Document 1ypXQY7X9dvXYkaym6k6KpbVo

CWA COMPLIANCE EVALUATION INSPECTION REPORT U.S. ENVIRONMENTAL PROTECTION AGENCY, REGION 5 Purpose: Compliance Evaluation Sampling Inspection Facility: Ranovael Dairy, LLC 1244 County Road U De Pere, Wisconsin 54115 Oneida Reservation Brown County 44.434399, -88.189796 WPDES Permit Number: WI-0062821 Date of Site Inspection: 07/15/2021 - Facility Walkthrough 07/22/2021 - Operator Interview EPA Representatives: Benjamin Atkinson, Inspector atkinson.ben@epa.gov 312-353-8243 Cheryl Burdett, Inspector burdett.cheryl@epa.gov 312-886-1463 State Representatives: Holly Stegemann, Agricultural Runoff Management Specialist Holly.Stegemann@Wisconsin.gov 920-360-0794 Facility Representatives: Ray Vanden Elzen, Co-Owner 920-366-5463 Shirley Vanden Elzen, Co-Owner Report Prepared by: Inspector Signature: Benjamin D. Atkinson, Inspector Digitally signed by Atkinson, Atkinson, Benjamin Benjamin _______________________D_at_e_: 2_0_21_.0_9_.2_9_1_0:_40_:_41_-_05_'0_0_' ___ Approver Name and Title: Ryan J. Bahr, Section 2 Chief Water Enforcement and Compliance Assurance Branch Digitally signed by RYAN Approver Signature and Date: RYAN BAHR Date: 2021.09.29 BAHR _____________1_4:_30_:1_3 _-05_'0_0'___________________ 1 Ranovael Dairy, LLC WI-0062821 July 15, 2021 Site Inspection 1. BACKGROUND The purpose of this report is to describe, evaluate and document the Ranovael Dairy, LLC's compliance with the Clean Water Act (CWA) at its De Pere, Wisconsin facility (the Facility) on 07/15/2021. This inspection was performed pursuant to Section 308(a) of the Federal Water Pollution Control Act, as amended. At the time of the inspection, the Facility stated they had approximately 90 beef cattle confined. Within the past 12 months, the Facility had confined and fed or maintained for a total of 45 days or more 700 mature dairy cows and meets the definition of a Large Concentrated Animal Feeding Operation. The owners stated they were out of the dairy business and that their son had put the beef cattle on the south side of the facility. An unnamed intermittent tributary to Dutchman Creek flows through the facility a distance of approximately 2.3 miles to its confluence with intermittent Dutchman Creek. Intermittent Dutchman Creek flows approximately 9 miles and becomes perennial Dutchman Creek. Perennial Dutchman Creek flows approximately 3 miles to the perennial Fox River a Traditionally Navigable Waterway. The Facility is located within the boundary of the Oneida Nation of Wisconsin reservation. That Wisconsin Department of Natural Resources (WDNR) issued the facility a Wisconsin Pollutant Discharge Elimination System Permit (WPDES) No. WI0062821. In April 2019, the State of Wisconsin issued a Stipulation for Judgement against the Facility related to discharges from the Facility's Vegetated Treatment Area. 2. SITE INSPECTION Table 1: Site Entry and Opening Conference Arrival Time: 8:22 AM Temperature: 67 F Precipitation: .4 inches Presented credentials? Yes Credentials presented to whom and at what Ray and Shirley Vanden Elzen (the time? Owners) Was an opening conference held? With whom? Yes, with the Owners If photographs or documents were taken, does the facility consider any to No be Confidential Business Information (CBI)? EPA vehicle parked in approved location? Yes Location where EPA vehicle was parked? West of the milking parlor Disposable boots worn? Yes Other bio-security measures taken (state vet contacted, etc.): State Vet was contacted 2 Ranovael Dairy, LLC WI-0062821 July 15, 2021 Site Inspection 2.1 Records Review (The following Records Review tables reflect information provided before the walk-through of the facility, unless otherwise noted.) Table 2: Documents Checklist(s) Used R5 CAFO Inspection Checklist Table 3: Facility Description Type of Animal Number of Animals Beef Cattle 90 Capacity 700 Minimum Number of Animals in previous 5 years: Type of Confinement Freestall barns and outdoor lots 90 Maximum Number of Animals in previous 5 years: 700 Number of Animals that are stabled/confined and/or fed/maintained for 45 days or more in previous 12 months: Amount of Liquid Manure Generated per year: Amount of Solid Manure Generated per year: Does the facility have an NPDES Permit? SIC or NAICS code: CAFO Designation Reason (If a designated CAFO) Do animals have direct access to WOUS? Are crops, vegetation, forage growth, or post harvest residues sustained in the normal growing season over any portion of the lot or facility where animals are kept? What is the area (acres) of the production area? What is the area (acres) of the pasture? How many employees (not counting family members)? Other facilities under common ownership (name and None 700 Unknown Unknown The Facility was issued a WPDES permit. 0241 Number of animals Not in the production area. Not in the production area. Approximately 10 300 None address): Table 4: Livestock Waste Storage Type of Storage Type Depth Storage Capacity of Markers Liner Present Last Time Waste was Removed Amount of Waste Removed Days of Storage 3 Pond 1.5 Clay Yes Million Gallons Pond 400,000 Clay No Gallons Records at site of storage structure design? Is manure stored for the short term? If yes, describe where it is stored, how it is drained and where it drains to. Are records kept of the level of manure in the storage structures? When was the last time a storage structure was emptied, either partially or completely? What amount of manure or process wastewater was removed the last time the storage structure was emptied, either partially or completely? Do the facility personnel inspect and keep records of all diversion devices? Do the facility personnel inspect and keep records of all impoundments? Do the facility personnel inspect and keep records of all the water lines? Do the facility personnel perform routine visual inspections and keep records of the production area? Does the waste storage system have a managed outfall or discharge point? If yes, provide a description of the outfall and a description of the area receiving the discharge. Has the facility had any documented discharges of livestock waste to surface water in the past year? Are there safety devices installed around any manure storage ponds? (Barriers at the end of manure push off platforms, fences around pond, signage.) Ranovael Dairy, LLC WI-0062821 July 15, 2021 Site Inspection Fall 2020 Unknown Unknown Spring 2020 No No Unknown Unknown No Fall 2020 Unknown No No No No No None documented by the facility. Yes Table 5: Livestock Waste Management Describe the way manure is collected and disposed of at the facility: 4 Ranovael Dairy, LLC WI-0062821 July 15, 2021 Site Inspection Waste on the south side of the facility is scraped or gravity flows to manure storage pond 2. Manure from the freestall barns on the north side of the facility was pumped to manure storage pond 1; however, these barns are no longer in use. Describe the way used bedding is collected and disposed of at the facility: No bedding is used. Are mortality records kept? No Describe the way mortalities are managed at the facility: A rendering service picks up mortalities. What type of method is used to provide Tanks with floats. drinking water for the animals? Describe the way spilled drinking water is collected and disposed of at the facility: Spilled water is collected with manure. Describe the way mist cooling water is collected and disposed of at the facility: No misting is used. Describe how chemicals are stored and how used or spilled chemicals are collected and disposed of at the facility: No chemicals are used as the facility is no longer a dairy. Describe the way water that has been used to wash/flush barns is collected and disposed of at the facility: No flushing occurs. Describe the way feed is contained and how runoff from feed is collected and disposed of at the facility: Feed is stored in the feed storage area, commodity barn, and in bagged hay bales. Leachate and runoff from the feed storage area gravity flows to the VTA. Table 6: Land Application and Disposal of Manure and Process Wastewater Does the facility perform and keep records of the The NMP writer kept the manure testing? records. When was the last time a sample was taken of the Fall 2020 manure and/or process wastewater? Describe the process to take the manure and/or Grab sample when pumping. process wastewater sample. Number of acres available for land application: Are land application records kept? 300 Acres of pasture. The NMP writer kept the records. 5 Ranovael Dairy, LLC WI-0062821 July 15, 2021 Site Inspection Who applies the manure and process wastewater to the fields? Are weather conditions at time of application kept? (24 before - 24 after) Does the facility perform and keep records of the soil testing? Is manure transferred off-site to another party? A hired manure spreader No Yes No Table 7: Receiving Surface Waters Describe the surface flow pathways: Surface runoff from the feed storage area flows to the VTA. All other stormwater flows to the unnamed intermittent tributary of Dutchman Creek. How many months out of the year is there flow in the nearest surface water pathway: Are there any storm water pathways entering the facility? Are there any clean water ponds on site? What is the name of the first waterway that is identified as a Traditional Navigable Water (TNW) for surface flow from the facility? Is the surface water pathway nearest to the facility considered to be ephemeral, intermittent or perennial? Has the surface water pathway nearest to the facility been assessed for water quality? Most of the year. No No The Fox River Intermittent No Table 8: Nutrient Management Plan NMP on site? No Additional NMP comments: NMP was last updated in 2019 and the NMP writer has it. 2.2 Walkthrough of the Facility Ben Atkinson and Cheryl Burdett (the Inspectors) met offsite with WDNR inspector Holly Stegemann (WDNR) and proceeded to the site arriving at 8:22 A.M. The weather was clear. 0.4 inches of rain had been reported the night before the inspection. The Inspectors donned their biosecurity boots and went to the on-site residence to locate a facility representative. Mr. Ray Vanden Elzen and Mrs. Shirley Vanden Elzen (the Owners) came to the door. The Inspectors presented their credentials and explained that we were there to conduct an inspection to determine compliance with the Clean Water 6 Ranovael Dairy, LLC WI-0062821 July 15, 2021 Site Inspection Act. The Owners stated that they had ceased operating the dairy and sold all of the animals the previous fall. The Inspectors asked if there were any animals on the facility and the Owners stated that their son had some beef cattle on the south side of the facility. The Inspectors notified the Owners that having had the requisite number of animals to be considered a Concentrated Animal Feeding Operation (CAFO) for at least 45 days within the last 12 months meant that they were still considered a CAFO and requested permission to conduct the inspection. The owners granted permission and declined to accompany the Inspectors. The Inspectors together with WDNR began by walking south from where their vehicles were parked past the machine shed to the feed storage area. The Inspectors observed two mounds of silage and multiple rows of plastic wrapped hay bales (photos 1 and 2). The Inspectors also observed darkly colored leachate and loose silage around the silage mounds. The inspectors observed the stormwater and leachate flowing to the south (photos 3-5). The Inspectors followed the flow path to the first flush collection system and vegetated treatment area (VTA). The Inspectors observed that the fist flush collection system and spreader bar were completely submerged and the VTA was ponded with darkly colored water (photos 6 and 7). The Inspectors then walked to the southwest around the west side of the VTA to the southwest side of the VTA. The Inspectors observed that the VTA was bermed on all sides and completely ponded with water. The Inspectors walked east along the southern berm and observed that the elevation of the ponded water in the VTA was level with the top of the berm in some places. The Inspectors observed that the ground of the berm was saturated. The Inspectors observed that liquid from the VTA was trickling over the berm, though it was difficult to see due to the tall grass and dense vegetation (photos 9 - 14). The Inspectors walked south toward the unnamed tributary and observed what appeared to be a spring or seep flowing from the side of the berm and flowing south toward the tributary (photos 15-22). The dense vegetation and wet, saturated soil conditions along the banks of the tributary made it difficult to document the flowpath to the tributary. The Inspectors then walked northeast between the tributary and the VTA berm to the northeast side of the feed storage area (photos 23-26). The Inspectors observed the vacant barns on the north side of the facility and then crossed the bridge over the tributary. The Inspectors walked northeast around the north side of manure storage pond 1. Manure storage pond 1 was heavily crusted and had significant vegetation growing over the top of it. The inspectors noted that manure storage pond 1 was not at the top of its berms and no overtopping was observed (photos 28-31). The Inspectors continued walking northeast and observed an eroded flow path with water flowing north to the tributary. The Inspectors followed the flow path to the southwest to document the source of the water and found that it appeared to fade away in the pastures east of the heifer barns on the south side of the facility (photos 32 - 48). No source of 7 Ranovael Dairy, LLC WI-0062821 July 15, 2021 Site Inspection water other than stormwater from the pasture area was observed for the water in the flow path. The Inspectors then walked to the west to the southwest side of the facility. The Inspectors observed more plastic wrapped round hay bales south of the heifer barns on the south side of the facility (photo 49). The Inspectors observed runoff from feed pad flowing south into the field south of the heifer lots (photos 50 - 53). The Inspectors then walked north around the west side of the southwestern heifer barn and observed a solid manure stacking area, concrete lot, and flow path for the surface runoff of the heifer barns' pens (photos 54-58). The Inspectors then observed manure storage pond 2. The inspectors observed that the pond had backed up on the concrete pad to the west. There was also a significant crust and abundant vegetation growing on the manure pond (photos 59 and 60). The Inspectors then walked around manure storage pond 2 and back south past the heifer barns (photos 61-64). The Inspectors then returned to their vehicle, collected sampling supplies, and prepared the field blank (photo 65). The Inspectors then returned to the southwest side of the VTA. The Inspectors observed a small channelized flow path on the top of the southwest corner of the VTA berm. The Inspectors observed that the channelized flow path led from the top of the berm south to the unnamed intermittent tributary. The Inspectors observed that there was water in portion of the flow path closest to the VTA. The Inspectors also noted duck weed, an aquatic plant, deposited along the channel from the VTA to unnamed intermittent tributary (Photos 66-75). The Inspectors collected sample S01 from the northern part of the channelized flow path at the top of the berm around the VTA (photos 76-77). The Inspectors then collected sample S02 from the ponded VTA (photos 78-79). The Inspectors then walked east, downstream, along the unnamed intermittent tributary approximately 20 feet and collected sample S03 (photo 80). The Inspectors then walked west and crossed County Road U and collected same S04 upstream of the confluence of the channelized flow path and the unnamed intermittent tributary (photos 81-83). Following the collection of sample S04, the Inspectors returned to the Owners residence and held a brief closing conference and interview. The Inspectors notified the Owners that they needed to act immediately to prevent any unpermitted discharges from the facility. A follow up phone call was held on July 22nd during which EPA completed the interview and checklist and repeated that the Owners should take immediate action to prevent unpermitted discharges from occuring. 2.3 Closing Conference and Post-Inspection 8 Ranovael Dairy, LLC WI-0062821 July 15, 2021 Site Inspection Table 12: Post Walk-Through Was a closing conference held? With A brief closing conference and interview whom? were held on-site with the Owners followed by a phone call to complete the interview closing conference on July 22nd. Were specific Areas of Concern discussed with facility personnel? Yes Who were the Areas of Concern The Owners. discussed with? Were any deficiencies or areas of No concern addressed or fixed during the inspection? If so, list what was done. Exit Time: Disposable Boots Left at Facility? Vehicle Washed after leaving facility? 1:00 PM Yes Yes Table 13a: Sampling Information Were samples taken? Were samples split with facility? Number of samples taken? Was a trip blank created (done prior to entering the facility)? Were field duplicate samples taken (1 duplicate per 20 samples)? Were equipment blanks taken (if more than one type of equipment was used to collect samples)? Identify which samples were equipment blanks. List chain of custody for fecal coliform samples: List chain of custody for nutrient and general chemistry samples: Location where samples were preserved: Name of people involved with sample preservation: Time of sample preservation: Were samples shipped to a lab? Did all inspectors involved with the sampling sign the chain of custody? Weather conditions at the time of sample collection: Camera name and type used to photograph sample collection: Yes No 5 No No Yes B01 5-65977 5-65954 On-site Ben Atkinson Cheryl Burdett 12:45 PM No Yes Sunny RICOH WG-4 GPS 9 Table 14b: Facility Sample Information Number Name Location Date Time B01 Ranovael Vehicle 7/15/20 11:23 21 AM S01 Overflow North end of 7/15/20 11:49 from VTA channelized 21 AM flow path from VTA S02 VTA VTA 7/15/20 11:52 21 AM Collector BA CB BA CB BA CB Color/ Smell Clear Bownish green Greenish S03 Downstream Downstream 7/15/20 12:00 BA CB Slight DC of VTA path 21 PM brownish confluence S04 Upstream DC West of 7/15/20 12:07 BA CB Slight County 21 PM brownish Road U Ranovael Dairy, LLC WI-0062821 July 15, 2021 Site Inspection Photo # RIMG0065 Photographer CB Method of Collection Grab RIMG0076- CB RIMG0077 Grab RIMG0078- CB RIMG0079 RIMG0080 CB Grab Grab CB RIMG0081 Grab # of Sulfuric Acid Ampoules 3 drops 8 drops 6 drops 5 drops 5 drops Name of Laboratory where fecal coliform/E.coli samples were taken: _Pace Analytical_____________________________________ Name of Laboratory where nutrients and general chemistry samples were taken: REGION 5 ANALYTICAL SERVICES BRANCH LABORATORY Additional laboratory notes: ____________________________________________________________________________________ 10 Table 15: Sample Results Sample ID Sample Description (all liquid samples unless otherwise noted) Typical limits B01 S01 S02 S03 S04 Biochemical Oxygen Demand (mg/L) 3 57 34 7 7 Total Kjeldahl Nitrogen (mg/L) U 15.2 11.1 2.59 2.36 NitrateNitrite N (mg/L) 0.1 * U 0.08 U 2.25 2.47 Ammonia as N (mg/L) 15 U 2.95 2.58 0.28 0.36 Total Phosphorus (mg/L) .05 U 9.56 9.66 1.30 1.33 Total Dissolved Solids (mg/L) 1000 U 425 428 244 240 Total Suspended Solids (mg/L) U 710 51 51 39 Fecal Coliform (CFU/100ml) 200** NA 45500 18200 173000 155000 U = Not Detected The typical limits are for general use waters and this data comes from the Illinois Water Quality Standards (IEPA 2004) unless otherwise noted. There are no Water Quality Standards for Biochemical Oxygen Demand, Total Kjeldahl Nitrogen, Nitrate-Nitrite, and Total Suspended Solids but some limits are provided and are meant to be a benchmark for comparison only. * Maximum Nitrate-Nitrite amount for aquatic life (North Carolina State University Water Quality Group) 11 3. AREAS OF CONCERN EPA observed these areas of concern: 1. The VTA was ponded with evidence of having overtopped and discharged through the channel located at the southwest corner. 2. Manure storage pond 2 was beyond its maximum capacity. 4. LIST OF ATTACHMENTS A) Aerial photograph of Ranovael Dairy with buildings, waterways and discharge pathways labeled. B) Photo Log C) Sampling Results 12 Calf Barn Redacted For Privacy Milking Parlor Machine Shed Dry Cow Barn Freestall Barn Freestall Barn Freestall Barn Feed Storage Area Commodity Shed Manure Storage Pond 1 Ponded Vegetated Treatment Area S02 S01 S03 Heiffer Barn 4 S04 Heiffer Barn 3 Heiffer Barn 2 Manure Storage Pond 2 Heiffer Barn 1 . 1 inch = 217 feet Ranovael Dairy, LLC 1244 County Road U De Pere, Wisconsin 54115 Oneida Reservation Brown County 44.434399, -88.189796 Legend Feed Storage Area National Hydrography Dataset Mapped Waterway Flow Path Observed !R Sampling Location Flow of Unnamed Intermittent Tributary As Observed During Inspection Source: Esri, DigitalGlobe, GeoEye, Earthstar Geographics, CNES/Airbus DS, USDA, USGS, AeroGRID, IGN, and the GIS User Community RANOVAEL DAIRY LLC EPA Inspection 07/15/2021 All photos taken by Cheryl Burdett, Environmental Scientist, U.S. EPA Camera: RICOH WG-4 GPS NOTE: Photos RIMG0001 - RIMG0008 were taken with an incorrect time and date set on the camera. Beginning with RIMG0009, the date and time were set by GPS. Times for photos RIMG0001-RIMG0008 are best estimates based on subsequent photos and elapsed time between photos. 1: RIMG0001 Description: Looking east along the north end of the feed storage area. Note the wrapped round hay bales (blue arrows), western silage mound (green arrow) and eastern silage mound (red arrow). Location: Northwest corner of the feed storage area. Camera Direction: East Date/Time: 07/15/2021 ~8:43 AM Recorded as 1/1/2014 12:02 AM Page 1 Ranovael Diary 07/15/2021 2: RIMG0002 Description: Looking northeast from the north end of the western silage mound. Location: North end of the feed storage area. Camera Direction: Northeast Date/Time: 07/15/2021 ~8:45 AM Recorded as 1/1/2014 12:04 AM 3: RIMG0003 Description: Looking southeast at the open end of the western silage mound. at the base of the silage mound. Location: North end of the feed storage area. Camera Direction: Southeast Date/Time: 07/15/2021 ~8:46 AM Recorded as 1/1/2014 12:05 AM Note the darkly colored leachate Page 2 Ranovael Diary 07/15/2021 4: RIMG0004 Description: Looking south along the east side of the western silage mound. Note the flow path with darkly colored leachate and runoff. The ponded vegetated treatment area is in the distance. The red arrow indicates the direction of flow of the leachate and runoff. Location: North end of the feed storage area and northeast of the western silage mound. Camera Direction: South Date/Time: 07/15/2021 ~8:46 AM Recorded as 1/1/2014 12:05 AM 5: RIMG0005 Description: Darkly colored leachate and runoff flowing toward the ponded vegetated treatment area. Location: North end of the feed storage area and northeast of the western silage mound. Camera Direction: South Date/Time: 07/15/2021 ~8:47 AM Recorded as 1/1/2014 12:06 AM Page 3 Ranovael Diary 07/15/2021 6: RIMG0006 Description: North end of the ponded vegetated treatment area. This structure was designed to be a manually operated first flush collection system. Location: North end of the ponded vegetated treatment area. Camera Direction: Southwest Date/Time: 07/15/2021 ~8:48 AM Recorded as 1/1/2014 12:07 AM 7: RIMG0007 Description: Looking south along the northern part of the ponded vegetated treatment area. Location: North end of the ponded vegetated treatment area. Camera Direction: South Date/Time: 07/15/2021 ~8:48 AM Recorded as 1/1/2014 12:07 AM Page 4 Ranovael Diary 07/15/2021 8: RIMG0008 Description: :Looking east toward the west end of the eastern silage mound. Location: The north end of the feed storage area. Camera Direction: East Date/Time: 07/15/2021 ~8:50 recorded as 1/1/2014 12:09 AM Page 5 Ranovael Diary 07/15/2021 9: RIMG0009 Description: Surface water observed on top of the southern berm of the ponded vegetated treatment area. Location: Berm along the southside of the ponded vegetated treatment area. Camera Direction: Down. Date/Time: 07/15/2021 9:00 AM Page 6 Ranovael Diary 07/15/2021 10: RIMG0010 Description: Surface water flowing south toward the unnamed intermittent tributary. Location: Berm along the southeast side of the ponded vegetated treatment area. Camera Direction: Down Date/Time: 07/15/2021 9:00 AM 11: RIMG0011 Description: Surface water flowing south toward the unnamed intermittent tributary. Location: Berm along the southeast side of the ponded vegetated treatment area. Camera Direction: Down Date/Time: 07/15/2021 9:01 AM Page 7 Ranovael Diary 07/15/2021 12: RIMG0012 Description: Duckweed covered liquid within the ponded vegetated treatment area. the liquid elevation to the top of the berm. Location: Berm along the southeast side of the ponded vegetated treatment area. Camera Direction: North Date/Time: 07/15/20219:03 AM Note the close proximity of 13: RIMG0013 Description: Duckweed covered liquid within the ponded vegetated treatment area. the liquid elevation to the top of the berm. Location: Berm along the southeast side of the ponded vegetated treatment area. Camera Direction: North Date/Time: 07/15/2021 9:04 AM Note the close proximity of Page 8 Ranovael Diary 07/15/2021 14: RIMG0014 Description: Duckweed covered liquid within the ponded vegetated treatment area. the liquid elevation to the top of the berm. Location: Berm along the southeast side of the ponded vegetated treatment area. Camera Direction: North Date/Time: 07/15/2021 9:04 AM Note the close proximity of 15: RIMG0015 Description: Water flowing toward the unnamed intermittent tributaty within a chanelized flow path south of the ponded vegetated treatment area. Location: North of the unnamed intermittent tributary and south of the ponded vegetated treatment area. Camera Direction: Down Date/Time: 07/15/2021 9:08 AM Page 9 Ranovael Diary 07/15/2021 16: RIMG0016 Description: Ponded water along the banks of the unnamed intermittent tributary. Location: North of the unnamed intermittent tributary and south of the ponded vegetated treatment area. Camera Direction: Southwest Date/Time: 07/15/2021 9:08 AM 17: RIMG0017 Description: The unnamed intermittent tributary. Location: South of the ponded vegetated treatment area. Camera Direction: South Date/Time: 07/15/2021 9:08 AM Page 10 Ranovael Diary 07/15/2021 18: RIMG0018 Description: The unnamed intermittent tributary. Location: South of the ponded vegetated treatment area. Camera Direction: South Date/Time: 07/15/2021 9:08 AM 19: RIMG0019 Description: Facing south along the slope down to the unnamed intermittent tributary. There appeared to be a seep or spring coming from the embankment (red arrow) flowing down to the tributary. Location: South of the ponded vegetated treatment area. Camera Direction: South Date/Time: 07/15/2021 9:10 AM Page 11 Ranovael Diary 07/15/2021 20: RIMG0020 Description: The unnamed intermittent tributary. Note that the tributary was high (water level indicated by blue line). Location: South of the ponded vegetated treatment area. Camera Direction: South Date/Time: 07/15/2021 9:10 AM 21: RIMG0021 Description: The unnamed intermittent tributary. Note that the tributary was high (water level indicated by blue line). Location: South of the ponded vegetated treatment area. Camera Direction: South Date/Time: 07/15/2021 9:10 AM Page 12 Ranovael Diary 07/15/2021 22: RIMG0022 Description: Water flowing south in flowpath towards the unnamed intermittent tributary. Location: North of the unnamed intermittent tributary and south of southwest side of the vegetated treatment area. Camera Direction: South Date/Time: 07/15/2021 9:11 AM 23: RIMG0023 Description: View west along the north edge of the feed storage area. Location: Northeast corner of the feed storage area. Camera Direction: West Date/Time: 07/15/2021 9:27 AM Page 13 Ranovael Diary 07/15/2021 24: RIMG0024 Description: View west along the north edge of the feed storage area. Location: Top of the concrete wall in the northeast corner of the feed storage area. Camera Direction: West Date/Time: 07/15/2021 9:27 AM 25: RIMG0025 Description: Looking southwest. Location: Top of the concrete wall in the northeast corner of the feed storage area. Camera Direction: Southwest Date/Time: 07/15/2021 9:27 AM Page 14 Ranovael Diary 07/15/2021 26: RIMG0026 Description: A mound of what appeared to be used bedding or waste feed located east of the feed storage area. Location: East of the feed storage area. Camera Direction: Southwest Date/Time: 07/15/2021 9:29 AM 27: RIMG0027 Description: Looking north along cattle walkway at the east end of the (nearest to furthest away) freestall barn 1, freestall barn 2, and dry cow barn. These barns were not in use at the time of the inspection. Location: Southeast of freestall barn 1. Camera Direction: North Date/Time: 07/15/2021 9:32 AM Page 15 Ranovael Diary 07/15/2021 28: RIMG0028 Description: Depth marker on western edge of manure storage pond 1. crusted over and growing vegitation. Location: Western edge of manure storage pond 1. Camera Direction: East Date/Time: 07/15/2021 9:35 AM Note that the manure storage pond is 29: RIMG0029 Description: Depth marker on western edge of manure storage pond 1. crusted over and growing vegitation. Location: Western edge of manure storage pond 1. Camera Direction: East Date/Time: 07/15/2021 9:35 AM Note that the manure storage pond is Page 16 Ranovael Diary 07/15/2021 30: RIMG0030 Description: Error photo. Location: Camera Direction: Date/Time: 07/15/2021 9:36 AM 31: RIMG0031 Description: Looking east along the north side of the manure storage pond 1. Location: Northwest corner of manure storage pond 1. Camera Direction: East Date/Time: 07/15/2021 9:39 AM Page 17 Ranovael Diary 07/15/2021 32: RIMG0032 Description: Water flowing north to the unnamed intermittent tributary northeast of the facilty. Location: Approximately 200 feet northeast of the northeast corner of manure storage pond 1. Camera Direction: Down Date/Time: 07/15/2021 9:56 AM 33: RIMG0033 Description: Water flowing north to the unnamed intermittent tributary northeast of the facilty. Location: Approximately 200 feet northeast of the northeast corner of manure storage pond 1. Camera Direction: Down Date/Time: 07/15/2021 9:56 AM Page 18 Ranovael Diary 07/15/2021 34: RIMG0034 Description: Looking north along the chanel conveying flow to the unnamed intermittent tributary. Location: Approximately 200 feet northeast of the northeast corner of manure storage pond 1. Camera Direction: North Date/Time: 07/15/2021 9:57 AM Page 19 Ranovael Diary 07/15/2021 35: RIMG0035 Description: Looking west, upstream, along the unnamed intermittent tributary. Location: Approximately 200 feet northeast of the northeast corner of manure storage pond 1. Camera Direction: West Date/Time: 07/15/2021 9:57 AM Page 20 Ranovael Diary 07/15/2021 36: RIMG0036 Description: Looking east, downstream, along the unnamed intermittent tributary. Location: Approximately 200 feet northeast of the northeast corner of manure storage pond 1. Camera Direction: East Date/Time: 07/15/2021 9:57 AM Page 21 Ranovael Diary 07/15/2021 37: RIMG0037 Description: Looking southeast along flow path. Location: Northeast of manure storage pond 1. Camera Direction: Southeast Date/Time: 07/15/2021 9:58 AM Page 22 Ranovael Diary 07/15/2021 38: RIMG0038 Description: Close up of water in flow path. Location: Northeast of manure storage pond 1. Camera Direction: Down Date/Time: 07/15/2021 9:59 AM Page 23 Ranovael Diary 07/15/2021 39: RIMG0039 Description: Following the flow path upstream as it passes under a direction of the flowpath through the tall grass. Location: Notheast of manure storage pond 1. Camera Direction: Southeast Date/Time: 07/15/2021 9:59 AM wire fence. The blue line highlights the Page 24 Ranovael Diary 07/15/2021 40: RIMG0040 Description: Showing the flowpath conveying flow under the fence seen in photos 37 and 39. Location: Notheast of manure storage pond 1. Camera Direction: Southeast Date/Time: 07/15/2021 10:00 AM Page 25 Ranovael Diary 07/15/2021 41: RIMG0041 Description: Water in the flowpath. Location: Southeast of the southeast corner of manure storage pond 1. Camera Direction: Southeast Date/Time: 07/15/2021 10:07 AM 42: RIMG0042 Description: View east along the flowpath. Location: Southeast of the southeast corner of manure storage pond 1. Camera Direction: East Date/Time: 07/15/2021 10:07 AM Page 26 Ranovael Diary 07/15/2021 43: RIMG0043 Description: Looking west along the flow path Location: South of manure storage pond 1. Camera Direction: West Date/Time: 07/15/2021 10:09 AM 44: RIMG0044 Description: Looking west along the flow path Location: South of manure storage pond 1. Camera Direction: West Date/Time: 07/15/2021 10:10 AM Page 27 Ranovael Diary 07/15/2021 45: RIMG0045 Description: Looking southwest along flowpath. Note culvert under animal walking path. Location: South of manure storage pond 1 at entrance to pastures. Camera Direction: Southwest Date/Time: 07/15/2021 10:10 AM 46: RIMG0046 Description: Looking west at the upstream side of culvert under the animal walking path Location: South of manure storage pond 1 at entrance to pastures. Camera Direction: West Date/Time: 07/15/2021 10:12 AM Page 28 Ranovael Diary 07/15/2021 47: RIMG0047 Description: Flow path entering culvert. Location: South of manure storage pond 1. Camera Direction: North Date/Time: 07/15/2021 10:13 AM 48: RIMG0048 Description: Looking soutwest across pastures. Heifer barn 2 visible in distance. Location: South of manure storage pond 1. Camera