Document 1gnw8mwRmQQGpmVQpZObNQoJq

MATERIAL SAFETY DATA SHEET GOOD-RITE^3I90X29 ANTIOXIDANT ISSUED SECTION I Manufacturer^ Name The BFGoodrich Company Chemical Group Address 6100 Oak Tree Blvd. Cleveland, Ohio 44131 Chemical Family Aromatic amines Chemical Name and Synonyms Alky 1 ated diphenylasjjaa,# Telephone Number Trademark SECTION IT - HAZARDOUS INGREDIENTS Residual diphenylamine Amount in Produc t < 22 ACGIH TLV-TWA 10 mg/ta^ OSHA PEL None established Notes: o TLV-TWA: Threshold Limit Value - Time Weighted Average for concentration of the chemical substance in the ambient workplace air. American Conference of Governmental Industrial Hygienists,3BP#^Sition. o OSHA PEL: OSHA Permissible Exposure Limit, 8-hour TWA. o ^ means "less than" BFGl2033 21234071 SECTION III - PHYSICAL DATA (Typical data, not specification*) Boiling Point Not applica'ple Specific Gravity (H20"l) 0.97-1.01 Solubility in Water Negligible Percent Volatile by Weight 0.5% maximum Appearance and Odor Reddish brown liquid. Slight amine odor. SECTION IV - FIRE AND EXPLOSION HAZARD DATA Flash 410F Lower explosion limit: Not known Upper explosion limit: Not known Extinguishing Media Water. ABC dry powder. Protein type air foams. Carbon dioxide may be ineffective on larger fires due to a lack of cooling capacity which may result in reignition. Special Fire Fighting Procedure Positive pressure self-contained breathing apparatus should be used. Personnel not having suitable respiratory protection should leave the area to prevent significant exposure to toxic combustion gases from any source. Unusual Fire and Explosion Hazards None known SECTION V - HEALTH HAZARD DATA Threshold Limit Value None established Effects of Overexposure None expected Emergency and First Aid Procedure IN CASE OF EYE CONTACT: Flush eyes with plenty of water for at least five (5) minutes while holding eyelids open. See a physician. IN CASE OF SKIN CONTACT: Wash the affected area with plenty of soap and water. See a physician. IN CASE OF INGESTION: Induce vomiting by sticking finger down throat or by giving Syrup of Ipecac. See a physician. IN CASE OF INHALATION: Not applicable. ZAOfrGZTZ BFG12034 SECTION vr - REACTIVITY DATA Stability Stable Hazardous Polymerization Will not occur Hazardoua Decomposition Products CO, CO2, oxides of nitrogen, and small amounts of aromatic and aliphatic hydrocarbons. avoid) Reacts with strong oxidizing agents such as hydrogen peroxide, permanganates and perchlorates. Contact can result in intense heat, boiling, flame development, explosion or toxic gas generation depending on the amount and specific materials involved. SECTION VII - SPILL OR LEAK PROCEDURE Steps to be taken in case material is released or spilled Dam-up spill. Absorb with an inert material such as sand, sweeping compound or a commercial absorbent. Place into container for disposal. Wash the spill area with soap and water. Do not flush chemical into public sewer or water system. in accordance with federal, state and local SEcprfcoduct is not defined or designated as hazardous of the Federal Resource Conservation and 'CRA). 40CFR261. SECTION VIII - SPECIAL PROTECTION INFORMATION Ventilation ugiaust ventilation should always be provided to draw fumes jmttf from workers to prevent routine inhalation. Ventilation should be adequate to maintain the ambient workplace atmosphere below the TLV listed in Section II. Respiratory Protection Wear a NIOSH/MSHA approved respirator whenever exposure to fumes or vapors exceed the TLV listed in Section II. Prot * ~ ' -Wea -We a SECTION IX - SPECIAL PRECAUTIONS -Wash thoroughly after handling. Always wash-up before eating, smoking or using toilet facilities. -Keep container closed. -Loosen bung before heating drum. -Store at a temperature above 72F (22C) to prevent crystallization. BFG12035 HN I SBCTIOW X - TRANSPORTATION For transportation purposes, this product is not defined or designated as a hazardous material by the U.S. Department of Jr.-igs-partatinn under Title 49 of the Coda of Federal Regulations, Y'9$0-Edition. USER'S RESPONSIBILITY A bulletin such as this cannot be expected to cover all possible individual situations. As the user has the responsibility to provide a safe workplace, all aspects of an individual operation should be examined to determine if, or where, precautions, in addition to those described herein, are required. Any health hazard and safety information contained herein should be passed on to your customers or employees, as the case may be. BFGoodrich must rely on the user to utilize the information we have supplied to develop work practice guidelines and employee instructional programs for the individual operation. DISCLAIMER OF LIABILITY As the conditions or methods of use are beyond our control, we do not assume any responsibility and expressly disclaim any liability for any use of this material. Information contained herein is believed to be true and accurate but all statements or suggestions are made without warranty, express or implied, regarding accuracy of the information, the hazards connected with the use of the material or the results