 105653 190530 1 2/ 8/10 2/9/10 11:52 105653 190530 1 2/ 8/10 2/9/10 00:55 105653 190530 1 2/ 8/10 2/9/10 00:55 105653 190530 1 2/ 8/10 2/9/10 00:55 105653 190530 1 2/ 8/10 2/9/10 11:52 105653 190530 1 2/ 8/10 2/9/10 00:55 105653 190530 Surrogate Name Perfluoro-n-[l,2,3,4,5-13C5] nonanoic acid Perfluoro-n-[l,2,3,4-13C4] butanoic acid Perfluoro-n-[l,2,3,4-13C4] octanoic acid Perfluoro-n-[l,2-13C2] decanoic acid Perfluoro-n-[l,2-13C2] hexanoicacid Perfluoro-n-[ 1,2-13C2]dodecanoic Acid Perfluoro-n-[ 1,2- 13C2]undecanoic Acid Sodium perfluoro-l-[l,2,3,4-13C4] octanesulfonate Sodium perfluoro-1-hexane[1802] sulfonate %Rec 87 58 90 100 65 56 56 75 76 Control Limits 50-150 50-150 50-150 50-150 50-150 50-150 50-150 50-150 50-150 Date Analyzed 2/9/10 00:55 2/9/10 11:52 2/9/10 00:55 2/9/10 00:55 2/9/10 11:52 2/9/10 00:55 2/9/10 00:55 2/9/10 00:55 2/9/10 11:52 Q Note Comments: Printed 2/23/10 13:37 \\Infiow2\Starlims\LimsReps\AnalyticalReport.rpt Form 1A 21 SuperSct Reference: 10-0000135123rev00 Client: Project: Sample Matrix: Sample Name: Lab Code: Analytical Report Camp Dresser & McKee, Incorporated (CDM) Baron & Budd, P.C./95779-75319 Water Lillian "Raw" K1000968-008 p. 96 Service Request: K 1000968 Date Collected: 2/ 2/10 1004 Date Received: 2/ 3/10 Units: ng/L Basis: NA Perfluorinated Sulfonic Acids and Perfluorinated Carboxylic Acids by HPLC/MS Analytical Method: PFOA Prep Method: Method Analyte Name Perfluoro-n-tetradecanoic acid Perfluoro-n-tridecanoic acid Perfluorobutanesulfonate Perfluorobutanoic Acid Perfluorodecane Sulfonate Perfluorodecanoic Acid Perfluorododecanoic Acid Perfluoroheptanoic Acid Perfluorohexanesulfonate Perfluorohexanoic Acid Perfluorononanoic Acid Perfluorooctanesulfonate Perfluorooctanoic Acid Perfluoropentanoic Acid Perfluoroundecanoic Acid Result Q ND U ND U 1.9 J 2.0 J 0.26 J 0.60 J ND u 2.9 J 6.7 4.7 J 0.67 J 13 8.2 5.1 ND u MRL 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 MDL 0.46 0.95 0.029 0.11 0.095 0.48 0.85 0.081 0.030 0.11 0.12 0.046 0.066 0.11 1.3 Dilution Date Date Extraction Analysis Factor Extracted Analyzed Lot Lot Note 1 2/ 8/10 2/9/10 01:03 105653 190530 1 2/ 8/10 2/9/10 01:03 105653 190530 1 2/ 8/10 2/9/10 12:01 105653 190530 1 2/ 8/10 2/9/10 12:01 105653 190530 1 2/ 8/10 2/9/10 01:03 105653 190530 1 2/ 8/10 2/9/10 01:03 105653 190530 1 2/ 8/10 2/9/10 01:03 105653 190530 1 2/ 8/10 2/9/10 12:01 105653 190530 1 2/ 8/10 2/9/10 12:01 105653 190530 1 2/ 8/10 2/9/10 12:01 105653 190530 1 2/ 8/10 2/9/10 01:03 105653 190530 1 2/ 8/10 2/9/10 01:03 105653 190530 1 2/ 8/10 2/9/10 01:03 105653 190530 1 2/8/10 2/9/10 12:01 105653 190530 1 2/ 8/10 2/9/10 01:03 105653 190530 Surrogate Name Perfluoro-n-[l,2,3,4,5-13C5] nonanoic acid Perfluoro-n-[l,2,3,4-13C4] butanoic acid Perfluoro-n-[l,2,3,4-1304] octanoic acid Perfluoro-n-[l,2-13C2] decanoicacid Perfluoro-n-[l,2-13C2] hexanoic acid Perfluoro-n-[1,2-13C2]dodecanoic Acid Perfluoro-n-[1,2-13C2]undecanoic Acid Sodium perfluoro-l-[l,2,3,4-13C4] octanesulfonate Sodium perfluoro-1-hexane[1802]sulfonate %Rec 83 74 88 100 80 46 * 47 * 64 89 Control Limits 50-150 50-150 50-150 50-150 50-150 50-150 50-150 50-150 50-150 Date Analyzed Q 2/9/10 01:03 2/9/10 12:01 2/9/10 01:03 2/9/10 01:03 2/9/10 12:01 2/9/10 01:03 2/9/10 01:03 2/9/10 01:03 2/9/10 12:01 Note Comments: Printed 2/23/10 13:37 \\Inflow2\Starlims\LimsReps\Ana]ylicalReport.rpt Form 1A 22 SupcrSet Reference: 10-0000135123 rev 00 Client: Project: Sample Matrix: Sample Name: Lab Code: Analytical Report Camp Dresser & McKee, Incorporated (CDM) Baron & Budd, P.C./95779-75319 Water Lillian "Treated" K1000968-009 p. 97 Service Request: K 1000968 Date Collected: 2/2/10 1015 Date Received: 2/ 3/10 Units: ng/L Basis: NA Perfluorinated Sulfonic Acids and Perfluorinated Carboxylic Acids by HPLC/MS Analytical Method: PFOA Prep Method: Method Analyte Name Perfluoro-n-tetradecanoic acid Perfluoro-n-tridecanoic acid Perfluorobutanesulfonate Perfluorobutanoic Acid Perfluorodecane Sulfonate Perfluorodecanoic Acid Perfluorododecanoic Acid Perfluoroheptanoic Acid Perfluorohexanesulfonate Perfluorohexanoic Acid Perfluorononanoic Acid Perfluorooctanesulfonate Perfluorooctanoic Acid Perfluoropentanoic Acid Perfluoroundecanoic Acid Result Q ND U ND U 1.9 J 1.8 J ND U ND U ND U 3.0 J 6.8 4.6 J 0.56 J 11 8.5 5.2 ND U MRL 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 MDL 0.46 0.95 0.029 0.11 0.095 0.48 0.85 0.081 0.030 0.11 0.12 0.046 0.066 0.11 1.3 Dilution Date Date Extraction Analysis Factor Extracted Analyzed Lot Lot Note 1 2/ 8/10 2/9/10 01:11 105653 190530 1 2/ 8/10 2/9/10 01:11 105653 190530 1 2/ 8/10 2/9/10 12:11 105653 190530 1 2/ 8/10 2/9/10 12:11 105653 190530 1 2/ 8/10 2/9/10 01:11 105653 190530 1 2/ 8/10 2/9/10 01:11 105653 190530 1 2/ 8/10 2/9/10 01:11 105653 190530 1 2/ 8/10 2/9/10 12:11 105653 190530 1 2/ 8/10 2/9/10 12:11 105653 190530 1 2/ 8/10 2/9/10 12:11 105653 190530 1 2/ 8/10 2/9/10 01:11 105653 190530 1 2/ 8/10 2/9/10 01:11 105653 190530 1 2/ 8/10 2/9/10 01:11 105653 190530 1 2/ 8/10 2/9/10 12:11 105653 190530 1 2/ 8/10 2/9/10 01:11 105653 190530 Surrogate Name Perfluoro-n-[l,2,3,4,5-13C5] nonanoic acid Perfluoro-n-[l,2,3,4-13C4] butanoic acid Perfluoro-n-[l,2,3,4-13C4] octanoic acid Perfluoro-n-[l,2-13C2] decanoic acid Perfluoro-n-[l,2-13C2] hexanoicacid Perfluoro-n-[ 1,2-13C2]dodecanoic Acid Perfluoro-n-[ 1,2-13C2]undecanoic Acid Sodium perfluoro-l-[l,2,3,4-13C4] octanesulfonate Sodium perfluoro-1-hexane[1802]sulfonate %Rec 79 71 92 100 77 48 * 39 * 60 82 Control Limits 50-150 50-150 50-150 50-150 50-150 50-150 50-150 50-150 50-150 Date Analyzed 2/9/10 01:11 2/9/10 12:11 2/9/10 01:11 2/9/10 01:11 2/9/10 12:11 2/9/10 01:11 2/9/10 01:11 2/9/10 01:11 2/9/10 12:11 Q Note Comments: Printed 2/23/10 13:37 \\Inflow2\Stariims\LimsReps\AnalyticalRepoitrpt Form 1A 23 SuperSet Reference: 10-0000135123 rev 00 Client: Project: Sample Matrix: Sample Name: Lab Code: Analytical Report Camp Dresser & McKee, Incorporated (CDM) Baron & Budd, P.C./95779-75319 Water Bronson "Raw" K1000968-010 p. 98 Service Request: K1000968 Date Collected: 2/2/10 1041 Date Received: 2/ 3/10 Units: ng/L Basis: NA Perfluorinated Sulfonic Acids and Perfluorinated Carboxylic Acids by HPLC/MS Analytical Method: PFOA Prep Method: Method Analyte Name Perfluoro-n-tetradecanoic acid Perfluoro-n-tridecanoic acid Perfluorobutanesulfonate Perfluorobutanoic Acid Perfluorodecane Sulfonate Perfluorodecanoic Acid Perfluorododecanoic Acid Perfluoroheptanoic Acid Perfluorohexanesulfonate Perfluorohexanoic Acid Perfluorononanoic Acid Perfluorooctanesulfonate Perfluorooctanoic Acid Perfluoropentanoic Acid Perfluoroundecanoic Acid Result Q ND U ND U 4.5 J 5.4 0.16 J ND U ND U 7.7 33 14 0.98 J 58 25 13 ND U MRL 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 MDL 0.46 0.95 0.029 0.11 0.095 0.48 0.85 0.081 0.030 0.11 0.12 0.046 0.066 0.11 1.3 Dilution Date Date Extraction Analysis Factor Extracted Analyzed Lot Lot Note 1 2/ 8/10 2/9/10 01:18 105653 190530 1 2/ 8/10 2/9/10 01:18 105653 190530 1 2/ 8/10 2/9/10 12:20 105653 190530 1 2/ 8/10 2/9/10 12:20 105653 190530 1 2/ 8/10 2/9/10 01:18 105653 190530 1 2/ 8/10 2/9/10 01:18 105653 190530 1 2/ 8/10 2/9/10 01:18 105653 190530 1 2/ 8/10 2/9/10 12:20 105653 190530 1 2/ 8/10 2/9/10 12:20 