Direction: Southwest Date/Time: 07/15/2021 10:15 AM Page 29 Ranovael Diary 07/15/2021 49: RIMG0049 Description: Looking east along the south end of the the southern portion of the facility. Location: Southwest corner of the facility. Camera Direction: East Date/Time: 07/15/2021 10:31 AM 50: RIMG0050 Description: Outdoor lots associated with heifer barn 2 (near) and heifer barn 1 (in distance). feedlane flowing to the south (red arrow). Location: South of heifer barn 2. Camera Direction: West Date/Time: 07/15/2021 10:33 AM Note runoff from Page 30 Ranovael Diary 07/15/2021 51: RIMG0051 Description: Solid manure stacked in outdoor lot of heifer barn 1. Location: Southeast of heifer barn 1. Camera Direction: Northwest Date/Time: 07/15/2021 10:33 AM 52: RIMG0052 Description: Ponded water standing in gravel area where wrapped round hay bales are being stored. Location: South of heifer barn 2. Camera Direction: Southwest Date/Time: 07/15/2021 10:33 AM Page 31 Ranovael Diary 07/15/2021 52: RIMG0053 Description: Field to the south of the gravel area where wrapped round hay bales are being stored. Location: South of heifer barn 1. Camera Direction: South Date/Time: 07/15/2021 10:37 AM Page 32 Ranovael Diary 07/15/2021 53: RIMG0054 Description: Solid manure stacked in bunker north of heifer barn 1. Location: North of heifer barn 1. Camera Direction: Southeast Date/Time: 07/15/2021 10:44 AM 54: RIMG0055 Description: Solid manure stacked in bunker north of heifer barn 1. Location: North of heifer barn 1. Camera Direction: East Date/Time: 07/15/2021 10:45 AM Page 33 Ranovael Diary 07/15/2021 55: RIMG0056 Description: Solid manure stacked in bunker north of heifer barn 1. Location: North of heifer barn 1. Camera Direction: North Date/Time: 07/15/2021 10:45 AM 56: RIMG0057 Description: Concrete lot with manure solids. Location: North of heifer barn 1. Camera Direction: East Date/Time: 07/15/2021 10:46 AM Manure storage pond 2 in distance. Page 34 Ranovael Diary 07/15/2021 57: RIMG0058 Description: Concrete lot north of heifer barn 1 and heifer barn 2. Runoff from the heifer barns drains through this lot to the manure storage pond 2 to the left (blue arrow indicates direction of flow). Location: Concrete lot north of heifer barn 1 and heifer barn 2 Camera Direction: South Date/Time: 07/15/2021 10:47 AM 58: RIMG0059 Description: Manure storage pond 2. Note that the level of manure within the pond has backed up into the concrete lot to west. Location: West side of manure storage pond 2. Camera Direction: East Date/Time: 07/15/2021 10:48 AM Page 35 Ranovael Diary 07/15/2021 59: RIMG0060 Description: Looking along the northeast side of manure storage pond 2 from the northeast corner. Heifer barn 2 in the distance to the right. Location: Northeast corner of manure storage pond 2. Camera Direction: Southeast Date/Time: 07/15/2021 10:49 AM 60: RIMG0061 Description:Looking south along gravel access road northeast of heifer barn 2. Location: East of manure storage pond 2. Camera Direction: South Date/Time: 07/15/2021 11:06 AM Page 36 Ranovael Diary 07/15/2021 61: RIMG0062 Description: Looking northeast across pastures. Location: East of manure storage pond 2. Camera Direction: Northeast Date/Time: 07/15/2021 11:06 AM 62: RIMG0063 Description: Looking north along gravel access road east of manure storage pond 2 and heifer barn 2. Location: East of manure storage pond 2. Camera Direction:North Date/Time: 07/15/2021 11:07 AM Page 37 Ranovael Diary 07/15/2021 63: RIMG0064 Description: Ponded water in pasture east of heifer barn 2. Location: East of heifer barn 2. Camera Direction: East Date/Time: 07/15/2021 11:08 AM 64: RIMG0065 Description: Field blank collected at vehicle while at facility. Location: At vehicle. Camera Direction: North Date/Time: 07/15/2021 11:24 AM Page 38 Ranovael Diary 07/15/2021 65: RIMG0066 Description: Chanel at top of berm on southwest corner of the ponded vegetated treatment area. Location: Southwest corner of ponded vegetated treatment area. Camera Direction: North Date/Time: 07/15/2021 11:44 AM Page 39 Ranovael Diary 07/15/2021 66: RIMG0067 Description: Flow path with duckweek present. Location: Southwest corner of ponded vegetated treatment area. Camera Direction: Down Date/Time: 07/15/2021 11:44 AM Page 40 Ranovael Diary 07/15/2021 67: RIMG0068 Description: Duckweed within the ponded vegetated treatment area just before the channel observed in photos 66 and 67. Location: Southwest corner of ponded vegetated treatment area. Camera Direction: Down Date/Time: 07/15/2021 11:44 AM Page 41 Ranovael Diary 07/15/2021 68: RIMG0069 Description: Erosional flow path from the top of the berm at the southwest corner of the ponded vegetated treatment area down to the unnamed intermittent tributary. Location: Southwest corner of ponded vegetated treatment area. Camera Direction: South Date/Time: 07/15/2021 11:44 AM Page 42 Ranovael Diary 07/15/2021 69: RIMG0070 Description: Erosional flow path from the top of the berm at the southwest corner of the ponded vegetated treatment area down to the unnamed intermittent tributary. Location: Southwest corner of ponded vegetated treatment area. Camera Direction: South Date/Time: 07/15/2021 11:45 AM Page 43 Ranovael Diary 07/15/2021 70: RIMG0071 Description: Duckweed in flow path. Location: Erosional flow path from the top of the berm at the southwest corner of the ponded vegetated treatment area. Camera Direction: Down Date/Time: 07/15/2021 11:45 AM 71: RIMG0072 Description: Duckweed in flow path. Location: Erosional flow path from the top of the berm at the southwest corner of the ponded vegetated treatment area Camera Direction: Down Date/Time: 07/15/2021 11:45 AM Page 44 Ranovael Diary 07/15/2021 72: RIMG0073 Description: Duckweed in flow path. Location: Erosional flow path from the top of the berm at the southwest corner of the ponded vegetated treatment area. Camera Direction: Down Date/Time: 07/15/2021 11:45 AM Page 45 Ranovael Diary 07/15/2021 73: RIMG0074 Description: Flow path entering the unnamed intermittent tributary. Location: Erosional flow path from the top of the berm at the southwest corner of the ponded vegetated treatment area. Camera Direction: South. Date/Time: 07/15/2021 11:45 AM Page 46 Ranovael Diary 07/15/2021 74: RIMG0075 Description: The unnamed intermittent tributary. Location: South of the ponded vegetated treatment area. Camera Direction: South Date/Time: 07/15/2021 11:45 AM 75: RIMG0076 Description: Sample S01 collected from the channel at the top the berm. Location: Erosional flow path from the top of the berm at the southwest corner of the ponded vegetated treatment area. Camera Direction: Down Date/Time: 07/15/2021 11:49 AM Page 47 Ranovael Diary 07/15/2021 76: RIMG0077 Description: Sample S01 collected from the channel at the top the berm. Location: Erosional flow path from the top of the berm at the southwest corner of the ponded vegetated treatment area. Camera Direction: North Date/Time: 07/15/2021 11:50 AM Page 48 Ranovael Diary 07/15/2021 77: RIMG0078 Description: Sample S02, collected from the ponded vegetated treatment area. Location: Southwest corner of the ponded vegetated treatment area. Camera Direction: Down Date/Time: 07/15/2021 11:53 AM 78: RIMG0079 Description: Sample S02, collected from the ponded vegetated treatment area. Location: Southwest corner of the ponded vegetated treatment area. Camera Direction: North Date/Time: 07/15/2021 11:53 AM Page 49 Ranovael Diary 07/15/2021 79: RIMG0080 Description: Sample S03 from unnamed intermittent tributary downstream of errosional pathway. Location: North bank of the unnamed intermittent tributary downstream of the errosional pathway. Camera Direction: South Date/Time: 07/15/2021 12:00 PM 80: RIMG0081 Description: Sample S04 from unnamed intermittent tributary upstream of discharge on the west side of County Road U. Location: North bank of the unnamed intermittent tributary west of County Road U. Camera Direction: South Date/Time: 07/15/2021 12:08 PM Page 50 Ranovael Diary 07/15/2021 81: RIMG0082 Description: Looking upstream along the unnamed intermittent tributary from sampling location of sample S04. Location: North bank of the unnamed intermittent tributary west of County Road U. Camera Direction: Southwest Date/Time: 07/15/2021 82: RIMG0083 Description: Looking southeast downstream under the County Road U bridge over the unnamed intermittent tributary from sample S04 collection location. Location: North bank of the unnamed intermittent tributary west of County Road U. Camera Direction: Southeast Date/Time: 07/15/2021 Page 51 Ranovael Diary 07/15/2021 UNITED STATES ENVIRONMENTAL PROTECTION AGENCY US EPA Region 5 LSASD Analytical Services Branch 536 SOUTH CLARK STREET CHICAGO, ILLINOIS 60605 Date: 8/26/2021 Title: To: From: ASB Data Report for Ranovael Water Division, US EPA Region 5 77 West Jackson Boulevard Chicago, IL 60604 Colin Breslin, Chemist breslin.colin@epa.gov US EPA Region 5 LSASD Analytical Services Branch The results reported in this document apply to the samples as received and relate only to the items tested. The data transmitted under this cover memo successfully passed the data review process and applicable Analytical Services Branch (ASB) laboratory Standard Operating Procedures. In accordance with the EPA QA/G-8 Guidance on Environmental Data Verification and Data Validation, ASB performs data verification on all the data generated internally. ASB does not perform data validation or quality assessment procedures. This report was reviewed and the information provided herein accurately represents the analysis performed. Please contact the analyst with any technical report issues, Amanda Wroble at (312)-353-0375 for sample project concerns, and Robert Snyder at (312)-353-9083 with data transmittal questions. Thank you. Attached are Results for: Ranovael Analyses included in this report: BOD Report Name: 2107010 BOD FINAL Aug 26 21 0911 Page 1 of 9 Water Division, US EPA Region 5 77 West Jackson Boulevard Chicago IL, 60604 Environmental Protection Agency Region 5 US EPA Region 5 LSASD Analytical Services Branch 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 Project: Ranovael Project Number: 02BA2021 Project Manager: Ben Atkinson Accredited Analyses included in this Report Reported: Aug-26-21 09:11 Method: Analysis: Analyte SM 5210 B in Water BOD Biochemical Oxygen Demand Certifications ISO/IEC 17025:2017 Analytes not listed above are not accredited by ANAB. Report Name: 2107010 BOD FINAL Aug 26 21 0911 Page 2 of 9 Water Division, US EPA Region 5 77 West Jackson Boulevard Chicago IL, 60604 Environmental Protection Agency Region 5 US EPA Region 5 LSASD Analytical Services Branch 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 Project: Ranovael Project Number: 02BA2021 Project Manager: Ben Atkinson Reported: Aug-26-21 09:11 ANALYSIS CASE NARRATIVE General Information Analyst: Colin Breslin Phone Number: 312-886-2912 Sample 2107010-01 2107010-02 2107010-03 2107010-04 2107010-05 Analysis List BOD BOD BOD BOD BOD All holding times were met. The samples were prepared and analyzed using laboratory SOP AIG006A, Version #6, based on: Method List SM 5210 B Additionally, a Pen&Ink document (ID# 23911) was used to document the SOP change from a dissolved oxygen membrane probe to a dissolved oxygen optical probe. Sample Analysis and Results The data reported herein meets any requirements referenced in the previously mentioned SOP and Sampling QAPP titled "General Field Sampling Plan for AFO Inspections" and dated FY 2021. QAPP and laboratory reporting limit requirements were met. The MDL is not applicable to BOD. Samples with laboratory identification numbers 2107010-04 and 2107010-05 did not have valid depletions of at least 2 mg/L dissolved oxygen (DO) from the initial day to the final day across the dilution series and were flagged as estimated. All other sample results had valid depletions. See below under quality control for additional impacts to sample results. Quality Control All quality control audits were within laboratory limits or did not result in qualification of the data, except as Report Name: 2107010 BOD FINAL Aug 26 21 0911 Page 3 of 9 Water Division, US EPA Region 5 77 West Jackson Boulevard Chicago IL, 60604 Environmental Protection Agency Region 5 US EPA Region 5 LSASD Analytical Services Branch 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 Project: Ranovael Project Number: 02BA2021 Project Manager: Ben Atkinson Reported: Aug-26-21 09:11 follows: Blanks and Continuing Checks for the Dissolved Oxygen (DO) Probe: Dilution water with no seed (DWNS) blank checks were recovered at 0.31 mg/L and 0.20 mg/L. One DWNS result was outside of the control limit and one was inside the limit of +/- 0.20 mg/L. One DO probe check on the final day of readings drifted a maximum of -0.26 mg/L from the expected DO result, which exceeded the allowance of +/- 0.20 mg/L. Sample results that were greater than ten times the absolute value of the DWNS blank exceedance were not qualified. Samples that were affected by the DO Probe check were flagged with a potential low bias, which was sample 2107010-02. Sample with laboratory identification number 2107010-01 was affected by the high DWNS blank and low DO probe drift, and was flagged as estimated for the offsetting factors, in addition to already being flagged for invalid depletions. Report Name: 2107010 BOD FINAL Aug 26 21 0911 Page 4 of 9 01234516718945878351717351 395735199549854 !"#$#%%& '(")&*+,, -.%/0123456, 7"8/0123554291 ?@A@<0 BCDEDCD :;07351;;<19839;74237=>491 43187KHELBDLBDBCCBHBEHMBN 3718H ?9874<323=351F:;07351 45G78H915297 45G78N91974H 179@ O49==9<923= 45G78IJ674H DB>BDBC 7P548Q5H Z%.X$'.U. R"%#S'T'U'.&VW-XY%)'. S"%S%/ Y%(%'T%\Z^/ +))%\*.Z^/ X)4,4211/,,0]\"^_X_3 !'.Z#%U!'. `%!U%^abc"!!%^ 66R%U["($U.Z!%T"#\ '(")&*+,,] S"%Y%(%'T%\/ [!41421,5/] S"%+))%\*./ [!41421,9/9 -.%/012342,,] 7"8/01235542,,1 "de!%")Uf!"g%!U %"!U*."( Y%(%'T%\.'(% -"e%#h#$*.(!\%\ i7= ?54O@4K74566718=H i7= i7= i7= !%#0U3'.j#d"'./ S%j"! !%#4k6, ;96P7l<H BCDEDCDmDC ;96P7KH rJmCmBCCCHBs ;96P7I967H >@C ;96P7566718=H 19 =3= Xdd.'"tSX&S'U'!!%\ o5K8367pK9=q 25 ZaS 2 t'#"%4t'#'%tSX&W.w^d"'(#%\('. 25 !'\U&_S 6 !'\U&_ 6 _`tSX 25 _"!-Ue#USX 25 N9843nH ?9874 ;96P7598351L566718=H 915297 0nP347= X)41242111/2 [!41642111/2 X)41242111/2 [!42242111/2 [!42242111/2 X)41242111/2 X)41242111/2 566718= euv1 euv6 euv1 euv6 euv6 euv1 euv1 ;96P7l<H BCDEDCDmDB ;96P7KH rJmCmBCCCHM{ N9843nH ?9874 ;96P7I967H ;@C ;96P7598351L566718=H @274x5yx456zQ ;96P7566718=H 19 =3= Xdd.'"tSX&S'U'!!%\ o5K8367pK9=q 0nP347= 566718= 25 X)41242111/]9 euv1 ZaS 2 [!41642111/]9 euv6 t'#"%4t'#'%tSX&W.w^d"'(#%\('. 25 X)41242111/]9 euv1 |Pa}~ge5of9 Page 6 of 9 Page 7 of 9 Water Division, US EPA Region 5 77 West Jackson Boulevard Chicago IL, 60604 Environmental Protection Agency Region 5 US EPA Region 5 LSASD Analytical Services Branch 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 Project: Ranovael Project Number: 02BA2021 Project Manager: Ben Atkinson Reported: Aug-26-21 09:11 BO1 (2107010-01) Analyte Biochemical Oxygen Demand SO1 (2107010-02) Analyte Biochemical Oxygen Demand SO2 (2107010-03) Analyte Biochemical Oxygen Demand SO3 (2107010-04) Analyte Biochemical Oxygen Demand SO4 (2107010-05) Analyte Biochemical Oxygen Demand BOD, 5 day, SM 5210 B (modified) US EPA Region 5 LSASD Analytical Services Branch Matrix: Water Sampled: Jul-15-21 11:23 Result Flags / Qualifiers MDL Reporting Limit 3 (BLK), 2 (CCV), J Matrix: Water Sampled: Jul-15-21 11:49 Result Flags / Qualifiers MDL Reporting Limit 57 (CCV), L 2 Received: Jul-16-21 08:46 Units mg/L Dilution 1 Batch B21G021 Received: Jul-16-21 08:46 Units mg/L Dilution 1 Batch B21G021 Matrix: Water Sampled: Jul-15-21 11:52 Result Flags / Qualifiers MDL Reporting Limit 34 2 Received: Jul-16-21 08:46 Units mg/L Dilution 1 Batch B21G021 Matrix: Water Sampled: Jul-15-21 12:00 Result Flags / Qualifiers MDL Reporting Limit 7 (BOD4), J 2 Received: Jul-16-21 08:46 Units mg/L Dilution 1 Batch B21G021 Matrix: Water Sampled: Jul-15-21 12:07 Result Flags / Qualifiers MDL Reporting Limit 7 (BOD4), J 2 Received: Jul-16-21 08:46 Units mg/L Dilution 1 Batch B21G021 Prepared Jul-16-21 Prepared Jul-16-21 Prepared Jul-16-21 Prepared Jul-16-21 Prepared Jul-16-21 Analyzed Jul-16-21 Analyzed Jul-16-21 Analyzed Jul-16-21 Analyzed Jul-16-21 Analyzed Jul-16-21 Report Name: 2107010 BOD FINAL Aug 26 21 0911 Page 8 of 9 Water Division, US EPA Region 5 77 West Jackson Boulevard Chicago IL, 60604 Environmental Protection Agency Region 5 US EPA Region 5 LSASD Analytical Services Branch 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 Project: Ranovael Project Number: 02BA2021 Project Manager: Ben Atkinson Reported: Aug-26-21 09:11 L J * (CCV) (BOD4) (BOD2) (BOD1) (BLK) U NR Q Notes and Definitions The identification of the analyte is acceptable; the reported value may be biased low. The actual value is expected to be greater than the reported value. The identification of the analyte is acceptable; the reported value is an estimate. This Quality Control measure meets the requirements of the CRL SOP for this analyte. Continuing calibration verification criteria not met for this analyte The samples did not have valid depletions of at least 2 mg/L dissolved oxygen (DO) from the initial day to the final day across the dilution series. BLK3 & BLK4: DWS recommended range is ~0.6 - 1 mg/L. BS4: Average GGA result of BS1, BS2, and BS3 used for final evaluation of QC limit. Method blank criteria not met for this analyte. Not Detected Not Reported QC limit Exceeded Report Name: 2107010 BOD FINAL Aug 26 21 0911 Page 9 of 9 UNITED STATES ENVIRONMENTAL PROTECTION AGENCY US EPA Region 5 LSASD Analytical Services Branch 536 SOUTH CLARK STREET CHICAGO, ILLINOIS 60605 Date: 8/26/2021 Title: To: From: ASB Data Report for Ranovael Water Division, US EPA Region 5 77 West Jackson Boulevard Chicago, IL 60604 Colin Breslin, Chemist breslin.colin@epa.gov US EPA Region 5 LSASD Analytical Services Branch The results reported in this document apply to the samples as received and relate only to the items tested. The data transmitted under this cover memo successfully passed the data review process and applicable Analytical Services Branch (ASB) laboratory Standard Operating Procedures. In accordance with the EPA QA/G-8 Guidance on Environmental Data Verification and Data Validation, ASB performs data verification on all the data generated internally. ASB does not perform data validation or quality assessment procedures. This report was reviewed and the information provided herein accurately represents the analysis performed. Please contact the analyst with any technical report issues, Amanda Wroble at (312)-353-0375 for sample project concerns, and Robert Snyder at (312)-353-9083 with data transmittal questions. Thank you. Attached are Results for: Ranovael Analyses included in this report: Nitrate-Nitrite N DA, Enzymatic reduction Report Name: 2107010 Nitrate-Nitrite N DA, Enzymatic reduction FINAL Aug 26 21 0926 Page 1 of 9 Water Division, US EPA Region 5 77 West Jackson Boulevard Chicago IL, 60604 Environmental Protection Agency Region 5 US EPA Region 5 LSASD Analytical Services Branch 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 Project: Ranovael Project Number: 02BA2021 Project Manager: Ben Atkinson Accredited Analyses included in this Report Reported: Aug-26-21 09:26 Method: Analysis: Analyte NECi Method NO7-0003 in Water Nitrate-Nitrite N DA, Enzymatic reduction Nitrate-Nitrite N Certifications ISO/IEC 17025:2017 Analytes not listed above are not accredited by ANAB. Report Name: 2107010 Nitrate-Nitrite N DA, Enzymatic reduction FINAL Aug 26 21 0926 Page 2 of 9 Water Division, US EPA Region 5 77 West Jackson Boulevard Chicago IL, 60604 Environmental Protection Agency Region 5 US EPA Region 5 LSASD Analytical Services Branch 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 Project: Ranovael Project Number: 02BA2021 Project Manager: Ben Atkinson Reported: Aug-26-21 09:26 ANALYSIS CASE NARRATIVE General Information Analyst: Colin Breslin Phone Number: 312-886-2912 Sample 2107010-01 2107010-02 2107010-03 2107010-04 2107010-05 Analysis List Nitrate-Nitrite N DA, Enzymatic reduction Nitrate-Nitrite N DA, Enzymatic reduction Nitrate-Nitrite N DA, Enzymatic reduction Nitrate-Nitrite N DA, Enzymatic reduction Nitrate-Nitrite N DA, Enzymatic reduction All holding times were met. The samples were prepared and analyzed using laboratory SOP AIG031B, Version #6, based on: Method List NECi Method NO7-0003 Sample Analysis and Results The data reported herein meets any requirements referenced in the previously mentioned SOP and Sampling QAPP titled "General Field Sampling Plan for AFO Inspections" and dated "FY 2021". QAPP and laboratory reporting limit requirements were met, and results were reported to the MDL. Quality Control All quality control audits were within laboratory limits or did not result in qualification of the data, except as follows: Laboratory Control Sample (LCS)/Blank Spike (BS) B21G025-BS6 Recovery for Nitrate-Nitrite N (111%) was outside acceptance limits (90-110%) for Nitrate-Nitrite N DA, Enzymatic reduction. Affected sample results were qualified accordingly. Non-detect results were not impacted by the high bias and remain unflagged. Report Name: 2107010 Nitrate-Nitrite N DA, Enzymatic reduction FINAL Aug 26 21 0926 Page 3 of 9 Water Division, US EPA Region 5 77 West Jackson Boulevard Chicago IL, 60604 Environmental Protection Agency Region 5 US EPA Region 5 LSASD Analytical Services Branch 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 Project: Ranovael Project Number: 02BA2021 Project Manager: Ben Atkinson Reported: Aug-26-21 09:26 Report Name: 2107010 Nitrate-Nitrite N DA, Enzymatic reduction FINAL Aug 26 21 0926 Page 4 of 9 01234516718945878351717351 395735199549854 !"#$#%%& '(")&*+,, -.%/0123456, 7"8/0123554291 ?@A@<0 BCDEDCD :;07351;;<19839;74237=>491 43187KHELBDLBDBCCBHBEHMBN 3718H ?9874<323=351F:;07351 45G78H915297 45G78N91974H 179@ O49==9<923= 45G78IJ674H DB>BDBC 7P548Q5H Z%.X$'.U. R"%#S'T'U'.&VW-XY%)'. S"%S%/ Y%(%'T%\Z^/ +))%\*.Z^/ X)4,4211/,,0]\"^_X_3 !'.Z#%U!'. `%!U%^abc"!!%^ 66R%U["($U.Z!%T"#\ '(")&*+,,] S"%Y%(%'T%\/ [!41421,5/] S"%+))%\*./ [!41421,9/9 -.%/012342,,] 7"8/01235542,,1 "de!%")Uf!"g%!U %"!U*."( Y%(%'T%\.'(% -"e%#h#$*.(!\%\ i7= ?54O@4K74566718=H i7= i7= i7= !%#0U3'.j#d"'./ S%j"! !%#4k6, ;96P7l<H BCDEDCDmDC ;96P7KH rJmCmBCCCHBs ;96P7I967H >@C ;96P7566718=H 19 =3= Xdd.'"tSX&S'U'!!%\ o5K8367pK9=q 25 ZaS 2 t'#"%4t'#'%tSX&W.w^d"'(#%\('. 25 !'\U&_S 6 !'\U&_ 6 _`tSX 25 _"!-Ue#USX 25 N9843nH ?9874 ;96P7598351L566718=H 915297 0nP347= X)41242111/2 [!41642111/2 X)41242111/2 [!42242111/2 [!42242111/2 X)41242111/2 X)41242111/2 566718= euv1 euv6 euv1 euv6 euv6 euv1 euv1 ;96P7l<H BCDEDCDmDB ;96P7KH rJmCmBCCCHM{ N9843nH ?9874 ;96P7I967H ;@C ;96P7598351L566718=H @274x5yx456zQ ;96P7566718=H 19 =3= Xdd.'"tSX&S'U'!!%\ o5K8367pK9=q 0nP347= 566718= 25 X)41242111/]9 euv1 ZaS 2 [!41642111/]9 euv6 t'#"%4t'#'%tSX&W.w^d"'(#%\('. 25 X)41242111/]9 euv1 |Pa}~ge5of9 Page 6 of 9 Page 7 of 9 Water Division, US EPA Region 5 77 West Jackson Boulevard Chicago IL, 60604 Environmental Protection Agency Region 5 US EPA Region 5 LSASD Analytical Services Branch 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 Project: Ranovael Project Number: 02BA2021 Project Manager: Ben Atkinson Reported: Aug-26-21 09:26 BO1 (2107010-01) Analyte Nitrate-Nitrite N SO1 (2107010-02) Analyte Nitrate-Nitrite N SO2 (2107010-03) Analyte Nitrate-Nitrite N SO3 (2107010-04) Analyte Nitrate-Nitrite N SO4 (2107010-05) Analyte Nitrate-Nitrite N Nitrate-Nitrite Nitrogen, Nitrate Reductase, NECi Method N07-0003 (modified) US EPA Region 5 LSASD Analytical Services Branch Matrix: Water Sampled: Jul-15-21 11:23 Result Flags / Qualifiers MDL Reporting Limit U 0.07 0.10 Received: Jul-16-21 08:46 Units mg/L Dilution 1 Batch B21G025 Prepared Jul-22-21 Matrix: Water Sampled: Jul-15-21 11:49 Result Flags / Qualifiers MDL Reporting Limit 0.08 (LCS), K 0.07 0.10 Received: Jul-16-21 08:46 Units mg/L Dilution 1 Batch B21G025 Prepared Jul-22-21 Matrix: Water Sampled: Jul-15-21 11:52 Result Flags / Qualifiers MDL Reporting Limit U 0.07 0.10 Received: Jul-16-21 08:46 Units mg/L Dilution 1 Batch B21G025 Prepared Jul-22-21 Matrix: Water Sampled: Jul-15-21 12:00 Result Flags / Qualifiers MDL Reporting Limit 2.25 (LCS), K 0.07 0.10 Received: Jul-16-21 08:46 Units mg/L Dilution 1 Batch B21G025 Prepared Jul-22-21 Matrix: Water Sampled: Jul-15-21 12:07 Result Flags / Qualifiers MDL Reporting Limit 2.47 (LCS), K 0.07 0.10 Received: Jul-16-21 08:46 Units mg/L Dilution 1 Batch B21G025 Prepared Jul-22-21 Analyzed Jul-22-21 Analyzed Jul-22-21 Analyzed Jul-22-21 Analyzed Jul-22-21 Analyzed Jul-22-21 Report Name: 2107010 Nitrate-Nitrite N DA, Enzymatic reduction FINAL Aug 26 21 0926 Page 8 of 9 Water Division, US EPA Region 5 77 West Jackson Boulevard Chicago IL, 60604 Environmental Protection Agency Region 5 US EPA Region 5 LSASD Analytical Services Branch 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 Project: Ranovael Project Number: 02BA2021 Project Manager: Ben Atkinson Reported: Aug-26-21 09:26 K (LCS) U NR Q Notes and Definitions The identification of the analyte is acceptable; the reported value may be biased high. The actual value is expected to be less than the reported value. Blank spike recovery criteria not met for this analyte Not Detected Not Reported QC limit Exceeded Report Name: 2107010 Nitrate-Nitrite N DA, Enzymatic reduction FINAL Aug 26 21 0926 Page 9 of 9 UNITED STATES ENVIRONMENTAL PROTECTION AGENCY US EPA Region 5 LSASD Analytical Services Branch 536 SOUTH CLARK STREET CHICAGO, ILLINOIS 60605 Date: 8/17/2021 Title: To: From: ASB Data Report for Ranovael Water Division, US EPA Region 5 77 West Jackson Boulevard Chicago, IL 60604 Christina Rice, Chemist Rice.Christina@epa.gov US EPA Region 5 LSASD Analytical Services Branch The results reported in this document apply to the samples as received and relate only to the items tested. The data transmitted under this cover memo successfully passed the data review process and applicable Analytical Services Branch (ASB) laboratory Standard Operating Procedures. In accordance with the EPA QA/G-8 Guidance on Environmental Data Verification and Data Validation, ASB performs data verification on all the data generated internally. ASB does not perform data validation or quality assessment procedures. This report was reviewed and the information provided herein accurately represents the analysis performed. Please contact the analyst with any technical report issues, Amanda Wroble at (312)-353-0375 for sample project concerns, and Robert Snyder at (312)-353-9083 with data transmittal questions. Thank you. Attached are Results for: Ranovael Analyses included in this report: Solids, TDS Report Name: 2107010 Solids, TDS FINAL Aug 17 21 1212 Page 1 of 8 Water Division, US EPA Region 5 77 West Jackson Boulevard Chicago IL, 60604 Environmental Protection Agency Region 5 US EPA Region 5 LSASD Analytical Services Branch 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 Project: Ranovael Project Number: 02BA2021 Project Manager: Ben Atkinson Accredited Analyses included in this Report Reported: Aug-17-21 12:12 Method: Analysis: Analyte SM 2540 C in Water Solids, TDS Total Dissolved Solids Certifications ISO/IEC 17025:2017 Analytes not listed above are not accredited by ANAB. Report Name: 2107010 Solids, TDS FINAL Aug 17 21 1212 Page 2 of 8 Water Division, US EPA Region 5 77 West Jackson Boulevard Chicago IL, 60604 Environmental Protection Agency Region 5 US EPA Region 5 LSASD Analytical Services Branch 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 Project: Ranovael Project Number: 02BA2021 Project Manager: Ben Atkinson Reported: Aug-17-21 12:12 ANALYSIS CASE NARRATIVE Analysis List Solids, TDS Analyst: Christina Rice Phone #: 312-353-7358 General Information Samples analyzed: Sample Analysis List 2107010-01 Solids, TDS 2107010-02 Solids, TDS 2107010-03 Solids, TDS 2107010-04 Solids, TDS 2107010-05 Solids, TDS Holding times: All holding times were met. Sample Analysis and Results The samples were analyzed using ASB SOP AIG017, Version #7. The samples were stored in the refrigerator at all times, except when in use. The data reported herein meets any requirements referenced in the previously mentioned SOP, except for those listed in the Quality Control section. The original samples were split into a second set by the client for possible use at another laboratory prior to sample analysis as documented in CC 26042. Samples were requested and reported to the MDL. Sample 2107010-02 used a reduced sample size of 20 mL for filtration time exceeding 10 minutes. SOP Based on: Method List SM 2540 C Quality Control All quality control audits were within ASB limits or did not result in qualification of the data. Report Name: 2107010 Solids, TDS FINAL Aug 17 21 1212 Page 3 of 8 01234516718945878351717351 395735199549854 !"#$#%%& '(")&*+,, -.%/0123456, 7"8/0123554291 ?@A@<0 BCDEDCD :;07351;;<19839;74237=>491 43187KHELBDLBDBCCBHBEHMBN 3718H ?9874<323=351F:;07351 45G78H915297 45G78N91974H 179@ O49==9<923= 45G78IJ674H DB>BDBC 7P548Q5H Z%.X$'.U. R"%#S'T'U'.&VW-XY%)'. S"%S%/ Y%(%'T%\Z^/ +))%\*.Z^/ X)4,4211/,,0]\"^_X_3 !'.Z#%U!'. `%!U%^abc"!!%^ 66R%U["($U.Z!%T"#\ '(")&*+,,] S"%Y%(%'T%\/ [!41421,5/] S"%+))%\*./ [!41421,9/9 -.%/012342,,] 7"8/01235542,,1 "de!%")Uf!"g%!U %"!U*."( Y%(%'T%\.'(% -"e%#h#$*.(!\%\ i7= ?54O@4K74566718=H i7= i7= i7= !%#0U3'.j#d"'./ S%j"! !%#4k6, ;96P7l<H BCDEDCDmDC ;96P7KH rJmCmBCCCHBs ;96P7I967H >@C ;96P7566718=H 19 =3= Xdd.'"tSX&S'U'!!%\ o5K8367pK9=q 25 ZaS 2 t'#"%4t'#'%tSX&W.w^d"'(#%\('. 25 !'\U&_S 6 !'\U&_ 6 _`tSX 25 _"!-Ue#USX 25 N9843nH ?9874 ;96P7598351L566718=H 915297 0nP347= X)41242111/2 [!41642111/2 X)41242111/2 [!42242111/2 [!42242111/2 X)41242111/2 X)41242111/2 566718= euv1 euv6 euv1 euv6 euv6 euv1 euv1 ;96P7l<H BCDEDCDmDB ;96P7KH rJmCmBCCCHM{ N9843nH ?9874 ;96P7I967H ;@C ;96P7598351L566718=H @274x5yx456zQ ;96P7566718=H 19 =3= Xdd.'"tSX&S'U'!!%\ o5K8367pK9=q 0nP347= 566718= 25 X)41242111/]9 euv1 ZaS 2 [!41642111/]9 euv6 t'#"%4t'#'%tSX&W.w^d"'(#%\('. 25 X)41242111/]9 euv1 |Pa}~ge4of8 Page 5 of 8 Page 6 of 8 Water Division, US EPA Region 5 77 West Jackson Boulevard Chicago IL, 60604 Environmental Protection Agency Region 5 US EPA Region 5 LSASD Analytical Services Branch 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 Project: Ranovael Project Number: 02BA2021 Project Manager: Ben Atkinson Reported: Aug-17-21 12:12 BO1 (2107010-01) Analyte Total Dissolved Solids SO1 (2107010-02) Analyte Total Dissolved Solids SO2 (2107010-03) Analyte Total Dissolved Solids SO3 (2107010-04) Analyte Total Dissolved Solids SO4 (2107010-05) Analyte Total Dissolved Solids Dissolved Solids, SM 2540C (modified) US EPA Region 5 LSASD Analytical Services Branch Matrix: Water Sampled: Jul-15-21 11:23 Result Flags / Qualifiers MDL Reporting Limit U 16 20 Received: Jul-16-21 08:46 Units mg/L Dilution 1 Batch B21G023 Matrix: Water Sampled: Jul-15-21 11:49 Result Flags / Qualifiers MDL Reporting Limit 425 16 20 Received: Jul-16-21 08:46 Units mg/L Dilution 1 Batch B21G023 Matrix: Water Sampled: Jul-15-21 11:52 Result Flags / Qualifiers MDL Reporting Limit 428 16 20 Received: Jul-16-21 08:46 Units mg/L Dilution 1 Batch B21G023 Matrix: Water Sampled: Jul-15-21 12:00 Result Flags / Qualifiers MDL Reporting Limit 244 16 20 Received: Jul-16-21 08:46 Units mg/L Dilution 1 Batch B21G023 Matrix: Water Sampled: Jul-15-21 12:07 Result Flags / Qualifiers MDL Reporting Limit 240 16 20 Received: Jul-16-21 08:46 Units mg/L Dilution 1 Batch B21G023 Prepared Jul-20-21 Prepared Jul-20-21 Prepared Jul-20-21 Prepared Jul-20-21 Prepared Jul-20-21 Analyzed Jul-20-21 Analyzed Jul-20-21 Analyzed Jul-20-21 Analyzed Jul-20-21 Analyzed Jul-20-21 Report Name: 2107010 Solids, TDS FINAL Aug 17 21 1212 Page 7 of 8 Water Division, US EPA Region 5 77 West Jackson Boulevard Chicago IL, 60604 U Not Detected NR Not Reported Q QC limit Exceeded Environmental Protection Agency Region 5 US EPA Region 5 LSASD Analytical Services Branch 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 Project: Ranovael Project Number: 02BA2021 Project Manager: Ben Atkinson Notes and Definitions Reported: Aug-17-21 12:12 Report Name: 2107010 Solids, TDS FINAL Aug 17 21 1212 Page 8 of 8 UNITED STATES ENVIRONMENTAL PROTECTION AGENCY US EPA Region 5 LSASD Analytical Services Branch 536 SOUTH CLARK STREET CHICAGO, ILLINOIS 60605 Date: 8/17/2021 Title: To: From: ASB Data Report for Ranovael Water Division, US EPA Region 5 77 West Jackson Boulevard Chicago, IL 60604 Christina Rice, Chemist Rice.Christina@epa.gov US EPA Region 5 LSASD Analytical Services Branch The results reported in this document apply to the samples as received and relate only to the items tested. The data transmitted under this cover memo successfully passed the data review process and applicable Analytical Services Branch (ASB) laboratory Standard Operating Procedures. In accordance with the EPA QA/G-8 Guidance on Environmental Data Verification and Data Validation, ASB performs data verification on all the data generated internally. ASB does not perform data validation or quality assessment procedures. This report was reviewed and the information provided herein accurately represents the analysis performed. Please contact the analyst with any technical report issues, Amanda Wroble at (312)-353-0375 for sample project concerns, and Robert Snyder at (312)-353-9083 with data transmittal questions. Thank you. Attached are Results for: Ranovael Analyses included in this report: Solids, TSS Report Name: 2107010 Solids, TSS FINAL Aug 17 21 0908 Page 1 of 8 Water Division, US EPA Region 5 77 West Jackson Boulevard Chicago IL, 60604 Environmental Protection Agency Region 5 US EPA Region 5 LSASD Analytical Services Branch 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 Project: Ranovael Project Number: 02BA2021 Project Manager: Ben Atkinson Accredited Analyses included in this Report Reported: Aug-17-21 09:08 Method: Analysis: Analyte SM 2540 D in Water Solids, TSS Total Suspended Solids Certifications ISO/IEC 17025:2017 Analytes not listed above are not accredited by ANAB. Report Name: 2107010 Solids, TSS FINAL Aug 17 21 0908 Page 2 of 8 Water Division, US EPA Region 5 77 West Jackson Boulevard Chicago IL, 60604 Environmental Protection Agency Region 5 US EPA Region 5 LSASD Analytical Services Branch 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 Project: Ranovael Project Number: 02BA2021 Project Manager: Ben Atkinson Reported: Aug-17-21 09:08 ANALYSIS CASE NARRATIVE Analysis List Solids, TSS Analyst: Christina Rice Phone #: 312-353-7358 General Information Samples analyzed: Sample Analysis List 2107010-01 Solids, TSS 2107010-02 Solids, TSS 2107010-03 Solids, TSS 2107010-04 Solids, TSS 2107010-05 Solids, TSS Holding times: All holding times were met. Sample Analysis and Results The samples were analyzed using ASB SOP AIG018, Version #7. The samples were stored in the refrigerator at all times, except when in use. The data reported herein meets any requirements referenced in the previously mentioned SOP, except for those listed in the Quality Control section. The original samples were split into a second set by the client for possible use at another laboratory prior to sample analysis as documented in CC 26042. Samples were requested and reported to the MDL. Sample 2107010-02 used a reduced sample size of 20 mL for filtration time exceeding 10 minutes. Duckweed plants were removed from samples 2107010-02 and 2107010-03. SOP Based on: Method List SM 2540 D Quality Control All quality control audits were within ASB limits or did not result in qualification of the data. Report Name: 2107010 Solids, TSS FINAL Aug 17 21 0908 Page 3 of 8 01234516718945878351717351 395735199549854 !"