Document 2R8GkrbK54oJLmodRGrvqn2r7

AGC SAFETY DATA SHEET 1. IDENTIFICATION OF THE SUBSTANCE / MIXTURE AND OF THE COMPANY/ UNDERTAKING This product is made in Japan by AGC Inc. AGC Inc. Document Reference Number: X-0106CLP-06 Product Name ASAHIKLINTM AC-2000 Address / Phone No. AGC Chemicals Europe, Ltd. Hillhouse International Thornton Cleveleys Lancs FY5 4QD E-Mail: Illi@agcce.com Emergency Phone No. Use Solvent 2. HAZARDS IDENTIFICATION Low acute toxicity. 2.1 Classification of the substance or mixture Regulation (EC) No. 1272/2008 (CLP) & UK CLP Not classified 3. COMPOSITION /INFORMATION ON INGREDIENTS Regulation (EC) No. 1272/2008 (CLP) Ingredient(s) 1,1,1,2,2,3,3,4,4,5,5,6,6Tridecafluorohexane A,(w/w) CAS No. >99.9 355-37-3 EC No. 206-581-9 Hazard symbol(s) and hazard statements) Not classified 4. FIRST AID MEASURES Description of first aid measures Inhalation Skin Contact Eye Contact Ingestion Product Name ASAHIKLINTM AC-2000 Revision: CLP06 Remove patient from exposure, keep warm and at rest. Oxygen may be beneficial if breathing is laboured. Obtain medical attention. Remove contaminated clothing immediately and wash affected skin with plenty of water or soap and water. If symptoms persist, obtain medical attention. Contaminated clothing should be thoroughly cleaned before reuse. Immediately irrigate with eyewash solution or clean water, holding the eyelids apart, for at least 15 minutes. Obtain medical attention. Do not induce vomiting. Provided the patient is conscious, wash out mouth with water and give 200-300 ml (half a pint) of water to drink. Obtain medical attention. Date: 06/2021 Page: 1 of 5 Further Medical Treatment Symptomatic treatment and supportive therapy as indicated. 5. FIREFIGHTING MEASURES General Non-flammable. Special hazards arising from the substance or mixture Thermal decomposition will evolve very toxic and corrosive vapours. (hydrogen fluoride and possibly carbonyl fluoride) Extinguishing media As appropriate for surrounding fire. Keep fire exposed containers cool by spraying with water. Advice for firefighters A self contained breathing apparatus and full protective clothing must be worn in fire conditions. Wear neoprene gloves when handling refuse from a fire involving this product, to protect against possible contamination with hydrofluoric acid. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Ensure suitable personal protection during the removal of spillages, for example: goggles, respiratory protection against organic vapours, rubber boots, gloves and apron. Ventilate area. Environmental precautions Do not allow spillages to enter drains, sewers, or watercourses. Methods and material for containment and cleaning up Adsorb spillages onto sand, earth or any suitable adsorbent material. Transfer to a container for disposal. Wash the spillage area with water. Washings must be prevented from entering surface water drains. Reference to other sections 8, 13 7. HANDLING AND STORAGE Precautions for safe handling Avoid contact with skin and eyes. Atmospheric concentrations should be minimised and kept as low as reasonably practicable below the occupational exposure limit. Provide adequate ventilation, including appropriate local extraction, if fumes or vapours are likely to be evolved. Avoid contact with naked flames and hot surfaces as corrosive and very toxic decomposition products can be formed. Conditions for safe storage, including any incompatibilities Keep container tightly closed and dry. Keep in a cool, well ventilated place. Specific use Solvent 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Appropriate engineering controls Personal protection equipment Atmospheric concentrations should be minimised and kept as low as reasonably practicable. Provide adequate ventilation, including appropriate local extraction, if fumes or vapours are likely to be evolved. Wear suitable gloves and eye/face protection. Contaminated clothing should be thoroughly cleaned before re-use. Wear suitable respiratory protective equipment if exposure to levels above the occupational exposure limit is likely. Respirators Where engineering controls are not fitted or inadequate wear suitable respiratory protective equipment. Where a cartridge/canister respirator is suitable use: Type A. Check with protective equipment manufacturer's data. Product Name ASAHIKLINTM AC-2000 Revision: CLP06 Date: 06/2021 Page: 2 of 5 Eye Protection Wear protective eyewear (goggles, face shield, or safety glasses). Gloves Impervious gloves (EN 374). Occupational Exposure Limits No Occupational Exposure Limit Assigned 9. PHYSICAL AND CHEMICAL PROPERTIES Form Colour. Odour Solubility (Water) Partition Coefficient (n-Octanol/water) Boiling Point ( C) Melting Point ( C) Vapour pressure (Pascal) Specific Gravity Kinematic Viscosity Flash Point (C) [Closed cup] Auto Ignition Point (C) Additional properties liquid colourless Ether-like. 1.5 mg/l @ 20C log Pow = 4.1 @ 35C 67 <-80 150000 @ 20C 1.68 @ 20C 0.51 mm2/s @ 20C; 0.39 mm2/s @ 40C Non-flammable. 