105653 190530 1 2/ 8/10 2/9/10 12:20 105653 190530 1 2/ 8/10 2/9/10 01:18 105653 190530 1 2/ 8/10 2/9/10 01:18 105653 190530 1 2/ 8/10 2/9/10 01:18 105653 190530 1 2/ 8/10 2/9/10 12:20 105653 190530 1 2/ 8/10 2/9/10 01:18 105653 190530 Surrogate Name Perfluoro-n-[l,2,3,4,5-13C5] nonanoic acid Perfluoro-n-[l,2,3,4-13C4] butanoic acid Perfluoro-n-[l,2,3,4-13C4] octanoic acid Perfluoro-n-[l,2-13C2] decanoic acid Perfluoro-n-[l,2-13C2] hexanoicacid Perfluoro-n-[ 1,2-13C2]dodecanoic Acid Perfluoro-n-[1,2-13C2]undecanoic Acid Sodiumperfluoro-l-[l,2,3,4-13C4] octanesulfonate Sodium perfluoro-l-hexane[1802]sulfonate %Rec 95 72 105 100 83 56 49 * 70 81 Control Limits 50-150 50-150 50-150 50-150 50-150 50-150 50-150 50-150 50-150 Date Analyzed 2/9/10 01:18 2/9/10 12:20 2/9/10 01:18 2/9/10 01:18 2/9/10 12:20 2/9/10 01:18 2/9/10 01:18 2/9/10 01:18 2/9/10 12:20 Q Note Comments: Printed 2/23/10 13:37 \\Inilow2\Starlims\LimsReps\AnalyticalReport.rpt Form 1A 24 SuperSet Reference: 10-0000135123 rev 00 Client: Project: Sample Matrix: Sample Name: Lab Code: Analytical Report Camp Dresser & McKee, Incorporated (CDM) Baron & Budd, P.C./95779-75319 Water Bronson "Treated" K 1000968-011 p. 99 Service Request: K1000968 Date Collected: 2/ 2/10 1054 Date Received: 2/ 3/10 Units: ng/L Basis: NA Perfluorinated Sulfonic Acids and Perfluorinated Carboxylic Acids by HPLC/MS Analytical Method: PFOA Prep Method: Method Analyte Name Perfluoro-n-tetradecanoic acid Perfluoro-n-tridecanoic acid Perfluorobutanesulfonate Perfluorobutanoic Acid Perfluorodecane Sulfonate Perfluorodecanoic Acid Perfluorododecanoic Acid Perfluoroheptanoic Acid Perfluorohexanesulfonate Perfluorohexanoic Acid Perfluorononanoic Acid Perfluorooctanesulfonate Perfluorooctanoic Acid Perfluoropentanoic Acid Perfluoroundecanoic Acid Result Q ND U ND U 12 9.7 ND U ND U ND U 18 98 37 1.6 J 81 68 32 ND U MRL 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 MDL 0.46 0.95 0.029 0.11 0.095 0.48 0.85 0.081 0.030 0.11 0.12 0.046 0.066 0.11 1.3 Dilution Date Date Extraction Analysis Factor Extracted Analyzed Lot Lot Note 1 2/ 8/10 2/9/10 01:26 105653 190530 1 2/ 8/10 2/9/10 01:26 105653 190530 1 2/ 8/10 2/9/10 12:30 105653 190530 1 2/ 8/10 2/9/10 12:30 105653 190530 1 2/ 8/10 2/9/10 01:26 105653 190530 1 2/ 8/10 2/9/10 01:26 105653 190530 1 2/ 8/10 2/9/10 01:26 105653 190530 1 2/ 8/10 2/9/10 12:30 105653 190530 1 2/ 8/10 2/9/10 12:30 105653 190530 1 2/ 8/10 2/9/10 12:30 105653 190530 1 2/ 8/10 2/9/10 01:26 105653 190530 1 2/ 8/10 2/9/10 01:26 105653 190530 1 2/ 8/10 2/9/10 01:26 105653 190530 1 2/ 8/10 2/9/10 12:30 105653 190530 1 2/ 8/10 2/9/10 01:26 105653 190530 Surrogate Name Perfluoro-n-[l,2,3,4,5-13C5] nonanoic acid Perfluoro-n-[l,2,3,4-13C4] butanoic acid Perfluoro-n-[l,2,3,4-13C4] octanoic acid Perfluoro-n-[l,2-13C2] decanoicacid Perfluoro-n-[l,2-13C2] hexanoicacid Perfluoro-n-[l,2-13C2]dodecanoic Acid Perfluoro-n-[ 1,2-13C2]undecanoic Acid Sodium perfluoro-l-[l,2,3,4-13C4] octanesulfonate Sodium perfluoro-1-hexane[1802] sulfonate %Rec 89 74 90 100 82 52 52 74 91 Control Limits 50-150 50-150 50-150 50-150 50-150 50-150 50-150 50-150 50-150 Date Analyzed 2/9/10 01:26 2/9/10 12:30 2/9/10 01:26 2/9/10 01:26 2/9/10 12:30 2/9/10 01:26 2/9/10 01:26 2/9/10 01:26 2/9/10 12:30 Q Note Comments: Printed 2/23/10 13:37 \Unflow2\Starlims\LimsReps\AnalyticalReport.rpt Form 1A 25 SuperSct Reference: 10-0000135123 rev 00 Client: Project: Sample Matrix: Sample Name: Lab Code: Analytical Report Camp Dresser & McKee, Incorporated (CDM) Baron & Budd, P.C./95779-75319 Water West Pensacola "Raw" K1000968-012 p. 100 Service Request: K1000968 Date Collected: 2/ 2/10 1203 Date Received: 2/ 3/10 Units: ng/L Basis: NA Perfluorinated Sulfonic Acids and Perfluorinated Carboxylic Acids by HPLC/MS Analytical Method: PFOA Prep Method: Method Analyte Name Perfluoro-n-tetradecanoic acid Perfluoro-n-tridecanoic acid Perfluorobutanesulfonate Perfluorobutanoic Acid Perfluorodecane Sulfonate Perfluorodecanoic Acid Perfluorododecanoic Acid Perfluoroheptanoic Acid Perfluorohexanesulfonate Perfluorohexanoic Acid Perfluorononanoic Acid Perfluorooctanesulfonate Perfluorooctanoic Acid Perfluoropentanoic Acid Perfluoroundecanoic Acid Result Q ND U ND U 0.75 J 0.54 J ND U ND U ND U 0.74 J 2.5 J 0.92 J 0.63 J 5.9 2.7 J 0.87 J ND u MRL 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 MDL 0.46 0.95 0.029 0.11 0.095 0.48 0.85 0.081 0.030 0.11 0.12 0.046 0.066 0.11 1.3 Dilution Date Date Extraction Analysis Factor Extracted Analyzed Lot Lot Note 1 2/ 8/10 2/9/10 01:33 105653 190530 1 2/ 8/10 2/9/10 01:33 105653 190530 1 2/ 8/10 2/9/10 12:40 105653 190530 1 2/ 8/10 2/9/10 12:40 105653 190530 1 2/8/10 2/9/10 01:33 105653 190530 1 2/ 8/10 2/9/10 01:33 105653 190530 1 2/ 8/10 2/9/10 01:33 105653 190530 1 2/ 8/10 2/9/10 12:40 105653 190530 1 2/ 8/10 2/9/10 12:40 105653 190530 1 2/ 8/10 2/9/10 12:40 105653 190530 1 2/ 8/10 2/9/10 01:33 105653 190530 1 2/ 8/10 2/9/10 01:33 105653 190530 1 2/ 8/10 2/9/10 01:33 105653 190530 1 2/ 8/10 2/9/10 12:40 105653 190530 1 2/ 8/10 2/9/10 01:33 105653 190530 Surrogate Name Perfluoro-n-[l,2,3,4,5-13C5] nonanoic acid Perfluoro-n-[l,2,3,4-13C4] butanoic acid Perfluoro-n-[l,2,3,4-13C4] octanoic acid Perfluoro-n-[l,2-13C2] decanoic acid PerfIuoro-n-[l,2-13C2] hexanoic acid Perfluoro-n-[1,2-13C2]dodecanoic Acid Perfluoro-n-[1,2-13C2]undecanoic Acid Sodium perfluoro-l-[l,2,3,4-13C4] octanesulfonate Sodium petfluoro-1-hexanef 1802]sulfonate %Rec 90 68 102 100 73 41 * 44 * 63 83 Control Limits 50-150 50-150 50-150 50-150 50-150 50-150 50-150 50-150 50-150 Date Analyzed 2/9/10 01:33 2/9/10 12:40 2/9/10 01:33 2/9/10 01:33 2/9/10 12:40 2/9/10 01:33 2/9/10 01:33 2/9/10 01:33 2/9/10 12:40 Q Note Comments: Printed 2/23/10 13:37 \Mnflow2\Starlims\LimsReps\AnalyticalReportrpt Form 1A 26 Superset Reference: 10-0000135123 rev 00 Client: Project: Sample Matrix: Sample Name: Lab Code: Analytical Report Camp Dresser & McKee, Incorporated (CDM) Baron & Budd, P.C./95779-75319 Water West Pensacola "Treated" K1000968-013 p. 101 Service Request: K 1000968 Date Collected: 2/2 /1 0 1214 Date Received: 2/ 3/10 Units: ng/L Basis: NA Perfluorinated Sulfonic Acids and Perfluorinated Carboxylic Acids by HPLC/MS Analytical Method: PFOA Prep Method: Method Analyte Name Perfluoro-n-tetradecanoic acid Perfluoro-n-tridecanoic acid Perfluorobutanesulfonate Perfluorobutanoic Acid Perfluorodecane Sulfonate Perfluorodecanoic Acid Perfluorododecanoic Acid Perfluoroheptanoic Acid Perfluorohexanesulfonate Perfluorohexanoic Acid Perfluorononanoic Acid Perfluorooctanesulfonate Perfluorooctanoic Acid Perfluoropentanoic Acid Perfluoroundecanoic Acid Result Q ND U ND u ND u 0.25 J ND u ND u ND u ND u 0.17 J 0.21 J ND u 0.28 J ND u 0.38 J ND u MRL 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 MDL 0.46 0.95 0.029 0.11 0.095 0.48 0.85 0.081 0.030 0.11 0.12 0.046 0.066 0.11 1.3 Dilution Date Date Extraction Analysis Factor Extracted Analyzed Lot Lot Note 1 2 / 8/10 2/9/10 01:41 105653 190530 1 2/ 8/10 2/9/10 01:41 105653 190530 1 2/ 8/10 2/9/10 12:49 105653 190530 1 2 / 8/10 2/9/10 12:49 105653 190530 1 2/ 8/10 2/9/10 01:41 105653 190530 1 2/ 8/10 2/9/10 01:41 105653 190530 1 2/ 8/10 2/9/10 01:41 105653 190530 1 2 / 8/10 2/9/10 12:49 