Document 2Rey291NDopnmnkxZG0gazBnb

PAGE 1 MATERIAL SAFETY DATA SHEET CIBA-GEIGY CORPORATION ADDITIVES DIVISION SEVEN SKYLINE DRIVE HAWTHORNE, NEW YORK 10532 (91A) 785-2000 EMERGENCY PHONE NUMBER< (800) 888-8372 SECTION I-IDENTITY INFORMATION IDENTITY (TRADENAME). IRGANOX 1520 IS FAMILY/CHEMICAL NAME. 2-METHYL-4,6-BIS((0CTYLTHI0)METHYL)PHENOL PRODUCT TYPE. STABILIZER IMPORTANT. XXXXXXXXXXXXXXXXXXXXXXXXXXXXXX X THIS MATERIAL IS NOT INTENDED FOR USE IN PRODUCTS FOR * X WHICH PROLONGED CONTACT WITH MUCOUS MEMBRANES OR ABRAD- X X ED SKIN, OR IMPLANTATION WITHIN THE HUMAN BODY, IS X X SPECIFICALLY INTENDED, UNLESS THE FINISHED PRODUCT HAS * x BEEN TESTED IN ACCORDANCE WITH THE FOOD AND DRUG ADMIN- X X ISTRATION AND/OR OTHER APPLICABLE SAFETY TESTING RE- X X QUIREMENTS. BECAUSE OF THE WIDE RANGE OF SUCH POTEN- X X TIAL USES, CIBA-GEIGY CORPORATION IS NOT ABLE TO RECOM- X X MEND THIS MATERIAL AS SAFE AND EFFECTIVE FOR SUCH USES X X AND ASSUMES NO LIABILITY FOR ANY SUCH USES. X xxxxxxxxxxxxxxxxxxxxxxxxxxxxxx THE ABOVE DISCLAIMER HAS BEEN REVISED. HAZARD STATEMENT . XXXXXXXXXXXXXXXXXXXXXXXXXXXXXX X THIS MATERIAL SAFETY DATA SHEET (MSDS) HAS BEEN X X PREPARED IN COMPLIANCE WITH THE FEDERAL OSHA HAZARD X X COMMUNICATION STANDARD 29 CFR 19X0.1200. X X THIS PRODUCT IS CONSIDERED TO BE A HAZARDOUS X X CHEMICAL UNDER THAT STANDARD. x XXXXXXXXXXXXXXXXXXXXXXXXXXXXXX / SECTION II-HAZARDOUS INGREDIENTS IRGANOX 1520 PAGE 2 SPECIFIC CHEMICAL NAMEt 2-METHYL-4,6-BIS{(OCTYLTHIO)METHYL)PHENOL CAS * 110553-27-0 COMMON NAME) NONE EXPOSURE LIMITSOSHA PEL- NONE ESTABLISHED ACGIH TLV. NONE ESTABLISHED CARCINOGENICITYTHIS CHEMICAL HAS NOT BEEN REVIEWED FOR CARCINOGENICITY BY NTP, IARC, OR OSHA. SECTION III-PHYSICAL DATA APPEARANCE: YELLOWISH OIL. ODORNOT DETERMINED. BOILING POINT>178C AT 0.083 MM HG. MELTING POINT19C. EVAPORATION RATENOT APPLICABLE. PERCENT VOLATILENEGLIGIBLE. VAPOR DENSITY. NOT APPLICABLE. VAPOR PRESSURE LESS THAN OR EQUAL TO 1.5 X 10(-7) AT 25C. SOLUBILITY IN WATER. AT 20C, < 2X 10C-5) G/L SPECIFIC GRAVITY0.98 C H20 = 1J. VISCOSITY87.0 MPA.S AT D = 109 S(-l) SECTION IV-FIRE AND EXPLOSION HAZARD DATA FLASH POINT>392F. FLAMMABLE LIMITS IN AIR-LOWER. NOT DETERMINED. FLAMMABLE LIMITS IN AIR-UPPER. NOT DETERMINED. AUTOIGNITION TEMPERATURE. 626F. NFPA CODE. NONE. EXTINGUISHING MEDIACARBON DIOXIDE, FOAM, DRY CHEMICAL, WATER SPRAY. WATER OR FOAM MAY CAUSE FROTHING. FIRE FIGHTING PROCEDURES-SPECIAL IRGANOX 1520 DO 085159 CONFIDENT TAI PAGE 3 t USE SELF-CONTAINED BREATHING APPARATUS. % UNUSUAL FIRE AND EXPLOSION HAZARDS* DECOMPOSITION AND COMBUSTION PRODUCTS MAY BE TOXIC. SECTION V-REACTIVITY DATA STABILITY* STABLE. INCOMPATIBILITY. STRONG OXIDIZING AGENTS. HAZARDOUS DECOMPOSITION PRODUCTS* THERMAL DECOMPOSITION AND BURNING MAY PRODUCE CARBON MONOX IDE, CARBON DIOXIDE, SULFUR OXIDES AND POSSIBLY OTHER TOXIC SPECIES. HAZARDOUS POLYMERIZATION. WILL NOT OCCUR. __ SECTION VI-HEALTH HAZARD DATA ; PRIMARY ROUTES OF EXPOSURE. DERMAL. ORAL LD50 > (RATS) >5000 MG/KG. DERMAL LD50 * (RATS) >2000 MG/KG. SKIN IRRITATION. (RABBITS) NOT AN IRRITANT. EYE IRRITATION. (RABBITS) NOT AN IRRITANT. SENSITIZATION. (GUINEA PIGS) SKIN SENSITIZATION IN MAXIMIZATION TEST.(7/20 AT FIRST CHALLENGE, 1/20 AT SECOND CHALLENGE) TERATOGENICITY. A TERATOLOGY STUDY WAS PERFORMED WITH RATS WHICH RECEIVED ORAL DOSES OF 0, 50, 150 OR 300 MG/KG/DAY DURING DAYS 6-15 OF GESTATION. WHILE 300 MG/KG WAS SLIGHTLY TOXIC TO THE MOTHERS, THERE WERE NO SIGNIFICANT EFFECTS ON PREGNANCY OR EMBRYO/FETAL DEVELOPMENT. MUTAGENICITY. AMES TEST. NON-MUTAGENIC. MICROMUCLEUS TEST. NON-MUTAGENIC. CHINESE HAMSTER CELLS (V79) NON-MUTAGENIC CHROMOSOME ABERRATION (CHO CELLS IN VITRO). NON-MUTAGENIC SUBCHRONIC ORAL FEEDING STUDIES. DURING A 28-DAY ORAL ADMINISTRATION STUDY WITH RATS, AN APPAR ENT FUNCTIONAL ADAPTATION OF THE LIVER OCCURRED IN ANIMALS RECEIVING 250 AND 1000 MG/KG BODY WEIGHT PER DAY. THE EFFECTS INCLUDED A LIMITED INCREASE IN LIVER WEIGHT (APPROXIMATELY 15X) AND SERUM ALKALINE PHOSPHATASE (APPROXIMATELY 30X) WITHOUT ANY SIGNS OF LIVER LESIONS. THE NO-OBSERVABLE-EFFECT-LEVEL (NOEL) FOR THESE EFFECTS WAS 50 MG/KG. A 90-DAY ORAL GAVAGE STUDY WAS CONDUCTED IN THE RAT USING DOSES OF 0, 10, 100 AND 1000 MG/KG/DAY. EFFECTS INCLUDED HYPERSALI- IRGANOX 1520 00 085160 CONFTDFNTTAl PAGE A v VATION AND INCREASED LIVER WEIGHT WITHOUT HISTOPATHOLOGIC ^ CHANGES. THE