Document 2jB4Mw37bzgn4Y7412qGRRZR5
cowFtBte$rjAi.t
Subject t.o
orrie'r
of 14th Judicial (district dourt
No. 91-1145
PER-TRi OPERATIONS
PRODUCTION T/D Perchlor Shipments
Inventory, tons Trtchlor
Shipments Inventory, tons Perchlor (Unit) Trtchlor (Unrt)
Jan-91 Feb-91 Mar-91 Apr-91 May-91 Jun-91 Jul-91 Auq-91 Sep-91 Oct-91 Nov-91 Dec-91
101.0 36.1 93.5 81.2 94.0 66.5 61.6 69.3 101.7 51.2 58.3 83.9
159.0 -9.9 78.9 82.1 114.1 71.5 61.3 -3.6 144.8
4.5 103.7 164.9
2539.0 3827.8 4280.0 4252.0 3629.4 3478.3 3485.9 5746.4 4432.2 5890.1 4528.6 2015.9
35.0 33.6 50.7 46.7 54.3 75.1 91.4 87.0 58.1 44.0 56.5 69.9
35.0 107.2 41.0 47.7 72.3 75.6 102.1 34.3 63.9 73.2 71.9 84.3
4006.0 1945.9 2246.6 2217.1 1661.0 1647.2 1318.0 2943.0 2767.9 1862.9 1402.0 955.3
71.0 61.5 97.3 85.6 97.4 68.1 59.6 69.6 105.0 58.3 56.7 85.4
35.0 35.2 53.1 49.3 45.7 80.5 94.5 84.7 56.2 45.7 56.1 75.6
YTD AVG
72.5 73.8 4142.4 60.7 70.3 1906.1 76.8 61.5
12M AVG
75.2 81.5 2015.9 58.7 67.1 955.3 76.4 59.4
1990 AVG
114 126 4348.7 66
71 4018.9
113 68
Consumption Ratios
NH3, lbsA 02Tt7t N2, t/d
KWH/T Stillbottoms, M
6.0 11.3 5.5 3.4 4.4 3.9 5.9 3.6 3.6 5.3 6.9 8.0 5.6 5.7 4.7 0.33 0.62 0.27 0.31 0.30 0.35 0.29 0.31 0.31 0.34 0.33 0.31 0.34 0.32 0.30
70 53 55 38 54 48 47 49 49 50 45 46 49 50 76
135.0 157.1 106.2 115.9 115.4 103.3 0.22 0.25 0.24 0.21 0.26 0.20
95.9 100.9 0.20 0.23
94.7 148.2 131.3 0.27 0.30 0.25
91.5 114.6 112.6 0.13 0.23 0.23
93.0 0.26
YIELDS Unit Basis
CI2 C Records Basis Q2
c
97.53 108.98 116.79 101.26 101.17 109.46 109.26 109.79 107.90 112.48 109.75 94.73 107.41 106.30 106.00 78.79 120.13 102.80 94.89 89.49 98.40 95.29 88.17 94.68 91.42 97.79 87.08 96.38 93.72 107.93
114.19 87.13 114.07 97.88 103.28 107.88 109.40 111.71 107.23 108.87 111.01 94.99 104.86 106.06 105.87 96.29 94.98 99.31 90.60 92.98 97.62 95.55 91.28 94.24 89.62 99.14 69.82 94.10 94.11 107.49
BIO SL 014310
PER-TRI OPERATIONS
CON'FT 0P.MTt At,i
Eqbjecfc l.o Protective Order of f4th Judicial District Court
o. 91-1145
REACTOR NO. 1
Jan-91 Feb-91 Mar-91 Apr-91 May-91 Jun-91 Jul-91 Aug-91 Sep-91 Oct-91 Nov-91 Dec-91 12M Avg 90 Avg
On Stream Time Hr.