105653 190530 1 2 / 8/10 2/9/10 12:49 105653 190530 1 2 / 8/10 2/9/10 12:49 105653 190530 1 2 /8 /1 0 2/9/10 01:41 105653 190530 1 2/ 8/10 2/9/10 01:41 105653 190530 1 2/ 8/10 2/9/10 01:41 105653 190530 1 2 / 8/10 2/9/10 12:49 105653 190530 1 2 / 8/10 2/9/10 01:41 105653 190530 Surrogate Name Perfluoro-n-[l,2,3,4,5-13C5] nonanoic acid Perfluoro-n-[l,2,3,4-13C4] butanoic acid Perfluoro-n-[ 1,2,3,4-13C4J octanoic acid Perfluoro-n-[l,2-13C2] decanoic acid Perfluoro-n-[l,2-13C2] hexanoicacid Perfluoro-n-[l,2-13C2]dodecanoic Acid Perfluoro-n-[l,2-13C2]undecanoic Acid Sodiumperfluoro-l-[l,2,3,4-13C4] octanesulfonate Sodium perfluoro-1-hexane[1802]sulfonate %Rec 93 80 100 100 86 48 * 46 * 64 82 Control Limits 50-150 50-150 50-150 50-150 50-150 50-150 50-150 50-150 50-150 Date Analyzed 2/9/10 01:41 2/9/10 12:49 2/9/10 01:41 2/9/10 01:41 2/9/10 12:49 2/9/10 01:41 2/9/10 01:41 2/9/10 01:41 2/9/10 12:49 Q Note Comments: Printed 2/23/10 13:37 \\Inflow2\StarIims\LimsReps\AnalyticalReport.rpt Form 1A 27 Superset Reference: 10-0000135123 rev 00 Client: Project: Sample Matrix: Sample Name: Lab Code: Analytical Report Camp Dresser & McKee, Incorporated (CDM) Baron & Budd, P.C./95779-75319 Water W & Avery "Raw" K1000968-014 p. 102 Service Request: K1000968 Date Collected: 2/ 2/10 1234 Date Received: 2/ 3/10 Units: ng/L Basis: NA Perfluorinated Sulfonic Acids and Perfluorinated Carboxylic Acids by HPLC/MS Analytical Method: PFOA Prep Method: Method Analyte Name Perfluoro-n-tetradecanoic acid Perfluoro-n-tridecanoic acid Perfluorobutanesulfonate Perfluorobutanoic Acid Perfluorodecane Sulfonate Perfluorodecanoic Acid Perfluorododecanoic Acid Perfluoroheptanoic Acid Perfluorohexanesulfonate Perfluorohexanoic Acid Perfluorononanoic Acid Perfluorooctanesulfonate Perfluorooctanoic Acid Perfluoropentanoic Acid Perfluoroundecanoic Acid Result Q ND U ND U 1.2 J 1.1 J ND U ND U ND U 1.6 J 5.8 2.7 J 0.41 J 5.5 4.4 J 2.5 J ND u MRL 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 MDL 0.46 0.95 0.029 0.11 0.095 0.48 0.85 0.081 0.030 0.11 0.12 0.046 0.066 0.11 1.3 Dilution Date Date Extraction Analysis Factor Extracted Analyzed Lot Lot Note 1 2/ 8/10 2/9/10 01:49 105653 190530 1 2/ 8/10 2/9/10 01:49 105653 190530 1 2/ 8/10 2/9/10 12:59 105653 190530 1 2/ 8/10 2/9/10 12:59 105653 190530 1 2/ 8/10 2/9/10 01:49 105653 190530 1 2/ 8/10 2/9/10 01:49 105653 190530 1 2/ 8/10 2/9/10 01:49 105653 190530 1 2/ 8/10 2/9/10 12:59 105653 190530 1 2/ 8/10 2/9/10 12:59 105653 190530 1 2/ 8/10 2/9/10 12:59 105653 190530 1 2/ 8/10 2/9/10 01:49 105653 190530 1 2/ 8/10 2/9/10 01:49 105653 190530 1 2/ 8/10 2/9/10 01:49 105653 190530 1 2/ 8/10 2/9/10 12:59 105653 190530 1 2/ 8/10 2/9/10 01:49 105653 190530 Surrogate Name Perfluoro-n-[l,2,3,4,5-13C5] nonanoic acid Perfluoro-n-[l,2,3,4-13C4] butanoic acid Perfluoro-n-[l,2,3,4-13C4] octanoic acid Perfluoro-n-[l,2-13C2] decanoicacid Perfluoro-n-[l,2-13C2] hexanoic acid Perfluoro-n-[l,2-13C2]dodecanoic Acid Perfluoro-n-[1,2-13C2]undecanoic Acid Sodiumperfluoro-l-[l ,2,3,4-13C4] octanesulfonate Sodium perfluoro-1-hexane[1802]sulfonate %Rec 98 74 105 100 84 56 47 * 71 96 Control Limits 50-150 50-150 50-150 50-150 50-150 50-150 50-150 50-150 50-150 Date Analyzed 2/9/10 01:49 2/9/10 12:59 2/9/10 01:49 2/9/10 01:49 2/9/10 12:59 2/9/10 01:49 2/9/10 01:49 2/9/10 01:49 2/9/10 12:59 Q Note Comments: Printed 2/23/10 13:37 \\Inflow2\Starlims\LimsReps\AnalyticalReport.rpt Form 1A 28 SuperSet Reference: 10-0000135123 rev 00 Client: Project: Sample Matrix: Sample Name: Lab Code: Analytical Report Camp Dresser & McKee, Incorporated (CDM) Baron & Budd, P.C./95779-75319 Water W & Avery "Treated" K 1000968-015 p. 103 Service Request: K 1000968 Date Collected: 2/ 2/10 1245 Date Received: 2/ 3/10 Units: ng/L Basis: NA Perfluorinated Sulfonic Acids and Perfluorinated Carboxylic Acids by HPLC/MS Analytical Method: PFOA Prep Method: Method Analyte Name Perfluoro-n-tetradecanoic acid Perfluoro-n-tridecanoic acid Pcrfluorobutanesulfonate Perfluorobutanoic Acid Perfluorodecane Sulfonate Perfluorodecanoic Acid Perfluorododecanoic Acid Perfluoroheptanoic Acid Perfluorohexanesulfonate Perfluorohexanoic Acid Perfluorononanoic Acid Perfluorooctanesulfonate Perfluorooctanoic Acid Perfluoropentanoic Acid Perfluoroundecanoic Acid Result Q ND U ND U 1.2 J 1.1 J ND U ND u ND u 1.7 J 5.9 2.8 J 0.47 J 5.9 5.0 2.6 J ND u MRL 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 MDL 0.46 0.95 0.029 0.11 0.095 0.48 0.85 0.081 0.030 0.11 0.12 0.046 0.066 0.11 1.3 Dilution Date Date Extraction Analysis Factor Extracted Analyzed Lot Lot Note 1 2/ 8/10 2/9/10 01:56 105653 190530 1 2/ 8/10 2/9/10 01:56 105653 190530 1 2/ 8/10 2/9/10 13:08 105653 190530 1 2/ 8/10 2/9/10 13:08 105653 190530 1 2/ 8/10 2/9/10 01:56 105653 190530 1 2/ 8/10 2/9/10 01:56 105653 190530 1 2/ 8/10 2/9/10 01:56 105653 190530 1 2/ 8/10 2/9/10 13:08 105653 190530 1 2/ 8/10 2/9/10 13:08 105653 190530 1 2/ 8/10 2/9/10 13:08 105653 190530 1 2/ 8/10 2/9/10 01:56 105653 190530 1 2/ 8/10 2/9/10 01:56 105653 190530 1 2/ 8/10 2/9/10 01:56 105653 190530 1 2/ 8/10 2/9/10 13:08 105653 190530 1 2/ 8/10 2/9/10 01:56 105653 190530 Surrogate Name Perfluoro-n-[l,2,3,4,5-13C5] nonanoic acid Perfluoro-n-[l,2,3,4-13C4] butanoic acid Perfluoro-n-[l,2,3,4-13C4] octanoic acid Perfluoro-n-[l,2-13C2] decanoicacid Perfluoro-n-[l,2-13C2] hexanoicacid Perfluoro-n-[1,2-13C2]dodecanoic Acid Perfluoro-n-[ 1,2-13C2]undecanoic Acid Sodiumperfluoro-l-[l,2,3,4-13C4] octanesulfonate Sodium perfluoro-1-hexane[1802] sulfonate %Rec 91 70 107 100 79 42 * 42 * 61 86 Control Limits 50-150 50-150 50-150 50-150 50-150 50-150 50-150 50-150 50-150 Date Analyzed 2/9/10 01:56 2/9/10 13:08 2/9/10 01:56 2/9/10 01:56 2/9/10 13:08 2/9/10 01:56 2/9/10 01:56 2/9/10 01:56 2/9/10 13:08 Q Note Comments: Printed 2/23/10 13:37 \\Inflow2\Starlims\LimsReps\AnalyticalReport.rpt Form 1A 29 Superset Reference: 10-0000135123 rev 00 Client: Project: Sample Matrix: Sample Name: Lab Code: Analytical Report Camp Dresser & McKee, Incorporated (CDM) Baron & Budd, P.C./95779-75319 Water West Well Plant "Raw" K1000968-016 P- 104 Service Request: K 1000968 Date Collected: I t 2/10 1305 Date Received: 2/ 3/10 Units: ng/L Basis: NA Perfluorinated Sulfonic Acids and Perfluorinated Carboxylic Acids by HPLC/MS Analytical Method: PFOA Prep Method: Method Analyte Name Perfluoro-n-tetradecanoic acid Perfluoro-n-tridecanoic acid Perfluorobutanesulfonate Perfluorobutanoic Acid Perfluorodecane Sulfonate Perfluorodecanoic Acid Perfluorododecanoic Acid Perfluoroheptanoic Acid Perfluorohexanesulfonate Perfluorohexanoic Acid Perfluorononanoic Acid Perfluorooctanesulfonate Perfluorooctanoic Acid Perfluoropentanoic Acid Perfluoroundecanoic Acid Result Q ND U ND U 1.1 J 0.76 J 0.30 J ND u ND u 1.2 J 4.1 J 1.8 J 0.56 J 7.1 4.4 J 1.4 J ND u MRL 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 MDL 0.46 0.95 0.029 0.11 0.095 0.48 0.85 0.081 0.030 0.11 0.12 0.046 0.066 0.11 1.3 Dilution Date Date Extraction Analysis Factor Extracted Analyzed Lot Lot Note 1 2/ 8/10 2/9/10 02:04 105653 190530 1 2/ 8/10 2/9/10 02:04 105653 190530 1 218/10 2/9/10 13:18 105653 190530 1 I t 8/10 2/9/10 13:18 105653 190530 1 2! 