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MFEoDnS-2:3-F1C3-8131)G FLUORAD Brand Flucrochemical Surfactant "3M 3. FIRE AND EXFLOSION HAZARD DATA teens inued) EXTVaItNeGrU,ISFHoIaNmG, MECDOZI,A:Dry Chemical SPNECoIeALKFrIoRnE FIGHTING PROCEDURES: UNHUeSsUAtLofFIRfEireANDmayEXPrLeOlSeIaOsNe MaAwZsAcRrDiSs: and HE. 5. REACTIVITY DATA SITNACROIMLPIATTYA:RILSItTaYble- MATERIALS TO AVOID: HAnZaARDOUS POLYMERIZATION: Will Mot Docur HAZTAhRevDsOaUlS dDeEcCoOmMpPoOSsIiTtIiOoNn mFaRyODpUrCoTdSuce tewic materials including HE. . ENVIRONMENTAL INFORMATION SPmIOLobLtseerrRivEaeSlF.OpNrSCeEocSlaluetcitonsmpiflrloemdotmahteerrisaelc.tioPnlsa.ceCoivneranwiatphproavbesdormbeetnatl RECCoOnMtEaNiDneErD, DaInSdFOsSeAa>Ll. wDiassctheamrogteerstpernetatuseonltutimoynstsewa.ndIsnwcailmleraprteedubcutlkqupernotdiutcitesi,n a(n5 ginadlu,strtioela FCeFscuoimemteirocnisalvarfya,cilciotnya.ultCoampbpulsitciaobnleprroedguucltastwiiolnls oinncaluudtehoHrEi.tieSsincbeefore ENVdiIsRpOoNsMaElN.TALU.BD.ATAESPA Hazardcus Haste Ne. Nome gDaitga)f;orSOp-rDodauyctBioscchleimdiecsalCheGwniycgaeln DOerwyagnedn D(eEwOaDnECd))(CNOiDl)j: SNi6l-Hr{.70L8CSG, MFilurewgrimil(lFiSmuenpfhioslhes IpLrecpmeewliass)msacr7e6c6himrausi):AS66--3rmgEsCLSyQ, HDrap.hnisLCDmSa,gneF:ath6e3a%d Cwoaiplrsicto4r-nDuatyomEC7S3 miecsabl.l dry weight), Green Algae (Selenastrum 5. SUGGESTED FIRST AID eveImcmoendtiaacttesly flush with plenty of water. Continue for 10 minutes. Call SKIaNpChOyNsTiAciCaTn:. INWHaALsAhTIaOfNfSected ares with soap ard water. c17alslysmptpohymssiccioaonu.r, remove peracr to fresh air. If symptoms continue, GEDSOTINOOTNSINDUCE VOMITING. Give copious amounts of water. IMMEDIATELY aTicaelRlFIaRSpThyAsIiDc:ian or Felson Control Center. ae Bnbreviaticonz: N/D - Net Determined N/A - Not Applicable EExxhhiibbiitt 11335566 State of Minnesota v. 3M Co., Court File No. 27-CV-10-28862 11335566..00000011 33MM4A0000220022550000 MFSeDnS-:e3-F1O9-16198 FLUDRAD Erand Flucrochemical Surfactant &. SUGGESTED FIRST AID = 7. PRECAUTIONARY INFORMATION Gberneeartehlingnaoffe vparpaocrtsi,cefrumeeqsu,irweissttsh,atocrondtuasctts wsihtohuldthebeokaivoni/deeyde.s aWnhder nroetloinmgeudm/e,reptehaetceodntbarienaetrhisnhgooufldcobneceknetptratteidghtvlapyorcsl.oseUds,e oAvnoliydin areas pFertflcuicernotstlyiylvenctairlbaotxeydlatteo pwraesvefnetd vtoapoarlbibunioldruapt.s Comper induced coreinagenicity wes found in the fNoOrTEZ: yeFaarmso,riunse study; statistically cTuironrienitcahnrtcwlceodmgpeo,andtherelFaitneddingbsenhiganvetemsothiucmuleanrhetauwlotrhs.imSpalsiceadtioonns. SPEEVCIEALPROPTREOCTTEICOTNI:ONSSafety Goggles SKIN PROTECTION: Rubber gloves, protective clothing. VREENSTPIILRAATTIOORNY: FLRoOcTaElCTIeOxNh:ausPtirvesrutppilliaetdicnresipairreactoormewnhdeerde. local exhaust ventilation is net aveilsble. ADDITIONAL EXPOSURE LTIMmITSEXPOSURE LIMITS ===) GREDIENTS VALUEF- XUFtNrI~TuR~ LITY~RIET~ AUTH ..... umes um Perflucrcalkyl Carbowylate @.1 ma/m3 THA 3M SZOAUCR0C1EH:OFAmEeXrPiOcSUaRnECoLnIfNeITrenDAcTeA:of Governmental Industrial Mygienists ~~ HSOmsNE:3%NEonrpeesEusrteablGiusihdeedlines a. HEALTH WAZARD DATA CcVaErbCoOxNyTlAaCtTe:cNaen tbeexiicrirtiytadtaitneg ftoortFhOe-1e1y6e. afndummoanyiumcaupserefleuyceroianljkuyrly from aSiHrIbNoCrOmNeTAeCxTp)osuNree.tonicity date for FO-118. Ammonium perflucroaikyl creanr-bsarrryiltaatteinige t2o1igtnhtelyshitno.xic when abiorbed through the sking it ie CIaNrHbAoLrATyIlOaNt:e Nmea:ytcooniucsietyrezdpaiteratfeorryFCS-y1s1t8e.w Aimrmrointiautmionperffrloumcrionahlaklyaltion) C2anmedbieanconlseithdaelredcommcoednetrraatteilcymtofnoricobys-hionuhraleaxtpioosnuorne 8instihnegleelbeixpnocsurraet; P1r2o7d3u6c0edmi311iivgernecmhsanpgeerscuabndicemleetveart.edRbelpoeoadtedcrgiarvheafllautciroindeexploesvuerles in FIaNtGeE.STION: No tonicity data for FO-118. Ammonium Carbeylate in conpidered mederetely tonic from pmeirfnlgulcerocoarleklyl ePrrpeocsauurtei;onacsuetcetioornalfoLrDSrOesu(lrtats) ofieS4y0eamra.stupdeyr- hg. of body weight. Ses Pobreviatiome: ND - Not Determined N/A - Not Applicable CThhieniionnfoornmattioontheGnptrhoipzerDawteee Gihneshtandrleipnrgeseofntsthciuerpcruordrucetntudnadtear anrodrmablest CDoavtaestSihcenent. orArmyhACuhmeiorfveltvheesprUosdiuncgttwhheicphrodiusctnotinicnomcobnifnoartmiaonncewitwhithantyhie Ciher product ar any ciher process in the responsibility of the user. 11335566..00000022 33M40A000220022550011 Product Information ( Fluorad FC-118 Sel (eleslSlas lorsIBST drole81: || i . ; 1356.0003 3MA00202502 FFlluuoorraadd"" FFlluuoorroocchheemmiiccaall SSuurrffaaccttaanntt FFCC--111188 IInnttrroodduuccttiioonn FaFinluuoaonrraiaoddniFFclluufoolrruoooccrhhoeecmmhieicncaialclaSSluursruffraafccattcaatnantntt.FFCCH--i11g11h88tliiyss faalnnuoaariqqnuuaeetooeduussmisscooellluultteiiosonncaoofnf aabmmemmfooonrnimiueumdmpipneerarqflluuuoeororoouooscctstaaynnsootaaettmee,s, a-~`mnaaonappornrmooioeppnreesricr.ttyyflutthohaartot chhhaaessmlleiecddattloosueexrxfttaeecnntssaiinvvtee. uuHssigeehootflfyFFfClCu--o11r11in88atiinendtthhmee ieecemmulluellsssiiocoannnppobolelyymmfoeerrmriizzeaadttiioionnnaooqffuffelluouoourrsiinnsaayttesedtdems monomers. FTToyyprpimiccaall PPrrooppeerrttiieess ((NNoott ffoorr SSppeecicfifiiccaattiioonn PPuurrppoosseess)) Light colored liauid COMPOSNON 11-111... 111 L L . . o oorrrrroiivossiooniooreroero.. Form ..................................................................... Composition ............................................................ 