Document 2QVexdBELDzJ2nmobYk4Xydp

MATERIAL SAFETY DATA SHEET Ashland ASHLAND CHEMICAL, INC. Subsitfitry oi o>i. Inc P.O. BOX 2219 COLUMBUS, OHIO 43216 (614) 889-3333 24-HOUR Emergency Telephone 1(800) 274-5263 or 1(800) ASHLAND 001683 ACETONE G S 0 03 THIS MSDS COMPLIES WITH 29 CFR 1910.1200 (THE HAZARD COAMJNICATION STANDARD) ' t Page: 1 Product Name: ACETONE General or Generic ID: KETONE DOT Hazard Classification: FLAhWABLE LIQUID (173.115) SECTI IF PRESENT, I ARC, NTP AND OSHA CARCINOGENS AND CHEMICALS SUBJECT TO THE REPORT ING REQUIREMENTS OF SARA TITLE III SECTION 313 ARE IDENTIFIED IN THIS SECTION. SEE DEFINITION PAGE FOR CLARIFICATION INWEOIENT % (by WT) PEL TLV ACETONE CAS #: 67-64-1 100 750 PPM 750 PPM Note (D Notes: ( 1) OSHA/ACGIH SHORT TERM EXPOSURE LIMIT (STEL) FOR ACETONE IS 1000 PPM. NIOSH RECOMMENDS A LIMIT OF 250 PPM. 8-HOUR TWA. THIS CHEMICAL IS SUBJECT TO TT-C REPORTING REQUIREMENTS OF SECTION 313 OF SARA TITLE III. SECTI ON Ill-PHYSICAL DATA Boiling Point for PRODUCT 133.00 Deg F 56.11 Deg C) 760.00 m Hg Vapor Pressure for PRODUCT 181.70 mm Hg t $8.00 Deg F 20.00 Deg C) Specific Vapor Density AIR = 1 2.0 Specific Gravity Percent Volatiles .785 - .788 77.00 Deg F ( 25.00 Oeg C) 100.00% Evaporation Rate (N-BUTYL ACETATE = 1) 14.40 FLASH POINT(TCC ) < -1.0 Oeg F ( -18.3 Deg C) EXPLOSIVE LIMIT (PRODUCT) LOWER - 2.6% UPPER - 12.8% EXTINGUISHING MEDIA: ALCOHOL FOAM OR CARBON OIOXIDE OR DRY CHEMICAL HAZARDOUS DECOMPOSITION PRODUCTS: MAY FORM TOXIC MATERIALS:. CARBON OIOXIDE ANO CARSON MONOXIDE, VARIOUS HYDROCARBONS, ETC. FIREFIGHTING PROCEDURES: WEAR SELF-CONTAINED BREATHING APPARATUS WITH A FULL FACEPIECE OPERATED IN THE POSITIVE PRESSURE DEMAND MODE WHEN FIGHTING FIRES. SPECIAL FIRE & EXPLOSION HAZARDS: MATERIAL IS HIGHLY VOLATILE AND READILY GIVES OFF VAPORS WHICH MAY TRAVEL ALONG THE GROUND OR BE MOVED BY VENTILATION ANO IGNITED BY PILOT LIGHTS, OTHER FLAMES, SPARKS, HEATERS, SMOKING, ELECTRIC MOTORS, STATIC DISCHARGE, OR OTHER IGNITION SOURCES AT LOCATIONS DISTANT FROM MATERIAL HANDLING POINT. NEVER USE WELDING OR CUTTING TORCH ON OR NEAR DRUM (EVEN EMPTY) BECAUSE PRODUCT (EVEN JUST RESIDUE) CAN IGNITE EXPLOSIVELY. ALL FIVE GALLON PAILS AND LARGER METAL CONTAINERS INCLUDING TANK CARS AND TANK TRUCKS SHOULD BE GROUNDED and/or bonded when material is transferred. NFPA COOES: HEALTH- 1 FLAWMABILITY- 3 REACTIVITY- 0 ea PERMISSIBLE EXPOSURE LEVEL 750 ehlmmj PPM "HRESHOLD LIMIT VALUE 750 PPM SEE SECTION II S*L 000009463 COPYRIGHT 1989 CONTINUED ON PAGE: 2 MATERIAL SAFETY DATA SHEET Ashland 001683 C S 0 0 8 ASHLAND CHEMICAL, INC. Sabti4i*ry 01 ArtlirU Oil. Inc P.O. BOX 2219 COLUMBUS, OHIO 43216 (614) 889-3333 ACETONE 24-HOUR Emergency Telephone 1(800) 274-5263 or 1(800) ASHLAND Page: 2 EFFECTS OF ACUTE OVEREXPOSURE: FOR PROOUCT EVES * CAUSES IRRITATION, REDNESS, TEARING. SKIN - CAN CAUSE SLIGHT IRRITATION. BREATHING - EXCESSIVE INHALATION OF VAPORS