Document 1gjo8GLL60jxVJwzE6qbga4B5

ALLOY ROOS CORPORATION MATERIAL SAFETY DATA SHEET (MSOS) For Welding Consumables and Related Products Complies with OSHA Hazard Communication Standard 29 C.F.R. 1910.1200 SECTION I . IDENTIFICATION Identity! DUAL SHIELD T-1 AND T-2 FLUX CORED WELOIMC ELECTROOES Manufacturer's Name! ALLOY ROOS CORPORATION Emergency Telephone No. - 717/837-8911 Address! P. 0. Box 517, Wilson Avenue, Hanover, PA 17331 Telephone No. for Inforautlon - 717/837-8911 Product Trade Name(s): OUAL SHIELD SP, T-63, and 110 7-62} 7-62 Hf} 78; IIIAj 111A-C; 111HD; 111-10; 7000; 1171; R-70; ACF-63; 7100; II 70| 111RB; II 70LC T-8; 78 Mo; 88-C3| 88CM; 88CH-MC; T-90C-1; 98; 98CM; 88-F3 98CM-HC; T-100; 150; 151; 7000-A1; 8000C-3; 800061; 900001; MET 2W 8000N12; II-101TM; 9000M; 9000C1; 900063; 800062; II 110 II 100; II 90-K2; II80N1-1; 8100W; 88W; 9100K2; 11 100-D1; T-4130; ANO DH-80 Product Classtflcatlon(s)i AWS AS.20, E70T-2 (SP, T-63, and 110) AWS AS.20, E70T-1 - T62 THtU II 70LC THE FOLLOWING ARE ALL AWS AS.29; E110T1-C; E80T1-A1; E80T1-N11; E80T1-B2; E80T1-B2H; E90T1-N12; E90T1-K2; E90T1-63; E80T1-C E90T1-83H; EIOOTI^K); E90T1-03; E80T1-82; E81T1-A1; E81T1-N11; EB1T1-B1; E91T1-01; NOT CLASSIFIED E81T1-N12; E91T1-C; E91T1-K2; E91T1-N12; E91T1-83; E81T1-B2; E110T1-K3 E101T1-K3; E91T1-K2; E81T1-N11; E80T1-W; E80T1-W; E91T1-K2; E101T1-C; E120T1-K5; NOT CLASSIFIED SECTION II - HAZARDOUS INGREDIENTS IMPORTANT THIS SECTION COVERS THE MATERIALS FROM WHICH THE PRODUCT IS MANUFACTURED. THE FUMES AND CASES PROOUCED OURINC WELDING WITH NORMAL USE OF THIS PROOUCT ARE COVERED IN SECTION V. THE TERM "HAZARDOUS- IN "HAZARDOUS MATERIALS" SHOULD BE INTERPRETED AS A TERM REQUIRED AND DEFINED IN OSHA HAZARD COMMUNICATION STANDARD (29 C.F.R. 1910.1200) ANO IT OOES NOT NECESSARILY IMPLY THE EXISTENCE OF ANY HAZARD. _________ Ingredient Iron Silicon 10) Molybdenum cm Cooper (E) (C) Quartz (CAS No.) (7439-89-6) (7440-21-3) (7439-98-7) (7440-50-8) (14808-60-7) Exposure Limit mg/M3) 5 Source ( 2) 10 ( 2) 5 ( 2) 1 (Dust) ( 1) 0.1 ( 2) Innredlent (CAS No.) Manganese (A) Chromium [Crl (7439-98-5) (7440-47-3) Nickel"' [Nil 1C) Tltanl'im Dioxide (F) ICJ Sodium Tltanafm (7440-02-0) (13463-67-7) (N/A) Exposure Limit ' mg/H3J 5 cl 0.5 1 10 (N/A) Source ( 1) ( 2) ( 2) ( 2) ( 3) 1. Occupational Safety and Health Administration, 29 C.F.R. 1910.luOO Permissible Exposure Limit (PEL). 2. American Conference of Governmental Industrial Hygenlsts (ACCIH) Threshold Limit Value (TLV[R]j. 3. Not known; nuisance particulate concentration per ACCIH Is 10 mg/M*. (A) In T-8, 88CM, 98CH, 98CH-MC, 151, 9000B3, 800062, 8100W, 88W, T-4130, MET 2W, 800001. (B) In T-8, 78M0, 88CM, 88CM-MC. 98. 98CM, 98CH-MC, T-100, 150, 151, 7000AJ, 9000M, 9C00B3, 8000B2, 11-110, II 100, 9100K2, T-4130, DH-80, ML I ZW, 800061, 900001. (C) In T-8, 88C3, 88F3, T-90C-1, 98, T-100, 8000C3, 8000N1-2, II 101-TM, 90OOM, 9nonci, TT 110, II 100, TT 90-K2, 8100W, 9100K2, T4130, DH-80. (D) In 8100W, 88W. (E) In SP, T-63, 78, T-8, 880, 88CM, 98, 98CM, 98CM-HC, T-100. (F) In II 71, II 70, II 70LC, II 101-TM, 900063 , 800062, II 110, II mu, II 80N1-1, II (G) Not m PH-3C. 8 vt' >U ; C . SECTION III - PHYSICAL DATA NOT APPLICABLE section ;v - f;rl an:; :x'io:ich h- z.r:> oata arc and ip.uks o. n Irg.i o V: i. '. 1 n. ; . 'e- r ! r; rrenceu In Section /ii. 1 _J 00 A 06153? CONFTDFNTTAL r I if V - B'^n r'v b*t . I Ii HAZARDOUS decomposition PWtxxxr.S: Welding fines cannot be classified simply. The composition ami quantity of both are dependent upon the etal being welded, the process, procedures and electrodes used. Other conditions which also Influence the composition and quantity o' <*s me gases tn <*h!rh workers may be exposed Include: coatings on the etal being welded (such as paint, plating, or galvanizing), nunber of welds and volume of work area, quality and amount of ventilation, positionof welder's head with respect to the fine plune, as well as the presence of contaminants In the *tmninhre (such as chlorinated hvrtrivxrhnn vapors from cleaning and degreasing activities. When the electrode Is consumed, the fine and gas