20% Light 20% acQqoUuloEerOoeUudSslSisqooulluiudttiioonn SpSepceicfiificc GGrraavivtityy 1... .......................................................... 11 .1! s8 SSuurrffaaccee TTeennssiioonn AaAllntthhobouuegglhhimFFiCCt-e-d1111in88 iiisnsossroogllauunbbillceesiiynnsccteeermrttsaa,iinnbppuoolltaahrreoroerrggiaasnngiieccnessrooallvlveleynnttsssufssfuuicccihhenaatsssoeelttuhhbaainlnoiotlly aatnnoddenaaaccbeeltteoonnFeeC,,-ss1oo1llu8ubbitlioliittyy cssiaiggnnniibffiieccaalninmttlliyyterrdeeddinuuccineeossrugurarffnaaiccceesttyeesnntsesiimoonns.,. bFFuCCt--11th11e88reiissisnnoogtteaanccettriivavelelyiinnsu11f0f0i0c0i%e%nootrrsggoaalnuniibccilisstyyysstttoeemmesns.a. ble FC-118 to SoSlovlveenntt DDHiyissdtrtiiolllecehddloWWraiatcteerArcid, 18.5% HHNHiyyytdrddrirrocoocAcchchhliolldoor,rriiiccc1A0AAccc%iiiddd,,, 331778%9.56%. NNNNiiiittttrrrriiiicccc AAAAcccciiiidddd,,,74410000%%%% SNSSuuuilltlrfffiuuucrrriiAiccccAAAidccciii7ddd0,,,%511000%%% SSSPuouultllfffauuusrrrisiiccciuAAAmccciiiHdddy,,,d599r50o5%%x%ide, 10% PPPoootttaaassssssiiiuuummm HHHyyydddrrroooxxxiiidddeee,,, 331000%%% GGrraammss 00.00 777222 7[76427 6667818 5777636 b758i68d 877 83 SSuurrffaaccee(dTTyeennnesssii/oocnnm)aatt 2255CC ooff FFCC--11(11d88y//n11e00s00/cGGmrra)ammss ooff SSoollvveenntt 00.000055 00.0055 0 53 "00.55 5665909 55559113 34220646* 665556 45330119 23119290* 5-55446 2a44707 2222525* 57477282 56265999 222225** 325473 252953 18232200* 22 19 18" * Not all dissolv~ 11335566..00000044 33MMAA0000220022550033 SSttoorraaggee tFFeCCm--p11e11r88atssuhhrooeuulalddndbbeethssettoosrroeelddutaaittonoorrstnnieeraraerrd rruonootoimml attelemmspopeleriardatsutuarrreee.. rFFerrcooizzseseonnlvcceoodnn.ttaaiinneerrss sshhoouulldd bbee wwaarrmmeedd ttoo rroooomm temperature and the solution stirred until all solids are redissolved. PPrroodduucctt SSaaffeettyy aaPPvlvlaeeaiaaillssaaeebbllerreeefttfheehrrrroottuhuhgegehhMMayyatooetuuerrririaallloolccSSaaalalffsseeaattllyyeessDDaarrteetaapprrSSeeshsheeeenentetattataaitivnnvededss.pp.rroodduucctt llaabbeell.. MMaateteririaall SSaaffeettyy DDaattaa SShheeeettss aarree < | | | ( Passso npn osconbckpag. Please see important notice on back page. 11335566..00000055 33MM4A0000220022550044 ' 33MM CCoorrppoorraattee HHeeaaddqquuaarrtteerrss st. 3MSt. pPCaeaunultl er Bldg. 223.6504 6663SSt111Mt..222/1PP/C7a77au3e33ul3n33l,,te111MMr776NN118B003ld55(((g85OPO.11rrr442odd24d2ee-u-r3r1c1ii-n0t6n0g0gS0I00-nPP0frr4ooorddmuuactctitoaannn)dd PPrriicciinngg)) 661122//773333 51663843 ((PTerochdnuicctalInAfossrmisattaionnce)) 612/733 5634 (Technical Assistance) RReepprreesseennttaattiivvee LLooccaattiioonnss A2At6tla6an0nttBaaankers Industri Drive