Document 1grV85xLGrm33jwJo5ywpn44X

FILE NAME Plastics PLAS DATE 1975 DOC PLAS002 DOCUMENT DESCRIPTION Journal Article - Handling Asbestos Chrysotile Asbestos in Plastics % . . + 7 Handling Itt ELA a " A. ed g Sade, xe ChrysotileChrysotile AsbAestossbestos ON JOURNAL OF PAINT TECHNOLOGY an : tee: seen . a a | Ag of w Laetamewing yt ates tar tld Union Carbide Corporation ARTE eB beter me tcc teend bee qretleeds ijunafik Rete eel - esa | . : molding . ett, inibeww received feeb Le af a ren rmee na ede og Fanegy iter FoeW recent By taf: oy oe Daan APS Se oa orf Wt Sy phenolic ag bpcs has a great deal attention Asbers eceit vedos and publicity in recent years floor tile and in phenolic molding -. in < especially after it was designated a target health hazard by OSHA and a compounds It is also used other - hazardous air pollutant by the EPA Many of the articles on asbestos by the plastics such as polypropylene poly- ~ press have been oriented or distorted and in some cases . polypropylene al emotionally polypropylene poly- stories have been sensationalized based on obvious misinterpretation facts ester nylon melamine , epoxy siomly i- Asbestos The use of truths orunsubstantiated statements has led to general con- cone and vinyl provides a _ fusion and the unfair castigation of asbestos and containing asbestos valuable function in such products as u=ho ~ The purpose of this paper is to put the matter of asbestos use and asbestos ~ i brake linings clutch facings electrical a3=:" paper the hazards into a logical and practical perspective In this | different components automotive furni- *- types of asbestos and their many uses are discussed along with government ture boats sealants coatings adhe- - regulations controlling the use asbestos The health hazards associated with ~ | * of and mastics The asbestos both occupational and environmental and some industrial ex- sives -functions -functions most important asbetos in . measures -functions oinfofrcemnt asbestos in plpasltaicssticsstability perience with air sampling and dust control are also covered <<<: KEY WORDS Asbestos Plastics wt Cte Te - UY :: Air pollution Toxicology 5 samen al " VON LT ST RP SeL tt. e e Br ee y - func purpose filling Most of the : supplied ar by tions are suppbylsihe ordt - eS Ge eee ann chrysotile asbestos fiber * although What is longer chrysotile fibers and re- Asbestos is Asbestos a commercial generic insulation Although there are some a or Ababa Ababa Ababa be = rh 3. cath + fy 2 in deposits of anthophyllite the U.S. most of it is imported from Finland longer quiredquired for . fibers and other other particular propertiproepersties >: Ttehrme Assibxestos is coarmemercial naturanaltulralyy for Whyparticular as com chrysotile Chrysotile apart from occurring asbestiform minerals that It used primarily a filler -- Use are fibrous hydrated metal silicates . polypropylene and in insulating ma- : - advantages varieties divided into two terials comparison of the four Among the several classes serpentine and amphibole -... Evarieties of asbestos which are crystal mercial importance is chrysotile * the which set it and serpentine amphibole minerals based presented in . their onlymember structure widespread and Chrysotile is the - Table 2. It should be noted that there for its while increasing availability availability me serpentine class the amphiboles are significant differences between age are world include include with regard include crocidolite amosite antho chrysotile and amphiboles chanical strength flexibility content soft- phyllite tremolite and actinolite to chemical composition and certain surface charge low iron of account us- positive Chrysotile is by far the most physical physical properties _ . _ . conservatively estimatedthat chryso- variety - variety and accounts for over 95 of . U.S. consumption as noted in Table 1 gure .. Where is Asbestos . Used and Why - tile in tile asbestos is used in over 3,000 ap- plications and in most of these appli- Crocidolite also known as blue asbestos is imported from South Africa and good Because of its high mechanical strength resistance to acids and alkalis it is used to reinforce a limited variety of plastics where its pronounced color is not objectionable Amosite also imported from South Africa is used primarily in thermal So she Coden ute Society's Man- agement