Document 1y5ozBJ9YyOwNE2bRx9mB7Z6a

STLS E V E R N TRENT STL Chicago 2 4 1 7 Bond Street University Park, IL 6 0 4 66 Tel: 70 534 5200 Fax; 708 534 5211 www.stl-inc.com SEVERN TRENT LABORATORIES ANALYTICAL ..JOB N U M B E R : 2 3 3 5 0 6 W e e t o n S o 111tiiono ;y;;;ilRt.;;;ii;: 1 4 W e s t o n Way i'ii':ii;liBu;lIding:i 5-2 .West C h e s t e r , P A 19 38 C -1 49 9 P r o j.C t :'' C o n f i d e n t i a l D e c a t u r - F C Irive a c ig a t i Oil AJ_ Le n L i o n ; J a i K e s a r i na.teT.;;;hL/:R6;/RL0.5'.' Signt N a m e : R i c h a r t f C. Wright. Title : Proj ect Manager E M a i l : r w r i g h t O s t l - i n e .c o m This Report Contains Leaders in Environmental Testing Date STL Chicago 2417 Bond Street U n i v e r s i t y Park, IL 60466' PHONE: (708) 5 3 4 -5 2 00 FAX. . : (708) 534-52].]. Pa ge s Severn Trent Laboratories, Ino. WET CHEMISTRY DATA PACKAGE CONFIDENTIAL DECATUR - FC INVESTIGATION JOB# 233506 Data Summary............................................................... 1 Chain of Custody......................................................... 27 Case Narrative............................................................. 33 Raw D ata......................................................................35 STL Chicago is part of Bevern Trent Laboratories, Inc. /S:' A '.P/LLE:' I N F O R K A T 0 N Date: 01/26/2005 Job Number.: 233506 Customer...: Weston Solutions, Inc. Attn...... : Jai Kessri Project Number......... 20004891 Customer Project ID--- CONFIDENTIAL DECATUR Project Description--- Confidential Decatur - FC Investigation Laboratory Sample ID 233506-1 233506-2 233506-3 233506-4 233506-5 233506-6 233506-7 233506-8 233506-9 233506-10 233506-11 233506-12 233506-13 233506-14 233506-15 233506-16 233506-17 233506-18 233506-19 Customer Sample ID DLOl-SB-220R-0-0000 DLOI-SB-220R-0-0005 DLQI-SB-220R-0-0020 DL0I-SB-220R-0-0050 DLOl-SB-220R-0-0170 DLOI-SB-220L-0-0000 DLOl-SB-220L-0-0005 DLOl-SB-220L-0-0020 DLDI-SB-220L-0-0050 DLOl-SB-220L-0-0070 DBKG-SB-OOIB-O-OOOO DBKG-SB-O1B-0-005 DBKG-SB-001B-0-0010 DBKG-SB-001B-0-0020 DBKG-SB-001E-0-0050 DBKG-SB-001B-0-0230 DBKG-SBC-001B'0-0000 DBKG^SBC-0018-0-0050 DBKG-SBC-001B-0-0100 5m./pYi,/. Soil Soil soi l Sol 1 Soi 1 Soil Soit Soi 1 Soil Soil Soi 1 soi 1 Soil Soi L soi t soi L Soi L Soil Soi L .Date.."...: sampled 01/11/2005 01/11/2005 01/11/2005 01/11/2005 01/11/2005 01/11/2005 01/11/2005 01/11/2005 01/11/2005 01/11/2005 01/12/2005 01/12/2005 01/12/2005 01/12/2005 01/12/2005 01/12/2005 01/12/2005 01/12/2005 01/12/2005 Time .Sampled 12:15 12:25 13:45 13:50 14:45 12:45 13:00 15:15 15:25 15:40 10:10 10:15 10:20 10:30 10:50 12:35 10:55 11:15 11:35 .Date Time Received ; Received 01/15/2005 09:00 01/15/2005 09:00 01/15/2005 09:00 01/15/2005 09:00 01/15/2005 09:00 01/15/2005 09:00 01/15/2005 09:00 01/15/2005 09:00 01/15/2005 09:00 01/15/2005 09:00 01/15/2005 09:00 01/15/2005 09:00 01/15/2005 09:00 01/15/2005 09:00 01/15/2005 09:00 01/15/2005 09:00 01/15/2005 09:00 01/15/2005 09:00 01/15/2005 09:00 STL Chicago Page 1 1 STL Chicago is pari of Severn Treni Laboratories, Ine. Job Ntmber: 233506 CUSTOMER: Wes ton So lut ions r Inc. Customer Sample ID: DLOI-SE-220R-0-Q0Q0 Date Sampled..... : 01/11/2005 Tiroe Sampled..... : 12:15 Sample Matrix.... : Soil TEST METHOD Lloyd Kahn PARAMETER/TEST DESCRIPTION Total Organic Carbon (Soils) TOC Average Duplicates, Solid ! LABORATORY TEST RESULTS !PROJECT: CONFIDENTIAL DECATUR Laboratory Sample ID: 233506-1 Date Received..___ : 01/15/2005 Time Received...... : 09:00 Date:01/26/2005 ATTN: Jai Kesari SAMPLE RESULT '' QjFLAGS ' 24000 mi 870 . . RL 3400 DILUTION- : .UNITS. ! &ATCH DT DATE/TIHE TECH L: . t mg/Kg t140117 01/19/05 2341 rnm i I 1r ! j { . i i1 i ; . i1 i f STL Chicago is part of Severn Trent Laboratories, Inc. Job Number: 2335D6 CUSTOMER:. Weston Solutions, Inc. Custemer Sample [0 Date Sampled..... Time S a n p le d .......... Sample Matrix.... DLOI-SB-22R-Q-0005 01/11/2005 12:25 Sol l TEST METHOD :p a r a m e Te r /Test :d e s c r i p t ion Lloyd Kahn jTotaL Organic Carbon (Soils) TOC Average Duplicates, Solid P LABOHKJH TEST RESULTS PROJECT: CONFIDENTIAL DECATUR Laboratory Sample ID: 233506-2 Date Received.......: 01/15/2005 Time Received...... : 09:00 Date:01/26/2005 ATTN: Jai Kesari SAMPLE RESULT 5300 FLAGS MGL 1S0 RL DILOTIpW UH ITS: BATCH: DT d a t e /time TECH 700 mg/Kg i140t!7 01/19/05 2352 T l .riiiicaon * In Description = Dry Ugt. Page 3 STL Chicago is part of Severn Trent Laboratories, Inc. Job Nwfcer: 233506 LABORATORY TEST RESULT S Date:01/26/2005 CUSTOMER; Weston Solutions , Inc. ; PROJE'CTCOHF!DENTtAL DECATUR ATTN: Jai Kesari Customer Sample ID: LOI-S&-220R-0-002Q Date Sampled..... : 01/11/2005 T ime Sampled..... : 13:45 Sample Matrix.... : Soi l j i TEST HETHCO ; ;;::PARAMETER/TEST DESCRIPT JON . . Lloyd Kahn Total Organic Carbon (Soils) TOC Average Duplicates, Solid . Laboratory Sample ED 233506-3 Date Received...... 01/15/2005 Time Received...... 09:00 i SAMPLE RESULT.- 3 FLAGS : 5000 MDL 320 R.L 1200 DILUTION,; UNITS [ mg/Kg 1 1! \ BATCH DT DATE/T1ME TECH: 140127 i 01/21/05 1737 rnm i j ; H i * In Description = Dry Wgt. Page 4 _______________ 1 STL Chicago STL Chicago is part of Severn Trent Laboratories, tnc. Job Number: 233506 ryjnt-h>'4 "Wlb!vli uylijLILHlb1^ li-rLi Customer Sample [D: DLOI-SB-220R-0*0050 Date Sampled..... : 01/11/2005 Time Sampled..... : 13:50 Sample Matrix.... : Soi l TEST METHOD Lloyd Kahn . PARAMETER/TEST DESCRIPTION Total Organic Carbon [Sails) TOC Average Duplicates, Solid V) LABORATORY TEST RESULTS D&rvitr-T . rnwcrnrux iai n m n i p ::::::: Laboratory Sample ID: 233506-4 Date Received...... : 01/15/2005 Time Received...... : 09:00 Date:01/26/2005 'i-TTif 'Yaeri ' SAHPLE RESULT' Q FLAGS 1100 . .MOL 200 RL DILUTION UNITS BATCH DT DATE/TIME jrECH 780 1 mg/Kg 140127 01/21/05 1307 rrun ' | * In Description = Dry Wgt. Page 5 TL Chicago STL Chicago is part of Severn Trent Laboratories, ]nc. Job Number: 233506 CUSTOHEfi: Weston S l u t i arts, -ine* Customer Sample ID: DLOI'$B-220R-0-0170 Date Sampled..... : 01 f\ 1/2005 Time Sampled..... : 14:45 [ Sample Matrix.... : Soil : TEST METHOD Lloyd Kahn PARAMETER/TEST DESCRIPTION ' Total Organic Carbon (Soils) TOC Average Duplicates, Solid LABORATORY TEST RESULTS PROJECT CONFIDENTSAL DECATUR : Laboratory Sample ID: 233506-5 Date Received........ :01/15/2005 Time Received,....... :09:00 Date:01/26/2005 ATTN: Jai (Cesari SAMPLE RESULT q FL.ACS 600 K*L - 100 RL DILUTION UNITS BATCH [dt DATE/TIME TECH: 400 \ (ng/Kg 140127 01/21/05 1813 rnm * In Description = Dry Wgt. Page 6 i i | STL Chicago STL Chicago is part of Severn Trent Laboratories, Inc. Job Number: 233506 CUSTOMER: Weston Solutions , Inc. Customer Sample ID: BLOI-SB-220L-0-Q000 Date Sampled...... :01/11/2005 Time Sampled...... :12:45 Sample Matrix..... :Soi* TEST METHG0 Lloyd Kahn PARAMETER/TEST. DES CR JPTIOK Total Organic Carbon (Soils) TOC Average Duplicates, Solid r~ LABORATORY TEST RESULTS PROJECT: DQKFtOEWTIAL DECATUR. Laboratory Sariple ID 233506-6 Date Received...... 01/15/2005 Time Received...... 09:00 Date:01/26/2005 ATTN: Jai Kesari SAMPLE RESULT 27000 FLAGS1 :MDL: 750 RL 2900 DILUTION; UNITS BATCH TOT. :DATE/TtKE: :lTECH mg/Kg =140127 101/21/05 1713 Chicago * In Description = Dry Wgt. Page 7 -I H STL Chicago is part oi Severn Trent Laboratories, Inc. Job Number: 233506 CUSTOMER: Weston :Solutions, Jnc. Customer Sample ID: DLOI-5B-22QL-0-0G05 Date Sampled...... :01/11/2005 Time Sampled...... :13:00 Sample Matrix..... :Soil TEST METHOD Lloyd Kahn PARAMETER/TEST DESCRIPTION ; Total Organic Carbon (Soils) TOC Average Duplicates, Solid QO LABORATORY TEST RESULTS . PROJECT: CONf]DENTIAL DECATUR Laboratory Sample ID: 233506-7 Date Received.... 01/15/2005 Time Received...... : 09:00 Date:01/26/2005 ATTN: Jai Kesari ? SAMPLE r e s u l t - flags 4600 MDL 130 RL DILUTION UNITS BATCH BT DATE/TIME TECH; 510 mg/Kg 140127 01/21/05 1829 STL Chicago * In Description - Dry Ugt. Page fl STL Chicago s part of Severn Trent Laboratories, Ino. Job Hunger: 233506 CUSTCWER: Weston Solutions, Jnc. Customer Sample ID:DLOI-SB-220L-0-0020 Date Sampled...... :01/11/2005 Time Sampled...... :15:15 Sample Matrix..... :Soil TEST-METHOD: .. PARAMETER/TEST .DESCRIPTION Lloyd Kahn Total Organic Carbon (Soils) TOC Average Duplicates, Solid ff\ LABORATORI TEST RESULTS PROJECT: CONFIDENTIAL DECATUR Laboratory Sample ID: 233506-3 Date Received...... : O1/15/2D05 Time Received.......: 09:00 Date:01/26/2005 ATN: Jai Kesari SAMPLE RESULT FLAGS 1800 ; 92 ] RL D-UJT.KM : UNITS BATCH :DT DATE/TIME TECH 360 1 mg/Kg 140127 01/21/05 1843 rnm : * ]n Description = Dry Ugt. Page 9 STL Chicago STL Chicago is part o+ Severn Treni Laboratories, Ine. Job Hunger: 233506 CUSTOMER; Weston Solutions, Inc. Customer Sample ED [>ate Sarrpled..... Time Sampled..... SarrpLe Matrix.... DIOI-SB~220L-0-0050 01/11/2GD5 15:25 Soi l TEST METHOC Lloyd Kahn PARAMETER/TEST ;DESCR1PTION; Total Organic Carbon (Soils) TOC Average Duplicates, Solid LABORATORY TEST RESULTS PROJECT : CONFIDENTIAL- DECATUR ' Laboratory Sample IE) 233506-9 Date Received...... 01/15/2005 Time Received...... 09:00 Date-.31/20/2005 AtTN: Jai Kesari SAMPLE RESULT 1900 FLAGS MDL 91 RL D ELUTIOk UK1TS BATCH BT d a t e /time TECH 350 mg/Kg 140127 01/21/05 1853 rnm STL Chicago * In Description = Dry Wgt. Page 10 STL Chicago is part of Severn Trent Laboratories, Irte. Job Number: 233506 CUSTOMER: Weston Solutions, inc. Customer Sample ID: DLOI-SB-220L-0-0070 Date Sampled..... : 0-1/11/2005 Time Sampled..... : 15:40 Sample Matrix.... ; Soil TEST METHOD Lloyd Kahn PARAMETER/TEST DESCRIPTION Total Organic Carbon [Soils) TOC Average Duplicates, Solid . LABORATORY TEST RESULTS . PROJECT: CONFIDENTIAL DECATUR Laboratory Sample ID: 233506-10 Date Received...... : 01/15/2005 Time Received...... : 09:00 Date:01/26/2D05 ATTN: Jai Kesari > SAMPLE RESULT [ | 1100 FLAGS;: MDL 76 RL DILUTION UNITS BATCH DT DATE/TIME TECH - 300 1 mg/Kg 140127 01/21/05 1909 rnm j L j | t r 1 j ; * In Description = Dry Wgt. i ! Page 11 i! STL Chicago STL Chicago is part of Severn Trent Laboratories, Inc. \ Job Number: 233506 ! CUSTOMER: Weston Solutions, Enc. 1----------------------- ----------------------- -- Customer Sample ID ate Sampled..... Tiine S am pled.......... Sample Matrix.... DBKG-SE-OOIB-O'OGGG 01/12/2005 10:10 Soi L TEST METHOD :PARAHETER/TEST :DES CPEPTION Lloyd Kahn Total Organic Carbon (Soils) TOC Average Duplicates, Solid 4 LABORATORY TEST RESULTS ' PROJECT: CONFIDENTIAL DEiATUR Laboratory Sample ID 233506-11 Date Received...... 