Document 2Nz8v4qbqv24pdeknkmKBvy7N

Information of PFAS and PFAS present in mixtures and articles Identity and quantity Please fill in the following table in the columns relevant to you with the respective information concerning your PFAS/prec Please assign quantities individually to each PFAS and PFAS in mixtures and/or articles. Please use one line for each individual substance and, if necessary, with multiple entries in one data field. If not, use multip # Chemical name Trade name(s) CAS No. 1 1,1,1,2-tetrafluoroethane Norflurane, R-134a, HFC-134a, Klea, 811-97-2 Zephex, Genetron, Forane, Freon, Daikin Note that mixtures of HFCs and HFOs may use these trade brand names or those that are used for HFOs 2 difluoromethane R-32, HFC-32, Klea, Genetron, Forane, Freon,Daikin 75-10-5 3 trifluoromethane R-23, HFC-23 75-46-7 4 pentafluoroethane R-125, HFC-125, Klea, Genetron, Forane, Freon,Daikin 354-33-6 5 1,1,1-trifluoroethane R-143a, HFC-143a, 420-46-2 6 1,1-difluoroethane R-152a, HFC-152a 75-37-6 7 1,1,1,2,3,3,3-heptafluoropropane R-227ea, HFC-227ea 431-89-0 8 1,1,1,3,3,3-hexafluoropropane R-236fa, HFC-236fa 690-39-1 9 1,1,1,3,3-pentafluoropropane R-245fa, HFC-245fa, Enovate 460-73-1 10 1,1,1,3,3-pentafluorobutane R-365mfc, HFC-365mfc, Solkane 406-58-6 11 1,1,1,2,2,3,4,5,5,5- decafluoropentane HFC-43-10mee, Vertrel 138495-42-8 12 2,3,3,3- tetrafluoroprop-1-ene R-1234yf, HFC-1234yf, Solstice, Opteon 754-12-1 13 Trans-1,3,3,3-tetrafluoroprop-1-ene R-1234ze(E), HFO-1234ze(E) , Solstice 29118-24-9 14 Cis-1,1,1,4,4,4-hexafluorobut-2-ene R-1336mzz(Z), HFO-1336mzz(Z), 692-49-9 Opteon 15 Trans-1,1,1,4,4,4-hexafluorobut-2- R- 1336mzz(E), HFO- 1336mzz(E ), 66711-86-2 ene Opteon 16 Trans 1-Chloro-3,3,3- trifluoroprop-1-ene R-1233zd(E) ,HCFO-1233zd(E), Solstice, Forane, 2730-43-0 17 chlorodifluoromethane R-22, HCFC-22 75-45-6 18 1-chloro-1,1 - difluoro-ethane R-142b, HCFC-142b 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 75-68-3 concerning your PFAS/precursor/perfluorinated precursor. data field. If not, use multiple lines for each individual substance, linked with a clear identification, such as CAS No., etc. EC No. Mixture Polyfluorinated precursors/polymers 212-377-0 Please indicate. Where indicated HFCs and no HFOs may be used in refrigerant mixtures.A spreadsheet attached separately shows all the known mixtures that may be used as refrigerants in the EU subject to restrictions under the F-Gas Regulation 517/2014. The EEA Report EEA Report No 20/2019 Fluorinated Greenhouse Gases 2019 provides data on supply of individual substances. Used in refrigerant mixtures 200-839-4 Used in refrigerant no mixtures 200-872-4 Used in refrigerant mixtures as well as use as refrigerant the substance is used as a feedstock to manufacture bromotrifluoromethane which is currently used as a feedstock for the manufacture of the pesticide fipronil 206-557-8 Used in refrigerant no mixtures 206-996-5 Used in refrigerant no mixtures 200-866-1 Proprietary mixtures may be used as blowing agents for insulation foams. Used in refrigerant mixtures Dehydrofluorination of 1,1difluoroethane (HFC-152a) is the most broadly used chemical process for the production of vinyl fluoride (used to produce polyvinylfluoride, however the quantity reported in by the EEA would not include any substance used for feedstock 207-079-2 Used in refrigerant no mixtures 425-320-1 Used in refrigerant no mixtures 419-170-6 Proprietary mixtures may no be used as blowing agents for insulation foams 430-250-1 Proprietary mixtures may no be used as blowing agents for insulation foams 420-640-8 Proprietary mixtures may no be used as solvents 468-710-7 Used in refrigerant no mixtures 810-135-4 As well as use as a no refrigerant, proprietary mixtures may be used as blowing agents for insulation foams. Used in refrigerant mixtures 700-651-7 As well as use as a working no fluid, proprietary mixtures may be used as blowing agents for insulation foams. Used in refrigerant mixtures 811-213-0 As well as use as a working no fluid, proprietary mixtures may be used as blowing agents for insulation foams 688-906-8 Proprietary mixtures may no be used as blowing agents for insulation foams 200-871-9 no 200-891-8 no production of tetrafluoroethylene, a monomer, or hexafluoropropene, a monomer. Hexafluropropene (HFP) can be used to produce hexafluoropropylene oxide, a monomer. HFP is also used to produce 1,1,1,2,3,3,3heptafluoropropane production of vinylidene fluoride, a monomer. Vinylidene fluoride HFO1132ais also used as a refrigerant ar identification, such as CAS