Document 2jyDD7XQYL4evVERbyprorgYg

P-1 Acquisition Date Vial Position Sample Name Acquisition Method 1 2/17/2010 18:30 1 IB PFCkinetexLong.dam 2 2/17/2010 18:52 2 PFC O.IOppb PFCkinetexLong.dam 3 2/17/2010 19:00 3 PFC 0.5ppb PFCkinetexLong.dam 4 2/17/2010 19:08 4 PFC 1.Oppb PFCkinetexLong.dam 5 2/17/2010 19:15 5 PFC 5.Oppb PFCkinetexLong.dam 6 2/17/2010 19:23 6 PFC10ppb PFCkinetexLong.dam 7 2/17/2010 19:30 7 PFC 20ppb PFCkinetexLong.dam 8 2/17/2010 19:38 8 PFC 50ppb PFCkinetexLong.dam 9 2/17/2010 19:53 7 PFC 20ppb CCV PFCkinetexLong.dam 10 2/17/2010 20:01 9 PFC 20ppb ICV PFCkinetexLong.dam 11 2/17/2010 20:08 25 K1001011-001 PFCkinetexLong.dam 12 2/17/2010 20:16 26 K1001011-002 PFCkinetexLong.dam 13 2/17/2010 20:23 27 K1001011-003 PFCkinetexLong.dam 14 2/17/2010 20:31 28 K1001011-004 PFCkinetexLong.dam 15 2/17/2010 20:38 29 K1001011-005 PFCkinetexLong.dam 16 2/17/2010 20:46 30 K1001011-006 PFCkinetexLong.dam 17 2/17/2010 20:54 31 K1001011-007 PFCkinetexLong.dam 18 2/17/2010 21:01 32 K1001011-008 PFCkinetexLong.dam 19 2/17/2010 21:09 33 K1001011-009 PFCkinetexLong.dam 20 2/17/2010 21:16 34 K1001011-010 PFCkinetexLong.dam 21 2/17/2010 21:24 35 K1001011-011 PFCkinetexLong.dam 22 2/17/2010 21:31 36 K1001011-012 PFCkinetexLong.dam 23 2/17/2010 21:39 37 K1001011-013 PFCkinetexLong.dam 24 2/17/2010 21:46 38 K1001011-014 PFCkinetexLong.dam 25 2/17/2010 21:54 39 K1001011-015 PFCkinetexLong.dam 26 2/17/2010 22:02 40 K1001011-016 PFCkinetexLong.dam 27 2/17/2010 22:09 41 K1001011-017 PFCkinetexLong.dam 28 2/17/2010 22:17 42 K 1001011-018 PFCkinetexLong.dam 29 2/17/2010 22:24 43 K1001011-019 PFCkinetexLong.dam 30 2/17/2010 22:32 44 K1001011-020 PFCkinetexLong.dam 31 2/17/2010 22:39 45 KQ1000664-01 PFC kinetexLong .dam 32 2/17/2010 22:47 46 KQ1000664-02 PFCkinetexLong.dam 33 2/17/2010 22:54 47 KQ 1000664-03 PFCkinetexLong.dam 34 2/17/2010 23:02 48 KQ 1000664-04 PFCkinetexLong.dam 35 2/17/2010 23:10 49 KQ 1000664-05 PFCkinetexLong.dam 36 2/17/2010 23:17 50 KQ 1000664-06 PFCkinetexLong.dam 37 2/17/2010 23:25 23 KQ1000620-01 PFCkinetexLong.dam 38 2/17/2010 23:32 24 KQ1000620-02 PFCkinetexLong.dam 39 2/17/2010 23:40 22 KQ1000620-05 PFCkinetexLong.dam 40 2/17/2010 23:47 21 KQ 1000620-06 PFCkinetexLong.dam File Name 021710\CalLong.wiff 021710\CalLong.wiff 021710\CalLong.wiff 02171 OICalLong.wiff 021710\CalLong.wiff 02171 OICalLong.wiff 02171 OICalLong.wiff 02171 OICalLong.wiff 02171 OICalLong.wiff 02171 OICalLong.wiff 021710\SamplesLong.wiff 021710\SamplesLong.wiff 021710\SamplesLong. wiff 021710\SamplesLong,wiff 021710\SamplesLong.wiff 021710\SamplesLong.wiff 021710\SamplesLong.wiff 02171 OISamplesLong.wiff 021710\SamplesLong.wiff 02171 OVSamplesLong.wiff 021710\SamplesLong.wiff 021710\SamplesLong.wiff 021710\SamplesLong.wiff 02171 OISamplesLong.wiff 021710\SamplesLong.wiff 02171 OISamplesLong. wiff 021710\SamplesLong.wiff 021710\SamplesLong. wiff 02171 OISamplesLong.wiff 021710\SamplesLong. wiff 021710\SamplesLong.wiff 021710\SamplesLong.wiff 021710\SamplesLong.wiff 021710\SamplesLong.wiff 021710\SamplesLong.wiff 021710\SamplesLong.wiff 021710\SamplesLong. wiff 021710\SamplesLong,wiff 021710\SamplesLong.wiff 021710\SamplesLong.wiff IS Peak Area (counts) 450.62 2504200 2783700 2542500 2677400 2754900 2957800 2651100 2907400 2664400 3217400 3083200 3489500 3542200 3322000 3135900 2890600 3090100 3320900 3007600 2911800 3291800 3060500 3300300 3145300 2786900 3174100 2954300 2900400 2939100 2634600 2867600 2693100 2491600 2954000 2741700 2971200 2881600 2873500 2808200 Z 402 Prep Run#: 105653 Team: Petroleum HC/SMCDONALD Number o f Copies to make: 1 # Lab Code Client ID 1 K1000968-001 2 K 1000968-020 3 K1000968-019 4 K 1000968-018 5 K 1000968-017 6 K 1000968-016 7 K1000968-015 8 K 1000968-014 9 K1000968-013 10 K 1000968-012 11 K 1000968-011 12 K1000968-010 13 K 1000968-009 K1000968-008 K1000968-007 16 K1000968-006 17 K1000968-005 18 K 1000968-004 19 K 1000968-003 20 K 1000968-002 21 K Q 1000620-03 22 K Q 1000620-04 23 KQ 1000620-01 24 KQ 1000620-02 25 KQ1000620-05 26 KQ 1000620-06 Field Blank 2 Field Blank 3 F: Scott "Treated" F:Scott "Raw" West Well Plant "Treated" West Well Plant "Raw" W & Avery "Treated" W & Avery "Raw" West Pensacola "Treated" West Pensacola "Raw" Bronson "Treated" Bronson "Raw" Lillian "Treated" Lillian "Raw" Dunaway "Treated" Dunaway "Raw" McCory "Treated" McCory "Raw" University Parkway "Treated" University Parkway "Raw" K1000968-010 MS K 1000968-010 DMS K 1000968-011 MS K1000968-011 DMS LCS MB Preparation information encnsneet Prep WorkFlow: OrgExtAq(14) Prep Method: Method Status: Prepped Prep Date/Time: 2/8/10 07:28 AM B # Method /Test .01 PFO A PFO A .01 PFOA/PFOA .01 PFOA/PFOA .01 PFOA/PFOA .01 PFOA'PFOA .01 PFOA'PFOA .01 PFOA/PFOA .01 PFO A PFO A .01 PFOA'PFOA .01 PFO A PFO A .01 PFO A PFO A .01 PFO A PFO A .01 PFO A PFO A .01 PFO A PFO A .01 PFO A PFO A .01 PFO A PFO A .01 PFO A PFO A .01 PFO A PFO A .01 PFO A PFO A .01 PFO A PFO A .01 PFO A PFO A .01 PFO A PFO A .01 PFO A PFO A .01 PFO A PFO A X PFOAPFOA PFOAPFOA pH Matrix X Water 7 Water 7 Water 7 Water 7 Water W ater X X Water / Water 7 Water W ater 7 y Water 7 Water 7 Water X Water 7 Water X Water 7 Water 7 Water 7" Water 7 Water 7 Liquid 7 Liquid 7 Liquid Liquid X 7 Liquid 7 Liquid Amt. Ext. 200mL 200mL 200mL 200m l. 200mL 200m L 200mL 200mL 200mL 200mL 200mL 200mL 200mL 200m L 200m L 200mL 200mL 200mL 200mL 200mL 200m L 200mL 200mL 200mL 200mL 200mL Final Voi Sample Description l.OOmL l.OOmL. l.OOmL 1 OOmL. l.OOmL l.OOmL l.OOmL l.OOmL. 1.OOmL l.OOmL l.OOmL l.OOmL l.OOmL l.OOmL l.OOmL l.OOmL l.OOmL l.OOmL l.OOmL l.OOmL l.OOmL l.OOmL l.OOmL l.OOmL 1.OOmL l.OOmL \ \ \ \ \ \ \ \ \ \ V p to Printed 2 8 10 14:10 Preparation Information Bcnchsheet Page P- 3 1111 oo oo oo oo dodo oo oo oo oc oo dd Prep Run#: 105653 Team: Petroleum HC/SMCDONALD Spiking Solutions Name: Periluorinated Surfactant Isotopes 1ppm K 1000968-001 K 1000968-007 K1000968-013 K1000968-019 KQ1000620-05 K1000968-002 K 1000968-008 K1000968-014 K1000968-020 K Q 1000620-06 preparation information encnsneet Prep WorkFlow: OrgExtAq(14) Prep Method: Method Status: Prepped Prep Date/Time: 2/8/10 07:28 AM Inventory ID 5362 K1000968-003 K 1000968-009 K1000968-015 KQ 1000620-01 Logbook Ref: LCMS2-26C K1000968-004 K 1000968-010 K1000968-016 KQ 1000620-02 K1000968-005 K1000968-011 K 1000968-017 KQ1000620-03 Expires On: 09/09/2009 K1000968-006 K1000968-012 K 1000968-018 KQ 1000620-04 o o o o od o od od od o o o od oo do o o ooo o od oo do o o oo o od oo do o o Name: Perfluorinated Surfactants Targets 2ppm Inventory ID 13189 KQ1000620-01 o.oopL KQ 1000620-02 lO.oopL KQ 1000620-03 o.oopL Preparation Steps Step: Started: Finished: j^ y : 4^ Extraction 2/8/10 07:28 2'8/10 14:10 SMCDONALD Logbook Ref: LCMS2-76P KQ 1000620-04 lo.oop L KQ 1000620-05 o.oopL Expires On: 10/29/2010 Comments: Reviewed By: Chain of Custody Relinquished By: Received By: \\A A A Printed 2 8 10 14:10 c J j r Date: '3~/ th/}0 D" : i\% \ Date: Extracts Examined Yes No Preparation Information Bcnchsheet Page : rep Run#: 105653 earn: Petroleum HC/SMCDONALD Number ofCopiestomake: 1 # Lab Code Client ID 1 Kl000968-001 k:; Kl000968-002 3 Kl 000968-003 k-v P<^684M14 5 Kl000968-005 Kl 000968-006 7 Kl000968-007 i K1^6?MW8 9 Kl000968-009 to Kl000968-010 11 Kl000968-011 12 Kl000968-012 13 K1000968-013 14 K1000968-014 K1000968-015 $ Kl 000968-016 17 K1000968-017 18- Kl000968-018 19 K1000968-019 Kl Kl000968-020 21 KQ1000620-01 22 KQ1OOO620-O2 23 KQ1000620-03 24 KQ1000620-04 25 KQ1000620-05 li KQ1000620-06 Field Blank 2 University' Parkway "Raw" UniversityParkway "Treated" MeCory"Raw" \ McCory "Treated" Dunaway"Raw" Dunaway `'Treated" Lillian"Raw" Lillian "Treated" Brunson"Haw" Bronson"Treated" West Pensacola"Raw": West Pensacola"Treated" \V&Avery"Raw" W&Avery "Treated" West Well Plat"Raw" West Well Plant "Treated" F;$cott "Raw" F: Scott "Treated" FieldBlank 3 K1000968-011 MS M<KW96X-0.il DMS K1000968-010 MS K1000968-010 DMS LCS mb , . Preparation injormatwn encnsneet Prep WorkFlow: OrgExtAq(14) Prep Method: Method Status: Draft Prep Date/Time: 2/8/10 07:28 AM B# a/ Method /Test Matrix Amt. Ext. pH Int. Voi Final Voi Surr Amt Spike Am ,o l PFOA/PFOA S-: ; PFOA/PFOA PFOA/PFOA / :s .. PFOA/PFOA y PFOA/ PFOA / PFOA/PFOA : PFOA PFOA y PFOA; PFOA ' . y PFOA/PFOA PFOA/PFOA T y PFOA/PFOA y PI'OA PFOA y PFOA/PFOA .y ] PFOA/PFOA y PFOA/PFOA y PFOA PFOA y PFOA/ PFOA y PFOA/PFOA y PFOA/PFOA y : PFOA/ PFOA y PFOA/PFOA y PFOA PFOA y PFOA/ PFOA f i / PFOA PFOA / PFOA PFOA PFOA PFOA ... Y\ ........ Water .Wtr Water Water Water Water Water Water Water Water ;//' Water Water Water ffow Ji ' . Yn- L T y y l s' \> ) / / / ,.ysf*' ) / /; s' / ./ / ' ' Water Water y ' ''^y y * - Water Water Water Water Water Liquid Liquid Liquid Liquid Liquid Liquid ' '. \ \ \. ... s' y' S' y' s' 'S '.. 'y y ^ ' s' ,y .... ............... \ y rouJL \ \ > ;\ V' . IV aM O jA l a c y L uJL fJ Comments: SutTOgate Witnessed By: Analyst: Printed 2 8 10 7:31 # 4 nK / f\ W t) Ioa> U Yo^/S i OMWLWbFjcrt- (S M \%\ 1*^1A ____ Spike ID: L P A A C . - L P Ib vJL , Assisted By: Preparation Information Bcnchsheet p "is Page 1 o! C o lum bia A n aly tic al S ervices- p. 5 H6 . www.caslab.com February 22, 2010 Analytical Report for Service Request No: K1001011 David Anderson Camp Dresser & McKee, Incorporated 325 John Knox Road Building M, Suite 100 Tallahassee, FL 32303 RE: Baron & Budd, P.C./95779-75319 Dear David: Enclosed are the results o f the samples submitted to our laboratory on February 04, 2010. For your reference, these analyses have been assigned our service request number K1001011. Analyses were performed according to our laboratory's NELAP-approved quality assurance program. The test results meet requirements of the current NELAP standards, where applicable, and except as noted in the laboratory case narrative provided. For a specific list o f NELAP-accredited analytes, refer to the certifications section at www.caslab.com. All results are intended to be considered in their entirety, and Columbia Analytical Services, Inc. (CAS) is not responsible for use of less than the complete report. Results apply only to the items submitted to the laboratory for analysis and individual items (samples) analyzed, as listed in the report. Please call if you have any questions. My extension is 3281. You may also contact me via Email at PDivvela@caslab.com. Respectfully submitted, Columbia Analytical Services, Inc. Pradeei Project Chemist PD/afs ASTM A2LA CARB CAS Number CFC CFU DEC DEQ DHS DOE DOH EPA ELAP GC GC/MS LUFT M MCL MDL MPN MRL NA NC NCASI ND NIOSH PQL RCRA SIM TPH tr Acronyms P-6 American Society for Testing and Materials American Association for Laboratory Accreditation California Air Resources Board Chemical Abstract Sendee registry Number Chlorofluorocarbon Colony-Forming Unit Department of Environmental Conservation Department of Environmental Quality Department of Health Services Department of Ecology Department o f Health U. S. Environmental Protection Agency Environmental Laboratory Accreditation Program Gas Chromatography Gas Chromatography/Mass Spectrometry Leaking Underground Fuel Tank Modified Maximum Contaminant Level is the highest permissible concentration of a substance allowed in drinking water as established by the USEPA. Method Detection Limit Most Probable Number Method Reporting Limit Not Applicable Not Calculated National Council o f the Paper Industry for Air and Stream Improvement Not Detected National Institute for Occupational Safety and Health Practical Quantitation Limit Resource Conservation and Recover}' Act Selected Ion Monitoring Total Petroleum Hydrocarbons Trace level is the concentration o f an analyte that is less than the PQL but greater than or equal to the MDL. 2 Inorganic Data Qualifiers # 'Die result is an outlier. See case narrative. # Tlie control limit criteria is not applicable. See case narrative. 3 The analyte was found in the associated method blank at a level that is significant relative to the sample result as defined by the DOD orNELAC standards. E The result is an estimate amount because the value exceeded the instrument calibration range. J The result is an estimated value that was detected outside the quantitation range. U Tlie analyte was analyzed for, but was not detected ("Non-detect") at or above the MRL/MDL. DOD-QSM 4.! definition: .Analyte was not detected and is reported as less than the LOD or as defined by the project. The detection limit is adjusted for dilution, i The MRL/MDL or LOQ/LOD is elevated due to a matrix interference. X See case narrative. Q See case narrative. One or more quality control criteria was outside the limits. Metals Data Qualifiers # The control limit criteria is not applicable. See case narrative. J The result is an estimated value that was detected outside the quantitation range. E The percent difference for the serial dilution was greater than 10%, indicating a possible matrix interference in the sample. M The duplicate injection precision was not met. N The Matrix Spike sample recovery is not within control limits. See case narrative. S The reported value was determined by the Method o f Standard Additions (MSA). {j The analyte was analyzed for, but was not detected (`'Non-detect") at or above the MRL/MDL. DOD-QSM 4 l definition: Analyte was not detected and is reported as less than the LOD or as defined by the project. The detection limit is adjusted for dilution. W Tire post-digestion spike for furnace AA analysis is out o f control limits, while sample absorbance is less than 50% o f spike absorbance. i The MRL/MDL or LOQ/LOD is elevated due to a matrix interference. X See case narrative. + The correlation coefficient for the MSA is less than 0.995. Q See case narrative. One or more quality control criteria was outside the limits. Organic Data Qualifiers # The result is an outlier. See case narrative. # The control limit criteria is not applicable. See case narrative. A A tentatively identified compound, a suspected aldol-condensation product. B The analyte was found in the associated method blank at a level that is significant relative to the sample result as defined by the DOD orNELAC standards. C The analyte was qualitatively confirmed using GC/MS techniques, pattern recognition, or by comparing to historical data. D The reported result is from a dilution. E The result is an estimate amount because the value exceeded the instrument calibration rauge. J The result is an estimated value that was detected outside the quantitation range. N The result is presumptive. The analyte was tentatively identified, but a confirmation analysis was not performed, p The GC orHPLC confirmation criteria was exceeded. The relative percent difference is greater than 40% between the two analytical results. U The analyte was analyzed for, but was not detected ("Non-detect") at or above the MRL/MDL. DOD-QSM 4 1 definition: Analyte was not detected and is reported as less than the LOD or as defined by the project. The detection limit is adjusted for dilution. i The MRL/MDL or LOQ/LOD is elevated due to a chromatographic interference. X See case narrative. Q See case narrative. One or more quality control criteria was outside the limits. Additional Petroleum Hydrocarbon Specific Qualifiers F The chromatographic fingerprint of the sample matches the elution pattern of the calibration standard. L The chromatographic fingerprint of the sample resembles a petroleum product, but the elution pattern indicates thepresence o f a greater amount o f lighter molecular weight constituents than the calibration standard. H The chromatographic fingerprint of the sample resembles a petroleum product, but the elution pattern indicates the presence o f a greater amount o f heavier molecular weight constituents than the calibration standard. O The chromatographic fingerprint of the sample resembles an oil, but does not match the calibration standard. Y The chromatographic fingerprint o f the sample resembles a petroleum product eluting in approximately the correct carbon range, but the elution pattern does not match the calibration standard. Z The chromatographic fingerprint does not resemble a petroleum product. 3 P- Columbia Analytical Services, Inc. Kelso, WA State Certifications, Accreditations, and Licenses Program Alaska DEC UST Arizona DHS Arkansas - DEQ California DHS Colorado DPHE Florida DOH Hawaii DOH Idaho DHW Indiana DOH Louisiana DEQ Louisiana DHH Maine DHS Michigan DEQ Minnesota DOH Montana DPHHS Nevada DEP New Jersey DEP New Mexico ED North Carolina DWQ Oklahoma DEQ Oregon - DHS South Carolina DHEC Utah DOH Washington DOE Wisconsin DNR Wyoming (EPA Region 8) Number UST-040 AZ0339 88-0637 2286 - E87412 - - C-WA-01 3016 LA050010 WA0035 9949 053-999-368 CERT0047 WA35 WA005 - 605 9801 WA200001 61002 COLU C l 203 998386840 - ME MB E R ACIL v IIT T am l 4 Gase Narrative p. 10 COLUMBIA ANALYTICAL SERVICES, INC. Client: Project: Sample Matrix: Camp Dresser & McKee, Inc. Baron & Budd, P.C Water Service Request No.: Date Received: K1001011 02/04/10 CASE NARRATIVE All analyses were performed consistent with the quality assurance program of Columbia Analytical Services, Inc. (CAS). This report contains analytical results for samples designated for Tier III validation deliverables including summary forms and all of the associated raw data for each of the analyses. When appropriate to the method, method blank results have been reported with each analytical test. Sample Receipt Twenty water samples were received for analysis at Columbia Analytical Services on 02/04/10. The samples were received in good condition and consistent with the accompanying chain of custody form. The samples were stored in a refrigerator at 4UC upon receipt at the laboratory. Perfluorinated Sulfonic Acids and Perfluorinated Carboxylic Acids by HPLC/M S Surrogate Exceptions: The recovery of Perfluoro-n-[ 1,2-13C2]undecanoic Acid in Lab Control Sample (KQ1000664-05 was outside the control limits listed in the results summary. The limits are default values temporarily in use until sufficient data points are generated to calculate statistical control limits. Based on the method and historic data, the recoveries observed were in the range expected for this procedure. No further corrective action was taken. The recovery of Perfluoro-n-[l,2-13C2]dodecanoic Acid in Villa "Raw", Muldoon "Raw", Airport North "Raw", Broad "Treated", Spanish Trail "Raw" and Spanish Trail "Treated" was outside the control limits listed in the results summary. The limits are default values temporarily in use until sufficient data points are generated to calculate statistical control limits. Based on the method and historic data, the recoveries observed were in the range expected for this procedure. No further corrective action was taken. The recovery of Perfluoro-n-[l,2-13C2]undecanoic Acid and Perfluoro-n-[l,2-13C2]dodecanoic Acid in Tennant "Treated" and Royce Street "Treated" were outside the control limits listed in the results summary. The limits are default values temporarily in use until sufficient data points are generated to calculate statistical control limits. Based on the method and historic data, the recoveries observed were in the range expected for this procedure. No further corrective action was taken The recovery o f Perfluoro-n-[ 1,2-13C2]dodecanoic Acid and Pertluoro-n-[l,2,3,4-13C4] butanoic acid in Muldoon "Treated" were outside the control limits listed in the results summary. The limits are default values temporarily in use until sufficient data points are generated to calculate statistical control limits. Based on the method and historic data, the recoveries observed were in the range expected for this procedure. No further corrective action was taken. Matrix Spike Recovery Exceptions: The matrix spike recovery of Perfurodecane Sulfonate for sample McAllister "Raw" was outside control criteria because of suspected rnauix interference. A matrix spike duplicate was also analyzed, but produced similar results. No further corrective action was appropriate. No other anomalies associated with the analysis of these samples were observe Approved by Datet ) 6 Chain of Custody Documentation C o lum bia Analytical Services- CHAIN OF CUSTODY 1317 South 13th Ave. Kelso, WA 98626 (360)577-7222 (800)695-7222x07 FAX (360) 636-1068 PROJECT NAME PROJECT NUMBER PROJECT MANAGER P<K\f~L A v -4 n M Y ftV ) ( JDN\COMPANY ADDRESS I lKri^~TV^)W^AA\/'\L( le SvAXh. IPO CITY'STATE, ZIP T ft tk^KSStJL . f L E-MAIL ADDRESS PAGE SR#: iQ /'t O F ___ _ C O C # _ VS SIGNATURE \ F'*1<J 3 /a a < j Z ,3 -h u> * / 1 ^ 1 u>&q rpAft.KT/^-1 " i ? w o<3i3 0833 CU; G \ K CGO i o 1 t X X 00 ' IkA**' " p - w c F yoF^pv 8f3 O /2. o TT o?z3 T7 H /* \c A i l . v W - a. ( iv v j " A \r/ M ro .O W 002 X J REPORT REQUIREMENTS ___ I. Routine Report: Method Blank, Surrogate, as required ___ II. Report Dup., MS, MSD as required ___III. Data Validation Report (includes all raw data) )( IV. CLP Deliverable Report INVOICE INFORMATION P .O . # _______________________ Bill T o : _________________ Circle which metals are to be analyzed: Total Metals: Al As Sb Ba Be B Ca Cd Co Cr Cu Fe Pb Mg Mn Mo Ni K Ag Na Se Sr T l Sn V Zn Hg Dissolved Metals. Al As Sb B a Be B C a Cd Co C r Cu Fe P b Mg Mn Mo Ni K Ag Na Se Sr T l S n V Zn Hg INDICATE STATE HYDROCARBON PROCEDURE: AK CA Wl NORTHWEST OTHER:_ TURNAROUND REQUIREMENTS SPECIAL INSTRUCTIONS/COMMENTS: _____ 24 hr. ______ 48 hr. ____ 5 Day Y Standard (10-15 working days) ____ Provide FAX Results .