CAN CAUSE NASAL ANO RESPIRATORY IRRITATION, CENTRAL NERVOUS SYSTEM EFFECTS INCLUDING DIZZINESS, WEAKNESS, FATIGUE, NAUSEA. HEADAOE AND POSSIBLE UNCONSCIOUSNESS, AND EVEN DEATH. SWALLOWING - CAN CAUSE GASTROINTESTINAL IRRITATION. NAUSEA, VOMITING. ANO DIARRHEA. FIRST AID: IF ON SKIN: THOROUGHLY WASH EXPOSED AREA WITH SOAP AND WATER. RBAOVE CONTAMINATED CLOTHING. LAUNDER CONTAMINATED CLOTHING BEFORE RE-USE. IF IN EYES: FLUSH WITH LARGE AMOUNTS OF WATER, LIFTING UPPER ANO LOWER LIDS OCCASIONALLY, GET MEDICAL ATTENTION. IF SWALLOWED: IMMEDIATELY DRINK TWO GLASSES OF WATER AND INDUCE VOMITING BY EITHER GIVING IPECAC SYRUP OR BY PLACING FINGER AT BACK OF 7HJOAT. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. GET MEDICAL ATTENTION IMMEDIATELY. IF BREATHED: IF AFFECTEO, REMOVE INDIVIDUAL TO FRESH AIR. IF BREATHING 1$ DIFFICULT, ADMINISTER OXYGEN. IF BREATHING HAS STOPPED GIVE ARTIFICIAL RESPIRATION. KEEP PERSON NARM, QUIET ANO GET MEDICAL ATTENTION. PRIMARY ROUTE(S) OF ENTRY: INHALATION. SKIN CONTACT EFFECTS OF CHRONIC OVEREXPOSURE: FOR PROOUCT OVEREXPOSURE TO THIS MATERIAL (OR ITS COMPONENTS) HAS APPARENTLY BEEN FOUND TO CAUSE THE FOLLOWING EFFECTS IN LABORATORY ANIMALS:, KIDNEY DAMAGE. EVE DAMAGE HAZARDOUS POLYMERIZATION: CANNOT OCCUR STABILITY; STABLE INCOMPATIBILITY: AVOID CONTACT WITH:, STRONG OXIDIZING AGENTS., STRONG ALKALIES.. STRONG MINERAL ACIDS. mm STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: SMALL SPILL: ABSORB LIQUID ON PAPER, VERMICULITE, FLOOR ABSORBENT, OR OTHER ABSORBENT MATERIAL AND TRANSFER TO HOOO. LARGE SPILL: ELIMINATE ALL IGNITION SOURCES (FLARES. FLAMES INCLUDING PILOT LIGHTS, ELECTRICAL SPARKS). PERSONS NOT WEARING PROTECTIVE EQUIPMENT SHOULD BE EXCLUDED FROM AREA OF SPILL UNTIL 6.EAN-UP HAS BEEN COMPLETED. STOP SPILL AT SOURCE, DIKE AREA OF SPILL TO PREVENT SPREADING, PUMP LIQUID TO SALVAGE TANK. REMAINING LIQUID MAY BE TAKEN UP ON SAND, CLAY. EARTH, FLOOR ABSORBENT, OR OTTER ABSORBENT MATERIAL AND SHOVELED INTO CONTAINERS. WASTE DISPOSAL ME7HOO: SMALL SPILL: DISPOSE OF IN ACCORDANCE WITH ALL LOCAL, STATE AND FEDERAL REGULATIONS. URGE SPILL: DISPOSE OF IN ACCORDANCE WITH ALL LOCAL, STATE AND FEDERAL REGULATIONS. RESPIRATORY PROTECTION: IF WORKPUCE EXPOSURE LIMIT(S) OF PROOUCT OR ANY COMPONENT IS EXCEEDED (SEE SECTION II). A NIOSH/MSHA APPROVED AIR SUPPLIED RESPIRATOR IS ADVISED IN ABSENCE OF PROPER ENVIRONMENTAL CONTROL. OSHA REGULATIONS ALSO PERMIT OTHER NIOSH/MSHA RESPIRATORS (NEGATIVE PRESSURE TYPE) UNDER SPECIFIED CONDITIONS (SEE YOUR SAFETY EQUIPMENT SUPPLIER). ENGINEERING OR ADMINISTRATIVE CONTROLS SHOULD BE IMPLEMENTED TO REDUCE EXPOSURE. VENTILATION: PROVIDE SUFFICIENT MECHANICAL (GENERAL AND/OR LOCAL EXHAUST) VENTIUTION TO MAINTAIN EXPOSURE BELOW TLV(S). PROTECTIVE GLOVES: WEAR RESISTANT GLOVES SUCH AS:. NATURAL RUBBS?, NEOPRENE. NITRILE RUBBER EYE PROTECTION: CHEMICAL SPUSH GOGGLES IN COMPLIANCE WITH OSHA REGULATIONS ARE ADVISED: HOWEVER. 