Document 2j9KeKER82jpd7gJKY4Yxrryg

r* oc. Mr! lffier(3) I W Mr. Jackson' ' - BBH Mr. Kimball - BT Bird Mr. Mai oof Mr. Marsh Mr. Roelofs - BBP - MK - BBH Mr. Wood - BBP lemolb: Mr. McGonagle - RL From: Mr. Jagocki - BBH-5>Tecfl File ibject: MATERIAL SAEEtfDATA SHEETS Date^ CHARLESTON/GLASS MAT PLANT April 28, 1982 PLAINTIFF'S EXHIBIT BIR-843 Attached please find Material Safety Data Sheets (0SHA-20) for chemicals currently in use at the Charleston Glass Mat Plant. These are as follows: Nalco Nalco Nalco 1 PC-059 aqueous solution of sodium chlorite 8601 hydrochloric acid 8669 defoamer The following chemical should be removed from your records as it is no longer used: Nalcon 7649 slimicide Those with the glass mat test manual should keep these in the miscellaneous section. RFJ'cei" Attachments C/ BIRD 013299 SECTION 1 - PRODUCT IDENTIFICATION I- OmoNi !r* UJ oU< u. < Ji <o 2 < 01 u s *a3a >25o " CL a si Sc. Q4 Nalco i PC-059 Trad* Namo_ An aqueous solution of sodium chlorite Synonyms. SECTION 2 - HAZARDOUS INGREDIENTS MATERIAL. OR COMPONENT Sodium chlorite Formula No._ Chemical Family. Inorganic % 15 SECTION 3 - PHYSICAL PROPERTIES Bolling Point. 760 MM HQ Spocifle Gravity (H20t) rreeze Point 21F Vapor Pressure Vapor Oanslty (Alr*t) 9.5 / gal. % Volatiles 8y Voi. Solubility In H*0. % By Wt. Soluble Evaporation Rato (Butyl AcatataM) Appearance and Odor Colorless to slight yellow, pungent odor pH (neat) = 12.1 SECTION 4 - FLAMMABILITY AND EXPLOSIVE PROPERTIES Flash Point {Test Mathad) >209F (PMCC) ptammahio Umlt* In Air, % By Vol. Lowar Upoar U& a! Extlngulrtilnp Media C02f dry chemical, water fog Special Fir* Fighting Procedures Uk Remove burning drum from area, spray other drums to keep cool. j3 unusun Fir. and explosion Heard Decomposes "at 35QaP, giving off oxygen, overheated ^ a drums may rupture spreading fire. 2S SECTION 5 -- HEALTH HAZARD DATA Threshold Umlt Vslue None established for the product. Chlorine dioxide = 0.1 ppm Effect* of Ovcrexposura May cause severe irritation to tissue and mucous membranes. Can cause pulmonary irritation.__________________________________________________________________ EMERGENCY AND FIRST AID PROCEDURES Eyes Flush with large amounts of water for 15 minutes. Call a physician. Skin Immediately flush with water for 15 minutes. (n?stton Do not induce vomiting. Give large amounts of water. Call a physician. Inhalation ________________ Remove to fresh air. Treat symptoms.___________________________________________________ FORM 507 (t 1*76) (Continued on Reverse Side) BIRD 013300 OonN< O 04 o JJ <0 2 n *an I Hm 4 <a Q0a0) si Og UgQ HV UMM c-- c< mg i5 sa. 35 Ji: J ^a 2 3- SECTlOIM 6 - REACTIVITY DATA Stability: Stable I unstable conditions to Avoid Do not contaminate with acids, combustible or reducing agents. Materials to Avoid. Acids Hazardous Oocompositlon Products. CIO? gas _. . ,, BWill Not Occur Hazardous Polymerization: May Occur LJ conditions to Avoid SECTION 7 - SPILL OR LEAK PROCEDURES Staps to Taka In Casa Material Is Released or Spilled Flush With COpjOUS amounts of Water. Dp not let spilled material dry on floors. waste ouposai Matnod Consult local, state and federal ordinances for appropriate disposal of pesticides. SECTION 8 - SPECIAL PROTECTION INFORMATION Full face cartridge respirator - use cartridges Type of Respiratory Protection Required approved for chlorine________________________ Ventilation: Local exhaust 0; Mechanical (General) D; Special (Specify)Other (SpecifyL Protectiveoiaves Neoprene y protection___ Face shield___ Other Protective Eouloment Rubber apron SECTION 9 - SPECIAL PRECAUTIONS Handling and storage Prtcautioo Store in cool, dry place, separate from certain acids, ccifabtistibie tirganics and reducing agents.