(CIRCLE ONE) Y V. EDD Requested Report Date RELINQUISHED BY: Signature Printed Name Date/Time Firm L RECEIVED BY: rS Signature * . D iw M Printed Name Z J - (a 6 ''C Date/Time C J) rv\ Firm V K RELINQUISHED BY: Signature Printed Name 2 3 .f0 Date/Time C_D (*\ Firm /t-'fS R C O C #1 07/09 Z X Columbia u z Analytical Services CHAIN OF CUSTODY 1317 South 13th Ave. Kelso, WA 98626 (360)577-7222 (800)695-7222x07 FAX (360) 636-1068 PROJECT NAME PROJECT NUMBER ^K l\t5y\ dlblA /U PROJECT MANAGER C O M P A N Y .A D D R E S S ___________ (U > m -kv~-i'l j A r Y ^ v \ l .v 3 r- C IT Y 'S T A T E -2 IP \ifU j l f tj 3>frs? e -m a il a d d r e s s PAGE SR#: j / f / 0 / / OF 3 COC# l C o - 3.8U ^ so q 5 SIGNATURE T SAMPLE I D. DATE TIME Mc AII'/W - fr ^ p * \J7 M /1 > 2.3./o / e > o 2 LAB I.D. MATRIX gui REMARKS Vv 11 X 3 . / o $ re Ld l' 2 .3 /0 " 2 .3> B cqaA V'X rgJvm ' 2 J - ' b TAAAM " i f l u j " 2 3 - / J2 .3 ./0 /o 5 5 II <# iW G /2oo I3c>s 134 Cyj Cw) Cw X. X 21 -L O K X AL Jr Y W u / 4 Qca i ` ILAvo " 2 - X / o 2 3 . M w icW cft u ' f K i* X j * 13^-? A foo 6^0 6 8 0 "2 - I / / / ) A vv fi f t1^* 2 . 3 1 , 0 ' 4 / g -to REPORT REQUIREMENTS I. Routine Report: Method Blank, Surrogate, as required II. Report Dup., MS. MSD as required _ III. Data Validation Report (Includes all raw data) YMV. CLP Deliverable Report W L V. EDD INVOICE INFORMATION P .O . # _______________________ Bill T o : _________________ Total Metals: Al As S b Ba Be B Ca Cd Co Cr Cu Fe Pb Mg Mn M o Ni K Ag Na S e Sr Tl Sn V Z n Hg Dissolved Metals: Al As S b Ba Be B Ca Cd C o Cr Cu Fe Pb Mg Mn Mo Ni K Ag Na Se Sr Tl Sn V Zn Hg ` INDICATE STATE HYDROCARBON PROCEDURE: AK CA Wl NORTHWEST OTHER: TURNAROUND REQUIREMENTS SPECIAL INSTRUCTIONS/COMMENTS: _____ 24 hr. ______ 48 hr. ____ 5 Day Standard (10-15 working days) - Y Provide FAX Results .(CIRCLE ONE) Requested Report Date RELINQUISHED BY: signature Printed Name Date/nme Firm V RECEIVED BY: C"'*T Ca/ Signature y^vrr4 Printed Name X /./o 6 : o o Date/Time CCM Firm V RELINQUISHED BY: f ^ ) C / k2 - ^ , / 0 /Y d Signature Printed Name ^DateTTime C-C Firm RCOC #1 07/09 AX Columbia O Analytical Services CHAIN OF CUSTODY 1317 South 13th Ave. Kelso, WA 98626 (360)577-7222 (800)695-7222x07 FAX (360) 636-1068 PROJECT NAME PROJECT NUMBER 8 ,w M t S' T - 1 * 3 f ________ PROJECT MANAGER t^ y f/ COMPANY, ADDRESS LJMC A v v ilii. CITY'STATE'ZIP ''I K o v v ^ v r lU H l , W h r~ T A U a M a ME-MAIL ADDRESS i J i . *. ir o i Co / 1 pc / g s! / 1 / ?S7 SAMPLER S S1GMTURE SAMPLE I.D. I/'Ia Hp y c - e h -fs-ttju+oJ * DATE 23.10 3 J ./0 * 3 jO TIME /y ^ 8 7? f /5 /t LAB I.D, MATRIX (>LU Qm ) CL uJ PAGE SR#: K ICO(OI OF3 COC# REMARKS C REPORT REQUIREMENTS ___ I. Routine Report: Method Blank, Surrogate, as required ___ II. Report Dup., MS, MSD as required ___III. Data Validation Report (includes all raw data) ^ IV. CLP Deliverable Report ` V. EDD INVOICE INFORMATION P .O . # _______________________ Bill To: ______ Total Metals. Al As S b Ba Be B Ca Cd Co Cr Cu Fe Pb Mg Mn Mo NI K Ag Na Se Sr T l Sn V Zn Hg Dissolved Metals. Al As S b Ba Be B Ca C d C o C r Cu Fe P b M g Mn M o Ni K A g Na S e S r T l S n V Z n Hg 'INDICATE STATE HYDROCARBON PROCEDURE: AK CA Wl NORTHWEST OTHER:. TURNAROUND REQUIREMENTS SPECIAL INSTRUCTIONS/COMMENTS: ____ 24 h r . _____48 hr. .(CIRCLE ONE) _____5 Day ]_V Standard (10-15 working days) ___Provide FAX Results Requested Report Date RELINQUISHED BY: Signature Printed Name Date/I ime Firm j. K RECEIVED BY: Ccehu a - i . / o /c>t:o Signature * ~ Date/Time Printed Name Firm V tv RELINQUISHED BY: Signature ~7 T- Z .3 -/0 / ( f^ O Date/Time UA-'M L- Qjf) rA______ Printed Name Firm RCOC #1 07/09 Client / Project^ ,, ( tt m Received: / / / Cooler Receipt and Preservation Form ServiceJUequest K l 0 Q j {) j ( Opened: & / '! / / / / ___ i 1. Samples were received via? Mail UPS DHL Pi Hand Delivered 2. Samples were received in: (circle) C Coolerj) Box 3. Were custodv seals on coolers? NA ( J ) N If present, were custody seals intact? fv N Envelope If yes, how many and where?_ 22 If present, were they signed and dated? NA &N Cooler TempaC if o.b 6 Temp Stank *C ~P 5~ /.er LI 11 i.r Thermometer *1 %ki Bv to mCooler/COC , -, Tracking Number NA Filed ~&T ~ ~kTT 7. Packing material used. Inserts Haggles} Bubble Wrap Gel Packs CWetTcS'^ Sleeves Other______ 8. Were custody papers properly filled out (ink, signed, etc.)? NA f y N 9. Did all bottles arrive in good condition (unbroken)? Indicate in the table below. NA N 10. Were all sample labels complete (i.e analysis, preservation, etc.)? NA R ) N 11. Did all sample labels and tags agree with custody papers? Indicate major discrepancies in the table on page 2. NA j y N 12. Were appropriate bottles/containers and volumes received for the tests indicated? NA y N 13. Were the pH-preserved bottles (see SMO GENSOP) received at the appropriate pH? Indicate in the table below |^ X Y N 14. Were VOA vials received without headspace? Indicate in the table below. 15. Was C12/Res negative? Y N YN Sample ID on Bottle Sample ID on COC Identified by; Sample ID Bottle Count Out of Head- Bottle Type Temp space3Broke pH Volume Reagent : : added Reagent Lot Number Initials Time Notes, Discrepancies, & Resolutions: 11 P a g e __1__ of_ Perfhiorinated Sulfonic Acids and Perfluorinated Carboxylic Acids by HPCL/MS 12 Client: Project: Sample Matrix: Sample Name: Lab Code: Analytical Report Camp Dresser & McKee, Incorporated (CDM) Baron & Budd, P.C./95779-753I9 Water Hagler Well " Raw" K1001011-001 p. 17 Service Request: K1001011 Date Collected: 2/ 3/10 0802 Date Received: 2/ 4/10 Units: ng/L Basis: NA Perfluorinated Sulfonic Acids and Perfluorinated Carboxylic Acids by HPLC/MS Analytical Method: PFOA Prep Method: Method Analyte Name Perfluoro-n-tetradecanoic acid Perfluoro-n-tridecanoic acid Perfluorobutanesulfonate Perfluorobutanoic Acid Perfluorodecane Sulfonate Perfluorodecanoic Acid Perfluorododecanoic Acid Perfluoroheptanoic Acid Perfluorohexanesulfonate Perfluorohexanoic Acid Perfluorononanoic Acid Perfluorooctanesulfonate Perfluorooctanoic Acid Perfluoropentanoic Acid Perfluoroundecanoic Acid Result Q ND U ND U 44 32 0.19 J 1.1 J ND u 46 170 120 7.3 220 39 96 ND u MRL 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 MDL 0.46 0.95 0.029 0.11 0.095 0.48 0.85 0.081 0.030 0.11 0.12 0.046 0.066 0.11 1.3 Dilution Date Date Extraction Analysis Factor Extracted Analyzed Lot Lot Note 1 2/ 9/10 2/17/10 20:08 105742 190532 1 2/ 9/10 2/17/10 20:08 105742 190532 1 2/ 9/10 2/18/10 02:09 105742 190532 1 2/ 9/10 2/18/10 02:09 105742 190532 1 2/ 9/10 2/17/10 20:08 105742 190532 1 2/ 9/10 2/17/10 20:08 105742 190532 1 2/ 9/10 2/17/10 20:08 105742 190532 1 2/ 9/10 2/18/10 02:09 105742 190532 1 2/ 9/10 2/18/10 02:09 105742 190532 1 2/ 9/10 2/18/10 02:09 105742 190532 1 2/ 9/10 2/17/10 20:08 105742 190532 1 2/ 9/10 2/17/10 20:08 105742 190532 1 2/ 9/10 2/17/10 20:08 105742 190532 1 2/ 9/10 2/18/10 02:09 105742 190532 1 2/ 9/10 2/17/10 20:08 105742 190532 Surrogate Name Perfluoro-n-[l,2,3,4,5-13C5] nonanoic acid Perfluoro-n-[l,2,3,4-13C4] butanoic acid Perfluoro-n-[l,2,3,4-13C4] octanoic acid Perfluoro-n-[l,2-13C2] decanoic acid Perfluoro-n-[l,2-13C2] hexanoic acid Perfluoro-n-[1,2-13C2]dodecanoic Acid Perfluoro-n-[l,2-13C2]undecanoic Acid Sodium perfluoro-1-[ 1,2,3,4-13C4] octanesulfonate Sodium perfluoro-1-hexane[1802]sulfonate %Rec 95 104 113 100 105 61 62 92 118 Control Limits 50-150 50-150 50-150 50-150 50-150 50-150 50-150 50-150 50-150 Date Analyzed Q 2/17/10 20:08 2/18/10 02:09 2/17/10 20:08 2/17/10 20:08 2/18/10 02:09 2/17/10 20:08 2/17/10 20:08 2/17/10 20:08 2/18/10 02:09 Note Comments: Printed 2/23/10 13:41 \Unflow2VStar!ims\LimsReps\AnalyticalReport.rpt Form 1A 13 SuperSet Reference: 10-0000135143 rev 00 Client: Project: Sample Matrix: Sample Name: Lab Code: Analytical Report Camp Dresser & McKee, Incorporated (CDM) Baron & Budd, P.C./95779-75319 Water Hagler Well " Treated" K1001011-002 p. 18 Service Request: K1001011 Date Collected: 2/ 3/10 0813 Date Received: 2/ 4/10 Units: ng/L Basis: NA Perfluorinated Sulfonic Acids and Perfluorinated Carboxylic Acids by HPLC/MS Analytical Method: PFOA Prep Method: Method Analyte Name Perfluoro-n-tetradecanoic acid Perfluoro-n-tridecanoic acid Perfluorobutanesulfonate Perfluorobutanoic Acid Perfluorodecane Sulfonate Perfluorodecanoic Acid Perfluorododecanoic Acid Perfluoroheptanoic Acid Perfluorohexanesulfonate Perfluorohexanoic Acid Perfluorononanoic Acid Perfluorooctanesulfonate Perfluorooctanoic Acid Perfluoropentanoic Acid Perfluoroundecanoic Acid Result Q ND U ND U 45 33 0.14 J 0.79 J ND U 51 180 130 7.6 240 42 100 ND U MRL 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 MDL 0.46 0.95 0.029 0.11 0.095 0.48 0.85 0.081 0.030 0.11 0.12 0.046 0.066 0.11 1.3 Dilution Date Date Extraction Analysis Factor Extracted Analyzed Lot Lot Note 1 2/ 9/10 2/17/10 20:16 105742 190532 1 2/ 9/10 2/17/10 20:16 105742 190532 1 2/ 9/10 2/18/10 02:18 105742 190532 1 2/ 9/10 2/18/10 02:18 105742 190532 1 2/ 9/10 2/17/10 20:16 105742 190532 1 2/ 9/10 2/17/10 20:16 105742 190532 1 2/ 9/10 2/17/10 20:16 105742 190532 1 2/ 9/10 2/18/10 02:18 105742 190532 1 2/ 9/10 2/18/10 02:18 105742 190532 1 2/ 9/10 2/18/10 02:18 105742 190532 1 2/ 9/10 2/17/10 20:16 105742 190532 1 2/ 9/10 2/17/10 20:16 105742 190532 1 2/ 9/10 2/17/10 20:16 105742 190532 1 2/ 9/10 2/18/10 02:18 105742 190532 1 2/ 9/10 2/17/10 20:16 105742 190532 Surrogate Name Perfluoro-n-[l,2,3,4,5-13C5] nonanoic acid Perfluoro-n-[l,2,3,4-13C4] butanoic acid Perfluoro-n-[l,2,3,4-13C4] octanoic acid Perfluoro-n-[l,2-13C2] decanoicacid Perfluoro-n-[l,2-13C2] hexanoic acid Perfluoro-n-[1,2-13C2]dodecanoic Acid Perfluoro-n-[1,2-13C2]undecanoic Acid Sodiumperfluoro-l-[l,2,3,4-13C4] octanesulfonate Sodium perfluoro-1-hexane[1802]sulfonate %Rec 91 111 121 100 109 58 67 87 118 Control Limits 50-150 50-150 50-150 50-150 50-150 50-150 50-150 50-150 50-150 Date Analyzed Q 2/17/10 20:16 2/18/10 02:18 2/17/10 20:16 2/17/10 20:16 2/18/10 02:18 2/17/10 20:16 2/17/10 20:16 2/17/10 20:16 2/18/10 02:18 Note Comments: Printed 2/23/10 13:41 \\Inflow2\StarlimsVLimsReps\AnalyticalReportrpt Form 1A 14 SuperSet Reference: 10-0000135143 rev 00 Client: Project: Sample Matrix: Sample Name: Lab Code: Analytical Report Camp Dresser & McKee, Incorporated (CDM) Baron & Budd, P.C./95779-75319 Water Spanish Trail "Raw" K1001011-003 p. 19 Service Request: K1001011 Date Collected: 2/ 3/10 0833 Date Received: 2/ 4/10 Units: ng/L Basis: NA Perfluorinated Sulfonic Acids and Perfluorinated Carboxylic Acids by HPLC/MS Analytical Method: PFOA Prep Method: Method Analyte Name Perfluoro-n-tetradecanoic acid Perfluoro-n-tridecanoic acid Perfluorobutanesulfonate Perfluorobutanoic Acid Perfluorodecane Sulfonate Perfluorodecanoic Acid Perfluorododecanoic Acid Perfluoroheptanoic Acid Perfluorohexanesulfonate Perfluorohexanoic Acid Perfluorononanoic Acid Perfluorooctanesulfonate Perfluorooctanoic Acid Perfluoropentanoic Acid Perfluoroundecanoic Acid Result Q ND U ND U 8.4 4.1 J 0.13 J ND u ND u 9.4 64 24 20 11 23 11 ND u MRL 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 MDL 0.46 0.95 0.029 0.11 0.095 0.48 0.85 0.081 0.030 0.11 0.12 0.046 0.066 0.11 1.3 Dilution Date Date Extraction Analysis Factor Extracted Analyzed Lot Lot Note 1 2/ 9/10 2/17/10 20:23 105742 190532 1 2/ 9/10 2/17/10 20:23 105742 190532 1 2/ 9/10 2/18/10 02:28 105742 190532 1 2/ 9/10 2/18/10 02:28 105742 190532 1 2/ 9/10 2/17/10 20:23 105742 190532 1 2/ 9/10 2/17/10 20:23 105742 190532 1 219/10 2/17/10 20:23 105742 190532 1 2/9/10 2/18/10 02:28 105742 190532 1 2/ 9/10 2/18/10 02:28 105742 190532 1 2/ 9/10 2/18/10 02:28 105742 190532 1 2/ 9/10 2/17/10 20:23 105742 190532 1 2/ 9/10 2/17/10 20:23 105742 190532 1 2/ 9/10 2/17/10 20:23 105742 190532 1 2/ 9/10 2/18/10 02:28 105742 190532 1 2/ 9/10 2/17/10 20:23 105742 190532 Surrogate Name Perfluoro-n-[l,2,3,4,5-13C5] nonanoic acid Perfluoro-n-[l,2,3,4-13C4] butanoic acid Perfluoro-n-[l,2,3,4-13C4] octanoic acid Perfluoro-n-[l,2-13C2] decanoic acid Perfluoro-n-[l,2-13C2] hexanoic acid Perfluoro-n-[1,2-13C2]dodecanoic Acid Perfluoro-n-[l,2-13C2]undecanoic Acid Sodium perfluoro-l-[l,2,3,4-13C4] octanesulfonate Sodium perfluoro-l-hexane[1802]sulfonate %Rec 78 91 93 100 89 49 * 67 74 106 Control Limits 50-150 50-150 50-150 50-150 50-150 50-150 50-150 50-150 50-150 Date Analyzed Q 2/17/10 20:23 2/18/10 02:28 2/17/10 20:23 2/17/10 20:23 2/18/10 02:28 2/17/10 20:23 2/17/10 20:23 2/17/10 20:23 2/18/10 02:28 Note Comments: Printed 2/23/10 13:41 '/inflow2\Starlims''LimsReps''AnaIyticalReport.rpt Form 1A 15 Superset Reference: 10-0000135143 rev 00 Client: Project: Sample Matrix: Sample Name: Lab Code: Analytical Report Camp Dresser & McKee, Incorporated (CDM) Baron & Budd, P.C./95779-75319 Water Spanish Trail "Treated" K1001011-004 p. 20 Service Request: K1001011 Date Collected: 2/ 3/10 0843 Date Received: 2/ 4/10 Units: ng/L Basis: NA Perfluorinated Sulfonic Acids and Perfluorinated Carboxylic Acids by HPLC/MS Analytical Method: PFOA Prep Method: Method Analyte Name Perfluoro-n-tetradecanoic acid Perfluoro-n-tridecanoic acid Perfluorobutanesulfonate Perfluorobutanoic Acid Perfluorodecane Sulfonate Perfluorodecanoic Acid Perfluorododecanoic Acid Perfluoroheptanoic Acid Perfluorohexanesulfonate Perfluorohexanoic Acid Perfluorononanoic Acid Perfluorooctanesulfonate Perfluorooctanoic Acid Perfluoropentanoic Acid Perfluoroundecanoic Acid Result Q ND U ND U 8.7 4.3 J 0.11 J ND u ND u 9.3 64 23 22 11 24 11 ND u MRL 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 MDL 0.46 0.95 0.029 0.11 0.095 0.48 0.85 0.081 0.030 0.11 0.12 0.046 0.066 0.11 1.3 Dilution Date Date Extraction Analysis Factor Extracted Analyzed Lot Lot Note 1 2/ 9/10 2/17/10 20:31 105742 190532 1 2/ 9/10 2/17/10 20:31 105742 190532 1 2/ 9/10 2/18/10 02:37 105742 190532 1 2/ 9/10 2/18/10 02:37 105742 190532 1 2/ 9/10 2/17/10 20:31 105742 190532 1 2/ 9/10 2/17/10 20:31 105742 190532 1 2/ 9/10 2/17/10 20:31 105742 190532 1 2/ 9/10 2/18/10 02:37 105742 190532 1 2/ 9/10 2/18/10 02:37 105742 190532 1 2/ 9/10 2/18/10 02:37 105742 190532 1 2/ 9/10 2/17/10 20:31 105742 190532 1 2/ 9/10 2/17/10 20:31 105742 190532 1 2/ 9/10 2/17/10 20:31 105742 190532 1 2/ 9/10 2/18/10 02:37 105742 190532 1 2/ 9/10 2/17/10 20:31 105742 190532 Surrogate Name Perfluoro-n-[l,2,3,4,5-13C5] nonanoic acid Perfluoro-n-[l,2,3,4-13C4] butanoic acid Perfluoro-n-[l,2,3,4-13C4] octanoic acid Perfluoro-n-[l,2-13C2] decanoicacid Perfluoro-n-[l,2-13C2] hexanoicacid Perfluoro-n-[1,2-13C2]dodecanoic Acid Perfluoro-n-[l,2-13C2]undecanoic Acid Sodium perfluoro-l-[l,2,3,4-13C4] octanesulfonate Sodium perfluoro-l-hexane[1802]sulfonate %Rec 80 85 102 100 90 44 * 64 78 100 Control Limits 50-150 50-150 50-150 50-150 50-150 50-150 50-150 50-150 50-150 Date Analyzed Q 2/17/10 20:31 2/18/10 02:37 2/17/10 20:31 2/17/10 20:31 2/18/10 02:37 2/17/10 20:31 2/17/10 20:31 2/17/10 20:31 2/18/10 02:37 Note Comments: Printed 2/23/10 13:41 \\Inflow2\Starlims\LimsReps\AnalyticalReport.rpt Form 1A 16 SuperSct Reference: 10-0000135143 rev 00 Client: Project: Sample Matrix: Sample Name: Lab Code: Analytical Report Camp Dresser & McKee, Incorporated (CDM) Baron & Budd, P.C./95779-75319 Water Airport North "Raw" K1001011-005 p. 21 Service Request: K1001011 Date Collected: 213/10 0912 Date Received: 2/ 4/10 Units: ng/L Basis: NA Perfluorinated Sulfonic Acids and Perfluorinated Carboxylic Acids by HPLC/MS Analytical Method: PFOA Prep Method: Method Analyte Name Perfluoro-n-tetradecanoic acid Perfluoro-n-tridecanoic acid Perlluorobutanesulfonate Perfluorobutanoic Acid Perfluorodecane Sulfonate Perfluorodecanoic Acid Perfluorododecanoic Acid Perfluoroheptanoic Acid Perfluorohexanesulfonate Perfluorohexanoic Acid Perfluorononanoic Acid Perfluorooctanesulfonate Perfluorooctanoic Acid Perfluoropentanoic Acid Perfluoroundecanoic Acid Result Q ND U ND U 5.0 J 2.9 J 0.48 J 1.0 J 1.1 J 6.5 34 14 58 32 14 7.8 2.2 J MRL 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 MDL 0.46 0.95 0.029 0.11 0.095 0.48 0.85 0.081 0.030 0.11 0.12 0.046 0.066 0.11 1.3 Dilution Date Date Extraction Analysis Factor Extracted Analyzed Lot Lot Note 1 2/ 9/10 2/17/10 20:38 105742 190532 1 2/ 9/10 2/17/10 20:38 105742 190532 1 2/ 9/10 2/18/10 02:47 105742 190532 1 2/ 9/10 2/18/10 02:47 105742 190532 1 2/ 9/10 2/17/10 20:38 105742 190532 1 2/ 9/10 2/17/10 20:38 105742 190532 1 2/ 9/10 2/17/10 20:38 105742 190532 1 2/ 9/10 2/18/10 02:47 105742 190532 1 2/ 9/10 2/18/10 02:47 105742 190532 1 2/ 9/10 2/18/10 02:47 105742 190532 1 2/ 9/10 2/17/10 20:38 105742 190532 1 2/ 9/10 2/17/10 20:38 105742 190532 1 2/ 9/10 2/17/10 20:38 105742 190532 1 2/ 9/10 2/18/10 02:47 105742 190532 1 2/ 9/10 2/17/10 20:38 105742 190532 Surrogate Name Perfluoro-n-[l,2,3,4,5-13C5] nonanoic acid Perfluoro-n-[l,2,3,4-13C4] butanoic acid Perfluoro-n-[l,2,3,4-13C4] octanoic acid Perfluoro-n-[l,2-13C2] decanoic acid Perfluoro-n-[l,2-13C2] hexanoic acid Perfluoro-n-[1,2-13C2]dodecanoic Acid Perfluoro-n-[1,2-13C2]undecanoic Acid Sodiumperfluoro-l-[l,2,3,4-13C4] octanesulfonate Sodium perfluoro-1-hexane[1802]sulfonate %Rec 81 80 107 100 87 34 * 51 75 110 Control Limits 50-150 50-150 50-150 50-150 50-150 50-150 50-150 50-150 50-150 Date Analyzed Q 2/17/10 20:38 2/18/10 02:47 2/17/10 20:38 2/17/10 20:38 2/18/10 02:47 2/17/10 20:38 2/17/10 20:38 2/17/10 20:38 2/18/10 02:47 Note Comments: Printed 2/23/10 13:41 \\Inflow2VStarlims\LunsReps\AnalyticalRepartrpt Form 1A 17 SuperSet Reference: 10-0000135143 rev 00 Client: Project: Sample Matrix: Sample Name: Lab Code: Analytical Report Camp Dresser & McKee, Incorporated (CDM) Baron & Budd, P.C./95779-75319 Water Airport North "Treated" K1001011-006 p. 22 Service Request: K100I011 Date Collected: 2/ 3/10 0923 Date Received: 2/ 4/10 Units: ng/L Basis: NA Perfluorinated Sulfonic Acids and Perfluorinated Carboxylic Acids by HPLC/MS Analytical Method: PFOA Prep Method: Method Analyte Name Perfluoro-n-tetradecanoic acid Perfluoro-n-tridecanoic acid Perfluorobutanesulfonate Perfluorobutanoic Acid Perfluorodecane Sulfonate Perfluorodecanoic Acid Perfluorododecanoic Acid Perfluoroheptanoic Acid Perfluorohexanesulfonate Perfluorohexanoic Acid Perfluorononanoic Acid Perfluorooctanesulfonate Perfluorooctanoic Acid Perfluoropentanoic Acid Perfluoroundecanoic Acid Result Q ND U ND u 4.8 J 2.9 J 0.34 J 0.54 J 1.0 J 6.0 31 14 54 30 15 8.0 ND u MRL 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 MDL 0.46 0.95 0.029 0.11 0.095 0.48 0.85 0.081 0.030 0.11 0.12 0.046 0.066 0.11 1.3 Dilution Date Date Extraction Analysis Factor Extracted Analyzed Lot Lot Note 1 2/ 9/10 2/17/10 20:46 105742 190532 1 2/ 9/10 2/17/10 20:46 105742 190532 1 219/10 2/18/10 02:57 105742 190532 1 2/ 9/10 2/18/10 02:57 105742 190532 1 2/ 9/10 2/17/10 20:46 105742 190532 1 2/ 9/10 2/17/10 20:46 105742 190532 1 2/ 9/10 2/17/10 20:46 105742 190532 1 2/ 9/10 2/18/10 02:57 105742 190532 1 2/9/10 2/18/10 02:57 105742 190532 1 2/ 9/10 2/18/10 02:57 105742 190532 1 2/ 9/10 2/17/10 20:46 105742 190532 1 2/ 9/10 2/17/10 20:46 105742 190532 1 2/ 9/10 2/17/10 20:46 105742 190532 1 2/ 9/10 2/18/10 02:57 105742 190532 1 2/ 9/10 2/17/10 20:46 105742 190532 Surrogate Name Perfluoro-n-[l,2,3,4,5-13C5] nonanoic acid Perfluoro-n-[l,2,3,4-13C4] butanoic acid Perfluoro-n-[l,2,3,4-13C4] octanoic acid Perfluoro-n-[l,2-13C2] decanoic acid Perfluoro-n-[l,2-13C2] hexanoicacid Perfluoro-n-[1,2-13C2]dodecanoic Acid Perfluoro-n-[l,2-13C2]undecanoic Acid Sodium perfluoro-l-[l,2,3,4-13C4] octanesulfonate