01/15/2005 Time Received...... 09:00 Date:01/26/2DD5 ATTN:' J'ai Kesan SAMPLE RESULT 25QQO FLAGS MOL 640 RL 2500 DILUTION UNITS BATCH DT DATE/TJME TECH mg/Kg U D 27 01/21/05 1920 * En Description = Dry Wgt. Page 12 CTT nui. STL Chicago is part oi Severn Trent Laboratories, Inc. Job Number: 233506 CUSTOMER: Weston Solutions, Enc. Customer Sample SO: DBKG-SB-D01B-0-0005 Date Sampled...... :01/12/2005 Time Sampled...... :10:15 Sample Katrik ..... :Soil TEST METHOD .. Lloyd Kahn : PARAMETER/TEST DESCRIPTION Total Organic Carbon [SoiLsJ TOC Average Duplicates, Solid m LABORATORY TEST RESULTS PROJECT; CONFIDENTIAL DECATUR ' Laboratory Sample ID: 233506-12 Date Received........ :01/15/2005 Time Received........ :09:00 Date:01/26/2005 . ATTN: Jai Kesari SAMPLE RESULT 0 FLAGS;; 11000 MOL 460 RL DILUTION i: UH ITS BATCH DT : 'DATE/TIME : TECH 1800 1 eng/Kg 140127 01/21/05 1952 rnm Chicago * In Description = Dry Ugt. Page 13 H STL Chicago is part of Severn Trent Laboratories, Inc. Job Number: 233506 CUSTOMER: Weston Solutions, Inc. Customer Sample ID: DBCG-SB-OO1B-0-OO1C Date Sampled...... :01/12/2005 Time Sampled...... :10:20 Sample Matrix..... :Soil TEST METHOD :PARAMETER/EST pESCSIPTiOft Lloyd Kahn Total Organic Carbon [Soils) jTOC Average Duplicates, Solid LABORATORY TEST RESULTS PROJECT: CONFIDENTIAL DECATUR ' Laboratory Sample ID 233506-13 Date Received...... 01/15/2005 Time Received...... 09:00 Date:01/26/2005 ATTH: Jai Kesari SAMPLE RESULT 2500 FLAGS MDL: 93 RL DILUTION; UNITS BATCH DT DATE/TIME TECH 360 mg/Kg 1140127 01/21/05 2007jrnm STL Chicago In Description = Dry Ugt. Page 14 STL Chicago is part of Severn Trent Laboratories, Inc. Job Number: 233506 CUSTOMER: Weston Solutions, Inc. Customer Sample ID Date Sampled..... Time Sampled..... Sample Matrix.... DB KG-SB- 001B-0-0020 01/12/2005 10:30 Sa iL TEST METHOD :PARANE TER/TE ST:D ESCRIPTION Lloyd Kahn Total Organic Carbon (Soils} 'TOC Average Duplicates, Solid LABORATORY TEST RESULTS PROJECT : CONFIDENTIAL DECATUR Laboratory Sample ID: 233506-14 Date deceived...... : 01/15/2Q05 7ime fiecei ved...... : 09:00 Date:01/26/2005 ATTN: Jai Kesari SAMPLE RESULT 2100 FLA& HEL 100 RL DILUTION UNITS :BATCH: DT: DATE/TIME TECH 400 mg/Kg 140127 01/21/05 2021 n Description = Dry Ugt. Page 15 STL Chicago is part of Severn Trent Laboratories, Inc. Job Ntmnber: 233506 CUSTOMER: VJeston Solutions, Inc. Customer Sample ID: DBKG-SB-001B-0-0050 Date Sampled..... : Q1/12/2005 Time Sampled..... : 10:50 Sample Matrix.... : Soil LABORATORY TEST RESULTS . .PROJECT: CONTDtJTjAL DECATUR- Laboratory Sample ID: 233506-15 Date Received....... : 01/15/2005 Time Received...... : 09:00 Date:01/26/2005 ATW: Jai Kesari 'O i STL Chicago * In Description = Dry Wgt. Page 16 STL Chicago is part of Severn Trent Laboratories, Enc. Job Number: 233506 ; CUSTOMER: Weston Solutions , Inc. Customer Sample ID: DBKG-5B-QQ1B-0-0230 Date Sampled...... :01/12/2005 Time Sampled...... :12:35 Sample Matrix..... :Soi l LABORATORT TEST RESULTS ' PROJECT: CONFIDENTIAL DECATUR Laboratory SarapLe 30: 233506*16 Date Received........:01/15/2005 Time Received........:09:00 Date:01/26/2005 ATTN: Jai Kesari t- ucago JC U ri tn STL Chicago is part of Severn Trent Laboratories, Inc. Jab Mrber: 233506 CUSTOMER: Weston Solutions , Inc. Customer Sample ID: OBKG-SEC-001B-0-DOO Date Sampled..T...: Dl/I2/2005 Time Sampled..... : 10:55 Sample Matrix.... : Soil t e s t ;m e t h o d ;: PARANE TER/TEST =.DES CR I PT IOH Lloyd Itahn Total Organic Carbon (Soils} TOC Average Duplicates, Solid LABORATORY TEST R ESU LTS PROJECT: CONFIDENTIAL DECATUR : Laboratory Sample ID: 233506-17 Pate Received...... : 01/15/2005 Time Received...... : 09:00 Date:D1/26/2005 :;:. ATTN: Jai;Kesari SAMPLE 'RESULT 5700 FLAGS .mi 200 RE.. DILUTION WILTS .BATCH DT DATE/TIME :TECH 790 ing/Kg 140127 01/21/05 2057 * In Description = Ory Ugt. Page 1B I STL Chicago is pari of Severn Trent Laboratories, Ine. STL Chicago * In Description = Dry Wgt. Page 19 STL Chicago is part of Severn Treni Laboratories, Ine. Job Nunte r: 233506 CUSTOMER: Weston Solutions , Inc. . Customer Sample ID: DBKG-SBC-OOlB--OI00 Date Sampled...... :01/12/2005 Time Sampled...... :11 ;35 Sample Matrix..... :Soil TEST METHOD PARAMETER/TE$7 DESCRIPT10M Lloyd Kahn ^Total Organic Carbon (Soils) TOC Average Duplicates, Solid LABORATORY TEST RESULTS PROJECT: CONFIDENTIAL DECATUR Laboratory Sample ID 233506-19 Date Received...... 01/15/2005 Time Received...... 09:00 Date:01/26/2005 ATTN: Jai Kesari SAMPLE' RESULT 780 FLAGS HDL 110 R L DILUTION .UNITS BATCH CT DATE/TIME TECH 410 11 mg/Kg 140127 01/21/05 2120 * In Description = dry Ugt. Page 20 STL Chicago is part of Severn Trent Laboratories, Inc. Job Number: 233506 LABORATORY CHRONICLE Date: 01/26/2005 ;CUSTOMER : Wes ton Solut ions 'fvi nc. Lab ID: 233506-1 METHOD EDD PKG INO (WC> Lloyd Kahn Client ID; DLQI-SB-220R-0-00 DESCRIPTION Electronic Data Deliverable PKG INO (WET CHEMISTRY) Total organic Carbon (Soils) Lab ID: 233506-2 Client ID: DLOI-SB-220R--0005 METHOD DESCRIPTION Lloyd Kahn Total Organic Carbon (Soils) Lab ID: 233506-3 Client ID: DLOI-SB-220R-0-0020 METHOD DESCRIPTION LLoyd Kahn Total Organic Carbon (Soils) Lab ID: 233506-4 Client ID: DL01-SB-22QR-Q-005Q METHOD DESCRIPTION Lloyd Kahn Total Organic Carbon (Soils) Lab ID: 233506-5 Client ID: DLOI-SB-220R-0-0170 METHOD DESCRIPTION LLoyd Kahn Total Organic Carbon (Soils) Lab ID: 233506-6 Client ID: DLOI-SB-22QL-0-DD00 METHOD DESCRIPTION Lloyd Kahn Total organic Carbon (Soils) Lab ID: 233506-7 Client ID: DLOI-SB-220L-0-005 METHOD DESCRIPTION Lloyd Kahn Total Organic Carbon (Soils) Lab ID: 233506-8 Client ID: DLOI-SB-22L-0-0020 METHOD DESCRIPTION Lloyd Kahn Total Organic Carbon (Soils) Lab ID: 233506-9 client ID: DLOI-SB-220L-0-0050 METHOD DESCRIPTION Lloyd Kahn Total Organic Carbon (Soils) Lab ID: 233506-10 Client ID: DLOI-SB-220L-0-0070 METHOD DESCRIPTION Lloyd Kahn Total Organic Carbon (soils) Lab ID: 233506-11 Client ID: DBKG-5B-OO1B-0-0QOO METHOD DESCRIPTION LLoyd Kahn Total Organic Carbon (Soils) Lab ID: 233506-12 Client ID: DBKG-SB-001B-0-0005 METHOD DESCRIPTION Lloyd Kahn Total Organic Carbon (Soils) Lab ID: 233506-13 Client ID; DBKG-SB-Q1B-0-0010 METHOD DESCRIPTION LLoyd Kahn Total Organic Carbon (Soils) Lab ID; 233506-14 client ID: DBKG-SB-001B-0-0020 METHOD DESCRIPTION Lloyd Kahn Total Organic Carbon (Soils) PROJECT: CONFIDENTIAL DECATUR . ATTN: Jai Kesari Date Recvd: 01/15/2005 Sample Date: Q1/11/2DQ5 RUN# BATCH# PREP BT #<S) DATE/TIME ANALYZED 1 1 1 140117 140117 01/19/2005 2341 DILUTION Date Recvd: 01/15/2005 Sample Date: 01/11/2005 RUN# BATCH# PREP BT #(S) DATE/TIME ANALYZED 1 140117 140117 01/19/2005 2352 DILUTION Date Recvd: 01/15/2005 Sample Date: 01/11/2005 RUN# BATCH# PREP BT #<S) DATE/TIME ANALYZED 1 140127 140127 01/21/2005 1737 DILUTION Date Recvd: 01/15/2005 Sample Date: 01/11/2005 RUN# BATCH# PREP BT #(S) DATE/TIME ANALYZED 1 140127 140127 01/21/2005 1807 DILUTION Date Recvd: 01/15/2005 Sample Date: 01/11/2005 RUN# BATCH# PREP BT #(S) DATE/TIME ANALYZED 1 140127 140127 01/21/2005 1818 DILUTION Date Recvd; 01/15/2005 Sample Date: 01/11/2005 RUN# BATCH# PREP BT #(S) DATE/TIME ANALYZED 1 140127 140127 01/21/2005 1713 DILUTION Date Recvd: 01/15/2005 Sample Date: 01/11/2005 RUN# BATCH# PREP BT #(S) DATE/TIME ANALYZED 1 140127 140127 01/21/2005 1829 DILUTION Date Recvd: 01/15/2005 Sample Date: 01/11/2005 RUN# BATCH# PREP BT #<S) DATE/TIME ANALYZED 1 140127 140127 01/21/2005 1843 DILUTION Date Recvd: 01/15/2005 Sample Date: 01/11/2005 RUN# BATCH# PREP BT #(5) DATE/TIME ANALYZED 1 140127 140127 01/21/2005 1858 DILUTION Date Recvd: 01/15/2005 SarnpLe Date: 01/11/2005 RUN# BATCH# PREP BT #<S) DATE/TIME ANALYZED 1 140127 140127 01/21/2005 1909 DILUTION Date Recvd: 01/15/2005 Sample Date: 01/12/2005 RUN# BATCH# PREP BT #(S) DATE/TIME ANALYZED 1 140127 140127 01/21/2005 1920 DILUTION Date Recvd: 01/15/2005 Sample Date: 01/12/2005 RUN# BATCH# PREP BT #(S) DATE/TIME ANALYZED 1 140127 140127 01/21/2005 1952 DILUTION Date Recvd; 01/15/2005 Sample Date: 01/12/2005 RUN# BATCH# PREP BT #(S) DATE/TIMEANALDYIZLEUDTION 1 140127 140127 01/21/2005 2007 Date Recvd: 01/15/2005 Sample Date: 01/12/2005 RUN# BATCH# PREP BT #(> DATE/TIMEANALDYIZLEUDTION 1 140127 140127 01/21/2005 2021 STL Chicago Page 21 21 STL Chicago is part of Severn Trent Laboratories, Inc, Job Number: 233506 LAB0RAOR C H R O N I CL Date: 01/26/2005 CUSTOMER :VWeston Solutions,.Inc ::! PROJECT :CONFIDENTIAL DECATUR ."\.V ATTN: Jai Kesari Lab ID: 233506-15 Client ID: DBKG-SB-QOlB-0'0050 METHOD DESCRIPTION Lloyd Kahn Total Drganic Carbon (Soils) Lab ID: 233506-16 Client ID: DBKG-SB-001B-0-0230 METHOD DESCRIPTION Lloyd Kahn Total Organic Carbon (SoiLs) Lab ID: 233506-17 Client ID: DBKG-SBC-OOlB-O-OOOQ METHOD DESCRIPTION Lloyd Kahn Total Organic Carbon (Soils) Lab ID: 233506-1S Client ID: DBKG-SBC-001B-0-0050 METHOD DESCRIPTION Lloyd Kahn Total Organic Carbon (Soils) Lab ID: 233506-19 Client ID: DBKG-SBC-001B-0-01QO METHOD DESCRIPTION Lloyd Kahn Total Organic Carbon (Soi Is) Date Recvd: 01/15/2005 Sample Date: 01/12/2005 RUN# BATCH# PREP BT #(S) DATE/TIME ANALYZED DILUTION 1 140127 140127 01/21/2005 2033 Date Recvd: 01/15/2005 Sample Date: 01/12/2005 RUN# BATCH# PREP ST #(S) DATE/TIME ANALYZED DILUTION 1 140127 140127 01/21/2005 2045 Date Recvd: 01/15/2005 Sample Date: 01/12/2005 RUN# BATCH# PREP BT #<S) DATE/TIME ANALYZED DILUTION 1 140127 140127 01/21/2005 2057 Date Recvd: 01/15/2005 Sample Date: 01/12/2005 RUN# BATCH# PREP BT #(S) DATE/TIME ANALYZED DILUTION 1 140127 140127 01/21/2005 2107 Date Recvd: 01/15/2005 Sample Date: 01/12/2005 RUN# BATCH# PREP BT #(5) DATE/TIME ANALYZED DILUTION 1 140127 140127 01/21/2005 2120 STL Chicago Page 22 77 Job Number.: 233506 COSTOMER : tystorv Soluti ons v'ine;:.: QUALITY CONTROL RESULTS '.PROJECT : ;CON FIDENT1L DECATUR Report Date,: 01/28/2005 AT-TN-: 'je.T.Kesri' = Test Method-. ^ ,... ! Lloyd Kahn .. Method :b^t^iptbn.: Total Phanie: 2arbiv<$iy) /parameter,., F___ prgiahic Carbon .'Tot: (TOC) - `Batch,...Viyi :::c,;;i4.0H7.