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BFGoodrich The BFGooclrteh Company 3925 Embassy Partway Akron, Ohio 44313-1799 /\f\) ~'5'Lp9'f1 September 18, 1991 Mr. Ron Anderson FESD, MPI, FSIS USDA Washington, D.C. 20205 SUBJECT: 8700 A BLACK 288 Dear Mr. Anderson: One of our customers. Dynamic Closures, is requesting USDA acceptance of an insulation door (dock door) installed in a meat packing plant. In support of their petition we are providing for your evaluation the confidential composition of 8700A Black 288 which is used in this product. Because one of the ingredients in our product is proprietary, we have requested that the Supplier, Witco Chemical, (MSDS attached) forward to you additional information on this tin mercaptide. Please call me at 216 374-4534 if additional data is needed. Sincerely, THE BFGOODRICH COMPANY Rvuci. u <v. miiuci. C4. , ru w < Manager, Health & Toxicology Environment, Health and Safety Management Systems bcc: Eric Whitewood (Dynamic Closures) BFG52225 i M l: O ai oo BFGOODRICH CONFIDENTIAL COMPOSITION OF 8700 A BLACK 288 INGREDIENT Geon Resin 30 Hycar 1430X20 WEIGHT % 80.821 4.344 21 CFR Prior Sanction No FDA Approval (MSDS Attached) Goodrite 2301 Tin Mercaptide 4.097 1.639 175.105/ 177.1200 175.300/177.1210 175.320/181.32 176.180 No FDA Approval (MSDS Attached)* Super-PFlex 200 6.146 175.300/177.1650 175.390/177.2260 176.170/177.2600 177.1210/177.2800 177.1350/178.3297 177.1460/181.30 Black 1CB-81 MB: 103EPF76 Resin Monarch 880 (Furnace Black Med. Color) CAS.NO. 1333-86-4 Calcium StearateFused Sanctioned) 1.315 1.639 Prior Sanction 177.2600 177.2600 178.2010 181.29(Prior * Witco to submit to USDA the proprietary formulation for Tin Mercaptide (S-20) they supply BFG. 22505002 BFG52226 1 Hycar Elastomers -7/0 70 l 7/o-pi c Form Number 11 ?Y2- MATERIAL SAFETY DATA SHEET HYCAR<*> ELASTOMERS: 1010X46 1430X20 MSDS Number: 88159 Issue date: NOVEMBER* 1988 Manufacturer The BPGoodrich Company Elastomers & Latex Division 6100 Oak Tree Blvd. Cleveland, OH 44131 Telephone: 1-800-528-0200 Chemical Name/Synonyms Elastomeric (nitrile) copolymer TCSCA Status On EPA Inventory CAS Registry No. 9003-18-3 Transportation Emergency Telephone CHEMTREC: (800) 424-9300 Formula CH2 CH:CH (GHz)2 CH(CN) SECTION II - HAZARDOUS INGREDIENTS/IDEOTITY INFORMATION All additives (except dusting agent) are physically bound in the compound during manufacturing and are not expected to create any hazard when the product is handled and processed in accordance with good manufacturing and industrial hygiene practice and by following the guidelines in this bulletin. Small amounts of the following may be present: - Acrylonitrile - Butadiene - Styrene - Talc (dusting agent present on 1430X20) C.A.S. Number 107-13-1 106-99-0 100-42-5 ----- Amount in Product* <20 ppm < 5 ppm <0.01% 3-7% ACGIH TLV-TWA 2 ppm, A2, skin 10 ppm, A2 50 ppm OSHA PEL 2 ppm 1,000 ppm** 100 ppm 2 rag/mJ 20 Mppcf * Typical amount - not a specification. ** OSHA intends to lower this value but has not proposed a specific limit. (SEE PAGE 2 FOR EXPLANATORY NOTES) BFG52227 u\ cn oo o Tha BFGoodrieh Company, Chemical Group/6100 Oak Tree Blvd.. Cleveland. Ohio 44131 INFGoodrich Chemical Group Th intormaitoo conm*rwd heroin b boltovod to b* roUabio. MnanpmManani. guaronim. or wononno. oIany kind we mod* a. to Htoeeuiaey. tuMbikly tor pcrfeutor appbcahont or iho tetulM to bo obtained thorofcom The intentwston It bOMd on loCoiorory work mih tmalW tcolo oquiprrdol and dot not noc.ioarily todieor. ond product portormpnco. Become ot the vondton* in motoodo cendMOA. and tqwpnMl wed commereiolly in presetting Ihete matototo. no .aronw or yujinn t mad. ot to iho tutaddry at ih producrt lor iho op- plication, dwtoted Full-tea** iomg end ond product performance an iho retpontibriitr o* ih aw. BfGoodrich dwH not bo Habto torand *m motomor aaumm ok ntk ond lio&ny ol Qny um or handling et any moWrtd beyond BFCoodieh't dkoc* eonaei. THE SELLER MAKES NO WARRANTIES. EXPRESS OR IMPLIED, NCLUDMO. BUT NOT UMITED TO. THE <MPUEO WARRANTIES OF MERCHANTABUTY ANO FITNESS FOR A PARTICULAR PURPOSE, Nothing contained herein It to bo eonbdered Ol ptnniwiijn. lecoovnendoMA. not at an uv cbcomonr to prooecowtypoiontodlnor*on Meow punbitonol too paten* oumor PFTENTIONCODE 704JDOC 1 Explanatory Notea: - TLV-TVA: Threshold Limit Value * Time Weighted Average for concentration of the chemical substance in the ambient workplace air for a normal 8-hour workdayi 40-hour workweek* to which nearly all workers may be repeatedly exposed without adverse effect. American Conference of Governmental Industrial Hygienists* 1988/1989 Edition. - QSg&_EEL: OSHA Permissible Exposure Limit* 8-hour TWA. 29CFR1910.1000 and 1910.1045. - The "skin" notation calls attention to the skin as an additional significant route of absorption of the listed chemical. - A2 means "suspected human carcinogen" (ACGIH) SECTION III - PHYSICAL/CHEMICAL CHARACTERISTICS (Typical data, not specifications) Boiling Point Not applicable (NA) eH NA Specific Gravity (HzO^l) 0.95-1.02 Solubility in Water Insoluble Vapor Density (Air=l) NA X Volatile by Weight <1% (moisture) Vapor Pressure NA Appearance and Odor 1010X46: Cream colored slab. 1430X20: Light brown powder. Mild odor is characteristic. SECTION IV - FIRE AND EXPLOSION HAZARD DATA Flash Point NA Ignition Temperature 700F (373C)* * ASTM D-1929 Flamnahle Limits; Lower explosion limit: NA Upper explosion limit: NA * Result obtained on Hycar* 1092-80. It is considered to be representative of the typical value expected for all Hycara nitrile elastomers. Extinguishing Media Water. ABC dry chemical. Protein type air foams. Hycar* nitrile elastomers would be considered "ordinary combustibles" (NFPA defined Class A). Carbon dioxide is generally not recommended for use on Class A fires as a lack of cooling capacity may result in reignition. Special Firefighting Procedure Wear positive pressure self-contained breathing apparatus (SCBA). Personnel not having suitable respiratory protection must leave the area to prevent significant exposure to toxic combustion gases from any source. In enclosed or poorly ventilated areas, wear SCBA during cleanup immediately after a fire as well as during the attack phase of firefighting operations. Unusual Fire and Explosion Hazards None expected for elastomer as delivered. NOTE: As delivered, powder elastomers do ;.ot represent a dust explosion hazard based on tests using the Hartmann vertical tube apparatus. These elastomers do not contain "fines," or dust, of sufficient particle size or amount to propagate ignition by this method of test. 22505004 2- - BpG52228 MSDS 88159 CAUTION; Grinding powder elastomers may produce particles 1 enough to create a dust explosion potential. As the need exists, implement standard safety precautions for handling finely divided powders such as eliminating likely sources of ignition , including static buildup, providing adequate ventilationi properly maintaining and operating dust control devices, and properly bonding and grounding processing equipment. SECTION V ^ REACTIVITY DATA stability Stable Hazardous Polymerization Will not occur Incompatibility Conditions to avoid: Overheating Materials to avoid: None known Decomposition Products 00, 002, HCN and small amounts of aromatic and aliphatic hydrocarbons. Combustion products from rubber, like those of other natural and synthetic materials, must be considered toxic. SECTION VI - HEALTH HAZARD DATA Threshold Limit Value None established by OSHA or ACGIH. Carcinogenicity