Seminar held Golden San Francisco Man- JuneMetals Div Niagara Falls N.Y. 14302 VOL 47 No. 611 December 1975 Asbestos has served mankind for for which no replacement is readily more than 100 years in a broad vari- available shows that ety of applications The general areas ' The information in Table 1 shows _ in which asbestos is used in the U.S. that the use chrysotile asbestos and are shown in Table 3. Based on infor- its share of the total market are stead- - mation from asbestos producers and ily increasing This is due partly to consumption surveys it is estimated that the plastics about industry uses technical advances permitting the broader use of chrysotile in plastics 33 of the 800,000 tons consumed an- | nually which makes it the largest " asbuse er s of t asbo estsos fiber The largest uses of asbestos by the and the general decline in the use of asbestos in certain fireprooafndining- sulating materials In addition there is increasing evidence that crocidolite plastics industry are in asbestos and amosite are more hazardous to sale OREN ee meme eR ee - ee ae an mimes a ~ -19 -19 a Year 1967 1968 1969 1970 1971 * Table AppaApparrent ent U.S. ConsCuonsmumpptiton ion of AsbesAsbtesotoss Tons Total + Chrysotile Amosite Crocidalite 720,583 817,563 784,321 728,131 " 686,044 95 775,711 12,558 14,917 20,467 13,965 1.7 10,558 3/5 749,708 96 > 3" 14,618 1.9 5 1.3 > =~695,770 96 ~* 14,261 2.0 ce. *. 8,9361.2 < . _ 6,953 0.9 Table Apparent U.S. Consumption of Asbestos By General Use Areas Area of Use General Percent of Consumption * 7 ; Friction and packing - 1972 and a Information on import production Bureau of Mines Minerals Yearbooks - parentheses b Percent of total shown in parentheses = A ery 3 _ Insulation rievo we take< f Pi Textiles 22.2 8 wherever possible cigaretteftisbhmeaorkting atndhelung cwahnocehravaes is evidenceon of an aosfsocmimaaintxeiytvouinyrdeeoeasfnrcsmmeieansgeoso- . Hazard -- caused solely of excess risk aasbsesb tosestAnoothser evidence - chrysotile yon caused solely inhalation inhalation cers aeo,f StEhHe Inta ernationaA l gAe gennc cyy for ' oC human health than chrysotile Since or by inhalation :* cers Research Cancer a division of the 1970 the use of crocidolite in Britain _ * important con-- World Health Organization There has been restricted after panel of sideration is the relation between ; . * experts concluded there was suffi Dr. E. C. Hammond and thelial tumors with air pollution in cient evidence to suggest other types reported by Selikoff In this study they the neighbcroocidr olithe ood of fibre should be substituted for Dr. I. J. __ seems clear then :,'" and of factories using * as- crocidolite reported It bestos fiber types The re ., on any SeDAD aR at GE 2 . that lung cancer is wuonrckoermsmon among ... lates to conditions of ~~ What isthe Asbestos Hazasbar_~*d * insulation _ and There is history of cigarette smoking . of no .- = is accepted if the asbestos air . It readilyreadily that asbestos . no that risk increased such in- of mesotheliomas from 7. is not great neighborhood like many other foreign bodies can +" crease increased =-- venta EER te mt Seth A tate neighborhood mesothelioma and amo + neighborhood of chrysotile amo - mesothelioma mesothelioma has cause disabling lung damage pul- ttohird disease mesothelioma mesothelioma commonly mesothemelsoithoelmioama as asbestosis This disease and raasorciateed of bronchogenic carcinoma lung can- mesothelioma .persons erecntxly poesedxposbedeen asbesMteosos- ences on .persons is s is an extremely or causesof thelioma common as- cer are the two most ~ related diseases It isimportant peritoneum to note that based on epidemiological In contrtao sthte diseases the data these diseases have occurred . that primarily in workers with high long ent term exposures to asbestos dust It is high fiber and noted.re- noted.re- of further interest that one not in- searcher has reported that neither of these diseases is peculiarly related to of the lining of the chest pleura or . the abdominal cavity lung there + is some evidence mesothelioma can occur after brief exposures to relatively levels According to the member Ad- visory Committee on Asbestos Can- oe ypog _ deyTt dertoais 4. also also concluded that no evidence of lung damage by asbestos to the general public such evidence as there is does dicate any risk of cancer resulting . < =". zt <! - from asbestos fibers present in water . Minerals Minerals >< beverages food or in the fluids used 2+". ~ 3 Table Comparative Data for Asbestos ~~ for the ~ re. administration druggseneere"al of Formula the is oF Chrysotile Crocidolite Amosite 7 Anthophyllite 85O 3MgO2SiO No 1O .5MgO 7M O While While seems be vO that public not <. . 