Document 1kbw1qZowVYZ83v8JJQVwD3K

SEVERN TRENT STL STL Chicago 2 4 1 7 Bond Street University Park, !L 6 0 4 6 6 Tel: /OS 534 5200 Fa*: 70S 534 5211 www.stlinc.com SEVER TRENT LABORAT ANALYTICAL REPORT J O B N U M B E R : 2 3 38i: Prepared"For : W e s L o n S o l u t i o n s i > in: .;1 4 G G ' W e st o n .W a y .;// B u i l d i n g / B p s West. C h e s t e r , PA 1 9 3 8 1 4 9:9 P r o j e c t. ; Coni'.idgnfc'.ia 1 D e c a t u r - F C T n v e s L i g a t i o n A t t e r r i c i --: d a i K e s a r i D a t e : 02/: :/2 0 0 5 Signt ure Na me : Richard C , Wright T i t l e : P r o -je c t M a n a g e r E - M a i l : r w r i g h t@st.l - i n c .c o m T h i s Report. C o n t a i n s Leaders in Environmental Testing Date. STL Chicago 2417 Bond Street University Park, IL 60466 PHO N E : (708) 5 3 4 - 5 2 0 0 F A X . .: (708) 5 3 4 - 5 2 1 1 ) Pages Stvern Treni Laboratories, Inc. WET CHEMISTRY DATA PACKAGE CONFIDENTIAL DECATUR - FC INVESTIGATION JOB# 233857 Data Summary............................................................... 1 Chain of Custody........... .............................................28 Case Narrative............................................................. 34 Raw Data...................................................................... 36 STL Chicago is part of Severn Trent Laboratories, Inc. S A M P L E I N "F O R M A T I Q:n'r.':\r. Date: 02/11/2005 Job Number.; 233857 Customer...: Uestoh Solutions, Inc. Attn...... : Jai Kesari Project Number........ : 20004891 Customer Project ID....: CONFIDENTIAL DECATUR Project Description....: Confidential Decatur - FC Investigation Laboratory ' Sample ID ."Customer. .:i:D- 233857-1 DF8b-SS-1-- 233857-2 DF8b-SS-Q001-0-OQ03 233857-3 DF8b-SS-0002-0-0000 233857-4 DF8b-SS-0002-0-0003 233857-5 DF8b-SS-0003-0-0000 233857-6 DFSb-SS-0003-0-0003 233857-7 DF8b-SS-0004-0-0000 233857-8 D F8b-SS-0004-0-0003 233857-9 D F8b-$$- 0005 -0-0000 233857-10 DF8b-SS-0005-0-0003 233857-11 D F14-SS-0001 -0-0000 233857-12 D F14-SS-0001 -0-0003 233857-13 D F14-SS-0002-0-0000 233857-14 D F14-SS-0002-0- 0003 233857-15 D F14-SS-0003-0-0000 233857-1 D F14-SS-0003-0-0003 233857-17 D F14-SS-0004-0-0000 233857-18 D F14-SS-0004-0-0003 233857-19 233857-2 DF14-SS-0Q5-Q-00O0 DF14-SS-0005-0-0003 Sample. / ''Date/: /..// ; ;;;;;;; Matrix ' sampled Soi l 01/27/2005 Soil 01/27/2005 Soil 01/27/2005 soi l 01/27/2005 Soi l 01/27/2005 Soil 01/27/2005 soi l 01/27/2005 Soi l 01/27/2005 Soil 01/27/2005 soil 01/27/2005 Soil 01/27/2005 soi l 01/27/2005 Soil 01/27/2005 soil 01/27/2005 Soi l 01/27/2005 Soil 01/27/2005 soi l 01/27/2005 Soi l 01/27/2005 Soil 01/27/2005 soil 01/27/2005 Sampled 11:25 11:35 11:15 11:25 11:45 11:55 10:20 11:25 11:35 11:40 13:55 14:05 14:30 14:35 14:10 14:15 14:30 14:40 14:00 14:10 . Date .Received 01/29/2005 01/29/2005 01/29/2005 01/29/2005 01/29/2005 01/29/2005 01/29/2005 01/29/2005 01/29/2005 01/29/2005 01/29/2005 01/29/2005 01/29/2005 01/29/2005 01/29/2005 01/29/205 01/29/2005 01/29/2005 01/29/2005 01/29/2005 lim/ Received 09:00 09:00 09:00 09:00 09:00 09:00 09:00 09:00 09:00 09:00 09:00 09:00 09:00 09:00 09:00 09:00 09:00 09:00 09:00 09:00 Page 1 1 STL Chicago is part of Severn Trent Laboratories, ]nc. Job Humber: 233857 CUSTOMER: Weston Solutions, Inc. - Customer Sample ID: DFBb-SS-0001 -0-0000 Date Sampled...... :01/27/2005 Time Sampled...... :11:25 Sample Matrik ..... :Soi l TEST METHOD Lloyd Kahn PARAMETER/TEST DESCRIPTION Total Organic Carbon (Soils) TOC Average Duplicates, Solid CM LABORATORI TEST RESULTS PROJECT: CONF EDEHTIAL DECATUR Laboratory Sample ED: 33857-1 Date Received........ :01/29/2005 Time Received........ :09:00 Date:02/11/2005 - ATTW: Jai (Cesari . SAMPLE RESULT : o'FLAGS ; 30000 i! MDL ' 91 =P RL 3500 DILUI0W UM ITS t:- BATCH ;:DT PATE/TJME TECH 1 mg/Kg 141662 ; 02/03/05 1009 els i1i1 11 i1 * En Description = Dry IJgt. Page 2 j i 1j STL Chicago is part of Severn Trent Laboratories, Inc. Job Nimber: 233057 CUSTOMER1: Weston Solutions, Inc. Customer Sample ]D D a te S am pled___ __ Time Sairpled..... Sample Matrix.... DFBb-SS-0001-0-0003 01/27/20D5 11:35 Soi L TEST METHOD Lloyd Kahn PARAMETE R/TE ST :DE SCR IP.TION Total Organic Carbon (Soils) TOC Average Duplicates, Solid n LABORATORY TEST RESULTS PROJEOT : :CON F IDENT IAL :DECATUR Laboratory Sample ID 233857-2 Date Received...... 01/29/2005 Time Received...... 09:00 Date:02/11/2005 ATTN: .Jai (Cesari 1 SAMPLE RESULT & FLAGS 10000 MOL 010 RL 3100 DILUTION UNITS :BATCH: BT DATE/TIHE TECH mg/Kg 1^1662 i 02/03/05 102S els * In Description = Dry Wgt. Page 3 STL Chicago is part of Severn Trent Laboratories, ]nc. Job Humber: 233857 CUSTOMER: Weston Solutions, Inc. Customer Saddle ED: DT8b-55-0002-0-0000 Date Sampled...... :01/27/2005 Time Sampled...... :11:15 Sample Matrix..... :Soil TEST METHCti Lloyd Kahn PARAMEER/TEST DESCRIPTION . ! Total Organic Carbon (Soils) TOC Average Duplicates, Soil'd LABORATORY TEST RESULTS PROJECT: CONFIDENTIAL DECATUR Laboratory Sample ID: 233857-3 Date Received........:01/29/2005 Time Received........:09:00 Date:02/11/2005 ATTN : Jai Kesari SAMPLE RESULT G PLAGS ; 28000 MDL 930 fiL 3600 DIU/TJ0H UNITS BATCH DT DATE/TIME :TECH 1 mg/Kg 141662 02/03/05 1107 c ls * In Description = Dry Wgt. 1 j Page 4 i1 i i ____ i STL Chicago is part of Severn Trent Laboratories, ]nc. Job Number: 233357 CUSTOMER: Weston Solutions, Jnc. Customer SampLe ID: OFBb-SS-0002-0-0003 Date Sampled...... :01/27/2005 Time Sampled...... :11:25 Sairple Matrix..... :Soil .-t e s t m e t h o d ; V PARAMETER/TEST DESCRIPTION Lleyd Kahn Total Organic Carbon (Soils) TOC Average Duplicates, Solid Vi LABORATORY TEST RESULTS PROJECT: CONFIDENTIAL DECATUR Laboratory Sample 30: 233857-4 Date Received........ :01/29/2005 Time Received........ :09:00 Date:02/11/2005 ATTN: Jai Kesari : SAMPLE RESULT 29000 FLAGS mdl ' 1200 RL 4600 10]LT]0M UNITS i ;1 mg/Kg j BATCH ;DT .DATE/TIME TECH \ 141665 | 02/03/05 1131 cis i j i * ]n Description = Dry tfgt. Page 5 j ij j j i j STL Chicago is part of Severn Trent Laboratories, [nc. Job Number: 233857 COSTOHER: Weston Spbuti ons , Inc. Customer Sample [D:DF3b-SS-QC'03-0-DOQQ Date Sampled...... :01/27/2005 Time Sampled...... :1t:45 Sample Matrix..... :Soil TEST METHOC Lloyd Kahn !:;PARAMETER/TEST DESCRIPTION Total Organic Carbon (Soils) TOC Average Duplicates, Solid (> LABORATORY TEST RESULTS PROJECT : CONFIDENTIAL DECATUR Laboratory Sample ID: 233857-5 Date Received........ :01/29/2005 Time Received........:09:00 Date:02/11/2005 ATTM: Jai (Cesari i SAMPLE RESULT Q FLAGS 27000 MOL 910 si 3500 d i l u t i o n ; UNITS j BATCH DT ' DATE/TIME ^ TECH 1 mg/Kg !H I 662 :02/03/05 1204 els ! j i 1 1j i1 j * In Description = Dry Wgt. Page 6 j STL Chicago is part of Severn Trent Laboratoriesr ]nc. Job Number: 233357 Customer Sample ID Date Sampled..... Time Sampled..... Sample Matrix.... DF3b-55-0003-0-0003 01/27/2005 11:55 Sol l TEST: METHOD LLoyd Kahn :PARAME TE R/TEST :DES CR1PT 10*1 : Total Organic Carbon (Soils) TOC Average Duplicates, Solid > LABORATORY TEST RESULTS PROJECT' CONFIDENTIAL DECATUR Laboratory Sample ID 233S57-6 Date Received...... 01/29/2005 T ime Recei ved...... 09:00 Date:02/11/2005 ATTN .1a i ri SAMPLE RESULT 0 :FLAGS 14000 HOL 670 rl: 2600 DILUTION: UNITS BATCH DT PATE/TIME TECH mg/Kg ;141662 02/03/05 1225 ;c Ls * In Description = Dry Ugt. Page 7 STL Chicago is part of Severn Trent Laboratories, Inc. Job NLTTiber: 233857 CUSTOMER: Weston Soluti ons, Inc. Customer Sample ID Date Sampled..... Time Sampled..... Sample Hat rix .... D F3b-SS-0004-0-QQ 01/27/2005 1 0 :2D Soi I TEST METHOD Lloyd Kahn :P A RA NET E R/ TES T :DESCRIPTION Total Organic Carbon ISoils) TOC Average Duplicates, Solid LABORATORY TEST RESULTS PROJECT: CONFIDENTIAL DECATUR Laboratory Sample ID: 33857-7 Date Received....... : 01/29/2005 Time Received....... : 09:00 Date:Q2/11/2005 ATTN : .Jai Kesari ! SAMPLE RESULT :Fl a g s : 18000 MOL 670 JRL 2600 DI LU TIOH UNITS BATCH |DT DATE/TIME TECH mg/Kg 141662 ; .02/03/05 1244;cls * in Description = Dry Ugt. Page 8 STL Chicago is part cf Severn Trent Laboratories, Inc. Job Number: 233857 CUSTOMER: Weston Solutions r Inc. Customer Sample ID: DFSb-SS-0004-0-0003 Date Sampled...... :01/27/2005 Time Sanpled...... :11:25 Sairple Matrix..... :Soi L TEST METHOD Lloyd Kahn PARAMETER/TEST DESCRIPTION Total Organic Carbon (Soils} TOC Average Duplicates, Solid 0) LABORATORY TEST RESULTS PROJECT: CONFIDENTIAL DECATUR Laboratory Sample ID: 233857-8 Date Received........ :01/29/2005 Time Received........ :09:00 Date:02/11/2005 ATTN: Jai Kesari SAMPLE RESULT 0 FLAGS 9000 MBL 480 RL 1900 DILUTION UNITS r*" r:b a t c h : Pi DATE/TIME TECH 1 mg/Kg 141662 02/03/05 1312 els i! ! * In Description = Dry Ugt. _I_______ Page 9 |i ____ 11 STL Chicago is part of Severn Trent Laboratories, inc. Job Nunijer: 233857 CUSTOMER: Weston Solutions, Inc. Customer Sairple ID: Df8b-SS-B005-Q-OflOO Date Sampled...... :Q1/27/20G5 Time Sampled...... :11:35 Sairple Matrix..... :Soil TEST METHCO Lloyd Kahn . ! PARAMETER/TEST DESCRIPTION Total Organic Carbon (Soils) TOC Average Duplicates, Solid O H LABORATORY TEST RESULTS PROJECT: CONFIDENTIAL DECATUR Laboratory Sample ID: 233857-9 Date Received....... : 01/29/20C5 Time Received....... : 09:00 Date:02/11/2005 ATTN: Jai Ke s a n SAMPLE RESULT Q FLAGS20000 MDL . 