Sodium perfluoro-l-hexane[1802]sulfonate %Rec 107 107 116 100 109 64 66 98 129 Control Limits 50-150 50-150 50-150 50-150 50-150 50-150 50-150 50-150 50-150 Date Analyzed 2/17/10 20:46 2/18/10 02:57 2/17/10 20:46 2/17/10 20:46 2/18/10 02:57 2/17/10 20:46 2/17/10 20:46 2/17/10 20:46 2/18/10 02:57 Comments: Printed 2/23/10 13:41 \\Inflow2VStarlims\LimsReps\AnalyticalReport.rpt Form 1A 18 SupcrSet Reference: 10-0000135143 rev 00 Client: Project: Sample Matrix: Sample Name: Lab Code: Analytical Report Camp Dresser & McKee, Incorporated (CDM) Baron & Budd, P.C./95779-75319 Water McAllister "Raw" K1001011-007 p. 23 Service Request: K1001011 Date Collected: 2/ 3/10 0949 Date Received: 2/ 4/10 Units: ng/L Basis: NA Perfluorinated Sulfonic Acids and Perfluorinated Carboxylic Acids by HPLC/MS Analytical Method: PFOA Prep Method: Method Analyte Name Perfluoro-n-tetradecanoic acid Perfluoro-n-tridecanoic acid Perfluorobutanesulfonate Perfluorobutanoic Acid Perfluorodecane Sulfonate Perfluorodecanoic Acid Perfluorododecanoic Acid Perfluoroheptanoic Acid Perfluorohexanesulfonate Perfluorohexanoic Acid Perfluorononanoic Acid Perfluorooctanesulfonate Perfluorooctanoic Acid Perfluoropentanoic Acid Perfluoroundecanoic Acid Result Q ND U ND U 5.8 5.0 0.13 J 0.83 J ND U 16 55 26 140 150 38 13 3.1 J MRL 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 MDL 0.46 0.95 0.029 0.11 0.095 0.48 0.85 0.081 0.030 0.11 0.12 0.046 0.066 0.11 1.3 Dilution Date Date Extraction Analysis Factor Extracted Analyzed Lot Lot Note 1 2/ 9/10 2/17/10 20:54 105742 190532 1 2/ 9/10 2/17/10 20:54 105742 190532 1 2/ 9/10 2/18/10 03:06 105742 190532 1 2/ 9/10 2/18/10 03:06 105742 190532 1 2/ 9/10 2/17/10 20:54 105742 190532 1 2/ 9/10 2/17/10 20:54 105742 190532 1 2/ 9/10 2/17/10 20:54 105742 190532 1 2/ 9/10 2/18/10 03:06 105742 190532 1 2/ 9/10 2/18/10 03:06 105742 190532 1 2/ 9/10 2/18/10 03:06 105742 190532 1 2/ 9/10 2/17/10 20:54 105742 190532 1 2/ 9/10 2/17/10 20:54 105742 190532 1 2/ 9/10 2/17/10 20:54 105742 190532 1 2/ 9/10 2/18/10 03:06 105742 190532 1 2/ 9/10 2/17/10 20:54 105742 190532 Surrogate Name Perfluoro-n-[l,2,3,4,5-13C5] nonanoic acid Perfluoro-n-[l,2,3,4-13C4] butanoic acid Perfluoro-n-[l,2,3,4-13C4] octanoic acid Perfluoro-n-[l,2-13C2] decanoicacid Perfluoro-n-[l,2-13C2] hexanoicacid Perfluoro-n-[l,2-13C2]dodecanoic Acid Perfluoro-n-[1,2-13C2]undecanoic Acid Sodium perfluoro-l-[l,2,3,4-13C4] octanesulfonate Sodium perfluoro-1-hexanef1802]sulfonate %Rec 96 96 118 100 103 63 79 101 121 Control Limits 50-150 50-150 50-150 50-150 50-150 50-150 50-150 50-150 50-150 Date Analyzed Q 2/17/10 20:54 2/18/10 03:06 2/17/10 20:54 2/17/10 20:54 2/18/10 03:06 2/17/10 20:54 2/17/10 20:54 2/17/10 20:54 2/18/10 03:06 Note Comments: Printed 2/23/10 13:41 \\Inflow2\Starlims\LimsReps\AnalyticalReport.rpt Form 1A 19 SuperSet Reference: 10-0000135143 rev 00 Client: Project: Sample Matrix: Sample Name: Lab Code: Analytical Report Camp Dresser & McKee, Incorporated (CDM) Baron & Budd, P.C./95779-75319 Water McAllister "Treated" K1001011-008 p. 24 Service Request: K1001011 Date Collected: 2/ 3/10 1002 Date Received: 2/4/10 Units: ng/L Basis: NA Perfluorinated Sulfonic Acids and Perfluorinated Carboxylic Acids by HPLC/MS Analytical Method: PFOA Prep Method: Method Analyte Name Perfluoro-n-tetradecanoic acid Perfluoro-n-tridecanoic acid Perfluorobutanesulfonate Perfluorobutanoic Acid Perfluorodecane Sulfonate Perfluorodecanoic Acid Perfluorododecanoic Acid Perfluoroheptanoic Acid Perfluorohexanesulfonate Perfluorohexanoic Acid Perfluorononanoic Acid Perfluorooctanesulfonate Perfluorooctanoic Acid Perfluoropentanoic Acid Perfluoroundecanoic Acid Result Q ND U ND U 0.29 J 6.7 0.57 J 0.62 J 1.3 J 0.32 J 0.30 J 0.95 J 0.56 J 0.77 J 0.45 J 3.3 J 1.9 J MRL 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 MDL 0.46 0.95 0.029 0.11 0.095 0.48 0.85 0.081 0.030 0.11 0.12 0.046 0.066 0.11 1.3 Dilution Date Date Extraction Analysis Factor Extracted Analyzed Lot Lot Note 1 2/ 9/10 2/17/10 21:01 105742 190532 1 2/ 9/10 2/17/10 21:01 105742 190532 1 2/ 9/10 2/18/10 03:16 105742 190532 1 2/ 9/10 2/18/10 03:16 105742 190532 1 2/ 9/10 2/17/10 21:01 105742 190532 1 2/ 9/10 2/17/10 21:01 105742 190532 1 2/ 9/10 2/17/10 21:01 105742 190532 1 2/ 9/10 2/18/10 03:16 105742 190532 1 2/ 9/10 2/18/10 03:16 105742 190532 1 2/ 9/10 2/18/10 03:16 105742 190532 1 2/ 9/10 2/17/10 21:01 105742 190532 1 2/ 9/10 2/17/10 21:01 105742 190532 1 2/ 9/10 2/17/10 21:01 105742 190532 1 2/ 9/10 2/18/10 03:16 105742 190532 1 2/ 9/10 2/17/10 21:01 105742 190532 Surrogate Name Perfluoro-n-[l,2,3,4,5-13C5] nonanoic acid Perfluoro-n-[l,2,3,4-13C4] butanoic acid Perfluoro-n-[l,2,3,4-13C4] octanoic acid Perfluoro-n-[l,2-13C2] decanoic acid Perfluoro-n-[l,2-13C2] hexanoic acid Perfluoro-n-[1,2-13C2]dodecanoic Acid Perfluoro-n-[l,2-13C2]undecanoic Acid Sodiumperfluoro-l-[l,2,3,4-13C4] octanesulfonate Sodium perfluoro-l-hexane[1802]sulfonate %Rec 97 113 120 100 115 56 67 93 118 Control Limits 50-150 50-150 50-150 50-150 50-150 50-150 50-150 50-150 50-150 Date Analyzed Q 2/17/10 21:01 2/18/10 03:16 2/17/10 21:01 2/17/10 21:01 2/18/10 03:16 2/17/10 21:01 2/17/10 21:01 2/17/10 21:01 2/18/10 03:16 Note Comments: Printed 2/23/10 13:41 \\Inflow2\Starlims\LimsReps\AnalyticalReport.rpt Form 1A 20 SuperSet Reference: 10-0000135143 rev 00 Client: Project: Sample Matrix: Sample Name: Lab Code: Analytical Report Camp Dresser & McKee, Incorporated (CDM) Baron & Budd, P.C./95779-75319 Water Humphrey "Raw" K1001011-009 p. 25 Service Request: K1001011 Date Collected: 2/ 3/10 1055 Date Received: 2/ 4/10 Units: ng/L Basis: NA Perfluorinated Sulfonic Acids and Perfluorinated Carboxylic Acids by HPLC/MS Analytical Method: PFOA Prep Method: Method Analyte Name Perfluoro-n-tetradecanoic acid Perfluoro-n-tridecanoic acid Perfluorobutanesulfonate Perfluorobutanoic Acid Perfluorodecane Sulfonate Perfluorodecanoic Acid Perfluorododecanoic Acid Perfluoroheptanoic Acid Perfluorohexanesulfonate Perfluorohexanoic Acid Perfluorononanoic Acid Perfluorooctanesulfonate Perfluorooctanoic Acid Perfluoropentanoic Acid Perfluoroundecanoic Acid Result Q ND U ND U 1.6 J 1.3 J 0.49 J ND u 0.87 J 3.1 J 7.5 4.8 J 0.61 J 5.9 7.9 3.7 J ND u MRL 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 MDL 0.46 0.95 0.029 0.11 0.095 0.48 0.85 0.081 0.030 0.11 0.12 0.046 0.066 0.11 1.3 Dilution Date Date Extraction Analysis Factor Extracted Analyzed Lot Lot Note 1 2/ 9/10 2/17/10 21:09 105742 190532 1 2/ 9/10 2/17/10 21:09 105742 190532 1 2/ 9/10 2/18/10 03:25 105742 190532 1 2/ 9/10 2/18/10 03:25 105742 190532 1 2/ 9/10 2/17/10 21:09 105742 190532 1 219/10 2/17/10 21:09 105742 190532 1 2/ 9/10 2/17/10 21:09 105742 190532 1 2/ 9/10 2/18/10 03:25 105742 190532 1 2/ 9/10 2/18/10 03:25 105742 190532 1 2/ 9/10 2/18/10 03:25 105742 190532 1 2/ 9/10 2/17/10 21:09 105742 190532 1 2/ 9/10 2/17/10 21:09 105742 190532 1 2/ 9/10 2/17/10 21:09 105742 190532 1 2/ 9/10 2/18/10 03:25 105742 190532 1 2/ 9/10 2/17/10 21:09 105742 190532 Surrogate Name Perfluoro-n-[l,2,3,4,5-13C5] nonanoic acid Perfluoro-n-[l,2,3,4-13C4] butanoic acid Perfluoro-n-[l,2,3,4-13C4] octanoic acid Perfluoro-n-[l,2-13C2] decanoicacid Perfluoro-n-[l,2-13C2] hexanoicacid Perfluoro-n-[1,2-13C2]dodecanoic Acid Perfluoro-n-[l,2-13C2]undecanoic Acid Sodiumperfluoro-l-[l,2,3,4-13C4] octanesulfonate Sodium perfluoro-l-hexane[1802]sulfonate %Rec 90 97 104 100 101 54 69 89 120 Control Limits 50-150 50-150 50-150 50-150 50-150 50-150 50-150 50-150 50-150 Date Analyzed 2/17/10 21:09 2/18/10 03:25 2/17/10 21:09 2/17/10 21:09 2/18/10 03:25 2/17/10 21:09 2/17/10 21:09 2/17/10 21:09 2/18/10 03:25 Comments: Printed 2/23/10 13:41 \\Inflow2\Starlims\LimsReps\AnalyticalRepoitrpt Form 1A 21 SuperSet Reference: 10-0000135143 rev 00 Client: Project: Sample Matrix: Sample Name: Lab Code: Analytical Report Camp Dresser & McKee, Incorporated (CDM) Baron & Budd, P.C./95779-75319 Water Humphrey "Treated" K1001011-010 p. 26 Service Request: K100I011 Date Collected: 2/3/10 1107 Date Received: 2/ 4/10 Units: ng/L Basis: NA Perfluorinated Sulfonic Acids and Perfluorinated Carboxylic Acids by HPLC/MS Analytical Method: PFOA Prep Method: Method Analyte Name Perfluoro-n-tetradecanoic acid Perfluoro-n-tridecanoic acid Perfluorobutanesulfonate Perfluorobutanoic Acid Perfluorodecane Sulfonate Perfluorodecanoic Acid Perfluorododecanoic Acid Perfluoroheptanoic Acid Perfluorohexanesulfonate Perfluorohexanoic Acid Perfluorononanoic Acid Perfluorooctanesulfonate Perfluorooctanoic Acid Perfluoropentanoic Acid Perfluoroundecanoic Acid Result Q ND U ND U ND U 0.21 J 0.13 J ND U ND U ND U 0.12 J 0.11 J ND U 0.20 J 0.22 J 0.20 J ND U MRL 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 MDL 0.46 0.95 0.029 0.11 0.095 0.48 0.85 0.081 0.030 0.11 0.12 0.046 0.066 0.11 1.3 Dilution Date Date Extraction Analysis Factor Extracted Analyzed Lot Lot Note 1 2/ 9/10 2/17/10 21:16 105742 190532 1 2/ 9/10 2/17/10 21:16 105742 190532 1 2/ 9/10 2/18/10 03:35 105742 190532 1 2/ 9/10 2/18/10 03:35 105742 190532 1 2/ 9/10 2/17/10 21:16 105742 190532 1 2/ 9/10 2/17/10 21:16 105742 190532 1 2/ 9/10 2/17/10 21:16 105742 190532 1 2/ 9/10 2/18/10 03:35 105742 190532 1 2/ 9/10 2/18/10 03:35 105742 190532 1 2/ 9/10 2/18/10 03:35 105742 190532 1 2/ 9/10 2/17/10 21:16 105742 190532 1 2/ 9/10 2/17/10 21:16 105742 190532 1 2/ 9/10 2/17/10 21:16 105742 190532 1 2/ 9/10 2/18/10 03:35 105742 190532 1 2/ 9/10 2/17/10 21:16 105742 190532 Surrogate Name Perfluoro-n-[l,2,3,4,5-13C5] nonanoic acid Perfluoro-n-[l,2,3,4-13C4] butanoic acid Perfluoro-n-[l,2,3,4-13C4] octanoic acid Perfluoro-n-[l,2-13C2] decanoicacid Perfluoro-n-[l,2-13C2] hexanoicacid Perfluoro-n-[1,2-13C2]dodecanoic Acid Perfluoro-n-[1,2-13C2]undecanoic Acid Sodium perfluoro-l-[l,2,3,4-13C4] octanesulfonate Sodium perfluoro-1-hexane[1802]sulfonate %Rec 96 94 116 100 101 58 68 92 118 Control Limits 50-150 50-150 50-150 50-150 50-150 50-150 50-150 50-150 50-150 Date Analyzed Q 2/17/10 21:16 2/18/10 03:35 2/17/10 21:16 2/17/10 21:16 2/18/10 03:35 2/17/10 21:16 2/17/10 21:16 2/17/10 21:16 2/18/10 03:35 Note Comments: Printed 2/23/10 13:41 \\lnflow2\Starlims\LimsReps\AnalyticalReportrpt Form 1A 22 SupcrSet Reference: 10-0000135143 rev 00 Client: Project: Sample Matrix: Sample Name: Lab Code: Analytical Report Camp Dresser & McKee, Incorporated (CDM) Baron & Budd, P.C./95779-75319 Water Broad "Raw" K1001011-011 p. 27 Service Request: K1001011 Date Collected: 2/ 3/10 1146 Date Received: 2/ 4/10 Units: ng/L Basis: NA Perfluorinated Sulfonic Acids and Perfluorinated Carboxylic Acids by HPLC/MS Analytical Method: PFOA Prep Method: Method Analyte Name Perfluoro-n-tetradecanoic acid Perfluoro-n-tridecanoic acid Perfluorobutanesulfonate Perfluorobutanoic Acid Perfluorodecane Sulfonate Perfluorodecanoic Acid Perfluorododecanoic Acid Perfluoroheptanoic Acid Perfluorohexanesulfonate Perfluorohexanoic Acid Perfluorononanoic Acid Perfluorooctanesulfonate Perfluorooctanoic Acid Perfluoropentanoic Acid Perfluoroundecanoic Acid Result Q ND U ND U 0.25 J 0.29 J 0.75 J 1.0 J 1.2 J 0.29 J 0.59 J 0.50 J 0.63 J 1.7 J 1.8 J 0.44 J 1.6 J MRL 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 MDL 0.46 0.95 0.029 0.11 0.095 0.48 0.85 0.081 0.030 0.11 0.12 0.046 0.066 0.11 1.3 Dilution Date Date Extraction Analysis Factor Extracted Analyzed Lot Lot Note 1 2/ 9/10 2/17/10 21:24 105742 190532 1 2/ 9/10 2/17/10 21:24 105742 190532 1 2/ 9/10 2/18/10 03:44 105742 190532 1 2/ 9/10 2/18/10 03:44 105742 190532 1 2/ 9/10 2/17/10 21:24 105742 190532 1 2/ 9/10 2/17/10 21:24 105742 190532 1 2/ 9/10 2/17/10 21:24 105742 190532 1 2/ 9/10 2/18/10 03:44 105742 190532 1 2/ 9/10 2/18/10 03:44 105742 190532 1 2/ 9/10 2/18/10 03:44 105742 190532 1 2/ 9/10 2/17/10 21:24 105742 190532 1 2/ 9/10 2/17/10 21:24 105742 190532 1 2/ 9/10 2/17/10 21:24 105742 190532 1 2/ 9/10 2/18/10 03:44 105742 190532 1 2/ 9/10 2/17/10 21:24 105742 190532 Surrogate Name Perfluoro-n-[l,2,3,4,5-13C5] nonanoic acid Perfluoro-n-[l,2,3,4-13C4] butanoic acid Perfluoro-n-[l,2,3,4-13C4] octanoic acid Perfluoro-n-[l,2-13C2] decanoic acid Perfluoro-n-[l,2-13C2] hexanoicacid Perfluoro-n-[1,2-13C2]dodecanoic Acid Perfluoro-n-[l,2-13C2]undecanoic Acid Sodium perfluoro-l-[l,2,3,4-13C4] octanesulfonate Sodium perfluoro-1-hexane[1802] sulfonate %Rec 103 84 120 100 88 77 97 117 112 Control Limits 50-150 50-150 50-150 50-150 50-150 50-150 50-150 50-150 50-150 Date Analyzed Q 2/17/10 21:24 2/18/10 03:44 2/17/10 21:24 2/17/10 21:24 2/18/10 03:44 2/17/10 21:24 2/17/10 21:24 2/17/10 21:24 2/18/10 03:44 Note Comments: Printed 2/23/10 13:41 \Mnflow2\Starlims\LimsReps\AnalyticalReportrpt Form 1A 23 SuperSet Reference: 10-0000135143 rev 00 Client: Project: Sample Matrix: Sample Name: Lab Code: Analytical Report Camp Dresser & McKee, Incorporated (CDM) Baron & Budd, P.C./95779-75319 Water Broad "Treated" K1001011-0I2 p. 28 Service Request: K100I011 Date CoUected: 2/ 3/10 1200 Date Received: 2/ 4/10 Units: ng/L Basis: NA Perfluorinated Sulfonic Acids and Perfluorinated Carboxylic Acids by HPLC/MS Analytical Method: PFOA Prep Method: Method Analyte Name Perfluoro-n-tetradecanoic acid Perfluoro-n-tridecanoic acid Perfluorobutanesulfonate Perfluorobutanoic Acid Perfluorodecane Sulfonate Perfluorodecanoic Acid Perfluorododecanoic Acid Perfluoroheptanoic Acid Perfluorohexanesulfonate Perfluorohexanoic Acid Perfluorononanoic Acid Perfluorooctanesulfonate Perfluorooctanoic Acid Perfluoropentanoic Acid Perfluoroundecanoic Acid Result Q ND U ND U 0.38 J 0.33 J 0.25 J 0.49 J ND U 0.37 J 0.65 J 0.71 J 0.34 J 1.2 J 2.1 J 0.56 J ND U MRL 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 MDL 0.46 0.95 0.029 0.11 0.095 0.48 0.85 0.081 0.030 0.11 0.12 0.046 0.066 0.11 1.3 Dilution Date Date Extraction Analysis Factor Extracted Analyzed Lot Lot Note 1 2/ 9/10 2/17/10 21:31 105742 190532 1 2/ 9/10 2/17/10 21:31 105742 190532 1 2/ 9/10 2/18/10 03:54 105742 190532 1 2/ 9/10 2/18/10 03:54 105742 190532 1 2/ 9/10 2/17/10 21:31 105742 190532 1 2/ 9/10 2/17/10 21:31 105742 190532 1 2/ 9/10 2/17/10 21:31 105742 190532 1 2/ 9/10 2/18/10 03:54 105742 190532 1 2/ 9/10 2/18/10 03:54 105742 190532 1 2/ 9/10 2/18/10 03:54 105742 190532 1 2/ 9/10 2/17/10 21:31 105742 190532 1 2/ 9/10 2/17/10 21:31 105742 190532 1 2/ 9/10 2/17/10 21:31 105742 190532 1 2/ 9/10 2/18/10 03:54 105742 190532 1 2/ 9/10 2/17/10 21:31 105742 190532 Surrogate Name Perfluoro-n-[l,2,3,4,5-13C5] nonanoic acid Perfluoro-n-[l,2,3,4-13C4] butanoic acid Perfluoro-n-[l,2,3,4-13C4] octanoic acid Perfluoro-n-[l,2-13C2] decanoicacid Perfluoro-n-[l,2-13C2] hexanoicacid Perfluoro-n-[1,2-13C2]dodecanoic Acid Perfluoro-n-[l,2-13C2]undecanoic Acid Sodiumperfluoro-l-[l,2,3,4-13C4] octanesulfonate Sodium perfluoro-1-hexane[ 1802]sulfonate %Rec 81 77 95 100 86 44 * 58 75 109 Control Limits 50-150 50-150 50-150 50-150 50-150 50-150 50-150 50-150 50-150 Date Analyzed 2/17/10 21:31 2/18/10 03:54 2/17/10 21:31 2/17/10 21:31 2/18/10 03:54 2/17/10 21:31 2/17/10 21:31 2/17/10 21:31 2/18/10 03:54 Comments: Printed 2/23/10 13:41 \\Inflow2\Starlims\LimsReps\AnalyticalReportrpt Form 1A 24 SuperSet Reference: 10-0000135143 rev 00 Client: Project: Sample Matrix: Sample Name: Lab Code: Analytical Report Camp Dresser & McKee, Incorporated (CDM) Baron & Budd, P.C./95779-75319 Water Tennant "Raw" K100I011-013 p. 29 Service Request: KL00I011 Date Collected: 2/ 3/10 1305 Date Received: 2/4/10 Units: ng/L Basis: NA Perfluorinated Sulfonic Acids and Perfluorinated Carboxylic Acids by HPLC/MS Analytical Method: PFOA Prep Method: Method Analyte Name Perfluoro-n-tetradecanoic acid Perfluoro-n-tridecanoic acid Perfluorobutanesulfonate Perfluorobutanoic Acid Perfluorodecane Sulfonate Perfluorodecanoic Acid Perfluorododecanoic Acid Perfluoroheptanoic Acid Perfluorohexanesulfonate Perfluorohexanoic Acid Perfluorononanoic Acid Perfluorooctanesulfonate Perfluorooctanoic Acid Perfluoropentanoic Acid Perfluoroundecanoic Acid Result Q ND U ND U 0.61 J 0.80 J 0.17 J ND u ND u 1.6 J 3.2 J 2.3 J 0.66 J 5.9 3.2 J 2.1 J ND u MRL 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 MDL 0.46 0.95 0.029 0.11 0.095 0.48 0.85 0.081 0.030 0.11 0.12 0.046 0.066 0.11 1.3 Dilution Date Date Extraction Analysis Factor Extracted Analyzed Lot Lot Note 1 2/ 9/10 2/17/10 21:39 105742 190532 1 2/ 9/10 2/17/10 21:39 105742 190532 1 2/ 9/10 2/18/10 04:03 105742 190532 1 2/ 9/10 2/18/10 04:03 105742 190532 1 2/ 9/10 2/17/10 21:39 105742 190532 1 2/ 9/10 2/17/10 21:39 105742 190532 1 2/ 9/10 2/17/10 21:39 105742 190532 1 2/ 9/10 2/18/10 04:03 105742 190532 1 2/ 9/10 2/18/10 04:03 105742 190532 1 2/ 9/10 2/18/10 04:03 105742 190532 1 2/ 9/10 2/17/10 21:39 105742 190532 1 2/ 9/10 2/17/10 21:39 105742 190532 1 2/ 9/10 2/17/10 21:39 105742 190532 1 2/ 9/10 2/18/10 04:03 105742 190532 1 2/ 9/10 2/17/10 21:39 105742 190532 Surrogate Name Perfluoro-n-[l,2,3,4,5-13C5] nonanoic acid Perfluoro-n-[l,2,3,4-13C4] butanoic acid Perfluoro-n-[l,2,3,4-13C4] octanoic acid Perfluoro-n-[l,2-13C2] decanoic acid Perfluoro-n-[l,2-13C2] hexanoicacid Perfluoro-n-[1,2-13C2]dodecanoic Acid Perfluoro-n-[1,2-13C2]undecanoic Acid Sodium perfluoro-l-[l,2,3,4-13C4] octanesulfonate Sodium perfluoro-1-hexane[1802]sulfonate %Rec 82 74 97 100 79 50 59 84 104 Control Limits 50-150 50-150 50-150 50-150 50-150 50-150 50-150 50-150 50-150 Date Analyzed 2/17/10 21:39 2/18/10 04:03 2/17/10 21:39 2/17/10 21:39 2/18/10 04:03 2/17/10 21:39 2/17/10 21:39 2/17/10 21:39 2/18/10 04:03 Comments: Printed 2/23/10 13:41 \\Inflow2\Starlims\LimsReps\AnalyticalRepoit.rpt Form 1A 25 SuperSet Reference: 10-0000135143 rev 00 Client: Project: Sample Matrix: Sample Name: Lab Code: Analytical Report Camp Dresser & McKee, Incorporated (CDM) Baron & Budd, P.C./95779-75319 Water Tennant "Treated" K1001011-014 p. 30 Service Request: K 1001011 Date Collected: 2/3/10 1317 Date Received: 2/ 4/10 Units: ng/L Basis: NA Perfluorinated Sulfonic Acids and Perfluorinated Carboxylic Acids by HPLC/MS Analytical Method: PFOA Prep Method: Method Analyte Name Perfluoro-n-tetradecanoic acid Perfluoro-n-tridecanoic acid Perfluorobutanesulfonate Perfluorobutanoic Acid Perfluorodecane Sulfonate Perfluorodecanoic Acid Perfluorododecanoic Acid Perfluoroheptanoic Acid Perfluorohexanesulfonate Perfluorohexanoic Acid Perfluorononanoic Acid Perfluorooctanesulfonate Perfluorooctanoic Acid Perfluoropentanoic Acid Perfluoroundecanoic Acid Result Q ND U ND U 0.67 J 0.81 J 0.12 J ND U ND U 1.3 J 3.5 J 2.1 J 0.57 J 5.8 3.6 J 2.1 J ND U MRL 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 MDL 0.46 0.95 0.029 0.11 0.095 0.48 0.85 0.081 0.030 0.11 0.12 0.046 0.066 0.11 1.3 Dilution Date Date Extraction Analysis Factor Extracted Analyzed Lot Lot Note 1 2/ 9/10 2/17/10 21:46 105742 190532 1 2/ 9/10 2/17/10 21:46 105742 190532 1 2/ 9/10 2/18/10 04:13 105742 190532 1 2/ 9/10 2/18/10 04:13 105742 190532 1 2/ 9/10 2/17/10 21:46 105742 190532 1 2/ 9/10 2/17/10 21:46 105742 190532 1 2/ 9/10 2/17/10 21:46 105742 190532 1 2/ 9/10 2/18/10 04:13 105742 190532 1 2/ 9/10 2/18/10 04:13 105742 190532 1 2/ 9/10 2/18/10 04:13 105742 190532 1 2/ 9/10 2/17/10 21:46 105742 190532 1 2/ 9/10 2/17/10 21:46 105742 190532 1 2/ 9/10 2/17/10 21:46 105742 190532 1 2/ 9/10 2/18/10 04:13 105742 190532 1 2/ 9/10 2/17/10 21:46 105742 190532 Surrogate Name Perfluoro-n-[l,2,3,4,5-13C5] nonanoic acid Perfluoro-n-[l,2,3,4-13C4] butanoic acid Perfluoro-n-[l,2,3,4-13C4] octanoic acid Perfluoro-n-[l,2-13C2] decanoic acid Perfluoro-n-[l,2-13C2] hexanoic acid Perfluoro-n-[1,2-13C2]dodecanoic Acid Perfluoro-n-[1,2-13C2]undecanoic Acid Sodium perfluoro-l-[l,2,3,4-13C4] octanesulfonate Sodium perfluoro-l-hexane[1802]sulfonate %Rec 89 97 103 100 101 45 * 47 * 90 113 Control Limits 50-150 50-150 50-150 50-150 50-150 50-150 50-150 50-150 50-150 Date Analyzed Q 2/17/10 21:46 2/18/10 04:13 2/17/10 21:46 2/17/10 21:46 2/18/10 04:13 2/17/10 21:46 2/17/10 21:46 2/17/10 21:46 2/18/10 04:13 Note Comments: Printed 2/23/10 13:41 UInflow2\Starlims\LimsReps\AnalyticalReport.rpt Form 1A 26 Superset Reference: 10-0000135143rev00 Client: Project: Sample Matrix: Sample Name: Lab Code: Analytical Report Camp Dresser & McKee, Incorporated (CDM) Baron & Budd, P.C./95779-75319 Water Muldoon "Raw" K1001011-015 p. 31 Service Request: K 1001011 Date Collected: 2/ 3/10 1347 Date Received: 2/ 4/10 Units: ng/L Basis: NA Perfluorinated Sulfonic Acids and Perfluorinated Carboxylic Acids by HPLC/MS Analytical Method: PFOA Prep Method: Method Analyte Name Perfluoro-n-tetradecanoic acid Perfluoro-n-tridecanoic acid Perfluorobutanesulfonate