Document 2q1M0vpORBGkMJydknjEXLMRa
AR 226-0HoH
BIODEGRADATION
TEST SUBSTANCE
Identity:
Perfluorooctanesulfonylamido(ethyl)acetate; may also be referred to as PFOSAA, FC-128 or as the major component of FC-127, FC-129, FC-109, FC-109-X or R1904. (Glycine, N-
ethyl-N-[(heptadecafluorooctyl)sulfonyl}-, potassium salt, CAS #
2991-51-7)
Remarks: The test sample is FC-129 referred to by the test laboratory
as R1904. Current information indicates it is a mixture of 42% test
substance, 32% water, 14% 2-butoxyethanol, 4% ethanol, and 8% C4-C7
fluoroalkyl carboxylate compounds. Test material was from 3M production
lot 930014, mfg. date 3/97.
The following summary is abbreviated because the test sample is a mixture of the test substance in a water/organic solvent solution.
Data does not accurately relate biodegradation of the test sample
with that of the test substance.
METHOD:
Method: Not noted. Type: Aerobic
GLP: No
Year completed: 1997 Contact time: 28 days
Inoculum: Polyseed NX, lot D257
RESULTS
COD: 462,000 mg Oz/ kg chemical
BOD
First Replicate BOD
Second Replicate BOD
[5 <8 |
oso |
[FoT18 | 6 sers0 0 |
[20 T"&70 | 7e400
|
C2 1 289000[280000|
Remarks: The BOD and COD values are expected tobethe result of biodegradationof the organic solvent componentsofthe test sample.
These values are not expected to be representative of the Perfluorooctanesulfonylamido(ethyl)acetate.
000353
Co
CONCLUSIONS This testing indicated that some portion of the test sample biodegraded in
aerobic environments capable of supporting biodegradation.
Submitter: 3M Company, Environmental Laboratory, P.O. Box 33331, St. Paul, Minnesota, 55133
DATA QUALITY
Reliability: Kiimisch ranking 3. This study lacks information on the
methodology. Testing cannot conclude what portions of the test sample
were responsible for the apparent biodegradation values. Comparison
`with the COD value for determination of the level of biodegradation is not valuable without a description of how the COD value was obtained. REFERENCES This study was conducted at AScl Corporation of Duluth, Minnesota at the
request of the 3M Company.
OTHER
Last changed: 5/17/00
000033554
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SuEbAnmSiietrleodnCnotmoopt3oaMrltTConoe/miApnSagcntyDDi-vui1s9ho7n ASCLDETD Study ID 45010.068
R1904 BOD REPORT FOR
3M COMPANY
Submitted to
3M
Environmental Technology and 935 Bush Avenue
Safety
Services
Building 2-3E-09
PO Box 33331
St. Paul, MN 55133-3331
Prepared by EAnSvcilroCnomrepnotraaltiToens/tAiSncgl-DDiuvilsuitohn
Du4l4u4th4, AMiirnpnaerksoBtoaule5v5a8r1d1
SSppoonnssoorr. Su3dMyCIoDmWpRa1ny04
JuLy 1997 . 000355
COD = 462,000 mg O, / kg chemical.
Dates of BOD test: 6/11/97 - 7/9/97.
`Water bath temperature range during the test: Lot number of Polyseed NX: D257.
19.0 - 20.0C.
SuEbSmmcirttoedCnomtmsepMnoaraCTiooonnAgoSenDDotonys SIDED Soy 5 Poses
Pr C lal TABLE 1. BOD Dilution Information for R1904
| pen | cmmmimen | Tw | em o se T 0] L ws |T es
[0 [ s [eswo ee T | wo as T | w an |
TABLE 2. BOD Blank Calculations for R1904
1 _ |ET FIRST T REPLICATE _ TsT cowmemomeJ
|
* Jano [reino |ooom |wino |rmino | 00ow|
[owTs[ wo | ow [ a0 | ou | ow |o |
[ow [oo[a0 [on[ow |i 0|an |on|
Soma sy 53R104
: -1- 000356
bEJmergCorponftoounnsDtcenkn Se eo
TABLE 3. BOD Seed Correction Factor Calculations for R1904
[== HEBEEERERREEl] -- - [oreo]
|I seed onecone. | Day f
wou | oo
cowEmmTon |]
ron| oo.
1 woAverage
To [onTow[on onTeaTonToon] [ L0 o T[oolboow[[5a0e[ To0n[Tooaw |oonnT[eow [|o2ns0[|aonn ||oamw||
*SCF = (D.O. drop *mlseedin test) / mlseed inseedblank.