NOAEL IS CONSIDERED TO BE 1000 MG/KG/DAY WITH THE NOEL EQUAL TO 10 MG/KG/DAY. A 14-DAY RANGE-FINDING STUDY WAS CONDUCTED USING THE BEAGLE DOG. THE NOEL IS 2000 MG/KG/DAY; HIGHER DOSAGES WERE NOT USED. ORAL ADMINISTRATION OF IRGANOX 1520 TO DOGS AT DOSE LEVELS OF 10, 100 OR 1000 MG/KG/DAY FOR THIRTEEN WEEKS WAS FOUND TO CAUSE BILIARY CELL PROLIFERATION AT THE 1000 MG/KG DOSE LEVEL THAT WAS NOT REVERSED BY 4-WEEKS, POST-DOSE. A SLIGHT TO MODERATE INCREASE IN AMINOTRANSFERASES AND/OR ALKALINE PHOSPHATASE ACTIVITIES WERE RECORDED AT THE 100 AND 1000 MG/KG DOSE LEVELS. THE NO-OBSERVABLE-EFFECT LEVEL (NOEL) WAS DETERMINED TO BE 10 MG/KG. SIGNS AND SYMPTOMS OF EXPOSURE. MAY CAUSE SKIN SENSITIZATION WHICH COULD BE SEEN AS REDNESS. MEDICAL CONDITIONS AGGRAVATED BY EXPOSUREi ALLERGY, ECZEMA. EMERGENCY AND FIRST AID PROCEDURES-EYES. FOR EYE CONTACT, FLUSH EYES WITH PLENTY OF WATER FOR SEVERAL MINUTES. GET MEDICAL ATTENTION IF IRRITATION OCCURS. EMERGENCY AND FIRST AID PR0CEDURE5-SKIN. FOR SKIN CONTACT, WASH AFFECTED AREAS WITH PLENTY OF WATER, AND SOAP, IF AVAILABLE, FOR SEVERAL MINUTES. GET MEDICAL ATTENTION IF IRRITATION OCCURS. EMERGENCY AND FIRST AID PROCEDURES-INGESTION. IF SWALLOWED, GIVE AT LEAST 3-4 GLASSES OF WATER BUT DO NOT INDUCE VOMITING. DO NOT GIVE ANYTHING BY MOUTH TO AN UN CONSCIOUS OR CONVULSING PERSON. EMERGENCY AND FIRST AID PROCEDURES-INHALATION. IF INHALED, REMOVE FROM AREA TO FRESH AIR. GET MEDICAL ATTENTION IF RESPIRATORY IRRITATION DEVELOPS OR IF BREATHING BECOMES DIFFICULT. EMERGENCY AND FIRST AID PROCEDURES-OTHER. REMOVE AND WASH CONTAMINATED CLOTHING PRIOR TO REUSE. SECTION VII-SPILL OR LEAK PROCEDURES SPILL PROCEDURESi ABSORB ONTO SAND OR OTHER ABSORBENT MATERIAL. SHOVEL INTO CLOSABLE CONTAINER FOR DISPOSAL. WEAR PROTECTIVE EQUIPMENT SPECIFIED BELOW. FLUSH RESIDUE WELL WITH DETERGENT SOLUTION. WASTE DISPOSAL METHODS. INCINERATE IN A CHEMICAL INCINERATOR EQUIPPED WITH AN AFTER BURNER AND SCRUBBER. FOLLOW ALL FEDERAL, STATE AND LOCAL REGULATIONS. EFFLUENT DATA-BOD. NOT BIODEGRADABLE IN MODIFIED STURM TEST. EFFLUENT DATA-COD. 2.66 G COD/G SEWAGE BACTERIAL TOXICITY. INHIBITORY CONCENTRATION ON RESPIRATION OF AEROBIC WASTE WATER BACTERIA. ICZO, IC50, IC80 >100 PPM IRGANOX 1520 Oo ?8si 61 OO/VF Td^NTTal PAGE 5 FISH TOXICITY* ZEBRA FISH, ACUTE 96 HOUR LC50> >100 PPM. INVERTEBRATE TOXICITY* DAPHNIA MAGNA, ACUTE 24 HOUR EC50* COULD NOT BE CALCULATED; ECO IS < 0.5 PPM AND EC100 IS >5.5 PPM. SECTION VIII-SPECIAL PROTECTION INFORMATION _ VENTILATION* WORK IN WELL VENTILATED AREAS. PROTECTIVE GLOVES. WEAR IMPERVIOUS GLOVES. EYE PROTECTION* WEAR SAFETY GLASSES OR GOGGLES IF EYE CONTACT IS POSSIBLE. RESPIRATORY PROTECTION. WEAR A NIOSH APPROVED RESPIRATOR FOR ORGANIC VAPORS TO MITIGATE EXPOSURE SHOULD VAPORS OR AEROSOLS BE GENERATED DURING EXTRUSION PROCESSING OPERATIONS. OTHER PROTECTIVE EQUIPMENT* WEAR APPROPRIATE PROTECTIVE EQUIPMENT TO AVOID PERSONAL CONTACT AND EXPOSURE. SECTION IX-SPECIAL PRECAUTIONS HANDLING PRECAUTIONS* MAY CAUSE ALLERGIC SKIN REACTIONS ON PROLONGED OR REPEATED CONTACT. DO NOT GET IN EYES, ON SKIN OR ON CLOTHING. DO NOT INHALE MISTS. USE ONLY WITH ADEQUATE VENTILATION. FOR INDUSTRIAL USE ONLY. SHIPPING AND STORING PRECAUTIONS: KEEP CONTAINER TIGHTLY CLOSED WHEN NOT IN USE AND DURING TRANSPORT. PERSONAL HYGIENE. WASH THOROUGHLY AFTER HANDLING AND BEFORE EATING, DRINKING, OR USING TOBACCO PRODUCTS. SECTION X- REGULATORY INFORMATION DOT PROPER SHIPPING NAME* NOT REGULATED AS A HAZARDOUS MATERIAL BY THE U.S. DEPT. OF TRANSPORTATION (DOT) 49 CFR 172.101 HAZARDOUS MATERIALS TABLE. DOT CLASS* NONE. DOT NUMBER* NONE. RCRA STATUS. NOT A HAZARDOUS WASTE UNDER RCRA (40 CFR 261). SARA/TITLE III - EHS LIST* THIS PRODUCT DOES NOT CONTAIN AN 'EXTREMELY HAZARDOUS SUB- / STANCE' (EHS) FOR EMERGENCY PLANNING UNDER SEC. 301-303 * (40 CFR 300 AND 355) AND FOR EMERGENCY RELEASE NOTIFICATION IRGANOX 1520 DO 085162 CONFIDENTIAL PAGE 6 UNDER SEC. 304. SARA/TITLE III - CERCLA LIST- THIS PRODUCT DOES NOT CONTAIN A 'CERCLA' LISTED HAZARDOUS SUBSTANCE FOR EMERGENCY RELEASE NOTIFICATION UNDER SEC. 304 (40 CFR 302). SARA/TITLE III - OSHA/HCS HAZARDOUS CHEMICAL > THIS PRODUCT IS CONSIDERED HAZARDOUS UNDER THE OSHA 'HAZARD COMMUNICATION STANDARD' CHCS) AND IS REGULATED UNDER SEC. 311-312 (40 CFR 370). ITS HAZARDS AREi IMMEDIATE (ACUTE) HEALTH HAZARD. SARA/TITLE III - TOXIC CHEMICALS LIST * THIS PRODUCT DOES NOT CONTAIN A TOXIC CHEMICAL FOR ROUTINE ANNUAL 'TOXIC CHEMICAL RELEASE REPORTING' UNDER SEC. 313 (40 CFR 372). TSCA INVENTORY STATUSCHEMICAL COMPONENTS LISTED ON TSCA INVENTORY. CALIFORNIA PROPOSITION 65THIS PRODUCT DOES NOT CONTAIN ANY CHEMICALS CURRENTLY ON THE CALIFORNIA LIST OF KNOWN CARCINOGENS AND REPRODUCTIVE TOXINS. MASSACHUSETTS RIGHT-TO-KNOW ACTCONTAINS NO COMPONENTS ON THE MASSACHUSETTS LIST AT A THRESHOLD LEVEL. NEW JERSEY RIGHT-TO-KNOW LABELING INFORMATIONTHIS PRODUCT CONTAINS THE FOLLOWING - CHEMICAL NAME - 6-METHYL-2,4-BISKOCTYLTHIO)METHYL)-PHENOL CAS NUMBER - 110553-27-0 XXX CHEMICAL NAME - 2-METHYL-6-{(OCTYLTHIO)METHYL)-PHENOL CAS NUMBER - NONE PERCENT - IMPURITY xxx PENNSYLVANIA RIGHT-TO-KNOW ACT- THE FOLLOWING IS REQUIRED COMPOSITION INFORMATION. CHEMICAL NAME - 2-METHYL-4,6-BISKOCTYLTHIO) METHYL) PHENOL CAS NUMBER - 110553-27-0 COMMON NAME - NONE COMMENTS - NOT ON PENNSYLVANIA HAZARDOUS SUBSTANCE LIST. XXX ISSUE DATE- 04/22/91 REVISION- OSC FOR FURTHER INFORMATION, PLEASE CONTACT- BRUCE SCHWEMMER THE INFORMATION AND RECOMMENDATIONS CONTAINED HEREIN ARE BASED UPON DATA BELIEVED TO BE CORRECT. HOWEVER, NO GUARANTEE OR WARRANTY OF ANY KIND EXPRESSED OR IMPLIED IS MADE WITH RESPECT TO THE INFORMATION CONTAINED HEREIN. IRGANOX 1520 DO 085163 CONFIDENTIAL PAGE 1 MATERIAL SAFETY DATA SHEET CIBA-GEIGY CORPORATION ADDITIVES DIVISION SEVEN SKYLINE DRIVE HAWTHORNE, NEW YORK 10532 (914) 347-4700 |j EMERGENCY PHONE NUMBER* I (800) 888-8372 SECTION I-IDENTITY INFORMATION IDENTITY (TRADENAME) IRGANOX 1520 FAMILY/CHEMICAL NAME. 2-METHYL-4,6-BIS{(OCTYLTHI0)METHYL)PHENOL PRODUCT TYPE* STABILIZER IMPORTANT* PLEASE NOTE* REVISION 06 - SECTIONS VI, IX REVISED. XXXXXXXXXXXXXXXXXXXXXXXXXXXXXX X THIS MATERIAL WILL NOT BE SOLD FOR USE IN PRODUCTS X x FOR WHICH PROLONGED CONTACT WITH MUCOUS MEMBRANES OR X X ABRADED SKIN, OR IMPLANTATION WITHIN THE HUMAN BODY, IS X X SPECIFICALLY INTENDED. BECAUSE OF THE WIDE RANGE OF X x SUCH POTENTIAL USES, CIBA-GEIGY CORPORATION IS NOT ABLE X X TO RECOMMEND THIS MATERIAL AS SAFE.AND EFFECTIVE FOR X X SUCH USES AND ASSUMES NO LIABILITY FOR ANY SUCH USES. X XXXXXXXXKXXXXXXXXXXXXXKXXXXXXX HAZARD STATEMENT * xxxxxxxxxxxxxxxxxxxxxxxxxxxxxx X THIS MATERIAL SAFETY DATA SHEET (MSDS) HAS BEEN X x PREPARED IN COMPLIANCE WITH THE FEDERAL OSHA HAZARD x X COMMUNICATION STANDARD 29 CFR 1910.1200. X X THIS PRODUCT IS CONSIDERED TO BE A HAZARDOUS X X CHEMICAL UNDER THAT STANDARD. X XXXXXXXXXXXXXXXXXXXXXXXXXXXXXX ________________________ SECTION II-HAZARDOUS INGREDIENTS SPECIFIC CHEMICAL NAME* 2-METHYL-4,6-BIS{(0CTYLTHI0)METHYLlPHENOL CAS > 110553-27-0 IRGANOX 1520 HO 085164 confidential PAGE 2 COMMON NAMEi NONE EXPOSURE LIMITSi OSHA PELi NONE ESTABLISHED ACGIH TLVt NONE ESTABLISHED CARCINOGENICITYi THIS CHEMICAL HAS NOT BEEN REVIEWED FOR CARCINOGENICITY BY NTP, IARC, OR OSHA. SECTION III-PHY5ICAL DATA APPEARANCE* YELLOWISH OIL. ODOR NOT DETERMINED. BOILING POINT. >178C AT 0.083 MM HG. MELTING POINT. 1 AC. EVAPORATION RATE. NOT APPLICABLE. PERCENT VOLATILE. NEGLIGIBLE. VAPOR DENSITY. NOT APPLICABLE. VAPOR PRESSURE. LESS THAN OR EQUAL TO 1.5 X 10(-7) AT 25C. SOLUBILITY IN WATER. AT 20C, < 2X 10(-5) G/L SPECIFIC GRAVITY. 0.98 CH20 = 1). VISCOSITY. 87.0 MPA.S AT D = 109 S(-l) SECTION IV-FIRE AND EXPLOSION HAZARD DATA FLASH POINT. >392F. FLAMMABLE LIMITS IN AIR-LOWER. NOT DETERMINED. FLAMMABLE LIMITS IN AIR-UPPER. NOT DETERMINED. AUTOIGNITION TEMPERATURE. 626F. NFPA CODE. NONE. EXTINGUISHING MEDIA. CARBON DIOXIDE, FOAM, DRY CHEMICAL, WATER SPRAY. WATER OR FOAM MAY CAUSE FROTHING. FIRE FIGHTING PROCEDURES-SPECIAL. USE SELF-CONTAINED BREATHING APPARATUS. UNUSUAL FIRE AND EXPLOSION HAZARDS. DECOMPOSITION AND COMBUSTION PRODUCTS MAY BE TOXIC. IRGANOX 1520 D 085165 CONFTDFNTXAL PAGE 3 SECTION V-REACTIVITY DATA STABILITY STABLE. INCOMPATIBILITY. STRONG OXIDIZING AGENTS. HAZARDOUS DECOMPOSITION PRODUCTS. THERMAL DECOMPOSITION AND BURNING MAY PRODUCE CARBON MONOX IDE, CARBON DIOXIDE, SULFUR OXIDES AND POSSIBLY OTHER TOXIC SPECIES. HAZARDOUS POLYMERIZATION. HILL NOT OCCUR. SECTION VI-HEALTH HAZARD DATA PRIMARY ROUTES OF EXPOSURE. DERMAL. ORAL LD50> (RATS) >5000 MG/KG. DERMAL LD50. (RATS) >2000 MG/KG. SKIN IRRITATION. (RABBITS) NOT AN IRRITANT. EYE IRRITATION. (RABBITS) NOT AN IRRITANT. SENSITIZATION. (GUINEA PIGS) SKIN SENSITIZATION IN MAXIMIZATION TEST.