Perfluorobutanoic Acid Perfluorodecane Sulfonate Perfluorodecanoic Acid Perfluorododecanoic Acid Perfluoroheptanoic Acid Perfluorohexanesulfonate Perfluorohexanoic Acid Perfluorononanoic Acid Perfluorooctanesulfonate Perfluorooctanoic Acid Perfluoropentanoic Acid Perfluoroundecanoic Acid Result Q ND U ND U 0.68 J 0.38 J 0.30 J ND u ND u 0.71 J 4.5 J 1.2 J 0.45 J 4.3 J 1.9 J 0.98 J ND u MRL 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 MDL 0.46 0.95 0.029 0.11 0.095 0.48 0.85 0.081 0.030 0.11 0.12 0.046 0.066 0.11 1.3 Dilution Date Date Extraction Analysis Factor Extracted Analyzed Lot Lot Note 1 2/ 9/10 2/17/10 21:54 105742 190532 1 2/ 9/10 2/17/10 21:54 105742 190532 1 2/ 9/10 2/18/10 04:23 105742 190532 1 2/ 9/10 2/18/10 04:23 105742 190532 1 2/ 9/10 2/17/10 21:54 105742 190532 1 2/ 9/10 2/17/10 21:54 105742 190532 1 2/ 9/10 2/17/10 21:54 105742 190532 1 2/ 9/10 2/18/10 04:23 105742 190532 1 2/ 9/10 2/18/10 04:23 105742 190532 1 2/ 9/10 2/18/10 04:23 105742 190532 1 2/ 9/10 2/17/10 21:54 105742 190532 1 2/ 9/10 2/17/10 21:54 105742 190532 1 2/ 9/10 2/17/10 21:54 105742 190532 1 2/ 9/10 2/18/10 04:23 105742 190532 1 2/ 9/10 2/17/10 21:54 105742 190532 Surrogate Name Perfluoro-n-[l,2,3,4,5-13C5] nonanoic acid Perfluoro-n-[l,2,3,4-13C4] butanoic acid Perfluoro-n-[l,2,3,4-13C4] octanoic acid Perfluoro-n-[l,2-13C2] decanoicacid Perfluoro-n-[l,2-13C2] hexanoicacid Perfluoro-n-[1,2-13C2]dodecanoic Acid Perfluoro-n-[1,2-13C2]undecanoic Acid Sodiumperfluoro-l-[l,2,3,4-13C4] octanesulfonate Sodium perfluoro-1-hexane[1802]sulfonate %Rec 86 86 102 100 86 46 * 52 93 105 Control Limits 50-150 50-150 50-150 50-150 50-150 50-150 50-150 50-150 50-150 Date Analyzed Q 2/17/10 21:54 2/18/10 04:23 2/17/10 21:54 2/17/10 21:54 2/18/10 04:23 2/17/10 21:54 2/17/10 21:54 2/17/10 21:54 2/18/10 04:23 Note Comments: Printed 2/23/10 13:41 \\Inflow2\Starlims\LimsReps\AnalyticalReport.rpt Form 1A 27 SuperSet Reference: 10-0000135143 rev 00 Client: Project: Sample Matrix: Sample Name: Lab Code: Analytical Report Camp Dresser & McKee, Incorporated (CDM) Baron & Budd, P.C./95779-75319 Water Muldoon "Treated" K1001011-016 p. 32 Service Request: K1001011 Date Collected: 2/ 3/10 1400 Date Received: 2/ 4/10 Units: ng/L Basis: NA Perfluorinated Sulfonic Acids and Perfluorinated Carboxylic Acids by HPLC/MS Analytical Method: PFOA Prep Method: Method Analyte Name Perfluoro-n-tetradecanoic acid Perfluoro-n-tridecanoic acid Perfluorobutanesulfonate Perfluorobutanoic Acid Perfluorodecane Sulfonate Perfluorodecanoic Acid Perfluorododecanoic Acid Perfluoroheptanoic Acid Perfluorohexanesulfonate Perfluorohexanoic Acid Perfluorononanoic Acid Perfluorooctanesulfonate Perfluorooctanoic Acid Perfluoropentanoic Acid Perfluoroundecanoic Acid Result Q ND U ND U 0.66 J 0.87 J 0.11 J ND U ND U 0.84 J 5.0 1.3 J 0.31 J 4.1 J 1.9 J 0.80 J ND U MRL 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 MDL 0.46 0,95 0.029 0.11 0.095 0.48 0.85 0.081 0.030 0.11 0.12 0.046 0.066 0.11 1.3 Dilution Date Date Extraction Analysis Factor Extracted Analyzed Lot Lot Note 1 2/ 9/10 2/17/10 22:02 105742 190532 1 2/ 9/10 2/17/10 22:02 105742 190532 1 2/ 9/10 2/18/10 04:32 105742 190532 1 2/ 9/10 2/18/10 04:32 105742 190532 1 2/ 9/10 2/17/10 22:02 105742 190532 1 2/ 9/10 2/17/10 22:02 105742 190532 1 2/ 9/10 2/17/10 22:02 105742 190532 1 2/ 9/10 2/18/10 04:32 105742 190532 1 2/ 9/10 2/18/10 04:32 105742 190532 1 2/ 9/10 2/18/10 04:32 105742 190532 1 2/ 9/10 2/17/10 22:02 105742 190532 1 2/ 9/10 2/17/10 22:02 105742 190532 1 2/ 9/10 2/17/10 22:02 105742 190532 1 2/ 9/10 2/18/10 04:32 105742 190532 1 2/ 9/10 2/17/10 22:02 105742 190532 Surrogate Name Perfluoro-n-[l,2,3,4,5-13C5] nonanoic acid Perfluoro-n-[l,2,3,4-13C4] butanoic acid Perfluoro-n-[l,2,3,4-13C4] octanoic acid Perfluoro-n-[l,2-13C2] decanoic acid Perfluoro-n-[l,2-13C2] hexanoicacid Perfluoro-n-[l,2-13C2]dodecanoic Acid Perfluoro-n-[l,2-13C2]undecanoic Acid Sodiumperfluoro-l-[l,2,3,4-13C4] octanesulfonate Sodium perfluoro-l-hexane[1802]sulfonate %Rec 85 15 * 110 100 86 46 * 52 91 98 Control Limits 50-150 50-150 50-150 50-150 50-150 50-150 50-150 50-150 50-150 Date Analyzed Q 2/17/10 22:02 2/18/10 04:32 2/17/10 22:02 2/17/10 22:02 2/18/10 04:32 2/17/10 22:02 2/17/10 22:02 2/17/10 22:02 2/18/10 04:32 Note Comments: Printed 2/23/10 13:41 \\lnflow2\Starlims\LimsReps\AnalyticalReport.ipt Form 1A 28 SuperSet Reference: 10-0000135143 rev 00 Client: Project: Sample Matrix: Sample Name: Lab Code: Analytical Report Camp Dresser & McKee, Incorporated (CDM) Baron & Budd, P.C./95779-75319 Water Villa "Raw" K1001011-017 p. 33 Service Request: K1001011 Date Collected: 2/ 3/10 1418 Date Received: 2/ 4/10 Units: ng/L Basis: NA Perfluorinated Sulfonic Acids and Perfluorinated Carboxylic Acids by HPLC/MS Analytical Method: PFOA Prep Method: Method Analyte Name Perfluoro-n-tetradecanoic acid Perfluoro-n-tridecanoic acid Perfluorobutanesulfonate Perfluorobutanoic Acid Perfluorodecane Sulfonate Perfluorodecanoic Acid Perfluorododecanoic Acid Perfluoroheptanoic Acid Perfluorohexanesulfonate Perfluorohexanoic Acid Perfluorononanoic Acid Perfluorooctanesulfonate Perfluorooctanoic Acid Perfluoropentanoic Acid Perfluoroundecanoic Acid Result Q ND U ND U 0.46 J 0.42 J ND u ND u ND u 0.45 J 1.4 J 0.92 J ND u 2.8 J 1.8 J 1.1 J ND u MRL 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 MDL 0.46 0.95 0.029 0.11 0.095 0.48 0.85 0.081 0.030 0.11 0.12 0.046 0.066 0.11 1.3 Dilution Date Date Extraction Analysis Factor Extracted Analyzed Lot Lot Note 1 2/ 9/10 2/17/10 22:09 105742 190532 1 2/ 9/10 2/17/10 22:09 105742 190532 1 2/ 9/10 2/18/10 04:42 105742 190532 1 2/ 9/10 2/18/10 04:42 105742 190532 1 2/ 9/10 2/17/10 22:09 105742 190532 1 2/ 9/10 2/17/10 22:09 105742 190532 1 2/ 9/10 2/17/10 22:09 105742 190532 1 2/ 9/10 2/18/10 04:42 105742 190532 1 2/ 9/10 2/18/10 04:42 105742 190532 1 2/ 9/10 2/18/10 04:42 105742 190532 1 2/ 9/10 2/17/10 22:09 105742 190532 1 2/ 9/10 2/17/10 22:09 105742 190532 1 2/ 9/10 2/17/10 22:09 105742 190532 1 2/ 9/10 2/18/10 04:42 105742 190532 1 2/ 9/10 2/17/10 22:09 105742 190532 Surrogate Name Perfluoro-n-[l,2,3,4,5-13C5] nonanoic acid Perfluoro-n-[l,2,3,4-13C4] butanoic acid Perfluoro-n-[l,2,3,4-13C4] octanoic acid Perfluoro-n-[l,2-13C2] decanoic acid Perfluoro-n-[l,2-13C2] hexanoic acid Perfluoro-n-[l,2-13C2]dodecanoic Acid Perfluoro-n-[1,2-13C2]undecanoic Acid Sodium perfluoro-l-[l,2,3,4-13C4] octanesulfonate Sodium perfluoro-1-hexane[1802]sulfonate %Rec 87 86 99 100 89 43 * 54 94 99 Control Limits 50-150 50-150 50-150 50-150 50-150 50-150 50-150 50-150 50-150 Date Analyzed Q 2/17/10 22:09 2/18/10 04:42 2/17/10 22:09 2/17/10 22:09 2/18/10 04:42 2/17/10 22:09 2/17/10 22:09 2/17/10 22:09 2/18/10 04:42 Note Comments: Printed 2/23/10 13:41 \\InHow2\Starlims\LimsReps\AnalyticalReport.ipt Forni 1A 29 SuperSet Reference: 10-0000135143 rev 00 Client: Project: Sample Matrix: Sample Name: Lab Code: Analytical Report Camp Dresser & McKee, Incorporated (CDM) Baron & Budd, P.C./95779-75319 Water Villa "Treated" K1001011-018 p. 34 Service Request: K1001011 Date Collected: 2/ 3/10 1428 Date Received: 2/ 4/10 Units: ng/L Basis: NA Perfluorinated Sulfonic Acids and Perfluorinated Carboxylic Acids by HPLC/MS Analytical Method: PFOA Prep Method: Method Analyte Name Perfluoro-n-tetradecanoic acid Perfluoro-n-tridecanoic acid Perfluorobutanesulfonate Perfluorobutanoic Acid Perfluorodecane Sulfonate Perfluorodecanoic Acid Perfluorododecanoic Acid Perfluoroheptanoic Acid Perfluorohexanesulfonate Perfluorohexanoic Acid Perfluorononanoic Acid Perfluorooctanesulfonate Perfluorooctanoic Acid Perfluoropentanoic Acid Perfluoroundecanoic Acid Result Q ND U ND U 0.43 J 0.52 J 0.41 J ND u ND u 0.45 J 0.99 J 0.87 J 0.38 J 1.8 J 1.6 J 0.84 J ND u MRL 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 MDL 0.46 0.95 0.029 0.11 0.095 0.48 0.85 0.081 0.030 0.11 0.12 0.046 0.066 0.11 1.3 Dilution Date Date Extraction Analysis Factor Extracted Analyzed Lot Lot Note 1 2/ 9/10 2/17/10 22:17 105742 190532 1 2/ 9/10 2/17/10 22:17 105742 190532 1 2/ 9/10 2/18/10 04:51 105742 190532 1 2/ 9/10 2/18/10 04:51 105742 190532 1 2/ 9/10 2/17/10 22:17 105742 190532 1 2/ 9/10 2/17/10 22:17 105742 190532 1 2/ 9/10 2/17/10 22:17 105742 190532 1 2/ 9/10 2/18/10 04:51 105742 190532 1 2/ 9/10 2/18/10 04:51 105742 190532 1 2/ 9/10 2/18/10 04:51 105742 190532 1 2/ 9/10 2/17/10 22:17 105742 190532 1 2/ 9/10 2/17/10 22:17 105742 190532 1 2/ 9/10 2/17/10 22:17 105742 190532 1 2/ 9/10 2/18/10 04:51 105742 190532 1 2/ 9/10 2/17/10 22:17 105742 190532 Surrogate Name Perfluoro-n-[l,2,3,4,5-13C5] nonanoic acid Perfluoro-n-[l,2,3,4-13C4] butanoic acid Perfluoro-n-[l,2,3,4-13C4] octanoic acid Perfluoro-n-[l,2-13C2] decanoicacid Perfluoro-n-[l,2-13C2] hexanoicacid Perfluoro-n-[l,2-13C2]dodecanoic Acid Perfluoro-n-[1,2-13C2]undecanoic Acid Sodium perfluoro-l-[l,2,3,4-13C4] octanesulfonate Sodium perfluoro-1-hexane[1802]sulfonate %Rec 93 103 108 100 102 66 100 102 106 Control Limits 50-150 50-150 50-150 50-150 50-150 50-150 50-150 50-150 50-150 Date Analyzed Q 2/17/10 22:17 2/18/10 04:51 2/17/10 22:17 2/17/10 22:17 2/18/10 04:51 2/17/10 22:17 2/17/10 22:17 2/17/10 22:17 2/18/10 04:51 Note Comments: Printed 2/23/10 13:41 \\Inilow2\Starlims\LimsReps\AmlyticalReport. rpt Form 1A 30 SuperSet Reference: 10-0000135143 rev 00 Client: Project: Sample Matrix: Sample Name: Lab Code: Analytical Report Camp Dresser & McKee, Incorporated (CDM) Baron & Budd, P.C./95779-75319 Water Royce Street "Raw" KI001011-019 p. 35 Service Request: K1001011 Date Collected: 2/ 3/10 1504 Date Received: 2/ 4/10 Units: ng/L Basis: NA Perfluorinated Sulfonic Acids and Perfluorinated Carboxylic Acids by HPLC/MS Analytical Method: PFOA Prep Method: Method Analyte Name Perfluoro-n-tetradecanoic acid Perfluoro-n-tridecanoic acid Perfluorobutanesulfonate Perfluorobutanoic Acid Perfluorodecane Sulfonate Perfluorodecanoic Acid Perfluorododecanoic Acid Perfluoroheptanoic Acid Perfluorohexanesulfonate Perfluorohexanoic Acid Perfluorononanoic Acid Perfluorooctanesulfonate Perfluorooctanoic Acid Perfluoropentanoic Acid Perfluoroundecanoic Acid Result Q ND U ND U 0.72 J 0.35 J 0.13 J ND U ND U 1.1 J 1.9 J 1.5 J 0.32 J 2.0 J 24 1.1 J ND u MRL 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 MDL 0.46 0.95 0.029 0.11 0.095 0.48 0.85 0.081 0.030 0.11 0.12 0.046 0.066 0.11 1.3 Dilution Date Date Extraction Analysis Factor Extracted Analyzed Lot Lot Note 1 2/ 9/10 2/17/10 22:24 105742 190532 1 2/ 9/10 2/17/10 22:24 105742 190532 1 2/ 9/10 2/18/10 05:01 105742 190532 1 2/ 9/10 2/18/10 05:01 105742 190532 1 2/ 9/10 2/17/10 22:24 105742 190532 1 2/ 9/10 2/17/10 22:24 105742 190532 1 2/ 9/10 2/17/10 22:24 105742 190532 1 2/ 9/10 2/18/10 05:01 105742 190532 1 2/ 9/10 2/18/10 05:01 105742 190532 1 2/ 9/10 2/18/10 05:01 105742 190532 1 2/ 9/10 2/17/10 22:24 105742 190532 1 2/ 9/10 2/17/10 22:24 105742 190532 1 2/ 9/10 2/17/10 22:24 105742 190532 1 2/ 9/10 2/18/10 05:01 105742 190532 1 2/ 9/10 2/17/10 22:24 105742 190532 Surrogate Name Perfluoro-n-[l,2,3,4,5-13C5] nonanoic acid Perfluoro-n-[l,2,3,4-13C4] butanoic acid Perfluoro-n-[l,2,3,4-13C4] octanoic acid Perfluoro-n-[l,2-13C2] decanoicacid Perfluoro-n-[l,2-13C2] hexanoicacid Perfluoro-n-[1,2-13C2]dodecanoic Acid Perfluoro-n-[1,2-13C2]undecanoic Acid Sodium perfluoro-l-[l,2,3,4-13C4] octanesulfonate Sodium perfluoro-1-hexane[1802]sulfonate %Rec 103 100 112 100 106 58 65 116 134 Control Limits 50-150 50-150 50-150 50-150 50-150 50-150 50-150 50-150 50-150 Date Analyzed Q 2/17/10 22:24 2/18/10 05:01 2/17/10 22:24 2/17/10 22:24 2/18/10 05:01 2/17/10 22:24 2/17/10 22:24 2/17/10 22:24 2/18/10 05:01 Note Comments: Printed 2/23/10 13:41 \\Inflow2\StarlimsVLiimReps\AnalyticalReport.rpt Form 1A 31 SuperSet Reference: 10-0000135143 revOO Client: Project: Sample Matrix: Sample Name: Lab Code: Analytical Report Camp Dresser & McKee, Incorporated (CDM) Baron & Budd, P.C./95779-75319 Water Royce Street "Treated" K1001011-020 p. 36 Service Request: K1001011 Date Collected: 2/3/10 1516 Date Received: 2/ 4/10 Units: ng/L Basis: NA Perfluorinated Sulfonic Acids and Perfluorinated Carboxylic Acids by HPLC/MS Analytical Method: PFOA Prep Method: Method Analyte Name Perfluoro-n-tetradecanoic acid Perfluoro-n-tridecanoic acid Perfluorobutanesulfonate Perfluorobutanoic Acid Perfluorodecane Sulfonate Perfluorodecanoic Acid Perfluorododecanoic Acid Perfluoroheptanoic Acid Perfluorohexanesulfonate Perfluorohexanoic Acid Perfluorononanoic Acid Perfluorooctanesulfonate Perfluorooctanoic Acid Perfluoropentanoic Acid Perfluoroundecanoic Acid Result Q ND U ND U 0.81 J 0.51 J 0.12 J ND U ND U 1.2 J 2.1 J 1.7 J 0.47 J 2.2 J 24 1.1 J ND U MRL 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 MDL 0.46 0.95 0.029 0.11 0.095 0.48 0.85 0.081 0.030 0.11 0.12 0.046 0.066 0.11 1.3 Dilution Date Date Extraction Analysis Factor Extracted Analyzed Lot Lot Note 1 2/ 9/10 2/17/10 22:32 105742 190532 1 2/ 9/10 2/17/10 22:32 105742 190532 1 2/ 9/10 2/18/10 05:10 105742 190532 1 2/ 9/10 2/18/10 05:10 105742 190532 1 2/ 9/10 2/17/10 22:32 105742 190532 1 2/ 9/10 2/17/10 22:32 105742 190532 1 2/ 9/10 2/17/10 22:32 105742 190532 1 2/ 9/10 2/18/10 05:10 105742 190532 1 2/ 9/10 2/18/10 05:10 105742 190532 1 2/ 9/10 2/18/10 05:10 105742 190532 1 2/ 9/10 2/17/10 22:32 105742 190532 1 2/ 9/10 2/17/10 22:32 105742 190532 1 2/ 9/10 2/17/10 22:32 105742 190532 1 2/ 9/10 2/18/10 05:10 105742 190532 1 2/ 9/10 2/17/10 22:32 105742 190532 Surrogate Name Perfluoro-n-[l,2,3,4,5-13C5] nonanoic acid Perfluoro-n-[l,2,3,4-13C4] butanoic acid Perfluoro-n-[l,2,3,4-13C4] octanoic acid Perfluoro-n-[l,2-13C2] decanoic acid Perfluoro-n-[l,2-13C2] hexanoicacid Perfluoro-n-[1,2-13C2]dodecanoic Acid Perfluoro-n-[1,2-13C2]undecanoic Acid Sodium perfluoro-l-[l,2,3,4-13C4] octanesulfonate Sodium perfluoro-l-hexane[1802]sulfonate %Rec 91 85 108 100 89 47 * 48 * 97 102 Control Limits 50-150 50-150 50-150 50-150 50-150 50-150 50-150 50-150 50-150 Date Analyzed Q 2/17/10 22:32 2/18/10 05:10 2/17/10 22:32 2/17/10 22:32 2/18/10 05:10 2/17/10 22:32 2/17/10 22:32 2/17/10 22:32 2/18/10 05:10 Note Comments: Printed 2/23/10 13:41 \\Inflow2\Starlims\LimsReps\AnaiyticalReportrpt Form 1A SuperSet Reference: 10-0000135143 rev 00 Client: Project: Sample Matrix: Sample Name: Lab Code: Analytical Report Camp Dresser & McKee, Incorporated (CDM) Baron & Budd, P.C./95779-75319 Water Method Blank KQ1000664-06 p. 37 Service Request: K1001011 Date Collected: NA Date Received: NA Units: ng/L Basis: NA Perfluorinated Sulfonic Acids and Perfluorinated Carboxylic Acids by HPLC/MS Analytical Method: PFOA Prep Method: Method Analyte Name Perfluoro-n-tetradecanoic acid Perfluoro-n-tridecanoic acid Perfluorobutanesulfonate Perfluorobutanoic Acid Perfluorodecane Sulfonate Perfluorodecanoic Acid Perfluorododecanoic Acid Perfluoroheptanoic Acid Perfluorohexanesulfonate Perfluorohexanoic Acid Perfluorononanoic Acid Perfluorooctanesulfonate Perfluorooctanoic Acid Perfluoropentanoic Acid Perfluoroundecanoic Acid Result Q ND U ND U 0.12 J 0.15 J 0.14 J ND u ND u ND u 0.11 J ND u ND u 0.59 J 0.21 J ND u ND u MRL 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 MDL 0.46 0.95 0.029 0.11 0.095 0.48 0.85 0.081 0.030 0.11 0.12 0.046 0.066 0.11 1.3 Dilution Date Date Extraction Analysis Factor Extracted Analyzed Lot Lot Note 1 2/ 9/10 2/17/10 23:17 105742 190532 1 2/ 9/10 2/17/10 23:17 105742 190532 1 2/ 9/10 2/18/10 06:08 105742 190532 1 2/ 9/10 2/18/10 06:08 105742 190532 1 2/ 9/10 2/17/10 23:17 105742 190532 1 2/ 9/10 2/17/10 23:17 105742 190532 1 2/ 9/10 2/17/10 23:17 105742 190532 1 2/ 9/10 2/18/10 06:08 105742 190532 1 2/ 9/10 2/18/10 06:08 105742 190532 1 2/ 9/10 2/18/10 06:08 105742 190532 1 2/ 9/10 2/17/10 23:17 105742 190532 1 2/ 9/10 2/17/10 23:17 105742 190532 1 2/ 9/10 2/17/10 23:17 105742 190532 1 2/ 9/10 2/18/10 06:08 105742 190532 1 2/ 9/10 2/17/10 23:17 105742 190532 Surrogate Name Perfluoro-n-[l,2,3,4,5-13C5] nonanoic acid Perfluoro-n-[l,2,3,4-13C4] butanoic acid Perfluoro-n-[l,2,3,4-13C4] octanoic acid Perfluoro-n-[l,2-13C2] decanoic acid Perfluoro-n-[l,2-13C2] hexanoicacid Perfluoro-n-[l,2-13C2]dodecanoic Acid Perfluoro-n-[l,2-13C2]undecanoic Acid Sodiumperfluoro-l-[l,2,3,4-13C4] octanesulfonate Sodium perfluoro-l-hexane[1802]sulfonate %Rec 90 107 117 100 105 61 52 105 107 Control Limits 50-150 50-150 50-150 50-150 50-150 50-150 50-150 50-150 50-150 Date Analyzed Q 2/17/10 23:17 2/18/10 06:08 2/17/10 23:17 2/17/10 23:17 2/18/10 06:08 2/17/10 23:17 2/17/10 23:17 2/17/10 23:17 2/18/10 06:08 Note Comments: Printed 2/23/10 13:41 \\Inflow2\Starlims\LimsReps\AnaIytica!Report.rpt Form 1A 33 SuperSet Reference: 10-0000135143 rev 00 Client: Project: Sample Matrix: Sample Name: Lab Code: Analytical Report Camp Dresser & McKee, Incorporated (CDM) Baron & Budd, P.C./95779-75319 Water Lab Control Sample KQ1000664-05 p. 38 Service Request: K1001011 Date Collected: NA Date Received: NA Units: ng/L Basis: NA Perfluorinated Sulfonic Acids and Perfluorinated Carboxylic Acids by HPLC/MS Analytical Method: PFOA Prep Method: Method Analyte Name Perfluoro-n-tetradecanoic acid Perfluoro-n-tridecanoic acid Perfluorobutanesulfonate Perfluorobutanoic Acid Perfluorodecane Sulfonate Perfluorodecanoic Acid Perfluorododecanoic Acid Perfluoroheptanoic Acid Perfluorohexanesulfonate Perfluorohexanoic Acid Perfluorononanoic Acid Perfluorooctanesulfonate Perfluorooctanoic Acid Perfluoropentanoic Acid Perfluoroundecanoic Acid Result Q 122 92.0 76.0 90.0 55.0 90.5 110 102 81.5 96.0 92.5 89.0 82.5 95.5 123 MRL 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 MDL 0.46 0.95 0.029 0.11 0.095 0.48 0.85 0.081 0.030 0.11 0.12 0.046 0.066 0.11 1.3 Dilution Date Date Extraction Analysis Factor Extracted Analyzed Lot Lot Note 1 2/ 9/10 2/17/10 23:10 105742 190532 1 2/ 9/10 2/17/10 23:10 105742 190532 1 2/ 9/10 2/18/10 05:58 105742 190532 1 2/ 9/10 2/18/10 05:58 105742 190532 1 2/ 9/10 2/17/10 23:10 105742 190532 1 219/10 2/17/10 23:10 105742 190532 1 2/ 9/10 2/17/10 23:10 105742 190532 1 2/ 9/10 2/18/10 05:58 105742 190532 1 2/ 9/10 2/18/10 05:58 105742 190532 1 2/ 9/10 2/18/10 05:58 105742 190532 1 2/ 9/10 2/17/10 23:10 105742 190532 1 2/ 9/10 2/17/10 23:10 105742 190532 1 2/ 9/10 2/17/10 23:10 105742 190532 1 2/ 9/10 2/18/10 05:58 105742 190532 1 2/ 9/10 2/17/10 23:10 105742 190532 Surrogate Name Perfluoro-n-[l,2,3,4,5-13C5] nonanoic acid Perfluoro-n-[l,2,3,4-13C4] butanoic acid Perfluoro-n-[l,2,3,4-13C4] octanoic acid Perfluoro-n-[l,2-13C2] decanoic acid Perfluoro-n-[l,2-13C2] hexanoicacid Perfluoro-n-[1,2-13C2]dodecanoic Acid Perfluoro-n-[l,2-13C2]undecanoic Acid Sodium perfluoro-l-[l,2,3,4-13C4] octanesulfonate Sodium perfluoro-1-hexane[1802]sulfonate %Rec 98 98 107 100 93 63 47 * 109 100 Control Limits 50-150 50-150 50-150 50-150 50-150 50-150 50-150 50-150 50-150 Date Analyzed Q 2/17/10 23:10 2/18/10 05:58 2/17/10 23:10 2/17/10 23:10 2/18/10 05:58 2/17/10 23:10 2/17/10 23:10 2/17/10 23:10 2/18/10 05:58 Note Comments: Printed 2/23/10 13:41 \\Inflow2\Starlims\LimsReps\AnaiyticalReportrpt Form 1A 34 SupcrSet Reference: 10-0000135143 rev 00 Client: Project: Sample Matrix: Sample Name: Lab Code: Run Type: Analytical Report Camp Dresser & McKee, Incorporated (CDM) Baron & Budd, P.C./95779-75319 Water McAllister "Treated" KQ1000664-01 Matrix Spike p. 39 Service Request: K1001011 Date Collected: 2/3/10 1002 Date Received: 2/ 4/10 Units: ng/L Basis: NA Perfluorinated Sulfonic Acids and Perfluorinated Carboxylic Acids by HPLC/MS Analytical Method: PFOA Prep Method: Method Analyte Name Perfluoro-n-tetradecanoic acid Perfluoro-n-tridecanoic acid Perfluorobutanesulfonate Perfluorobutanoic Acid Perfluorodecane Sulfonate Perfluorodecanoic Acid Perfluorododecanoic Acid Perfluoroheptanoic Acid Perfluorohexanesulfonate Perfluorohexanoic Acid Perfluorononanoic Acid Perfluorooctanesulfonate Perfluorooctanoic Acid Perfluoropentanoic Acid Perfluoroundecanoic Acid Result Q 91.5 86.0 85.0 101 55.0 104 96.5 105 86.5 103 105 93.5 93.5 99.5 130 MRL 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 MDL 0.46 0.95 0.029 0.11 0.095 0.48 0.85 0.081 0.030 0.11 0.12 0.046 0.066 0.11 1.3 Dilution Date Date Extraction Analysis Factor Extracted Analyzed Lot Lot Note 1 2/ 9/10 2/17/10 22:39 105742 190532 1 2/ 9/10 2/17/10 22:39 105742 190532 1 2/ 9/10 2/18/10 05:20 105742 190532 1 2/ 9/10 2/18/10 05:20 105742 190532 1 2/ 9/10 2/17/10 22:39 105742 190532 1 2/ 9/10 2/17/10 22:39 105742 190532 1 2/ 9/10 2/17/10 22:39 105742 190532 1 2/ 9/10 2/18/10 05:20 105742 190532 1 2/ 9/10 2/18/10 