TABLE 4. BOD Reference? and Tox Blanks Calculations for R1904
= To ae[on [oo oe i[oT | [ oT Conc.| Day| SCF rem | e oowmmm on I
Mfeo [5[on]RosooTew T1oDnp[|cDoroT|p omyth[|eDwO[|oDOa.[| oDrnop[|oDerT|o omampt.] (oa [JooLoo [an[onTosToon [rus [na[sm|vs|]
* Reference = 150 mg glucose and 150 mg glutamic acid in 1 liter BOD dilution water, tested at 2%
dilution.
BOD mg/L = (corrected D.O. drop) * 300 ml BOD volume / 6 ml reference.
Sr
. 000357
SEmAsetrgCoipoTCniosnnigtoron5tsnetn pr
TABLE 5. BOD Calculations for R1904
|Iccooee| ow FEE |ser |mFe ou| Do. r | come|o 500 HEEEGE cc [ Fo ou|w 00|mcornes|o50n 0|
[[oieoesTLsssTTToooooalPoaonwwT[Poooomae[[FuoonneT[[oovsaoe| T|o=] m[oi oom[[e room[Luon aoe|[rooo snwe| T[on 7o--n]||
[a ee
[rorToTow
|
as
Tem[oe
1 [20Jovomo|I
wou[7a[ame|
am|=]
Fue ToTow ow Tomo[vo [am| oro [om[am| aur|ome |
pei [ioToco [eoLoo Too
[asoTame[ore[ss [mmm [ooo|ase|536| are | woo | Le TomTos TomTomo[asoTous[as|ows| -|
1
[verse]
[osTooToo
J| as
ToonTow[om |
1
= [oo[ow[10
|
am
|
|
Live [0Loon [21[20Tow
L| aoww T[osmo[{2arm[[uosme [|nn|[oomw|[eoosn[[a7se ||
oo| - | aw |sem |
[5L 00[anToe m | om[wam n ws|5] s[wo| om [ass|535 |soo |somo|
rr
[io TosTroe|aso [ase[soe |26[osamo | oor[se[ws|a | emo|
[isTos[vos[om [ow[ow[sur[oem | so [225|oes | 557 | sono|
PaarlfeeLealonLom]
eww]
ew]
* BOD = corrected drop x 1,000,000 /test concentration.
Omidtatatpoe intds: FiDn.aOl. Ddr.o0p. c<or0r.e5ct0edmgf/oLr.SCF too low (<2.0).
Som Sty mais
:
-3-
000358
EAnSveilroCnomernptoarltoTne/vAiSncgl-DDivuilsuitohn SAuSbmCiDteEdT1D 3StMudCyoImDp#a5n0-1y0.705678
APPENDIX A -- Raw Data Sheets
SpSopnonssoorrS:tu3dMyICDom#pRaInSy04
. 000359
BIODEGRADATION (METHYLENE BLUE ACTIVE SUBSTANCE) TEST SUBSTANCE
Identity: Perfluorooctanesulfonylamido(ethyl)acetate; may also be
FreCf-e1r2r7ed, tFoC-a1s2P9,FOFSCA-A10,9,FCF-C1-21809or-XasorthRe19m0a4j.or (cGolmycpionne,enNt- of
ethyk-N-{(heptadecafiuorooctyl)sulfonyil-, 2991-51-7)
potassium
salt,
CAS
#
Remarks: The test sample is FC-129 referred to by the test laboratory
iansfosrammaptlioenGi1n2d0i8ca-t1esaint disraepmliixctatuereaonfal4ys2i%s atessstasmupbslteanGc1e2,083-42.% Cwuarterre,nt 14% 2-butoxyethanol, 4% ethanol, and 8% Cs-C; fluoroalkyl carboxylate
compounds. Test material was from 3M production lot 564.
The following summary is abbreviated because thetestsample is a mixtureofthe test substance in a water/organic solvent solution. Data does not accurately relate biodegradation of the test sample with that of the test substance.
METHOD:
Method: EPA Method 425.1
Type: Methylene Blue Active Substance GLP: No Year completed: 1989
RESULTS
G1208-1: 2200 mgikg
G1208-4: 2800 mg/kg (duplicate of G1208-1) Duplicate EPA LAS Reference samples: 60,000 mg/kg
60,000 mg/kg
CONCLUSIONS
This testing indicated MBAS study.
that
the
test
sample
exhibited
minimal
activity
in
this
Submitter: 3M Company, Environmental Laboratory, P.O. Box 33331,
St. Paul, Minnesota, 55133
DATA QUALITY
000360
Reliability: Klimisch ranking 2. This study lacks information on the methodology and testing parameters. Test substance purity within the test
sample was not sufficiently characterized
REFERENCES
This study was conducted at Pace Analytical of Minneapolis, Minnesota at the requestof the 3M Company.