Products not listed by IARC, NTP or OSHA. Acute Health Effects None known. Chronic Health Effects None known. Medical Conditions Aggravated by Exposure None known for product as delivered. Routes of Entry Inhaling process vapors. Skin contact. Effects of Overexposure - None expected at ambient temperature. Talc (dust) may cause eye irritation in the same manner as nuisance dust. Dust can cause shortness of breath, chronic cough or upper respiratory tract irritation. - No adverse health effects are expected during normal processing when potential exposures are eliminated by good industrial hygiene practice and well ventilated conditions. At processing temperatures, the sum total of all ingredients may emit fumes and vapors that may cause irritation to the respiratory tract, eyes and/or skin of sensitive people. Typically, these effects are reversible upon removal from exposure and no lasting effects are expected. Most importantly, the potential for irritation will depend on the effectiveness of exhaust ventilation provided to the process area. - Overexposure to decomposition or combustion products will cause irritation of the respiratory tract, eyes and skin. Symptoms such as coughing, taring, and irritation should be regarded as potentially hazardous and measures taken to avoid exposure. Emergency and First Aid Procedure - Eve Contact: Treat as any foreign particulate matter. - Skin Contact: Wash skin with soap and wate3. No effects requiring first aid are expected. - Dust Inhalation: Remove individual to fresh air. NOTE: For any of the above, if irritation develops, see a physician. If irritation persists from exposure to processing vapors or decomposition products, remove the affected individual from the area. Call a physician. Provide protection before allowing reentry. BFG52229 3 MSDS 88159 1 22505005 i SECTION VII - PRECAUTIONS FOR SAFE HANDLING AND STORAGE Steps to be taken in case material i3_ released or spilled Pick up slabs. Sweep, shovel or vacuum powder, crumbs or chunks into containers for reuse or disposed.. Waste Disposal Method Landfill or incineration in accordance with federal, state and local regulations. These products are not defined or designated as hazardous by current provisions of the Federal (EPA) Resource Conservation and Recovery Act (RjCRA, 40CFR261) . Precautions to be takers in handling and storage - Avoid breathing dust. - Avoid eye contact and repeated or prolonged skin contact. - Normal Melt Processing. Virtually all elastomers will emit fumes and/or vapors when heated to processing temperatures. The concentration and composition of these vapors will depend upon variables such as the specific formulation and processing method and temperature. Always use Hycar4 elastomers under well ventilated conditions and avoid continued or prolonged breathing of process vapors. For personal hygiene, wash thoroughly after processing compound, especially before eating, smoking or using toilet facilities. Do not store or consume food in processing areas. Do not use processing equipment to heat food. - Cleanup following normal processing should be performed under well ventilated conditions. Elastomer may be held at process temperatures for a short time without significant thermal degradation. However, it should be noted that exposure to either elevated temperature or excessive heat history (time) will result in decomposition. Equipment should not be shut down for extended time periods with compound in it or decomposition will occur. - Processing fume condensates, which may include toxic contaminants, may be combustible and should be periodically removed from exhaust hoods, ductwork and other surfaces. Protective clothing, including rubber gloves, should be worn during cleanup operations to prevent skin contact. - Store in a cool, dry place away from direct light to maintain quality. - Abnormal conditions such as equipment malfunction or using improper equipment or procedures, or hangup or stagnation of material during processing may cause decomposition. Einployees involved in removing decomposing material should be provided suitable air-supplied respirators, such as NIOSH/MSHA approved positive pressure self-contained breathing apparatus. - Compounding ingredients purchased to add to Hycar4 elastomer may require special handling. It is your responsibility to follow the recommended precautions of the individual additive suppliers. - Post-processing operations at your workplace or at your customer's workplace involving heat sufficient to result in polymer breakdown emitting smoke and fumes should always be conducted in such a manner to avoid inhalation of fumes. Local exhaust ventilation should be provided to prevent significant employee exposure. 22505006 BFG52230 -4 MSDS 88159 SECTION VIII - OONIBCL MEASURES Ventilation Effective general and, if necessary, local exhaust ventilation must always be provided to draw fumes or vapors away from workers to prevent routine inhalation* Ventilation must be adequate to maintain the ambient workplace atmosphere below the limits listed in Section II. Ventilation guidelines/techniques may be found in publications such as Industrial Ventilation. 19th Edition, American Conference of Governmental Industrial Hygienists, 6500 Glenway Avenue, Bldg* D-7, Cincinnati, OH 45211-4438 ($20.00 as of October, 1988). Respiratory Protection Not typically required. If protection against dust is necessary, wear a particulate respirator approved by NIOSH/MSHA. Abnormal conditions such as equipment malfunction, use of improper equipment or procedures, or hangup or stagnation of compound during processing may cause decomposition. If general or local exhaust ventilation is not adequate to keep fume or vapor concentrations at nonirritating levels, then employees involved in removing decomposing material must be provided with suitable air supplied respirators, such as NIOSH/MSHA approved positive pressure self-contained breathing apparatus. Protective Equipment - Safety glasses (goggles suitable for keeping dust out of the eyes when handling powdered rubber). - Protective gloves. SECTION IX - TRANSPORTATION For domestic transportation purposes, these products are not defined or designated as a hazardous material by the U.S. Department of Transportation under Title 49 of the Code of Federal Regulations, 1986 Edition. - DOT Proper Shipping Name: Not applicable - DOT Hazard Class: Not applicable - DOT Label: Not applicable - UN/NA Hazard No.: Not applicable - Reportable Quantity (RQ): Not applicable SECTION' X - HAZARD CODES NFPA 704* Health; Flammability: Reactivity: Special: 2 1 0 None HMIS** Health: Flammability: Reactivity: Personal Protection: 0 1 0 B Key: 0 = insignificant; 1 = slight; 2 = moderate; 3 = high; 4 = extreme. * National Fire Protection Association rating identifies the severity of hazards of material during a fire emergency (i.e., "on fire"). ** Hazardous Materials Identification System, National Paint and Coatings Assn, rating applies to product "as packaged" (i.e., ambient temp.). MSDS 88159 ft) ft CTi o cn o o BFG52231 i USER'S RESPONSIBILITY This bulletin cannot cover all possible situations which the user may experience during processing. Each aspect of your operation should be examined to determine if, or where, additional precautions may be necessary- All health and safety information contained in this bulletin should be provided to your employees or customers. It is your responsibility to use this information to develop appropriate work practice guidelines and