to be obtained from the use thereof. Compliance with all applicable federal; state and local laws and regulations remains the responsibility of the user. 21294074 6981E/wp BFG12036 6ood-rite" CHEMICALS MATERIAL SAFETY DATA SHEET Good-rite 3190 Antioxidant April, 1980 SECTION I Manufacturer*3 Name The BFGoodrich Company Chemical Group Address 6100 Oak Tree Blvd. Cleveland, Ohio 44131 Chemical Family Aromatic amine Chemical Name and Synonyms Alkylated diphenylamlnes, Antioxidant Telephone Number (216} 524-0200 Trademark Good-rite 3190 Antioxidant SECTION II - HAZARDOUS INGREDIENTS Residual Dlphenylamlne, 2 in Product < 22 TLV-TWA* 10 mg/*3 * American Conference of Governmental Industrall Hygienists, 1979. Note: <, means "less than" SECTION III - PHYSICAL DATA Boiling Point Not known Specific Gravity (H2O-I) 0.99 Solubility in Water Negligible Percent Volatile by Weight 0.52 maximum Appearance and Odor Reddish brown liquid. Slight amine odor. BFG12037 W H* to CjS 4* in B.F.Goodrich Chemical Company/6100Oak Tree Blvd., Cleveland, Ohio 44131 ^REGoodrich Printed in U S A The information contained herein 1$ believed to be reliable. Dot no representations, guarantees, or warranties of any kind are made as to its accuracy, suitability for particular applications or the results to be obtained therefrom. Nothing contained herein is to be considered as permission, recommendation, nor as an inducement, to practice any patented invention without permission of the patent owner. SECTION TV - FIRE AND EXPLOSION HAZARD Flash Point 4.10F (Cleveland Open Cup) Extinguishing Media Water spray. ABC dry powder and protein type air foams. Carbon dioxide may be ineffective on larger fires due to a lack of cooling capacity which may result in reignition. Special Fire Fighting Procedure Positive pressure self-contained breathing apparatus should be used. Personnel not having suitable respiratory protection should leave the area to prevent significant exposure to toxic combustion gases. Unusual Fire and Explosion Hazards None known SECTION V - HEALTH HAZARD DATA Threshold Limit Value None established Effects of Overexposure None expected Emergency and First Aid Procedures IN CASE OF EYE CONTACT: Flush eyes with plenty of water for at least 5 minutes. If irritation develops, see a physician. IN CASE OF SKIN CONTACT: Wash area with plenty of soap and water. If irritation develops, see a physician. IN CASE OF INGESTION: Induce vomiting by sticking finger down throat or by giving syrup of Ipecac. See a physician. IN CASE OF INHALATION: Not applicable. fC h* 2- - o BFG12038 SECTION X - TRANSPORTATION INFORMATION For transportation purposes, this product is not defined or designated as a hazardous material by the U. S. Depart ment of Transportation under Title 49 of the Code of Federal Regulations, 1978 edition. USER'S RESPONSIBILITY A bulletin such as this cannot be expected to cover all possible individual situations. As the user has the responsibility to provide a safe workplace, all aspects of an individual operation should be examined to determine if or where precautions, in addition to those described herein, are required. Any health hazard and safety in formation contained herein should be passed on to your customers or employees, as the case may be. BFGoodrich must rely on the user to utilize the information we have supplied to develop work practice guidelines and employee instructional programs for the individual operation. DISCLAIMER OF LIABILITY As the conditions or methods of use are beyond our control, we do not assume any responsibility and expressly disclaim any liability for any use of this material. Information contained herein is believed to be true and accurate but all statements or suggestions are made without any warranty, express or implied, regarding accuracy of the information, the hazards connected with the use of the material or the results to be obtained from use thereof. 4-- - BFG12039 21294077 SECTION VI - REACTIVITY DATA S tability Stable Hazardous Polymerization Will not occur Hazardous Decomposition Carbon monoxide, carbon dioxide, oxides of nitrogen and aromatic and aliphatic hydrocarbons Incompatibility None known SECTION VII - SPILL OR LEAK PROCEDURES Steps to be taken in case material is released or spilled; Dam up the spill. Absorb spill with inert porous material. Shovel into containers for disposal. Wash the spill area with soap and water. Do not flush chemicals into a public sewer. Waste Disposal Method Sanitary landfill or incineration in accordance with federal, state and local regulations. SECTION VIII - SPECAIL PROTECTION INFORMATION Ventilation Ventilation should be adequate to maintain ambient atmosphere below the 10 mg/m3 TLV for diphenylamine. Protective Equipment - Wear rubber gloves - Wear chemical splash goggles SECTION IV - SPECIAL PRECAUTIONS v - Wash hands thoroughly after handling containers. Always wash up before eating, smoking or using toilet facilities. - - Keep container tightly closed^ - Loosen bung before heatingsdrum. - Store at temperature jibove 72F to prevent crystallation of product. 8Q &6ZTZ -3- BFG12040