-. - Equi pment Coda T0C4; :;:; .';:.Analyst ,:-t:rotti . . Test Ctidifc : !TOC .; ; QC Lab ID Reagent Unita CCV 140117-016 I04LSTTC2 CCB 140117-019 ICV 140117-002 I04LSTTC2 ICB 140117-003 LCS 140117-004 I00FSTLK3 LCD 140117-005 I00FSTLK3 mg/Kg mg/Kg mg/Kg mg/Kg mg/Kg mg/Kg CCV 140117-018 I04LSTTC2 mg/Kg CCB 140117-019 mg/Kg OC Result QC Result 1966.55 32.00 U 2125.68 32.00 U 4602.14 4465.78 4802.14 2078.20 32.00 U True Value 2000.00 2000.00 4780.00 4780.00 2000.00 Orig. Value C CaU. F * Limits Date Time 98 106 188.93 216.04 U 100 U 93 7 104 % 85-115 % 85-115 % 53-140 % 53-140 R 30 % 85-115 01/19/2005 0006 01/19/2005 0009 01/19/2005 1830 01/19/2005 1833 01/19/2005 1843 01/19/2005 1850 01/19/2005 2248 01/19/2005 2251 .Tsi. Method.........,::-'LLyd.Kahh Method-OaspHptlion-.: Total, Organic carbon-(SoHs): ' '' P a r a m e t e r . O r g a n i c - C a r b o n , Tt. (TOC) isatbh Equipment; Cde -!-:::.:irt&tyt; :i.ijinm: Test Cod ,--TQC QC Lab ID Reagent units lev 140127-002 I04LSTTC2 ICB 140127-003 LCS 140127-004 I00FSLK3 LCD 140127-005 I0QFSTLK3 mg/Kg mg/Kg mg/Kg mg/Kg CCV 140127-018 I04LSTTC2 CCB 140127-019 ccv 140127-018 IQ4LSTTC2 CCB 140127-019 mg/Kg mg/Kg mg/Kg mg/Kg QC Result QC ResuLt 2033.16 32.00 U 4013.62 4204.36 4013.62 1994.52 32.00 2052.63 32.00 U u True value 2000.00 4780.00 4780.00 2000.00 2000.00 Ori g. Value QC Cale. F * Limits Date Time 102 197.68 165.70 U 84 U 88 5 loo 103 % 85-115 % 53-140 % 53-140 R 30 % 35-115 % 85-115 01/21/2D05 1643 01/21/2005 1646 01/21/2005 1654 01/21/2005 1700 01/21/2005 1942 01/21/2005 1945 01/21/2005 2133 01/21/2005 2136 Test :Method,: , ; . Lloyd Kahn !.. 'Method Description. :-Total'-Organi b crbn (S6 IsJ P a r a m e t e r .> TO Average Duplicates . :B a t c h 140127 . . Equipment Lode*..,? :-:-:-::A'niyst.F:::-rnm' .Test Code. :' T O C V . 2 QC Lab ID MS 233506-3 MSD 233506-3 Reagent Uni ts I04LSTC2 mg/Kg I04LSTTC2 mg/Kg QC Result 9686.34 9583.28 QC Result 9686.34 True Value 2000.00 2000.00 Orig. Value 4978.99 4978.99 QC Cale. F * Limits Date Time 92 97 18.9 % 53-140 01/21/2005 1754 % 53-140 01/21/2005 1801 R 30 STL Chicago Page 23 * %=% RC, R=RPP, A=ABS Diff., D=% Diff. 71 Q U A L I T yY A $ S.u R A N E R E F E R E N C E S A N D .N 0 T E S "! :Report Date: 01/26/2O5 REPORT COMMENTS 1) AIL pages of this report are integral parts of the analytical data. Therefore, this report should be reproduced only in its entirety, 2) Soil, sediment and sludge sample results are reported on a "dry weight" basis except when analyzed for landfiLL disposal or incineration parameters. All other solid matrix samples are reported on an "as received" basis unless noted differently. 3} Reporting limits are adjusted for sample size used, dilutions and moisture content if applicable. 4) The test results for the noted analytical method(s) meet the requirements of NELAC. Lab Cert. ID# 10020] 5) According to 40CFR Part 136.3, pH, Chlorine Residual and Dissolved Oxygen analyses are to be performed immediately after aqueous sample collection, When these parameters are not indicated as field (e.g. pH Field) they were not analyzed iiwtiedlately, but as soon as possible on laboratory receipt. Glossary of flags, qualifiers and abbreviations (any number of which may appear in the report) Ihorganic Qualifiers (Q-Column) U AhaLyte was not detected at or above the stated limit. < Not detected at or above the reporting Limit, J Result is less than the RL, but greater than or equal to the method detection Limit. B Result is less than the CRDL/RL, but greater than or equal to the IDL/MDL. S Result was determined by the Method of Standard Additions. F AFCEE: Result is Less than the RL, but greater than or equal to the methoddetection Limit. Inorganic Flags (Flag Column) ICV,CCV,ICB.CCB,ISA,ISB,CRI,CRA,MRL: Instrument related QC exceed the upper or lower control limits. * LCS, LCD, MD: Batch QC exceeds the upper or Lower control limits. + MSA correlation coefficient is less than 0.995. 4 MS, MSD: The ahaLyte present in the original sample is 4 times greater than the matrix spike concentration; therefore, control limits are not applicable. E SD: Serial dilution exceeds the controL Limits. H MB, EB1, EB2, EB3: Batch QC is greater than reporting limit or had a negative instrument reading tower than the absolute value of the reporting limit. N MS, MSD: Spike recovery exceeds the upper or Lower control Limits. W AS(GFAA) Post-digestion spike was outside 65-115% control limits. Organic Qualifiers (Q - Column) U Analyte was not detected at or above the stated Limit. ND Confound hot detected. J Result is an estimated value below the reporting limit or a tentatively identified compound (TIC). Q Result was qualitatively confirmed, but not quantified. C Pesticide identification was confirmed by GC/MS, Y The chromatographic response resembles a typical fuel pattern. Z The chromatographic response does not resemble a typical fuel pattern. E Result exceeded calibration range, secondary dilution required. F AFCEE:ResuLt is an estimated value below the reporting limit ora tentativelyidentified compound (TIC) Orgshic Flags (Flags Column) E MB: Batch QC is greater than reporting limit. * LCS, LCD, ELC, ELD, CV, MS, MSD, Surrogate: Batch QC exceeds the upper orlower controL Limits. EB1, EBZ, EB3, MLE: Batch QC is greater than reporting Limit A concentration exceeds the instrument calibration range a Concentration is below the method Reporting Limit (RL) B Compound was found in the blank and sample. D Surrogate or matrix spike recoveries were not obtained because the extract was diluted for analysis; also compounds analyzed at a dilution will be flagged with a D. H Alternate peak selection upon analytical review I indicates the presence of an interfence, recovery is not calculated. M Manually integrated compound. P The Lower of the two values is reported when the % difference between the results of two GC columns is Page E4 STL Chicago it y a s s u r a n c e m e t h o d s ... 'R E F E R E N C E $ A N D SI-`D' ; \:\;Report Date: 01/26/2005 ;. greater than 25%. Abbreviations AS Post Digestion Spike (GFAA Samples - See Note 1 below) Batch Designation given to identify a specific extraction, digestion, preparation set. or analysis set CAP Capillary Column CCB Continuing Calibration Blank CCV Continuing Calibration Verification CF Confirmation analysis of original Cl Confirmation ana Lysis of A1 or D1 C2 Confirmation ana Lysis of A2 or D2 C3 Confirmation analysis of A3 or 03 CRA Low Level Standard Check - GFAA; Mercury CRJ Low Level Standard Check - ICP cv CaliLbration Verification Standard D U Fac DiLution Factor Secondary dilution analysis D1 Di Lution 1 D2 Dilution 2 D3 Dilution 3 DLFac Detection Limit Factor DSH Distilled Standard - High Level DSL Distilled Standard - Low Level DSM Distilled Standard - Medium Level EB1 Extraction Blank 1 EB2 Extraction Blank 2 EB3 DI Blank ELC Method Extracted LCS ELD Method Extracted LCD ICAL Initial calibration ICB Initial Calibration Blank ICV InitiaL Calibration Verification IDL Instrument Detection Limit ISA interference Check Sample A 1CAP 1SB Interference Check Sample B - ICAP Job No. The first six digits of the sampLe ID which refers to a specific client, project and sanale group Lab ID An S number unique laboratory identification LCD Laboratory Control Standard Duplicate LCS Laboratory Control Standard with reagent grade water or a matrix free from the analyte of interest MB Method Blank or (PB) Preparation Blank MD Method Duplicate MDL Method Detection Limit MLE Medium Level Extraction Blank MRL Method Reporting Limit Standard MSA Method of Standard Additions MS Matrix Spike MSD Matrix Spike Duplicate nd Not Detected PREPF Preparation factor used by the Laboratory's Information Management System (LIMS) PDS Post Digestion Spike (ICAP) RA Re^analysis of original A1 Re-analysis of Di A2 Re-analysis of D2 A3 Re-ana lysis of D3 RD Re-extraction of dilution RE Re-extraction of original RC Re-extraction Confirmation RL Reporting Limit RPD Relative Percent Difference of duplicate (unrounded) analyses RRF Relative Response Factor RT Retention Time Page 25 STL Chicago . T: i'A S $ U R A. H C E M E T H O D S REFER EMC E S ANO ' i-jEV.-S--;;'-""-'' Report Date: Q:1/2!6,/20p!5 RTW Retention Time Window Sample ID A 9 digit number unique for each sample, the first six digits are referred as the job number SCB Seeded Control Blank SD StriaL Dilution (Calculated when sample concentration exceeds 50 times the MDL) UCB Unseeded control Blank ssv Second Source Verification Standard SLCS Solid Laboratory ControL Standard(LCS) PHC pH Calibration Check LCSP pH Laboratory Control Sample LCDP pH Laboratory Control Sample Duplicate MDPH pH Sample Duplicate NDFP Flashpoint Sample Duplicate LCFP Flashpoint LCS G1 Gelex, Check Standard Range 0-1 G2 GeLex Check Standard Range 1-10 G3 Gelex Check Standard Range 10-100 G4 GeLex Check Standard Range 100'1000 Note 1: The Post Spike Designation on Batch QC for GFAA is designated with an added to the current abbreviation used. Ex. LCS S=LCS Post Spike (GFAA); MSS=MS Post Spike (GFAA) Note 2 i The MD calculates an absolute difference (A) when the sample concentration is less than 5 times the reporting limit. The control limit is represented as +/- the RL. STL nhiilHfrn Page 26 CHAIN OF CUSTODY 'X % V & CHAIN OF CUSTODY / ANALYSIS REQUEST FORM N Severn Trent Laboratories T: 703-534-5200 F: 703-534-5211 2417 Bond Street University Park, IL 60466 PAGE 1 o f PROJECT INFORMATION Client: Weston Solutions, Inc. 1400 Weston Way, Bldg. 5-2 West Chester, PA 19330 T: 610-701-3761 F: 610-701-7401 Project Manager: Jai Kesari email: i.kesariio)westo nsol uti ons. co m Project Name: Reference No: Decatur, Alabama 02181-129-081-0001 ANALYSES REQUESTED Sampler: E. Caldwell, B. McCanless 256-552-6189 P.O.