____________________________________ s otfiferPrccailtlohi----JLernaVcL.nntamina11d rlnthing immprfiatelv and wash with water. On nnf . take internally, Avoid.evie and skin contact. Do not inhale vaoors or mist if____________ generated.______________________________ ____________ vSSsk Similar to Form OSpA-20 Title Corporate Toxicologist Oate EMERGENCY TELEPHONE NUMBER - (312) 920-1510 5/21/82 Page 2 BIRD 013301 SECTION 1 - PRODUCT IDENTIFICATION e* H >*f Trad. N.m._______ ^ 6 0 ______________________________ synonym.______Hydrochloric Acid < t 3 Uo L ID CO 0 J t c J t Tg3O3 ak_. SECTION 2 - HAZARDOUS INGREDIENTS MATERIAL. OR COMPONENT Hydrogen Chloride SECTION 3 - PHYSICAL PROPERTIES oMn Point, 7*0 MM MG Meltlnf Point FovTOUta No., Chemical Family. Inhibited acid % 30 Spflcinc Gravity (m20i) 1.14 e`op Vapor Density (AJr*1| * Volatiles Oy VoL Vapor Pressure Solubility In M2Ot * fty Wt Soluble Evaporation Ran (Butyl Acatat*t) Appearance and Odor Clear-amber liquid with a punqent acidic odor SECTION 4 - FLAMMABILITY AND EXPLOSIVE PROPERTIES Flesn Point (Tost Metnoai None Ftemmebie Limits In Air, H ly VoU Lower UPpar Extinguishing MedU siweiai nr. nntin procMtum pight as any acid fire - reacts with water or steam to produce toxic and corrosive fumes Unusual Fire and Explosion Hasans N A L C O C H G M I C A M jfN H P A N V ?ium n u t m m * o moatt oak iv ^ S 0 f x t \\.\ inlhb nonfM '^ SECTION 5 --HEALTH HAZARD DATA ThreHiold Limit Value . Hydrogen., chloride.. _5ppm. i celling) Effect* of Overexposure Severe acid burns-neurosis-corrosive. < Harmful if swallowed or if mist inhaled.__________________________________________________ ____ KMCROCNCY AND FIRST AID PROCEDURES cy*t Immediately flood with water for at least 15 minutes. physician at once. Call a *Wn Immediately flood with water for 15 minutes. Call a physician inflection Do nQt induce vomiting. Call a physician. Give victim milk or water.___Sever, give an unconscious person anything by mouth. tnnatktton jjemove to freSh air. Treat symptomatically FORM SO? (7/71) (CentinuMt en Revere* StdJ BIRD 013302 N A L C O C H E M IC A L C O M P A N Y * )1111s111 ! i m h i n M n a h n t >a k " n n o f t K . n .t i n u m & i SECTION 6 - REACTIVITY DATA Stability: cs t>< G Condition* to Avoid "S As any strong acid (see 8PF-6Q2 product bulletin for specific information) o Hturdout Dicompoiition Pmo..on May produce toxic fumes of chloride or hydrogen VD i CO which is extremely flammable CS.Hazardous Polymerization: Will Not Occur May Occur Q Condition* to Avoid e SECTION 7 - SPILL OR LEAK PROCEDURES Slept to Take In Cate Material Is Released or Spilled,, Cover contaminated area with sodium bicarbonate or a soda ash-slaked lime mixture (50-50) mix and .add.-Hater ...if necessary., to.,,.forni...a..slurry,.