744 678 672 365 0 0 0 0 0 0 0 0 205 5342
TEMPERATURES, DEG. F. Vaporizer Liquor Dowtherm Out Reactor Vent
337 323 332 331 453 466 437 445 41 37 31 32
331 328 450 493
35 37
Organics, gpm Oxygen, scfh
HCI, scfh Vent Flow, scfh Catalysts, lbs
9 8 940000000028 11314 9939 11018 5322 0 0 0 0 0 0 0 0 3133 10745 10659 9426 10534 4192 0 0 0 0 0 0 0 0 2901 10693 9204 8747 10281 4034 0 0 0 0 0 0 0 0 2689 8208
9800 9450 7700 3150 0 0 0 0 0 0 0 0 2508 8505
REACTOR CRUDE PERCENTS Per/Tri
Per & Tri TCE
Heavies lights
2.75 89.12
0.05 6.05 1.15
289 86.62
0.16 7.01 1.76
266 86.65
0.07 6.98 1.86
3.42 87.47
0.14 6.28 252
3.42 87.47
0.14 6.28 252
3.03 87.47
0.11 6.52 1.96
289 86.62
0.16 7.01 1.76
B20
SL
Subj.? - 4-c.
PER-TRI OPERATIONS
REACTOR NO. 2 On Stream Time Hr.
Jan-91 Feb-91 Mar-91 Apr-91 May-91 Jun-91 Jul-91 Aug-91 Sep-91 Oct-91 Nov-91 Dec-91 12M Avg 90 Avg 723 0 0 0 296 522 708 744 700 676 716 728 484 7436
TEMPERATURES, DEQ. F. Vaporizer Liquor Dowthemn Out Reactor Vent
335
440 31
335 332 323 331 320 313 295 303 321 328 466 546 454 450 450 430 429 426 455 488
28 31 29 33 25 24 21 23 27 29
Organics, gpm Oxygen, scfh
HCl.scth Vent Flow, scfh Catalysts, lbs
5
4
7 11
12
6
6
6
5
7
8
10417
5666 8189 13131 14144 10962 9383 10369 11323 10398 11803
10532
4774 6989 9907 10235 9099 7900 8528 8110 8453 10951
11924
4786 7518 11175 9962 6626 6498 5871 6185 7838 9098
9100 0 0 0 3500 7700 7700 5950 8750 7350 8400 8050 5542 7146
REACTOR CRUDE PERCENTS Per/Tri Per&Tri TCE Heavies Lights
2.65 89.48
0.05 6.28 1.01
210 86.30
0.12 7.60 2.20
3.56 90.39
0.03 5.13 1.53
3.16 89.06
0.08 4.30 266
1.62 86.80
0.04 5.54 3.35
1.27 86.38
0.13 6.16 3.47
3.10 91.76
0.14 5.29 1.51
287 89.06
0.03 5.73 244
1.82 94.66
0.02 4.64 2.20
1.46 88.70
0.02 5.43 267
2.36 89.26 0.07
5.61 2.30
2.59 90.08 0.09 5.05
1.27
SL 014312
B30
PER-TRI OPERATIONS
CONFIDENTIAL: Subject to Protective Order of -14th Judicial District Court
Ho. ill-1145
REACTOR NO. 3 On Stream Time Hr.