(7/20 AT FIRST CHALLENGE, 1/20 AT SECOND CHALLENGE) TERATOGENICITY. A TERATOLOGY STUDY WAS PERFORMED WITH RATS WHICH RECEIVED ORAL DOSES OF 0, 50, 150 OR 300 MG/KG/DAY DURING DAYS 6-15 OF GESTATION. WHILE 300 MG/KG WAS SLIGHTLY TOXIC TO THE MOTHERS, THERE WERE NO SIGNIFICANT EFFECTS ON PREGNANCY OR EMBRYO/FETAL DEVELOPMENT. MUTAGENICITY. AMES TEST. NON-MUTAGENIC. MICRONUCLEUS TEST. NON-MUTAGENIC. CHINESE HAMSTER CELLS (V79). NON-MUTAGENIC SUBCHRONIC ORAL FEEDING STUDIES. DURING A 28-DAY ORAL ADMINISTRATION STUDY WITH RATS, AN APPAR ENT FUNCTIONAL ADAPTATION OF THE LIVER OCCURRED IN ANIMALS RECEIVING 250 AND 1000 MG/KG BODY WEIGHT PER DAY. THE EFFECTS INCLUDED A LIMITED INCREASE IN LIVER WEIGHT (APPROXIMATELY 15)0 AND SERUM ALKALINE PHOSPHATASE (APPROXIMATELY 30%) WITHOUT ANY SIGNS OF LIVER LESIONS. THE NO-OBSERVABLE-EFFECT-LEVEL (NOEL) FOR THESE EFFECTS WAS 50 MG/KG. A 90-DAY ORAL GAVAGE STUDY WAS CONDUCTED IN THE RAT USING DOSES OF 0, 10, 100 AND 1000 MG/KG/DAY. EFFECTS INCLUDED HYPERSALI VATION AND INCREASED LIVER WEIGHT WITHOUT HISTOPATHOLOGIC CHANGES. THE NOAEL IS CONSIDERED TO BE 1000 MG/KG/DAY WITH THE NOEL EQUAL TO 10 MG/KG/DAY. A 19-DAY RANGE-FINDING STUDY WAS CONDUCTED USING THE BEAGLE IRGANOX 1520 00 085166 CONFTDFNTTAl.. PAGE 4 DOG. THE NOEL IS ZOOO MG/KG/DAY; HIGHER DOSAGES WERE NOT USED. SIGNS AND SYMPTOMS OF EXPOSUREi MAY CAUSE SKIN SENSITIZATION WHICH COULD BE SEEN AS REDNESS. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE ALLERGY, ECZEMA. EMERGENCY AND FIRST AID PROCEDURES-EYES. FLUSH EYES WITH WATER FOR 15 MINUTES WHILE HOLDING EYELIDS OPEN. GET MEDICAL ATTENTION. EMERGENCY AND FIRST AID PROCEDURES-SKIN. WASH WITH MILD SOAP AND WATER. IF IRRITATION OCCURS, GET MEDICAL ATTENTION. EMERGENCY AND FIRST AID PROCEDURES-INGESTION IF CONSCIOUS, GIVE LARGE QUANTITIES OF WATER. GET MEDICAL ATTENTION. EMERGENCY AND FIRST AID PROCEDURES-INHALATIONi REMOVE TO FRESH AIR. EMERGENCY AND FIRST AID PROCEDURES-OTHER. REMOVE AND WASH CONTAMINATED CLOTHING PRIOR TO REUSE. ________________________ SECTION VII-5PILL OR LEAK PROCEDURES _______________ SPILL PROCEDURES. ABSORB ONTO SAND OR OTHER ABSORBENT MATERIAL. SHOVEL INTO CLOSABLE CONTAINER FOR DISPOSAL. WEAR PROTECTIVE EQUIPMENT SPECIFIED BELOW. FLUSH RESIDUE WELL WITH DETERGENT SOLUTION. WASTE DISPOSAL METHODS. INCINERATE IN A CHEMICAL INCINERATOR EQUIPPED WITH AN AFTER BURNER AND SCRUBBER. FOLLOW ALL FEDERAL, STATE AND LOCAL REGULATIONS. EFFLUENT DATA-BOD. NOT BIODEGRADABLE IN MODIFIED STURM TEST. EFFLUENT DATA-COD. 2.66 G COD/G SEWAGE BACTERIAL TOXICITY. INHIBITORY CONCENTRATION ON RESPIRATION OF AEROBIC WASTE WATER BACTERIA. IC20, IC50, IC80 >100 PPM FISH TOXICITY. ZEBRA FISH, ACUTE 96 HOUR LC50. >100 PPM. INVERTEBRATE TOXICITY. DAPHNIA MAGNA, ACUTE 24 HOUR EC50. COULD NOT BE CALCULATED; ECO IS < 0.5 PPM AND EC100 IS >5.5 PPM. SECTION VIII-SPECIAL PROTECTION INFORMATION VENTILATION. WORK IN WELL VENTILATED AREAS. PROTECTIVE GLOVES. WEAR IMPERVIOUS GLOVES. EYE PROTECTION: WEAR SAFETY GLASSES OR GOGGLES IF EYE CONTACT IS POSSIBLE. RESPIRATORY PROTECTION. WEAR A NIOSH APPROVED RESPIRATOR FOR ORGANIC VAPORS TO MITIGATE IRGANOX 1520 no O8BI67 CONFIDENTIAL PAGE 5 EXPOSURE SHOULD VAPORS OR AEROSOLS BE GENERATED DURING EXTRUSION PROCESSING OPERATIONS. OTHER PROTECTIVE EQUIPMENTi WEAR APPROPRIATE PROTECTIVE EQUIPMENT TO AVOID PERSONAL CONTACT AND EXPOSURE. SECTION IX-SPECIAL PRECAUTIONS HANDLING PRECAUTIONS> MAY CAUSE ALLERGIC SKIN REACTIONS ON PROLONGED OR REPEATED CONTACT. DO NOT GET IN EYES, ON SKIN OR ON CLOTHING. DO NOT INHALE MISTS. USE ONLY WITH ADEQUATE VENTILATION. FOR INDUSTRIAL USE ONLY. SHIPPING AND STORING PRECAUTIONS! KEEP CONTAINER TIGHTLY CLOSED WHEN NOT IN USE AND DURING TRANSPORT. PERSONAL HYGIENEi WASH THOROUGHLY AFTER HANDLING AND BEFORE EATING, DRINKING, OR USING TOBACCO PRODUCTS. SECTION X- REGULATORY INFORMATION DOT PROPER SHIPPING NAME' NOT REGULATED AS A HAZARDOUS MATERIAL BY THE U.S. DEPT. OF TRANSPORTATION (DOT) A9 CFR 172.101 HAZARDOUS MATERIALS TABLE. DOT CLASSi NONE. DOT NUMBER: NONE. RCRA STATUS: NOT A HAZARDOUS WASTE UNDER RCRA (AO CFR 261). SARA/TITLE III - EHS LISTi THIS PRODUCT DOES NOT CONTAIN AN 'EXTREMELY HAZARDOUS SUB STANCE' (EHS) FOR EMERGENCY PLANNING UNDER SEC. 301-303 (AO CFR 300 AND 355) AND FOR EMERGENCY RELEASE NOTIFICATION UNDER SEC. 30A. SARA/TITLE III - CERCLA LIST: THIS PRODUCT DOES NOT