05:20 105742 190532 1 2/ 9/10 2/18/10 05:20 105742 190532 1 2/ 9/10 2/17/10 22:39 105742 190532 1 2/ 9/10 2/17/10 22:39 105742 190532 1 2/ 9/10 2/17/10 22:39 105742 190532 1 2/ 9/10 2/18/10 05:20 105742 190532 1 2/ 9/10 2/17/10 22:39 105742 190532 Surrogate Name Perfluoro-n-[l,2,3,4,5-13C5] nonanoic acid Perfluoro-n-[l,2,3,4-13C4] butanoic acid Perfluoro-n-[l,2,3,4-13C4] octanoic acid Perfluoro-n-[l,2-13C2] decanoic acid Perfluoro-n-[l,2-13C2] hexanoicacid Perfluoro-n-[l,2-13C2]dodecanoic Acid Perfluoro-n-[1,2-13C2]undecanoic Acid Sodium perfluoro-l-[l,2,3,4-13C4] octanesulfonate Sodium perfluoro-1-hexane[1802]sulfonate %Rec 113 104 135 100 105 60 73 119 113 Control Limits 50-150 50-150 50-150 50-150 50-150 50-150 50-150 50-150 50-150 Date Analyzed Q 2/17/10 22:39 2/18/10 05:20 2/17/10 22:39 2/17/10 22:39 2/18/10 05:20 2/17/10 22:39 2/17/10 22:39 2/17/10 22:39 2/18/10 05:20 Note Comments: Printed 2/23/10 13:41 Wlnflow2\Starlims\LinBReps\AnalyticalReport.rpt Forni 1A 35 SuperSet Reference: 10-0000135143 rev 00 Client: Project: Sample Matrix: Sample Name: Lab Code: Run Type: Analytical Report Camp Dresser & McKee, Incorporated (CDM) Baron & Budd, P.C./95779-75319 Water McAllister "Raw" KQ1000664-03 Matrix Spike p. 40 Service Request: K1001011 Date Collected: 2/ 3/10 0949 Date Received: 2/ 4/10 Units: ng/L Basis: NA Perfluorinated Sulfonic Acids and Perfluorinated Carboxylic Acids by HPLC/MS Analytical Method: PFOA Prep Method: Method Analyte Name Perfluoro-n-tetradecanoic acid Perfluoro-n-tridecanoic acid Perfluorobutanesulfonate Perfluorobutanoic Acid Perfluorodecane Sulfonate Perfluorodecanoic Acid Perfluorododecanoic Acid Perfluoroheptanoic Acid Perfluorohexanesulfonate Perfluorohexanoic Acid Perfluorononanoic Acid Perfluorooctanesulfonate Perfluorooctanoic Acid Perfluoropentanoic Acid Perfluoroundecanoic Acid Result Q 101 100 91.5 96.5 48.5 89.5 103 125 130 122 209 232 122 110 120 MRL 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 MDL 0.46 0.95 0.029 0.11 0.095 0.48 0.85 0.081 0.030 0.11 0.12 0.046 0.066 0.11 1.3 Dilution Date Date Extraction Analysis Factor Extracted Analyzed Lot Lot Note 1 2/ 9/10 2/17/10 22:54 105742 190532 1 2/ 9/10 2/17/10 22:54 105742 190532 1 2/ 9/10 2/18/10 05:39 105742 190532 1 2/ 9/10 2/18/10 05:39 105742 190532 1 2/ 9/10 2/17/10 22:54 105742 190532 1 2/ 9/10 2/17/10 22:54 105742 190532 1 2/ 9/10 2/17/10 22:54 105742 190532 1 2/ 9/10 2/18/10 05:39 105742 190532 1 2/ 9/10 2/18/10 05:39 105742 190532 1 2/ 9/10 2/18/10 05:39 105742 190532 1 2/ 9/10 2/17/10 22:54 105742 190532 1 2/ 9/10 2/17/10 22:54 105742 190532 1 2/ 9/10 2/17/10 22:54 105742 190532 1 2/ 9/10 2/18/10 05:39 105742 190532 1 2/ 9/10 2/17/10 22:54 105742 190532 Surrogate Name Perfluoro-n-fl^^AS-lSCS] nonanoic acid Perfluoro-n-[l,2,3,4-13C4] butanoic acid Perfluoro-n-[l,2,3,4-13C4] octanoic acid Perfluoro-n-[l,2-13C2] decanoicacid Perfluoro-n-[l,2-13C2] hexanoicacid Perfluoro-n-[1,2-13C2]dodecanoic Acid Perfluoro-n-[1,2-13C2]undecanoic Acid Sodium perfluoro-l-[l,2,3,4-13C4] octanesulfonate Sodium perfluoro-1-hexane[1802]sulfonate %Rec 103 99 116 100 93 57 51 113 107 Control Limits 50-150 50-150 50-150 50-150 50-150 50-150 50-150 50-150 50-150 Date Analyzed Q 2/17/10 22:54 2/18/10 05:39 2/17/10 22:54 2/17/10 22:54 2/18/10 05:39 2/17/10 22:54 2/17/10 22:54 2/17/10 22:54 2/18/10 05:39 Note Comments: Printed 2/23/10 13:41 \\Inilow2\Starlims\LimsReps\AnalyticalReport.ipt Form 1A 36 SuperSet Reference: 10-0000135143 rev 00 Client: Project: Sample Matrix: Sample Name: Lab Code: Run Type: Analytical Report Camp Dresser & McKee, Incorporated (CDM) Baron & Budd, P.C./95779-75319 Water McAllister "Treated" KQ1000664-02 Duplicate Matrix Spike p. 41 Service Request: K 10010II Date Collected: 2/ 3/10 1002 Date Received: 2/4/10 Units: ng/L Basis: NA Perfluorinated Sulfonic Acids and Perfluorinated Carboxylic Acids by HPLC/MS Analytical Method: PFOA Prep Method: Method Analyte Name Perfluoro-n-tetradecanoic acid Perfluoro-n-tridecanoic acid Perfluorobutanesulfonate Perfluorobutanoic Acid Perfluorodecane Sulfonate Perfluorodecanoic Acid Perfluorododecanoic Acid Perfluoroheptanoic Acid Perfluorohexanesulfonate Perfluorohexanoic Acid Perfluorononanoic Acid Perfluorooctanesulfonate Perfluorooctanoic Acid Perfluoropentanoic Acid Perfluoroundecanoic Acid Result Q 107 102 88.5 102 56.0 99.0 85.0 108 89.5 103 102 95.0 96.0 101 142 MRL 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 MDL 0.46 0.95 0.029 0.11 0.095 0.48 0.85 0.081 0.030 0.11 0.12 0.046 0.066 0.11 1.3 Dilution Date Date Extraction Analysis Factor Extracted Analyzed Lot Lot Note 1 2/ 9/10 2/17/10 22:47 105742 190532 1 2/ 9/10 2/17/10 22:47 105742 190532 1 2/ 9/10 2/18/10 05:29 105742 190532 1 2/ 9/10 2/18/10 05:29 105742 190532 1 2/ 9/10 2/17/10 22:47 105742 190532 1 2/ 9/10 2/17/10 22:47 105742 190532 1 2/ 9/10 2/17/10 22:47 105742 190532 1 2/ 9/10 2/18/10 05:29 105742 190532 1 2/ 9/10 2/18/10 05:29 105742 190532 1 2/ 9/10 2/18/10 05:29 105742 190532 1 2/ 9/10 2/17/10 22:47 105742 190532 1 2/ 9/10 2/17/10 22:47 105742 190532 1 2/ 9/10 2/17/10 22:47 105742 190532 1 2/ 9/10 2/18/10 05:29 105742 190532 1 2/ 9/10 2/17/10 22:47 105742 190532 Surrogate Name Perfluoro-n-[l,2,3,4,5-13C5] nonanoic acid Perfluoro-n-[l,2,3,4-13C4] butanoic acid Perfluoro-n-[l,2,3,4-13C4] octanoic acid PerfIuoro-n-[l,2-13C2] decanoic acid Perfluoro-n-[l,2-13C2] hexanoic acid Perfluoro-n-[1,2-13C2]dodecanoic Acid Perfluoro-n-[1,2-13C2]undecanoic Acid Sodium perfluoro-l-[l,2,3,4-13C4] octanesulfonate Sodium perfluoro-1-hexane[1802]sulfonate %Rec 104 106 122 100 107 55 62 111 111 Control Limits 50-150 50-150 50-150 50-150 50-150 50-150 50-150 50-150 50-150 Date Analyzed Q 2/17/10 22:47 2/18/10 05:29 2/17/10 22:47 2/17/10 22:47 2/18/10 05:29 2/17/10 22:47 2/17/10 22:47 2/17/10 22:47 2/18/10 05:29 Note Comments: Printed 2/23/10 13:41 \\Inflow2\Starlims\LimsReps\AnalyticalReport.rpt Form 1A 37 SuperSet Reference: 10-0000135143 rev 00 Client: Project: Sample Matrix: Sample Name: Lab Code: Run Type: Analytical Report Camp Dresser & McKee, Incorporated (CDM) Baron &Budd, P.C./95779-75319 Water McAllister "Raw" KQ1000664-04 Duplicate Matrix Spike p. 42 Service Request: K1001011 Date Collected: 2/ 3/10 0949 Date Received: 2/ 4/10 Units: ng/L Basis: NA Perfluorinated Sulfonic Acids and Perfluorinated Carboxylic Acids by HPLC/MS Analytical Method: PFOA Prep Method: Method Analyte Name Perfluoro-n-tetradecanoic acid Perfluoro-n-tridecanoic acid Perfluorobutanesulfonate Perfluorobutanoic Acid Perfluorodecane Sulfonate Perfluorodecanoic Acid Perfluorododecanoic Acid Perfluoroheptanoic Acid Perfluorohexanesulfonate Perfluorohexanoic Acid Perfluorononanoic Acid Perfluorooctanesulfonate Perfluorooctanoic Acid Perfluoropentanoic Acid Perfluoroundecanoic Acid Result Q 89.5 79.5 93.0 98.0 47.9 89.0 85.5 114 140 120 225 233 133 103 115 MRL 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 MDL 0.46 0.95 0.029 0.11 0.095 0.48 0.85 0.081 0.030 0.11 0.12 0.046 0.066 0.11 1.3 Dilution Date Date Extraction Analysis Factor Extracted Analyzed Lot Lot Note 1 2/ 9/10 2/17/10 23:02 105742 190532 1 2/ 9/10 2/17/10 23:02 105742 190532 1 2/ 9/10 2/18/10 05:49 105742 190532 1 2/ 9/10 2/18/10 05:49 105742 190532 1 2/ 9/10 2/17/10 23:02 105742 190532 1 2/ 9/10 2/17/10 23:02 105742 190532 1 2/ 9/10 2/17/10 23:02 105742 190532 1 2/ 9/10 2/18/10 05:49 105742 190532 1 2/ 9/10 2/18/10 05:49 105742 190532 1 2/ 9/10 2/18/10 05:49 105742 190532 1 2/ 9/10 2/17/10 23:02 105742 190532 1 2/ 9/10 2/17/10 23:02 105742 190532 1 2/ 9/10 2/17/10 23:02 105742 190532 1 2/ 9/10 2/18/10 05:49 105742 190532 1 2/ 9/10 2/17/10 23:02 105742 190532 Surrogate Name Perfluoro-n-[l,2,3,4,5-13C5] nonanoic acid Perfluoro-n-[l,2,3,4-13C4] butanoic acid Perfluoro-n-[l,2,3,4-13C4] octanoic acid Perfluoro-n-[l,2-13C2] decanoic acid Perfluoro-n-[1,2-13C2] hexanoic acid Perfluoro-n-[1,2-13C2]dodecanoic Acid Perfluoro-n-[1,2-13C2]undecanoic Acid Sodium perfluoro-l-[l,2,3,4-13C4] octanesulfonate Sodium perfluoro-1-hexane[1802] sulfonate %Rec 97 94 110 100 97 58 64 114 106 Control Limits 50-150 50-150 50-150 50-150 50-150 50-150 50-150 50-150 50-150 Date Analyzed Q 2/17/10 23:02 2/18/10 05:49 2/17/10 23:02 2/17/10 23:02 2/18/10 05:49 2/17/10 23:02 2/17/10 23:02 2/17/10 23:02 2/18/10 05:49 Note Comments: Printed 2/23/10 13:41 \\Inflow2\Starlims\LimsReps\AnalyticalReport.rpt Form 1A 38 SupcrSet Reference: 10-0000135143 rev 00 Client: Project: Sample Matrix: QA/QC Report p. 43 Camp Dresser & McKee, Incorporated (CDM) Baron & Budd, P.C./95779-75319 Water Service Request: K1001011 Date Collected: 2/3/10 Date Received: 2/4/10 Date Analyzed: 2/17/10 2/18/10 Matrix Spike Summary Perfluorinated Sulfonic Acids and Perfluorinated Carboxylic Acids by HPLC/MS Sample Name: Lab Code: McAllister "Raw" K1001011-007 Units: ng/L Basis: NA Analytical Method: PFOA Prep Method: Method Analyte Name Perfluoro-n-tetradecanoic acid Perfluoro-n-tridecanoic acid Perfluorobutanesulfonate Perfluorobutanoic Acid Perfluorodecane Sulfonate Perfluorodecanoic Acid Perfluorododecanoic Acid Perfluoroheptanoic Acid Perfluorohexanesulfonate Perfluorohexanoic Acid Perfluorononanoic Acid Perfluorooctanesulfonate Perfluorooctanoic Acid Perfluoropentanoic Acid Perfluoroundecanoic Acid Sample Result ND ND 5.8 5.0 0.13 0.83 ND 16 55 26 140 150 38 13 3.1 Matrix Spike KQ1000664-03 Result Amount % Ree Duplicate Matrix Spike KQ1000664-04 Result Amount % Ree % Ree RPD Limits RPD Limit 101 100 101 89.5 100 90 50 - 150 12 30 100 100 100 79.5 100 80 50 - 150 23 30 91.5 100 86 93.0 100 87 50 -150 2 30 96.5 100 92 98.0 100 93 50 -150 2 30 48.5 100 48 * 47.9 100 48 * 50 -150 1 30 89.5 100 89 89.0 100 88 50 -150 1 30 103 100 103 85.5 100 86 50 - 150 19 30 125 100 109 114 100 98 50 -150 10 30 130 100 75 140 100 85 50 - 150 7 30 122 100 96 120 100 94 50 - 150 2 30 209 100 73 225 100 89 50 -150 7 30 232 100 79 233 100 80 50 - 150 0 30 122 100 83 133 100 94 50 -150 9 30 110 100 97 103 100 90 50 - 150 6 30 120 100 117 115 100 111 50 - 150 5 30 Comments: Printed 2/23/10 13:41 \\Inflow2\Starlims\LimsReps\MatrixSpike.rpt Matrix Spike Summary 39 SuperSet Reference: 10-0000135143 rev 00 Client: Project: Sample Matrix: QA/QC Report p. 44 Camp Dresser & McKee, Incorporated (CDM) Baron & Budd, P.C./95779-75319 Water Service Request: K1001011 Date Collected: 2/3/10 Date Received: 2/4/10 Date Analyzed: 2/17/10 - 2/18/10 Matrix Spike Summary Perfluorinated Sulfonic Acids and Perfluorinated Carboxylic Acids by HPLC/MS Sample Name: Lab Code: McAllister "Treated" K1001011-008 Units: ng/L Basis: NA Analytical Method: PFOA Prep Method: Method Analyte Name Perfluoro-n-tetradecanoic acid Perfluoro-n-tridecanoic acid Perfluorobutanesulfonate Perfluorobutanoic Acid Perfluorodecane Sulfonate Perfluorodecanoic Acid Perfluorododecanoic Acid Perfluoroheptanoic Acid Perfluorohexanesulfonate Perfluorohexanoic Acid Perfluorononanoic Acid Perfluorooctanesulfonate Perfluorooctanoic Acid Perfluoropentanoic Acid Perfluoroundecanoic Acid Sample Result ND ND 0.29 6.7 0.57 0.62 1.3 0.32 0.30 0.95 0.56 0.77 0.45 3.3 1.9 Matrix Spike KQ1000664-01 Result Amount % Ree 91.5 100 92 86.0 100 86 85.0 100 85 101 100 94 55.0 100 54 104 100 103 96.5 100 95 105 100 104 86.5 100 86 103 100 102 105 100 104 93.5 100 93 93.5 100 93 99.5 100 96 130 100 128 Duplicate Matrix Spike KQ1000664-02 Result Amount % Ree 107 100 107 102 100 102 88.5 100 88 102 100 95 56.0 100 55 99.0 100 98 85.0 100 84 108 100 107 89.5 100 89 103 100 102 102 100 101 95.0 100 94 96.0 100 96 101 100 98 142 100 140 % Ree RPD Limits RPD Limit 50 - 150 50 - 150 50 -150 50 - 150 50 -150 50 -150 50 - 150 50 - 150 50 -150 50 - 150 50 - 150 50 -150 50 - 150 50 -150 50 - 150 15 17 4 1 2 4 13 3 3 0 2 2 3 1 9 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 Comments: Printed 2/23/10 13:41 \\Inflow2\Starlims\LimsReps\MatrixSpike.rpt Matrix Spike Summary 40 Superset Reference: 10-0000135143 rev 00 Client: Project: Sample Matrix: QA/QC Report p. 45 Camp Dresser & McKee, Incorporated (CDM) Baron & Budd, P.C./95779-75319 Water Service Request: KI00101I Date Analyzed: 2/17/10 - 2/18/10 Lab Control Sample Summary Perfluorinated Sulfonic Acids and Perfluorinated Carboxylic Acids by HPLC/MS Analytical Method: PFOA Prep Method: Method Units: ng/L Basis: NA Extraction Lot: 105742 Analyte Name Perfluoro-n-tetradecanoic acid Perfluoro-n-tridecanoic acid Perfluorobutanesulfonate Perfluorobutanoic Acid Perfluorodecane Sulfonate Perfluorodecanoic Acid Perfluorododecanoic Acid Perfluoroheptanoic Acid Perfluorohexanesulfonate Perfluorohexanoic Acid Perfluorononanoic Acid Perfluorooctanesulfonate Perfluorooctanoic Acid Perfluoropentanoic Acid Perfluoroundecanoic Acid Lab Control Sample KQ1000664-05 Result Expected % Rec 122 100 122 92.0 100 92 76.0 100 76 90.0 100 90 55.0 100 55 90.5 100 91 110 100 110 102 100 102 81.5 100 82 96.0 100 96 92.5 100 93 89.0 100 89 82.5 100 83 95.5 100 96 123 100 123 % Rec Limits 50 - 150 50 -150 50 - 150 50 - 150 50 - 150 50 - 150 50 - 150 50 - 150 50 -150 50 - 150 50 - 150 50 -150 50 - 150 50 - 150 50 - 150 Comments: Printed 2/23/10 13:41 \\Inflow2\Starlims\LimsReps\LabControlSample.ipt Lab Control Sample Summary 41 Superset Reference: 10-0000135143 rev 00 p. 46 Created with Analyst Reporter Printed: 18/02/2010 3:24:00 PM Project Data File Result Table Instrument Name Ewan's Projects\PFCs 021710\SamplesLong.wiff 021710long.rdb API 5000 Sample Name Acquisition Date Acquisition Method Injection Vial K1001011-001 2/17/2010 8:08:37 PM PFCkinetexLong.dam 25 Injection Volume Sample Type Dilution Factor Weight to Volume 5 Unknown 1.00 0.00 Results Summary Analyte Peak Name IS Name PFOA 1 13C-PFOA PFNA 1 13C-PFNA PFOS 1 13C-PFOS PFDA 1 13C-PFDA PFUnA 1 13C-PFUnA PFDS 1 13C-PFOS PFDoA 1 13C-PFDOA PFTrA 1 13C-PFDOA PFTeA 1 13C-PFD0A IS Area 4565100 3052300 8397900 3217400 155240 8397900 206180 206180 206180 Analyte RT (Exp RT ) 1.24 (1.36) 2.07 (2.06) 2.07 (2.09) 3.08 (3.06) 3.87 (4.06) 3.89 (3.87) 4.53 (4.55) 5.19 (5.06) 5.59 (5.51) Analyte Area 1782800 Calc. Cone (ng/mL) 7.720 469780 1.450 39358000 43.800 72676 0.211 19744 0.090 16581 0.037 TffiW-i-r------ ^ 'UTJ94> fJb 4624 N/A 4916 N/A Modified? No No No No No No No No No S' 4- II g ( & Page 50 of 170 42 p. 47 Created with Analyst Reporter Printed: 18/02/2010 3:24:00 PM IRC Summary Analyte Peak Name PFOA2 S_13C_PFOA PFNA2 S_13C_PFNA PFOS 2 SJ3C-PFOS PFDA2 S_13C-PFDA PFUnA2 S_13C-PFUnA PFDS 2 PFDoA2 S_13C-PFDoA PFTrA 2 PFTeA2 RT (Exp RT ) 1.23 (1.36) 1.25(1.36) 2.01 (2.08) 0.00 (2.44) 2.08 (2.12) 2.09 (2.00) 3.05(3.06) 3.10(3.04) 3.89 (3.88) 3.88 (3.88) 3.88(3.87) 0.00 (4.53) 4.53 (4.64) 5.05(5.13) 5.54(5.56) Area 3760400 4565100 151510 0 13116000 8397900 10291 3217400 4997 155240 4672 0 206180 856 762 Modified? Calc (Exp) MRM Ratio No 2.11 (2.16) Ratio Confirms IO YES No 2.56 (43.19) No No 0.32(0.34) YES No 0.00(0.00) No No 0.33(0.32) YES No 0.21 (21.71) No No 0.14(0.14) YES No 44.27(17.53) No No 0.25(0.19) No No 7.86(1.60) No No 0.28(0.32) YES No 0.00 (0.28) No No 19.12(3.71) No No 0.19(0.34) No No 0.15(0.29) No Page 51 of 170 43 iumbia p. 48 Created with Analyst Reporter Printed: 18/02/2010 3:24:00 PM Quantitative Peak Review PFOA 1 413.0/169.0 Da Baseline Missed n Wrnnn Peak 1 13C-PFOA 417.0/372.0 Da Baseline c Missed n Wrnnn Peak ; 2.09 PFOS 1 499.0/80.0 Da d Baseline c Missed r Wronn Peak 3,87 1 PFUnA 1 563.0/519.0 Da o Baseline Missed Pnnk___ 13C-PFOS 503.0/80.0 Da Baseline o Missed n Wrnnn Peak 13C-PFUnA 565.0/270.0 Da Baseline Missed __ n Wrnnn Peak___ K1001011-001 I PFNA 1 463.0/419.0 Da Baseline u Missed n Wrnnn Peak I 13C-PFNA 468.0/423.0 Da Baseline Missed ____ n Wrnnn Peak___ I 3.10 PFDA 1 513.0/469.0 Da Baseline Missed n Wrnnn Peak 13C-PFDA 515.0/470.0 Da Baseline o Missed r Wrnnn Peak 3,89 PFDS 1 599.0/80.0 Da Baseline Missed n Wrnnn Peak___ 13C-PFOS 503.0/80.0 Da Baseline Missed n Wrnnn Peak___ 4.53 -- Aju.A PFDoA 1 613.0/569.0 Da Baseline Missed n Wrnnn Peak 13C-PFD0A 615.0/169.0 Da o Baseline Missed n Wrnnn Peak 5.19 PFTrA 1 663.0/619.0 Da Baseline Missed ___ n Wrnnn Peak___ 13C-PFDOA 615.0/169.0 Da d Baseline Missed n Wrnnn Peak___ 5.59 PFTeA 1 713.0/669.0 Da Baseline Missed ___h Wrnnn Peak___ 13C-PFDoA 615.0/169.0 Da Baseline Missed ____ n Wrnnn Peak___ Before After Page 52 of 170 44 p. 49 Created with Analyst Reporter Printed: 18/02/2010 3:24:00 PM Ion Ratio Confirmation : - 1.23 -- ..... i l_JL _ PFOA2 413.0/369.0 Da Baseline u Missed c Wrong Peak t t-e 1 4,'fi ?5 1U PFNA2 463.0/219.0 Da Baseline c Missed Wrong Peak K1001011-001 1*{. Aaos `1.T0k*nii i* .c 30 PFOS2 499.0/99.0 Da Baseline Missed Wrong Peak PFDA2 513.0/269.0 Da Baseline l Missed Wrong Peak .......... Iw.. PFUnA 2 563.0/269.0 Da Baseline c Missed c Wrong Peak PFDS 2 599.0/99.0 Da Baseline Missed Wrong Peak PFDoA2 613.0/169.0 Da Baseline Missed Wrong Peak PFTrA 2 663.0/169.0 Da Baseline Missed Wrong Peak PFTeA2 713.0/169.0 Da Baseline Missed Wrong Peak Before After Page 53 of 170 45 p. 50 Created with Analyst Reporter Printed: 18/02/2010 4:02:00 PM Project Data File Result Table Instrument Name Ewan's Projects\PFCs 021710\SamplesShort.wiff 021710short.rdb API 5000 Sample Name Acquisition Date Acquisition Method Injection Vial K1001011-001 2/18/2010 2:09:16 AM PFCkinetexShort.dam 25 Injection Volume Sample Type Dilution Factor Weight to Volume 5 Unknown 1.00 0.00 Results Summary Analyte Peak Name IS Name PFBA 1 13C-PFBA PFPeA 1 13C-PFHXA PFBS 1 180-PFHS PFHxA 1 13C-PFHXA PFHpA 1 130-PFHxA PFHxS 1 180-PFHS SJ80-PFHS 13C-PFDA S_13C-PFDA 13C-PFDA IS Area 5419700 6605900 3903500 6605900 6605900 3903500 4111000 4111000 Analyte RT (Exp RT ) 1.24 (1.27) 3.54 (3.60) 4.20 (4.26) 5.25 (5.31) 6.17 (6.23) 6.26 (6.32) 6.26 (6.31) 7.56 (7.65) Analyte Area 3692600 11992000 11657000 15821000 2182800 36876000 3903500 4111000 Calc. Cone (ng/mL) 6.44 19.10 8.73 24.60 9.23 34.70 1.18 1.00 Modified? No No No No No No No No gho Z-i' Page 49 o f 169 46 p. 51 Created with Analyst Reporter Printed: 18/02/2010 4:02:00 PM IRC Summary Analyte Peak Name PFBA2 PFPeA2 PFBS2 PFHxA 2 PFHpA2 PFHxS2 S_13C-PFBA S_13C-PFHxA RT (Exp RT) 1.24(1.27) 3.54(3.60) 4.20 (4.26) 5.25(5.31) 6.17(6.22) 6.26 (6.32) 1.24 (1.26) 5.25(5.30) Area 3692600 11992000 4554000 1533100 6739300 18707000 5419700 6605900 Modified? Calc (Exp) MRM Ratio No 1.00(1.00) Ratio Confirms ID YES No 1.00(1.00) YES No 0.39 (0.40) YES No 0.10(0.10) YES No 3.09 (2.90) YES No 0.51 (0.40) No No 1.47 (13.20) No No 0.42(13.71) No Page 50 of 169 47 CcOftllHHiljisI c L i Analytical Smmmr Quantitative Peak Review PFBA 1 213.0/169.0 Da d Baseline o Missed n Wrnnn Peak I 13C-PFBA 217.0/172.0 Da c Baseline c Missed n Wrnnn Peak___ p. 52 Created with Analyst Reporter Printed! 18/02/2010 4!02i00 PM K1001011-001 3.54 1 PFPeA 1 263.0/219.0 Da Baseline Missed n Wrnnn Peak 13C-PFHxA 315.0/270.0 Da Baseline Missed ___n Wrnnn Peak___ PFBS 1 299.0/80.0 Da Baseline a Missed n Wrnnn Peak 6.17 180-PFHS 403.0/103.0 Da Baseline Missed n Wrnnn Peak PFHxA 1 313.0/269.0 Da Baseline l Missed n Wrnnn Peak 13C-PFHxA 315.0/270.0 Da Baseline c Missed n Wrnnn Peak PFHpA 1 363.0/169.0 Da o Baseline l Missed ___f Wrnnn Peak 13C-PFHXA 315.0/270.0 Da Baseline Missed ___ n Wrnnn Peak___ PFHxS1 399.0/80.0 Da Baseline o Missed Wrnnn Peak 180-PFHS 403.0/103.0 Da c Baseline c Missed Wrnnn Peak S_180-PFHS 403.0/103.0 Da c Baseline Missed ____ n Wrnnn Pnak 13C-PFDA 515.0/470.0 Da Baseline a Missed __ n Wrnnn Peak___ S_13C-PFDA 515.0/470.0 Da Baseline Missed ____ n Wrnnn Peak__ Before After 13C-PFDA 515.0/470.0 Da o Baseline Missed n Wrnnn Peak___ Page 51 of 169 48 Arei p. 53 Created with Analyst Reporter Printed: 18/02/2010 4:02:00 PM Ion Ratio Confirmation K1001011-001 ~4: PFBA2 213.0/169.0 Da Baseline Missed c Wrong Peak PFPeA2 263.0/219.0 Da c Baseline Missed Wrong Peak PFBS2 299.0/99.0 Da Baseline a Missed Wrong Peak ; ; -I 6.17 i (<et> f A ft 6.36 10* iOirt 63*5 ............. 1l ....... j f ............... ?0*`. St 69 tt 70 PFHpA 2 363.0/319.0 Da Baseline c Missed c: Wrong Peak PFHxS 2 399.0/99.0 Da c Baseline Missed Wrong Peak S 13C-PFDA 515.0/470.0 Da Baseline Missed Wrong Peak NB. PFBA and PFPeA do not have qualifying ion transitions. Before After PFHxA 2 313.0/119.0 Da Baseline Missed c Wrong Peak Thisinageisrdavaiable N/A d Baseline Missed d Wrong Peak Page 52 of 169 49 C o lu m b ia A nalytioi Sorvicos" p. 54 Created with Analyst Reporter Printed! 