Document 2jOb2a97EapRxK8kNmZ17n5pr

00 0 * A, # * i TRADE NAMES Canadian Centre for Occupational Health and Safety * RECORD MUMPER LANGUAGE TRADE NAME(S) PRODUCT IDENTIFICATION DATA DATE OF MSDS IDENTIFICATION 67823 English VINYL CHLORIDE MONOMER, UNINHIBITED CS Dow Product Codes 91578 Dow MSDS Numbers 00066* 1908-03-20 MANUFACTURER *** MANUFACTURER INFORMATION *** DOW CHEMICAL CANADA INC ADDRESS EMERGENCY TELEPHONE NO.<S> SARNIA ONTARIO CANADA N7T 7K7 519-379-3711 SARNIA 407 990-0282 FORT SASKATCHEWAN *** MATERIAL- SAFETY DATA *** MATERIAL SAFETY DATA SHEET Dow Chemical Canada Inc. Sarnia, Ont. N7T 7K7 Phone* 519-339-3711 Product Code: 91S78 Paget 1 PRODUCT NAME* VINYL CHLORIDE MONOMER, UN1NHIBI TED CS Lffective Date: 03/20/BB Date Printed: 03/23/B8 MSDS:000664 i. INGREDIENTS: Vinyl chloride CAS# 000075-01-4 99.97. 2. PHYSICAL DATA: BOILING POINT: -13.83 (+7.UF) VAP PRESS: 2524 mmHg, 336 6 20C VAP DENSITY <Air=l>: 2.16 SOL. IN WATER: <0.1 mole 7. 3 1 atm t 25C SP. GRAVITY: 0.913 Q 20/20C, 6F APPEARANCE: Extremely flammable, colorless gas or liquid under pressure. ODOR: Faint, sweet odor. 3. FIRE AND EXPLOSION HAZARD DATA: FLASH POINT: METHOD USED: -7BC (-108.4F) COC FLAMMABLE LIMITS LFL: 3.6 voi X UFL: 33.0 vol X EXTINGUISHING MEDIA: For containment of fire and protection of surrounding equipment only. Water foq, foam, CD2, dry chemical. FIRE fV EXPLOSION HA2ARDSJ Vapors, can form flammable mixtures with air at all normal ambirnt temperatures RSV 0021007 All sources rf possible j gr.j * ; or, 5v?a .*.*** --eyt;* . . 'I >.' -uld t-* a^r:e<-d in areas Mhr vinyl chloride vapors are present. Autoignition temperature 472C <882F) FIRE-FIGHTING EQUIPMENTt Wear positive-pressure, seU-contained . (Continued on Page 2) ~'(R) Indicates a trademark of The Don Chemical Company MATERIAL SAFETY DATA SHEET Dow Chemical Canada Inc. Sarnia, Ont. N7T 7K7 Phonei 519-339-3711 Product Code* 91578 Pages 2 PRODUCT NAMES VINYL CHLORIDE MONOMER, UNINHIBITED CS Effective Dates 03/20/88 Date Printed! 03/23/88 MSD5i000664 3. FIRE AND EXPLOSION HAZARD DATA: (CONTINUED) breathing apparatus. 4. REACTIVITY DATAi STABILITY! (CONDITIONS TO AVOID) Avoid exposure to air, oxygen, sunlight, moisture, and all sources of heat or ignition. Autoigm ces in air at 472C (082F). INCOMPATIBILITY! (SPECIFIC MATERIALS TO AVOID) material, and aluminum or aluminum alloys. Oxidizing HAZARDOUS DECOMPOSITION PRODUCTS* monoxide. Hydrogen chloride, carbon HAZARDOUS POLYMERIZATION: May occur. Avoid exposures to oxygen (air), heat, sunlight, moisture, and free radical initiators or other c*talytic impurities. ENVIRONMENTAL AND DISPOSAL INFORMATION: ACTION TO TAKE FOR SPILLS/LEAKS* Remove all sources of ignition; supply ample ventilation, allow only properly protected personnel into the area: do not allow vinyl chloride to enter the sewer system because of explosive hazard. DISPOSAL METHOD* Incinerate in equipment with a hydrochloric acid scrubber according to local, state, and federal regulations. Contact The Dow Chemical Company for additional help. HEALTH HAZARD DATA: EYE: If liquid contacts eye, evaporation may cause frostbite-type injury due to rapid cooling. SKIN CONTACT: If liquid contacts si in, evaporation may cause frost--bite type injury due to rapid cooling. (Continued on Page 3) (R) Indicates a trademark of Thr Dow Chemical Company MATERIAL SAFETY DATA SHEET Dow Chemical Canada Inc. Sarnia, Ont. N7T 7K7 Phones 519-339-3711 RSV 0021008 " 1 '"ode? cjf.TR F'aaes 3 --a* vir<iib wn^uniyb nUNuntiKt ui4iNil|tlTEO CS ^'Effective Date: 03/20/ee Date Printed* 03/23/00 USDSi000664 HEALTH HAZARD DATAt (CONTINUED) SKIN ABSORPTION! Skin absorption is unlikely due to physical * propertias. INGESTION* Ingestion is unlikelysdue to physical state. ! I | 3 | i j { V t 7. X J INHALATION* A single brie* (minutes) inhalation exposure to easily