CONTAIN A 'CERCLA' LISTED HAZARDOUS SUBSTANCE FOR EMERGENCY RELEASE NOTIFICATION UNDER SEC. 30A (AO CFR 302). SARA/TITLE III - OSHA/HCS HAZARDOUS CHEMICALi THIS PRODUCT IS CONSIDERED HAZARDOUS UNDER THE OSHA 'HAZARD COMMUNICATION STANDARD* (HCS) AND IS REGULATED UNDER SEC. 311-312 (AO CFR 370). ITS HAZARDS ARE: IMMEDIATE (ACUTE) HEALTH HAZARD. SARA/TITLE III - TOXIC CHEMICALS LISTi THIS PRODUCT DOES NOT CONTAIN A TOXIC CHEMICAL FOR ROUTINE ANNUAL 'TOXIC CHEMICAL RELEASE REPORTING' UNDER SEC. 313 (AO CFR 372). TSCA INVENTORY STATUS: CHEMICAL COMPONENTS LISTED ON TSCA INVENTORY. IRGANOX 1520 0 085168 ConftofNTtai PAGE 6 CALIFORNIA PROPOSITION 65 THIS PRODUCT DOES NOT CONTAIN ANY CHEMICALS CURRENTLY ON THE CALIFORNIA LIST OF KNOWN CARCINOGENS AND REPRODUCTIVE TOXINS. MASSACHUSETTS RIGHT-TO-KNOW ACT. CONTAINS NO COMPONENTS ON THE MASSACHUSETTS LIST AT A THRESHOLD LEVEL. NEW JERSEY RIGHT-TO-KNOW LABELING INFORMATION. THIS PRODUCT CONTAINS THE FOLLOWING . CHEMICAL NAME . 6-METHYL-2,A-BISLCOCTYLTHIOJMETHYL)-PHENOL CAS NUMBER 110553-27-0 XXX CHEMICAL NAME . 2~METHYL-6-{(0CTYLTHI0)METHYL)-PHEN0L CAS NUMBER > NONE PERCENT . IMPURITY xxx PENNSYLVANIA RIGHT-TO-KNOW ACT. THE FOLLOWING IS REQUIRED COMPOSITION INFORMATION. CHEMICAL NAME . 2-METHYL-A,6-BISt(OCTYLTHIO)METHYL)PHENOL CAS NUMBER . 110553-27-0 COMMON NAME . NONE COMMENTS > NOT ON PENNSYLVANIA HAZARDOUS SUBSTANCE LIST. XXX ISSUE DATE. 06/15/90 REVISION. 06C FOR FURTHER INFORMATION, PLEASE CONTACT. BRUCE SCHWEMMER THE INFORMATION AND RECOMMENDATIONS CONTAINED HEREIN ARE BASED UPON DATA BELIEVED TO BE CORRECT. HOWEVER, NO GUARANTEE OR WARRANTY OF ANY KIND EXPRESSED OR IMPLIED IS MADE WITH RESPECT TO THE INFORMATION CONTAINED HEREIN. IRGANOX 1520 DO 085l69 COfs/p r08NTXAL AC-10 ASPHALT E^ON COMPANY. USA A DIVISION OF EXXON CORPORATION DATE ISSUED: 10/18/88 SUPERSEDES DATE: 03/02/88 MATERIAL EXXON COMPANY, U.S.A. ______________ .. . ** SAFETY DATA SHEET P.O. BOX 2180 HOUSTON, TX \ V 77252*2180 A IDENTIFICATION AND EMERGENCY INFORMATION PRODUCT NAME AC-10 ASPHALT PRODUCT CODE 171520 - 07152 CHEMICAL NAME Petroleum Asphalt CAS NUMBER 8052-42-4 PRODUCT APPEARANCE AND ODOR Sami-solid when cold, viscous fluid whan hot; black color Charactarlstlc asphaltic odor EMERGENCY TELEPHONE NUMBER (713) 656-3424 9o B. COMPONENTS AND HAZARD INFORMATION COMPONENTS CAS NO. OP COMPONENTS APPROXIMATE CONCENTRATION Asphalt 8052-42-4 1007. Sa# Section E for Health and Hazard Information. See Section H for additional Environmental Information. HAZARDOUS MATERIALS IDENTIFICATION SYSTEM (HMIS) Health Flanmabl1 tty Reactivity BASIS 11 0 Recommanded by Exxon EXPOSURE LIMIT FOR TOTAL PRODUCT 5 mg/m3 for oil mist in air BASIS OSHA Regulation 29 CFR 1910.1000 5 mg/m3 for oil mist or fumes (10 mg/m3 STEL) Recommended by the American Conference of Governmental Industrial Hygienists (ACGIH) 5 mg/m3 for mist In air Recommenced by Exxon The American Conference of Governmental Industrial Hygienists (ACGIH) has adopted a Threshold Limit Value for hydrogen sulfide (H2S) of 10 ppm in air as e time-weighted average for an 8-nour workday with a 15 ppm (21 mg/m3) STEL. OSHA Regulation 29 CFR 1910.1000 further lists a celling concentration of 20 ppm, and a maximum peak of 50 ppm for 10 minutes once per day if no other measurable exposure occurs. NIOSH-approved respiratory equipment should be used when permissible concentrations are exceeded. C. PRIMARY ROUTES OF ENTRY AND EMERGENCY AND FIRST AID PROCEDURES 0851 ?o _____ CONFTDFNTIAl. _ EYE CONTACT If hot product is splashed into eyes, flush with clear water end contact physician Immediately. SKIN If skin is contaminated with c ol, solid asphalt, the contaminated area should be cleaned with waterless skin cleanser followed by soap and water. If skin is contacted with hot asphalt, thermal burns will result. In this case, the contaminated 945*0277(MWHO0 V AC-10 ASPHALT area sh uld be treated slmlllar to othar thermal burns by cooling tha affactad araa Immediately with cooiast available watar. it la not usually advisable to immediately remove the asphalt material. Natural separation will occur in 48-72 hours. Removal should be attempted only under tha direction of a physician. If removal Is attempted, mineral oil (not mineral spirits) r mineral oil ointment may be applied to soften the asphalt to facilitate removal. INHALATION If vercome by