03HA REGULATIONS ALSO PERMIT OTHER TYPE SAFETY GLASSES. (CONSULT YOUR SAFETY EQUIPMENT SUPPLIER) OTHER PROTECTIVE EQUIPMENT: TO PREVENT REPEATED OR PROLONGEO SKIN CONTACT, WEAR IMPERVIOUS CLOTHING AND BOOTS. OR OTHER [;K1IS CONTAINERS OF THIS MATERIAL MAY BE HAZARDOUS WHEN EMPTIED.SINCE EMPTIED CONTAINERS RETAIN PROOUCT RESIDUES (VAPOR, LIQUID. AND/OR SOLID). ALL HAZARD PRECAUTIONS GIVEN IN THE DATA SHEET MUST BE OBSERVED. THE INFORMATION ACCUMUUTEO FfcREIN IS BELIEVED TO BE ACCURATE BUT IS NOT WARRANTED TO BE WHETHER ORIGINATING WITH THE COMPANY OR NOT. RECIPIENTS ARE ADVISED TO CONFIRM IN ADVANCE OF NEED THAT THE INFORMATION IS CURRENT, APPLICABLE, AND SUITABLE TO THEIR CIRCUMSTANCES. SAL 000009464 COPYRIGHT 1989 LAST PAGE--SEE ATTACHMENT PAGE ENCLOSED--LAST PAGE G S 0 t)3 MATERIAL SAFETY DATA SHEET Ashland ASHLAND CHEMICAL, INC Subsidiary of Asbalod Oil. Inc. P.0. BOX 2219 COLUMBUS, OHIO 43216 (614) 889-3333 24-HOUR Emergency Telephone 1(800) 274-5263 or 1 (800) ASHLAND DEFINITIONS ft S 0 0 8 This definition page is intended for use with Material Safety Data Sheets supplied by the Ashland Chemical Company. Recipients of these data sheets should consult the OSHA Safety and Health Standards (29 CFR 1910), particularly subpart G - Occupational Health and Environmental Control, and subpart I - Personal Protective Equipment, for general guidance on control of potential Occupational Health and Safety Hazards. SECTION I PRODUCT IDENTIFICATION GENERAL OR GENERIC ID: Chemical family or product description. DOT HAZARD CLASSIFICATION: Product meets DOT criteria for hazards listed. SECTION II COMPONENTS SECTION IV (cnnt.) EXTINGUISHING MEDIA: Following National Fire Protection Association criteria. FIREFIGHTING PROCEDURES: Minimum equipment to protect firefighters from toxic products of vaporization, combustion or decomposition in fire situations. Other firefighting hazards may also be indicated. SPECIAL FIRE AND EXPLOSION HAZARDS: Slates hazards not covered by other sections. Components are listed in this section if they present a physical or health hazard and are present at or above 1% in the mixture. If a component is identified as a CARCINOGEN by NTP. (ARC. or OSHA as of the date on the MSDS, it will be listed and footnoted in this section when present at or above 0.1% in the product. Negative conclusions concerning carcinogenicity are not reported. Additional health information may be found m Section V. Components subject to the reporting requirements of Section 313 of SARA Title III are identified in the footnotes in this section, along with typical percentages. Other components may be listed if deemed appropriate. Exposure recommendations are for components. OSHA Permissible Exposure Limits (PELS) and American Conference of Governmental Industrial Hygienists (ACGIH) Threshold Limit Values (TLVs) appear on the line with the component