employee instructional programs for your operation. DISCLAIMER OF LIABILITY As the conditions or methods of use are beyond our control, we do not assume any responsibility and expressly disclaim any liability for any use of this material. Information contained herein is believed to be true and accurate but all statements or suggestions are made without warranty, express or implied, regarding accuracy of the information, the hazards connected with the use of the material or the results to be obtained from the use thereof. Compliance with all applicable federal, state and local laws and regulations remains the responsibility of the user. APPENDIX A - ACRYLONITRILE By simulating manufacturing conditions, we have generated objective data indicating that Hycar* NBR elastomers are incapable of releasing acrylonitrile resulting in airborne concentrations above one (1) ppm under normally expected conditions of handling, processing and use. Exaggerated conditions, including open mill mixing at elevated temperatures, indicates the maximum acrylonitrile level to which a mill operator would be exposed to is less than 0.5 ppm. Based on these data, Hycar* NBR elastomers do not require warning labels under the acrylonitrile standard (OSHA 1910.1045). Customers should not claim exemption from any of the provisions of the OSHA standard by use of BFGoodrich data alone, but should do sufficient in-plant testing of acrylonitrile levels to assure compliance of their operations. APPENDIX B - BUTADIENE Personnel monitoring during manufacture of Hycar* 1043 and 1094 elastomer determined that worker exposure level was below 0.2 ppm. This is well below the 10 ppm Threshold Limit Value established by ACGIH. Based on our experience, we expect the presence of butadiene in the ambient workplace air to be below 1.5 ppm for all Hycar* elastomers. APPENDIX C - STYRENE During March, 1988, based upon revised definitions, the International Agency for Research on Cancer (IARC) reclassified styrene monomer from Group 3 to Group 2B. For hazard communication purposes under OSHA Standard 1910.1200, this reclassification requires styrene monomer to be listed as a possible carcinogen. Literature reports indicate that styrene can damage chromosomes (Clastogen). The human health implications of these Invivo/Invitro results are not known. Styrene is not teratogenic but may damage a developing fetus. 22505003 -6- BFG52232 1 MSDS 88159 - -witco MARK"A material safety* d*.ta: shefp JUK 0 5 W* -j, HAZARD RATING fr 4 Extreme F-abJiK.- High P ' - Moderate A 1 - Slight 0 - Insignificant HMIS HAZARD INDEX Hazardous 4 - Severe Materials Serious Identification Moderate System Slight Minimal HMIS RATINGS Health.............................................. 1 FI ammabii 1 ty...............................l Reactivity....................................0 Personal protection.... .B DIVISION AND LOCATION------SECTION I Division: ARGUS Location; BROOKLYN, NY 633 COURT ST.,BROOKLYN,NY,11231-2193 Emergency Telephone Wuinbflr; 718-858-5678 Transportation Emergency: CHEM TREC 1-(800) 424-9300 (U.S. and Canada) CHEMICAL AND PHYSICAL PROPERTIES------SECTION II Chemical Name: alkyl tin mercaptlde Formula: trade secret Dg<;Qippg.&itloji sulfur dioxide oxides of tin carbon monoxide and carbon dioxide from burning. InqqTOatifrUjr.tY (KeeP, aVAY frQffi) i ... strong oxidizers such as hydrogen peroxide, bromine, and chromic acid, strong mineral acids Tpxig-,?m<i.aagag<teus insrretiientgs aTKyltin mercaptlde tin compounds (as per State Right to Know lists) Form: liquid Odor: Appearance: clear Specific J3yavitv_ Iwatei^l) t Color: very pale yellow .999 Soiling Point: not distillable Melting Point: not applicable Solubility in Water (by weight %): negligible Volatile (bv weight %V:5 Evaporation Rate: (butyl acetate - l)less than 1 Vapor_Presfure (mm Ha at 20*Cl: less than 1 Vapor Density (airl): no data aval 1 able stability: Product is stable under normal conditions Viscosity SUS at IQQAF: (Continued on next page) 10 con cn o Q FIRE AND EXPLOSION DATA-------SECTION III .qpGci^^ijre^^Fiaht^i^a ^^cedu^ prevent breathlng of vapors or products ofb combustion. Wear an approved self-contained breathing apparatus and protective clothing. unusual Fire and_Explosion Hazards; Oxides of tin and sulfur are produced at decomposition temperatures. Flashpoint: (Method Used) Pensky-Martens closed-cup 185*C (36S*F) Flammable limits %: no data available Extinguishing agents: Orychemical or Waterspray or Waterfog or CO2 or Foam or Sand/Earth Closed containers exposed to fire may be cooled with water. HEALTH HAZARD DATA-------SECTION IV Permissible concentrations fair!: 0.1 mg as tin (OSHA/ACGIH) (skin) chronic effects of overexposure: no data available Acute toxicological properties: for similar products: oral LO50 about 1100 mg/kg (rat) for similar products: dermal LD50 about 6800 mg/kg (rabbit) Emergency First Aid Procedures: Eves: Immediately flush with large quantities of water for at least 15 minutes and call a physician. Skin Contacts Wash with soap and water. If Irritation occurs, see a physician. Inhalation: Remove victim to fresh air. If Swallowed: Call a physician immediately. Induce vomiting if victim Is conscious. Never give anything by mouth to an unconscious person. SPECIAL PROTECTION INFORMATION-------SECTION V Ventilation Tvpe_Reguir.ed (Local.mechanical.specialV: Local if necessary to maintain allowable PEL(perm1ssib1e exposure limit) or TLV(threshhold limit value) Respiratory Protection (.Specify type): Use NIOSH/OSHA approved respirator with organic vapor cartridge if vapor concentration exceeds permissible exposure limit - Protective Gloves: neoprene type Eve Protection: chemical safety goggles Other Protective Eguipment: neoprene protective type apron recommended (Continued on next page) ro ro cn o ti o H* O .MARK A PAGE 3 HANDLING OF SPILLS OR LEAKS-------SECTION VI Procedures for Clean-Up; Use appropriate protective clothing during clean-up. Absorb with an inert material such as sand, soil or vermiculite; sweep up and dispose of in accordance with federal, state and local regulations. Waste Disposal: Dispose of in accordance with all applicable federal, state and local regulations. Use controlled incineration with scrubbers for metallic oxides and sulfur dioxide. SPECIAL PRECAUTIONS-------SECTION VII Precautions to be taken in handling and storage: Do not store near strong oxidizing agents or concentrated acids. Keep drums tightly closed. TRANSPORTATION DATA-------SECTION VIII D.o.T.: Not Regulated Reportable Quantity; not applicable Freight Classifications Special.Transportation Notes: ENVIRONMENTAL/SAFETY REGULATIONS-------SECTION IX Section 313 (Title III Superfund Amendment and Reauthorization Act): This product does not contain any chemical subject to the reporting requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372. signature: Otto Kauder Title: Vice President, Technical Original Date: 11/07/85 Sent to: Revision Date: 05/12/89 _____ Supersedes : 11/07/85 _____ Date Sent______: ______ We believe the statements, technical information and recommendations contained herein are reliable, but they are given without warranty or guarantee of any kind, express or implied, and we assume no responsibility for any loss, damage, or expense, direct or consequential, arising out of their use. 22505011 08/23^91 11:21 216 447 6439 DEPT. 5450 03 SHFGoodrich tq: daTI MR. rtiAegia^H"~ TTmT A- U I ms . ^0///70ob COMPANY: . AOORESS: 4Wl4N*tC Uot^AFS TELEPHONE NO: (Sri) sV7`x>7^ Telephoned Lj Please Call Returned Your Call Will Call Vanes To Saa You P~) Cano To Saa You SPECIAL ATTENTION URGENT . ~U~ MESSAGE: S/&FbS ' APfKotfX- ON SlooA &lAC AS6 52,33^ 22505011 08/28/91 12:30 216 933 1678 BFG C.V. PURKS @001 BFG52239 08/28/91 12:31 0216 933 1678 BFG C.V, PURRS HFGoodrich 002 January 1989 n i a ct n I //.cs 0 ^ ' ?