H2S. Immediately remove to fresh air and call a physician. If breathing Is irregular or has stopped, start resuscitation, administer oxygen, if avalleble. INGESTION If ingested, 00 NOT induce vomiting; call a physician Immediately. D. FIRE AND EXPLOSION HAZARD INFORMATION FLASH POINT (MINIMUM) 218'C (425*F) ASTM D 92, Cleveland Open Cup AUTOIGNITION TEMPERATURE Greater than 260*C (500*F) NATIONAL FIRE PROTECTION ASSOCIATION (NFPA) - HAZARD IDENTIFICATION Health Flammability Reactivity BASIS 01 0 Recommended by the National Fire Protection Association HANDLING PRECAUTIONS Use product with caution around heat, sparks, pilot lights, static electricity, and pan flame. FLAMMABLE OR EXPLOSIVE LIMITS (APPROXIMATE PERCENT BY VOLUME IN AIR) Estimated values: Lower Flammable Limit 0.9K Upper FlammaDle Limit 7X hot asphalt flash warning Studies have shown that relatively low flash point substances, such as hydrogen sulfide and low-boiling hydrocarbons, may accumulate in the vapor space of hot asphalt tanks and bulk transport compartments. Such vapors may exhibit flammability characteristics of a significantly lower flash product than would be indicated by the open cup flash test. As a precaution, keep Ignition sources away from vents and openings, including prevention of accumulation of pyrophoric iron sulfide. Asphalt Institute Publication IS-1B0 and American Petroleum Institute Publication 852-20230 contain further information and guidance on the safe storage and handling of hot asphalt. EXTINGUISHING MEDIA AND FIRE FIGHTING PROCEDURES Foam, water spray (fog), dry chemical, carbon dioxide and vaporizing liquid type extinguishing agents may all be suitable for extinguishing fires involving this type of product, depending on size or potential size of fire and clrcumstances related to the situation. Plan fire protection and response strategy through consultation with local fire protection authorities or appropriate specialtlsts. The following procedures for this type of product are based on the recommendations in the National Fire Protection Association's "Fire Protection Guide on Hazardous Materials*. Eighth Edition (1984): Use water spray, dry chemical, foam, or carpon dioxide. Water or foam may cause frothing. Use water to keep fire-exposed containers cool. Water spray may be used to flush spills away from exposures. Minimize breathing gases, vapor, fumes or decomposition products. Use supplled-alr breathing equipment for enclosed or confined spaces or as otherwise needed. DECOMPOSITION PRODUCTS UNDER FIRE CONDITIONS Fumes, smoke, carbon monoxide, hydrogen sulfide, sulfur oxides, aldehydes and other decomposition products. In the case of incomplete combustion. 00 085171 "EMPTY* CONTAINER WARNING CONFTDFNTTA! "Empty* containers retain residue (liquid and/or vapor) and can be dangerous. DO NOT PRESSURIZE. CUT. WELD, BRAZE. SOLDER, DRILL, GRIND OR EXPOSE SUCH CONTAINERS TO HEAT. FLAME. SPARKS. STATIC ELECTRICITY. OR OTHER SOURCES OF IGNITION; THEY MAY EXPLODE AND CAUSE INJURY OR DEATH. Do not attempt to clean since residue Is difficult to remove. "Empty" drums should be completely drained, properly bunged and promptly returned to a drum reconditioner. All other containers should be disposed of In an environmentally safe manner and in accordance with governmental regulations. For work on tanks refer to Occupational Safety and Health Administration regulations. ANSI Z49.1, and other governmental and Industrial references pertaining to cleaning, repairing, welding, or other contemplated operations. 945.0:77(MWH002) PAGE: 2 DATEISSUED: 10/18/88 SUPERSEDES DATE: 03/02/88 AC-10 ASPHALT E HEALTH AND HAZARD INFORMATION VARIABILITY AMONG INDIVIDUALS Health studies have shown that many petroleum hydrocarbons and synthetic lubricants pose potential human health risks which may vary from person to person. As a precaution, exposure to liquids, vapors, mists or fumes should be minimized. EFFECTS OF OVEREXPOSURE (Signs and synptoms of exposure) Inhalation of high vapor concentrations may cause eye and respiratory irritation, headaches, dizziness or nausea, unconsciousness and possibly death. Prolonged or repeated contact with product at warm or near ambient temperature may cause skin Irritation. CAUTION: Product normally shipped hot (approximately 225-350*F). NATURE OF HAZARD AND TOXICITY INFORMATION Skin contact