#$#%%& '(")&*+,, -.%/0123456, 7"8/0123554291 ?@A@<0 BCDEDCD :;07351;;<19839;74237=>491 43187KHELBDLBDBCCBHBEHMBN 3718H ?9874<323=351F:;07351 45G78H915297 45G78N91974H 179@ O49==9<923= 45G78IJ674H DB>BDBC 7P548Q5H Z%.X$'.U. R"%#S'T'U'.&VW-XY%)'. S"%S%/ Y%(%'T%\Z^/ +))%\*.Z^/ X)4,4211/,,0]\"^_X_3 !'.Z#%U!'. `%!U%^abc"!!%^ 66R%U["($U.Z!%T"#\ '(")&*+,,] S"%Y%(%'T%\/ [!41421,5/] S"%+))%\*./ [!41421,9/9 -.%/012342,,] 7"8/01235542,,1 "de!%")Uf!"g%!U %"!U*."( Y%(%'T%\.'(% -"e%#h#$*.(!\%\ i7= ?54O@4K74566718=H i7= i7= i7= !%#0U3'.j#d"'./ S%j"! !%#4k6, ;96P7l<H BCDEDCDmDC ;96P7KH rJmCmBCCCHBs ;96P7I967H >@C ;96P7566718=H 19 =3= Xdd.'"tSX&S'U'!!%\ o5K8367pK9=q 25 ZaS 2 t'#"%4t'#'%tSX&W.w^d"'(#%\('. 25 !'\U&_S 6 !'\U&_ 6 _`tSX 25 _"!-Ue#USX 25 N9843nH ?9874 ;96P7598351L566718=H 915297 0nP347= X)41242111/2 [!41642111/2 X)41242111/2 [!42242111/2 [!42242111/2 X)41242111/2 X)41242111/2 566718= euv1 euv6 euv1 euv6 euv6 euv1 euv1 ;96P7l<H BCDEDCDmDB ;96P7KH rJmCmBCCCHM{ N9843nH ?9874 ;96P7I967H ;@C ;96P7598351L566718=H @274x5yx456zQ ;96P7566718=H 19 =3= Xdd.'"tSX&S'U'!!%\ o5K8367pK9=q 0nP347= 566718= 25 X)41242111/]9 euv1 ZaS 2 [!41642111/]9 euv6 t'#"%4t'#'%tSX&W.w^d"'(#%\('. 25 X)41242111/]9 euv1 |Pa}~ge4of8 Page 5 of 8 Page 6 of 8 Water Division, US EPA Region 5 77 West Jackson Boulevard Chicago IL, 60604 Environmental Protection Agency Region 5 US EPA Region 5 LSASD Analytical Services Branch 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 Project: Ranovael Project Number: 02BA2021 Project Manager: Ben Atkinson Reported: Aug-17-21 09:08 BO1 (2107010-01) Analyte Total Suspended Solids SO1 (2107010-02) Analyte Total Suspended Solids SO2 (2107010-03) Analyte Total Suspended Solids SO3 (2107010-04) Analyte Total Suspended Solids SO4 (2107010-05) Analyte Total Suspended Solids Total Suspended Solids, SM 2540 D (modified) US EPA Region 5 LSASD Analytical Services Branch Matrix: Water Sampled: Jul-15-21 11:23 Result Flags / Qualifiers MDL Reporting Limit U 3 5 Received: Jul-16-21 08:46 Units mg/L Dilution 1 Batch B21G022 Matrix: Water Sampled: Jul-15-21 11:49 Result Flags / Qualifiers MDL Reporting Limit 710 3 5 Received: Jul-16-21 08:46 Units mg/L Dilution 1 Batch B21G022 Matrix: Water Sampled: Jul-15-21 11:52 Result Flags / Qualifiers MDL Reporting Limit 51 3 5 Received: Jul-16-21 08:46 Units mg/L Dilution 1 Batch B21G022 Matrix: Water Sampled: Jul-15-21 12:00 Result Flags / Qualifiers MDL Reporting Limit 51 3 5 Received: Jul-16-21 08:46 Units mg/L Dilution 1 Batch B21G022 Matrix: Water Sampled: Jul-15-21 12:07 Result Flags / Qualifiers MDL Reporting Limit 39 3 5 Received: Jul-16-21 08:46 Units mg/L Dilution 1 Batch B21G022 Prepared Jul-19-21 Prepared Jul-19-21 Prepared Jul-19-21 Prepared Jul-19-21 Prepared Jul-19-21 Analyzed Jul-19-21 Analyzed Jul-19-21 Analyzed Jul-19-21 Analyzed Jul-19-21 Analyzed Jul-19-21 Report Name: 2107010 Solids, TSS FINAL Aug 17 21 0908 Page 7 of 8 Water Division, US EPA Region 5 77 West Jackson Boulevard Chicago IL, 60604 U Not Detected NR Not Reported Q QC limit Exceeded Environmental Protection Agency Region 5 US EPA Region 5 LSASD Analytical Services Branch 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 Project: Ranovael Project Number: 02BA2021 Project Manager: Ben Atkinson Notes and Definitions Reported: Aug-17-21 09:08 Report Name: 2107010 Solids, TSS FINAL Aug 17 21 0908 Page 8 of 8 Table of Contents UNITED STATES ENVIRONMENTAL PROTECTION AGENCY REGION 5 ANALYTICAL SERVICES BRANCH LABORATORY 536 SOUTH CLARK STREET (LAB-10C) CHICAGO, ILLINOIS 60605 ELECTRONIC LABORATORY DATA PACKAGE FINAL LEVEL IV COVER PAGE LIMS Work order(s): Primary Analyst: Analysis: Date: Data Reporting Qualtrax Workflow ID: Digital Signature of Primary Analyst: 2107010 Nidia Fuentes Ammonia N DA, Distilled August 26, 2021 26394 Digital Signature Agreement: By signing above the primary analyst understands and agrees that they will be held legally bound, obligated, and responsible for the use of their digital signature as they would be by using their hand-written signature. Page 1 of 100 Client Project Name: Work Order Number: Ranovael @2BA2021) 2107010 1 Cover Page 2 Level I Report 3 QC Summary 4 Checklist 5 Sample Prep and Supporting Data (Ammonia N DA, Distilled) 5.1 Bench Sheets (B21G032) 5.2 Batch Reagents (B21G032) 5.3 Analysis Data and Supporting Documents (21H0203) 5.4 Analysis Data and Supporting Documents (21H0402) 5.5 Standards (21E0614) 5.6 Standards (21G2804) 5.7 Standards (21G2805) 5.8 Standards (21G2806) 5.9 Standards (21G2807) 5.10 Standards (21H0222) 5.11 Standards (21H0223) 5.12 Standards (21H0224) 5.13 Standards (21H0225) 5.14 Standards (21H0226) 5.15 Standards (21H0402) 5.16 Standards (21H0403) 5.17 Standards (21H0404) 5.18 Standards (21H0405) 5.19 Standards (21H0406) 5.20 Sequence Reagents (21H0203) Table of Contents Table of Contents 1 4 12 15 19 20 23 44 50 59 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 536 South Clark Street, Chicago, IL 60605 TEL: 312-353-1226 FAX: 312-353-9069 Page 2 of 100 Client Project Name: Work Order Number: Ranovael @2BA2021) 2107010 5.21 Sequence Reagents (21H0402) Table of Contents Table of Contents (continued) 88 536 South Clark Street, Chicago, IL 60605 TEL: 312-353-1226 FAX: 312-353-9069 Page 2 of 100 UNITED STATES ENVIRONMENTAL PROTECTION AGENCY US EPA Region 5 LSASD Analytical Services Branch 536 SOUTH CLARK STREET CHICAGO, ILLINOIS 60605 Table of Contents Date: 8/26/2021 Title: To: From: ASB Data Report for Ranovael Water Division, US EPA Region 5 77 West Jackson Boulevard Chicago, IL 60604 Nidia Fuentes, Chemist fuentes.nidia@epa.gov US EPA Region 5 LSASD Analytical Services Branch The results reported in this document apply to the samples as received and relate only to the items tested. The data transmitted under this cover memo successfully passed the data review process and applicable Analytical Services Branch (ASB) laboratory Standard Operating Procedures. In accordance with the EPA QA/G-8 Guidance on Environmental Data Verification and Data Validation, ASB performs data verification on all the data generated internally. ASB does not perform data validation or quality assessment procedures. This report was reviewed and the information provided herein accurately represents the analysis performed. Please contact the analyst with any technical report issues, Amanda Wroble at (312)-353-0375 for sample project concerns, and Robert Snyder at (312)-353-9083 with data transmittal questions. Thank you. Attached are Results for: Ranovael Analyses included in this report: Ammonia N DA, Distilled Report Name: 2107010 Ammonia N DA, Distilled FINAL Aug 26 21 1155 Page 4 of 100 Water Division, US EPA Region 5 77 West Jackson Boulevard Chicago IL, 60604 Environmental Protection Agency Region 5 US EPA Region 5 LSASD Analytical Services Branch 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 Project: Ranovael Project Number: 02BA2021 Project Manager: Ben Atkinson Accredited Analyses included in this Report Table of Contents Reported: Aug-26-21 11:55 Method: Analysis: Analyte SM 4500-H+ B in Water Ammonia N DA, Distilled Ammonia as N Certifications ISO/IEC 17025:2017 Analytes not listed above are not accredited by ANAB. Report Name: 2107010 Ammonia N DA, Distilled FINAL Aug 26 21 1155 Page 5 of 100 Water Division, US EPA Region 5 77 West Jackson Boulevard Chicago IL, 60604 Environmental Protection Agency Region 5 US EPA Region 5 LSASD Analytical Services Branch 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 Project: Ranovael Project Number: 02BA2021 Project Manager: Ben Atkinson Table of Contents Reported: Aug-26-21 11:55 ANALYSIS CASE NARRATIVE Analysis List Ammonia N DA, Distilled Analyst: Nidia Fuentes Phone #: 312-353-9079 General Information Samples analyzed: Sample Analysis List 2107010-01 Ammonia N DA, Distilled 2107010-02 Ammonia N DA, Distilled 2107010-03 Ammonia N DA, Distilled 2107010-04 Ammonia N DA, Distilled 2107010-05 Ammonia N DA, Distilled Holding times: All holding times were met. Sample Analysis and Results The samples were analyzed using ASB SOP AIG029B, Version #9. The data reported herein meets any requirements referenced in the previously mentioned SOP and Sampling QAPP titled "General Field Sampling Plan for AFO Inspections" and dated FY 2021, except for those listed in the Quality Control section. SOP Based on: Method List SM 4500-H+ B Quality Control All quality control audits were within ASB limits or did not result in qualification of the data. Report Name: 2107010 Ammonia N DA, Distilled FINAL Aug 26 21 1155 Page 6 of 100 01234516718945878351717351 395735199549854 !"#$#%%& '(")&*+,, -.%/0123456, 7"8/0123554291 Table of Contents ?@A@<0 BCDEDCD :;07351;;<19839;74237=>491 43187KHELBDLBDBCCBHBEHMBN 3718H ?9874<323=351F:;07351 45G78H915297 45G78N91974H 179@ O49==9<923= 45G78IJ674H DB>BDBC 7P548Q5H Z%.X$'.U. R"%#S'T'U'.&VW-XY%)'. S"%S%/ Y%(%'T%\Z^/ +))%\*.Z^/ X)4,4211/,,0]\"^_X_3 !'.Z#%U!'. `%!U%^abc"!!%^ 66R%U["($U.Z!%T"#\ '(")&*+,,] S"%Y%(%'T%\/ [!41421,5/] S"%+))%\*./ [!41421,9/9 -.%/012342,,] 7"8/01235542,,1 "de!%")Uf!"g%!U %"!U*."( Y%(%'T%\.'(% -"e%#h#$*.(!\%\ i7= ?54O@4K74566718=H i7= i7= i7= !%#0U3'.j#d"'./ S%j"! !%#4k6, ;96P7l<H BCDEDCDmDC ;96P7KH rJmCmBCCCHBs ;96P7I967H >@C ;96P7566718=H 19 =3= Xdd.'"tSX&S'U'!!%\ o5K8367pK9=q 25 ZaS 2 t'#"%4t'#'%tSX&W.w^d"'(#%\('. 25 !'\U&_S 6 !'\U&_ 6 _`tSX 25 _"!-Ue#USX 25 N9843nH ?9874 ;96P7598351L566718=H 915297 0nP347= X)41242111/2 [!41642111/2 X)41242111/2 [!42242111/2 [!42242111/2 X)41242111/2 X)41242111/2 566718= euv1 euv6 euv1 euv6 euv6 euv1 euv1 ;96P7l<H BCDEDCDmDB ;96P7KH rJmCmBCCCHM{ N9843nH ?9874 ;96P7I967H ;@C ;96P7598351L566718=H @274x5yx456zQ ;96P7566718=H 19 =3= Xdd.'"tSX&S'U'!!%\ o5K8367pK9=q 0nP347= 566718= 25 X)41242111/]9 euv1 ZaS 2 [!41642111/]9 euv6 t'#"%4t'#'%tSX&W.w^d"'(#%\('. 25 X)41242111/]9 euv1 P|ag}~e7of 100 Table of Contents Page 8 of 100 Table of Contents Page 9 of 100 Water Division, US EPA Region 5 77 West Jackson Boulevard Chicago IL, 60604 Environmental Protection Agency Region 5 US EPA Region 5 LSASD Analytical Services Branch 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 Project: Ranovael Project Number: 02BA2021 Project Manager: Ben Atkinson Table of Contents Reported: Aug-26-21 11:55 BO1 (2107010-01) Analyte Ammonia as N SO1 (2107010-02) Analyte Ammonia as N SO2 (2107010-03) Analyte Ammonia as N SO3 (2107010-04) Analyte Ammonia as N SO4 (2107010-05) Analyte Ammonia as N Ammonia Nitrogen, SM4500B & H (modified) US EPA Region 5 LSASD Analytical Services Branch Matrix: Water Sampled: Jul-15-21 11:23 Result Flags / Qualifiers MDL Reporting Limit U 0.16 0.20 Received: Jul-16-21 08:46 Units mg/L Dilution 1 Batch B21G032 Matrix: Water Sampled: Jul-15-21 11:49 Result Flags / Qualifiers MDL Reporting Limit 2.95 0.16 0.20 Received: Jul-16-21 08:46 Units mg/L Dilution 1 Batch B21G032 Matrix: Water Sampled: Jul-15-21 11:52 Result Flags / Qualifiers MDL Reporting Limit 2.58 0.16 0.20 Received: Jul-16-21 08:46 Units mg/L Dilution 1 Batch B21G032 Matrix: Water Sampled: Jul-15-21 12:00 Result Flags / Qualifiers MDL Reporting Limit 0.28 0.16 0.20 Received: Jul-16-21 08:46 Units mg/L Dilution 1 Batch B21G032 Matrix: Water Sampled: Jul-15-21 12:07 Result Flags / Qualifiers MDL Reporting Limit 0.36 0.16 0.20 Received: Jul-16-21 08:46 Units mg/L Dilution 1 Batch B21G032 Prepared Jul-28-21 Analyzed Aug-02-21 Prepared Jul-28-21 Analyzed Aug-03-21 Prepared Jul-28-21 Analyzed Aug-02-21 Prepared Jul-28-21 Analyzed Aug-02-21 Prepared Jul-28-21 Analyzed Aug-02-21 Report Name: 2107010 Ammonia N DA, Distilled FINAL Aug 26 21 1155 Page 10 of 100 Water Division, US EPA Region 5 77 West Jackson Boulevard Chicago IL, 60604 U Not Detected NR Not Reported Q QC limit Exceeded Environmental Protection Agency Region 5 US EPA Region 5 LSASD Analytical Services Branch 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 Project: Ranovael Project Number: 02BA2021 Project Manager: Ben Atkinson Notes and Definitions Table of Contents Reported: Aug-26-21 11:55 Report Name: 2107010 Ammonia N DA, Distilled FINAL Aug 26 21 1155 Page 11 of 100 Environmental Protection Agency US EPA Region 5 LSASD Analytical Services Branch 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 Table of Contents Date: Project: 8/26/2021 Ranovael Quality Control Summary Analyst: Nidia Fuentes Analyte: Ammonia as N Analysis: Ammonia N DA, Distilled QC Sample Name 21H0203-CAL1 Result -0.02 Units mg/L Flags / Qualifiers MDL Reporting Limit Spike Level 0.16 0.20 0.000 Source Result % REC or abs diff (pH) % REC or abs diff (pH) Limits % % RPD or abs diff (pH) %RPD or abs diff ( pH) Limits 21H0203-CAL2 0.11 mg/L 0.16 0.20 0.1000 112% 21H0203-CAL3 0.21 mg/L 0.16 0.20 0.2000 106% 21H0203-CAL4 0.40 mg/L 0.16 0.20 0.4000 100% 21H0203-CAL5 0.81 mg/L 0.16 0.20 0.8000 101% 21H0203-CAL6 1.99 mg/L 0.16 0.20 2.000 100% 21H0203-CAL7 4.00 mg/L 0.16 0.20 4.000 100% 21H0203-CCB1 -0.02 mg/L 0.16 0.20 21H0203-CCV1 3.13 mg/L 0.16 0.20 3.000 104% 90-110 21H0203-ICB1 0.0020 mg/L 0.16 0.20 21H0203-ICV1 3.11 mg/L 0.16 0.20 3.000 104% 90-110 21H0402-CAL1 -0.02 mg/L 0.16 0.20 0.000 % 21H0402-CAL2 0.09 mg/L 0.16 0.20 0.1000 92% 21H0402-CAL3 0.21 mg/L 0.16 0.20 0.2000 103% 21H0402-CAL4 0.41 mg/L 0.16 0.20 0.4000 102% 21H0402-CAL5 0.82 mg/L 0.16 0.20 0.8000 102% 21H0402-CAL6 1.99 mg/L 0.16 0.20 2.000 99% 21H0402-CAL7 4.00 mg/L 0.16 0.20 4.000 100% 21H0402-CCB1 -0.01 mg/L 0.16 0.20 Report Name: 2107010 Ammonia N DA, Distilled FINAL Aug 26 21 1155 Page 12 of 100 Environmental Protection Agency US EPA Region 5 LSASD Analytical Services Branch 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 Table of Contents Quality Control Summary Date: 8/26/2021 Analyst: Nidia Fuentes Project: Ranovael Analyte: Ammonia as N Analysis: Ammonia N DA, Distilled QC Sample Name 21H0402-CCB2 Result -0.01 Units mg/L Flags / Qualifiers MDL Reporting Limit Spike Level 0.16 0.20 Source Result % REC or abs diff (pH) % REC or abs diff (pH) Limits % RPD or abs diff (pH) %RPD or abs diff ( pH) Limits 21H0402-CCB3 -0.02 mg/L 0.16 0.20 21H0402-CCV1 3.09 mg/L 0.16 0.20 3.000 103% 90-110 21H0402-CCV2 3.02 mg/L 0.16 0.20 3.000 101% 90-110 21H0402-CCV3 3.15 mg/L 0.16 0.20 3.000 105% 90-110 21H0402-ICB1 -0.02 mg/L 0.16 0.20 21H0402-ICV1 2.97 mg/L 0.16 0.20 3.000 99% 90-110 B21G032-BLK1 U mg/L 0.16 0.20 B21G032-BS1 2.03 mg/L 0.16 0.20 2.000 102% 73-120 B21G032-DUP1 Source: 2107010-02 B21G032-MRL1 2.83 mg/L 0.22 mg/L 0.16 0.20 2.95 4 14 0.16 0.20 0.2000 109% 71-147 B21G032-MS1 Source: 2107010-02 5.26 mg/L 1.60 2.00 2.000 2.95 116% 50-148 U Not Detected NR Not Reported Q QC limit Exceeded Notes and Definitions Report Name: 2107010 Ammonia N DA, Distilled FINAL Aug 26 21 1155 Page 13 of 100 Date: Project: 8/26/2021 Ranovael Environmental Protection Agency US EPA Region 5 LSASD Analytical Services Branch 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 Quality Control Summary Analyst: Nidia Fuentes Table of Contents Nidia Fuentes Report Name: 2107010 Ammonia N DA, Distilled FINAL Aug 26 21 1155 Page 14 of 100 Table of Contents Work: 2107010 UNITED STATES ENVIRONMENTAL PROTECTION AGENCY REGION 5 LSASD ANALYTICAL SERVICE BRANCH 536 SOUTH CLARK STREET CHICAGO, ILLINOIS 60605 Data Verification Checklist Project: Ranovael Analysis: Ammonia N DA, Distilled CRL SOP Used: AIG029B v9 Batch ID: General Information B21G032 Question # 1 Question Did samples meet the laboratory's standard conditions of sample acceptability upon receipt? 2 Was customer contact communication included? 3 Are all field sample ID numbers cross-referenced to the laboratory ID numbers? 4 Were all samples prepared and analyzed within holding times? Analyst Response (YES/ NO/ NA) YES By NFUENTES at 11:23 am, Aug 25, 2021 NA NO YES YES Question # 5 6 7 8 9 10 11 12 13 Sample Results Were calculations checked? Question Were all analyte results checked? Were all results for soil and sediment samples reported on a dry weight basis? Were % moisture (or solids) reported for all soil and sediment samples? Other than those results < RL, were all other raw values bracketed by calibration standards? Are the RLs for each method analyte included in the laboratory data package? Are MDLs/RLs adjusted for dilutions? Were the raw data (for example, chromatograms, spectral data) reviewed? Were data associated with manual integrations flagged on the raw data? Analyst Response (YES/ NO/ NA) YES YES NA NA YES YES YES YES NA Question # 14 15 Standards Question Are all standards used in the analyses NIST-traceable or obtained from other appropriate sources as specified in the analytical SOP? Were standard/reagent preparations checked (preparation date, expiration date, parent standard IDs, etc.), if applicable? Batch Quality Control Analyst Response (YES/ NO/ NA) YES YES Print Date: 8/5/2021 PaPgaeg1e51ooff1400 Work: 2107010 Project: Ranovael Question # 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 Batch Quality Control Were appropriate type(s) of blanks analyzed? Question Were blanks analyzed at the appropriate frequency? Were method blanks taken through the entire analytical process, including preparation and, if applicable, cleanup procedures? Were blank concentrations <= MDL or RL, as applicable in the analytical SOP? Was each LCS/SRM taken through the entire analytical procedure, including prep and cleanup steps? Were LCSs/SRMs analyzed at the required frequency? Were LCS/SRM %Rs within the laboratory QC limits or other acceptance criteria? Were the project/method specified analytes included in the MS? Were MS analyzed at the appropriate frequency? Were MS %Rs within the laboratory QC limits? Were appropriate analytical duplicates analyzed for each matrix? Were analytical duplicates analyzed at the appropriate frequency? Were RPDs or relative standard deviations within the laboratory QC limits or other acceptance criteria? Were RLs analyzed at the appropriate frequency? Were RL recoveries within the laboratory QC limits? Question # 31 32 33 34 Calibration Question Were calibration correlation coefficient or other acceptance criteria met? Was the number of calibration standards recommended in the method used for all analytes? Were all points generated between the lowest and highest standard used to calculate the curve? Are calibration data available for all instruments used? Question # 35 36 37 Calibration Verification Question Was the absolute value of the analyte concentration in the ICB/CCB <= MDL or RL, as applicable in the analytical SOP? Was the calibration curve verified for each analyte? Has the calibration curve been verified using an appropriate second source standard? Print Date: 8/5/2021 Table of Contents Analyst Response (YES/ NO/ NA) YES YES YES YES YES YES YES YES YES YES YES YES YES YES YES Analyst Response (YES/ NO/ NA) YES YES YES YES Analyst Response (YES/ NO/ NA) YES YES YES PaPgaeg1e62ooff1400 Work: 2107010 Project: Ranovael Question # 38 39 Calibration Verification Question Were ICV/CCV analyzed at the method-required frequency? Were ICV/CCV %R within the laboratory QC limits? Question # 40 41 42 Quality Control QC limits in LIMS checked against the SOP? Question Were percent differences, recoveries, and the linearity within the QC limits specified in the method? Were QC charts checked if a QC audit, excluding matrix QC (MS or DUP), was out of limit? Question # 43 44 Supporting Data Question Were support equipment data (balance verification, data logs, logbook entries, etc.) included in data package? Were approved spreadsheet(s) used? Question # 45 46 47 48 49 50 Document Verification Question Is the MDL or RL study up-to-date for each reported analyte? Is documentation of the analyst's capability up-to-date and on file? ID: 24456 Are the procedures for compound/analyte identification documented? Are laboratory SOPs current and on file for the method performed? Were data evaluated against project QAPP or Sample Plan, any special requests in the sample schedule, and documented in case narrative? Were electronic pathways checked (add pathway and files below)? Notes/Comments: J:\Vol1\Projects (New File Structure)\Ranovael\1.$&I\NFuentes\DA-4\08022021-AMM\ARC_70.bak J:\Vol1\Projects (New File Structure)\Ranovael\1. A&I\NFuentes\DA-4\08032021-AMM\ARC_70.bak Question # 51 ANAB logo used appropriately? Accreditation Question Table of Contents Analyst Response (YES/ NO/ NA) YES YES Analyst Response (YES/ NO/ NA) YES YES NA Analyst Response (YES/ NO/ NA) YES YES Analyst Response (YES/ NO/ NA) YES YES YES YES YES YES Analyst Response (YES/ NO/ NA) YES Analyst's Signature and Date*: Print Date: 8/5/2021 Fuentes, Nidia Digitally signed by Fuentes, Nidia Date: 2021.08.25 11:24:01 -05'00' PaPgaeg1e73ooff1400 Work: 2107010 Project: Ranovael Table of Contents Reviewer's Signature and Date*: ANNA KNOEBEL Date: 2021.08.26 10:38:43 -05'00' Digitally signed by ANNA KNOEBEL Additional Notes/Comments (if applicable): *Reviewer Concurs with Analyst Responses Print Date: 8/5/2021 PaPgaeg1e84ooff1400 Table of Contents Ammonia N DA, Distilled Page 19 of 100 BATCH B21G032 [TOC_1]Benchsheets[TOTCa]ble of Contents Page 20 of 100 Prepared Date: Analyst (initials): Jul-28-21 NF US EPA Region 5 LSASD Analytical Services Branch 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 Date: 7/28/2021 AMMONIA DISTILLATION LOG (EASY STILL/MIDI) FOR WATER SAMPLES Batch Number: B21G032 Analyses Included On This Benchsheet Ammonia N DA, Distilled Distillation # Sample Number 1 2107010-01 1 2107010-02 1 2107010-03 1 2107010-04 1 2107010-05 1 B21G032-BLK1 1 B21G032-BS1 1 B21G032-DUP1 1 B21G032-MRL1 1 B21G032-MS1 Instrument ID: MIDIDIST1 Source ID Spike Type Pre-Prep 2107010-02 Pre-Prep By NFUENTES at 11:26 am, Aug 25, 2021 Static 2107010-02 Pre-Prep Spike ID 21E0614 21G2807 21E0614 Spike Volume Sample Volume (uL) (mL) 50 50 50 50 50 50 100 50 50 2500 50 100 50 Adjusted pH is ~ 9.5 (Y/N) Y Y Y Y Y Y Y Y Y Y pH = 1 pH = 1 pH = 1 pH = 1 pH = 1 Comments Table of Contents Page 21 of 100 Batch Comments: Page 1 of 2 Prepared Date: Analyst (initials): Jul-28-21 NF US EPA Region 5 LSASD Analytical Services Branch 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 Date: 7/28/2021 AMMONIA DISTILLATION LOG (EASY STILL/MIDI) FOR WATER SAMPLES Batch Number: B21G032 Analyses Included On This Benchsheet Ammonia N DA, Distilled PREPARATION REAGENTS/STANDARDS/PIPETTES: 21E0614: NH3N-StockControlStandard 21G2807: NH3N-MRL Spike 19) : NH3N Distilled-Borate Buffer 19F0521: Sodium Hydroxide 10% (w/v) 20K0528: Test Strip: pH 5.0 - 10 21B2306: Pipette (Electronic) -- 50 -1,000 uL 21B2307: Pipette (Electronic) -- 200 -5000 uL 21B2308: Pipette (Electronic) -- 500 - 10,000 uL 21B2309: Pipette (Electronic) -- 5 -100 uL 21G2803: NH3NDistilled-ReceivingSol/BLK Prepared: May-06-21 Prepared: Jul-28-21 Prepared: -XQ- -19 Prepared: May-02-19 Prepared: Nov-05-20 Prepared: Feb-15-21 Prepared: Feb-15-21 Prepared: Feb-15-21 Prepared: Feb-15-21 Prepared: Jul-28-21 Expires: Nov-03-22 By NFUENTES at 11:28 am, Aug 25, 2021 Expires: Jul-11-21 Aug-28-21 Expires: Dec- -30 Expires: Apr-30-22 Expires: Oct-31-21 Expires: Aug-31-21 Expires: Aug-31-21 Expires: Aug-31-21 Expires: Aug-31-21 Expires: Aug-28-21 Table of Contents Page 22 of 100 Batch Comments: Page 2 of 2 BATCH REAGENTS 19F0521 Table of Contents Page 23 of 100 Certificate of Analysis Table of Contents 1490 Lammers Pike Batesville, IN 47006 http://www.riccachemical.com 1-888-GO-RICCA customerservice@riccachemical.com Sodium Hydroxide, 10% (w/v) (100 g/L) Lot Number: 4905821 Product Number: 7260 Manufacture Date: MAY 02, 2019 Expiration Date: APR 2022 Name Water Sodium Hydroxide CAS# 7732-18-5 1310-73-2 Grade ACS/ASTM/USP/EP Reagent Test Appearance Assay (vs. Sulfuric Acid/Phenolphthalein) Specification Colorless liquid 9.96-10.04 % (w/v) Result Passed 9.97 % (w/v) NIST SRM# 723 Specification Reference Sodium hydroxide solution (100 g/1000 mL) TAPPI (T 602 cm-97) Sodium Hydroxide Solution (100 g/L) ASTM (D 3866 A) Sodium Hydroxide Solution (100 g/L) ASTM (D 858 B) Sodium Hydroxide Solution (100 g/L) ASTM (D 1886 B) Sodium Hydroxide Solution (100 g/L) ASTM (D 3557 B) Sodium Hydroxide Solution (100 g/L) ASTM (D 3558 B) Sodium Hydroxide Solution (100 g/L) ASTM (D 1688 B) Sodium Hydroxide Solution (100 g/L) ASTM (D 3559 B) Sodium hydroxide, 10% solution TAPPI (T 618 cm-84) Sodium Hydroxide Solution (100 g/L) ASTM (D 1266) Sodium Hydroxide Solution (100 g/L) ASTM (D 3372) Sodium Hydroxide Solution (100 g/L) ASTM (D 1266) Sodium Hydroxide Reagent Solution ACS (N/A) Volumetric glassware complies with Class A tolerance requirements of ASTM E 288 and NIST Circular 434; it is calibrated before first use and recalibrated regularly in accordance with ASTM E 542 and NIST Procedure NBSIR 74-461. Balances are calibrated regularly with weights certified traceable to the NIST national mass standard. Thermometers and temperature probes are calibrated before first use and recalibrated regularly with a thermometer traceable to NIST standards. All products are prepared according to master documents that assure manufacture according to validated methods. Batch records document raw material traceability and production and testing history for each lot manufactured. Part Number Size / Package Type Shelf Life (Unopened Container) 7260-1 7260-16 7260-2.5 7260-32 7260-4 4 L natural poly 500 mL natural poly 10 L Cubitainer 1 L natural poly 120 mL natural poly Recommended Storage: 15C - 30C (59F - 86F) 36 months 36 months 36 months 36 months 36 months Version: 1.3 By AK at 10:51 am, Feb 11, 2020 Lot Number: 4905821 Product Number: 7260 Page 1 of 2 Page 24 of 100 Table of Contents Jim Gibbs (05/02/2019) Quality Control Supervisor This Certificate of Analysis is designed to comply with ISO Guide 31 "Reference Materials -- Contents of Certificates and Labels." This test report shall not be reproduced, except in full, without the written approval of Ricca Chemical Company. Version: 1.3 Lot Number: 4905821 Product Number: 7260 Page 2 of 2 Page 25 of 100 BATCH REAGENTS 19F1209 Table of Contents Page 26 of 100 Environmental Protection Agency Region 5 Chicago Regional Laboratory 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 Reagent Preparation Bench Sheet Table of Contents Print Date: 6/12/2019 Parameter / SOP #: NH3N (Distilled)/AIG029B v6 Reagent: NH3N Distilled-Borate Buffer LIMS ID: 19F1209 0.1 N NaOH Chemical Name (Formula) Prepared by: Nidia Fuentes Preparation Date: Jun-12-19 By AK at 10:31 am, Mar 18, 2021 Expiration Date: Dec-09-20 LIMS ID Dec-12-30 Mass or Volume (specify units) 19F1203 44 mL 0.025 M Sodium Tetraborate Solution 19F1208 250 mL Total Volume : 500 mL Comments : By AK at 7:55 am, Jun 26, 2019 Reviewed with WO# 1906002 AK 6-26-19 No expiration date - Existing expiration date (Dec-09-20) was updated to Dec-12-30 since there is no expiration for this reagent. See user defined fields for reagent information prep Analyst Signature: By AK at 10:33 am, Mar 18, 2021 Page 27Paogfe1100of 1 BATCH REAGENTS 20K0528 Table of Contents Page 28 of 100 Table of Contents By AK at 1:28 pm, May 06, 2021 Page 29 of 100 BATCH REAGENTS 21B2306 Table of Contents Page 30 of 100 Table of Contents Page 31 of 100 Table of Contents Page 32 of 100 BATCH REAGENTS 21B2307 Table of Contents Page 33 of 100 Table of Contents Page 34 of 100 Table of Contents Page 35 of 100 BATCH REAGENTS 21B2308 Table of Contents Page 36 of 100 Table of Contents Page 37 of 100 Table of Contents Page 38 of 100 BATCH REAGENTS 21B2309 Table of Contents Page 39 of 100 Table of Contents Page 40 of 100 Table of Contents Page 41 of 100 BATCH REAGENTS 21G2803 Table of Contents Page 42 of 100 Table of Contents Environmental Protection Agency Region 5 Chicago Regional Laboratory Print Date: 8/6/2021 Copy was inadvertently not print 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 By NFUENTES at 9:39 am, Aug 09, 2021 Reagent Preparation Bench Sheet Parameter / SOP #: NH3N Distilled/AIG029B v7 9 Reagent: NH3NDistilled-ReceivingSol/BLK By NFUENTES at 2:10 pm, Aug 25, 2021 LIMS ID: 21G2803 Chemical Name (Formula) Sulfuric Acid (H2SO4) Prepared by: Nidia Fuentes Preparation Date: Jul-28-21 Expiration Date: Aug-28-21 LIMS ID 21G0902 Mass or Volume (specify units) 1 mL Total Volume : 1000 mL Comments : See user defined fields for details Analyst Signature: By Anna Knoebel at 6:21 am, Aug 26, 2021 PaPgaeg4e31ooff1100 SEQUENCE 21H0203 [TOC_1]Sequence[TOC] Table of Contents Sequence Date: 08/02/2021 Instrument: DA-4 Sequence Analyses: Ammonia N DA, Distilled Page 44 of 100 Instrument: Order 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 ANALYSIS SEQUENCE 21H0203 DA-4 Container A A A A Analysis Date: Aug-02-21 Lab Number Sample name or QC sample designation 21H0203-CAL3 NH3-4 21H0203-CAL4 NH3-4 21H0203-CAL5 NH3-4 21H0203-CAL6 NH3-4 21H0203-CAL7 NH3-4 21H0203-CAL1 NH3-0 21H0203-CAL2 NH3-4 21H0203-ICB1 ICB 21H0203-ICV1 ICV B21G032-MRL1 MRL Check B21G032-BLK1 Blank 2107010-01 BO1 2107010-03 SO2 2107010-04 SO3 2107010-05 SO4 21H0203-CCB1 ICB 21H0203-CCV1 ICV Calibration ID: UNASSIGNED Analysis QC QC QC QC QC QC QC QC QC QC QC Ammonia N DA, Distilled Ammonia N DA, Distilled Ammonia N DA, Distilled Ammonia N DA, Distilled QC QC Printed: 8/26/2021 6:30:24AM Matrix: Water STD ID 21H0222 21H0223 21H0224 21H0225 21G2804 21G2806 21H0226 21G2805 Comments 21G2805 pH = 1 pH = 1 pH = 1 pH = 1 Table of Contents Page 45 of 100 Page 1 of 2 Order Container Lab Number Sample name or QC sample designation PREPARATION REAGENTS/STANDARDS/PIPETTES: 21G2807: NH3N-MRL Spike Prepared: Jul-28-21 21G2804: NH3N-WCS (4.00 mg/L) Prepared: Jul-28-21 21G2805: NH3N-WcS (3 mg/L) Prepared: Jul-28-21 21G2806: NH3N-WCS (0.00 mg/L) Prepared: Jul-28-21 21H0222: NH3N - WCS (0.2 mg/L) Prepared: Aug-02-21 21H0223: NH3N - WCS (0.4 mg/L) Prepared: Aug-02-21 21H0224: NH3N - WCS (0.8 mg/L) Prepared: Aug-02-21 21H0225: NH3N - WCS (2.0 mg/L) Prepared: Aug-02-21 21H0226: NH3N - WCS (0.10 mg/L) Prepared: Aug-02-21 21B0403: NH3N-Sodium Phenolate Sol. Prepared: Feb-04-21 21B0404: NH3N-5% EDTA Buffer Sol. Prepared: Feb-04-21 21B0405: NH3N-SodiumNitroprusside Prepared: Feb-04-21 21G2803: NH3NDistilled-ReceivingSol/BLK Prepared: Jul-28-21 21H0221: NH3N-Sodium Hypochlorite Solution Prepared: Aug-02-21 Analysis Expires: Aug-28-21 Expires: Aug-28-21 Expires: Aug-28-21 Expires: Aug-28-21 Expires: Aug-03-21 Expires: Aug-03-21 Expires: Aug-03-21 Expires: Aug-03-21 Expires: Aug-03-21 Expires: Feb-04-22 Expires: Feb-04-22 Expires: Feb-04-22 Expires: Aug-28-21 Expires: Aug-03-21 STD ID Comments Table of Contents Page 46 of 100 Page 2 of 2 Table of Contents ! " )! )! )! )! )! )! )! +, + ! "" # $ ' ! $ (" $ (" $ $ (" % & %& % % % # % %& % %* %& % % % % $ !% & % % % % % %* % %* % % % %& % !% % % .& % % ! ( ( ( ( ( ( ( ( - $" * ( %BUBOPUVTFECFDBVTF$"-BOE$"-XFSF SFBOBMZ[FEBGUFSUIFTFSFTVMUT*$#BOE*$7XFSF BOBMZ[FEBUTUBSUPGSVO By NFUENTES at 2:46 pm, Aug 25, 2021 Page 47 of 100 Table of Contents ! " #$ ) (" #*+ % % #*, % % +- . / % %0 + - .+/1 % %23 + - .+ % % 42 3. % %0 3. % %4 + - .$) % % +- . % % 3. % %2303 3. % % 324 3 .2 % %4 #*+ % .% #*, % %2 #*+ % %2 0 #*, % % + - .+ % %2 3. % %233 + - .$) % %2 4 +- . % . #*+ % .% 0 #*, % %2 +- . % 2%3 #*+ % %3 #*, % %4 #*, % #*+ % % #*, % % 03 + - .+ % %4 2 #*+ % % * within calibration By NFUENTES at 2:49 pm, Aug 25, 2021 $% & % % % % % % % % % % % % % % % % % % % % % % 0% % % % % % % % !! !! !! !! !! !! !! !! !! !! !! !! !! !! !! !! !! !! !! "9 !! !! !! !! !! "9 !! !! !! !! '"" " Failed QC By NFUENTES at 9:17 am, Aug 05, 2021 By NFUENTES at 2:47 pm, Aug 25, 2021 By NFUENTES at 2:47 pm, Aug 25, 2021 Failed QC, reanalyzed By NFUENTES at 8:24 am, Aug 06, 2021 5 6! " * 7*8 By NFUENTES at 3:22 pm, Aug 04, 2021 ( 6 Failed QC $ % : ;8 5 6 ! " 5 6! " % " 9 ! 