Document 2NRgrEV7jayZzjbzjgxynnKoL

l>IOTECTlVE EQUIPMENT *9 RESPIRATORY PROTECTIVE EQUIPMENT PLAINTIFF'S EXHIBIT DUP-1820 CT> iltUlO SAFETY ENGINEERING standaid JAN IMA OCT 1f S2H . Poge t of 3 CCH OU rI Eo H N T O I NT IS S O M fA PfNM C lD| Nt A T OU W N $ O f NEMOURS N R C N TO O U C EO W IT H O U M IC A i.K PONT t. SCOPE This standard providn information for ihr selection, u-ir. and car* of respiralorv protective equipment Irrspirniort). The tarin "respirator" in Ihia standard in ward inclusively and applies lo atmosphrre-supplving and air purify mg drvicra dial provide breathable air lo the wearer thin the limila of die equipment. whatever the aourre of air. This atandard dora not apply for exposure to air borne radioactive contamination for which apeetal con sideration may be neceaaarv 2. GENERAL 2.1 Respiratory protective equipment should not be used as a substitute for adequate exhaust ventilation or other engineering eontroi methods. 2.3 Respiratory protective equipment shall be worn at alt limes where the atmosphere may be harmful lo env ploy res due lo unusual condidons. and where work 1ne-'essary in contaminated or oat gen-deficient, confined an-as. Z2.1 M hen the air is defiriral in oxy gen. the tv mgtoins range from increased volume of breathing and ac celeration of pulse rale to unconsciousness and death, defending upon oxy gen content and the degree of a per son's activity. Unaansdausnass is immadiota whan a mtm breathes pur* nitrogen and daath may follow in a loir minutas. 2.2.2 An oxygen deficiency mav indicate a hazard in addition to inert gas: eg. flammabiJily (see 4.4). skin toxicity, or absorption through the akin, particularly hydrogen cyanide. Threshold limit values (TL\'*) of air eoMaminants are given in Standard S2T. Portable oxy. per and toxic-gas detectors art covered in Standard S3T. 2.3 Pure oxygen shall aot be used in atmospheresupplying respirators. the Superintendent of Document!. I. S. Government Printing Office, Washington. DC 20402. Copies of a upplemental liat containing approvals since 1903 mav be obtained from the Bureau of Mines. Health and Safety Research and Testing Center. 4800 Forbes Ave. Pittsburgh, Pennsylvania 15213. At the present time, the Bureau does not have approval schedule* lor the following equipment: a. Filler-type respirators for protection against paniculate aerosols, such as beryllium duals and fumes, dusts impregnated with orpanir phosphurus insecticides (paratbionl. and radioactive substances b. Air-supplied suits. c. Chemical cartridge respirators for respiratory protection against gases and vapors other than organic vapors. 2.4.2 A list of respirators for respiratory protection against certain pesticides may be obtained from the l. S. Department of Agriculture. Pesticide Chemicals Research Branch. Beilsvilie. Maryland 20703. 3. MANUFACTURERS Names and addresses of companies lo which ap pro vais on currently available respiratory protective de vices have been granted by the l . S. Bureau of Mines are given in Table 1. Companies lo which approvals have been given by the l . S. Department of Agriculture for insecticide respiratory protective devices slut are indicated in Table I. The listing of s manufacturer in this standard does not mean necessarily that all of hi> products are approved. 4. TYPES, USE, AND LIMITATIONS 4.1 A list of the several typea of respiratory protective equipment, method of operation, use. limitations, and remarks is given in Table 2. For additional information in this regard, reference should be made to: OF C t OSCO N O P H U P E B IT A Y NOT Mt TM '* DOCUMENT is t il M *O R M A T IO N H tN C O H NOTE -- oo 2.4 Only equipment Baled and approved by the l . S. Bureau of Mtaea shall be uaed, it schedules for a particu lar ty pe of equipment have been eetabiiahed. ISA Standard Safety Code for Head. Kyr. and Respiratory Protection. Z2.1. I niled biuies of America Standards institute. 