with hot product may cause thermal burns. Prolonged or repeated contact with this product at warm or amoient temperatures may cause akin irritation and dermatitis: however, based on human experience and available toxicological data, this product Is Judged to be neither a "corrosive" nor an "Irritant1 by OSHA criteria. Eye contact with hot product may cause thermal burns. Contact with this product at warm or ambient temperatures may cause eye Irritation but will not damage eye tissue. CAUTION: Under certain circumstances sulfur compounds In hot product may form hydrogen sulfide (H2S) gas. Cooling product may continue to emit traces of H2S temporarily from entrapped or dissolved gases. H2S is a colorless, toxic and extremely flammable gas with an odor at low concentrations characteristic of rotten eggs and a sweetish odor at high concentrations. Odor cannot be relied upon as a means of detection because the sense of smell rapidly becomes insensitive to H2S, and the H2S odor may be masked by the general odor of hot product. Because H2S may accumulate In tanks and bulk transport compartments, personnel should stand upwind, keep their faces at least two feet from compartment openings, and avoid breathing vapors when opening hatches and dome covers. (In a large number f tests, permissible concentrations In the breathing zone were not exceeded by following this procedure. ) Prolonged breathing of 50 to 100 ppm of H2S may produce eye and respiratory tract irritation, headache, nervousness and nausea, and only a few breaths of high concentrations (e.g. 700 to 1000 ppm) may lead to unconsciousness and could be fatal. To avoid possible inhalation toxicity, the American Conference of Governmental Industrial Hygienists (ACGIH) has adopted a Threshold Limit Value for H2S of 10 ppm In air as time-weighed average for an 8-hour workday. OSHA Regulation 29 CFR 1910.1000 further lists a ceiling concentration of 20 ppm, and a maximum peak of 50 ppm for 10 minutes once per day If no other measurable exposure occurs. NIOSH-approved respiratory equipment should be used when permissible concentrations are exceeded. Product has a low order of acute oral and dermal toxicity, but minute amounts aspirated into the lungs during ingestion or vomiting may cause mild to severe pulmonary injury and possibly death. This product is Judged to have an acute oral LD50 (rat) greater than 5 g/kg of body weight, and an acute dermal LDSO (rabbit) greater than 3.16 g/kg of body weight. PRE-EXISTING MEDICAL CONDITIONS WHICH MAY BE AGGRAVATED BY EXPOSURE None Recognized F. PHYSICAL DATA The following data are approximate or typical values and should not be used for precise design purposes. BOILING RANGE IBP Approximately 480*C (900`F) VAPOR PRESSURE Less than 0.1 mm Hg * 20*C SPECIFIC GRAVITY (15.6 C/1S.6 C) 1 .05 VAPOR DENSITY (AIR - 1) Greater than 5 DO 08517? CONFTDFNTTAL 945-0277IMWH002) PAGE: 3 DATE ISSUED: 10/18/BB SUPERSEDES DATE: 03/02/8F AC-10 ASPHALT MOLECULAR WEIGHT Not determined PH Essentially neutral POUR, CONGEALING OR MELTING POINT Not aval labia VISCOSITY Minimum BOO Poisa p SO" C PERCENT VOLATILE BY VOLUME Negligible from opan contalnar In 4 hours P 38*C (100'F) EVAPORATION RATE P 1 ATM. AND 2B C (77 F) (n-BUTYL ACETATE 1) Lata than 0.01 SOLUBILITY IN WATER 1 ATM. AND 29 C (77 F) Nagllgibla; last than 0.1% G REACTIVITY This product is stabia. Hazardous polymtrlzatlon will not occur. Avoid contact with strong oxidants such as liquid chlorlna, coneantratad oxygan, sodium hypochlorlta or calcium hypochlorlta. Hot product in contact with watar can causa foaming or auddan avolutlon of staam which could causa prassura build-up and possibly ruptura a tank or vassal. Hydrogen sulfide from the product can react with the iron in an asphalt storage tank to form ferrous sulfide which is pyrophoric. K ENVIRONMENTAL INFORMATION STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Recover free product. Add sand, earth, or other suitable absorbent to spill area. Minimize skin contact. Hot product will solidify whan cooled. Keep product out of sewers and watercourses by diking or impounding. Advise authorities if product has entered or may enter sewers or watercourses. Assure conformity with applicable governmental regulations. THE FOLLOWING INFORMATION MAY BE USEFUL IN COMPLYING WITH VARIOUS STATE AND FEDERAL REGULATIONS