attainable concentrations may cause serious adverse effects* even death. Signs and symptoms of excessive exposure at concentrations of 0,000 to 10,000 ppm may be anesthetic or narcotic ejects. Signs and symptoms of excessive exposure may be central nervous system effects. SYSTEMIC Si OTHER EFFECTS: Excessive exposure may cause lung, liver and kidney effects. Excessive exposure has been shown to cause cancer in humans and in laboratory animals. Repeated excessive exposure may cause Raynaud's Phenomenon* pseudDscleroderma and acroosteolysis in humans. Has been shown to be a mutagen in bacteria. Has been shown to produce reversible chromosomal abnormalities in humans. Vinyl chloride is listed as a carcinogen by The National Toxicology Program* The Internal!onal Agency for Research, and QSHA. FIRST AID: EYES* Irrigate immediately with water for at least 5 minutes. SKIN: No adverse effects anticipated by this route of exposure except for frostbite. INGESTION: No adverse -effects anticipated by this route of exposure due to physical properties. INHALATION: Remove to fresh air. If not breathing, give mouth-to-mouth resuscitation. If breathing is difficult* give oxygen. Call a physician. NOTE TO PHYSICIAN: No specific antidote. Supportive care. Treatment based on judgment of the physician in response to "i reactions of the patient. (Continued on Page 4) <R) Indicates a trademark of The Dow Chemical Company i MATERIAL SAFETY DATA SHEET Dow Chemical Canada Inc. Sarnia, Ont. N7T 7K.7 Phone: 519-339--3711 Product Code: 91578 Page: 4 PRODUCT NAME: VINYL CHLORIDE MONOMER, UNINHIBITED CS Effective Date: 03/20/89 Date Printed: 03/23/08 J MSDS:000664 i 8. HANDLING PRECAUTIONS: i EXPOSURE GUI DELINE(S) : ACGIH TLV is 5 ppm for vinyl chloride. ' OSHA PEL is 1 ppm for vjryl chloride with a 0.5 ppm action 1evel 4 RSV 0021009 guaoenna. ubs only hiui eiiu**Liwu. w.wv* a< ventilation may be necessary for some operation*. RESPIRATORY PROTECTION* When airborne exposure guidelines and/or comfort levels may be exceeded, use an approved positive-pressure self-contained breathing apparatus. SICIN PROTECTION* Use an impervious full slicker suit when there any possibility of skin contact with liquid or vapors in excess of exposure guidelines. EYE PROTECTION* Use che<-ical guggles. If vapor exposure causes eye irritation, use a full-face, supplied--air respirator. 9. ADDITIONAL INFORMATION* REGULATORY REQUIREMENTS* SARA HAZARD CATEGORY* Tfis product has been reviewed according to the EPA `Hazard Categories* promulgated under Sections 311 and 312 of the Superfund Amendment and Reauthorization Act of 19e6 (SARA Title III) and is considered, under applicable definitions, to meet the following categories: ' An immediate health nazard A delayed health hazard A fire hazard A sudden release of pressure hazard SPECIAL PRECAUTIONS TO PE TAKEN IN HANDLING AND STORAGE: Storage should be in an isolated, wel1-ventilated area. Pits, de pressions, and basements should be avoided. Avoid all skin and eye contact. Avoid breathing vapors. Vinyl chloride should (Continued on Page 5) (R) Indicates a trademark of The Dow Chemical Company MATERIAL SAFETY DATA SHEET Dow Chemical Canada Inc. Sarnia, Ont. N7T 7K7 Phone: S19-339--3711 Product Code: 9157B Page: 5 PRODUCT NAME: VINYL CHLORIDE MONOMER, UNINHIBITED CS Effective Date: 03/20/BB Date Printed: 07/23/88 MSDS:000664 ADDITIONAL INFORMATION* (CONTINUED) always be handled with full recognition of its volatility and its flammability. Keep the material enclosed and eliminate all sources of ignition. MSDS STATUS: Revised Section 9. i (R) Indicates a trademark of The Dow Chemical Company j The Information Herein Is Given In Gocd Faith, But No Warranty, i Express Or Implied, Is Made. Consult The Paw Chemical Company 1 For Further Information. ii } ****#**##***#***#***** > ' RSV 0021010