10 East lOtlt Street. New York. .New York 10016 2.4.1 Information Circular 8281, "Respiratory Prcifctivr Devices Approved by the Bureau of Mines at of October 1. 1965." can be obtained for 23 rents from Respiratory Protective Equipment. Data Sheet D--444. National Safety Council. 425 North Michigan Avenue. Chicago. Illinois Vandsct end mtrshandiss dssianstisns a>a glean ta describe materials snd'atay nat include all aasastabls grsduers. Substitutisns by tuasliart ara ra ha mud's sniy sn saaesesl at fha taaal suths-ity initiating tka vta af this standard. suaeotmtiTTaa no. ss DUP. 0960492 DU 040702 S2H Page 2 JANUARY 1964 RESPIRATORY PROTECTIVE EQUIPMENT ICG .... _________ ___________ This Poga Rev Oct 1969 >: I'miertive Device* Manual publi>lir<l \n.rrii.m Industrial 11\ fiirrtp \--ocuiUun and ........... hi ( mifrretitr of (foirrnmrm.il industrial *. 11opies .irr nvuiluhle frmn liratin and i,....an .1 tin Hh\ ldd-1. \nn \rhnr. Michigan.) 4.2 TVs air purifying retpirolors, ia. canister gasmasks, chawwal crtri4fs respirators. and mechanical filter retp<retert Tebie 20 (hail not ba utad far raieua work, or to' eme-gency work af any neture. Tlii i( bees use dir-e I--1.H.H..I. require ul least 16 percent oxygen in the ,nr mi" i.j~Hi for this requirement (irr dial (a) pas mass. .iif imrmlrd for use with no more than 2 percent ul m...i i.-w fje*. and lb) chemical cartridge respirator arr .HI filed for no more than 1000 ppm by vol ume ui urcaiiK \apnr in air. 4.3 I -r ..I rammer masks dial bear the label "MlSeri ar V I Purpose." or "l nnersai" is prohibited. 4 4 Miluiuili 'if-runtained breathing apparatus and ho-- ni.i.i. -nh bluaer have no conrenlration limit in rritunl i" tjxifitv. mum toxic gates and vapors are Hanim-ilile and ihr uer roulil lie exposed to a potential fire nr eMi|..lun. Tlte 2-percent concentration limits apprmed lur iu\tr pas removal ajih canister-type masks mix tie mdiin the flammable range for some gases. Siun.l.it.l li J provides informaiion and instructions fur u>e ui portal Ir flammable vapor und gas deleetors. s. stucnoN 5.1 In general, in choosing a respirator, die following factors should be considered: (a) nature of the liuzard. lb) fvrriiv of the luzurtl. Ir) type of contaminant, (d) conrentratmr of die rontaminant. (e) period protection is reiiuned. ifi loraiion of llie contaminated area with respect iu a -ource of respirable air. (g) expected activity of die nearer. (li) operating chararteristics and limita tions of die mailable respirators, (i) safety regulations of sMir or luial governments (see Tabic 2). 5.1 1 'pparatus classified for 30-minule service time, ur longer, 'should be used for entry into an irrespiraMs atmosphere. In certain casea. 15-minute unit* may be |ierimiied. depending upon local conditions. 5.1.2 Duration ratings (or self-contained apparatus are based upon moderate work rule, brevier life of an air w Under w ill be ies for greater work rate. 5.1.3 Only salkcantoinad brootfiing apparatus, combination air-lina respirator and salf-canlainad braothing opoorotui. ar hasa mask arith Master shall ba utad in osygan-daficiant otmaspharas ar swhaea tha can. tominant it. >r might ba, immadiotaly dangaraut to Ufa. I hr latlsr tsmdiiion is definrd as one from which a worker tannol i*.i|ic uninjured without rrs|iirulory pro. lei'llvs 1`iiiiipineui. I lie .nr in die srlf.cunluiued unit of die combination air-line respirator und srlf-ctinUtiaed lircathmg apparatus 'hull hr used only for egress in eu-ui the hose-line supply of air is interrupted. The v olume ol this evil supply may vary for different applications, but'hull be ample to ullow the worker suflicirnt air to escape from the contaminated urea. In any case, this supply shall not be less than J minute*. 