Document 2oJYq5Ge8BOpLvbVa79mLNxr

03/31/93 09:29 DU PONT OEM 302 773 0123 001 V / Du Pont Chemicals 2190FR Revised 28-Jan-92 Printed 23-Dec-92 "SUVA" CENTRI-LP # MATERIAL IDENTIFICATION Corporate Number DU002798 *8UVA* is a registered trademark of Du Pont. ManufacturerfDlstrlbutor Phone Numbers Chemical Family Du Pont Registry Number Formula TSCA Inventory Status NPCA-HMIS Ratings Du Pont 1007 Market 8treet Wilmington, DE 19898 Product Information Transport Emergency Medical Emergency 1*800-441*9442 CHEMTREC: 1-800-424-9300 1-800-441-3637 HALOGENATED HYDROCARBON DPI 37-37-5 CHCI2CF3 Reported/Included Health: 1 Flammability: 0 Reactivity: 1, Personal Protection rating to be supplied by user depending on use conditions. # COMPONENTS Material ETHANE, 2,2-DICHLORO-1,1,1-TRIFLUORO- (HCFC 123) CA8 Number 306-83-2 Percent 100 # PHYSICAL DATAflcd Boiling Point Vapor Pressure Vapor Density ' 27.6*0 (81.7*F) at 760 mm Hg. 13 psla at 25 deg C (77 deg F) 5.3 (Air-1.0) Post-it* brand fax transmittal memo 7871 pdh * yfoucUL____________ ",ra TMuvUs Dipt </(// 9W(/ Jr* 75' Fail Printed on Recycled Paoer (oontJnu*d) DO A 061620 CONFIDENTIAL 03/31/93 09:29 DU PONT CHEM 302 773 0123 002 V # PHYSICAL DATA (continued) ( % Volatiles Evaporation Rate 100 WT% (CCI4 w i.o) Less than 1 Water Solubility 0.39 WT % at 25*C (77F) pH Neutral Odor 8llgh( ethereal Form Liquid Color Clear, colorless Liquid Density : 1.46 g/oo ate 25 dog C (77 dog r) # HAZARDOUS REACTIVITY Instability Incompatibility Polymerization Material Is stable. However, avoid open flame and high temperature. Incompatible with alkali or alkaline earth metals* powdered Al, Zn, Be, etc. Polymerization wffl not occur. Meeapocltlon, t DtcoMpotitim produces arc hancdoui. ' ' ' This compound oan ba daeenpoHd by high t*opHtun (epn tliuni, glowing anil urfaeM, ate.) forming hydrochloric and f hydrofluorlo aelde-poselbly carbonyl halldee. FIRE AND EXPLOSION DATA Flash Point Will not bum Flammable Limits In Air, % by Volume LEL Not applicable UEL Not applicable Autoignttlon Not determined Autodeoomposltion Not determined Fire and Explosion Hazards Containers may rupture under fire conditions. Decomposition may occur. Extinguishing Modia Special Firs Fighting Instructions As appropriate tor oombustlblss In area. Use water spray to cool oontalners. Setf-oorrtalned breathing apparatus (SCBA) Is required If drums rupture and contents are spilled under Are conditions. (continued) f 2100FR Pag* 2 DO A 0616?1 OONFTDFNTTAl 03/31/93 09:30 DU PONT CHEM 302 773 0123 003 y # HEALTH HAZARD INFORMATION mxMCXrAX. kaalth hazards (including Bignifioant Aoutes, Bffects, Symptoms of Overexposure, and Madical Conditions Aggravated by exposure) Inhalation of high concentrations of vapor it harmful and ay causa heart irregularities, unconsciousness, or death. Intentional misuse or deliberate inhalation sty cause death * without warning. Vapor reduces oxygen available for breathing and is heavier than air. Product causes mild eye irritation. Decomposition products are haserdous. ANIMAL DATA: Inhalation 4-hour fcCSOt Oral ALD : Skin Absorption LD50 92,000 ppm in rats 9000 mg/kg in rate >2090 ag/kg in rabbits The compound is not a skin irritant, is a mild to moderat eye irritant, and is not a skin sensitises in animals. Single applications of high doses to the skin caused nonspecific offeats such as weight loss and irritation. Toxic affects noted in animals from single exposure by inhalation at concentrations of 8000 ppm or greater include effects on unconditioned reflexes, locomotor activity and coordination, suggesting anesthetic effects. Single inhalation exposures of oonoentrations above 16,900 caused eantral nervous system effeats, such as anesthesia, and nonspecific effeots associated