650 RL 2500 IDI LUT]DM UNITS 11 mg/Kg BATCH.: ;dt -- DATE/T[ME TECH 141662 02/03/05 1405 cLs * In Description = Dry Ugt. Page 10 I STL Chicago is part oi Severn Trent Laboratories, Inc, 1 Jab Number: 233S57 ;. CUSTGKER: ;Weston Sotutions , Inc. Customer Sample [D: DF8b-5S-0005-0-0003 Date Sampled...... :01/27/2005 Time Sampled...... :11:40 Sample Matrix..... :Soi l TEST METHOD PARAMETER/TEST DE SCRIPT IOil Lloyd Kahn ! t otaL Organic Carbon {Soils) TOC Average D u p L icates, Solid ! | * In Description = Dry Wgt. LABORATORY TEST RESULTS PROJECT: CONf1DENT[AL DECATUR Laboratory Sample ID: 233857-10 Date Received....... : 01/29/2005 Time Received....... : 09:00 Date:D2/11/2005 ATTN: Jai Kesari SAMPLE RESULT O FLAGS : 7400 ! MDl 640 | jj j i i RL 2500 DILUTION 5 : UM ITS BATCH DT : DATE/TIME TECH 1 ng/Kg 141662 02/D3/Q5 1427 c ls i i 1 j i j1 1 11 i j Page 11 STL Chicago is part of Severn Trent Laboratories, Inc, Job Number: 233857 .CUSTOMER: Weston Solu tions r lno - Customer Sample ID Date Sampled..... Time Sampled..... Sample Matrix.... DF14-SS-0D01 -0-0000 01/27/2005 13:55 Soi l TEST METHOD Lloyd Kahn PARAMETE R/TEST. :D ESCRIPT ]ON Total Organic Carbon (Soils) TOC Average Duplicates, Solid CM H LABORATORY TEST RESULTS PROJC T::CON F IDE NTTAL :DECATUR Laboratory Sample ID 233857-11 Date Received...... Q1/29/2D5 Time Received...... 09:00 Date:02/11/2005 ATTN: Jai Cesari SAMPLE RESULT O FLAGS 9100 :HBL: 390 RL 1500 DILUTION-.. /UNITS; b a t o n ; DT DAT/TEME TECH. mg/Kg 141662 02/03/05 1449 c Is J * In Description = Dry Wgt. Page 12 STL Chicago is part of Severn Trent Laboratories, Inc. Job Number: 233857 CUSTOMER: Ueston Solutions, Inc. Customer Sairple ID Date Sampled..... Time Sampled..... Sample Matrix.... BF14-SS-Q001-0-0003 01/27/2005 14:05 Soi L TEST METH: :PARAMETER/TEST ;DEE CREP1} ON Lloyd Kahn Total Organic Carbon iSai Is) ;TOC Average Duplicates, Solid H LABORATORY TEST RESULTS PROJECT: CONFIDENTIAL DECATUR Laboratory Sample ID 233657-12 Date Received...... 01/29/2005 Time Received.______ 09: DO Date:02/11/2005 ATTN: Jai Kesari SAMPLE: RESULT 7100 FLAGS. MTL 260 RL 1000 DILUTION UNITS : &ATCK DT DATE/1ME TECH. mg/Kg 141662 02/03/05 1501 els In Description = Dry Wgt. Page 13 STL Chicago is part of Severn Trent Laboratories, ]nc. Job Timber: 233B57 CUSTOMER: Ueston Solutions, Inc. Customer Sample ID DF14-55-Q02-0-0000 date Sampled..... 01/27/2005 T ime Sampled..... 14:30 Sample Matrix.... : Sci l TEST METHOD Lloyd Kahn PARAMETER/TEST DESCRIPTION Total Organic Carbon (Soils! TOC Average Duplicates, Solid H LABORATORY TEST RESULTS : PROJECT: CONFIDENTIAL DECATUR Laboratory Sample ID 233357-13 Date Received...... 01/29/2Q05 Time Received...... 09:00 Date:02/11/2UG5 ATTN: Jat Kesari SAMPLE RESULT1 6B00 FLAGS ! MDL 400 :RL 1600 DILUTION LhNTTS --------T-- BATCH DT DATE/T IME TECH mg/Kg 141662 02/03/05 1517 cLs * In Description = Dry Ugt. Page 14 STL Chicago is part of Severn Trent Laboratories, Inc. Job Member: 233857 CUSTOMER: Ueston Solutions, Inc. Customer Sample ]D: DF14-5S-0002-0-IJDC3 Date Sampled...... ;01/27/2005 Time Sampled...... :14:35 Sample Matrix..... ;Soi l LABORATORY TEST RESULTS : : : o:.::: PROJECT: CONFIDENTIAL DECATUR Laboratory Sample ID 233857-14 Date Received...... 01/29/2005 Time Received...... 09:00 Date:02/11/2005 ATTN: Jai Kesan \n H TEST MET HOC.. ;PARANETFR/TEST.DESCRIPTION Lloyd Kahn Total Organic Carbon (Soils) TOC Average Duplicates, Solid SAMPLE: RESULT PLAGS 320 HL 260 RL 1000 DI LUTI ON, UM ITS BATCH &T DATE/TIME TECH 1 mg/Kg !141662 02/03/05 1532 els * In Description = Dry Wgt. Page 15 STL Chicago is part oi Severn Trent Laboratories, Inc. Job Number: 233857 CUSTOMER: Weston Solutions, 1nc. : . Customer Sarr^ale ID: D F 14-SS-0003-0-0000 Date Sampled...... :01/27/2005 Time Sampled...... :14:10 Sample Matrix..... :Soil TEST .METHOD Lloyd Kalin PARAMETER/TEST DESCRIPTION Total Organic Carbon (Soils} TOC Average Duplicates. Solid LABORATORY TEST RESULTS PROJECT: CONFIDENTIAL DECATUR Laboratory Sample 10: 233857-15 Date Received........ :01/29/2005 Time Received........ :09:00 Pate:02/11/2005 ATTN; Jai Kesari vH SAMPLE RESULT 6300 FLACS ; MDL 280 RL 1100 DILUTION UNITS: BATCH DT DTE/TEHE TECH: mg/Kg 141703 02/09/05 1038 cis ]n Description = Dry Wgt. Page 16 STL Chicago is part of Severn Trent Laboratori es, [ne. Job Number: 233B57 CUSTOMER: Weston Solutions, Inc. Customer Sample ID: Df T4-SS-0003-0-0003 Date Sampled...... :01/27/2005 Time Sampled...... :14:15 Sample Matrix..... :Soi l TEST METHOD Lloyd Kahn PARAMETER/TEST DESCRIPTION Total Organic Carbon (Soils} TOC Average Duplicates, Solid A. rH LABORATORY TEST RESULTS PROJECT: CONFIDENTIAL DECATUR Laboratory Sample ID: 233B57-T6 Date Received........ :01/29/2005 Time Received........ :09:00 Date:02/11/2005 ATTN: Jai (Cesari SAMPLE RESULT Q Fiias; ; 5500 MDL 220 RL DILUTION' UNITS BATCH : DE ' DATE/TIME TECH 840 1 mg/Kg 141703 02/09/05 1123 cLs * In Description = Dry Wgt. Page 17 STL Chicago is part of Severn Trent Laboratories, ine. co H * In Description = Dry Wgt. Page 13 STL Chicago is part of Severn Trent Laboratories, Inc. Job Nunber: 233B57 C U S T O M E R :W & t i i t i : i s b El i t i , In c. Cost einer Sample [D Date Sampled..... Time Sampled..... Sample Matrix.... Df K-SS-0004-0-0003 01/27/2005 14:40 Soi L TEST METHOT Lloyd Kahn :PARAHETER/TEST 0 ESCRIPT IOh Total Organic Carbon (Soils) TOC Average Duplicates, Solid LABORATORY TEST RESULTS PROJECT: CONFIDENTIAL DECATUR Laboratory Sample ID 233357-IS Date Received...... 01/29/2005 Time Received...... 09: DO . Date :02/11/2005 :::: ATT.N: Jai Kesari H SAMPLE RESULT 5100 FLAGS MDL 310 at: 1200 DILUTION UNITS BATCH ;DT DATE/TIME TECH mg/Kg 141703 02/09/05 1304 !cIs * In Deaeri pti on - Dry Ugt. Page 19 O * In Description = Dry Ugt. Page 20 STL Chicago is part of Severn Trent Laboratories, Inc. H N * In Description = Dry Wgt. Page 21 STL Chicago is part of Severn Trent Laboratories, Inc. Job Number: 233657 LABORATORY CHRONICLE Date: 02/11/2005 CUSTOMER: Weston Solutions, Inc, Lab ID: 233857-1 METHOD EDD PKG INO (WC> Lloyd Kahn Client ID: DF8b-SS-0001-0-0000 DESCRIPTION Electronic Data Deliverable PKG INO (WET CHEMISTRY: Total Organic Carbon (Soils) Lab ID: 233657-2 Client ID: DF8b-SS-0001-0-0003 METHOD DESCRIPTION Lloyd Kahn TotaL Organic Carbon (Soils) Lab ID: 233857-3 CLient ID: DF8b-SS-0002-0-0000 METHOD DESCRIPTION Lloyd Kahn Total Organic Carbon (Soils) Lab ID: 233657-A Client ID: DF8b-SS-0002'0-0003 METHOD DESCRIPTION Lloyd Kahn Total Organic Carbon (Soils) Lab ID: 233857-5 Client ID: DF8b-SS-0003-0- METHOD DESCRIPTION Lloyd Kahn Total Organic Carbon (Soils) Lab ID: 233857-6 Client ID: DFSb-SS-0003-0-0003 METHOD DESCRIPTION Lloyd Kahn Total Organic Carbon (Soils) Lab ID: 233857-7 Client ID: DF8b-SS-0004-Q-0000 METHOD DESCRIPTION Lloyd Kahn Total Organic Carbon (Soils) Lab ID: 233857-8 Client ID: DF8b-SS-0004-0-0003 METHOD DESCRIPTION Lloyd Kahn Total Organic Carbon (Soils) Lab ID: 233657-9 Client ID: DF8b-SS-0005-0-0000 METHOD DESCRIPTION Lloyd Kahn Total Organic Carbon (Soils) Lab ID: 233657-10 Client ID: DFSb-SS-0005-0-0003 METHOD DESCRIPTION Lloyd Kahn TotaL Organic Carbon (Soils) Lab ID: 233857-11 Client ID: DF14-SS-D001 -0-0000 METHOD DESCRIPTION Lloyd Kahn Total Organic Carbon (Soils) Lab ID: 233857-12 CLient ID: DFU-SS-DDD1-D-0003 METHOD DESCRIPTION Lleyd Kahn Total Organic Carbon (Soils) Lab ID: 233857-13 CLient ID: DFK-SS-002-0-0 METHOD DESCRIPTION Lloyd Kahn TotaL Organic Carbon (Soils) Lab ID: 233857-1A Client ID: DF14-S5-0002-0-0003 METHOD DESCRIPTION Lloyd Kahn Total Organic Carbon (Soils) PROJECT: CONFIDENTIAL DECATUR " ATTN: Jai Kesari Date Recvd: 01/29/2005 SatiipLe Date: 01/27/2005 RUN# BATCH# PREP BT #(S) DATE/TIME ANALYZED 1 1 1 141662 141662 02/03/2005 1009 DILUTION Date Recvd: 01/29/2005 Sample Date: 01/27/2005 RUN# BATCH# PREP BT #(S) DATE/TIME ANALYZED 1 141662 141662 02/03/2005 1028 DILUTION Date Recvd: 01/29/2005 Sample Date: 01/27/2005 RUN# BATCH# PREP BT #(5> DATE/TIME ANALYZED 1 141662 141662 02/03/2005 1107 DILUTION Date Recvd: 01/29/2005 Sample Date: 01/27/2005 RUN# BATCH# PREP BT #(S> DATE/TIME ANALYZED 1 141662 141662 02/03/2005 1131 DILUTION Date Recvd: 01/29/2005 Sample Date: 01/27/2005 RUN# BATCH# PREP BT #(5> DATE/TIME ANALYZED 1 141662 141662 02/03/2005 1204 DILUTION Date Recvd: 01/29/2005 Sample Date: 01/27/2005 RUN# BATCH# PREP BT #(S) DATE/TIME ANALYZED 1 141662 141662 02/03/2005 1225 DILUTION Date Recvd: 01/29/2005 Sample Date: 01/27/2005 RUN# BATCH# PREP BT #(S) DATE/TIME ANALYZED 1 141662 141662 02/03/2005 1244 DILUTION Date Recvd: 01/29/2005 Sample Date: 01/27/2005 RUN# BATCH# PREP BT #(S) DATE/TIME ANALYZED 1 141662 141662 02/03/2005 1312 DILUTION Date Recvd: 01/29/2005 Sample Date; 01/27/2005 RUN# BATCH# PREP BT #<S) DATE/TIME ANALYZED 1 141662 141662 02/03/2005 1405 DILUTION Date Recvd: 01/29/2005 Sample Date: 01/27/2005 RUN# BATCH# PREP BT #<S) DATE/TIME ANALYZED 1 141662 141662 02/03/2005 1427 DILUTION Date Recvd: 01/29/2005 Sample Date: 01/27/2005 RUN# BATCH# PREP BT #<S) DATE/TIME ANALYZED 1 141662 141662 02/03/2005 1449 DILUTION Date Recvd: 01/29/2005 Sample Date: 01/27/2005 RUN# BATCH# PREP BT #<s> DATE/TIME ANALYZED 1 141662 141662 02/03/2005 1501 DILUTION Date Recvd: 01/29/2005 Sample Date: 01/27/2005 RUN# BATCH# PREP BT #(S) DATE/TIME ANALYZED 1 141662 141662 02/03/2005 1517 DILUTION Date Recvd: 01/29/2005 Sample Date: 01/27/2005 RUN# BATCH# PREP BT #(S) DATE/TIME ANALYZED 1 141662 141662 02/03/2005 1532 DILUTION Page 22 22 STL Chicago is part oi Severn Trent Laboratories, Inc, Job Number: 233857 LABORATORY CHRONICLE Date: 02/11/2005 