Document 2j1p1weMooQVLeOXvrq6N5Ee6

APPENDIX G WASTEWATER TREATMENT RELEASE DATA AND CALCULATIONS SARA TITLE III, SECTION 313 1990 TOXIC CHEMICAL RELEASE INVENTORY LAKE CHARLES REFINERY SAL 000004251 Wastewater Treatment Release Wastewater releases were calculated as follows: 1. Effluent a. Used 1990 Benzene NESHAP source survey/design basis to estimate flowrate. b. Used 1989 composition to obtain total release to water. (From Dave Kersey) 2. Volatilization a. Volatilization from wastewater treatment facilities was estimated using a SIMS model (EPA supported) b. Compositional data obtained from the 1990 Benzene NESHAP source survey were used as input parameters. Releases from the API and CPI were calculated as follows: 1. Emission factors were taken from the NSPS-BID document to estimate VOC. 2. Crude oil composition has been assumed for the oil layer in the API/CPI traps. 3. Emissions are based on the weight fraction of each component with respect to crude oil. SAL 000004252 o >* JfioNssnnsN j'-'Or-ri-ncoi-T- CrvM CcoO S2 cr $ CM 7D E t/i I co o CM T3 o - oc LU J2 W< co UJ -J CO LU cc cr UJ t- c oco i oooooooooo <w5o3 -- T3 ?oOQQQQOOQ OSZZZZZZZZ --1 *o T3 c a 2 >* 3 *o "o (A CM tO CM U) CM IO Ui to CM w> CM t; to a c c N C m 3E O c E Tuo3i3 il c </J Q. 5, E X< & CO SAL 000004253 LAKE CHARLES API SEPARATOR RELEASE LAKE CHARLES REFINERY, 1990 SARA SECTION 313 REPORT LIST OF TRAPS: Lake Charles API Trap Lake Charles CPI Trap Emission Type Covered open Emission factor (est.) Lbs/1000 gal WasteWater 0.03 0.93 Trap flowrate GPM 780 780 Total: Annual Release Tons/yr 6 191 197 Individual Component Release: Benzene Cumene Cyclohexane Ethylbenzene Naphthalene Toluene Pseudo-cumene Xylene Total Release 197 197 197 197 197 197 197 197 Component Part. Pressure 1.5 0.062 1.6 0.18 0.0045 0.4 0.039 0.19 Oil wt frac. 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 Release Estimation Lbs/Yr 243 5 926 35 0 213 3 132 NOTE: Measured Partial pressure of crude oil Is 3.4 psia. SIMS ESTIMATED AIR EMISSIONS STUDY DESCRIPTION Title: Lake Charles Wastewater System Feed flow rate: 4*92e--002 m3/s Location: Industrial Study definition file: C:\SIHS\DATA\LAKEUPDA.SDF INDUSTRIAL CATEGORIES GENERATING FEED TO SYSTEM Code 3 IndustrialCategory COAL, OIL, PETROLEUM PRODS, & REFINING DEVICE NUMBER 1 Description Name: Primary DAF Type: Diffused Air SI, No Biodegradation Flow znodei: FIow-through Physical Dimensions Surface area: Liquid depth: 4.00e+001 m2 2.46e+000 a Operational Parameters Retention time Temperature Wind speed Air flow rate 5.56e-001 hr 2 .S0e+001 deg C 4.47e+000 m/s 1.44e-Q03 m3/s AIR EMISSION SUMMARY Inlet Cone* (lb/ft3) Mass Loading (lb/yr) Effluent Cone. (Ib/ft3) Biodeg. Removal (lb/yr) Air Emissions (lb/yr) SAL 000004255 BENZENE CUMENE (ISOPROPYLBENZENE) CYCLOHEXANE ETHYLBENZENE NAPHTHALENE 1.06e-003 5.81e+004 1.0Se-003 0.OOe+OOO 6.89e+002 3,12b--004 