>3 08/28/91 12:32 216 933 1678 BFG C.V. PURRS @003 ABOUT THIS BULLETIN The data in this bulletin applies to all Geon vinyl com pounds except polyblends (blend of polyvinyl chloride and nitrile rubber). Geon vinyl compounds are mixtures of thermoplastic polyvinyl chloride resin, which is a white granular powder, end functional additives such as pro* cessing aid, heat stabilizer, plasticizer, lubricant. Impact modifier, pigment and/or other ingredients. Compound may be prepared as either granules (t.e., pellets of vary. ing size and shape) or free-flowing powders. Although they may vary in terms of physical properties or other characteristics, safety and handling precautions are similar for aD compounds. Please note: Pellet com pound does not represent any inhalation hazard because of its physical form. However, fine particle size additives in powder compound may result In airborne dust. Respiratory protection against nuisance dust may be necessary when handling powder compound. The dam in this bulletin dees not include any informa tion on the suitability of vinyl for any particular applica tion nor does it discuss any precautions that may apply to specific end products. Moreover, this bulletin cannot cover all possible situations which the user may ex perience during processing. Each aspect of your opera tion should be examined to determine If, or where, addi tional precautions may be necessary. All health and safely information contained In this bulletin should be provided to your employees or customers. We must rely on you to use this information to develop appropriate work practice guidelines and employee instructional pro grams for your operation. For information pertinent tp resin, please read BFGoodrich Bulletin, "Material Safety Data, Geort Vinyl Resin.*' Also, a separate safety data bulletin is available for Geon vinyl polyblend compounds. SPECIAL NOTE: Vinyl chloride and polyvinyl chloride (PVC) are notthe same materia). Vinyl chloride is a flam mable gas that is strictly regulated by the Ontario Ministry of Labour (OML). Through a chemical reaction, this gas -- known as a monomer -- is converted to a non- hazardous white granular powder called polyvinyl chloride resin, PVC. or simply, vinyl, it is this vinyl resin that is then combined with functional additives to make compound. Moreover, the i processing or wall not cauee poiyvinyrt chloride to ijffliF :1b vinyl chloride monomer. (See Section II.) SECTION 1 -r PRODUCT INFORMATION Manufacturer's Name ' Address Telephone Number Trademark Chemical Name/Synonyms Formula Chemical Family CAS Registry Number Transportation Emergency Telephone BJF.Goodrich Canada Inc. 195 Columbia St. W., Waterloo, Ont N2J 4N9 (519) 888-4318 (Technical) Geon Vinyl Poly (vinyl chlorideVFlexIble Compound Poly (vinyl chloridej/Rigid Compound Poly (vinyl chioride)/Rigid Powder Compound Vinyl resin* plus functional additives *(CHCHCI),, Vinyl resin: chloroethene polymer Not applicable to compounds CANUTEC (613) 996-6666 . -Virtually ail Geon vinyl compounds are manufactured with homopolymer polyvinyl chloride resin (CAS Registry Number 9002*86-2). We do market a limited number of compounds based upon vinyl chloride/vinyi acetate copolymer resin. Specific grades of Goon vinyl compounds comply wSth applicable provisions of the U.S. Food and Drug Administration regulations governing food contact (21CFH). Please consult product literature for details. Geon vinyl resin and the functional additives used to manufacture compound are included in the Toxic Substances Control Act, Inventory of Chemical Substances, developed by the U.S. Environmental Protection Agency. N UT BFG52241 08/28/01 12:34 218 033 1678 BFG C.V. PITRKS 004 SECTION U HAZARDOUS INGREDIENTS * Vinyl resin contains a very small amount of residual. vinyl chloride monomer (CAS Registry Number. 753)1*4). Extensive product ana process im- > provements have rented in the radiation of residual monomer to overage [vela leas than 1 6 porta per milBon (pprrp in the vinyl resins used to manufacture compounds posure, ' when to _ . w. . Please toad Section below bn Vinyl Chtonde Monomer (VCM) for wodtoiace exposure Omits. ' The sum total ofingrerSents present In virtually any iher- moplastic compound will emit vapors and odors dur ing .processing. The visible fumes that occur during norma! processing of vinyl compound are mainly water vapor, /raceamounts or Hydrogencnioncte. anirmsnt, are possible if there is any hangup or stagnation of compound in processing equipment Vaporsfrom non- PVC compon&itSr are principally trace amounts of volatiles from stabijzere, plasticizers. lubricants, etc. Some people may be sensitive to fumes'or dorefrom these edd&ives.-uie primary effect is irritation to the e^;-*e8pitow To protect your employees'beam,.`conduct any operation emitting fumes or vapors under weU-verrtiiated conditions. Functional addffives mbcedwfth-vinyi resin to create compounds include: GEON VINYL COMPOUND/FLEXIBLE -- GROUP 1 AND 2 -- Stabilizer generally in amounts less than 5% by weight* These may include organomegalies such as fin, lead, cadmium, barium enaano end metallic salts suob as trt base leadsulfate. (Lead stabilized flexible compounds fairunder Group 2. M nemafnfng Hexf* bie compounds fall under Group, -- Commercially available. pigments based on iron oxide, carbon black, chromium, ultramarines, titanium dioxide, cadmiums, phthafocyanines. molybdates, lead, qirinacridones and other organic or inorganic materials. -- Polymeric, monomeric or mixed ester piasticizer in amounts generally between 20-50% by weight in pfas&azeo compound- Plasticizers are volatile when Heated, and they will contributeto the sum total ofthe vapors released during processing. GEQN VINYL COMPOUND/RIGID -- GROUP 3 & GEON VINYL COMPOUND/RIGID POWDER -- GROUP 4 -- Stabilizergenerally in amounts less than 5% by weight consisting of ergandtrns. -- Commerdafiy available pigments based on iron odde, carbon black, chromium, ultramarines, titanium dioxide, cadmiums, pftthalocyanines, molydates, lead, quinacridones and other organic or Inorganic materials. In pellet compound, additives are bound-up in the manufacturing,process and are not expected to create any hazard when handled or processed in accordance wUh.yuuJ ii mi tufduh-uu ty at rJ u nktfdi kaf ptdi^zicea and by following the guidelines presentee in this bulletin. With powder compound, respiratory pro' ^on against nuisance dust mav be reouired. Rea read secaiori below on Functional Additives used in PVC Compound for more information about additives and- hazardous substances. FUNCTIONAL ADDITIVES USED IN PVC COMPOUND AUUiilytsa iX mawt rgi a specific compound wUl vary ac cording to processing and final product requirements. Thetofewing Est does not represenraS possibleadditives but ft does represem typical ingredients-whkrfi may be used in vinyt compounds. StabOtzBr inhibits thermal degradation of the com-. pound during processing and throughout the service Efe of the product Stabilizers may be grouped into four dacsorr organometalfic tins, lead salts, mixed metal salts and special-purpose stabilizers. The most com mon organometaiSc tin stabilizers are tin mereaptides, mainly methyf tin