CUSTOMER: Weston Solutions, Inc. . Lab ID: 233857-15 client ID: DF14-SS-0003-0-0000 METHOD DESCRIPTION Lloyd Kahn Total Organic Carbon [Soils) Lab ID: 233357-16 Client ID: DF14-SS-0003-0-0003 METHOD DESCRIPTION Lloyd Kahn Total Orgahie Carbon [Soils) Lab ID: 233857-17 Client ID: DF14-SS-4--OO METHOD DESCRIPTION Lloyd Kahn Total Organic Carbon (Soils) Lab ID: 233857-1& Client ID: DF14-SS-0004-0-0003 METHOD DESCRIPTION Lloyd Kahn Total Organic Carbon (Soils) Lab ID: 233357-19 Client ID: DF14-SS-05--00 METHOD DESCRIPTION Lloyd Kahn Total Organic Carbon (Soils) Lab ID: 233857-20 Client ID: DF14-SS-0005-0-0003 METHOD DESCRIPTION Lloyd Kahn Total Organic Carbon (SoiLs) PROJECT: CONFIDENTIAL DECATUR ATTN; Jai Kesari Date Recvd: 01/29/2005 Sample Date: 01/27/2005 RUN# BATCH# PREP BT #(S) DATE/TIME ANALYZED 1 141703 141703 02/09/2005 1033 Date Recvd: 01/29/2005 Sample Date: 01/27/2005 RUN# BATCH# PREP BT #(S) DATE/TIME ANALYZED 1 141703 141703 02/09/2005 1123 Date Recvd: 01/29/2005 Sample Date: 01/27/2005 RUN# BATCH# PREP BT #(S) DATE/TIME ANALYZED 1 141703 141703 02/09/2005 1236 Date Recvd: 01/29/2005 Sample Date; 01/27/2005 RUN# BATCH# PREP BT #(S) DATE/TIME ANALYZED 1 141703 141703 02/09/2005 1304 Date Recvd: 01/29/2005 Sample Date: 01/27/2005 RUN# BATCH# PREP BT #(S) DATE/TIME ANALYZED 1 141703 141703 02/09/2005 1321 Date Recvd: 01/29/2005 Sample Date: 01/27/2005 RUN# BATCH# PREP BT #(S) DATE/TIME ANALYZED 1 141703 141703 02/09/2005 1336 DILUTION DILUTION DILUTION DILUTION DILUTION DILUTION Page 23 23 Job Number.: 233357 c u s t o m e r :vUeston Solutions, 1nc.';; QUAL I T Y CONTROL RESULTS PROJECT: CONFIDENTIAL DECATUR Report Date.: 02/11/2005 ATTN: J# -;K-e;r-1- Test Method........: Lloyd Kahn :Method Deser iption. Total Organic Carbon (Solls) Parameter........ .. : Organi\c,/Carbon, Tot. \ Batch. ___ 141662 Equipment Code... TC4 .. Analyst. : :els-, Test Code,:. TOC QC Lab ID Reagent Unite ICV 141662-002 IQ5ASTTC2 MB 141662-003 LCS 141662-004 I00FSTLK3 LCD 141662-005 I00FSTLK.3 mg/Kg mg/Kg mg/Kg mg/Kg ccv 141662-016 I05ASTTC2 CCB 141662-017 CCV 141662-016 I05ASTTC2 CCB 141662-017 mg/Kg mg/Kg mg/Kg mg/Kg QC Result QC Result 2061.54 32.00 U 4840.71 6513.46 4840.71 2043.23 32.00 2025.92 32.00 u u True Value 2000.00 4780.00 4780.00 2000.00 2000.00 Qrig. Value QC Calc, F * Limits Date T ime 103 177-16 157.54 u 101 U 136 29 102 101 % 85-115 % 53-140 % 53-140 R 30 % 85-115 % 85-115 02/03/2005 0833 02/03/2005 0346 02/03/2005 0930 02/03/2005 0947 02/03/2005 1349 02/03/2005 1356 02/03/2005 1557 02/03/2005 1600 Test Method Method Descr ption.: Total Organic Carbon (Soil's) Parameter...., QC Lab ID Reagent Uni ts ICV 141703-002 I05ASTTC2 MB 141703-003 LCS 141703-004 IO0FSTLK3 LCD 141703-005 I00FSTLK3 mg/Kg mg/Kg mg/Kg mg/Kg QC Result QC Result 1821.76 32.00 U 4620.49 3491.99 4620.49 CCV 141703-016 I05ASTTC2 CCB 141703-017 CCV 141703-016 I05ASTTC2 CCB 141703-017 mg/Kg mg/Kg mg/Kg mg/Kg 1922-51 32.00 2033.29 32.00 U u Batch.. ___ : 14173 Equipment Code ...,: OC4 Analyst.. /:P.1 Test Code .: TOC True Value 2000.00 4780.00 4780.00 2000.00 2000.00 Qrig. Value QC Cale. F * Limi t Date Time 176.55 170.10 91 U 97 U 73 23 96 102 % 35-115 % 53-140 % 53-140 R 28 % 85-115 % 35-115 02/09/2005 0336 02/09/2005 0842 02/09/2005 0904 02/09/2005 0912 02/09/2005 1412 02/09/2005 1417 02/09/2005 1609 02/09/2005 1612 Test Method.- '.V.V>.: Lloyd Kahn ;Method Description.: Total Organic .Carban (Soils) ..Parameter... ri.'__ _: TOC Average Duplicates QC Lab ID MS 233357-4 MSI) 233357-4 Reagent Uni ta I05ASTTCZ mg/Kg I05ASTTC2 mg/Kg QC Result 43543.81 47833.53 QC Result 43543.81 !Batch........ 141662 .quipaient Code ___ : TQC4 Analyst.'. .: cls . .. : test-Code TOCV2 True Velue 2000.00 2000.00 Or g. Value 23713,13 23713.13 QC Cale. F * Limits Date T ime 77 82 6.3 % 53-140 02/03/2005 1147 % 53-140 02/03/2005 1156 R 30 'Test Method....... -,Lloyd Kahn Method Description. Total Organic Carbon (Soils? Parameter., toc Average Duplicates . . .. ""Batch....... ..... .: 141703 Equipment Code... .: T0C4 Analyst.,.: cls ' Test oder: TQCAV2 QC Lab ID MS 233857-15 MSD 233857-15 Reagent Uni ts I05ASTTC2 mg/Kg I05ASTTC2 mg/Kg QC Result 9888.89 9433.10 QC Result True Value 2000.00 2000.00 Orig. Value 6339.47 6339.47 QC Cale. F * Limits Date Time 72 66 3.7 % 53-140 02/09/2005 1056 % 53-140 02/09/2005 1113 R 30 Page 24 * %=% REC, R=RPD, A=AB$ Diff., D=% Diff. 24 .0 U A L 1 T Y A S S U R A N C E M E T H C'"D S'. R E F E R E N C E S A N D N 0 T: E S Report Oste: 02/11/2QO5 ..... REPORT COMMENTS 1) AIL pages of this report are integral parts of the analytical data. Therefore, this report should be reproduced only In its entirety. 2) Soil, sediment and sludge sample results are reported on a "dry weight" basis except when analyzed for landfill disposal or incineration parameters. All other solid matrix samples are reported on an "as received" basis Unless noted differently. 3) Reporting limits are adjusted for sample size used, dilutions and moisture content if applicable. 4) The test resuLts for the noted analytical method(s) meet the requirements of NELAC. Lab Cert. ID# 100201 5) According to 40CFR Part 136.3, pH, Chlorine Residual and Dissolved Oxygen analyses arc to be performed immediately after aqueous sample collection. When these parameters are not indicated as field (e.g. pH Field) they were not analyzed immediately, but as soon as possible on Laboratory receipt. Glossary of flags, qualifiers and abbreviations (any number of which may appear in the report) Inorganic Qualifiers (Q-Column) U Analyte was not detected at or above the stated Limit. < Not detected at or above the reporting limit. J Result is Less than the RL, but greater than or equaL to the method detection limit. B Result is Less than the CRDL/RL, but greater than or equal to the IDL/MDL. S Result was determined by the Method of Standard Additions. F AFCEE: Result is less than the RL, but greater than or equal to the methoddetection limit, inorganic Flags (FLag Column) IDV,CCV,ICB,CCB,ISA,ISB,CRI,CRA,MRL: Instrument related QC exceed the upper or lower control Limits. * Lcs, LCD, MD: Batch QC exceeds the upper or Lower control limits. + MSA correlation coefficient is less than 0.995. 4 MS, MsD: The analyte present in the original sample is 4 times greater than the matrix spike concentration; therefore, controL limits are not applicable. E SD: Serial dilution exceeds the control Limits. H MB, EB1, EB2, EB3: Batch QC is greater than reporting limit or had a negative instrument reading lower than the absoLute vaLue of the reporting Limit. N Ms, MSD: Spike recovery exceeds the upper or Lower control limits. W AS(GFAA) Post-digestion spike was outside 85-115% control limits. Organic Qualifiers (Q - Column) U Analyte was not detected at or above the stated Limit. ND Compound not detected. J Result is an estimated value below the reporting Limit or a tentatively identified compound (TIC). Q Result was qualitatively confirmed, but not quantified. C Pesticide identification was confirmed by GC/M5. Y The chromatographic response resembles a typical fuel pattern. 1 The chromatographic response does not resembLe a typical fuel pattern. E Result exceeded calibration range, secondary dilution required. F AFCEE:Result is an estimated value below the reporting Limit or a tentativelyidentified compound (TIC) Organic Flags (Flags Column) B MB: Batch QC is greater than reporting limit. * LCS, LCD, ELC, ELD, CV, MS, MSD, Surrogate: Batch QC exceeds the upper or Lowercontrol limits. EBl, EB2, EB3, MLE: Batch QC is greater than reporting Limit A Concentration exceeds the instrument calibration range a Concentration is below the method Reporting Limit (RL) E Compound was found in the blank and sampLe. D Surrogate or matrix spike recoveries were not obtained because the extract was diluted for analysis; also compounds analyzed at a dilution will be flagged with a D. H Alternate peak selection upon analytical review I indicates the presence of an interfence, recovery is not calculated. M Manually integrated compound. P The Lower of the two values is reported wheh the % difference between the results of two GC columns is Page 25 25  U A L:1 T Y A S S U R A R C E M E T H P:'S . RE F E R E U C E N D NOT S Report Date: 02/11/2005 greater than 25%. Abbreviations AS post Digestion Spike (GFAA samples - Sec Note 1 below] Batch Designation given to identi-fy a speci-fie extraction, digestion, preparation set, or analysis set CAP Capillary Column CCB Continuing Calibration Blank CCV Continuing Calibration Verification CF Confirmation analysis of original Cl Confirmation analysis of A1 or D1 C2 Confirmation analysis of A2 or D2 C3 Confirmation analysis of A3 or D3 CRA Low Level Standard Check - GFAA; Mercury CRI Low Level Standard Check - ICP CV Calibration Verification Standard Dil Fac Dilution Factor - Secondary dilution aha lysis D1 Dilution 1 DZ Di Lution 2 D3 Di Lution 3 DLFac Detection Limit Factor DSH Distilled Standard High Level DSL Distilled standard - Low Level DSM Distilled Standard - Medium Level EBl Extraction Blank 1 EB2 Extraction Blank 2 EB3 DI Blank ELC Method Extracted LCS ELD Method Extracted LCD lCAL Initial calibration ICB Initial Calibration Blank ICV Initial calibration Verification IDL Instrument Detection Limit ISA Interference Check Sample A - ICAP ISB Interference Check Sample B - ICAP Job No. The first six digits of the sample ID which refers to a specific client, project and