1.71e+004 3.056-004 0.006+000 3.72e+002 3.12e--004 1.71b+004 3.06e-004 0.OOe+OOO 3.626+002 8.746-005 4.786+003 8.63a-005 0.006+000 5.976+001 3.126-004 1.716+004 3.10e-004 0.006+000 1.056+002 TOLUENE XYLENE(-M) 6.87e-004 3.766+004 6.78e-004 0.OOe+OOO 4.87&+002 4.066-004 2.226+004 4.01e-004 0.OOe+OOO 2.456+002 Total VOC 3.186-003 1.746+005 3.146-003 0.OOe+OOO 2.326+003 DEVICE NUMBER 2 Description Name: Equalization Pond Type: Mechanically Aerated SI, No Biodegradation Flow model: FIov--through Physical -Dimensions Surface area: Liquid depth: 1.00e+003 m2 3,05e+000 m Operational Parameters Retention time: Temperature: Wind speed: Total power to aerators: Number of aerators: Turbulent surface area: Impeller speed: Impeller diameter: Impeller power efficiency: 02 transfer rating of aerator: 02 transfer correction factor: 1.726+001 hr 2.50e+001 deg C 4.476+000 m/s S.62e+002 hp 7.00e+000 2.406+001 % 1.26e+002 rad/s 6.10e+001 cm 8.506+001 % 5.00e-003 lb 02/hp-hr 8.306+001 % AIR EMISSION SUMMARY Pollutant BENZENE CUMENE (ISOPROPYLBENZENE) CYCLOHEXANE Inlet Cone. (Ib/ft3) Mass Loading (Ib/yr) Effluent Cone. (Ib/ft3) Biodeg. Removal (Ib/yr) Air Emissions (Ib/yr) 1.05e-003 3.05e-004 3.06e-004 5.746+004 1.67e+004 1.67e+004 6.68e-004 2.05e-004 1.976-004 0.00e+000 0.00e+000 0.00e+000 2.09e+004 5.49e+003 5.94e+003 SAL 000004256 ETHYLBENZENE NAPHTHALENE TOLUENE XYLENE(-M) DEVICE NUMBER 3 8.63e-005 4.72e+003 S.71e-005 O.OOe+OOO J.60e+003 3.10e-004 1.70e+004 2.08e-004 O.OOe+OOO 5.61e+003 6.78e-004 3.719+004 4.41e-004 O.OOe+OOO 1,29e+004 4.Ole--004 2.20e+004 2.66e-004 O.OOe+OOO 7.42e+003 Total VOC 3.14e-003 1.72e+005 2.040-003 O.OOe+OOO 5.99e+004 Description Name: Type: Flov model: Lake Charles Bio-Pond Mechanically Aerated SI, Flow-through Activated Sludge Physical Dimensions Surface area; 1.60e+003 m2 Liquid depth: 2,44e+000 n Operational Parameters Retention time: Temperature: Wind speed: Biomass concentration: Total power to aerators: Number of aerators: Turbulent surface area: Impeller speed: Xaipeller dlaneter; Impeller power efficiency: 02 transfer rating of aerator: 02 transfer correction factor: 2.21e+001 hr 2.50e+001 deg C 4.47e+000 m/s 1.00e+003 g/m3 3.000+002 hp 7.000+000 7.000+001 % 1.260+002 rad/s 3.500+001 cm 8.500+001 % S.00e-002 lb 02/hp-hr 8.30e+001 % AIR EMISSION SUMMARY BENZENE CUMENE (ISOPROPYLBENZENE) CYCLOHEXANE ETHYLBENZENE NAPHTHALENE Inlet Cone. (Ib/ft3) Mass Loading (Ib/yr) Effluent Cone. (Ib/ft3) Biodeg. Removal (Ib/yr) Air Emissions (Ib/yr) 6.68e-004 3.66e+004 1.98e-005 3.27e+004 2. 