8/10 2/9/10 02:04 105653 190530 1 2/ 8/10 2/9/10 02:04 105653 190530 1 2/ 8/10 2/9/10 02:04 105653 190530 1 I t 8/10 2/9/10 13:18 105653 190530 1 2/ 8/10 2/9/10 13:18 105653 190530 1 2/ 8/10 2/9/1013:18 105653 190530 1 2/8/10 2/9/10 02:04 105653 190530 1 2/ 8/10 2/9/10 02:04 105653 190530 1 2/ 8/10 2/9/10 02:04 105653 190530 1 218/10 2/9/10 13:18 105653 190530 1 2/ 8/10 2/9/10 02:04 105653 190530 Surrogate Name Perfluoro-n-[l,2,3,4,5-13C5] nonanoic acid Perfluoro-n-[l,2,3,4-13C4] butanoic acid Perfluoro-n-[l,2,3,4-13C4] octanoic acid Perfluoro-n-[l,2-13C2] decanoicacid Perfluoro-n-[l,2-13C2] hexanoicacid Perfluoro-n-[1,2-13C2]dodecanoic Acid Perfluoro-n-[1,2-13C2]undecanoic Acid Sodium perfluoro-l-[l,2,3,4-13C4] octanesulfonate Sodium perfluoro-1-hexane[1802]sulfonate %Rec 94 73 112 100 82 49 * 40 * 68 87 Control Limits 50-150 50-150 50-150 50-150 50-150 50-150 50-150 50-150 50-150 Date Analyzed Q 2/9/10 02:04 2/9/10 13:18 2/9/10 02:04 2/9/10 02:04 2/9/10 13:18 2/9/10 02:04 2/9/10 02:04 2/9/10 02:04 2/9/10 13:18 Note Comments: Printed 2/23/10 13:37 \\Inflow2\Starlims\LimsReps\AnalyticalReport.rpt Form 1A 30 SuperSet Reference: 10-0000135123 rev 00 Client: Project: Sample Matrix: Sample Name: Lab Code: Analytical Report Camp Dresser & McKee, Incorporated (CDM) Baron & Budd, P.C./95779-75319 Water West Well Plant "Treated" K 1000968-017 p. 105 Service Request: K 1000968 Date Collected: 2/2 /1 0 1312 Date Received: 2/ 3/10 Units: ng/L Basis: NA Perfluorinated Sulfonic Acids and Perfluorinated Carboxylic Acids by HPLC/MS Analytical Method: PFOA Prep Method: Method Analyte Name Perfluoro-n-tetradecanoic acid Perfluoro-n-tridecanoic acid Perfluorobutanesulfonate Perfluorobutanoic Acid Perfluorodecane Sulfonate Perfluorodecanoic Acid Perfluorododecanoic Acid Perfluoroheptanoic Acid Perfluorohexanesulfonate Perfluorohexanoic Acid Perfluorononanoic Acid Perfluorooctanesulfonate Perfluorooctanoic Acid Perfluoropentanoic Acid Perfluoroundecanoic Acid Result Q ND U ND U 0,14 J 0.79 J 0.17 J ND U ND U 0.13 J 0.19 J 0.32 J ND u 0.47 J ND u 0.31 J ND u MRL 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 MDL 0.46 0.95 0.029 0.11 0.095 0.48 0.85 0.081 0.030 0.11 0.12 0.046 0.066 0.11 1.3 Dilution Date Date Extraction Analysis Factor Extracted Analyzed Lot Lot Note 1 2/ 8/10 2/9/10 02:11 105653 190530 1 2/ 8/10 2/9/10 02:11 105653 190530 1 2/ 8/10 2/9/10 13:27 105653 190530 1 2/ 8/10 2/9/10 13:27 105653 190530 1 2/ 8/10 2/9/10 02:11 105653 190530 1 2/ 8/10 2/9/10 02:11 105653 190530 1 2/ 8/10 2/9/10 02:11 105653 190530 1 2/ 8/10 2/9/10 13:27 105653 190530 1 2/ 8/10 2/9/10 13:27 105653 190530 1 2/ 8/10 2/9/10 13:27 105653 190530 1 2/ 8/10 2/9/10 02:11 105653 190530 1 2/ 8/10 2/9/10 02:11 105653 190530 1 2/ 8/10 2/9/10 02:11 105653 190530 1 2/ 8/10 2/9/10 13:27 105653 190530 1 2/ 8/10 2/9/10 02:11 105653 190530 Surrogate Name Perfluoro-n-[l,2,3,4,5-13C5] nonanoic acid Perfluoro-n-[l,2,3,4-13C4] butanoic acid Perfluoro-n-[l,2,3,4-13C4] octanoic acid Perfluoro-n-[l,2-13C2] decanoicacid Perfluoro-n-[l,2-13C2] hexanoic acid Perfluoro-n-[1,2-13C2]dodecanoic Acid Perfluoro-n-[ 1,2-13C2]undecanoic Acid Sodium perfluoro-l-[l,2,3,4-13C4] octanesulfonate Sodium perfluoro-l-hexane[1802]sulfonate %Rec 88 66 86 100 74 51 45 * 68 92 Control Limits 50-150 50-150 50-150 50-150 50-150 50-150 50-150 50-150 50-150 Date Analyzed 2/9/10 02:11 2/9/10 13:27 2/9/10 02:11 2/9/10 02:11 2/9/10 13:27 2/9/10 02:11 2/9/10 02:11 2/9/10 02:11 2/9/10 13:27 Q Note Comments: Printed 2/23/10 13:37 \\Inflow2\Starlims\LimsReps\AnafyticalReportrpt Form 1A 31 Superset Reference: 10-0000135123 rev 00 Client: Project: Sample Matrix: Sample Name: Lab Code: Analytical Report Camp Dresser & McKee, Incorporated (CDM) Baron & Budd, P.C./95779-75319 Water F:Scott "Raw" K1000968-018 p. 106 Service Request: K 1000968 Date Collected: 2/2 /1 0 1331 Date Received: 2/ 3/10 Units: ng/L Basis: NA Perfluorinated Sulfonic Acids and Perfluorinated Carboxylic Acids by HPLC/MS Analytical Method: PFOA Prep Method: Method Analyte Name Perfluoro-n-tetradecanoic acid Perfluoro-n-tridecanoic acid Perfluorobutanesulfonate Perfluorobutanoic Acid Perfluorodecane Sulfonate Perfluorodecanoic Acid Perfluorododecanoic Acid Perfluoroheptanoic Acid Perfluorohexanesulfonate Perfluorohexanoic Acid Perfluorononanoic Acid Perfluorooctanesulfonate Perfluorooctanoic Acid Perfluoropentanoic Acid Perfluoroundecanoic Acid Result Q 0.66 J ND U 1.1 J 2.7 J 0.35 J ND U ND U 3.3 J 4.0 J 3.7 J 2.2 J 12 5.8 4.6 J ND U MRL 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 MDL 0.46 0.95 0.029 0.11 0.095 0.48 0.85 0.081 0.030 0.11 0.12 0.046 0.066 0.11 1.3 Dilution Date Date Extraction Analysis Factor Extracted Analyzed Lot Lot Note 1 2/ 8/10 2/9/10 02:19 105653 190530 1 2/ 8/10 2/9/10 02:19 105653 190530 1 2/ 8/10 2/9/10 13:37 105653 190530 1 2/ 8/10 2/9/10 13:37 105653 190530 1 2/ 8/10 2/9/1002:19 105653 190530 1 2/ 8/10 2/9/10 02:19 105653 190530 1 2/ 8/10 2/9/10 02:19 105653 190530 1 218/10 2/9/10 13:37 105653 190530 1 2/ 8/10 2/9/10 13:37 105653 190530 1 2/ 8/10 2/9/10 13:37 105653 190530 1 2/ 8/10 2/9/10 02:19 105653 190530 1 2/ 8/10 2/9/10 02:19 105653 190530 1 2/ 8/10 2/9/10 02:19 105653 190530 1 21 8/10 2/9/10 13:37 105653 190530 1 2/ 8/10 2/9/10 02:19 105653 190530 Surrogate Name Perfluoro-n-[l,2,3,4,5-13C5] nonanoic acid Perfluoro-n-[l,2,3,4-13C4] butanoic acid Perfluoro-n-[l,2,3,4-13C4] octanoic acid Perfluoro-n-[l,2-13C2] decanoic acid Perfluoro-n-[l,2-13C2] hexanoicacid Perfluoro-n-[l,2-13C2]dodecanoic Acid Perfluoro-n-[l,2-13C2]undecanoic Acid Sodiumperfluoro-1-[1,2,3,4-13C4] octanesulfonate Sodium perfluoro-l-hexane[1802]sulfonate %Rec 92 78 107 100 92 52 47 * 66 86 Control Limits 50-150 50-150 50-150 50-150 50-150 50-150 50-150 50-150 50-150 Date Analyzed Q 2/9/10 02:19 2/9/10 13:37 2/9/10 02:19 2/9/10 02:19 2/9/10 13:37 2/9/10 02:19 2/9/10 02:19 2/9/10 02:19 2/9/10 13:37 Note Comments: Printed 2/23/10 13:37 \\Inflow2\Starlims\LunsReps\AnalyticalReport.rpt Form 1A 32 SuperSet Reference: 10-0000135123 rev 00 Client: Project: Sample Matrix: Sample Name: Lab Code: Analytical Report Camp Dresser & McKee, Incorporated (CDM) Baron & Budd, P.C./95779-75319 Water F: Scott "Treated" K1000968-019 p. 107 Service Request: K1000968 Date Collected: 2/ 2/10 1342 Date Received: 2/ 3/10 Units: ng/L Basis: NA Perfluorinated Sulfonic Acids and Perfluorinated Carboxylic Acids by HPLC/MS Analytical Method: PFOA Prep Method: Method Analyte Name Perfluoro-n-tetradecanoic acid Perfluoro-n-tridecanoic acid Perfluorobutanesulfonate Perfluorobutanoic Acid Perfluorodecane Sulfonate Perfluorodecanoic Acid Perfluorododecanoic Acid Perfluoroheptanoic Acid Perfluorohexanesulfonate Perfluorohexanoic Acid Perfluorononanoic Acid Perfluorooctanesulfonate Perfluorooctanoic Acid Perfluoropentanoic Acid Perfluoroundecanoic Acid Result Q ND U ND U 0.57 J 2.6 J ND U ND u ND u 1.2 J 1.3 J 2.0 J 0.52 J 1.7 J 2.3 J 3.0 J ND u MRL 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 MDL 0.46 0.95 0.029 0.11 0.095 0.48 0.85 0.081 0.030 0.11 0.12 0.046 0.066 0.11 1.3 Dilution Date Date Extraction Analysis Factor Extracted Analyzed Lot Lot Note 1 2/ 8/10 2/9/10 02:26 105653 190530 1 2/ 8/10 2/9/10 02:26 105653 190530 1 2/ 8/10 2/9/10 13:46 105653 190530 1 2/ 8/10 2/9/10 13:46 105653 190530 1 2/ 8/10 2/9/10 02:26 105653 