5.1.4 \n unconlaminated supply of air must be assured when using a hose mask with blower. 5.1.5 Schedule 13E of the l. S. Bureau f Mines on self-contained breathing apparatus requires u remainmg service-life indicator or warning for compressed breathing air (except for self-rescue, which has a mod* mum ruled service lime of 30 minutes). Some equipment now on plants may not have these alarms. Thesr can und should be ubiwned from equipment suppliers for appara tus not so equipped. 5.1.S.I When the device is a combination selfcontained breathing apparatus und air-line respirator Isupplied-air respirator), cither a manual or automatic valve(s) shall be provided to change to the self-contained air supply if the air-line supply (uils. und to prevent the wearer breathing contaminated air from the outside atmosphere. If a munuu) valve is provided, it shall be easily operable nod located in a position which is conlenient to the weurer. If an automatic valve is provided. a warning also shall be provided to alert the wearer that lie is breathing from Ihe self-contained air supply. It) when his normul air-line supply fail*, or (2) when the self-contained air supply falls below 95 percent of its full container pressure. \ quick disconnect und check valve shall be provided between the uppurutus and the air-line supply hose to permit ready escape from the area, and to prevent loss of breathing air from the dev ice or inhaling the surrounding atmosphere, respectively. 5.2 Tuble 3 lists the hazards and the respirators that are recommended to afford respiratory protection against them. By reference to this table, and by considering the foregoing factors, the user can determine the type of respirator that should be used. 6. PRECAUTIONS 6.1 Purchased cy finders of breathing air should be analy ted for o xy gen and carbon monoxide content before use. This analysis normally should be done by die plant (see S3T). Mso. (he water content of cy linder air used for air masks should be below the dew poim for the lowest prob able temperature to be encountered. This is necessary to prev ent (reeieup und stoppuge of uir flow- to the mask. Drw points at v ariout temperatures cats be obtained from the "Handbook of Compressed Cases." 6.2 Vn extensive list of instructions in ue and precau tions for each tvpr of respirator is'given in "the previously REV. l 3 Q> oo CONFIDENTIAL m> DUP 0960493 'v DU 040703  ________________________ S * ^______________________________________________ JANUArf 1*M " " S2H MSPIIATOtY PROTECTIVE EQUIPMENT 6* This Pago Rav Pafa 1 tit____________________ Pag* 3 refn-enrfd USAS 7.2.1 . Some precaution-. art- pnrn in 1 able 2 under heading,- of Limitation* and Heniyrk. *.3 The manufacturer's instruction* or precaution* of thr USA Standard abouJd be potted with the respiratory device. 4.4 All parsons who may have occasion la at* raspir alary davkat, or can** thorn to ba utad, should be properly Iraniad in thair via bafar* circumstances ra- guir* that they u*a ibain to prated their live* and the property of the Company. Alto, in eieculion of plant ditaiter plant, proper training in nte of rttpiratory pro- tecti-** equipment will aid in the performance of smooth and tafe reteue or repair operation*. a 4.5 A negative prttenre occur* intide tb* facepiece of face-fitting air-purifying rtepiratort (Table 2C). Care nut be taken to obtain an effective teal between the facepiece and fact to prevent inward contaminant leakage. Alto, demand-type air-eupplitd rtepiratort and demand- type self-contained rtepiratort operate under negative pretnure wben tbe wearer inbaltt; tome inward leakage of contaminant may be poteibl*. A preteure-demand type telf-cooiained retpirator may be weed where tpecial pre caution! mutt be taken to prevent the wearer from in- baliig any trace of contaminant. (A tmail positive pree- urt it maintaiaed at all timet and. even if a leak ihould develop, there would be no leakage of contaminant into ibt fiiMpim.) 