Jan-91 Feb-91 Mar-91 Apr-91 May-91 Jun-91 Jul-91 Aug-91 Sep-91 Oct-91 Nov-91 Dec-91 12MAvg 90 Avg 642 672 720 694 7024 652 188 632 716 620 704 740 640 7164
TEMPERATURES, DEG. F. Vaporizer Liquor Dowtherm Out Reactor Vent
326 325 324 334 340 336 314 314 309 301 263 246 311 326
517 491 496 458 543 520 601 519 485 481 514 452 506 491
25 325 324 334 340 336 314 314 309 301 263 246 286
28
Organics, gpm Oxygen, scfh
HCI, scfh Vent Flow, scfh Catalysts, lbs
6 10928 9453 10434 9100
6 13471 12444 11188 8400
7 12193 11392 9671 9100
8 13258 10408 10308 8400
9 11431 9672 10301 8400
6 11030 9350 10460 8400
2 2787 2905 2756 2450
7 12081 9243 7069 6650
7 14989 10255 6590 9100
5 11010 7174 5575 6650
6
10149 8498 5303 7700
8 11418 8877 5878 8400
6 11229 9139 7961 7729
7 12785 11271 8956 9071
REACTOR CRUDE PERCENTS Per/Tri Per&Tri TCE Heavies Lights
3.30 88.78
0.13 5.55 1.73
3.04 90.73
0.04 4.88 1.77
3.95 96.00 0.03 5.01
1.27
3.07 89.81
0.05 5.60 1.62
3.53 89.53
0.02 5.45 2.14
1.53 83.66
0.07 5.99 5.00
0.94 69.86
1.16 5.62 5.98
1.85 88.84
0.10 3.98 3.74
3.77 92.30
0.02 4.01 246
3.09 89.68 0.06 5.16 280
1.79 91.06
0.01 3.96 1.91
1.48 90.94
0.01 5.10 1.95
2.61 88.43
0.14 5.03 270
2.69 88.92
0.16 5.41 1.90
SL 014313
B4Q
PER-TRI OPERATIONS
; t i'iSN'i'*A1> ` S-.ib'-e'jt "t*.* rrotective
.. c '< 4 f i> ,1 inl >.ca-3 * v> L s fc ~ ' i!o. 9l-U
^
REACTOR NO. 4 On Stream Time Hr.
Jan-91 Feb-91 Mar-91 Apr-91 May-91 Jun-91 Jul-91 Aug-91 Sep-91 Oct-91 Nov-91 Dec-91 12M Avg 90 Avg 0 672 720 694 702 652 188 632 716 620 704 740 587 6859
TEMPERATURES, DEG. F. Vaporizer Liquor DowthermOut Reactor Vent
323 322 329 330 316 324 310 312 308 275 291 313 334
505 526 512 514 494 510 519 534 499 506 489 510 499
30 33 40
42 42 41
39 37 35 30 31
36 31
Organics, gpm Oxyqen, scfh
HCI, scfh Vent Flow, scfh Catalysts, lbs
5 88 8687887678
9781 10394 10586 10867 10328 12375 11024 10449 9769 9537 8976 10371 10993
8640 10396 10925 9971 9850 9832 9546 8511 7303 7928 7301 9109 10968 6607 8467 10759 9889 10288 11103 9246 7357 7813 6412 6505 8586 10524 0 5250 8750 8400 8400 8050 8050 8050 7700 8400 8750 8400 7350 9713
REACTOR CRUDE PERCENTS Per/Tri Per & Tri TCE Heavies Lights
3.06 89.87
0.06 5.42 2.01
3.81 97.11
0.03 4.52 1.20
3.00 90.31
0.06 5.56 1.01
3.40 95.30
0.04 5.53 1.46
1.55 88.50
0.02 5.67 1.94
1.11 88.46
0.04 5.10 2.02
1.47 69.86
0.01 4.72 2.07
3.14 91.69
0.02 4.53 219
278 90.44
0.04 5.49 206
1.93 90.48
0.04 4.73 1.60
1.55 90.60
0.02 5.36 1.24
244 91.15
0.04 5.15 1.71
263 88.74
0.31 5.40 1.74
SL 014314 B50
PER-TRI OPERATIONS
CCWPiIDBHIJafc: Subject to Frctsetiv# Order
of 14th Judicial Oietrict Court Ko. 91-11 *5
REACTOR NO. 5 On Stream Time Hr.