#: Quotation #: SAMPLE ANALYSIS ExyLIMS # l JL to Client Sample Identification DLOI SB 220R 0000 DLOI SB 220R 0005 DLOI SB 22 OR 0020 DLOI SB 220R 0050 DLOI SB DLOI SB 220R 220L 00017000 D L O J SB 220L 0005 DLOI SB 220L 0020 DLOI SB 220L 0050 DLOI SB 220L 0070 Collection Date 11-Jan-05 11-Jan-05 11-Jan-05 11-Jan-05 11-Jan-05 11-Jan-05 11-Jan-05 11-Jan-0 5 11-Jan-05 11-Jan-05 Collection Time 12:15 12:25 13:45 13:50 14:45 12:45 13:00 15:15 15:25 15:40 X X c 's 3 o. oE Z CJ Sample Matrix SOIL SOIL SOIL SOIL SOIL SOIL SOIL SOIL SOIL SOIL CHAIN OF CUSTODY Rei incuj i Date f/f /v ^ fy Cooler ID No.: Time Received By: Fed Ex fp a Cooler Temp. (C): Date Time / / / ^ r Iff too 4 a k cftoo Comments X PROJECT REQUIREMENTS Results Deadline: Laboratory Report Options: Sample Results Only Add Case Narrative Add Quality Control Summary Add Calibration Summary Add Raw Data Other: STL Chicago CHAIN OF CUSTODY/ANALYSIS REQUEST FORM 'YiiZa r * a- r< Severn Trent Laboratories T: 708-534-5200 F: 708-534-5211 2417 Bond Street University Park, IL 60466 PAGE ^ o f PROJECT INFORMATION Client: Weston Solutions, Inc. 1400 Weston Way, Bldg. 5-2 West Chester, PA 19360 T: 610-701-3761 F: 610-701-7401 Project Manager: Jai Kesari emiail: i.kesariwesto nso Iuti ns. com Project Name Reference No: Decatur, Alabama 02181-129-081-0001 ANALYSES REQUESTED Sampler: E. Caldwell, B. McCanEess 256-552-6189 P.O. #: Quotation #: Grab Sample Composite No. of Containers STL Chicago SAMPLE ANALYSIS ExyLIMS # U a = it _____________________________ Collection Collection Client Sample Identification ,_ Date Time DBKGl SB 1 001B 0 0000 12-Jan-05 10:10 DB KG, SB 001B 0 0005 12-Jan-05 10:15 D8KG SB 001B 0 0010 12-Jan-05 10:20 DB KG SB 001B 0 0020 12-Jan-05 10:30 DB KG SB 001B 0 0050 12-Jan-05 10:50 DBKG SB 001B 0 0230 12-Jan-05 1 12:35 X X X X X X Sample Matrix 1 SOIL 1 SOIL 1 SOIL 1 SOIL 1 SOIL 1 SOIL 17 :=x- <6 DBKG SBC DBKG SBC DBKG SBC 0018 001B 001B 0 0000 12-Jan-05 0 0050 12-Jan-05 0 0100 12-Jan-05 10:55 11:15 11:35 X1 X1 X1 SOIL SOIL SOIL CHAIN OF AJSTODY Cooler ID No.: Rel iQfluis Date Time ///A*r f/ Received By: Fed Ex )rOF Cooler Temp. (C): Date, Time / 9 C Affc\k $0 Comments O O1X X X X X X X X X _LJ PROJECT REQUIREMENTS Results Deadline: Laboratory Report Options: Sample Results Only Add Case Narrative Add Quality Control Summary Add Calibration Summary Add Raw Data Other: SampJe Lot#: STL Chicago Internal Sample Custody Transfer Record S~0 fc_______________ Client: Sample No. i - i ei ( -ft? Analysis fu c !U/ Relinquished by: Received by: //' /' A .* . uV ^ H Date Time hi <fv f /Cor Comments v ---------------------------------i C HI-22-11-001/C-1/99 rpjsckl Job Sample Receipt checklist Report Job Number.: 233506 Location.: 57222 Check List Number,: 1 Description.: Customer Job ID....: Job Check List Date.: 01/15/2005 Project Number.: 20004391 Project Description.: Confidential Decatur - FC Investigation Customer...... : Ueeton Solutions, Inc. Contact.: Jai Kesari Questions ? (Y/N) Comments V2 Date of the Report.. : 01/20/2005 Project Manager.... : rcw Chain-of-Custody Present?........................ Y were samples dropped off at or picked up by STL?.. N Custody seal on shipping container?.............. Y ...If "yes", custody seal intact?...*-.,,........ Y Custody seals on sampLe containers?............ .. U ...If "yes", custody seal intact?...... . Samples iced?..... ................... ..... Y 3.1 Temperature of cooler acceptable? (4 deg C +/* 2). Y Samples received intact (good condition)?....,___ Y Volatile samples acceptable? (no headspace)...... Correct containers used?...... ................. . Y Adequate sample volume provided?................. Y Samples preserved correctly?.......... Y Samples received within holding^time?............ Y Agreement between COG and sample labels?......... Y Radioactivity at or below background Levels?..... Y A san^Le Discrepancy Report (SDR) was needed?.... N If samples were shipped was there an air bill #?.. Y Sample Custodian Signature/Date............. . Y Page 1 STL Chicago Fecfcc. USAirbill a 8404^400850 S T I :Chicago CASE NARRATIVE Client: Job #: STL Chicago Wet Chemistry Case Narrative Weston Solutions, Inc. 233506 Date Rec'd: 01/15/05 ]. This narrative covers the analysis o f the samples in the above Job # for TOC by the Lloyd Kahn Method. The samples were analyzed for TOC in duplicate by furnace combustion and nondispcrsive infrared detection on a Dohrmann Phoenix 8000 TOC analyzer, after acidification to remove inorganic carbon, and drying. No correction was made, therefore, tor moisture content. The average o f the sample bums is reported. 2. The method-recommended holding time o f 2 weeks was met. Refer to the laboratory Chronicle Page for dates o f sampling, receipt, and analysis. 3. The TOC calibration curve and the initial and continuing verification standards and blanks met acceptance criteria. 4. The method blanks were less than the reporting limit. Please note that the method blanks and the ICBs arc the same, and are reported here as ICBs. 5. The LCSs were within acceptance limits. 6. The matrix QC done on sample 233506-3 was within acceptance limits. Diane L. Harper / Wei Chemistry Section Manager /- 3 i - 0 Date RAW DATA L< TOC S *** RUN LOG *** <V2 ) /T-" 1/24/05 17:12 Total Organic Carbon (Soils) Method Code..: TOCS Batch Code...: 140117 Status....... ; RAW Batch Pate,..: 01/24/05 Batch Time..: 1637 User Name......: rnm QC code...*.,..: TOCS Calc Code......: TOCS Location Code..: 57222 Equipment Code.: Import Code____: TEST CODE TT T T T T TT TT T TT O00OO00CCC III Cc cCCccSssCCC 234AAA 2A sSS VVV V 2A 234 2 2 SAMPLE : Grp Poej Sample ID Di luti on TEST POS Date / Time 1234 56 7 111222 7 8 9 0 12 11 __ ICAL_I04LSTTC1_ 1/17/05 0000 0 12 __ ICVJ04LSTTC2_ 1/19/05 1830 0 13 ___ICB__ 1/19/05 1833 0 14 ___LCS_lO0FSTLK3_3 1/19/05 1843 0 15 ___LCD_IOOFSTLK3_3 1/19/05 1850 0 16 233505^5_S__ 1/19/05 1856 0 17 233505_5_S_MSJ04LSTTC2_6 1/19/05 1925 0 18 233505_5_SJ4SDJ 04LSTTC2_6 1/19/05 1932 0 19 233505_6_S___ 1/19/05 1941 0 1 10 233505_7_S___ 1/19/05 1957 0 1 11 233505J _ S ___ 1/19/05 2035 0 1 12 2 3 3 5 0 5 9 S ___ 1/19/05 2052 0 1 13 233505J 0 _ S :__ 1/19/05 2109 0 1 14 2335Q5_11mS___ 1/19/05 2128 0 1 15 1 16 233505_12_S___ 233505J3_S___ 1/19/05 2141 1/19/05 2215 0 0 1 17 1 18 1 19 233505_14^jSj__ CCV_I04LSTTC2_ ___ CCB__ 1/19/05 2234 1/19/05 224B 0 1/19/05 2251 0 0 1 20 233505_15_S__ 1/19/05 2257 0 1 21 233505J 6 _ S __ 1/19/05 2309 0 1 22 1 23 1 24 233505_17_S__ ^ 2335Q6_J_S___ 233506_2_S___ 1/19/05 2322 1/19/05 2341 1/19/05 2352 0 0 0 1 25 ___CCV_l04lTTC2_ 1/19/05 0006 0 1 26 ___CCB_ 1/19/05 0009 0 STL Chicaeo Page 1 -- #** QC Summary *** <V2 ) Total Organic Carbon (Soils) Method Code,.: TOCS Batch Code...: 140117 Status...... : RAW Batch Date...: 01/24/05 Batch Time,..: 1637 User Name.... rnm QC Code........ : TOCS Calc Code..... : TOCS Location Code..: 57222 Grp smp Sample ID Pos Test Result Known Original 1 2 __ ICV_I04LSTTC2_ 1 TOC 2125.68 2000 1 3 ,__ ICB__ 1 TOC -2.31 1 4 __ LCSi_l00FSTLK3_3 1 TOC 4802.14 4780 -2.31 1 5 __ LCD_I00FSTLK3_3 1 TOC 4465.78 4780 -2.31 1 7 233505J AMS_104LSTTC2_6 5 TOCAV2 3764.38 2000 1480.19 1 8 233505_5_S_MSDJ04LSTTC2^6 5 T0CAV2 3134.89 2000 1480.19 1 18 ___CCV_I04LSTTC2_ 1 TOC 2078.20 2000 1 19 u__ CCB__ 1 TOC -3.14 1 25 ___CCV_I04LSTTC2_ 1 TOC 1968.55 2000 1 26 __ CCBi_ 1 TOC -3.80 Report Date; 1/24/05 17:12 Equipment Code.: Import Code____; Alternate QC Res 106 F QC Res F 4802.14 3764.38 100 93 7 74 ...i/ti f a 8 104 98 STL Chicago Page 1 *** RAW TEST DATA 4** <V2 ) Total Organic Carbon (Soi La) Method Code..: TOCS Batch Coderrr: 140117 Status...... : RAW Batch Date.. : 01/24/05 Batch Time.. : 1637 User Name... : rnm SAMPLE: Grp Pos Sample ID 11 12 13 14 15 16 17 18 19 1 10 1 11 1 12 1 13 1 14 1 15 1 16 1 17 1 18 1 19 1 20 1 21 1 22 1 23 1 24 1 25 1 26 ICAL I04LSTTC1 ICV 4LSTTC2 ICE ICS I00FSTLK3 3 LCD I00FSTLK3 3 233505 5 S 233505 5 S MS I04LSTTC2 6 233505 5 S MSD I04LSTTC2 6 233505 6 S 233505 7 S 233505 8 S 233505 9 S 233505 10 S 233505 11 S 233505 12 S 233505 13 S 233505 14 S CCV I04LSTTC2 CCB 233505 15 S 233505 16 S 233505 17 S 233506 1 S 233506 2 S CCV I04LSTTC2 CCB QC Code...... .: Tocs CaLe Code..... Location Code. 57222 Dilution TOC mg/Kg T0C2 mg/Kg Report Date: 1/24/05 17:12 Equipment Code.: Import Code___ : T0C3 mg/Kg TOC4 mg/Kg TCAV2 mg/Kg 2125.68 -2,31 4802.14 4465.78 1538.73 3764.38 3134.89 680.30 490.15 19674.39 5484.53 1714.66 1383.89 659.43 30439.31 5254.46 2078.20 -3.14 4116.25 1611.45 1153.37 20934.94 5999.47 1968.55 -3.80 1421.65 645.18 214.25 2093B.65 4977.54 2256.91 1777.87 849.82 33738.10 5792.24 4125.66 1419.15 1075.65 27492.02 5682.64 1480.19 3764.38 3134.89 662.74 352.20 20306.52 5231.03 1985.79 1580.88 754.62 32088.71 5523.35 4120.95 1515.30 1114.51 24213.48 5841,06 STL Chicago Page 1 10 *** RAW TEST DATA *** (V2 ) Total Organic Carbon (Soils) Method Code..: TOCS Batch Code...: 140117 Status...... : RAW Batch Date...: 01/24/05 Batch Time...: 1637 User Name___ : rnm SAMPLE: Grp Pos Sample ID 11 ICAL I04LSTTC1 12 lev I04LSTTC2 13 ICB 14 LCS I00FSTLK3 3 15 LCD IQ0F5TLK3 3 1 6 233505 5 S 1 7 233505 5 S MS I04LSTTC2 6 1 8 233505 5 S MSD I04LSTTC2 6 1 9 233505 6 S 1 10 233505 7 S 1 11 233505 S S 1 12 233505 9 S 1 13 233505 10 S 1 14 233505 11 S 1 15 233505 12 S 1 16 233505 13 S 1 17 233505 14 S 1 IB CCV I04LSTTC2 1 19 CCB 1 20 233505 15 S 1 21 233505 16 S 1 22 233505 17 S 1 23 233506 1 S 1 24 233506 2 S 1 25 CCV I04LSTTC2 1 26 CCB QC Code........: TOCS Calc Code......: TOCS Location Code..: 57222 Dilution TQCAV3 mg/Kg T0CAV4 mg/Kg Report Date: 1/24/05 17:12 Equipment Code.: Import code____: TOCRl ug TQCR2 ug TOCR3 ug 106.2840 -0.3704 130.1381 105.8390 84.9377 233.0150 182.1373 45.2399 30.6343 206.5811 144.2431 64.8140 47.6058 38.7084 304.3931 173.3973 103.9098 '0.5022 97.5551 82.5063 61.9362 142.3576 77.3931 98.4275 -0.6080 84.1619 61.4859 18.9826 314.0798 117.9677 105.6234 94.7606 39.9417 232.7929 166.2374 112.2180 101.4690 63.5711 137.4601 249,4678 STL Chicago Page 2 39 ftft* RAW TEST DATA CV2 ) Total Organic Carbon (Soils) Method code..: TOCS Batch Code...: 1401 7 Status.. RAW Catch Date... : 01/24/05 Batch Time.,. : 1637 User Marne.... SAMPLE: Grp PO SampLe ID 11 ICAL IQ4LSTTC1 12 13 ICV I04LSTTC2 ICB 14 LCS I0QFSTLK3 3 15 LCD I00FSTLK3 3 1 6 233505 5 S 17 13 19 233505 5 S MS I04LSTTC2 6 233505 5 S MSD ID4LSTTC2 6 233505 6 S 