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Thermlnol 77 Preliminary Technical Data Sheet
August 30, 1903
DEVELOPMENT DEPARTMENT MONSANTO CHEMICAL COMPANY
ORGANIC CHEMICALS DIVISION ST. LOUIS 66, MISSOURI
TO ASSIST YOU IN THE EVALUATION OF THE ABOVE PRODUCT, WE HAVE OBTAINED THE INFORMATION CON TAINED IN THIS BULLETIN FROM LITERATURE SOURCES AND PRELIMINARY INVESTIGATION IN OUR OWN LABORATORIES. WHILE WE BELIEVE THE INFORMATION IS ACCURATE, WE ASSUME NO RESPONSIBILITY AND DISCLAIM ANY LIABILITY INCURRED IN USING THESE DATA OR SUGGESTIONS. ONLY QUALIFIED TECHNICAL PERSONNEL SHOULD WORK WITH THIS PRODUCT UNTIL SUBSEQUENT STUDIES JUSTIFY ITS USE IN YOUR PROD UCTS OR PROCESSES. OBVIOUSLY NOTHING IN THIS BULLETIN SHOULD BE CONSTRUED AS A RECOMMEN DATION TO USE ANY PRODUCT IN CONFLICT WITH EXISTING PATENTS COVERING ANY MATERIAL OR ITS USE.
Therminol 77 is a clear, amber fluid with exceptionally high thermal and oxidative stability. It was especially designed for use as a liquid-phase heflt transfer fluid at temperatures above 600F. Following are some fluid
properties s
Temp. F
Vapor Pressure
(mm Hp)
Viscosity
(cs)
(Lbs/Ft-Hr)
Density (GMS/cc) (Lbs/Gal)
100 210 300 400 500 600 700 800
Temp. F
100 200 3D0 400 500 600 700 800
--
0.27 1.03 9.2 44 168 530
181 7.78
-----
1.50 0.96 0.66 0.46*
--
Specific Heat (BTU/Lb)
0.350 0.385 0.420 0.455 0.495 0.530 0,565 0.600
505 20,8
--
3.74 2,28 1.49 0.99
1.152 1.106
--
1.029 0.981 0.931 0.885
---
9.60 9.22
--
8.58 8.16 7.76 7.38
Thermal Conductivity (Cal/cm . C, sec). (BTU/F. Ft-1
32.25 x 10"5 31.40 x 10'5 30.50 x 10"? 29.65 x 10'5 28.80 x 10'5
--
..
' --
0.0781 0.0760
0.0739 0.0719 0.0698
___ ___
*Extrapolation
^0953
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TOWOLDMON0043765 WATER_PCB-00028234
Refractive Index
1.6413
Pour Point Plash Point
+45 460r
Tire Point
540n
A. I, T.
1U5F
thermal Decomposition
800r
E1 e c tr i c a l^P r o psjrti e a Dielectric Constant at 100C
60 Cycle 3.77
1000 Cycle 3.54" '
Power Factor at 100c'C, 1
Resistivity, ohm-cm
19.3
at 100C
WTio9
1.21
Oxidatlon-Corroglon Teat (48 hrs, 450F, Alt, MII.-L-9236A Method)
S Viscosity lues, at 100F at 210F
2 Metal Weight Loss, mg/cm
Cva Fe Mg Ag Yi A1
37 13
-1,56 +0.01 +0.02 -0.99
0.0 0.0
Tx_ixity and Safe Handling :
Appropriate animal toxicity studies indicate that rherminol 77 is "practically non-toxic" from the standpoint of accidental swallowing or single massive shin exposures. Irritation potential studies indicate that it should not be irritating to the skin and only slightly irritating to the eyes if there is occidental contact. Animals survived a single four-hour exposure to an atmosphere saturated with vapors at room temperature. It appears that no particular safety precautions are necessary during the handling of this fluid at room temperature.
^Thermal decomposition was determined by the isoteniscope method as described in the"Journal of Chemical and Engineering Data*,' January 1961, Volume 6, No. 1. It is defined as the temperature at which dp/dt = 0.014 mm. Hg per second or 500 mm. Hg per 10 hours.
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TOWOLDMON0043766 WATER_PCB-00028235