Jan-91 Feb-91 Mar-91 Apr-91 May-91 Jun-91 Jul-91 Aug-91 Sep-91 Oct-91 Nov-91 Dec-91 12M Avg 90 Avg 555 150 744 696 744 660 744 728 720 0 0 660 533 7010
TEMPERATURES, DEG. F. Vaporizer Liquor Dowtherm Out Reactor Vent
324 325 327 329 333 324 335 315 317 500 468 466 485 478 447 449 436 440
28 27 33 35 29 32 27 24 21
319 325 331 472 464 475
20 28 27
Organics, gpm Oxygen, scfh
HCl.scfh Vent Flow, scfh Catalysts, lbs
5 1 11 14 14 10 10 8 9 0 0 8 8 7 8494 2550 13251 11540 10075 9407 11026 10159 10280 0 0 12333 8260 11050 7840 2528 10436 10563 9854 9627 10224 9087 8369 0 0 7768 7191 10419 9984 3338 10063 9974 8326 9303 9472 6788 6234 0 0 8630 6843 8931 8400 1400 9450 8400 8400 7700 7350 6300 7000 0 0 22050 7204 8546
REACTOR CRUDE PERCENTS Per/Tri Per & Tri TCE Heavies Lights
3.37 91.84
0.04 4.70 1.43
2.59 84.51
0.70 8.58 1.92
3.69 91.89
0.03 4.33 1.73
2.96 90.81
0.05 4.78 1.47
3.38 91.37
0.05 4.67 1.31
1.29 86.63
0.12 5.02 1.89
1.14 88.88
0.10 5.44 1.84
1.48 91.95
0.05 4.50 1.10
279 9284
0.03 4.60 1.18
221 88.58 0.13 5.53 2.07
249 89.93
0.13 5.22 1.59
265 88.83
0.23 6.03 1.50
SL 014315
PER-TRI OPERATIONS
subject
to
Protectiv-
Ord^T ct Court
nth Judicial Vi***
HEAVY STILL BOTTOMS
t-1,2 Dichlorethylene 1,1,1 Trichloroethane
Perchloroehylene U - Tetrahloroehtane S - Tetrahloroehtane
Pentachloroethane Hexachloroethane Pentachlorobutadiene Hexchlorobutadiene Heavy Unknowns
PER-TRI BOTTOMS TO W.R.
t-1,1 Dichlorethylene 1,1,2 - Trichloroethane
Perchloroehylene U - Tetrahloroehtane S - Tetrahloroehtane
Pentachloroethane Hexachloroethane Pentachlorobutadiene Hexchlorobutadiene Heavy Unknowns
RECYCLE FEED
1,1 Dichloroethane 1,1,2 - Trichloroethane
Perchloroehylene U - Tetrahloroehtane S - Tetrahloroehtane
Pentachloroethane Heavy Unknowns Carbon Tetrachloride
FeCI3 Hexachloroethane
Jan-91 Feb-91 Mar-91 Apr-91 May-91 Jun-91 Jul-91 Aug-91 Sep-91 Oct-91 Nov-91 Dec-91 12M Avg 90 Avg
48.20 0.01 1.31
13.00 2.91 5.61 14.00 14.11
54.77 0.35 4.64
15.66 1.68
12.75 1.20 9.52
73.78 0.00 0.88 6.48 1.55 7.18 9.70 0.43
59.83 0.01 1.15 6.65 3.02 3.96
22.77 2.70
52.14 0.02 0.30 6.00 2.86 4.43
22.73 11.52
57.02 0.16 1.06 3.15 2.10 6.09
15.75 14.62
54.18 0.19 4.35 4.64 1.41 6.94
14.51 13.77
51.40 0.06 6.83 5.86 1.22 6.83
17.10 10.69
59.07 0.01 0.47 6.42 0.94 3.32
19.99 9.77
52.99 0.01 0.67 4.90 0.61 2.42
17.09 21.38
62.63 0.02 2.03 5.57 0.49 3.09
17.38 8.77
52.56 0.07 2.36 8.41 1.04 4.65
19.68 11.22
56.55 0.07 2.17 7.23 1.65 5.61
15.99 10.71
52.40 0.22 3.39 9.81 2.48 3.25
14.10 13.68
8.84 28.87
5.88 7.38 8.84 2.63
9.29 25.03
7.41 9.55 8.97 2.24
7.43 33.58
5.98 6.13 6.72 1.90
6.71 33.19
6.56 6.61 5.94 1.95
.