6 Ran out of standard Not used Failed QC By NFUENTES at 3:18 pm, Aug 04, 2021 Page 48 of 100 Date Time 8/3/2021 User NF 8:14:38 AM Software version: 7.0 Sample/ctrl ID Pat/Ctr/cAl Test name Test type Result Result unit Result time STAT NH3-0 A NH3-4 A NH3-4 A NH3-4 A NH3-4 A NH3-4 A NH3-4 A ICB C ICV C NH3-0 A NH3-4 A ICB C ICV C B21G032-MRL1 P B21G032-BLK1 P B21G032-BS1 P 2107010-01 P 2107010-02 P B21G032-DUP1 P B21G032-MS1 P 2107010-03 P 2107010-04 P 2107010-05 P ICB C ICV C ICB C ICV C B21G032-BS1 P 2107010-02 P B21G032-DUP1 P B21G032-MS1 P ICB C ICV C B21G032-MS1 P ICB C ICV C ICV C ICB C ICV C B21G032-BS1 P ICB C Ammonia_2P Ammonia_2P Ammonia_2P Ammonia_2P Ammonia_2P Ammonia_2P Ammonia_2P Ammonia_2P Ammonia_2P Ammonia_2P Ammonia_2P Ammonia_2P Ammonia_2P Ammonia_2P Ammonia_2P Ammonia_2P Ammonia_2P Ammonia_2P Ammonia_2P Ammonia_2P Ammonia_2P Ammonia_2P Ammonia_2P Ammonia_2P Ammonia_2P Ammonia_2P Ammonia_2P Ammonia_2P Ammonia_2P Ammonia_2P Ammonia_2P Ammonia_2P Ammonia_2P Ammonia_2P Ammonia_2P Ammonia_2P Ammonia_2P Ammonia_2P Ammonia_2P Ammonia_2P Ammonia_2P 0.05759 mg/l 0.07179 mg/l 0.21201 mg/l 0.39886 mg/l 0.8068 mg/l 1.99303 mg/l 4.00135 mg/l -0.01916 mg/l 3.07527 mg/l -0.02395 mg/l 0.1119 mg/l 0.00204 mg/l 3.11081 mg/l 0.21888 mg/l 0.05071 mg/l 2.46495 mg/l 0.00981 mg/l 3.38255 mg/l 3.33243 mg/l 3.00433 mg/l 2.57967 mg/l 0.27556 mg/l 0.36236 mg/l -0.02134 mg/l 3.13346 mg/l 0.50978 mg/l 3.28183 mg/l 2.80542 mg/l 3.57724 mg/l 3.52619 mg/l 6.72044 mg/l -0.00094 mg/l 3.24578 mg/l 5.73281 mg/l 0.01713 mg/l 3.16804 mg/l mg/l 0.00281 mg/l 3.19741 mg/l 3.68579 mg/l 0.00112 mg/l 8/2/2021 14:43 8/2/2021 14:45 8/2/2021 14:47 8/2/2021 14:49 8/2/2021 14:51 8/2/2021 14:53 8/2/2021 14:54 8/2/2021 14:55 8/2/2021 14:56 8/2/2021 15:17 8/2/2021 15:18 8/2/2021 15:37 8/2/2021 15:37 8/2/2021 15:38 8/2/2021 15:39 8/2/2021 15:40 8/2/2021 15:41 8/2/2021 15:42 8/2/2021 15:43 8/2/2021 15:43 8/2/2021 15:45 8/2/2021 15:46 8/2/2021 15:47 8/2/2021 15:47 8/2/2021 15:49 8/2/2021 16:20 8/2/2021 16:21 8/2/2021 16:22 8/2/2021 16:23 8/2/2021 16:23 8/2/2021 16:25 8/2/2021 16:26 8/2/2021 16:26 8/2/2021 16:38 8/2/2021 16:39 8/2/2021 16:40 8/2/2021 16:49 8/2/2021 16:59 8/2/2021 17:00 8/2/2021 17:01 8/2/2021 17:02 Status MR MR MA MA MA MA MA MA MA MA MA MA MA MA MA MA MA MA MA MA MA MA MA MA MA MA MA MA MA MA AR MA MA MA MA MA AR MA MA MA MA Errors 30, 30, 27, 19,30, 30, 1, Notes R R Dilution 1 +Manual diluRteiosponse Blank respoMnsain abs. 1Blank abs. 1Sample type 0 0.02394 -0.00013 0.02381 -0.00013 39 0.02447 -0.0001 0.02437 -0.0001 19 0.02863 -0.00017 0.02846 -0.00017 9 0.0361 -0.0002 0.0359 -0.0002 4 0.0526 -0.00031 0.05228 -0.00031 1 0.10215 -0.00004 0.1021 -0.00004 0 0.19134 -0.00009 0.19124 -0.00009 0 0.01947 -0.00021 0.01926 -0.00021 0 0.14938 -0.00003 0.14935 -0.00003 0 0.01928 0.00147 0.02076 0.00147 39 0.02465 -0.00035 0.0243 -0.00035 0 0.02031 -0.00032 0.01999 -0.00032 0 0.15096 -0.00006 0.15091 -0.00006 0 0 0.0289 -0.00019 0.02871 -0.00019 Sample type 1 0 0 0.02223 -0.00007 0.02216 -0.00007 Sample type 1 0 0 0.1225 -0.00012 0.12239 -0.00012 Sample type 1 0 0 0.02061 -0.00021 0.0204 -0.00021 Sample type 1 0 0 0.16315 -0.00023 0.16292 -0.00023 Sample type 1 0 0 0.16089 -0.00018 0.16071 -0.00018 Sample type 1 0 0 0.14622 -0.00019 0.14604 -0.00019 Sample type 1 0 0 0.12751 -0.00023 0.12728 -0.00023 Sample type 1 0 0 0.03116 -0.00016 0.031 -0.00016 Sample type 1 0 0 0.03463 -0.00026 0.03437 -0.00026 Sample type 1 0 0.01938 0.00012 0.0195 0.00012 0 0.15197 -0.00002 0.15196 -0.00002 0 0.04056 0.01756 0.05811 0.01756 0 0.15862 -0.00025 0.15837 -0.00025 0 0 0.13742 -0.00023 0.13719 -0.00023 Sample type 1 0 0 0.17195 -0.00017 0.17178 -0.00017 Sample type 1 0 0 0.16963 -0.00006 0.16957 -0.00006 Sample type 1 0 0 0.31652 -0.00032 0.31619 -0.00032 Sample type 1 0 0.02019 -0.00019 0.02 -0.00019 0 0.157 -0.00025 0.15675 -0.00025 9 0 0.04312 -0.00039 0.04273 -0.00039 Sample type 1 0 0.0209 -0.00024 0.02067 -0.00024 0 0.15352 -0.00022 0.1533 -0.00022 0 0 0.02034 0.00001 0.02034 0.00001 0 0.15483 0.00008 0.15491 0.00008 0 0 0.17688 0.04087 0.21775 0.04087 Sample type 1 0 0.02027 -0.00009 0.02019 -0.00009 Table of Contents Page 49 of 100 SEQUENCE 21H0402 [TOC_1]Sequence[TOC] Table of Contents Sequence Date: 08/03/2021 Instrument: DA-4 Sequence Analyses: Ammonia N DA, Distilled Page 50 of 100 Instrument: Order 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 ANALYSIS SEQUENCE 21H0402 DA-4 Container A Analysis Date: Aug-03-21 Lab Number Sample name or QC sample designation 21H0402-CAL1 NH3-0 21H0402-CAL2 NH3-4 21H0402-CAL3 NH3-4 21H0402-CAL4 NH3-4 21H0402-CAL5 NH3-4 21H0402-CAL6 NH3-4 21H0402-CAL7 NH3-4 21H0402-ICB1 ICB 21H0402-ICV1 ICV 21H0402-CCB1 ICB 21H0402-CCV1 ICV B21G032-BS1 LCS 2107010-02 SO1 B21G032-DUP1 Duplicate 21H0402-CCB2 ICB 21H0402-CCV2 ICV B21G032-MS1 Matrix Spike 21H0402-CCB3 ICB 21H0402-CCV3 ICV Calibration ID: UNASSIGNED Analysis QC QC QC QC QC QC QC QC QC QC QC QC Ammonia N DA, Distilled QC QC QC QC QC QC Printed: 8/25/2021 2:53:39PM Matrix: Water STD ID 21G2806 21H0406 21H0402 21H0403 21H0404 21H0405 21G2804 21G2805 21G2805 Comments pH = 1 21G2805 21G2805 Table of Contents Page 51 of 100 Page 1 of 2 Order Container Lab Number Sample name or QC sample designation PREPARATION REAGENTS/STANDARDS/PIPETTES: 21E0614: NH3N-StockControlStandard Prepared: May-06-21 21G2804: NH3N-WCS (4.00 mg/L) Prepared: Jul-28-21 21G2805: NH3N-WcS (3 mg/L) Prepared: Jul-28-21 21G2806: NH3N-WCS (0.00 mg/L) Prepared: Jul-28-21 21H0402: NH3N - WCS (0.2 mg/L) Prepared: Aug-03-21 21H0403: NH3N - WCS (0.4 mg/L) Prepared: Aug-03-21 21H0404: NH3N - WCS (0.8 mg/L) Prepared: Aug-03-21 21H0405: NH3N - WCS (2.0 mg/L) Prepared: Aug-03-21 21H0406: NH3N - WCS (0.10 mg/L) Prepared: Aug-03-21 21B0403: NH3N-Sodium Phenolate Sol. Prepared: Feb-04-21 21B0404: NH3N-5% EDTA Buffer Sol. Prepared: Feb-04-21 21B0405: NH3N-SodiumNitroprusside Prepared: Feb-04-21 21G2803: NH3NDistilled-ReceivingSol/BLK Prepared: Jul-28-21 21H0401: NH3N-Sodium Hypochlorite Solution Prepared: Aug-04-21 Analysis Expires: Nov-03-22 Expires: Aug-28-21 Expires: Aug-28-21 Expires: Aug-28-21 Expires: Aug-04-21 Expires: Aug-04-21 Expires: Aug-04-21 Expires: Aug-04-21 Expires: Aug-04-21 Expires: Feb-04-22 Expires: Feb-04-22 Expires: Feb-04-22 Expires: Aug-28-21 Expires: Aug-05-21 STD ID Comments Table of Contents Page 52 of 100 Page 2 of 2 Table of Contents ! " +! +! +! +! +! +! +! ,, ! "" # $ ) ! $ *" $ *" $ $ *" %&&&&'& (%& % %& % # %( %( % % (( % %( %( %( %( $ ! % ('' % %& % % (& % % &' % %& % %& ' % %( % !% ( % %& % % ! * * * * * * * * . $" * * Page 53 of 100 Table of Contents ! " #$ #*+ ) (" % .% #*/ % B21G032 By NFUENTES at 9:24 am, Aug 05, 2021 + .+ % 2 103. % By NFUENTES at 8:38 am, Aug 06, 2021 B21G032 By NFUENTES at 9:24 am, Aug 05, 2021 + .$) % B21G032 +. % %01 %1 %0 2 %1 .D #*+ % By NFUENTES at 9:25 am, Aug 05, 2021 .% 0 #*/ % B21G032 +. % #*+ % By NFUENTES at 9:25 am, Aug 05, 2021 %2 3% 1 .% #*/ % %3 * within calibration ByNFUENTESat3:00pm,Aug25,2021 D - diluted by instrument $% & % % % % % % % % 0% % % !! !! !! !! !! "4 !! !! !! !! !! '"" " , -! " * $ % 5 67 , - ! " , -! " * , -! " * Page 54 of 100 Date Time 8/4/2021 User NF 8:35:10 AM Software version: 7.0 Sample/ctrl ID Pat/Ctr/cAl Test name Test type Result Result unit Result time STAT NH3-0 A NH3-4 A NH3-4 A NH3-4 A NH3-4 A NH3-4 A NH3-4 A ICB C ICV C ICB C ICV C 21B0320-BS1 P 2107005-02 P 21B0320-DUP1 P 21B0320-MS1 P ICB C ICV C 21B0320-MS1 P ICB C ICV C Ammonia_2P Ammonia_2P Ammonia_2P Ammonia_2P Ammonia_2P Ammonia_2P Ammonia_2P Ammonia_2P Ammonia_2P Ammonia_2P Ammonia_2P Ammonia_2P Ammonia_2P Ammonia_2P Ammonia_2P Ammonia_2P Ammonia_2P Ammonia_2P Ammonia_2P Ammonia_2P -0.01655 mg/l 0.09183 mg/l 0.2069 mg/l 0.40915 mg/l 0.81789 mg/l 1.98851 mg/l 4.00163 mg/l -0.02064 mg/l 2.97369 mg/l -0.011 mg/l 3.09356 mg/l 2.03161 mg/l 2.94784 mg/l 2.82613 mg/l 5.02626 mg/l -0.00982 mg/l 3.01734 mg/l 5.26219 mg/l -0.0181 mg/l 3.151 mg/l 8/3/2021 15:52 8/3/2021 15:54 8/3/2021 15:56 8/3/2021 15:58 8/3/2021 16:00 8/3/2021 16:02 8/3/2021 16:02 8/3/2021 16:04 8/3/2021 16:05 8/3/2021 16:25 8/3/2021 16:26 8/3/2021 16:27 8/3/2021 16:28 8/3/2021 16:28 8/3/2021 16:30 8/3/2021 16:31 8/3/2021 16:31 8/3/2021 16:43 8/3/2021 16:44 8/3/2021 16:45 Status MA MA MA MA MA MA MA MA MA MA MA MA MA MA AR MA MA MA MA MA Errors 30, 30, 19,30, 30, 30, Notes R R Dilution 1 +Manual diluRteiosponse Blank respoMnsain abs. 1Blank abs. 1Sample type 0 0.02595 0.00007 0.02603 0.00007 39 0.03576 -0.00024 0.03551 -0.00024 19 0.04651 -0.00007 0.04643 -0.00007 9 0.0663 -0.00006 0.06624 -0.00006 4 0.10977 0.00005 0.10981 0.00005 1 0.25994 -0.00018 0.25976 -0.00018 0 0.60726 -0.00011 0.60716 -0.00011 0 0.02558 -0.00003 0.02555 -0.00003 0 0.41584 -0.00004 0.4158 -0.00004 0 0.02645 0.00002 0.02647 0.00002 0 0.43665 -0.00005 0.4366 -0.00005 0 0 0.2662 -0.00006 0.26614 -0.00006 Sample type 1 0 0 0.41141 -0.00005 0.41136 -0.00005 Sample type 1 0 0 0.39077 -0.00004 0.39074 -0.00004 Sample type 1 0 0 0.81209 0 0.81209 0 Sample type 1 0 0.02656 0.00003 0.02658 0.00003 0 0.42337 0.00032 0.42369 0.00032 9 0 0.07827 0.00004 0.07831 0.00004 Sample type 1 0 0.02581 -0.00006 0.02575 -0.00006 0 0.44676 -0.00014 0.44662 -0.00014 Table of Contents Page 55 of 100 Table of Contents Page 56 of 100 Table of Contents Page 57 of 100 Table of Contents Page 58 of 100 Table of Contents By Anna Knoebel at 7:19 am, Aug 25, 2021 Page 59 of 100 Table of Contents Page 60 of 100 Environmental Protection Agency Region 5 Chicago Regional Laboratory 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 Description: Standard Type: Solvent: Final Volume (mls): Vials: Vendor: Lot Number: Analytical Standard Record US EPA Region 5 LSASD Analytical Services Branch 21G2804 NH3N-WCS (4.00 mg/L) Other Solution reagent water 50 1 Absolute Grade 102819 Expires: Prepared: Prepared By: Department: Last Edit: Aug-28-21 Jul-28-21 Nidia Fuentes A&I Jul-28-21 11:53 by NF Table of Contents Analyte Ammonia as N Total Kjeldahl Nitrogen CAS Number NA NA Concentration (ppm) 4 4 Parent Standards used in this standard: Standard 19K1901 Description NH3N/TKN-SCS (1000 mg/L) 21B2408 21G0902 Pipette (Electronic) -- 50 -1,000 uL Sulfuric Acid 9673-00 Prepared Nov-19-19 Feb-15-21 Jul-09-21 Prepared By ** Vendor ** Colin Breslin ** Vendor ** Expires Oct-28-21 Aug-31-21 May-11-25 Last Edit Jun-03-21 12:36 by NF Feb-24-21 12:57 by NF Jul-28-21 10:03 by NF (mls) 0.2 0.2 0.05 By Anna Knoebel at 7:26 am, Aug 25, 2021 PaPgaeg6e11ooff1100 Environmental Protection Agency Region 5 Chicago Regional Laboratory 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 Description: Standard Type: Solvent: Final Volume (mls): Vials: Vendor: Lot Number: Analytical Standard Record US EPA Region 5 LSASD Analytical Services Branch 21G2805 NH3N-WcS (3 mg/L) Other Solution reagent water 50 1 ERA 091120m Expires: Prepared: Prepared By: Department: Last Edit: Aug-28-21 Jul-28-21 Nidia Fuentes A&I Aug-25-21 15:19 by NF Table of Contents Analyte Ammonia as N CAS Number NA Concentration (ppm) 3 Parent Standards used in this standard: Standard 21E0614 Description NH3N-StockControlStandard 21B2408 21G0902 Pipette (Electronic) -- 50 -1,000 uL Sulfuric Acid 9673-00 Prepared May-06-21 Feb-15-21 Jul-09-21 Prepared By ** Vendor ** Colin Breslin ** Vendor ** Expires Nov-03-22 Aug-31-21 May-11-25 Last Edit Aug-25-21 15:16 by NF Feb-24-21 12:57 by NF Jul-28-21 10:03 by NF (mls) 0.15 0.15 0.05 By Anna Knoebel at 6:37 am, Aug 26, 2021 PaPgaeg6e21ooff1100 Environmental Protection Agency Region 5 Chicago Regional Laboratory 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 Description: Standard Type: Solvent: Final Volume (mls): Vials: Vendor: Lot Number: Same as 21G2803 Analyte Analytical Standard Record US EPA Region 5 LSASD Analytical Services Branch 21G2806 NH3N-WCS (0.00 mg/L) Other Solution reagent water 1000 1 see standards list see standards list Expires: Prepared: Prepared By: Department: Last Edit: Aug-28-21 Jul-28-21 Nidia Fuentes A&I Jul-28-21 10:04 by NF By Anna Knoebel at 8:34 am, Aug 25, 2021 CAS Number Concentration (ppm) Ammonia as N Total Kjeldahl Nitrogen NA 0 NA 0 Table of Contents Parent Standards used in this standard: Standard 19K1901 Description NH3N/TKN-SCS (1000 mg/L) 21B2306 21G0902 Pipette (Electronic) -- 50 -1,000 uL Sulfuric Acid 9673-00 Prepared Nov-19-19 Feb-15-21 Jul-09-21 Prepared By ** Vendor ** Nidia Fuentes ** Vendor ** Expires Oct-28-21 Aug-31-21 May-11-25 Last Edit Jun-03-21 12:36 by NF Apr-05-21 09:19 by AK Jul-28-21 10:03 by NF (mls) 0 1 1 PaPgaeg6e31ooff1100 Environmental Protection Agency Region 5 Chicago Regional Laboratory 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 Analytical Standard Record US EPA Region 5 LSASD Analytical Services Branch 21G2807 Description: Standard Type: Solvent: Final Volume (mls): Vials: Vendor: Lot Number: NH3N-MRL Spike Analyte Spike reagent water 50 1 Absolute Grade 102819 Same as WCS - 21G2804 Analyte Expires: Prepared: Prepared By: Department: Last Edit: Aug-28-21 Jul-28-21 Nidia Fuentes A&I Aug-04-21 15:43 by NF By Anna Knoebel at 7:26 am, Aug 25, 2021 CAS Number Concentration (ppm) Ammonia as N Total Kjeldahl Nitrogen NA 4 NA 4 Table of Contents Parent Standards used in this standard: Standard 19K1901 Description NH3N/TKN-SCS (1000 mg/L) 21B2408 21G0902 Pipette (Electronic) -- 50 -1,000 uL Sulfuric Acid 9673-00 Prepared Nov-19-19 Feb-15-21 Jul-09-21 Prepared By ** Vendor ** Colin Breslin ** Vendor ** Expires Oct-28-21 Aug-31-21 May-11-25 Last Edit Jun-03-21 12:36 by NF Feb-24-21 12:57 by NF Jul-28-21 10:03 by NF (mls) 0.2 0.2 0.05 PaPgaeg6e41ooff1100 Environmental Protection Agency Region 5 Chicago Regional Laboratory 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 Table of Contents Analytical Standard Record US EPA Region 5 LSASD Analytical Services Branch 21H0222 Description: Standard Type: Solvent: Final Volume (mls): Vials: Vendor: Lot Number: NH3N - WCS (0.2 mg/L) Other Solution BLANK: 21G2806 2 1 Absolute Grade 102819 Prepared by instrument DA-4 Expires: Prepared: Prepared By: Department: Last Edit: Aug-03-21 Aug-02-21 Nidia Fuentes A&I Aug-04-21 14:51 by NF By Anna Knoebel at 8:40 am, Aug 25, 2021 Analyte CAS Number Concentration (ppm) Ammonia as N Total Kjeldahl Nitrogen NA 0.2 NA 0.2 Parent Standards used in this standard: Standard 21G2804 Description NH3N-WCS (4.00 mg/L) Prepared Jul-28-21 Prepared By Nidia Fuentes Expires Aug-28-21 Last Edit Jul-28-21 11:53 by NF (mls) 0.1 PaPgaeg6e51ooff1100 Environmental Protection Agency Region 5 Chicago Regional Laboratory 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 Analytical Standard Record US EPA Region 5 LSASD Analytical Services Branch 21H0223 Description: Standard Type: Solvent: Final Volume (mls): Vials: Vendor: Lot Number: NH3N - WCS (0.4 mg/L) Other Solution BLANK: 21G2806 2 1 Absolute Grade 102819 Expires: Prepared: Prepared By: Department: Last Edit: Aug-03-21 Aug-02-21 Nidia Fuentes A&I Aug-06-21 12:28 by NF Prepared by instrument DA-4 By Anna Knoebel at 8:47 am, Aug 25, 2021 Analyte CAS Number Concentration (ppm) Ammonia as N Total Kjeldahl Nitrogen NA 0.4 NA 0.4 Table of Contents Parent Standards used in this standard: Standard 21G2804 Description NH3N-WCS (4.00 mg/L) Prepared Jul-28-21 Prepared By Nidia Fuentes Expires Aug-28-21 Last Edit Jul-28-21 11:53 by NF (mls) 0.2 PaPgaeg6e61ooff1100 Environmental Protection Agency Region 5 Chicago Regional Laboratory 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 Analytical Standard Record US EPA Region 5 LSASD Analytical Services Branch 21H0224 Description: Standard Type: Solvent: Final Volume (mls): Vials: Vendor: Lot Number: NH3N - WCS (0.8 mg/L) Other Solution BLANK: 21G2806 2 1 Absolute Grade 102819 Expires: Prepared: Prepared By: Department: Last Edit: Aug-03-21 Aug-02-21 Nidia Fuentes A&I Aug-04-21 14:53 by NF Prepared by instrument DA-4 By Anna Knoebel at 8:47 am, Aug 25, 2021 Analyte CAS Number Concentration (ppm) Ammonia as N Total Kjeldahl Nitrogen NA 0.8 NA 0.8 Table of Contents Parent Standards used in this standard: Standard 21G2804 Description NH3N-WCS (4.00 mg/L) Prepared Jul-28-21 Prepared By Nidia Fuentes Expires Aug-28-21 Last Edit Jul-28-21 11:53 by NF (mls) 0.4 PaPgaeg6e71ooff1100 Environmental Protection Agency Region 5 Chicago Regional Laboratory 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 Table of Contents Analytical Standard Record US EPA Region 5 LSASD Analytical Services Branch 21H0225 Description: Standard Type: Solvent: Final Volume (mls): Vials: Vendor: Lot Number: NH3N - WCS (2.0 mg/L) Other Solution BLANK: 21G2806 2 1 Absolute Grade 102819 Prepared by instrument DA-4 Expires: Prepared: Prepared By: Department: Last Edit: Aug-03-21 Aug-02-21 Nidia Fuentes A&I Aug-04-21 14:54 by NF By Anna Knoebel at 8:48 am, Aug 25, 2021 Analyte Ammonia as N Total Kjeldahl Nitrogen CAS Number NA NA Concentration (ppm) 2 2 Parent Standards used in this standard: Standard 21G2804 Description NH3N-WCS (4.00 mg/L) Prepared Jul-28-21 Prepared By Nidia Fuentes Expires Aug-28-21 Last Edit Jul-28-21 11:53 by NF (mls) 1 PaPgaeg6e81ooff1100 Environmental Protection Agency Region 5 Chicago Regional Laboratory 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 Analytical Standard Record US EPA Region 5 LSASD Analytical Services Branch 21H0226 Description: Standard Type: Solvent: Final Volume (mls): Vials: Vendor: Lot Number: NH3N - WCS (0.10 mg/L) Other Solution Blank LIMS#: 21G2806 2 1 Absolute Grade 102819 Prepared by instrument DA-4 Expires: Prepared: Prepared By: Department: Last Edit: Aug-03-21 Aug-02-21 Nidia Fuentes A&I Aug-04-21 14:55 by NF By Anna Knoebel at 8:50 am, Aug 25, 2021 Analyte CAS Number Concentration (ppm) Ammonia as N Total Kjeldahl Nitrogen NA 0.1 NA 0.1 Table of Contents Parent Standards used in this standard: Standard 21G2804 Description NH3N-WCS (4.00 mg/L) Prepared Jul-28-21 Prepared By Nidia Fuentes Expires Aug-28-21 Last Edit Jul-28-21 11:53 by NF (mls) 0.05 PaPgaeg6e91ooff1100 Environmental Protection Agency Region 5 Chicago Regional Laboratory 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 Analytical Standard Record US EPA Region 5 LSASD Analytical Services Branch 21H0402 Description: Standard Type: Solvent: Final Volume (mls): Vials: Vendor: Lot Number: NH3N - WCS (0.2 mg/L) Other Solution BLANK: 21G2806 2 1 Absolute Grade 102819 Prepared by instrument DA-4 Expires: Prepared: Prepared By: Department: Last Edit: Aug-04-21 Aug-03-21 Nidia Fuentes A&I Aug-25-21 15:25 by NF Analyte By Anna Knoebel at 6:39 am, Aug 26, 2021 CAS Number Concentration (ppm) Ammonia as N Total Kjeldahl Nitrogen NA 0.2 NA 0.2 Table of Contents Parent Standards used in this standard: Standard 21G2804 Description NH3N-WCS (4.00 mg/L) Prepared Jul-28-21 Prepared By Nidia Fuentes Expires Aug-28-21 Last Edit Jul-28-21 11:53 by NF (mls) 0.1 PaPgaeg7e01ooff1100 Environmental Protection Agency Region 5 Chicago Regional Laboratory 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 Table of Contents Analytical Standard Record US EPA Region 5 LSASD Analytical Services Branch 21H0403 Description: Standard Type: Solvent: Final Volume (mls): Vials: Vendor: Lot Number: NH3N - WCS (0.4 mg/L) Other Solution BLANK: 21G2806 2 1 Absolute Grade 102819 Prepared by instrument DA-4 Analyte Expires: Prepared: Prepared By: Department: Last Edit: Aug-04-21 Aug-03-21 Nidia Fuentes A&I Aug-05-21 08:40 by NF By Anna Knoebel at 9:17 am, Aug 25, 2021 CAS Number Concentration (ppm) Ammonia as N Total Kjeldahl Nitrogen NA 0.4 NA 0.4 Parent Standards used in this standard: Standard 21G2804 Description NH3N-WCS (4.00 mg/L) Prepared Jul-28-21 Prepared By Nidia Fuentes Expires Aug-28-21 Last Edit Jul-28-21 11:53 by NF (mls) 0.2 PaPgaeg7e11ooff1100 Environmental Protection Agency Region 5 Chicago Regional Laboratory 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 Table of Contents Analytical Standard Record US EPA Region 5 LSASD Analytical Services Branch 21H0404 Description: Standard Type: Solvent: Final Volume (mls): Vials: Vendor: Lot Number: NH3N - WCS (0.8 mg/L) Other Solution BLANK: 21G2806 2 1 Absolute Grade 102819 Prepared by instrument DA-4 Expires: Prepared: Prepared By: Department: Last Edit: Aug-04-21 Aug-03-21 Nidia Fuentes A&I Aug-06-21 12:44 by NF By Anna Knoebel at 9:16 am, Aug 25, 2021 Analyte CAS Number Concentration (ppm) Ammonia as N Total Kjeldahl Nitrogen NA 0.8 NA 0.8 Parent Standards used in this standard: Standard 21G2804 Description NH3N-WCS (4.00 mg/L) Prepared Jul-28-21 Prepared By Nidia Fuentes Expires Aug-28-21 Last Edit Jul-28-21 11:53 by NF (mls) 0.4 PaPgaeg7e21ooff1100 Environmental Protection Agency Region 5 Chicago Regional Laboratory 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 Analytical Standard Record US EPA Region 5 LSASD Analytical Services Branch 21H0405 Description: Standard Type: Solvent: Final Volume (mls): Vials: Vendor: Lot Number: NH3N - WCS (2.0 mg/L) Other Solution BLANK: 21G2806 2 1 Absolute Grade 102819 Prepared by instrument DA-4 Expires: Prepared: Prepared By: Department: Last Edit: Aug-04-21 Aug-03-21 Nidia Fuentes A&I Aug-05-21 08:46 by NF By Anna Knoebel at 9:15 am, Aug 25, 2021 Analyte CAS Number Concentration (ppm) Ammonia as N Total Kjeldahl Nitrogen NA 2 NA 2 Table of Contents Parent Standards used in this standard: Standard 21G2804 Description NH3N-WCS (4.00 mg/L) Prepared Jul-28-21 Prepared By Nidia Fuentes Expires Aug-28-21 Last Edit Jul-28-21 11:53 by NF (mls) 1 PaPgaeg7e31ooff1100 Environmental Protection Agency Region 5 Chicago Regional Laboratory 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 Table of Contents Analytical Standard Record US EPA Region 5 LSASD Analytical Services Branch 21H0406 Description: Standard Type: Solvent: Final Volume (mls): Vials: Vendor: Lot Number: NH3N - WCS (0.10 mg/L) Other Solution Blank LIMS#: 21G2806 2 1 Absolute Grade 102819 Prepared by instrument DA-4 Expires: Prepared: Prepared By: Department: Last Edit: Aug-04-21 Aug-03-21 Nidia Fuentes A&I Aug-05-21 08:47 by NF By Anna Knoebel at 9:14 am, Aug 25, 2021 Analyte Ammonia as N Total Kjeldahl Nitrogen CAS Number NA NA Concentration (ppm) 0.1 0.1 Parent Standards used in this standard: Standard 21G2804 Description NH3N-WCS (4.00 mg/L) Prepared Jul-28-21 Prepared By Nidia Fuentes Expires Aug-28-21 Last Edit Jul-28-21 11:53 by NF (mls) 0.05 PaPgaeg7e41ooff1100 Table of Contents ANALYSIS REAGENTS/STANDARDS 21B0403 Page 75 of 100 Environmental Protection Agency Region 5 Chicago Regional Laboratory 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 Reagent Preparation Bench Sheet Table of Contents Print Date: 2/4/2021 Parameter / SOP #: Ammonia \ SOP AIG029B ver #7 #8 Reagent: NH3N-Sodium Phenolate Sol. By NFUENTES at 8:51 am, Mar 03, 2021 LIMS ID: 21B0403 Phenol (C6H6O) Chemical Name (Formula) Prepared by: Nidia Fuentes Preparation Date: Feb-04-21 Expiration Date: Feb-04-22 LIMS ID 19I0601 Mass or Volume (specify units) 8.3275 g Sodium Hydroxide (NaOH) 20C1103 3.2465 g Total Volume : 100 mL Comments : Balance #17 Reviewed w/ By AK at 8:44 am, Mar 04, 2021 Analyst Signature: Page 76Paogfe1100of 1 Table of Contents Page 77 of 100 Table of Contents ANALYSIS REAGENTS/STANDARDS 21B0404 Page 78 of 100 Environmental Protection Agency Region 5 Chicago Regional Laboratory 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 Reagent Preparation Bench Sheet Table of Contents Print Date: 2/4/2021 Parameter / SOP #: NH3N (Distilled)/AIG029B v7 8 Reagent: NH3N-5% EDTA Buffer Sol. By NFUENTES at 8:54 am, Mar 03, 2021 LIMS ID: 21B0404 Chemical Name (Formula) Disodium dihydrogen EDTA (Na2EDTA.2H2O) Prepared by: Nidia Fuentes Preparation Date: Feb-04-21 Expiration Date: Feb-04-22 LIMS ID 19J0107 Mass or Volume (specify units) 5.5033 g Sodium hydroxide (NaOH) 17K0806 20C1103 By NFUENTES at 8:55 am, Mar 03, 2021 0.5535 g Total Volume : Comments : Balance #17 Reviewed by 100 mL By AK at 8:49 am, Mar 04, 2021 Analyst Signature: Page 79Paogfe1100of 1 Table of Contents Page 80 of 100 Table of Contents ANALYSIS REAGENTS/STANDARDS 21B0405 Page 81 of 100 Environmental Protection Agency Region 5 Chicago Regional Laboratory 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 Reagent Preparation Bench Sheet Table of Contents Print Date: 2/4/2021 Parameter / SOP #: NH3N/AIG029B V Reagent: NH3N-SodiumNitroprusside LIMS ID: 21B0405 Chemical Name (Formula) Sodium Nitroprusside (Na2Fr(CN)5NO.2H2O Prepared by: Nidia Fuentes Preparation Date: Feb-04-21 Expiration Date: Feb-04-22 LIMS ID 19F1901 Mass or Volume (specify units) 0.0535 g Total Volume : 100 mL Comments : Balance #17 Reviewed w/ By AK at 8:31 am, Mar 04, 2021 Analyst Signature: Page 82Paogfe1100of 1 Table of Contents Page 83 of 100 Table of Contents ANALYSIS REAGENTS/STANDARDS 21G2803 Page 84 of 100 Table of Contents Environmental Protection Agency Region 5 Chicago Regional Laboratory Print Date: 8/6/2021 Copy was inadvertently not print 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 By NFUENTES at 9:39 am, Aug 09, 2021 Reagent Preparation Bench Sheet Parameter / SOP #: NH3N Distilled/AIG029B v7 9 Reagent: NH3NDistilled-ReceivingSol/BLK By NFUENTES at 2:10 pm, Aug 25, 2021 LIMS ID: 21G2803 Chemical Name (Formula) Sulfuric Acid (H2SO4) Prepared by: Nidia Fuentes Preparation Date: Jul-28-21 Expiration Date: Aug-28-21 LIMS ID 21G0902 Mass or Volume (specify units) 1 mL Total Volume : 1000 mL Comments : See user defined fields for details Analyst Signature: By Anna Knoebel at 6:21 am, Aug 26, 2021 PaPgaeg8e51ooff1100 Table of Contents ANALYSIS REAGENTS/STANDARDS 21H0221 Page 86 of 100 Table of Contents Environmental Protection Agency Region 5 Print Date: 8/26/2021 Chicago Regional Laboratory This prep sheet was inadvertently not printed on the 536 South Clark Street, Chicago, IL 60605 day of prep Phone:(312)353-8370 Fax:(312)886-2591 By NFUENTES at 9:52 am, Aug 26, 2021 Reagent Preparation Bench Sheet Parameter / SOP #: NH3/AIG029B v9 Reagent: NH3N-Sodium Hypochlorite Solution LIMS ID: 21H0221 Chemical Name (Formula) Sodium hypochlorite 5% (NaOCl ) Prepared by: Nidia Fuentes Preparation Date: Aug-02-21 Expiration Date: Aug-03-21 LIMS ID 21H0201 Mass or Volume (specify units) 5 mL Total Volume : Comments : 10 mL Analyst Signature: By Anna Knoebel at 10:23 am, Aug 26, 2021 PaPgaeg8e71ooff1100 Table of Contents ANALYSIS REAGENTS/STANDARDS 21B0403 Page 88 of 100 Environmental Protection Agency Region 5 Chicago Regional Laboratory 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 Reagent Preparation Bench Sheet Table of Contents Print Date: 2/4/2021 Parameter / SOP #: Ammonia \ SOP AIG029B ver #7 #8 Reagent: NH3N-Sodium Phenolate Sol. By NFUENTES at 8:51 am, Mar 03, 2021 LIMS ID: 21B0403 Phenol (C6H6O) Chemical Name (Formula) Prepared by: Nidia Fuentes Preparation Date: Feb-04-21 Expiration Date: Feb-04-22 LIMS ID 19I0601 Mass or Volume (specify units) 8.3275 g Sodium Hydroxide (NaOH) 20C1103 3.2465 g Total Volume : 100 mL Comments : Balance #17 Reviewed w/ By AK at 8:44 am, Mar 04, 2021 Analyst Signature: Page 89Paogfe1100of 1 Table of Contents Page 90 of 100 Table of Contents ANALYSIS REAGENTS/STANDARDS 21B0404 Page 91 of 100 Environmental Protection Agency Region 5 Chicago Regional Laboratory 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 Reagent Preparation Bench Sheet Table of Contents Print Date: 2/4/2021 Parameter / SOP #: NH3N (Distilled)/AIG029B v7 8 Reagent: NH3N-5% EDTA Buffer Sol. By NFUENTES at 8:54 am, Mar 03, 2021 LIMS ID: 21B0404 Chemical Name (Formula) Disodium dihydrogen EDTA (Na2EDTA.2H2O) Prepared by: Nidia Fuentes Preparation Date: Feb-04-21 Expiration Date: Feb-04-22 LIMS ID 19J0107 Mass or Volume (specify units) 5.5033 g Sodium hydroxide (NaOH) 17K0806 20C1103 By NFUENTES at 8:55 am, Mar 03, 2021 0.5535 g Total Volume : Comments : Balance #17 Reviewed by 100 mL By AK at 8:49 am, Mar 04, 2021 Analyst Signature: Page 92Paogfe1100of 1 Table of Contents Page 93 of 100 Table of Contents ANALYSIS REAGENTS/STANDARDS 21B0405 Page 94 of 100 Environmental Protection Agency Region 5 Chicago Regional Laboratory 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 Reagent Preparation Bench Sheet Table of Contents Print Date: 2/4/2021 Parameter / SOP #: NH3N/AIG029B V Reagent: NH3N-SodiumNitroprusside LIMS ID: 21B0405 Chemical Name (Formula) Sodium Nitroprusside (Na2Fr(CN)5NO.2H2O Prepared by: Nidia Fuentes Preparation Date: Feb-04-21 Expiration Date: Feb-04-22 LIMS ID 19F1901 Mass or Volume (specify units) 0.0535 g Total Volume : 100 mL Comments : Balance #17 Reviewed w/ By AK at 8:31 am, Mar 04, 2021 Analyst Signature: Page 95Paogfe1100of 1 Table of Contents Page 96 of 100 Table of Contents ANALYSIS REAGENTS/STANDARDS 21G2803 Page 97 of 100 Table of Contents Environmental Protection Agency Region 5 Chicago Regional Laboratory Print Date: 8/6/2021 Copy was inadvertently not print 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 By NFUENTES at 9:39 am, Aug 09, 2021 Reagent Preparation Bench Sheet Parameter / SOP #: NH3N Distilled/AIG029B v7 9 Reagent: NH3NDistilled-ReceivingSol/BLK By NFUENTES at 2:10 pm, Aug 25, 2021 LIMS ID: 21G2803 Chemical Name (Formula) Sulfuric Acid (H2SO4) Prepared by: Nidia Fuentes Preparation Date: Jul-28-21 Expiration Date: Aug-28-21 LIMS ID 21G0902 Mass or Volume (specify units) 1 mL Total Volume : 1000 mL Comments : See user defined fields for details Analyst Signature: By Anna Knoebel at 6:21 am, Aug 26, 2021 PaPgaeg9e81ooff1100 Table of Contents ANALYSIS REAGENTS/STANDARDS 21H0401 Page 99 of 100 Table of Contents Environmental Protection Agency Region 5 Chicago Regional Laboratory Print Date: 8/4/2021 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 Benchsheet was inadvertently not created on the day it was prepared. Reagent Preparation Bench Sheet By NFUENTES at 2:30 pm, Aug 04, 2021 Parameter / SOP #: By NFUENTES at 4:26 pm, Aug 25, 2021 NH3/AIG029B v8 9 Prepared by: Nidia Fuentes Reagent: NH3N-Sodium Hypochlorite Solution Preparation Date: Aug-03-21 LIMS ID: 21H0401 Expiration Date: Aug-04-21 Chemical Name (Formula) LIMS ID Mass or Volume (specify units) Sodium hypochlorite 5% (NaOCl ) 21H0201 5 mL Total Volume : 10 mL Comments : 7KH UHDJHQW ZDV SUHSDUHG RQ EXW QRW HQWHUHG LQWR /,06 XQWLO 7KLV ZDV GRQH LQDGYHUWHQWO\ Analyst Signature: By Anna Knoebel at 7:01 am, Aug 26, 2021 PaPgeag1e010 of 100 Table of Contents UNITED STATES ENVIRONMENTAL PROTECTION AGENCY REGION 5 ANALYTICAL SERVICES BRANCH LABORATORY 536 SOUTH CLARK STREET (LAB-10C) CHICAGO, ILLINOIS 60605 ELECTRONIC LABORATORY DATA PACKAGE FINAL LEVEL IV COVER PAGE LIMS Work order(s): Primary Analyst: Analysis: Date: Data Reporting Qualtrax Workflow ID: Digital Signature of Primary Analyst: 2107010 Nidia Fuentes TKN DA August 26, 2021 26392 Digital Signature Agreement: By signing above the primary analyst understands and agrees that they will be held legally bound, obligated, and responsible for the use of their digital signature as they would be by using their hand-written signature. Page 1 of 91 Client Project Name: Work Order Number: Ranovael @2BA2021) 2107010 1 Cover Page 2 Level I Report 3 QC Summary 4 Checklist 5 Sample Prep and Supporting Data (TKN DA) 5.1 Bench Sheets (B21G029) 5.2 Batch Reagents (B21G029) 5.3 Standards (19K1902) 5.4 Standards (21G2605) 5.5 Standards (21G2606) 5.6 Standards (21G2607) 5.7 Standards (21G2608) 5.8 Standards (21G2909) 5.9 Standards (21G2910) 5.10 Standards (21G2911) 5.11 Standards (21G2912) 5.12 Standards (21G2913) 5.13 Standards (21G2914) 5.14 Standards (21G2925) 5.15 Standards (21G2926) 5.16 Standards (21G2927) 5.17 Standards (21G2928) 5.18 Standards (21G2929) 5.19 Standards (21G2930) 5.20 Analysis Data and Supporting Documents (21F1003) Table of Contents Table of Contents 1 4 12 16 20 21 26 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 536 South Clark Street, Chicago, IL 60605 TEL: 312-353-1226 FAX: 312-353-9069 Page 2 of 91 Client Project Name: Work Order Number: Ranovael @2BA2021) 2107010 5.21 Analysis Data and Supporting Documents (21G2902) 5.22 Sequence Reagents (21F1003) 5.23 Sequence Reagents (21G2902) Table of Contents Table of Contents (continued) 71 78 85 536 South Clark Street, Chicago, IL 60605 TEL: 312-353-1226 FAX: 312-353-9069 Page 2 of 91 UNITED STATES ENVIRONMENTAL PROTECTION AGENCY US EPA Region 5 LSASD Analytical Services Branch 536 SOUTH CLARK STREET CHICAGO, ILLINOIS 60605 Table of Contents Date: 8/26/2021 Title: To: From: ASB Data Report for Ranovael Water Division, US EPA Region 5 77 West Jackson Boulevard Chicago, IL 60604 Nidia Fuentes, Chemist fuentes.nidia@epa.gov US EPA Region 5 LSASD Analytical Services Branch The results reported in this document apply to the samples as received and relate only to the items tested. The data transmitted under this cover memo successfully passed the data review process and applicable Analytical Services Branch (ASB) laboratory Standard Operating Procedures. In accordance with the EPA QA/G-8 Guidance on Environmental Data Verification and Data Validation, ASB performs data verification on all the data generated internally. ASB does not perform data validation or quality assessment procedures. This report was reviewed and the information provided herein accurately represents the analysis performed. Please contact the analyst with any technical report issues, Amanda Wroble at (312)-353-0375 for sample project concerns, and Robert Snyder at (312)-353-9083 with data transmittal questions. Thank you. Attached are Results for: Ranovael Analyses included in this report: TKN DA Report Name: 2107010 TKN DA FINAL Aug 26 21 1149 Page 4 of 91 Water Division, US EPA Region 5 77 West Jackson Boulevard Chicago IL, 60604 Environmental Protection Agency Region 5 US EPA Region 5 LSASD Analytical Services Branch 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 Project: Ranovael Project Number: 02BA2021 Project Manager: Ben Atkinson Accredited Analyses included in this Report Table of Contents Reported: Aug-26-21 11:49 Method: Analysis: Analyte EPA 351.2 in Water TKN DA Total Kjeldahl Nitrogen Certifications ISO/IEC 17025:2017 Analytes not listed above are not accredited by ANAB. Report Name: 2107010 TKN DA FINAL Aug 26 21 1149 Page 5 of 91 Water Division, US EPA Region 5 77 West Jackson Boulevard Chicago IL, 60604 Environmental Protection Agency Region 5 US EPA Region 5 LSASD Analytical Services Branch 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 Project: Ranovael Project Number: 02BA2021 Project Manager: Ben Atkinson Table of Contents Reported: Aug-26-21 11:49 ANALYSIS CASE NARRATIVE Analysis List TKN DA Analyst: Nidia Fuentes Phone #: 312-353-9079 General Information Samples analyzed: Sample Analysis List 2107010-01 TKN DA 2107010-02 TKN DA 2107010-03 TKN DA 2107010-04 TKN DA 2107010-05 TKN DA Holding times: All holding times were met. Sample Analysis and Results The samples were analyzed using ASB SOP AIG035B, Version #8. The data reported herein meets any requirements referenced in the previously mentioned SOP and Sampling QAPP titled "General Field Sampling Plan for AFO Inspections" and dated FY 2021, except for those listed in the Quality Control section. SOP Based on: Method List EPA 351.2 Quality Control All quality control audits were within ASB limits or did not result in qualification of the data except for matrix spike recovery. B21G029-MS1 Source: 2107010-02 Recovery for Total Kjeldahl Nitrogen (112%) was outside acceptance limits (90-110%) for TKN DA. Affected sample results were qualified accordingly. Report Name: 2107010 TKN DA FINAL Aug 26 21 1149 Page 6 of 91 01234516718945878351717351 395735199549854 !"