Document 2j2jnGzK9qLG1wkVbQdZ9pNz7

+----------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------- --- Date Printed: 08-15-1996 Page 1 LA-MAR-KA MSDS for HYDROCHLORIC ACID SOLUTIONS 1 -PRODUCT IDENTIFICATION PRODUCT NAME: COMMON SYNONYMS: CHEMICAL FAMILY: FORMULA: FORMULA WT.: CAS NO.: NIOSH/RTECS NO.: PRODUCT USE: HYDROCHLORIC ACID SOLUTIONS 2N TO 0.0IN CHLOROHYDRIC ACID; AQUEOUS INORGANIC ACIDS HCL 36.46 N/E N/E LABORATORY REAGENT HYDROGEN CHLORIDE, CHEMTREC # (800) 424-9300 LA-MAR-KA, INC. 10272 SOUTH PERDUE STREET BATON ROUGE, LA. 70814 EFFECTIVE: 10-01-93 REVISION #04 ISSUED: 10-01-93 REVIEWED 1-1-95 PRECAUTIONARY LABELING .-MAR-KA LABELING SYSTEM ( HEALTH 3 SEVERE (POISON) FLAMMABILITY - 0 NONE REACTIVITY 2 MODERATE CONTACT 3 SEVERE (CORROSIVE) LABORATORY PROTECTIVE EQUIPMENT GOGGLES & SHIELD; LAB COAT & APRON; VENT HOOD; PROPER GLOVES U.S. PRECAUTIONARY LABELING POISON DANGER CAUSES SEVERE BURNS. MAY BE FATAL IF SWALLOWED OR INHALED. DO NOT GET IN EYES, ON SKIN, ON CLOTHING. DO NOT BREATHE VAPOR. CAUSES DAMAGE TO RESPIRATORY SYSTEM (LUNGS), EYES AND SKIN. KEEP IN TIGHTLY CLOSED CONTAINER. LOOSEN CLOSURE CAUTIOUSLY. USE WITH ADEQUATE VENTILATION. WASH THOROUGHLY AFTER HANDLING. IN CASE OF SPILL NEUTRALIZE WITH SODA ASH OR LIME AND PLACE IN DRY CONTAINER. PRECAUTIONARY LABELING (CONTINUED) INTERNATIONAL LABELING IRRITATING TO EYES AND SKIN. KEEP OUT OF REACH OF CHILDREN. IN CASE OF CONTACT WITH EYES, RINSE IMMEDIATELY WITH PLENTY OF WATER AND SEEK MEDICAL ADVICE. ( DO A 060719 CONFIDENTIAL H----------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------- Date Printed: 08-15-1996 Page 2 LA-MAR-KA MSDS for HYDROCHLORIC ACID SOLUTIONS ----------------------------------------------------------------------------------------------------------------------------------------------------------------+ 1 -PRODUCT IDENTIFICATION (continued) LA-MAR-KA STORAGE COLOR CODE: WHITE (CORROSIVE) 2 -COMPONENTS COMPONENT HYDROCHLORIC ACID WATER CAS NO. 7647-01-0 7732-18-5 WEIGHT % 8- 0.068 92 ->99 OSHA/PEL 5 PPM N/E ACGIH/TLV 5 PPM N/E 3 -PHYSICAL DATA BOILING POINT: N/E (AT 760 MM HG) VAPOR PRESSURE (MMHG): N/A MELTING POINT: N/E (AT 760 MM HG) VAPOR DENSITY (AIR=1): 1.3 'ECIFIC GRAVITY: 1.19 -1.0 (H20=l) EVAPORATION RATE: N/A SOLUBILITY(H20): COMPLETE (100%) % VOLATILES BY VOLUME: 100 (21 C) PH: 1.0 (0.1M SOLUTION) ODOR THRESHOLD (P.P.M.): N/A PHYSICAL STATE: LIQUID COEFFICIENT WATER/OIL DISTRIBUTION: N/A APPEARANCE & ODOR: CLEAR, COLORLESS FUMING LIQUID. PUNGENT ODOR. 4 -FIRE AND EXPLOSION HAZARD DATA FLASH POINT (CLOSED CUP): N/A NFPA 704M RATING: 3-0-0 AUTOIGNITION TEMPERATURE: N/A FLAMMABLE LIMITS: UPPER - N/A LOWER - N/A FIRE EXTINGUISHING MEDIA USE EXTINGUISHING