No., etc. Production process of PFAS, Production process of PFAS- PFAS-containing mixture containing article Electrochemically or by other methods other methods REACH definitions of articles used throughout. The only relevant articles would be finished insulation foams for all substances listed. Some substances have never been used in foams, and some are no longer used due to the F-Gas Regulation 517/2014 HFC-134a is unlikely to be used alone or in mixtures in articles. other methods no other methods no other methods no other methods no other methods yes other methods no other methods no other methods no other methods no other methods no other methods no other methods yes other methods yes other methods yes other methods yes other methods no other methods no Production process of polymers, fluorescins or other complex perluorated compounds not applicable NIAS (e.g. oligomers or impurities) Purity is typically > 99.8%. Main Impurity 1,1,2,2-tetrafluoroethane EC no.: 206-628-3. Very minor impurities are substances of similar boiling points from the production process. not applicable Purity is typically > 99.8%. Minor impurities are substances of similar boiling points from the production process. trifluoromethane is brominated with Purity is typically > 99.8%. Minor impurities bromine. According to the REACH are substances of similar boiling points from Registration Dossier on the ECHA website the production process as well as https://echa.europa.eu/sv/registration- chlorodifluoromethane. dossier/-/registered-dossier/10495/1 bromotrifluoromethane is manufactured and/or imported in the European Economic Area for industrial use resulting in the manufacture of another substance (use of intermediates) for fine chemicals production. Fipronil contains a CF3 group not applicable Purity is typically > 99.8%. Minor impurities are substances of similar boiling points from the production process. not applicable Purity is typically > 99.8%. Minor impurities are substances of similar boiling points from the production process. dehydrofluorinated to vinyl fluoride, a monomer Purity is typically > 99.8%. Minor impurities are substances of similar boiling points from the production process. no Purity is typically > 99.8%. Minor impurities are substances of similar boiling points from the production process. no Purity is typically > 99.8%. Minor impurities are substances of similar boiling points from the production process. no Purity is typically > 99.8%. Minor impurities are substances of similar boiling points from the production process. no Purity is typically > 99.8%. Minor impurities are substances of similar boiling points from the production process. may be used as a solvent carrier forfluorocarbon lubricant or adhesive Purity is typically > 99.8%. Minor impurities are substances of similar boiling points from the production process. no Purity is typically > 99.8%. Minor impurities are substances of similar boiling points from the production process. no Purity is typically > 99.8%. Minor impurities are substances of similar boiling points from the production process. no Purity is typically > 99.8%. Minor impurities are substances of similar boiling points from the production process. no Purity is typically > 99.8%. Minor impurities are substances of similar boiling points from the production process. no Purity is typically > 99.8%. Minor impurities are substances of similar boiling points from the production process. pyrolysis of chlorodifluoromethane at Purity is typically > 99.8%. Minor impurities about 650C to give TFE and HCl, followed are substances of similar boiling points from by polymerisation or copolymerisation. the production process. Depending on reaction conditions hexafluoropropene (HFP) can be produced, which can be copolymerised. HFP can be reacted with an oxygen donor to give hexafluoropropylene oxide, a monomer used in oligomerisation and polymerisation. The substance is used as a feedstock to produce vinylidene fluoride (1,1difluoroethene) which is polymerised to to poly-vinylidene fluoride or copolymers. Purity is typically > 99.8%. Minor impurities are substances of similar boiling points from the production process. Exposure-related questions Generation and/or use e of any relevant fluorinated substance including e.g. volatile substances during production that could be released to environment Tonnage range production or import of PFAS and/or PFAS containing mixtures per year do we need to add specifics for any substances that are produced in the EU. In the EU all emissions from chemical