with lethality. Cardiac sensitisation occurred in dogs at concentrations of 20,000 ppm or greater. Aepeated exposures to 800 ppm resulted in alterations in blood chemistry; higher doses caused I anesthetic effects, reduced lymphocyte counts, increased liver weight and ensyme alterations, and decreased body weight gain. Long-term exposure caused decreased body weight, altered clinical ohaaistry, and increased urinary fluoride concentration in rats; dogs demonstrated slight liver damage. inhalation of 300, 1000 or 8000 ppm for two years caused an increase in benign testicular and benign pancreatic tumors in male rats; an increase in benign pancreatic tumors was observed in female rats exposed to 8000 ppm. In the same study, male and female rats exposed to 8000 ppm showed an increased incidence in benign liver toners. Smaller increases in the incidence of these benign liver tumors were observed in females at 300 and 1000 ppm, while none were observed in female controls. The biologiaal significance f the preceding tumors is unknown at this time; however all were late-occurring and none were judged to be life-threatening. No tumors were seen at the one-year interim pathological evaluation. Additionally, evidence f retinal atrophy was observed in this two-year study in both treated and control animals, although the toxicological slgnifloanca is undetermined. (oorttfnusd) 2100FR P0 3 DO A 0616?? CONFIDENTIAL 03/31/93 09:31 DU PONT CHEM 302 773 0123 004 f # HEALTH HAZARD INFORMATION (oonunvod) No animal toot: npocti ra mllablt to 4*ClM reproductive hazards. AnInal data indicate that thla material doaa not specifically ham tha unborn anlnal. Tha compound doaa not produca genetic danaga in baetaclal oall oultoraa or in anInala; however, in ona atud^ genetlo danaga wes produoed In aamnallan oall oulturaa. WOMAN HEALTH BITSCT8: Human haalth effects of overexposure by aya oontaot any Inoluda aya irritation with discomfort, ttaring, or blurring of Tiaion. Overexposure by inhalation to tha vapors any eauaa tanporary narroua ayatam depression with anaathatle affaota auoh as disalasss, headache, oonfualon, incoordination, and loss of oonaoiouaaaas; or with gross overexposure (>20%), possibly tanporary altaration of tha haart'a alaetrieal activity with irregular pulaa, palpitations, or Inadequate eiroulatlon. r., i Individuals with praaxisting disaasas of tha oantral narvous or cardiovascular ayatarn any hava inoraaaad suacaptibility to tha toxicity of axoaaalva axposuras._____________________________ Carcinogenicity None of the component* In this material I* Oeted by IARC, NTP, __________________________________OSHA, or ACQIH a* a oardnogen. ____ Applicable Exposure Limits ETHANE, 2,2-DICHLORO-I.IJ-TRIFLUORO- (HCFC123) AEL * (Du Pont) & 10 ppm, (8 * 18 hr TWA) TLV (ACQIH) None Established PEL (OSHA) None Established | y * AELhDu lont' Aoosptol* ExposureUrn*. WhoropovemmentaiyimpessdoooupaSonalexposureImts whlohaialowerthen ____ th AEL ate In effect, ouch limits shall taka preeedonoe. 8afety Precautions Avoid breathing high oonoentratlont of vapor. Provide adequate ventilation for. storage, handling, and use, especially for endosed or low tpaoes. Avoid oontact of liquid with eyes and prolonged akin axposure. Do not allow product to oontaot open dame or electrical heating elements because dangerous decomposition products may form.