UNDER VARIOUS ENVIRONMENTAL STATUES: REPORTABLE QUANTITY (RQ), EPA REGULATION 40 CFR 302 (CERCLA Section 102) Not applicable THRESHOLD PLANNING QUANTITY (TPQ), EPA REGULATION 40 CFR 3BS (SARA Sections 301-304) Not applicable TOXIC CHEMICAL RELEASE REPORTING, EPA REGULATION 40 CFR 372 (SARA Sections 311-313) Not applicable Acute Chronic Fire EPA HAZARD CLASSIFICATION CODE: Hazard Hazard Hazard Pressure Hazard Reactive Hazard ' Not Applicable XXX I. PROTECTION AND PRECAUTIONS VENTILATION Use local exhaust to capture vapor, mists or fumes when handling hot product, if necessary. Pr vide ventilation sufficient to prevent exceeding recommended exposure limit or buildup f explosive concentrations of vapor in air. Use explosion-proof equipment. RESPIRATORY PROTECTION Use supplled-alr respiratory protection in confined or enclosed spaces, if needed, or when H2S exceeds permissible limits. PROTECTIVE GLOVES Protect against hot liquid. Use chemical-resistant gloves to avoid skin cont 00 085j 73 OoNF r^NTTAi 945-0277IMWH002) PAGE: 4 DATE ISSUED: 10/18/88 SUPERSEDES DATE: 03/02/88 AC-10 ASPHALT EYE PROTECTION Uaa splash gogglas or faca shlald whan aya contact may occur. OTHER PROTECTIVE EQUIPMENT Usa chamlcal-rasistant apron or othar Imparvlous clothing, if neadad, to protact against hot liquid and to avoid skin contact. WORK PRACTICES / ENGINEERING CONTROLS Kaap containers and storage containers closed whan not in usa. flame or strong oxidants. Do net store near heat, sparks, PERSONAL HYGIENE Minimize breathing vapor, mist or fumes. Avoid prolonged or repeated contact with skin. Remove contaminated clothing; launder or dry-clean before reuse. Remove contaminated sh as and thoroughly clean before reuse; discard If oil-soaked. Cleanse skin thoroughly after contact, before breaks and meals, and at end of work period. Product is readily removed from skin by waterless hand cleaners followed by washing thoroughly with soap and water. J. TRANSPORTATION AND OSHA RELATED LABEL INFORMATION TRANSPORTATION INCIDENT INFORMATION For furtner information relative to spills resulting from transportation incidents, refer to latest Department of Transportation Emergency Response Guidebook for Hazardous Materials Incidents, DOT P 5800.3. DOT IDENTIFICATION NUMBER Not applicable OSHA REQUIRED LABEL INFORMATION In compliance with hazard and right-to-know requirements, the following OSHA Hazard Warnings should be found on a label, bill of lading or invoice accompanying this shipment. CAUTION! MAY FORM HYDROGEN SULFIDE (H2S) WHEN HEATED INHALATION OF H2S MAY BE FATAL HOT PRODUCT MAY CAUSE THERMAL BURNS Note: Product label will contain additional non-OSHA related information. The information and recomsendations contained herein are, to the best of Exxon's knowledge end belief, accurate end reliable as of the date issued. Exxon does not warrant or guarantee their accuracy or reliability, and Exxon shall not be liable for any loss or damage arising out of tho use thereof. The information and racommendations are offered for the user's consideration and examination, and it is tha user's responsibility to satisfy itself that they are suitable and conplat* for Its particular uss. If buysr repackages this product, legal counci 1 should bo consulted to Insure proper health, safety and other necessary Information Is Included on the container. The Environmental Information Included under Section H hereof as well as the Hazardous Materials Identification System (HMIS) and National Fire Protection Association (NFPA) ratings have been included by Exxon Conpany, U.S.A. in order to provide additional health and hazard classification Information. The ratings recornnsnded are based upon the criteria supplied by the developers of these rating systems, together with Exxon's interpretation of the available data. FOR ADDITIONAL INFORMATION ON HEALTH EFFECTS CONTACT: 945-OS77(MWM002) FOR OTHER PRODUCT INFORMATION CONTACT; DO 085174 CONFIDENTIAL PAGE: 5 DATE ISSUED: 10/18/F SUPERSEDES DATE: 03/02/ DIRECTOR OF INDUSTRIAL HYGIENE EXXON COMPANY. U.S.A. P. 0. BOX 2180 ROOM 3157 HOUSTON. TX 77252-2180 (713) 656-2443 AC-10 ASPHALT MANAGER, MARKETING TECHNICAL SERVICES EXXON COMPANY. U.S.A. P. 0. BOX 2180 ROOM 2355 HOUSTON, TX 77252-2180 (713) 656-5949 945-OI77IMWH002I PAGE: 6 DO 085175 confidential DATE ISSUED: 10/18/ee SUPERSEDES DATE: 03/02/88