1 10 233505 7 S 1 11 233505 S 1 12 233505 9 S 1 13 233505 10 S 1 14 233505 11. S 1 15 233505 12 S 1 16 233505 13 S 1 17 233505 14 S 1 13 CCV I04LSTTC2 1 19 CCB 1 20 233505 15 S 1 21 233505 16 S 1 22 233505 17 S 1 23 233506 1 S 1 24 233506 2 S 1 25 CCV I4LSTTC2 1 26 CCB QC Cade__ TOCS Calc Code..... ; TOCS Location Code..; 57222 D Luti oh TCR4 ug WT1 9 Report Date; 1/24/05 17:12 Equipment Code.: Import Code.., ,,; WT2 WT3 WT4 0 99 0.05 0.16 0.0271 0.0237 0.0552 0.0619 0.0581 0.0665 0.0625 0.0105 0,0263 0.0378 0.0344 0.0587 0.0100 0.0330 0.05 0.16 0.0237 0.0512 0.0537 0.0068 0.0129 0.05 0.16 0.0592 0.0953 0.0886 0.0150 0.0237 0.0468 0.0533 0.0470 0.0069 0.0287 0.0272 D.0715 0.0591 0.0050 0.0439 STL Cliicago Page 3 40 *** RAW TEST DATA *** (V2 ) Total Organic Carbon (Soils) Method Code..: TOCS Batch Code...: 140117 Status...... : RAW Batch Date.. : 01/24/05 Batch Time.. : 1637 User Name__ : rnm SAMPLE: Grp Pos Sample ID 11 ICAL I04LSTTC1 12 ICV I04LSTTC2 13 ICB 14 LCS I00FSTLK3 3 15 LCD IQ0FSTLK3 3 1 6 233505 5 S 1 7 233505 5 S MS I04LSTTC2 6 1 0 233505 5 S MSD I04LSTTC2 6 1 9 233505 6 S 1 10 233505 7 S 1 n 233505 8 S 1 12 233505 9 S 1 13 233505 10 S 1 14 233505 11 S 1 15 233505 12 S 1 16 233505 13 S 1 17 233505 14 S 1 18 CCV I04LSTTC2 1 19 CCB 1 20 233505 15 S 1 21 233505 16 S 1 22 233505 17 S 1 23 233506 1 S 1 24 233506 2 S 1 25 CCV I04LSTTC2 1 26 CCB QC Code.. . - TOCS Calc code ..... : TOCS Location code..: 57222 Dilutioh DLFAC N/A TCS mg/Kg Report Date: 1/24/05 17:12 Equipment Code.: Import Code___ : TCS2 mg/Kg TCSAV2 mg/Kg TICS mg/Kg 3.2000 1.0000 5.9041 6.7511 2.7972 2.5848 2.7539 1.9778 2.1178 12.5490 6.4000 3.7825 3.6488 3.0274 18.9349 5.1864 3.2000 1.0000 6.2868 2.6080 2.8369 27.1186 5.6338 3.2000 1.0000 STL Chicago Rage 4 A1 Calibration Report Print Date/Time: 2005/01/20 0:12:11 Cal. Curve ID: Created: Calibration Factor Y Intercept (b}: r-squared: (m) SOILCURVE 01/17/2005 8.53Be+04 436425 0.99800 11:33 Standard ID 0 ugram C lOugramC 20 ugram C 40 ugram C 80 ugram C 120 ugram C 200 ugram C 300 ugram C 400 ugram C Y Raw Data "4 5 3 0 1085240 1870210 3806480 7357282 11114689 18428840 26478564 33682344 X Expected ug C 0.000 10.000 20.000 40.000 80.000 120.000 200.000 300.000 400.000 Measured Message ug C -5.165 No Sample Det 7,599 16,794 39-473 81.062 125.072 210.740 305.025 389.401 Date & Time 01/17/2005 09:53 01/17/2005 10:15 01/17/2005 10:26 01/17/2005 10:34 01/17/2005 10:45 01/17/2005 10:58 01/17/2005 11:07 01/17/2005 11:15 01/17/2005 11:32 ST L Chicago 42 Multiple Analysis Report Print Date/Time: 2005/01/20 0:11:54 Sample ID Result Std. Dev. RSD Mode ALT ICV 106.2840 ICB -0.3704 LCS 130.1381 L C D ..................................... 105.8390. . . 233505-5 84.9377 233505-5 84.1619 233505-5 M S ........................... 233.0150... 233505-5 MSD 182.1373 233505-6 45.2399 2 3 3 5 0 5 - 6 ................................ 61.4859... 233505-7 30.6343 233505-7 18.9826 2 3 3 5 0 5 - 8 ............................... 1049,2341. . . 233505-8 206.5811 233505-8 314.0798 233505 -9 ................................ 144.2431... 233505-9 117.9677 233505 -10 64.8140 23 3 5 0 5 - 1 0 .............................. 105.6234, . . 233505-11 47.6058 233505-11 94.7606 2 3 3 5 0 5 - 1 2 .............................. 38.7084... 233505-12 39.9417 233505-13 1049.7812 2 3 3 5 0 5 - 1 3 .............................. 551.7590... 233505-13 304.3931 233505-13 232.7929 2 3 3 5 0 5 - 1 4 .............................. 173.3973. . , 233505-14 166.2374 CCV 103.9098 C C B ..................................... -0.5 022... 233505-15 97.5551 233505-15 112.2180 2 3 3 5 0 5 - 1 6 .............................. 82,5063... 233505-16 101.4690 233505-17 61.9362 2 3 3 5 0 5 - 1 7 ............................. 63.5711... 233506- 1 675.8541 233506-1 142.3576 2 3 3 5 0 6 - 1 ............................... 137.4601... 233506-2 77,3931 233506-2 249.4678 C C V ..................................... 98.4275. . . CCB -0.6080 .. .. .. ., .. .. .. .. .. .. ,, .. .. TC TC TC . . -TC TC TC ...TC TC TC . . .TC TC TC . . .TC TC TC . . .TC TC TC . , .TC TC TC . . .TC TC TC . , .TC TC TC . . ,TC TC TC ...TC TC TC . . .TC TC TC , , ,TC TC TC . . .TC TC TC . ..TC TC STL Chicago Detailed Analysis Report Print Date/Time: 2005/01/20 0:11:56 Sample ID: ICV Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Rep # ppm C ug C Raw Data 1 106.2840 106,2840 9510653 Mode: TC Filename: 01191825 ^ ^ Timestamp: 01/19/200x 18:30 Sample Type: Cal. Verifidarbin Beginning Baseline 2,423 Ending Baseline 3,420 Integration Time 261 Sample ID: ICB Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Rep # ppm C ug C Raw Data 1 -0.3704 "0 , 3 7 0 4 -5861 Last Message: No Sample Detected Mode: TC Filename: 01191831 Timestamp: 01/19/200^1 18 :33 . Sample Type: Sample Beginning Baseline 2.002 Ending Baseline 1.962 Integration Time 120 Sample ID: LCS Method: boat Cal. Curve: SOILCURVE operator ID: CAROL Rep # ppm C ug C Raw Data 1 130.1381 130,1381 11136586 Mode: Filename: Timestamp: Sample Type: TC 01191838 01/19/200 Sample Beginning Baseline 1.891 Ending Baseline 2.888 Integration Time 283 Sample ID: LCD Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Rep ft ppm C ug C Raw Data 1 105.8390 105.8390 9062003 Mode: Filename: Timestamp: Sample Type: TC 01191845 01/19/2005 Sample Beginning Baseline 2.069 Ending Baseline 3.069 Integration Time 264 Sample ID: 233505-5 Method: boat Cal. Curve : SOILCURVE Operator ID: CAROL Mode : Filename: Timestamp: Sample Type: TC 01191851 01/19/2005/18:56 Sample Rep # 1 ppm C 84.9377 ug C 84.9377 Raw Data^x Beginning \ Baseline 7277504 \ "X 2.927 Ending Baseline 3.925 Integration Time 244 STL Chicago dd Rep # ppm C 304.3931 vug C Raw Data 304 3931 26013986 Sample ID: 233505-13 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Rep # ppm C ug C R&w Data 1 232.7929 232,7929 199' 10968 Sample ID: 233505-14 Method: boat Cal. Curve; SOILCURVE Operator ID: CAROL Rep # ppm C ug C Raw Data 1 173.3973 173.3973 14829940 Sample ID: Method: Cal. Curve: Operator ID: 233505-14 boat SOILCURVE CAROL Rep # ppm C ug C Raw Data 1 166.2374 166,2374 14218644 Sample ID: CCV Method: boat Cal. Curve : SOILCURVE Operator ID: CAROL Rep # ppm C ug C Raw Data 1 103.9098 103.9098 9307950 Sample ID: CCB Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Rep # ppm C ug C Raw Data 1 -0.5022 -0.5022 -17112 Beginning Baseline 2.542 Ending Baseline 3,540 Integration Time 307 Mode : TC Filename : 01192217 Timestamp: 01/19/2005 22:22 Sample Type: Sample Beginning Baseline 2.278 Ending Baseline 3.277 Integration Time 298 Mode : TC Filename: 01192226 Timestamp: 01/19/200^22:34 Sample Type: Sample Beginning aseline 1.880 Ending Baseline 2.880 Integration Time 295 de: TC ename: 01192235 Stamp: 01/19/2005 22:40 Sample Type : Sample Beginning Baseline 2.120 Ending Lseline 3,116 Integration Time 275 Mode: Filename : Timestamp: Sample Type TC 01192242 -- 01/19/2005^22 :4(T) Cal. Verification Beginning Baseline 1.955 Ending Baseline 2.952 Integration Time 266 Mode : Filename : Timestamp: Sample Type: TC _ __ 01192248 01/19/200^22:51 Sample Beginning Baseline 1.890 Ending Baseline 1.681 Integration Time 120 STL Chicago 45 Last Message: No Sample Detected Sample IDx 233505-15 Method: \ boat Cal. CurveSOILCURVE Operator ID:\cAROL Rep # 1 \ppm ^ 97,5551 \ ug C 97.5551 \ Raw Data 3354745 Sample ID: 2 3 3 5 0 5 V 15 Method: boat \ Cal. Curve : SOILCURVE Operator ID CAROL \\ Rep ft ppm C ug 'C Raw Data Baseline 1 112.2180 Time \ 1 1 2 .2180\ 9606623 \ Sample ID: Method: Cal. Curve : Operator ID: 233505-16 boat SOILCURVE CAROL Rep # 1 ppm C 82,5063 ug C 82.5063 R a w Dat'h \ 7069917 \ Mode: Filename : Timestamp : Sample Type: TC 01192252 01/19/200^22:57" Sample ^ Beginning Baseline 2,110 Ending Baseline 3.109 Integration Time 255 Mode; Filename: Timestamp: Sample Type: TC 01192258 01/19/2005 Sample 23:02 Beginning Baseline Ending Integration 2.149 3.145 258 ^ := = = = = =: ^ ^ ^ m ^ h SI TMS QDBESSS! " Mode: Filename : Timestamp: Sample Type TC 01192305 r7---01/19/2005^ 23: 09') Sample Beginning Baseline 2,346 Ending Baseline 3.342 Integration Time 247 Sample ID: 233505-16 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Rep # ppm C ug C Raw Data 1 101,4690 101.4690 8688906 Mode: TC \ Filename: 01192311 \ Timestamp: 01/19/2005 23:16 \ Sample Type: Sample \ Beginning Baseline 2,X^1 Ending Baseline 3.349 Integration Time 262 Sample ID: 233505-17 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Rep # ppm C ug C Raw Data 1 61.9362 61.9362 5313701 Mode TC Filename: 01192317 Timestamp: 01/19/20 Sample Type: Sample Beginning Baseline 2.265 Ending Baseline 3/261 Integration Time 239 STL Chicago 46 Sample ID: Method: C a l , Curve: Operator ID: -\ \ 233505-l l \ boat SOILCURVE CAROL Rep # ppm C ug C 1 63,5711 63,5711 Data 545^285 Sample ID: Method: Cal. Curve : Operator ID 233506 -1 boat SOILCURVE CAROL Rep # ppm C ug C Raw Data 1 675,8541 675.8541 57728284 Sample ID : Method: Cal, Curve: Operator ID; 233506-1 boat SOILCURVE CAROL Rep # ppm C ug C Raw Data 142.3576 142*3576 12179852 Sample ID: 233506-1 Method: boat cal Curve: SOILCURVE Operator ID: CAROL Rep # ppm C ug C Raw Data 1 137.4601 137.4601 11761723 Sample ID: 233506-2 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Rep # ppm C ug C Raw Data 1 77.3931 77.3931 6633365 Mode: TC Filename: 01192323 Timestamp: 01/19/2005 23:28 Sample Type: Sample Beginning Baseline 2,206 Ending Baseline 3*205 Integration Time 242 Mode: Filename : Timestamp: Sample Type TC 01192329 01/19/2005 Sample 23:35 Beginning Baseline 2,140 Endizag B asoelline 3 *137 Integration Time ~ 3 tS 5 -- _ Mode : Filename: Timestamp: Sample Type: TC 01192336 01/19/2005(23:41 Sample Beginning Baseline 2,736 Ending Baseline 3.735 Integration Time 258 Mode: Filename: Timestamp: Sample Type: TC 01192341 01/19/2005 Sample 23:47 Beginning Baseline 2,362 Ending Baseline 3.362 Integration Time 271 Mode: Filename : Timestamp: Sample Type TC 01192347 --- 01/19/200^ 23:52 Sample Beginning Baseline 2*411 Ending Baseline 3.409 Integration Time 246 STL Chicago 47 Sample ID: Method: Cal. Curve: Operator ID: 233506-2 boat SOXLCURVE CAROL Rep # ppm C ug C Raw Data 1 249.4678 249*4678 21324626 Sample ID: Method: Cal. Curve: Operator ID: CCV boat SOILCURVE CAROL Rep # ppm C ug C Raw Data 1 98.4275 98.4275 8839886 Sample ID: CCB Method: boat Cal* Curve: SOILCURVE Operator ID: CAROL Rep # ppm C ug C Raw Data 1 -0*6080 -0*6080 -26143 Last Message: No Sample Detected Mode: Filename: Timestamp: Sample Type: TC 01192354 01/20/2005 Sample 00:00 Beginning Baseline 1.822 Ending Baseline 2.822 Integration Time 308 Mode: TC F i l e n a m e : 01200001 ^ - ~ ' Timestamp: 0 1 / 2 0 / 2 0 0 S _ 0 0 :06^) Sample Type: Cal* Verification Beginning Baseline 2.236 Ending Baseline 3*233 Integration Time 258 Mode: Filename : Timestamp: Sample Type TC 01200006 ^-7-- 01/20/2005^ 0 0 :09j) Sample '^ ^ Beginning Baseline 2.073 Ending Baseline 1.744 Integration Time 120 STL Chicago 122 _ / v n 7 &991? iT0C4* urvs., Page #_ noted Stock Solutions.