74e+003 2.0Se-004 1.12e+004 4.61e-006 1.04e+004 5.45e+002 1.97e-004 1.08e+004 7.77e-006 9.32e+003 1.04e+003 5.710-005 3.I3e+003 1.16e-006 2.92e+003 1.430+002 2.08e-004 1.140+004 8.26e-006 9.94e+003 9.82e+002 SAL 000004-257 TOLUENE XYLENE(-M) DEVICE NUMBER 4 4.41e-004 2.426*004 7.87e-006 2.27e+004 1.02**003 2.66e-004 1.45e*004 5.12e-006 1.36**004 6.32e*002 Total VOC 2.046-003 1.12**005 5.46e-005 1.02e*005 7.11e*003 Description Name: Clarifier Type: Non-Aerated SI, No Biodegradation Flow model: Flow-through Physical Dimensions Surface area: Liquid depth: 5.00e+001 m2 2.46e*000 m Operational Parameters Retention time Temperature Wind speed 6.95e-001 hr 2.50e*001 deg C 4.47e*000 m/s AIR EMISSION SUMMARY Pollutant Inlet Cone. (Ib/ft3) Mass Loading (Ih/yr) Effluent Cone. (Ib/ft3) Biodeg. Removal (Ib/yr) Air Emissions (Ib/yr) BENZENE CUMENE (ISOPROPYLBENZENE) CYCLOHEXANE ETHYLBENZENE NAPHTHALENE 1.98e-005 1.08e+003 1.97e-005 0.00e*000 7.27e+000 4.61e-006 2.52e+002 4.58e-006 0,00e*000 1.48**000 7.77e-006 4.25**002 7.72e-006 0.00e+000 2.77e+000 1.16e-006 6.34e*001 1.15e--006 0.00e+000 3.87e-001 8.26e-006 4.52**002 8.21e-006 0.00e+000 2.67e+000 TOLUENE XYLENE(-M) 7.87e-006 4.3le*002 7.82e-006 0.00e+000 2.74e*000 5.12e--006 2.80e*002 5.08e-006 0.00e+000 1.71e+000 Total VOC 5.46e-005 2.99e*003 5.42e-005 0.00e+000 1.90e*001 DEVICE NUMBER 5 SAL 00000425Q Description Name: Process Lagoon Type: Mechanically Aerated SI, No Biodegradation Flow model: Flow-through Physical Dimensions Surface area: Liquid depth: 3.00e+002 m2 2.46e+000 m Operational Parameters Retention time: Temperature: Wind speed: Total power to aerators: Number of aerators: Turbulent surface area: Impeller speed: Impeller diameter: Impeller power efficiency: transfer rating of aerator: transfer correction factor: 4.17e+000 hr 2.506+001 deg C 4.47e+000 m/s 1.000+001 hp 2.00e+000 2.40e+001 % 1.26e+002 rad/a 6.10e+001 cm 8.506+001 % 3.00e+000 lb 02/hp-hr 8.300+001 \ AIR EMISSION SUMMARY Pollutant Inlet Cone. (Ib/ft3) Mass Loading (Ib/yr) Effluent Cone. (Ib/ft3) Biodeg. Removal (Ib/yr) Air Emissions (Ib/yr) BENZENE CUMENE (ISOPROPYLBENZENE) CYCLOHEXANE ETHYLBENZENE NAPHTHALENE 1.97e-005 1.0Be+003 4.30e-006 0.00e+000 8.42e+002 4.58e-006 2.51e+002 9.70e--007 0.00e+000 1.98e+002 7.72e-006 4.23e+002 1.49e--006 0.00e+000 3.41e+002 1.lSe-006 6.30e+001 2.64e-007 0.00e+000 4.86e+001 8.21e-006 4.49e+002 3.33e-006 0.00e+000 2.67e+002 TOLUENE XYLENE(-M) 7.82e-006 4.28e+002 1.70e-006 0.00e+000 3.356+002 S.0Se-006 2.78e+QQ2 1,23e-006 0.00e+000 2.lle+002 Total VOC 5.42e-005 2.97e+003 1.33e-005 0.00e+000 2.24e+003 DEVICE NUMBER 6 Description Name: Final DAF SAL 000004259 Type: Diffused Air SI, No Biodegradation Flow model: Flow-through Physical Dimensions Surface area: Liquid depth; 5.OOe+OOl m2 2.OOe+OOO m Operational Parameters Retention time Temperature Wind speed Air flow rate 5.65e-001 hr 2.50e+001 deg C 4,47e+000 m/s 2.41e-003 m3fs AIR EMISSION SUMMARY inlet Cone. (Ih/ft3) Mass Loading (Ib/yr) Effluent Cone. (lb/ft3) Biodeg. Removal (lb/yr) Air Emissions (lb/yr) BENZENE CUMENE (ISOPROPYLBENZENE) CYCLOHEXANE ETHYLBENZENE NAPHTHALENE 4.30e-006 2.35e+002 4.22e-006 0.OOe+OOO 4.10e+000 9.70e-007 5.31e+001 9.37e--007 0.OOe+OOO 1.80e+000 1.49e-006 8.16e+001 