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PROGRAM Schedule #1 Schedule #2 Schedule #3 Schedule #4 Schedule #5 Schedule #6 Schedule #7 Schedule m JANUARY 1984 ROUTINE MONITORING SCHEDULES DESCRIPTION OF SAMPLING COVERAGE . Five consecutive 8 hr. measurements collected on Shift #2 semi-annually. 7 Five consecutive 8 hr. measurements collected on Shift #2 quarterly. Schedule #2 plus additional monitoring to provide coverage for 7 consecutive days on Shift #1, (#2) and #3 annually. One 8 hr. sample collected on Shift #2 quarterly (minimum). Five consecutive 8 hr. measurements collected on Shift 2 semiannually for all personnel working craft in areas having > 1% benzene. Semi-annual measurement(s) collected. Each employee monitored once per quarter. Annual monitoring. LAM 000454 DPMC-16165 2 SPECIAL EXPOSURE STUDIES 1984 Asbestos Pipefitter, Insulators and other maintenance personnel. Metals, Dusts Bulldozer Driver Environmental North Vacuum Truck Drivers Most significant exposures TEL/EDB Audit/review of exposures Hydrazine Followup Levels produced from dilute concentrations. VNOx Low Lead Paint Gas Welding Processes Spray Painting Exposure Potential Analytical Lab North To Be Determined Carbon Monoxide LRDF Hydrogen Sulfide Total Hydrocarbons Gas Recovery Development of a test method for establishing respirator requirements when odors are present. LAM 000455 DPMC-16166 UTILITIES SOUTH Operations Foreman 09310 Boiler Inside 09510 Operator Boiler Outside 09511 Operator East Utilities 09512 Operator General 09513 Utility Oper. G OPERATIONS Chlorine Unloading Operator 07514 Utility Operator 07517 LTH Operator 07515 100 Operator 07510 Operations Foreman 07310 C Unit Operator 04534 300 Chlorinator Oper. 07513 200 Fract 07511 ionator Oper. 200 Reactor Operator 07512 C (MS & H) Utility Oper. 07561 M Plant Oper. 07565 3 Schedule #6 Hydrazine Schedule #1 AC, D-D, ECH AC, D-D AC, D-D AC, ECH, TCP AC, D-D, ECH, TCP AC, D-D AC, D-D Schedule 8 DMRY MIBCTMIBK, MO, SBA, DAA, HG DMK, MIBC, MIBK, MO, DAA LAM 000456 DPMC-16167 4 RESINS DISTRIBUTION SOLIDS OIS - LRDF DISTRIBUTION Foreman ER2/6 5331 Foreman LRDF 5330 LRDF Drumming 5530 Operator Solids OIS 5537 ER 2/6 Palletizer Operator LRDF Small Package Oper. 5531 LRDF Bulk Operator 5534 Solids OIS 5532 Shipping & Receiving Oper. Solids OIS ER 2/6 Bulk Loading Oper. 5535 Solids OIS 5536 ER 2/6 Bagging Operator LRDF Warehouse 5533 Shipping and Receiving Oper. Schedule #6~ Product Components* Product Components* Product Components* (all spots) Schedule #6 BPA (Hopper Car Loading) Total Dust (Bagging BPA and Resins) *To Include Glycidyl Ethers, Ethyl and Methol Oxitol and MDA. LAM 000457 DPMC-16168 MAJOR RESINS LIQUID RESINS AND SOLID RESINS RESIN SOLUTIONS Finishing 4520 Operator Operations 4340 Foreman Liquids Reaction Operator 4521 Utility Operator 4540 Belt Oper. 4541 Sol ids Reaction Operator 4543 EPON III Kettle Operator Flaker Charge Operator Utility Operator