and butyl tin. Some stabifizere, in cluding cB-rvocty! and dimethyl tin mercaptlde, are FDA acceptable for food contact applications. Lead salts, tike dibasic lead phosphite, are mainly organic lead compounds and Include sulfates, siBcates, phosphates, stearates, phthalates.and maieates. Mixed metal salts indude calcium-zinc and bariurrK^dmHjm systems. Special-purpose stabilizers indiide flame retardants such as antimony derivates and ultraviolet light ab sorbers. Stabilizer will typically be present in amounts up to 5% by weight . . Processing olds. The most common processing aids used wth vinyl compound are acrylics or styreneacrytanifcrite copolymers present at levels up to 5.0% by weight Impact modifiers commonly used with vinyl include acrylate^ 'chlorinated polyethylene, meihacryfatebutadiene-styrene (MBS),. acryionitrile-butadienestyrene (ABS). and rubber. Although not present in all compounds, when used, impact modifier may range up to 20% by weight Fillers. Most common are metal carbonates, mainly calcium carbonate, which is usually In the form of ground limestone and coaled with stearic add. Other filers may be siBcates, gypsum, day, alum and barytes. Ptestfcfzer. Many kinds of plasticizers are available such as dioctyl, dihexyi and dibutyl phthlates. phosphate esters such as isodecyi diphenyl phosphate, aliphatic alcohol esters such as cfioctyl adipate, polymeric plasticizer such as polyesters of adrpic adfe, and monomeric esters such as trimeflftate. Dioctylphthlate Is FDA acceptable for food contact ap plications. When used in flexible vinyl compound, pias&^zerconcentration win generally fangs between 200%, by weight Lubricants indude paraffin waxes, mineral oils, polyethylene, salts of fatty adds and tatty adds, esters and amides. Lubricants would be present up to ap proximately 5%. Pigment. A fist of common pigments appears in Sec tion II. Pigments may be present up to 5% to achieve npoty mnd color. In wcatficrabte compounds, titanium dioxide may be present at concentrations up to i<M5% to achieve acceptable ultraviolet Iigh screening. 22505013 08/28/91 12: 36 # 0216 930 1678 BFG C.V. PURKS VINYL CHLORIDE MONOMER (VCM) SECTION IV 005 * Employee exposure to vinyl chloride monomer (CAS Registry Number: 75-01-4), a carcinogen, is regulatedby O.M.L. The current regulation requires that no employee may be exposed to VCM concentrations greater than 2.0 ppm (parts per million by volume), averaged over any 40 hour period, or 10 ppm maximum- The regulation applies to the manufacture, packaging, repackaging, storage, handling or use of vinyl chloride or polyvinyl chloride. Typically, purchasers of vinyi com pound for processing purposes must comply with the permissible exposure limits set by O.M.L Moreover, the regulation requires a program of inlliai monitoring in each facility to determine if there is any employee exposure. Monitoring of.vfnyi projecting and fabricating plant? and modeling studies show that 0.5 ppm cannot be exceed ed when residual VCM is at or below S.5 ppm in Geon vinyl compound. .Shipping containers for these com pounds are not . labeled by BFGoodrich unless a customer specifies otherwise. FIRE AND EXPLOSION HAZARD DATA Ignition Characteristics (ASTM D-1929) Rigid vinyi compound (Le,, no plasticizei) has a flashignition temperature of about 391 C (735F) and s'selfignition temperature of about 454C (850F). When plasticizer is added, ignition temperatures decrease. At a 30% plasticizer content the flash-ignition temperature will be about 321 C (610CF) and the self-ignition temperature will be about435C (815F). By themselves, most vinyl compounds (i.e., rigid compound and com pound with less than about 35% plasticizer) will not sup portcombustion becausethey require a higher concen tration of oxygen for burning than is presort in the earth's atmosphere. Any vinyi compound can be forced to bum by continuous application of intense heat Uke ail com bustible material, protect from open flame and maintain proper clearance when using portable heat devices, etc. Store flammable liquids away from vinyi compound. Polyvinyl chloride is not a cancer suspect agent It is the trace amount of unreacted vinyl chloride monomer that must be controlled, not the vinyl itself. Although some containers may be labeled, this does not necessarily mean that employee exposure to VCM will exceed permissible exposure limits. Using "worst case" conditions of thermal processing, our studies show that more than 30 ppm of unreacted monomer in vinyl resin is needed to cause 0.5 ppm to be present in the at mosphere of a hot. poorly ventilated workplace. For funther information, please read BFGoodrich Technical Ser vice Bulletin No. 12. "Vinyl Studies/' Good ventilation in those areas where VCM might concentrate = such as where containers are stored and first opened, where materials are mixed and where compound is melted -- will further ensure a work environment virtually free of VCM.. Rash-Ignition Temperature; The lowest initial temperature of air passing around the specimen at which sufficient combustible gas is evolved to be ignited by a small external pilot flame. Self-Ignition Temperature: The lowest initial temperature of air passing around the specimen at ' which, in the absence of an ignition source, ignition occurs of itself, as indicated by an explosion, flame or sustained glow. Extinguishing Media Water is mast effective. ABC dry chemical, AFFF. and protein type air foams are also effective. Geon vinyls are "ordinary combustibles" (NFPA defined Class A). Carbon dioxide Is not generally recommended for use on Class A fires as a lack of cooling capacity may result ' in reignition. i SECTION 111 PHYSICAL DATA (Typical data, not specifications) Solubility In Water -- Sight Specific Gravity (H20=1) -- Range: 1.15-1.55 Appearance and Odor Pigmented or unpigmented pellets or powder. Practically or bland odor. The appearance of pellet com pound will vary from cubical granules measuring appro& imateiy 3/16-inch per sideto spheres to wafers depen ding upon manufacturing method. Other Characteristics such as vapor pressure, vapor density, boiling point and evaporation rate are not applicable to solid materials such as vinyi compound. Special Fire Fighting Procedure Wear positive pressure, Self-Contained Breathing Ap paratus (SCBA). Personnel not having suitable respiratory protection must leave the area to prevent significant ex posure to toxic combustion gases from any source, in enclosed or pooriy ventilated areas, wear SCBA during cleanup- immediately after a fire as well as during the attack phase of firefighting operations. Combustion Products When forced to bum, the primary combustion gases from vinyl compound will be hydrogen chloride, carbon monoxide and carbon dioxide. Other gases win include small amounts of benzene and aromatic and aliphatic hydrocarbons. Plasticized compounds will also contribute aliphatic olefins. The combustion products of vinyl resin, like those from other natural and synthetic material, must be considered toxic. Uke wood, paper and cotton, the major hazard is carbon menoxioe, careen monoxide is an asphyxiant while hydrogen chloride is an irritant When vinyl is burn ed, it win have a detectable, pungent odor, BFG52243 0 i 08/28/91 12:38 216 933 1678 BFG C.V. PURKS @006 UnusualFire and Explosion Hazards Hydrogen chloride has a corrosive effect on many metals. Affected equipment surfaces and unprotected structural elements of buildings should be washed to . remove corrosive deposits as soon as possible after bepostions have occured. .'V" Pellet compound does net represent any explosion risk because of its large partide aze. Pow(ter compound Tnay-have dust explosion potential-because of fine par* tide size filiers-and additives or liquids added to vinyl resin. - ' * * .