1.44e-006 0.OOe+OOO 2.68e+000 2.64e-007 1.44e+001 2.59e-007 0.OOe+OOO 2.70e-001 3,33e-006 1.82e+002 3.30e-006 0.OOe+OOO 1,50e+000 TOLUENE XYLENE(-M) 1.70e-006 9.33e+001 1.67e-006 0.OOe+OOO 1.81e+000 1.23e-006 6.72e+001 1.21e-006 0.OOe+OOO 1.09e+000 Total VOC 1.33e-005 7.27e+002 1.30e-005 0.OOe+OOO 1.33e+001 SYSTEM AIR EMISSION SUMMARY Pollutant BENZENE CUMENE (ISOPROPYLBENZENE) CYCLOHEXANE ETHYLBENZENE NAPHTHALENE TOLUENE XYLENE(-M) Inlet Cone. (Ib/ft3) Mass Loading (lb/yr) Effluent Cone. (Ib/ft3) Biodeg. Removal (lb/yr) Air missions (lb/yr) 1.06e-003 5.81e+004 4.22e-006 3.27e+004 2.51e+004 3.12e-004 1.71e+004 9.37e-007 1.04e+004 6.61e+003 3.12e-004 1.71e+004 1.44e-006 9.32e+003 7.69e+003 8.74e-005 4.78e+003 2.59e-007 2.92e+003 1.85e+003 3.12e-004 1.71e+004 3.30e-006 9.94e+003 6.97e+003 6.87e-004 3.76e+004 1.67e-006 2.27e+004 1.48e+004 4 .060-004 2.22e+004 1.21e-006 1.36e+004 8.51e+003 SAL 000004260 Total VOC 3.18e-003 174e+005 1.306-005 1,02e+005 7.16&+004 SAL 000004261 c oMftjf 5 SAL 000004263 Wi VlX.'b Gulf South Environmental Laboratory formerly GSRJ February 28, 1989 Ms. Leslie Ziegman Remediation Technologies 23 Old Town Square, Suite 250 Fort Collins, CO 80524 Subject; Project No. 6200-3600, Episode EXT Dear Ziegman: Enclosed please find the analytical results for the Wastewater Test samples delivered to the Gulf South Environmental Laboratory on February 4, 1989. A brief discussion of the analytical methodologies employed is presented, as well as a summary of quality control data generated as part of the analyses. If you have any questions regarding any aspect of these results, please feel free to call us at any time. Sincerely, RRW/cp Enclosure Richard R. Whitney, Ph.D. Senior Research Chemist SAL 000004264 Post Office Box 26518 New Orleans, Louisiana 70186 Phone (504)283-^223 Fax (504)288-3625 Analytical Methodology Remediation Technologies Wastewater Test samples received on February 4, 1989 were analyzed for volatile organics, semivolatile organics, metals, cyanide and sulfide. Specific methods employed for the analyses are indicated. --Volatile Organics - Appendix IX of 40 CFR Part 264, EPA Method 8240, SW-846 --Semivolatile Organics - Appendix IX of 40 CFR Part 264, EPA Method 8270, SW-846 --Metals - Appendix IX of 40 CFR Part 264, EPA Method SW-846 series --Conventional Parameters -Appendix IX of 40 CFR Part 264 --Cyanide - EPA Method 9010, SW-846 --Sulfide - EPA Method 9030, SW-846 Quality Assurance/Quality Control Quality assurance/quality control (QA/QC) measures are employed to Insure the quality and define the accuracy of analytical data. The QA/QC measures employed with these analyses are summarized below: Organics Analyses (Volatile and Semivolatile) Instrument calibration - Instrument calibration is performed in accordance with EPA contract laboratory protocols. Instrument recalibration is performed every 12 hours. Blank