identification. Other recommendations appear as footnotes. NFPA CODES: Hazard ratings assigned by the National Fire Protection Association. SECTION V HEALTH HAZARD DATA PERMISSIBLE EXPOSURE LIMIT: For product THRESHOLD LIMIT VALUE: For product. EFFECTS OF ACUTE OVEREXPOSURE: Potential local and systemic effects due to single or short term overexposure to the eyes and skin or through inhalation or ingestion. EFFECTS OF CHRONIC OVEREXPOSURE: Potential local and systemic effects due to repeated or long term overexposure to the eyes and skin or through inhalation or ingestion. FIRST AID: Procedures to be followed when dealing with accidental overexposure. SECTION III BOILING POINT: Of product if known. The lowest value of the components is listed for mixtures. VAPOR PRESSURE: Of product if known. The highest value of the components is listed for mixtures. SPECIFIC VAPOR DENSITY: Compared to AIR = 1. If the Specific Vapor Density of a product is not known, the value is expressed as lighter or greater than air. SPECIFIC GRAVITY: Compared to WATER = V If Specific Gravity of product is not known, the value is expressed as less than or greater than water. pH: If applicable. PERCENT VOLATILES: Percentage of material with initial boiling point below 425 degrees Fahrenheit and vapor pressure above 0.1mm Hg at 68 F. EVAPORATION RATE: Indicated as faster or slower than ETHYL ETHER, unless otherwise stated. SECTION IV FIRE AND EXPLOSION DATA FLASH POINT: Method identified. EXPLOSION LIMITS: For product if known. The lowset value of the components is listed for mixtures. HAZARDOUS DECOMPOSITION PRODUCTS: Known or expected hazardous products resulting from heating, burning or other reactions. PRIMARY ROUTE OF ENTRY: Based on properties and expected use. SECTION VI REACTIVITY DATA HAZARDOUS POLYMERIZATION: Conditions to avoid to prevent hazardous polymerization resulting in a large release of energy. STABILITY: Conditions to avoid to prevent hazardous or violent decomposition. INCOMPATIBILITY: Materials and conditions to avoid to prevent hazardous reactions. SECTION VII SPILL OR LEAK PROCEDURES Reasonable precautions to be taken and methods of containment, clean-up and disposal. Consult federal, state and local regulations for accepted procedures and any reporting or notification requirements. SECTION VIII PROTECTIVE EQUIPMENT TO BE USED Protective equipment which may be needed when handling the product. SECTION IX SPECIAL PRECAUTIONS OR OTHER COMMENTS Covers any relevant points not previously mentioned. ADDITIONAL COMMENTS Containers should be either reconditioned by CERTIFIED firms or properly disposed of by APPROVED firms. Disposal of containers should be in accordance with applicable laws and regulations. "EMPTY" drums should not be given to individuals Serious accidents have resulted from the misuse of "EMPTIED" containers (drums.pa'is.etc.). Refer to Sections IV and IX. SAL 000009465