18/02/2010 3124100 PM Project Data File Result Table Instrument Name Ewan's Projects\PFCs 021710\SamplesLong.wiff 021710long.rdb API 5000 Sample Name Acquisition Date Acquisition Method Injection Vial K1001011-002 2/17/2010 8:16:09 PM PFCkinetexLong.dam 26 Injection Volume Sample Type Dilution Factor Weight to Volume 5 Unknown 1.00 0.00 Results Summary Analyte Peak Name IS Name PFOA 1 13C-PFOA PFNA 1 13C-PFNA PFOS 1 13C-PFOS PFDA 1 13C-PFDA PFUnA 1 13C-PFUnA PFDS 1 13C-PFOS PFDoA 1 13C-PFD0A PFTrA 1 13C-PFD0A PFTeA 1 13C-PFD0A IS Area 4705700 2801000 7641700 3083200 142010 7641700 214170 214170 214170 Analyte RT (Exp RT ) 1.22 (1.36) 1.98 (2.06) 2.05 (2.09) 3.06 (3.06) 3.96 (4.06) 3.87 (3.87) 4.51 (4.55) 5.03 (5.06) 0.00(5.51) Analyte Area 1974500 452680 38813000 52591 14069 6958 9972-A-Zl 2002 0 Calc. Cone (ng/mL) 8.300 1.520 47.500 0.157 0.063 0.028 0^65- fJb N/A N/A Modified? No No No No No No No No No -n> 3 (10 Page 54 of 170 50 p. 55 Created with Analyst Reporter Printed: 18/02/2010 3:24:00 PM IRC Summary j Analyte Peak Name PFOA2 S_13C_PFOA PFNA2 S_13C_PFNA PFOS2 SJ3C-PFOS PFDA2 SJ3C-PFDA PFUnA2 S_13C-PFUnA PFDS2 PFDoA2 S_13C-PFDoA PFTrA 2 PFTeA2 RT (Exp RT ) 1.22(1.36) 1.22(1.36) 2.04 (2.08) 0.00 (2.44) 2.06 (2.12) 2.04 (2.00) 3.06 (3.06) 3.06 (3.04) 0.00 (3.88) 3.87 (3.88) 0.00 (3.87) 0.00 (4.53) 4.54 (4.64) 5.12(5.13) 5.36 (5.56) Area 4248300 4705700 147470 0 12754000 7641700 7387 3083200 0 142010 0 0 214170 117 106 Modified? No Calc (Exp) MRM Ratio 2.15(2.16) Ratio Confirms ID YES No 2.38 (43.19) No No 0.33(0.34) YES No 0.00 (0.00) No No 0.33(0.32) YES No 0.20 (21.71) No No 0.14(0.14) YES No 58.63(17.53) No No 0.00(0.19) No No 10.09(1.60) No No 0.00 (0.32) No No 0.00(0.28) No No 21.48(3.71) No No 0.06 (0.34) No No 0.00 (0.29) No Page 55 of 170 51 p. 56 Created with Analyst Reporter Printed: 18/02/2010 3:24:00 PM Quantitative Peak Review 11 2 K1001011-002 1.98 2.03 I PFOA 1 413.0/169.0 Da q Baseline Missed [i Wrnnn Peak l PFOS 1 499.0/80.0 Da Baseline o Missed n Wrnnn Pnak 3.96 JL PFUnA 1 563.0/519.0 Da d Baseline Missed n Wrnnn Peak 1 ___ 13C-PFOA 417.0/372.0 Da Baseline c Missed ------- n Wrnnn Peak___ L PFNA 1 463.0/419.0 Da o Baseline Missed n Wrnnn Peak \i L.'n i v) 13C-PFOS 503.0/80.0 Da Baseline Missed n Wrnnn Peak I PFDA 1 513.0/469.0 Da Baseline Missed n Wrnnn Peak 13C-PFUnA 565.0/270.0 Da Baseline c Missed ..Wrnnn Reals 4^ 3.87 PFDS 1 599.0/80.0 Da c Baseline Missed n Wrnnn Peak___ i 13C-PFNA 468.0/423.0 Da Baseline Missed ------- r Wrnnn Peak -- I 13C-PFDA 515.0/470.0 Da Baseline Missed n Wrnnn Peak 13C-PFOS 503.0/80.0 Da Baseline c Missed n Wrnnn Peak 4.51 PFDoA 1 613.0/569.0 Da Baseline Missed n Wrnnn Peak rp, iiOw; 1; 13C-PFDOA 615.0/169.0 Da Baseline Missed ja.Wrnnn Peak 5.03 PFTrA 1 663.0/619.0 Da o Baseline Missed r. Wrnnn Peak 13C-PFDOA 615.0/169.0 Da Baseline Missed n Wrnnn Peak PFTeA 1 713.0/669.0 Da Baseline a Missed ___ n Wrnnn Peak__ 13C-PFDOA 615.0/169.0 Da Baseline Missed ___n.Wrnnn Peak___ Before After Page 56 of 170 52 Services1 Ion Ratio Confirmation p. 57 Created with Analyst Reporter Printed: 18/02/2010 3:24:00 PM K1001011-002 Before After Page 57 of 170 53 iumbia p. 58 Created with Analyst Reporter Printed: 18/02/2010 4:02:00 PM Project Data File Result Table Instrument Name Ewan's Projects\PFCs 021710\SamplesShort.wiff 021710short.rdb API 5000 Sample Name Acquisition Date Acquisition Method Injection Vial K1001011-002 2/18/2010 2:18:48 AM PFCkinetexShort.dam 26 Injection Volume Sample Type Dilution Factor Weight to Volume 5 Unknown 1.00 0.00 Results Summary Analyte Peak Name IS Name PFBA 1 13C-PFBA PFPeA 1 13C-PFHXA PFBS 1 180-PFHS PFHxA 1 13C-PFHxA PFHpA 1 13C-PFHxA PFHxS 1 180-PFHS SJ80-PFHS 13C-PFDA S_13C-PFDA 13C-PFDA IS Area 5801700 6881600 3960300 6881600 6881600 3960300 4153700 4153700 Analyte RT (ExpRT) 1.24 (1.27) 3.54 (3.60) 4.20 (4.26) 5.24 (5.31) 6.14 (6.23) 6.23 (6.32) 6.24 (6.31) 7.54 (7.65) Analyte Area 4075600 13252000 12172000 16914000 2502900 37695000 3960300 4153700 Calc. Cone (ng/mL) 6.65 20.30 8.99 25.30 10.20 35.10 1.18 1.00 Modified? No No No No No No No No -5 'Z i Page 53 of 169 54 / % C o lu m b ia w a Analytical Sorvicos" p. 59 Created with Analyst Reporter Printed: 18/02/2010 4:02:00 PM IRC Summary i------------------------------------- Analyte Peak Name RT (Exp R T ) PFBA2 1.24(1.27) PFPeA2 3.54(3.60) PFBS2 4.20 (4.26) PFHxA 2 5.24(5.31) PFHpA2 6.15(6.22) PFHxS2 6.24 (6.32) S_13C-PFBA 1.24 (1.26) S_13C-PFHxA 5.23(5.30) Area 4075600 13252000 4802400 1682800 7337000 19514000 5801700 6881600 Modified? Calc (Exp) MRM Ratio No 1.00(1.00) Ratio Confirms ID YES No 1.00(1.00) YES No 0.39 (0.40) YES No 0.10(0.10) YES No 2.93 (2.90) YES No 0.52 (0.40) No No 1.42(13.20) No No 0.41 (13.71) No Page 54 of 169 55 Services" Quantitative Peak Review p. 60 Created with Analyst Reporter Printed: 18/02/2010 4:02:00 PM K1001011-002 PFBA 1 213.0/169.0 Da o Baseline Missed n Wrnnn Peak 13C-PFBA 217.0/172.0 Da Baseline Missed n Wrnnn Peak PFPeA 1 263.0/219.0 Da Baseline Missed Wrnnn Peak 5.^ 13C-PFHxA 315.0/270.0 Da Baseline g Missed n Wrnnn Peak PFBS 1 299.0/80.0 Da c Baseline c Missed n Wrnnn Peak 6.14 180-PFHS 403.0/103.0 Da Baseline c Missed n Wrnnn Peak J6 '] 60 PFHxA 1 313.0/269.0 Da Baseline Missed i Wrnnn Peak 13C-PFHXA 315.0/270.0 Da o Baseline c Missed n Wrnnn Peak PFHpA 1 363.0/169.0 Da c Baseline Missed __ r. Wrnnn Peak___ 13C-PFHxA 315.0/270.0 Da Baseline g Missed n Wrnnn Peak PFHxS 1 399.0/80.0 Da Baseline Missed n Wrnnn Peak 7.^4_________ 180-PFHS 403.0/103.0 Da Baseline Missed n Wrnnn Peak S_180-PFHS 403.0/103.0 Da a Baseline Missed r. Wrnnn Peak 13C-PFDA 515.0/470.0 Da Baseline Missed ____ n Wrnnn Peak S_13C-PFDA 515.0/470.0 Da Baseline Missed n Wrnnn Peak___ Before After 13C-PFDA 515.0/470.0 Da Baseline Missed n Wrnnn Peak___ Page 55 of 169 56 p. 61 Created with Analyst Reporter Printed: 18/02/2010 4:02:00 PM Ion Ratio Confirmation !l 1.24 3.54 PFBA2 213.0/169.0 Da g Baseline Missed u Wrong Peak S.15 PFPeA2 263.0/219.0 Da Baseline Missed Wrong Peak K1001011-002 ..... 4 .; PFBS2 299.0/99.0 Da Baseline Missed Wrong Peak 5. i t ________ PFHxA 2 313.0/119.0 Da Baseline a Missed d Wrong Peak r PFHpA2 363.0/319.0 Da a Baseline Missed g Wrong Peak PFHxS2 399.0/99.0 Da Baseline a Missed c Wrong Peak S_13C-PFDA 515.0/470.0 Da Baseline Missed Wrong Peak NB. PFBA and PFPeA do not have qualifying ion transitions. Before After N/A Baseline a Missed Wrong Peak Page 56 o f 169 57 p. 62 Created with Analyst Reporter Printed: 18/02/2010 3:24:00 PM Project Data File Result Table Instrument Name Ewan's Projects\PFCs 021710\Samplesl_ong .wiff 021710long.rdb API 5000 Sample Name Acquisition Date Acquisition Method Injection Vial K1001011-003 2/17/2010 8:23:41 PM PFCkinetexLong.dam 27 Injection Volume Sample Type Dilution Factor Weight to Volume 5 Unknown 1.00 0.00 Results Summary Analyte Peak Name IS Name PFOA 1 13C-PFOA PFNA 1 13C-PFNA PFOS 1 13C-PFOS PFDA 1 13C-PFDA PFUnA 1 13C-PFUnA PFDS 1 13C-PFOS PFDoA 1 13C-PFDOA PFTrA 1 13C-PFDOA PFTeA 1 130-PFDoA IS Area 4084100 2701100 7331000 3489500 134890 7331000 241810 241810 241810 Analyte RT (Exp RT ) 1.21 (1.36) 1.97 (2.06) 2.00 (2.09) 0.00 (3.06) 0.00 (4.06) 3.83 (3.87) 0.00 (4.55) 5.03 (5.06) 5.67 (5.51) Analyte Area 938810 1169300 1724700 0 0 3992 0 4852 5339 Calc. Cone (ng/mL) 4.560 4.010 2.220 N/A N/A 0.025 N/A N/A N/A Modified? No No No No No No No No No <7 X 1' (l4 ((0 Page 58 o f 170 58 p. 63 Created with Analyst Reporter Printed: 18/02/2010 3:24:00 PM IRC Summary Analyte Peak Name PFOA2 S_13C_PFOA PFNA2 S_13C_PFNA PFOS 2 SJ3C-PFOS PFDA 2 SJ3C-PFDA PFUnA2 S_13C-PFUnA PFDS 2 PFDoA2 S_13C-PFDoA PFTrA 2 PFTeA2 RT (Exp RT ) 1.18(1.36) 1.17 (1.36) 1.97 (2.08) 0.00(2.44) 2.01 (2.12) 2.00 (2.00) 3.02 (3.06) 3.02 (3.04) 0.00 (3.88) 3.84(3.88) 0.00 (3.87) 0.00 (4.53) 4.49 (4.64) 5.02(5.13) 5.56(5.56) Area 1823500 4084100 368930 0 582840 7331000 308 3489500 0 134890 0 0 241810 672 139 Modified? Calc (Exp) MRM Ratio No 1.94(2.16) Ratio Confirms ID YES No 4.35 (43.19) No No 0.32(0.34) YES No 0.00(0.00) No No 0.34(0.32) YES No 4.25 (21.71) No No 0.00 (0.14) No No 0.00(17.53) No No 0.00(0.19) No No 0.00(1.60) No No 0.00 (0.32) No No 0.00(0.28) No No 0.00(3.71) No No 0.14(0.34) No No 0.03 (0.29) No Page 59 o f 170 59 Services" p. 64 Created with Analyst Reporter Printed: 18/02/2010 3:24:00 PM Quantitative Peak Review I I PFOA 1 413.0/169.0 Da u Baseline c Missed n Wrnnn Pnak 13C-PFOA 417.0/372.0 Da Baseline Missed -- n Wrnnn Pftfrt__ 2.00 L L _ I_ _ PFOS 1 499.0/80.0 Da o Baseline c Missed i Wrnnn Paak if'. . ! Liv.ivj , j ; ,jj A > s ;V -'v 13C-PFOS 503.0/80.0 Da Baseline Missed n Wrnnn Paak ;yno 3 ^ __________ :twoc< IUUQU PFUnA 1 563.0/519.0 Da Baseline Missed 13C-PFUnA 565.0/270.0 Da Baseline Missed n Wrnnn Peak K1001011-003 Li PFNA 1 463.0/419.0 Da Baseline Missed i Wrnnn Paak 13C-PFNA 468.0/423.0 Da Baseline Missed n Wrnnn Peak j^ I; ' i f 1> PFDA 1 513.0/469.0 Da Baseline Missed p Wrnnn Peak 13C-PFDA 515.0/470.0 Da d Baseline Missed h Wrnnn Ppak 3.83 )(i Ji PFDS 1 599.0/80.0 Da Baseline Missed n Wrnnn Peak 13C-PFOS 503.0/80.0 Da o Baseline Missed i Wrnnn Peak PFDoA 1 613.0/569.0 Da Baseline Missed n Wrnnn Peak 13C-PFDOA 615.0/169.0 Da Baseline Missed n Wrnnn Peak PFTrA 1 663.0/619.0 Da Baseline Missed ___ n Wrnnn Peak___ 130-PFDoA 615.0/169.0 Da Baseline Missed ___ r Wrnnn Peak___ 5.67 PFTeA 1 713.0/669.0 Da Baseline Missed ___n Wrnnn Peak 130-PFDoA 615.0/169.0 Da Baseline Missed ___ Wrong Peak___ Before After Page 60 of 170 60 Services" p. 65 Created with Analyst Reporter Printed: 18/02/2010 3:24:00 PM Ion Ratio Confirmation 1.18 K1001011-003 -JL.-- . PFOA2 413.0/369.0 Da Baseline o Missed l Wrong Peak PFNA2 463.0/219.0 Da Baseline c Missed a Wrong Peak PFOS 2 499.0/99.0 Da Baseline Missed Wrong Peak ir-Oiwj \um- PFDA2 513.0/269.0 Da Baseline c Missed c Wrong Peak PFUnA2 563.0/269.0 Da Baseline c Missed Wrong Peak PFDS2 599.0/99.0 Da Baseline Missed Wrong Peak PFDoA2 613.0/169.0 Da Baseline Missed Wrong Peak PFTrA 2 663.0/169.0 Da Baseline Missed Wrong Peak PFTeA2 713.0/169.0 Da Baseline c Missed Wrong Peak Before After Page 61 of 170 61 / ? Columbia .ilytfcal Smmms* p. 66 Created with Analyst Reporter Printed: 18/02/2010 4:02:00 PM Project Data File Result Table Instrument Name Ewan's Projects\PFCs 021710\SampiesShort.wiff 021710short.rdb API 5000 Sample Name Acquisition Date Acquisition Method Injection Vial K1001011-003 2/18/2010 2:28:20 AM PFCkinetexShort.dam 27 Injection Volume Sample Type Dilution Factor Weight to Volume 5 Unknown 1.00 0.00 Results Summary Analyte Peak Name IS Name PFBA 1 13C-PFBA PFPeA 1 130-PFHxA PFBS 1 180-PFHS PFHxA 1 130-PFHxA PFHpA 1 13C-PFHxA PFHxS1 180-PFHS S_180-PFHS 13C-PFDA S_13C-PFDA 13C-PFDA IS Area 4866300 5778700 3651900 5778700 5778700 3651900 4256500 4256500 Analyte RT (Exp RT ) 1.25 (1.27) 3.53 (3.60) 4.19 (4.26) 5.23 (5.31) 6.12 (6.23) 6.22 (6.32) 6.23 (6.31) 7.51 (7.65) Analyte Area 453610 1220100 2161500 2810100 401400 14457000 3651900 4256500 Calc. Cone (ng/mL) 0.83 2.22 1.68 4.75 1.88 12.70 1.06 1.00 Modified? No No No No No No No No 7 ,1 '* '* Page 57 o f 169 62 p. 67 Created with Analyst Reporter Printed: 18/02/2010 4:02:00 PM IRC Summary Analyte Peak Name PFBA2 PFPeA2 PFBS2 PFHxA2 PFHpA2 PFHxS2 S_13C-PFBA S_13C-PFHxA RT (Exp R T ) 1.25(1.27) 3.53 (3.60) 4.19(4.26) 5.23 (5.31) 6.13(6.22) 6.22 (6.32) 1.24(1.26) 5.23(5.30) Area 4536101220100 820410 243730 1239300 5769800 4866300 5778700 Modified? Calc (Exp) MRM Ratio No 1.00(1.00) Ratio Confirms ID YES No 1.00(1.00) YES No 0.38(0.40) YES No 0.09(0.10) YES No 3.09 (2.90) YES No 0.40 (0.40) YES No 10.73(13.20) YES No 2.06(13.71) No Page 58 o f 169 63 Quantitative Peak Review p. 68 Created with Analyst Reporter Printed: 18/02/2010 4:02:00 PM K1001011-003 3.53 PFBA 1 213.0/169.0 Da Baseline c Missed r Wrnnn Peak 4^9________ 13C-PFBA 217.0/172.0 Da Baseline d Missed Wronn Peak PFPeA 1 263.0/219.0 Da o Baseline Missed ___ n Wrnnn Peak__ 5 ^ ________ 13C-PFHxA 315.0/270.0 Da Baseline Missed __ n Wronn Peak___ PFBS 1 299.0/80.0 Da Baseline Missed r Wrnnn Ppak 180-PFHS 403.0/103.0 Da Baseline Missed n Wrnnn Peak PFHxA 1 313.0/269.0 Da Baseline c Missed n Wrnnn Peak 13C-PFHxA 315.0/270.0 Da c Baseline c Missed r Wrnnn Peak PFHpA 1 363.0/169.0 Da Baseline Missed ___ n Wrnnn Peak 13C-PFHxA 315.0/270.0 Da Baseline Missed ___n Wronn Peak PFHxS 1 399.0/80.0 Da Baseline Missed n Wrnnn Peak 180-PFHS 403.0/103.0 Da Baseline Missed ___ n Wrnnn Peak__ _ `.(I*?, S_180-PFHS 403.0/103.0 Da Baseline Missed ___ n Wrnnn Peak 13C-PFDA 515.0/470.0 Da o Baseline Missed _ _ _ n Wrnnn Peak___ SJ3C-PFDA 515.0/470.0 Da Baseline Missed n Wrnnn Peak Before After 13C-PFDA 515.0/470.0 Da Baseline Missed ___ n Wrnnn Peak___ Page 59 o f 169 64 Ion Ratio Confirmation p. 69 Created with Analyst Reporter Printed: 18/02/2010 4:02:00 PM K1001011-003 PFBA2 213.0/169.0 Da Baseline c Missed Wrong Peak ..............6.., {1..3........ ....... s1 i PFPeA2 263.0/219.0 Da Baseline Missed Wrong Peak :Z \ 2f ......... &. ............... ' 3 .... A ............... PFBS2 299.0/99.0 Da Baseline u Missed c Wrong Peak 10*6 $0*5 & | JiVt, r ........... PFHpA2 363.0/319.0 Da Baseline a Missed c Wrong Peak PFHxS2 399.0/99.0 Da Baseline Missed Wrong Peak S 13C-PFDA 515.0/470.0 Da D Baseline Missed o Wrong Peak NB. PFBA and PFPeA do not have qualifying ion transitions. Before After Ml PFHxA 2 313.0/119.0 Da Baseline Missed Wrong Peak Thisrnage isruit av^atile N/A Baseline Missed Wrong Peak Page 60 o f 169 65 p. 70 Created with Analyst Reporter Printed: 18/02/2010 3:24:00 PM Project Data File Result Table Instrument Name Ewan's Projects\PFCs 021710\SamplesLong.wiff 021710long.rdb API 5000 Sample Name Acquisition Date Acquisition Method Injection Vial K1001011-004 2/17/2010 8:31:17 PM PFCkinetexLong.dam 28 Injection Volume Sample Type Dilution Factor Weight to Volume 5 Unknown 1.00 0.00 Results Summary Analyte Peak Name IS Name PFOA 1 13C-PFOA PFNA 1 13C-PFNA PFOS 1 13C-PFOS PFDA 1 13C-PFDA PFUnA 1 13C-PFUnA PFDS 1 13C-PFOS PFDoA 1 13C-PFD0A PFTrA 1 13C-PFD0A PFTeA 1 13C-PFD0A IS Area 4529300 2826400 7797500 3542200 123850 7797500 235170 235170 235170 Analyte RT (Exp RT ) 1.26 (1.36) 2.06 (2.06) 2.08 (2.09) 0.00(3.06) 3.90 (4.06) 3.88 (3.87) 0.00 (4.55) 5.06 (5.06) 0.00 (5.51) Analyte Area 1094100 1341200 1785900 0 7037-- -- 1821 0 5603 0 Calc. Cone (ng/mL) 4.790 4.400 2.160 N/A /I) 0.023 N/A N/A N/A Modified? No No No No No No No No No /\r~ * Page 62 of 170 66 p. 71 Created with Analyst Reporter Ml Printed: 18/02/2010 3:24:00 PM IRC Summary Analyte Peak Name PFOA2 S_13C_PFOA PFNA2 S_13C_PFNA PFOS2 S_13C-PFOS PFDA 2 S_13C-PFDA PFUnA 2 S_13C-PFUnA PFDS 2 PFDoA2 S_13C-PFDoA PFTrA 2 PFTeA2 RT (Exp RT ) 1.27(1.36) 1.28(1.36) 2.04 (2.08) 0.00 (2.44) 2.08 (2.12) 2.08 (2.00) 3.06 (3.06) 3.08 (3.04) 0.00 (3.88) 3.86 (3.88) 0.00(3.87) 0.00 (4.53) 4.51 (4.64) 5.08 (5.13) 5.66 (5.56) Area 2127000 4529300 449440 0 627690 7797500 646 3542200 0 123850 0 0 235170 457 162 Modified? Calc (Exp) MRM Ratio No 1.94(2.16) Ratio Confirms ID YES No 4.14 (43.19) No No 0.34(0.34) YES No 0.00 (0.00) No No 0.35(0.32) YES No 4.37 (21.71) No No 0.00 (0.14) No No 0.00(17.53) No No 0.00(0.19) No No 15.60(1.60) No No 0.00 (0.32) No No 0.00 (0.28) No No 0.00 (3.71) No No 0.08 (0.34) No No 0.00 (0.29) No Page 63 of 170 67 Services' p. 72 Created with Analyst Reporter Printed: 18/02/2010 3:24:00 PM Quantitative Peak Review K1001011-004 JL2.06 PFOA 1 413.0/169.0 Da Baseline Missed n Wrnnn Peak 2.08 PFOS 1 499.0/80.0 Da o Baseline Missed i Wrnnn Paak 3.90 y ,r"i >' >,1/ 13C-PFOA 417.0/372.0 Da Baseline l Missed Wronn Peak i_ _H 2i8 i; L:(i io 13C-PFOS 503.0/80.0 Da a Baseline Missed n Wrnnn Peak PFNA 1 463.0/419.0 Da Baseline c Missed n Wrnnn Peak ' 'VijV>/W;*' '''' ' PFDA 1 513.0/469.0 Da Baseline Missed Wrnnn Paak 13C-PFNA 468.0/423.0 Da Baseline c Missed r Wrnnn Peak 13C-PFDA 515.0/470.0 Da Baseline c Missed ___ n W rnnn P aak___ PFUnA 1 563.0/519.0 Da Baseline c Missed __ n Wrnnn Peak 13C-PFUnA 565.0/270.0 Da u Baseline u Missed __ p Wrong PoaK__ PFDS 1 599.0/80.0 Da Baseline Missed n Wrnnn Peak 13C-PFOS 503.0/80.0 Da Baseline l Missed __ n Wrnnn Peak__ _ PFDoA 1 613.0/569.0 Da d Baseline Missed n W rnnn Pnak 13C-PFDOA 615.0/169.0 Da Baseline c Missed n Wrnnn Peak PFTrA 1 663.0/619.0 Da Baseline Missed n Wrnnn Paak 13C-PFDOA 615.0/169.0 Da Baseline Missed ____ n W rnnn P nak PFTeA 1 713.0/669.0 Da Baseline Missed n W rnnn Paak 13C-PFDOA 615.0/169.0 Da Baseline Missed ____ p Wrnnn Peak___ Before After 68 Page 64 of 170 Services' p. 73 Created with Analyst Reporter Printed: 18/02/2010 3:24:00 PM Ion Ratio Confirmation 1.27 K1001011-004 JOClC ; - I i ........... :! 1 ...M l -------- PFOA2 413.0/369.0 Da Baseline c Missed l Wrong Peak .Of4 i? IM;0 L i OdS | ... 1 . 3 0$ ........... jo t` :it jo 3.06 ;* u ji 40 PFNA2 463.0/219.0 Da Baseline o Missed u Wrong Peak PFOS2 499.0/99.0 Da Baseline Missed Wrong Peak PFDA2 513.0/269.0 Da Baseline c Missed c Wrong Peak PFUnA2 563.0/269.0 Da Baseline Missed c. Wrong Peak PFDS2 599.0/99.0 Da Baseline Missed d Wrong Peak PFDoA2 613.0/169.0 Da a Baseline o Missed Wrong Peak PFTrA 2 663.0/169.0 Da Baseline c Missed Wrong Peak PFTeA2 713.0/169.0 Da Baseline Missed Wrong Peak Before After Page 65 of 170 69 p. 74 Created with Analyst Reporter Printed: 18/02/2010 4:02:00 PM Project Data File Result Table Instrument Name Ewan's ProjectsVPFCs 02171 OVSamplesShort.wiff 021710short.rdb API 5000 Sample Name Acquisition Date Acquisition Method Injection Vial K1001011-004 2/18/2010 2:37:56 AM PFCkinetexShort.dam 28 Injection Volume Sample Type Dilution Factor Weight to Volume 5 Unknown 1.00 0.00 Results Summary Analyte Peak Name IS Name PFBA 1 13C-PFBA PFPeA 1 130-PFHxA PFBS 1 180-PFHS PFHxA 1 13C-PFHXA PFHpA 1 13C-PFHxA PFHxS1 180-PFHS S_180-PFHS 13C-PFDA S_13C-PFDA 13C-PFDA IS Area 5149200 6607200 3878300 6607200 6607200 3878300 4818300 4818300 Analyte RT (Exp RT ) 1.24 (1.27) 3.53 (3.60) 4.19 (4.26) 5.22 (5.31) 6.13 (6.23) 6.22 (6.32) 6.22 (6.31) 7.52 (7.65) Analyte Area 500500 1417100 2368700 3072800 453840 15308000 3878300 4818300 Calc. Cone (ng/mL) 0.87 2.25 1.73 4.54 1.86 12.70 1.00 1.00 Modified? No No No No No No No No /. ,, -r * Page 61 of 169 70 M C o lu m b ia i L j Analytical Sonricos'' p. 75 Created with Analyst Reporter Printed: 18/02/2010 4:02:00 PM IRC Summary Analyte Peak Name PFBA2 PFPeA2 PFBS2 PFHxA 2 PFHpA2 PFHxS2 S_13C-PFBA S_13C-PFHxA RT (Exp R T ) 1.24(1.27) 3.53(3.60) 4.18(4.26) 5.22(5.31) 6.13(6.22) 6.22 (6.32) 1.23(1.26) 5.22(5.30) Area 500500 1417100 877890 276180 1400300 6236000 5149200 6607200 Modified? No Calc (Exp) MRM Ratio 1.00(1.00) Ratio Confirms ID YES No 1.00(1.00) YES No 0.37(0.40) YES No 0.09(0.10) YES No 3.09(2.90) YES No 0.41 (0.40) YES No 10.29(13.20) No No 2.15(13.71) No Page 62 of 169 71 C -O ltlllisb is 3 AnafySicai $rvkF Quantitative Peak Review p. 76 Created with Analyst Reporter Printed! 18/02/2010 4!02i00 PM K1001011-004 1 PFBA 1 213.0/169.0 Da Baseline c Missed n Wronn Peak 4.19 13C-PFBA 217.0/172.0 Da Baseline Missed ___n Wronn Peak___ PFPeA 1 263.0/219.0 Da Baseline Missed n W rnnn P eak___ _ 5.^ 13C-PFHxA 315.0/270.0 Da Baseline c Missed ___ n W rnnn Peak----- 5.2 L 1 __ _ PFBS 1 299.0/80.0 Da Baseline Missed r Wronn Peak 6 13 180-PFHS 403.0/103.0 Da Baseline u Missed n Wrnnn Ppak PFHxA 1 313.0/269.0 Da Baseline Missed n Wrnnn Ppak `I . j L_ PFHpA 1 363.0/169.0 Da c Baseline c Missed n W rnnn Pfak 6.^2 13C-PFHxA 315.0/270.0 Da Baseline Missed ___n Wronn Peak___ PFHxS 1 399.0/80.0 Da Baseline c Missed ___r Wrnnn Peak___ S_180-PFHS 403.0/103.0 Da Baseline a Missed ___ n W rnnn Pnak 13C-PFDA 515.0/470.0 Da Baseline Missed n Wrnnn Peak S_13C-PFDA 515.0/470.0 Da Baseline Missed n Wrnnn Pnak___ Before After 13C-PFHXA 315.0/270.0 Da Baseline c Missed p Wrnnn Peak 6.22 i 180-PFHS 403.0/103.0 Da Baseline c Missed ___ n W rnnn Peak___ 7.52 A 13C-PFDA 515.0/470.0 Da Baseline Missed ___n Wrnnn P aak___ Page 63 of 169 72 p. 77 Created with Analyst Reporter Printed: 18/02/2010 4:02:00 PM Ion Ratio Confirmation r1.24 ...3.53 PFBA2 213.0/169.0 Da c Baseline c Missed c Wrong Peak 6.13 PFPeA2 263.0/219.0 Da Baseline l: Missed c Wrong Peak K1001011-004 PFBS2 299.0/99.0 Da Baseline c Missed Wrong Peak PFHxA 2 313.0/119.0 Da d Baseline Missed o Wrong Peak PFHpA2 363.0/319.0 Da Baseline Missed u Wrong Peak PFHxS2 399.0/99.0 Da Baseline Missed Wrong Peak S_13C-PFDA 515.0/470.0 Da Baseline Missed Wrong Peak NB. PFBA and PFPeA do not have qualifying ion transitions. Before After N/A Baseline Missed Wrong Peak Page 64 of 169 73 p. 78 Created with Analyst Reporter Printed: 18/02/2010 3:24:00 PM Project Data File Result Table Instrument Name Ewan's Projects\PFCs 021710\SamplesLong.wiff 021710long.rdb API 5000 Sample Name Acquisition Date Acquisition Method Injection Vial K1001011-005 2/17/2010 8:38:51 PM PFCkinetexLong.dam 29 Injection Volume Sample Type Dilution Factor Weight to Volume 5 Unknown 1.00 0.00 Results Summary Analyte Peak Name IS Name PFOA 1 13C-PFOA PFNA 1 13C-PFNA PFOS 1 13C-PFOS PFDA 1 13C-PFDA PFUnA 1 13C-PFUnA PFDS 1 13C-PFOS PFDoA 1 130-PFDoA PFTrA 1 130-PFDoA PFTeA 1 13C-PFD0A IS Area 4475900 2692200 7108800 3322000 88655 7108800 174210 174210 174210 Analyte RT (Exp RT ) 1.21 (1.36) 2.01 (2.06) 2.02 (2.09) 3.03 (3.06) 3.87 (4.06) 3.86 (3.87) 4.50 (4.55) 5.07 (5.06) 5.52 (5.51) Analyte Area 611930 Calc. Cone (ng/mL) 2.720 3390500 11.600 4803400 6.330 74442 0.209 43553 0.438 63887 0.097 21358 0.210 4281 N/A '4 'X h , 590-3--^ ---- e r n e t t O Modified? No No No No No No No No No Page 66 of 170 74 ....................................................... J?