Document 2RKK9mBV4V5rx4nzLNZgwLdy6

AR 226 - 0692 BIODEGRADATION (BOD/COD) TEST SUBSTANCE Identity: A mixture containing perfluorooctanesulfonate, which may also be referredtoas PFOS, FC-85 or as a component of FC-201AF. (1- Octanesulfonic acid) (CAS # 2795-39-3). Remarks: The 3M production lot number was not noted. The test sample is FC-201AF (L-13652). Current information indicates it is a mixture of 3% PFOS, 18.59% diethylene glycol butyl ether, 37.81% water, 14% ethylene glycol, 8.25% Acrylic foamer, 9% sodium octyl sulfate, 0.3% sodium lauryl sulfate, 3% triethanolamine, 6% sulfonated alkyl ether salts, and 0.05% tolyltriazole. _ Thefollowing summaryapplies to amixturewithincompletely crehfalreacctttehreizbeidodceognrcaednatbrialtiityoonfsotfheimfpluuroirtioecsh.emDiactaal mcoamypnoonteanctcoufrtahteelytest sample. METHOD: Method: Not given Type: Aerobic GLP: Year cNomopleted: 1996 Contact time: 28 days Inoculum: Not given. RESULTS Chemical Oxygen Demand (COD): 1,710,000 mg/kg Biochemical Oxygen Demand (BOD): 5-Day: 265,000 mg/kg 10-Day: 20-Day: 288,000 385,000 mmgg//kkgg (replicate) 382,000 mg/kg (replicate) 494,000 mg/kg 28-Day: 550018,,000000 mmgg//kkgg (replicate) 504,000 mg/kg (replicate) ---- IN SIONS No conclusions given. 000177 Submitter: 3M Company, Environmental Laboratory, P.O. Box 33331, St. Paul, Minnesota, 55133 DATA QUALITY Reliability: Kiimisch ranking 3. Study lacks description and records of the method followed. The inoculum was not properly characterized. Sample purity was not properly characterized and the study lacks analytical confirmationofthe amountof fluorochemical proportion in the solution. REFERENCES "This study was conducted by Pace Analytical ServicesofGolden Valley, MN at the requestofthe 3M Company, Lab Request number N3747, 1995. OTHER - Last changed: 6/26/00 000178 06/25/2000 EANRVCIHRIOVNEMDENTFAILNALLABROERPOARTTORY 1 RLAEBQUERSEQTUOERSTNAMNEO:. $NGB7S4/7Shari Loushin DEPARTHENT: 3058 DPARTOEJECRTECENOI:VEDB:ILT1W1E/N3V0I/R1995 DESC: FG-201AF Light Water BOD (L-13652) CEOXNPTCROAMCPT DLAATBE(:S):01/P0AC4E/1996 DPARTOEJECCOTMPLLEEATD:ED:TL0H2A/T0F6I/1E9L9D6 3PMHONFEAX NON:O: 65615-17-7787-87-6816736 dAaqpuhantiiac, Tmoxicrtoetsotxingandressullutdsg:e rSeesepirLRatiNo32n81inhfiobritailogna.e, and N2964 for fish, sab 11/30/95 sLaomwpelrecdoinlcuetnitornastiodnesple1t/e5/d95a.fter 10 days for bod. Sample Will be re-set at mjc pace 1/2/95 SAMPLE DATE CODE DESCRIPTION RESULT 1 09/04/95 FC-201AF Dark Liquid PACE PACE COD