#$#%%& '(")&*+,, -.%/0123456, 7"8/0123554291 Table of Contents ?@A@<0 BCDEDCD :;07351;;<19839;74237=>491 43187KHELBDLBDBCCBHBEHMBN 3718H ?9874<323=351F:;07351 45G78H915297 45G78N91974H 179@ O49==9<923= 45G78IJ674H DB>BDBC 7P548Q5H Z%.X$'.U. R"%#S'T'U'.&VW-XY%)'. S"%S%/ Y%(%'T%\Z^/ +))%\*.Z^/ X)4,4211/,,0]\"^_X_3 !'.Z#%U!'. `%!U%^abc"!!%^ 66R%U["($U.Z!%T"#\ '(")&*+,,] S"%Y%(%'T%\/ [!41421,5/] S"%+))%\*./ [!41421,9/9 -.%/012342,,] 7"8/01235542,,1 "de!%")Uf!"g%!U %"!U*."( Y%(%'T%\.'(% -"e%#h#$*.(!\%\ i7= ?54O@4K74566718=H i7= i7= i7= !%#0U3'.j#d"'./ S%j"! !%#4k6, ;96P7l<H BCDEDCDmDC ;96P7KH rJmCmBCCCHBs ;96P7I967H >@C ;96P7566718=H 19 =3= Xdd.'"tSX&S'U'!!%\ o5K8367pK9=q 25 ZaS 2 t'#"%4t'#'%tSX&W.w^d"'(#%\('. 25 !'\U&_S 6 !'\U&_ 6 _`tSX 25 _"!-Ue#USX 25 N9843nH ?9874 ;96P7598351L566718=H 915297 0nP347= X)41242111/2 [!41642111/2 X)41242111/2 [!42242111/2 [!42242111/2 X)41242111/2 X)41242111/2 566718= euv1 euv6 euv1 euv6 euv6 euv1 euv1 ;96P7l<H BCDEDCDmDB ;96P7KH rJmCmBCCCHM{ N9843nH ?9874 ;96P7I967H ;@C ;96P7598351L566718=H @274x5yx456zQ ;96P7566718=H 19 =3= Xdd.'"tSX&S'U'!!%\ o5K8367pK9=q 0nP347= 566718= 25 X)41242111/]9 euv1 ZaS 2 [!41642111/]9 euv6 t'#"%4t'#'%tSX&W.w^d"'(#%\('. 25 X)41242111/]9 euv1 P|a}g~e7of91 Table of Contents Page 8 of 91 Table of Contents Page 9 of 91 Water Division, US EPA Region 5 77 West Jackson Boulevard Chicago IL, 60604 Environmental Protection Agency Region 5 US EPA Region 5 LSASD Analytical Services Branch 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 Project: Ranovael Project Number: 02BA2021 Project Manager: Ben Atkinson Table of Contents Reported: Aug-26-21 11:49 BO1 (2107010-01) Analyte Total Kjeldahl Nitrogen SO1 (2107010-02) Analyte Total Kjeldahl Nitrogen SO2 (2107010-03) Analyte Total Kjeldahl Nitrogen SO3 (2107010-04) Analyte Total Kjeldahl Nitrogen SO4 (2107010-05) Analyte Total Kjeldahl Nitrogen Total Kjeldahl Nitrogen, EPA 351.2 (modified) US EPA Region 5 LSASD Analytical Services Branch Matrix: Water Sampled: Jul-15-21 11:23 Result Flags / Qualifiers MDL Reporting Limit U 0.30 0.50 Received: Jul-16-21 08:46 Units mg/L Dilution 1 Batch B21G029 Matrix: Water Sampled: Jul-15-21 11:49 Result Flags / Qualifiers MDL Reporting Limit 15.2 (MS), K 3.00 5.00 Received: Jul-16-21 08:46 Units mg/L Dilution 10 Batch B21G029 Matrix: Water Sampled: Jul-15-21 11:52 Result Flags / Qualifiers MDL Reporting Limit 11.1 3.00 5.00 Received: Jul-16-21 08:46 Units mg/L Dilution 10 Batch B21G029 Matrix: Water Sampled: Jul-15-21 12:00 Result Flags / Qualifiers MDL Reporting Limit 2.59 0.30 0.50 Received: Jul-16-21 08:46 Units mg/L Dilution 1 Batch B21G029 Matrix: Water Sampled: Jul-15-21 12:07 Result Flags / Qualifiers MDL Reporting Limit 2.36 0.30 0.50 Received: Jul-16-21 08:46 Units mg/L Dilution 1 Batch B21G029 Prepared Jul-26-21 Prepared Jul-26-21 Prepared Jul-26-21 Prepared Jul-26-21 Prepared Jul-26-21 Analyzed Jul-27-21 Analyzed Jul-27-21 Analyzed Jul-27-21 Analyzed Jul-27-21 Analyzed Jul-27-21 Report Name: 2107010 TKN DA FINAL Aug 26 21 1149 Page 10 of 91 Water Division, US EPA Region 5 77 West Jackson Boulevard Chicago IL, 60604 Environmental Protection Agency Region 5 US EPA Region 5 LSASD Analytical Services Branch 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 Project: Ranovael Project Number: 02BA2021 Project Manager: Ben Atkinson Table of Contents Reported: Aug-26-21 11:49 K (MS) U NR Q Notes and Definitions The identification of the analyte is acceptable; the reported value may be biased high. The actual value is expected to be less than the reported value. Matrix spike recovery criteria not met for this analyte Not Detected Not Reported QC limit Exceeded Report Name: 2107010 TKN DA FINAL Aug 26 21 1149 Page 11 of 91 Environmental Protection Agency US EPA Region 5 LSASD Analytical Services Branch 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 Table of Contents Date: Project: 8/26/2021 Ranovael Quality Control Summary Analyst: Nidia Fuentes Analyte: Total Kjeldahl Nitrogen Analysis: TKN DA QC Sample Name 21F1003-CAL1 Result 0.09 Units mg/L Flags / Qualifiers MDL Reporting Limit Spike Level 0.30 0.50 0.000 Source Result % REC or abs diff (pH) % REC or abs diff (pH) Limits % % RPD or abs diff (pH) %RPD or abs diff ( pH) Limits 21F1003-CAL2 0.33 mg/L 0.30 0.50 0.2500 131% 21F1003-CAL3 0.49 mg/L 0.30 0.50 0.5000 97% 21F1003-CAL4 0.94 mg/L 0.30 0.50 1.000 94% 21F1003-CAL5 1.94 mg/L 0.30 0.50 2.000 97% 21F1003-CAL6 2.37 mg/L 0.30 0.50 2.500 95% 21F1003-CAL7 5.11 mg/L 0.30 0.50 5.000 102% 21F1003-CAL8 9.99 mg/L 0.30 0.50 10.00 100% 21F1003-CCB1 0.09 mg/L 0.30 0.50 21F1003-CCB2 0.11 mg/L 0.30 0.50 21F1003-CCB3 0.02 mg/L 0.30 0.50 21F1003-CCB4 0.07 mg/L 0.30 0.50 21F1003-CCB5 0.10 mg/L 0.30 0.50 21F1003-CCB6 0.01 mg/L 0.30 0.50 21F1003-CCB7 0.03 mg/L 0.30 0.50 21F1003-CCB8 0.07 mg/L 0.30 0.50 21F1003-CCB9 0.01 mg/L 0.30 0.50 21F1003-CCBA 0.02 mg/L 0.30 0.50 21F1003-CCBB 0.04 mg/L 0.30 0.50 Report Name: 2107010 TKN DA FINAL Aug 26 21 1149 Page 12 of 91 Environmental Protection Agency US EPA Region 5 LSASD Analytical Services Branch 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 Table of Contents Quality Control Summary Date: 8/26/2021 Analyst: Nidia Fuentes Project: Ranovael Analyte: Total Kjeldahl Nitrogen Analysis: TKN DA QC Sample Name 21F1003-CCV1 Result 5.24 Units mg/L Flags / Qualifiers MDL Reporting Limit Spike Level 0.30 0.50 5.000 Source Result % REC or abs diff (pH) % REC or abs diff (pH) Limits 105% 90-110 % RPD or abs diff (pH) %RPD or abs diff ( pH) Limits 21F1003-CCV2 5.31 mg/L 0.30 0.50 5.000 106% 90-110 21F1003-CCV3 4.99 mg/L 0.30 0.50 5.000 100% 90-110 21F1003-CCV4 5.36 mg/L 0.30 0.50 5.000 107% 90-110 21F1003-CCV5 5.39 mg/L 0.30 0.50 5.000 108% 90-110 21F1003-CCV6 4.82 mg/L 0.30 0.50 5.000 96% 90-110 21F1003-CCV7 5.30 mg/L 0.30 0.50 5.000 106% 90-110 21F1003-CCV8 5.37 mg/L 0.30 0.50 5.000 107% 90-110 21F1003-CCV9 5.06 mg/L 0.30 0.50 5.000 101% 90-110 21F1003-CCVA 5.30 mg/L 0.30 0.50 5.000 106% 90-110 21F1003-CCVB 5.33 mg/L 0.30 0.50 5.000 107% 90-110 21F1003-ICB1 0.05 mg/L 0.30 0.50 21F1003-ICV1 4.98 mg/L 0.30 0.50 5.000 100% 90-110 21G2902-CAL1 0.13 mg/L 0.30 0.50 0.000 % 21G2902-CAL2 0.33 mg/L 0.30 0.50 0.2500 130% 21G2902-CAL3 0.51 mg/L 0.30 0.50 0.5000 103% 21G2902-CAL4 0.93 mg/L 0.30 0.50 1.000 93% 21G2902-CAL5 1.88 mg/L 0.30 0.50 2.000 94% 21G2902-CAL6 2.38 mg/L 0.30 0.50 0.2500 954% Report Name: 2107010 TKN DA FINAL Aug 26 21 1149 Page 13 of 91 Environmental Protection Agency US EPA Region 5 LSASD Analytical Services Branch 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 Table of Contents Quality Control Summary Date: 8/26/2021 Analyst: Nidia Fuentes Project: Ranovael Analyte: Total Kjeldahl Nitrogen Analysis: TKN DA QC Sample Name 21G2902-CAL7 Result 5.12 Units mg/L Flags / Qualifiers MDL Reporting Limit Spike Level 0.30 0.50 5.000 Source Result % REC or abs diff (pH) % REC or abs diff (pH) Limits 102% % RPD or abs diff (pH) %RPD or abs diff ( pH) Limits 21G2902-CAL8 9.99 mg/L 0.30 0.50 10.00 100% 21G2902-CCB1 0.13 mg/L 0.30 0.50 21G2902-CCB2 0.15 mg/L 0.30 0.50 21G2902-CCB3 0.05 mg/L 0.30 0.50 21G2902-CCV1 5.41 mg/L 0.30 0.50 5.000 108% 90-110 21G2902-CCV2 5.43 mg/L 0.30 0.50 5.000 109% 90-110 21G2902-CCV3 5.13 mg/L 0.30 0.50 5.000 103% 90-110 21G2902-ICB1 0.13 mg/L 0.30 0.50 21G2902-ICV1 5.38 mg/L 0.30 0.50 5.000 108% 90-110 B21G029-BLK1 U mg/L 0.30 0.50 B21G029-BS1 2.15 mg/L 0.30 0.50 2.000 107% 90-110 B21G029-DUP1 Source: 2107010-02 B21G029-MRL1 15.4 mg/L 0.53 mg/L 3.00 5.00 15.2 1 24 0.5000 107% 74-153 B21G029-MS1 Source: 2107010-02 17.5 mg/L Q 3.00 5.00 2.000 112% 90-110 15.2 Report Name: 2107010 TKN DA FINAL Aug 26 21 1149 Page 14 of 91 Environmental Protection Agency US EPA Region 5 LSASD Analytical Services Branch 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 Table of Contents Date: Project: 8/26/2021 Ranovael Quality Control Summary Analyst: Nidia Fuentes Notes and Definitions K (MS) U NR Q The identification of the analyte is acceptable; the reported value may be biased high. The actual value is expected to be less than the reported value. Matrix spike recovery criteria not met for this analyte Not Detected Not Reported QC limit Exceeded B21G029-MS1 TKN DA Total Kjeldahl Nitrogen Q Nidia Fuentes Report Name: 2107010 TKN DA FINAL Aug 26 21 1149 Page 15 of 91 UNITED STATES ENVIRONMENTAL PROTECTION AGENCY REGION 5 LSASD ANALYTICAL SERVICE BRANCH 536 SOUTH CLARK STREET CHICAGO, ILLINOIS 60605 Work: 2107010 Data Verification Checklist Project: Ranovael Analysis: TKN DA CRL SOP Used: AIG035B Version #8 Batch ID: General Information B21G029 Question # 1 Question Did samples meet the laboratory's standard conditions of sample acceptability upon receipt? 2 Was customer contact communication included? 3 Are all field sample ID numbers cross-referenced to the laboratory ID numbers? 4 Were all samples prepared and analyzed within holding times? Question # 5 6 7 8 9 10 11 12 13 Sample Results Were calculations checked? Question Were all analyte results checked? Were all results for soil and sediment samples reported on a dry weight basis? Were % moisture (or solids) reported for all soil and sediment samples? Other than those results < RL, were all other raw values bracketed by calibration standards? Are the RLs for each method analyte included in the laboratory data package? Are MDLs/RLs adjusted for dilutions? Were the raw data (for example, chromatograms, spectral data) reviewed? Were data associated with manual integrations flagged on the raw data? Question # 14 15 Question # Standards Question Are all standards used in the analyses NIST-traceable or obtained from other appropriate sources as specified in the analytical SOP? Were standard/reagent preparations checked (preparation date, expiration date, parent standard IDs, etc.), if applicable? Batch Quality Control Question Print Date: 8/9/2021 Table of Contents Analyst Response (YES/ NO/ NA) YES NA YES YES Analyst Response (YES/ NO/ NA) YES YES NA NA YES YES YES YES NA Analyst Response (YES/ NO/ NA) YES YES Analyst Response (YES/ NO/ NA) PPagagee116 of 941 Work: 2107010 Project: Ranovael Question # 16 17 18 19 20 21 Batch Quality Control Were appropriate type(s) of blanks analyzed? Question Were blanks analyzed at the appropriate frequency? Were method blanks taken through the entire analytical process, including preparation and, if applicable, cleanup procedures? Were blank concentrations <= MDL or RL, as applicable in the analytical SOP? Was each LCS/SRM taken through the entire analytical procedure, including prep and cleanup steps? Were LCSs/SRMs analyzed at the required frequency? 22 Were LCS/SRM %Rs within the laboratory QC limits or other acceptance criteria? 23 Were the project/method specified analytes included in the MS? 24 Were MS analyzed at the appropriate frequency? 25 Were MS %Rs within the laboratory QC limits? Notes/Comments: Matrix Spike Recovery for Total Kjeldahl Nitrogen (112%) was outside acceptance limits (90-110) in B21G029-MS1 for TKN DA 26 Were appropriate analytical duplicates analyzed for each matrix? 27 Were analytical duplicates analyzed at the appropriate frequency? 28 Were RPDs or relative standard deviations within the laboratory QC limits or other acceptance criteria? 29 Were RLs analyzed at the appropriate frequency? 30 Were RL recoveries within the laboratory QC limits? Question # 31 32 33 34 Calibration Question Were calibration correlation coefficient or other acceptance criteria met? Was the number of calibration standards recommended in the method used for all analytes? Were all points generated between the lowest and highest standard used to calculate the curve? Are calibration data available for all instruments used? Question # 35 36 Calibration Verification Question Was the absolute value of the analyte concentration in the ICB/CCB <= MDL or RL, as applicable in the analytical SOP? Was the calibration curve verified for each analyte? Print Date: 8/9/2021 Table of Contents Analyst Response (YES/ NO/ NA) YES YES YES YES NA YES NA YES YES NO YES YES YES YES YES Analyst Response (YES/ NO/ NA) YES YES YES YES Analyst Response (YES/ NO/ NA) YES YES PPagagee127 of 941 Work: 2107010 Project: Ranovael Question # 37 38 39 Calibration Verification Question Has the calibration curve been verified using an appropriate second source standard? Were ICV/CCV analyzed at the method-required frequency? Were ICV/CCV %R within the laboratory QC limits? Question # 40 41 42 Quality Control QC limits in LIMS checked against the SOP? Question Were percent differences, recoveries, and the linearity within the QC limits specified in the method? 5HIHU WR Were QC charts checked if a QC audit, excluding matrix QC (MS or DUP), was out of limit? Question # 43 44 Supporting Data Question Were support equipment data (balance verification, data logs, logbook entries, etc.) included in data package? Were approved spreadsheet(s) used? Document Verification Question # 45 Question Is the MDL or RL study up-to-date for each reported analyte? 46 Is documentation of the analyst's capability up-to-date and on file? Notes/Comments: ID: 24456 24463 By NFUENTES at 11:56 am, Aug 24, 2021 47 Are the procedures for compound/analyte identification documented? 48 Are laboratory SOPs current and on file for the method performed? 49 Were data evaluated against project QAPP or Sample Plan, any special requests in the sample schedule, and documented in case narrative? 50 Were electronic pathways checked (add pathway and files below)? Notes/Comments: I:\Projects (New File Structure)\Ranovael\1. A&I\NFuentes\DA3\07272021-TPTKN\ARC_70.bak Accreditation Question # 51 ANAB logo used appropriately? Question Table of Contents Analyst Response (YES/ NO/ NA) YES YES Analyst Response (YES/ NO/ NA) YES NO YES Analyst Response (YES/ NO/ NA) YES YES Analyst Response (YES/ NO/ NA) YES YES YES YES YES YES Analyst Response (YES/ NO/ NA) YES Print Date: 8/9/2021 PPagagee138 of 941 Work: 2107010 Project: Ranovael Table of Contents Analyst's Signature and Date*: Fuentes, Nidia Date: 2021.08.24 11:56:55 -05'00' Digitally signed by Fuentes, Nidia Reviewer's Signature and Date*: Digitally signed by ANNA ANNA KNOEBEL Date: 2021.08.25 14:11:29 KNOEBEL -05'00' *Reviewer Concurs with Analyst Responses Additional Notes/Comments (if applicable): Print Date: 8/9/2021 PPagagee149 of 941 TKN DA Table of Contents Page 20 of 91 BATCH B21G029 [TOC_1]Benchsheets[TOTCa]ble of Contents Page 21 of 91 US EPA Region 5 LSASD Analytical Services Branch 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 Date: 7/26/2021 Prepared Date: Analyst (initials): Jul-26-21 NF Digestion # Block # 1 8 1 8 1 8 1 8 1 8 1 8 1 8 1 8 1 8 1 8 Batch Comments: Sample Number 2107010-01 2107010-02 2107010-03 2107010-04 2107010-05 B21G029-BLK1 B21G029-BS1 B21G029-DUP1 B21G029-MRL1 B21G029-MS1 Source ID (MS and DUP only) 2107010-02 2107010-02 TP/TKN DIGESTION LOG Spike ID Spike Volume (uL) 19K1902 20 21G2608 19K1902 20 Batch Number: B21G029 Analyses Included On This Benchsheet TKN DA Spike Final Volume (mL) (MRL, BS, MS only) Sample Volume (mL) 10 10 10 10 10 Comments pH = 1 pH = 1 pH = 1 pH = 1 pH = 1 10 10 10 10 10 10 10 Table of Contents Page 22 of 91 Page 1 of 4 US EPA Region 5 LSASD Analytical Services Branch 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 Date: 7/26/2021 Prepared Date: Analyst (initials): Jul-26-21 NF TP/TKN DIGESTION LOG PREPARATION REAGENTS/STANDARDS/PIPETTES: 19K1902: TKN-Spike Mix (1000 mg/L) 21G2608: TKN - MRL (0.50 mg N/L) 21B2306: Pipette (Electronic) -- 50 -1,000 uL 21B2308: Pipette (Electronic) -- 500 - 10,000 uL 21B2309: Pipette (Electronic) -- 5 -100 uL 21) : TP/TKN Digestion Solution Prepared: Nov-19-19 Prepared: Jul-26-21 Prepared: Feb-15-21 Prepared: Feb-15-21 Prepared: Feb-15-21 Prepared: Jun- 9-21 Expires: Oct-28-21 Expires: Aug-26-21 Expires: Aug-31-21 Expires: Aug-31-21 Expires: Aug-31-21 Expires: Jun- 9-22 Batch Number: B21G029 Analyses Included On This Benchsheet TKN DA Table of Contents Page 23 of 91 Page 2 of 4 Prepared Date: Analyst (initials): Jul-26-21 NF Only standards were used from this block By NFUENTES at 11:08 am, Aug 24, 2021 US EPA Region 5 LSASD Analytical Services Branch 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 Date: 7/26/2021 TP/TKN DIGESTION LOG Batch Number: B21G029 Analyses Included On This Benchsheet TKN DA Hot Block ID: #9 Block Digital Temp 1 Reading (C ) - Start - Stop Time/ Block Digital Temp 2 Reading (C ) - Start - Stop Time: 33 34 35 36 200C-1:22 3M -2:22 PM/ 380C-2:22 PM - :55 PM 37 38 25 26 27 28 29 30 39 DB 31 40 DB 32 17 18 19 20 21 22 23 24 9 10 11 12 13 14 15 16 TKN TKN Calibration ICV/CCV 1 2 3 4 5 6 7 8 DB= Dilution Blank Table of Contents Page 24 of 91 Page 3 of 4 US EPA Region 5 LSASD Analytical Services Branch 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 Date: 7/26/2021 Prepared Date: Analyst (initials): Jul-26-21 NF TP/TKN DIGESTION LOG Batch Number: B21G029 Analyses Included On This Benchsheet TKN DA 2nd Hot Block ID: #8 Block Digital Temp 1 Reading (C ) - Start - Stop Time/ Block Digital Temp 2 Reading (C ) - Start - Stop Time: 33 34 35 36 TKN TKN CCB CCV 25 26 27 28 200C-1:30 PM -2:30 PM/ 380C-2:30 PM - :00 PM 37 38 29 30 39 DB 31 40 DB 32 17 18 19 20 21 22 23 24 9 10 11 12 13 14 15 16 1 2 3 4 5 6 7 8 DB= Dilution Blank Table of Contents Page 25 of 91 Page 4 of 4 BATCH REAGENTS 21B2306 Table of Contents Page 26 of 91 Table of Contents Page 27 of 91 Table of Contents Page 28 of 91 BATCH REAGENTS 21B2308 Table of Contents Page 29 of 91 Table of Contents Page 30 of 91 Table of Contents Page 31 of 91 BATCH REAGENTS 21B2309 Table of Contents Page 32 of 91 Table of Contents Page 33 of 91 Table of Contents Page 34 of 91 BATCH REAGENTS 21F2904 Table of Contents Page 35 of 91 Environmental Protection Agency Region 5 Chicago Regional Laboratory 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 Reagent Preparation Bench Sheet Table of Contents Print Date: 6/29/2021 Parameter / SOP #: TP/TKN SOP AIG34B ver#7, AIG35B ver#8 Reagent: TP/TKN Digestion Solution LIMS ID: 21F2904 Chemical Name (Formula) Sulfuric Acid (H2S04) Prepared by: Nidia Fuentes Preparation Date: Jun-29-21 Expiration Date: Jun-29-22 LIMS ID 20B0607 Mass or Volume (specify units) 200 mL Mercuric Sulfate solution 21F2903 25 mL Potassium Sulfate (K2SO4) 20J2902 133.3216 g Total Volume : Comments : Balance #17 1000 mL Analyst Signature: By Anna Knoebel at 7:04 am, Aug 24, 2021 PPagagee316 of 911 Balance Check Table of Contents BALANCE ID: #17 DATE: 6/29/2021 ANALYST: Christina Rice WEIGHT SET ID: TROEMNER S/N: 4000026116 WGT SET # CONFIRMED: YES WEIGHT SET 2 ID: WGT SET # CONFIRMED: *NOTE: Save as excel file and print to pdf. Store both files in balance check folders on the computer. *NOTE: Confirm # of weights in weight set before and after use above. # of weights in weight sets are listed at bottom of page. Create IR if find that weights are missing . Note any weights that are missing in the comments field below and contact QAO to remove weight(s) from Qualtrax records. Analytical Balance Tolerance Limits Top-Loading Balance Tolerance Limits Standard Weight (g) 0.0100 0.0200 0.0200* 0.0500 0.1000 0.2000 0.2000* 0.5000 1.0000 2.0000 2.0000* 5.0000 10.0000 20.0000 20.0000* 50.0000 100.0000 200.0000 Actual LCL (g) Weight (g) 0.0099 0.0500 0.1001 0.5000 1.0000 10.0000 100.0003 199.9999 0.0099 0.0199 0.0199 0.0499 0.0999 0.1999 0.1999 0.4999 0.9999 1.9999 1.9999 4.9999 9.9999 19.9999 19.9999 49.9999 99.9997 199.9995 UCL (g) 0.0101 0.0201 0.0201 0.0501 0.1001 0.2001 0.2001 0.5001 1.0001 2.0001 2.0001 5.0001 10.0001 20.0001 20.0001 50.0001 100.0003 200.0005 Standard Weight (g) 0.01 0.02 0.02* 0.05 0.10 0.20 0.20* 0.50 1.00 2.00 2.00* 5.00 10.00 20.00 20.00* 50.00 100.00 200.00 300.00 500.00 1000.00 Actual Weight (g) LCL (g) 0.00 0.01 0.01 0.04 0.09 0.19 0.19 0.49 0.99 1.99 1.99 4.99 9.99 19.99 19.99 49.99 99.99 199.99 299.99 499.99 999.99 UCL (g) 0.02 0.03 0.03 0.06 0.11 0.21 0.21 0.51 1.01 2.01 2.01 5.01 10.01 20.01 20.01 50.01 100.01 200.01 300.01 500.01 1000.01 Weight Sets: TROEMNER S/N: 4000017548: 21 weights TROEMNER S/N: 4000020557: 21 weights Denver Inst Co S/N: 01-25360-3A: 1 weight TROEMNER S/N: 06679: 5 weights TROEMNER S/N: 4000026116: 22 weights COMMENTS: Standard Weight 0.001g Actual Weight 0.0009g Qualtrax ID 23790 Version 6, Updated: June 8, 2021 Print Date: 6/29/2021 Page 37 of 91 By AK at 10:47 am, Feb 04, 2020 Table of Contents Page 38 of 91 Environmental Protection Agency Region 5 Chicago Regional Laboratory 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 Description: Standard Type: Solvent: Final Volume (mls): Vials: Vendor: Lot Number: Analytical Standard Record US EPA Region 5 LSASD Analytical Services Branch 21G2605 TKN - WCS (0.00 mg N/L) Other Solution Reagent water 200 1 Absolute Grade 102819 Expires: Prepared: Prepared By: Department: Last Edit: Aug-26-21 Jul-26-21 Nidia Fuentes A&I Aug-24-21 12:01 by NF Table of Contents Analyte Ammonia as N Total Kjeldahl Nitrogen CAS Number NA NA Concentration (ppm) 0 0 Parent Standards used in this standard: Standard 19K1901 Description NH3N/TKN-SCS (1000 mg/L) 21B2306 21G0902 Pipette (Electronic) -- 50 -1,000 uL Sulfuric Acid 9673-00 Prepared Nov-19-19 Feb-15-21 Jul-09-21 Prepared By ** Vendor ** Nidia Fuentes ** Vendor ** Expires Oct-28-21 Aug-31-21 May-11-25 Last Edit Jun-03-21 12:36 by NF Apr-05-21 09:19 by AK Jul-28-21 10:03 by NF (mls) 0 0.2 0.2 By Anna Knoebel at 5:10 pm, Aug 24, 2021 PPagagee319 of 911 Environmental Protection Agency Region 5 Chicago Regional Laboratory 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 Description: Standard Type: Solvent: Final Volume (mls): Vials: Vendor: Lot Number: Analytical Standard Record US EPA Region 5 LSASD Analytical Services Branch 21G2606 TKN - WCS (10.00 mg N/L) Other Solution Reagent water 100 1 Absolute Standards Inc. 102819 Expires: Prepared: Prepared By: Department: Last Edit: Aug-26-21 Jul-26-21 Nidia Fuentes A&I Aug-10-21 12:55 by NF Table of Contents Analyte Ammonia as N Total Kjeldahl Nitrogen CAS Number NA NA Concentration (ppm) 10 10 Parent Standards used in this standard: Standard 19K1901 Description NH3N/TKN-SCS (1000 mg/L) 21B2309 Pipette (Electronic) -- 5 -100 uL 21B2306 21G0902 Pipette (Electronic) -- 50 -1,000 uL Sulfuric Acid 9673-00 Prepared Nov-19-19 Feb-15-21 Feb-15-21 Jul-09-21 Prepared By ** Vendor ** Nidia Fuentes Nidia Fuentes ** Vendor ** Expires Oct-28-21 Aug-31-21 Aug-31-21 May-11-25 Last Edit Jun-03-21 12:36 by NF Apr-05-21 09:33 by AK Apr-05-21 09:19 by AK Jul-28-21 10:03 by NF (mls) 1 0.1 1 0.1 By Anna Knoebel at 9:57 am, Aug 24, 2021 PPagagee410 of 911 Environmental Protection Agency Region 5 Chicago Regional Laboratory 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 Description: Standard Type: Solvent: Final Volume (mls): Vials: Vendor: Lot Number: Analytical Standard Record US EPA Region 5 LSASD Analytical Services Branch 21G2607 TKN - WcS (5.00 mg N/L) Other Solution Reagent water 100 1 Absolute Standards Inc. 040521 Expires: Prepared: Prepared By: Department: Last Edit: Aug-26-21 Jul-26-21 Nidia Fuentes A&I Aug-10-21 12:56 by NF Table of Contents Analyte Total Dissolved Phosphorus Total Kjeldahl Nitrogen Total Phosphorus CAS Number NA NA NA Concentration (ppm) 5 5 5 Parent Standards used in this standard: Standard 21B2309 Description Pipette (Electronic) -- 5 -100 uL 21B2306 21G0902 Pipette (Electronic) -- 50 -1,000 uL Sulfuric Acid 9673-00 21F0222 TP&TKN Stock Control Std. Prepared Feb-15-21 Feb-15-21 Jul-09-21 Jun-02-21 Prepared By Nidia Fuentes Nidia Fuentes ** Vendor ** ** Vendor ** Expires Aug-31-21 Aug-31-21 May-11-25 Apr-05-23 Last Edit Apr-05-21 09:33 by AK Apr-05-21 09:19 by AK Jul-28-21 10:03 by NF Aug-03-21 14:46 by NF (mls) 0.1 0.5 0.1 0.5 By Anna Knoebel at 10:11 am, Aug 24, 2021 PPagagee41 of 911 Environmental Protection Agency Region 5 Chicago Regional Laboratory 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 Description: Standard Type: Solvent: Final Volume (mls): Vials: Vendor: Lot Number: Analytical Standard Record US EPA Region 5 LSASD Analytical Services Branch 21G2608 TKN - MRL (0.50 mg N/L) Reference Material Reagent water 100 1 Absolute Grade 102819 Expires: Prepared: Prepared By: Department: Last Edit: Aug-26-21 Jul-26-21 Nidia Fuentes A&I Aug-10-21 12:56 by NF Table of Contents Analyte Ammonia as N Total Kjeldahl Nitrogen CAS Number NA NA Concentration (ppm) 0.5 0.5 SRM Control Limits 0-200 74-153 Parent Standards used in this standard: Standard 19K1901 Description NH3N/TKN-SCS (1000 mg/L) 21B2309 Pipette (Electronic) -- 5 -100 uL 21G0902 Sulfuric Acid 9673-00 Prepared Nov-19-19 Feb-15-21 Jul-09-21 Prepared By ** Vendor ** Nidia Fuentes ** Vendor ** Expires Oct-28-21 Aug-31-21 May-11-25 Last Edit Jun-03-21 12:36 by NF Apr-05-21 09:33 by AK Jul-28-21 10:03 by NF (mls) 0.05 0.05 0.1 By Anna Knoebel at 9:51 am, Aug 24, 2021 PPagagee412 of 911 Environmental Protection Agency Region 5 Chicago Regional Laboratory 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 Analytical Standard Record US EPA Region 5 LSASD Analytical Services Branch 21G2909 Description: Standard Type: Solvent: Final Volume (mls): Vials: Vendor: Lot Number: TKN - WCS (0.25 mg N/L) Other Solution Blank: 21G2605 2 1 Absolute Grade 102819 Expires: Prepared: Prepared By: Department: Last Edit: Jul-28-21 Jul-27-21 Nidia Fuentes A&I Jul-30-21 10:18 by NF Prepared by Instrument (DA-3) By Anna Knoebel at 10:11 am, Aug 24, 2021 Analyte CAS Number Concentration (ppm) Ammonia as N Total Kjeldahl Nitrogen NA 0.25 NA 0.25 Table of Contents Parent Standards used in this standard: Standard 21G2606 Description TKN - WCS (10.00 mg N/L) Prepared Jul-26-21 Prepared By Nidia Fuentes Expires Aug-26-21 Last Edit Jul-26-21 11:58 by NF (mls) 0.05 PPagagee413 of 911 Environmental Protection Agency Region 5 Chicago Regional Laboratory 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 Table of Contents Analytical Standard Record US EPA Region 5 LSASD Analytical Services Branch 21G2910 Description: Standard Type: Solvent: Final Volume (mls): Vials: Vendor: Lot Number: TKN - WCS (0.5 mg N/L) Other Solution Blank: 21G2605 2 1 Absolute Grade 102819 Prepared by Instrument (DA-3) Analyte Expires: Prepared: Prepared By: Department: Last Edit: Jul-28-21 Jul-27-21 Nidia Fuentes A&I Jul-30-21 10:16 by NF By Anna Knoebel at 10:12 am, Aug 24, 2021 CAS Number Concentration (ppm) Ammonia as N Total Kjeldahl Nitrogen NA 0.5 NA 0.5 Parent Standards used in this standard: Standard 21G2606 Description TKN - WCS (10.00 mg N/L) Prepared Jul-26-21 Prepared By Nidia Fuentes Expires Aug-26-21 Last Edit Jul-26-21 11:58 by NF (mls) 0.1 PPagagee414 of 911 Environmental Protection Agency Region 5 Chicago Regional Laboratory 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 Table of Contents Analytical Standard Record US EPA Region 5 LSASD Analytical Services Branch 21G2911 Description: Standard Type: Solvent: Final Volume (mls): Vials: Vendor: Lot Number: TKN - WCS (1.0 mg N/L) Other Solution Blank: 21G2605 2 1 Absolute Grade 102819 Prepared by Instrument (DA-3) Expires: Prepared: Prepared By: Department: Last Edit: Jul-28-21 Jul-27-21 Nidia Fuentes A&I Jul-30-21 10:14 by NF By Anna Knoebel at 10:12 am, Aug 24, 2021 Analyte CAS Number Concentration (ppm) Ammonia as N Total Kjeldahl Nitrogen NA 1 NA 1 Parent Standards used in this standard: Standard 21G2606 Description TKN - WCS (10.00 mg N/L) Prepared Jul-26-21 Prepared By Nidia Fuentes Expires Aug-26-21 Last Edit Jul-26-21 11:58 by NF (mls) 0.2 PPagagee415 of 911 Environmental Protection Agency Region 5 Chicago Regional Laboratory 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 Analytical Standard Record US EPA Region 5 LSASD Analytical Services Branch 21G2912 Description: Standard Type: Solvent: Final Volume (mls): Vials: Vendor: Lot Number: TKN - WCS (2.0 mg N/L) Other Solution Blank: 21G2605 2 1 Absolute Grade 102819 Expires: Prepared: Prepared By: Department: Last Edit: Jul-28-21 Jul-27-21 Nidia Fuentes A&I Jul-30-21 10:11 by NF Prepared by Instrument (DA-3) Analyte By Anna Knoebel at 10:13 am, Aug 24, 2021 CAS Number Concentration (ppm) Ammonia as N Total Kjeldahl Nitrogen NA 2 NA 2 Table of Contents Parent Standards used in this standard: Standard 21G2606 Description TKN - WCS (10.00 mg N/L) Prepared Jul-26-21 Prepared By Nidia Fuentes Expires Aug-26-21 Last Edit Jul-26-21 11:58 by NF (mls) 0.4 PPagagee416 of 911 Environmental Protection Agency Region 5 Chicago Regional Laboratory 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 Analytical Standard Record US EPA Region 5 LSASD Analytical Services Branch 21G2913 Description: Standard Type: Solvent: Final Volume (mls): Vials: Vendor: Lot Number: TKN - WCS 2.5mg N/L) Other Solution Blank: 21G2605 2 1 Absolute Grade 102819 Prepared by Instrument (DA-3) Expires: Prepared: Prepared By: Department: Last Edit: Jul-28-21 Jul-27-21 Nidia Fuentes A&I Jul-30-21 10:08 by NF By Anna Knoebel at 10:13 am, Aug 24, 2021 Analyte CAS Number Concentration (ppm) Ammonia as N Total Kjeldahl Nitrogen NA 0.25 NA 0.25 Table of Contents Parent Standards used in this standard: Standard 21G2606 Description TKN - WCS (10.00 mg N/L) Prepared Jul-26-21 Prepared By Nidia Fuentes Expires Aug-26-21 Last Edit Jul-26-21 11:58 by NF (mls) 0.05 PPagagee417 of 911 Environmental Protection Agency Region 5 Chicago Regional Laboratory 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 Analytical Standard Record US EPA Region 5 LSASD Analytical Services Branch 21G2914 Description: Standard Type: Solvent: Final Volume (mls): Vials: Vendor: Lot Number: TKN - WCS (5.0 mg N/L) Other Solution Blank: 21G2605 2 1 Absolute Grade 102819 Prepared by Instrument (DA-3) Analyte Expires: Prepared: Prepared By: Department: Last Edit: Jul-28-21 Jul-27-21 Nidia Fuentes A&I Jul-30-21 10:06 by NF By Anna Knoebel at 10:14 am, Aug 24, 2021 CAS Number Concentration (ppm) Ammonia as N Total Kjeldahl Nitrogen NA 5 NA 5 Table of Contents Parent Standards used in this standard: Standard 21G2606 Description TKN - WCS (10.00 mg N/L) Prepared Jul-26-21 Prepared By Nidia Fuentes Expires Aug-26-21 Last Edit Jul-26-21 11:58 by NF (mls) 1 PPagagee418 of 911 Environmental Protection Agency Region 5 Chicago Regional Laboratory 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 Analytical Standard Record US EPA Region 5 LSASD Analytical Services Branch 21G2927 Description: Standard Type: Solvent: Final Volume (mls): Vials: Vendor: Lot Number: TKN - WCS (1.0 mg N/L) Other Solution Blank: 21G2605 2 1 Absolute Grade 102819 Expires: Prepared: Prepared By: Department: Last Edit: Jul-30-21 Jul-29-21 Nidia Fuentes A&I Aug-09-21 12:13 by NF Prepared by Instrument (DA-3) By Anna Knoebel at 11:18 am, Aug 24, 2021 Analyte CAS Number Concentration (ppm) Ammonia as N Total Kjeldahl Nitrogen NA 1 NA 1 Table of Contents Parent Standards used in this standard: Standard 21G2606 Description TKN - WCS (10.00 mg N/L) Prepared Jul-26-21 Prepared By Nidia Fuentes Expires Aug-26-21 Last Edit Jul-26-21 11:58 by NF (mls) 0.2 PPagagee51 of 911 Environmental Protection Agency Region 5 Chicago Regional Laboratory 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 Analytical Standard Record US EPA Region 5 LSASD Analytical Services Branch 21G2926 Description: Standard Type: Solvent: Final Volume (mls): Vials: Vendor: Lot Number: TKN - WCS (0.5 mg N/L) Other Solution Blank: 21G2605 2 1 Absolute Grade 102819 Expires: Prepared: Prepared By: Department: Last Edit: Jul-30-21 Jul-29-21 Nidia Fuentes A&I Aug-09-21 12:13 by NF Prepared by Instrument (DA-3) By Anna Knoebel at 11:18 am, Aug 24, 2021 Analyte CAS Number Concentration (ppm) Ammonia as N Total Kjeldahl Nitrogen NA 0.5 NA 0.5 Table of Contents Parent Standards used in this standard: Standard 21G2606 Description TKN - WCS (10.00 mg N/L) Prepared Jul-26-21 Prepared By Nidia Fuentes Expires Aug-26-21 Last Edit Jul-26-21 11:58 by NF (mls) 0.1 PPagagee510 of 911 Environmental Protection Agency Region 5 Chicago Regional Laboratory 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 Analytical Standard Record US EPA Region 5 LSASD Analytical Services Branch 21G2927 Description: Standard Type: Solvent: Final Volume (mls): Vials: Vendor: Lot Number: TKN - WCS (1.0 mg N/L) Other Solution Blank: 21G2605 2 1 Absolute Grade 102819 Expires: Prepared: Prepared By: Department: Last Edit: Jul-30-21 Jul-29-21 Nidia Fuentes A&I Aug-09-21 12:13 by NF Prepared by Instrument (DA-3) By Anna Knoebel at 11:18 am, Aug 24, 2021 Analyte CAS Number Concentration (ppm) Ammonia as N Total Kjeldahl Nitrogen NA 1 NA 1 Table of Contents Parent Standards used in this standard: Standard 21G2606 Description TKN - WCS (10.00 mg N/L) Prepared Jul-26-21 Prepared By Nidia Fuentes Expires Aug-26-21 Last Edit Jul-26-21 11:58 by NF (mls) 0.2 PPagagee51 of 911 Environmental Protection Agency Region 5 Chicago Regional Laboratory 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 Analytical Standard