6.6 A prp*r *ot cannot oitobJUhotf if Hi* tempi* bars ol oyo fiascos oaion4 ArsvyH Iho tsslin^ 0690 fulMtca masks. 4.4.1 All eyepitett in full-face mask* approved by the iSureau of Mince will pace tbe ball drop test. but ottit plank- eyepitett may not pat* the needle drop tatt (StH). Current tcbedule* of the Bureau of Mioei. bowever, require that eyepiece* iball meet the pertiient requirimrntt for impact and pesetration tptcjficd in the matt recent USA Standard Safety Code for Eye Protection. 4.4.2 At a temporary mtaaure with fall-face piece*. glattee with than temple ban or withoat temple ban may be taped l* lb* waarer'a bead. Full-face maaka have been developed with tyttoni for moonting conective Icatc.t iatid* tht facepiece. iiJ A half-mask facepiece abouid tot interfere with the wtartr't ate of tpeetacie* or. goggle*. Proper ttlection of equip**ant normally will climiaale aay prob lem of proper Gt when utieg a combiattiot of baif-matk facepiece and tpactadct or goggle*. 4.7 Conventional respirator* do not conttitulr an abtolutc barrier to trantmit.ion of tpeeeh. 1 he retpirator exhalation valve uaually provide* a aatitfactory pathway for tpeeeh tranemittion over short distance* in relatively quiat aroot. Speech traatmiaaion device* arr available. (Caution: check for acceptability of tlcetrieal elaeaification for uae in hatardout ana*.) 4J Major problem* in tbe ua* of full-fact matkt at low temperatures aae poor vitibility and Irming of exhala tion valve*. Antifog compoundtean be uaed to coat the intide of the eyepiece to prevent its fogging dow n to about 32 F. Below 0 F. however, antifog compound will not prevent aevtrr fogging. 4.4 Hotee for air tuppiy abouid be telactad to retiat chemicals to which they may be exposed. 7. CAM 7.1 Ooaaroi. A centraJbrd maintenance, denning, and ttorage nation abouid be used to care for respiratory protective equipment. 7.2 Procedures Applicable to All Ratptrotore-' 7.2.1 Inspection. All retpirator* eball be inspected at regular interval* to make sure that they art ready to ate. It it good practice to integrate tbe retpiratory and firewntjapuieber inspection and maintenance prapram. Maintenance. When It is necessary to replace worn or deteriorated parts, only (boa* made specifically for thr device abouid be used; and tbe repair work abouid be accomplished by traiaed personnel. For most plants, it is preferable that part* of thi* type be replaced at a unit or rtturnad to tb* manufacturer (or repair. 7.2J Cleaning and Disinfading. Respiratory pro tective equipment, except canister* and cartridgra. should be daaacd and diaiafected after each at*, unless assigned to individuals. Rttpiratory cqaipmtat can bt cleaned with detergent and lukewarm water (lata than 125 F) by band brushing or agitation ia a washing machine, rinsed, and dried. The qaateraary ammonium salt dis infectants* are recommended for sterilising rttpiratory device*. Riate completely in clean, warm water. Assure thorough drying of mask and demand apparatus tfttr cleaning to prevent irming if used ia cold weather. 7.2A Storage. All respiratory protective equipment should be stored ia a dtaa, cool, dry' plae*. out of direct sunlight, under conditions of moderate temperature (tee Chemox mask in Table 2B). * Wilts**, Of*wi-Clo*t,; Ameriean Oftiaal Co, No. 101 and 102 Garmteidel Ooteraont; Putmasan S niiitoe: MSA Cloon*. $* tr _____ ________ GOSSIP DUP 0960494 CONFIDENTIAL DU 040704 emn*m S2H Fog* 4 1V ,RESPIRATORY PROTECTIVE EQUIPMENT JANUAtY 1*44 This at Ra Fab ItM 70 7.3 Special Frocndurot for Maintaining, Cleaning. Dis infecting. and Staring Respirator* 7.3.1 S#ll-C#nt#i#d IraatHing Apparatus In demand-type (Table 2H), (hr cylinder pressure ihould be cheeked periodically and brought lo rated procure if necoeary. (Minimum pretaure in 1600 pai ul 70 F.) Ilechargc after each uae, following manufacturer'* in struction*. Follow manufacturer * inalructiona oa tightnet* teat* for ielf-contained reapirator* and hydroatatic toting of eomptoaed-air cyliadcra. 