sample group Lab ID An S number unique laboratory identification LCD Laboratory Control Standard Duplicate LCS Laboratory Control Standard with reagent grade water or a matrix free from the analyte of interest MB Method Blank or (PB) Preparation Blank MD Method Duplicate MDL Method Detection Limit MLE Medium Level Extraction Blank MRL Method Reporting Limit Standard MSA Method of Standard Additions MS Matrix spike MSD Matrix Spike Duplicate ND Not Detected PREPF Preparation factor used by the Laboratory's Information Management System (LIMS) PDS Post Digestion Spike (ICAP) RA Re-analysis of original Al Re-analysis of Dl A2 Re-analysis of DZ A3 Re-analysis of D3 RD Re-extraction of dilution RE Re-extraction of original RC Re-extract ion Confirmation RL Reporting Limi t RPD Relative Percent Difference of duplicate (unrounded) analyses RRF Relative Response Factor RT Retention Time Page 26 QUAL T Y A S S U R A N C E M E O ODS .R.:E' . A N D N O T Report Date: 02/11/2005 RTU Retention Time Window Sample Jp A 9 digit number unique for each six digits are referred as the job number SCB Seeded Control Blank SD Seri aL Dilution (Calculated when sample concentration exceeds 50 UCB Unseeded Control Blank ssv Second Source Verification Standard SLCS Solid Laboratory Control Standard(LCS) PHC pH Calibration Check LCSP pH Laboratory Control Sample LCDP pH Laboratory Control Sample Duplicate HDPH pH SatipLe Duplicate MDFP Flashpoint Sample Duplicate LCFP Flashpoint LCS Gl Gel ex Check Standard Range Q-l G2 GeLex Check Standard Range 1-10 GZ Gel ex Check Standard Range 10-100 G4 GeLex Check Standard Range 100-1000 Note 1: The Post Spike Designation on Batch QC for GFAA is designated with an "S" added to the current abbreviation used. EX. LCS S-LCS Post Spike (GFAA); MSS=MS Post Spike (GFAA) Note 2: The HD calculates ah absolute difference (A) when the sample concentration is less than 5 times the reporting limit. The control Limit is represented as +/- the RL. Page 27 27 CHAIN OF CUSTODY 28 CHAIN OF CUSTODY / ANALYSIS REQUEST FORM 2 3 3 8 5 7 Severn Trent Laboratories T: 703-534-5200 F: 708-534-5211 2417 Bond Street University Park, IL 60466 PAGE _j_ o f _ PROJECT INFORMATION Client: Weston Solutions, Inc. 1400 Weston Way, Bldg. 5-2 West Chester, PA 19380 T: 610-701-3761 F: 610-701-7401 Project Manager: Jai Kesari email: Lkesarifo)westo nso Iuti ons.com Project Name: Reference No: Decatur, Alabama 02181-129-081-0001 ANALYSES REQUESTED Sampler: T Frinak, A Murphy 256-552-6189 P.O. #: Quotation #: SAMPLE ANALYSIS ExyLIMS # I f I m. Client Sample Identificati on DF8b SS 0001 0000 DFSb SS 0001 0003 DF8b SS 0002 0000 DF8b SS 0002 0003 DFSb SS 0003 0000 DF8b SS 0003 0003 DFSb SS 0004 0000 DFSb SS 0004 0003 DFSb SS 0005 0000 DFSb SS 0005 0003 Collection Date 27-Jan-05 27-Jan-05 27-Jan-05 2 7-Jan-05 2 7-Jan-05 27-Jan-05 27-Jan-05 27-Jan-05 27-Jan-05 27-Jan-Q5 Collection Time 11:25 11:35 11:15 11:25 11:45 11:55 10:20 11:25 11:35 11:40 X X X Oc'oS. oc Z tJ Sample Matrix SOIL SOIL SOIL SOIL SOIL SO EL SOIL SOIL SOIL SOIL CHAIN OF CUSTODY Relinquislred-i: ^ Date -- Jf / ------- --------------- / Cooler ID No.: Time rfo e Received By: Fed Ex v fr* Cooler Temp. {C): Date Time /Y o t> v^oo 0 Comments 0-3 INCHES 3-6 INCHES 0-3 INCHES 3-6 INCHES 0-3 INCHES 3-6 INCHES 0-3 INCHES 3-6 INCHES 0-3 INCHES 3-6 INCHES p PROJECT REQUIREMENTS Results Deadline: Laboratory Report Options: Sample Results Only Add Case Narrative Add Quality Control Summary Add Calibration Summary Add Raw Data Other: CHAIN OF CUSTODY/ANALYSIS REQUEST FORM 857 o n Severn Trent Laboratories T: 708-534-5200 F: 708-534-5211 2417 Bond Street University Park, JL 60466 PAGE PROJECT INFORMATION Client: Weston Solutions, Inc. 1400 Weston Way, Bldg. 5-2 W estchester, PA 13360 T: 610-701-3761 F: 610-701-7401 Project Manager: Jai Kesari email: i.kesa ri western solutions. com Project Name: Reference No: Decatur, Alabama 02181-129-081-0001 ANALYS ES REQU ESTED Sampler: T Frinak, A Murphy 256-552-6189 P.O. #: Quotation #: SAMPLE ANALYSIS ExyLIMS # Client Sample Identification | DF14 SS 0001 0 0000 KZ DF14 SS 0001 0 0003 n DF14 SS 0002 0 0000 Af DF14 SS 0002 0 0003 ts DF14 SS 0003 0 0000 I t :...... DF14 SS n DF14 SS DF14 SS 0003 0004 0004 0 0003 0 0000 0 0003 DF14 SS 0005 0 0000 ____I s ___ _ DF14 SS 0005 0 0003 Collection Date 27-Jan-05 27-Jan-05 27-Jan-05 27-Jan-05 27-Jan-05 27-Jan-0 5 27-Jan-05 2 7-Jan-05 27-Jan -05 27-Jan-05 Collection Time 13:55 14:05 14:30 14:35 14:10 14:15 14:30 14:40 14:00 14:10 X X X X X X X X X X Sample Matrix 1 SOIL 1 SOIL 1 SOIL 1 SOIL 1 SOIL 1 SOIL 1 SOIL 1 SOIL 1 SOIL 1 SOIL Grab Sample Composite No. of Containers TOC Comments 0-3 INCHES 3-6 INCHES 0-3 INCHES 3-6 INCHES 0-3 INCHES 3-6 INCHES 0-3 INCHES 3-6 INCHES 0-3 INCHES 3-6 INCHES !x X X X X X X X X X PROJECT REQUIREMENTS Results Deadline: Laboratory Report Options: Sample Results Only Add Case Narrative Add Quality Control Summary Add Calibration Summary Add Raw Data Other: S am ple Lot#: Sam ple No. /- 2 0 / -- a-c' A n a ly s is i L /C il k STL Chicago Internal Sample Custody Transfer Record Client: bJ^XVn Relinquished by: R eceived by: _______________ f\ _________ / \ / .. .-er L-'t-s-f 0 Date T im e z J z /c -T ~ - ? 1 3 & 3 ~ /z fc / r . 'jiT ' Com m ents n CHI-22-11-G01/C-1/99 rpjsckl Job Sample Receipt Checklist Report Job Number.: 233857 Location.: 57222 Check List Number.: 1 Description.: Customer Job ip___ Job Check List Date.: 01/29/2005 Project Number.: 2000AS91 Project Description.: Confidential Decatur - Fc Investigation Customer...... : Weston Solutions, Inc. Contact.: Jai Kesari Questions ? (Y/N) Comments V2 Date of the Report..: 02/11/2005 Project Manager.....: rew Chain-of-Custody Present?......................... Y Were samples dropped off at or picked up by STL?.. N Custody seal on shipping container?......... . Y ...If "yes" , custody seal intact?................. Y Custody seals on sample containers?............... N ...If "yes", custody seal intact?.... ....... . Samples iced?............................. Y Temperature of cooler acceptable? (4 deg C +/- 2). Y 3.2 Samples received intact lgood condition)?..........Y VolatiLe samples acceptable? (no headspace)...... Correct containers used?.......................... Y Adequate sample volume provided?.................. y Samples preserved correctLy?..,,...,,....,,,,,,...... Y Samples received within holding-time?............. Y Agreement between C0C and sample labels?......... Y Radioactivity at or below background Levels?..... Y A Sample Discrepancy Report (SDR) was needed?.... N If sampLes were shipped was there an air bill #?.. Y Sample Custodian Signature/Date................... Y Page 1 32 U S Airbill T"1i v'._irrFKlt<in&i E xpress 1 Fron 4a Express P tacta|eS em ca uoua ^ rr S e n d e r's Hem e Cdm m nx / 77,n : 'w *<-'; . $ r .i HS ^uf ra aE Sa iuS i f ~ J=t / i l 1 / / / i aPIlDfW ^ jC, > / 7 / h.)> " < - C -> C c ^ . ,i. ^ A- c pC jF fld fr PricntyOxenrngirt Tvrrwrf P I FedExStandaid Owaireght I-- I W iab ar i t te f l g r a r f Stomdfennaifet* *--~--~\>>TTFtTiervtddMBWcrriEMi-&tplinrjh*a's Saver -- FrtfaErwtetintenctukUi ttimiOw-wirima Hb Express hrightSfirvics A d d ress /yoo /i n Fetffix ID ax FraitfrP -- 1 I | FedEx JD ayFraght I-- ' Sectndbmtnu i w f * fteAagm m tB tSB **. *,Tna^krsinr I I FedBcFest (hrernisArt I-- I CMwgrMyiwabturetikltHenskwnv?it ftcbgviHirfnfc "T.m M w , II-- II TFtedWEUxw3DaaftxxF*raiflhi C ity / --= "=.. r V 1 VouiJitHnalBilfaigHcfmsca 3 Ta Recipients Meme f \ C i. JC om * K ii ..,v - 'v ' Recipients / Addrees '~ i f i Wacsumtdiawu PH.tuna PJI.Bf ' Address Td ^ ^ strife MEB.kta*,IFTflTii.>44ntitora. y/ (Six - ^ / * '. ^ ^ > . '. ' .. Stete / i C ap PtHHie A- X . ." j y ^ rT " . Stete / ^ ZIP C P.< s 8 C tttiftn M H n i ^ :V , , g? i y c Psraging iFneudEisxAPiafki*saii*it BFecxdEx FHE*latP*.cid Fa*:3ard,pEA Tfoudba&t l^ UD H ier Special Handing -- -- -- hcwsFeCxeMMSiSMitea ------ -------- , SATUDATCWAm v 1 |-- | HOLDWMtdey r-- , H O U IS M m 1 w it*TM?TM*> JFretaJoto,- I_J tfeavtwfFtiieHfreEftexOfLfctoirici^atlion I__i .eJatnFfletUd*aElxjkfhtcreMtboi trnif DmssfMt$ ^icdmFencfti-UPeqr nDob*till*iCfkcwikpmwMNC!ftHoUtkfwictaetn.gmutggodcT I vASia^peerreti-xDtKiiirjrtiiIn-- ISnkofcfrteTqELinaJdscIsatn cDtrfyVaI.cee.u D a q t n u p f fa fr c U f e ig C f T XjH e i u n t o w e d in fo d& tp ecfcicn t I ! Catgp W crattflnty 7 P m'ie e l fIl-f-fl-ir -- -- _EM_r_h_C_i_J_t_e_LNKwCMtlCuENo.,b_dHo_i_E._________ _ACtc_rct_str_Nifaltcp.'I-- I 1 bMtfeadi.lvd Recipient : O niidPartp O CreditCend Q CasMCheek 4 L CO n CASE NARRATIVE Client; Job #: STL Chicago Wet Chemistry Case Narrative Weston Solutions, Inc. 233857 Date Rec'd: 01/29/05 1. This narrative covers the analysis o f the samples in the above Job # for TOC by the Lloyd Kahn Method. The samples were analyzed for TOC in duplicate by furnace combustion and nondispersive infrared detection on a Dohrmann Phoenix 8000 TOC analyzer, after acidification to remove inorganic carbon, and drying. No correction was made, therefore, for moisture content. The average o f the sample bums is reported, 2. The method-recommended holding time o f 2 weeks was met. Refer to the Laboratory Chronicle Page for dates o f sampling, receipt, and analysis. 3. The TOC calibration curve and the initial and continuing verification standards and blanks met acceptance criteria, although the final CCV in batch 141662 was high at first attempt and required re-injection. 