Record US EPA Region 5 LSASD Analytical Services Branch 21G2928 Description: Standard Type: Solvent: Final Volume (mls): Vials: Vendor: Lot Number: TKN - WCS (2.0 mg N/L) Other Solution Blank: 21G2605 2 1 Absolute Grade 102819 Prepared by Instrument (DA-3) Analyte Expires: Prepared: Prepared By: Department: Last Edit: Jul-30-21 Jul-29-21 Nidia Fuentes A&I Aug-09-21 12:14 by NF By Anna Knoebel at 11:19 am, Aug 24, 2021 CAS Number Concentration (ppm) Ammonia as N Total Kjeldahl Nitrogen NA 2 NA 2 Table of Contents Parent Standards used in this standard: Standard 21G2606 Description TKN - WCS (10.00 mg N/L) Prepared Jul-26-21 Prepared By Nidia Fuentes Expires Aug-26-21 Last Edit Jul-26-21 11:58 by NF (mls) 0.4 PPagagee512 of 911 Environmental Protection Agency Region 5 Chicago Regional Laboratory 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 Analytical Standard Record US EPA Region 5 LSASD Analytical Services Branch 21G2929 Description: Standard Type: Solvent: Final Volume (mls): Vials: Vendor: Lot Number: TKN - WCS 2.5mg N/L) Other Solution Blank: 21G2605 2 1 Absolute Grade 102819 Expires: Prepared: Prepared By: Department: Last Edit: Jul-30-21 Jul-29-21 Nidia Fuentes A&I Aug-09-21 12:15 by NF Prepared by Instrument (DA-3) By Anna Knoebel at 11:20 am, Aug 24, 2021 Analyte CAS Number Concentration (ppm) Ammonia as N Total Kjeldahl Nitrogen NA 2.5 NA 2.5 Table of Contents Parent Standards used in this standard: Standard 21G2606 Description TKN - WCS (10.00 mg N/L) Prepared Jul-26-21 Prepared By Nidia Fuentes Expires Aug-26-21 Last Edit Jul-26-21 11:58 by NF (mls) 0.5 PPagagee513 of 911 Environmental Protection Agency Region 5 Chicago Regional Laboratory 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 Analytical Standard Record US EPA Region 5 LSASD Analytical Services Branch 21G2930 Description: Standard Type: Solvent: Final Volume (mls): Vials: Vendor: Lot Number: TKN - WCS (5.0 mg N/L) Other Solution Blank: 21G2605 2 1 Absolute Grade 102819 Expires: Prepared: Prepared By: Department: Last Edit: Jul-30-21 Jul-29-21 Nidia Fuentes A&I Aug-09-21 12:15 by NF Prepared by Instrument (DA-3) By Anna Knoebel at 11:20 am, Aug 24, 2021 Analyte CAS Number Concentration (ppm) Ammonia as N Total Kjeldahl Nitrogen NA 5 NA 5 Table of Contents Parent Standards used in this standard: Standard 21G2606 Description TKN - WCS (10.00 mg N/L) Prepared Jul-26-21 Prepared By Nidia Fuentes Expires Aug-26-21 Last Edit Jul-26-21 11:58 by NF (mls) 1 PPagagee514 of 911 SEQUENCE 21F1003 [TOC_1]Sequence[TOC] Table of Contents Sequence Date: Instrument: Sequence Analyses: Page 55 of 91 Instrument: Order 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 ANALYSIS SEQUENCE 21F1003 DA-3 Container A A A A A A Analysis Date: Jul-29-21 Lab Number Sample name or QC sample designation 21F1003-CAL1 Cal Standard 21F1003-CAL2 Cal Standard 21F1003-CAL3 Cal Standard 21F1003-CAL4 Cal Standard 21F1003-CAL5 Cal Standard 21F1003-CAL6 Cal Standard 21F1003-CAL7 Cal Standard 21F1003-CAL8 Cal Standard 21F1003-ICB1 ICB 21F1003-ICV1 ICV B21F016-MRL1 MRL Check B21F016-BLK1 Blank B21F016-BS1 LCS 2105027-01 21GS02S90 B21F016-DUP1 Duplicate B21F016-MS1 Matrix Spike 2105027-02 21GS02S91 2105027-03 21GS02I92 2105027-04 21GS03S41 2105027-05 21GS03S43 21F1003-CCB1 ICB 21F1003-CCV1 ICV 2105027-06 21GS03S50 Calibration ID: UNASSIGNED QC QC QC QC QC QC QC QC QC QC QC QC QC TKN DA QC QC TKN DA TKN DA TKN DA TKN DA QC QC TKN DA Analysis Matrix: Water STD ID 21G2605 21G2925 21G2926 21G2927 21G2928 21G2929 21G2930 21G2606 21G2607 Printed: 8/9/2021 2:55:45PM Comments pH = 1, yellow label 21G2607 pH = 1, yellow label pH = 1, yellow label pH = 1, yellow label pH = 1, yellow label pH = 1, yellow label Table of Contents Page 56 of 91 Page 1 of 5 Table of Contents Page 57 of 91 Order 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 Container Lab Number A 2105027-07 A 2105027-08 A 2105027-09 A 2105027-10 A 2105027-11 B21F016-DUP2 B21F016-MS2 21F1003-CCB2 21F1003-CCV2 21F1003-CCB3 21F1003-CCV3 A 2105027-12 A 2105027-13 A 2105027-14 A 2105027-15 A 2105027-16 A 2105027-17 A 2105027-18 A 2105027-19 A 2105027-20 A 2105027-21 21F1003-CCB4 21F1003-CCV4 B21F016-DUP3 B21F016-MS3 A 2105027-22 A 2105027-23 Sample name or QC sample designation 21GS03S51 21GS03I52 21GS03S61 21GS03S63 21GS03S70 Duplicate Matrix Spike ICB ICV ICB ICV 21GS03S71 21GS03I72 21GS03S21 21GS03S22 21GS03S23 21GS03S24 21GS03S25 21GS03S26 21GS03D26 21GS03S27 ICB ICV Duplicate Matrix Spike 21GS03S28 21GS03S30 TKN DA TKN DA TKN DA TKN DA TKN DA QC QC QC QC QC QC TKN DA TKN DA TKN DA TKN DA TKN DA TKN DA TKN DA TKN DA TKN DA TKN DA QC QC QC QC TKN DA TKN DA Analysis STD ID Comments pH = 1, yellow label pH = 1, yellow label pH = 1, yellow label pH = 1, yellow label pH = 1, yellow label 21G2607 21G2607 21G2607 pH = 1, yellow label pH = 1, yellow label pH = 1, yellow label pH = 1, yellow label pH = 1, yellow label pH = 1, yellow label pH = 1, yellow label pH = 1, yellow label pH = 1, yellow label pH = 1, yellow label pH = 1, yellow label pH = 1, yellow label Page 2 of 5 Table of Contents Page 58 of 91 Order 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 Container Lab Number A 2105027-24 A 2105027-25 A 2105027-26 A 2105027-27 21F1003-CCB5 21F1003-CCV5 21F1003-CCB6 21F1003-CCV6 A 2105027-29 A 2105027-30 A 2105027-31 B21F016-DUP4 B21F016-MS4 A 2105027-32 A 2105027-33 A 2105027-34 A 2105027-35 21F1003-CCB7 21F1003-CCV7 A 2105027-36 A 2105027-37 A 2105027-38 A 2105027-39 A 2105027-40 21F1003-CCB8 21F1003-CCV8 21F1003-CCB9 Sample name or QC sample designation 21GS03S31 21GS03I32 21GS03S01 21GS03S03 ICB ICV ICB ICV 21GS03S11 21GS03C11 21GS03I12 Duplicate Matrix Spike 21GS02S61 21GS02S63 21GS02S70 21GS02S71 ICB ICV 21GS02I72 21GS02S21 21GS02S23 21GS02S30 21GS02D30 ICB ICV ICB TKN DA TKN DA TKN DA TKN DA QC QC QC QC TKN DA TKN DA TKN DA QC QC TKN DA TKN DA TKN DA TKN DA QC QC TKN DA TKN DA TKN DA TKN DA TKN DA QC QC QC Analysis STD ID 21G2607 21G2607 Comments pH = 1, yellow label pH = 1, yellow label pH = 1, yellow label pH = 1, yellow label pH = 1, yellow label pH = 1, yellow label pH = 1, yellow label 21G2607 21G2607 pH = 1, yellow label pH = 1, yellow label pH = 1, yellow label pH = 1, yellow label pH = 1, yellow label pH = 1, yellow label pH = 1, yellow label pH = 1, yellow label pH = 1, yellow label Page 3 of 5 Order 78 79 80 81 82 83 84 Container Lab Number 21F1003-CCV9 A 2105027-28 B21G029-BS1 21F1003-CCBA 21F1003-CCVA 21F1003-CCBB 21F1003-CCVB Sample name or QC sample designation ICV 21GS03S10 LCS CCB Second rack CCV Second rack ICB ICV QC TKN DA QC QC QC QC QC Analysis PREPARATION REAGENTS/STANDARDS/PIPETTES: 19K1902: TKN-Spike Mix (1000 mg/L) 21G2608: TKN - MRL (0.50 mg N/L) 21G2605: TKN - WCS (0.00 mg N/L) 21G2606: TKN - WCS (10.00 mg N/L) 21G2607: TKN - WcS (5.00 mg N/L) 21G2925: TKN - WCS (0.25 mg N/L) 21G2926: TKN - WCS (0.5 mg N/L) 21G2927: TKN - WCS (1.0 mg N/L) 21G2928: TKN - WCS (2.0 mg N/L) 21G2929: TKN - WCS 2.5mg N/L) 21G2930: TKN - WCS (5.0 mg N/L) 21* : TKN - Sodium salicylate/sodium nitroprusside sol. 21* : TKN-Working Buffer Solution 21G2923: TKN-Sodium Hypochlorite Prepared: Nov-19-19 Prepared: Jul-26-21 Prepared: Jul-26-21 Prepared: Jul-26-21 Prepared: Jul-26-21 Prepared: Jul-29-21 Prepared: Jul-29-21 Prepared: Jul-29-21 Prepared: Jul-29-21 Prepared: Jul-29-21 Prepared: Jul-29-21 Prepared: -XO-0 -21 Prepared: JXO- -21 Prepared: Jul-29-21 Expires: Oct-28-21 Expires: Aug-26-21 Expires: Aug-26-21 Expires: Aug-26-21 Expires: Aug-26-21 Expires: Jul-30-21 Expires: Jul-30-21 Expires: Jul-30-21 Expires: Jul-30-21 Expires: Jul-30-21 Expires: Jul-30-21 Expires: -XO-0 -22 Expires: JXO- -22 Expires: Jul-30-21 STD ID 21G2607 Comments pH = 1, yellow label 21G2607 21G2607 Table of Contents Page 59 of 91 Page 4 of 5 Order Container Lab Number Sample name or QC sample designation Analysis STD ID Comments Table of Contents Page 60 of 91 Page 5 of 5 !"# $ % & '( !"# )) * + ! , + -) + -) + + -) # &"" # #& # # " # $ % ! # ." # # - # #. #" - #. # ."& #" - #. #& # - #" # # - #. #. #" - #.&& "# & "# - # #. & # - Table of Contents Page 61 of 91 Table of Contents !" # $ %& ' './ '.1 / 3 / /3 / /# / - / # 0 './ '.1 2 / - / # './ '.1 './ '.1 0 -) , & )( 00 02 0 2 2 2 2 00 0 2 00 0 2 2 00 22 00 02 2 ( )* # +&&(& %% %% %% %% %% %% %% %% %% %% %% %% %% %% %% %% %% %% %% %% %% %% %% %% %% %% %% %% %% %% %% %% Page 62 of 91 # $ %& ' 2 './ '.1 / - / # 0 './ '.1 './ '.1 2 / -0 / #0 -) , & )( 2 0 0 0 2 0 20 02 00 2 -34 0 By NFUENTES at 2:53 pm, Aug 09, 2021 './ '.1 2 0 './ '.1 './ '.1 020 2 2 2 22 2 0 2 ( )* # +&&(& Table of Contents %% %% %% %% %% %% %% %% %% %% %% %% %% %% %% %% %% %% By NFUENTES at 2:51 pm, Aug 09, 2021 %% 4 )5 % )!& )( reanalyzed %% %% %% %% %% %% %% %% %% %% %% %% %% %% %% %% %% %% %% %% Page 63 of 91 # $ %& ' , & )( 0 / - / # 2 / 6 29 /#By NFUENTES at 2:52 pm, Aug 09, 2021 2 0 0 ../ # %( 5 %7 ..1 # %( 5 & %7 './ 0 '.1 -) ( )* # +&&(& Table of Contents %% Not needed, used results from first run %% %% %% By NFUENTES at 2:54 pm, Aug 09, 2021 same cup %% BS from different work order %% %% %% %% Page 64 of 91 Date Time DA-3 7/29/2021 User NF 2:06:59 PM Software version: 7.0 Sample/ctrl ID TKN-0 TKN-10 TKN-10 TKN-10 TKN-10 TKN-10 TKN-10 TKN-10 ICB ICV B21F016-MRL1 B21F016-BLK1 B21F016-BS1 2105027-01 B21F016-DUP1 B21F016-MS1 2105027-02 2105027-03 2105027-04 2105027-05 ICB ICV 2105027-06 2105027-07 2105027-08 2105027-09 2105027-10 2105027-11 B21F016-DUP2 B21F016-MS2 ICB ICV ICB ICV 2105027-12 2105027-13 2105027-14 2105027-15 2105027-16 2105027-17 2105027-18 2105027-19 Pat/Ctr/cAl Test name Test type Result Result unit Result time STAT A TKN_351.2 P A TKN_351.2 P A TKN_351.2 P A TKN_351.2 P A TKN_351.2 P A TKN_351.2 P A TKN_351.2 P A TKN_351.2 P C TKN_351.2 P C TKN_351.2 P P TKN_351.2 P P TKN_351.2 P P TKN_351.2 P P TKN_351.2 P P TKN_351.2 P P TKN_351.2 P P TKN_351.2 P P TKN_351.2 P P TKN_351.2 P P TKN_351.2 P C TKN_351.2 P C TKN_351.2 P P TKN_351.2 P P TKN_351.2 P P TKN_351.2 P P TKN_351.2 P P TKN_351.2 P P TKN_351.2 P P TKN_351.2 P P TKN_351.2 P C TKN_351.2 P C TKN_351.2 P C TKN_351.2 P C TKN_351.2 P P TKN_351.2 P P TKN_351.2 P P TKN_351.2 P P TKN_351.2 P P TKN_351.2 P P TKN_351.2 P P TKN_351.2 P P TKN_351.2 P 0.09417 mg/l 0.32748 mg/l 0.48564 mg/l 0.94069 mg/l 1.9434 mg/l 2.37408 mg/l 5.10609 mg/l 9.98736 mg/l 0.04742 mg/l 4.9785 mg/l 0.47727 mg/l 0.09365 mg/l 2.11106 mg/l 0.1631 mg/l 0.18625 mg/l 2.16081 mg/l 0.10152 mg/l 0.13756 mg/l 0.13229 mg/l 0.12687 mg/l 0.09301 mg/l 5.23786 mg/l 0.15584 mg/l 0.11779 mg/l 0.21442 mg/l 0.13403 mg/l 0.15383 mg/l 0.15134 mg/l 0.20557 mg/l 2.4474 mg/l 0.10691 mg/l 5.30801 mg/l 0.01847 mg/l 4.99448 mg/l 0.08284 mg/l 0.03444 mg/l 0.05477 mg/l 0.09264 mg/l 0.23281 mg/l 0.12294 mg/l 0.17003 mg/l 0.11357 mg/l 7/29/2021 10:09 7/29/2021 10:10 7/29/2021 10:12 7/29/2021 10:14 7/29/2021 10:15 7/29/2021 10:17 7/29/2021 10:19 7/29/2021 10:20 7/29/2021 11:00 7/29/2021 11:01 7/29/2021 11:01 7/29/2021 11:03 7/29/2021 11:04 7/29/2021 11:05 7/29/2021 11:06 7/29/2021 11:07 7/29/2021 11:08 7/29/2021 11:09 7/29/2021 11:10 7/29/2021 11:11 7/29/2021 11:12 7/29/2021 11:13 7/29/2021 11:14 7/29/2021 11:15 7/29/2021 11:16 7/29/2021 11:17 7/29/2021 11:19 7/29/2021 11:19 7/29/2021 11:20 7/29/2021 11:22 7/29/2021 11:23 7/29/2021 11:23 7/29/2021 11:58 7/29/2021 11:59 7/29/2021 12:00 7/29/2021 12:01 7/29/2021 12:02 7/29/2021 12:03 7/29/2021 12:05 7/29/2021 12:05 7/29/2021 12:06 7/29/2021 12:08 Status MA MA MA MA MA MA MA MA MA MA MA MA MA MA MA MA MA MA MA MA MA MA MA MA MA MA MA MA MA MA MA MA MA MA MA MA MA MA MA MA MA MA Dilution 1 +Manual diluRteiosponse Blank respoMnsain abs. 1Blank abs. 1Sample type 0 0.08538 -0.00008 0.0853 -0.00008 39 0.11062 -0.00041 0.11022 -0.00041 19 0.12835 -0.00053 0.12782 -0.00053 9 0.18213 -0.00022 0.18191 -0.00022 4 0.31519 -0.0004 0.31479 -0.0004 3 0.37848 -0.00047 0.37801 -0.00047 1 0.866 -0.00063 0.86537 -0.00063 0 2.10699 -0.00027 2.10672 -0.00027 0 0.08046 -0.00015 0.08031 -0.00015 0 0.83993 -0.0006 0.83933 -0.0006 0 0 0.1274 -0.00062 0.12678 -0.00062 Sample type 1 0 0 0.08533 -0.00046 0.08487 -0.00046 Sample type 1 0 0 0.33939 -0.00027 0.33912 -0.00027 Sample type 1 0 0 0.09273 -0.0005 0.09223 -0.0005 Sample type 1 0 0 0.09522 -0.00055 0.09466 -0.00055 Sample type 1 0 0 0.34667 -0.00065 0.34602 -0.00065 Sample type 1 0 0 0.08616 -0.00063 0.08553 -0.00063 Sample type 1 0 0 0.08999 -0.00003 0.08997 -0.00003 Sample type 1 0 0 0.08943 -0.00024 0.08919 -0.00024 Sample type 1 0 0 0.08886 -0.00037 0.08849 -0.00037 Sample type 1 0 0.08526 -0.00049 0.08477 -0.00049 0 0.89327 -0.00036 0.89291 -0.00036 0 0 0.09195 0.00025 0.0922 0.00025 Sample type 1 0 0 0.08789 0.00188 0.08977 0.00188 Sample type 1 0 0 0.09826 -0.00034 0.09792 -0.00034 Sample type 1 0 0 0.08962 -0.00031 0.08931 -0.00031 Sample type 1 0 0 0.09173 -0.00032 0.09141 -0.00032 Sample type 1 0 0 0.09147 -0.00055 0.09092 -0.00055 Sample type 1 0 0 0.0973 0.00016 0.09746 0.00016 Sample type 1 0 0 0.38962 -0.00046 0.38916 -0.00046 Sample type 1 0 0.08673 -0.00033 0.0864 -0.00033 0 0.90793 -0.00036 0.90757 -0.00036 0 0.07743 -0.00039 0.07703 -0.00039 0 0.84317 -0.00027 0.8429 -0.00027 0 0 0.08418 -0.00038 0.0838 -0.00038 Sample type 1 0 0 0.0791 -0.00036 0.07874 -0.00036 Sample type 1 0 0 0.08123 0.01874 0.09997 0.01874 Sample type 1 0 0 0.08522 -0.00064 0.08458 -0.00064 Sample type 1 0 0 0.10025 -0.00053 0.09972 -0.00053 Sample type 1 0 0 0.08844 -0.00062 0.08782 -0.00062 Sample type 1 0 0 0.09347 -0.00027 0.0932 -0.00027 Sample type 1 0 0 0.08744 -0.00064 0.0868 -0.00064 Sample type 1 Table of Contents Page 65 of 91 Table of Contents Page 66 of 91 2105027-20 P TKN_351.2 P 0.18627 mg/l 7/29/2021 12:09 MA 2105027-21 P TKN_351.2 P 0.10499 mg/l 7/29/2021 12:10 MA ICB C TKN_351.2 P 0.07395 mg/l 7/29/2021 12:11 MA ICV C TKN_351.2 P 5.35513 mg/l 7/29/2021 12:12 MA B21F016-DUP3 P TKN_351.2 P 0.1121 mg/l 7/29/2021 12:13 MA B21F016-MS3 P TKN_351.2 P 2.21496 mg/l 7/29/2021 12:14 MA 2105027-22 P TKN_351.2 P 0.1574 mg/l 7/29/2021 12:15 MA 2105027-23 P TKN_351.2 P 0.33468 mg/l 7/29/2021 12:16 MA 2105027-24 P TKN_351.2 P 0.12947 mg/l 7/29/2021 12:17 MA 2105027-25 P TKN_351.2 P 0.20379 mg/l 7/29/2021 12:18 MA 2105027-26 P TKN_351.2 P 0.13742 mg/l 7/29/2021 12:19 MA 2105027-27 P TKN_351.2 P 0.18335 mg/l 7/29/2021 12:20 MA ICB C TKN_351.2 P 0.10012 mg/l 7/29/2021 12:21 MA ICV C TKN_351.2 P 5.39067 mg/l 7/29/2021 12:22 MA ICB C TKN_351.2 P 0.01363 mg/l 7/29/2021 12:50 MA ICV C TKN_351.2 P 4.81716 mg/l 7/29/2021 12:51 MA 2105027-28 P TKN_351.2 P -0.16087 mg/l 7/29/2021 12:52 MA 2105027-29 P TKN_351.2 P 0.05061 mg/l 7/29/2021 12:53 MA 2105027-30 P TKN_351.2 P 0.09445 mg/l 7/29/2021 12:54 MA 2105027-31 P TKN_351.2 P 0.13847 mg/l 7/29/2021 12:55 MA B21F016-DUP4 P TKN_351.2 P 0.15022 mg/l 7/29/2021 12:56 MA B21F016-MS4 P TKN_351.2 P 1.97688 mg/l 7/29/2021 12:57 MA 2105027-32 P TKN_351.2 P 0.16562 mg/l 7/29/2021 12:58 MA 2105027-33 P TKN_351.2 P 0.13329 mg/l 7/29/2021 12:59 MA 210502734 P TKN_351.2 P 0.25905 mg/l 7/29/2021 13:00 MA 2105027-35 P TKN_351.2 P 0.1484 mg/l 7/29/2021 13:01 MA ICB C TKN_351.2 P 0.03106 mg/l 7/29/2021 13:02 MA ICV C TKN_351.2 P 5.29828 mg/l 7/29/2021 13:03 MA 2105027-36 P TKN_351.2 P 0.22603 mg/l 7/29/2021 13:04 MA 2105027-37 P TKN_351.2 P 0.18174 mg/l 7/29/2021 13:06 MA 2105027-38 P TKN_351.2 P 0.16985 mg/l 7/29/2021 13:07 MA 2105027-39 P TKN_351.2 P 0.10875 mg/l 7/29/2021 13:07 MA 2105027-40 P TKN_351.2 P 0.15806 mg/l 7/29/2021 13:09 MA ICB C TKN_351.2 P 0.06736 mg/l 7/29/2021 13:10 MA ICV C TKN_351.2 P 5.37299 mg/l 7/29/2021 13:11 MA ICB C TKN_351.2 P 0.01275 mg/l 7/29/2021 13:53 MA ICV C TKN_351.2 P 5.05951 mg/l 7/29/2021 13:54 MA 2105027-11 P TKN_351.2 P 0.05405 mg/l 7/29/2021 13:55 MA B21F016-DUP2 P TKN_351.2 P 0.102 mg/l 7/29/2021 13:56 MA B21F016-MS2 P TKN_351.2 P 2.38551 mg/l 7/29/2021 13:57 MA 2105027-28 P TKN_351.2 P 0.06428 mg/l 7/29/2021 13:58 MA B21G028-BS1 P TKN_351.2 P 2.14898 mg/l 7/29/2021 13:59 MA CCB Second Rack P TKN_351.2 P 0.01621 mg/l 7/29/2021 14:00 MA CCV Second rack P TKN_351.2 P 5.29724 mg/l 7/29/2021 14:01 MA ICB C TKN_351.2 P 0.04349 mg/l 7/29/2021 14:03 MA ICV C TKN_351.2 P 5.33205 mg/l 7/29/2021 14:04 MA 0 0 0.09522 -0.00027 0.09495 -0.00027 Sample type 1 0 0 0.08653 0.00088 0.08741 0.00088 Sample type 1 0 0.08325 -0.00027 0.08298 -0.00027 0 0.91783 -0.00051 0.91732 -0.00051 0 0 0.08728 -0.00056 0.08673 -0.00056 Sample type 1 0 0 0.35466 -0.00038 0.35428 -0.00038 Sample type 1 0 0 0.09212 -0.00051 0.0916 -0.00051 Sample type 1 0 0 0.11142 -0.0005 0.11092 -0.0005 Sample type 1 0 0 0.08913 -0.00059 0.08855 -0.00059 Sample type 1 0 0 0.09711 -0.00058 0.09653 -0.00058 Sample type 1 0 0 0.08998 -0.00035 0.08963 -0.00035 Sample type 1 0 0 0.0949 -0.00026 0.09464 -0.00026 Sample type 1 0 0.08601 -0.0003 0.08571 -0.0003 0 0.92533 -0.00042 0.92491 -0.00042 0 0.07692 -0.00007 0.07686 -0.00007 0 0.80742 -0.00028 0.80714 -0.00028 0 0 0.05861 0.02357 0.08218 0.02357 Sample type 1 0 0 0.08079 -0.00036 0.08043 -0.00036 Sample type 1 0 0 0.08541 0.00155 0.08696 0.00155 Sample type 1 0 0 0.09009 -0.00049 0.0896 -0.00049 Sample type 1 0 0 0.09135 -0.0006 0.09074 -0.0006 Sample type 1 0 0 0.31997 -0.00049 0.31948 -0.00049 Sample type 1 0 0 0.093 -0.00022 0.09278 -0.00022 Sample type 1 0 0 0.08954 -0.00053 0.08901 -0.00053 Sample type 1 0 0 0.10311 0.00302 0.10613 0.00302 Sample type 1 0 0 0.09115 -0.00047 0.09068 -0.00047 Sample type 1 0 0.07874 -0.00039 0.07835 -0.00039 0 0.90589 -0.00052 0.90537 -0.00052 0 0 0.09952 -0.00029 0.09923 -0.00029 Sample type 1 0 0 0.09473 -0.00037 0.09436 -0.00037 Sample type 1 0 0 0.09345 -0.00049 0.09296 -0.00049 Sample type 1 0 0 0.08693 -0.00061 0.08632 -0.00061 Sample type 1 0 0 0.09219 -0.00046 0.09173 -0.00046 Sample type 1 0 0.08255 -0.00044 0.08212 -0.00044 0 0.9216 -0.00017 0.92142 -0.00017 0 0.07683 -0.00014 0.07669 -0.00014 0 0.85644 0.00003 0.85648 0.00003 0 0 0.08115 -0.00012 0.08104 -0.00012 Sample type 1 0 0 0.08621 -0.00017 0.08605 -0.00017 Sample type 1 0 0 0.38021 -0.0003 0.37991 -0.0003 Sample type 1 0 0 0.08223 -0.00012 0.08211 -0.00012 Sample type 1 0 0 0.34494 -0.00003 0.34491 -0.00003 Sample type 1 0 0 0.07719 -0.00009 0.07711 -0.00009 Sample type 1 0 0 0.90567 -0.00034 0.90533 -0.00034 Sample type 1 0 0.08004 -0.00009 0.07995 -0.00009 0 0.91298 0.00007 0.91305 0.00007 Table of Contents Page 67 of 91 By NFUENTES at 10:35 am, Aug 10, 2021 workorder 2105027 By NFUENTES at 10:36 am, Aug 10, 2021 Table of Contents Page 68 of 91 Table of Contents Page 69 of 91 By NFUENTES at 10:37 am, Aug 10, 2021 workorder 2105027 Table of Contents Page 70 of 91 SEQUENCE 21G2902 [TOC_1]Sequence[TOC] Table of Contents Sequence Date: 07/27/2021 Instrument: DA-3 Sequence Analyses: TKN DA Page 71 of 91 Instrument: Order 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 ANALYSIS SEQUENCE 21G2902 DA-3 Container B A A B A Analysis Date: Jul-27-21 Lab Number Sample name or QC sample designation 21G2902-CAL1 Cal Standard 21G2902-CAL2 Cal Standard 21G2902-CAL3 Cal Standard 21G2902-CAL4 Cal Standard 21G2902-CAL5 Cal Standard 21G2902-CAL6 Cal Standard 21G2902-CAL7 Cal Standard 21G2902-CAL8 Cal Standard 21G2902-ICB1 ICB 21G2902-ICV1 ICV B21G029-MRL1 MRL Check B21G029-BLK1 Blank 2107010-01 BO1 2107010-04 SO3 2107010-05 SO4 21G2902-CCB1 ICB 21G2902-CCV1 ICV 2107010-02 SO1 21G2902-CCB2 ICB 21G2902-CCV2 ICV B21G029-DUP1 Duplicate B21G029-MS1 Matrix Spike 2107010-03 SO2 Calibration ID: UNASSIGNED QC QC QC QC QC QC QC QC QC QC QC QC TKN DA TKN DA TKN DA QC QC TKN DA QC QC QC QC TKN DA Analysis Matrix: Water STD ID 21G2605 21G2909 21G2910 21G2911 21G2912 21G2913 21G2914 21G2606 21G2607 Printed: 8/9/2021 3:08:43PM Comments 21G2607 21G2607 pH = 1 pH = 1 pH = 1 pH = 1 pH = 1 Table of Contents Page 72 of 91 Page 1 of 2 Order 24 25 Container Lab Number 21G2902-CCB3 21G2902-CCV3 Sample name or QC sample designation ICB QC ICV QC PREPARATION REAGENTS/STANDARDS/PIPETTES: 19K1902: TKN-Spike Mix (1000 mg/L) Prepared: Nov-19-19 21G2608: TKN - MRL (0.50 mg N/L) Prepared: Jul-26-21 21G2605: TKN - WCS (0.00 mg N/L) Prepared: Jul-26-21 21G2606: TKN - WCS (10.00 mg N/L) Prepared: Jul-26-21 21G2607: TKN - WcS (5.00 mg N/L) Prepared: Jul-26-21 21G2909: TKN - WCS (0.25 mg N/L) Prepared: Jul-27-21 21G2910: TKN - WCS (0.5 mg N/L) Prepared: Jul-27-21 21G2911: TKN - WCS (1.0 mg N/L) Prepared: Jul-27-21 21G2912: TKN - WCS (2.0 mg N/L) Prepared: Jul-27-21 21G2913: TKN - WCS 2.5mg N/L) Prepared: Jul-27-21 21G2914: TKN - WCS (5.0 mg N/L) Prepared: Jul-27-21 21G0808: TKN - Sodium salicylate/sodium nitroprusside sol. Prepared: Jul-08-21 21G1204: TKN-Working Buffer Solution Prepared: Jul-12-21 21G2702: TKN-Sodium Hypochlorite Prepared: Jul-27-21 Analysis Expires: Oct-28-21 Expires: Aug-26-21 Expires: Aug-26-21 Expires: Aug-26-21 Expires: Aug-26-21 Expires: Jul-28-21 Expires: Jul-28-21 Expires: Jul-28-21 Expires: Jul-28-21 Expires: Jul-28-21 Expires: Jul-28-21 Expires: Jul-08-22 Expires: Jul-12-22 Expires: Jul-28-21 STD ID 21G2607 Comments Table of Contents Page 73 of 91 Page 2 of 2 !" # $ % &' !" (( ) * ! - * .( * .( * * .( "+++ ,",+ " "+ " " # $ % ! "% " %+ " . " "+ " . " "% " . " "+ ,+ " . " " ,, " . "+ " ,% " . " "% " . " +"+ % , " . Table of Contents Page 74 of 91 Table of Contents !" # $ %& ' './ '.5 './ '.5 './ '.5 /7 /7 /7 68 6 /8 6 /# / 7 6/76# 4 './ '.5 '.5 './ './ '.5 / 7 6/76# './ '.5 /7 './ '.5 6 /# -) , & )( 4 66 44 4 4 4 6 D D D D 4 4 4 4 4 4 4 4 ( )* # +&&(& %% 0.1 2 )3 % )!& )( 1 ,)( 3 %% %% 2 )3 % )!& )( %% 0.1 2 )3 % )!& )( 1 ,)( 3 %% Calibration was not accepted at this point trouble-shooting run. %% By NFUENTES at 3:13 pm, Aug 09, 2021 %% %% %% %% Failed QC By NFUENTES at 12:24 pm, Aug 24, 2021 %% &9 ! :) :1 ) ) ) ;) :1 2 )3 % )!& &9 ! :) :1 ) ) ) ;) :1 2 )3 % )!& &9 ! :) :1 ) ) ) ;) :1 2 )3 % )!& &9 ) ) ) ;) :1 2 )3 % )!& )( %% %% %% %% &9 & 9 % 3 Ran out of standard &9 &9% 3 By NFUENTES at 3:15 pm, Aug 09, 2021 6 %% %% %% 6 %% 6 %% 6 %% %% %% %% Failed QC, analyzed again on 07/29/2021 in sequence 21F1003 %% By NFUENTES at 3:17 pm, Aug 09, 2021 %% Not used By NFUENTES at 12:25 pm, Aug 24, 2021 Page 75 of 91 Date Time DA-3 7/29/2021 User NF 9:39:22 AM Software version: 7.0 TP/TKN Sample/ctrl ID Pat/Ctr/cAl Test name Test type Result Result unit Result time STAT TP-0 A TP-3.0 A TP-3.0 A TP-3.0 A TP-3.0 A TP-3.0 A TP-3.0 A CCB C CCV C B21G028-MRL1 P B21G028-BLK1 P B21G028-BS1 P 2107010-01 P 2107010-02 P B21G028-DUP1 P B21G028-MS1 P 2107010-03 P 2107010-04 P 2107010-05 P CCB C CCV C 2107010-02 P CCB C CCV C B21G028-DUP1 P B21G028-MS1 P 2107010-03 P CCB C CCV C CCB C CCV C 2107010-02 P B21G028-DUP1 P B21G028-MS1 P CCB C CCV C CCB C CCV C 2107010-02 P B21G028-DUP1 P B21G028-MS1 P 2107010-03 P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P 0.02248 mg/l 0.15208 mg/l 0.29665 mg/l 0.74217 mg/l 0.99413 mg/l 1.47669 mg/l 3.0158 mg/l 0.01415 mg/l 2.006 mg/l 0.13959 mg/l 0.01167 mg/l 1.01386 mg/l 0.00983 mg/l 9.0961 mg/l 9.12321 mg/l 9.73685 mg/l 9.05994 mg/l 1.29788 mg/l 1.33234 mg/l 0.01514 mg/l 1.98734 mg/l 9.35786 mg/l 0.01326 mg/l 2.0101 mg/l 9.4878 mg/l 10.69863 mg/l 9.50995 mg/l 0.01458 mg/l 1.9969 mg/l 0.01396 mg/l 2.00128 mg/l 9.47931 mg/l 9.5848 mg/l 10.73251 mg/l 0.01468 mg/l 2.00464 mg/l 0.01412 mg/l 2.00326 mg/l 9.56274 mg/l 9.53297 mg/l 10.76756 mg/l 9.6625 mg/l 7/27/2021 10:48 7/27/2021 10:50 7/27/2021 10:51 7/27/2021 10:52 7/27/2021 10:54 7/27/2021 10:55 7/27/2021 10:56 7/27/2021 11:25 7/27/2021 11:25 7/27/2021 11:26 7/27/2021 11:27 7/27/2021 11:28 7/27/2021 11:29 7/27/2021 11:30 7/27/2021 11:31 7/27/2021 11:32 7/27/2021 11:33 7/27/2021 11:34 7/27/2021 11:34 7/27/2021 11:35 7/27/2021 11:36 7/27/2021 11:41 7/27/2021 11:41 7/27/2021 11:42 7/27/2021 11:44 7/27/2021 11:46 7/27/2021 11:48 7/27/2021 11:49 7/27/2021 11:50 7/27/2021 12:05 7/27/2021 12:05 7/27/2021 12:07 7/27/2021 12:09 7/27/2021 12:10 7/27/2021 12:11 7/27/2021 12:12 7/27/2021 12:43 7/27/2021 12:44 7/27/2021 12:46 7/27/2021 12:47 7/27/2021 12:49 7/27/2021 12:50 Status MA MA MA MA MA MA MA MA MA MA MA MA MA AR AR AR AR MA MA MA MA MA MA MA MA MA MA MA MA MA MA MA MA MA MA MA MA MA MA MA MA MA Errors 19, 19, 19, 19, Notes R R R R R R R R Dilution 1 +Manual diluRteiosponse Blank respoMnsain abs. 1Blank abs. 1Sample type 0 0.00728 -0.00015 0.00713 -0.00015 19 0.02703 -0.00016 0.02687 -0.00016 9 0.04905 0.00018 0.04923 0.00018 3 0.11694 0.00035 0.11728 0.00035 2 0.15532 0.00055 0.15588 0.00055 1 0.22885 0.00092 0.22977 0.00092 0 0.46336 0.0026 0.46596 0.0026 0 0.00601 -0.00004 0.00597 -0.00004 0 0.3095 0.00121 0.31071 0.00121 0 0 0.02512 0.00042 0.02554 0.00042 Sample type 1 0 0 0.00563 0.00018 0.00582 0.00018 Sample type 1 0 0 0.15833 0.00132 0.15966 0.00132 Sample type 1 0 0 0.00535 0.00042 0.00578 0.00042 Sample type 1 0 0 1.3898 0.01195 1.40175 0.01195 Sample type 1 0 0 1.39393 0.01206 1.40599 0.01206 Sample type 1 0 0 1.48743 0.06211 1.54954 0.06211 Sample type 1 0 0 1.38429 0.06838 1.45267 0.06838 Sample type 1 0 0 0.20161 0.0028 0.20441 0.0028 Sample type 1 0 0 0.20686 0.00459 0.21145 0.00459 Sample type 1 0 0.00616 0 0.00617 0 0 0.30666 0.00125 0.30791 0.00125 9 0 0.14644 0.00275 0.14919 0.00275 Sample type 1 0 0.00587 -0.00013 0.00574 -0.00013 0 0.31013 0.00114 0.31127 0.00114 9 0 0.14842 0.00099 0.14941 0.00099 Sample type 1 9 0 0.16686 0.00096 0.16782 0.00096 Sample type 1 9 0 0.14875 0.0009 0.14966 0.0009 Sample type 1 0 0.00607 -0.00002 0.00605 -0.00002 0 0.30811 0.00137 0.30948 0.00137 0 0.00598 0.00017 0.00615 0.00017 0 0.30878 0.00134 0.31012 0.00134 9 0 0.14829 0.00123 0.14952 0.00123 Sample type 1 9 0 0.14989 0.00091 0.1508 0.00091 Sample type 1 9 0 0.16738 0.00071 0.16809 0.00071 Sample type 1 0 0.00609 0.00026 0.00635 0.00026 0 0.30929 0.00109 0.31038 0.00109 0 0.006 -0.00028 0.00573 -0.00028 0 0.30908 0.00087 0.30996 0.00087 4 0 0.29526 0.0046 0.29986 0.0046 Sample type 1 4 0 0.29435 0.00271 0.29706 0.00271 Sample type 1 4 0 0.33198 0.00203 0.334 0.00203 Sample type 1 5 0 0.24923 0.00376 0.25299 0.00376 Sample type 1 Table of Contents Page 76 of 91 Table of Contents Page 77 of 91 CCB C CCV C ICB C ICV C 2P ICB C ICV C TKN-0 A TKN-10 A TKN-10 A TKN-10 A TKN-10 A TKN-10 A TKN-10 A TKN-10 A ICB C ICV C B21G029-MRL1 P B21G029-BLK1 P B21G029-BS1 P 2107010-01 P 2107010-02 P B21G029-DUP1 P B21G029-MS1 P 2107010-03 P 2107010-04 P 2107010-05 P ICB C ICV C ICV C ICB C 2107010-02 P ICB C ICV C B21G029-DUP1 P B21G029-MS1 P 2107010-03 P ICB C ICV C B21G029-BS1 P ICB C ICV C Total Phos P Total Phos P TKN_351.2 P TKN_351.2 P TKN_351.2 P TKN_351.2 P TKN_351.2 P TKN_351.2 P TKN_351.2 P TKN_351.2 P TKN_351.2 P TKN_351.2 P TKN_351.2 P TKN_351.2 P TKN_351.2 P TKN_351.2 P TKN_351.2 P TKN_351.2 P TKN_351.2 P TKN_351.2 P TKN_351.2 P TKN_351.2 P TKN_351.2 P TKN_351.2 P TKN_351.2 P TKN_351.2 P TKN_351.2 P TKN_351.2 P TKN_351.2 P TKN_351.2 P TKN_351.2 P TKN_351.2 P TKN_351.2 P TKN_351.2 P TKN_351.2 P TKN_351.2 P TKN_351.2 P TKN_351.2 P TKN_351.2 P TKN_351.2 P TKN_351.2 P TKN_351.2 P 0.01552 mg/l 2.01696 mg/l -0.7437 mg/l 5.19585 mg/l -1.43424 mg/l -0.77506 mg/l 5.21282 mg/l 0.12692 mg/l 0.32509 mg/l 0.51256 mg/l 0.93495 mg/l 1.87844 mg/l 2.3846 mg/l 5.12026 mg/l 9.98614 mg/l 0.1334 mg/l 5.38377 mg/l 0.53481 mg/l 0.08217 mg/l 2.3242 mg/l 0.19384 mg/l 14.43118 mg/l 14.83068 mg/l 30.63917 mg/l 11.66146 mg/l 2.58539 mg/l 2.36081 mg/l 0.13011 mg/l 5.40877 mg/l mg/l mg/l 15.22712 mg/l 0.14699 mg/l 5.43335 mg/l 15.41182 mg/l 17.46176 mg/l 11.05071 mg/l 0.05066 mg/l 5.13417 mg/l 2.27707 mg/l 0.25039 mg/l 5.03558 mg/l 7/27/2021 12:51 7/27/2021 12:52 7/27/2021 14:34 7/27/2021 14:35 7/27/2021 14:36 7/27/2021 14:37 7/27/2021 14:38 7/27/2021 15:44 7/27/2021 15:45 7/27/2021 15:47 7/27/2021 15:49 7/27/2021 15:50 7/27/2021 15:52 7/27/2021 15:54 7/27/2021 15:55 7/27/2021 16:20 7/27/2021 16:21 7/27/2021 16:22 7/27/2021 16:24 7/27/2021 16:25 7/27/2021 16:25 7/27/2021 16:27 7/27/2021 16:28 7/27/2021 16:29 7/27/2021 16:30 7/27/2021 16:31 7/27/2021 16:32 7/27/2021 16:33 7/27/2021 16:34 7/27/2021 16:37 7/27/2021 16:38 7/27/2021 16:40 7/27/2021 16:41 7/27/2021 16:42 7/27/2021 16:44 7/27/2021 16:46 7/27/2021 16:53 7/27/2021 16:54 7/27/2021 16:55 7/27/2021 16:56 7/27/2021 16:57 7/27/2021 16:58 MA MA MA 27,30, MA MA 30, MA 27,30, MA MA MA MA MA MA MA MA MA MA MA MA MA MA MA AR 3,19,30, R AR 3,19,30, R AR 3,19,30, R AR 19,30, R MA MA MA MA AR 1, AR 1, MA R MA MA MA R MA R MA R MA MA MA MA MA 0 0.00622 -0.0004 0.00582 -0.0004 0 0.31117 0.00114 0.31231 0.00114 0 0.053 -0.00007 0.05293 -0.00007 0 0.52039 0.00002 0.5204 0.00002 0 0 0.0403 0.00014 0.04044 0.00014 Sample type 1 0 0.05242 0.00042 0.05284 0.00042 0 0.52306 0.00012 0.52318 0.00012 0 0.06761 -0.00004 0.06756 -0.00004 39 0.08811 0.00003 0.08814 0.00003 19 0.10842 -0.00035 0.10807 -0.00035 9 0.15737 -0.00021 0.15716 -0.00021 4 0.28278 -0.00014 0.28264 -0.00014 3 0.3592 -0.00022 0.35899 -0.00022 1 0.88279 -0.00001 0.88278 -0.00001 0 2.2751 0.00001 2.27511 0.00001 0 0.06826 0.00001 0.06827 0.00001 0 0.94308 -0.00025 0.94283 -0.00025 0 0 0.11088 0.00001 0.1109 0.00001 Sample type 1 0 0 0.06311 -0.00019 0.06292 -0.00019 Sample type 1 0 0 0.34975 -0.00012 0.34963 -0.00012 Sample type 1 0 0 0.07442 -0.00013 0.07429 -0.00013 Sample type 1 0 0 3.81258 0.00368 3.81626 0.00368 Sample type 1 0 0 3.95076 0.00416 3.95493 0.00416 Sample type 1 0 0 9.41866 0.00365 9.42231 0.00365 Sample type 1 0 0 2.85458 0.00133 2.85591 0.00133 Sample type 1 0 0 0.39129 0.00103 0.39232 0.00103 Sample type 1 0 0 0.35547 0.00082 0.35629 0.00082 Sample type 1 0 0.06793 -0.00011 0.06782 -0.00011 0 0.94889 -0.0003 0.94859 -0.0003 0 0 9 0 0.23289 0.00041 0.2333 0.00041 Sample type 1 0 0.06964 -0.0001 0.06954 -0.0001 0 0.95461 -0.00017 0.95445 -0.00017 9 0 0.2354 0.00091 0.23631 0.00091 Sample type 1 9 0 0.26386 0.00095 0.26481 0.00095 Sample type 1 9 0 0.17834 0.00733 0.18568 0.00733 Sample type 1 0 0.05997 0.02088 0.08086 0.02088 0 0.88593 -0.00039 0.88554 -0.00039 0 0 0.34243 -0.00057 0.34187 -0.00057 Sample type 1 0 0.08027 -0.0005 0.07977 -0.0005 0 0.86379 0.0002 0.86399 0.0002 Table of Contents ANALYSIS REAGENTS/STANDARDS 21G0808 Page 78 of 91 Environmental Protection Agency Region 5 Chicago Regional Laboratory 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 Reagent Preparation Bench Sheet Table of Contents Print Date: 7/8/2021 Parameter / SOP #: TKN/ SOP AIG035B VER #8 Reagent: TKN - Sodium salicylate/sodium nitroprusside sol. LIMS ID: 21G0808 Chemical Name (Formula) Sodium Nitroprusside (Na2Fe(CN)5NO*2H2O Prepared by: Nidia Fuentes Preparation Date: Jul-08-21 Expiration Date: Jul-08-22 LIMS ID 19F1901 Mass or Volume (specify units) 0.0308 g Sodium Salicylate (NaC7H5O3) 19L1207 15.0161 g Total Volume : Comments : Balance #17. 100 mL Analyst Signature: By Anna Knoebel at 10:40 am, Aug 24, 2021 PPagagee719 of 911 Balance Check Table of Contents BALANCE ID: #17 DATE: 7/8/2021 ANALYST: Nidia Fuentes WEIGHT SET ID: TROEMNER S/N: 4000026116 WGT SET # CONFIRMED: YES WEIGHT SET 2 ID: WGT SET # CONFIRMED: *NOTE: Save as excel file and print to pdf. Store both files in balance check folders on the computer. *NOTE: Confirm # of weights in weight set before and after use above. # of weights in weight sets are listed at bottom of page. Create IR if find that weights are missing . Note any weights that are missing in the comments field below and contact QAO to remove weight(s) from Qualtrax records. Analytical Balance Tolerance Limits Top-Loading Balance Tolerance Limits Standard Weight (g) 0.0100 0.0200 0.0200* 0.0500 0.1000 0.2000 0.2000* 0.5000 1.0000 2.0000 2.0000* 5.0000 10.0000 20.0000 20.0000* 50.0000 100.0000 200.0000 Actual LCL (g) Weight (g) 0.0200 0.1000 0.9999 4.9999 10.0000 20.0000 50.0000 99.9999 0.0099 0.0199 0.0199 0.0499 0.0999 0.1999 0.1999 0.4999 0.9999 1.9999 1.9999 4.9999 9.9999 19.9999 19.9999 49.9999 99.9997 199.9995 UCL (g) 0.0101 0.0201 0.0201 0.0501 0.1001 0.2001 0.2001 0.5001 1.0001 2.0001 2.0001 5.0001 10.0001 20.0001 20.0001 50.0001 100.0003 200.0005 Standard Weight (g) 0.01 0.02 0.02* 0.05 0.10 0.20 0.20* 0.50 1.00 2.00 2.00* 5.00 10.00 20.00 20.00* 50.00 100.00 200.00 300.00 500.00 1000.00 Actual Weight (g) LCL (g) 0.00 0.01 0.01 0.04 0.09 0.19 0.19 0.49 0.99 1.99 1.99 4.99 9.99 19.99 19.99 49.99 99.99 199.99 299.99 499.99 999.99 UCL (g) 0.02 0.03 0.03 0.06 0.11 0.21 0.21 0.51 1.01 2.01 2.01 5.01 10.01 20.01 20.01 50.01 100.01 200.01 300.01 500.01 1000.01 Weight Sets: TROEMNER S/N: 4000017548: 21 weights TROEMNER S/N: 4000020557: 21 weights Denver Inst Co S/N: 01-25360-3A: 1 weight TROEMNER S/N: 06679: 5 weights TROEMNER S/N: 4000026116: 22 weights COMMENTS: Qualtrax ID 23790 Version 6, Updated: June 8, 2021 Print Date: 7/8/2021 Page 80 of 91 Table of Contents ANALYSIS REAGENTS/STANDARDS 21G1204 Page 81 of 91 Environmental Protection Agency Region 5 Chicago Regional Laboratory 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 Reagent Preparation Bench Sheet Table of Contents Print Date: 7/12/2021 Parameter / SOP #: SOP AIG 035B VER #8 Reagent: TKN-Working Buffer Solution LIMS ID: 21G1204 Chemical Name (Formula) Stock Sodium Potassium Tartrate Prepared by: Nidia Fuentes Preparation Date: Jul-12-21 Expiration Date: Jul-12-22 LIMS ID 21G1201 Mass or Volume (specify units) 50 mL Stock Buffer Solution 21G1202 40 mL Stock Sodium Hydroxide 21G1203 50 mL Total Volume : Comments : 200 mL By Anna Knoebel at 10:56 am, Aug 24, 2021 Analyst Signature: PPagagee812 of 911 Table of Contents ANALYSIS REAGENTS/STANDARDS 21G2923 Page 83 of 91 Environmental Protection Agency Region 5 Chicago Regional Laboratory 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 Reagent Preparation Bench Sheet Table of Contents Print Date: 8/4/2021 Inadvertently Not printed on the day it was prepared By NFUENTES at 11:15 am, Aug 10, 2021 Parameter / SOP #: TKN /AIG035B_VERSION 8 Reagent: TKN-Sodium Hypochlorite LIMS ID: 21G2923 Chemical Name (Formula) Sodium Hypochlorite (NaOCl) Prepared by: Nidia Fuentes Preparation Date: Jul-29-21 Expiration Date: Jul-30-21 LIMS ID 21C0923 Mass or Volume (specify units) 1.2 mL Total Volume : Comments : 20 mL Analyst Signature: By Anna Knoebel at 11:12 am, Aug 24, 2021 PPagagee814 of 911 Table of Contents ANALYSIS REAGENTS/STANDARDS 21G0808 Page 85 of 91 Environmental Protection Agency Region 5 Chicago Regional Laboratory 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 Reagent Preparation Bench Sheet Table of Contents Print Date: 7/8/2021 Parameter / SOP #: TKN/ SOP AIG035B VER #8 Reagent: TKN - Sodium salicylate/sodium nitroprusside sol. LIMS ID: 21G0808 Chemical Name (Formula) Sodium Nitroprusside (Na2Fe(CN)5NO*2H2O Prepared by: Nidia Fuentes Preparation Date: Jul-08-21 Expiration Date: Jul-08-22 LIMS ID 19F1901 Mass or Volume (specify units) 0.0308 g Sodium Salicylate (NaC7H5O3) 19L1207 15.0161 g Total Volume : Comments : Balance #17. 