7.3.2 Hoia Maaka. Check the blower periodically for proper operation. Check hoar for ttrur and tear after each uae and Meant dean when neceaaary. keep ho*# capped when not in uae to prevent entrance of dual or other conlamina nla. 7.3.3 Air-lina Kaapirotora. The facepiece ahould be am iced after ench uae, aa for all other reapiralora. The flow control val .ea ahould be inapected after euch uae and deaned and repaired, if neceaaary. Air-line hoae ahould be cheeked for wear and tear after each uae and be *t*am cleaned when nnceaaary. See Standard Sill on air-*upply yatem. 7.3.4 Salf-Rateuar*. Frequent inspection is the moat important phaae of the maintenance program with thin type of equipment becuuae the equipment i* addum uxetl but tiway* mual be ready. 7.3.5 Chamieal Cartridfa laepiealare. Chemical cartridge* ahould be ehanged when the wearer detect* the odor or irritating effect of the eoniambiunt. la planta with centralized maintenance *lation, cartridge* sometime* are diacurdfd aftee a given period of uae (hated upon group experience); but. in'mtniT cu*e*. the wearer ia reaponaible for diacarding and replacing cartridge* in hi* reapirator. Particular cure ihauld be eacrcind in the atornge of chemical cartridges bccaaae nasally they de teriorate if exposed to exeesa moisture sad to guaeoua air contaminants. Cartridge* ahould not be stored in the area where it ia necessary for the workmen to uae chemical cartridge reepiratora. 7.3.4 Mechanical Pillar Respirator*. Mechanical filler* of the "throw-away" type should be discarded when tht breathing resistance becomes bothtraomt to the wearer. Some mechanical filler respirators us* reelennabl* filter*, in which ease the filters are cleaned when the respirator ia being serviced. CK-1 CONFIDENTIAL DUP 0960495 DU 040705 REV. JANUARY 1964 7t ' Thi Fog* Rev Feb T9M RESPIRATORY PROTECTIVE EQUIPMENT S3H Png* 5 TAW T - MANUFACTURERS OF APPROVED RESPIRATORY OEVICES- Acme Protection Equipment Co. 1201 Koiomoioo Sir*t. South Hoven Micnigon 49090 Amerxon Opticol Co. Soulhbndge, Mossochusetis 0155' Souich i tomb, Inc. P. O. Box 478, Rochester, Nw York 14602 3mu Monulpcturing Co, 3114 Carroll Avenue. Chicogo, Illinois 60612 : D. Bullo'd Co, 2680 Brldgtway. Souialiio, California 94965 Coco Softly Products, Inc (formerly Chicago Ey* Shitld Co), 2727 W#t Rosea* Streei, Chicogo, Illinois 60618 H. S Cover, Stotion A. South Bond, Indiana 46614 Davit Emergency Equipment Co, Inc, 45 Halleck Si, Nework, New Jersey 07104 h DeVilbiti Co, Toledo, Ohio 43601 "he Firtwel Co, Inc. Subtidiory ol The Aro Corporotion. 3695 Broadway, Buffalo, New York 14225 "he Fyr-Fyter Co, 221 Crane Street, Dayton, Ohio 45401 . Glendole Optical Co. Inc. 130 Crossways Park Drive, Woodbury, New York 11797 Globe Salety Products. Inc (formerly Glob* Industries, me), 125 Sunns* Pioco, Daylon, Ohio 45407 Metallizing Engineering Co. Inc. 1101 Prospect Avenue, Westbury, New York 11590 r Min* Safety Appliances Co, 201 North Braddock Avenue, Pittsburgh. Pennsylvania 15208 r Mm* Solely Appliances Co, Ltd, Oueemlie Industrial Etta's. Glasgow E. 3, Scotland Minnesota Mining ond Manufacturing Co, 2501 Hudson Road. St Poul. Minnesota 55101 f'angborn Corporation, Hagettown, Morylond 21740 ' Pulmosan Safety Equipment Corp, 30--48 Linden Place, Flushing, Nev/ York I 1354 F ile Hardware Manufacturing Co. 540 Wes' Chevy Chase Drive, Glendale, Coliformo 91209 Safeime Products, Post Office Bax 