4. The method blanks were less than the reporting limit. 5. The LCSs were within acceptance limits. 6. The matrix QC done on samples 233857-4 and -15, The recoveries were all within acceptance limits, as were the RPDs between the MSs and the MSDs. Diane L. Harper / Wet Chemistry Section Manager j .a .> Date 35 RAW DATA *** RUM LOG *** CV2 > 2/11/05 11:14 Total Method Code .: TOCS Batch Code, 141662 Status..... .: RVUD Batch Date. 02/10/05 Batch Time.. 1128 Usar Mame..... els c code...... *; TOCS cele code___ ._ TOCS Location Code. 57222 Equipmeht Cade.: TOC4 Import Code. TEST CODE TTT TTTTTTTTTT 0O 0O0O0CCC III CCCCCc CSS S CCC 2 34AAA 2ASSS VV V V 2A 234 2 2 SAMPLE: Grp Po Sample IO Di Lut ion TEST POS Date / Time 12 34 56 7 111 222 789012 11 ICAL^I05ASTTC1_ 0 12 ___IDV_I05ASTTC2_ 2/3/05 1 0833 0 13 ___ M B __ 2/3/05 1 0646 0 14 ___LCS_I00FSTLK3tw3 2/3/05 1 0930 0 15 ___LCD_I00FSTLK3_3 2/3/05 1 0947 0 16 233857_1_S___ 2/3/05 1 1009 0 17 233B57_2_Si__ 2/3/05 1 102B 0 18 233857 3 S 2/3/05 1 1107 0 19 233857_4_S___ 2/3/05 1 1131 0 1 10 233857J^SJ1S_I05ASTTC2_9 2/3/05 1 1147 0 1 11 233857_4_S_MSD_I05ASTTC2_9 2/3/05 1 1156 0 1 12 233857_5_S___ 2/3/05 1 1204 0 1 13 233857_6_S___ 2/3/05 1 1225 0 1 14 233857_7_S___ 2/3/05 1 1244 0 1 15 233857_8_S___ 2/3/05 1 1312 0 1 16 ___CDV_I05ASTTC2_ 2/3/05 1 1349 0 1 17 CCS 2/3/05 1 1356 0 1 18 233857_9_S___ 2/3/05 1 1405 0 1 19 233857_10_S___ 2/3/05 1 1427 0 1 20 233657 11 S 2/3/05 1 1449 0 1 21 23385 7 J 2 _ S ___ 2/3/05 1 1501 0 1 22 233857_13_S___ 2/3/05 1 1517 0 1 23 23365 7 J 4J ___ 2/3/05 1 1532 0 1 24 ___CDV_I05ASTTC2_ 2/3/05 1 1557 0 1 25 ___ C C B _ 2/3/05 1 1600 0 Peoe 1 -- 37 *** QC summary **# (V2 ) Total rgahic Carbon (Soils) Report Date: 2/11/05 11:14 Method Code..: TOCS Batch code...: 141662 Status...... : RVWD Eiatch Dato...: 02/10/05 Batch Time...: 1128 User Name____: els QC c o d e T O C S Calc Code..... : TOCS Location Code..: 57222 Equipment Code.: TC4 Import Code____ : Grp Snip Sample ID Pas Test Result Known Original Alternate QC Res F QC Res F 1 2 ___ICV_I05ASTTC2_ 1 TOC 2061.54 2000 103 1 3 ___MB__ 1 TOC -1.99 1 4 ___LCS_I00FSTLK3_3 1 TOC 4840.71 4780 "1.99 101 1 5 ___LCD_IQ0FSTLK3J3 1 TOC 6513.46 4780 -1.99 4840.71 136 29 1 10 233857_4_S_MS_IQ5ASTTC2_9 5 T0CAV2 43543.B1 2000 28718.18 77 1 11 233857_4_S_MSD_I05ASTTC2J? 5 TOCAV2 47888,,53 2000 28718.18 43543.81 82 6.3 1 16 ___CCVJQ5ASTTC2_ 1 TOC 2043.23 2000 102 1 17 ___CCB__ 1 24 ___CCVJ05ASTTC2_ 1 TOC 1 TOC -2.03 2025.92 2000 --- ............ 101 1 25 :___CCB__ 1 TOC -3.96 Paga 1 38 *** RAW TEST DATA *+* <VZ ) Total Organic Carbon (Soils) Method Code..: TOCS Batch Code...: 14166Z Status___ ... : RVUD Batch Date,.. : 02/10/05 Batch Time... : 1128 User Name___ : els SAMPLE: Grp Pos Sample ID 11 1Z 13 14 15 16 17 1B 19 1 10 1 11 1 12 1 13 1 14 1 15 1 16 1 17 1 18 1 19 1 ZD 1 21 1 22 1 23 1 24 1 25 1CAL I05ASTC1 ICV I05ASTTC2 MS LCS IOOFSTLK3 3 LCD IO0FSTLK3 3 233857 1 S 23357 2 S 233857 3 S Z33857 4 S 233857 4 S MS I05ASTTC2 9 233857 4 S MSD IQ5A5TTC2 9 233857 5 S 233857 6 S 233B57 7 S 233857 8 S CCV IQ5ASTTC2 CCB Z33857 9 S 233857 10 S 233857 11 S 233857 12 S 233857 13 S 233857 14 S CCV I05ASTTC2 CCB qc code,.. --- : TOCS Calc Code. ___ : TOCS Location Code..: 57222 Dilution TOC mg/Kg TOC2 mg/Kg Report Date: 2/11/05 11:14 Equipment Code.: TOC4 Import Code___ : TOC3 mg/Kg OC4 mg/Kg T0CAV2 mg/Kg 2061.54 -1,99 4840.71 6513.46 43368.34 19508.48 33285.54 36540,12 43543.81 47888.53 29162.04 16423.19 15954.38 8745.34 2043.23 -2.03 22274.40 7802.66 10018.09 7238.26 7162.79 2938.66 2025.92 "3.96 16829.77 16571.49 21999.68 20896,24 25458.22 12193.80 19275.13 9206.94 17207.07 7082.92 8281.74 6956,48 6410.81 3498.86 30099.06 18039.99 27642.61 28718.18 43543.81 47888.53 27310.13 14308.49 17614.76 8976.14 19740.74 7442.89 9149.92 7097.37 67B.80 3218.76 Page 1 39 *** RAU TEST DATA (V2 ) Total Organic Carbon (Soils) Method Code..: TOCS Batch Code... : 141662 Status...... : RVWD Batch Date.. : 02/10/05 Batch Time,, : 1120 User Name... : c Lb SAMPLE: Grp Pos Sample ID 11 12 13 14 15 16 17 18 19 1 10 1 11 1 12 1 13 1 14 1 15 1 16 1 17 1 18 1 19 1 20 1 21 1 22 1 23 1 24 1 25 ICAL J05ASTTC1 ICV I05ASTTC2 MB LOS I00FSTLK3 3 LCD I00FSTLK3 3 233857 1 S 233057 2 S 233057 3 S 233857 4 S 233857 4 S MS I5ASTTC2 9 233857 4 S MSD I05ASTC2 9 233857 5 S 233857 6 S 233857 7 S 233857 8 S CCV I5ASTTC2 CCB 233857 9 S 233857 10 S 233857 11 S 233857 12 S 233857 13 S 233857 14 S CCV ID5ASTTC2 ___ CCB__ QC Code....... : TOCS Cale Code..... : TOCS Location Code.. : 57222 Dilution TCAV3 mg/Kg OCAV4 mg/Kg Report Date; 2/11/05 11;14 Equipment Code.: TQC4 Import Code___ : TOCR1 ug TQCR2 ug T0CR3 ug 103.0771 -0.31B 139.0966 211.6873 264.5469 117.0509 189.7276 153.4685 226.4278 205.9207 154.5588 111.6777 130.8259 94.4497 102.1614 -0.3249 155.920S 53.8397 132.2388 142.5938 78.0744 55.2468 101.2960 -0.6328 87.5148 111.0290 116.5983 94.0331 152.7493 102.4279 134.9259 97.5936 151.4222 64.4546 106.8344 132.8687 92.3157 72.7763 Page 2 40 RAW TEST DATA *** (V2 ) Total Organic Carbon (Soils) M e th o d C o d e .. Batch Code.. . Status...... TOCS 141662 RVWD Batoh h a t e ___ ; 02/10/05 Batch Time...: 1128 " User Name_____ : els SAMPLE: Grp Pos Sample ID 11 ICAL I05ASTTC1 12 ICV I05ASTTC2 13 MB 14 LC5 I00FSTLK3 3 15 LCD I00FSTLK3 3 16 233857 1 S 1 7 233857 2 S 1 8 233857 3 S 1 9 233B57 4 S 1 ID 233B57 4 S MS I05ASTTC2 9 1 11 233857 4 S MSD I05ASTTC2 9 1 12 233857 5 S 1 13 233857 6 S 1 14 233857 7 S 1 15 233857 8 S 1 16 CCV I05ASTTC2 1 17 CCB 1 1 8 233857 9 S 1 19 233857 10 S 1 2 0 233857 11 S 1 21 233857 12 S 1 22 233857 13 S 1 23 233857 14 S 1 24 CCV I05ASTTC2 1 25 ____ C C B ___ QC code.. . C a lc C o d e . ip ! Location Code.. : TOCS TOCS 57222 Di luti on TOCR4 ug UT1 g Report Date: 2/11/05 11:14 Equipment Code.; TOC4 Import Code___ : WT2 WT3 WT4 ggg 0.05 0.16 0.0289 0.0325 0.0061 0.0060 0.0057 0.0042 0.0052 0.0043 0.0053 0.0068 0.0082 0.0108 0.05 0.16 0.0070 0.0Q69 0.0132 0.0197 0.0109 0.0186 0.05 0.16 0.0052 0.0067 0.0053 0.0045 0.0060 0.0084 0.0070 0.0106 0.0088 0.0091 0.0129 0.0191 0.0144 0.0208 Page 3 41 *** RAU TEST DATA **vt <V2 ) Total Organic Carbon (Soils) M e th o d C o d e. TOCS Batch Code.. . : 141662 Status..... . : RVWD Batch Date. . : 0 2 /1 0/05 Batch Time.. . : 1128 User Name.. . : cls SAMPLE: Grp Pas Sample JD 11 ICAL I05ASTTC1 12 ICV 105ASTTC2 13 MB 14 LCS I0FSTLK3 3 15 LCD 1D0FSTLK3 3 1 6 233857 1 S 1 7 233857 2 S 1 8 233857 3 s 1 9 233857 4 S 1 10 233857 4 S M S I05ASTTC2 9 1 11 233857 4 S MSD IQ5ASTTC2 9 1 12 233857 5 S 1 13 233857 6 S 1 14 233857 7 S 1 15 233857 8 S 1 16 c c v I05ASTTC2 1 17 CCB 1 18 233857 9 S 1 19 233857 10 S 1 20 233857 11 S 1 21 233857 12 S 1 22 233857 13 S 1 23 233857 14 S 1 24 c c v I05ASTTC2 1 25 :____ C C B ___ de Code....... : T O C S Calc Code... . *,, : TOCS Location Code.. : 57222 Dilution DLFAC M/A TCS mg/Kg Report Date; 2/11/05 11:14 Equipment Code.: 0C4 Import Code.. . TCS2 mg/Kg TCSAV2 mg/Kg TICS mg/Kg 3.2000 1.0000 5.5363 4.9231 28.3186 25.1969 29.0909 36.7816 30.7692 37.2093 28.3186 21.0526 21.0526 14.9533 3.2000 1.0000 20.2532 20.0000 12.2605 8.2474 12.6482 8.0808 3.2000 1.0000 Page A 42 Calibration Report Print Date/Time: 2005/02/08 7:02:33 Cal. Curve ID: SOJLCURVE Created: 01/17/200511:33 Calibration Factor (m): 8.538e+04 Y intercept (b): 436425 r-squared: 0,99800 Standard ID Y X Expected Measured Message Date & Raw Data ug C ug C Time 0 ugram C -4530 0.000 5.165 No sample Det 01/17/2005 09:53 10ugramC 1085240 10,000 7.599 01/17/200510:15 20 ugram C 1870210 20.000 16.794 01/17/200510:26 40 ugram C 3806480 40.000 39.473 01/17/2005 10:34 80 ugram C 7357282 80.000 81.062 01/17/200510:45 120 ugram C 11114689 120.000 125.072 01/17/2005 10:58 200 ugram C 18428840 200.000 210.740 01/17/2005 11:07 300 ugram C 26478564 300.000 305.025 01/17/2005 11:15 400 ugram C 33682344 400.000 389.401 01/17/2005 11:32 Multiple Analysis Report Print Date/Tjme: 2005/02/08 7:05:05 Sample ID Result Std. Dev. RSD Mode ALT ICV 103.0771 TC ICB-MB -5,1590 TO ICB-MB -0.3186 TC LC S .................... ....... 139.8966........... ...TC .. LCD 1.4210 TC LCD 211.6873 TC 233857-1............. .......... 8952349... ......... TC 233857-1 204.5469 TC 233857-1 87.5148 TC 233857-2............. .......... 117.0509,,. ......... TC 233857-2 111.0290 TC 233857-3 189.7276 TC 233857-3............. .......... 116.5983.. ......... TC 233857-4 -0.0518 TC 233857-4 153,4685 TC 233857-4............. .......... 94.0331... .........TC , 233857-4ms 226.4278 TC 233857-4msd 205.9207 TC 233857-5...... ...... ..... 154.5588... ......... T C 233857-5 152.7493 TC 233857-6 111.6777 TC 233857-6............. ...........102.4279... ......... TC 233857-7 130.8259 TC 233857-7 134.9259 TC 233857-8............. .......... 94.4497... ......... TC , 233857-8 97,5936 TC CCV 102.1614 TC C C B ............................-0.3249............ .,,TC .. 233857-9 155.9208 TC 233857-9 151.4222 TC 233857-10........... ........... 53.8397... ......... TC 233857-10 64.4546 TC 233857-11 132.2388 TC 233857-11........... ........... 106.8344... ......... TC 233857-12 142.5938 TC 233857-12 132.8687 TC 233857-13........... ........... 78.0744... ......... TC 233857-13 92.3157 TC 233857-14 55.2468 TC 233857-14........... ........... 72.7763... ......... TC CCV 120.7288 CCV 101.2960 C C B .................... ........-0.6328............ TC TC ...TC .. Detailed Analysis Report Print Date/Time: 2005/02/08 7:05:21 Sample ID: ICV Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 02070828 Timestamp: 02/07/2005m8:33 Sample Type: Cal. Verification-^- Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 103.0771 103.0771 9236858 1.258 2.256 280 Sample ID: ICB-\|B Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL' Mode: TC Filename: 02070837 Timestamp: 02/07/2005 08:40 Sample Type: Cal. Verification Rep # ppm C ug Raw Data Beginning Ending Integration Baseline Baseline Time 1 -5.1590 -5.1590 r4034 1.432 1.384 120 Last Message: Out of Calibration m i Sample ID: ICB-MB Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC __ ^ Filename: 02070843 f Timestamp: 02/07/200& 08:46 Sample Type: Sample ! Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 -0.3186 -0,3186 -1434 1.340 1.325 120 Last Message: No Sample Detected Sample ID: LCS Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 02070922 Timestamp: 02/07/2 Sample Type: Sample Rep# ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 139.8966 139.8966 11969744 1.449 2.447 282 Sample ID: LCD Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Tiiename^Ja20l0933 TimestampTl527 Sample Type: Sample Rep# ppm C / k i R a w Data Beginning Ending Integration \ pr p Baseline Baseline Time 1 1.4210\ 1.4210 147087 1.651 2.650 72 Sample ID: LCD Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 02070941 Timestamp: 02/07/2005 09:47 / Sample Type: Sample ( ^ Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 211.6873 211.6873 18099028 1.405 2.405 311 Sample ID: 233857-1 Mode: TC Method: boat \ r . Filename: 02070955 Cal. Curve: SO iLCURVEv Timestamp: 02/07/200510:02 Operator ID: CARO L \ v ^ Sample Type: Sample Rep # ppm C ug c\ Raw Data Beginning Ending Integration \Baseline Baseline Time 1 895.2349 895.234976458400 1,690 2.688 422 Last Message: Over-range Sample ID: 233857-1 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC -- Filename: 02071004 Timestamp: 02/07/200510:09 Sample Type: Sample! Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 264.5469 264.5469 22612032 2.330 3.329 289 "\ Sample ID: 233857-1 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 02071016 Timestamp: 02/07/2005 10:21 Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 87.5148 87.5148 7497530 1.617 2.613 256 Sample ID: 233857-2 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 02071023 Timestamp: 02/07/200 Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 117,0509 117.0509 10019243 2.083 3.081 253 Sample ID: 233857-2 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TO Filename: 02071032 Timestamp: 02/07/2005 10:38 Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 111.0290 111.0290 9505105 3.090 4.086 230 Sample ID: 233857-3 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 02071101 Timestamp: 02/07/20' Sample Type: Sample Rep# ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 189.7276 189.7276 16224171 1.540 2.538 290 Sample ID: 233857-3 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 02071109 Timestamp: 02/07/2005 11:14 Sample Type: Sample Rep# ppm C u g C Raw Data Beginning Ending Integration Baseline Baseline Time 1 116,5983 116.5983 9980595 1.793 2.790 258 Sample ID: 233857-4 Method: boat Cal. Curve: SOiLCURVI Operator ID: CAROL Mode: TC Filename: 02071121 Timestamp: 02/07/2005 11:24 Sample Type: Sample Rep # ppm C ug C RaW^Data Beginning Ending integration Baseline Baseline Time 1 -0.0518 -0.0518 21339 \ 1.684 1.904 120 Last Message: No Sample Detected sample ID: 233857-4 Method: boat Cal. Curve: SOILCURVE Mode: TC " Filename: 02071125 / Timestamp: 02/07/2005 11:31 v. 47 Operator ID: CARO L Sample Type: Sample Rep# ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 153.4685 153.4685 13128471 1.785 2.783 270 Sample ID: 233857-4 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 02071134 Timestamp: 02/07/2005 11:40 Sample Type: Sample Rep # ppm C ug C 1 94.0331 94.0331 58 2.755 256 Raw Data Beginning Ending Baseline Baseline Time 8054048 1.7 Integration Sample ID: 233857-4ms Method; boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 02071141 Timestamp: 02/07/200^11:47 Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 226.4278 226.4278 19357532 3.003 4.002 292 Sample ID: 233857-4msd Method: boat Cal. Curve; SOILCURVE Operator ID: CAROL Mode: TC Filename: 02071151 Timestamp: 02/07/200$ 11:5( Sample Type: Sample Rep# ppm C u g C Raw Data Beginning Ending Inte Baseline Baseline Time 1 205.9207 205.9207 17606694 3.754 4.750 250 Sample ID: 233857-5 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 02071159 Timestamp: 02/07/20 Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integ Baseline Baseline Time 1 154.5588 154.5588 13221560 1.992 2.989 265 Sample ID: 233857-5 Method: boat Cal. Curve: SOILCURVE Mode: TC Filename: 02071207 Timestamp: 02/07/2005 12:12 Operator ID: CARO L Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 1527493 1527493 13067072 1.903 2.902 270 Sample ID: 233857-6 Method: boat Cal, Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 02071218 Timestamp: 02/07/20 Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 111.6777 111.6777 9560493 1797 2797 269 Sample ID: 233857-6 Method: boat Cal. Curve: SOILCURVE Operator ID: CARO L Mode: TC Filename: 02071226 Timestamp: 02/07/2005 12:33 Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Time 1 102.4279 102.4279 8770768 2.123 3.120 247 Sample ID; 233857-7 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC ^ Filename: 02071240 f ) Timestamp: 02/07/2005 12:44 . Sample Type: Sample f Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 130.8259 130,8259 11195312 8.082 9.074 199 Sample ID: 233857-7 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 02071252 Timestamp: 02/07/2005 12:57 Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 134.9259 134.9259 11545354 1.874 2,874 260 Sample ID: 233857-8 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 02071307 Timestamp: 02/07/20I Sample Type: Sample Rep# ppm C u g C Raw Data Beginning Ending Integration Baseline Baseline Time 1 94,4497 94.4497 8089611 1.820 2.817 251 Sample ID: 233857-8 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 02071313 Timestamp: 02/07/2005 13:18 Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 97.5936 97,5936 8358035 1,870 2.867 257 Sample ID: CCV Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 02071343 / Timestamp: 02/07/2005 13:49 Sample Type: Cal. Verification Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 102.1614 102.1614 9158679 1.654 2.653 269 =;=:r;"=:=:==================;X;^;^^^3=:==:===^==============i^=:? Sample ID: CCB Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 02071353 ^ Timestamp: 02/07/2005 fl3:56 j Sample Type: Sample I / Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 -0.3249 -0.3249 -1974 1.755 1,707 120 Last Message: No Sample Detected Sample ID: 233857-9 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 02071359 Timestamp: 02/07/20] Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending inte' Baseline Baseline Time 1 155.9208 155.9208 13337840 1809 2.806 274 Sample ID: 233857-9 Method: boat Cal. Curve: SOILCURVE Mode: TC Filename: 02071408 Timestamp: 02/07/2005 14:14 50 operator iu: c a r o l sample lype: sample Rep # ppm C ug C Raw Data Beginning Ending integration Baseline Baseline Time 1 151.4222 151.4222 12953763 1.860 2.855 289 Sample ID: 233857-10 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 02071423 Timestamp: 02/07/20, Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 53.8397 53.8397 4622450 1.816 2.816 234 Sample ID: 233857-10 Method: boat Cal, Curve: SOILCURVE Operatorio: CAROL Mode: TC Filename: 02071435 Timestamp: 02/07/2005 14:40 Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 64,4546 64.4546 6528715 2,029 3.029 235 Sample ID: 233857-11 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 02071442 f Timestamp: 02/07/20015 14:49] Sample Type: Sample ( / Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 132.2388 132.2388 11315940 1.921 2.921 276 Sample ID: 233857-11 Method: boat Cal, Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 02071449 Timestamp; 02/07/2005 14:54 Sample Type: Sample Rep# ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 106.8344 106.8344 9146981 2.354 3.352 245 Sample ID: 233867-12 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename; 02071455 Timestamp: 02/07/200: Sample Type: Sample Rep# ppm C u g C Raw Data Beginning Ending Integration Baseline Baseline Time 1 142.5938 142.5938 12200021 2.192 3.189 266 Sample ID: 233857-12 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 02071502 Timestamp: 02/07/2005 15:07 Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 132.8687 132.8687 11369721 2.137 3.136 264 Sample ID: 233857-13 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 02071510 Timestamp: 02/07/20 Sample Type: Sample Rep# ppm C u g C Raw Data Beginning Ending Integration Baseline Baseline Time 1 78.0744 78.0744 6691535 1.963 2.963 249 Sample ID: 233857-13 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 02071520 Timestamp: 02/07/200 Sample Type: Sample Rep# ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 92.3157 92.3157 7907421 1.837 2.836 252 Sample ID: 233857-14 Method: boat Cal. Curve: SOILCURVE Operator ID: CARO L Mode: TC Filename; 02071527 Timestamp: 02/07/20015 15:32 Sample Type; Sample V ^ Rep# ppm C u g C Raw Data Beginning Ending Integration Baseline Baseline Time 1 55.2468 55.2468 4742580 2.137 3.134 235 Sample ID: 233857-14 