P-0B0D-05 cop *B0D-05 (CARBONACEOUS) PPAACCEE PP--CCBBOODD--2100 **BBOODD--2100 ((CCAARRBBOONNAACCEEOOUUSS)) PAE P.CBOD-28 *B0D-28 (CARBONACEOUS) 2167510000000 mHgG//kkgg 348954000000 nngg//kkgg 508000 mg/kg 2 UP #1 omen PPAACCEE PP--CCBBOODD--1005 **BBOODD--1005 ((CCAARRBBOONNAACCEEOOUUSS)) PPAACCEE PP--CCBBOODD--2208 **BBOODD--2208 ((CCAARRBBOONNAACCEEOOUUSS)) 328828000000 mmgg//kkgg 550041000000 mmgg//kkgg * = CONTRACT LAB DATA MOL or (95% C.I.) 114000000 1144000000 14000 1144000000 1144000000 000179 . ro Product Testing Modified CBOD Test 5,10,20 & 28 Day Analyses & 2 15-968 BEST COPY AVAILABLE cline So 3 8) i ee 7 Saiki iad bE lpACESamplato. R5C50T 5 Hi i Product 1D ar eh ae a Pr3 optoockSroansSoanmprost, (omCoCodBnidas50n0msotat)g oct,La53 FSloelviconistSpoduLer5.r45a0 ips TaGSRata ulGeo |Hie J SFomlesc] oC0miciaerlesRoeeoGddmCSESIER CLEBR ER i ERs Ses LE C| HBS ISEhREi 7l.[205 FitWo+ngiSsaiiessConcanva5io0n 5 SUntsBSilOaN SsUeS OSIGddsUBdbF Sa ag S| RE ee dnp| ET EE. v nce OmL ions |EER RAT e Hra REgL e a| A R HS Pri ode uctiafR AeeA C 3 Gam RpySO: LS E G i i R i||| ob k i E oE PreopfStaockrSclauttoofiProoducntSR (NominalConcent15r0a0mtoin)oin! + | 0x + HARES 21[b tseat2mTi pEE leSE n m50A 0a 7 are IESGSEa s | h e heae ad |ConcetirofaStoocnk Solutins 5005 imoy RR [a a MEoOai s iinor EACEEASPonCoaW GMR EBL| :|ER ACESample NORi)A10)S)08 a 3+ pSaerirsenne SE ; CE oN : ) loc Siehai e ee[0n 8e7.7n75rrans d I ]| Soli oro i (CaloriesSST Contentssonst 17 He i he A;aan. 4 : 000180 NET aE serie Sa a tii NP5or.do1di0uT,ce2td0TC8esS2tO8iDnDgaTyosAtnalyses QC Data 1 500 BEST COPY AVAILABLE a fo : or [rm ; 2A 4 roo] [000s] weat- [251 no. | 7 10 [navi| ho | va | YN | Vol| cone|orsen|oben LimpfFEw | 2] ob |e) o | mom] gm] Tra emp] erase! emory git | 8 48 Be oome oev oam2s] msm[e|cse[sso[rooe[Troc ors|wiJono] sneni05e ommone| 03134[s5|| ia foam| ooo | |v| Fooo5r7[|ssaeos[[011a] osrl 2]si| 2 four[isan sud[soc[Beas] So5n0 oeo|oe[so|J [oo[e[Fnoor[[sSieosn[[atac0om|i]ssosce[[11023%] S57E5 me es] ws r[oR Se w| [||v 0HElensor[isosn[iasooss||assasot(2i5Z0)) roi pan. | io[5MRS||v ooWMfeveats]soem] Hm obsaci wo meseme e i|ae ES RE n B3RRco BSREERN eo [265=5GePBR o EoREm125%2 AME |ana | dese dlexlEl [rs IEE uci J[2A s0S37aScEmFeVA =.ro5c 750NEA wRn O17-5]9 EOC URASRERYB28 4N 03 1030 fWeEel| [fe = raET5.o7s [pe +cvJME a ang (nv=1o0- J = PES en ipeerairowate [ee TCR Jy RCPEP eh EE Te EEE ebdo tice RicRR E DeletrodSCAT RRS |i ACRA SR TEE, ae ih Rae a SR pages: a Wah BEST COPY AVAILABLE owe_j- 5-6=,ii >roduct Testing : Tee T TTT n Aodified CBODTest Anayst:_ JCS i 513,208.28 Day Analyses : Reviewed) pues wh Rg we aes BATA YU A Toi | ren|00oes |1a00pDiroep||:SA57R7O7E3s `ample No] CB0D Sond and | Resurs vo Sano] one.