analysis - Method blanks are analyzed every 12 hours for volatile analyses and with every extraction batch for semivolatiles. Method blanks demonstrate the level of background (laboratory) contamination. Blank data are presented in the QA/QC Summary. Surrogate spike analysis - Each sample is fortified with recovery (surrogate) standards prior to or purging. The recovery of the surrogate standards is a measure of the efficiency of the analysis. A summary of surrogate recovery data is presented in the QA/QC Summary. Matrix spike/duplicate spike - Specific analytes are added to selected samples prior to the extraction or purging. The results of the matrix spike/duplicate spike analyses are a measure of the precision and accuracy of the analysis. Matrix spike data are included in the QA/QC Summary. Metals Analysis Instrument calibration - Instrument calibration is performed in accordance with EPA contract laboratory protocols. Calibration verification is conducted every two hours or every ten samples, whichever is more frequent. Blank analysis - A method blank is prepared with each batch of samples digested. The method blank defines the level of background (laboratory) contamination. (Results are presented as ug/L in the digestate.) Duplicate analysis - Selected samples are prepared and analyzed in duplicate to define the precision of the results. Matrix spike analysis - Each of the metals of interest are added to selected samples prior to sample preparation. The results of spike analyses define the accuracy of the results. Blank, duplicate and matrix spike results for metals analyses are summarized in the QA/QC Summary. SAL 000004265 Conventional Parameters Calibration - Calibration for each of the specific conventional analyses is performed according to the specific method utilized. Replicate analyses ~ QC for the conventional analyses was limited Co replicate analyses to define precision (reproducibility) of the analyses. Check Samples - Known check samples for Che conventional analyses also analyzed to verify calibration and to measure the efficiency of each method. SAL 000004-266 Parameter Sample ID Lab Number ANALYTICAL RESULTS WASTEWATER TEST RESULTS Det'n Limits Units Analvtical Clarifier Effluent BXT-25 Results Outfall BXT-38 ./ HOI / VOLATILE COMPOUNDS Acetone Acetonitrile Acrolein Acrylonitrile Allyl chloride 10 10 10 10 5 Benzene Bromodlchloromethane Bromoform Bromomethane Carbondisulfide 5 5 5 5 5 Carbontetrachloride Chlorobenzene Chloroprene* Chloroe thane Chiorodlbromome thane 5 5 10 10 5 Chloroform 5 Chloromethane 10 1,2-Dibromoethane 5 1,2-Dib romo- 3-chloropropane 5 D ibromome thane 5 trans-l,4-Dichloro-2-butene 5 Dichlorodifluoromethane 10 1,1-Dichloroethane 5 1,2 -Dichloroethane 5 trans-1,2-Dichloroethylene 5 1,1-Dichloroethylene 5 ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L 230 80 ND ND ND 5 / ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 14 29 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND *Pure standard not commercially available; 5-point calibration not run for this compound. SAL 000004267 ANALYTICAL RESULTS WASTEWATER TEST SAMPLE RESULTS Dec'n Parameter________________________ Limits Sample ID Lab Number ___Units_________-----------Analytical Results____________ Clarifier Effluent Outfall BXT-25 BXT-38 VOLATILE COMPOUNDS Dichloromethane 1,2 -Dichloropropane cis-1,3-Dichloropropene trans-1,3-Dichloropropene 1,4-Dioxane 5 5 5 5 250 Ethyl benzene Ethyl cyanide 2-Hexanone lodomethane Isobutyl Alcohol 5 10 10 5 250 Methacrylonitrile Methyl ethyl ketone 4-Methyl-2-pentanone Styrene 1,1,1,2-Tetrachloroethane 10 10 10 5 5 1,1,2, 2-Tetrachloroethane Te trachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane 5 5 5 5 5 Trichloroethene Trichlorofluoromethane 1,2,3-Trlchloropropane Vinyl Acetate Vinyl Chloride Xylene 5 5 5 10 10 5 ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ND ND ND ND ND ND v'' ND ND ND 48 ND ND ND ^ ND</ ND ND ND 5^ ND ND ND ND ND ND /- ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 00 00 ANALYTICAL RESULTS wastewater test results Det'n Parameter_____________________________Limits Sample ID Lab Number _____Units_______----------Analytical Results Clarifier Effluent Outfall BXT-32 -BXT-44 SEMIVOLATILE COMPOUNDS Acenaphthene Ac e naphtha1ene Acetophenone 2 -Acetylaminofluorene 4-Aminobipheny1 10 10 10 10 10 Aniline Anthracene Aramite Benz(a)anthracene Benzo(ghi)perylene 10 10 10 10 10 Benzo(k)fluoranthene Benzyl alcohol Benz o(b)fluoranthene Benz o(a)pyrene Bis(2-Chloroethoxy)methane 10 10 10 10 10 Bis(2-Chloroethyl)ether Bis(2-Chloroisopropyl)ether Bis(2-ethylhexyl)phthalate 4-Bromophenyl phenyl ether Butyl benzyl phthalate 10 10 10 10 10 2-sec-Butyl-4,6-dinitrophenol p-Chloroaniline p-Chloro-m-cresol 2-Chloronaphthalene 2-Chlorophenol 20 10 10 10 10 4-Chlorophenyl phenyl ether Chrysene m-Cresol o-Cresol p-Cresol 10 10 10 10 10 ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L 42 ND ND ND ND ND 27 ND 17 ND ND ND 6 7 ND ND ND ND ND ND ND ND ND ND ND ND 31 ND ND ND ND ND ND ND 5 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND SAL 000004269 ANALYTICAL RESULTS WASTEWATER TEST RESULTS Parameter Sample ID Lab Number Det'n Limits ______Units Analytical Clarifier Effluent BXT-32 Results Outfall -3XT-44 SEMIVOLATILE COMPOUNDS Dibenz(a,h)anthracene Dibenzofuran Di-n-butyl phthalate o-Dichlorobenzene m-Dichlorobenzene p-Dichlorobenzene 3,3'-Dichlorobenzidine 2,4-Dichlorophenol 2,6-Dichlorophenol Diethyl phthalate p-Dimethylaminoazobenzene 7,12-Dimethylbenz(a) anthracene 3,3'Dimethyl benzidine alpha,alpha *Dime thy1- phene thy1 amine 2,4-Dimethylphenol Dimethyl phthalate m-Dinitrobenzene 4,6-Dinitro-o-cresol 2,4-Dinitrophenol 2,4-Dinitrotoluene 2,6-Dinitrotoluene Di-n-octyl phthalate Dipheny1amine Ethyl