2" -* agreement = asbestos it is also that excessive long- danger from Composition % : ~ 49-53 49-53 ON 56-58 "' any present recognized 56-58 term SiO we 37-44 ne 49-53 we - a 34 i! - occupational exposure can cause man- | MgO 39-44 Ong Cele" 54-44 ! too 2 uo problems Also man- FeO Los i 13-202 F 1: made emissions are not controlled . - Fe Al -O HO i . . + -5 " -- 12-15 7 2-5 ; | 29 sreg. gg. nT Be %a : tA. ez Dat tet Ome W6 C O Na 22 7%" NaO aA Ste oe me Crystals -. Fine fibers __ " Color Gray green _ Texture Soft silky Brittle fibers Blue Harsh . Good - -- Prismatic . brown Harsh Good Prismatic Gray Harsh Poor Flexibility ; Hardness mohs Fiber diameter A Tensile mpsi . .. . 254 .180-300 800 Positive 4 600 5.5-6 - 600-900 - 200 " . Negative . 5.5-6 Surface charge . Resistance to acid Resistance to alkali Poor Good Good _ Fair eo ead . Good .vig ~ - mee . v Plastics Encyclopedia 1978 and Encyclopedia of Chem a Sources Modern Tech Vol 2 could could approach harmful levels - been enacted by the During the past two years significant legislation has reduce ~ and Federal government to control occupational expostuoraes- environment Addi- bestos fibers emissions to the tional standards environment environment or regulations have been proposed enacbt y e mad ny states and local .E . a ne on Summary of OSHA Regulations The William Occupational on Safety and Health Act of 1970 be- came effective April 28 1971 with repo ,7e wre Journal of Paint TechnolOGY * the following Congressional purpose Improper interpretation of the reg- EPA Standards mercury identified employees To assure so far as possible every ulations has created many miscon- Whereas OSHA is responsible for working man and woman in the na- ceptions about equipment and pro- the protection of the worker the En- tion safe and healthful working con- cedures needed to properly use vironmental Protection Agency EPA ditions and to preserve our human asbestos If exposure limits are not is charged with improving the en- resources The Act established the 1 exceeded there are no further com- vironment to which the general public Occupational Safety and Health Ad- pliance requirements except for med- is exposed On March 31 1971 as- | ministration OSHA within the De- ical examinations Medical examina- ; bestos along with beryllium and partment of Labor which has re- tions are required for all ; " hazard- was sponsibility for administration and | in any occupation airbtooairrbnornee 3 . mercury ous air the " pollutant by the Administra- Administra- we ~. The enforcement Research and related concentrations of asbestos fibers =. of the Emission 2 relatively simple and EPA National functions are handled by the Depart- examinations are asbestos were ~ no tor . Standards for then pub- ment of Health Education and should cost more than 50 per the National ' year per emplop yeere -- lished by EPA in Federal Regis- than the fare HEW through ~ and year Respirators employee clothing , ter Vol 38 No. 66 April 8 1973 Institute of Occupational Safety Respirators and special clothing Although no numerical operating stan- ~ dards were Health NIOSH Five million em- are required in the construction trade established operating ori- ployers and 60 million of the nation's for the spray application of insulation teria are prescribedprescribemisionsetdo prevent out- or .. - 80 million workers are covered ~ and fireproofing materials and the limit asbestos emissions the out- - OSHA Specifically excluded . from removal of such materTihias lspse- ; side air from asbestos mills roadways ~: coverage are government employees cial protection is not required for any certain manufacturing operations - . unless exposure and operations which are protected other use of asbestos ~ building demolition and the spray under other federal health and safety - limits are exceeded This is also true application of materials used to in= ->. for other as laws In a news release issued January items such specially