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 02071537 Timestamp: 02/07/2005 15:42 Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 727763 727763 6239202 1.845 2.843 262 Sample ID: CCV Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL MocTer-- --Tp Filename: 0207T544--___ Timstamp: 02/07/20 Sample Type: Cal. Verification Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 1207288 1207288 10743905 1.850 2.848 283 Last Message: Out of Calibration Sample ID: C C V Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 02071552 Timestamp: 02/07/2 Sample Type: Cal. Verifi Rep# ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 101.2960 101,2960 9084793 2.096 3.096 260 Sample ID: CCB Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 02071557 \ Timestamp: 02/07/200516:00 Sample Type: Sample ( Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 -0.6328 -0.6328 -28262 2.337 2.014 120 Last Message: No Sample Detected S T L C h ic a g o Page No.:. __1_3__7_ T O C in S o ils Book No. . "1 7 V 7 M e th o d : L lo y d K a h n Instrument: Phoenix 8000 (TOC41 LabNet Batch: / Q "Z_ Calculation: Date of Standard Curve: / / / 2 / ^ , TOC (mg/kg) = ug C / grams sample Book # 7 V ? Page # / ? - / MS, MSD Known Cone, (mg/kg) * 100 ug C / grams sample MS, MSD Observed (mg/kg) = ug C / grams sample MS, MSD Ree. = fobserved ma/ko - avo, samolo result fma/kcOl x 100 known concentration in mg/kg Standard Traceability: (Note: Working Standards are prepared daily from the noted Stock Solutions.) Stock I (Curve) V f ( Stock 11(ICV/CCV) LCS Source ID 'Z O O F T ^ I LCS True Value v 7F& Acceptance Range _______ S a m p le ID : V ? iJ <TM S a m p le W e ig h t (g ) o .o f ug C T T f c ~ ----------- ^ P 9 C U C o m m e n te : ______ - * 7 7 ______ St < ! n .n O SFZ7 ~. y ? -------------- - e - , T t - z j -------------- h / r + M ---------- . o .-' L cp Q 1 < r `7 J j / ^-- ! -i ./R 1 j < ^ 2 7 /R/ O o "'- . C /; '= * ^ 1 O -O O Q -( -2 ^ ne? c 2 n - o o f,, // 8 7 -- ---- IM L 'S /- /2 1-> . 97 //9 tfc ? /' / -2 - O .Q 0 J n T o fj . tf/ . W a t r i.7 2 - i n. 0 0 f i l i r f? > --. --------------- f--------- { *n ( Y O t f ^ z --------------- r C t \ -------- o . aoH Z- /O . \,a ? 7 /f./p 1 .1 ______________/ ^ ~ T a J ^2 o . oovf y < 7 ^ 5" 2 r t .n c H ' y Y. 0 3 5 / 9 .2 .< ? , y .7 ?7 . ( 2 7 Vj^ f/ / n. O j (Oj G 0 ( 0 ./ /' 0 O Q g ,$' . IN / -fr . a 0 9 l /f7 < tf/ i^n^y 7/7. 771 /2, F t f - n . c) ^ Prep Analyst: Analyst Reviewed by: Date:, S L / 3 / 0 3 tj.. ,, g Date: o / ? / o i Date: y / / of-- c a 1*22-12-095/5-0001 STL Chicago Page No. 138 TOC in Soils Book No.: fj Method: Lloyd Kahn Instrument: Phoenix 8QQ0 (TQC4) LabNet Batch: Calculation: Date of Standard Curve:___ TOC(mg/kg) = ug C / grams sample Book#________ Page# MS, MSD Known Cone, (mg/kg) = 100 ug C / grams sample ^ MS, MSD Observed (mg/kg) * ug C / grams sample MS, MSD Rec. = Observed mo/kg - avo, sample result (mg/kq)^ x 1 0 0 ^ - ^ known concentration In mg/kg 1 Standard Traceability: (Note: Working gtandardi afe prepared daily from the noted Stock Solutions.) Stock I (Curve) feck II (ICV/CCV) LCS Source ID rue Value Acceptance Range Sample ID: _ -J r 00<y den 2 .W ^ 7 - $ .~ i -(o ! r-tC. . _ I r~ U .A . -IX. . r(J. . ' . : V ^/15--/i ~fl H C l . 0 iS C L 0 f1) Sample Weight (g) ug C -.nrt'ki. o o yo , f t OY' /v/T^? T w 7 o . _o>/f it, T fy ? 'd ,o < f a i , l i ry o ( $. 32,99 0 . f n 7 rJ /fO `fXPOX 0 , fjo 0 , 0 0 G>7 r s T J i i o , rra ? / (fV ieri O- r?> 2 - 0 / o 9 /$X. /S3YY 0 r t-Ol WXWs? 7 , 7 ( T i 1 152, r f i 0 , 0 1 0 7 if, 0, &/ W . o t ? 0" 0.OX o ? -' 1 \/ "Ji ' .i \ . . . . . . . -o<' &~f 92. 5sr7 *rC 2 Y ^ f > fin e i T c / Y / W 1- 10 i, Ileo - o .ly y i Comments: y_ Prep Analyst:. __ __ Analyst: ^ Reviewed by:______ l j 1-' 0 W U Date:_ a l I r - Date:. i' 7 i d 'I T Date: CHI-22*1249S/B4fi/01 * * * KUk LOG *** (v2 : 2/10/05 15:17 Total Orgahic Carbon (Soils) Method Code.. : TOCS Batch Code... : 141705 Status...... Batch Date... Batch Time... RVWD 02/10/05 1335 User Name___ . . : e ls DC Code..... ..: TOCS c a lc Code-- ..: TOCS Location Code..;: 57222 Equipment Code.:: T0C4 Import Code___ : TEST CODE TT T TTTTTT TTTT OO0 0 O0 0 C C c I I I cc Cc Cc c SSSc CC 234AAA 2ASSS VVV V 2A 234 2 2 SAMPLE: Grp PO sample id Dilution TEST POS Date / Time 123 4 5 6 7 1 1 12 22 7 89 0 12 11 ___ ICAL_I05ASTTC1_ 0 12 ___ ICV_IQ5ASTTC2_ 2/9/05 1 0836 0 13 ___ MBu__ 2/9/05 1 0842 0 14 ___ LCS_I00FSTLK3_3 2/9/05 1 0904 0 15 LCD IO0FSTLK3 3 2/9/05 1 0912 0 16 233991 J _ S ___ 2/9/05 1 1000 0 17 233992_1_S___ 2/9/05 1 1019 0 18 2 3 3 B 5 7 J 5_S___ 2/9/05 1 1038 0 19 23 38 5 7 J5_ S _M S J 05ASTTC2_8 2/9/05 1 1056 0 1 10 2 3 3 8 5 7 J 5_S_MSD_105ASTTC2_B 2/9/05 1 1113 0 1 11 233857J 6 _ S ___ 2/9/05 1 1123 0 1 12 233B57_17_S___ 2/9/05 1 1236 0 1 13 2 3 3 B 5 7 J 8 S ___ 2/9/05 1 1304 0 1 14 233857J 9 _ S ___ 2/9 /0 5 1 1321 0 1 15 233857__20_S___ 2/9/05 1 1336 0 1 16 ___ CCV_I05ASTTC2_ 2/9/05 1 1412 0 1 17 ___ CCE__ 2/9/05 1 1417 0 1 18 233858^1_S___ 2/9/05 1 1437 0 1 19 233858_2,,S_ 2 /9 /0 5 1 1455 0 1 20 233858_3_S___ 2/9/05 1 1508 0 1 21 2 3 3 8 5 8 J * _ S ___ 2/9/05 1 1524 0 1 22 233858_5mS___ 2/9/05 1 1540 0 1 23 2 3 3 8 5 B ,, 6 _ S ___ 2 /9 /0 5 1 1557 D 1 24 1 25 ___ CCV_I05ASTTC2_ ___ CCB__ 2/9/05 1 1609 0 2/9/05 1 1612 0 PflQP 1 -- 56 *** QC Summary ##* V2 > Total Organic Carbon (Soils) Method Code..: TOCS Batch Code... : 141703 Status...... : RVWD Batch Date,r : 02/10/05 Batch Time.. : 1335 User Name... : els QC Code...... .: TOCS Calc Code.... TOCS Location Code. 57222 Grp Smp Sample ID PaS Test Result Khown Original 1 2 ___ICV_I05ASTTC2_ 1 TOC 1821.76 2000 1 3 ,___MB__ 1 TOC -2.14 1 4 ___ LC_IQQFSTLK3_3 1 TOC 4620.49 4780 -2.14 1 5 ___ LCD_I00FSTLK3_3 1 TOC 3491.99 4780 -2.14 1 9 233857J5_S_MSJ05ASTTC2_8 5 TOCAV2 9888.89 2000 6339.47 ^.1. 10 1 16 233857_15_S_MSD_l05ASTTC2m8 ___ CC\/_I05ASTTC2_ 5 TCAV2 9488.10 1 TOC 1922.51 2000 2D00 6339.47 1 17 ___CCB_ 1 TOC '2.98 1 24 CCV I5ASTTC2 1 TOC 2033.29 2000 1 25 ___CCB__ 1 TOC -3.68 Report Date: 2/10/05 15:17 Equipment Code.: T0C4 Import code,,..: Alternate QC Res 91 F QC Res F 4620.49 97 73 72 66 96 28 8.7 102 Page 1 57 *44 RAW TEST DATA 44* V2 ) Total Organic Carbon <SoiLs) Method Code.,,: TOCS Batch Code__ : 141703 Status....... : RVWD Batch Date...: 02/10/05 Batch Time...: 1335 User Name..f.: els SAMPLE: Grp Pos Sample ID 11 ICAL I05ASTTC1 12 ICV I05ASTTC2 13 MB 14 ICS IQQFSTLK3 3 15 LCD I0FSTLK3 3 1 6 233991 1 S 1 7 233992 1 S 1 8 233857 15 S 1 9 233857 15 S MS IQ5ASTTC2 8 1 10 233857 15 S MSD I05ASTTC2 S 1 11 233657 16 S 1 12 233857 17 S 1 13 233B57 18 S 1 14 233857 19 S 1 15 233657 20 S 1 16 CCV I5ASTTC2 1 17 CCB 1 IS 233858 1 S 1 19 233858 2 S 1 20 233858 3 S 1 21 233858 4 S 1 22 233856 5 S 1 23 233858 6 S 1 24 CCV I5ASTTC2 1 25 CCB QC Code....... : TOCS CaLc Code..... ; TOCS Location Code..: 57222 Dilution TOC mg/Kg TOC2 mg/Kg Report Date: 2/10/05 15:17 Equipment Code.: TOC4 Import Code___ : T0C3 mg/Kg TOC4 tng/Kg TOCAV2 mg/Kg 1821.76 '2.14 4620.49 3491.99 861036.50 391869.38 5555.71 9888.89 9488.10 5264.93 11715.02 4884.24 8024.53 6565.24 1922.51 -2.98 27408.08 14928.04 6655.65 3921.65 20712.70 8671.09 2033.29 -3.68 767109.20 406765.50 7123.22 5762.03 12068.69 5256.29 5384.98 6954.60 27690.76 11545.22 9772.0 1862.60 15212.28 6747.67 814072.85 399317.44 6339.47 9888.89 9488.10 5513.48 11891.85 5070.26 6704.75 6759.92 27549.42 13236.63 8213.83 2892.12 17962.49 7709.38 Page 1 58 *** RAW TEST DATA +** (V2 ) TotaL Organic Carbon (SoiLs) Method Code.. TOCS Batch Code.., 141703 Status... t,r. RVWD Batch Data...: 02/10/05 Batch Time...: 1335 User Name___ : els SAMPLE: Grp Pos Sample id 11 ICAL I05ASTTC1 12 ICV I05ASTTC2 13 MB 14 LC5 IQQFSTLK3 3 15 LCD IDDFSTLK3 3 1 6 233991 1 S 1 7 233992 1 S 1 8 233857 15 S 1 9 233857 15 S MS I05ASTTC2 8 1 10 233857 15 S MSD I05AS7TC2 8 1 11 233857 16 S 1 12 233857 17 S 1 13 233857 18 S 1 14 233857 19 S 1 15 233857 20 S 1 16 CCV IQ5ASTTC2 1 17 CCB 1 18 233858 1 S 1 19 233858 2 S 1 20 233B58 3 S 1 21 233858 4 S 1 22 233858 5 S 1 23 233858 6 S 1 24 CCV I05ASTTC2 1 25 CCB oc Code... ___ : TOCS Calc Code. ___ : TOCS Location Code..: 57222 Dilution TQCAV3 mg/Kg TQCAV4 mg/Kg Report Date: 2/10/05 15:17 Equipment Code.: T0C4 Import Code T0CR1 ug TOCR2 Ug T0CR3 ug 91.0879 -0.3422 133.9942 1D5.1089 172.2073 313.4955 102.2250 199.7555 198,3013 113.7225 250.7015 71.7983 125.1827 138.5266 96.1255 -0.4764 178.1525 120.9171 99.1692 58.0404 124.2762 118.7939 101.6647 -0.5882 383.5546 325.4124 133.9166 149.2366 232.9257 98.B 182 88.3137 167.6059 174.4518 79.6620 150.4888 38.3696 132.3468 84.3459 Page 2 59 ***r RAW TEST DATA *** <V2 ) Total Organic Carbon (Soils) Method Code,. TOCS Batch Code . 