} STL Chicago TOC in Soils Method: Lloyd Kahn Pag* No.; 123 Book No.:_L_BZLh2L instrument: Phoenix SDQO(TOC4) Calculation*; TOC(mg/kg) ug C i grams sample LabNet Batch; N i ) I O Date of Standard CurvaT T j n fC^> Book# Page# 0 7 MS, MSD Known Cone, (mg/kg) - 100 ug C i grams sample MS, MSD Observed (mg/kg) - ug C / grams sample MS, MSD Ree, fobaerved mg/ko - avo, sample rwultlmg/ko)! x100 known concentration in mg/kg Standard Traceability; (Note: Working Standards are prepared deify from the noted Stock Solutions.} Stock i /CurvaL X r ^ i A K lT c f Stock II ncVfCCV>^ C o 4 i S T T T 2 . LCS Source ipl C ^ S T U 3 LCS True Valu*U )PD Acceptance Range 5 ^ ^ - I* i % Sample ID: Sample Weight (g) Ug C Commente: Co/ LCS LCS5 Oofs o.tu> 0 . 02/11 O-023 ^ IJ. 3 S ` 0 _ -- 0 :3 7 0 i 130. 1' / />- S '.^O SB3 K 25-4 5 . 0 ,0 ^ S L _ S'/ .c & > /_____- . 5 _ O _ O .O t^R 2 2 / 3 - 0 1 * 5 0 3 n ^ 4 f4 iu t 5 . ,bi - PfLMSlQ _______ 0 :0 ^ 1 O .O L pCpS 0 . o c |5 ?, |6 2 - 3 1 A 4 2 3 q<H fe n y s s g 3 f3+^1 C H Q I , h 1n 4 r - - *=^g3--u \ - .-S L -q _ b-O VizZ O V S - |0 rkq$Q_(^ LL 0 4QH4 .-2 3 4 1 Q. oi 0 5 Sj^vbf f t ~ - 2 tzr^ ~ 0 -4 C5^ |U ,C !1<^ 0 .0 2 _ " J4 . a i / > l 0 - OASI- '!? % }* - i d _ P -0 3 TB- . -to -1 . UH'JW , /0 5 ,fo2 3 f nw sp / - I I 0.05 3 ' 0 . 5 ?? fy l-V c ftp know /? f& /fe # --- Prep Analyst C * Analyst. Reviewed by: 2L^ Date: / / / 7 fa r : D te :Z jB fc Z J S -2 /j _ Date:' V /Z fc /fr " <... ... ,ch ij-is i-w s /B jjs /o i STL Chicago STL Chicago Page No:_ 124 TOC in Soil* Book No.: Method: Lloyd Kahn Instrument' Phoenix B000 T0 C4) LabNet Batch:_[;O J f ^ C alculation: Data of Standard Curva )(fip" : TOC (mg/Kg) ug C i grams sample Book # ^ 7 4 ^L Faoe * I MS, MSD Known Cone, (mg/kg) - 100 ug C / grama ampia MS, MSD Observed (mg/kg) - ug C / grams sample MS, MSD Ree. - [observed mo/kg - avo, smole result (mg/Ko x 100 known concentration in mg/kg Standard T racea bility; (Nate: W orking Standards are prepared daily from the noted Stock Solutions.) Stock I (Curve) /Stock II (ICV/CCV), LCS Source ID LCS True Value _ ."Acceptance Range. Sample ID: Sampl* Weight (g) .. Comment*: r r O P T f ) ' 2336 ' - . - O H O ..... ' 3 q p M | ^ . --\ ..... . 3 O rO iq q . - / o /J -ra t^ rc iifW u i------; ski n ^ C ...... 'z a k & r i i 'O t J ^ - 3-3n crjt -- hh- 0 .0 3 -3 0 n h -'W ^ -" 1. . r.C H . <?. o S ' n i Ipln . SS H - ` f l P r .... 1o 3 .d r i f t s .IU - -0. *jC 00 ...... ' 'S e s - / s ' .... 0 : 0 1 ^ < 1 1 ,9 3 5 1 - " 1 5 : 0 . o a m 1 3 :Q l8(') ....... " / - " . - C 6 T & f t S O t i ' ............'........ . -+ ? - O -fT t 15 ' T 6 fc 4 t n .m c L ,i ....,. ... ^ G ^ jUj1I ' O . 'iP ii b 3 :& il- - - P r Q O ___-- -- rfehPb. r\Bbr^ 0 ; ODloS .W 3?-3S?i/> - ..... C h-O O sfr vL ... ....... o . o J a 'i - ... .. r - W t & f l .. c o s --------- '..0 `0 S ' ..... ' ; % : - l a i y e e G > -- - ...O . I U ) ............. ... .... ..:, : ; ........... -; ... . Prep AnaivsfrC AnalvstT r v r P VX r -iAl 1_ Data: /jY ?/^~ i/^(H Pats:7 M ^ ^ / 5 ( > ( m i Data: l / f i f r L' ; CHI.22`n24lwa-0filD1 ft*# RUN LOG L & 'T d C tyX - CVJ > 1/28/05 13:03 Total Organic Carbon (Soils) Method Code..: TOCS Batch Code...: 140127 Status...... : RVWD Batch Date...: 01/24/05 Batch Time...: 2239 User Name......: rnm QC Code........ : TOCS C alc Code....... :TOCS Location Code..: 57222 Equipment Code.: Import Code----: TEST CODE T T TT TT TT T T T T T O0O0000CCC III C cC C CcC S SS CC C 234AAA 2Asss VVV V 2A 234 2 2 SAMPLE: Grp PO Sample ID Di lut ion TEST PQS Date / Time 1234 56 7 111222 78 9 0 12 11 __ ICAL__ 0 12 1CV I04LSTTC2 1/21/05 1643 0 13 __ ICB__ 1/21/05 1646 0 14 __ LCS_I0FSTLK3_3 1/21/05 1654 0 15 __ LCD_I00FSTLIC3_3 1/21/05 1700 0 16 233506_6_S___ 1/21/05 1713 0 17 255505 3 S 1/21/05 1726 0 18 233506J _ S ___ 1/21/05 1737 0 19 233506_3_S_MSJ04LSTTC2^8 1/21/05 1754 0 1 10 233506_3^S_MSD_I04LSTTC2_8 1/21/05 1801 0 1n 255506 4 S 1/21/05 1807 0 1 12 233506_5_S__ 1/21/05 1818 0 1 13 233506_7_S___ 1/21/05 1829 0 1 14 233506_8_S___ 1/21/05 1843 0 1 15 233506_9_S__ 1/21/05 1858 0 1 16 233506 10 S 1/21/05 1909 0 1 17 233506_11_S__ 1/21/05 1920 0 1 18 __ CCVJQ4L5TTC2_ 1/21/05 1942 0 1 19 ___CCB__ 1/21/05 1945 0 1 20 233506_12_S__ 1/21/05 1952 0 1 21 233506_13_S___ 1/21/05 2007 0 1 22 233506J 4 _ S __ 1/21/05 2021 0 1 23 233506_15_S___ 1/21/05 2033 0 1 24 233506^16_s__ 1/21/05 2045 0 1 25 233506_17_S__ 1/21/05 2057 0 1 26 233 5 0 6 J 8 S __ 1/21/05 2107 0 1 27 233506J9_S___ 1/21/05 2120 0 1 2 ,__ CCV_l04LSTTC2_ 1/21/05 2133 0 Page 1 -- STL Chicago 51 *** RUN LOG CV2 ) 1/28/05 13:03 STL Chicago Page 2 52 ft** QC Summary *** CV2 ) Total Organic Carbon (Soils) Report Date: 1/28/05 13:01 Method Code..: TOCS Batch Code...: 140127 Status..... RVWD Batch Date...: 01/24/05 Batch Time...: 2239 User Name______ : rnm QC Code.... ...: TOCS Calc Code..... : TOCS Location Code..: 57222 Equipment Code.: Import code____: Grp Smp SampLe id Pos Test Result Known Original Alternate QC Res F QC Res F 1 2 ___ICV_I04LSTTC2_ 1 TOC 2033.16 2000 102 1 3 __ ICB_ 1 TOC -3.55 1 4 ,__ LCSJQ0FSTLK3J 1 TOC 4013.62 4780 -3.55 84 1 5 __ LCD_I OOFSTLK3_3 1 TOC 4204.36 4780 -3.55 4013.62 88 5 1 9 233506_3_S_MSJ04LSTTC2_8 5 TOCAi/2 9686.34 2000 4978.99 92 1 10 233506^3_S_MSD_I04LSTTC2_8 1 18 .__ CCV_JQ4LSTTC2_ 5 TQCAV2 9583.28 1 TOC 1994.52 2000 2000 4978.99 9686.34 97 100 18.9 - 1 19 __ CCB__ 1 TOC -3.98 1 28 ___CCV_I04LSTTC2_ 1 TOC 2052.63 2000 103 1 29 ___CCB__ 1 TOC 3.33 STL Chicago Page 1 et *** RAW TEST DATA #** V2 ) Total Organic Carbon (Soils} Method Code..: TOCS Batch Code__ : 140127 Status.... RAW Batch Date...: 01/24/05 Batch Time...: 2239 User Name___ : rnm SAMPLE: Grp Pos SampLe ID 11 ICAL 12 ICV I04LSTTC2 13 ICB 14 LCS IQQFSTLK3 3 15 LCD I00F5TLK3 3 1 6 233506 6 S 1 7 233505 3 S 1 8 233506 3 S 1 9 233506 3 S MS I04LSTTC2 8 1 10 233506 3 S MSD I04LSTTC2 8 1 11 233506 4 S 1 12 233506 5 S 1 13 233506 7 S 1 14 233506 8 S 1 15 233506 9 S 1 16 233506 10 S 1 17 233506 11 S 1 18 CCV I04LSTTC2 1 19 CCB 1 20 233506 12 S 1 21 233506 13 S 1 22 233506 14 S 1 23 233506 15 S 1 24 233506 16 S 1 25 233506 17 S 1 26 233506 18 S 1 27 233506 19 S 1 28 CCV 104LSTTC2 1 29 CCB QC Code....... : TOCS Calc Code.... .: TOCS Location Code..: 57222 Dilution TOC mg/Kg T0C2 mg/Kg Report Date: 1/24/05 23:07 Equipment Code.; import Code___ : TOC3 mg/Kg TOC4 mg/Kg TQCAV2 mg/ICg 2033.16 -3.55 4013.62 4204.36 29617.40 15624.60 5566.22 9686.34 9583.28 1519.47 786.08 5113.65 2005.07 1921.46 1168.77 23659.84 1994.52 -3.98 11049.30 3014.50 1979.26 1409.13 578.72 5986.11 571.29 963.29 2052.63 -3.33 24872.29 10795.43 4391.76 762.24 418.61 4046.57 1693.53 1864.13 1006.59 26215.18 10499.02 1928.52 2226.09 1335.91 319.53 5356.64 762.67 575.74 27244b85 13210.01 4978.99 9686.34 9583.28 1140.86 602.35 4580.11 1849.30 1892.80 1087.68 24937.51 10774.16 22417012..5618 1372.52 449.12 5671.38 666.98 779.51 STL Chicago Page 1 e4 *** RAW TEST DATA *** (V2 ) Total Organic Carbon (Soils) Method Code Batch Code. Status.,,,,.. TOCS 140127 RAW Batch Date.. : 01/24/05 Batch Time., : 2239 User Name... : rnm SAMPLE: Grp Pos Sample ID 11 ICAL 12 ICV I04LSTTC2 13 ICB 14 LCS I00FSTLK3 3 15 LCD I0DFSTLK3 3 1 6 233506 6 S 1 7 233505 3 S 1 a 233506 3 S 1 9 233506 3 S MS I04LSTTC2 8 1 10 233506 3 S MSD I04LSTTC2 8 1 n 233506 4 S 1 12 233506 5 S 1 13 233506 7 S 1 14 233506 3 S 1 15 233506 9 S 1 16 233506 10 S 1 17 233506 n S 1 18 CCV I04L5TC2 1 19 CCS 1 20 233506 12 S 1 21 233506 13 S 1 22 233506 14 S 1 23 233506 15 S 1 24 233506 16 S 1 25 233506 17 S 1 26 233506 10 S 1 27 233506 19 S 1 28 CCV I04LSTTC2 1 29 TM CCB1 0c code.., ,___ : TOCS Calc Code..... : TOCS Location Code..: 57222 Dilution TQCAV3 mg/Kg TOCAV4 mg/Kg Report Date: 1/24/05 23:07 Equipment Code.: Import code...f; TOCR1 ug T0CR2 ug TDCR3 ug 101,6581 -0.5684 103.9527 129.9146 213.2453 201.5574 59.0019 189.8522 202.2072 31.7570 33.6442 207.1029 102.8601 118.9383 66.1523 257.8923 99.7258 -0.6372 155.7952 206.4931 94.6084 72.7111 29.5145 150.8500 23.1942 32.5469 102.6316 -0.5328 161.6699 68.0112 95.3011 23,0196 23.5676 150.5324 100.9346 94.8841 78.2121 133.6974 86.0920 79.8409 117.7600 84.4298 28.2141 137.1299 44.0822 36.5594 STL Chicago Page 2 *** RAW TEST DATA ** CVS ) Total Organic Carbon (Soils) Method Cade..: TOCS Batch Code... : 140127 Status..... . : RAW Batch Date.. : 01/24/05 Batch Time.. : 2239 User kme,... : rnm SAMPLE: Grp Pos Sample ID 11 ICAL 12 ICV I04LSTC2 13 ICB 14 LCS I00FSTLK3 3 15 LCD I00FSLK3 3 1 6 233506 6 S 1 7 233505 3 S 1 8 233506 3 S 1 9 233506 3 S MS I04LSTTC2 8 1 10 233506 3 S MSD I04LSTC2 8 1 11 233506 4 S 1 12 233506 5 S 1 13 233506 7 S 1 14 233506 $ 1 15 233506 9 S 1 16 233506 10 S 1 17 233506 11 $ 1 18 CCV I04LSTTC2 1 19 CCB 1 20 233506 12 S 1 21 233506 13 S 1 22 233506 14 S 1 23 233506 15 S 1 24 233506 16 S 1 25 233506 17 S 1 26 233506 18 S 1 27 233506 19 S 1 28 CCV I04LSTTC2 1 29 CCB QC Code..... .. : TOCS calc Code..... : TOCS Location Code.. : 57222 Di Lution TQCR4 ug WT1 g Report Date: 1/24/05 23:07 Equipment Code Import Code*.. WT2 UT3 WT4 g gg 0.05 0.16 0.0259 0.0309 0.0072 0.0129 0.0106 0.0196 0.0211 0.0209 0.0428 0.0405 0.0513 0.0619 0.0566 0.0109 0.05 0.16 0.0141 0.0685 0.047B 0.0516 0.0510 0.0252 0.0406 0.0331 0.05 0.16 0.0065 0.0063 0.0217 0.0302 0.0563 0.0372 0.0596 0.0509 0.0777 0.0051 0.0082 0.0414 0.0529 0.0632 0.0883 0.0256 0.0578 0.0635 STL Chicago Page 3 *** RAW TEST DATA *** (VZ ) Total Organic Carbon (Soils) Method Code.,: TOCS Batch C o d e ...: 140127 Status......: RAW Batch Date...: 01/24/05 Batch Time :2239 User Warne :rnm SAMPLE: Grp Pos Sample ID 11 ICAL 12 ICV I04LSTTC2 13 ICB 14 LCS IOOFSTLK3 3 15 LCD I00FSTLK3 3 1 6 233506 6 S 1 7 233505 3 S 1 6 233506 3 S 1 9 233506 3 S MS I4LSTTC2 8 1 10 233506 3 S MSD 04LSTTC2 8 1 11 233506 4 S 1 12 233506 5 S 1 13 233506 7 S 1 14 233506 8 S 1 15 233506 9 S 1 16 233506 10 S 1 17 233506 11 S 1 18 CCV I04LSTTC2 1 19 COB 1 20 233506 12 S 1 21 233506 13 S 1 22 233506 14 S 1 23 233506 15 S 1 24 233506 16 S 1 25 233506 17 S 1 26 233506 18 S 1 27 233506 19 S 1 2S CCV I04LSTTC2 1 29 CCB QC code...,___ : TOCS Calc Code......: TOCS Location Code..: 57222 D luti on DL FAC M/A TCS mg/Kg Report Date: 1/24/05 23:07 Equipment Code,: Import Code____: TCS2 mg/Kg TCSAV2 mg/Kg TICS mg/Kg 3,2000 1.0000 6.1776 5.1780 23.3577 16.6667 9.9071 8.1633 7.5829 6.2622 3.2291 4.1184 2.8855 2,8369 2.3827 20.0000 3.2000 1.0000 14.3498 2.9117 3.1778 2.7875 2.2972 6.2992 3.2520 3.3126 3.2000 1,0000 STL Chicago --- Page 4 7 Calibration Report Print Date/Time: 2005/01/21 21:37:01 Cal. Curve I D : Created: Calibration Factor Y Intercept (b): r-squared: SOILCURVE 01/17/2005 (m) : 8.538e+Q4 436425 0*99800 11:33 Standard ID 0 ugram C lQugramC 20 ugram C 40 ugram C 80 ugram C 120 ugram C 200 ugram C 300 ugram C 400 ugram C Y Raw Data -4530 1085240 1870210 3806480 7357282 11114689 18428840 26478564 33682344 X Expected ug C 0*000 10.000 20.000 40.000 80.000 120.000 200.000 300.000 400.000 Measured Message ug C -5.165 No Sample Det 7.599 16.794 39.473 81.062 125.072 210.740 305.025 389.401 Date & Time 01/17/2005 09:53 01/17/2005 10:15 01/17/2005 10:26 01/17/2005 10:34 01/17/2005 10:45 01/17/2005 10:58 01/17/2005 11:07 01/17/2005 11:15 01/17/2005 11:32 STL Chicago 58 Multiple Analysis Report Print Date/Time: 2005/01/21 21:39:44 Sample ID Result std. Dev. RSD Mode ALT ICV 101.6581 ICB -0,5684 DCS 103,9527 L C D , ............ ....................... 129.9146.,. 233506-6 474.9272 233506-6 213,2453 2 3 3 5 0 6 - 6 ................................ 161,6699. . . 233505-3 201,5574 233505- 3 68.0112 2 3 3 5 0 6 - 3 ............................... 59,0019... 233506-3 95.3011 233506-3 MS 189.8522 233506-3 M S D ........................... 202.2072.,, 233506-4 31,7570 233506-4 23,0196 2 3 3 5 0 6 - 5 ................................ 33.6442,,. 233506-5 23.5676 233506-7 207.1029 2 3 3 5 0 6 - 7 ................................ 150.5324... 233506-8 102.8601 233506-8 lb0.9346 2 3 3 5 0 6 - 9 ................................ 118.9383. . . 233506-9 94.8841 233506-10 66.1523 2 3 3 5 0 6 - 1 0 .............................. 78,2121... 233506-11 257.8923 233506-11 413.2112 2 3 3 5 0 6 - 1 1 ............................... 133.6974. . . CCV 99.7258 CCB -0,6372 2 3 3 5 0 6 - 1 2 ............................... 155,7952.., 233506-12 86.0920 233506-13 206.4931 2 3 3 5 0 6 - 1 3 .............................. 79.8409.,. 233506-14 94.6084 233506-14 117.7600 233506-15 ................. 72.7111... 233506-15 84.4298 233506 -16 29.5145 2 3 3 5 0 6 - 1 6 .............................. 28.2141... 233506-17 150.8500 233506-17 137,1299 2 3 3 5 0 6 - 1 8 .............................. 23.1942... 233506-18 44.0822 233506-19 32.5469 233506-19 .............................. 36.5594... CCV 102.6316 CCB -0.5328 TC TC TC ...TC TC TC . . . ..TC TC TC .. . . .TC TC TC ,. . ,,TC TC TC .. .,,TC TC TC .. . ,.TC TC TC . . . ..TC TC TC ., . . .TC TC TC .. . ..TC TC TC ., . ..TC TC TC .. . . ,TC TC TC .. , ,,TC TC TC . . . .,TC TC TC ...TC TC TC .. , ,,TC TC TC STL Chicago en Detailed Analysis Report Print Date/Time: 2005/01/21 21i39:46 Sample ID : ICV Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Rep # ppm C ug C Raw Data 1 101.6581 101.6581 9115704 Mode: Filename: Timestamp: Sample Type: TC 01211636 - 0l/2l/20tfg.JL6^43J) Cal. Verification Beginning Baseline 2.17B Ending Baseline 3,174 Integration Time 346 Sample ID: 1CB Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Rep # ppm C ug C Raw Data 1 -0.5684 -0.5684 -22765 Last Message: No Sample Detected Mode: TC Filename: 01211643 Timestamp: 01/21/200 Sample Type: Sample Beginning Baseline 2.887 Ending Baseline 2,559 Integration Time 120 Sample ID: LCS Method: boat Cal. Curve: SOILCURVE Operator ID : CAROL Rep # ppm C ug C Raw Data 1 103. 9527 103.9527 8900951 Mode: Filename: Timestamp: Sample Type: TC 01211649 0 1 / 2 1 / 2 0 0 ^ 1 6 : 54\ Sample ^^ Beginning Baseline 2,377 Ending Baseline 3. 376 Integration Time 263 Sample ID: LCD Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Rep # ppm C ug C Raw Data 1 129.9146 129.9146 11117508 Mode: TC Filename: 01211654 Timestamp: 01/21/2005 'T:00S Sample Type: Sample Beginning Baseline 2.703 Ending Baseline 3.699 Integration Time 273 Sample ID: ^ ^ 2 T T ! Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Rep # ppm C ug C Raw Data 1 474.9272 474.9272 40573712 Mode': TC Filename: 01211700 Timestamp: 01/21/2005*^17:061 ample Type: Sample Beginning Baseline 3,059 EK Baseline 4.057 Integration Time STL Chicago /A Sample ID: 233506-6 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Rep # ppm C ug C Raw Data 1 213,2453 213.2453 18232048 Mode: TC Filename: 0 1 2 1 1 7 0 7 ^ ^ -- __ Timestamp: 01/21/20^5^17:1^ Sample Type: Sample y Beginning Baseline 3.593 Ending Baseline 4.591 Integration Time 333 Sample ID: 233506-6 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Rep # ppm C ug C 1 161.6699 161.6699 Raw Data 13828681 Mode: TC \ Filename: 01211715 Timestamp: 0 1 / 2 1 / 2 0 0 ^ 177l9"'\ Sample Type: Sample Beginning Baseline 3,184 Ending Baseline 4.179 Integration Time 259 Sample ID: 2 3 3 5 0 ^ 3 Method: boat \ Cal. Curve: S O I L C U R V E \ Operator ID: CAROL s` Rep # ppm C ug C Ra^w, Data 1 21.5574 201.5574 1723414, Sample ID: 233505-3 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Rep # ppm C ug C Raw Data 1 6 8 .0112 6 8 .0112 5832365 Mode : TC Filename: 0 1 2 1 172 0 Timestamp: 0 1 / 2 l / 2 0 o C l 7 :26 Sample Type: Sample '--- Beginning Baseline 2.823 Ending Baseline 3.821 Integration Time 294 X. X ,v X Mode : TC ' "Filename : 01211727 T n ^ s t a m p : 01/21/2005 Sample Type : Sample 17:31 Beginning Baseline 3.022 Ending Baseline 4,0lfe Integration Time 231 Sample ID: Method: Cal. Curve : Operator ID 233506-3 boat SOILCURVE CAROL Rep # ppm C ug C Raw Data 1 59.0019 59.0019 5063184 Mode : Filename : Timestamp: Sample Type TC 01211733 01/21/200 Sample Beginning Baseline 2.674 Ending Baseline 3.668 Integration Time 244 Sample ID: 233506-3 Mode : TC S TL Chicago 1 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Rep # ppm C ug C Raw Data 1 95*3011 95.3011 8162301 Sample ID: 233506-3 MS Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Rep # ppm C ug C Raw Data 1 139.8522 139.8522 16234814 Sample ID: 233506-3 M S D Method: boat Cal. Curve : SOILCURVE Oper a tor ID: CAROL Rep # ppm C ug C Raw Data 1 202.2072 202.2072 17289642 Sample ID: Method: Cal. Curve: Operator ID: 233506-4 boat SOILCURVE CAROL Rep # ppm C ug C Raw Data 1 31.7570 31.7570 2737092 Sample ID: Method: Cal. Curve : Operator ID 233506-4 boat SOILCURVE CAROL Rep # ppm C ug C Raw Data 1 23.0196 23.0196 1991115 Sample ID: Method: Cal. Curve : Operator ID: 233506-5 boat SOILCURVE CAROL Filename : 01211740 Timestamp: 01/21/2005pT77 Sample Type: Sample Beginning Baseline 2.483 Ending Baseline 3.482 Integration Time 310 Mode : Filename : Timestamp: Sample Type: TC 01211748 01/21/2005^17:54 Sample Beginning Baseline 2.498 Ending Baseline 3.497 Integration Time 350 Mode : Filename : Timestamp: Sample Type: TC 01211756 0 1 /21/200(5 Sample ^ 18:01 --- ^ Beginning Baseline 3.325 Ending Baseline 4.322 Integration Time 277 Mode : Filename: Timestamp: Sample Type TC 01211803 01/21/205 Sample 18:07 Beginning Baseline 2.751 Ending Baseline 3.747 Integration Time 224 Mode: Filename: Timestamp: Sample Type: TC 01211808 01/21/2005 Sample 18:12 Beginning Baseline 3.051 Ending Baseline 4.049 Integration Time 194 Mode : TC Filename : 01211813 Timestamp: 01/21/200(5 Sample Type : Sample 18:18 STL Chicago Rep # 1 ppm C 33.6442 ug C Raw Data 33.6442 2898216 Beginning Baseline 2*411 Ending Baseline 3.410 Integration Time 230 Sample ID: 233506-5 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: Filename: Timestamp: Sample Type: Sample TC 01211819 01/21/200518:23 Rep # 1 ppm C 23.5676 ug C Raw Data 23,5676 2037903 Beginning Baseline 2.483 Ending Baseline 3,481 Integration Time 205 Sample ID: Method: Cal, Curve : Operator ID 233506-7 boat SOILCURVE CAROL Rep # ppm C ug C Raw Data 1 207.1029 207.1029 17707628 Mode : Filename : Timestamp : Sample Type TC 01211823 01/ 21/200 Sample Beginning Baseline 2*500 Ending Baseline 3.497 Integration Time 293 Sample ID: Method: Cal, Curve : Operator ID 233506-7 boat SOILCURVE CAROL Rep # ppm C ug C Raw Data 1 150.5324 150.5324 12877798 Mode: Filename: Timestamp: Sample Type TC 01211831 01/21/2005 Sample 18:36 Beginning Baseline 2.507 Ending Baseline 3.505 Integration Time 281 Sample ID: Method: Cal. Curve : Operator ID 233506-8 boat SOILCURVE CAROL Rep # ppm C ug C Raw Data 1 102.8601 102,8601 8807669 Mode : Filename : Timestamp: Sample Type TC 01211837 01/21/2005(^18:43) Sampl e ...^ Beginning Baseline 2,302 Ending Baseline 3*302 Integration Time 268 Sample ID: Method: Cal. Curve : Operator ID: 233506-8 boat SOILCURVE CAROL Rep # ppm C ug C Raw Data Mode : Filename : Timestamp: Sample Type TC 01211847 01/21/2005 Sample 18:52 Beginning Ending Integration STL Chicago 6% 1 100.9346 100.9346 0643275 Sample ID; 233506-9 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Rep # ppm C ug C Raw Data 1 118.9383 118.9383 10180378 Sample ID: 233506-9 Method: boat Cal. Curve: SOILCURVE Operator ID; CAROL Rep # ppm C ug C Raw Data 1 94.8841 94.8841 8126704 Sample ID: 233506-10 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Rep # ppm C ug C Raw Data 1 66.1523 66.1523 5673664 Sample ID: 233506-10 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Rep # ppm C ug C Raw Data 1 78.2121 78.2121 6703290 Sample ID: Method: Cal, Curve : Operator ID: 233506-11 boat SOILCURVE CAROL Rep # ppm C ug C Raw Data 1 257.8923 257.8923 22043884 Baseline 1.992 Baseline 2.990 Time 275 Mode: Filename: Timestamp: Sample Type: TC 01211853 01/21/200^18:58 N Sample Beginning Baseline 2.442 Ending Baseline 3.438 Integration Time 282 Mode: TC Filename: 01211858 Timestamp: 01/21/2005 19:03 Sample Type: Sample Beginning Baseline 2.658 Ending Baseline 3.655 Integration Time 251 Mode: TC Filename: 01211904 ^ -- Timestamp: 01/21/200^^19:09^) Sample Type: Sample Beginning Baseline 2.519 Ending Baseline 3.518 Integration Time 267 Mode: TC Filename: 01211909 Timestamp: 01/21/2005 Sample Type: Sample 19:14 Beginning Baseline 2.492 Ending Baseline 3.489 Integration Time 248 Mode : Filename : Timestamp: Sample Type TC 01211915 0l/2l/2005(l9:2C). Sample Beginning Baseline 2.563 Ending Baseline 3.563 Integration Time 295 STL Chicago 64 Sample ID^--^33506-ll Method: C a l , C u r v e : SOILCUHA?