190530 1 2/ 8/10 2/9/10 02:26 105653 190530 1 2/ 8/10 2/9/10 02:26 105653 190530 1 2/ 8/10 2/9/10 13:46 105653 190530 1 2/8/10 2/9/10 13:46 105653 190530 1 2/ 8/10 2/9/10 13:46 105653 190530 1 2/ 8/10 2/9/10 02:26 105653 190530 1 2/ 8/10 2/9/10 02:26 105653 190530 1 2/ 8/10 2/9/10 02:26 105653 190530 1 2/ 8/10 2/9/10 13:46 105653 190530 1 2/ 8/10 2/9/10 02:26 105653 190530 Surrogate Name Perfluoro-n-[l,2,3,4,5-13C5] nonanoic acid Perfluoro-n-[l,2,3,4-13C4] butanoic acid Perfluoro-n-[l,2,3,4-13C4] octanoic acid Perfluoro-n-[l,2-13C2] decanoic acid Perfluoro-n-[l,2-13C2] hexanoicacid Perfluoro-n-[l,2-13C2]dodecanoic Acid Perfluoro-n-[l,2-13C2]undecanoic Acid Sodium perfluoro-l-[l,2,3,4-13C4] octanesulfonate Sodium perfluoro-1-hexane[l802]sulfonate %Rec 95 76 100 100 89 48 * 44 * 68 87 Control Limits 50-150 50-150 50-150 50-150 50-150 50-150 50-150 50-150 50-150 Date Analyzed 2/9/10 02:26 2/9/10 13:46 2/9/10 02:26 2/9/10 02:26 2/9/10 13:46 2/9/10 02:26 2/9/10 02:26 2/9/10 02:26 2/9/10 13:46 Q Note Comments: Printed 2/23/10 13:37 \\[nflow2\Starlims\LimsReps\AnalyticalReport.ipt Form 1A 33 SuperSet Reference: 10-0000135123 rev 00 Client: Project: Sample Matrix: Sample Name: Lab Code: Analytical Report Camp Dresser & McKee, Incorporated (CDM) Baron & Budd, P.C./95779-75319 Water Field Blank 3 K1000968-020 p. 108 Service Request: K 1000968 Date Collected: 2/ 3/10 0750 Date Received: 2/ 4/10 Units: ng/L Basis: NA Perfluorinated Sulfonic Acids and Perfluorinated Carboxylic Acids by HPLC/MS Analytical Method: PFOA Prep Method: Method Analyte Name Perfluoro-n-tetradecanoic acid Perfluoro-n-tridecanoic acid Perfluorobutanesulfonate Perfluorobutanoic Acid Perfluorodecane Sulfonate Perfluorodecanoic Acid Perfluorododecanoic Acid Perfluoroheptanoic Acid Perfluorohexanesulfonate Perfluorohexanoic Acid Perfluorononanoic Acid Perfluorooctanesulfonate Perfluorooctanoic Acid Perfluoropentanoic Acid Perfluoroundecanoic Acid Result Q ND U ND U ND U 0.17 J ND U ND u ND u ND u 0.12 J 0.16 J ND u 0.19 J ND u 0.14 J ND u MRL 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 MDL 0.46 0.95 0.029 0.11 0.095 0.48 0.85 0.081 0.030 0.11 0.12 0.046 0.066 0.11 1.3 Dilution Date Date Extraction Analysis Factor Extracted Analyzed Lot Lot Note 1 2/ 8/10 2/9/10 02:34 105653 190530 1 2/ 8/10 2/9/10 02:34 105653 190530 1 2/ 8/10 2/9/10 13:56 105653 190530 1 2/ 8/10 2/9/10 13:56 105653 190530 1 2/ 8/10 2/9/10 02:34 105653 190530 1 2/ 8/10 2/9/10 02:34 105653 190530 1 2/ 8/10 2/9/10 02:34 105653 190530 1 2/ 8/10 2/9/10 13:56 105653 190530 1 218/10 2/9/10 13:56 105653 190530 1 2/ 8/10 2/9/10 13:56 105653 190530 1 2/ 8/10 2/9/10 02:34 105653 190530 1 2/ 8/10 2/9/10 02:34 105653 190530 1 2/ 8/10 2/9/10 02:34 105653 190530 1 2/ 8/10 2/9/10 13:56 105653 190530 1 2/ 8/10 2/9/10 02:34 105653 190530 Surrogate Name Perfluoro-n-[l,2,3,4,5-13C5] nonanoic acid Perfluoro-n-[l,2,3,4-13C4] butanoic acid Perfluoro-n-[l,2,3,4-13C4] octanoic acid Perfluoro-n-[l,2-13C2] decanoicacid Perfluoro-n-[l,2-13C2] hexanoic acid Perfluoro-n-[l ,2-13C2]dodecanoic Acid Perfluoro-n-[l ,2-13C2]undecanoic Acid Sodium perfluoro-l-[l,2,3,4-13C4] octanesulfonate Sodium perfluoro-l-hexane[1802]sulfonate %Rec 110 89 110 100 94 81 52 83 88 Control Limits 50-150 50-150 50-150 50-150 50-150 50-150 50-150 50-150 50-150 Date Analyzed 2/9/10 02:34 2/9/10 13:56 2/9/10 02:34 2/9/10 02:34 2/9/10 13:56 2/9/10 02:34 2/9/10 02:34 2/9/10 02:34 2/9/10 13:56 Q Note Comments: Printed 2/23/10 13:37 \VInflow2\SUrlims\LimsReps\AnalyticalReportrpt Form 1A 34 SuperSet Reference: 10-0000135123 rev 00 Client: Project: Sample Matrix: Sample Name: Lab Code: Analytical Report Camp Dresser & McKee, Incorporated (CDM) Baron & Budd, P.C./95779-75319 Water Method Blank KQ1000620-06 p. 109 Service Request: K 1000968 Date Collected: NA Date Received: NA Units: ng/L Basis: NA Perfluorinated Sulfonic Acids and Perfluorinated Carboxylic Acids by HPLC/MS Analytical Method: PFOA Prep Method: Method Analyte Name Perfluoro-n-tetradecanoic acid Perfluoro-n-tridecanoic acid Perfluorobutanesulfonate Perfluorobutanoic Acid Perfluorodecane Sulfonate Perfiuorodecanoic Acid Perfluorododecanoic Acid Perfluoroheptanoic Acid Perfluorohexanesulfonate Perfluorohexanoic Acid Perfluorononanoic Acid Perfluorooctanesulfonate Perfluorooctanoic Acid Perfluoropentanoic Acid Perfluoroundecanoic Acid Result Q ND U ND U ND u 0.31 J ND u ND u ND u ND u 0.12 J 0.16 J ND u 1.6 J 0.23 J ND u ND u MRL 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 MDL 0.46 0.95 0.029 0.11 0.095 0.48 0.85 0.081 0.030 0.11 0.12 0.046 0.066 0.11 1.3 Dilution Date Date Extraction Analysis Factor Extracted Analyzed Lot Lot Note 1 2/ 8/10 2/17/10 23:47 105653 190530 1 2/ 8/10 2/17/10 23:47 105653 190530 1 2/ 8/10 2/9/10 17:24 105653 190530 1 2/ 8/10 2/9/10 17:24 105653 190530 1 2/ 8/10 2/17/10 23:47 105653 190530 1 2/ 8/10 2/17/10 23:47 105653 190530 1 2/ 8/10 2/17/10 23:47 105653 190530 1 2/ 8/10 2/9/10 17:24 105653 190530 1 2/ 8/10 2/9/10 17:24 105653 190530 1 2/ 8/10 2/9/10 17:24 105653 190530 1 2/ 8/10 2/17/10 23:47 105653 190530 1 2/ 8/10 2/17/10 23:47 105653 190530 1 2/ 8/10 2/17/10 23:47 105653 190530 1 2/ 8/10 2/9/10 17:24 105653 190530 1 2/ 8/10 2/17/10 23:47 105653 190530 Surrogate Name Perfluoro-n-[l,2,3,4,5-13C5] nonanoic acid Perfluoro-n-[l,2,3,4-13C4] butanoic acid Perfluoro-n-[l,2,3,4-13C4] octanoic acid Perfluoro-n-[l,2-13C2] decanoic acid Perfluoro-n-[l,2-13C2] hexanoic acid Perfluoro-n-[ 1,2-13C2]dodecanoic Acid Perfluoro-n-[1,2-13C2]undecanoic Acid Sodium perfluoro-l-[l,2,3,4-13C4] octanesulfonate Sodium perfluoro-1-hexane[1802]sulfonate %Rec 118 102 111 100 103 85 66 114 100 Control Limits 50-150 50-150 50-150 50-150 50-150 50-150 50-150 50-150 50-150 Date Analyzed Q 2/17/10 23:47 2/9/10 17:24 2/17/10 23:47 2/9/10 17:24 2/9/10 17:24 2/17/10 23:47 2/17/10 23:47 2/17/10 23:47 2/9/10 17:24 Note Comments: Printed 2/23/10 13:37 \\Inflow2\StarHms\LimsReps\AnalyticalRepoitrpt Form 1A 35 Superset Reference: 10-0000135123 rev 00 Client: Project: Sample Matrix: Sample Name: Lab Code: Analytical Report Camp Dresser & McKee, Incorporated (CDM) Baron & Budd, P.C./95779-75319 Water Lab Control Sample KQ1000620-05 p.110 Service Request: K1000968 Date Collected: NA Date Received: NA Units: ng/L Basis: NA Perfluorinated Sulfonic Acids and Perfluorinated Carboxylic Acids by HPLC/MS Analytical Method: PFOA Prep Method: Method Analyte Name Perfluoro-n-tetradecanoic acid Perfluoro-n-tridecanoic acid Perfluorobutanesulfonate Perfluorobutanoic Acid Perfluorodecane Sulfonate Perfluorodecanoic Acid Perfluorododecanoic Acid Perfluoroheptanoic Acid Perfluorohexanesulfonate Perfluorohexanoic Acid Perfluorononanoic Acid Perfluorooctanesulfonate Perfluorooctanoic Acid Perfluoropentanoic Acid Perfluoroundecanoic Acid Result Q 111 108 90.5 103 69.5 107 146 104 98.0 95.5 102 102 96.0 103 120 MRL 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 MDL 0.46 0.95 0.029 0.11 0.095 0.48 0.85 0.081 0.030 0.11 0.12 0.046 0.066 0.11 1.3 Dilution Date Date Extraction Analysis Factor Extracted Analyzed Lot Lot Note 1 2/ 8/10 2/17/10 23:40 105653 190530 1 2/8/10 2/17/10 23:40 105653 190530 1 2/ 8/10 2/9/10 17:15 105653 190530 1 2/ 8/10 2/9/1017:15 105653 190530 1 2/ 8/10 2/17/10 23:40 105653 