sulate or fireproof equipment and. 4 1972 OSHA announced a Target change equipped tools change rooms clothes machinery The law further requires -. aimed disposalRes- that spray materials used to in- wimiptrohvinwgorHkainzgards factors asociated ;=,laundareeriang conditions The follow- pirators not substitute en- sulate or fireproof buildings struc- TS shall.con ~ substances were but the law allows tures pipes conduits shall.con ing five designated gineering .. on 7 implemented use while controls situations situations tainless than This asbestos significantly to be the focus of initial and con- implemented controls special situations weight basis This should significantly -" asbestos cotton dust silica lead and the time new At present standards have been established established only for asbes tos although of the 8,000 toxic substances on the NIOSH list only 500 are covered by standards and many of those need updating The new Standard for Exposure to Asbestos Dust was published in the Federal Register Vol 37 No. 110 on June 7 1972. The basic exposure standard is an hr time weighted average TWA of five fibers longer than 5 micrometers per cubic centimeter of air The TWA limit is to be reduced to two fibers per cubic centimeteorn July 1 1976. A peak concentration of 10 fibers per cubic centimeter is not to be exceeded at any time All of the fiber concentrations are those to which an employee may be exposed without protective clothing and equipment The first basic require- adequate emergencies for eral public may exposed especially adequate in and large urban Administrator frequent short assignments in Administrator of EPA required + Caution labels are required on prod- the Administrator of EPA =". ucts containing asbestos except where has determined that in order to pro the fibers have been modified by bonding agent or other material to prevent dusting during any normal subsequent use or handling Besides raw asbestos fiber products which vide an ample margin of safettyo protect the public health from as- bestos it is necessary to control emis- sions from major made sources . of asbestos emissions into the atmos- require package labeling could in- phere but that it isnot necessary to clude dry acoustical spray products ~ and joint cements unsaturated roof- . . In this determinatitohne Admin- ing felt and textiles and some in- ~ istrator has reloinethde National ~ sulating products made without ade- Academy of Sciences report on as- -- quate binders The labeling of prod- -bestos which concludes is ~ rS uct does not prohibit use It - * here that | should be noted at least the known 90 of the products containing es- bestos the fibers are solidly locked too important in our technology and ~~ economy for its essential use to be stopped But because of - serious effects of uncontrolled inha- into the product thereby presenting little danger of dust generation dur- . lation of asbestos minerals in industry and uncertainty as to the shape ing normal use and handling of the product flee we 7 M eTTT aut 7 one ete < and character of the curve in man it would tpt ar ee * response be highly im- a} ws ment of the new standard is monitor- ing to determine whether or not fiber concentrations are in excess of the pliers provide a monitoring service to customers and a similar service may be obtained from state health depart- af JOHN L. MYERS Marketing Manager for the Calidria Asbestos Group in Union Carbide's Metals Div received his B.S. Degree in Chemical Engineering from Purdue University in 1951. Joining Union Carbide that same year he served in the Nuclear Division until 1966 when he be- ment officials insurance carriers or private consultants The law requires that monitoring be repeated as nec came a Research Engineer in the asbestos group group He was promoted 1970. vw By to his present position in meget cchyaty 7 2 - .. Tanah ake 6 07 essary to ensure that employees are not exposed to levels in excess of the OU BOTT ee ttue. ae Ute? rake ets VOL 47 No. 611 DECEMBER 1975 prudent to permit additional contamination of the public environment with asbestos Continued use at min- Table Typical Air Sampling Results Ceiling | Control Measures Asbestos producers and users are imal risk to the public requires that Type Plant Plant - Concentration spending a considerable amount of the major sources