550, Putnam, Connecticut 06260 t Scott Air--Pak, Ltd, 2254 South Sheridan Way, Clarkson, Ontorio, Canada r Scott Aviation Corporation, Lancaster, New York 14086 U. S. Divers Co, 3323 West Worner Avenue, Santa Ana, Californio 92700 W. W. Sly Manufacturing Co. 4735 Train Avenue. Cleveland. Ohio 44102 V/*lsh Manufacturing Co. 9 Mognolio Street, Providence. Rhode Island 02909 ** Willson Products Division, The Electric Sforog* Battery Co (formerly Willson Products Division, Ray--O--Vac Co. and Willson Products, Inc), P. O. Box 622, Reading, Pennsylvania 19603 TAW 2 - TYPES OP RESPIRATORY PROTECTIVE EQUIPMENT Merited ef Operation Table 2A -- Air-Supplied Suit Air supply from tupplied-air breathing apparatus. Sae Standard SIH on oir-distribution system. Use Untrlefians Operating or rppair work whero thero is exposure to substances that ore irritating or corrosive to the skin and mucuous membranes, but where the atmosphere is not immediately dangerous to life. The wearing of on impervious suit lor ony extended period is extremely fatiguing and dongorous unless it is wall ventilated. The suit must be impervious to the substance encountered. lamnrbs No U. S. Bureau of Minas approval. For additional Information, saa Fleming, A. J,, D`Alonzo, C. A., and Zapp, J. A.. "Modern Occupational Medicine," Chapter 7, "Pro tective Clothing for the Chemical Industry," Lea ond Febiger, Philadelphia, I960, A Ranque-Hilsch vertex tube worn as o portable refrigerator con satisfactorily cool com pressed air for personnel weonng industrial protective clothing the vortex tube is light and email, ond con be strapped to the belt where it does noet interfere with physical movement. The tube operates on 20-25 cfm ef compressed oir ot 80 - 100 psi and delivers 15--IB cfm of dir coaled 50 -- 60 F below the inlet air temperature. The lube con be reversed and used as a heater. * Approvals on currently available respiratory protective devices which have been granted by U. S. Bureau af Min** ** Approval given by U. S. Department ol Agriculture for certom pesticides DUP 096Q496 DU 040706 iaE&aaagiaiMJtMHH sa--E-ift /fesiLsafesaBa ilailBiaai'jjfr^Br^asaIBii o. *' DU 040707 DU 040708 S2H hit 1 *ISHA70Y MOTICTIVI IOUI9MINT JANUA.1V 1944 This Asfl* l<> ilk llil T*U - SELECTION Of HISWIATOKY MQTfCTVI OtVICE Hatord Respirator C*yQ*ft atUCitrtfy Stoff'Contained breathing apparatus Hose mask with blower Combination oir-line respirator and self-contained breathing apparatus GattOus comominant lmm#d'0*fy dangerous la lit* (sta 5.1.3) Self-contained breathing apparatus Hose mask with blower ~ Combination airline respirator and self'caniained breathing apparatus No* >mm#0iOH*iy dangerous to lift Air-line respirator Has# mask without blower Chemicai'cortridge respirator Port>cula>* contaminant Immediate1 jr dongtrous to lift (set 5.1.3) Self-contained breathing apparatus Hot# mask with blower Combination oir-line retptrafor and seif-contomed breathing apparatus Not immtco't'ty dangerous to lift Mechanical filter resptrotor Air-lme respirator Abrasive-blasting respiroter Hose mask without blower Comp.notion gc'.toui ond oarticuiatad contaminant immtdiottiv dongtrous to lift (it# 5.1.3) Self-contained breathing apparatus Hose mask with blower Combination oir-line respirator and self*contoined breathing apparatus No* immediately dangerous to lift Air-lme respirator x Hose mask without blower Combination chemical and mechanical filter respirators Nete: !h itlf-cSKIaTned breathing opporotut. combination oiHme respirotor and teif*contoined breathing apparatus, and hose mask with blower would give respiratory protection against any of the Hazards listed, but tnese atvcoi or* net included in th list of respirators that could b used in the lots hazardous situations. 74 REV. "Si;ct" S1IP RY CONFIDENTIAL DUP 0960499 DU 040709