* ' For plasticized powder compound the National Rre Protection Association (NFPA) reports the followingfor a PVC/plasticfeer.mixture (i.e., 67% PVC/33% dioctyi phthalate):* ' Explosibility index: 2.9 (Strong] ignition sensitivity: 3.6 (Strong) Explosion severity: 0.8 (Moderate) Ignition temp., dust cloud:- 320C (608^ "NFPA 6S4-197S, "Preven&xi.of Du^ aiplcisOfe in the Plastics Industry". . . Eecsusedthevvfde varietyof possible ingredient com-. Binations* operations using plasticized. or unpiastiefe* -ed powder compound should be evaluated on an In dividual basiscjmplement .precautions to control or efimi/WJikefy sources of igrftion, such as static build up. Maintain good housekeeping; notably, ventilation, to prevent accumulation ofpotereially explore dust cbncerttratlona'. Properly maintain and operate dust contnaideyices. SECTION V TOXICOLOGICAL PROPERTIES Threshold Limit Value None established. Effects of Overexposure There are no significant health hazards from vinyl com pound si ambient temperature (see Dust Exposure). No adverse health effects are expected from process* ing vinyl compound when potential exposures are minimized by good industrial hygiene practice and adequate ventilation. Nevertheless, individual additives and/or various combinations of additives may affect the overall toxicological properties. Detailed studies have not been performed on each of the many possible ad ditive combinations. At processing temperatures, ad ditives may emit fumes and vapors that are irritating to the respiratory tract, eyes or skin of some sensitive people. This depends upon processing technique and temperature, volume processed and, most importantly, the effectiveness of exhaust ventilation provided to the process area. Inhalation of decomposition or combustion products, especially hydrogen chloride, will cause irritation of the respiratory tract, eyes and skin. Depending on the severity of exposure, physiological response will be coughing, pain and inflammation. Individuals with bronchial asthma end other types of chronic obstruc tive respiratory diseases may develop bronchspasm if SPECIAL NOTE; Hydrogen chloride is detectable by its sharp, pungent odor in concentrations as low as 1-5 ppm. Low concentrations (below 50 ppm) are not harm ful in shortterm exposures, but ..do provide excellent warning properties by causing coughing or irritation.' Because the protective response is so strong, humans rarely submit to damaging concentrations -- instead, thereis an unmistakable urgeto leave the area. Repeated or prolonged exposure to high concentrations can cause eye and respiratory damage. In studies sponsored bythe Federal Aviation Administration, no incapacitation, ho impairment to escape and no significant post-exposure effects occurred in baboons exposed to hydrogen chloride up to 11,400 ppm (1.14%). OSHA has establish ed a ceiling limit of 5 ppm for workplace exposure to hydrogen chloride. Dust Exposure (Geon Vinyl Compound/Rigid Powder) Fine particle size additives in powder compound may result irvairbome dust Routine inhalation of dust of any kind should be avoided. Exercise care when dumping bags, sweeping, mixing or dang other tasks which can create dust Where large amounts of any dust may oc cur. wear a respirator approved by NIOSH/MSHA to pro tect against nuisance dust SECTION VI - REACTIVITY DATA Stability -- Stabie Hazardous Polymerization - W3I not occur Hazardous Decomposition Products Hydrogen .chloride, carbon monoxide, carbon dioxide, and small amounts of benzene and aromatic and aiipnanc nyorocarbons, Ftestkazed compounds wffl also contribute aliphatic olefins. Incompatibility (materials to avoid) Avoid contact with acetal or acetal copolymers and with amine containing materials during processing. At pro cessing conditions these materials are mutually.desmjctive and involve rapid degradation. Thoroughly purge and mechanically dean processing equipment to avoid even trace quantities of these materials from coming In contact with each drier. Prevent cross contamination of feedstocks. SECTION VII PREVENTATIVE MEASURES Steps to be taken in case material is released or spilled Vacuum or sweep Into a dosed container for reuse or disposaL Waste Disposal Method Dispose of waste in a tioensed landfill or by incineration in accordance with federal, provincial and local regula tions, For waste disposal purposes, Geon* vinyl com* pounds are not defined or designated as hazardous. If Incinerated. be aware that hydrogen chioride is V\ BFG52244 08/28/91 12:40 0210 933 1678 BFG C.V, PURRS 007 SECTION VIII FIRST AID MEASURES Emergency and Ftrat Aid Procedure If irritation persists from exposure to processing vapors or decomposition products, remove the affected in dividual from the area. Call a physician. Provide praisetion before allowing reentry. SECTION IX PREPARATION INFORMATION Prepared by: BFGoodrich WHMIS Co-ordinators Date? February, 1989 TRANSPORTATION For domestic transportation purposes, vinyl compounds are not classified as hazardous by Transport Canada under the Transportation of Dangerous Goods Act SPECIAL PROTECTION INFORMATION Ventiiatioii Provide effective exhaust ventilation to draw and/or tomes away from workers to prevert routine Inhalation. Compounding, hot mefr processing (extruding, molding, etc.), cutting or sawing, machining, regrinding, heat welding, thermoforming, and other processing or post processing operations involving heat sufficient to result in polymer breakdown should be examined to ensure adequate ventilation. Ventilation guidelines and techniques may be found in the following publications. -- NlOSH Recommended Industrial Ventilation Guidelines; GPO #017-033-00136-7. Avafiabte from the Superintendent of Documents, U.S. Government Printing Office, Washington. DC 20402 ($9.00 U.S. as of.December 1984). -- industrial Ventilation, 18th Edition. Avatiabte from the American Conference of Governmental Industrial Hygienists, 6500 Gienway Ave., Bldg. D-5, Cincinnati, Ohio 45211 ($16.00 U.S. as of December 1984). Respiratory Protection Not normally required. Abnormal conditions such as equipment malfunction, use of improper equipment or procedures, or hangup or stagnation of compound dur ing processing may cause decomposition. Employees involved in removing decomposing materia! should be provided with suitable air-supplied respirators, such as NIOSH/MSHA - approved positive pressure, selfcontained breathing apparatus, protective Equipment Not normally required- Wear protective qIaupr when . handling hat material during processing- Safety glasses are recommended for ail industrial workplaces. SPECIAL PRECAUTIONS Normal Uelt Processing. Virtually all thermoplastic materials will emit fumes and/or vapors when heated to processing temperatures. The concentration and composition of these vapors wBl depend upon variables such as the specific compound formulation and processing method and temperature. Always use vinyl compound under well-ventilated conditions and avoid continued or prolonged breathing of process vapors. For personal hygiene, wash thoroughly after processing compound, especially before eating, smoking or using toiletfacilities. Do not store or consume food in processing areas. Do not use processing equipment