____ * FIRST AID XNHALATXOH If high concentrations era inhaled, lit--aiHataly remove t fresh air. Heap parsons calm. If not breathing, give artificial respiration. If breathing ia difficult, give oxygen. Cell e physiolen. SKIN CONTACT In ease of oontaot, flush with water. attention if irritation ia present. Oat wartteal EYE CONTACT In case of contact, iasaadiately flush eyes with plenty Of water for 15. minutes. Call, a physician. t*' (oontinuad) 2190FR D... / DO A 061673 CONFTDFNTTAL 03/31/93 09:31 DU PONT OEM 302 773 0123 005 V. # FIRST AID {oongnuad) XNQX8TX0M X *w*llowd, no p*olia intervention la indicated as tha oeapound Lb not likely to bo heeerdou* by ingeetlon. However, consult a physician It naoaaaacy. Do not indue* vomiting boeoua* tho haeerd of aspirating tha material ~ ________into tha lungs la oonsidsrod graatar than mllwlng it. Notes to Physician Btcaust of possible disturbances of cardlao rhythm, catecholamine drugs, such as epinephrine, should be considered only as a last resort In life-threatening emergencies. X-------------------------- rn---------------------------------------------------- # PROTECTION INi FORMATION Generally Applicable Control Measures and Precautions Normal ventilation for standard manufacturing procedures Is generally adequate. Looal exhaust should be used when large amounts are released. Mechanical ventilation should be used In low or enclosed plaoes. Personal Protectlva Equipment Impervious gloves should be used to avoid prolonged or repeated exposure. Chemical splash goggles should be available for use as needed to prevent eye oontaot. Uee NIOSH approved respiratory protection It exposure Omits may be exceeded. 8etf-oonta!ned breathing apparatus (SCBA) Is required If a large spin oocurs. ^ # DISPOSAL INFORMATION \ i,, Aquatic Toxicity The oompound Is expected to be eHchtly toxic. __________________________________06-hour L050, fathead minnows: >77mg/L Spill, Leak, or Release NOTE: Review FIRE AND EXPLOSION HAZARDS and SAFETY PRECAUTIONS before prooeedlng with dean up. Use appropriate PERSONAL PROTECTIVE EQUIPMENT during dean up. Dike spiff. Prevent flqtofd from entering sewers, waterways or low areas. Ventilate area. Collect on absorbent material and transfer to steel drums for reoovery/dlsposel. Comply with Federal, State, and local regulations on reporting releases. Du Pont Emergency Exposure Limits (EEL) are established to facilitate site or plant emergency evaouation and specify airborne concentrations of brief durations which should not result In permanent adverse health effects or Interfere with escape. EEL'S are expressed as airborne concentration multiplied by time (CxT) for up to e maximum of 80 minutes and as a celling airborne oonoentration. These Omits ere used In conjunction with engineering oontrole/monltoring and as an aid In planning for episodic releases and spins. For more information on the applicability of EEL's, oontaot Du Pont ______ The Du Pont Emergency Exposure Limit (EEL) for HCFC-123 Refrigerant Is 1000 ppm for up to 60 minutes withal minute not-to-exoeed oeiBng of 2500 ppm. _______ ____ Watte Disposal Recover by distillation or remove to permitted waste disposal fadRty. Comply with Federal, State, and local regulations._______________________ __ 2100FR Page 5 00 A 061624 cnftdfnttal (oontlnuad) __ 03/31/93 09:32 DU PONT OEM 302 773 0123 006 /'>V f SHIPPING INFORMATION f Shipping Containers Tank Car Tank Truck Palls Drums 'SUVA* Centrt-LP is not regulated as a hazardous material by DOT or IMO. STORAGE CONDITIONS Clean, dry area Do not heat above 126 deg P. TITLE m HAZARD CLASSIFICATIONS Acute Chronic Fire Reactivity Pressure z^ctrs: Yes Yes No No No . c ( totrwily latudoui Substenoe CtJtCIA Maaareous Substance CMde Cheniaels -Mo -Mo -Mo ' The date in this Material 8afety Data Sheet relates only to the specific material designated herein and does not relate to use in oombInatlon with any other material or in any process. ResponsibtBty for MSDS: W. J. Brock Du Pont Chemicals P. O. Box 00709. Chestnut Run Wilmington, DE 19880*0709 Indieste* updated Mctkm. End of MSDS V5 ( f <S4 DO A 061625 CONFIDFNTTAL