4.82 35.63
4.96 5.12 6.11 1.43
3.52 41.93
3.49 4.40 3.88 2.68
5.93 35.07
5.05 7.04 4.37 3.68
5.15 47.04
3.72 5.72 5.77 3.15
7.20 46.07
6.09 6.48 5.73 0.95
7.25 47.37
4.87 5.45 4.91 0.82
5.06 42.97
4.75 6.02 5.24 1.01
4.56 36.75
5.53 7.99 7.57 1.65
6.31 37.79
5.36 6.49 6.17 2.01
9.32 38.58
7.25 7.43 7.70 2.11
34.79 34.48 38.01 34.93 41.16 40.10 38.75 29.45 27.48 29.33 34.95 34.99 34.87 22.36
5.01 30.18 18.35 14.07
9.01 4.20 0.46 2.61 9.74 0.63
6.02 32.33 13.88 15.02
9.26 4.55 0.45 2.69 11.51 0.67
5.61 24.20 26.83 13.11
8.06 4.20 0.73 2.72 17.62 0.67
5.95 24.51 24.62 15.21
9.84 4.49 0.83 2.18 14.39 0.70
5.17 21.82 36.66 10.35
7.39 3.11 0.73 2.12 11.52 0.84
11.78 28.47 26.46
3.78 4.57 1.74 0.60 3.54 7.68 0.79
21.08 20.45 19.85 13.59 10.24
3.52 0.32 1.01 8.27 0.66
20.35 23.26 25.98
8.23 7.22 2.69 0.32 1.32 8.85 0.59
13.41 23.47 30.81 11.37
7.82 3.22 0.26 2.27 10.78 0.55
7.59 26.64 29.42
8.68 7.33 2.60 0.36 4.65 16.98 0.46
9.46 19.90 27.96 14.20 9.53
3.42 0.18 2.50 17.04 0.29
13.11 23.47 19.12 14.54 10.11
4.82 0.25 2.20 14.33 0.81
10.38 24.89 24.99 11.85
8.37 3.55 0.46 2.48 12.39 0.62
9.49 27.43 18.59 14.58
9.31 4.74 0.69 1.79 10.81 0.88
B70 SL 014316
..oi-rf .1 ? V -1 1 *V ^;rri3vr:ci: Cour r ;4^. >umc.'-''1 1 r.`
' ,;o. *n~ i
PER-TRI OPERATIONS
WEIGHT PERCENTS
Jan-91 Feb-91 Mar-91 Apr-91 May-91 Jun-91 Jul-91 Aug-91 Sep-91 Oct-91 Nov-91 Dec-91 12M Avg 90 Avg
TYPE 208 Perchioroethylene 1,1 -Dichlorobromoethylene 1,2-Cichlorobromoethylene 1,1,2-Trichloroethane U -Tetrachloroethane
EPE Hqmme Total Impurities
99.90 <0.01
0.02
<0.01 0.05
<0.01 0.04
99.92 5.10
11.67
2.08 0.05 0.01 0.03
99.90 0.01 0.02
0.01 0.06 0.01 0.04
99.91 18.70 32.41
2.24 0.44 0.01 0.03
99.90
0.02
0.00 0.07 0.01 0.03
99.88
0.01
0.01 0.08 0.01 0.04
99.89 0.01 0.02
99.89 0.01 0.02
0.01 0.01 0.06 0.06 0.01 0.01 0.05 0.05
99.92 0.01 0.02
0.01 0.05 0.01 0.04
99.90 0.01 0.02
0.01 0.06 0.01 0.05
99.90 0.00 0.01
0.00 0.07 0.01 0.03
99.90 2.65 4.02 0.00 0.40 0.09 0.01 0.04
99.90 0.01 0.02 0.02
<0.01 0.05
<0.01 0.04
TYPE 230 Perchioroethylene 1,1 -Dichlorobromoethylene 1,2- Cichlorobromoethylene 1,1,2-Trichloroethane U -Tetrachloroethane
EPE Hqmme
MLE
Total Impurities
CHO
99.82 0.01 0.02
0.00 0.06 0.01 0.00
0.04
0.08
99.83
0.03
0.00 0.06 0.01 0.01 0.01
0.05
0.04
99.83 0.01 0.02
0.00 0.07 0.01 0.01
0.03
0.06
0.00 0.00 0.00
0.00 0.00 0.00 0.00
0.00
0.00
99.82 0.01 0.02
0.01 0.06 0.01 0.01
0.05
0.08