complexes are required to be reported and are available at the European Pollutant Release and Transfer Register (E-PRTR) Chlorinated substances are feedstocks used for its manufacture. As the product is a low boiling point substance productionn is in closed systems on chemical plant complexes, with abatement measures to minimise emissions. There are several possible processes for its manufacture. The main commercial processes include: hydro-fluorination of trichloroethylene, via 1chloro-2,2,2-trifluoroethane; isomerisation/hydro-fluorination of 1,1,2- trichloro-1,2,2-trifluoroethane to 1,1, dichloro-1,2,2,2 tetrafluoroethane followed by hydro-dechlorination of the latter; hydro-fluorination of tetrachloroethylene to 1 chloro-1,2,2,2 tetrafluoroethane and subsequent hydro-dechlorination to 1,1,1,2tetrafluoroethane. Data for HFCs, HFOs and HCFOs is from 2018 from EEA Report EEA Report No 20/2019 Fluorinated Greenhouse Gases 2019 and is the total EU supply. Data is for 2018 unless stated. The supply total excludes Feedstock use. Information on feedstock use, if available is included. 32543 tonnes Difluoromethane is produced from dichloromethane by fluorination. As the product is a low boiling point substance production is in closed systems on chemical plant complexes, with abatement measures to minimise emissions. 14647 tonnes Trifluoromethane is produced as a by-product 54 tonnes for use as refrigerant. It is during the production of thought that significantly less than chlorodifluromethane. In the EU, any 1000 tonnes of trifluoromethane or trifluoromethane not required for use as a bromotrifluoromethane are used for feedstock or refrigerant is destroyed on site by the manufacture of fipronil thermal oxidation. Difluoromethane is produced from dichloromethane by fluorination. As the product is a low boiling point substance production is in closed systems on chemical plant complexes, with abatement measures to minimise emissions. 12938 tonnes 1,1,1-trifluoroethane is produced from 1,1dichloro-1-fluoro- ethane by fluorination. As the product is a low boiling point substance production is in closed systems on chemical plant complexes, with abatement measures to minimise emissions. 1,1-dichloro-1-fluoroethane is produced from 1,1,1-trichloroethane Total EU Supply 2017, 6006 tonnes, the supply in 2018 is listed as confidential 1,1-dichloroethane is fluorinated to produce the substance.As the product is a low boiling point substance production is in closed systems on chemical plant complexes, with abatement measures to minimise emissions 3245 tonnes The substance is produced from 1387 tonnes hexafluoropropene by reaction with HF. As the product is a low boiling point substance production is in closed systems on chemical plant complexes, with abatement measures to minimise emissions. The feedstock is a chlorinated propane, which 18 tonnes is fluorinated to produce the substance. As the product is a low boiling point substance production is in closed systems on chemical plant complexes, with abatement measures to minimise emissions. The feedstock is a chlorinated propane, which supply for all years listed as is fluorinated to produce the substance. As the confidential product is a low boiling point substance production is in closed systems on chemical plant complexes, with abatement measures to minimise emissions. The feedstock is a chlorinated butane, which supply for all years listed as is fluorinated to produce the substance. As the confidential product is a low boiling point substance production is in closed systems on chemical plant complexes, with abatement measures to minimise emissions. supply for all years listed as confidential except 2009 at 50 tonnes The feedstock is a chlorinated propene, which 11437 tonnes is fluorinated to produce the substance. As the product is a low boiling point substance production is in closed systems on chemical plant complexes, with abatement measures to minimise emissions.. The feedstock is a chlorinated propene, which supply for all years listed as is fluorinated to produce the substance. As the confidential Total HFOs and HCFOs product is a low boiling point substance 17750 tonnes production is in closed systems on chemical plant complexes, with abatement measures to minimise emissions. tetrachloroethene is used as a feedstock to supply for all years listed as produce -1,1,1,4,4,4-hexafluorobut-2-ene confidential Total HFOs and HCFOs isomers, with trichlorotrrifluoroethane isomers 17750 tonnes as intermediates.As the product is a low boiling point substance