190530 1 2/ 8/10 2/17/10 23:40 105653 190530 1 2/ 8/10 2/17/10 23:40 105653 190530 1 2/ 8/10 2/9/10 17:15 105653 190530 1 2/ 8/10 2/9/10 17:15 105653 190530 1 2/ 8/10 2/9/10 17:15 105653 190530 1 218/10 2/17/10 23:40 105653 190530 1 2/ 8/10 2/17/10 23:40 105653 190530 1 2/ 8/10 2/17/10 23:40 105653 190530 1 2/ 8/10 2/9/10 17:15 105653 190530 1 2/ 8/10 2/17/10 23:40 105653 190530 Surrogate Name Perfluoro-n-[l,2,3,4,5-13C5] nonanoic acid Perfluoro-n-[l,2,3,4-13C4] butanoic acid Perfluoro-n-[l,2,3,4-13C4] octanoic acid Perfluoro-n-[l,2-13C2] decanoicacid Perfluoro-n-[l,2-13C2] hexanoicacid Perfluoro-n-[1,2-13C2]dodecanoic Acid Perfluoro-n-[1,2-13C2]undecanoic Acid Sodium perfluoro-l-[l,2,3,4-13C4] octanesulfonate Sodium perfluoro-1-hexane[1802]sulfonate %Rec 102 100 100 100 100 82 60 111 96 Control Limits 50-150 50-150 50-150 50-150 50-150 50-150 50-150 50-150 50-150 Date Analyzed Q 2/17/10 23:40 2/9/10 17:15 2/17/10 23:40 2/9/10 17:15 2/9/10 17:15 2/17/10 23:40 2/17/10 23:40 2/17/10 23:40 2/9/10 17:15 Note Comments: Printed 2/23/10 13:37 \\Inflow2\Starlims\LimsReps\AnalyticalReport.rpt Form 1A 36 SuperSet Reference: 10-0000135123 rev 00 Client: Project: Sample Matrix: Sample Name: Lab Code: Run Type: Analytical Report Camp Dresser & McKee, Incorporated (CDM) Baron & Budd, P.C./95779-75319 Water Bronson "Treated1 KQ1000620-01 Matrix Spike p. 111 Service Request: K1000968 Date Collected: 2/ 2/10 1054 Date Received: 2/ 3/10 Units: ng/L Basis: NA Perfluorinated Sulfonic Acids and Perfluorinated Carboxylic Acids by HPLC/MS Analytical Method: PFOA Prep Method: Method Analyte Name Perfluoro-n-tetradecanoic acid Perfluoro-n-tridecanoic acid Perfluorobutanesulfonate Perfluorobutanoic Acid Perfluorodecane Sulfonate Perfluorodecanoic Acid Perfluorododecanoic Acid Perfluoroheptanoic Acid Perfluorohexanesulfonate Perfluorohexanoic Acid Perfluorononanoic Acid Perfluorooctanesulfonate Perfluorooctanoic Acid Perfluoropentanoic Acid Perfluoroundecanoic Acid Result Q 107 107 115 116 59.0 78.5 113 134 188 152 107 198 177 139 101 MRL 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 MDL 0.46 0.95 0.029 0.11 0.095 0.48 0.85 0.081 0.030 0.11 0.12 0.046 0.066 0.11 1.3 Dilution Date Date Extraction Analysis Factor Extracted Analyzed Lot Lot Note 1 2/ 8/10 2/17/10 23:25 105653 190530 1 2/ 8/10 2/17/10 23:25 105653 190530 1 2/ 8/10 2/9/10 16:56 105653 190530 1 2/ 8/10 2/9/10 16:56 105653 190530 1 2/ 8/10 2/17/10 23:25 105653 190530 1 2/ 8/10 2/17/10 23:25 105653 190530 1 2/ 8/10 2/17/10 23:25 105653 190530 1 2/ 8/10 2/9/10 16:56 105653 190530 1 2/ 8/10 2/9/10 16:56 105653 190530 1 2/ 8/10 2/9/10 16:56 105653 190530 1 2/ 8/10 2/17/10 23:25 105653 190530 1 2/ 8/10 2/17/10 23:25 105653 190530 1 2/ 8/10 2/17/10 23:25 105653 190530 1 2/ 8/10 2/9/10 16:56 105653 190530 1 2/ 8/10 2/17/10 23:25 105653 190530 Surrogate Name Perfluoro-n-[l,2,3,4,5-13C5] nonanoic acid Perfluoro-n-[l,2,3,4-13C4] butanoic acid Perfluoro-n-[l,2,3,4-13C4] octanoic acid Perfluoro-n-[l,2-13C2] decanoicacid Perfluoro-n-[l,2-13C2] hexanoicacid Perfluoro-n-[l,2-13C2]dodecanoic Acid Perfluoro-n-[l ,2-13C2]undecanoic Acid Sodium perfluoro-l-[l,2,3,4-13C4] octanesulfonate Sodium perfluoro-1-hexane[l802]suIfonate %Rec 85 72 86 100 77 60 46 * 88 88 Control Limits 50-150 50-150 50-150 50-150 50-150 50-150 50-150 50-150 50-150 Date Analyzed Q 2/17/10 23:25 2/9/10 16:56 2/17/10 23:25 2/9/10 16:56 2/9/10 16:56 2/17/10 23:25 2/17/10 23:25 2/17/10 23:25 2/9/10 16:56 Note Comments: Printed 2/23/10 13:37 \\Inflow2\Starlims\LimsReps\AnalyticaIReport.rpt Form 1A Superset Reference: 10-0000135123 rev 00 Client: Project: Sample Matrix: Sample Name: Lab Code: Run Type: Analytical Report Camp Dresser & McKee, Incorporated (CDM) Baron & Budd, P.C./95779-75319 Water Bronson "Raw" KQ1000620-03 Matrix Spike p. 112 Service Request: K 1000968 Date Collected: 2/ 2/10 1041 Date Received: 2/ 3/10 Units: ng/L Basis: NA Perfluorinated Sulfonic Acids and Perfluorinated Carboxylic Acids by HPLC/MS Analytical Method: PFOA Prep Method: Method Analyte Name Perfluoro-n-tetradecanoic acid Perfluoro-n-tridecanoic acid Perfluorobutanesulfonate Perfluorobutanoic Acid Perfluorodecane Sulfonate Perfluorodecanoic Acid Perfluorododecanoic Acid Perfluoroheptanoic Acid Perfluorohexanesulfonate Perfluorohexanoic Acid Perfluorononanoic Acid Perfluorooctanesulfonate Perfluorooctanoic Add Perfluoropentanoic Acid Perfluoroundecanoic Acid Result Q 105 101 100 104 53.5 83.0 111 107 122 114 93.5 152 121 110 95.5 MRL 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 MDL 0.46 0.95 0.029 0.11 0.095 0.48 0.85 0.081 0.030 0.11 0.12 0.046 0.066 0.11 1.3 Dilution Date Date Extraction Analysis Factor Extracted Analyzed Lot Lot Note 1 2/ 8/10 2/9/10 02:42 105653 190530 1 2/ 8/10 2/9/10 02:42 105653 190530 1 2/ 8/10 2/9/10 14:06 105653 190530 1 2/ 8/10 2/9/10 14:06 105653 190530 1 2/ 8/10 2/9/10 02:42 105653 190530 1 2/ 8/10 2/9/10 02:42 105653 190530 1 2/ 8/10 2/9/10 02:42 105653 190530 1 2/ 8/10 2/9/10 14:06 105653 190530 1 2/ 8/10 2/9/10 14:06 105653 190530 1 2/ 8/10 2/9/10 14:06 105653 190530 1 2/ 8/10 2/9/10 02:42 105653 190530 1 2/ 8/10 2/9/10 02:42 105653 190530 1 2/ 8/10 2/9/10 02:42 105653 190530 1 2/ 8/10 2/9/10 14:06 105653 190530 1 2/ 8/10 2/9/10 02:42 105653 190530 Surrogate Name Perfluoro-n-[l,2,3,4,5-13C5] nonanoic acid Perfluoro-n-[l,2,3,4-13C4] butanoic acid Perfluoro-n-[l,2,3,4-13C4] octanoic acid Perfluoro-n-[l,2-13C2] decanoic acid Perfluoro-n-[l,2-13C2] hexanoic acid Perfluoro-n-[l,2-13C2]dodecanoic Acid Perfluoro-n-[1,2-13C2]undecanoic Acid Sodiumperfluoro-l-[l,2,3,4-13C4] octanesulfonate Sodium perfluoro-l-hexane[1802]sulfonate %Rec 99 72 103 100 78 64 51 83 83 Control Limits 50-150 50-150 50-150 50-150 50-150 50-150 50-150 50-150 50-150 Date Analyzed 2/9/10 02:42 2/9/10 14:06 2/9/10 02:42 2/9/10 02:42 2/9/10 14:06 2/9/10 02:42 2/9/10 02:42 2/9/10 02:42 2/9/10 14:06 Q Note Comments: Printed 2/23/10 13:37 \\Inflow2\Starlims\LimsReps\AnalyticalReport.ipt Form 1A 38 SupcrSet Reference: 10-000013523rev00 Client: Project: Sample Matrix: Sample Name: Lab Code: Run Type: Analytical Report Camp Dresser & McKee, Incorporated (CDM) Baron & Budd, P.C./95779-753I9 Water Bronson "Treated" KQ1000620-02 Duplicate Matrix Spike p. 113 Service Request: K 1000968 Date Collected: 2/ 2/10 1054 Date Received: 2/ 3/10 Units: ng/L Basis: NA Perfluorinated Sulfonic Acids and Perfluorinated Carboxylic Acids by HPLC/MS Analytical Method: PFOA Prep Method: Method Analyte Name Perfluoro-n-tetradecanoic acid Perfluoro-n-tridecanoic acid Perfluorobutanesulfonate Perfluorobutanoic Acid Perfluorodecane Sulfonate Perfluorodecanoic Acid Perfluorododecanoic Acid Perfluoroheptanoic Acid Perfluorohexanesulfonate Perfluorohexanoic Acid Perfluorononanoic Acid Perfluorooctanesulfonate Perfluorooctanoic Acid Perfluoropentanoic Acid Perfluoroundecanoic Acid Result Q 123 92.0 113 115 60.5 84.0 112 120 186 138 105 209 196 130 110 MRL 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 MDL 0.46 0.95 0.029 0.11 0.095 0.48 0.85 0.081 0.030 0.11 0.12 0.046 0.066 0.11 1.3 Dilution Date Date Extraction Analysis Factor Extracted Analyzed Lot Lot Note 1 2/ 8/10 2/17/10 23:32 105653 190530 1 2/ 8/10 2/17/10 23:32 105653 190530 1 2/ 8/10 2/9/10 17:05 105653 