of made as- Or Operation Asbestos Fibers . time and money on various dust - _ bestos emission into the atmosphere and . defined be controlled compoundincgompoundinag eJs oa What IndustryDoing is , similar conversion ___ i Floor Polyester tile. She ebeeet, Polyestercompounding :si Phenoliccompounding * WF. 1-3 Feet tral measures Conventional means to . achieve minimum dust levels include - ~_ equipment local kg equipment local ventilation for saws - and , to ~ =: Associa- Information sealants wetted operation pack- The Asbestos Associa- HanGydpslucmoimpnougncomdpousnds ae aging North America reports that dur- GypsuGmypsum a Source ing the past 30 years the asbestos - a monitoring pel- dustry has spent millions of dollars to < clean more leakproof eS andcsompounds md vacuum care in _ UniwoenyCCaarbirdeboitde Corp. from * air bag disposal and other asbestos waste reports "rw. YENCorp. age, 2h : handling and automatic bag openers _ Unusual innovations includeopeners improve mining milling and manufacturing methods The establishment of safer working conditions has been a able level 10 fibers short avail-aa prime target and this work continues vk aR fae, ee Bt ~ Stale et letized asbestos special packaging is OSHA , 0 ante 4 . and treated products893,05 avail- , able Only chrysotile is In able as pellets but serves . this product unabated and in close association with independent Pellets -- : government agencies and most cases the TWA exposure level a fair portion of asbestos marketSi. would be well below OSHAstan- -7 not only reduce dust during were collected conventional medical researchers independent tet. dards Most of the data *oe handling but they are asbestos special The ultimate goals of the before the installation ofany 15 e Monitoring also available in bulk hopper cars and be industry are Reduction of work control measures of can can transferred and usedin . *. totally _ dust to minimum levels Protection - shows that obviously dusty 7~~ ~ con- enclosed systemsBarring leaksthe asbestos in of workers from dis- ditionscaused bymaterials other system system wor wok rk areas is virtually Used preclude eases Maintenance of environmental ~ than asbestosThis does not f- ieeliminated inbulkasbestos warehouse shipping costs emissions at levels low enough to pre- _ the need for controlsbutit could"* pelletsalso reduce = ; ~ public faciltae shiping clude easdah de _" change their scope and facilitatecom* e. liminate warehouse storageand endangerment sah regulations pliance with government handling facilitate automation reduce Sampling iar Air aX * Becofabau d s pree ss asbestisoscleaunp and eliminate bagbag handling frequently ordered out ofuse without - and The containno withOSHA - or air are be not In order to comply ., regard to whether hazard~binder and friableenough to - " standards and to determine the need actually dispersed dry form . exists dueto air contamina- in or or aqueous 5 " ther o for dust control measures air monitor- tion If acceptable dust levels are or resinoussystems with . conventional ing should be conducted in areas feasible there is no need to replace shear grinding equipment packaging where asbestos is regularly handled asbestos at the expense of product Several types of special _ packaging suppliers or used OSHA standards require that quality or economic penalty Gordon _ are currently available and - Ae: for unus- all determinations of airborne con- Everett of EPA points out that in- consider customer requests centrations of asbestos fibers shall be formation on the biological effects of ~- ual requirements The floor tile indus- - oe made by the membrane filter method asbestos is very limited and that the try can obtain asbestos in plastic bags - at 400-450X magnification 4 milli- effects of many substitutes have not which can be added directly to the meter objective with phase contrast been investigated at all Before as- compounding operation Asbestos in illumination The equipmentthan for bestos is replaced it should be cer- bleached paper bags assembled with collecting air samplescosts less than - stain that avail- . alternative 2 glue printed 2 a safer is soluble with 400 andis readily available A phase dispersible more able ~ begrunde begrunde Bik people .ink canadded ~~. Obviously people more making finishes contrast microscope can be obtained there are directlyto added or containing for as little as 600 or an existing exposed to products _ asbes- - acoustical tile formulations rasng tn Cape , is microscope can be modified for a Tent ~ tos than thereare to raw asbestos ' -, Althoughwetted asbestosis not available counting the asbestos fibers in com- fibers As noted previously more than generally . most . - suppliers pliance with NIOSH criteria . 