100 mL Analyst Signature: By Anna Knoebel at 10:40 am, Aug 24, 2021 PPagagee816 of 911 Balance Check Table of Contents BALANCE ID: #17 DATE: 7/8/2021 ANALYST: Nidia Fuentes WEIGHT SET ID: TROEMNER S/N: 4000026116 WGT SET # CONFIRMED: YES WEIGHT SET 2 ID: WGT SET # CONFIRMED: *NOTE: Save as excel file and print to pdf. Store both files in balance check folders on the computer. *NOTE: Confirm # of weights in weight set before and after use above. # of weights in weight sets are listed at bottom of page. Create IR if find that weights are missing . Note any weights that are missing in the comments field below and contact QAO to remove weight(s) from Qualtrax records. Analytical Balance Tolerance Limits Top-Loading Balance Tolerance Limits Standard Weight (g) 0.0100 0.0200 0.0200* 0.0500 0.1000 0.2000 0.2000* 0.5000 1.0000 2.0000 2.0000* 5.0000 10.0000 20.0000 20.0000* 50.0000 100.0000 200.0000 Actual LCL (g) Weight (g) 0.0200 0.1000 0.9999 4.9999 10.0000 20.0000 50.0000 99.9999 0.0099 0.0199 0.0199 0.0499 0.0999 0.1999 0.1999 0.4999 0.9999 1.9999 1.9999 4.9999 9.9999 19.9999 19.9999 49.9999 99.9997 199.9995 UCL (g) 0.0101 0.0201 0.0201 0.0501 0.1001 0.2001 0.2001 0.5001 1.0001 2.0001 2.0001 5.0001 10.0001 20.0001 20.0001 50.0001 100.0003 200.0005 Standard Weight (g) 0.01 0.02 0.02* 0.05 0.10 0.20 0.20* 0.50 1.00 2.00 2.00* 5.00 10.00 20.00 20.00* 50.00 100.00 200.00 300.00 500.00 1000.00 Actual Weight (g) LCL (g) 0.00 0.01 0.01 0.04 0.09 0.19 0.19 0.49 0.99 1.99 1.99 4.99 9.99 19.99 19.99 49.99 99.99 199.99 299.99 499.99 999.99 UCL (g) 0.02 0.03 0.03 0.06 0.11 0.21 0.21 0.51 1.01 2.01 2.01 5.01 10.01 20.01 20.01 50.01 100.01 200.01 300.01 500.01 1000.01 Weight Sets: TROEMNER S/N: 4000017548: 21 weights TROEMNER S/N: 4000020557: 21 weights Denver Inst Co S/N: 01-25360-3A: 1 weight TROEMNER S/N: 06679: 5 weights TROEMNER S/N: 4000026116: 22 weights COMMENTS: Qualtrax ID 23790 Version 6, Updated: June 8, 2021 Print Date: 7/8/2021 Page 87 of 91 Table of Contents ANALYSIS REAGENTS/STANDARDS 21G1204 Page 88 of 91 Environmental Protection Agency Region 5 Chicago Regional Laboratory 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 Reagent Preparation Bench Sheet Table of Contents Print Date: 7/12/2021 Parameter / SOP #: SOP AIG 035B VER #8 Reagent: TKN-Working Buffer Solution LIMS ID: 21G1204 Chemical Name (Formula) Stock Sodium Potassium Tartrate Prepared by: Nidia Fuentes Preparation Date: Jul-12-21 Expiration Date: Jul-12-22 LIMS ID 21G1201 Mass or Volume (specify units) 50 mL Stock Buffer Solution 21G1202 40 mL Stock Sodium Hydroxide 21G1203 50 mL Total Volume : Comments : 200 mL By Anna Knoebel at 10:56 am, Aug 24, 2021 Analyst Signature: PPagagee819 of 911 Table of Contents ANALYSIS REAGENTS/STANDARDS 21G2702 Page 90 of 91 Table of Contents Environmental Protection Agency Region 5 Chicago Regional Laboratory Print Date: 8/9/2021 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 Inadvertently not printed on the day of analysis By NFUENTES at 12:52 pm, Aug 24, 2021 Reagent Preparation Bench Sheet Parameter / SOP #: TKN /AIG035B_VERSION 8 Reagent: TKN-Sodium Hypochlorite LIMS ID: 21G2702 Chemical Name (Formula) Sodium Hypochlorite (NaOCl) Prepared by: Nidia Fuentes Preparation Date: Jul-27-21 Expiration Date: Jul-28-21 LIMS ID 21C0923 Mass or Volume (specify units) mL Total Volume : Comments : 20 mL By Anna Knoebel at 5:19 pm, Aug 24, 2021 Analyst Signature: PPagagee91 of 911 Table of Contents UNITED STATES ENVIRONMENTAL PROTECTION AGENCY REGION 5 ANALYTICAL SERVICES BRANCH LABORATORY 536 SOUTH CLARK STREET (LAB-10C) CHICAGO, ILLINOIS 60605 ELECTRONIC LABORATORY DATA PACKAGE FINAL LEVEL IV COVER PAGE LIMS Work order(s): Primary Analyst: Analysis: Date: Data Reporting Qualtrax Workflow ID: Digital Signature of Primary Analyst: 2107010 Nidia Fuentes Total Phosphorus DA August 26, 2021 26390 Digital Signature Agreement: By signing above the primary analyst understands and agrees that they will be held legally bound, obligated, and responsible for the use of their digital signature as they would be by using their hand-written signature. Page 1 of 68 Client Project Name: Work Order Number: Ranovael @2BA2021) 2107010 1 Cover Page 2 Level I Report 3 QC Summary 4 Checklist 5 Sample Prep and Supporting Data (Total Phosphorus DA) 5.1 Bench Sheets (B21G028) 5.2 Batch Reagents (B21G028) 5.3 Analysis Data and Supporting Documents (21G2701) 5.4 Standards (21D0715) 5.5 Standards (21G2601) 5.6 Standards (21G2602) 5.7 Standards (21G2603) 5.8 Standards (21G2604) 5.9 Standards (21G2703) 5.10 Standards (21G2704) 5.11 Standards (21G2705) 5.12 Standards (21G2706) 5.13 Standards (21G2707) 5.14 Sequence Reagents (21G2701) Table of Contents Table of Contents 1 3 11 13 17 18 23 38 46 51 52 53 54 55 56 57 58 59 60 536 South Clark Street, Chicago, IL 60605 TEL: 312-353-1226 FAX: 312-353-9069 Page 2 of 68 UNITED STATES ENVIRONMENTAL PROTECTION AGENCY US EPA Region 5 LSASD Analytical Services Branch 536 SOUTH CLARK STREET CHICAGO, ILLINOIS 60605 Table of Contents Date: 8/26/2021 Title: To: From: ASB Data Report for Ranovael Water Division, US EPA Region 5 77 West Jackson Boulevard Chicago, IL 60604 Nidia Fuentes, Chemist fuentes.nidia@epa.gov US EPA Region 5 LSASD Analytical Services Branch The results reported in this document apply to the samples as received and relate only to the items tested. The data transmitted under this cover memo successfully passed the data review process and applicable Analytical Services Branch (ASB) laboratory Standard Operating Procedures. In accordance with the EPA QA/G-8 Guidance on Environmental Data Verification and Data Validation, ASB performs data verification on all the data generated internally. ASB does not perform data validation or quality assessment procedures. This report was reviewed and the information provided herein accurately represents the analysis performed. Please contact the analyst with any technical report issues, Amanda Wroble at (312)-353-0375 for sample project concerns, and Robert Snyder at (312)-353-9083 with data transmittal questions. Thank you. Attached are Results for: Ranovael Analyses included in this report: Total Phosphorus DA Report Name: 2107010 Total Phosphorus DA FINAL Aug 26 21 1143 Page 3 of 68 Water Division, US EPA Region 5 77 West Jackson Boulevard Chicago IL, 60604 Environmental Protection Agency Region 5 US EPA Region 5 LSASD Analytical Services Branch 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 Project: Ranovael Project Number: 02BA2021 Project Manager: Ben Atkinson Accredited Analyses included in this Report Table of Contents Reported: Aug-26-21 11:43 Method: Analysis: Analyte EPA 365.4 in Water Total Phosphorus DA Total Phosphorus Certifications ISO/IEC 17025:2017 Analytes not listed above are not accredited by ANAB. Report Name: 2107010 Total Phosphorus DA FINAL Aug 26 21 1143 Page 4 of 68 Water Division, US EPA Region 5 77 West Jackson Boulevard Chicago IL, 60604 Environmental Protection Agency Region 5 US EPA Region 5 LSASD Analytical Services Branch 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 Project: Ranovael Project Number: 02BA2021 Project Manager: Ben Atkinson Table of Contents Reported: Aug-26-21 11:43 ANALYSIS CASE NARRATIVE Analysis List Total Phosphorus DA Analyst: Nidia Fuentes Phone #: 312-353-9079 General Information Samples analyzed: Sample Analysis List 2107010-01 Total Phosphorus DA 2107010-02 Total Phosphorus DA 2107010-03 Total Phosphorus DA 2107010-04 Total Phosphorus DA 2107010-05 Total Phosphorus DA Holding times: All holding times were met. Sample Analysis and Results The samples were analyzed using ASB SOP AIG034B, Version #7. The data reported herein meets any requirements referenced in the previously mentioned SOP and Sampling QAPP titled "General Field Sampling Plan for AFO Inspections" and dated FY 2021, except for those listed in the Quality Control section. SOP Based on: Method List EPA 365.4 Quality Control All quality control audits were within ASB limits or did not result in qualification of the data. Report Name: 2107010 Total Phosphorus DA FINAL Aug 26 21 1143 Page 5 of 68 01234516718945878351717351 395735199549854 !"#$#%%& '(")&*+,, -.%/0123456, 7"8/0123554291 Table of Contents ?@A@<0 BCDEDCD :;07351;;<19839;74237=>491 43187KHELBDLBDBCCBHBEHMBN 3718H ?9874<323=351F:;07351 45G78H915297 45G78N91974H 179@ O49==9<923= 45G78IJ674H DB>BDBC 7P548Q5H Z%.X$'.U. R"%#S'T'U'.&VW-XY%)'. S"%S%/ Y%(%'T%\Z^/ +))%\*.Z^/ X)4,4211/,,0]\"^_X_3 !'.Z#%U!'. `%!U%^abc"!!%^ 66R%U["($U.Z!%T"#\ '(")&*+,,] S"%Y%(%'T%\/ [!41421,5/] S"%+))%\*./ [!41421,9/9 -.%/012342,,] 7"8/01235542,,1 "de!%")Uf!"g%!U %"!U*."( Y%(%'T%\.'(% -"e%#h#$*.(!\%\ i7= ?54O@4K74566718=H i7= i7= i7= !%#0U3'.j#d"'./ S%j"! !%#4k6, ;96P7l<H BCDEDCDmDC ;96P7KH rJmCmBCCCHBs ;96P7I967H >@C ;96P7566718=H 19 =3= Xdd.'"tSX&S'U'!!%\ o5K8367pK9=q 25 ZaS 2 t'#"%4t'#'%tSX&W.w^d"'(#%\('. 25 !'\U&_S 6 !'\U&_ 6 _`tSX 25 _"!-Ue#USX 25 N9843nH ?9874 ;96P7598351L566718=H 915297 0nP347= X)41242111/2 [!41642111/2 X)41242111/2 [!42242111/2 [!42242111/2 X)41242111/2 X)41242111/2 566718= euv1 euv6 euv1 euv6 euv6 euv1 euv1 ;96P7l<H BCDEDCDmDB ;96P7KH rJmCmBCCCHM{ N9843nH ?9874 ;96P7I967H ;@C ;96P7598351L566718=H @274x5yx456zQ ;96P7566718=H 19 =3= Xdd.'"tSX&S'U'!!%\ o5K8367pK9=q 0nP347= 566718= 25 X)41242111/]9 euv1 ZaS 2 [!41642111/]9 euv6 t'#"%4t'#'%tSX&W.w^d"'(#%\('. 25 X)41242111/]9 euv1 P|a}g~e6of68 Table of Contents Page 7 of 68 Table of Contents Page 8 of 68 Water Division, US EPA Region 5 77 West Jackson Boulevard Chicago IL, 60604 Environmental Protection Agency Region 5 US EPA Region 5 LSASD Analytical Services Branch 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 Project: Ranovael Project Number: 02BA2021 Project Manager: Ben Atkinson Table of Contents Reported: Aug-26-21 11:43 BO1 (2107010-01) Analyte Total Phosphorus SO1 (2107010-02) Analyte Total Phosphorus SO2 (2107010-03) Analyte Total Phosphorus SO3 (2107010-04) Analyte Total Phosphorus SO4 (2107010-05) Analyte Total Phosphorus Phosphorus, Colorimetric, EPA 365.4 (modified) US EPA Region 5 LSASD Analytical Services Branch Matrix: Water Sampled: Jul-15-21 11:23 Result Flags / Qualifiers MDL Reporting Limit U 0.06 0.15 Received: Jul-16-21 08:46 Units mg/L Dilution 1 Batch B21G028 Matrix: Water Sampled: Jul-15-21 11:49 Result Flags / Qualifiers MDL Reporting Limit 9.56 0.30 0.75 Received: Jul-16-21 08:46 Units mg/L Dilution 5 Batch B21G028 Matrix: Water Sampled: Jul-15-21 11:52 Result Flags / Qualifiers MDL Reporting Limit 9.66 0.36 0.90 Received: Jul-16-21 08:46 Units mg/L Dilution 6 Batch B21G028 Matrix: Water Sampled: Jul-15-21 12:00 Result Flags / Qualifiers MDL Reporting Limit 1.30 0.06 0.15 Received: Jul-16-21 08:46 Units mg/L Dilution 1 Batch B21G028 Matrix: Water Sampled: Jul-15-21 12:07 Result Flags / Qualifiers MDL Reporting Limit 1.33 0.06 0.15 Received: Jul-16-21 08:46 Units mg/L Dilution 1 Batch B21G028 Prepared Jul-26-21 Prepared Jul-26-21 Prepared Jul-26-21 Prepared Jul-26-21 Prepared Jul-26-21 Analyzed Jul-27-21 Analyzed Jul-27-21 Analyzed Jul-27-21 Analyzed Jul-27-21 Analyzed Jul-27-21 Report Name: 2107010 Total Phosphorus DA FINAL Aug 26 21 1143 Page 9 of 68 Water Division, US EPA Region 5 77 West Jackson Boulevard Chicago IL, 60604 U Not Detected NR Not Reported Q QC limit Exceeded Environmental Protection Agency Region 5 US EPA Region 5 LSASD Analytical Services Branch 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 Project: Ranovael Project Number: 02BA2021 Project Manager: Ben Atkinson Notes and Definitions Table of Contents Reported: Aug-26-21 11:43 Report Name: 2107010 Total Phosphorus DA FINAL Aug 26 21 1143 Page 10 of 68 Environmental Protection Agency US EPA Region 5 LSASD Analytical Services Branch 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 Table of Contents Date: Project: 8/26/2021 Ranovael Analyte: Total Phosphorus Analysis: Total Phosphorus DA Quality Control Summary Analyst: Nidia Fuentes QC Sample Name 21G2701-CAL1 Result 0.02 Units mg/L Flags / Qualifiers MDL Reporting Limit Spike Level 0.06 0.15 0.000 Source Result % REC or abs diff (pH) % REC or abs diff (pH) Limits % % RPD or abs diff (pH) %RPD or abs diff ( pH) Limits 21G2701-CAL2 0.15 mg/L 0.06 0.15 0.1500 101% 21G2701-CAL3 0.30 mg/L 0.06 0.15 0.3000 99% 21G2701-CAL4 0.74 mg/L 0.06 0.15 0.7500 99% 21G2701-CAL5 0.99 mg/L 0.06 0.15 1.000 99% 21G2701-CAL6 1.48 mg/L 0.06 0.15 1.500 98% 21G2701-CAL7 3.02 mg/L 0.06 0.15 3.000 101% 21G2701-CCB1 0.02 mg/L 0.06 0.15 21G2701-CCB2 0.01 mg/L 0.06 0.15 21G2701-CCB3 0.02 mg/L 0.06 0.15 21G2701-CCV1 1.99 mg/L 0.06 0.15 2.000 99% 92-112 21G2701-CCV2 2.00 mg/L 0.06 0.15 2.000 100% 92-112 21G2701-CCV3 2.02 mg/L 0.06 0.15 2.000 101% 92-112 21G2701-ICB1 0.01 mg/L 0.06 0.15 21G2701-ICV1 2.01 mg/L 0.06 0.15 2.000 100% 92-112 B21G028-BLK1 U mg/L 0.06 0.15 B21G028-BS1 1.01 mg/L 0.06 0.15 1.000 101% 89-111 B21G028-DUP1 Source: 2107010-02 B21G028-MRL1 9.53 mg/L 0.14 mg/L 0.30 0.75 9.56 0.3 10 0.1500 93% 68-132 Report Name: 2107010 Total Phosphorus DA FINAL Aug 26 21 1143 Page 11 of 68 Environmental Protection Agency US EPA Region 5 LSASD Analytical Services Branch 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 Table of Contents Date: 8/26/2021 Project: Ranovael Analyte: Total Phosphorus Analysis: Total Phosphorus DA Quality Control Summary Analyst: Nidia Fuentes QC Sample Name B21G028-MS1 Source: 2107010-02 Result 10.8 Units mg/L Flags / Qualifiers MDL Reporting Limit Spike Level 0.30 0.75 1.000 Source Result 9.56 % REC or abs diff (pH) % REC or abs diff (pH) Limits 120% 79-124 % RPD or abs diff (pH) %RPD or abs diff ( pH) Limits U Not Detected NR Not Reported Q QC limit Exceeded Notes and Definitions Nidia Fuentes Report Name: 2107010 Total Phosphorus DA FINAL Aug 26 21 1143 Page 12 of 68 Work: 2107010 UNITED STATES ENVIRONMENTAL PROTECTION AGENCY REGION 5 LSASD ANALYTICAL SERVICE BRANCH 536 SOUTH CLARK STREET CHICAGO, ILLINOIS 60605 Data Verification Checklist Project: Ranovael Analysis: Total Phosphorus DA CRL SOP Used: AIG034B v7 Batch ID: General Information B21G028 Question # 1 Question Did samples meet the laboratory's standard conditions of sample acceptability upon receipt? 2 Was customer contact communication included? 3 Are all field sample ID numbers cross-referenced to the laboratory ID numbers? 4 Were all samples prepared and analyzed within holding times? Question # 5 6 7 8 9 10 11 12 13 Sample Results Were calculations checked? Question Were all analyte results checked? Were all results for soil and sediment samples reported on a dry weight basis? Were % moisture (or solids) reported for all soil and sediment samples? Other than those results < RL, were all other raw values bracketed by calibration standards? Are the RLs for each method analyte included in the laboratory data package? Are MDLs/RLs adjusted for dilutions? Were the raw data (for example, chromatograms, spectral data) reviewed? Were data associated with manual integrations flagged on the raw data? Question # 14 15 Standards Question Are all standards used in the analyses NIST-traceable or obtained from other appropriate sources as specified in the analytical SOP? Were standard/reagent preparations checked (preparation date, expiration date, parent standard IDs, etc.), if applicable? Batch Quality Control Print Date: 8/9/2021 Table of Contents Analyst Response (YES/ NO/ NA) YES NA YES YES Analyst Response (YES/ NO/ NA) YES YES NA NA YES YES YES YES NA Analyst Response (YES/ NO/ NA) YES YES PPagagee113 of 648 Work: 2107010 Project: Ranovael Question # 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 Batch Quality Control Were appropriate type(s) of blanks analyzed? Question Were blanks analyzed at the appropriate frequency? Were method blanks taken through the entire analytical process, including preparation and, if applicable, cleanup procedures? Were blank concentrations <= MDL or RL, as applicable in the analytical SOP? Was each LCS/SRM taken through the entire analytical procedure, including prep and cleanup steps? Were LCSs/SRMs analyzed at the required frequency? Were LCS/SRM %Rs within the laboratory QC limits or other acceptance criteria? Were the project/method specified analytes included in the MS? Were MS analyzed at the appropriate frequency? Were MS %Rs within the laboratory QC limits? Were appropriate analytical duplicates analyzed for each matrix? Were analytical duplicates analyzed at the appropriate frequency? Were RPDs or relative standard deviations within the laboratory QC limits or other acceptance criteria? Were RLs analyzed at the appropriate frequency? Were RL recoveries within the laboratory QC limits? Question # 31 32 33 34 Calibration Question Were calibration correlation coefficient or other acceptance criteria met? Was the number of calibration standards recommended in the method used for all analytes? Were all points generated between the lowest and highest standard used to calculate the curve? Are calibration data available for all instruments used? Question # 35 36 37 Calibration Verification Question Was the absolute value of the analyte concentration in the ICB/CCB <= MDL or RL, as applicable in the analytical SOP? Was the calibration curve verified for each analyte? Has the calibration curve been verified using an appropriate second source standard? Print Date: 8/9/2021 Table of Contents Analyst Response (YES/ NO/ NA) YES YES YES YES YES YES YES YES YES YES YES YES YES YES YES Analyst Response (YES/ NO/ NA) YES YES YES YES Analyst Response (YES/ NO/ NA) YES YES YES PPagagee124 of 648 Work: 2107010 Project: Ranovael Question # 38 39 Calibration Verification Question Were ICV/CCV analyzed at the method-required frequency? Were ICV/CCV %R within the laboratory QC limits? Question # 40 41 42 Quality Control QC limits in LIMS checked against the SOP? Question Were percent differences, recoveries, and the linearity within the QC limits specified in the method? Were QC charts checked if a QC audit, excluding matrix QC (MS or DUP), was out of limit? Question # 43 44 Supporting Data Question Were support equipment data (balance verification, data logs, logbook entries, etc.) included in data package? Were approved spreadsheet(s) used? Question # 45 46 47 48 49 50 Question # 51 Document Verification Question Is the MDL or RL study up-to-date for each reported analyte? Is documentation of the analyst's capability up-to-date and on file? Notes/Comments: ID 24465 Are the procedures for compound/analyte identification documented? Are laboratory SOPs current and on file for the method performed? Were data evaluated against project QAPP or Sample Plan, any special requests in the sample schedule, and documented in case narrative? Were electronic pathways checked (add pathway and files below)? Notes/Comments: I:\Projects (New File Structure)\Ranovael\1. A&I\NFuentes\DA3\07272021-TPTKN\ARC_70.bak Accreditation ANAB logo used appropriately? Question Analyst's Signature and Date*: Print Date: 8/9/2021 Fuentes, Nidia Date: 2021.08.09 15:51:59 -05'00' Digitally signed by Fuentes, Nidia Table of Contents Analyst Response (YES/ NO/ NA) YES YES Analyst Response (YES/ NO/ NA) YES YES NA Analyst Response (YES/ NO/ NA) YES YES Analyst Response (YES/ NO/ NA) YES YES YES YES YES YES Analyst Response (YES/ NO/ NA) YES PPagagee135 of 648 Work: 2107010 Project: Ranovael Table of Contents Reviewer's Signature and Date*: ANNA KNOEBEL Date: 2021.08.25 14:19:21 -05'00' Digitally signed by ANNA KNOEBEL *Reviewer Concurs with Analyst Responses Additional Notes/Comments (if applicable): Print Date: 8/9/2021 PPagagee146 of 648 Table of Contents Total Phosphorus DA Page 17 of 68 BATCH B21G028 [TOC_1]Benchsheets[TOTCa]ble of Contents Page 18 of 68 US EPA Region 5 LSASD Analytical Services Branch 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 Date: 7/26/2021 Prepared Date: Analyst (initials): Jul-26-21 NF Digestion # Block # 1 8 1 8 1 8 1 8 1 8 1 8 1 8 1 8 1 8 1 8 Batch Comments: Sample Number 2107010-01 2107010-02 2107010-03 2107010-04 2107010-05 B21G028-BLK1 B21G028-BS1 B21G028-DUP1 B21G028-MRL1 B21G028-MS1 Source ID (MS and DUP only) 2107010-02 2107010-02 TP/TKN DIGESTION LOG Spike ID Spike Volume (uL) 21D0715 100 21G2604 21D0715 100 Batch Number: B21G028 Analyses Included On This Benchsheet Total Phosphorus DA Spike Final Volume (mL) (MRL, BS, MS only) Sample Volume (mL) 10 10 10 10 10 Comments pH = 1 pH = 1 pH = 1 pH = 1 pH = 1 10 10 10 10 10 10 10 Table of Contents Page 19 of 68 Page 1 of 4 US EPA Region 5 LSASD Analytical Services Branch 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 Date: 7/26/2021 Prepared Date: Analyst (initials): Jul-26-21 NF TP/TKN DIGESTION LOG PREPARATION REAGENTS/STANDARDS/PIPETTES: 21D0715: TP-Stock Cal Standard (SCS) Prepared: Apr-07-21 21G2604: TP - MRL (0.15 mg P/L) Prepared: Jul-26-21 21B2306: Pipette (Electronic) -- 50 -1,000 uL Prepared: Feb-15-21 21B2307: Pipette (Electronic) -- 200 -5000 uL Prepared: Feb-15-21 21B2308: Pipette (Electronic) -- 500 - 10,000 uL Prepared: Feb-15-21 21B2309: Pipette (Electronic) -- 5 -100 uL Prepared: Feb-15-21 21F2904: TP/TKN Digestion Solution Prepared: Jun-29-21 Expires: Apr-07-22 Expires: Aug-26-21 Expires: Aug-31-21 Expires: Aug-31-21 Expires: Aug-31-21 Expires: Aug-31-21 Expires: Jun-29-22 Batch Number: B21G028 Analyses Included On This Benchsheet Total Phosphorus DA Table of Contents Page 20 of 68 Page 2 of 4 Prepared Date: Analyst (initials): Jul-26-21 NF Only the Calibration standard was used from this block By NFUENTES at 11:05 am, Aug 24, 2021 US EPA Region 5 LSASD Analytical Services Branch 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 Date: 7/26/2021 TP/TKN DIGESTION LOG Batch Number: B21G028 Analyses Included On This Benchsheet Total Phosphorus DA Hot Block ID: #9 Block Digital Temp 1 Reading (C ) - Start - Stop Time/ Block Digital Temp 2 Reading (C ) - Start - Stop Time: 33 34 35 36 200C-1: 3M -2: 3M/ 380C-2: 3M - : PM 37 38 25 26 27 28 29 30 39 DB 31 40 DB 32 17 18 19 20 21 22 23 24 9 10 11 12 13 14 15 16 1 TP 2 TP 3 4 5 6 7 8 Calibration DB= Dilution Blank ICV/CCV Table of Contents Page 21 of 68 Page 3 of 4 US EPA Region 5 LSASD Analytical Services Branch 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 Date: 7/26/2021 Prepared Date: Analyst (initials): Jul-26-21 NF TP/TKN DIGESTION LOG Batch Number: B21G028 Analyses Included On This Benchsheet Total Phosphorus DA 2nd Hot Block ID: #8 Block Digital Temp 1 Reading (C ) - Start - Stop Time/ Block Digital Temp 2 Reading (C ) - Start - Stop Time: 200C-1: 3M - : 3M/ 380C- : 3M - : PM 33 34 35 36 37 38 TP TP CCB CCV 25 26 27 28 29 30 39 DB 31 40 DB 32 17 18 19 20 21 22 23 24 9 10 11 12 13 14 15 16 1 2 3 4 5 6 7 8 DB= Dilution Blank Table of Contents Page 22 of 68 Page 4 of 4 BATCH REAGENTS 21B2306 Table of Contents Page 23 of 68 Table of Contents Page 24 of 68 Table of Contents Page 25 of 68 BATCH REAGENTS 21B2307 Table of Contents Page 26 of 68 Table of Contents Page 27 of 68 Table of Contents Page 28 of 68 BATCH REAGENTS 21B2308 Table of Contents Page 29 of 68 Table of Contents Page 30 of 68 Table of Contents Page 31 of 68 BATCH REAGENTS 21B2309 Table of Contents Page 32 of 68 Table of Contents Page 33 of 68 Table of Contents Page 34 of 68 BATCH REAGENTS 21F2904 Table of Contents Page 35 of 68 Environmental Protection Agency Region 5 Chicago Regional Laboratory 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 Reagent Preparation Bench Sheet Table of Contents Print Date: 6/29/2021 Parameter / SOP #: TP/TKN SOP AIG34B ver#7, AIG35B ver#8 Reagent: TP/TKN Digestion Solution LIMS ID: 21F2904 Chemical Name (Formula) Sulfuric Acid (H2S04) Prepared by: Nidia Fuentes Preparation Date: Jun-29-21 Expiration Date: Jun-29-22 LIMS ID 20B0607 Mass or Volume (specify units) 200 mL Mercuric Sulfate solution 21F2903 25 mL Potassium Sulfate (K2SO4) 20J2902 133.3216 g Total Volume : Comments : Balance #17 1000 mL Analyst Signature: By Anna Knoebel at 7:04 am, Aug 24, 2021 PPagagee316 of 618 Balance Check Table of Contents BALANCE ID: #17 DATE: 6/29/2021 ANALYST: Christina Rice WEIGHT SET ID: TROEMNER S/N: 4000026116 WGT SET # CONFIRMED: YES WEIGHT SET 2 ID: WGT SET # CONFIRMED: *NOTE: Save as excel file and print to pdf. Store both files in balance check folders on the computer. *NOTE: Confirm # of weights in weight set before and after use above. # of weights in weight sets are listed at bottom of page. Create IR if find that weights are missing . Note any weights that are missing in the comments field below and contact QAO to remove weight(s) from Qualtrax records. Analytical Balance Tolerance Limits Top-Loading Balance Tolerance Limits Standard Weight (g) 0.0100 0.0200 0.0200* 0.0500 0.1000 0.2000 0.2000* 0.5000 1.0000 2.0000 2.0000* 5.0000 10.0000 20.0000 20.0000* 50.0000 100.0000 200.0000 Actual LCL (g) Weight (g) 0.0099 0.0500 0.1001 0.5000 1.0000 10.0000 100.0003 199.9999 0.0099 0.0199 0.0199 0.0499 0.0999 0.1999 0.1999 0.4999 0.9999 1.9999 1.9999 4.9999 9.9999 19.9999 19.9999 49.9999 99.9997 199.9995 UCL (g) 0.0101 0.0201 0.0201 0.0501 0.1001 0.2001 0.2001 0.5001 1.0001 2.0001 2.0001 5.0001 10.0001 20.0001 20.0001 50.0001 100.0003 200.0005 Standard Weight (g) 0.01 0.02 0.02* 0.05 0.10 0.20 0.20* 0.50 1.00 2.00 2.00* 5.00 10.00 20.00 20.00* 50.00 100.00 200.00 300.00 500.00 1000.00 Actual Weight (g) LCL (g) 0.00 0.01 0.01 0.04 0.09 0.19 0.19 0.49 0.99 1.99 1.99 4.99 9.99 19.99 19.99 49.99 99.99 199.99 299.99 499.99 999.99 UCL (g) 0.02 0.03 0.03 0.06 0.11 0.21 0.21 0.51 1.01 2.01 2.01 5.01 10.01 20.01 20.01 50.01 100.01 200.01 300.01 500.01 1000.01 Weight Sets: TROEMNER S/N: 4000017548: 21 weights TROEMNER S/N: 4000020557: 21 weights Denver Inst Co S/N: 01-25360-3A: 1 weight TROEMNER S/N: 06679: 5 weights TROEMNER S/N: 4000026116: 22 weights COMMENTS: Standard Weight 0.001g Actual Weight 0.0009g Qualtrax ID 23790 Version 6, Updated: June 8, 2021 Print Date: 6/29/2021 Page 37 of 68 SEQUENCE 21G2701 [TOC_1]Sequence[TOC] Table of Contents Sequence Date: 07/27/2021 Instrument: DA-3 Sequence Analyses: Total Phosphorus DA Page 38 of 68 Instrument: Order 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 ANALYSIS SEQUENCE 21G2701 DA-3 Container A A A A A Analysis Date: Jul-27-21 Lab Number Sample name or QC sample designation 21G2701-CAL1 Cal Standard 21G2701-CAL2 Cal Standard 21G2701-CAL3 Cal Standard 21G2701-CAL4 Cal Standard 21G2701-CAL5 Cal Standard 21G2701-CAL6 Cal Standard 21G2701-CAL7 Cal Standard 21G2701-ICB1 CCB 21G2701-ICV1 CCV B21G028-MRL1 MRL Check B21G028-BLK1 Blank B21G028-BS1 LCS 2107010-01 BO1 2107010-04 SO3 2107010-05 SO4 21G2701-CCB1 CCB 21G2701-CCV1 CCV 21G2701-CCB2 CCB 21G2701-CCV2 CCV 2107010-02 SO1 B21G028-DUP1 Duplicate B21G028-MS1 Matrix Spike 2107010-03 SO2 Calibration ID: UNASSIGNED Analysis QC QC QC QC QC QC QC QC QC QC QC QC Total Phosphorus DA Total Phosphorus DA Total Phosphorus DA QC QC QC QC Total Phosphorus DA QC QC Total Phosphorus DA Matrix: Water STD ID 21G2601 21G2703 21G2704 21G2705 21G2706 21G2707 21G2602 21G2603 Printed: 7/27/2021 3:30:27PM Comments 21G2603 21G2603 pH = 1 pH = 1 pH = 1 pH = 1 pH = 1 Table of Contents Page 39 of 68 Page 1 of 2 Order 24 25 Container Lab Number 21G2701-CCB3 21G2701-CCV3 Sample name or QC sample designation CCB QC CCV QC PREPARATION REAGENTS/STANDARDS/PIPETTES: 21D0715: TP-Stock Cal Standard (SCS) Prepared: Apr-07-21 21G2604: TP - MRL (0.15 mg P/L) Prepared: Jul-26-21 21G2601: TP - WCS (0.00 mg P/L) Prepared: Jul-26-21 21G2602: TP - WCS (3.00 mg P/L) Prepared: Jul-26-21 21G2603: TP - WcS (2.00 mg P/L) Prepared: Jul-26-21 21G2703: TP - WCS (0.15 mg P/L) Prepared: Jul-27-21 21G2704: TP - WCS (0.3 mg P/L) Prepared: Jul-27-21 21G2705: TP - WCS (0.75 mg P/L) Prepared: Jul-27-21 21G2706: TP - WCS (1.0 mg P/L) Prepared: Jul-27-21 21G2707: TP - WCS (1.5 mg P/L) Prepared: Jul-27-21 21G0808: TKN - Sodium salicylate/sodium nitroprusside sol. Prepared: Jul-08-21 21G2609: TP-NaCl Solution Prepared: Jul-26-21 21G2610: TP- Ascorbic Acid Prepared: Jul-26-21 21B1701 TP-Molybdate Antimony Solution Prepared: Feb-17-21 Analysis STD ID 21G2603 Expires: Apr-07-22 Expires: Aug-26-21 Expires: Aug-26-21 Expires: Aug-26-21 Expires: Aug-26-21 Expires: Jul-28-21 Expires: Jul-28-21 Expires: Jul-28-21 Expires: Jul-28-21 Expires: Jul-28-21 Expires: Jul-08-22 Expires: Jul-26-22 Expires: $XJ- -2 By NFUENTES at 10:05 am, Aug 24, 2021 Expires: Feb-17-22 By NFUENTES at 10:08 am, Aug 24, 2021 Comments Table of Contents Page 40 of 68 Page 2 of 2 ! " #$ && ' ( % % )* +)%+ ! # +)%+ " ) $ % ) ) ) ) ) ) ) ) ) %% ) ) ) )+ & ' ! )* ) , )% * )% , ) ++% ) , ) )% , ) ) , ) ++ )% , ) %* ) , Table of Contents Page 41 of 68 Table of Contents ! " #$ % ,,,,/ -1 -1 -1 2 -24 -! -1 + -1 ! . ,,,,/ ,,- ,,/ -1 + -1 ! ,,,,/ ,,,,/ -1 + -1 ! ,,- ,,/ ,,- ,,/ +& *$& ' '. ' '0 ' ' 30 ' ' ' '3 ' '3 ' D ' D ' D ' D ' '33 ' ' ' ' ' '3 ' 3' 3 ' ' ' ' ' 3'. ' '03 0 ' 3' ' ' .0 ' '3303 ' '. ' ' ' 3'. 3 ' 3' . ' ' ' '. ' ' .0 ' '. ' ' ' 3' 0 &' ( ! )$$ $ ' ## ' ## ' ## ' ## ' ## ' ## ' $5 & ' & & 6& ' $5 & ' & & 6& ' $5 & ' & & 6& ' $5 & ' & & 6& ' ## ' ## ' ## ' ## Not used, reanalyzed because of failed matrix spike QC 3' ## ' ## By NFUENTES at 10:11 am, Aug 24, 2021 ' ## 3' ## 3' ## 3' ## ' ## ' ## ' ## ' ## 3' ## same cup 3' ## 3' ## ' ## By NFUENTES at 2:54 pm, Jul 27, 2021 ' ## ' ## ' ## .' ## new cups By NFUENTES at 10:11 am, Aug 24, 2021 Page 42 of 68 ! " #$ % -1 + -1 ! ,,,,/ +& *$& ' 3' ' '00 ' 3'00 ' ' ' ' D - diluted by the instrument &' ( ! .' ## .' ## ' ## ' ## ' ## )$$ $ Table of Contents new cups By NFUENTES at 10:11 am, Aug 24, 2021 new cup By NFUENTES at 10:11 am, Aug 24, 2021 same cup By NFUENTES at 10:12 am, Aug 24, 2021 Page 43 of 68 Date Time DA-3 7/27/2021 User NF 12:54:28 PM Software version: 7.0 Sample/ctrl ID Pat/Ctr/cAl Test name Test type Result Result unit Result time STAT TP-0 A TP-3.0 A TP-3.0 A TP-3.0 A TP-3.0 A TP-3.0 A TP-3.0 A CCB C CCV C B21G028-MRL1 P B21G028-BLK1 P B21G028-BS1 P 2107010-01 P 2107010-02 P B21G028-DUP1 P B21G028-MS1 P 2107010-03 P 2107010-04 P 2107010-05 P CCB C CCV C 2107010-02 P CCB C CCV C B21G028-DUP1 P B21G028-MS1 P 2107010-03 P CCB C CCV C CCB C CCV C 2107010-02 P B21G028-DUP1 P B21G028-MS1 P CCB C CCV C CCB C CCV C 2107010-02 P B21G028-DUP1 P B21G028-MS1 P 2107010-03 P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P Total Phos P 0.02248 mg/l 0.15208 mg/l 0.29665 mg/l 0.74217 mg/l 0.99413 mg/l 1.47669 mg/l 3.0158 mg/l 0.01415 mg/l 2.006 mg/l 0.13959 mg/l 0.01167 mg/l 1.01386 mg/l 0.00983 mg/l 9.0961 mg/l 9.12321 mg/l 9.73685 mg/l 9.05994 mg/l 1.29788 mg/l 1.33234 mg/l 0.01514 mg/l 1.98734 mg/l 9.35786 mg/l 0.01326 mg/l 2.0101 mg/l 9.4878 mg/l 10.69863 mg/l 9.50995 mg/l 0.01458 mg/l 1.9969 mg/l 0.01396 mg/l 2.00128 mg/l 9.47931 mg/l 9.5848 mg/l 10.73251 mg/l 0.01468 mg/l 2.00464 mg/l 0.01412 mg/l 2.00326 mg/l 9.56274 mg/l 9.53297 mg/l 10.76756 mg/l 9.6625 mg/l 7/27/2021 10:48 7/27/2021 10:50 7/27/2021 10:51 7/27/2021 10:52 7/27/2021 10:54 7/27/2021 10:55 7/27/2021 10:56 7/27/2021 11:25 7/27/2021 11:25 7/27/2021 11:26 7/27/2021 11:27 7/27/2021 11:28 7/27/2021 11:29 7/27/2021 11:30 7/27/2021 11:31 7/27/2021 11:32 7/27/2021 11:33 7/27/2021 11:34 7/27/2021 11:34 7/27/2021 11:35 7/27/2021 11:36 7/27/2021 11:41 7/27/2021 11:41 7/27/2021 11:42 7/27/2021 11:44 7/27/2021 11:46 7/27/2021 11:48 7/27/2021 11:49 7/27/2021 11:50 7/27/2021 12:05 7/27/2021 12:05 7/27/2021 12:07 7/27/2021 12:09 7/27/2021 12:10 7/27/2021 12:11 7/27/2021 12:12 7/27/2021 12:43 7/27/2021 12:44 7/27/2021 12:46 7/27/2021 12:47 7/27/2021 12:49 7/27/2021 12:50 Status MA MA MA MA MA MA MA MA MA MA MA MA MA AR AR AR AR MA MA MA MA MA MA MA MA MA MA MA MA MA MA MA MA MA MA MA MA MA MA MA MA MA Dilution 1 +Manual diluRtieosponse Blank respoMnsain abs. 1Blank abs. 1Sample type 0 0.00728 -0.00015 0.00713 -0.00015 19 0.02703 -0.00016 0.02687 -0.00016 9 0.04905 0.00018 0.04923 0.00018 3 0.11694 0.00035 0.11728 0.00035 2 0.15532 0.00055 0.15588 0.00055 1 0.22885 0.00092 0.22977 0.00092 0 0.46336 0.0026 0.46596 0.0026 0 0.00601 -0.00004 0.00597 -0.00004 0 0.3095 0.00121 0.31071 0.00121 0 0 0.02512 0.00042 0.02554 0.00042 Sample type 1 0 0 0.00563 0.00018 0.00582 0.00018 Sample type 1 0 0 0.15833 0.00132 0.15966 0.00132 Sample type 1 0 0 0.00535 0.00042 0.00578 0.00042 Sample type 1 0 0 1.3898 0.01195 1.40175 0.01195 Sample type 1 0 0 1.39393 0.01206 1.40599 0.01206 Sample type 1 0 0 1.48743 0.06211 1.54954 0.06211 Sample type 1 0 0 1.38429 0.06838 1.45267 0.06838 Sample type 1 0 0 0.20161 0.0028 0.20441 0.0028 Sample type 1 0 0 0.20686 0.00459 0.21145 0.00459 Sample type 1 0 0.00616 0 0.00617 0 0 0.30666 0.00125 0.30791 0.00125 9 0 0.14644 0.00275 0.14919 0.00275 Sample type 1 0 0.00587 -0.00013 0.00574 -0.00013 0 0.31013 0.00114 0.31127 0.00114 9 0 0.14842 0.00099 0.14941 0.00099 Sample type 1 9 0 0.16686 0.00096 0.16782 0.00096 Sample type 1 9 0 0.14875 0.0009 0.14966 0.0009 Sample type 1 0 0.00607 -0.00002 0.00605 -0.00002 0 0.30811 0.00137 0.30948 0.00137 0 0.00598 0.00017 0.00615 0.00017 0 0.30878 0.00134 0.31012 0.00134 9 0 0.14829 0.00123 0.14952 0.00123 Sample type 1 9 0 0.14989 0.00091 0.1508 0.00091 Sample type 1 9 0 0.16738 0.00071 0.16809 0.00071 Sample type 1 0 0.00609 0.00026 0.00635 0.00026 0 0.30929 0.00109 0.31038 0.00109 0 0.006 -0.00028 0.00573 -0.00028 0 0.30908 0.00087 0.30996 0.00087 4 0 0.29526 0.0046 0.29986 0.0046 Sample type 1 4 0 0.29435 0.00271 0.29706 0.00271 Sample type 1 4 0 0.33198 0.00203 0.334 0.00203 Sample type 1 5 0 0.24923 0.00376 0.25299 0.00376 Sample type 1 Table of Contents Page 44 of 68 Table of Contents Page 45 of 68 CCB C CCV C Total Phos P Total Phos P 0.01552 mg/l 7/27/2021 12:51 MA 2.01696 mg/l 7/27/2021 12:52 MA 0 0.00622 -0.0004 0.00582 -0.0004 0 0.31117 0.00114 0.31231 0.00114 Environmental Protection Agency Region 5 Chicago Regional Laboratory 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 Table of Contents Analytical Standard Record US EPA Region 5 LSASD Analytical Services Branch 21D0715 Description: Standard Type: Solvent: Final Volume (mls): Vials: Vendor: Lot Number: TP-Stock Cal Standard (SCS) Analyte Spike NA 125 1 Inorganic Ventures P2-P688018 Expires: Prepared: Prepared By: Department: Last Edit: Apr-07-22 Apr-07-21 Nidia Fuentes A&I Apr-13-21 14:43 by NF Enter dates opened of each bottle under User-Defined Fields. NOTE: Bottle expires one year after the package is opened (See date when openned) or the Expiration date 04/07/2022, whichever one is sooner. Analyte CAS Number Concentration (ppm) Total Dissolved Phosphorus Total Phosphorus NA 100 NA 100 By AK at 9:58 am, Apr 14, 2021 PPagagee4P16aogfe 6118of 1 Table of Contents 1.0 ACCREDITATION / REGISTRATION INORGANIC VENTURES is accredited to ISO 17034, "General Requirements for the Competence of Reference Material Producers" and ISO/IEC 17025, "General Requirements for the Competence of Testing and Calibration Laboratories". Inorganic Ventures is also an ISO 9001 registered manufacturer (QSR Certificate Number QSR-1034). Testing Laboratory Certificate 883.01 Reference Material Producer Certificate 883.02 2.0 PRODUCT DESCRIPTION Product Code: Catalog Number: Lot Number: Matrix: Value / Analyte(s): Starting Material: Single Analyte Mass Spec Solution MSP-100PPM P2-P688018 H2O 100 g/mL ea: Phosphorus H3PO4 By AK at 9:58 am, Apr 14, 2021 Starting Material Lot#: 108587 Starting Material Purity: 100.0000% 3.0 CERTIFIED VALUES AND UNCERTAINTIES Certified Value: Density: 100.06 0.70 g/mL 0.998 g/mL (measured at 20 4 C) Assay Information: ANALYTE P METHOD ICP Assay NIST SRM# 3139a SRM LOT# 060717 P Acidimetric 84L 84L The following equations are used in the calculation of the certified value and the uncertainty. Reported uncertainties represent expanded uncertainties expressed at approximately the 95% confidence level using a coverage factor of k = 2. 