=_: win. otipoui Mrthod Scoop up slurry and wash down drain with copious amounts of water. SECTION 8 - SPECIAL PROTECTION INFORMATION Tyo.of R<r,tory Proticuon wamm Wear self contained mist severe Ventilation. Cecal Cxtiauat G: Mtchinlcil (Cmmt) D; Special KMdtvl breathino apparatus other fSeecIfvt if_ Protictiv*ciovi* Acid proof cyProtiction Safety googles otn.rPretiettv.cquipm.nt_______________Acid resistant. clothing_____________ SECTION 9 - SPECIAL PRECAUTIONS Handling.ndstem. Pmautien Handle as any strong acid (See 8PF-6Q2 product hnl let in--fo.r -specific -handling information) otnarPrecautiom Do not take -internally. Do not contact eves, skin or . clothing------Remove and launder contaminated clothing hefrvre reuse. See 8PF-602 product bulletin - Prepared By A. Similar to Form OSHA-20 Title Corporate Toxicologgt& 3/13/81 EMERGENCYrmVELEPHONE NUMBER - (312) 332-3560 Pag* 2 BIRD 013303 IWIMI CK1 IM L. O M r U I U r t lM O ' -fc-l SECTION 1 -PBODUCI IDb-Nl IHCA1 ION 4 Nalco 8669 Tr4de Name __ _ _ ______ __________ Synonym* _ Fatty_Acid - Poly^gly** col Formula No*. Antifoam Chemical Family. a\ SECTION 2 - HAZARDOUS INGREDIENTS to VO 03 MATERIAL OR COMPONENT OO None in z s Uoo3 SECTION 3 - PHYSICAL PROPERTIES Bolting Point, 765 MM HG Melting Point Specific Gravity (H20=1) 0.881 e 77F Vapor Density (AIr*t) %. Volatiles By Vol. Vapor Pressure Solubility In H20, % By WL Insoluble Evaporation Rate (Butyl AcetateM) 0 J <2 0a 5c a< U-Il 10o Uw tL as Ot: <5 Zl Appearance and Odor Hazy straw liquid with faint aromatic odor SECTION 4 - FLAMMABILITY AND EXPLOSIVE PROPERTIES Flash Point (Test Method) >300F (COC) Flammable Limits In Air, % By Vol. Lower Extinguishing Media Foam, dry chemical, Special Fire Fighting Procedures C02, water spray None Unusual Fire and Explosion Hazard None . ... SECTION 5 - HEALTH HAZARD DATA Threshold Umit Vaiue T None established for product. Effects of Overexposure May cause eye or skin irritation. Upper EMERGENCY AND FIRST AID PROCEDURES Eyes T) Flush with water for 15 minutes. Call a physician. --~~ ` Wash with mild soap and rinse thoroughly with water. Ingestion Do not induce vomiting. Call a physician. Inhalation BIRD 013304 N alC O 8669 Product_____________________ SECTION 6 - REACTIVITY DATA Stable IS Stability: Unstable 0 Conditions to Avoid Material* to Avoid. None Hazardous Decomposition Products. unburned hydrocarbon Will Not Occur SI CDHazardous Polymerization: May Occur conditions to Avoid SECTION 7 - SPILL OR LEAK PROCEDURES Use absorbent material to contain spill. Steps to Take In Case Material Is Released or Spilled. N A IL C O C U n iV U C A L C O M P A N Y 3901 HUT r6 n l'(l;l,0 (lUAOll IIAK SHOOK, ILLINOIS BOS21 Dispose by complete combustion or burial. Waste Disposal Method. SECTION 8 - SPECIAL PROTECTION INFORMATION Type of Respiratory Protection Required.. None CD;Ventilation: Coca) Exhaust : Mechanical (Central) Special (Specify). Protective Cloves. Rubber Eye Protection. Other Protective Equipment. None Other (SpedfyL Safety goggles SECTION 9 - SPECIAL PRECAUTIONS Handling end Storage Precaution Store at room temperature. If product separates upon storage, mix thoroughly to redisperse. Other Precautions Avoid prolonged skin contact. Avoid eye contact. ; (1 1 a-'"? _________________JZ Prepared By 1/ Similar to Form OSHA-20 -____ J.j. f( TTHieC8yg2^ne Date June, 1977 EMERGENCY TELEPHONE. NUMBFR _ (31?) 970-1510 BIRD 013305