| Seed| car | Dyssoomv,ea|| G"Doisvotees|| itamifs | FSionanldmioers| [5 morair3on518 HR srotvetip]_ (moa) fe iro pc| mts| Figs| mis|in| Sins| a|isi lerv oolv2 ane ssero | S10 Fo [F6[s7o[F7as] Et nazar|S lio[5 55 5TosTorsSNWao] ewe] | SE [o|aT ooc |mr sf [SeIs[117s|vilioo|Sasloem| 50.22] 7.02]25.2 RAE siesta| i farse|[t1a 25[[7e vso 5[[svvs iil[e5al s0a[[eLiri aslsllooes eseirn)] [o 97c ac 5675) Cassoool|N4|az5|svr[a20s|olslo'eesn] Fr| 4 [e |vll ools ] on] J32 o 2 5ooDEIR saszoisl 2[ho| 21363oo[1al5ic]e [CEARAERRAEET|T fo {iioll osToi e3|5 e73|B4 soo Zahn stss1os|Fo|a'|Fs |v:20| ts[iz] [I ee is |BSCE [20[15 os |85]1557| ati [76 |5 esa[eva rs Husa Fasarenc|20|7 [#57 evi|5:| s|Fito 1728[7K 953[5% i | 5s 3 1725| 3% ro [892 553 7 | ed: comma BILAEGIL Ama ro7 m Ips s| al| emaa re 7 esar5487 | OES:M | Oe S|SE | Ce walll Jl [rs= cocoa Leseon scence nn Ls eT BE Ecoa SRE oy Poh eRe Bris com omen oir orESRIH GORD am 0 Se i OARS Ee Be ci comin umirns OT ROAAs oa ESC i 00018 TR A RI TS a. TE B F3e mE EsEEEE ERE mPreoiduoctTesting BEST COPY AVAILA< BLE Toinwe:s:_!-$-56 iii E Modified CBOD Test SU anavst_JGS SR ae a 510, 20 8 28 Day Analyses EE WEoGws:3a a m Sr SOE NS "S3aDUmP(p5l8%e rx Sa [eg] rea] 4 iia mii ana. | Resins | va|me an'| oman seekcon| % sin08 proc] Fimyno) 7 in| ion) gi| many | inBR B EseyBt[FooTFJileos [v5[oeo[]enoass)flits |mouin)| gerd FTE lavas ord cam) Bal Te [aoe |wo) we[sls[lool ardocs) |50i. n.00]i1 co5EA] T f|2000i3s0)281aas 7] [72 |55 [ivi oo [iv2sloco 0] 757.70]59K7704|BATES fe | snseail 5[1a [fs[W[58 irslogon [3020a]= soo]ERGPAR Camano) [s[[G 7[ass lo [Peonr OVER] RY [G5| Gs [oir s|v[oo|asliion] 807. s.00]1 Wess2 | G] AR bo li Secsel [ro [raR [Ts [osTeoe [sao ss] |856 0.12] 0.55]e3r55e.s me BRB) Bl(Bsaetocs| BedEi [705||953%s7%[[v13w7 oo |fio 55 35 ito) |cs vo os | |Boo|<5 1| ria | J | 203| |v:|15st[ars| tis | svc|she|Re e:|A i; 501] Rsooree | T 50|14]8e 5 |ov:a ot|02's s 1TistoSA {ae 81|is e7o|DSEE21c 1S|SOOE i I {28 258 53|C53 050 75s 2 RE cr AEUS iI i 50 (22[5H5 577523srss 2 A [WO i|s 7:rs , |OS OE ETRn o occoeun ceoin oocoe TEE Es Rie on po Ovo Goo ce: DUNE er cor ECSE te eeT clsnd vS eotas ER Bt sis. 73) SET CT RE A EN: RE GEERT MAT PY I:J eae CER SE TEN CTE AY SDCEA WAG RT ee La ESEsa CUBR SIRI, Hor RRR pa AA