Operating Foreman Auxiliary Operator 4551 4552 4553 4350 4557 5 Schedule #4 DMK, ECH-----DMK, ECH . DMK, ECH ECH, MIBK ECH, MIBK Schedule #4 mnniiMr Ethyl and Methyl Oxitol ECH, MIBK Ethyl and Methyl Oxitol LAM 000458 DPMC-16169 LIGHT OLEFINS SBA BPA Auxiliary Operator Compression Operator Operations Foreman Fractionator Operator Refrigeration Operator Treaters Operator Utility Operator 1550 1551 1350 1552 1553 1554 1555 No Chemical Monitoring BPA 1/Rec. Operator 4510 BPA 2 Oper. 4511 Operations Foreman 4310 Recovery/Utility 4514 Entry 3C Operator 4513 3R Operator 4512 6 Schedule #1 Benzene Benzene Benzene Benzene Benzene Benzene Schedule #6 Hydrazine Benzene No Chemical Monitoring LAM 000459 DPMC-16170 OP III PYROLYSIS II E. Kerosene Operator 1540 Ethane Furnace 1541 Operator Fractionation Operator 1542 Gas Oil Operator 1543 South Tank Farm 1545 West Kerosene 1544 Operator Operations Foreman 1340 Firewatch 1546 OP III BUTADIENE/ HYDROTREATER BD-111 TOO Operator 1532 BD--III 200/ 300/400 Oper. 1533 HT-II Fract ionator Operator 1534 HT-II Reactor 1535 Operator HT-III Operator 1536 Operations Foreman BD/ HT-II/III 1330 HT III North Tank Farm 1537 Schedule #1 Benzene Benzene Benzene Benzene Benzene Benzene Benzene Schedule #6 ACN, BD BD Schedule #1 Benzene Benzene Benzene Benzene Benzene 7 Schedule #6 Hydrazine Schedule #6 TJUPlTTTTi Loading LAM 000460 DPMC-16171 8 DISTRIBUTION OLEFINS, INTER. AND SOLVENTS Site III Facilities Operator 05527 Schedule #4 VCR-------------- Foreman Site III/ West Rack 05321 VCM Tank Car Operator 05526 5X/Month for 1st half 1984 then IX/Month per job. Tank Truck 05525 Operator Schedule #6 Butadiene Denaturing 05521 Plant Oper. Assigned Shell Maint Schedule #4 VCW West Rack Drumming Operator 05524 Schedule #6 AC, ECH, DD Tank Truck 05523 Operator ECH, AC, Acetone, MIBK, IPA, MEK Tank Car Operator 05522 ECH, AC, Acetone, MIBK, IPA, MEK Operations 05320 Foreman LAM 000461 DPMC-16172 VINYL CHLORIDE EDC-100 Operator 07530 Schedule #2 edt,- vcm-- HCIN-II/III Operator 07532 Operating Supervisor VCM Unit 07231 Oxychlorination 150 Operator 07533 Operations 07330 Foreman (VCM) Utility Operator 07534 VCM 200 Oper. 07535 Assigned Shell Maintenance Schedule #2 'EDC , VCM----- EDC, VCM EDC, VCM VCM CONTRACTOR MAINTENANCE B&R Boilermaker 99539 B&R Foreman 99301 B&R General Mechanic 99543 B&R Pipefitter 99542 9 Schedule #4 EDC, VCM EDC, VCM EDC, VCM Schedule #4 EDC, VCM Schedule #4 EDC, VCM EDC, VCM EDC, VCM EDC, VCM LAM 000462 DPMC-16173 10 TECHNICAL - SOUTH QUALITY CONTROL LAB OP II/III Lab Tech Olefins 40464 Schedule #4 Benzene TECHNICAL - SOUTH QUALITY CONTROL LAB SOLVENTS/ INTERMEDIATES Lab Tech Solvents 40455 DMK, IPA, MEK, MIBK Lab Tech 40456 Intermediates Lab Tech Resins 40474 VCM, AC, D-D, ECH ECH, MEK, MIBK, Methyl Oxitol A OPERATIONS Chemico Operator DPS-LPG-SBA Operator Furnace Operator IPA Reactor Operator IPA Stripper Operator Operations Foreman 07540 07541 07542 07543 07544 