4.0 TRACEABILITY TO NIST - This product is traceable to NIST via an unbroken chain of comparisons. The uncertainties for each certified value are reported, taking into account the SRM/RM uncertainty error and the measurement, weighing and volume dilution errors. In rare cases where no NIST SRM/RM are available, the term 'in-house std.' is specified. Page 1 of 4 Page 47 of 68 4.1 Thermometer Calibration Table of Contents - All thermometers are NIST traceable through thermometers that are calibrated by an accredited calibration laboratory. 4.2 Balance Calibration - All analytical balances are calibrated by an accredited calibration laboratory and procedure. The weights used for testing are annually compared to master weights and are traceable to NIST. 4.3 Glassware Calibration - An in-house procedure is used to calibrate all Class A glassware used in the manufacturing and quality control of CRM/RMs. 5.0 TRACE METALLIC IMPURITIES (TMI ) DETERMINED BY ICP-MS AND ICP-OES (g/mL) CRM/RMs are tested for trace metallic impurities by Axial ICP-OES and ICP-MS. The result from the most sensitive method for each element, is reported below. Solutions tested by ICP-MS were analyzed in an ULPA-Filtered Clean Room. An ULPA-Filter is 99.9985% efficient for the removal of particles down to 0.3 m. M Ag < M Al < M As < M Au < MB < O Ba < M Be < M Bi < O Ca M Cd < M Ce < M Co < M Cr M Cs < O Cu < M Dy < M Er < 0.000040 M 0.003405 O 0.000324 M 0.000040 M 0.001216 M 0.000639 M 0.000121 M 0.000040 M 0.000019 M 0.000040 M 0.000040 O 0.000081 M 0.000004 O 0.000040 M 0.003837 O 0.000040 M 0.000040 M Eu < Fe Ga < Gd < Ge < Hf < Hg < Ho < In < Ir < K< La < Li < Lu < Mg Mn < Mo < 0.000040 O 0.000008 M 0.000040 M 0.000040 M 0.000081 M 0.000040 s 0.000081 M 0.000040 M 0.000040 M 0.000040 M 0.010660 M 0.000040 M 0.000106 M 0.000040 M 0.000001 O 0.000081 M 0.001216 O Na Nb < Nd < Ni < Os < P< Pb < Pd < Pr < Pt < Rb < Re < Rh < Ru < S< Sb Sc < 0.000047 M 0.000243 O 0.000040 M 0.003000 M 0.000040 M M 0.000040 M 0.000040 M 0.000040 M 0.000040 O 0.000040 M 0.000040 M 0.000040 M 0.000405 M 0.031980 M 0.000002 M 0.001066 M Se < Si < Sm < Sn < Sr < Ta < Tb < Te < Th < Ti < Tl < Tm < U< V< W< Y< Yb < 0.003405 M 0.014924 M 0.000040 0.000040 0.000040 0.000040 0.000040 0.000324 0.000040 0.001066 0.000040 0.000040 0.000040 0.000040 0.000405 0.000040 0.000040 Zn < Zr < 0.001054 0.001054 M - Checked by ICP-MS O - Checked by ICP-OES i - Spectral Interference n - Not Checked For s - Solution Standard Element 6.0 INTENDED USE - For the calibration of analytical instruments and validation of analytical methods as appropriate. 7.0 INSTRUCTIONS FOR THE CORRECT USE OF THIS REFERENCE MATERIAL 7.1 Storage and Handling Recommendations - Store between approximately 4 - 30 C while in sealed TCT bag. - While stored in the sealed TCT bag, transpiration of this CRM/RM is negligible. After opening the sealed TCT bag transpiration of the CRM/RM will occur, resulting in a gradual increase in the analyte concentration(s). It is the responsibility of the user to account for this effect. When the bottle is weighed both before and after being placed in storage, the mass difference observed will be a measure of transpiration mass loss. - After opening the sealed TCT bag, keep cap tightly sealed when not in use and store between 4 - 24 C to minimize the effects of transpiration. Use at 20 4 C to minimize volumetric dilution error when using the reported density. Do not pipette from the container. Do not return removed aliquots to container. - For more information, visit www.inorganicventures.com/TCT Page 2 of 4 Page 48 of 68 Table of Contents Atomic Weight; Valence; Coordination Number; Chemical Form in Solution - 30.97 +5 6 O=P(OH)2(O)1- Chemical Compatibility -Soluble in HCl, HNO3, H2SO4 and HF aqueous matrices water and NH4OH. Stable with all metals and inorganic anions at low to moderate ppm levels under acidic conditions; precipitates with several metals occur in neutral media at higher concentrations. Stability - 2-100 ppb levels- stability unknown - in 1% HNO3 / LDPE container. 1-10,000 ppm solutions chemically stable for years in 0-1% HNO3 / LDPE container. P Containing Samples (Preparation and Solution) -Metal (Never found free in nature ); Oxides (Water soluble); Ores (Naturally occurring only as the phosphate except for a few rare minerals found in meteorites - Na2CO3fusion in Pt0); Organic Matrices (Dry ash mixed with Na2CO3 in Pt0 at 450EC then increase heat to 1000EC to fuse; or perform an H2SO4 / H2O2 acid digestion ). Atomic Spectroscopic Information (ICP-OES D.L.s are given as radial/axial view): Technique/Line Estimated D.L. Order Interferences (underlined indicates severe) ICP-MS 31 amu 6000+ ppt n/a 15N21H, 15N16O, 14N17O, 13C18O, 12C18O1H, 62Ni2+ ICP-OES 177.495 nm 0.01 / 0.005 g/mL 1 Cu, Hf ICP-OES 178.287 nm 0.03 / 0.002 g/mL 1 I ICP-OES 213.618 nm 0.08 / 0.03 g/mL 1 Cu, Mo 8.0 9.0 10.0 11.0 HAZARDOUS INFORMATION - Please refer to the Safety Data Sheet for information regarding this CRM/RM. HOMOGENEITY - This solution was mixed according to an in-house procedure and is guaranteed to be homogeneous. Homogeneity data indicate that the end user should take a minimum sample size of 0.2 mL to assure homogeneity. QUALITY STANDARD DOCUMENTATION 10.1 ISO 9001 Quality Management System Registration - QSR Certificate Number QSR-1034 10.2 ISO/IEC 17025 "General Requirements for the Competence of Testing and Calibration Laboratories" - Chemical Testing - Accredited / A2LA Certificate Number 883.01 10.3 ISO 17034 "General Requirements for the Competence of Reference Material Producers" - Reference Material Producer - Accredited / A2LA Certificate Number 883.02 Inorganic Ventures, 300 Technology Drive, Christiansburg, Va. 24073, USA; Telephone: 800.669.6799; 540.585.3030, Fax: 540.585.3012; inorganicventures.com; info@inorganicventures.com CERTIFICATION, LOT EXPIRATION AND PERIOD OF VALIDITY 11.1 Certification Issue Date February 07, 2020 - The certification is valid within the measurement uncertainty specified provided the CRM/RM is stored and handled in accordance with instructions given in Sec 7.1. This certification is nullified if instructions in Sec 7.1 are not followed or if the CRM/RM is damaged, contaminated, or otherwise modified. 11.2 Lot Expiration Date - February 07, 2024 - The date after which this CRM/RM should not be used. - The lot expiration date reflects the period of time that the stability of a CRM/RM can be supported by long term stability studies conducted on properly stored and handled CRM/RMs. Lot expiration is limited primarily by transpiration (loss of water from the solution) and infrequently by chemical stability. Page 3 of 4 Page 49 of 68 12.0 11.3 Period of Validity Table of Contents - Sealed TCT Bag Open Date: __________________________ - This CRM/RM should not be used longer than one year (or six months in the case of a 30 mL bottle) from the date of opening the aluminized bag or after the date given in Sec. 11.2, whichever comes first. This is contingent upon the CRM/RM being stored and handled in accordance with the instructions given in Sec. 7.1. NAMES AND SIGNATURES OF CERTIFYING OFFICERS Certificate Approved By: Michael Booth Manager, Quality Control Certifying Officer: Paul Gaines CEO, Senior Technical Director Page 4 of 4 Page 50 of 68 Environmental Protection Agency Region 5 Chicago Regional Laboratory 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 Description: Standard Type: Solvent: Final Volume (mls): Vials: Vendor: Lot Number: Analytical Standard Record US EPA Region 5 LSASD Analytical Services Branch 21G2601 TP - WCS (0.00 mg P/L) Other Solution Reagent water 200 1 Inorganic Ventures P2-P688018 Expires: Prepared: Prepared By: Department: Last Edit: Aug-26-21 Jul-26-21 Nidia Fuentes A&I Aug-10-21 12:57 by NF Table of Contents Analyte Total Dissolved Phosphorus Total Phosphorus CAS Number NA NA Concentration (ppm) 0 0 Parent Standards used in this standard: Standard 21B2306 21G0902 Description Pipette (Electronic) -- 50 -1,000 uL Sulfuric Acid 9673-00 21C0910 TP-Stock Cal Standard (SCS) Prepared Feb-15-21 Jul-09-21 Apr-07-21 Prepared By Nidia Fuentes ** Vendor ** Nidia Fuentes Expires Aug-31-21 May-11-25 Apr-07-22 Last Edit Apr-05-21 09:19 by AK Jul-28-21 10:03 by NF Apr-14-21 09:24 by AK (mls) 0.2 0.2 0 By Anna Knoebel at 7:33 am, Aug 24, 2021 PPagagee51 of 618 Environmental Protection Agency Region 5 Chicago Regional Laboratory 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 Description: Standard Type: Solvent: Final Volume (mls): Vials: Vendor: Lot Number: Analytical Standard Record US EPA Region 5 LSASD Analytical Services Branch 21G2602 TP - WCS (3.00 mg P/L) Other Solution Reagent water 100 1 Inorganic Ventures P2-P688018 Expires: Prepared: Prepared By: Department: Last Edit: Aug-26-21 Jul-26-21 Nidia Fuentes A&I Aug-10-21 12:58 by NF Table of Contents Analyte Total Dissolved Phosphorus Total Phosphorus CAS Number NA NA Concentration (ppm) 3 3 Parent Standards used in this standard: Standard 21B2307 21B2309 Description Pipette (Electronic) -- 200 -5000 uL Pipette (Electronic) -- 5 -100 uL 21G0902 Sulfuric Acid 9673-00 21C0910 TP-Stock Cal Standard (SCS) Prepared Feb-15-21 Feb-15-21 Jul-09-21 Apr-07-21 Prepared By Nidia Fuentes Nidia Fuentes ** Vendor ** Nidia Fuentes Expires Aug-31-21 Aug-31-21 May-11-25 Apr-07-22 Last Edit Apr-05-21 09:23 by AK Apr-05-21 09:33 by AK Jul-28-21 10:03 by NF Apr-14-21 09:24 by AK (mls) 3 0.1 0.1 3 By Anna Knoebel at 7:34 am, Aug 24, 2021 PPagagee512 of 618 Environmental Protection Agency Region 5 Chicago Regional Laboratory 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 Description: Standard Type: Solvent: Final Volume (mls): Vials: Vendor: Lot Number: Analytical Standard Record US EPA Region 5 LSASD Analytical Services Branch 21G2603 TP - WcS (2.00 mg P/L) Other Solution Reagent water 100 1 Absolute Standards Inc. 012721 Expires: Prepared: Prepared By: Department: Last Edit: Aug-26-21 Jul-26-21 Nidia Fuentes A&I Aug-10-21 12:58 by NF Table of Contents Analyte Total Dissolved Phosphorus Total Kjeldahl Nitrogen Total Phosphorus CAS Number NA NA NA Concentration (ppm) 2 2 2 Parent Standards used in this standard: Standard 21B2309 Description Pipette (Electronic) -- 5 -100 uL 21B2306 21G0902 Pipette (Electronic) -- 50 -1,000 uL Sulfuric Acid 9673-00 21C1801 TP&TKN Stock Control Std. Prepared Feb-15-21 Feb-15-21 Jul-09-21 Mar-16-21 Prepared By Nidia Fuentes Nidia Fuentes ** Vendor ** Nidia Fuentes Expires Aug-31-21 Aug-31-21 May-11-25 Jan-07-23 Last Edit Apr-05-21 09:33 by AK Apr-05-21 09:19 by AK Jul-28-21 10:03 by NF Jun-02-21 08:19 by NF (mls) 0.1 0.2 0.1 0.2 By Anna Knoebel at 7:37 am, Aug 24, 2021 PPagagee513 of 618 Environmental Protection Agency Region 5 Chicago Regional Laboratory 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 Description: Standard Type: Solvent: Final Volume (mls): Vials: Vendor: Lot Number: Analytical Standard Record US EPA Region 5 LSASD Analytical Services Branch 21G2604 TP - MRL (0.15 mg P/L) Reference Material Reagent water 100 1 Inorganic Ventures P2-P688018 Expires: Prepared: Prepared By: Department: Last Edit: Aug-26-21 Jul-26-21 Nidia Fuentes A&I Aug-10-21 12:59 by NF Table of Contents Analyte Total Dissolved Phosphorus Total Phosphorus CAS Number NA NA Concentration (ppm) 0.15 0.15 SRM Control Limits 0-200 0-200 Parent Standards used in this standard: Standard 21B2309 Description Pipette (Electronic) -- 5 -100 uL 21B2306 21G0902 Pipette (Electronic) -- 50 -1,000 uL Sulfuric Acid 9673-00 21C0910 TP-Stock Cal Standard (SCS) Prepared Feb-15-21 Feb-15-21 Jul-09-21 Apr-07-21 Prepared By Nidia Fuentes Nidia Fuentes ** Vendor ** Nidia Fuentes Expires Aug-31-21 Aug-31-21 May-11-25 Apr-07-22 Last Edit Apr-05-21 09:33 by AK Apr-05-21 09:19 by AK Jul-28-21 10:03 by NF Apr-14-21 09:24 by AK (mls) 0.15 0.1 0.1 0.15 By Anna Knoebel at 6:54 am, Aug 24, 2021 PPagagee514 of 618 Environmental Protection Agency Region 5 Chicago Regional Laboratory 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 Analytical Standard Record US EPA Region 5 LSASD Analytical Services Branch 21G2703 Description: Standard Type: Solvent: Final Volume (mls): Vials: Vendor: Lot Number: TP - WCS (0.15 mg P/L) Other Solution Blank:21G2601 2 1 Inorganic Ventures P2-P688018 Expires: Prepared: Prepared By: Department: Last Edit: Jul-28-21 Jul-27-21 Nidia Fuentes A&I Aug-10-21 12:58 by NF Prepared by instrument (DA-3) By Anna Knoebel at 7:42 am, Aug 24, 2021 Analyte Total Dissolved Phosphorus Total Phosphorus CAS Number NA NA Concentration (ppm) 0.15 0.15 Table of Contents Parent Standards used in this standard: Standard 21G2602 Description TP - WCS (3.00 mg P/L) Prepared Jul-26-21 Prepared By Nidia Fuentes Expires Aug-26-21 Last Edit Aug-10-21 12:58 by NF (mls) 0.1 PPagagee515 of 618 Environmental Protection Agency Region 5 Chicago Regional Laboratory 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 Analytical Standard Record US EPA Region 5 LSASD Analytical Services Branch 21G2704 Description: Standard Type: Solvent: Final Volume (mls): Vials: Vendor: Lot Number: TP - WCS (0.3 mg P/L) Other Solution Blank:21G2601 2 1 Inorganic Ventures P2-P688018 Expires: Prepared: Prepared By: Department: Last Edit: Jul-28-21 Jul-27-21 Nidia Fuentes A&I Aug-16-21 10:29 by NF Prepared by instrument (DA-3) By Anna Knoebel at 7:43 am, Aug 24, 2021 Analyte CAS Number Concentration (ppm) Total Dissolved Phosphorus Total Phosphorus NA 0.3 NA 0.3 Table of Contents Parent Standards used in this standard: Standard 21G2602 Description TP - WCS (3.00 mg P/L) Prepared Jul-26-21 Prepared By Nidia Fuentes Expires Aug-26-21 Last Edit Aug-10-21 12:58 by NF (mls) 0.2 PPagagee516 of 618 Environmental Protection Agency Region 5 Chicago Regional Laboratory 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 Analytical Standard Record US EPA Region 5 LSASD Analytical Services Branch 21G2705 Description: Standard Type: Solvent: Final Volume (mls): Vials: Vendor: Lot Number: TP - WCS (0.75 mg P/L) Other Solution Blank:21G2601 2 1 Inorganic Ventures P2-P688018 Expires: Prepared: Prepared By: Department: Last Edit: Jul-28-21 Jul-27-21 Nidia Fuentes A&I Aug-10-21 12:58 by NF Prepared by instrument (DA-3) By Anna Knoebel at 7:43 am, Aug 24, 2021 Analyte CAS Number Concentration (ppm) Total Dissolved Phosphorus Total Phosphorus NA 0.75 NA 0.75 Table of Contents Parent Standards used in this standard: Standard 21G2602 Description TP - WCS (3.00 mg P/L) Prepared Jul-26-21 Prepared By Nidia Fuentes Expires Aug-26-21 Last Edit Aug-10-21 12:58 by NF (mls) 0.5 PPagagee517 of 618 Environmental Protection Agency Region 5 Chicago Regional Laboratory 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 Analytical Standard Record US EPA Region 5 LSASD Analytical Services Branch 21G2706 Description: Standard Type: Solvent: Final Volume (mls): Vials: Vendor: Lot Number: TP - WCS (1.0 mg P/L) Other Solution Blank:21G2601 2 1 Inorganic Ventures P2-P688018 Expires: Prepared: Prepared By: Department: Last Edit: Jul-28-21 Jul-27-21 Nidia Fuentes A&I Aug-10-21 12:58 by NF Prepared by instrument (DA-3) By Anna Knoebel at 7:44 am, Aug 24, 2021 Analyte CAS Number Concentration (ppm) Total Dissolved Phosphorus Total Phosphorus NA 1 NA 1 Table of Contents Parent Standards used in this standard: Standard 21G2602 Description TP - WCS (3.00 mg P/L) Prepared Jul-26-21 Prepared By Nidia Fuentes Expires Aug-26-21 Last Edit Aug-10-21 12:58 by NF (mls) 0.6666666 PPagagee518 of 618 Environmental Protection Agency Region 5 Chicago Regional Laboratory 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 Analytical Standard Record US EPA Region 5 LSASD Analytical Services Branch 21G2707 Description: Standard Type: Solvent: Final Volume (mls): Vials: Vendor: Lot Number: TP - WCS (1.5 mg P/L) Other Solution Blank:21G2601 2 1 Inorganic Ventures P2-P688018 Expires: Prepared: Prepared By: Department: Last Edit: Jul-28-21 Jul-27-21 Nidia Fuentes A&I Aug-10-21 12:58 by NF Prepared by instrument (DA-3) Analyte By Anna Knoebel at 7:45 am, Aug 24, 2021 CAS Number Concentration (ppm) Total Dissolved Phosphorus Total Phosphorus NA 1.5 NA 1.5 Table of Contents Parent Standards used in this standard: Standard 21G2602 Description TP - WCS (3.00 mg P/L) Prepared Jul-26-21 Prepared By Nidia Fuentes Expires Aug-26-21 Last Edit Aug-10-21 12:58 by NF (mls) 1 PPagagee519 of 618 Table of Contents ANALYSIS REAGENTS/STANDARDS 21B1701 Page 60 of 68 Environmental Protection Agency Region 5 Chicago Regional Laboratory 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 Reagent Preparation Bench Sheet Table of Contents Print Date: 2/17/2021 Parameter / SOP #: TP / AIG034B VER# 7 Reagent: TP-MolybdateAntimonySolution LIMS ID: 21B1701 Chemical Name (Formula) Ammonium Molybdate tetrahydrate * Prepared by: Nidia Fuentes Preparation Date: Feb-17-21 Expiration Date: Feb-17-22 LIMS ID 19K1225 Mass or Volume (specify units) 0.8024g Potassium antimonyl tartrate trihydrate ** 19K0602 0.0223g * [(NH4)6Mo7O24*4H2O] ** [K2(C4H2O6Sb)2*3H2O] Total Volume : Comments : Balance ID: 17 100 mL Analyst Signature: By AK at 12:15 pm, May 07, 2021 Page 6P1aogfe 618of 1 Table of Contents Page 62 of 68 Table of Contents ANALYSIS REAGENTS/STANDARDS 21G2609 Page 63 of 68 Environmental Protection Agency Region 5 Chicago Regional Laboratory 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 Reagent Preparation Bench Sheet Table of Contents Print Date: 7/26/2021 Parameter / SOP #: TP / AIG034B VER#7 Reagent: TP-NaCl Solution LIMS ID: 21G2609 Chemical Name (Formula) Sodium Chloride (NaCl) Prepared by: Nidia Fuentes Preparation Date: Jul-26-21 Expiration Date: Jul-26-22 LIMS ID 19C1203 Mass or Volume (specify units) 4.0044g Total Volume : 100 mL Comments : See user defined fields for details Balance#17 By Anna Knoebel at 7:53 am, Aug 24, 2021 Analyst Signature: PPagagee614 of 618 Table of Contents " "= > > 9 * . $1 + * & + ' &+ , $ -& &' &+ ( / &'' $ + - &, ! ( & ( +/ & -& + $ - +& $ , $ - +& + !$ -&. / &+ , ++ , $ ' $$ / & % , & 0 & '&. , $ + &' 0! 1 $& $, $ & $/ % & "' $ &()"& & ! "" #" ! "" &'(! / $$ ' $$ "' $ #" $ .$ ! $ $% # 2 3444456738 2 3444494776 & 2 45)97<:4)< 2 4::6; 2 344449:55: #& ' (% # "# "# "# "# "# # )' ( * +, - . / 01$ $! 2' 3/ 4 ,! Page 65 of 68 Table of Contents ANALYSIS REAGENTS/STANDARDS 21G2610 Page 66 of 68 Environmental Protection Agency Region 5 Chicago Regional Laboratory 536 South Clark Street, Chicago, IL 60605 Phone:(312)353-8370 Fax:(312)886-2591 Reagent Preparation Bench Sheet Table of Contents Print Date: 7/26/2021 Parameter / SOP #: Toal Phosphorus/ AIG034B ver#7 Reagent: TP- Ascorbic Acid LIMS ID: 21G2610 Chemical Name (Formula) Ascorbic acid (C6H8O6) Prepared by: Nidia Fuentes Preparation Date: Jul-26-21 Expiration Date: $XJ- -2 LIMS ID 21D0503 Mass or Volume (specify units) 6.0377 Acetone ((CH3)2CO) 19J0101 2 mL Total Volume : Comments : balance #17 100 mL Analyst Signature: PPagagee617 of 618 Table of Contents " "= > > 9 * . $1 + * & + ' &+ , $ -& &' &+ ( / &'' $ + - &, ! ( & ( +/ & -& + $ - +& $ , $ - +& + !$ -&. / &+ , ++ , $ ' $$ / & % , & 0 & '&. , $ + &' 0! 1 $& $, $ & $/ % & "' $ &()"& & ! "" #" ! "" &'(! / $$ ' $$ "' $ #" $ .$ ! $ $% # 2 3444456738 2 3444494776 & 2 45)97<:4)< 2 4::6; 2 344449:55: #& ' (% # "# "# "# "# "# # )' ( * +, - . / 01$ $! 2' 3/ 4 ,! Page 68 of 68 Analytical Data Package Prepared by: Pace Analytical Services Pace Project No.: 40229994 Table Of Contents Project Overview Final Report with COC/SCUR 1 Certifications 2 Sample Summary 3 Sample Analyte Count 4 Analytical Results 5 Quality Control Data 9 Qualifiers 10 Quality Control Data Cross Reference Table 11 Chain of Custody 12 SDG Narrative 15 InOrganic Microbiology Analytical Results (Form 1-IN) 16 Blanks (Form 3-IN) 20 Duplicates (Form 6-IN) 22 Microbiological Raw Data 23 Certificate of Analysis 24 #=CL# LIMS USE: FR - CASSIDY OWEN LIMS OBJECT ID: 40229994 July 20, 2021 Pace Analytical Services, LLC 1241 Bellevue Street - Suite 9 Green Bay, WI 54302 (920)469-2436 Cassidy Owen Eastern Research Group, Inc. 14555 Avion Parkway Suite 200 Chantilly, VA 20151 RE: Project: RANOVAEL Pace Project No.: 40229994 Dear Cassidy Owen: Enclosed are the analytical results for sample(s) received by the laboratory on July 15, 2021. The results relate only to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report. The test results provided in this final report were generated by each of the following laboratories within the Pace Network: Pace Analytical Services - Green Bay If you have any questions concerning this report, please feel free to contact me. Sincerely, Steven Mleczko steve.mleczko@pacelabs.com (920)469-2436 Project Manager Enclosures cc: Daniela Ayala, Eastern Research Group, Inc. Jessica Gray, Eastern Research Group, Inc. 40229994 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 1 of 31 Page 1 of 14 #=CP# Project: Pace Project No.: RANOVAEL 40229994 Pace Analytical Services Green Bay 1241 Bellevue Street, Green Bay, WI 54302 Florida/NELAP Certification #: E87948 Illinois Certification #: 200050 Kentucky UST Certification #: 82 Louisiana Certification #: 04168 Minnesota Certification #: 055-999-334 New York Certification #: 12064 North Dakota Certification #: R-150 CERTIFICATIONS Pace Analytical Services, LLC 1241 Bellevue Street - Suite 9 Green Bay, WI 54302 (920)469-2436 Virginia VELAP ID: 460263 South Carolina Certification #: 83006001 Texas Certification #: T104704529-14-1 Wisconsin Certification #: 405132750 Wisconsin DATCP Certification #: 105-444 USDA Soil Permit #: P330-16-00157 Federal Fish & Wildlife Permit #: LE51774A-0 40229994 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 2 of 31 Page 2 of 14 #=SS# Project: Pace Project No.: RANOVAEL 40229994 Lab ID Sample ID 40229994001 40229994002 40229994003 40229994004 OVERFLOW FROM VTA VTA DOWNSTREAM DC UPSTREAM DC SAMPLE SUMMARY Pace Analytical Services, LLC 1241 Bellevue Street - Suite 9 Green Bay, WI 54302 (920)469-2436 Matrix Water Water Water Water Date Collected 07/15/21 11:49 07/15/21 11:52 07/15/21 12:00 07/15/21 12:07 Date Received 07/15/21 14:05 07/15/21 14:05 07/15/21 14:05 07/15/21 14:05 40229994 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 3 of 31 Page 3 of 14 #=SA# Project: Pace Project No.: RANOVAEL 40229994 Lab ID Sample ID 40229994001 40229994002 40229994003 40229994004 OVERFLOW FROM VTA VTA DOWNSTREAM DC UPSTREAM DC PASI-G = Pace Analytical Services - Green Bay SAMPLE ANALYTE COUNT Method SM 9222D SM 9222D SM 9222D SM 9222D Pace Analytical Services, LLC 1241 Bellevue Street - Suite 9 Green Bay, WI 54302 (920)469-2436 Analysts HNT HNT HNT HNT Analytes Reported 1 1 1 1 40229994 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 4 of 31 Page 4 of 14 #=AR# Pace Analytical Services, LLC 1241 Bellevue Street - Suite 9 Green Bay, WI 54302 (920)469-2436 Project: Pace Project No.: RANOVAEL 40229994 Sample: OVERFLOW FROM VTA ANALYTICAL RESULTS Lab ID: 40229994001 Collected: 07/15/21 11:49 Received: 07/15/21 14:05 Matrix: Water Parameters 9222D MICRO Fecal Coli by MF Fecal Coliforms Results Units LOQ LOD DF Prepared Analyzed CAS No. Analytical Method: SM 9222D Preparation Method: SM 9222D Pace Analytical Services - Green Bay 45500 CFU/100 mL 9090 9090 9090 07/15/21 17:05 07/15/21 17:05 Qual Date: 07/20/2021 09:14 AM 40229994 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 5 of 31 Page 5 of 14 #=AR# Pace Analytical Services, LLC 1241 Bellevue Street - Suite 9 Green Bay, WI 54302 (920)469-2436 Project: Pace Project No.: Sample: VTA RANOVAEL 40229994 Parameters 9222D MICRO Fecal Coli by MF Fecal Coliforms ANALYTICAL RESULTS Lab ID: 40229994002 Collected: 07/15/21 11:52 Received: 07/15/21 14:05 Matrix: Water Results Units LOQ LOD DF Prepared Analyzed CAS No. Analytical Method: SM 9222D Preparation Method: SM 9222D Pace Analytical Services - Green Bay 18200 CFU/100 mL 9090 9090 9090 07/15/21 17:05 07/15/21 17:05 Qual Date: 07/20/2021 09:14 AM 40229994 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 6 of 31 Page 6 of 14 #=AR# Pace Analytical Services, LLC 1241 Bellevue Street - Suite 9 Green Bay, WI 54302 (920)469-2436 Project: Pace Project No.: RANOVAEL 40229994 Sample: DOWNSTREAM DC Parameters 9222D MICRO Fecal Coli by MF Fecal Coliforms ANALYTICAL RESULTS Lab ID: 40229994003 Collected: 07/15/21 12:00 Received: 07/15/21 14:05 Matrix: Water Results Units LOQ LOD DF Prepared Analyzed CAS No. Analytical Method: SM 9222D Preparation Method: SM 9222D Pace Analytical Services - Green Bay 173000 CFU/100 mL 9090 9090 9090 07/15/21 17:05 07/15/21 17:05 Qual Date: 07/20/2021 09:14 AM 40229994 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 7 of 31 Page 7 of 14 #=AR# Pace Analytical Services, LLC 1241 Bellevue Street - Suite 9 Green Bay, WI 54302 (920)469-2436 Project: Pace Project No.: RANOVAEL 40229994 Sample: UPSTREAM DC Parameters 9222D MICRO Fecal Coli by MF Fecal Coliforms ANALYTICAL RESULTS Lab ID: 40229994004 Collected: 07/15/21 12:07 Received: 07/15/21 14:05 Matrix: Water Results Units LOQ LOD DF Prepared Analyzed CAS No. Analytical Method: SM 9222D Preparation Method: SM 9222D Pace Analytical Services - Green Bay 155000 CFU/100 mL 9090 9090 9090 07/15/21 17:05 07/15/21 17:05 Qual Date: 07/20/2021 09:14 AM 40229994 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 8 of 31 Page 8 of 14 #=QC# Pace Analytical Services, LLC 1241 Bellevue Street - Suite 9 Green Bay, WI 54302 (920)469-2436 QUALITY CONTROL DATA Project: Pace Project No.: RANOVAEL 40229994 QC Batch: 390759 Analysis Method: SM 9222D QC Batch Method: SM 9222D Analysis Description: 9222D MICRO Fecal Coliform by MF Laboratory: Pace Analytical Services - Green Bay Associated Lab Samples: 40229994001, 40229994002, 40229994003, 40229994004 METHOD BLANK: 2252085 Matrix: Water Associated Lab Samples: 40229994001, 40229994002, 40229994003, 40229994004 Parameter Units Blank Result Reporting Limit Fecal Coliforms CFU/100 mL <1.00 1.0 Analyzed 07/15/21 17:05 Qualifiers METHOD BLANK: 2252087 Matrix: Water Associated Lab Samples: 40229994001, 40229994002, 40229994003, 40229994004 Parameter Units Blank Result Reporting Limit Fecal Coliforms CFU/100 mL <1.00 1.0 Analyzed 07/15/21 17:05 Qualifiers SAMPLE DUPLICATE: 2252086 Parameter Fecal Coliforms Units CFU/100 mL 40229964003 Result 10 Dup Result 12 RPD Max RPD Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Date: 07/20/2021 09:14 AM 40229994 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 9 of 31 Page 9 of 14 #=QL# Pace Analytical Services, LLC 1241 Bellevue Street - Suite 9 Green Bay, WI 54302 (920)469-2436 QUALIFIERS Project: Pace Project No.: RANOVAEL 40229994 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above LOD. J - Estimated concentration at or above the LOD and below the LOQ. LOD - Limit of Detection adjusted for dilution factor, percent moisture, initial weight and final volume. LOQ - Limit of Quantitation adjusted for dilution factor, percent moisture, initial weight and final volume. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean-Up U - Indicates the compound was analyzed for, but not detected at or above the adjusted LOD. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. Date: 07/20/2021 09:14 AM 40229994 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 10 of 31 Page 10 of 14 #=CR# Pace Analytical Services, LLC 1241 Bellevue Street - Suite 9 Green Bay, WI 54302 (920)469-2436 Project: Pace Project No.: RANOVAEL 40229994 QUALITY CONTROL DATA CROSS REFERENCE TABLE Lab ID 40229994001 40229994002 40229994003 40229994004 Sample ID OVERFLOW FROM VTA VTA DOWNSTREAM DC UPSTREAM DC QC Batch Method SM 9222D SM 9222D SM 9222D SM 9222D QC Batch 390521 390521 390521 390521 Analytical Method SM 9222D SM 9222D SM 9222D SM 9222D Analytical Batch 390759 390759 390759 390759 Date: 07/20/2021 09:14 AM 40229994 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 11 of 31 Page 11 of 14 40229994 12 of 31 Page 12 of 14 40229994 13 of 31 Page 13 of 14 40229994 14 of 31 Page 14 of 14 CASE NARRATIVE - GENERAL CHEMISTRY ANALYSIS Lab Report Number (SDG): 40229994 Client: EASTERN RESEARCH GROUP, INC. Project Name: RANOVAEL Project Number: 02BA2021 1. RECEIPT Samples were received on ice at 2.5C. 2. HOLDING TIMES A. Sample Preparation: All method specified holding times were met. B. Sample Analysis: All method specified holding times were met. 3. METHOD Preparation: Not Applicable Analysis: SM 9222D 4. PREPARATION Sample preparation proceeded normally. 5. ANALYSIS A. B. C. D. E. F. Calibration: 1. Positive Control (BOD Seed Check): The method acceptance criteria were met. (TNTC = Too numerous to count.) Blanks: 1. Negative Control (Sterility Blank): The method acceptance criteria were met. 2. Method: Not applicable to this SDG. Sample Duplicates: A batch duplicate sample was analyzed with this SDG. The in- house precision criteria were met. Samples: Sample analyses proceeded normally. Reanalysis: None required for this SDG. Comments: No additional comments are needed. I certify that this data package is in compliance, with the terms and conditions agreed to by Pace Analytical Services, LLC, and by the client, both technically and for completeness, except for the conditions detailed above. The Laboratory Manager or his designee, as verified by the following signature, has authorized release of the data contained in this hard copy data package: Signed: Name: Leigh A. Begalske Date: 07/20/21 Position: Quality Assurance Auditor 40229994 15 of 31 FORM I INORGANIC-1 INORGANIC ANALYSIS DATA SHEET SAMPLE NO. OVERFLOW FROM VTA Lab Name: Pace Analytical - Green Bay Lab Sample ID: 40229994001 SDG No. : 40229994 Contract: RANOVAEL Percent Moisture: CAS No. Analyte Fecal Coliforms Concentration Q Units DF Analysis Date/Time 45500 CFU/100 9090 07/15/2021 17:05 07/20/2021 11:30 40229994 16 of 31 FORM I INORGANIC-1 INORGANIC ANALYSIS DATA SHEET SAMPLE NO. VTA Lab Name: Pace Analytical - Green Bay Lab Sample ID: 40229994002 SDG No. : 40229994 Contract: RANOVAEL Percent Moisture: CAS No. Analyte Fecal Coliforms Concentration Q Units DF Analysis Date/Time 18200 CFU/100 9090 07/15/2021 17:05 07/20/2021 11:30 40229994 17 of 31 FORM I INORGANIC-1 INORGANIC ANALYSIS DATA SHEET SAMPLE NO. DOWNSTREAM DC Lab Name: Pace Analytical - Green Bay Lab Sample ID: 40229994003 SDG No. : 40229994 Contract: RANOVAEL Percent Moisture: CAS No. Analyte Fecal Coliforms Concentration Q Units DF Analysis Date/Time 173000 CFU/100 9090 07/15/2021 17:05 07/20/2021 11:30 40229994 18 of 31 FORM I INORGANIC-1 INORGANIC ANALYSIS DATA SHEET SAMPLE NO. UPSTREAM DC Lab Name: Pace Analytical - Green Bay Lab Sample ID: 40229994004 SDG No. : 40229994 Contract: RANOVAEL Percent Moisture: CAS No. Analyte Fecal Coliforms Concentration Q Units DF Analysis Date/Time 155000 CFU/100 9090 07/15/2021 17:05 07/20/2021 11:30 40229994 19 of 31 FORM III INORGANIC-1 BLANKS Lab Name: Pace Analytical - Green Bay SDG No. : 40229994 Contract : RANOVAEL Method Blank Matrix: Water Instrument ID: 40INCA Method Blank Concentration Units: CFU/100 mL Analyte Initial Calibration Blank Continuing Calibration Blank C C C Fecal Coliforms Method Blank C 2252085 C <1.0 U 07/20/2021 11:30 40229994 20 of 31 FORM III INORGANIC-2 BLANKS Lab Name: Pace Analytical - Green Bay SDG No. : 40229994 Contract : RANOVAEL Method Blank Matrix: Water Instrument ID: 40INCA Method Blank Concentration Units: CFU/100 mL Analyte Initial Calibration Blank Continuing Calibration Blank C C C Fecal Coliforms Method Blank C 2252087 C <1.0 U 07/20/2021 11:30 40229994 21 of 31 40229994 22 of 31 40229994 23 of 31 40229994 24 of 31 40229994 25 of 31 40229994 26 of 31 40229994 27 of 31 40229994 28 of 31 40229994 29 of 31 40229994 30 of 31 40229994 31 of 31