90 of the asbestos used in this coun- are working with customers to pro- Air samples have been collected try is in products in which the asbes- vide dustless products When justi- and analyzed on a regular basis by tos is locked in or bound with ce- fied by market demand asbestos can the asbestos industry for years Ex- ment plastics or other bindersso be treated with water mineral spirits cept for a few applications where dust that there is no release or at least no __ glycol or other materials > control is an engineering problem in- significant release of fibers in work with the or compatible dustry is finding that dust levels are areas or to the environment Materials eigr application system " already within acceptable standards or products with looked fibers we ~ we Conclusion industry's or that minimum changes are nec- would include floor tile polyester wait essary to achieve compliance Al- industry's though data on many asbestos resins phenolics sealants coatings brake linings friction materials rub- Asbestos is oneof many raw materials which involves a po applications are not available the summary in Table 4 is typical of our ber roofing compounds and reinforced plastics Since an abrading ac- tential hazard when not used with reasonable respect and care Although measurements of dust levels during asbestos handling in various types of plants and operations The dust levels tion on some of these products could " all forms of asbestaorse recognized release asbestos fibers appropriate monitoring and control measures as hazardous to health when inhaled - excessively there is growing evidence reported are ceiling concentrations should be instituted if it is thought that crocidolite and amosite are more and it should be noted that the allow. . that such action would release fibers hazardous than chrysotile Fortunate- TOLINAL OF BAINT TECHNOLO TECHNOLO ly the plastics industry uses primarily chrysotile asbestos and in lockeprdimarily ucts the fibers are to pre- vent airborne contamination Al- though asbestos dust levels are gen- 9 erally lower than expected industry: =':; continues to expend large amounts of no oo, we ee gw Chrysotile asbestos is an important and necessary raw material vital to the nation's safety and economy and : with proper control it can be used - safely and in compliance with govern- ment regulations Medical scientific government and industrial personnel. * References 312 Arch Environ Health 27 Nov. 1973 C. paptarnters ee TES : Ann Hyg 2 Wagner J. C. Occup 15 61 1972 A nn FH Gemsee nad 3 Wright G. W. statement before * ,'_. U.S. Dept. of Labor Occupational Safety and Health hearing on pro- ~ - , . . wot 0 wr Lot i, os . oo, . co . dard March 16 1972 3 _ J. 4 Relation Cigarette Smoking Of Relation Risk of Cigarette Smoking To < Asbestos Death Cigaret e ated Disease among Insulation Workers in the U.S.A. presented at meeting of the Working Group to Assess Biological Effects of As- bestos International Agency for Re- . search on Cancer Lyon France Oct. 4 1972 5 Report of the Advisory Committee Brit on Asbestos Cancers dustr Med 30 180 1973 J. Ina 3.3 Asbestos Safety EOE National News 3.3 Oct. 9. 1973 Emission 3.3 National MVE a Standards for Hazardous Air Pollutants Federal ; Register April ,. 38 66 8820 No. Worker 8 P1rot9ect7ing3 Protecting "the Asbesr toe s e eae) wt Booklet No. 101D The Asbestos Association . Industr 9 Medicine 10 Information America p 5 Selikoff I. J. 39 No. 4 21 April 1970. Standard for Exposure to Asbestos Dust Federal Register 37 No. 110 11 , , et al Procedures EquipmentMillipore for Mounting Asbestos Fibres Filters and Counting Equipment Fibres by Contrast Microscopy Bureau of Occup Safety and - Health U.S. Dept. of Health . 1969 cation & Welfare Feb. , 12 Asbestos Health Question_Per- Question_Per- - - . plexeEsxperts EngNews Y AsbestosInformation Association -: N. W. . 2 VAS 1660 L Street ~ VOL 47. No. 611 DECEMBER 1975 Washington C. 20036