07340 A Distillation Operator B Distillation Operator 07562 07563 A Gauger Operator 07560 Operations Foreman 07360 Schedule #8 DMK, IPA IPA Schedule #8 1M----------- DMK, MIBC, MIBK, MO SBA DMK, MEK, IPA, MO, MIBK, MIBC LAM 00041 DPMC-16174 ENVIRONMENTAL SOUTH Rover Opr. 52510 Effluent Treater Operator 52512 Filter Press 52511 Incinerator Operator BA/SR BA Finishing 07550 Operator BA Reactor Operator 07551 HBAX Operator 07554 LPG Operator 07555 Operations Foreman 07350 (EP) Girbitol 07556 Operator (EP) EA Weigh 07558 Room Operator (EP) Sulfur Recovery Operator 07557 Utility Operator 07559 Gas EHA Operator 07553 Schedule 8 Benzene Schedule #4 2EH, NBA",'TBA 2EH, NBA, I BA 2EH, NBA, I BA 2EH, NBA, I BA Schedule #4 Benzene - 11 LANl 000464 DPMC-16175 12 Monitoring Coverage* R Area - Maintenance South Epon V Solutions Boilermaker 22501 Electrician 22503 ECH, DMK ECH, MIBK Instrument 22504 Machinist 22507 Pipefitter 22601 Olefins Area - Maintenance South PY LO BD Boilermaker 25501 BZ 13Z, N2H2 BD, Acetonitrile Electrician 25503 Instrument 25504 HT II/III ISOPRENE Machinist Pipefitter 25501 25601 BZ BZ DCPD A Area - Maintenance South G 100/200 G 300 Boilermaker Electrician 28511 28513 AC AC, DD DD ECH, TCP Instrument 28514 M&H A C Machinist Pipefitter 28517 28611 MO MIBK MIBC DMK I PA DMK (MIBC) (MIBK) (MO) AC ECH TCP E Area - Maintenance South BA VCM SITE III Boilermaker Electrician 28531 28533 NBA VCM VCM EHA EDC I BA Machinist 28534 Instrument Pipefitter 28537 28631 LAM 000465 * Monitoring will approximately be semiannually; data to be collected along with operations surveys DPMC-16176 SOUTH - MAINTENANCE SOUTH Boilermaker 31511 Carpenter 31512 Electrician 31513 Instrument 31514 Machinist 31517 Painter 31519 Pipefitter 31611 Tinner 31613 Welder 31614 13 lam 000466 DPMC-16177 14 MAINTENANCE WEST - MAINTENANCE NORTH Boilermaker - Tank Farm 36500 Schedule #5 Boilermaker - West Operations 36502 Schedule #5 Pipefitters - West Operations 36526 Schedule '-#5 Machinist - West Operations 37540 Schedule #5 CENTRAL MAINTENANCE - MAINTENANCE NORTH Shop Painters Painters Plannable 35512 35513 Study needed on exposure to paint containing low Pb levels. Truck Drivers (Gasoline) 36522 Total HC, BTX, (Noise) 5 day survey required Garage Mechanic 36516 Asbestos Sx during brake change semiannual Shop Carpenters 35507 Study required on pentachlorophenol treated wood Shop Welders 35540 Study required on 0-NO Exposure from TIG/MiG x LAM 000467 DPMC-16178 15 SOUTHEAST MAINTENANCE Boilermaker 35502 Schedule #5: Benzene Carpenter 35508 Pipefitter CCU, Hydro. 35521 Pipefitter Gas Rec.,Arom. 35522 Schedule #5: Benzene Electrician Gas Rec.,Arom. 37500 Electrician CCU, Hydro. 37504 Instrument Mechanic Arom.,Gas Rec. 37521 Instrument Mechanic CCU, Hydro. 37523 Machinist CCU, Hydro. 