99.82 0.01 0.02
0.00 0.07 0.01 0.00
0.04
0.06
99.83 0.00 0.01
0.09 0.01 0.01
0.01
0.09
85.56 0.01 0.02
99.82 0.01 0.02
0.00 0.06 0.01 0.00
0.01 0.06 <0.01 <0.01
0.03 0.20
0.06 0.07
TYPE 232 Perchioroethylene 1,1 -Dichlorobromoethylene 1,2-Cichlorobromoethylene 1,1,2-Trichloroethane U -Tetrachloroethane
Chlorobenzene Hqmme
99.99 0.02 0.05
<0.001 <0.01 <0.001 <0.01
99.98 32.04 81.79
99.77 51.23 119.89
16.77 9.23 1.50
14.23 14.89 0.01
99.97 35.95 85.64
63.93 18.06 4.00
99.98 58.22 133.74
8.74 7.56
99.98 41.18 107.54
11.30 3.44
99.98 45.65 110.14
0.00 4.40
99.98 49.72 123.84
13,74 3.76 5.00
99.98 43.92 105.73
8.53 4.48 4.90
99.98 50.81 120.29
6.16 4.26 14.30
99.98 49.70 123.22
6.77 3.66 3.30
99.98 52.57 130.22
9.78 3.92 5.60
99.96 42.58 103.51
0.00 13.33
6.47 4.29
99.56 0.05 0.09
<0.01 <0.01 <0.01 <0.01
B80
SL 0143T7
PER-TRI OPERATIONS
COMF1 DEffPl Aht
Subject to Protective Order of 14th Judicial District Court
Ho. 91-1145
WEIGHT PERCENTS
Jan-91 Feb-91 Mar-91 Apr-91 May-91 Jun-91 Juf-91 Aug-91 Sep-91 Oct-91 Nov-91 Dec-91 12M Avg 90 Avg
TYPE 145 Carbon Tetrachloride
BLM
NPL Trichloroethylene Perchloroethylene 1,1,2-1richloroethane
0.25 0.146 99.44
0.02 0.06 0.104 99.57
0.01 0.21 0.104 99.56
0.01 0.07 0.156 99.56
0.00 0.10 0.086 99.65
0.01 0.31 0.125 99.50
0.01 0.29
0.123 99.50
0.00 0.29 0.125 99.50
0.01 0.30 0.061 99.50
0.01 0.32 0.143 76.95
0.00 0.32 0.142 99.46
0.00 0.32 0.137 99.47
0.01 0.24 0.121 97.64
<0.01 0.29
0.141 99.45
Unidentified Total GDL ADH TYL CHO
Total Impurities
0.01 0.03 0.02 0.03 0.03 0.02 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.012 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01
0.1 0.04 0.03 0.03 0.02 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.05 0.03 0.03 0.04 0.03 0.03 0.03 0.03 0.02 0.02 0.03 0.03
CarbonTetrachtoride TYPE 113
Trichloroethylene Perchloroethylene 1,1,2-Trichloroethane
Total Impurities Unidentified Total
DPE
99.94
0.01 0.06 0.02 27.00
99.97 0.03
99.98 99.99 99.97
0.03 0.02 0.03 27.50 32.00 28.00
0.00 99.98 99.98 99.98 88.86 99.96
0.00 0.03 0.02 0.00 28.00 28.00
0.01 0.03 0.03
0.02 0.00 21.31
0.04 0.02 0.03
Specific Gravity, 20/20
pH Dist. Range, Deg. C.
Low
________ mi________
1.468 8.5
86.6 87.1
1.47 1.47 1.47 9.65 9.70 9.50
86.78 86.80 86.90 87.33 87.40 87.30
0.00 1.47 1.47 0.00 9.70 9.53
0.00 86.80 86.80 0.00 87.20 87.33
0.00 1.100 1.467 6.50 7.9 8.9
0.00 65.1 86.4 0.00 65.5 87.1
SL 014318
B90