590C Surface tension = 73.2 mN/m @ 20C 10. STABILITY AND REACTIVITY Chemical stability Stable under normal conditions. Possibility of hazardous reactions May react violently with oxidising agents, alkali metals, alkali earth metals. Conditions to avoid Heat and direct sunlight. Incompatible materials oxidising agents, akali metals, alkali earth metals, acids and alkalis Hazardous Decomposition Product(s) Thermal decomposition will evolve very toxic and corrosive vapours. (hydrogen fluoride and possibly carbonyl fluoride) 11. TOXICOLOGICAL INFORMATION Acute toxicity / Ingestion Acute toxicity / Inhalation Acute toxicity / Skin Contact Skin corrosion/irritation Serious eye damage/irritation Respiratory irritation Sensitisation Repeated dose toxicity Low acute toxicity. LD50 (mouse). >5000 mg/kg Low acute toxicity. LC50 (rat) >11,100 ppm (145.3 mg/l) No information available. Non-irritant (OECD 439) Non-irritant (OECD 437) No information available. It is not a skin sensitiser. (OECD 429 LLNA) In a 28-day repeated dose oral study in the rat, males administered 1000mg/kg b.w./day showed increased liver weights. The NOEL in this study was 200 mg/kg b.w./day. Product Name ASAHIKLINTM AC-2000 Revision: CLP06 Date: 06/2021 Page: 3 of 5 Mutagenicity Negative in in-vitro mutagenicity tests. Carcinogenicity No information available Reproductive toxicity No adverse reproductive or developmental effects were observed in rats administered 1000 mg/kg/day by the oral route. Specific target organ toxicity -- single exposure Not classified Specific target organ toxicity -- repeated exposure Not classified Aspiration hazard Not applicable 12. ECOLOGICAL INFORMATION Environmental Fate and Distribution Liquid with high volatility. Toxicity LC50 (48 hr) (Fish) (Oryzias latipes) > 125 mg/l EC50 (48 hr) (Daphnia magna) > 1.1 mg/l EC50 (72 hr) (Algae) (Psuedokirchneriella subcapita) > 0.098 mg/l Effect on Effluent Treatment Activated sludge respiration inhibition test: EC 50 (3hr) > 1000 mg/l Bioaccumulative potential Bioconcentration factor (BCF) : 293 - 658 in carp Mobility in soil The product has low mobility in soil. log Koc = 3.7. Results of PBT and vPvB assessment Not classified as PBT or vPvB. 13. DISPOSAL CONSIDERATIONS Regulatory information Disposal should be in accordance with local, state or national legislation. Waste code : 14 06 03 Waste treatment methods Incinerate under approved controlled conditions, using incinerators suitable for the disposal of noxious chemical waste. Decontaminate empty containers before recycling. 14. TRANSPORT INFORMATION Not classified as dangerous for transport. 15. REGULATORY INFORMATION European Regulations Special Restrictions: None known Chemical Safety Assessment A Chemical Safety Assessment has been completed for this substance. 16. OTHER INFORMATION This data sheet was prepared in accordance with Regulation (EC) No. 1907/2006 & UK REACH. The following sections contain revisions or new statements: 1,11,15 Product Name ASAHIKLINTM AC-2000 Revision: CLP06 Date: 06/2021 Page: 4 of 5 This product is not designed for special applications such as pharmaceutical or medical use. For other technical information, contact the address in Section 1. Information in this publication is believed to be accurate and is given in good faith, but it is for the Customer to satisfy itself of the suitability for its own particular purpose. Accordingly, AGC Chemicals Europe, Ltd. gives no warranty as to the fitness of the Product for any particular purpose and any implied warranty or condition (statutory or otherwise) is excluded except to the extent that such exclusion is prevented by law. Freedom under Patent, Copyright and Designs cannot be assumed. Any trademarks herein identified are trademarks of AGC Inc. - * GLOSSARY UK REACH: The REACH etc. (Amendment etc.) (EU Exit) Regulations 2020 UK CLP: Retained CLP Regulation (EU) No. 1272/2008 as amended for Great Britain WEL: Workplace Exposure Limit (UK HSE EH40) COM: The company aims to control exposure in its workplace to this limit TLV: The company aims to control exposure in its workplace to the ACGIH limit TLV-C: The company aims to control exposure in its workplace to the ACGIH Ceiling limit MAK: The company aims to control exposure in its workplace to the German limit Sk: Can be absorbed through skin Sen: Capable of causing respiratory sensitisation Bmgv: Biological monitoring guidance value (UK HSE EH40) Product Name ASAHIKLINTM AC-2000 Revision: CLP06 Date: 06/2021 Page: 5 of 5