production is in closed systems on chemical plant complexes, with abatement measures to minimise emissions. tetrachloroethene is used as a feedstock to supply for all years listed as produce -1,1,1,4,4,4-hexafluorobut-2-ene confidential Total HFOs and HCFOs isomers, with trichlorotrrifluoroethane isomers 17750 tonnes as intermediates.As the product is a low boiling point substance production is in closed systems on chemical plant complexes, with abatement measures to minimise emissions. The feedstock is a chlorinated propene, which supply for all years listed as is fluorinated to produce the substance. As the confidential Total HFOs and HCFOs product is a low boiling point substance 17750 tonnes production is in closed systems on chemical plant complexes, with abatement measures to minimise emissions. Chlorodifluoromethane (HCFC-22) is produced by the reaction of chloroform (CHCl3) and hydrogen fluoride (HF) in the presence of antimony pentachloride (SbCl 5 ) catalyst. Trifluoromethane is the major by-product and ius either destroyed or used as a feedstock of refrigerant. The EU reports its emissions of HFC-23, as part of its Annual greenhouse gas inventory submission to the unfccc . From this, in 2017 the EU reported over 98% reduction in emissions compared to 1990, due to the adoption of abatement technology.. Data for HCFCs is from EEA Report 12/2019 Ozone Depelting Substances 2019. Total 2018 production of HCFCs in the EU was 129594 tonnes and imports of 4968 tonnes. EEA does not break down the data further but for production HCFC-22 (chlorodifluoromethane) and HCFC 142b (1-chloro-1,1 - difluoro-ethane) are thought to account for the vast majority of the total, with HCFC-22 being the major substance. Both are used as feedstocks. 1-chloro-1,1 - difluoro-ethane is produced from 1,1,1,-trichloroethane by reaction with HF in the liquid phase. 1,1-dichloro-1fluoroethane is an intermediate. see answer for HCFC-22 Exposure-related questions Tonnage range of PFAS Tonnage range production of Number of workers involved in handling at company or incorporated in articles per year PFAS containing article per year customer sites REACH definitions of articles used throughout. Expected to be zero. The substance is not incorporated in articles, but is used in articles. It is assumed that this relates to the use of the substance in eg airconditioners, refrigeration systems or MDIs and the question is answered throughout on this basis. It is expected that all the reported supply will be used in articles. Assume the production text only apply to substances produced in the EU. 5 companies reported production of HFCs in the EU-please check. It is used by professional workers (widespread uses), in formulation or re-packing, at industrial sites and in manufacturing. Handled on chemical sites for its production and industrial sites used in closed systems to transfer into mixtures, repackaging, refrigeration, air-conditioning and heat pump equipment, MDIs and similar. Handled widely by professional and technical staff for servicing and maintenance of refrigeration, air-conditioning and heat pump equipment. In total of the order of 100,000 workers Expected to be zero. Expected to be zero. Expected to be zero. It is expected that all the reported supply will be used in articles. It is used by professional workers (widespread uses), in formulation or re-packing, or destruction at industrial sites and in manufacturing.Handled on chemical sites for its production and industrial sites used in closed systems to transfer into mixtures, repackaging, refrigeration, air-conditioning and heat pump equipment and similar. Handled widely by professional and technical staff for servicing and maintenance of refrigeration, airconditioning and heat pump equipment. In total of the order of 100,000 workers It is expected that all the reported supply will be used in articles. It is used by professional workers (widespread uses), in formulation or re-packing, at industrial sites and in manufacturing. Handled on chemical sites for its production and industrial sites used in closed systems as a feedstock, to transfer into mixtures, repackaging, low temperature refrigeration. Handled widely by professional and technical staff for servicing and maintenance of refrigeration. In total of the order of 5,000 workers It is expected that all the reported supply will be used in articles. It is used by professional workers (widespread uses), in formulation or re-packing, at industrial sites and in manufacturing. Handled on chemical sites for its