A``2As8ttla6aal0nnsttaaaB,,?aGGn7k0AAe9r335s0033In56d00u--2s2t77r66ia44l Drive 884800000004////242246441117 3337666077690609 (((IIOnnusstiidsdieedeGGAAG)A) ) B8o0s0t/2o4n1 3669 (Outside GA) 8N8Be55owsWWtteooenlnl,lss MAAvAveenn0uu2ee1959114 617/558 Newton, 617/558 7354 MA 02195-9114 7354 800/634 880000//885511 800/634 0023 11551155 0023 (Outside MA) ((IInnssiiddee MMAA)) (Outside MA) CC90hh6iiccNaaoggrooth Em Street 9H6Hi10inn28ss7ddN7aa3oll3eret,,h17IILEL1l066m0055S22t11reet 800/942 612/733 800/942 39611710 3961 2DD1aal2ll1laassSanta Ara Avene 22DDa11al42lll1/aa3ssS,2, 4aTTn6XXt1a777A55222n22n88a.-11A66v66e77nue 882800010004//1/344524424227 8881001644746268 (((IiOnnusstiidsdieedeTTXXT))X) L8o00n/d5o2n7, Ontario 1648 (Outside TX) PLLPooOOnndBBdoooonxxn,,55OO77n55tn7a7t,r,airTToieoerNrmmGiiAnnaal4lTAA1 5190451 London, 519/451 2500 Ontario 2500 N6A 4T1 oWIfIwomeapbfmboaewlrlatieeaprvvnaoetnNfotNtoooeots5btir,ieccreerxoettodtliooaraPbbeaPullseur,s,crenchbudhautosat1testhrheIe:rn:aAagAcfclcftceusus,rttraaaaItctcneyyemcomuoeerirnnncctssgoo,mmttshpepcoctlehhoItnnemniinpeccelaasslolssditnowtfhhoamrermrereaaoontfinoi5ssnanooanontfdtgdmgrurueaeacercroaaomnnmrtmemeeecdnn,ddaahaanttinadorannsthshenehffefrioorstnlellooiennwwasaiairnnrceggrbbfpbissaualmsrmsepaaadeoddsoeeoneninnftfeoliseietuss B`WoSBoSfheeooaflalloelrtrlrresw''souauaasersnrinivannddneggIm,t,mriuaeusansCse,onuenrufernsfaxaeshpccchratttaeuiulfsrtordesdneeere''tsdtteehooorrmrnrnmleiyyiimnwnoeop.bblhiteghliogdeNaa,SlEstiiaounToicbnnHtaliuEssbdthhiRliayiantyfSlgtobEboftLhoefteLtthteEoofemRporpreppNrpolloiOeldaadduRccucoewcMtasfuAfruoorcNcarrhUhniitqFtsqieuAuistanCaotnonTenftnUidmtdyReoeeEocfdruRfctushthSsohaee,Hn,ApptaaarrLbononLisdddliuutGyuuccEstsateeLppnrrIrrdaoaAosfsvBvitsseeLnuuddEermTsteEoosesIsbbfaToaeaHriGlElpdarrReuilissfreekIpkccNaotatsvinvTneeedOd.:.lRliaTabbOiliRityy UIIwNSNhECCatOOOsNoFNeTTOvRReRAArTCCinTHTcEFFoOOnInRRNeAAAcBtNNIioLYYnITLLtYhOOTeSSrOeSSUwOOiStFRhE. DDTNAAHEMMEITAAHPGGEREER,O, DSDDUEIIRCLRELETCECNTRT,oNIINsNOtCGRaIItDDMeEEmNANeTNTnAAtULLF_o,AOOCoRRTcUoCCmROOmENeNRnSSdESEeQHQtUAUiELoENLnNTTBnIIEtAAcLLL,aIAnAABRtRLIaISESIINENGIGTOeHOUErURTnTOIsONFhFTaOTTHHRaEET.vOeR anyfrcoorafctunless i a agreement signed afc ofsel andmanacturr USE OF OR THE INABILITY TO USE THE PRODUCT. No statement or recommendation not any force or effect unless in an agreement signed by officers of seller and manufacturer. contained herein shaft have 98-0211-4581-2(59.2)R1 XY 3M Industral Chemica! Products Divison 3M Industrial Chemical Products Divison a Contr Bid 2236501 3M Center Bldg. 223-6S-04 Senn sitio St. Paul, MN 55144-1000 3M 1989 Issued: 5189 "Litho in USA with 3M offset plates, film and proofing systems." 11335566..00000066 3aMMAA0000220022550055