37541 Machinist Arom.,Gas Rec. 38500 Schedule #5: Benzene NORTHEAST MAINTENANCE - MAINTENANCE NORTH Lube Phenol MEK/Toluene Benzene,Cumene,ToT Boilermaker Lube/P.A. 35503 Instrument Mechanic 35509 Pipefitter, Lube A,B,C 35523 Pipefitter P.A. 35524 Schedule #2 All others schedule Insulator 36510 Electrician, Lube/PA 37505 Machinist, Lube/PA 37542 - LAM 000468 DPMC-16179 CATALYTIC CRACKING Compressor Operator 10530 Control Board Operator 10531 Fractionator Operator 10532 Operations Foreman 10330 Reactor-Regen. Operator 10533 General Operator 10534 PHENOL A Cleavage Oper. 16510 Cumene Operator 16511 PHENOL B Operations Foreman Oxidation Operator 16310 16512 Acetone Oper. 16520 Effluent Oper. 16523 Phenol Fract ionator Oper. Recovery Oper. 16521 16522 16 Schedule #2 (20 Sx/Yr/Job) Benzene, Cumene, Toleune Benzene, Cumene, To!uene Benzene, Cumene, Toluene Benzene, Cumene, Toluene Schedule #4 (4 Sx/Yr/Job) Benzene, Cumene, Toluene Schedule #2 Benzene, Cumene, Toluene Schedule #4 Benzene Benzene, AMS lam 000469 DPMC- 16180 17 DISTILLING DU-3 Operator DU-1 Primary Operator Secondary DU-1 Operator DU-2 Crude Operator 13532 13534 13535 13530 DU-2 Auxiliary Operator Naphtha Hydro treater Oper. Operations Foreman DU-2 Vacuum Flash Operator 13531 13533 13330 13536 Schedule #1 (10 Sx/Job/Yr) Benzene & Toluene Benzene & Toluene Benzene & Toluene ENVIRONMENTAL NORTH Rover Operator 52501 Effluent Treater Oper. 52502 Oil Recovery Operator Shift Foreman Treaters 52503 52301 Schedule #2 (20 Sx/Job/Yr) Benzene, Toluene, Xylene THERMAL CRACKING Dubbs Pumphouse 13540 Operator Flashers #1 13541 Flashers #2 13542 Operations Foreman 13340 Primary Cracking 13543 Operator Secondary Cracking Oper. 13544 Schedule #1 Benzene & Toluene LAM 000470 Benzene & Toluene Benzene & Toluene Benzene & Toluene DPMC-16181 18 SOLVENTS AND TREATING LOFU-A Operator 13521 LOFU-C Operator 13522 Operations Foreman 13320 Treater Operator 13520 NORTH LAB Bottlewasher 43710 Gasoline Distilling Tester 43522 GLC Sample Shipping Special Tester 43510 Gas Oil Distillation Tester 43521 Mi sc./Motor Lab 43511 Special Tester Motor Lab Special 43512 Tester Catalyst Tester 43520 RA Special Tester 43513 RI Special Tester 43514 RVP Special Tester 43515 Sample Carrier 43610 Stability Special 43516 Tester UVA Special Tester 43517 Viscosity Special 43518 Tester Wax Special Tester 43519 Schedule #1 (10 Sx/Job/Yr) Benzene Benzene Benzene Benzene Schedule #1 Benzene, Cumene, Toluene, Xylene Benzene Benzene Benzene Schedule #2 20 Sx/ Benzene Job/Yr Benzene Benzene Benzene Benzene Benzene LAM 000471 DPMC-16182 19 DISPATCHING TANK FARM Blender Operator 13551 Board Operator 13550 Operations Foreman Solvents Racks Operator 13350 13554 Pumper Gauger 13552 Tank Car Loading 13553 Rack Operator Railroad Foreman 13351 Railroad Operator 13655 Railroad T.C. Repairman 13656 No.l Switchman 13657 No.2 Switchman 13658 CENTRAL POWER STATION B.T.G. Operator 19530 Station Operator 19533 Operations Foreman 19330 Systems Operator 19531 Water Treater Operator 19532 UTILITIES DISTRIBUTION Operations Foreman 19340 UCC #1/UCC i2 Operator 19540 Utility Operator 19541 CW System Oper. 19542 East Operator 19523 Schedule #1 (10 Sx/Job/Yr) Benzene Total Hydrocarbon, BTX Schedule #1 Benzene Schedule #6 2 Sx/Job/Yr.