production and industrial sites used in closed systems to transfer into mixtures, repackaging, refrigeration, air-conditioning and heat pump equipment and similar, or for destruction. Handled widely by professional and technical staff for servicing and maintenance of refrigeration, air-conditioning and heat pump equipment. In total of the order of 100,000 workers REACH definitions of articles used throughout. Expected to be zero. The substance is not incorporated in articles, but is currently used in articles. However as the major use of 1,1,1trifluoroethane is for Refrigerant R404A and this is subject to use restrictions in the EU under tghe F-Gas Regulation, it is expected that its supply will continue to decrease very qucikly in the next few years It is expected that all the reported supply will be used in articles. It is used by professional workers (widespread uses), in formulation or re-packing, at industrial sites and in manufacturing. Handled on chemical sites for its production and industrial sites used in closed systems to transfer into mixtures, repackaging, refrigeration equipment and similar, or for destruction. Handled widely by professional and technical staff for servicing and maintenance of refrigeration, air-conditioning and heat pump equipment. In total of the order of 100,000 workers The F-Gas Regulation 517/2014 bans the use of HFCs or HFC blends with a GWP >150 in the manufacture of all foams by 1 January 2023 and for extruded polystyrene (XPS) from 1 January 2020. As the substance has a GWP less than 150 it could be used in extruded polystyrene foam production alone or in a mixture. The quantity is not known but would be included in the EEA reported quantity. According to the F-gas Regulation, the substance can be used in technical aerosols as it has a GWP less than 150. It may be used alone or in mixtures. It is not widely used in RAC applications. It is used by professional workers (widespread uses), in formulation or re-packing, at industrial sites and in manufacturing. Handled on industrial sites used in closed systems to transfer into mixtures, repackaging, technical aerosols, for production of XPS foam and similar, or for destruction. In total of the order of 5,000 workers The F-Gas Regulation 517/2014 bans the use of HFCs or HFC blends with a GWP >150 in the manufacture of all Used in MDIs, fire extinguishers, and some refrigeration equipment foams by 1 January 2023. Until then the substance can be used as a foam blowing agent It is used by professional workers (widespread uses), in formulation or re-packing, at industrial sites and in manufacturing. Handled on industrial sites used in closed systems to transfer into mixtures, repackaging, MDIs,fire extinguishers, for production of PU foams , or for destruction. In total of the order of 5,000 workers expected to be zero expected to be for fire extinguishers It is used by professional workers (widespread uses), in formulation or re-packing, at industrial sites and in manufacturing. Handled on industrial sites used in closed systems to transfer into mixtures, repackaging, ,fire extinguishers, In total of the order of less than 1.000 workers The F-Gas Regulation 517/2014 bans the use of HFCs or HFC blends with a GWP >150 in the manufacture of all foams by 1 January 2023. Until then the substance can be used as a foam blowing agent. The quantitiy is not known The substance is used as a refrigerant and as a working fluid for Organic Rankine Cycle systems It is used by professional workers (widespread uses), in formulation or re-packing, at industrial sites and in manufacturing. Handled on chemical site for its production and industrial sites used in closed systems to transfer into mixtures, repackaging, for production of PU foams , or for destruction. In total of the order of 5,000 workers The F-Gas Regulation 517/2014 bans the use of HFCs or HFC blends with a GWP >150 in the manufacture of all foams by 1 January 2023. Until then the substance can be used as a foam blowing agent. The quantitiy is not known The substance is used as a working fluid for Organic Rankine Cycle systems It is used by professional workers (widespread uses), in formulation or re-packing, at industrial sites and in manufacturing. Handled on industrial sites used in closed systems to transfer into mixtures, repackaging, for production of PU foams , or for destruction. In total of the order of 5,000 workers expected to be zero expected to be zero It is used by professional workers (widespread uses), in formulation or re-packing, at industrial sites