MEDIA APPROPRIATE FOR SURROUNDING FIRE. DO A 060720 CONFIDENTIAL ---------- ------------+------------------- ---------------------------- ------------------------------------------------------------ ----------------------------------------------------------------------------------------------------------------------------- + Date Printed: 08-15-1996 Page 3 LA-MAR-KA MSDS for HYDROCHLORIC ACID SOLUTIONS ----------------------------------------------------------------------------------------------------------------------------------------------------------------+ 4 -FIRE AND EXPLOSION HAZARD DATA (continued) SPECIAL FIRE-FIGHTING PROCEDURES FIREFIGHTERS SHOULD WEAR PROPER PROTECTIVE EQUIPMENT AND SELF-CONTAINED BREATHING APPARATUS WITH FULL FACEPIECE OPERATED IN POSITIVE PRESSURE MODE. MOVE CONTAINERS FROM FIRE AREA IF IT CAN BE DONE WITHOUT RISK. USE WATER TO KEEP FIRE-EXPOSED CONTAINERS COOL. DO NOT GET WATER INSIDE CONTAINERS. UNUSUAL FIRE & EXPLOSION HAZARDS MAY EMIT HYDROGEN GAS UPON CONTACT WITH METAL. TOXIC GASES PRODUCED HYDROGEN CHLORIDE, HYDROGEN EXPLOSION DATA-SENSITIVITY TO MECHANICAL IMPACT NONE IDENTIFIED. EXPLOSION DATA-SENSITIVITY TO STATIC DISCHARGE NONE IDENTIFIED. -HEALTH HAZARD DATA .iRESHOLD LIMIT VALUE (TLV/TWA) : 7 MG/M3 (5 PPM) TLV (CEILING) IS FOR HYDROGEN CHLORIDE. SHORT-TERM EXPOSURE LIMIT (STEL): NOT ESTABLISHED PERMISSIBLE EXPOSURE LIMIT (PEL): 7 MG/M3 (5 PPM) PEL (CEILING) IS FOR HYDROGEN CHLORIDE. TOXICITY OF COMPONENTS INTRAPERITONEAL MOUSE LD50 FOR HYDROCHLORIC ACID ORAL RABBIT LD50 FOR HYDROCHLORIC ACID INHALATION-1HR RAT LC50 FOR HYDROCHLORIC ACID INTRAPERITONEAL MOUSE LD50 FOR WATER INTRAVENOUS MOUSE LD50 FOR WATER CARCINOGENICITY: NTP: NO IARC: NO Z LIST: NO CARCINOGENICITY NONE IDENTIFIED. REPRODUCTIVE EFFECTS NONE IDENTIFIED. OSHA REG: 40 MG/KG 900 MG/KG 3124 PPM 190 G/KG 25 G/KG NO ( 00 A 060721 CONFIDENTIAL +------------------------------ ------ -------- ------------------------------------------- ----------- ------- ----------------------------------------------------------------- --------- + Date Printed: 08-15-1996 Page 4 LA-MAR-KA MSDS for HYDROCHLORIC ACID SOLUTIONS ---------------------------------------------------------------------------------------------------------------------------------------------------------------- + ( 5-HEALTH HAZARD DATA (continued) EFFECTS OF OVEREXPOSURE INHALATION: PULMONARY EDEMA, CIRCULATORY FAILURE, RESPIRATORY SYSTEM DAMAGE, COLLAPSE, COUGHING, DIFFICULT BREATHING SKIN CONTACT: SEVERE BURNS EYE CONTACT: SEVERE BURNS SKIN ABSORPTION: NONE IDENTIFIED INGESTION: IS HARMFUL AND MAY BE FATAL, SEVERE BURNS TO MOUTH, THROAT, AND STOMACH, NAUSEA, VOMITING CHRONIC EFFECTS: NONE IDENTIFIED TARGET