OTHER
Last changed: 5/17/00
000361
ee
". 0> 2/22/1989
ENVIRONMENkTtALRELVAIBSOERDATO%R4Yk FINAL REPORT
1
LAB REQUEST NO. G1208
:
RDEEQPUARETSHTEONRT:NAM0E5:35EA REINER PDARTOEJECRETCENIO:VED9:970020/10031/010989 DESC: MBAS OF FC-129, TRITON HG
CCOONNTTRRAACCTT LLAABB: COPSATC:E 162 E3XKPB-COLMPHOUDRAST:E: 020/17/1989 DATE COMPLETED: 02/15/1989
SSATHAPNLDEASRDSLHAOSULDSOLBEUTIDOENLIVFEORREDCOMIPNARWIYSONNA.ME TDOO TAHLEL LEAXBT.RACTRIUONNSA AMNEDASUBRAECMKENVTASHONCTAHLELED FSOTRANIDNARDPROICSEDPURROEB.ABLEFC-A1B2O9UTIS3255.0% TSEOSLITDSF.C-12I9TSATMVAIMSOL62A3R.COTNHCEENTMRVATOIFONTHEEQULAALS TO TGH1A2T08-O3F LIASS.AN EPA LAS REFERENCE MATERIAL: LOT $1138, AVE. M.V. 318, ACTIVE LDAESTE6R.G0E0NTX,ASSPORCEIPAATRIEODN,BYDAETWESL9C65I.NCINNATI US EPA IN COOPERATION VITH SOAP AND
Revised report shows correction in project description above.
SAMPLE DATE CODE
DESCRIPTION RESULT " MIN DET LIMIT
1
Fc-129
LOT 564
SIUNROFRAGCATNAINCTSTES--TSMBARSEPORT 2S2E0E0AMTGT/AKCGHED REPORT 5
2
TRITON E66 RH-RM 6-1536
*SURFACTANTS - MBAS
1000 HG/KG
5
3
Las STO. EPA LOT 1138
v
*SURFACTANTS - MBAS
60000 MG/KG
*5
:
4
DUPLICATE #1
*SURPACTANTS - MBAS
2800 MG/KG
5
5
DUPLICATE 42 ~=====~~~="
SURFACTANTS - MBAS
1200 KG/KG
5
6
DUPLICATE 3
SURFACTANTS - MBAS
60000 MG/KG
5
* = CONTRACT LAB
SUBMITTED BY: _(_ Wane DATED: __ 2-23-99
000362
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boratories. nc
REPORT OF LABORATORY .ANALYSIS
Ofices: TtCMiooninsneaeepcoFiliisod, weMiannesota
February 10, 1989
M3r. EnWvadieronSmcehnetlall Laboratory
935 Bush Avenue Bldg. 2-3E St. Paul, MN 55133
Gl208
oe Hitfeg
wh"i
Dear Mr. Schell:
ti Enclosed 1s the report of laboratory analyses for samples received If you have any questions concerning. this report, please feel free
to contact Tom Halverson or me.
Sincerely,
Bn Godel! f-
RoghrC. Splinter, Ph.D.
Director, Laboratory Services
.
#
Enclosures
.
A
'
000363
:
140 Gouge Dv North Minesprlis, WNs5u5422 Phone 012) 3445543
pace
:
ries,nc
REPORT OF LABORATORY ANALYSIS
:
OfficTMeaisnm:npeaa.poFlliosr,idMainnesota
Nova. Saiowia
3M Environmental Laboratory 935 Bush Avenue
Bldg. 2-3E
St. Paul, MN 55133
February 10, 1989 PACE Project Number: 890203509
Attn: Mr. Wade Schell
G1208
Date Sample(s) Collected: By Client Date Sample(s) Received: 02/03/89
PPaArCaEmeStameprle Number: INORGANIC ANALYSIS
INDIVIDUAL PARAMETERS Surfactants (1)
Units
mg/kg
MDL 0G3I221018-0)
-
5
2200
0G312210280-2
1000
03G2l123008-3
60000
MOL
Method Detection Limit
}
000364
1710 Douglas Drive North1qMitnrneoapppolriusn,tMyeNm5i54r222 Phone (612) 544-5643
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REPORT OF LABORATORY ANALYSIS
VTianmnpeaa,poFlosr,idMainnesota
boratories, ne
:
Elle.
Mr. Wade Schell
Page 2
February 10, 1989
PACE Project Number: 890203509
PPaArCaEmeStameprle Number: INORGANIC ANALYSIS
INDIVIDUAL PARAMETERS Surfactants (1)
Units
mg/kg
MOL am
Method Detection Limit Analysis performed by EPA Method 425.1.
MDL 0G312210480-4 03G2210580-5
5
2800
1200
0G3220186-06
60000
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my direct supervision.
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Inorganic Chemistry Manager
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000365
1710 Douglas Dive Northan0ecMuisnlneoapppoolrtiusn,itMyNerm5pi5o4y2e2r 2 Phone (612) 544.5543
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DATE ANALYZED: 2/b[57
AUALYZED BY:
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PROJECT NUMBER:
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