to heat food. Cleanup following normal melt processing should be performed under well-ventilated conditions. Vinyl com pound may be held at process temperatures for a short time without significant thermal degradation, However, it should be recognized that exposure to either elevated temperature dr excessive heat history (time) will result in decomposition. *Equipment should not be shut downfor extended time periods with compound in it, or decom position and posable corrosion of unprotected metal may result If dies and screws are not to be cleaned manual ly, then compound should be purged from processing equipment prior to shutdown using spoofol vinyl purge compound or a computable thermoplastic such as general purpose A8S (do not use flame-retarded or halogen-containing grades for this purpose). *Timeand tempMiLre required id initiatedesradatteavMvary deperv dnfl upon processing technique, degree ofcompound tiatifeation and tfhflrfactors. As agenera) nile-afrfcmmb. degradation beginsto OOCUf aboutone hourat 177C (3S0F), aboutten minutes MS04C(W0*f) and within five minutes at 232C (450F). In case of power foes or other mishap, shut off tire machine and dismantle the die assembly as soon as possible before degradation or decomposition begins. If decomposition begins (with gassing and "popping" sounds) before the die can be disassembled, dangerous ly high pressure may occur In the die system. In this event, shut off the machine, dear the area of personnel and waft until decomposition stops. Thoroughlyvertflate the area. Remove and disassemble the die system. These are guidelines only. Rder to technical service reports and bulletins (such as BFGoodrich Bulletin G-63 "Injection Molding Guide, Rigid Geon Vinyls) and to equipment manufacturers recommendations forfurther information. Regrinding scrap normally generates substantial heat Cool regrind before placing it in containers. The excellent insulating quality of vinyl will prevent heat In the center of a container from escaping, potentially resulting in stow thermal decomposition of the material. This may not only renderthe product unsatisfactory for further processing but also results in fumes and vapors being released into the workplace atmosphere. Remove vinyl resin from walkways and floorsto prevent dtppory footing. Alwayewdar tublMr glowsv/iwn clean ing condensate from exhaust equipment or other surfaces. iz frs o s z z j - ,J BFG52245 i 08/J8/91 12:42 216 633 m KFGoodrich B^Goodrich Canada Inc. 195 CoJumtaia StW. Waterloo, Ontario N2G4N9 0519) 888*4318 BFG C.V. PURKS @,009 V BFGoodrich Tha Iraaffianen ccnta&ima harew it btatawi ta Ps ttatatata tiui ij ii |miniiiilk ii i jmimnnrn............. r#orryTiimi . mnaoreataeaceuxy.&MHaifqrfe-prtfiutaraepfe*- pcncorgwwajteIn 6a utMinedihatafeum. TTm rtuwwtot aa net roc*ss**y ` 1 "I I11 " ' and proast totsinnca Seca^tathe wanwiflnsm maawda, contatinaad equip- tocedkt Canada mm Med mmptitly In pwwwg ffea manta. * wmaRerom*Bafin*to*stt0aiUt*tyatt pratfesstrffiaadettnicfecfesad-ftddaaeoataigwtt and product pmtumanca am ffa m^wwataBy tatha tsar. BFGacariditftfndbaiBtaBtora^ibftaaacnMmKtai ai tdiadEsbUy ta any tas or hara*T0 of any mmtal bfr->.*H^0Mncn*ibaaea(lntTHS SELLS MAKES NO WAWWmgS. E*WESS OR IMPUgO. NCU/ONG. BUT NOT LIMITS TO. THE. IMPLIED WAftftAKTlES OF MSCHANTAaUTr AND ftTNESS PC* a paFTHCI^ah PURPOSE. NdnhgccaatansdrttwiBtafie eonaome a* twitata0ft.eaniii4sacrt.ncrcift*damarttopcae- lies n PtaMed maden MAout pmfndataft d ffw patm ownar. BFG52247 - -- -i U:42 true BRabodrieh duFjQoodrlch Canaria Inc. 196 Columbia St W. Waterloo. Ontario N264N9 {519) 888-4318 17 BFC C.V. PURKS 8)009 V*' ' BFSoodrich Tw taewMm cortahod timm k MM la M nfeto. QuinaMpMMmkmffMMacorMaaMMafKykM MiiMItttaniaqr.uHiiy^pMaArvpfctBOnqrgMM>ifciPot**i^etmiinton.'niartuiiaiKn fcbMadontoMwywak-win HidMWiiMBW at** m Nnw*)' tty** tnd pmact ptfmn 9*aaa*Vi* irntfontmaMAjd^ oorattm *fld *** Mood ki Canada wwawauwiTi'iil) In pwcwllnj * wwkfr. no wmnfiMoriMwwMOTKadMtoMafeftStrtifAe pradua Brffapieam(fcdsmd.Pufrao**toting d andgwefctftartomanco m a* ^arnetty t to (. WkMIftMabftiMlBrnltttlltfCRWBBlW > wfc id Whrty cf ao nr t*rwfrQ H any ammUt bvcr>.< hfCoedncn's dfawacomHESOlR MMS NO WANMNTKS. S*PRS3 OR IUPUES. iNCLUONG. BUT NOT UMTQ3 TO. THE IMPUSD WMWAKnES OF MjFOtMflMiUTY AND HTnESS FOR a PARTICULAR PURPCCft-NcBwownntod haranjsto BoeoneoaaJas pairnwi. ramqHwaacfyrKrosaninaxarmrttoptoctiBotoPWWBi*aton taiMXpantoiencltopWBat onft BFG52247 ) ROUTE TO: BATH COMPUTER ROOM fc-R-tf **#**-* *# #* * **#**#*#*#* * fr **## *r *#*--R--R-* * GEON VINYL TECHNICAL DOCUMENT #* fc*^****** ***#*#*#tt***#**'********************#-***-*-* *-***** * CUSTOMER NO / DESC: BFG CANADA Fr! 103360 G EON V I N Y L RECIPE 08/23/91 11:34:35 NO EXT PROD DESC ON DATABASE COMMODITY NO.: 7S710 000 2830 SBC NBR: 13C1 LAB REF: CANADIAN RECIPE BASED ON: BFO CANADA RECIPE APPLICATION: PROFILE EXTRUSION S7O0A OSHA WARNING LABEL: A LUC: 10 DEPT: 5772 ISSUE: 101 EFFECTIVE DATE: 11/06/36 DELETE FLAG: NO CMPR: BFG CANADA/CVP 2880 PARTS INGREDIENT' SEQ LOO PERCENT 98.63200 5.30000 5.00000 2.00000 7.50000 1.60500 2.00000 961 000277 30 GEON RESIN 942- 710701 1430 X 20 941 710699 2301 912 00S020 TIN MERCAPTIDE 925 709635 SUPER-PFLEX 200 923 710321 BLACK 1CB-S1 MB 943 00LC34 CA STEARATE-FUSED 122.03700 110 210 220 310 410 510 620 10 TOTAL SO.821 4.343 4.097 1.639 6. 146 1.315 1.639 100.000 SPECIFIC: GRAVITY: TYPE SAMPLE: MATCHED TO: ISSUED: MARKETING APPROVAL: 1.37 X TO MAKE CHANGE PER BFG CANADA HARDNESS: COLOR: l toJZ BFG52248 'S i MARK A WITCO JUN 0 5 VW N F P A MATERIAL SAFETY1 JUN 0 5 1990 HAZARD RATING 4 - Extreme 3 - High 2 - Moderate 1 - Slight 0 - Insignificant Toxicity DA T A /I HMIS HAZARD INDEX Hazardous 4 - Severe Materials 3 - Serious Identification 2 - Moderate System 1 - Slight 0 - Minimal HMIS RATINGS Health............. ...................... .....1 FI ammabi 11 ty..........................1 Reactivity.......................... .. .0 Personal protection..... .B DIVISION AND LOCATION-------SECTION I Divisions ARGUS Locations BROOKLYN, NY 633 COURT ST.,BROOKLYN,NY,11231-2193 Emergency Telephone Number; 718-858-5678 Transportation Emergency; CHEM TREC l-(800) 424-9300 (U.S. and Canada) CHEMICAL AND PHYSICAL PROPERTIES-------SECTION II aasBBimrniB8----aags--irtMaaamrnaaBBtiuasinn BuaawaaBaBgM Chemical Name: alKyitin mercapt1de Formulas trade secret Hazardous Decomposition Products: sulfur dioxide oxides of tin carbon monoxide and carbon dioxide from burning. Incompatibility (Keep avav froml; strong oxidizers such as hydrogen peroxide, bromine, and chromic acid, strong mineral acids Toxic and Hazardous_Tngredients: alkyltln mercaptide tin compounds (as per State Right to Know lists) Forms liquid Odor: Appearances clear Color: very pale yellow Specific Gravity (water=l): .9$9 Boiling Point; not distillable Melting Points not applicable Solubility in WaterL_(bv weight %) ; negligible Volatile (bv weight %1s 0 Evaporation Rate: (butyl acetate - 1)1 ess than 1 Vapor Pressure (mm Hg at 20*Cl: less than 1 Vapor Density /air^ll; no data available stability: Product is stable under normal conditions viscosity SUS at 100VF: (Continued on next page) MARK A FIRE AND EXPLOSION DATA-------SECTION III special Fire Fighting Procedures; Firefighters must be equipped to prevent breathing of vapors or products of combustion. Wear an approved self-contained breathing apparatus and protective clothing. Unusual Fire and Explosion Hazards: Oxides of tin and sulfur are produced at decomposition temperatures. Flashpoint: (Method Used) Pensky-Martens closed-cup 185*C (365*F) Flammable limits %: no data available EX i Drychemlcal or Waierspray or Waterfog or CO2 or Foam or Sand/Earth Closed containers exposed to fire may be cooled with water. HEALTH HAZARD DATA-------SECTION IV Permissible consentrations (airl: 0.1 mg as tin (OSHA/ACGIH) (skin) chronic effects,of overexposure: no data available Acute,toxicological properties: for similar products: oral LD50 about 1100 mg/kg (rat) for similar products: dermal LD50 about 6800 mg/kg (rabbit) Emergency First Aid Procedures: Eves: Immediately flush with large quantities of water for at least 15 minutes and call a physician. skin Contact: Wash with soap and water. If irritation occurs, see a physician. inhalation: Remove victim to fresh air. if swallowed: Call a physician immediately. Induce vomiting if victim is conscious. Never give anything by mouth to an unconscious person. SPECIAL PROTECTION INFORMATION-------SECTION V Ventilation Type Required (Local.mechanical.special): Local if necessary to maintain allowable PEL(permissible exposure limit) or TLV(threshhold limit value) Respiratory Protection (Specify type): Use NI0SH/0SHA approved respirator with organic vapor cartridge if vapor concentration exceeds permissible exposure limit Protective Gloves: neoprene type Eve Protection: chemical safety goggles Other Protective Eguipment: neoprene protective type apron recommended (Continued on next page) *0 Ul (1 BFG52250 i MARK A WITCO MATERIAL SAFETY D-ATA SHEET PAGE 3 HANDLING OF SPILLS OR LEAKS-------SECTION VI Procedures for Clean-Up: Use appropriate protective clothing during clean-up. Absorb with an inert material such as sand, soil or vermicullte; sweep up and dispose of in accordance with federal, state and local regulations. Waste Disposal; Dispose of in accordance with all applicable federal, state and local regulations. Use controlled incineration with scrubbers for metallic oxides and sulfur dioxide. SPECIAL PRECAUTIONS-------SECTION VII Precautions to be taken in handling and storage: Do not store near strong oxidizing agents or concentrated acids. Keep drums tightly closed. TRANSPORTATION DATA-------SECTION VIII D.o.T. ; Not Regulated Reportable Quantity; not applicable Freight Classification: Special Transportation Notes; ENVIRONMENTAL/SAFETY REGULATIONS-----SECTION IX Section 313 (Title III Superfund Amendment and Reauthorization Act^; This product does not contain any chemical subject to the reporting requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372. Signature; Otto Kauder Title; Vice President, Technical Original Date; 11/07/85 Sent to; Revision Date; 05/12/89 _____ Supersedes : 11/07/85 _____ Date Sent : ______ Me believe the statements, technical information and recommendations contained herein are reliable, but they are given without warranty or guarantee of any kind, express or implied, and we assume no responsibility for any loss, damage, or expense, direct or consequential, arising out of their use. 0 ^ q JNj c* BFG52251 SEP-10-91 TUE 7:32 DYNAMIC CLOSURES CORP. FAX NO. 18175475070 P.02 August 27, 1991 B.F. Goodrich Att: Dr. Bob Hinderer Re: Q700A-288 Dear Sir: Theaddress for the USDA is as follows: Ron Anderson FESD,MPI,FSIS USDA Washington, D-C. 20205 :dr_your immediate attention to our problem. As discussed he is looking for the chemical breakdown of the product to verify its use in the meat packing industry. DYNAMIC wOSUftES CORP. 1304 Oak Hill Drive, Copperas Cove, Texa? 76522 Tel: (817) 547-0070 Fax: (817} 547-5070 BFG52252 SEP-10-91 TUE 7:31 DYNAMIC CLOSURES CORP. FAX HO, 18175475070 Mm&MXV'P* CLEARANCE DETAILS P. 01 08330/DYNc MANUAL OPERATION CHAIN OPERATION MOTOR OPERATION opening HEIGHT to S'-O" - 10'-0" - 12'-0" - 14'-0" - 16''0" - 20'-0" DOOR THICKNESS INSUL-AIR ' SERIES STEEL ALUMINUM YYY 17 19 21 19 21 23 21 21 25 21 25 27 23 25 29 25 29 31 1" 1%" 1B/e" Y 23 25 27 31 33 35 ro * HOODS (Optional) Not Required With Lintel Seals. Coil to be housed with a minimum 24 gauge galvanized steel sheet metal hood, with a high-grade zinc coaling per ASTM Standards. Lintel wealherstripping to be applied to minimize air infiltration and la comprised of a special combination aluminum and P.V.C. weather soai attached to the lintel extending the full width ot the opening. VISION PANELS Where indicated furnish double glazed clear glass over individual slai cutouts, 5* wide x %' high x 3 cutouts wide FINISHES Finish for ungalvanizad surfaces is to consist of a shop coat of metallic primer. Standard aluminum finish is mill and is available in clear anodize, medium bronze acrylic paint, or an acrylic paint finish or the architects choice. Other finishes included black, light, medium or dark bronze hard colour anodizing all available as optional extras. Operatic.' - to be by Gearhead Operators, with suiip' H.P. 3$ determined by the manufa-v . or chain hoist for doors undo, , ..3. ft. Instaiiatu.. 5 to be by manufacturer or his authorized representative. -v P.V.C. Extrusion / backing R-10.6 foamed in place polyurethane insulation K { L l.. -l Interlocking <-vt- atuminum extrusion PAT. PENDING Distinguishing Characteristics of Dynamic's `'Foamed-in-Place" Polyurethane (UCo-393/905-005 1.4 p.e.f. System) FIRE RETARDANT CLASS 2 CANDIDATE 'Non-Friable 'Excellent Adhesion to Metal Substrates 'K-Fsctor (Initial) - 0.12 BTivit. ^FVHt/in. BFG52253 to v\ o til K o AUTOMATIC COVER SHEET TO: FAX #: 12163742238 v> .r / 4 h y ->\ya- / ' -f x^ v '<s"v 'J -A \ ,v V. FROM: DYNAMIC CLOSURES CORP. FAX #: 18175475070 03 PAGES RE SENT (INCLUDING THIS COVER PAGE) BFG52254 M OH 1 4 ; 3 > BRG UIT l_ O O ^ W B SHORE R. 1 3.1L 37V B.F.GOODRICH TELEFAX MESSAGE B.F.GOODRICH CANADA INC 1 TELEFAX NO.(519) 8S8-t*3o 195 COLUMBIA ST. W. 1 P.O. BOX 1625, WATERLOO, ONTI IF YOU DO NOT RECEIVE ALL N2J 4N9 1 PAGES - PLEASE CALL (519) 888-4300 1 AUDRE - (619) 888-4318 DATE! O cj 1 O <\ | t | TO-. f G- - <Sb frTU ATTENTION! *\S,, COUVJWFROMi U ICC- pfl-y PAGES TOTAL: 1 T> ILLo tJ - B.F.GOODRICH (INCLUDING COVER PAGE) NOTES: Cow(Vl: ;tL-r-e t" s C-ec2 ,,/.-$/ -<. c ,5oW 302- ._ r' j)_|_0_ 5_ jPF76 _ _ j^e x_,V, " -- / ' / J- V7?5 ri 11 ^ .- ' * o _f/s_ _ _ BFG52255 to s C8/27/91 12:21 S 216 447 6459 DEPT. 5450 >' FACSIMILE MESSAGE BFGOODRIPH COMPANY 6100 OAK TF BOULEVARD CLEVELA OHIO 44131 'TEL: ( , 447-6517 FAX: [k. 6) 447-6459 DDAATTEE:: 2c>> 1( DELIVER TO: ^ TTIIMMEE:: 0fcJ 1111^-J) j iJwdjZAJr. =ar FROM: MESSAGE: yiiaxX~ ^aaoc? C^JL^cJhx^J^______ 01 1 uo... ir of pages including this cover letter. If all pages have not been ' tK Kite Peters at ? 0-447-D517. 10 o LI o \ BFG52256 L- i . ' ;:j oniMze; ;:Yo:sK32ft GEON ROD BI-GOODRICH GEON VINYL DIVISION RECIPE INQUIRY USERID; N50MSH1A PTERMID: PV120100 PRODUCT NBK: 78710 000 2880 8700A BLACK 288 LOO: JO DEPT: 5772 ISSUE? 101 VL4`. KVPECTTVR DATP-i ft fi 1 1 t) INTERMEDIATE KM NBBi TOTAL l.HS RM: 122.037000 LDS PRODUCT; 122.037000 RECIPE TYPE: 2 SKQ RAW MATL DESCRIPTION MO 9ft 1 "00027 7 30 GEON RESIN 210 9-J 2 - 7 1 0701 1430 X,20, O ^ 220 941-710699 2301 j$ptr&< QUANTITY lc 98.032000 10 6.300000 5.000000 PAGE PERCENT COMMENTS 80.8214 PS 4.3429 4.0971 HC^ 1 OF 310 912-OOS020 TIN MERCAPT1DK 410 925-709&3^ SUPER-PFLKX 200 MO *>20-7 J DLA-CK 100-81 M Jj *? 2.000000 7.500000 1.000000 1.6388 TCn ft . 1 4 f> 7 v - * 1.3132 Cj/^-^1/'7$i%fcO0j-yj %x ft20 94 3-001.034 CA STEARATE-PUS 2.000000 1.0388V1 s n rs , > '.EXT RESPONSE; .'900016 RECIPE INQUIRY OK IJ/LT-1 Aa NEXT KEY; . -tA f r.\i ` iiC-'M PF5-PROP PF6-RMKS PF9-SAFE PF10-INST 23/018 n BFG52257 i i>