*? C olu itlilfe is c L J A re ly ficaf Services1' p. 79 Created with Analyst Reporter Printed: 18/02/2010 3:24:00 PM IRC Summary Analyte Peak Name i PFOA2 S_13C_PFOA PFNA2 S_13C_PFNA PFOS 2 S_13C-PFOS PFDA 2 S_13C-PFDA PFUnA2 S_13C-PFUnA PFDS 2 PFDoA2 S_13C-PFDoA PFTrA 2 PFTeA2 RT (Exp R T ) 1.20(1.36) 1.19(1.36) 1.99(2.08) 0.00 (2.44) 2.03 (2.12) 2.02(2.00) 3.03 (3.06) 3.03 (3.04) 3.87(3.88) 3.86(3.88) 3.87(3.87) 4.52 (4.53) 4.52 (4.64) 5.06 (5.13) 5.52 (5.56) Area 1247100 4475900 1091900 0 1684900 7108800 8581 3322000 7504 88655 20832 3852 174210 1681 627 Modified? No Calc (Exp) MRM Ratio 2.04 (2.16) Ratio Confirms ID YES No 7.31 (43.19) No No 0.32(0.34) YES No 0.00 (0.00) No No 0.35(0.32) YES No 1.48 (21.71) No No 0.12(0.14) YES No 44.63(17.53) No No 0.17(0.19) YES No 2.04(1.60) No No 0.33 (0.32) YES No 0.18(0.28) No No 8.16(3.71) No No 0.39(0.34) YES No 0.11 (0.29) No Page 67 of 170 75 lymfoia p. 80 Created with Analyst Reporter Printed: 18/02/2010 3:24:00 PM Quantitative Peak Review I PFOA 1 413.0/169.0 Da c Baseline o Missed n Wrnnn Peak 13C-PFOA 417.0/372.0 Da Baseline Missed n Wrnnn Peak K1001011-005 2.01 1.99 fioft -- ---- ---------- . PFNA 1 463.0/419.0 Da Baseline a Missed -Q-Wronn Peak L 13C-PFNA 468.0/423.0 Da Baseline Missed ------r W rnnn Peak___ j_______ 3^3 PFOS 1 499.0/80.0 Da c Baseline c Missed n Wrnnn Peak 3.87 PFUnA 1 563.0/519.0 Da u Baseline Missed ___ n W rnnn P eak L 13C-PFOS 503.0/80.0 Da Baseline Missed n Wrnnn Peak 3.86 PFDA 1 513.0/469.0 Da Baseline Missed n Wrnnn Peak 1 13C-PFUnA 565.0/270.0 Da Baseline Missed ___ n W rnnn Peak___ PFDS 1 599.0/80.0 Da Baseline Missed ___n Wrnnn Peak 13C-PFDA 515.0/470.0 Da d Baseline a Missed n Wrnnn Peak I2.02 13C-PFOS 503.0/80.0 Da a Baseline o Missed ___ n Wrnnn Peak___ 4.50 -JL PFDoA 1 613.0/569.0 Da Baseline Missed n Wrnnn Peak y 13C-PFD0A 615.0/169.0 Da Baseline o Missed n Wrnnn Peak 5.07 PFTrA 1 663.0/619.0 Da d Baseline a Missed ___ n W rnnn Peak 5.52 PFTeA 1 713.0/669.0 Da c Baseline Missed ___n Wrnnn Peak 13C-PFD0A 615.0/169.0 Da Baseline Missed ___ n Wrnnn Peak Before After 13C-PFDOA 615.0/169.0 Da Baseline Missed ___ n W rnnn P eak___ Page 68 of 170 76 Ion Ratio Confirmation p. 81 Created with Analyst Reporter Printed: 18/02/2010 3:24:00 PM K1001011-005 PFOA2 413.0/369.0 Da Baseline g Missed Wrong Peak PFNA2 463.0/219.0 Da a Baseline g Missed Wrong Peak PFOS2 499.0/99.0 Da Baseline Missed Wrong Peak PFDA2 513.0/269.0 Da c Baseline g Missed c Wrong Peak PFUnA2 563.0/269.0 Da Baseline Missed c Wrong Peak PFDS2 599.0/99.0 Da Baseline Missed Wrong Peak PFDoA2 613.0/169.0 Da Baseline Missed Wrong Peak PFTrA 2 663.0/169.0 Da Baseline Missed Wrong Peak ,,_5J?2 PFTeA2 713.0/169.0 Da Baseline Missed a Wrong Peak Before After Page 69 o f 170 77 p. 82 Created with Analyst Reporter Printed: 18/02/2010 4:02:00 PM Project Data File Result Table Instrument Name Ewan's Projects\PFCs 021710\SamplesShort.wiff 021710short.rdb API 5000 Sample Name Acquisition Date Acquisition Method Injection Vial K1001011-005 2/18/2010 2:47:27 AM PFCkinetexShort.dam 29 Injection Volume Sample Type Dilution Factor Weight to Volume 5 Unknown 1.00 0.00 Results Summary Analyte Peak Name IS Name PFBA 1 13C-PFBA PFPeA 1 13C-PFHXA PFBS 1 180-PFHS PFHxA 1 13C-PFHXA PFHpA 1 13C-PFHXA PFHxS1 180-PFHS S_180-PFHS 13C-PFDA S_13C-PFDA 13C-PFDA IS Area 4418900 5838700 3904700 5838700 5838700 3904700 4391200 4391200 Analyte RT (Exp RT ) 1.24 (1.27) 3.53 (3.60) 4.19 (4.26) 5.24 (5.31) 6.14 (6.23) 6.23 (6.32) 6.23 (6.31) 7.53 (7.65) Analyte Area 295630 865220 1360400 1673600 281040 8474300 3904700 4391200 Calc. Cone (ng/mL) 0.58 1.55 0.99 2.76 1.29 6.74 1.10 1.00 Modified? No No No No No No No No z . n * llb Page 65 of 169 78 p. 83 Created with Analyst Reporter Printed: 18/02/2010 4:02:00 PM IRC Summary Analyte Peak Name PFBA2 PFPeA2 PFBS2 PFHxA2 PFHpA2 PFHxS2 S_13C-PFBA S_13C-PFHxA RT (Exp RT) 1.24(1.27) 3.53 (3.60) 4.19(4.26) 5.23 (5.31) 6.14(6.22) 6.23 (6.32) 1.23 (1.26) 5.23(5.30) Area 295630 865220 515360 154580 868120 3325700 4418900 5838700 Modified? No Calc (Exp) MRM Ratio 1.00(1.00) Ratio Confirms ID YES No 1.00(1.00) YES No 0.38(0.40) YES No 0.09(0.10) YES No 3.09 (2.90) YES No 0.39(0.40) YES No 14.95(13.20) YES No 3.49(13.71) No Page 66 of 169 79 p. 84 Created with Analyst Reporter Printed: 18/02/2010 4:02:00 PM Quantitative Peak Review I K1001011-005 PFBA 1 213.0/169.0 Da a Baseline u Missed n Wrnnn Peak 4.19 JL PFBS 1 299.0/80.0 Da Baseline Missed r Wrnnn Pnak 6.14 PFHpA 1 363.0/169.0 Da g Baseline u Missed __ f Wrnnn Peak___ S_180-PFHS 403.0/103.0 Da Baseline Missed ___n Wrnnn Peak 13C-PFBA 217.0/172.0 Da Baseline Missed n Wrnnn Peak 6.23 1 1 | PFPeA 1 263.0/219.0 Da Baseline d Missed n Wrnnn Peak T| I 13C-PFHxA 315.0/270.0 Da Baseline Missed Wrnnn Peak lo-/. Oe! J t.G*5 40*5 >1M 180-PFHS 403.0/103.0 Da Baseline u Missed n Wrnnn Peak 1 5.23 i ce i 1 1ii? I PFHxA 1 313.0/269.0 Da o Baseline Missed r~<Wrnnn Peak I: a 6.23 , ? 1Uah __ ~ . _1S0*5 1 13C-PFHxA 315.0/270.0 Da Baseline g Missed n Wrnnn Pnak ,r 13C-PFHxA 315.0/270.0 Da Baseline Missed ___n Wrnnn Peak 17.53 13C-PFDA 515.0/470.0 Da Baseline Missed ____ n Wrnnn Peak___ PFHxS 1 180-PFHS 399.0/80.0 Da 403.0/103.0 Da Baseline Missed Baseline c Missed n Wrnnn Peak___ n Wrnnn Peak i 1Qm *. Sues t 0-5 7.53 A1CeC KU*6 ' 0*5 7.53 ci fail (Kk-0 ? 7r ? a 5 S_13C-PFDA 515.0/470.0 Da c Baseline Missed n Wrnnn Pnak___ 13C-PFDA 515.0/470.0 Da Baseline Missed n Wrnnn Peak___ Before After Page 67 o f 169 80 fit Ion Ratio Confirmation 1.24 p. 85 Created with Analyst Reporter Printed: 18/02/2010 4:02:00 PM K1001011-005 PFBA2 213.0/169.0 Da Baseline Missed Wrong Peak 6.14 PFPeA2 263.0/219.0 Da Baseline c Missed Wrong Peak PFBS2 299.0/99.0 Da a Baseline Missed Wrong Peak eS '0 _L PFHpA2 363.0/319.0 Da Baseline Missed Wrong Peak PFHxS2 399.0/99.0 Da Baseline Missed Wrong Peak S_13C-PFDA 515.0/470.0 Da Baseline Missed Wrong Peak NB. PFBA and PFPeA do not have qualifying ion transitions. Before After PFHxA 2 313.0/119.0 Da Baseline c Missed c Wrong Peak This inage is.not o tH s N/A o Baseline Missed Wrong Peak Page 68 of 169 81 p. 86 Created with Analyst Reporter Printed: 18/02/2010 3:24:00 PM Project Data File Result Table Instrument Name Ewan's Projects\PFCs 021710\SamplesLong.wiff 021710long.rdb API 5000 Sample Name Acquisition Date Acquisition Method Injection Vial K1001011-006 2/17/2010 8:46:26 PM PFCkinetexLong.dam 30 Injection Volume Sample Type Dilution Factor Weight to Volume 5 Unknown 1.00 0.00 Results Summary Analyte Peak Name IS Name PFOA 1 13C-PFOA PFNA 1 13C-PFNA PFOS 1 13C-PFOS PFDA 1 13C-PFDA PFUnA 1 13C-PFUnA PFDS 1 13C-PFOS PFDoA1 13C-PFD0A PFTrA 1 13C-PFD0A PFTeA 1 13C-PFDOA IS Area 4571200 3363200 8676500 3135900 160990 8676500 212730 212730 212730 Analyte RT (Exp RT ) 1.26 (1.36) 2.08 (2.06) 2.08 (2.09) 3.12 (3.06) 3.88 (4.06) 3.88 (3.87) 4.52 (4.55) 5.06 (5.06) 5.54 (5.51) Analyte Area 686910 3948100 5517200 37567 40520 47853 24862 7715 9970 Calc. Cone (ng/mL) 2.990 10.800 5.960 0.108 0.209 0.067 0.201 N/A 0.081 Modified? No No No No No No No No No s? i ( is Page 70 of 170 82 p. 87 Created with Analyst Reporter Printed: 18/02/2010 3:24:00 PM IRC Summary : Analyte Peak Name PFOA2 S_13C_PFOA PFNA2 S_13C_PFNA PFOS 2 SJ3C-PFOS PFDA2 S_13C-PFDA PFUnA2 S_13C-PFUnA PFDS 2 PFDoA2 S_13C-PFDoA PFTrA 2 PFTeA2 RT (Exp RT ) 1.27(1.36) 1.28(1.36) 2.07(2.08) 0.00 (2.44) 2.07 (2.12) 2.07 (2.00) 3.10(3.06) 3.09(3.04) 3.88 (3.88) 3.88 (3.88) 3.89 (3.87) 4.54 (4.53) 4.52 (4.64) 5.05 (5.13) 5.51 (5.56) Area 1315500 4571200 1243500 0 1865900 8676500 3999 3135900 7282 160990 16129 5806 212730 2072 1481 Modified? No Calc (Exp) MRM Ratio 1.92 (2.16) Ratio Confirms ID YES No 6.65(43.19) No No 0.31 (0.34) YES No 0.00 (0.00) No No 0.34(0.32) YES No 1.57 (21.71) No No 0.11 (0.14) YES No 83.47 (17.53) No No 0.18(0.19) YES No 3.97(1.60) No No 0.34(0.32) YES No 0.23(0.28) YES No 8.56(3.71) No No 0.27(0.34) YES No 0.15(0.29) No Page 71 of 170 83 p. 88 Created with Analyst Reporter Printed: 18/02/2010 3:24:00 PM Quantitative Peak Review 1.26 K1001011-006 2.08 1 PFOA 1 413.0/169.0 Da g Baseline c Missed r W ronn Pftak PFOS 1 499.0/80.0 Da Baseline Missed n Wrnnn Peak PFUnA 1 563.0/519.0 Da Baseline Missed n Wrnnn Peak 4.52 .A PFDoA 1 613.0/569.0 Da Baseline Missed n Wrnnn Ppak 13C-PFOA 417.0/372.0 Da g Baseline Missed r Wrnnn Peak j^ PFNA 1 463.0/419.0 Da Baseline c Missed n Wrnnn Ppak 3.12 13C-PFNA 468.0/423.0 Da Baseline o Missed r Wrnnn Peak___ |________ ___________ 1 13C-PFOS 503.0/80.0 Da c Baseline c Missed __ n Wrnnn Peak___ Ii 3.88 13C-PFUnA 565.0/270.0 Da Baseline Missed n Wrnnn Peak 4^ 13C-PFDOA 615.0/169.0 Da Baseline Missed n Wrnnn Pnak PFDA 1 513.0/469.0 Da Baseline Missed r Wrnnn Peak 1'00 ^ 'ooo 1 00 2 .<0 :coo m i3.88 13C-PFDA 515.0/470.0 Da c Baseline c Missed n Wrnnn Peak | Jri 15 :c PFDS 1 599.0/80.0 Da Baseline Missed n Wrnnn Peak 13C-PFOS 503.0/80.0 Da Baseline Missed n Wrnnn Peak__ _ XnV, 1- 4) 1 50u>] 5.06 *5 50 55 60 PFTrAI 663.0/619.0 Da Baseline Missed n W rnnn Peak_____ 13C-PFDOA 615.0/169.0 Da c Baseline Missed n W rnnn P e a k ___ 5.54 PFTeA 1 713.0/669.0 Da n Baseline Missed __ n Wrnnn Peak___ 13C-PFDOA 615.0/169.0 Da Baseline Missed ___ n Wrnnn Peak___ Before After Page 72 o f 170 84 cai Servie'' Ion Ratio Confirmation p. 89 Created with Analyst Reporter Printed: 18/02/2010 3:24:00 PM K1001011-006 Before After Page 73 of 170 85 lym ba p. 90 Created with Analyst Reporter Printed: 18/02/2010 4:02:00 PM Project Data File Result Table Instrument Name Ewan's Projects\PFCs 021710\SamplesShort.wiff 021710short.rdb API 5000 Sample Name Acquisition Date Acquisition Method Injection Vial K1001011-006 2/18/2010 2:57:03 AM PFCkinetexShort.dam 30 Injection Volume Sample Type Dilution Factor Weight to Volume 5 Unknown 1.00 0.00 Results Summary Analyte Peak Name IS Name PFBA 1 13C-PFBA PFPeA 1 130-PFHxA PFBS 1 180-PFHS PFHxA 1 130-PFHxA PFHpA 1 130-PFHxA PFHxS 1 180-PFHS S_180-PFHS 13C-PFDA S_13C-PFDA 13C-PFDA IS Area 5352600 6600200 4103600 6600200 6600200 4103600 3952600 3952600 Analyte RT (Exp RT ) 1.24 (1.27) 3.53 (3.60) 4.19 (4.26) 5.24 (5.31) 6.15 (6.23) 6.24 (6.32) 6.24 (6.31) 7.54 (7.65) Analyte Area 355640 1000900 1388100 1867400 296690 8305800 4103600 3952600 Calc. Cone (ng/mL) 0.57 1.59 0.97 2.73 1.20 6.27 1.29 1.00 Modified? No No No No No No No No Page 69 of 169 86 ...................................................... f C olliftlllbiia *J Analytical San/icas" p. 91 Created with Analyst Reporter Printed: 18/02/2010 4:02:00 PM IRC Summary Analyte Peak Name PFBA2 PFPeA2 PFBS2 PFHxA 2 PFHpA2 PFHxS2 S_13C-PFBA S_13C-PFHxA RT (Exp R T ) 1.24(1.27) 3.53 (3.60) 4.19(4.26) 5.24(5.31) 6.14(6.22) 6.24 (6.32) 1.24(1.26) 5.24(5.30) Area 355640 1000900 520110 170640 869850 3252300 5352600 6600200 Modified? Calc (Exp) MRM Ratio No 1.00(1.00) Ratio Confirms ID YES No 1.00(1.00) YES No 0.37(0.40) YES No 0.09(0.10) YES No 2.93 (2.90) YES No 0.39(0.40) YES No 15.05(13.20) YES No 3.53(13.71) No Page 70 o f 169 87 Columbia Analytical Services' Quantitative Peak Review p. 92 Created with Analyst Reporter Printed: 18/02/2010 4:02:00 PM K1001011-006 PFBA 1 213.0/169.0 Da o Baseline c Missed n Wrnnn Ppak 4.19 i_ L 13C-PFBA 217.0/172.0 Da Baseline a Missed __ nWronn P.aak__ PFPeA 1 263.0/219.0 Da Baseline c Missed n Wrnnn Peak 13C-PFHxA 315.0/270.0 Da o Baseline u Missed ___h Wrnnn Peak___ PFBS 1 299.0/80.0 Da u Baseline c Missed r Wrnnn Peak 6.15 180-PFHS 403.0/103.0 Da Baseline Missed _______ 5^4________ PFHxA 1 313.0/269.0 Da c Baseline Missed Wrnnn Peak 13C-PFHxA 315.0/270.0 Da Baseline Missed r Wrnnn Peak nns bOti PFHpA 1 363.0/169.0 Da Baseline d Missed n Wrnnn Peak 13C-PFHxA 315.0/270.0 Da Baseline c Missed n Wrnnn Peak PFHxS 1 399.0/80.0 Da o Baseline Missed ____ n Wrnnn Peak___ 180-PFHS 403.0/103.0 Da a Baseline Missed n Wrnnn Peak S_180-PFHS 403.0/103.0 Da Baseline Missed ____ n Wrnnn Peak 13C-PFDA 515.0/470.0 Da Baseline Missed ___ n W rnnn Peak___ S_13C-PFDA 515.0/470.0 Da Baseline Missed ____ n W rnnn P eak___ Before After 13C-PFDA 515.0/470.0 Da Baseline Missed p W rnnn P e a k ___ Page 71 of 169 88 5ffe5' p. 93 Created with Analyst Reporter Printed: 18/02/2010 4:02:00 PM Ion Ratio Confirmation L1.24 PFBA2 213.0/169.0 Da Baseline Missed Wrong Peak ...... 6 .1 4 ....... PFPeA2 263.0/219.0 Da Baseline q Missed o Wrong Peak K1001011-006 PFBS2 299.0/99.0 Da Baseline c Missed a Wrong Peak PFHxA 2 313.0/119.0 Da o Baseline u Missed d Wrong Peak This mage is not avaiable PFHpA2 363.0/319.0 Da Baseline c Missed o Wrong Peak PFHxS2 399.0/99.0 Da Baseline Missed Wrong Peak S 13C-PFDA 515.0/470.0 Da Baseline Missed Wrong Peak NB. PFBA and PFPeA do not have qualifying ion transitions. Before After N/A o Baseline Missed Wrong Peak Page 72 of 169 89 Created with AnalysPpeporter Printed: 18/02/2010 3:24:00 PM Project Data File Result Table Instrument Name Ewan's Projects\PFCs 02171 OVSamplesLong.wiff 021710long.rdb API 5000 Sample Name Acquisition Date Acquisition Method Injection Vial K1001011-007 2/17/2010 8:54:00 PM PFCkinetexLong.dam 31 Injection Volume Sample Type Dilution Factor Weight to Volume 5 Unknown 1.00 0.00 Results Summary Analyte Peak Name IS Name PFOA 1 13C-PFOA PFNA 1 13C-PFNA PFOS 1 13C-PFOS PFDA 1 13C-PFDA PFUnA 1 13C-PFUnA PFDS 1 13C-PFOS PFDoA 1 13C-PFDOA PFTrA 1 13C-PFDOA PFTeA 1 13C-PFDOA IS Area 4304300 2764500 8288000 2890600 145620 8288000 235890 235890 235890 Analyte RT (Exp RT ) 1.20 (1.36) 2.00 (2.06) 2.03 (2.09) 3.03 (3.06) 3.85 (4.06) 3.89 (3.87) 0.00 (4.55) 5.07 (5.06) 5.33 (5.51) Analyte Area 1659700 8141200 27116000 51755 97691 4315 0 2351 2222 Calc. Cone (ng/mL) 7.630 27.100 30.600 0.165 0.610 0.025 N/A N/A N/A Modified? No No No No No No No No No tA "7 {I, r l ' ' Page 74 of 170 90 / C olum bia A nalytical S e rv fe sr p. 95 Created with Analyst Reporter Printed: 18/02/2010 3:24:00 PM IRC Summary Analyte Peak Name PFOA2 S_13C_PFOA PFNA 2 S_13C_PFNA PFOS2 SJ3C-PFOS PFDA 2 S_13C-PFDA PFUnA2 S_13C-PFUnA PFDS 2 PFDoA2 S_13C-PFDoA PFTrA 2 PFTeA2 RT (Exp RT ) 1.23(1.36) 1.23(1.36) 2.00 (2.08) 0.00(2.44) 2.02 (2.12) 2.03 (2.00) 3.08(3.06) 3.04(3.04) 3.87(3.88) 3.85(3.88) 0.00 (3.87) 0.00 (4.53) 4.51 (4.64) 5.11 (5.13) 5.48(5.56) Area 3306600 4304300 2605400 0 9011900 8288000 6556 2890600 17209 145620 0 0 235890 240 155 Modified? Calc (Exp) MRM Ratio No 1.99 (2.16) Ratio Confirms ID YES No 2.59 (43.19) No No 0.32(0.34) YES No 0.00(0.00) No No 0.33(0.32) YES No 0.31 (21.71) No No 0.13(0.14) YES No 55.85(17.53) No No 0.18(0.19) YES No 1.49(1.60) YES No 0.00 (0.32) No No 0.00(0.28) No No 0.00(3.71) No No 0.10(0.34) No No 0.07 (0.29) No Page 75 o f 170 p. 96 Created with Analyst Reporter Printed: 18/02/2010 3:24:00 PM Quantitative Peak Review K1001011-007 i J L i 2.00 1.99 i PFOA 1 413.0/169.0 Da Baseline c Missed r Wrnnn Paak 13C-PFOA PFNA 1 417.0/372.0 Da 463.0/419.0 Da Baseline Missed Baseline Missed lJL_ Ir Wrnnn Peak ___ i W rnnn Paak___ 3.03 13C-PFNA 468.0/423.0 Da Baseline c Missed r Wrnnn Peak___ 3.04 1 PFOS 1 499.0/80.0 Da Baseline c Missed r Wrnnn Paak 13C-PFOS 503.0/80.0 Da Baseline Missed n Wrnnn Peak PFDA 1 513.0/469.0 Da Baseline Missed n Wrnnn Peak 3.89 i 13C-PFDA 515.0/470.0 Da Baseline Missed r Wrnnn Paak L PFUnA 1 563.0/519.0 Da c Baseline u Missed ___p Wrnnn Peak___ 13C-PFUnA 565.0/270.0 Da Baseline u Missed ___n Wrnnn Peak i4.51 PFDS 1 599.0/80.0 Da Baseline Missed n Wrnnn Peak___ 13C-PFOS 503.0/80.0 Da Baseline g Missed ___n Wrnnn Peak___ 4^1 5.07 PFDoA 1 613.0/569.0 Da Baseline Missed n W rnnn Paak '-'i 13C-PFD0A 615.0/169.0 Da Baseline Missed n Wrnnn Peak 4.51 PFTrA 1 663.0/619.0 Da c Baseline Missed n W rnnn Peak 13C-PFDOA 615.0/169.0 Da Baseline Missed n Wrnnn Peak___ 5.33 PFTeA 1 713.0/669.0 Da Baseline o Missed ___ n Wrnnn Peak 1 13C-PFDOA 615.0/169.0 Da Baseline Missed ___n Wrnnn Peak___ Before After Page 76 of 170 92 Columbia Analytical Services1 Ion Ratio Confirmation p. 97 Created with Analyst Reporter Printed: 18/02/2010 3:24:00 PM K1001011-007 PFOA2 413.0/369.0 Da Baseline Missed c Wrong Peak PFNA2 463.0/219.0 Da Baseline Missed Wrong Peak PFOS 2 499.0/99.0 Da Baseline Missed c Wrong Peak PFDA2 513.0/269.0 Da c Baseline Missed g Wrong Peak PFUnA2 563.0/269.0 Da Baseline g Missed u Wrong Peak PFDS2 599.0/99.0 Da Baseline Missed d Wrong Peak PFDoA2 613.0/169.0 Da Baseline Missed Wrong Peak PFTrA 2 663.0/169.0 Da Baseline c Missed Wrong Peak PFTeA2 713.0/169.0 Da Baseline Missed g Wrong Peak Before After Page 77 o f 170 93 um fela p. 98 Created with Analyst Reporter Printed: 18/02/2010 4:02:00 PM Project Data File Result Table Instrument Name Ewan's Projects\PFCs 021710\SamplesShort.wiff 021710short.rdb API 5000 Sample Name Acquisition Date Acquisition Method Injection Vial K1001011-007 2/18/2010 3:06:37 AM PFCkinetexShort.dam 31 Injection Volume Sample Type Dilution Factor Weight to Volume 5 Unknown 1.00 0.00 Results Summary Analyte Peak Name IS Name PFBA 1 13C-PFBA PFPeA 1 13C-PFHXA PFBS 1 180-PFHS PFHxA 1 130-PFHxA PFHpA 1 13C-PFHXA PFHxS 1 180-PFHS SJ80-PFHS 13C-PFDA SJ3C-PFDA 13C-PFDA IS Area 4953300 6424100 4002000 6424100 6424100 4002000 4103700 4103700 Analyte RT (Exp RT ) 1.23 (1.27) 3.53 (3.60) 4.19 (4.26) 5.24 (5.31) 6.16 (6.23) 6.25 (6.32) 6.24 (6.31) 7.55 (7.65) Analyte Area 553800 1588500 1632700 3364400 742110 13858000 4002000 4103700 Calc. Cone (ng/mL) 1.00 2.60 1.16 5.12 3.17 11.00 1.21 1.00 Modified? No No No No No No No No -4 Page 73 of 169 94 / T Columbia 3 Analytical Sorvicos" p. 99 Created with Analyst Reporter Printed: 18/02/2010 4:02:00 PM IRC Summary j Analyte Peak Name PFBA2 PFPeA2 PFBS2 PFHxA 2 PFHpA2 PFHxS2 SJ3C-PFBA S_13C-PFHxA RT (Exp RT ) 1.23(1.27) 3.53 (3.60) 4.19(4.26) 5.24(5.31) 6.15(6.22) 6.25 (6.32) 1.23 (1.26) 5.24 (5.30) Area 553800 1588500 615480 306160 2304900 5615100 4953300 6424100 Modified? No Calc (Exp) MRM Ratio 1.00(1.00) Ratio Confirms ID YES No 1.00(1.00) YES No 0.38 (0.40) YES No 0.09(0.10) YES No 3.11 (2.90) YES No 0.41 (0.40) YES No 8.94 (13.20) No No 1.91 (13.71) No Page 74 o f 169 95 p. 100 Created with Analyst Reporter Printed: 18/02/2010 4:02:00 PM Quantitative Peak Review 1.23 PFBA 1 213.0/169.0 Da g Baseline c Missed n Wronn Peak 4.^ 1 13C-PFBA 217.0/172.0 Da Baseline o Missed ___n Wrnnn Peak___ K1001011-007 I PFPeA 1 263.0/219.0 Da Baseline Missed n Wrnnn Peak 5.^1 13C-PFHxA 315.0/270.0 Da a Baseline c Missed ___ n W rnnn Peak___ I PFBS 1 180-PFHS 299.0/80.0 Da 403.0/103.0 Da Baseline Missed Baseline Missed n Wrnnn Ppak n Wrnnn Peak__ _ _ _L6.16 ' c'*'5 4 5.24 1 PFHxA 1 313.0/269.0 Da Baseline Missed n Wrnnn Peak 13C-PFHXA 315.0/270.0 Da Baseline Missed r W rnnn Peak PFHpA 1 363.0/169.0 Da Baseline g Missed ___r Wrnnn Peak S_180-PFHS 403.0/103.0 Da Baseline Missed n W rnnn P eak___ 13C-PFHxA 315.0/270.0 Da Baseline Missed n Wrnnn Peak 7.