(Min.) Hydrazine LAM 000472 DPMC-16183 20 UTILITIES NORTH Operations Foreman 19321 PP #2 650 2B Operator 19527 650 #2-A-0perator 19526 Surface Water 19528 Clarifier Operator I.W.T. Operator 19529 CAT REFORMING Schedule #2 (20 Sx/Job/Yr) Auxiliary Operator 10540 Benzene, Toluene, Xylene CR-3 Reactor Oper. 10541 Benzene, Toluene, Xylene CR-3 Regen. Oper. 10542 Benzene, Toluene, Xylene Offsite Operator 10543 Benzene, Toluene, Xylene Operations Foreman 10340 Benzene, Toluene, Xylene Sats Gas Plant Opei 10544 Benzene, Toluene, Xylene Orthoxylene Oper. Aromatics East 10513 Schedule #1 (10 Sx/Job/Yr) Ethyl Benzene, Xylene GAS RECOVERY CFH Operator 10550 DHT Operator 10551 Fractionator Oper. 10552 Mol Sieve Oper. 10553 Operations Foreman 10350 Treaters Operator 10554 LAM 000473 DPMC-16184 HYDROPROCESSING LUBE A 21 HP-1 Operator 10560 Hydrogen Plant Board Operator 10561 Olefin Feed Hydrotreater Utility Oper. Olefin Feed Hydrotreater 10562 Operations Foreman 10360 Board Oper. SR5/SC0T 10563 Utility Oper. SR5/SC0T 10564 Schedule #1 (10 Sx/Job/Yr) Benzene Benzene Benzene DA Operator 16530 HVI Operator 16531 LVI Operator 16532 Operations Foreman 16330 Phenol Extract 16533 ion Unit No. 1 Operator Phenol Entry Operator 16534 LAM 000474 DPMC-16185 LUBE B 22 Control Board Operator 16540 DO Filter Oper. 16541 LHT Operator No.2 16544 DW Filter Oper. 16542 Operations Foreman 16341 LHT Operator No.l 16543 Entry Operator 16547 Operations Foreman LHT 2 16340 Recovery Operator 16545 Refrigeration Operator 16546 Schedule #1 (10 Sx/Job/Yr) MIR''& Toluene MEK & Toluene MEK & Toluene MEK & Toluene FPPH Operator 16550 Greer Operator 16551 Operations Foreman 16350 Perc Operator 16552 Rackman Operator 16554 ABC Pumpers 16553 Wax Pumper/ 16555 Utility Operator Christenson Wax Helper 99501 LAM 000475 DPMC-16186 23 AROMATICS WEST BEU Operator 10520 East ACU Oper. 10521 Gauger 10522 Operations Foreman ABC/B Column Operator West ACU Oper. 10320 10523 10524 HDU #1 Operator 10512 Platformer #2 Operator 10514 ALKYLATION Compressor Oper. 13510 Fractionator Operator 13511 Operations Foreman 13310 Reactor Operator 13512 Refrigeration Operator 13513 Schedule #3 (36 Sx/Job/Yr) Benzene, Hexane, Toluene, Xylene Benzene, Hexane, Toluene, Xylene Benzene, Hexane, Toluene, Xylene Benzene, Hexane, Toluene, Xylene Benzene, Hexane, Toluene, Xylene Benzene, Hexane, Toluene, Xylene LAM 000476 DPMC-16187 DISPATCHING DOCKS PJS06/01 1-18-84 24 Cargo Inspector 13560 Construction/ Maint. Dockman 13561 Dockman Operator 13562 Operations Foreman 13361 Pumper Gauger 13563 Special study required for benzene exposure on all jobs. 2nd half '84. Remainder of '84 to follow Schedule #2 for benzene, ECH, EDC, MTBE, Toluene and Xylene. LAM 000477 DPMC-16188 lam 000453 l W oFeRjmwS m<i la&.i DPMC 16164.1