and in manufacturing. Handled on industrial sites Used in co-solvent systems and vapor degreasing equipment for cleaning, rinsing, and drying. In total of the order of 5,000 workers expected to be zero expected to be 11437 tonnes It is used by professional workers (widespread uses), in formulation or re-packing, or destruction at industrial sites and in manufacturing. Handled on industrial sites used in closed systems to transfer into mixtures, repackaging, refrigeration, air-conditioning and heat pump equipment and similar. Handled widely by professional and technical staff for servicing and maintenance of refrigeration, air-conditioning and heat pump equipment. In total of the order of 100,000 workers Used as a foam blowing agent, mainly for PU foam but can be used for XPS. Quantity not known Quantity used as a refrigerant is not known. It is used by professional workers (widespread uses), in formulation or re-packing, at industrial sites and in manufacturing. Handled on chemical sites for its production and industrial sites used in closed systems to transfer into mixtures, repackaging, refrigeration, air-conditioning and heat pump equipment and similar, production of insulation foams, or for destruction. Handled widely by professional and technical staff for servicing and maintenance of refrigeration, air-conditioning and heat pump equipment. In total of the order of 100,000 workers Used as a foam blowing agent, mainly for PU foam. Quantity not known quantity used as a refrigerant is not known. Also used as a working fluid for Organic Rankine Cycle systems It is used by professional workers (widespread uses), in formulation or re-packing, at industrial sites and in manufacturing. Handled on chemical sites for its production and industrial sites used in closed systems to transfer into mixtures, repackaging, refrigeration, air-conditioning and heat pump equipment and similar, production of insulation foams, or for destruction. Handled widely by professional and technical staff for servicing and maintenance of refrigeration, air-conditioning and heat pump equipment. In total of the order of 20,000 workers Used as a foam blowing agent, mainly for PU foam. Quantity not known quantity used as a refrigerant is not known. Also used as a working fluid for Organic Rankine Cycle systems It is used by professional workers (widespread uses), in formulation or re-packing, at industrial sites and in manufacturing. Handled on chemical sites for its production and industrial sites used in closed systems to transfer into mixtures, repackaging, refrigeration, air-conditioning and heat pump equipment and similar, production of insulation foams, or for destruction. Handled widely by professional and technical staff for servicing and maintenance of refrigeration, air-conditioning and heat pump equipment. In total of the order of 20,000 workers Used as a foam blowing agent, mainly for PU foam but can be used for XPS. Quantity not known quantity used as a refrigerant is not known. Also used as a working fluid for Organic Rankine Cycle systems It is used by professional workers (widespread uses), in formulation or re-packing, at industrial sites and in manufacturing. Handled on chemical sites for its production and industrial sites used in closed systems to transfer into mixtures, repackaging, refrigeration, air-conditioning and heat pump equipment and similar, production of insulation foams, or for destruction. Handled widely by professional and technical staff for servicing and maintenance of refrigeration, air-conditioning and heat pump equipment. In total of the order of 100,000 workers Should be zero due to ban under the Ozone Regulation 1005/2009 Should be zero due to ban under the Ozone Regulation 1005/2009 It may still be handled to some extent by professional workers (widespread uses) if there are remaining RAC systems in the EU that contain HCFC22 that requires its removal at the equipment location. However these are expected to be quite relatively few. Handled on chemical sites for its production and use in closed systems as a feedstock. May be handled on industrial sites for its destruction. In total of the order of 5,000 workers. Should be zero due to ban under the Ozone Regulation 1005/2009 Should be zero due to ban under the Ozone Regulation 1005/2009 Handled on chemical sites for its production and use in closed systems as a feedstock. May be handled on industrial sites for its destruction. In total of the order of 1,000 workers. Number of workers involved in handling at company or customer sites