^5 /0 .10 5 13C-PFDA 515.0/470.0 Da Baseline Missed n Wronn Peak_____ PFHxS 1 399.0/80.0 Da Baseline c Missed Wronn Pfiak 7.55 180-PFHS 403.0/103.0 Da Baseline Missed n W rnnn Peak___ l11. \ | 40fS 7.55 rii oo i `. S 13C-PFDA 515.0/470.0 Da Baseline Missed n W rnnn Peak_____ 13C-PFDA 515.0/470.0 Da O Baseline Miss n Wrnnn Peak Before After Page 75 of 169 96 S^rw km ' p. 101 Created with Analyst Reporter Printed: 18/02/2010 4:02:00 PM Ion Ratio Confirmation 1.23 3,53 1 PFBA2 213.0/169.0 Da u Baseline g Missed g Wrong Peak 6.15 ""I PFPeA2 263.0/219.0 Da c Baseline Missed c Wrong Peak K1001011-007 PFBS2 299.0/99.0 Da Baseline o Missed a Wrong Peak PFHxA 2 313.0/119.0 Da Baseline c Missed g Wrong Peak J _______ PFHpA2 363.0/319.0 Da Baseline Missed c Wrong Peak PFHxS2 399.0/99.0 Da Baseline Missed a Wrong Peak S_13C-PFDA 515.0/470.0 Da Baseline Missed Wrong Peak NB. PFBA and PFPeA do not have qualifying ion transitions. Before After N/A Baseline a Missed Wrong Peak Page 76 of 169 97 Columbia Analytical St p. 102 Created with Analyst Reporter Printed: 18/02/2010 3:24:00 PM Project Data File Result Table Instrument Name Ewan's Projects\PFCs 021710\SamplesLong.wiff 021710long.rdb API 5000 Sample Name Acquisition Date Acquisition Method Injection Vial K1001011-008 2/17/2010 9:01:32 PM PFCkinetexLong.dam 32 Injection Volume Sample Type Dilution Factor Weight to Volume 5 Unknown 1.00 0.00 Results Summary Analyte Peak Name IS Name PFOA 1 13C-PFOA PFNA 1 13C-PFNA PFOS 1 13C-PFOS PFDA 1 13C-PFDA PFUnA 1 13C-PFUnA PFDS 1 13C-PFOS PFDoA 1 13C-PFD0A PFTrA 1 13C-PFDOA PFTeA 1 13C-PFDOA IS Area 4647000 2994300 8178800 3090100 138370 8178800 214500 214500 214500 Analyte RT (Exp RT ) 1.21 (1.36) 1.94 (2.06) 2.00 (2.09) 3.03 (3.06) 0.00 (4.06) 3.84 (3.87) 4.52 (4.55) 5.03 (5.06) 5.48 (5.51) Analyte Area 14325 25104 121880 42135 0 89312 31849 18331 10051 Calc. Cone (ng/mL) 0.090 0.111 0.154 0.124 N/A 0.113 0.253 0.049 0.081 Modified? No No No No No No No No No > r,\^ "V' ? J ^ U Page 78 of 170 98 p. 103 Created with Analyst Reporter Printed: 18/02/2010 3:24:00 PM IRC Summary ! Analyte Peak Name PFOA2 S_13C_PFOA PFNA2 S_13C_PFNA PFOS2 S_13C-PFOS PFDA2 S_13C-PFDA PFUnA2 S_13C-PFUnA PFDS 2 PFDoA2 S_13C-PFDoA PFTrA 2 PFTeA2 RT (Exp R T ) 1.16 (1.36) 1.18(1.36) 1.97 (2.08) 0.00 (2.44) 1.99 (2.12) 2.00(2.00) 3.00 (3.06) 3.00 (3.04) 3.86(3.88) 3.83(3.88) 3.84 (3.87) 4.48 (4.53) 4.50 (4.64) 5.02(5.13) 5.49(5.56) Area 20062 4647000 7612 0 42672 8178800 6068 3090100 11006 138370 26821 8926 214500 3543 2113 Modified? No Calc (Exp) MRM Ratio 1.40(2.16) Ratio Confirms ID No No 324.40(43.19) No No 0.30(0.34) YES No 0.00 (0.00) No No 0.35(0.32) YES No 67.11 (21.71) No No 0.14(0.14) YES No 73.34(17.53) No No 0.00(0.19) No No 0.00(1.60) No No 0.30(0.32) YES No 0.28 (0.28) YES No 6.73(3.71) No No 0.19(0.34) No No 0.21 (0.29) No Page 79 o f 170 99 f i Columbia m Analytical Services" Quantitative Peak Review I PFOA 1 413.0/169.0 Da l Baseline g Missed ! Wronn Peak 13C-PFOA 417.0/372.0 Da Baseline g Missed r Wronn Pnak 2.00 PFOS 1 499.0/80.0 Da Baseline g Missed ; W rnnn Peak L 13C-PFOS 503.0/80.0 Da g Baseline Missed n Wrnnn Pnak Created with Analysf Reporter Printed: 18/02/2010 3:24:00 PM K1001011-008 1.94 PFNA 1 463.0/419.0 Da g Baseline g Missed r Wrnnn Peak 3.03 1 PFDA 1 513.0/469.0 Da u Baseline g Missed f :Wrnnn Peak 3^ 13C-PFNA 468.0/423.0 Da Baseline u Missed r Wmnn Peak 13C-PFDA 515.0/470.0 Da c Baseline Missed i Wmnn Peak PFUnA 1 563.0/519.0 Da a Baseline g Missed ___ n Wrnnn Peak 4.52 L PFDoA 1 613.0/569.0 Da Baseline u Missed n Wrnnn Pnak 13C-PFUnA 565.0/270.0 Da Baseline g Missed ___n Wrnnn Peak___ PFDS 1 599.0/80.0 Da c Baseline c Missed ___in Wmnn Peak 13C-PFDOA 615.0/169.0 Da a Baseline Missed n Wrnnn Peak 5.03 PFTrA 1 663.0/619.0 Da Baseline Missed n Wrnnn Peak L 13C-PFOS 503.0/80.0 Da o Baseline Missed r Wronn Peak___ 13C-PFDOA 615.0/169.0 Da Baseline Missed n W rnnn P eak___ - G 5.48 ,j____ JC PFTeAl 713.0/669.0 Da g Baseline Missed ___ n Wrnnn Peak 13C-PFD0A 615.0/169.0 Da g Baseline Missed n Wrnnn Peak Before After Page 80 of 170 100 Columbia Analytical i-ervices' Ion Ratio Confirmation p. 105 Created with Analyst Reporter Printed: 18/02/2010 3:24:00 PM K1001011-008 Before After Page 81 of 170 101 Columbia p. 106 Created with Analyst Reporter Printed: 18/02/2010 4:02:00 PM Project Data File Result Table Instrument Name Ewan's Projects\PFCs 021710\SamplesShort.wiff 021710short.rdb API 5000 Sample Name Acquisition Date Acquisition Method Injection Vial K1001011-008 2/18/2010 3:16:09 AM PFCkinetexShort.dam 32 Injection Volume Sample Type Dilution Factor Weight to Volume 5 Unknown 1.00 0.00 Results Summary Analyte Peak Name IS Name PFBA 1 13C-PFBA PFPeA 1 130-PFHxA PFBS 1 180-PFHS PFHxA 1 130-PFHxA PFHpA 1 13C-PFHxA PFHxS 1 180-PFHS SJ80-PFHS 13C-PFDA SJ3C-PFDA 13C-PFDA IS Area 5709700 7020500 3812500 7020500 7020500 3812500 3991000 3991000 Analyte RT (Exp RT ) 1.24 (1.27) 3.54 (3.60) 4.20 (4.26) 5.24 (5.31) 6.17 (6.23) 6.25 (6.32) 6.25 (6.31) 7.57 (7.65) Analyte Area 834270 446160 51257 175480 30008 91124 3812500 3991000 Calc. Cone (ng/mL) 1.33 0.66 0.06 0.19 0.06 0.06 1.18 1.00 Modified? No No No No No No No No Page 77 of 169 102 p. 107 Created with Analyst Reporter Printed: 18/02/2010 4:02:00 PM IRC Summary Analyte Peak Name PFBA2 PFPeA2 PFBS2 PFHxA 2 PFHpA2 PFHxS2 S_13C-PFBA S_13C-PFHxA RT (Exp R T ) 1.24(1.27) 3.54(3.60) 4.19(4.26) 5.25(5.31) 6.17(6.22) 6.25 (6.32) 1.23 (1.26) 5.25 (5.30) Area 834270 446160 18188 17312 86426 35546 5709700 7020500 Modified? No Calc (Exp) MRM Ratio 1.00(1.00) Ratio Confirms ID YES No 1.00(1.00) YES No 0.35(0.40) YES No 0.10(0.10) YES No 2.88 (2.90) YES No 0.39(0.40) YES No 6.84(13.20) No No 40.01 (13.71) No Page 78 of 169 103 Analytical Services" Quantitative Peak Review 1 23 p. 108 Created with Analyst Reporter Printed! 18/02/2010 4!Q2!00 PM K1001011-008 5.25 PFBA 1 213.0/169.0 Da Baseline l Missed i : Wronn Peak PFBS 1 299.0/80.0 Da Baseline c Missed r Wrnnn Pfiak 6.17 PFHpA 1 363.0/169.0 Da Baseline u Missed n Wrnnn Peak S_180-PFHS 403.0/103.0 Da o Baseline Missed ____ n W rn n n P aak___ i 13C-PFBA 217.0/172.0 Da t_ Baseline l Missed n Wronn Peak PFPeA 1 263.0/219.0 Da l Baseline l Missed 11 Wronn Peak I 180-PFHS 403.0/103.0 Da Baseline l Missed n Wrnnn Peak 13C-PFHXA 315.0/270.0 Da Baseline Missed ___r Wrnnn Peak___ i7.57 PFHxA 1 313.0/269.0 Da L* Baseline i_ Missed r Wrnnn Peak 6.25 i PFHxS 1 399.0/80.0 Da Baseline n Missed n Wrnnn Peak 7.57 13C-PFDA 515.0/470.0 Da Baseline Missed n W rnnn PRak___ S_13C-PFDA 515.0/470.0 Da c Baseline c Missed ____ n Wrnnn Peak Before After 13C-PFHxA 315.0/270.0 Da l: Baseline i_ Missed i Wronn Peak___ 13C-PFHXA 315.0/270.0 Da c Baseline Missed r. W rnnn P aak 6.2 180-PFHS 403.0/103.0 Da Baseline c Missed __ n Wrnnn Peak___ 13C-PFDA 515.0/470.0 Da c Baseline c Missed ____ n Wrnnn Peak___ Page 79 of 169 104 iym bia t* p. 109 Created with Analyst Reporter Printed: 18/02/2010 4:02:00 PM Ion Ratio Confirmation 1.24 ` 3.54................. K1001011-008 I V MW, 4. l : ->< ,, 0 >-'3 11 1 PFBA2 213.0/169.0 Da c Baseline c Missed g Wrong Peak PFPeA2 263.0/219.0 Da l Baseline Missed c Wrong Peak PFBS2 299.0/99.0 Da u Baseline l Missed u Wrong Peak PFHxA 2 313.0/119.0 Da c. Baseline Missed l' Wrong Peak - 6.17 ... Jt' ------ i .......... .... moo| 6. 55...... V PFHpA 2 363.0/319.0 Da c- Baseline c Missed l Wrong Peak PFHxS 2 399.0/99.0 Da Baseline Missed Wrong Peak S 13C-PFDA 515.0/470.0 Da D Baseline g Missed u Wrong Peak NB. PFBA and PFPeA do not have qualifying ion transitions. Before After Tte mage :s rid a # le N/A Baseline l Missed Wrong Peak Page 80 of 169 105 7$ di.JfT^5sS O Analytical Services1' p. 110 Created with Analyst Reporter Printed! 18/02/2010 3:24:00 PM Project Data File Result Table Instrument Name Ewan's ProjectsVPFCs 021710\SamplesLong.wiff 021710long.rdb API 5000 Sample Name Acquisition Date Acquisition Method Injection Vial K1001011-009 2/17/2010 9:09:05 PM PFCkinetexLong.dam 33 Injection Volume Sample Type Dilution Factor Weight to Volume 5 Unknown 1.00 0.00 Results Summary Analyte Peak Name IS Name PFOA 1 13C-PFOA PFNA 1 13C-PFNA PFOS 1 13C-PFOS PFDA 1 13C-PFDA PFUnA 1 13C-PFUnA PFDS 1 13C-PFOS PFDoA 1 13C-PFD0A PFTrA 1 13C-PFD0A PFTeA 1 13C-PFD0A IS Area 4349300 2971800 8394300 3320900 144110 8394300 236750 236750 236750 Analyte RT (Exp RT ) 1.26 (1.36) 2.04 (2.06) 2.06 (2.09) 3.05 (3.06) 3.87 (4.06) 3.87 (3.87) 4.49 (4.55) 5.05 (5.06) 5.51 (5.51) Analyte Area 342940 27925 1035000 31691 36253 75841 23760 12826 9011 Calc. Cone (ng/m L) 1.580 0.121 1.170 0.084 0.209 0.097 0.174 N/A 0.045 Modified? No No No No No No No No No 4 n\'- <7 'L I , a <c Page 82 of 170 106 Columbia Areivtkal Stn/icos1 p. 111 Created with Analyst Reporter Printed: 18/02/2010 3:24:00 PM IRC Summary Analyte Peak Name PFOA2 S_13C_PFOA PFNA 2 S_13C_PFNA PFOS 2 S_13C-PFOS PFDA2 S_13C-PFDA PFUnA2 S_13C-PFUnA PFDS2 PFDoA2 S_13C-PFDoA PFTrA 2 PFTeA2 RT (Exp RT ) 1.25(1.36) 1.26(1.36) 2.05 (2.08) 0.00(2.44) 2.06 (2.12) 2.07 (2.00) 3.05 (3.06) 3.07(3.04) 3.86(3.88) 3.87(3.88) 3.87(3.87) 4.50 (4.53) 4.51 (4.64) 5.05(5.13) 5.50(5.56) Area 618800 4349300 9231 0 336370 8394300 3070 3320900 7407 144110 25221 6379 236750 3090 2379 Modified? No Calc (Exp) MRM Ratio 1.80(2.16) Ratio Confirms ID YES No 12.68 (43.19) No No 0.33(0.34) YES No 0.00(0.00) No No 0.32(0.32) YES No 8.11 (21.71) No No 0.10 (0.14) YES No 104.79(17.53) No No 0.20(0.19) YES No 3.98 (1.60) No No 0.33(0.32) YES No 0.27 (0.28) YES No 9.96(3.71) No No 0.24(0.34) No No 0.26(0.29) YES Page 83 of 170 107 Columbia Analytical Services*1 Quantitative Peak Review p. 112 Created with Analyst Reporter Printed: 18/02/2010 3:24:00 PM K1001011-009 2.04 PFOA 1 13C-PFOA 413.0/169.0 Da 417.0/372.0 Da D Baseline l Missed i_ Baseline Missed r Wronn Peak ___h Wrnnn Peak___ i^L I ^ PFOS 1 499.0/80.0 Da Baseline l Missed n W ronn Peak 13C-PFOS 503.0/80.0 Da Baseline Missed r Wrnnn Peak PFNA 1 463.0/419.0 Da Baseline l Missed ii Wrnnn Peak PFDA 1 513.0/469.0 Da l Baseline c Missed n Wrnnn Peak 13C-PFNA 468.0/423.0 Da u Baseline l Missed ___' Wronn Peak___ 3.07 13C-PFDA 515.0/470.0 Da l Baseline c Missed n Wrnnn Peak PFUnA 1 563.0/519.0 Da Baseline l Missed ___' i Wronn Peak 13C-PFUnA 565.0/270.0 Da Baseline l Missed ___r Wrnnn Peak___ PFDS 1 599.0/80.0 Da o Baseline c Missed ___n Wrnnn Peak___ 13C-PFOS 503.0/80.0 Da Baseline Missed ___n Wronn Peak___ 4.49 JL PFDoA 1 613.0/569.0 Da o Baseline Missed n Wrnnn Peak 13C-PFDOA 615.0/169.0 Da Baseline Missed n Wrnnn Peak 5.05 4k PFTrA 1 663.0/619.0 Da Baseline Missed ___ n W rnnn Peak 13C-PFDOA 615.0/169.0 Da c Baseline Missed ___ r W rnnn P e a k 5.51 PFTeA 1 713.0/669.0 Da u Baseline Missed i : Wrnnn Paak 13C-PFDOA 615.0/169.0 Da Baseline Missed n Wrnnn Peak Before After Page 84 o f 170 108 p. 113 Created with Analyst Reporter Printed: 18/02/2010 3:24:00 PM iIon Ratio Confirmation f: km 1 2k PFOA2 413.0/369.0 Da u Baseline Missed c Wrong Peak PFNA2 463.0/219.0 Da Baseline Missed Wrong Peak . A ym' 1 '* 1 3. 86 ^ a. 7* *,' zi;CjiilUO.......... .Dili 3.E PFUnA 2 563.0/269.0 Da Baseline Missed u Wrong Peak PFDS2 599.0/99.0 Da Baseline c Missed Wrong Peak K1001011-009 A f J --- / - v-4\............ i' rj lit .11... L. PFOS2 499.0/99.0 Da Baseline c Missed g Wrong Peak PFDA2 513.0/269.0 Da Baseline Missed Wrong Peak PFDoA2 613.0/169.0 Da Baseline a Missed Wrong Peak PFTrA 2 663.0/169.0 Da Baseline Missed c Wrong Peak PFTeA2 713.0/169.0 Da Baseline Missed c Wrong Peak Before After Page 85 o f 170 109 p. 114 Created with Analyst Reporter Printed: 18/02/2010 4:02:00 PM Project Data File Result Table Instrument Name Ewan's ProjectsVPFCs 021710\SamplesShort.wiff 021710short.rdb API 5000 Sample Name Acquisition Date Acquisition Method Injection Vial K1001011-009 2/18/2010 3:25:43 AM PFCkinetexShort.dam 33 Injection Volume Sample Type Dilution Factor Weight to Volume 5 Unknown 1.00 0.00 Results Summary Analyte Peak Name IS Name PFBA 1 13C-PFBA PFPeA 1 13C-PFHXA PFBS 1 180-PFHS PFHxA 1 13C-PFHXA PFHpA 1 130-PFHxA PFHxS 1 180-PFHS SJ80-PFHS 13C-PFDA S_13C-PFDA 13C-PFDA IS Area 5305500 6678100 4186200 6678100 6678100 4186200 4326800 4326800 Analyte RT (Exp RT ) 1.22 (1.27) 3.53 (3.60) 4.20 (4.26) 5.24 (5.31) 6.16 (6.23) 6.25 (6.32) 6.25 (6.31) 7.57 (7.65) Analyte Area 176570 477230 449130 691860 160730 2087100 4186200 4326800 Calc. Cone (ng/mL) 0.26 0.74 0.32 0.96 0.62 1.50 1.20 1.00 Modified? No No No No No No No No >fc. Ns Page 81 of 169 110 p. 115 Created with Analyst Reporter Printed: 18/02/2010 4:02:00 PM IRC Summary Analyte Peak Name PFBA2 PFPeA2 PFBS2 PFHxA2 PFHpA2 PFHxS2 S_13C-PFBA S_13C-PFHxA RT (Exp RT ) 1.22(1.27) 3.53 (3.60) 4.20 (4.26) 5.24 (5.31) 6.16(6.22) 6.25 (6.32) 1.23(1.26) 5.25 (5.30) Area 176570 477230 168740 61577 472420 818380 5305500 6678100 Modified? No Calc (Exp) MRM Ratio 1.00(1.00) Ratio Confirms ID YES No 1.00(1.00) YES No 0.38(0.40) YES No 0.09(0.10) YES No 2.94(2.90) YES No 0.39(0.40) YES No 30.05(13.20) No No 9.65(13.71) No Page 82 o f 169 111 p. 116 Created with Analyst Reporter Printed: 18/02/2010 4:02:00 PM Quantitative Peak Review K1001011-009 3.53 l**. i. l PFBA 1 213.0/169.0 Da Baseline Missed n Wrnnn Peak 4.20 I OS 10 i s id 13C-PFBA 217.0/172.0 Da Baseline Missed n Wrnnn Peak 6.^5 I PFPeATM1 263.0/219.0 Da Baseline Missed p Wrnnn Peak I5$ 5.24 jf. SO 55 >: 13C-PFHxA 315.0/270.0 Da (I Baseline Missed n Wrnnn Peak ! US' 5.25 >>.*6 i ilfcS .UeC 1 i 4`, 5(146 55 6.0 SS ' ll PFBsT 299.0/80.0 Da o Baseline Missed n Wrnnn Peak 6.^5 180-PFHS 403.0/103.0 Da Baseline Missed n Wrnnn Peak I S- 5.^5 r ' 0*5 46 ` 0 55 60 PFHxAl 313.0/269.0 Da Baseline c Missed n Wrnnn Peak 5S I i 13C-PFHxA 315.0/270.0 Da Baseline Missed n Wrnnn Peak i 8 0e5 ^ (.<*5 -ms II PFHpAI 363.0/169.0 Da d Baseline o Missed n Wrnnn Peak 6.^5 13C-PFHxA 315.0/270.0 Da Baseline Missed n Wrnnn Peak 7.57 1t*6 PFHxS 1 399.0/80.0 Da Baseline Missed i:(, n Wrnnn Peak 7.57 I lle 180-PFHS 403.0/103.0 Da Baseline Missed n Wrnnn Peak 7.^7 . CM-, :os J htws i 40*'. ill IS -til 85 l i 045 S 180-PFHS 403.0/103.0 Da c Baseline Missed _____ n Wrnnn Peak_____ 13C-PFDA 515.0/470.0 Da Baseline Missed n Wrnnn Peak S 13C-PFDA 515.0/470.0 Da Baseline Missed n Wrnnn Peak_____ 13C-PFDA 515.0/470.0 Da Baseline Missed n Wrnnn Peak__ Before After Page 83 of 169 112 Columbia &?saiytfcai p. 117 Created with Analyst Reporter Printed: 18/02/2010 4:02:00 PM Ion Ratio Confirmation i1.22 ...... if.'SH ^ 6CM ..... 3,53............... t K1001011-009 PFBA2 213.0/169.0 Da Baseline Missed Wrong Peak PFPeA2 263.0/219.0 Da Baseline Missed Wrong Peak PFBS2 299.0/99.0 Da Baseline a Missed Wrong Peak UMJT,1-. 80? 1-- PFHxA 2 313.0/119.0 Da d Baseline a Missed Wrong Peak PFHpA2 363.0/319.0 Da Baseline c Missed c Wrong Peak PFHxS2 399.0/99.0 Da d Baseline Missed Wrong Peak S_13C-PFDA 515.0/470.0 Da Baseline Missed Wrong Peak NB. PFBA and PFPeA do not have qualifying ion transitions. Before After N/A Baseline Missed Wrong Peak Page 84 of 169 113 Created with Analyst Reporter Printed: 18/02/2010 3:24:00 PM Project Data File Result Table Instrument Name Ewan's Projects\PFCs 021710\Samplesl_ong .wiff 021710long.rdb API 5000 Sample Name Acquisition Date Acquisition Method Injection Vial K1001011-010 2/17/2010 9:16:38 PM PFCkinetexLong.dam 34 Injection Volume Sample Type Dilution Factor Weight to Volume 5 Unknown 1.00 0.00 Results Summary Analyte Peak Name IS Name PFOA 1 13C-PFOA PFNA 1 13C-PFNA PFOS 1 13C-PFOS PFDA 1 13C-PFDA PFUnA 1 13C-PFUnA PFDS 1 13C-PFOS PFDoA 1 13C-PFDOA PFTrA 1 13C-PFDoA PFTeA 1 13C-PFDOA IS Area 4380800 2895200 7862300 3007600 138820 7862300 209670 209670 209670 Analyte RT (Exp RT ) 1.19 (1.36) 0.00 (2.06) 2.01 (2.09) 2.99 (3.06) 3.88 (4.06) 3.85 (3.87) 0.00 (4.55) 5.08 (5.06) 5.36 (5.51) Analyte Area 3426 Calc. Cone (ng/mL) 0.044 0 N/A 21458 v m s?----- - 0.041 rrm r NO 5049 0.026 0 N/A 5662 N/A 4857 N/A Modified? No No No No No No No No No *7 fA Page 86 of 170 114 lumbia p. 119 Created with Analyst Reporter Printed: 18/02/2010 3:24:00 PM IRC Summary i Analyte Peak Name PFOA2 S_13C_PFOA PFNA2 S_13C_PFNA PFOS2 SJ3C-PFOS PFDA2 SJ3C-PFDA PFUnA2 S_13C-PFUnA PFDS 2 PFDoA2 S_13C-PFDoA PFTrA 2 PFTeA2 RT (Exp RT ) 1.57(1.36) 1.20(1.36) 2.14(2.08) 0.00 (2.44) 2.14(2.12) 2.00 (2.00) 3.06 (3.06) 3.04(3.04) 0.00(3.88) 3.85(3.88) 0.00 (3.87) 0.00 (4.53) 4.50 (4.64) 5.02 (5.13) 5.50 (5.56) Area 2586 4380800 152 0 574 7862300 737 3007600 0 138820 0 0 209670 424 359 Modified? No Calc (Exp) MRM Ratio 0.75 (2.16) Ratio Confirms ID No No 1278.58 (43.19) No No 0.00 (0.34) No No 0.00 (0.00) No No 0.03 (0.32) No No 366.40(21.71) No No 0.06 (0.14) No No 244.30(17.53) No No 0.00(0.19) No No 12.44(1.60) No No 0.00(0.32) No No 0.00(0.28) No No 0.00 (3.71) No No 0.07 (0.34) No No 0.07 (0.29) No Page 87 of 170 115 Services' Quantitative Peak Review 1.19 1.20 p. 120 Created with Analyst Reporter Printed: 18/02/2010 3:24:00 PM K1001011-010 PFOA 1 413.0/169.0 Da c Baseline a Missed n Wrnnn Peak 2.01 1 13C-PFOA 417.0/372.0 Da Baseline Missed n Wrnnn Peak PFOS 1 499.0/80.0 Da Baseline Missed n Wrnnn Ppak A/ 3.88 J* 13C-PFOS 503.0/80.0 Da Baseline c Missed n Wrnnn Peak PFNA 1 463.0/419.0 Da X Baseline o Missed n W rnnn Peak Ar V!.<!/ '\i 'v . c,IKlj| PFDA 1 513.0/469.0 Da Baseline o Missed n Wrnnn Peak 3.85 PFUnA 1 563.0/519.0 Da u Baseline d Missed ___n Wrnnn Peak___ PFDoA 1 613.0/569.0 Da Baseline Missed n Wrnnn Peak 5.36 PFTeA 1 713.0/669.0 Da Baseline Missed ___n Wrnnn Peak 13C-PFUnA 565.0/270.0 Da d Baseline Missed n Wronn Peak___ PFDS 1 599.0/80.0 Da o Baseline Missed J,.Wronn Peak fj9 5.08 13C-PFDOA 615.0/169.0 Da Baseline g Missed n Wrnnn Peak I_l_4.50 PFTrA 1 663.0/619.0 Da Baseline Missed n Wrnnn Peak 13C-PFD0A 615.0/169.0 Da Baseline Missed __ n Wrnnn Peak___ Before After L 13C-PFNA 468.0/423.0 Da o Baseline Missed n Wronn Peak Ii 3.04 13C-PFDA 515.0/470.0 Da Baseline Missed n Wrnnn Ppak L 13C-PFOS 503.0/80.0 Da c Baseline Missed n Wrnnn Peak___ 13C-PFDOA 615.0/169.0 Da o Baseline a Missed ___ n W rnnn Peak___ Page 88 of 170 116 fumbla Ion Ratio Confirmation p. 121 Created with Analyst Reporter Printed: 18/02/2010 3:24:00 PM K1001011-010 Before After Page 89 of 170 117 p. 122 Created with Analyst Reporter Printed: 18/02/2010 4:02:00 PM Project Data File Result Table Instrument Name Ewan's Projects\PFCs 021710\SamplesShort.wiff 021710short.rdb API 5000 Sample Name Acquisition Date Acquisition Method Injection Vial K1001011-010 2/18/2010 3:35:15 AM PFCkinetexShort.dam 34 Injection Volume Sample Type Dilution Factor Weight to Volume 5 Unknown 1.00 0.00 Results Summary Analyte Peak Name IS Name PFBA 1 13C-PFBA PFPeA 1 130-PFHxA PFBS 1 180-PFHS PFHxA 1 13C-PFHxA PFHpA 1 130-PFHxA PFHxS 1 180-PFHS SJ80-PFHS 13C-PFDA S_13C-PFDA 13C-PFDA IS Area 5107100 6588200 4088400 6588200 6588200 4088400 4282000 4282000 Analyte RT (Exp RT ) 1.23 (1.27) 3.54 (3.60) 0.00 (4.26) 5.25 (5.31) 6.17 (6.23) 6.27 (6.32) 6.26 (6.31) 7.56 (7.65) Analyte Area 56395 31211 0 52290 15278 47817 4088400 4282000 Calc. Cone (ng/mL) 0.04 0.04 N/A 0.02 0.01 0.02 1.18 1.00 Modified? No No No No No No No No V` -2 //iff Page 85 o f 169 118 p. 123 Created with Analyst Reporter Printed: 18/02/2010 4:02:00 PM IRC Summary Analyte Peak Name PFBA2 PFPeA2 PFBS2 PFHxA 2 PFHpA2 PFHxS2 S_13C-PFBA S_13C-PFHxA RT (Exp R T ) 1.23(1.27) 3.54 (3.60) 0.00(4.26) 0.00(5.31) 6.18(6.22) 6.26 (6.32) 1.23(1.26) 5.25(5.30) Area 56395 31211 0 0 51983 18742 5107100 6588200 Modified? No Calc (Exp) MRM Ratio 1.00(1.00) Ratio Confirms ID YES No 1.00(1.00) YES No 0.00(0.40) No No 0.00(0.10) No No 3.40(2.90) YES No 0.39 (0.40) YES No 90.56(13.20) No No 125.99(13.71) No Page 86 of 169 119 p. 124 Created with Analyst Reporter Printed: 18/02/2010 4:02:00 PM Quantitative Peak Review i1.23 1.23 1 PFBA 1 213.0/169.0 Da Baseline Missed n W rnnn Peak 13C-PFBA 217.0/172.0 Da Baseline Missed n Wrnnn Ppak K1001011-010 PFPeA 1 263.0/219.0 Da Baseline Missed n Wrnnn Ppak 13C-PFHxA 315.0/270.0 Da Baseline Missed n Wrnnn Peak PFBS 1 299.0/80.0 Da Baseline o Missed n Wrnnn Pnak I PFHpA 1 363.0/169.0 Da Baseline c Missed ___ n Wrnnn Peak___ 180-PFHS 403.0/103.0 Da Baseline Missed n Wrnnn Ppak 13C-PFHxA 315.0/270.0 Da c Baseline Missed __ n Wrnnn Peak PFHxA 1 313.0/269.0 Da Baseline c Missed r: W rnnn Ppak i6.27 PFHxS 1 399.0/80.0 Da c Baseline Missed n W r n n n Peak SCiS S_180-PFHS 403.0/103.0 Da Baseline Missed ___ r W rnnn Ppak___ 13C-PFDA 515.0/470.0 Da Baseline Missed n W rnnn P eak___ S_13C-PFDA 515.0/470.0 Da c Baseline Missed n Wrnnn Ppak Before After 13C-PFHxA 315.0/270.0 Da Baseline g Missed n Wrnnn Ppak 180-PFHS 403.0/103.0 Da Baseline c Missed n Wrnnn Peak___ .L 13C-PFDA 515.0/470.0 Da a Baseline Missed n W rnnn P e a k___ Page 87 of 169 120 p. 125 Created with Analyst Reporter Printed: 18/02/2010 4:02:00 PM Ion Ratio Confirmation 1.23. 3.54 K1001011-010 PFBA2 213.0/169.0 Da a Baseline Missed Wrong Peak W v* PFPeA2 263.0/219.0 Da Baseline Missed Wrong Peak PFBS2 299.0/99.0 Da Baseline Missed Wrong Peak PFHxA 2 313.0/119.0 Da a Baseline Missed c Wrong Peak ......6. 26................. 6.18 ............. IV.... .......... PFHpA2 363.0/319.0 Da Baseline Missed Wrong Peak 6C *inrPFHxS2 399.0/99.0 Da Baseline Missed Wrong Peak S_13C-PFDA 515.0/470.0 Da Baseline Missed Wrong Peak NB. PFBA and PFPeA do not have qualifying ion transitions. Before After This rnage is not avaiable N/A Baseline Missed Wrong Peak Page 88 o f 169 121