^-- Operator ID: CAROL Rep # ppm C ug C Raw Data 1 413.2112 413.2112 35304576 Sample ID: 233506-11 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Rep # ppm C ug C Raw Data 1 133.6974 133,6974 11440474 Sample ID: CCV Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Rep # ppm C ug C Raw Data 1 99.7258 99.7258 8950736 Sample ID: CCB Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Rep # ppm C ug C Raw Data 1 -0.6372 -0.6372 -28635 Last Message: No Sample Detected Sample ID: 233506-12 Method: boat Cal. Curve : SOILCURVE Operator ID: CAROL Rep # ppm C ug C Raw Data 1 155.7952 155,7952 13327117 Mode: TC Filename: 01211922 Timestamp: 01/21/2005 19:28 Sample Type: Sample Begiiirtirig Ending Baseline^'-^B^seline 2.600 ^3v^97 Integration Time 328 Mode: Filename: Timestamp: Sample Type: TC 01211929 01/21/2005 Sample 19:34 Beginning Baseline 2.947 Ending Baseline 3.947 Integration Time 254 Mode: Filename: Timestamp; Sample Type: TC 01211936 0 1 / 2 1 / 2 0 0 ^ 1 9 :42j Cal. Verification Beginning Baseline 2.293 Ending Baseline 3.292 Integration Time 310 Mode: Filename: Timestamp: Sample Type: TC 01211943 ^ ^ 0 1 / 2 1 / 2 0 0 5 ^ 1 9 :45_J Sample ^ Beginning Baseline 2.685 Ending Baseline 2.279 Integration Time 120 Mode : Filename : Timestamp: Sample Type: TC 01211947 01/21/2005^19:52 Sample Beginning Baseline 2,174 Ending Baseline 3,171 Integration Time 266 STL Chicago A* Sample ID: 233506-12 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Rep # ppm C ug C 1 86 *092 0 86.092 0 Raw Data 73 76053 Sample ID: 233506-13 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Rep # ppm C ug C Raw Data 1 206.4931 206.4931 17655568 Sample ID; Method: Cal. Curve : Operator ID: 233506-13 Mode: boat SOILCURVE CAROL TC Rep # ppm C ug C Raw Data 1 79.8409 79.8409 6S42358 Sample ID: Method: Cal. Curve: Operator ID: 233506-14 boat SOILCURVE CAROL Rep # ppm C ug C Raw Data 1 94.6084 94,6084 8103166 Sample ID: 233506-14 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Rep # ppm C ug C Raw Data 1 117.7600 117.7600 10079786 Sample ID; 233506-15 STL Chicago Mode: Filename: Timestamp: Sample Type: TC 01211956 01/21/2005 Sample 20:00 Beginning Baseline 3.565 Ending Baseline 4.565 Integration Time 225 Mode: Filename : Timestamp: Sample Type: TC 01212002 0l/2l/2QQ$f 20:07 Sample ^ -- Beginning Baseline 2.890 Ending Baseline 3.884 Integration Time 275 Filename: 01212008 Timestamp: 01/21/2005 20:13 Sample Type; Sample Beginning Baseline 2.515 Ending Baseline 3.509 Integration Time 242 Mode: Filename : Timestamp; Sample Type: TC 01212015 sz-- - 01/21/200^ 20:^2 Sample '" ^ Beginning Baseline 2.123 Ending Baseline 3.118 Integration Time 279 Mode: TC Filename: 01212022 Timestamp; 01/21/2005 20:27 Sample Type: Sample Beginning Baseline 2.197 Ending Baseline 3.195 Integration Time 267 Mode : TC Method; boat Cal. Curve: SOILCURVE Operator ID: CAROL Rep # ppm C ug C Raw Data 1 72 *7111 72.7111 6233637 Sample ID: Method: Cal. Curve : Operator ID: 233506-15 boat SOILCURVE CAROL Rep # ppm C ug C Raw Data 1 84.4298 84.4298 7234142 Sample ID: Method: Cal. Curve : Operator ID: 233506-16 boat SOILCURVE CAROL Rep # ppm C ug C Raw Data 1 29,5145 29.5145 2545629 Sample ID: Method: Cal. Curve : Operator ID: 233506-16 boat SOILCURVE CAROL Rep # ppm C ug C Raw Data 1 28 2141 28.2141 2434601 Sample ID: 233506-17 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Rep # ppm C ug C Raw Data 1 150.8500 150.8500 12904911 Sample ID: 233506-17 Method: boat Cal. Curve : SOILCURVE Operator ID: CAROL Filename : 01212028 Timestamp: 01/21/2005 20:33 Sample Type: Sample Beginning Baseline 2,127 Ending Baseline 3.126 Integration Time 257 Mode : Filename : Timestamp: Sample Type TC 01212036 01/21/2005 Sample 20:40 Beginning Baseline 2.092 Ending Baseline 3.088 Integration Time 255 Mode : Filename : Timestamp: Sample Type: TC 01212041 ^ 01/21/20^?20:45 Sample ^ ^ Beginning Baseline 2.493 Ending Baseline 3.489 Integration Time 221 Mode : Filename : Timestamp : Sample Type: TC 01212046 01/21/2005 Sample 20:50 Beginning Baseline 2.519 Ending Baseline 3,517 Integration Time 211 Mode: TC Filename : 01212052 --\ Timestamp: 01/21/200^ 20:57/ Sample Type: Sample Beginning Baseline 2.015 Ending Baseline 3.011 Integration Time 288 Mode: Filename: Timestamp: Sample Type TC 01212058 01/21/2005 Sample 21:03 STL Chicago 7 Rep # ppm C 1 137 *1299 ug C Raw Data 137 *1299 11733527 Sample ID: Method: Cal. Curve : Operator ID 233506-18 boat SOILCURVE CAROL Rep # ppm C ug C Raw Data 1 23.1942 23.1942 2 006019 Sample ID: 233506-18 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Rep # ppm C ug C Raw Data 1 44.0822 44.0822 3789378 Sample ID: 233506-19 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Rep # ppm C ug C Raw Data 1 32.5469 32.5469 2804525 Sample ID: Method: Cal. Curve : Operator ID 233506-19 boat SOILCURVE CAROL Rep # ppm C ug C Raw Data 1 36.5594 36,5594 3147102 Sample ID: Method: Cal. Curve : Operator ID: ccv boat SOILCURVE CAROL Rep # ppm C ug C Raw Data STL Chicago Beginning Baseline 2.372 Ending Baseline 3.372 Integration Time 272 Mode : Filename : Timestamp: Sample Type TC 01212104 01/21/2005 $1:07 Sample Beginning Baseline 2.810 Ending Baseline 3.805 Integration Time 196 Mode: TC Filename: 01212111 Timestamp: 01/21/2005 21:14 Sample Type: Sample Beginning Baseline 6.872 Ending Baseline 7.855 Integration Time 180 Mode: Filename: Timestamp: Sample Type: TC 01212116 01/21/2005^ 21:20. Sample Beginning Baseline 2.227 Ending Baseline 3.224 Integration Time 219 Mode: Filename : Timestamp: Sample Type TC 01212122 01/21/20 Sample Beginning Baseline 2,224 Ending Baseline 3,223 Integration Time 222 Mode: Filename : Timestamp: Sample Type: TC 01212128 ^ ""''"N 01/21/200 21:33 Cal. Vrificatif Beginning Baseline Ending Baseline Integration Time 68 1 102.6316 102 *6316 9198821 Sample ID: CCB Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Rep # ppm C ug C Raw Data 1 -0.5328 -0.5328 -19725 Last Message: No Sample Detected 2.149 3.148 260 Mode: Filename: Timestamp: Sample Type: TC 01212134 01/21/2005 Sample 21:36 Beginning Baseline 2.137 Ending Baseline 1.909 Integration Time 120 STL Chicago STL Chicago TOC in Soils Mothod: Uoyd Kahn ^age No InstruBmoeonkt:N_o,: Calculation*; TOC (mg/kg) ug C / grama sample Date of StaLnadbaNredt CBuartcvhe:: Book # Pat MS, MSO Known Cone, {mg/kg) * 100 ug / grame sample MS, MSD Observed (mg/kg) ug C / grams sample MS, MSD Ree. (observed mo/ko - avo, sample result (mo/kail x 100 known concentration in mg/kg Standard Traceability: (Note: Working Standards a n prepared daily from the noted Stock Solutions.) Stock I (CurveP t e A S T n r I - Stock 11(ICV/CCV) LC5 Source ipX C Q F S t" iK hCS True Value 4-1P-T)Uoj Accaotanca Range 5 3 fc - H f Sample ID: Tl jei _vV Sample W *ight (fl) I ug C 1 /J&f&u*5 ~ ~ I'Q I . ^~D f t l " Commenta: 0 .0 5 i^ >.-omit /2 ,SL<?r)l l .^ H L liir a g p Prep A n alyst^ ---------------- - V A n a l y a y ^ n b a Y Y YY^lV^Q---- - Reviewed bv: CHUZZ-12-0Sa/B-0S/(H STL Chicago TOC In Soil Pas No,:, Book No.3 126 Method: Lloyd Kahn Instrum ent Fhognix 6Q00 (TQC4) LabNet Batcn.X Categlgtiant= TOC (mg/kg) => ug C / grams sample Date of StCaanndolard Curve: j j i Book # ^ 2 2 t-G Pane# MS, MSD Known Cone, (mg/kg) * 100 ug C / grama sample MS, MSD Observed (mg/kg) u g C f grama sample MS, MSD Rec. * fob sprvyl mg/kQ.^ ayg,.sample result (m qflq ill x 100 known concentration In mg/kg Standard TraceabHIftc (Note: Working Standard* are prepared dally from the noted Stock Solutions.) Stock l (Curve) , . r .stock II (ICV/CCV), TL 1 ^^ LCS Source ID , . LCSTrueValue. ,Acceptance Range. S am p le ID : S am ple W e ig h t (g ) ,0 -0 5 0 3 ugC \ . - l o ... HO - r J i,, <?. 0 l O ^ - -- =l>Jl- - ^ - O j - S t i r --------- i4 a ii'i -'ll Y -_ { IV _ O .0 0 5 I o . g s .: i ?>'?*. i f i m - Y . _ C q j_ . 0 ^ -O ih io Z 'lp C om m ent: . Ha f). C p fiV i _ _ . - i g : . . . . 0 * Q ( j? & o iS lO in - m i , - i 3 ' O . C - l H - _ ~ i`f 0^ _ ~ ih ,0 5 a 3 _ , i n .i^ o o , , - 1 5 , O 0 5 / (/? "7 3 , '< m 0 . G<d 3 hX . fi'-i.'-R R ft- . -H U ). - o . O O lO -- _ # , 9 3 __ - n O ,0 a 5 a _ r5 # S 0 0 - - - o .^ a s to ; -1 3 V .O H M f, 4 _(L 6 5 7 # J S i- i'a ffi 3 3 j< m . 1 'H O i t s a - , Prep Analvsf.e s ^ V- A Reviewed n a - d ? J .,L Date: _____ Date: J m / o i ~ / S V S - 2 l ( ~........... : Date: ` / ' f j l f c f c r 71 STL Chicago TOC In Soils Method: Lloyd Kahn 127 Page No.:,_______ 3 2 5 5Book No.: Instrument: Ph LabNat Batch! Calculation; S C C PCu l^ c T Data of Standard Curve: TOC (mg/kg) ug C / grams sample Book # 3 Paae MS, M5D Known Cone, (mg/kg) 100 ug C / grama sample MS, MSD Observed (mg/kg) ug C / grams sample MS, MSD Rk . * fobserved mo/Kq - avq. sample ragit (ffig/kq)1 x 100 known concentration in mg/kg Standard Trag$flftiltty; (Note: Working Standards are prepared daily from the noted Stock Solutions,) Stock I (Curve}___________________ Stock II (ICV/CCV) __________________ LCS Source ID ___________ LCS True Value Acceptance Range Sample ID: J> _ - n CCJ <XP>. V X X . r Sample Weight (g) ugC 0 .0 3 3 1 0 . C Xo.55 om a its . 3 la l Z U n 'M ti :) - 0 . 0,322 Commente: x. -X X \ X ' s. X .\ \ X, \ Prep A n a tv s tfA xP A n a ly s t: Reviewed by: / __y i U r i ------Pv^-Q. ------- Data: f f r 7 ^ Data: l / a l | O T Date: CHIJJ-13-05WB-05/01 %