decomposition products are dlffererent in percent and form from the ingredients listed in Section II. Fume and gas decomposition products, not the ingredients in the electrode, are Important, Drcnmnosltlon products Include those nrlqtnatlng from the volatilization, reac tion, or oxidation of the materials shown in Section II plus those from base metal, coating, etc. as noted above. These components are virtually always present as complex compounds and not as metals (Characterization of Arc Welding Fume: American Welding Society). Reasonably expected fine constituents from these products would include: complex oxides of Iron, manga nese, silicon, copper, and in the case of Spoolarc 87 (AWS ER8090-2), molybdenun. Caseous reaction products may Include carbon monoxide and carbon dioxide. Ozone and nitrogen oxides may be formed by the radiation from the arc. One recownended way to determine the composlt'nn and quantity of fuses and gases to which workers are exposed Is to take an air sample inside the welders helmet, if worn, or In the worker's breathing zone. ANSI/AWS F1.1, available fnmi the American Welding Society, C.u. box 351040, Miami, Fl 33135. SECTION VI - HEALTH HAZARD DATA Threshold Limit Value: The ACCIH recommended general limit for welding fume HOC (Not Otherwise Classified) Is 5 mg/H3. The AlJClH 1984-85 preface states: "The TLV-TWA should be used as guides In the control of health hazards and should not be used as firm lines between safe and dangerous concentrations." See bectlon V for specific fuse constituents which may modify this TLV. 1 Effects of Overexposure: FUMES AND CASES can be danaerous to your health. SHORT-TERM (ACUTE) OVEREXPOSURE to welding runes may result In discomfort such as: dizziness, nausea, or dryness or irritation of nose, throat, or eyes. LONC TERM (CHRONIC) OVEREXPOSURE may lead to slderosls (Iron deposits In the lung) and is believed by some investigators to affect pulmonary function. ARC RAYS can Injure eyes and burn skin. ELECTRIC SHOCK can kill. See Section VII. Emergency 8 First Aid Procedures: Call for medical aid. Employ first aid techniques recommended by the American Red Cross. CarcinoQenicitv ----- RTF?-----None I ARC MonoqraphsV None U5HA HeoulatedY None SECTION VII - PRECAUTIONS FOR SAFE HANDLING AM) USE/APPLICABLE CONTROL MEASURES Read and understand the manufacturer's Instructions and the precautionary label on this product. See American National Standard Z-49.1, Safety In Welding and Cutting, published by the Aiaerlcan Voiding Society, P.0. Box 351040, Miami, FL 33135 and OSHA Publication 2206 (29 C.F.R. 1910), U. S. Government Printing Office, Washington, D.C. 20402 for more detail on many of the following: Ventilation: Use enough ventilation, local exhaust at the arc, or both, to keep the fuses and gases below the ilV's in the worker's breathing zone and the general area. Train the welder to keep his head out of the fuses. Respiratory Protection: Use respirable fume respirator or air supplies respirator when welding In confined space or where local exhaust or ventilation does not keep exposure below TLV. Eye Protection: Wear helmet or use face shield with filter lens. As a rule of thusb, start with a shade which" litoo dark to see the weld zone. Then go to the next lighter shade which gives sufficient view of the weld zone. Provide protective screens and flash goggles. If necessary, to shield others. Protective Clothlnq: Wear head, hand and body protection which help to prevent Injury from radlaton, sparks and electrical snoctc. See ANSI Z-49.1. At a minimum, this Includes welder's gloves and a proteclve face shield and may Include arm protectors, aprons, hats, shoulder protection, as well as dark substantial cloth ing. Train the welder not to touch live electrical parts and to Insulate himself from work and ground. Procedure for Cleanup of Spills or leaks: NOT APPLICABLE We-* 0!oo3il Method: Prevent waste from contaminating surrounding environment. Discard anv or.->duct, reslJue. disposable container, or liner In n nvronme"tlly ecceotsble --r. '- '-'.l ------:.` .' HSDS-1.3-.4 OO A 061533 CONFIDFNTTAL