ORGANS RESPIRATORY SYSTEM, EYES, SKIN MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE NONE IDENTIFIED [MARY ROUTES OF ENTRY INGESTION, INHALATION, SKIN CONTACT, EYE CONTACT EMERGENCY AND FIRST AID PROCEDURES INGESTION: CALL A PHYSICIAN. IF SWALLOWED, DO NOT INDUCE VOMITING. IF CONSCIOUS, GIVE WATER, MILK, OR MILK OF MAGNESIA. INHALATION: IF INHALED, REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN. SKIN CONTACT:: IN CASE OF CONTACT, IMMEDIATELY FLUSH SKIN WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES WHILE REMOVING CONTAMINATED CLOTHING AND SHOES. WASH CLOTHING BEFORE RE-USE. EYE CONTACT: IN CASE OF EYE CONTACT, IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. SARA/TITLE III HAZARD CATEGORIES AND LISTS ACUTE: YES CHRONIC: YES FLAMMABILITY: NO PRESSURE: NO REACTIVITY: NO EXTREMELY HAZARDOUS SUBSTANCE: YES CONTAINS HYDROGEN CHLORIDE (RQ = 1 LB, TPQ = 500 LBS) CERCLA HAZARDOUS SUBSTANCE: YES CONTAINS HYDROCHLORIC ACID (RQ = 5000 LBS) DO A 060722 CONFIDENTIAL H-- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- ---------------- ______ _---- LA-MAR-KA MSDS for HYDROCHLORIC ACID SOLUTIONS ---------- -- -- -- -- -- -- -- -- -- -f Date Printed: 08-15-1996 Page 5 5 -HEALTH HAZARD DATA (continued) SARA 313 TOXIC CHEMICALS: GENERIC CLASS: TSCA INVENTORY: YES CONTAINS HYDROCHLORIC ACID C16 YES 6 -REACTIVITY DATA STABILITY: STABLE HAZARDOUS POLYMERIZATION: WILL NOT OCCUR CONDITIONS TO AVOID: HEAT, MOISTURE INCOMPATIBLES: MOST COMMON METALS, WATER, AMINES, METAL OXIDES, ACETIC ANHYDRIDE, PROPIOLACTONE, VINYL ACETATE, MERCURIC SULFATE, CALCIUM PHOSPHIDE, FORMALDEHYDE, ALKALIES, CARBONATES, STRONG BASES, SULFURIC ACID, CHLOROSULFONIC ACID DECOMPOSITION PRODUCTS: HYDROGEN CHLORIDE, HYDROGEN, CHLORINE -SPILL & DISPOSAL PROCEDURES STEPS TO BE TAKEN IN THE EVENT OF A SPILL OR DISCHARGE WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING. STOP LEAK IF YOU CAM DO SO WITHOUT RISK. VENTILATE AREA. NEUTRALIZE SPILL WITH SODA ASH OR LIME. WITH CLEAN SHOVEL, CAREFULLY PLACE MATERIAL INTO CLEAN, DRY CONTAINER AND COVER; REMOVE FROM AREA. FLUSH SPILL AREA WITH WATER. DISPOSAL PROCEDURE DISPOSE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE, AND LOCAL ENVIRONMENTAL REGULATIONS. EPA HAZARDOUS WASTE NUMBER: D002 (CORROSIVE WASTE) 8 -INDUSTRIAL PROTECTIVE EQUIPMENT VENTILATION: USE GENERAL OR LOCAL EXHAUST VENTILATION TO MEET TLV REQUIREMENTS. RESPIRATORY PROTECTION: RESPIRATORY PROTECTION REQUIRED IF AIRBORNE CONCENTRATION EXCEEDS TLV. AT CONCENTRATIONS UP TO 100 PPM, A CHEMICAL CARTRIDGE RESPIRATOR WITH ACID CARTRIDGE IS RECOMMENDED. ABOVE THIS LEVEL, A SELF-CONTAINED BREATHING APPARATUS IS ADVISED. D0 A 060773 CONFrDFNTrAl --------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------- + Date Printed: 08-15-1996 Page 6 LA-MAR-KA MSDS for HYDROCHLORIC ACID SOLUTIONS I ----------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------+ 8 -INDUSTRIAL PROTECTIVE EQUIPMENT (continued) EYE/SKIN PROTECTION: SAFETY GOGGLES AND FACE SHIELD, UNIFORM, PROTECTIVE SUIT, NEOPRENE GLOVES ARE RECOMMENDED. 