methacrylate Ethyl methane sulfonate Fluoranthene Fluorene Hexachlorobenzene Hexachlorobutadiene Hexachlorocyclopentadiene 10 10 10 10 10 10 20 10 10 10 10 10 20 10 10 10 10 20 20 10 10 10 10 20 10 10 10 10 10 10 ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ND ND ND ND ND ND ND ND ND ND ND ND ND ND 40 ND ND ND ND ND ND ND ND ND ND 24 32 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND SAL 000004270 ANALYTICAL RESULTS WASTEWATER TEST RESULTS Det'n garwactgg_____________________________Limits Sample ID Lab Number _____HnLts ... -- - Analytical Results Clarifier Effluent Outfall BXT-44 SEMIVOLATILE COMPOUNDS Hexachloroethane Hexachlorophene* Hexachloropropene lndeno(l,2,3-cd)pyrene Isophorone Isosafrole Methapyrilene 3-Methylcholanthrene Methyl methacrylate Methyl methanesulfonate 2 - Me thylnaphthalene Naphthalene 1,4-Naphthoquinone 1-Naphthylamine 2*Naphthylaaine o-Nitroaniline m-Nitroaniline p-Nitroaniline Nitrobenzene o-Nitrophenol p-Nitropheno1 4-Nltroquinoline 1-oxide N-Nitrosodi* n-butylaalne N-Nitrosodlethylamine N-Nitrosomethylethylamine N-Nitrosodlphenylamine N-Nitrosodimethylamine N-Nltrosodlpropylamine N-Nitrosomorpholine N-Nitrosopiperidine 10 10 10 10 10 10 10 10 20 10 10 10 10 10 50 50 50 10 10 50 20 10 20 20 10 50 10 10 10 US/L ug/L ug/L ug/L Ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 5 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND *Not recovered in spiking recovery studies. ooooo^11 Parameter Sample ID Lab Number ANALYTICAL RESULTS WASTEWATER TEST RESULTS Det'n _______________Limits _ ______Unit?_______ Analytical Results Clarifier Effluent Outfall BXT.-32 RXT-44 SEMIVOLATILE COMPOUNDS N-Nitrosopyrrolidine 5 -Nitro-o-toluidine Pentachlorobenzene Pentachloroethane Pentachloronitrobenzene Pentachloropheno1 Phenacetin Phenanthrene Phenol p-Phenylenediamine 2-Picoline Pronamide Pyrene Pyridine Safrole 1,2,4,5-Tetrachlorobenzene 2,3,4,6-Tetrachlorophenol o-Toluidine 1,2,4-Trichlorobenzene 2,4,5-Trichlorophenol 2,4,6-Trichlorophenol Sym-Trinitrobenzene 10 10 10 10 20 50 10 10 10 50 10 10 10 20 10 10 10 10 10 10 10 20 ug/L ug/L ug/L ug/L Ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ND ND ND ND ND ND ND 77 ND ND 16 ND 97 ND ND ND ND 23 ND ND ND ND ND ND ND ND ND ND ND ND 9 ND 9 ND 6 ND ND ND ND ND ND ND ND ND o0000^1Z SAX Parameter Sample ID Lab Number METALS Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Mercury Nickel Selenium Silver Thallium Tin Vanadium Zinc PARAMETER Cyanide Sulfide ANALYTICAL RESULTS WASTEWATER TEST RESULTS Det'n Limits Units Analytical Results Clarifier Effluent Outfall VSL-AbJmL. BXT.46.47 & 48 300 10 20 3 40 70 70 60 10 2 50 20 70 10 8000 80 20 40 10000 ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ND 12.8 57.6 ND ND ND ND ND ND ND ND 353 ND ND ND ND 70.2 ug/L ug/L 80 ND ND ND 116 ND ND ND ND ND ND ND ND 102 ND ND ND ND 168 96 ND C&A/W-f SfWJOCS SAL 000004273