190530 1 2/ 8/10 2/9/10 17:05 105653 190530 1 2/ 8/10 2/17/10 23:32 105653 190530 1 2/ 8/10 2/17/10 23:32 105653 190530 1 2/ 8/10 2/17/10 23:32 105653 190530 1 2/ 8/10 2/9/10 17:05 105653 190530 1 2/ 8/10 2/9/10 17:05 105653 190530 1 2/ 8/10 2/9/10 17:05 105653 190530 1 2/ 8/10 2/17/10 23:32 105653 190530 1 2/ 8/10 2/17/10 23:32 105653 190530 1 2/ 8/10 2/17/10 23:32 105653 190530 1 2/ 8/10 2/9/10 17:05 10565.3 190530 1 2/ 8/10 2/17/10 23:32 105653 190530 Surrogate Name Perfluoro-n-[l,2,3,4,5-13C5] nonanoic acid Perfluoro-n-[l,2,3,4-13C4] butanoic acid Perfluoro-n-[l,2,3,4-13C4] octanoic acid Perfluoro-n-[l,2-13C2] decanoicacid Perfluoro-n-[l,2-13C2] hexanoic acid Perfluoro-n-[l,2-13C2]dodecanoic Acid Perfluoro-n-[1,2-13C2]undecanoic Acid Sodium perfluoro-l-[l,2,3,4-13C4] octanesulfonate Sodium perfluoro-1-hexane[1802] sulfonate %Rec 86 77 86 100 87 60 50 92 94 Control Limits 50-150 50-150 50-150 50-150 50-150 50-150 50-150 50-150 50-150 Date Analyzed 2/17/10 23:32 2/9/10 17:05 2/17/10 23:32 2/9/10 17:05 2/9/10 17:05 2/17/10 23:32 2/17/10 23:32 2/17/10 23:32 2/9/10 17:05 Comments: Printed 2/23/10 13:37 \\Inflow2\Stariims\LimsReps\AnalyticalReport.rpt Forni 1A Superset Reference: 10-0000135123 rev 00 Client: Project: Sample Matrix: Sample Name: Lab Code: Run Type: Analytical Report Camp Dresser & McKee, Incorporated (CDM) Baron & Budd, P.C./95779-75319 Water Bronson "Raw" KQ1000620-04 Duplicate Matrix Spike P- 114 Service Request: K1000968 Date Collected: 2/ 2/10 1041 Date Received: 2/ 3/10 Units: n g /L Basis: NA Perfluorinated Sulfonic Acids and Perfluorinated Carboxylic Acids by HPLC/MS Analytical Method: PFOA Prep Method: Method Analyte Name Perfluoro-n-tetradecanoic acid Perfluoro-n-tridecanoic acid Perfluorobutanesulfonate Perfluorobutanoic Acid Perfluorodecane Sulfonate Perfluorodecanoic Acid Perfluorododecanoic Acid Perfluoroheptanoic Acid Perfluorohexanesulfonate Perfluorohexanoic Acid Perfluorononanoic Acid Perfluorooctanesulfonate Perfluorooctanoic Acid Perfluoropentanoic Acid Perfluoroundecanoic Acid Result Q 84.5 113 108 110 55.0 65.5 139 110 133 120 91.0 163 122 114 118 MRL 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 MDL 0.46 0.95 0.029 0.11 0.095 0.48 0.85 0.081 0.030 0.11 0.12 0.046 0.066 0.11 1.3 Dilution Date Date Extraction Analysis Factor Extracted Analyzed Lot Lot Note 1 2/ 8/10 2/9/10 02:49 105653 190530 1 2/ 8/10 2/9/10 02:49 105653 190530 1 2/ 8/10 2/9/10 14:15 105653 190530 1 2/ 8/10 2/9/10 14:15 105653 190530 1 218/10 2/9/10 02:49 105653 190530 1 2/ 8/10 2/9/10 02:49 105653 190530 1 2/ 8/10 2/9/10 02:49 105653 190530 1 2/ 8/10 2/9/10 14:15 105653 190530 1 2/ 8/10 2/9/10 14:15 105653 190530 1 2/ 8/10 2/9/10 14:15 105653 190530 1 2/ 8/10 2/9/10 02:49 105653 190530 1 2/8/10 2/9/10 02:49 105653 190530 1 2/ 8/10 2/9/10 02:49 105653 190530 1 2/ 8/10 2/9/10 14:15 105653 190530 1 2/ 8/10 2/9/10 02:49 105653 190530 Surrogate Name Perfluoro-n-[l,2,3,4,5-13C5] nonanoic acid Perfluoro-n-[l,2,3,4-13C4] butanoic acid Perfluoro-n-[l,2,3,4-13C4] octanoic acid Perfluoro-n-[l,2-13C2] decanoic acid Perfluoro-n-[l,2-13C2] hexanoic acid Perfluoro-n-[l,2-13C2]dodecanoic Acid Perfluoro-n-[1,2-13C2]undecanoic Acid Sodium p e rflu o ro -l-[l,2 ,3 ,4 -1 3 C 4 ] octanesulfonate Sodium perfluoro-l-hexane[1802]sulfonate %Rec 81 72 96 100 78 40 * 31 * 58 80 Control Limits 50-150 50-150 50-150 50-150 50-150 50-150 50-150 50-150 50-150 Date Analyzed 2/9/10 02:49 2/9/10 14:15 2/9/10 02:49 2/9/10 02:49 2/9/10 14:15 2/9/10 02:49 2/9/10 02:49 2/9/10 02:49 2/9/10 14:15 Q Note Comments: Printed 2/23/10 13:37 \Unflow2\Starlims\LimsReps\AnalyticalReportipt Form 1A 40 SuperSet Reference: 10-0000135123 rev 00 Client: Project: Sample Matrix: QA/QC Report p. 115 Camp Dresser & McKee, Incorporated (CDM) Baron & Budd, P.C./95779-75319 Water Service Request: K1000968 Date Collected: 2/2/10 Date Received: 2/3/10 Date Analyzed: 2/9/10 Matrix Spike Summary Perfluorinated Sulfonic Acids and Perfluorinated Carboxylic Acids by HPLC/MS Sample Name: Lab Code: Bronson "Raw" K1000968-010 Units: ng/L Basis: NA Analytical Method: PFOA Prep Method: Method Analyte Name Perfluoro-n-tetradecanoic acid Perfluoro-n-tridecanoic acid Perfluorobutanesulfonate Perfluorobutanoic Acid Perfluorodecane Sulfonate Perfluorodecanoic Acid Perfluorododecanoic Acid Perfluoroheptanoic Acid Perfluorohexanesulfonate Perfluorohexanoic Acid Perfluorononanoic Acid Perfluorooctanesulfonate Perfluorooctanoic Acid Perfluoropentanoic Acid Perfluoroundecanoic Acid Sample Result ND ND 4.5 5.4 0.16 ND ND 7.7 33 14 0.98 58 25 13 ND Matrix Spike KQ1000620-03 Result Amount % Rec 105 100 105 101 100 101 100 100 96 104 100 99 53.5 100 53 83.0 100 83 111 100 111 107 100 99 122 100 89 114 100 99 93.5 100 93 152 100 94 121 100 96 110 100 97 95.5 100 96 Duplicate Matrix Spike KQ1000620-04 Result Amount % Rec 84.5 100 85 113 100 113 108 100 104 110 100 104 55.0 100 55 65.5 100 66 139 100 139 110 100 102 133 100 100 120 100 105 91.0 100 90 163 100 105 122 100 97 114 100 101 118 100 118 % Rec RPD Limits RPD Limit 50 - 150 50 - 150 50 - 150 50 - 150 50 - 150 50 - 150 50 - 150 50 - 150 50 -150 50 -150 50 - 150 50 - 150 50 - 150 50 - 150 50 - 150 22 11 8 5 3 24 23 3 9 5 3 7 1 3 21 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 Comments: Printed 2/23/10 13:38 \\Inilow2\Starlims\LimsReps\MatrixSpike.rpt M atrix Spike Sum m ary 41 Superset Reference: 10-0000135123 rev 00 Client: Project: Sample Matrix: QA/QC Report p. 116 Camp Dresser & McKee, Incorporated (CDM) Baron & Budd, P.C./95779-75319 Water Service Request: K1000968 Date Collected: 2/2/10 Date Received: 2/3/10 Date Analyzed: 2/ 9/10 2/17/10 Matrix Spike Summary Perfluorinated Sulfonic Acids and Perfluorinated Carboxylic Acids by HPLC/MS Sample Name: Lab Code: Bronson "Treated" K1000968-011 Units: ng/L Basis: NA Analytical Method: PFOA Prep Method: Method Analyte Name Perfluoro-n-tetradecanoic acid Perfluoro-n-tridecanoic acid Perfluorobutanesulfonate Perfluorobutanoic Acid Perfluorodecane Sulfonate Perfluorodecanoic Acid Perfluorododecanoic Acid Perfluoroheptanoic Acid Perfluorohexanesulfonate Perfluorohexanoic Acid Perfluorononanoic Acid Perfluorooctanesulfonate Perfluorooctanoic Acid Perfluoropentanoic Acid Perfluoroundecanoic Acid Sample Result ND ND 12 9.7 ND ND ND 18 98 37 1.6 81 68 32 ND Matrix Spike KQ1000620-01 Resull: Amount % Ree 107 100 107 107 100 107 115 100 103 116 100 106 59.0 100 59 78.5 100 79 113 100 113 134 100 116 188 100 91 152 100 115 107 100 105 198 100 117 177 100 109 139 100 107 101 100 101 Duplicate Matrix Spike KQ1000620-02 Result Amount % Ree 123 100 123 92.0 100 92 113 100 101 115 100 105 60.5 100 61 84.0 100 84 112 100 112 120 100 102 186 100 88 138 100 101 105 100 103 209 100 128 196 100 128 130 100 98 110 100 110 % Ree Limits 50 -150 50 - 150 50 - 150 50 - 150 50 -150 50 -150 50 -150 50 - 150 50 - 150 50 - 150 50 - 150 50 - 150 50 - 150 50 - 150 50 -150 RPD RPD Limit 14 30 15 30 2 30 1 30 3 30 7 30 1 30 11 30 1 30 10 30 2 30 5 30 10 30 6 30 9 30 Comments: Printed 2/23/10 13:38 \\3nflow2\StarlimsVUmsReps\MatrixSpike.ipt M atrix Spike Summ ary 42 Superset Reference: 10-0000135123 rev 00 Client: Project: Sample Matrix: QA/QC Report p. 117 Camp Dresser & McKee, Incorporated (CDM) Baron & Budd, P.C./95779-75319 Water Service Request : K1000968 Date Analyzed: 2/ 9/10 - 2/17/10 Lab Control Sample Summary Perfluorinated Sulfonic Acids and Perfluorinated Carboxylic Acids by HPLC/MS Analytical Method: PFOA Prep Method: Method Units: ng/L Basis: NA Extraction Lot: 105653 Analyte Name Perfluoro-n-tetradecanoic acid Perfluoro-n-tridecanoic acid Perfluorobutanesulfonate Perfluorobutanoic Acid Perfluorodecane Sulfonate Perfluorodecanoic Acid Perfluorododecanoic Acid Perfluoroheptanoic Acid Perfluorohexanesulfonate Perfluorohexanoic Acid Perfluorononanoic Acid Perfluorooctanesulfonate Perfluorooctanoic Acid Perfluoropentanoic Acid Perfluoroundecanoic Acid Lab Control Sample KQ1000620-05 Result Expected % Rec 111 100 111 108 100 108 90.5 100 91 103 100 103 69.5 100 70 107 100 107 146 100 146 104 100 104 98.0 100 98 95.5 100 96 102 100 102 102 100 102 96.0 100 96 103 100 103 120 100 120 % Rec Limits 50 - 150 50 - 150 50 - 150 50 - 150 50 - 150 50 - 150 50 - 150 50 - 150 50 - 150 50 -150 50 - 150 50 - 150 50 - 150 50 - 150 50 -150 Comments: Printed 2/23/10 13:38 \\Inilow2\Starlims\LimsReps\LabControlSample.ipt Lab Control Sample Sum m ary 43 SuperSet Reference: 10-0000135123 rev 00 p. 118 Created with Analyst Reporter Printed: 14/02/2010 6:41:00 PM Project Data File Result Table Instrument Name Ewan's ProjectsVPFCs 02081 Ob\SamplesLong.wiff 02081 OSamplesLong.rdb API 5000 Sample Name Acquisition Date Acquisition Method Injection Vial K1000968-001 2/9/2010 12:10:38 AM PFCkinetexLong.dam 21 Injection Volume Sample Type Dilution Factor Weight to Volume 5 Unknown 1.00 0.00 Results Summary Analyte Peak Name IS Name PFOA 1 13C-PFOA PFNA 1 13C-PFNA PFOS 1 13C-PFOS PFDA 1 13C-PFDA PFUnA 1 13C-PFUnA PFDS 1 13C-PFOS PFDoA 1 13C-PFDOA PFTrA 1 13C-PFDOA PFTeA 1 13C-PFDOA IS Area 3412900 2798300 6231700 2675300 128760 6231700 136190 136190 136190 Analyte RT (Exp RT ) 0.00(1.36) 0.00 (2.42) 2.38 (2.53) 0.00 (3.34) 4.13 (4.06) 0.00 (4.10) 0.00 (4.63) 0.00(5.14) 0.00(5.74) Analyte Area 0 0 14302 0 4354 0 0 0 0 Calc. Cone (ng/mL) N/A N/A 0.036 N/A 0.014 N/A N/A N/A N/A Modified? No No No No No No No No No o 2- Page 154 of 242 44 p. 119 Created with Analyst Reporter Printed: 14/02/2010 6:41:00 PM IRC Summary A n a ly te P eak N am e PFOA2 S_13C_PFOA PFNA2 S_13C_PFNA PFOS2 S_13C-PFOS PFDA2 S_13C-PFDA PFUnA2 S_13C-PFUnA PFDS2 PFDoA2 S_13C-PFDoA PFTrA 2 PFTeA2 RT (E xp RT ) 0.00(1.36) 1.40 (1.36) 2.45 (2.44) 2.36 (2.44) 2.38 (2.53) 2.39 (2.53) 0.00 (3.34) 3.37 (3.34) 0.00 (4.06) 4.14(4.06) 4.15(4.10) 4.59 (4.64) 4.78 (4.64) 0.00(5.13) 5.42 (5.56) A rea 0 3412900 168 2798300 3689 6231700 0 2675300 0 128760 310 1140 136190 0 257 M o d ifie d ? No C a lc (E xp ) MRM R a tio 0.00(2.38) R a tio C o n firm s ID No No 0.00 (50.17) No No 0.00 (0.28) No No 0.00(19.17) No No 0.26(0.32) YES No 435.72 (22.53) No No 0.00 (0.15) No No 0.00(22.10) No No 0.00 (0.22) No No 29.57(1.86) No No 0.00 (0.32) No No 0.00 (0.29) No No 0.00 (3.08) No No 0.00 (0.32) No No 0.00(0.36) No Page 155 of 242 45 Quantitative Peak Review p. 120 Created with Analyst Reporter Printed: 14/02/2010 6:41:00 PM K1000968-001 Before After 46 Page 156 of 242 p. 121 Created with Analyst Reporter Printed: 14/02/2010 6:41:00 PM Ion Ratio Confirmation .. i ', ' 'Om. ' IMJIi "4 ' - _.... PFOA2 413.0/369.0 Da Baseline a Missed Wrong Peak PFNA2 463.0/219.0 Da n Baseline Missed Wrong Peak K1000968-001 i miifl 1 i: h PFOS2 499.0/99.0 Da d Baseline Missed Wrong Peak PFDA2 513.0/269.0 Da Baseline c Missed u Wrong Peak PFUnA2 563.0/269.0 Da Baseline Missed u Wrong Peak 4 .1 5 PFDS2 599.0/99.0 Da d Baseline Missed Wrong Peak PFDoA2 613.0/169.0 Da Baseline Missed q Wrong Peak PFTrA 2 663.0/169.0 Da d Baseline Missed Wrong Peak PFTeA2 713.0/169.0 Da Baseline a Missed Wrong Peak Before After Page 157 of 242 47 iumbia p. 122 Created with Analyst Reporter Printed: 15/02/2010 2:34:00 PM Project Data File Result Table Instrument Name Ewan's Projects\PFCs 020810\SamplesShort.wiff 02081 OSamplesShortedit.rdb API 5000 Sample Name Acquisition Date Acquisition Method Injection Vial K 1000968-001 2/9/2010 10:55:02 AM PFCkinetexShort.dam 21 Injection Volume Sample Type Dilution Factor Weight to Volume 5 Unknown 1.00 0.00 Results Summary Analyte Peak Name IS Name PFBA 1 13C-PFBA PFPeA 1 13C-PFHxA PFBS 1 180-PFHS PFHxA 1 130-PFHxA PFHpA 1 130-PFHxA PFHxS 1 180-PFHS SJ80-PFHS 13C-PFDA SJ3C-PFDA 13C-PFDA IS Area 5103700 5834800 3174700 5834800 5834800 3174700 5140400 5140400 Analyte RT (ExpRT) 1.26 (1.27) 3.59 (3.60) 0.00 (4.26) 5.30 (5.31) 6.22 (6.23) 6.31 (6.32) 6.31 (6.31) 7.64 (7.65) Analyte Area 81389 48124 0 62044 14286 49102 3174700 5140400 Calc. Cone (ng/mL) 0.09 0.07 N/A 0.05 0.00 0.04 0.70 1.00 Modified? No No No No No No No No '5 Page 137 o f 245 48 p. 123 Created with Analyst Reporter Printed: 15/02/2010 2:34:00 PM IRC Summary Analyte Peak Name PFBA2 PFPeA2 PFBS2 PFHxA 2 PFHpA2 PFHxS2 S_13C-PFBA S_13C-PFHxA RT (Exp RT ) 1.26(1.27) 3.59(3.60) 0.00 (4.26) 5.30 (5.31) 6.21 (6.22) 6.31 (6.32) 1.26(1.26) 5.30(5.30) Area 81389 48124 0 5281 201680 18600 5103700 5834800 M o d ified ? No Calc (Exp) MRM R a tio 1.00(1.00) Ratio C onfirm s IO YES No 1.00(1.00) YES No 0.00(0.40) No No 0.09(0.10) YES No 14.12(3.03) No No 0.38(0.40) YES No 62.71 (13.55) No No 94.04(13.06) No Page 138 of 245 49 p. 124 Created with Analyst Reporter Printed: 15/02/2010 2:34:00 PM Quantitative Peak Review K1000968-001 L1 PFBA 1 213.0/169.0 Da Baseline Missed ii Wronn Peak 4li 45 SO PFBS 1 299.0/80.0 Da Baseline Missed r Wrnnn Peak 6.22 i H ..... PFHpAI 363.0/169.0 Da Baseline o Missed n Wrnnn Peak 6.31 1.26 L is m i s :a 13C-PFBA 217.0/172.0 Da c Baseline Missed n Wronn Peak 6.31 I 5Pf be-S 1 >5 55 | ft ft. Ml 05 711 180-PFHS 403.0/103.0 Da Baseline Missed n Wrnnn Peak l 5Ms h 1IWb 5.30 I si 1 * r. Ill SS bfl 13C-PFHxA 315.0/270.0 Da Baseline Missed n Wronn Peak 1 7 .^ 4 3e4 6 144 3.59 _ 1 PFPeA 1 263.0/219.0 Da Baseline Missed n Wrnnn Peak XM V am 5,000 | JU)0 .000 lOJO 4`, 5.30 MML . $(* S5 0 II 13C-PFHxA 315.0/270.0 Da n Wronn Peak 1M i | 45 so PFHxaI 313.0/269.0 Da a Baseline Missed n Wrnnn Peak 6.31 i.'Onii h woKICKill 81 1 i Mjno ~ 4000 i Sr :cic< . i.O. . . .L 85 . ............ 70 13C-PFHXA 315.0/270.0 Da Q n Wrnnn Peak *5 ?eS- PFHxSI 399.0/80.0 Da Baseline Missed n Wrnnn Peak 180-PFHS 403.0/103.0 Da n Wronn Peak 7 .^ 4 1 sm s Sb Cl) b', ? ) S 180-PFHS 403.0/103.0 Da Baseline a Missed n Wrnnn Peak_____ 70 75 fie <5 13C-PFDA 515.0/470.0 Da Baseline Missed n Wronn Peak_____ 1ts- ,o*t S 5.OeS i 7n ?S 80 ,15 S 13C-PFDA 515.0/470.0 Da Baseline Missed n Wrnnn Peak_____ 13C-PFDA 515.0/470.0 Da Baseline o Misse n Wrnnn Peak Before After Page 139 of 245 50 p. 125 Created with Analyst Reporter Printed: 15/02/2010 2:34:00 PM Ion Ratio Confirmation 1.26 PFBA2 213.0/169.0 Da Baseline Missed Wrong Peak 3 .5 9 i PFPeA2 263.0/219.0 Da Baseline Missed o Wrong Peak K1000968-001 PFBS2 299.0/99.0 Da Baseline Missed Wrong Peak 1 '3 0 PFHxA 2 313.0/119.0 Da Baseline Missed Wrong Peak PFHpA2 363.0/319.0 Da Baseline Missed Wrong Peak PFHxS2 399.0/99.0 Da Baseline Missed d Wrong Peak S_13C-PFDA 515.0/470.0 Da Baseline Missed c Wrong Peak NB. PFBA and PFPeA do not have qualifying ion transitions. Before After N/A Baseline Missed Wrong Peak Page 140 of 245 51