9 -STORAGE AND HANDLING PRECAUTIONS LA-MAR-KA STORAGE COLOR CODE: WHITE (CORROSIVE) STORAGE REQUIREMENTS KEEP CONTAINER TIGHTLY CLOSED. STORE IN CORROSION-PROOF AREA. ISOLATE FROM INCOMPATIBLE MATERIALS. DO NOT STORE NEAR OXIDIZING MATERIALS. 10 -TRANSPORTATION DATA AND ADDITIONAL INFORMATION DOMESTIC (D.O.T.) UN1789 'A = NOT APPLICABLE OR NOT AVAILABLE E = NOT ESTABLISHED THE INFORMATION IN THIS MATERIAL SAFETY DATA SHEET MEETS THE REQUIREMENTS OF THE UNITED STATES OCCUPATIONAL SAFETY AND HEALTH ACT AND REGULATIONS PROMULGATED THEREUNDER {29 CFR 1910.1200 ET. SEQ.) AND THE CANADIAN WORKPLACE HAZARDOUS MATERIALS INFORMATION SYSTEM. THIS DOCUMENT IS INTENDED ONLY AS A GUIDE TO THE APPROPRIATE PRECAUTIONARY HANDLING OF THE MATERIAL BY A PERSON TRAINED IN, OR SUPERVISED BY A PERSON TRAINED IN, CHEMICAL HANDLING. THE USER IS RESPONSIBLE FOR DETERMINING THE PRECAUTIONS AND DANGERS OF THIS CHEMICAL FOR HIS OR HER PARTICULAR APPLICATION. DEPENDING ON USAGE, PROTECTIVE CLOTHING INCLUDING EYE AND FACE GUARDS AND RESPIRATORS MUST BE USED TO AVOID CONTACT WITH MATERIAL OR BREATHING CHEMICAL VAPORS/FUMES. EXPOSURE TO THIS PRODUCT MAY HAVE SERIOUS ADVERSE HEALTH EFFECTS. THIS CHEMICAL MAY INTERACT WITH OTHER SUBSTANCES. SINCE THE POTENTIAL USES ARE SO VARIED, LA-MAR-KA CANNOT WARN OF ALL OF THE POTENTIAL DANGERS OF USE OR INTERACTION WITH OTHER CHEMICALS OR MATERIALS. LA-MAR-KA WARRANTS THAT THE CHEMICAL MEETS THE SPECIFICATIONS SET FORTH ON THE LABEL. LA-MAR-KA DISCLAIMS ANY OTHER WARRANTIES, EXPRESSED OR IMPLIED, WITH REGARD TO THE PRODUCT SUPPLIED HEREUNDER, ITS MERCHANTABILITY OR ITS FITNESS FOR A PARTICULAR PURPOSE. THE USER SHOULD RECOGNIZE THAT THIS PRODUCT CAN CAUSE SEVERE INJURY AND EVEN DEATH, ESPECIALLY IF IMPROPERLY HANDLED OR THE KNOWN DANGERS OF USE ARE NOT HEEDED. READ ALL PRECAUTIONARY INFORMATION. AS NEW DOCUMENTED GENERAL OO A 060724 CONFIDENTIAL -----------------------------------------------------------------------------------------------------------------------------------------------------------------------Date Printed: 08-15-1996 Page 7 LA-MAR-KA MSDS for HYDROCHLORIC ACID SOLUTIONS 10 -TRANSPORTATION DATA AND ADDITIONAL INFORMATION (continued) SAFETY INFORMATION BECOMES AVAILABLE, THIS MATERIAL SAFETY DATA SHEET. LA-MAR-KA WILL PERIODICALLY REVISE APPROVED BY LA-MAR-KA, INC. DO A 060725 CONFIDENTIAL