141703 Status___ RVWD Batch Date...: 02/10/05 Batch T i m e . : 1335 User Name___ : cLs SAMPLE: Grp Pos Sample ID 11 ICAL I05ASTTC1 12 ICV I05ASTTC2 13 MB 14 LCS IQ0FSTLK3 3 15 LCD I00FSTLK3 3 1 6 233991 1 S 1 7 233992 1 S 1 a 233S57 15 S 1 9 233857 15 S MS I05ASTTC2 8 1 10 233857 15 S MSD I05ASTTC2 8 1 11 233857 16 S 1 12 233857 17 S 1 13 233857 18 S 1 14 233857 19 S 1 15 233857 20 S 1 16 CCV 1D5ASTTC2 1 17 CCB 1 IB 233858 1 S 1 19 233858 2 S 1 20 233858 3 S 1 21 233858 4 S 1 22 23385B 5 S 1 23 233858 6 S 1 24 CCV I5ASTTC2 1 25 CCB DC Code.,, .. w : TOCS Calc Code. .... : TOCS Location Code..: 57222 Dilution T0CR4 ug WT1 g Report Date: 2/10/05 15:17 Equipment Code.: T0C4 Import Code___ : WT2 WT3 WT4 9 99 0.05 0.16 0.0290 0*0301 0.0002 0.0008 0,0184 0.0202 0.0209 0.0216 0.0214 0.0147 0.0156 0.0211 0.05 0.16 0.0065 0,0081 0,0149 0.0148 0.0060 0.0137 0.05 0.16 0.0005 0.0008 0.0188 0.0259 0.0193 0.0188 0.0164 0.0241 0.D063 0.0069 0.0154 0.0206 D.0087 0.0125 Page 3 60 *** RAW TEST DATA Total Organic Carbon (Soils) Method Code..L TOCS Batch Code... : 141703 status...... : RVWD Batch Date....: 02/10/05 Batch Time... 1335 User Name___ .: els SAMPLE: Grp Pos Sample ID 11 ICAL 105ASTTC1 12 ICV I05ASTTC2 13 MB 14 LCS IOOFSTLK3 3 15 LCD I00FSTLK3 3 1 6 233991 1 S 1 7 233992 1 S 1 8 233857 15 S 1 9 233857 15 S MS I5ASTTC2 8 1 10 233857 15 S MSD I05ASTTC2 8 1 11 233857 16 S 1 12 233857 17 S 1 13 233857 18 S 1 14 233857 19 S 1 15 233857 20 S 1 16 CCV I05ASTTC2 1 17 CCB 1 18 233858 1 S 1 19 233858 2 S 1 20 233858 3 S 1 21 233858 4 S 1 22 233858 5 S 1 23 233858 6 S 1 24 CCV I05ASTTC2 1 25 CCB QC Code .... r,. : TOCS Calc Code..... : TOCS Location Code.. : 57222 Dilution DLFAC N/A TCS mg/Kg 3.2000 1.0000 5.5172 5.3156 457.1429 200.0000 8.6022 7.9208 7.6555 6.7368 7.8624 9.5522 10.0000 7.0796 3.2000 1.0000 25.00QD 21.3333 10.5611 9.0395 21.7687 12.2137 3.2000 1.0000 <V2 ) Report Date: 2/10/05 15:17 Equipment Code: TQC4 Import Code___ : TCS2 mg/Kg TCSAV2 mg/Kg TICS mg/Kg Page 4 61 Calibration Report Print Date/Time: 2005/02/09 7:14:15 Cal. Curve ID: SOILCURVE Created: 01/17/2005 11:33 Calibration Factor (m): 8.538e+04 Y Intercept (b): 436425 r-squared: 0,99800 Standard ID Y X Expected Measured Message Date& Raw Data ug C ug C Time 0 ugram C -4530 0,000 5.165 No sample Det 01/17/2005 09:53 10ugramC 1085240 10.000 7.599 01/17/200510:15 20 ugram C 1870210 20.000 16.794 01/17/2005 10:26 40 ugram C 3806480 40.000 39.473 01/17/2005 10:34 80 ugram C 7357282 80.000 81.062 01/17/2005 10:45 120 ugram C 11114689 120.000 125.072 01/17/2005 10:58 200 ugram C 18428840 200.000 210.740 01/17/200511:07 300 ugram C 26478564 300.000 305.025 01/17/200511:15 400 ugram C 33682344 400.000 389.401 01/17/200511:32 Multiple Analysis Report Print Date/Time: 2005/02/10 8:05:27 Sample ID Result Std. Dev. RSD Mode ALT ICV 91.0879 TC ICB-MB -0.3422 TC LCS 133.9942 TC LCD............................ 105.1089........... ...TC 233991-1 742.3906 TC 233991-1 172.2073 TC 233991-1.............. ......... 383.5546... ......... TC 233992-1 33.2797 TC 233992-1 313.4965 TC 233992-1.............. ......... 325.4124... ......... TC 233857-15 102.2250 TC 233857-15 133.9166 TC 233857-15....................... 1997555... ......... TC 233857-15msd 198.3013 TC 233857-16 113.7225 TC 233857-16....................... 1 2880... . ...TC . 233857-16 149.2366 TC 233857-17 250.7015 TC 233857-17.......................232.9257... ......... TC 233857-18 71.7983 TC 233857-18 98.8182 TC 233857-19.......................125.1827... ......... TC 233857-19 88.3137 TC 233857-20 138.5266 TC 233857-20............ ..........1676059... ......... TC ccv 96.1255 TC CCB -0.4764 TC 233858-1.............. ......... 542.9560... ......... TC 233858-1 178.1525 TC 233858-1 174.4518 TC 233858-2.............. ......... 120.9171... ......... TC 233858-2 79.6620 TC 233858-3 99.1692 TC 233858-3.............. ......... 150.4888... ......... TC 233858-3 58.0404 TC 233858-4 0.0137 TC 233858-4.............. ......... 38.3696... . ...TC . 233858-5 124.2762 TC 233858-5 132.3468 TC 233858-8.............. ......... 118.7939... ......... TC 233858-6 84.3459 TC CCV 101.6647 TC C C B ..................... ...... -0.5882............ ...TC .. Detailed Analysis Report Print Date/Time: 2005/02/10 8:05:39 Sample ID: ICV Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC ^. Filename: 02090830 f }/ Timestamp: 02/09/2005 0^36 ...X Sample Type: Cal. Verification Rep# ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 91.0879 91.0879 8213256 1.176 2.175 266 Sample ID: ICB-MB Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 02090839 f Timestamp: 02/09/2005 08:42 Sample Type: Sample V . Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 '0.3422 '0.3422 ^3453 1.332 1.281 120 Last Message: No Sample Detected Sample ID: LCS Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 02090859 Timestamp: 02/09/220000550^90:90:404' Sample Type: Sample l Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 133.9942 133.9942 11465814 1.517 2.517 267 Sample ID: LCD Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 02090908 Timestamp: 02/09/2005/09:12 Sample Type: Sample ( / Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 105.1089 105.1089 8999669 4.884 5.877 210 Sample ID: 233991-1 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL . Mode: TC Filename: 02090941 Tinrfstemp: 02/09/200 Sample TyjskSample Rep # ppm C ug C Raw Data Beginning Ending' Integration Baseline Baseline Time / 1 sample ID: 233857-15 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 02091032 1 Timestamp: 02/09/2006 10:38 Sample Type: Sample Rep# ppm C u g C Raw Data Beginning Ending Integration Baseline Baseline Time 1 102.2250 102.2250 8753444 1720 2.716 247 sample ID: 233857-15 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 02091042 Timestamp: 02/09/200510:47 Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 133.9166 133.9166 11459185 1768 2766 261 Sample ID: 233857-15 ^ "7 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 02091052 Timestamp: 02/09/20! Sample Type: Sample Rep# ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 1997555 199.7555 17080324 3.306 4.306 248 Sample ID: 233857-15msd Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC ----- ^ Filename: 02091106 X Timestamp: 02/09/200511:13 Sample Type: Sample l y Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 198.3013 198.3013 16956172 3.152 4.151 274 Sample ID: 233857-16 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 02091118 Timestamp: 02/09/20 Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 1137225 113.7225 9735069 1.683 2.682 260 Sample ID: 233857-16 Method: boat \ Cal. Curve: SOILcfcjRVEr Operator ID: CARO tX & Mode: TC Filename: 02091202 Timestamp: 02/09/200512:04 Sample Type: Sample Rep # ppm C ug C\ Raw Data Beginning Ending Integration \Baseline Baseline Time 1 1.2680 1.2880 t35729 1.817 2.816 74 Sample ID: 233857-16 Mode: TC Method: boat Filename: 02091209 Cal. Curve: SOILCURVE Timestamp: 02/09/200512:14 Operator ID: CAROL Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 149.2366 149.2366 12767161 1 560 2.559 287 Sample ID: 233857-17 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 02091231 Timestamp: 02/09/20 Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 250.7015 250.7015 21429952 1.760 2.757 293 Sample ID: 233857-17 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 02091241 Timestamp: 02/09/2005 12:46 Sample Type: Sample Rep# ppm C u g C Raw Data Beginning Ending Integration Baseline Baseline Time 1 232.9257 232.9257 19912302 2.394 3.392 272 Sample ID: 233857-18 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 02091300 Timestamp: 02/09/200; Sample Type: Sample j 3:04 Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 71.7983 71.7983 6155704 1.928 2.928 233 Sample ID: 233857-18 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 02091306 Timestamp: 02/09/200513:12 Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 98.8182 98.8182 8462586 1.852 2.849 247 Sample ID: 233857-19 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 02091318 z'* > Timestamp: 02/09/2005 13:21 i Sample Type: Sample v / Rep# ppm C u g C Raw Data Beginning Ending Integration Baseline Baseline Time 1 125.1827 125.1827 10713514 1.876 2.862 158 sample ID: 233857-19 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 02091323 Timestamp: 02/09/200513:26 Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 88.3137 88.3137 7565742 18.477 19.467 161 Sample ID: 233857-20 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC ----- - Filename: 02091331 \ Timestamp: 02/09/2K)05 13:36 Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 138.5266 138.5266 11852772 1,882 2.879 262 Sample ID: 233857-20 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 02091350 Timestamp: 02/09/2005 13:55 Sample Type; Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 167.6059 167.6059 14335487 2.755 3.750 246 Sample ID: C C V Method: boat Cal. Curve: SOILCURVE Operatorio: CAROL Mode: TC --_ Filename: 02091406 ^ Timestamp: 02/09/2005 14:12 Sample Type: Cal, Verification^ Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 96,1255 96.1255 8643346 1.541 2,539 306 Sample ID: CCB Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 02091414 ^ Timestamp: 02/09/200514:17 7 Sample Type: Sample V ^ Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 -0,4764 -0.4764 -14907 1,939 1.765 120 Last Message: No Sample Detected Sample ID: 23385* Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: /^Filename: 02091422^ Timestamp: 02/09/2(56544:28 Sample Type: Sample V ^ Rep# ppm C u g C Raw Data Beginning Ending Integration Baseline" y Baseline Time 1 542,9560 542.9560 4638181S \ 1.874 2.873 338 Sample ID: 233858-1 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: n Filename: Time* Sample TC 391432 : 02/09 l iS am p le Rep # ppm C ug C Raw Data Beginning Erring Integration Baseline Baseline Time 1 178.1525 178.1525 15235919 2.272 3.272\ 266 Sample ID: 233858-1 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 02091438 Timestamp: 02/09/2005 14^44 Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration1 Baseline Baseline Time 1 174.4518 174.4518 14919964 2.450 3.447 253